TWI364408B - A method for sintering aggregates from wasted sludge - Google Patents

A method for sintering aggregates from wasted sludge Download PDF

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TWI364408B
TWI364408B TW96148432A TW96148432A TWI364408B TW I364408 B TWI364408 B TW I364408B TW 96148432 A TW96148432 A TW 96148432A TW 96148432 A TW96148432 A TW 96148432A TW I364408 B TWI364408 B TW I364408B
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waste sludge
waste
sludge
sintering
temperature
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TW96148432A
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TW200927695A (en
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Shih Pin Tu
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Axlom Internat Engineering Corp
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1364408 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一種以廢棄污泥燒結骨材方法, • 尤其是指一種將廢棄污泥經諸多步驟再以高溫燒結方 式,製造成一定強度以上之人造骨材,係將資源再利 - 用達到完善回收運用為目的之發明設計。 【先前技術】 按,在供建築、土木、農業上都會使用一些鋪設 的基礎骨材,而這些骨材大都取自大自然的岩石、石 ® 塊,由挖掘煉取再將破碎、研磨製成各行各業所需之 骨材大小的粒徑,然而,這些大自然的物資經由數十 年的開採墾伐,終究會破壞自然的生態及美感。 續,在自然環境中,如河川、湖泊或蓄水的水庫 等本身都具有與自然環境連結與相互鏈結的關係及功 4 能,而這些河川、湖泊或水庫的水除了可帶給我們景 觀、供水等功能外,水中也會有泥質且沉澱為底泥, 而這些底泥只會囤積越厚而改變河川、湖泊或水庫面 • 積或蓄水量;另,所引進的水源大都會經由淨水處理 場來作水質淨化處理,而其處理過程中會產生廢棄的 污泥,淨水經生活及工廠製程使用後所產生之廢(污) • 水,在排入回大自然水體前均須經過廢水處理廠之淨 . 化處理,處理過程亦將產生大量廢水污泥,此等廢棄 的污泥也無法再作他用,也都需經由人員來清除;因 此,若可以將這些自然或人為衍生的資源加以利用, 5 除可改善上述問題之外,亦可有另一種造福人類的發 展,相信會是人類的一大福音。 緣是,本發明人有鑑於此,秉持多年對研發骨材 處理製作技術的豐富專業設計製造及實際研究開發之 經驗,兹針對現有狀態及其缺失予以研究改良,提供 一種創新的以廢棄污泥燒結骨材方法,以期完全改善 現有之所有缺失者。 【發明内容】 爰是,本發明係有關於一種以廢棄污泥燒結骨材 1 方法,其主要係q水庫(湖泊)、河川所產生的底泥或 各淨水處理場及廢(污)水處理廠所產生之廢棄污泥 經由破碎篩選,再經攪拌混合、乾燥程序、磨碎程序、 造粒程序及燒結程序而製成具有符合抗壓強度標準之 人造骨材,以提供建築、土木、農業等多種用途使用 為首先應用發明者。 【實施方式】 7 而為令本發明之技術手段能夠更完整且清楚的揭 露,茲請一併參閱所附圖式及圖號,並詳細說明如下: 首先,請參閱第一圖所示,係為本發明以廢棄污 妮燒結骨材方法之流程示意圖,其流程步驟如下: '廢棄污泥(S1): 該廢棄污泥可經由各式廢(污)水處理廠產生之污 泥、淨水廠產生之污泥、河川底泥、水庫(湖泊)底泥 中獲得;而所獲得的廢棄污泥固體物含量中需有二氧 化矽加上氧化鋁〔Si〇2+Al2〇3〕的礦物成份,且須高於1364408 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a method for sintering aggregates with waste sludge, and in particular to a method in which a waste sludge is subjected to high-temperature sintering in a plurality of steps to produce a certain strength. The above-mentioned artificial aggregates are designed to re-use resources for the purpose of perfecting recycling. [Prior Art] According to the construction, civil engineering, agriculture, some laid foundation materials are used. Most of these aggregates are taken from the rock and stone blocks of nature, which are made by excavation and then crushed and ground. The size of the aggregate size required by all walks of life, however, these natural materials will destroy the natural ecology and beauty after decades of mining and cutting. Continued, in the natural environment, such as rivers, lakes or reservoirs that have water storage, they have the relationship and function of connecting with the natural environment, and the water of these rivers, lakes or reservoirs can bring us the landscape. In addition to water supply and other functions, there will be muddy water in the water and sedimentation as sediment. These sediments will only accumulate thicker and change the surface or water storage capacity of rivers, lakes or reservoirs. In addition, the water source will be introduced. The water purification treatment is carried out through the water purification treatment field, and waste sludge is generated during the treatment. The waste water (soil) generated by the clean water after being used in the life and factory process is discharged before being discharged into the natural water body. All must be cleaned and treated by the wastewater treatment plant. The treatment process will also produce a large amount of wastewater sludge. These abandoned sludges can no longer be used for other purposes, and they must be removed by personnel; therefore, if these natural Or the use of artificially derived resources, 5 In addition to improving the above problems, there is another kind of development for the benefit of mankind, which is believed to be a great boon for mankind. In view of this, the inventors of the present invention have been researching and improving the existing state and its lack of research, and have provided an innovative waste sludge for many years. The method of sintering aggregates with a view to completely improving all existing defects. SUMMARY OF THE INVENTION The present invention relates to a method for sintering aggregate 1 by waste sludge, which is mainly a sediment produced by a q reservoir (lake), a river, or a water treatment plant and waste (sewage) water. The waste sludge produced by the treatment plant is subjected to crushing and screening, and then stirred and mixed, a drying process, a grinding process, a granulation process and a sintering process to produce artificial aggregates having a compressive strength standard to provide construction, civil engineering, The use of a variety of uses such as agriculture is the first application of the inventors. [Embodiment] 7 In order to make the technical means of the present invention more complete and clear, please refer to the drawings and drawings, and the details are as follows: First, please refer to the first figure, The flow chart of the method for scraping the sinter of the sinter of the present invention is as follows: 'Abandoned sludge (S1): The waste sludge can be sent through various waste (sewage) water treatment plants to produce sludge and purified water. It is obtained from the sludge produced by the plant, the sediment in the river, and the sediment in the reservoir (lake); and the solid content of the waste sludge obtained requires the mineral of cerium oxide plus alumina [Si〇2+Al2〇3]. Ingredients and must be higher than

Claims (1)

1364408 _ 101年2月20日修正替換頁 十、申請專利範圍: - 1. 一種以廢棄污泥燒結骨材方法,其流程步驟如下: . (1)廢棄污泥一取用廢棄資源中的廢棄污泥,而該廢 , 棄污泥固體物中其二氧化矽加上氧 化铭〔Si〇2 + Al2〇3〕的礦物成份含量須 * * ·» 高於40%(w/w),而其助溶鑛物成份 * ; 不高於二氧化矽加上氧化鋁成份之 四分之一; (2) 乾燥程序一將廢棄污泥之含水率控制於10〜25% 的比例,且將乾燥溫度控制在 300〜400°C之間去除高揮發性有機物 質; (3) 磨碎程序一將乾燥後之廢棄污泥以磨碎設備將 廢棄污泥粉碎,且磨碎之污泥顆粒粒 徑至少在10 mesh以下; (4) 造粒程序一以成型製胚機將磨碎之廢棄污泥粉 ' 粒製成粗胚,粗胚之密度須高於 0. 8g/cm3以上,及厚度介於0. 1〜3cm; (5) 燒結程序一以翻轉式升溫模式進行粗胚燒結成 形,其以小於8°C/min之升溫速度, 持續升溫直至1000°C〜1250°C燒結溫 · 度為止,當達燒結溫度時,以恆溫持 . 溫至少一小時後,以自然降溫方式使 燒結成品降至室溫者。 2.如申請專利範圍第1項所述以廢棄污泥燒結骨材方 13 1364408 - 101年2月20 3修正替換頁 法,其中該廢棄污泥步驟中助熔礦物成份包含有氧 • 化鈣、氧化鎂、氧化鐵及氧化鉀〔CaO、MgO、Fe2〇3 . 及K2O〕至少一種者。 , 3.如申請專利範圍第1項所述以廢棄污泥燒結骨材方 / 法,其中該廢棄污泥步驟中二氧化矽加上氧化鋁的 ·〆 礦物成份不足時需添加一定比例之礦物材料,而其 • 礦物材料包含有礦化添加劑、粘土、陶瓷土、矽藻 土、岩礦、焚化底禮、焚化飛灰、廢梦砂粉、廢玻 - 璃粉至少一種。 4. 如申請專利範圍第3項所述以廢棄污泥燒結骨材方 ; 法,其中不同種類的廢棄污泥及添加不同礦物材料 於廢棄污泥中,需進一步經由攪拌混合步驟將其預 先充份混合,以利後續步驟的進行者。 5. 如申請專利範圍第4項所述以廢棄污泥燒結骨材方 法,其中該造粒程序步驟中以最大荷重至少8000 公斤以上的成型製胚機為之。 6. 如申請專利範圍第5項所述以廢棄污泥燒結骨材方 法,其中該造粒程序步驟中粗胚之形狀以圓球型為 佳。 7. 如申請專利範圍第6項所述以廢棄污泥燒結骨材方 法,其中該燒結程序步驟中所述之翻轉式升溫模式 ·' 為於燒結過程中該粗胚體均能隨時轉動,而單一粗 . 胚顆粒表面四週於高溫爐燒結過程,須能接觸與設 定值同溫度之熱源者。 8. 如申請專利範圍第7項所述以廢棄污泥燒結骨材方 14 1364408 - 101年2月20 a修正替換頁 法,其中該燒結程序步驟中以旋轉式爐體為之,其 • 粗胚填充率須小於30%,且翻轉速度須大於0. 5rpm . 者。 9. 一種以廢棄污泥燒結骨材方法,其流程步驟如下: ' (1)廢棄污泥一取用廢棄資源中的廢棄污泥,而該廢 棄污泥固體物中其二氧化矽加上氧 ’ 化铭〔Si〇2 + Al2〇3〕的礦物成份含量須 高於40%(w/w),而其助熔礦物成份 不高於二氧化矽加上氧化鋁成份之 四分之一; (2) 乾燥程序一將廢棄污泥之含水率控制於10〜25% 的比例,且將乾燥溫度控制在 300〜40(TC之間去除高揮發性有機物 質; (3) 磨碎程序一將乾燥後之廢棄污泥以磨碎設備將 廢棄污泥粉碎,且磨碎之污泥顆粒粒 徑至少在10 mesh以下; (4 )造粒程序一以成型製胚機將磨碎之廢棄污泥粉 粒製成粗胚,粗胚之密度須高於 0. 8g/cm3以上,及厚度介於0. 1〜3cm; ' (5)燒結程序一以靜置式升溫模式進行粗胚燒結成 jr f ' 形,其粗胚層堆靜置之各方厚度不大 . 於10cm,採以多段式升溫法,常溫 至500°C階段以小於8°C/min之升溫 速度,501°C至600°C階段以小於 15 1364408 101年2月20曰修正替換頁 3ΐ/πΰη之升溫速度,6〇rc至85〇t 階段以小於8°C/min之升溫速度, 851。(:直950°C階段以小於St/nlin 之升溫速度’ 951°C至燒結溫度階段 以小於8°C/min之升溫速度,以此升 溫方式直至1G00°C〜1250°C燒結溫度 為止,當達燒結溫度時,以恒溫持溫 至少兩小時後以自然降溫方式使燒 結成品降至室溫者。 H).如申請專利範圍第9 方法,其中該廢辛污、、尸案可/尼^結骨材 氧简、氧化鎂中助炫礦物成份包含有 及Κ2〇〕至少—種2鐵及氣化却〔Ca〇、MgO、Fe2〇3 11.如申請專利範圍第 而 矽 方法,其中該廢棄污沪2所述以廢棄污泥燒結骨材 的礦物成份不足時需=步驟中二氧化矽加上氣化鋁 其礦物材料包含有二:加一定比例之礦物材料,而 藻土、岩礦、焚化』=添加劑、粘土、陶瓷土、 破璃粉至少一種。-〜、焚化飛灰、廢矽砂粉'廢 12·如申請專利範固苐 方法,其中不_=所述以廢棄污泥燒結骨材 料於廢棄污泥中,需谁一棄污泥及添加不同礦物材 預先充份混合,以:一步經由授拌混合步驟將其 13.如申請專利範圍苐後續步驟的進行者。 方法’其中該造所述以廢棄污泥燒結 4步驟中以最大荷重至少咖 16 1364408 - 101年2月20日修正替換頁 • 公斤以上的成型製胚機為之。 - 14.如申請專利範圍第13項所述以廢棄污泥燒結骨材 . 方法,其中該造粒程序步驟中粗胚之形狀以圓球型 為佳。 171364408 _ February 20, 2011 Revision Replacement Page 10, Patent Application Scope: - 1. A method for sintering aggregates with waste sludge, the process steps are as follows: (1) Waste sludge is taken away from waste materials Sludge, and the content of minerals of cerium oxide plus oxidized [Si〇2 + Al2〇3] in the waste sludge and solid waste sludge shall be ** ·» higher than 40% (w/w), and Its solubilizing mineral content*; not higher than a quarter of the cerium oxide plus alumina component; (2) drying procedure 1 control the moisture content of the waste sludge to a ratio of 10 to 25%, and the drying temperature Controlling the removal of highly volatile organic substances between 300 and 400 ° C; (3) Grinding procedure - the dried sludge is pulverized by grinding equipment, and the crushed sludge particles are at least The granulation process is as follows: the granulation process is carried out by using a sizing machine to form a pulverized waste sludge powder into a coarse embryo, and the density of the coarse embryo must be higher than 0. 8g/cm3 or more, and the thickness is between 0. 1~3cm; (5) Sintering procedure - rough embryo sintering in a flip-type heating mode, which is less than 8 ° C / min Speed, continue to heat up until 1000 ° C~1250 ° C · sintering temperature of, when the sintering temperature is reached, in order to maintain a constant temperature. After warming at least one hour, followed by natural cooling down to room temperature refined manner by sintering. 2. As described in the scope of claim 1, the scrap sludge sintered aggregate material 13 1364408 - February 20, 2003 revised replacement page method, wherein the waste mineral component of the waste sludge step contains aerobic calcium At least one of magnesium oxide, iron oxide and potassium oxide [CaO, MgO, Fe2〇3 and K2O]. 3. If the waste sludge is sintered in the waste sludge step according to the first paragraph of the patent application, in the waste sludge step, a certain proportion of minerals is added when the cerium oxide plus alumina cerium mineral component is insufficient. Materials, and its mineral materials include mineralized additives, clay, ceramic soil, diatomaceous earth, rock ore, incineration, incineration fly ash, waste dream sand powder, waste glass - glass powder at least one. 4. If the waste sludge is sintered in the waste sludge as described in the third paragraph of the patent application, the different types of waste sludge and the different mineral materials are added to the waste sludge, and the mixture is further pre-charged through a stirring and mixing step. Mix the parts to facilitate the progress of the subsequent steps. 5. The method of sintering aggregate material by waste sludge according to item 4 of the patent application, wherein the granulation step is carried out by a molding machine having a maximum load of at least 8000 kg. 6. The method of sintering aggregate material by waste sludge as described in claim 5, wherein the shape of the rough embryo in the granulation step is preferably a spherical shape. 7. The method for sintering aggregate material by waste sludge according to item 6 of the patent application, wherein the inverting heating mode described in the sintering procedure step is capable of rotating at any time during the sintering process. Single coarse. The surface of the embryo particles is surrounded by a high temperature furnace and must be exposed to a heat source of the same temperature as the set value. 8. As described in the scope of patent application, the scrapping of the aggregate material of the waste sludge, 14 1364408 - February 20, 2010, is replaced by a rotary furnace body, which is thick. 5rpm。 The embryo fill rate must be less than 30%, and the flip speed must be greater than 0. 5rpm. 9. A method for sintering aggregate material by using waste sludge, the process steps are as follows: ' (1) Waste sludge is taken from waste sludge in waste resources, and the waste sludge solids are added with oxygen dioxide. 'Ming Ming [Si〇2 + Al2〇3] must have a mineral content of more than 40% (w/w), and its fluxing mineral composition is not higher than a quarter of that of cerium oxide plus alumina; 2) Drying procedure: control the moisture content of the waste sludge to a ratio of 10~25%, and control the drying temperature to 300~40 (to remove high volatile organic substances between TC; (3) the grinding process will dry The waste sludge is crushed by the grinding equipment, and the particle size of the crushed sludge is at least 10 mesh; (4) Granulation procedure: the waste sludge powder to be ground by the molding machine The grain is made into a coarse embryo, the density of the coarse embryo must be higher than 0. 8g/cm3 or more, and the thickness is between 0. 1~3cm; ' (5) Sintering procedure: the coarse embryo is sintered into a jr f ' shape in a static heating mode The thickness of the rough pile layer is not large. At 10cm, the multi-stage heating method is adopted, and the room temperature is up to 500 °C. Temperature rise rate less than 8 ° C / min, 501 ° C to 600 ° C stage with less than 15 1364408 101 February 20 曰 correction replacement page 3 ΐ / π ΰ η heating rate, 6 〇 rc to 85 〇 t stage to less than 8 ° C/min heating rate, 851. (: Straight 950 ° C stage with a temperature increase rate less than St / nlin '951 ° C to the sintering temperature stage with a temperature increase of less than 8 ° C / min, this way to the temperature up to 1G00 ° When the sintering temperature is C~1250 °C, when the sintering temperature is reached, the sintered product is cooled to room temperature by a natural temperature reduction method after holding at a constant temperature for at least two hours. H). Stained, corpse can be / Nie ^ knot oxygen, the magnesium minerals in the magnesia contains and Κ 2 〇] at least - species 2 iron and gasification but [Ca 〇, MgO, Fe2 〇 3 11. The method of applying for the patent scope is the same as the method of the patent, wherein the waste minerals of the waste sludge sintered aggregate are required to be in the step = the step of cerium oxide plus vaporized aluminum, the mineral material of which contains two: plus a certain proportion Mineral material, while algae, rock, incineration = additive, clay, ceramic soil, At least one kind of glass powder. -~, incinerated fly ash, waste sand powder 'waste 12 · If applying for patent Fan Guyu method, which does not _= the waste sludge sintered bone material in waste sludge, who needs one Disposing the sludge and adding different mineral materials in advance, and mixing them in a step by a mixing and mixing step. 13. As in the scope of the patent application, the subsequent steps are carried out. Method 'The process of sintering the waste sludge 4 steps In the maximum load of at least coffee 16 1364408 - February 20, 101 revised replacement page • More than one kilogram of molding machine. - 14. The method of claim 13, wherein the shape of the rough embryo in the granulation step is preferably a spherical shape. 17
TW96148432A 2007-12-18 2007-12-18 A method for sintering aggregates from wasted sludge TWI364408B (en)

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