1351433 Λ 、 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種頭髮清潔組合物’具體而言，本發明係關於 一種包含天然多孔隙磨砂顆粒之頭髮清潔組合物。 【先前技術】BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a hair cleansing composition. In particular, the present invention relates to a hair cleansing composition comprising natural porous scrub particles. [Prior Art]
隨著時代的變遷，大眾對於個人潔淨產品（諸如潔膚產品口 腔清潔產品、及頭髮清潔產品等）的品質與功效要求逐日提高。 除基本的清潔效果之外’可提供其他附加、協同功效的多功：性 潔淨產品，更能符合消費者的期待與需求。 目前’許多市售的個人潔淨產品中，均標榜額外添加可去除老 廢角質及/或提高清潔效果的研磨物質。舉例言之，部分市售牙膏 除含有保濕劑、發泡劑、黏結劑、抗菌劑等成分外，亦含有研磨 劑（例如碳酸㈣_、或氧化銘等），可在不傷害牙齒表面 的情況下，去除其表面上的附著物（例如食物殘渣），以恢復牙齒 原本的光澤度。此外’許多市面上的洗面乳、洗手乳及沐浴乳等 潔膚產品，亦含有顆粒成分（例如果核粉末等），故可在清潔皮膚 的同時提供去除表皮老化角質之目的。關於此，具有去^質功用 之研磨物質（物理性方式）通线選自磨碎的植物種子或果實外 设（如杏仁果、核果殼或綠讀）、礦物性粉體微粒（如滑石、_ 氧化石夕、天然泥、灰、砂或息土）、金屬粉體微粒（如氧化紐）、 高分子聚合物微珠（如聚乙稀）、可溶性柔珠微粒（如㈣、粗睡、、 砂糖或奶粉）、及膠質成份（如高分子膠或黏性物質）。 ^ 然而’該等市售產品所含之研磨物質，若使用者的使用方式或 1351433 力道不當，很容易由於研磨物質本身的質地過硬（如高分子聚合 物微珠或果實外殼）或所具有之銳角（如氧化鋁、砂、或礦物性 粉體微粒）而對施用處之皮膚造成刺激感、甚至刮傷，故無法提 供一舒適的使用條件。With the changes of the times, the quality and efficacy requirements of personal cleansing products (such as cleansing products for mouth cleaning products and hair cleaning products) have been increasing day by day. In addition to the basic cleaning effect, it can provide other additional and synergistic effects: the sexual cleansing products are more in line with the expectations and needs of consumers. At present, many of the commercially available personal cleansing products are marked with additional abrasive substances that remove old dead skin cells and/or improve cleaning results. For example, some commercially available toothpastes contain an emollient, a foaming agent, a binder, an antibacterial agent, and the like, and also contain an abrasive (for example, carbonic acid (tetra), or oxidized, etc.), without damaging the surface of the tooth. Remove the attachments on the surface (such as food debris) to restore the original gloss of the teeth. In addition, many skin cleansing products such as facial cleansers, hand lotions and shower gels also contain granules (such as nuclear powder), so they can cleanse the skin and provide the purpose of removing the aged keratin. In this regard, the abrasive material (physical mode) through which the function of the material is removed is selected from the group consisting of ground plant seeds or fruit peripherals (such as almond fruit, nuclear shell or green read), mineral powder particles (such as talc, _ oxidized stone, natural mud, ash, sand or earthy soil), metal powder particles (such as oxidized New Zealand), high molecular polymer beads (such as polyethylene), soluble soft bead particles (such as (four), rough sleep, , sugar or milk powder), and gelatinous ingredients (such as polymer glue or sticky substances). ^ However, 'the abrasive substances contained in these commercially available products, if the user uses it or the 1354143 is not properly used, it is easy to be due to the texture of the abrasive itself (such as polymer microbeads or fruit shells) or Sharp angles (such as alumina, sand, or mineral powder particles) can cause irritation or even scratching on the skin of the application site, and thus do not provide a comfortable use condition.
至於頭髮清潔產品，以洗髮精為例，除提供應具備的潔淨能力 之外，另冀望可滿足去除因頭皮表皮細胞代謝加速、成熟過程不 元王、甚或皮屑芽孢菌（malassezia furfur )所引起的頭皮屑（即， 成群脫落之表皮細胞，而非臉部或身體上之表皮老化細胞）之附 加需求。迄今，洗髮精大多採用化學性的去屑或抗屑成份，像是 較具刺激性的果酸成分及克多可那挫加沉刪滅）#。此外， 台灣專利公告第300851號係揭露-種具增進粒子去除頭皮屬藥劑 沉積之高泡沫去頭皮屑洗髮精，其係、含有粒子去頭皮屑藥劑（例 如^定硫酮鋅等金屬鹽類）之洗髮精組合物。然而，金屬鹽類通 常為銳角狀且硬度高，易刺傷頭皮表面；同時，金屬鹽類藥劑需 先沉積卿皮上核發揮去财屑的仙，卻又因其親膚性差， 致使其去除頭皮屑之效果大為降低。 碎藻土（diat〇mite)係碎藻（例如金黃藻類）死亡後，所留下 =且切質的外殼堆積而成。如第1圖所示，石夕藻土的表面 … 在使用上不會刺傷施用部位；且由於矽藤土 =力二會粉碎成如究土般的細微粉體，因此當使用者的施 面=虽時:並不會對所施用之部位造成刺痛感或到傷其表 頭作爭產广尤又Γ有含有如残土之天然多孔隙研磨顆粒之 其是洗髮精）見諸於世。究其原因，乃因石夕蕩 1351433 土在黏度較低之頭部潔淨產品令容易沉殿且沉殿後難以分散之 故。換5之，一旦研磨顆粒無法懸浮於清潔產品中時，其去屑功 能亦將喪失。另一方面，洗髮精中常添加之護髮成分（如石夕靈 (dimethicone)或石夕烧氧（siUc〇ne))，會促使如石夕藻土等研磨顆 粒的聚合（flocculation )及點附（adhesi〇n )現象，使其喪失作用。 緣此’目前尚未成功地將天然多孔隙研磨顆粒應用於頭部清潔產 品47的例子。 ' • 4十對上述問題，本案發明人經一連串之實驗及研究，提出一種 含有天然多孔隙磨砂顆粒之頭髮清潔組合物。其中，可均勻地將 天然多孔隙磨砂顆粒分散於頭髮清潔組合物令，從而得藉由物理 性的方式去除頭皮屑、淨化頭皮頭髮、去除污垢，提高潔淨效能， 節省洗蘇時間及清洗頭部之頻率。时，本發明組合物亦可促進 頭皮呼吸及營養劑、抗屑劑等有效成分的滲透，滿足多方面的需 求。 • 【發明内容】 本發明之一目的在於提供一種頭髮清潔組合物，其包含： 10重量％至80重量％之界面活性劑； 0.01重量％至10重量％之增稠劑； 〇. 1重量％至25重量％之天然多孔隙磨砂顆粒；以及 水。 在參閱圖式及隨後描述之實施方式後，本發明所屬技術領域中 具有通常知識者當可輕易瞭解本發明之基本精神及其他發明目 的，以及本發明所採用之技術手段與較佳實施態樣。 • / 7 1351433 【實施方式】 根據本發明之頭髮清潔組合物，所含天然多孔隙磨砂顆粒可提 供快速、有效的頭皮潔淨去屑效果，甚至可清除細菌防止其滋生。 叙而。’可用於本發明之天然多孔隙磨砂顆粒，具有形狀圓滑 及中空易碎結構的特點，與頭皮接觸時不會產生刺痛感或刮傷皮 膚+例。之，可用於本發明之天然多孔隙磨砂顆粒係選自以下 ^ 群組^夕藻土、活性碳（如竹碳）' 骨粉（如骨鈣）、及其組合。 於本發明組合物之一較佳實施態樣中，係採用石夕藻土作為天然 多孔隙磨砂顆粒。如上所述，矽藻土具有圓滑的矽質外殼與易粉 碎性，可溫和有效的去除皮屑而不傷及頭皮及頭髮。 此外，天然多孔隙磨砂顆粒之用量，以可達到所欲之去屑功效 且不影響應有料潔效果為標準。亦即，若其帛㈣低，無法提 供所欲之^屑效果；反之，則可能因顆粒過多有實際使用上的困 難且影響清潔劑本身的去污能力。一般而纟，以本發明頭髮清潔 • 組合物之總量計，天然多孔隙磨砂顆粒之用量為0.1重量％至25 重量％，較佳為0.5重量％至15重量％，更佳為ι·〇重量％至5重 量％的範圍内。 如上所述，天然多孔隙磨砂顆粒必須能均勻地懸浮於本發明之 頭髮清潔組合物甲，以發揮其功效。因此，本發明組合物中另含 有一增稠劑以調整頭髮清潔組合物之黏度，提供可均勻分散天然 多孔隙磨砂顆粒的基質環境。根據本發明，通常係將頭髮清潔組 合物之黏度調整在4000 cps至100000 cps的範圍内。具體言之， 右組合物之黏度低於4000 cps，天然多孔隙磨砂顆粒將會沉澱且 1351433 無法均勻地懸浮於組合物中，甚至發生團聚、黏附的情形，影響 其效能；另一方面’若組合物之黏度高於100000 cps，將因組合 物本身過於黏稠而不利於實際應用（例如無法利用喷頭擠出方式 加以使用）。較佳地，本發明頭髮清潔組合物之黏度為12000 cps 至 65000 cps 〇 可使用如電解質鹽類、經或未經加工之天然膠體（其中經加工 之天然膠體亦可稱為半合成膠體）、合成膠體等作為本發明增稠 劑。其中’電解質鹽類增稠劑可增加組合物之極性，使所含界面 活性劑（即’去除油污之主要成分）的溶解度下降，形成膠束微 胞（micelle)而達到增稠之目的（換言之，黏度提高）。 適用於本發明組合物作為增稠劑之電解質鹽類包括（但不限於 此）選自以下群組：氯化鈉、氣化鉀、氯化錢、硫酸納、硫酸钟、 硫酸銨、硝酸鈉、硝酸鉀、硝酸銨、醋酸鈉、醋酸鉀、醋酸銨、 碳酸鈉、碳酸鉀、碳酸銨、氫氧化鈉、氫氧化鉀、氫氧化銨、及 其組合；較佳地，係採用氯化鈉為電解質鹽類增稠劑。 適用於本發明組合物作為增稠劑之天然膠體之實例包括（但不 限於此）：藻膠（align)、藻酸（alignic acid)、蕩酸鈉（sodium alginate)、藻酸鉀（potassium alginate)、膨潤土（bentonite)、明 膠（gelatin )、杲膠（pectin )、托辣甘樹穋（tragacanth Gum )、黃 原膠（xanthan gum )、亞拉伯膠（gum arabic/gum acacia )、纖維素 膠（cellulose gum )、甲基纖維素（methylcellulose ，MC)、羰曱 纖維素納（sodium carboxymethylcellulose )、經乙基纖維素 (hydroxyethylcellulose ) 羧丙基 纖維素 9 1351433 (hydroxypropylcellulose)、及其它天然樹脂（natural resin)等。 適於作為增稠劑之合成膠體之實例則包括（但不限於此）：聚乙二 醇（polyethylene glycol ’ PEG )、聚烧醇酿胺（polyalkanolamide )、 聚酿胺（polyamide )、聚丙稀（polyacrylate )、聚乙烯。比17各烧_ (polyvinyl pyrrolidone，PVP)、聚乙烯醇（poly vinyl alcohol， PVA )、卡波姆（carbomer or carbopol )、及其它合成樹脂（synthetic resin)等。 增稠劑之用量，以頭髮清潔組合物之重量計，係在0.01重量％ 至10.0重量％的範圍内，較佳在0.5重量％至2.0重量％的範圍内。 不同於一般市售洗髮精添加油份或臘質以乳化方式來提高其稠 度，本發明係採用如電解質鹽類及天然、半合成、或合成膠體之 不含油份或臘質之增稠成分以提供增稠效果，從而可避免因採用 油份或臘質等乳化增稠成分所導致天然多孔隙磨砂顆粒發生聚合 或黏附的情形。因此，較佳地，係避免於本發明頭髮清潔組合物 中避免添加矽靈或矽油成分。 本發明頭髮潔組合物另包含一界面活性劑。界面活性劑即提供 清潔功效之主要成份，可幫助頭皮與頭髮上之油垢溶於水中經沖 洗後帶走。可使用任何合宜的界面活性劑於本發明組合物中，根 據本發明組合物之一具體實施態樣，所用界面活性劑係一親水性 界面活性劑，例如陰離子界面活性劑、陽離子界面活性劑、兩性 界面活性劑、及非離子界面活性劑，亦可視需要使用前述界面活 性劑的任意組合。 舉例言之，用於本發明組合物中之界面活性劑可選自以下群 10 1351433As for hair cleansing products, taking shampoo as an example, in addition to providing the cleansing ability to be provided, it is also desirable to satisfy the removal of the metabolism of the scalp epidermal cells, the maturation process, or the malassezia furfur. Additional requirements for dandruff (ie, epidermal cells that are shed in groups, rather than epidermal aging cells on the face or body). To date, shampoos have mostly used chemical anti-dandruff or anti-dandruff ingredients, such as the more irritating fruit acids and the creases. In addition, Taiwan Patent Publication No. 300851 discloses a high-foam anti-dandruff shampoo for improving particle removal of scalp genus, which is a metal-containing dandruff agent (for example, a metal salt such as zinc thione) ) shampoo composition. However, metal salts are usually sharp-angled and have high hardness, which is easy to stab the surface of the scalp. At the same time, the metal salt agent needs to deposit the nucleus on the upper nucleus to remove the dandruff, but because of its poor skin-friendly nature, it removes the scalp. The effect of the chips is greatly reduced. After the diat〇mite is killed by the algae (such as golden algae), the left and the cut outer shell are piled up. As shown in Fig. 1, the surface of Shixiazao soil does not puncture the application site in use; and since the vine soil = force will pulverize into a fine powder like soil, when the user applies = Although: it does not cause a tingling sensation on the applied part or a slap in the head. It is also a shampoo containing natural porous abrasive particles such as residual soil. . The reason is because Shi Xidang 1351433 soil cleansing products in the head with low viscosity makes it easy to sink the temple and it is difficult to disperse after sinking the temple. In the case of 5, once the abrasive particles cannot be suspended in the cleaning product, the anti-dusting function will also be lost. On the other hand, hair care ingredients (such as dimethicone or siUc〇ne) often added to shampoos promote the flocculation and point of abrasive particles such as Shiyoshi. Attached (adhesi〇n) phenomenon, making it useless. Thus, there has been no successful application of natural porous abrasive particles to the head cleaning product 47. ' • For the above ten questions, the inventor of the present invention proposed a hair cleaning composition containing natural porous scrub particles through a series of experiments and studies. Among them, the natural porous grind particles can be uniformly dispersed in the hair cleansing composition, thereby physically removing dandruff, purifying the scalp hair, removing dirt, improving the cleansing efficiency, saving the washing time and cleaning the head. The frequency. In the meantime, the composition of the present invention can also promote the penetration of active ingredients such as scalp respiration and nutrient and anti-dandruff, and meet various needs. • SUMMARY OF THE INVENTION An object of the present invention is to provide a hair cleansing composition comprising: 10% by weight to 80% by weight of a surfactant; 0.01% by weight to 10% by weight of a thickener; 〇. 1% by weight Up to 25% by weight of natural porous frosted particles; and water. The basic spirit and other objects of the present invention, as well as the technical means and preferred embodiments of the present invention, can be readily understood by those skilled in the art in view of the drawings and the embodiments described hereinafter. . • / 7 1351433 [Embodiment] According to the hair cleansing composition of the present invention, the natural porous scrub particles can provide a fast and effective scalp cleansing and anti-dandruff effect, and even remove bacteria to prevent their growth. Narrative. The natural porous frosted particles which can be used in the present invention have the characteristics of a smooth shape and a hollow and fragile structure, and do not cause tingling or scratching the skin when in contact with the scalp. The natural porous frosting particles useful in the present invention are selected from the group consisting of the following: group algae, activated carbon (e.g., bamboo carbon) 'bone powder (e.g., bone calcium), and combinations thereof. In a preferred embodiment of the composition of the present invention, Shixiazao soil is used as the natural porous abrasive particle. As mentioned above, diatomaceous earth has a smooth enamel shell and easy to be pulverized, which can gently and effectively remove dandruff without damaging the scalp and hair. In addition, the amount of natural porous scrub particles is based on the ability to achieve the desired anti-dandruff effect without affecting the desired cleansing effect. That is, if the crucible (four) is low, it is impossible to provide the desired shaving effect; on the contrary, it may be difficult to actually use the particles and affect the decontamination ability of the cleaning agent itself. Generally, the amount of the natural porous frosting particles is from 0.1% by weight to 25% by weight, preferably from 0.5% by weight to 15% by weight, more preferably ι·〇, based on the total amount of the hair cleansing composition of the present invention. It is in the range of % by weight to 5% by weight. As described above, the natural porous frosted particles must be uniformly suspended in the hair cleansing composition A of the present invention to exert its efficacy. Accordingly, the compositions of the present invention additionally comprise a thickening agent to adjust the viscosity of the hair cleansing composition to provide a matrix environment for uniformly dispersing the natural porous scrub particles. According to the present invention, the viscosity of the hair cleansing composition is usually adjusted in the range of 4000 cps to 100,000 cps. Specifically, if the viscosity of the right composition is less than 4000 cps, the natural porous frosted particles will precipitate and 1541433 will not be uniformly suspended in the composition, and even agglomeration and adhesion will affect the performance; The viscosity of the composition above 100,000 cps will be unfavorable for practical use due to the composition itself being too viscous (for example, it cannot be used by nozzle extrusion). Preferably, the hair cleansing composition of the present invention has a viscosity of from 12,000 cps to 65000 cps, and may be used as an electrolyte salt, a natural colloid or an unprocessed natural colloid (where the processed natural colloid may also be referred to as a semi-synthetic colloid), A synthetic colloid or the like is used as the thickener of the present invention. Among them, 'electrolyte salt thickener can increase the polarity of the composition, so that the solubility of the surfactant (ie, the main component of 'oil removal)) is reduced, forming micelle micelles for thickening purposes (in other words , viscosity increases). Electrolyte salts suitable for use as thickening agents in the compositions of the present invention include, but are not limited to, selected from the group consisting of sodium chloride, potassium hydride, chlorinated money, sodium sulphate, sulphuric acid, ammonium sulphate, sodium nitrate , potassium nitrate, ammonium nitrate, sodium acetate, potassium acetate, ammonium acetate, sodium carbonate, potassium carbonate, ammonium carbonate, sodium hydroxide, potassium hydroxide, ammonium hydroxide, and combinations thereof; preferably, sodium chloride is used. It is an electrolyte salt thickener. Examples of natural colloids suitable for use as thickening agents in the compositions of the present invention include, but are not limited to, align, alignic acid, sodium alginate, potassium alginate (potassium alginate) ), bentonite, gelatin, pectin, tragacanth Gum, xanthan gum, gum arabic/gum acacia, cellulose gum Cellulose gum ), methylcellulose (MC), sodium carboxymethylcellulose, hydroxyethylcellulose carboxypropylcellulose 9 1351433 (hydroxypropylcellulose), and other natural resins )Wait. Examples of synthetic colloids suitable as thickeners include, but are not limited to, polyethylene glycol 'PEG, polyalkanolamide, polyamide, polypropylene (polyethylene glycol 'PEG), polyamide (polyamide), polypropylene (polyethylene glycol) Polyacrylate), polyethylene. More than 17 (polyvinyl pyrrolidone, PVP), polyvinyl alcohol (PVA), carbomer or carbopol, and other synthetic resins. The thickener is used in an amount ranging from 0.01% by weight to 10.0% by weight, preferably from 0.5% by weight to 2.0% by weight, based on the weight of the hair cleansing composition. Different from the general commercially available shampoo added oil or wax to increase its consistency by emulsification, the present invention uses a thickening component such as an electrolyte salt and a natural, semi-synthetic or synthetic colloid containing no oil or wax. In order to provide a thickening effect, it is possible to avoid the polymerization or adhesion of natural porous frosted particles due to the use of emulsified thickening components such as oil or wax. Accordingly, it is preferred to avoid the addition of a scorpion or eucalyptus component to the hair cleansing compositions of the present invention. The hair cleansing composition of the present invention further comprises a surfactant. The surfactant is the main ingredient that provides cleansing benefits. It helps the oil on the scalp and hair to be dissolved in water and washed away. Any suitable surfactant can be used in the compositions of the present invention. According to one embodiment of the composition of the present invention, the surfactant used is a hydrophilic surfactant such as an anionic surfactant, a cationic surfactant, The amphoteric surfactant, and the nonionic surfactant may also be used in any combination of the foregoing surfactants as needed. By way of example, the surfactant used in the compositions of the present invention may be selected from the group 10 1351433
組：烷基硫酸鹽類（alkyl sulfates，ASs)(如十二烷基硫酸鈉（sodium lauryl sulphate，SLS))、聚氧乙稀烧基謎硫酸鹽類（alkyl ether sulfates，AESs)(如聚氧乙稀烧基硫酸鈉（sodium laureth sulphate， SLES ))、異丙基苯績酸鈉（sodium cumene sulfonate)、十二硫錢 (ammonium lauryl sulphate，ALS)、十二S旨硫酸敍（ammonium laureth sulphate，ALES )、十二烧基硫酸三乙醇胺（triethanolamine lauryl sulphate ’ TLS )、酿基曱基牛膽素鹽類（acyl methyl taurates， AMTs)、N-酿基麵胺酸鹽類（N-acyl glutamates)、烧基甜菜驗（alkyl betaine)、院基醯胺甜菜驗（alkyl amide betaine)、咪。坐琳基甜菜 驗（imidazolinium betaine)、脂肪酸烧醇酿胺（fatty acid alkanol amide )、單乙醇胺（monoethanol amine，MEA )、二乙醇酿胺 (diethanol amine，DEA )、及其組合。 一般而言，若欲提供油性髮質所用之清潔劑，通常採用去污力 較強但刺激性稍強的陰離子界面活性劑如SLS或SLES作為界面 活性劑；若欲提供乾性、受損髮質、嬰幼兒所用之低刺激性清潔 劑，則採用洗淨力雖沒有SLS與SLES等強但較為溫和的陰離子 界面活性劑如AMTs或N-醯基麩胺酸鹽類，及兩性界面活性劑如 異丙基笨磺酸鈉、烷基甜菜鹼、烷基醯胺甜菜鹼或咪唑啉基甜菜 驗（imidazolinium betaine)作為界面活性劑。此外，本發明組合 物可進一步包含一輔助界面活性劑，通常為非離子界面活性劑如 脂肪酸烷醇醯胺、MEA或DEA，以提高整體的催泡、穩泡、增稠、 清潔、及降低主劑的刺激性等效能。 根據本發明，界面活性劑之用量以可達到所欲清潔功效為基Group: alkyl sulfates (ASs) (such as sodium lauryl sulphate (SLS)), alkyl ether sulfates (AESs) (such as poly Sodium laureth sulphate (SLES), sodium cumene sulfonate, ammonium lauryl sulphate (ALS), ammonium sulphate (ammonium laureth) Sulphate, ALES ), triethanolamine lauryl sulphate ' TLS , acyl methyl taurates ( AMTs ) , N-acyl sulphate ( N-acyl ) Glutamates), alkyl betaine, alkyl amide betaine, and microphone. It is based on imidazolinium betaine, fatty acid alkanol amide, monoethanol amine (MEA), diethanol amine (DEA), and combinations thereof. In general, if you want to provide a cleanser for oily hair, an anionic surfactant such as SLS or SLES with strong detergency and a little irritating power is usually used as a surfactant; if you want to provide dry and damaged hair Low-irritant detergents for infants and young children, although there are no strong but milder anionic surfactants such as AMTs or N-mercapto glutamate, such as SLS and SLES, and amphoteric surfactants. Sodium isopropyl sulfonate, alkylbetaine, alkylguanamine betaine or imidazolinium betaine is used as a surfactant. In addition, the compositions of the present invention may further comprise a co-surfactant, typically a nonionic surfactant such as a fatty acid alkanolamine, MEA or DEA, to enhance overall foaming, foam stabilization, thickening, cleaning, and reduction. The irritating equivalent energy of the main agent. According to the present invention, the amount of the surfactant is based on the desired cleaning effect.
11 1351433 準，以頭髮清潔劑組合物之重量計，一般為10重量％至80重量％， 較佳在25重量％至50重量％。 此外，本發明頭髮清潔組合物亦可進一步含有任何其他的合宜 成分，例如抗氧化劑（如丁基化羥基曱笨（butylated hydroxytoluene )、丁基化經基苯曱醚（butylated hydroxy anisole )、 及維生素E)、防止產生不溶性金屬化合物之螯合劑（如乙二胺酸 四乙酸胺（ethylenediaminetetraacetic acid，EDTA))、抗菌劑、延 長保存期限之防腐劑、紫外線吸收劑、pH值調整劑、及提供視覺 效果之增色劑（如珠光劑、乳濁劑、色素）等。再者，可視需要 添加化學性去角質成份，例如單一水基果酸（alpha hydroxy acid， AH A )及其衍生物、水楊酸（beta hydroxy acid，BHA )及其衍生物、 A 酸、A 搭、A 醇、酸性胺基酸（amino acid filaggrin based antioxidants，AFAs )、丙酮酸（pyruvic acid )、植酸（phytic acid )、 複合酸、二虱醋酸、及酵素成份（如蛋白酵素、木瓜酵素），以去 除老廢角質；添加芳香成份（如薰衣草、薄荷、歐百芷等）以提 供清洗時與清洗後的清新感受；添加營養成分，如維他命B、維 他命E以提供柔絲般觸感的髮質而易於整理；添加植物萃取物（如 蘆薈、絲瓜）、胎盤素、中藥方、膠原蛋白等成分進一步滋養頭髮； 及/或添加具療效活性之成分，以針對各種症狀提供醫療用途，如 具止癢效果的有三氣二苯脲（trichlorocarbanilid )、硫黃、水楊酸、 «比咬硫酮鋅（Zinc pyrithione’ Z-pt)及異丙基甲基酚（is〇pr〇pyl methyl phenol)。前述視需要採用之成分的用量，以不影響所欲清 潔與去頭皮屑之功效為原則。 12 1351433 本發明頭髮清潔組合物係特別用於清潔頭皮及頭髮，其所含之 天然多孔隙磨砂顆粒，可透過較溫和之物理性方式，在不傷害頭 皮及頭髮的情況下，達到去屑的目的。此外，磨砂顆粒還有助於 按摩頭皮、打開頭皮毛孔，促進頭皮呼吸作用及營養吸收效果等。 為進一步彰顯本發明之特徵及所達功效，茲例示以下實施例進 一步說明。 【實施例1】（組合物之懸浮穩定性的測試） 以30重量％之十二烷基硫酸鈉溶液為基料，添加如表1所示不 同含量之氣化鈉（NaCl)。再以每10克十二烷基硫酸鈉溶液添加 0.2克之比例添加矽藻土，獲得具不同電解質鹽類增稠劑濃度之組 合物。接著，測量各該樣品於不同轉速（30 i*pm、10 rpm或6rpm ) 下的黏度平均值。之後，對樣品分別進行離心加速實驗，使用離 心機以每分鐘3000轉之速度分離15秒，觀察樣品中磨砂顆粒的 懸浮穩定性（即物理安定性），測試結果如表1所列。 表111 1351433 is generally from 10% by weight to 80% by weight, preferably from 25% by weight to 50% by weight, based on the weight of the hair cleansing composition. Further, the hair cleansing composition of the present invention may further comprise any other suitable ingredients such as an antioxidant (e.g., butylated hydroxytoluene, butylated hydroxy anisole, and vitamins). E), a chelating agent that prevents the formation of insoluble metal compounds (such as ethylenediaminetetraacetic acid (EDTA)), an antibacterial agent, a preservative that prolongs shelf life, a UV absorber, a pH adjuster, and provides vision Effect of coloring agents (such as pearlescent agents, opacifiers, pigments). Furthermore, chemical exfoliating ingredients such as alpha hydroxy acid (AH A ) and its derivatives, beta hydroxy acid (BHA ) and its derivatives, A acid, A may be added as needed. Amino alcohol, amino acid filaggrin based antioxidants (AFAs), pyruvic acid (pyruvic acid), phytic acid (phytic acid), complex acid, diacetic acid, and enzyme components (such as proteinase, papaya enzyme) ) to remove old dead skin cells; add aromatic ingredients (such as lavender, mint, osmium, etc.) to provide a refreshing feeling after washing and washing; add nutrients such as vitamin B, vitamin E to provide a silky touch The hair is easy to organize; adding plant extracts (such as aloe vera, loofah), placenta, traditional Chinese medicine, collagen and other ingredients to further nourish the hair; and / or add therapeutically active ingredients to provide medical use for various symptoms, Trichlorocarbanilid, sulfur, salicylic acid, Zinc pyrithione' Z-pt and isopropyl methyl group have antipruritic effects. (Is〇pr〇pyl methyl phenol). The above-mentioned ingredients are used as needed, so as not to affect the efficacy of the desired cleansing and anti-dandruff. 12 1351433 The hair cleansing composition of the present invention is particularly useful for cleaning scalp and hair, and the natural porous scrub particles contained therein can achieve dandruff removal through a milder physical manner without damaging the scalp and hair. purpose. In addition, the matte particles help to massage the scalp, open the pores of the scalp, promote scalp respiration and nutrient absorption. In order to further illustrate the features of the present invention and the effects thereof, the following examples are further illustrated. [Example 1] (Test for suspension stability of composition) Using a 30% by weight sodium lauryl sulfate solution as a base, sodium carbonate (NaCl) of different contents as shown in Table 1 was added. Further, diatomaceous earth was added in a ratio of 0.2 g per 10 g of sodium lauryl sulfate solution to obtain a composition having a concentration of a thickener of different electrolyte salts. Next, the average viscosity of each of the samples at different rotation speeds (30 i*pm, 10 rpm or 6 rpm) was measured. Thereafter, the samples were subjected to a centrifugal acceleration test, and separated by a centrifugal machine at a speed of 3000 rpm for 15 seconds to observe the suspension stability (i.e., physical stability) of the abrasive particles in the sample. The test results are listed in Table 1. Table 1
NaCl 濃度(％)a) 懸浮穩定性 (3000rpm » 15 sec) 黏度平均值(cps) 0 少量沉澱 2920 0.1 微量沉澱 4893 0.2 微量沉澱 6767 0.4 極微量沉澱 12347 0.6 均勻 26820 0.9 均勻 50700 1.0 均勻 53033 1.1 均勻 56900 1.5 均勻 63500 1351433 a)漢度係以十二烷基硫酸鈉溶液之總重量計 根據表1之録果可知’黏度在約4〇〇〇 cps至100000 cps範圍内 的本發明組合物’可展現良好的懸浮均勻度。尤其，黏度在約12000 cps以上者，其懸浮均勻度的表現尤佳。 【實施例2】（洗後頭皮檢測） 以30重量％之十二烷基硫酸鈉溶液為基料，添加1.〇 (%)之氣 化鈉（NaCl)(以十二烧基硫酸納溶液之總重量計），再以每10克 ' 十二烧基硫酸納溶液添加0.2克之比例添加石夕藻土，製得一本發明 樣品。 重複上述方式調配一清潔劑組合物’惟未加入石夕藻土’製得一 對照樣品。 以均勻相同之力道與流程，取用各5毫升之本發明樣品及對照 樣品，分別清洗實驗者之左半部及右半部頭皮’清洗完畢後吹乾。 • 搔著，以下述三種皮膚毛囊檢測儀攝影（白光、偏極光及紫外光）， 觀察頭皮清潔、刺激及受損情形。 (A)白光光學顯微鏡法（light microscopy): 本方法係藉由一皮膚分析系統（SKIN ANALYSIS SYSTEM )(儀 器商：Professional Scientific Instrument Co，Korea)進行頭皮檢 測。其係將頭皮表面放大至50倍，以協助肉眼觀察。拍攝結果係 如第2A及2B圖所示。其中，第2A圖係以本發明樣品清潔後的 頭皮，係乾淨且無頭皮屑；第2B圖係對照樣品清潔後的頭皮，圖 14 1351433 中可見仍有殘存之頭皮屑。 (B) 偏極光光學顯微鏡法（polar microscopy): 使用與檢測方法（A)相同之儀器並採用偏極光進行頭皮檢測，其 中，偏極光可消除角質層之反光，故可提供清楚顯示皮膚中淺層 血管、毛囊及皮脂腺的照片。經使用本發明樣品與對照樣品之頭 皮的攝影結果，分別如第3A圖（本發明樣品）及第3B圖（對照 樣品）所示，結果顯示經本發明樣品及對照樣品清潔後的頭皮， 均無刮傷或刺激發紅現象。由此可知，本發明所含之天然多孔隙 磨砂顆粒（此實施例係使用矽藻土）並不會對頭皮造成損傷。 (C) 紫外光光學顯微鏡法（UV microscopy): 使用與檢驗方法（A)相同之儀器並採用紫外光進行頭皮檢測，此 方式係用於檢視皮膚頭皮屑的殘留情形（當頭皮角質越厚，所顯 示之圖像顏色也越白），並觀察是否有細菌的繁殖狀況，其中痤瘡 桿菌（P. acnes )與極小棒狀桿菌（corynebacterium minutissimum ) 於紫外光照射下分別呈紫紅色螢光及珊瑚紅螢光。拍攝洗淨後之 頭皮的前頂部與上頂部，結果分別顯示於第4A及4B圖與第5A 及5B圖。其中，第4A圖顯示經本發明樣品清潔後之左前頂部頭 皮，係乾淨且無頭皮屑；第4B圖係顯示經對照樣品清潔後之右前 頂部頭皮，由其相較於第4A圖略白之顏色可知具有較厚的角質 層，亦發現細菌殘留的痕跡（紫紅色螢光）。 續參第5A及5B圖，第5A圖係經本發明樣品清潔後的左上頂 部頭皮，乾淨無頭皮屑；第5B圖係經對照樣品清潔後的右上頂部 頭皮，角質層較厚（略白）且髮根處有細菌殘留之痕跡（呈珊瑚 15 1351433 紅色）。 上述實施例僅為例示性說明本發明之原理及其功效，並闡述本 發明之技術特徵，而非用於限制本發明之保護範疇。任何熟悉本 技術者在不違背本發明之技術原理及精神下，可輕易完成之改變 或安排，均屬本發明所主張之範圍。因此，本發明之權利保護範 圍係如後附申請專利範圍所列。 【圖式簡單說明】 第1圖係為矽藻土之外觀示意圖； 第2A及2B圖係根據實施例2以白光光學顯微鏡法所攝之圖片； 第3A及3B圖係根據實施例2以偏極光光學顯微鏡法所攝之圖 片； 第4A及4B圖係根據實施例2以紫外光光學顯微鏡法所攝之圖 片；以及 第5A及5B圖係根據實施例2以紫外光光學顯微鏡法所攝之圖 片0 【主要元件符號說明】 (無） • / % 16NaCl concentration (%) a) Suspension stability (3000 rpm » 15 sec) Viscosity average (cps) 0 Small amount of precipitate 2920 0.1 Trace precipitate 4893 0.2 Trace precipitate 6767 0.4 Very small precipitate 12347 0.6 Uniform 26820 0.9 Uniform 50700 1.0 Uniform 53033 1.1 Uniform 56900 1.5 Uniform 63500 1351433 a) Hando is based on the total weight of the sodium lauryl sulfate solution. According to the results of Table 1, the composition of the present invention having a viscosity of about 4 〇〇〇 cps to 100,000 cps can be used. Shows good suspension uniformity. In particular, the viscosity uniformity is particularly good for those with a viscosity above about 12,000 cps. [Example 2] (Detection of scalp after washing) Using a 30% by weight solution of sodium lauryl sulfate as a base, adding 1. 〇 (%) of sodium hydride (NaCl) (with sodium sulfonate solution) The total weight of the sample was further added to the mixture of 0.2 g per 10 g of the sodium dodecyl sulfate solution to prepare a sample of the invention. A control sample was prepared by repeating the above-described manner, except that no Shixiazao soil was added to prepare a control sample. With the same force and flow, 5 ml of each of the inventive sample and the control sample were taken, and the left and right scalp of the experimenter were respectively cleaned and dried. • Look at the scalp cleansing, irritation, and damage with the following three skin follicle detectors (white, off-polar, and ultraviolet). (A) Light microscopy: This method is performed by a SKIN ANALYSIS SYSTEM (instrumenter: Professional Scientific Instrument Co, Korea) for scalp detection. It enlarges the surface of the scalp to 50 times to aid visual inspection. The results are shown in Figures 2A and 2B. Among them, Fig. 2A shows that the scalp after cleaning of the sample of the present invention is clean and free of dandruff; Fig. 2B shows the scalp after cleaning of the control sample, and there is still residual dandruff in Fig. 14 1351433. (B) Polar microscopy: The same instrument as the detection method (A) is used and the scalp is detected by using polarized light. Among them, the polarized light can eliminate the reflection of the stratum corneum, so it can clearly show the shallowness in the skin. Photographs of layers of blood vessels, hair follicles, and sebaceous glands. The photographic results of the scalp using the sample of the present invention and the control sample were as shown in Fig. 3A (sample of the present invention) and Fig. 3B (control sample), respectively, and the results showed that the scalp after cleaning of the sample of the present invention and the control sample did not Scratching or irritating redness. From this, it is understood that the natural porous frosted particles (this embodiment uses diatomaceous earth) contained in the present invention do not cause damage to the scalp. (C) Ultraviolet light microscopy (UV microscopy): The same method as the test method (A) is used and the scalp is detected by ultraviolet light. This method is used to check the residual condition of the skin dandruff (when the scalp is thicker, The color of the displayed image is also whiter, and observe whether there is bacterial reproduction. Among them, P. acnes and corynebacterium minutissimum are purple-red fluorescent and coral under ultraviolet light. Red fluorescent. The front top and top top of the washed scalp were taken and the results are shown in Figures 4A and 4B and Figures 5A and 5B, respectively. 4A shows the left front scalp after cleaning of the sample of the present invention, which is clean and free of dandruff; and FIG. 4B shows the right front scalp after cleaning of the control sample, which is slightly whiter than that of FIG. 4A. It can be seen that there is a thicker cuticle layer, and traces of bacterial residue (purple red fluorescence) are also found. Continue to refer to Figures 5A and 5B, Figure 5A is the top left scalp after cleaning of the sample of the invention, clean dandruff; Figure 5B is the upper right top scalp after cleaning of the control sample, the stratum corneum is thicker (slightly white) and There are traces of bacterial residues in the hair roots (corrosion 15 1351433 red). The above embodiments are merely illustrative of the principles and effects of the present invention, and are illustrative of the technical features of the present invention and are not intended to limit the scope of the present invention. Any changes or arrangements that can be easily made by those skilled in the art without departing from the technical principles and spirit of the invention are within the scope of the invention. Therefore, the scope of the invention is set forth in the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the appearance of diatomaceous earth; Figs. 2A and 2B are photographs taken by white light optical microscopy according to Example 2; Figs. 3A and 3B are biased according to Example 2 Picture taken by aurora optical microscopy; pictures 4A and 4B are pictures taken by ultraviolet light microscopy according to Example 2; and pictures 5A and 5B are taken according to Example 2 by ultraviolet light microscopy Picture 0 [Description of main component symbols] (none) • / % 16