六、發明說明： 【發明所屬之技術領域】 本發明係關於一種4膜洛顧用構件，特別是關於一種凝结 管及過賴組，應用於空氣間隙薄膜蒸顧（air-gap memb_ distillation; AGMD)，且可提高薄膜蒸餾之通量（flux)，進而 提高蒸餾速度。 【先前技術】 薄膜蒸德’係藉由一可通過蒸氣但不通過液體之多孔性薄 膜將一高溫液體與一低溫液體隔開進行蒸餾過程。利用薄膜蒸 顧之方法通常可分類為直接接觸薄膜蒸餾（direct_c〇nt'ac't membrane distillation; DCMD)、空氣間隙薄膜蒸餾（aif_gap membrane distillation; AGMD )、空氣掃掠薄膜蒸餾 (sweeping-gas membrane distillation; SGMD )及真空薄膜▲餾 (vacuum membrane distillation; VMD )四種。其中空氣間 jj家薄 膜蒸餾具有最高的熱效率，已應用於各種從水中分離非揮發性 成分，例如海水淡化系統，而且亦適合應用於在DCM〇法無 法分離之某些揮發性成分，例如從水溶液中分離出酒精。但是 介於薄膜與凝結表面之空氣間隙，造成質量傳輸時的阻礙而使 AGMD的滲透通量降低。國際專利W〇86〇7585A揭露一種 AGMD式蒸顧設備’指出空氣間隙的厚度必須為〇2〜 1.0mm，以提高流速及降低熱損耗。 目^，關於空氣間隙薄臈蒸餾的理論及實驗的文獻，雖然 有各種尚滲透薄膜之製造及設計的報導，但是迄今工業上沒有 實用化的空氣難細細（AGMD)模喊㈣，由於薄膜 蒸餾為非等溫過程（isothermal pr〇cess )，因此薄膜蒸餾的設計 不僅需要提供良好的流動條件、低廢差及高堆集密度（paddng density) ’而且需要保證良好的熱回收功能及熱穩定性。雖然 在板框式模組（plate and frame m〇dule)中(Liu，G L ; zhu，c;VI. Description of the Invention: [Technical Field] The present invention relates to a 4-membrane member, in particular to a coagulation tube and a group for use in air-gap memb_ distillation; ), and can increase the flux of the thin film distillation, thereby increasing the distillation speed. [Prior Art] The membrane vaporization process is carried out by separating a high temperature liquid from a cryogenic liquid by a porous membrane which can pass through a vapor but does not pass through a liquid. The method of film evaporation can be generally classified into direct contact membrane distillation (DCMD), af_gap membrane distillation (AGMD), and air-sweeping membrane distillation (sweeping-gas membrane). Distillation; SGMD) and vacuum membrane distillation (VMD). Among them, air-to-air thin film distillation has the highest thermal efficiency, and has been applied to various non-volatile components separated from water, such as seawater desalination system, and is also suitable for application to certain volatile components that cannot be separated by DCM, such as from aqueous solution. Separate alcohol from it. However, the air gap between the film and the condensed surface causes an obstacle in mass transfer and reduces the permeation flux of the AGMD. International Patent W〇86〇7585A discloses an AGMD type steaming device' indicating that the thickness of the air gap must be 〇2 to 1.0 mm to increase the flow rate and reduce heat loss.目^, the literature on the theory and experiment of air gap thinning distillation, although there are reports of the manufacture and design of various infiltrated films, so far there is no practical air-to-fine (AGMD) model in the industry (4), due to the film Distillation is a non-isothermal process (isothermal pr〇cess), so the design of thin film distillation not only needs to provide good flow conditions, low waste difference and high paddng density 'and needs to ensure good heat recovery and thermal stability. . Although in the plate and frame m〇dule (Liu, G L ; zhu, c;
Cheng, C. S., Leung, C.W., Theoretical and experimental studies on air gap membrane distillation. Heat Mass Transf. 1998. 34, 329) 平板薄膜顯示最高的滲透通量’但是單一模組薄膜的比表面積 為最低。另一方面，雖然使用中空纖維之模組(Cheng，L H ; Wu， P.-C.; Chen, J. Numerical simulation and optimal design of AGMD-based hollow fiber modules for desalination. Ind. Eng. CTzew.版2009, 48, 4948)可具有最高的堆集密度，但因為纖維 的直徑對長度的比而導致沿著纖維的壓差為最大。 因此，如何提高薄膜蒸餾模組或系統之通量，以達到 實用化的需求，乃目前產業界亟欲發展的技術重點。 【發明内容】 鑒於上述之發明背景，為了符合產業上之要求，本發明之 目的之一在於提供一種新的凝結管及過濾模組，可提高空 氣間隙薄膜蒸餾之通量。 本發明之目的之一在於提供一種凝結管，應用於空氣間 隙薄膜蒸餾模組時，除用於支持薄膜外，可提供各種空氣間隙 的厚度及數目，藉由調整這些可變結構，可提高滲透通量。 本發明之目的之一在於提供一種過濾模組，藉由結合 電能、太陽能、廢物轉化能源作為提供溫度梯度之能量 來源，進行薄膜蒸餾，達成各種過濾處理之效果。 本發明之特徵在於揭露一種凝結管，其係用於薄膜蒸 餾之凝結用構件，該凝結管包含：一中空芯體，具有—中空隔 間；一多孔隙外殼，具有氣體滲透性但不透過液體；以及一凝 結室（chamber )’係由該中空芯體與該多孔隙外殼之間的空間 所構成’包含一與外部連通之出口，且該凝結室包含沿該^芯 體間呈放射狀設置之複數鰭片，該複數鰭片將該凝結室分隔成 複數凝結隔間（condensation compartments ；)。 本發明之另一特徵在於揭露一種過滤模組，用於勝 蒸館，該過濾模組包括：一中空芯體，具有一中空隔間.一多 孔性薄膜，具有氣體滲透性但不透過液體；一外殼，具一入 口’以便提供-流體進行過滤；一蒸發室，係由該多孔性薄戚 5該外殼之間的空騎構成’無外殼的該人σ連通，該 ,接收來自外部的熱源，以蒸發該流體；以及一凝結室 (condensation chamber)，係由該中空芯體與該多孔性薄^ 間的空間所構成’包含一與外部連通之出口，且顧結室包 芯Μ呈放射狀設置之複，該複㈣將該凝 ^至彳刀隔成複數凝結隔間（condensati〇n c〇mpartments )。 —本發明之另一特徵在於揭露一種過濾模組，用於薄膜 洛潑，該過_組包括：一外殼，具有一入口，以便提供^ 體進行過遽，複數中空芯體，該中空芯體分別具有一中 中空隔間互相連通；複數多孔性薄膜，具有氣體滲透 及—蒸發室’係由該些多孔性薄膜與該外 ίϋ1所構成，與該外殼的該人σ連通，該蒸發室接收 來自外部的熱源，以蒸發該流體；複數凝結室，其中每一凝結 =由：中空芯體分別與一對應之多孔性薄膜之間的空間戶； 構成，各凝結室包含-與外部連通之出口，該些出口互 通、，且各繼室包含沿該中空频呈放射狀妓之複數鰭片， 該複數鰭片將各凝結室分隔成複數凝結隔間。 模組中’該熱源係可為電阻式加熱器、紅外線 加熱器、太陽能、廢棄物轉化熱能。 於上，過渡模組十，該中空芯體與該複數藉片可為一體成 :為空芯體可由至少一中空管連結而成，該中空管的剖 也kίϊΐ濾模組可應用於水純化系統、鹽水淡化處理系統、 f水淨化系統、血液透析之水處理系統等各種過遽純化處理系 統。 【實施方式】 此揭示一種凝結管及過濾模組。為了能徹 ί 2 ΐίΓ ’將在下觸贿17❹詳盡的步驟及 其構成。地，本發明的施行並未限定於該領域之技 1374052 藝者所熟習的特殊細節。另一方面，眾所周知的構成或 步驟並未描述於細節中，以避免造成本發明不必要之限 制。本發明的較佳實施例會詳細描述如下，然而除了這 些詳細描述之外，本發明還可以廣泛地施行在其他的實 施例中’且本發明的範圍不受限定，其以之後的專利範 圍為準。 一第一圖顯示空氣間隙薄膜蒸餾（AGMD)的基本操作原理 ^示意圖。如第一圖所示，蒸氣從高溫側通過疏水性薄膜及空 軋間隙後，凝結於冷凝表面上。因為滲透通量是薄臈在供給側 (feed side)的絕對溫度及透膜溫度差的函數，為了提高 AGMD的效能以及顯著地降低系統的成本與能量消耗， AGMD的設計必須達成：（i)薄空氣間隙但流暢的質量傳輸 (占g+〆)；（2 )高供給流速（feed flow rate )及供給溫度（fee(j temperature#)); (3)低的低溫侧（凝結侧⑺）；（4)在流動 方向上溫度變動低；（户及产）；（5)有效運用太陽能；（6)容 易運作及維護；以及（7)容易依比例放大。 因此，根據本發明一實施例，提供一種凝結管，其係用於 薄膜蒸餾之凝結用構件。該凝結管包含：一中空芯體，具有一 中空隔間；一多孔隙外殼’具有氣體滲透性但不透過液體；以 及一凝結室（chamber)，係由該中空芯體與該多孔隙外殼之間 的空間所構成，包含一與外部連通之出口，且該凝結室包含沿 該中芯體間呈放射狀設置之複數鰭片，該複數鰭片將該凝結室 分隔成複數凝結隔間（condensation compartments )。 於一實施例中，該多孔隙外殼可包含一多孔性薄膜。其 中，該多孔性薄臈可選自下列之一者或其任意組合：聚四氟乙 稀（polytetrafluoroethylene)、聚偏二氟乙婦（poiyvinyiidene fluoride)。此外，該多孔隙外殼可更包含一網狀物（mesh)， 用以支持上述多孔性薄膜。於另一實施例，可藉由使上述 複數鰭片與該多孔性薄膜接觸的面上具有複數細微構造，例 如複數凹槽（grooves),以支持上述多孔性薄膜，維持該複 6 的。上述凝結管，可更包含—冷卻媒介，流過該中 中1用以提供供給側與凝結側間的溫度差。上述凝結管 可I工心體與該複數縛片可為一體成形。例如該中空芯體 圖管連結而成，該衫管的剖面域片狀。第二 根據本發明—實施例之凝結f 1G的剖面示意圖。如第 1G包含一中找體13、—多孔隙外殼11 14中Ιϋΐ該中空芯體13具有一中空隔間15，凝結室 機絲二、有複數鰭片12。該中空芯體13與複數鰭片12可藉由 質可Α二體成形所構成。該中空芯體13與複數籍# 12的材 依據^金、歸或複合材料’例如銅或工程塑膠， 該中找體13與複數鰭片12的材質必須為 相錄作溫度麵料產生科物之倾。此外，更理 =1成為使，、_供給似凝賴沒*触，亦即達到最高 材ϋ則結侧間的溫度差，依據該原貝，卜在使用不同構成 由調整系統構成的設計，例如中空芯體13的長度、 ^等或則的厚度、寬度等，可以使系統通量最佳化。 第二圖所示的結構示意圖僅為本發明的實施態樣之一， 不^^二騎示的結構示意®，實際的結構會隨使用 的材料、系統設計、應用需求等因素而異。 根據本發邮—實施例，揭露—種過細組，用於薄膜某 德:該過濾模組包括··-中空芯體，具有—中空隔間；一多^ 性薄膜，具有氣體滲透性但不透過液體；一外殼，具有一入口， 以便提供-流體進行過u發冑，制該乡孔性薄膜與該 外威之間的郎所構成，與該外殼賴人^連通，該蒸發室接 收來自外部的熱源，以蒸發該流體；以及一凝結室 (condensation chamber)，係由該中空芯體與該多孔性薄膜之 間的空間所構成’包含-與外部連通之出口，且該凝結室包含 沿該中空芯體間呈放射狀設置之複數則，該複數鰭片將該凝 結室分隔成複數凝結隔間（condensati〇n c〇mpartments)。 於-實施例巾’上賴源可選自τ列之_者或其任意組 合·電阻式加熱器、紅外線加熱器、太陽能、廢棄物轉化熱能。 =-實施财’上述多孔性薄膜可為—多孔性薄膜，該多孔性 f膜可選自下列之一者或其任意組合：聚四氟乙烯 (Polytetrafl_ethylene)、聚偏二氟乙烯（ρ〇ι__6η6 fluoride}。亡述過濾模組’可更包含一網狀物（mesh)，設置 ，該夕$性薄膜上’用以支持該多孔性薄膜，網狀物設置於該 夕孔性薄膜上的方法，例如可將網狀物與多孔性薄膜藉由熱壓 ^合。於另-實施例，可藉由使上述複數則與該多孔性 ，膜接觸的面上具有複數細微構造，例如複數凹槽 ^grooves)，以支持上述多孔性薄膜，維持該複數通道的空 ^。此外，上述過遽模組可更包含一冷卻媒介，流過該中空隔 坍，用以提供供給側與凝結侧間的溫度差。於一實施例中，上 慮模組之中空芯體與複數鰭片可為一體成形，該中空芯體 、°+、、j少一中空管連結而成’該中空管的剖面可為韓片狀。上 組中，該出口_峨集通職多孔性薄膜之流體。 模組，可細於水純化纽、鹽水淡化處理系統、廢 不淨·化系統、或血液透析之水處理系統等。 體地’例如第三_示根據本發明—實施例之過遽模組 立ΐ示意圖，第四（A)圖顯示第三圖所示之過遽模組 思圖’第四⑻圖顯示第四（A)圖所示之過雜 加，/〇 α_α’線之剖面示意圖。過濾模組100包含一中空芯體 i 多孔性薄膜咖、一外殼、一蒸發室·、一凝Ϊ ^-牲^'^口 410 ’位於外殼400上，與外界連通，以便提 ^寺f滤流體進行過濾程序。一出口 610，使凝結室與外部 通過該多孔性_ 300且在凝結t 600凝結之流體，經 610流出過渡模組100。此外，一冷卻媒介（或冷卻 i甘办過該中空芯、體2〇()的中空隔間21G，該中空隔間210藉 心圓柱體結構’經由上下開口與外部連通。 中，’本發明不限於上述空心圓柱體結構，於另一實施例 ，〜中空隔間可具有多邊形空心柱狀結構，其剖面可為其他 複數鰭片i H包含沿該巾找體間呈放射狀設置之 為其他各種形狀2ϋ形狀不限於第四圖所示的形狀，可 可為4、6等|責=的數目不限於第四⑻圖所示1〇片， 模組的設計，例如1鞋=第五圖及第六圖所示，可依據過滤 比）等各種可ΐ件及韓片的形狀、大小（剖面的長寬 參考第= f，進仃調整，使過濾模組的效能最佳化。 = 慮模組1〇0之中空芯體200與複數韓片620為 是，本於明尤可利用一空心銅管藉由機械加工而形成。但 置。例;第七Z此，中空芯體200與複數鰭片620可分別設 及複數鰭片不根據本發明另一實施例之中空芯體200, 體200,可難* ^結構之剖面示意圖。如第七圖所中空芯 且有對摩^、盖；^ ^ f心管沿直徑方向形成複數溝槽而構成，將 i有/fif槽狀之複數則62g，鉗人溝槽巾而固定。而 的大小複數中空管連結所構成，如此可使中空芯體 .ρ,,，長又）任意變化，不受加工機的限制，而且可以降 f本J另一方面更可以使過滤模組容易地依比例放大（scale 叩），達到量產的需求。 此外’於-實施例中，該多孔性細3GG為聚四氣乙稀 _ytetmfluoroethyiene; PTFE)薄膜，而於另一實施例中， 該夕孔性薄膜300可包含一 pTFE薄膜及層合於該多孔性薄膜 之一網狀物（mesh)(未圖示）。 、 根據本發明另一實施例，揭露一種過濾模組，用於薄膜蒸 餾，該過濾模組100,係由複數個上述過濾模組1〇〇所構成，但 僅具有一個外殼。 第八圖顯示根據本發明一實施例之過濾模組1〇〇，的立體 透視示意圖，該過濾模組包括：一外殼，具有一入口，以便提 供一流體進行過濾；複數中空芯體，該中空芯體分別具有一中 空隔間，該些中空隔間互相連通；複數多孔性薄膜，具有氣體 滲透性但不透過液體；以及一蒸發室，係由該些多孔性薄膜與 該外殼之間的空間所構成’與該外殼的該入口連通，該蒸發室Heat Mass Transf. 1998. 34, 329) Flat film shows the highest permeation flux' but the single module film has the lowest specific surface area. On the other hand, although the module of hollow fiber is used (Cheng, LH; Wu, P.-C.; Chen, J. Numerical simulation and optimal design of AGMD-based hollow fiber modules for desalination. Ind. Eng. CTzew. 2009, 48, 4948) may have the highest packing density, but the pressure differential along the fiber is maximized because of the diameter to length ratio of the fibers. Therefore, how to improve the throughput of thin film distillation modules or systems to achieve practical needs is the technical focus of the industry's current development. SUMMARY OF THE INVENTION In view of the above-described background of the invention, in order to meet the requirements of the industry, one of the objects of the present invention is to provide a new condensing tube and a filter module which can improve the flux of air gap thin film distillation. One of the objects of the present invention is to provide a condensing tube which, when applied to an air gap film distillation module, can provide various thicknesses and numbers of air gaps in addition to the supporting film, and can improve the penetration by adjusting these variable structures. Flux. One of the objects of the present invention is to provide a filter module which performs thin film distillation by combining electric energy, solar energy, and waste conversion energy as a source of energy for providing a temperature gradient, thereby achieving various filtration treatment effects. The invention is characterized by exposing a condensation tube for a condensation member for thin film distillation, the condensation tube comprising: a hollow core having a hollow compartment; a porous outer shell having gas permeability but not liquid permeation And a chamber "constituted by the space between the hollow core and the porous outer casing" includes an outlet communicating with the outside, and the condensation chamber includes a radial arrangement along the core a plurality of fins that divide the condensation chamber into a plurality of condensation compartments; Another feature of the present invention is to disclose a filter module for a flash steaming chamber. The filter module comprises: a hollow core body having a hollow compartment. A porous film having gas permeability but not liquid permeable. a casing having an inlet for providing a fluid for filtration; an evaporation chamber for constituting the vacant ride between the casings by the porous membrane 5, the outer casing is σ-connected, and receiving from the outside a heat source for evaporating the fluid; and a condensation chamber formed by the space between the hollow core and the porous thin body, comprising an outlet communicating with the outside, and After the radial setting, the complex (4) separates the condensate into a plurality of condensate compartments (condensati〇nc〇mpartments). - Another feature of the present invention is to disclose a filter module for film sloping, the slab comprising: a casing having an inlet for providing a plurality of hollow cores, the hollow core Each of the hollow compartments is in communication with each other; a plurality of porous membranes having gas permeation and evaporation chambers are formed by the porous membranes and the outer membrane 1 and are in communication with the person σ of the outer casing, the evaporation chamber receiving a heat source from the outside to evaporate the fluid; a plurality of condensation chambers, wherein each condensation = by: a space between the hollow core and a corresponding porous film; each of the condensation chambers includes an outlet that communicates with the outside The outlets are interconnected, and each of the relay chambers includes a plurality of fins that are radially entangled along the hollow frequency, the plurality of fins separating each condensation chamber into a plurality of condensation chambers. In the module, the heat source can be a resistive heater, an infrared heater, solar energy, and waste heat. In the above transition module, the hollow core body and the plurality of borrowing sheets can be integrated: the hollow core body can be connected by at least one hollow tube, and the hollow tube can also be applied to the filter module. Various purification systems for water purification systems, brine desalination systems, f water purification systems, and hemodialysis water treatment systems. [Embodiment] This discloses a condensation tube and a filter module. In order to be able to thoroughly ΐ 2 将 Γ 将 will be under the bribe 17 detailed steps and its composition. The present invention is not limited to the specific details familiar to those skilled in the art. On the other hand, well-known components or steps are not described in detail to avoid unnecessary limitation of the invention. The preferred embodiments of the present invention will be described in detail below, but the present invention may be widely practiced in other embodiments, and the scope of the present invention is not limited, which is subject to the scope of the following patents. . A first diagram shows the basic operating principle of air gap thin film distillation (AGMD). As shown in the first figure, the vapor condenses on the condensing surface after passing through the hydrophobic film and the air gap from the high temperature side. Because the permeate flux is a function of the absolute temperature of the thin feed on the feed side and the temperature difference across the membrane, in order to improve the performance of the AGMD and significantly reduce the cost and energy consumption of the system, the design of the AGMD must be achieved: (i) Thin air gap but smooth mass transfer (g + 〆); (2) high feed flow rate and supply temperature (fee (j temperature #)); (3) low low temperature side (condensation side (7)); (4) Low temperature variation in the flow direction; (household and production); (5) efficient use of solar energy; (6) easy operation and maintenance; and (7) easy scale-up. Therefore, according to an embodiment of the present invention, there is provided a condensing tube which is used for a member for coagulation of thin film distillation. The condensing tube comprises: a hollow core having a hollow compartment; a porous housing 'having gas permeability but not permeable to liquid; and a chamber from which the hollow core and the porous outer shell The space is configured to include an outlet communicating with the outside, and the condensation chamber includes a plurality of fins radially disposed along the central core, the plurality of fins separating the condensation chamber into a plurality of condensation compartments (condensation Compartments). In one embodiment, the porous outer casing can comprise a porous film. The porous thin layer may be selected from one of the following or any combination thereof: polytetrafluoroethylene, poiyvinyiidene fluoride. In addition, the porous outer casing may further comprise a mesh to support the porous film. In another embodiment, the plurality of fine structures, such as a plurality of grooves, may be supported by the plurality of fins in contact with the porous film to support the porous film to maintain the composite. The condensing tube may further comprise a cooling medium flowing through the medium 1 for providing a temperature difference between the supply side and the condensation side. The condensing tube can be integrally formed with the plurality of gussets. For example, the hollow core tube is connected, and the cross section of the tube is in the form of a sheet. Second, a schematic cross-sectional view of the condensation f 1G according to the present invention - an embodiment. For example, the 1G includes a center-finding body 13 and a porous outer casing 11 14 . The hollow core body 13 has a hollow compartment 15 , and the condensation chamber has two filaments 12 and a plurality of fins 12 . The hollow core 13 and the plurality of fins 12 can be formed by forming a two-body. The hollow core body 13 and the plurality of materials 12 are based on a metal, a composite or a composite material such as copper or engineering plastic, and the materials of the body 13 and the plurality of fins 12 must be recorded as temperature fabrics. pour. In addition, the more reasonable = 1 to make, the _ supply is like the condensate does not touch, that is, the highest material is the temperature difference between the junction side, according to the original shell, the use of different configurations composed of the adjustment system, For example, the length of the hollow core 13, the thickness or width of ^ or the like, and the like, can optimize the system flux. The schematic diagram shown in the second figure is only one of the embodiments of the present invention. The structure of the structure is not shown in the second diagram. The actual structure will vary depending on the materials used, system design, application requirements and the like. According to the present invention, an ultra-fine group is disclosed for a film: the filter module comprises a hollow core having a hollow compartment and a multi-membrane having gas permeability but not Permeating through a liquid; an outer casing having an inlet for providing a fluid to be circulated, forming a porch between the porphyrin film and the genus, and communicating with the outer casing, the evaporation chamber receiving An external heat source to evaporate the fluid; and a condensation chamber formed by a space between the hollow core and the porous film as an 'inclusive-outside connection, and the condensation chamber includes along The plurality of fins are radially disposed between the plurality of fins, and the plurality of fins divide the condensation chamber into a plurality of condensation chambers (condensati〇nc〇mpartments). The source of the embodiment may be selected from the group consisting of τ columns or any combination thereof, a resistive heater, an infrared heater, solar energy, and waste conversion heat energy. The above porous film may be a porous film, and the porous f film may be selected from one of the following or any combination thereof: polytetrafluoroethylene (polytetrafluoroethylene), polyvinylidene fluoride (ρ〇ι__6η6) Fluoride. The death filter module can further comprise a mesh, a method for supporting the porous film on the solar film, and the mesh is disposed on the transparent film For example, the mesh and the porous film may be combined by heat pressing. In another embodiment, a plurality of fine structures, such as a plurality of grooves, may be formed on the surface in contact with the porous film by the plural. ^grooves) to support the above porous film to maintain the space of the complex channel. In addition, the above-mentioned over-clamping module may further comprise a cooling medium flowing through the hollow partition to provide a temperature difference between the supply side and the condensation side. In one embodiment, the hollow core body and the plurality of fins of the upper consideration module may be integrally formed, and the hollow core body, °+, j, and one hollow tube are connected together. Korean flaky. In the upper group, the outlet _ collects the fluid of the porous film. The module can be finer than water purification, brine desalination system, waste cleaning system, or hemodialysis water treatment system. The body 'for example, the third embodiment of the present invention is shown in the drawings, and the fourth (A) diagram shows the pattern of the over-the-top module shown in the third figure. The fourth (8) figure shows the fourth. (A) Schematic diagram of the cross-addition, /〇α_α' line shown in the figure. The filter module 100 comprises a hollow core i porous film coffee, a casing, an evaporation chamber, and a condensate ^- 牲 ^ ^ port 410 'located on the outer casing 400 to communicate with the outside to facilitate the filter The fluid is filtered. An outlet 610 allows the condensation chamber to flow out of the transition module 100 via the 610 through the fluid condensed by the porosity _300 and condensed at t 600 . In addition, a cooling medium (or a cooling compartment) passes through the hollow compartment 21G of the hollow core and the body 2, and the hollow compartment 210 communicates with the outside via the upper and lower openings. The hollow cylinder structure is not limited to the above. In another embodiment, the hollow compartment may have a polygonal hollow columnar structure, and the cross section may be that the other plurality of fins i H are radially arranged along the surface of the towel. The shape of each shape is not limited to the shape shown in the fourth figure, and the number of cocoa is 4, 6, etc. The number of blame = is not limited to the one piece shown in the fourth (8) figure, the design of the module, for example, 1 shoe = fifth figure and In the sixth figure, depending on the filter ratio, etc., the shape and size of various removable parts and Korean pieces (the length and width of the section can be adjusted with reference to the f = ,, and the efficiency of the filter module is optimized. The hollow core body 200 of the group 1〇0 and the plurality of Korean tablets 620 are formed by mechanical processing in a hollow copper tube. However, the seventh core, the hollow core 200 and the plural The fins 620 can be respectively provided with a plurality of fins. The hollow core 2 is not according to another embodiment of the present invention. 00, body 200, can be difficult * ^ structure of the schematic diagram. As shown in the seventh figure hollow core and there are pairs of friction, cover ^ ^ f heart tube formed in the diameter direction of a plurality of grooves, will have /fif slot The plural of the shape is 62g, and the clamp is fixed by the grooved towel. The size of the plurality of hollow tubes is connected, so that the hollow core. ρ,,, and length can be arbitrarily changed, and is not limited by the processing machine, and On the other hand, it is possible to make the filter module easy to scale up (scale 叩) to meet the needs of mass production. In addition, in the embodiment, the porous fine 3GG is a polytetraethylene ytetmfluoroethyiene (PTFE) film, and in another embodiment, the transparent film 300 may include a pTFE film and laminated thereon. One of the porous films is a mesh (not shown). According to another embodiment of the present invention, a filter module for thin film distillation is disclosed. The filter module 100 is composed of a plurality of the above filter modules, but has only one outer casing. 8 is a perspective perspective view showing a filter module 1 according to an embodiment of the present invention. The filter module includes: a casing having an inlet for providing a fluid for filtering; a plurality of hollow cores, the hollow The cores each have a hollow compartment, the hollow compartments are in communication with each other; the plurality of porous membranes are gas permeable but impermeable to liquid; and an evaporation chamber is formed by the space between the porous membranes and the outer casing Constructed to communicate with the inlet of the outer casing, the evaporation chamber
If部的熱源’以蒸發該流體；複數凝結室，其中每- 由—中找體21G分別與_對應之纽性薄膜 σ _ B ^二間所構成，各凝結冑6GG包含—與外部連通之出 一 口 _互相連通’且各凝結室_包含沿該中 = 射狀設置之複數鰭片62G，該複數鰭片620將 ^鈇二至600分隔成複數凝結隔間6〇5，如第四a圖盥 b 圖所示。 第八圖所示之過濾模組1〇〇，之外殼可由金屬、合金、 材料構成，只要可以讓蒸發室接收來自外 人.施例中’上述熱源可選自下列之一者或其任意組 :阻式加熱器、紅外、線加熱器、太陽能、廢棄物轉化執能。 上^夕孔性薄膜可為一多孔性薄膜，該多孔性薄膜可選自下列 之者，其任思、組合·聚四氟乙稀（）、 聚偏二氟乙烯（polyvinylidene fluoride)。上述過濾模組，可更 包含複數一網狀物（mesh)，分別設置於該複數多孔性薄膜上， 用以支持該多孔性薄膜。此外，上述過雜組可更包含一冷卻 媒介，流過該中空隔間，用以提供供給侧與凝結侧間的溫度 差。於一實施例中，上述過濾模組之中空芯體與複數鰭片可為 一體成形，該甲空芯體可由至少一中空管連結而成，該中空管 的剖面可為則狀。上述過顏組巾，該出口制以收集通過 該多孔性薄膜之流體。上述過濾模組，可應用於水純化/系統、 水淡化處理系統、廢水淨化系統、或血液透析之水處理系統If the heat source 'to evaporate the fluid; a plurality of coagulation chambers, wherein each of the -21G is formed by a new film σ _ B ^ corresponding to _, and each condensed 胄 6GG includes - communicating with the outside One _ interconnected and each condensing chamber _ includes a plurality of fins 62G disposed along the middle=shooting, the plurality of fins 620 separating the two to 600 into a plurality of condensing compartments 6〇5, such as the fourth a Figure 盥b is shown. The filter module 1A shown in the eighth figure may be made of metal, alloy or material as long as the evaporation chamber can be received from an outsider. In the example, the heat source may be selected from one of the following or any group thereof: Resistive heaters, infrared, line heaters, solar energy, waste conversion. The upper film may be a porous film, and the porous film may be selected from the group consisting of polytetrafluoroethylene (polyvinylidene fluoride) and polyvinylidene fluoride. The filter module may further comprise a plurality of meshes respectively disposed on the plurality of porous films to support the porous film. Additionally, the above-described interference group may further comprise a cooling medium flowing through the hollow compartment to provide a temperature difference between the supply side and the condensation side. In one embodiment, the hollow core body and the plurality of fins of the filter module may be integrally formed, and the hollow core body may be formed by joining at least one hollow tube, and the hollow tube may have a cross section. In the above-mentioned over-panel tissue, the outlet is formed to collect fluid passing through the porous film. The above filter module can be applied to water purification/system, water desalination system, wastewater purification system, or hemodialysis water treatment system
¥ ° I 第九圖顯示第三圖之過濾模組的凝結管所含的韓片數目 與通量之柱狀圖。第九圖顯示凝結管所含的鰭片數目對過濾模 組的通量之影響，第三圖的過濾模組僅包含單一凝結管，過濾 模組的通量隨凝結管的·鰭片數目增加而增加，其中凝結側(尸^ = 303K，供給溫度（feed temperature(户)）=323K。鰭片數目¥ ° I The ninth chart shows the histogram of the number of Koreans and the flux contained in the condensing tube of the filter module of the third figure. The ninth graph shows the influence of the number of fins contained in the condensing tube on the flux of the filter module. The filter module of the third figure only contains a single condensing tube, and the flux of the filter module increases with the number of fins of the condensing tube. And increase, where the condensation side (corporate ^ = 303K, feed temperature (household)) = 323K. Number of fins
為10時，通量約為15kg/m2h’對照C.Feng等人發表之AGMD 的海水/炎化糸統（參考 C. Feng α/.，Journal of MembraneAt 10 o'clock, the flux is about 15 kg/m2h'. The seawater/inflammation of AGMD published by C. Feng et al. (Ref. C. Feng α/., Journal of Membrane
Seienee’/ll (2008)1-6)，在溫度差60°C下最高的通量為11〜 12kg/m2h’另外j. K〇schk〇wski等人發表之基於之太陽能 熱驅動的，炎化工座（參考j 故乂，Desalination 15^2003) 295·304) ’ 其最大輸出僅約為 U7 kg/m2h (281/ m d> 1此’根據本發明的設計，僅利用第三圖之過濾模組即 ^越目則使用之系統’此外根據本發明的設計，如第八圖所 示’在過遽模組中使用複數的凝結管，可以容易地放大系統規 模（scaleup)，如第八圖之系統的實測中，使用複數的凝結管 時通量會隨凝結管的數目倍數增加。 在海水淡化系統的應用上，若將鹽度（salinity) 7800ppm 的鹽水導人第三圖之過雜組，其輸出的水之鹽度為9〇ppm， =照一般淡水的鹽度為18〇ppm。由此得知，根據本發明的過 遽模組，具有優異的去鹽（desalination)效果。 练上所述，根據本發明的凝結管，可應用於空氣間隙薄 館模組，除用於支持薄膜外，可提供各種空氣間隙的厚度 目，藉由調整這些可變結構，可提高滲透通量，可提高 隙薄膜蒸顧之通量M吏用其之過舰組，應用於空氣 j隙4膜_模組，可容易地依比例放大（sealeup)，達到量 ί ϊ it °此外’藉由結合電能、太陽能、廢物轉化能源 溫度梯度之能量來源，進行薄膜频 種過濾處理之效果。 & 夕^上雖以特定實施例說明本發明，但並不因此限定本發明 要不脫離本個之要旨，熟悉本聽者瞭解在不脫 的意圖及範圍下可進行各種變形或變更，例如上述多 ίίί為各種薄膜，使過親組達成各種過濾的目的。另 靈ίϊΓ的任—實施例或㈣專利範圍不須達成本發明所揭 結^。卩目的或優點或特點。此外，摘要部分和標題僅是用來 辅助專利文件搜尋之用，並_來關本發明之權利範園。 1374052 【圖式簡單說明】 ，一圖顯示空氣間隙薄膜蒸餾（AGMD)的基本操作原理之八 意圖； ' 第二圖顯示根據本發明一實施例之凝結管之剖面示意圖； 第三圖顯示根據本發明一實施例之過濾模組的立體透視示 圖； 、 第四（A)圖顯示第三圖所示之過濾模組的侧面示意圖； 第四（B)圖顯示第四（A)圖所示之過濾模組的丨;:A_A， 剖面示意圖； w 第五圖顯示根據本發明另一實施例之過濾模組的剖面示意圖； 第六圖顯示根據本發明另一實施例之過濾模組的剖面示g圖: 第七圖顯示根據本發明另一實施例之中空芯體2 片620,的結構之剖面示意圖； 錢数鰭 第八圖顯示根據本發明一實施例之過濾模組1〇〇，的立體 示意圖；以及 ，九圖顯示第三圖之過濾模組的凝結管所含的鰭片數目與通 "S之柱狀圖。 【主要元件符號說明】 10 :凝結管 11 :多孔隙外殼 12 :鰭片 13 :中空芯體 14 :凝結室 15 :中空隔間 100, 100,：過濾模組 200, 200’ ：中空芯體 210 :中空隔間 3〇〇 :多孔性薄膜 400 :外殼 12 1374052 410 入口 500 蒸發室 600 凝結室 605 凝結隔間 610 出口 620,620’ ：鰭片Seienee' / ll (2008) 1-6), the highest flux at a temperature difference of 60 ° C is 11 ~ 12kg / m2h 'in addition to j. K〇schk〇wski et al. based on solar heat driven, inflammation Chemical Block (Ref. j De, Desalination 15^2003) 295·304) 'The maximum output is only about U7 kg/m2h (281/ m d> 1 this 'Design according to the present invention, only using the third graph The module is the system used by the eye. In addition, according to the design of the present invention, as shown in the eighth figure, the use of a plurality of condensation tubes in the over-clamping module can easily amplify the system scale, such as the eighth. In the actual measurement of the system, the flux will increase with the number of condensing tubes when using a plurality of condensing tubes. In the application of seawater desalination system, if the salinity 7800ppm of brine is introduced, the third figure is too complicated. In the group, the salinity of the water output is 9 〇 ppm, and the salinity of the fresh water is 18 〇 ppm. It is thus known that the sputum module according to the present invention has an excellent desalination effect. As described above, the condensation tube according to the present invention can be applied to an air gap thin museum module, except In addition to the support film, various air gap thicknesses can be provided. By adjusting these variable structures, the permeation flux can be increased, and the flux of the vapor film can be increased. The gap 4 membrane _ module can be easily scaled up (sealeup) to achieve the amount ί ϊ it ° 'by combining the energy source of electric energy, solar energy, waste conversion energy temperature gradient, the film frequency filtering effect. The present invention has been described with respect to the specific embodiments of the present invention, and is not intended to limit the scope of the present invention. The above-mentioned multi-layers are used for various kinds of films to achieve various filtering purposes. The scope of the invention or the scope of the patents does not need to achieve the advantages of the present invention. And the title is only used to assist in the search of patent documents, and to the scope of the invention. 1374052 [Simple diagram], a picture shows air gap thin film distillation (AGMD) The second embodiment shows a schematic cross-sectional view of a condensing tube according to an embodiment of the present invention; the third figure shows a perspective view of a filter module according to an embodiment of the present invention; A) The figure shows a side view of the filter module shown in the third figure; the fourth (B) shows the 丨 of the filter module shown in the fourth (A); A_A, a schematic cross-sectional view; w The fifth figure shows A cross-sectional view of a filter module according to another embodiment of the present invention; a sixth view showing a cross-sectional view of a filter module according to another embodiment of the present invention: a seventh view showing a hollow core according to another embodiment of the present invention FIG. 8 is a schematic cross-sectional view showing the structure of the filter module 1 according to an embodiment of the present invention; and FIG. 9 is a perspective view showing the condensation of the filter module of the third embodiment; The number of fins contained in the tube and the histogram of the "S". [Main component symbol description] 10: Condensation tube 11: Porous housing 12: Fin 13: Hollow core 14: Condensation chamber 15: Hollow compartment 100, 100, Filter module 200, 200': Hollow core 210 : Hollow compartment 3 〇〇: porous film 400: outer casing 12 1374052 410 inlet 500 evaporation chamber 600 condensation chamber 605 condensation compartment 610 outlet 620, 620': fin