TWI373406B - - Google Patents

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TWI373406B
TWI373406B TW94141786A TW94141786A TWI373406B TW I373406 B TWI373406 B TW I373406B TW 94141786 A TW94141786 A TW 94141786A TW 94141786 A TW94141786 A TW 94141786A TW I373406 B TWI373406 B TW I373406B
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Taiwan
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heat
resistant
cushioning material
layer
woven fabric
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TW94141786A
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Chinese (zh)
Inventor
Mamoru Sawada
Muneo Tsukamoto
Shinichi Noda
Takayuki Tagawa
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Mitsuboshi Belting Ltd
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1373406 九、發明說明: 【發明所屬之技術領域】 本發明係關於耐熱性壓製用緩衝材及其製造方法,詳細 而言,係關於配置於熱壓製盤與成形品之間、防止熱壓製 盤及成形品的瑕疵並傳導均勻之壓力與熱、且提高緩衝性 之耐熱性壓製用緩衝材及其製造方法。 【先前技術】 耐熱性壓製用緩衝材,配置於熱壓製盤與成形品之間, 使用於加壓成型時爲了防止熱壓製盤的瑕疫及施加均勻之 壓力與熱,而要求緩衝性、熱傳導性及耐久性。先前,雖 使用將牛皮紙5〜20張左右重疊者,但由於使用次數僅爲^ 次左右,耐久性差’近年幾乎不被使用。 相對於此,作爲提高耐久性之緩衝材,提供有使用合成 橡膠者’現在亦袜大量使用。其代表性構成係組合由玻璃 纖維、芳香族聚醯胺纖維等高耐熱性纖維所構成之織布、 不織布或毛氈之層、與丁基橡膠、氟橡膠等合成橡膠層並 層疊一體化者。又,已知,於其中爲使保持離型性,將在 緩衝材的表面塗敷氟樹脂薄膜或耐熱樹脂後之薄板等耐熱 性離型層黏著一體化。 又’亦有於玻璃纖維布的兩面設置氟橡膠,並於該氟橡 膠的表面層疊聚醯胺纖維而使用。(記載於專利文獻丨)於此 情形’除表面的織布的緩衝性之外,有因層疊時産生之層 間空隙而進一步提高緩衝性之特長。 [專利文獻1]專利第3259741號說明書 106048.doc ^73406 “,、'而’若使用先前被良好使用之毛氈作爲緩衝材的構成 構件’由於構成纖維的自由度大、柔軟,因此,會有即使 於微小重量之斑存在之情形,於層疊板等被處理物易產生 厚度斑及空隙之問題及壽命短之問題。 又,根據成形品之構成所要求之撓曲量不同。於成形品 需要大撓曲量之情形,會有缓衝材的撓曲量不足之問題。 又,橡膠層之橡膠於硫化時可塑化,朝織布或不織布的1373406 IX. The present invention relates to a cushioning material for heat-resistant pressing and a method for producing the same, and more particularly to a heat-pressing disk and a molded article, and a hot-pressed disk and A heat-resistant pressing cushioning material and a method for producing the same, which have a uniform pressure and heat and a cushioning property. [Prior Art] The heat-resistant pressing cushioning material is disposed between the hot-pressed disc and the molded product, and is used for pressure-proof molding to prevent plague of the hot-pressed disc and to apply uniform pressure and heat, and to require cushioning and heat conduction. Sex and durability. In the past, the use of kraft paper was about 5 to 20 sheets, but the number of uses was only about ^ times, and the durability was hardly used in recent years. On the other hand, as a cushioning material for improving durability, a person who uses synthetic rubber is now used. The representative structure is a combination of a woven fabric, a nonwoven fabric or a felt layer composed of a high heat resistant fiber such as glass fiber or an aromatic polyamide fiber, and a synthetic rubber layer such as butyl rubber or fluororubber. Further, it is known that in order to maintain the release property, a heat-resistant release layer such as a thin plate coated with a fluororesin film or a heat-resistant resin on the surface of the cushioning material is bonded. Further, a fluororubber is provided on both surfaces of the glass fiber cloth, and a polyamide fiber is laminated on the surface of the fluororubber. (Patent Document 丨) In this case, in addition to the cushioning property of the surface woven fabric, there is a feature that the cushioning property is further improved by the interlayer voids generated at the time of lamination. [Patent Document 1] Patent No. 3,259,741, Specification No. 106048.doc ^73406 "," and "If a previously used felt is used as a cushioning member", since the degree of freedom of the constituent fibers is large and soft, there will be Even in the case where the fine particles are present, the problem of the thickness and the voids and the short life are likely to occur in the object to be processed such as a laminate. Further, the amount of deflection required for the composition of the molded article is different. In the case of a large amount of deflection, there is a problem that the amount of deflection of the cushioning material is insufficient. Further, the rubber of the rubber layer can be plasticized during vulcanization, toward the woven or non-woven fabric.

層之空隙部流人’會有織布或不織布的層本應具有之緩衝 性降低之問題。 【發明内容】 本發明蓉於如上述之實際情況,作為應對於此者,其目 的係在於提供緩衝性良好、減小壓縮永久變形、使耐:性 提高之耐熱性壓製用緩衝材及其製造方法。 即’於本發明’本發明係—種耐熱性壓製用緩衝材,其 係使用於熱壓製盤與成形品之間者,其特徵在於:使用^ 少1層之蓬鬆性的多重織造布作爲其構成構件,且緩衝 好’減小壓縮永久變形,且提高耐久性。 ^ 又,本發明由於包含:在表面層設置以耐熱性樹 之对熱性纖維構件,於中間層設h層或2層之多重^ 布’於上述表面層與中間層之間或於中間層之間介以橡 層,因此’緩衝性更佳’塵縮永久變形小,提高耐久: 而且’於使用2層之多重織造布之情形, 變形時之撓曲量即使大,亦可… 厚度增加’㈣ 衝性。 ㈠吏大’亦可減小壓縮永久變形、維持海 I06048.doc 1373406 =發明,在表面層設置經耐熱性樹脂處理之耐熱性 =構件’於中間層設置2層之多重織造布,於上述表面層 ::間層之間或於中間層之間介以橡膠層之情形,總厚度 增加’壓縮變形時之撓曲量即使大 每- 形、維持緩H ”烕小屢缩水久變 ^本發明包含多重織造布之構成線包含:捲縮加工線之情 :,多重織造布爲2重織造乃至4重織造布之情形;多重織 造布的構成線係以選自玻璃纖維、碳纖維m纖維之 至少1種之無機纖維作爲素材之情形;表面層的耐熱性纖維 構件係由選自芳香族聚酿胺纖維、聚苯硫㈣維、玻璃纖 維、一碳纖維之至少!種之耐熱性纖維、或芳香族聚酿胺纖維 的短纖絲構成之情形;表面層的耐熱性纖維構件經耐熱性 樹脂處理之情形;使用選自氟橡膠及矽橡膠之 ^ 種之 耐熱性橡膠作爲橡膠層之情形;及於表面層與中間層之門 或於中間層之間介以經短纖維強化之橡膠層之情形。 再者,本發明係一種耐熱性熱壓製用緩衝材之製造方 法’該耐熱性熱壓製用緩衝材係使用於熱壓製盤與成形品 之間’該方法係於表面層設置对熱性纖維構件,且於中間 層設置至少1層之蓬鬆性的多重織造布,於上述表面層與中 間層之間及/或於中間層之間介以未硫化的橡膠層製造層 疊物後’將該層疊物於加熱下於無麼狀態放置,橡膠層交 聯反應開始後立即加塵、硫化、層疊而一體化者,藉由於 無壓狀態放置於交聯反應開始後立即使橡膠層加壓、疏 化’可抑制橡膠滲入多重織造布,可製造藉由充分地確保 106048.doc l3734〇6 孔滯抓在於内部之空間而提高緩衝性、虔縮永久變形 小、及耐久性提高之耐熱性壓製用緩衝材。 本發明係將層疊物於溫度15〇ec〜i8(rc、於無塵狀態放置 2 15刀鐘後’維持在該溫度之狀態加壓、硫化而層疊一 體化者’可確實地抑制橡膠於硫化時滲入多重織造布。 本發月作爲橡膠層藉由使用選自說橡谬及石夕橡踢之至 少一種之耐熱性橡膠,可製造富於耐熱性之緩衝材。 【實施方式】 依據本發明之耐熱性壓製用緩衝材,由於以至少i層蓬鬆 !生之多重織布作爲其構成構件,因此,設有許多空間部 分而具有緩衝性及阻止於反複進行壓製時之緩衝材的變形 之功能,而有可減小壓縮變形、使耐久性提高之效果。 又,於本發明之耐熱性壓製用緩衝材之製造方法,可藉 由將層疊物於無壓狀態放置、於交聯開始後立即對橡膠層^ 加壓、硫化、層疊一體化,可抑制橡膠於硫化時滲入多重 織布中,藉由充分地確保使空氣滞留在内部之空間可提 高緩衝性,再者由於以至少丨層蓬鬆性之多重織造布作爲其 構成構件,因此,設有許多空間部分而具有緩衝性及阻止 於反複進行壓製時之緩衝材變形之功能,有可減小壓縮變 形、使耐久性提高之效果。 以下’參照附圖說明本實施。圖1係關於本發明之耐熱性 壓製用緩衝材之剖面圖,關於本發明之耐熱性壓製用緩衝 材1,係使由耐熱性纖維構件2所構成之表面層3 ;由具有蓬 鬆性之多重織造布5所構成之中間層6 ;及於表面層3與中間 106048.doc 1373406 層6之間介以向表面層3及中間層6一部分含浸後之橡膠層 7,加以硫化而一體化使各層間黏著之層疊物。由於中間層 6使用有蓬鬆性之纖維,且爲多重織造布,因此,存在許: 空間部分而具有緩衝性及阻止於反複進行壓製時之緩衝= 變形之功能。The voids in the layer will have a problem that the woven or non-woven layer should have a reduced cushioning property. The present invention has been made in view of the above-described circumstances, and it is an object of the present invention to provide a heat-resistant pressing cushioning material which is excellent in cushioning property, reduces compression set, and improves resistance. method. In the present invention, the present invention is a heat-resistant pressing cushioning material which is used between a hot-pressed disk and a molded article, and is characterized in that a bulky multi-woven fabric having a layer of less than one layer is used. The components are constructed and cushioned to 'reduce compression set and improve durability. Further, the present invention comprises: a heat-sensitive fiber member provided with a heat-resistant tree on the surface layer, and a plurality of layers of the h layer or the second layer in the intermediate layer between the surface layer and the intermediate layer or in the intermediate layer Between the layers of the rubber layer, the 'buffering is better', the dust shrinkage and permanent deformation are small, and the durability is improved: and 'in the case of using two layers of multiple woven fabrics, the amount of deflection during deformation is large, and the thickness can be increased. (iv) Impulsiveness. (1) 吏大' can also reduce compression set and maintain sea I06048.doc 1373406=Invention, heat resistance treated with heat-resistant resin in the surface layer = member's multi-woven fabric with two layers in the middle layer, on the above surface Layer: The case where a rubber layer is interposed between the interlayers or between the intermediate layers, and the total thickness is increased. 'The amount of deflection during compression deformation is large even every shape, and the temperature is kept slow. The constituent line comprising the multiple woven fabric comprises: a crimping processing line: the case where the multiple woven fabric is a 2-weave or a 4-weave woven fabric; and the constituent thread of the multi-woven fabric is at least selected from the group consisting of glass fiber and carbon fiber m fiber. One type of inorganic fiber is used as a material; the heat-resistant fiber member of the surface layer is made of a heat-resistant fiber selected from aromatic polyamine fibers, polyphenylene sulfide (tetra), glass fibers, and carbon fibers, or aromatic a case where the short fibrils of the aramid fiber are formed; the heat-resistant fiber member of the surface layer is treated with a heat-resistant resin; and a heat-resistant rubber selected from the group consisting of fluororubber and ruthenium rubber is used as the rubber layer. And a case where a rubber layer reinforced by a short fiber is interposed between a gate of a surface layer and an intermediate layer or a middle layer. Further, the present invention is a method for producing a heat-resistant hot press cushioning material. The heat-pressing cushioning material is used between the hot-pressed disc and the molded article. The method is to provide a multi-woven fabric having a bulky layer of at least one layer on the surface layer and a bulky woven fabric on the intermediate layer. After the laminate is formed between the intermediate layers and/or between the intermediate layers with an unvulcanized rubber layer, the laminate is placed under heating without any state, and the rubber layer is dusted and vulcanized immediately after the crosslinking reaction starts. By laminating and integrating, by placing the rubber layer under pressure and thinning immediately after the start of the crosslinking reaction in the pressureless state, it is possible to suppress the penetration of the rubber into the multi-woven fabric, and it is possible to manufacture the hole by sufficiently ensuring 106048.doc l3734〇6 The heat-resistant pressing cushioning material which has a cushioning property, a small shrinkage permanent deformation, and an improved durability is provided in the space of the interior. The present invention is a laminate having a temperature of 15 〇 ec to i8 (rc, in a dust-free state). After being placed for 2 15 knives, 'pressurizing and vulcanizing at this temperature and laminating the integrated one' can surely inhibit the penetration of the rubber into the multi-woven fabric during vulcanization. This month as a rubber layer is selected from the rubber layer. And a heat-resistant rubber which is at least one kind of a stone rubber, and a heat-resistant cushioning material can be produced. [Embodiment] According to the heat-resistant pressing cushioning material of the present invention, a multi-woven fabric which is fluffy at least i-layer is produced. As a constituent member, a plurality of space portions are provided to have a cushioning property and a function of preventing deformation of the cushioning material when the pressing is repeated, and the effect of reducing compression deformation and improving durability can be achieved. In the method for producing a heat-resistant pressing cushioning material of the present invention, by laminating the laminate in a pressureless state, pressurizing, vulcanizing, laminating and integrating the rubber layer immediately after the start of crosslinking, the rubber can be inhibited from infiltrating during vulcanization. In the multi-woven fabric, the cushioning property can be improved by sufficiently ensuring the space in which the air is retained in the interior, and further, the multi-woven fabric having at least a layer of loftiness is used as the constitution. Therefore, a space provided with a plurality of portions and having a buffer function to prevent the buffering of the modification of the material is repeatedly pressed with a compression deformation can be reduced, so that an effect of improving the durability. The present embodiment will be described below with reference to the drawings. 1 is a cross-sectional view of a heat-resistant pressing cushioning material according to the present invention, and the heat-resistant pressing cushioning material 1 of the present invention is a surface layer 3 composed of a heat-resistant fibrous member 2; The intermediate layer 6 composed of the woven fabric 5; and the rubber layer 7 impregnated with the surface layer 3 and the intermediate layer 6 between the surface layer 3 and the intermediate layer 106048.doc 1373406 6 are vulcanized and integrated. a layer of adhesive between layers. Since the intermediate layer 6 is made of a bulky fiber and is a multi-woven fabric, there is a space portion which has a cushioning property and a function of blocking the cushioning/deformation when the pressing is repeated.

又,圖2所示之耐熱性壓製用緩衝材丨,由具有蓮鬆性之 多重織造布5所構成之中間層6以2片層疊。即,該緩衝材 1 爲由耐熱性纖維構件2所構成之表面層3、由2層具有蓬穸眭 之多重織造布5所構成之中間層6、及於表面層3與中間層6 之間' 中間層6與中間層6之間、及中間層6與表面層^之間 介以橡膠層7、加以硫化一體化而使各層間黏著後之層疊 物。上述耐熱性壓製用緩衝材丨,即使總厚度大,較於使用 1層中間層6之情形,由於壓縮率未變化,因此即使撓曲量 增大亦可維持缓衝效果。 於本發明,由多重織造布5所構成之中間層6可以3〜5片左 右層疊。 於本發明之製造方法中,於多重織造布5之兩面,分別層 疊厚度0.10〜0.50 mm之未硫化的橡膠薄板之橡膠層7,進一 步於橡膠層7之各表面層疊耐熱性纖維布2 ,將層疊物以通 常之壓製硫化裝置於溫度15〇〜18〇〇c及無壓狀態下放置 〇·2〜15分鐘《於橡膠層7交聯開始後立即於維持在上述溫度 之狀態下,將面壓提高至〇1〜5 〇 MPa,以時間1〇〜4〇分鐘 硫化’層疊一體化,製作圖1所示之耐熱性壓製用緩衝材1。 又’於圖2所示之耐熱性壓製用緩衝材1之製造方法中, 106048.doc 1373406 - 於多重織造布5之兩面,分別層疊厚度0.1 0〜0.50 mm之未硫 化的橡膠薄板之橡膠層7,進一步將多重織造布5層疊後, 於單面上將相同之橡膠層7層疊,而形成2層中間層6,且於 兩面上將时熱性纖維布2層疊後,以通常之壓製硫化裝置於 • 溫度150〜180°C及無壓狀態下放置0.2〜15分鐘,使橡膠層7 開始交聯。於該溫度’將面壓提高至0.^5 〇 MPa,以時間 10〜40分鐘硫化、層疊一體化。如此地將橡膠層預先於無壓 ^ 力狀態使開始父聯、將表面層與中間層層疊一體化,可抑 制於硫化時橡膠滲入多重織造布,藉由充分地確保使空氣 充分滯留在内部之空間可提高緩衝性。 於無壓力狀態放置之時間’以流變儀試驗之最小扭矩值 時之時間以上、未滿最高扭矩值時之時間爲佳。於本發明 之情形,以0.2〜15分鐘爲佳。於未滿最小扭矩值時之時間 之情形,將層疊物加壓、硫化時,橡膠層朝多重織造布5流 動,而充填纖維間之空隙,無法獲得充分之緩衝性、耐久 • 性。另一方面,若爲最高扭矩值時之時間以上,橡膠層與 多重織造布之黏著差,表面層與中間層易發生剝離。 又,爲進一步使耐壓縮變形性提高,亦可於2〇〇〜25〇。匚實 施後硬化3 0分鐘〜4小時。 上述具有蓬鬆性之多重織造布5可為2重織造布、3重織造Further, in the heat-resistant pressing cushioning material 图 shown in Fig. 2, the intermediate layer 6 composed of the multi-woven fabric 5 having a lotus-like property is laminated in two pieces. That is, the cushioning material 1 is a surface layer 3 composed of the heat-resistant fiber member 2, an intermediate layer 6 composed of two layers of the multi-woven fabric 5 having a fluff, and between the surface layer 3 and the intermediate layer 6. A laminate in which the rubber layer 7 is interposed between the intermediate layer 6 and the intermediate layer 6, and between the intermediate layer 6 and the surface layer, and is vulcanized and integrated, and the layers are adhered. In the above-mentioned heat-resistant pressing cushioning material, even if the total thickness is large, since the compression ratio is not changed as compared with the case where one intermediate layer 6 is used, the cushioning effect can be maintained even if the amount of deflection is increased. In the present invention, the intermediate layer 6 composed of the multi-woven fabric 5 may be laminated on the left and right sides of 3 to 5 sheets. In the manufacturing method of the present invention, the rubber layer 7 of the unvulcanized rubber sheet having a thickness of 0.10 to 0.50 mm is laminated on both surfaces of the multi-woven fabric 5, and the heat-resistant fiber cloth 2 is further laminated on each surface of the rubber layer 7. The laminate is placed in a normal press vulcanization apparatus at a temperature of 15 Torr to 18 〇〇c and placed under no pressure for 2 to 15 minutes. "After the crosslinking of the rubber layer 7, the surface is maintained at the above temperature, and the surface is placed. The pressure was increased to 〇1 to 5 〇 MPa, and vulcanization was carried out for 1 〇 to 4 〇 minutes to form a heat-resistant pressing cushioning material 1 shown in Fig. 1 . Further, in the method for producing the heat-resistant pressing cushioning material 1 shown in Fig. 2, 106048.doc 1373406 - a rubber layer of an unvulcanized rubber sheet having a thickness of 0.10 to 0.50 mm is laminated on both sides of the multi-woven fabric 5, respectively. 7. After laminating the multiple woven fabrics 5, the same rubber layer 7 is laminated on one surface to form two intermediate layers 6, and the heat-sensitive fiber cloth 2 is laminated on both sides, and then the conventional vulcanization apparatus is pressed. Place the resin layer 7 at a temperature of 150 to 180 ° C for 2 to 15 minutes without pressure to start crosslinking. At this temperature, the surface pressure was increased to 0.^5 〇 MPa, and vulcanization was carried out for 10 to 40 minutes, and the laminate was integrated. In this way, the rubber layer is preliminarily joined to the unbonded state, and the surface layer and the intermediate layer are laminated and integrated, and the rubber can be prevented from infiltrating into the multi-woven fabric during vulcanization, thereby sufficiently ensuring that the air is sufficiently retained inside. Space can improve cushioning. The time to be placed in the no-pressure state is preferably greater than the time when the minimum torque value of the rheometer test is exceeded or less than the maximum torque value. In the case of the present invention, it is preferably from 0.2 to 15 minutes. When the laminate is pressurized or vulcanized, the rubber layer flows toward the multi-woven fabric 5, and the gap between the fibers is filled, and sufficient cushioning properties and durability are not obtained. On the other hand, if it is at least the time of the highest torque value, the adhesion between the rubber layer and the multi-woven fabric is poor, and the surface layer and the intermediate layer are liable to be peeled off. Moreover, in order to further improve the compression deformation resistance, it may be 2 to 25 Torr.匚 After hardening, apply for 30 minutes to 4 hours. The above-mentioned bulky multi-woven fabric 5 can be a 2 woven fabric, a 3 woven fabric

布、或4重織造布等, 狀態經逢鬆加工者。 例如’ 2重織造布如圖1所示,成爲於 第4根經線9,另一方面於裏面,在同— 成爲於表面緯線8&交織 位置之另—緯線8b 106048.doc 11 1373406 - 同樣地交織於第4根經線9之2重織造之構成。如此,由於2 • 重織造布保持有許多間隙部分,因此具有緩衝性及阻止於 反複進行壓製時之緩衝材變形之功能。由於壓製成型時之 使用環境需要於200 C以上及80分鐘左右之使用時間,因此 右無耐熱性,無法強化緩衝材,會使變形。又,於細絲間 若不存在空隙,則未展現高緩衝性。因此,係具有耐熱性, 爲高強度、高彈性之纖維,加之經捲縮加工者。 φ 又,3重織造布,例如,如於圖3所示之其概略圖,由將 經線9a、經線9b、經線9c、經線9d、經線9e、經線9f、經線 9g等平行地配置,最外層之緯線8A交織於經線处與第4根之 9f ’中間層之緯線8B交織於經線%與第2根之經線%,且最 内層之緯線8C交織於經線9d之構成而形成。3重織造布成爲 將3根緯線8A、8B、8C層疊後之構造。 再者,4重織造布,例如,如於圖4所示之其概略圖,由 將經線9a'經線9b、經線9c、經線9d、經線%、經線妤、經 • 線%、經線9h、經線9i等平行地配置,最外層之緯線8A交 織於經線9b與第6根之9h,第2層之緯線8B交織於經線氕與 第4根之經線9g,第3層之緯線扣交織於經線%與第2根之 9f、且最内層之緯線81)交織於經線%之構成而形成。*重織 造布成爲將4根緯線8A、8B、8C、8D層疊後之構造。 上述夕重織造布5之構成線係聚芳酿胺纖維、pB〇(聚笨并 雙噁唑)纖維、玻璃纖維、碳纖維、陶瓷纖維等高強度、高 彈性且具有耐熱性之纖維,良好者可列舉玻璃纖維 '碳纖 維、陶瓷纖維等無機纖維。 106048.docCloth, or 4 heavy woven fabrics, etc., the state is processed by the pine. For example, the 'two-weave woven fabric is as shown in Fig. 1, and is formed on the fourth warp yarn 9, and on the other hand, on the same side, on the surface weft 8 & interlaced position, another weft 8b 106048.doc 11 1373406 - the same The structure is interwoven with the second weaving of the fourth warp yarn 9. Thus, since the 2 • heavy woven fabric retains a large number of gap portions, it has a cushioning property and a function of preventing the deformation of the cushioning material when the pressing is repeated. Since the use environment at the time of press molding requires a use time of 200 C or more and 80 minutes or so, there is no heat resistance on the right side, and the cushioning material cannot be reinforced and deformed. Further, if there is no void between the filaments, high cushioning properties are not exhibited. Therefore, it is a heat-resistant, high-strength, high-elastic fiber, and is a crimper. φ Further, a three-weave woven fabric, for example, as shown in Fig. 3, a warp yarn 9a, a warp yarn 9b, a warp yarn 9c, a warp yarn 9d, a warp yarn 9e, a warp yarn 9f, and a warp yarn 9g. Arranged in parallel, the outermost weft 8A is interlaced at the warp and the 4th of the 4f' intermediate layer is interlaced with the warp % and the second warp %, and the innermost weft 8C is interwoven It is formed by the structure of the line 9d. The three-weave woven fabric has a structure in which three weft threads 8A, 8B, and 8C are laminated. Further, the 4-weave woven fabric, for example, as shown in Fig. 4, has a warp 9a' warp 9b, a warp 9c, a warp 9d, a warp thread, a warp thread, and a warp thread. %, warp 9h, warp 9i, etc. are arranged in parallel, the outermost weft 8A is interlaced to the warp 9b and the sixth root 9h, and the second layer of weft 8B is interwoven between the warp and the fourth warp 9g The weft fastener of the third layer is formed by interlacing the warp % and the second root 9f, and the innermost weft 81 ) is interlaced with the warp %. * Re-weaving The fabric is a structure in which four wefts 8A, 8B, 8C, and 8D are laminated. The constituent wires of the above-mentioned woven fabric 5 are high-strength, high-elasticity and heat-resistant fibers such as polyaraminic amine fibers, pB〇 (polyphenylene bisazole) fibers, glass fibers, carbon fibers, and ceramic fibers. Examples thereof include inorganic fibers such as glass fibers, carbon fibers, and ceramic fibers. 106048.doc

• 12- l3?34〇6 形成上述表面層3之耐熱性纖維構件2,由於壓製形成時 之使用環境需要於上及8G分鐘左右之使用時間,因 此右無耐熱性,則會熱熔融而密著於被著物上。 作爲上述耐熱性纖維構件2,可使用聚㈣胺纖維、pB〇 纖維、請维、玻璃纖維、碳纖維m纖料,亦可 使用布、不織布、編織物、毛氈等。 又’根據情形’亦可將耐熱性纖維構件2以耐熱性樹脂含 浸處理。作爲上述耐熱性樹脂,可列舉環氧樹脂、苯酚樹 脂、三聚氰胺樹脂、氟樹脂、不飽和聚g旨樹脂、石夕氧樹脂、 聚酿亞胺樹脂、熱固化性丙歸酸樹脂、^樹脂、尿素樹 脂、苯二酸二烯㈣樹脂等單體㈣合㈣、或者共聚合體。 朴祕修層7,爲展現緩衝材之緩衝性者,作爲所要求特 性之耐熱性與低麼縮變形性,較好厚度狀^⑼職、• 12- l3?34〇6 The heat-resistant fiber member 2 forming the surface layer 3 is required to be used for the pressurization and the use time of about 8 G minutes. Therefore, if there is no heat resistance right, it will be thermally melted and dense. On the object. As the heat-resistant fibrous member 2, poly(tetra)amine fibers, pB〇 fibers, glass, carbon fibers, or m-fibers can be used, and a cloth, a nonwoven fabric, a woven fabric, a felt, or the like can be used. Further, the heat-resistant fibrous member 2 may be impregnated with a heat-resistant resin depending on the case. Examples of the heat resistant resin include an epoxy resin, a phenol resin, a melamine resin, a fluororesin, an unsaturated polyg resin, a sulphur oxide resin, a styrene resin, a thermosetting aristoyl resin, and a resin. A monomer (tetra) or a copolymer of a urea resin or a diene (tetra) phthalate resin or a copolymer. The simplification layer 7 is used to exhibit the cushioning property of the cushioning material, and has the heat resistance and the low shrinkage deformation property of the required characteristics, and the thickness is preferably (9).

橡膠硬度(JISA)爲65〜85。。至於作爲該橡膠層7所使用之橡 膠,有氟橡膠及石夕橡膠。氟橡膠,作爲其原料,有含說丙 烯酸酯聚合體、偏氟乙烯之共聚合體、含氟矽橡膠 聚酯橡膠等。 於該敦橡膠及料膠中,作爲硫化劑,可❹二酿 氣化物、過氧H丙基過氧化物、二第三丁基過氧化 物第二丁基異丙苯基過氧化物、二異丙苯過氧化物'25 二甲基-2,5-二(第三丁基過氧基l·己院-3、!,3·雙(第三丁,其 :氧-異丙基)苯、二-丁基過氧_3,3,5·三甲基環己燒等二 機過氧化物系硫化劑、六亞甲基胺基甲酸醋、n,n,·二氰基 -綠-1,6-己二胺、雙苯*AF、苯甲基三苯基氣化鐫鹽等多 106048.doc •13· 1373406 元醇系硫化劑、及三伸乙基四胺(ΤΕΤΑ)、三伸乙基五胺 (ΤΕΡΑ)、六亞甲基二胺(HMDA)等胺系硫化劑,作爲氟橡膠 之硫化劑’可使用習知者。其添加量,相對於聚合物100質 量份’爲約0.2〜5.0質量份,以〇.5〜3.0質量份爲佳。 此外,根據需要’可含有如填充劑、可塑劑、穩定劑、 加工助劑、著色劑之通常使用於橡膠配合物者。又,爲了 橡膠強化’亦可相對於橡膠100質量份填充5〜30質量份之長 1〜10 mm之短纖維。作爲該短纖維,可使用例如商品名The rubber hardness (JISA) is 65 to 85. . As the rubber used as the rubber layer 7, there are fluorine rubber and Shixia rubber. The fluororubber is a raw material containing a acrylate polymer, a vinylidene fluoride copolymer, or a fluorine-containing ruthenium rubber polyester rubber. In the rubber and rubber of the Dundee, as a vulcanizing agent, it can be used as a vulcanizing agent, a peroxyl H-propyl peroxide, a di-tert-butyl peroxide, a second butyl cumyl peroxide, and a second. Cumene peroxide '25 dimethyl-2,5-di (t-butylperoxy l. hexanyl-3, !, 3 bis (third butyl, its: oxy-isopropyl) Two kinds of peroxide-based vulcanizing agents such as benzene, di-butylperoxy_3,3,5·trimethylcyclohexane, hexamethylene amino carboxylic acid vinegar, n, n, · dicyano-green -1,6-hexanediamine, bisphenyl*AF, benzyltriphenylphosphonium sulfonium salt, etc. 106048.doc •13· 1373406-valent alcohol-based vulcanizing agent, and tri-ethyltetramine (ΤΕΤΑ), An amine-based vulcanizing agent such as triethylamine pentaamine or hexamethylenediamine (HMDA) can be used as a vulcanizing agent for fluororubbers. The amount of addition is 100 parts by mass relative to the polymer. It is preferably from 0.2 to 5.0 parts by mass, preferably from 5% to 3.0 parts by mass. Further, if necessary, it may contain a filler such as a filler, a plasticizer, a stabilizer, a processing aid, or a colorant, which is usually used for a rubber compound. Also, for rubber reinforcement, it can also be 1~10 mm staple fibers to 100 parts by mass of the rubber filler 5~30 parts by mass long as the short fibers, may be used, for example, under the trade name

Conex、Nomex、KEVLAR、Technora、Twaron等聚芳酿胺 纖維、PBO纖維、玻璃纖維等耐熱性纖維。 [實施例] 實施例1 準備將耐熱性環氧樹脂含浸、固化後之玻璃布(佳麗寶股 伤有限公司産之KS1600)作爲以耐熱性樹脂處理之耐熱性 纖維布,準備由經捲縮加工後之玻璃纖維所構成之2重織造 布(佳麗寶股份有限公司産之KS4325)作爲中間層,準備聚醇 爪化系之敗橡膠(杜邦公司産之Vit〇n v9〇〇6)作爲氟橡膠。 將氟橡膠藉由壓光輪製成厚度爲mm之薄板,層疊於 中間層與表面層之間,於溫度170°C壓製15分鐘將此硫化一 體化,製作緩衝材。緩衝材之總厚度爲2 1〇 mm。 將所得之緩衝材測定在面壓1〇 與面壓4〇 kg/cm2時 式樣之加壓厚度’測定緩衝性(定義:壓縮率 (%)=[(tliM40)/tl0]x100, tl〇=15 kg/cm2負荷時之試樣厚 度,t40=4〇kg/cm2負荷時之試樣厚度)。其結果,壓縮率爲 106048.doc 1373406 11.3% 〇 • 又’將所得之緩衝材設定於2〇〇t、由壓製以40 kg/cm2 反複進行30分鐘之加壓後之結果,第i次加壓後之厚度變化 !爲〇.〇3 mm,第30次加壓後之厚度變化量爲〇 〇5 mm,第 • 200次加壓後之厚度變化量爲〇.〇8 mm。 實施例2 準備以與實施例1同樣之耐熱性樹脂處理後之耐熱性纖 • 維布、及準備由與實施例1同樣之捲縮加工後之玻璃纖維形 成之2重織造布2層作爲中間層。於上述表面層與中間層之 間、^間層之間、及中間層與表面層間,介以厚度〇〇3曰_ 之聚醇硫化系之氟橡膠(杜邦公司產之Vh〇n V9〇〇6)並層 疊,由壓製於溫度170。(:、以15分鐘時間將此硫化一體化, 製作緩衝材。緩衝材之總厚度爲2 26 mm。 然後,於與實施例丨相同之條件下測定壓縮率及厚度變化 量之結果,壓縮率爲m,第1次加壓後之厚度變化量爲 ,0·05 mm,第30次加歷後之厚度變化量爲〇〇8咖,第· 次加壓後之厚度變化量爲〇.1〇_。於本實施例,判明塵縮 率與實施例】大致相同,即使撓曲量大,亦可維持緩衝性。 比較例1 代替中間層之由捲縮加工後之玻璃纖維形成之2重織造 布,而使用由未捲縮加工之玻螭纖維形成之2重織造布之 外,與實施例1同樣地製作緩衝材。緩衝材之厚度爲 軸然纟’於與實施例i相同之條件下測定麼縮率及厚度 變化量之結#,壓縮率爲6.4%,第i次加麼後之厚度變化^ 106048.doc 15 1373406 爲(MO nun,第30次加虔後之厚度變化量爲〇 ΐ7·。 . 比較例2 代替中間層之由玻璃纖維形成之2重織造布,而使用由聚 . 芳醯胺纖維(Conex:帝人公司產)形成之毛氈之外,與實施 , 例1同樣地製作緩衝材。缓衝材之厚度爲2·10 mme然後, 於與實施例1相同之條件下測定壓縮率及厚度變化量之結 果,壓縮率爲7.8%,第1次加壓後之厚度變化量爲〇 21 , φ 第30次加壓後之厚度變化量爲0.30 mm,第200次加壓後之 厚度變化量爲0.34 mm。 實施例3 準備Conex織物(帝人公司産之c〇191〇)作爲表面層之耐 熱性纖維布、由捲縮加工後之玻璃纖維形成之2重織造布 (曰東紡產之KS4325)作爲中間層、及聚醇硫化系之氟橡膠 (杜邦公司産之Viton V9006)作爲氟橡膠。 中間層成2片層疊後之構造’將氟橡膠藉由壓光輪製成厚 • 度爲0.30 mm之薄片,於中間層之間、中間層與表面層之間 層疊,於壓製中’初期5分鐘、於溫度!“^、於無壓狀態 保持’將氟橡膠部分地交聯,此後,以面壓2 〇 Mpa,於溫 度165°C、時間15分鐘將此硫化、層疊一體化,製作緩衝材。 緩衝材之總厚度爲3.15 mm 0 將所得之緩衝材測定面壓1 MPa與面壓5 MPa時之撓曲 量°其結果分別爲0.55 mm及0.95 mm。 又’將所得之緩衝材成面壓5 MPa之狀態,由5〇〇c經3〇 刀鐘升’皿至200°C,於200°C保持15分鐘後,經3〇分鐘降溫 106048.docHeat-resistant fibers such as Conex, Nomex, KEVLAR, Technora, and Twaron, such as polyarylamine fibers, PBO fibers, and glass fibers. [Examples] Example 1 A glass cloth (KS1600 manufactured by Kanebo Co., Ltd.) impregnated and cured with a heat-resistant epoxy resin was prepared as a heat-resistant fiber cloth treated with a heat-resistant resin, and was prepared by crimping. As a middle layer, a 2 woven fabric made of glass fiber (KS4325 from Kanebo Co., Ltd.) is used as a middle layer, and a rubber of a polyester clawing system (Vit〇n v9〇〇6 manufactured by DuPont) is prepared as a fluororubber. . The fluororubber was formed into a thin plate having a thickness of mm by a calender roll, laminated between the intermediate layer and the surface layer, and pressed at a temperature of 170 ° C for 15 minutes to form a cushioning material. The total thickness of the cushioning material is 2 1 〇 mm. The obtained cushioning material was measured at a surface pressure of 1 Torr and a surface pressure of 4 〇 kg/cm 2 in the form of a pressurized thickness 'measuring cushioning property (definition: compression ratio (%) = [(tliM40) / tl0] x 100, tl 〇 = The thickness of the sample at a load of 15 kg/cm2, t40 = the thickness of the sample at a load of 4 〇kg/cm2). As a result, the compression ratio was 106048.doc 1373406 11.3% 〇• Further, the obtained cushioning material was set at 2 〇〇t, and the result of pressurization was repeated for 40 minutes by pressing at 40 kg/cm2, and the i-th addition was performed. The thickness change after pressing! is 〇.〇3 mm, the thickness change after the 30th press is 〇〇5 mm, and the thickness change after the 200th press is 〇.〇8 mm. Example 2 A heat-resistant fiber treated with the same heat-resistant resin as in Example 1 and a 2 layer of 2 woven fabric prepared by crimping the same glass fiber as in Example 1 were prepared. Floor. Between the surface layer and the intermediate layer, between the intermediate layer, and between the intermediate layer and the surface layer, a fluororubber of a polycarbonate vulcanization system having a thickness of 〇〇3曰_ (Vh〇n V9 produced by DuPont) 6) and laminated, pressed to a temperature of 170. (:, the vulcanization was integrated in 15 minutes to prepare a cushioning material. The total thickness of the cushioning material was 2 26 mm. Then, the results of the compression ratio and the thickness variation were measured under the same conditions as in Example ,, and the compression ratio. For m, the thickness change after the first press is 0.05 mm, and the thickness change after the 30th calendar is 〇〇8 coffee, and the thickness change after the first press is 〇.1 In the present embodiment, it was found that the dust shrinkage ratio was substantially the same as that of the Example, and the cushioning property was maintained even when the amount of deflection was large. Comparative Example 1 Two weights of glass fibers formed by crimping instead of the intermediate layer A cushioning material was produced in the same manner as in Example 1 except that a woven fabric made of glass fibers which were not crimped was used, and the thickness of the cushioning material was the same as in Example i. Under the measurement of the shrinkage rate and thickness variation, the compression ratio is 6.4%, and the thickness change after the ith addition is ^106048.doc 15 1373406 is (MO nun, the thickness variation after the 30th twist is 〇ΐ7·. Comparative Example 2 Instead of the intermediate layer, a 2 woven fabric formed of glass fibers, and A cushioning material was produced in the same manner as in Example 1 except that a felt formed of polyaryleneamine fiber (Conex: Teijin Co., Ltd.) was used. The thickness of the cushioning material was 2·10 mme, and then it was the same as in Example 1. The compression ratio and the thickness change amount were measured under the conditions, and the compression ratio was 7.8%. The thickness change after the first press was 〇21, and the thickness change after φ 30th press was 0.30 mm, the 200th. The thickness change after the secondary press is 0.34 mm. Example 3 Preparation of Conex fabric (c〇191〇 produced by Teijin Co., Ltd.) as a heat-resistant fiber cloth of the surface layer, and 2-weaving of the glass fiber after crimping Cloth (KS4325 produced by Jidong Textile) as the intermediate layer, and the fluororubber of the polyol vulcanization system (Viton V9006 by DuPont) as the fluororubber. The intermediate layer is formed into two laminated structures. The fluororubber is used by the calender wheel. A sheet having a thickness of 0.30 mm is laminated between the intermediate layers, between the intermediate layer and the surface layer, and in the pressing, 'initial 5 minutes, at a temperature!", and the fluororubber portion is maintained in a non-pressurized state. Cross-linking, after which, with a face pressure of 2 〇Mpa, at a temperature of 165 C. The vulcanization was laminated and integrated for 15 minutes to prepare a cushioning material. The total thickness of the cushioning material was 3.15 mm. 0 The obtained cushioning material was measured for a surface pressure of 1 MPa and a surface pressure of 5 MPa. It is 0.55 mm and 0.95 mm. In addition, the obtained cushioning material is pressed into a surface pressure of 5 MPa, and it is heated from 5 〇〇c to 3 °C to 200 ° C, and kept at 200 ° C for 15 minutes. 3 minutes to cool down 106048.doc

• 16 · 1373406 至5(TC,使處於無壓狀態》將該模式重複2〇〇次之結果面 麼1 MPa與面壓5 MPa時之撓曲量分別爲〇 45咖及〇 6〇麵。 實施例4 中間層成4重織造布、爲i片層疊之構造以外,與實施例3 同樣地製作緩衝材。緩衝材之厚度爲3 12mme所得之緩衝 材在面壓爲1 MPa及面壓爲5 MPa時之撓曲量,分別爲〇95 mm及 1.20 mm。 又,將所得之缓衝材成面壓5 MPa之狀態,由“七經“ 分鐘升溫至200。(:,於200。(:保持15分鐘後,經3〇分鐘降溫 至50C,使處於無壓狀態。將該模式重複2〇〇次之結果,在 面壓1 MPa與5 MPa時之撓曲量分別爲〇 55 mm&〇 65瓜爪。 比較例3 與實施例3同樣之材料成層疊構造,以壓製面壓2 .〇 、 溫度165°C、時間15分鐘將此硫化一體化,製作緩衝材。緩 衝材之總厚度爲2.28 mm。所得之緩衝材在面壓爲1 Mpa及 面壓爲5 MPa時之撓曲量,分別爲〇 〇5 mm&〇 15 。 比較例4 代替中間層之捲縮加工後之玻璃纖維形成之4重織造 布,而使用由未捲縮加工之玻璃纖維形成之4重織造布之 外’餘與實施例4同樣之層疊構造,以壓製面壓2 .〇河以, 溫度16YC、時間15分鐘將此硫化一體化,製作緩衝材。緩 衝材之厚度爲2.45 mm。所得之緩衝材在面壓爲1 Μρ&及面 壓爲5 MPa時之撓曲量’分別爲0.21 mm及0.3 5 mm。 比較例5 106048.doc •17· 丄J/J4U0 代替中間層之由玻璃纖維形成之4重織造布,而使用由間 位系聚方酿胺纖維形成之毛氈之外’與實施例4同樣地製作 緩衝材。緩衝材之厚度爲2.10mme所得之緩衝材在面遲幻 MPa及面塵爲5 MPa時之撓曲量,分別爲〇 23贿及〇 43随。 [産業上之利用可能性]• 16 · 1373406 to 5 (TC, in a state of no pressure) This mode is repeated 2 times. The deflection of 1 MPa and surface pressure of 5 MPa is 〇45 coffee and 〇6〇. Example 4 A cushioning material was produced in the same manner as in Example 3 except that the intermediate layer was a 4-weave woven fabric and the i-sheet was laminated. The buffer material having a thickness of 3 12 mme was a surface pressure of 1 MPa and a surface pressure of The amount of deflection at 5 MPa is 〇95 mm and 1.20 mm, respectively. The resulting cushioning material is placed in a state of 5 MPa, and the temperature is raised to 200 by the "seven cycles" (:, at 200. : After 15 minutes, the temperature was lowered to 50 C after 3 minutes, so that it was in a no-pressure state. The pattern was repeated 2 times, and the deflection amount at surface pressures of 1 MPa and 5 MPa was 〇55 mm& 〇65 melon claws. Comparative Example 3 The same material as in Example 3 was laminated, and the vulcanization was integrated by pressing surface pressure 2, 温度, temperature 165 ° C, and time for 15 minutes to prepare a cushioning material. It is 2.28 mm. The amount of deflection of the obtained cushioning material at a surface pressure of 1 Mpa and a surface pressure of 5 MPa is 〇〇5 mm& Comparative Example 4 A laminated structure similar to that of Example 4 except that a 4-weave woven fabric formed of glass fibers after crimping of the intermediate layer was used, and a 4-weave woven fabric formed of unfolded glass fibers was used. The vulcanization material was prepared by pressing the surface pressure 2 to the river at a temperature of 16 YC for 15 minutes. The thickness of the cushioning material was 2.45 mm. The obtained cushioning material had a surface pressure of 1 Μρ & The amount of deflection at 5 MPa is 0.21 mm and 0.35 mm, respectively. Comparative Example 5 106048.doc •17· 丄J/J4U0 Instead of the intermediate layer, the 4-weave woven fabric formed of glass fiber is used by the meta-system. A cushioning material was produced in the same manner as in Example 4 except that the felt was formed of a poly-branched amine fiber. The cushioning material obtained by the thickness of the cushioning material was 2.10 mme, and the amount of deflection of the cushioning material was 5 MPa, and the surface dust was 5 MPa. For the sake of 贿23 bribes and 〇43. [Industrial use possibilities]

關於本發明之耐熱性壓製用缓衝材係藉由介於熱壓製盤 與成形品之間,於加壓形成時防止熱壓製盤的瑕疵,且賦 予均句之壓力與熱之緩衝材。 【圖式簡單說明】 圖1係藉由本發明方法製得之耐熱性壓製用缓衝材的剖 面圖。 圖2係藉由本發明方法製得其他實施例之耐熱性壓製用 緩衝材的剖面圖。 圖3係3重織造布之概略圖。 圖4係4重織造布之概略圖。The heat-resistant pressing cushioning material of the present invention is a cushioning material which prevents the enthalpy of the hot-pressed disc from being formed between the hot-pressed disc and the molded article at the time of pressurization formation, and which imparts pressure and heat to the uniform sentence. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing a heat-resistant pressing cushioning material obtained by the method of the present invention. Fig. 2 is a cross-sectional view showing a heat-resistant pressing cushioning material of another embodiment produced by the method of the present invention. Figure 3 is a schematic view of a 3 heavy woven fabric. Figure 4 is a schematic view of a 4 heavy woven fabric.

【主要元件符號說明】 1 耐熱性壓製用緩衝 2 耐熱性纖維構件 3 表面廣 5 多重織造布 6 中間層 7 橡膠層 8 緯線 9 經線 106048.doc[Main component symbol description] 1 Heat-resistant pressing buffer 2 Heat-resistant fiber member 3 Wide surface 5 Multi-woven fabric 6 Intermediate layer 7 Rubber layer 8 Weft line 9 Warp 106048.doc

Claims (1)

第094141786號專利申請案 中文申請專利範圍替換本(101年4月)〇a 十、申請專利範圍: 耐熱丨生壓製用緩衝材’其係使用於熱壓製盤與成形 品之間者,j 4士 丹特徵在於:使用至少1層蓬鬆性的多重織造 布作爲其構成構件,且多重織造布之構成線包含捲縮加 工線。 2·如吻求項1之耐熱性壓製用緩衝材,其中於表面層設置耐 &性纖維構件、於中間層設置1層或2層多重織造布,且 使橡膠層間介於上述表面層與中間層之間或者中間層之 間。 3. 如°月求項1之耐熱性壓製用緩衝材,其中多重織造布係2 重織造布至4重織造布。 4. 如明求項2之耐熱性壓製用緩衝材,其中多重織造布係2 重織造布至4重織造布。 5. 如明求項1至4中任一項之耐熱性壓製用緩衝材,其中多 重織U布之構成線係選自玻璃纖維、碳纖維、及陶瓷纖 維之至少1種之無機纖維。 6. 如清求項2之耐熱性壓製用緩衝材,其中表面層之耐熱性 纖維構件係以選自芳香族聚醯胺纖維、聚苯硫醚纖維、 玻璃纖維、碳纖維之至少1種之財熱性纖維構成。 7_如請求項2之耐熱性壓製用緩衝材,其中表面層之耐熱性 纖維構件係以芳香族聚酿胺纖維之短纖絲構成。 8. 如明求項2、6及7中任一項之耐熱性壓製用緩衝材,其中 表面層之对熱性纖維構件係經耐熱性樹脂處理。 9. 如請求項2之耐熱性壓製用緩衝材,其中橡膠層係選自氟 106048-10I0413.doc 1373406 ίο. 11. 12. 橡膠及矽橡膠之至少一種。 如請求項2或9之耐熱性壓製用緩衝材,其令於表面層與 中間層之間或者中間層之間’介以經短纖維強化之橡膠 層。 一種耐熱性壓製用緩衝刼之製造方法,該緩衝材係使用 於熱壓製盤與成形品之間,該方法之特徵在於:於表面 層执置耐熱性纖維構件,且於中間層設置至少1層蓮鬆性 的多重織造布,於上述表面層與中間層之間及/或於中間 層之間介以未硫化之橡膠層而製作層疊物後,將該層疊 物於加熱下放置於無壓狀態,於橡膠層開始交聯反應後 立即加壓、硫化及層疊一體化。 如請求項11之耐熱性壓製用緩衝材之製造方法,其中將 層疊物於溫度150°c〜180。(:、無壓狀態放置02〜15分鐘 後,於維持該溫度之狀態加壓、硫化及層疊一體化。 106048-1010413.docPatent Application No. 094,141,786, the scope of application for the Chinese patent application (April 101) 〇a X. Patent application scope: A cushioning material for heat-resistant twin pressing is used between a hot pressed disk and a molded article, j 4 Shidan is characterized in that at least one layer of bulky multi-woven fabric is used as its constituent member, and the constituent thread of the multi-woven fabric comprises a crimping processing line. 2. The heat-resistant pressing cushioning material according to the item 1, wherein the surface layer is provided with a resistant fiber member, and one or two layers of the multi-woven fabric are provided on the intermediate layer, and the rubber layer is interposed between the surface layer and the surface layer. Between intermediate layers or between intermediate layers. 3. The heat-resistant pressing cushioning material according to item 1 of the above, wherein the multi-woven fabric is a 2-weaving fabric to a 4-weave woven fabric. 4. The heat-resistant pressing cushioning material according to item 2, wherein the multi-woven fabric is a 2-weaving fabric to a 4-weave woven fabric. The heat-resistant pressing cushioning material according to any one of claims 1 to 4, wherein the constituent thread of the multi-woven U-cloth is selected from the group consisting of at least one of glass fibers, carbon fibers, and ceramic fibers. 6. The heat-resistant pressing cushioning material according to item 2, wherein the heat-resistant fibrous member of the surface layer is at least one selected from the group consisting of aromatic polyamide fibers, polyphenylene sulfide fibers, glass fibers, and carbon fibers. Heat fiber composition. The heat-resistant pressing cushioning material according to claim 2, wherein the heat-resistant fibrous member of the surface layer is composed of short fibers of aromatic polyamine fibers. 8. The heat-resistant pressing cushioning material according to any one of claims 2, 6 and 7, wherein the heat-resistant fiber member of the surface layer is treated with a heat-resistant resin. 9. The heat-resistant pressing cushioning material according to claim 2, wherein the rubber layer is selected from the group consisting of fluorine 106048-10I0413.doc 1373406 ίο. 11. 12. at least one of rubber and enamel rubber. The heat-resistant pressing cushioning material according to claim 2 or 9, which is interposed between the surface layer and the intermediate layer or between the intermediate layers by a short fiber-reinforced rubber layer. A method for producing a heat-resistant pressing buffer which is used between a hot-pressed disk and a molded article, wherein the method comprises: applying a heat-resistant fiber member to the surface layer, and providing at least one layer in the intermediate layer A multi-woven fabric of lotus-like type, wherein a laminate is formed between the surface layer and the intermediate layer and/or between the intermediate layers via an unvulcanized rubber layer, and the laminate is placed under pressure without pressure. Immediately after the crosslinking reaction of the rubber layer is started, the pressure, vulcanization, and lamination are integrated. The method for producing a heat-resistant pressing cushioning material according to claim 11, wherein the laminate is at a temperature of from 150 ° C to 180 °. (:, after being placed in a pressureless state for 02 to 15 minutes, it is pressurized, vulcanized, and laminated and integrated while maintaining the temperature. 106048-1010413.doc
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110785274A (en) * 2017-06-02 2020-02-11 山内株式会社 Hot-pressing cushioning material and method for manufacturing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110785274A (en) * 2017-06-02 2020-02-11 山内株式会社 Hot-pressing cushioning material and method for manufacturing same

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