1343932 九、發明說明： 【發明所屬之技術領域】 本發明涉及-種隔熱聚氯乙_明膠布，尤指—種以非塗佈加工 衣知具遮蔽紅外線及料線触的隔熱餘乙舰明勝布。 【先前技術】 如圖1所示的習知隔熱透明膠膜1G，是既可容許可見光穿透又可 阻隔紅外光的隔熱透明物件’―般黏貼在建秘玻璃或汽車玻璃上面 ’使建築物賴或汽車玻輯_無果和财透_視覺要求。 但，習知隔熱透明膠膜10的紫外光遮蔽效果不佳。為此，建築玻 璃或汽車賴㈣财皆會添加紫外光㈣吸㈣，使賴玻璃或气 車玻璃具備遮蔽料摘能力，贿護人體避免受到料光的傷宝。 習知隔熱義顧的製法，有乾式塗佈製法及赋塗佈製法兩種 ’皆在塑膠基材的上面㈣—層隔熱膜而製得具隔熱和透 熱透明膠膜。 如圖1所示’以乾式塗佈加工製成的隔熱透明_ 1G，係以真， 舰或蒸财式’將金顧金概化鱗無猜料12均物著在瓣 基材11的上面而形成隔熱膜。 々圖2所7F ’⑽式塗佈加工製成的隔熱翻膠膜⑼，係將具^ 熱功能的無機顆粒22均勻分散在合適的樹脂23及溶射，姐配製: 5 21 後，無機顆㈣她旨23就形成附著在娜基材21上㈣隔孰膜。 但，不錢_乾式塗㈣法或赋塗佈製法1包括兩道製程 1343932 ’即，必触製作娜基材後，再於所製成的塑膠基材上面塗佈一層 隔熱膜。所以’ f知隔熱透明膠布採用乾式塗佈製法或濕式塗佈製法 的缺點’就疋加J1製程多’ _〇_設備成本高及產速偏低。而且，採用濕 式塗佈製法還有廢溶劑的環保問題。 【發明内容】 本發明的主要目的在於提供一種隔熱聚氣乙烯透明膠布及其製法 ,以特定配方的混合料為原料，並直接採用製作聚氣乙轉布的傳統 製程，不必使驗佈加卫’財製得具錢紅外線及料線特性的隔 熱聚氣乙烯透明膠布。 其製法為：在製作聚氣乙烯膠布的傳統製程中，直接使用含有特 疋配方的I氣乙馳脂、可鋪、無機隔熱顆粒及其它添加助劑的混 a料纟二壓延機或T_Die機或吹氣成型機，以壓延加工或T_Die加工或 氣力工乂彳于種隔熱聚氣乙稀透明膠布。這種隔熱聚氣乙稀透明膠 布不僅保有♦氣乙烯既有物性，更兼具透明性、低霧度及優異的紅 外線及紫外線遮蔽效果。 本电月的隔熱小氣乙稀透明勝布製法，因為直接使用製作聚氣乙 烯膠布的傳統製程，除不必使用塗佈加工之外，且可以省卻塗饰製法 的設備投資、以及可避免濕式塗佈製法的廢溶劑環保問題。因此，本 I明的製法具製程簡單、加工成本低簾、產速快及環保的優點。 【實施方式】 如圖3所示，本發明所示的隔熱聚氣乙烯透明膠布3〇，是厚度介 於0.02〜i.omm且具透明性及遮蔽紅外線及紫外線特性的透明 或半 丄州932 夥布膠布，其結構特徵為：以厚度介於G.G2〜Μ麵的聚氯乙稀 的益座-為基材且所述的聚氣乙稀耀布31的組織中，包含均勻散佈 的無機隔熱顆粒32。 :本發日㈣隔_氣乙_霄布％的製法，是崎定配方的混合 二：:料，不必使用塗佈加工，直接採用製作聚氯乙婦膠布的傳統製 程，就可製得具魏紅外線及紫外線特性賴熱聚氣乙稀透_布％ 且'、力口工衣知簡單，設備成本低簾及產速快的優點。 # 據此’本發明的隔熱聚氯乙稀透明膠布30，是由包括下列步驟的 製法所製得： ⑴將聚氣乙烯樹脂腑HR、可塑劑〇〜8職、無機隔熱顆粒 0.3〜15 PHR、安定劑〇」〜15 PHR、滑劑〇1〜15 pHR、助劑（包括 改質劑、界面活性劑、分散劑及紫外線吸收劑）〇 3〜25舰及色 料0.0〜12PHR以混合機混合均勻後，引入萬馬力機均勾混煉； ⑵料溫控制在150〜19Gt，雜輪娜化後，將充分反應的混合料 ’以壓延機加工成型厚度控制介於__〜1()_的熱炫膠布， ，於成型後，Ik即引入溫度在20〜85°C的水中冷卻硬化，以提升 聚氣乙烯膠布的透明性，再經過除水後，引入步驟（3);或以丁_ Die機加工成型厚度㈣介於咖職〜⑺聰的熱轉布，於成 型後，直接引入步驟(3);或以吹氣成型機加工成型厚度控制介於 0.02mm〜〇.8mm的熱熔膠布，於成型後，直接引入步驟⑶； (3)將膠布引入冷卻輪組冷卻定型，經捲取製成本發明的隔熱聚氣乙 烯透明膠布30。 1343932 在步驟（1)中，所使用的聚氣乙烯樹脂，可選自以塊狀聚合(Bulk1343932 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a kind of heat-insulating polyvinyl chloride-gelatin cloth, in particular, a kind of heat-insulating material which is shielded from infrared rays and material lines by a non-coated processing garment. Ship Ming wins cloth. [Prior Art] The conventional heat-insulating transparent film 1G shown in Fig. 1 is a heat-insulating transparent object that can both transmit visible light and block infrared light, and is adhered to the glass or the glass of the automobile. Building Lai or Auto Glass _ No Fruit and Caijing _ Visual Requirements. However, the conventional heat-insulating transparent film 10 has a poor ultraviolet shielding effect. To this end, the building glass or the car (4) will add ultraviolet light (4) suction (4), so that the glass or air glass has the ability to cover the material, and protect the human body from the damage of the material. In the conventional method of heat insulation, there are two methods, namely, a dry coating method and a coating method, which are made of a heat-insulating and heat-transparent transparent film on the upper surface of the plastic substrate (4). As shown in Fig. 1, 'insulating and transparent _ 1G made by dry coating process, which is based on the true, ship or steamed type', puts Jin Gujin's generalized scale without guessing 12 on the top of the valve substrate 11 A heat insulation film is formed.隔热 Figure 2, 7F '(10) type of heat-insulating film (9), the inorganic particles 22 with heat function are uniformly dispersed in a suitable resin 23 and sprayed, sister: 5 21, inorganic particles (4) She aims to form a film on the substrate 21 (4). However, no money _ dry coating (four) method or coating method 1 includes two processes 1343932 ‘that is, after the substrate is made, a layer of thermal insulation film is applied on the finished plastic substrate. Therefore, the shortcomings of the dry-coating method or the wet-coating method of the heat-insulating transparent tape are increased by the J1 process. _〇_ The equipment cost is high and the production speed is low. Moreover, the wet coating process also has environmental problems of waste solvents. SUMMARY OF THE INVENTION The main object of the present invention is to provide a heat-insulating gas-glycol transparent tape and a preparation method thereof, which are prepared by using a compound of a specific formula as a raw material, and directly adopting a traditional process for producing a gas-gathering cloth, without having to make a cloth inspection Wei's financial system has a heat-insulating polystyrene transparent tape with infra-red and wire characteristics. The preparation method is as follows: in the traditional process for producing the gas-gum vinyl tape, directly using the I gas-containing polyurethane, the slab, the inorganic heat-insulating granules and other additive additives, the squeezing machine or the T_Die Machine or blow molding machine, with calendering processing or T_Die processing or pneumatic work in a kind of insulated and condensed polyethylene transparent tape. This kind of heat-insulating polyethylene transparent tape not only retains the physical properties of qi ethylene, but also has transparency, low haze and excellent infrared and ultraviolet shielding effects. This electric month's heat-insulating, small-gas, transparent and transparent cloth-making method, because the traditional process of making poly-glycolated vinyl tape is used directly, in addition to the need to use coating processing, the equipment investment of the finishing method can be omitted, and the wet type can be avoided. Environmental protection problems of waste solvents in coating process. Therefore, the method of the present invention has the advantages of simple process, low processing cost, fast production speed and environmental protection. [Embodiment] As shown in Fig. 3, the heat-insulating polystyrene transparent adhesive tape 3 shown in the present invention is a transparent or semi-fine state having a thickness of 0.02 to i.omm and having transparency and shielding infrared rays and ultraviolet rays. 932 smear tape, which is characterized in that: a substrate having a thickness of between G.G2 and Μ 的 为 为 为 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 且 的 的 的Inorganic thermal insulation particles 32. : The date of this issue (4) _ _ _ _ 霄 % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % Wei infrared and ultraviolet characteristics rely on hot gas, ethylene, sinter, _ cloth% and ', force mouth work clothes know simple, low equipment cost and fast production speed. # According to this invention, the insulated polyvinyl chloride transparent tape 30 of the present invention is obtained by the following method: (1) Polyethylene resin 腑HR, plasticizer 〇8, inorganic insulating particles 0.3~ 15 PHR, stabilizer 〇"~15 PHR, slip agent 〜1~15 pHR, additives (including modifier, surfactant, dispersant and UV absorber) 〇3~25 ship and color material 0.0~12PHR After the mixer is evenly mixed, it is introduced into the 10,000-horsepower machine and hooked and mixed; (2) The material temperature is controlled at 150~19Gt, and after the miscellaneous rounding, the fully-reacted mixture is controlled by the calendering machine. The thickness control is between __~1 () _ the hot tape, after molding, Ik is introduced into the temperature of 20 ~ 85 ° C water cooling hardening to enhance the transparency of the polyethylene gas tape, after water removal, introduced into step (3); Or by Ding _ Die machining forming thickness (four) between the cadre ~ (7) Cong's thermal transfer cloth, after molding, directly into the step (3); or by the blow molding machine processing forming thickness control between 0.02mm ~ 〇. 8mm hot-melt tape, after molding, directly into step (3); (3) Introduce the tape into the cooling wheel set to cool The type is wound up to form the heat-insulating polyethylene transparent tape 30 of the present invention. 1343932 In the step (1), the polystyrene resin used may be selected from a bulk polymerization (Bulk)
Polymerization)、>谷液聚合（Solution Polymerization)、懸浮聚合 (Suspension Polymerization) ^(Emulsion Polymerization)^ t 得的聚氯乙稀聚合物或共聚物的其中一種或一種以上的組合物。 在步驟（1)中，所使用的可塑劑，可選自磷酸酯類、酜酸系、苯三 酸酯類、環氧類、聚酯類、氣化烴類或脂肪族二酸酯類可塑劑的其中 一種或一種以上。 在步驟（1)中’所使用的無機隔熱顆粒32，粒徑介於0 005〜2μηι， 視透明度、霧度等不同物性的需求，可選自二氧化鈦(Ti〇2)、氧化辞 (Zn〇)、氧化釩(v2〇5)、氧化銦_3)、氧化爾、氧化錫⑼a)、 氧化銻(Sb203)、石爪化鋅(zns)、銻踢氧化物(AT〇)、銦錫氧化物(iTO)、 類似金屬氧化物的其中一種或一種以上。 在步驟⑴巾’所制的蚊劑，可選自Ba-Zn系或Ca-Zn系或有 機錫等之一種或多種複合安定劑。 在步驟（1)中，所使用的滑劑，可以是硬喊系、脂肪酸系、脂肪 祕胺#自日系、金屬石驗類、有機衫等之滑劑。可利用上述不同 種類的滑劑其中之—種、多種甚至全部搭配使用皆可。 “在步驟（1)中’所使用的助劑，可以是偶合劑、界面活性劑、分散 劑、、高分子聚合物改質劑或紫外線吸收劑的其卜種或—種以上搭配 的fv力77如1及助劑的目的，在於促使所製成的聚氣乙稀膠布31 的：中之無機隔熱顆粒32達到均勾分散的目的。 '视的偶⑽，可選自有機魏化合物、有機触化合物 1343932 或有機鈦鋁化合物的其中一種。所述的分散劑’可選自高分子型的共 聚物分散劑、含矽成份分散劑或含氟成份分散劑的其中一種或一種以 .上搭配而成。所述的紫外線吸收劑，可選自羥基苯基苯并三唑類紫外 .線吸收劑、或羥基二笨甲酮類紫外線吸收劑的其中一種或一種以上。 在步驟（1)中，所使用的色料，可視產品的色相需求酌予添加，或 為有機系色料，或為無機系色料，亦可採無機、有機色料混合方式。 在使用上，本發明的隔熱聚氣乙烯透明膠布30可以單層使用外， 鲁還可以如圖4所示的以多層疊合在一起使用，或者，如圖5所示的與 他種塑膠基材40疊合在一起使用上。 以下，以實施例具體說明以本發明製法所製成的隔熱聚氣乙烯透 明膠布30的特性，而且，隔熱聚氣乙烯透明膠布加各項物性的評估 方式’係依據下列的測試方法。 (1)可見光穿透率及霧度測試： 採用日商 Tokyo Denshoku 透率及霧度測試機(Haze Meter)，依JIS K77〇5測試標準，測試聚 氣乙烯膠布的光透過率及霧度值。 測試結果為可見光穿透率越高、霧度值越低，則代表聚氣乙稀 膠布的透明性越佳。 (2)紅外線及紫外線阻隔率測試： 採用日商難產製_為紅外線阻隔率測試機， 依邶R雇測試標準，測試聚氯乙烯夥布的紅外線阻隔率。 賴結果為紅外線阻隔率愈高，代表聚氣乙稀膠布的隔熱效果 1343932 越佳；紫外線穿透率愈低’代表聚氯乙烯膠布的阻隔紫外線(uv) 效果越佳。 〔實施例1〕 生產度0.2mm軟度40PHR的隔熱聚氣乙烯透明膠布3〇 ,其製 法為· (1) 依表1的特定配方，將聚氣乙烯樹脂 '可塑劑、無機燏熱顆粒、 助劑（包括改質劑、界面活性劑、分散劑及紫外線吸收劑）、安定劑 _ 、滑劑等原物料用混合機混合均勻後，引入萬馬力機均勻混煉·， (2) 料溫控制在i50〜19(rc，經輥輪機膠化後，以壓延加工將充分反 應的混合料製成厚度〇,2mm的熱熔膠布，隨即引入溫度在〜幻 °C的水中冷卻硬化； (3) 經過除水後，將膠布引入冷卻輪組冷卻定型，經捲取即製得厚度 0.2mm軟度40PHR的隔熱聚氯乙烯透明膠布3〇。 測試結果如表1所示，顯示所製得的隔熱聚氯乙烯透明膠布3〇具 鲁備良好的透明性、紅外線遮蔽率及紫外線阻隔率，且加工過程中勘 不會有析出的現象。 〔實施例2〕 除厚度為0.3mm外，所製得的隔熱聚氣乙烯透明膠布3〇的原物料 •配方及製法皆同實施例1。 測试結果如表1所*，顯示所製得的厚度a3m_熱聚氣乙稀透 明膠布30仍具備良好的透明性、紅外線遮蔽率及紫外線阻隔率，且加 工過程中ΑΤΟ不會有析出的現象。 1343932 〔實施例3〕 除使用吹氣加工外，依表1的特定配方，使用實施例1的製法生 •產厚度G.G2mm軟度4GPHR的隔熱聚氣乙稀透明膠布3〇。 .· 職結果如表1所示’顯示所製得的隔熱聚氣乙稀透明膠布3〇且 備良好的透難、紅外線遮蔽率及料線阻隔率，且加璃程中at〇 不會有析出的現象。 〔實施例4〕 • 除厚度為h〇mm外’所製得的隔熱聚氣乙稀透明膠布30的原物料 配方及製法皆同實施例1。 測試結果如表1所示，顯示所製得的厚度l.Omm隔熱聚氣乙稀透 明膠布30仍具備透明性、且具備相當優異紅外線遮蔽率及紫外線阻隔 率，且加工過程中AT0不會有析出的現象。 〔貫施例5〕 除使用T-Die加工外’依表i的特定配方，使用實施例】的製法生 •產厚度0.2麵軟度40酿的隔熱聚氣乙稀透明膠布％。 、 測試結果如表1所示，顯示所製得的隔熱聚氣乙烯透明膠布30仍 具備透明性 '且·相當優異紅外線遮蔽率及料線阻辭，且加工 •過程中AT0不會有析出的現象。 〔實施例6〕 除厚度為〇.3咖外，所製得的隔熱聚氣乙稀透明膠布别 配方及製法皆同實施例5。 狀。果如表i所不，顯示所製得的厚度〇3_隔熱聚氣乙稀透 1343932 ， 仍具備透明性、且具備相當優異紅外線遮蔽率及紫外線阻隔 率’且加工過程中AT〇不會有析出的現象。 〔實施例7〕 絲1的特定配方’使用實施例i的製法生產厚度〇2mm軟度 40PHR的隔熱聚H乙騎明膠布30。 暮式結果如表1所示’顯示所製得的隔熱聚氣乙稀透明膠布3〇仍 具備透明性、且具_當優異紅外線遮神及紫外線阻醉，且加工 鲁過程中ΑΤΟ不會有析出的現象。 〔實施例8〕 除厚度為0.3麵外，所製得的隔熱聚氣乙烯透明膠布％的原物料 配方及製法皆同實施例7。 測試結果如表i所示，顯示所製得的厚度〇·3_隔熱聚氣乙稀透 明膠布30仍具備透明性、且具備相當優異紅外線遮蔽率及紫外線阻隔 率，且加工過程中ΑΤΟ不會有析出的現象。 •〔比較例1〕 生產厚度0.2疆軟度卿HR的聚氯乙歸透明膠布，其原物料配方 除不含無機隔熱齡’改_、界面活_、分散斜，其製法皆同 •貫施例1。 ' _結果如表1所示，顯示所製得的厚度0.2咖聚氣乙稀透明膠 布’因為原料配方巾不含域隔熱雌’在紅外線雜率方面較實施 例1、5及7所製得的隔熱聚氣乙烯透明膠布3〇劣等許多。 、 〔比較例2〕 1343932 生產厚度〇.2_軟度仙歷的聚氯乙烯透明膠布，其原物料配方 除不含改質劑、界面活性劑、分散劑外，其餘皆同實施例卜 .測試結果如表！所示，顯示所製得的厚度〇2_聚氣乙稀透明膠 .’ _沒有使収質劑、界面活_、分㈣，在紅外線遮蔽率及 i外線阻隔率方面皆較實施例i、5及7劣等許多。而且，加工過程中 會有析出現象，進而影響聚氣乙稀透明勝布產品的加工性及品併。 〔比較例3〕 〇口貝0 •以尺寸^m⑽麵*〇·3 _的無色透明麵為對照物 里”光透麟、霧度、紅外線遮辭及料線阻隔率。 測試結果如表丨所示，顯示無色透明玻璃的紅外 線阻隔率確實不佳，較實施例2、4、6及8相差很多。羊及表外 1343932 表1Polymerization), >Solution Polymerization, Suspension Polymerization ^ (Emulsion Polymerization) ^ One or more compositions of the polyvinyl chloride polymer or copolymer. In the step (1), the plasticizer used may be selected from the group consisting of phosphates, citric acid, trimellitic acid esters, epoxy resins, polyesters, gasified hydrocarbons or aliphatic diesters. One or more of the agents. In the step (1), the inorganic heat insulating particles 32 used have a particle diameter of 0 005 to 2 μm, and may be selected from titanium oxide (Ti〇2) and oxidized (Zn) depending on the requirements of different physical properties such as transparency and haze. 〇), vanadium oxide (v2〇5), indium oxide_3), oxidized oxide, tin oxide (9) a), cerium oxide (Sb203), zinc claw zinc (zns), strontium oxide (AT〇), indium tin One or more of oxides (iTO), similar to metal oxides. The mosquito prepared in the step (1) can be selected from one or more complex stabilizers of Ba-Zn type or Ca-Zn type or organic tin. In the step (1), the slip agent to be used may be a lubricant such as a hard shout, a fatty acid, a fat secret amine, a Japanese, a metal stone, or an organic shirt. It is possible to use various types of the above-mentioned kinds of slip agents, one kind, a plurality of types, or even all of them. The auxiliary agent used in the step (1) may be a coupling agent, a surfactant, a dispersing agent, a polymer polymer modifier or a UV absorber, or a fv force of the above-mentioned type. The purpose of 77 and the auxiliary agent is to promote the purpose of the uniform inorganic heat insulating particles 32 of the prepared polyethylene film 31 to be uniformly dispersed. The visual couple (10) may be selected from organic Wei compounds, One of organic contact compound 1343932 or an organotitanium aluminum compound. The dispersant' may be selected from one or more of a polymeric copolymer dispersant, a cerium-containing dispersing agent or a fluorine-containing dispersing agent. The ultraviolet absorber may be selected from one or more of a hydroxyphenylbenzotriazole ultraviolet light ray absorbing agent or a hydroxydibenzophenone ultraviolet absorbing agent. In the step (1) In the use, the coloring material used may be added according to the hue requirement of the product, or may be an organic coloring material or an inorganic coloring material, or may be a mixed manner of inorganic or organic coloring materials. Hot polyethylene vinyl transparent tape 30 It can be used in a single layer, and the ru can also be used in a plurality of layers as shown in FIG. 4, or can be used in combination with other kinds of plastic substrates 40 as shown in FIG. 5. Hereinafter, by way of example The characteristics of the heat-insulating polystyrene transparent tape 30 produced by the method of the present invention are specifically described, and the evaluation method of the heat-insulating gas-gum transparent tape plus various physical properties is based on the following test methods: (1) Visible light wear Permeability and haze test: The light transmittance and haze value of the polyethylene gas tape were tested according to the JIS K77〇5 test standard using the Japanese Denshoku Density and Haze Meter. The test result is visible light. The higher the penetration rate and the lower the haze value, the better the transparency of the polyethylene foil. (2) Infrared and UV blocking rate test: Adopting the Japanese manufacturer's difficult production system _ is the infrared blocking rate test machine, relying on R employs the test standard to test the infrared blocking rate of the PVC cloth. The higher the infrared blocking rate is, the better the heat insulation effect of the polyethylene foil is 1343932; the lower the UV transmittance is, the representative is PVC. Tape The effect of blocking ultraviolet (uv) is better. [Example 1] A heat-insulating polystyrene transparent adhesive tape of 0.20 degree softness and 40PHR is produced, and the preparation method is (1) according to the specific formula of Table 1, the gas is collected. Vinyl resin 'plasticizer, inorganic hot particles, additives (including modifiers, surfactants, dispersants and UV absorbers), stabilizers, lubricants and other raw materials are mixed evenly with a mixer, and then introduced into 10,000 horsepower. (2) The material temperature is controlled at i50~19 (rc, after being gelled by the roller mill, the mixture which is fully reacted by calendering is made into a thickness of 〇, 2 mm of hot-melt adhesive tape, and then the temperature is introduced. ~ illusion °C water cooling hardening; (3) After removing water, the tape is introduced into the cooling wheel set for cooling and shaping, and the heat-insulating polyvinyl chloride transparent tape with a thickness of 0.2 mm and a thickness of 40 PHR is obtained by winding. The test results are shown in Table 1. It shows that the obtained heat-insulating polyvinyl chloride transparent tape 3 has good transparency, infrared shielding rate and ultraviolet blocking rate, and there is no precipitation during processing. [Example 2] In addition to the thickness of 0.3 mm, the raw material of the obtained heat-insulating polystyrene transparent adhesive tape 3 was formulated and prepared in the same manner as in Example 1. The test results are as shown in Table 1. It shows that the thickness of the obtained a3m_heat-polyethylene transparent tape 30 still has good transparency, infrared shielding rate and ultraviolet blocking rate, and there is no precipitation during processing. phenomenon. 1343932 [Example 3] In addition to the use of the blowing process, according to the specific formulation of Table 1, the method of the method of Example 1 was used to produce a heat-insulating polyethylene transparent tape of thickness G G G G G G G G G G G G G G G G G G G G G G G G G G. .. The results of the job are shown in Table 1. 'The display of the insulated and condensed polyethylene transparent tape 3 is prepared and has good penetration, infrared shielding rate and material line rejection rate, and at the time of the addition of glass. There is a phenomenon of precipitation. [Example 4] • The raw material formulation and preparation method of the heat-insulating polyethylene transparent transparent tape 30 prepared in addition to the thickness of h 〇 mm were the same as in Example 1. The test results are shown in Table 1. It shows that the obtained thickness of 1.0 mm of heat-insulating polyethylene transparent tape 30 still has transparency, and has excellent infrared shielding rate and ultraviolet blocking rate, and AT0 will not be processed during processing. There is a phenomenon of precipitation. [Example 5] In addition to the use of T-Die processing, according to the specific formulation of Table i, the method of using the method of the method] produces a thickness of 0.2 surface softness 40% of the heat-insulating polyethylene transparent tape. The test results are shown in Table 1. It shows that the obtained heat-insulating polystyrene transparent tape 30 still has transparency 'and · is excellent in infrared shielding rate and material line resistance, and AT0 will not precipitate during processing and processing. The phenomenon. [Example 6] Except that the thickness was 〇.3, the obtained heat-insulating polyethylene transparent transparent tape was formulated and prepared in the same manner as in Example 5. shape. If it is not shown in Table i, it shows that the thickness 〇3_insulating gas-gas smear is 1343932, which still has transparency, and has excellent infrared shielding rate and ultraviolet blocking rate', and AT does not process during processing. There is a phenomenon of precipitation. [Example 7] Specific Formulation of Silk 1 The heat-insulating poly-H-bake gelatin 30 having a thickness of 〇 2 mm and a softness of 40 PHR was produced by the method of Example i. The results of the 暮 type are shown in Table 1. 'The display of the heat-insulating polyethylene transparent tape 3 〇 still has transparency, and has excellent infrared ray and ultraviolet light, and it will not be processed during processing. There is a phenomenon of precipitation. [Example 8] The raw material formulation and the preparation method of the obtained heat-insulating polystyrene transparent tape% were the same as in Example 7 except that the thickness was 0.3. The test results are shown in Table i, which shows that the thickness 〇·3_insulated polyethylene transparent tape 30 still has transparency, and has excellent infrared shielding rate and ultraviolet blocking rate, and does not process during processing. There will be a phenomenon of precipitation. • [Comparative Example 1] Polychloroethane-based transparent tape with a thickness of 0.2 Kuanqingqing HR is produced. The raw material formula is the same as the inorganic heat-insulating age, _, interface _, scatter oblique, and its method is the same. Example 1. The results of the results are shown in Table 1. The results show that the thickness of the 0.2-gauge polyethylene transparent tape is 'because the raw material formula does not contain the domain insulation female' in terms of infrared noise ratio compared to the examples 1, 5 and 7. The insulated polystyrene vinyl transparent tape 3 is a lot worse. [Comparative Example 2] 1343932 The production of polyvinyl chloride transparent tape of thickness 〇.2_softness of the calendar, the original material formula except the modifier, surfactant, dispersant, the rest are the same as the examples. The test results are as shown! As shown, the thickness 〇2_polyethylene transparent veneer produced is shown. _ No sizing agent, interface _, sub-(4), in terms of infrared shielding rate and i-line rejection ratio, compared with the example i, 5 and 7 are inferior. Moreover, there will be an appearance in the processing process, which will affect the processability and quality of the gas-glued transparent woven cloth products. [Comparative Example 3] Sakaguchi 0 • The colorless transparent surface of the size ^m (10) plane * 〇 · 3 _ is used as a control. "Light penetration, haze, infrared ray, and material line rejection. Test results are as follows." As shown, the infrared blocking rate of the colorless transparent glass is indeed poor, which is much different from the examples 2, 4, 6 and 8. Sheep and off-balance 1343932 Table 1
ΤΤΓίΤ^ϊ 名稱 實施例 1 實施例 2 實施例 3 實施例 4 實施例 5 實施例 6 實施例 7 實施例 8 比較例 1 1 一 3 基材 聚氣 乙烯 100 100 100 100 100 100 100 100 100 100 無色透 明玻瑀 破填 — — 一 可塑劑 DINP 40 40 40 40 40 40 40 40 40 40 __ 配 無機隔熱 顆粒 ΑΤΟ 2.2 2.2 0.3 2.2 6.0 6.0 15 15 — 2.2 - 安定劑 鋇鋅系 3 3 3 3 3 3 3 3 3 3 一 方 滑削 硬SI酸 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 一 改質劑 3.2 3.2 0.44 3.2 5.73 573 7.18 7.18 — 一 — 助劑 界面活 性劑 0.82 0.82 0.11 0.82 1.24 1.24 3.59 3.59 — -- — 分散劑 0.75 075 0.10 0.75 0.95 0.95 2.61 2.61 一 一 — 紫外線 吸收刑 0.8 08 0.8 0.8 0.8 0.8 08 0.8 0.8 Ο.β - 基材厚度（mm) 0.2 0.3 0.02 1.0 0.2 03 0.2 0.3 0.2 0.2 0.3 物 光透過率（％) 69 58 85 49 40 26 19 17 86 50 93 性 霧度（％> 2.2 2.5 1.2 3.1 8.7 10.3 10.4 12.7 1.4 12.0 0.6 紅外線遮蔽率（％) 43 61 14 70 73 87 92 95 8 29 22 紫外線阻隔率（％〉 99 99 98 99 99 99 99 99 98 98 27 加工過程ΑΤΟ是否析出 否 否 否 否 否 否 否 否 否 會 配方用量單位為：PHR (每百份重量樹脂） 14 1343932 【圖式簡單說明】 圖1係以習知乾式塗佈加工製得的隔熱透明膠膜的斷面放大圖。 圖2係以習知濕式塗佈加工製得的隔熱透明膠膜的斷面放大圖。 ； 圖3係以非塗佈加工製得的本發明具遮蔽紅外線及紫外線效果的隔 熱聚氣乙烯透明膠布的斷面放大圖。 圖4係本發明的隔熱聚氣乙稀透明膠布以多層疊合在一起使用的示 意圖。 • ® 5係本發明的隔熱聚氣乙烯透明膠布與另-片娜紐疊合在一 起使用的示意圖。实施ίΤ^ϊ Name Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Comparative Example 1 1 - 3 Substrate Polyethylene Ethylene 100 100 100 100 100 100 100 100 100 100 Colorless Transparent glass bottle breaking - a plasticizer DINP 40 40 40 40 40 40 40 40 40 40 __ with inorganic insulating particles ΑΤΟ 2.2 2.2 0.3 2.2 6.0 6.0 15 15 — 2.2 - stabilizer 钡 zinc system 3 3 3 3 3 3 3 3 3 3 One side slipping hard SI acid 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 One modifier 3.2 3.2 0.44 3.2 5.73 573 7.18 7.18 — I— Additive surfactant 0.82 0.82 0.11 0.82 1.24 1.24 3.59 3.59 — - Dispersant 0.75 075 0.10 0.75 0.95 0.95 2.61 2.61 One - UV absorption penalty 0.8 08 0.8 0.8 0.8 0.8 08 0.8 0.8 Ο.β - Substrate thickness (mm) 0.2 0.3 0.02 1.0 0.2 03 0.2 0.3 0.2 0.2 0.3 Transmittance (%) 69 58 85 49 40 26 19 17 86 50 93 Sexual haze (%> 2.2 2.5 1.2 3.1 8.7 10.3 10.4 12.7 1.4 12.0 0.6 Infrared shielding rate (%) 43 61 14 70 73 87 92 95 8 29 2 2 UV blocking rate (%> 99 99 98 99 99 99 99 99 98 98 27 Whether the process is precipitated or not No No No No No No No No formula dosage unit: PHR (per hundred parts by weight of resin) 14 1343932 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is an enlarged cross-sectional view showing a heat-insulating transparent film obtained by a conventional dry coating process. Fig. 2 is a cross section of a heat-insulating transparent film obtained by a conventional wet coating process. Fig. 3 is an enlarged cross-sectional view of the heat-insulating polystyrene transparent tape of the present invention having the effect of shielding infrared rays and ultraviolet rays, which is obtained by non-coating processing. Fig. 4 is a transparent and transparent polyethylene transparent film of the present invention. A schematic view of the tape being used in multiple layers. • ® 5 is a schematic diagram of the use of the insulated, gas-laid vinyl transparent tape of the present invention in combination with another sheet of Nana.
【主要元件符號說明】 10.· •…隔熱透明膠膜 11… •••塑膠基材 12.. •…金屬或金屬氧化物等無機物 20..· 21.· …·塑膠基材 22·.. 23.· …·樹脂 30…. ••隔熱聚氣乙烯透明膠布 31- …·聚氣乙烯膠布 32·.« 40.· …·塑膠基材[Explanation of main component symbols] 10.· •...Insulation transparent film 11... •••Plastic substrate 12..•...Inorganic substances such as metal or metal oxide 20..· 21.···Plastic substrate 22· .. 23.· ...·Resin 30.... ••Insulated Polyethylene Ethylene Clear Tape 31- ...·Polyethylene Vinyl Tape 32·.« 40.···Plastic Substrate