TWI325008B - - Google Patents

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TWI325008B
TWI325008B TW95127345A TW95127345A TWI325008B TW I325008 B TWI325008 B TW I325008B TW 95127345 A TW95127345 A TW 95127345A TW 95127345 A TW95127345 A TW 95127345A TW I325008 B TWI325008 B TW I325008B
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Taiwan
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film
stripping
fouling
antifouling
porous
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TW95127345A
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TW200806740A (en
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Kuo Chin Chen
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九、發明說明: 【發明所屬之技術領域】 本發明係關於一種具備微多孔特性之聚四氟乙烯薄膜,尤指一種 「防污及抗層剝組成物、具防污及抗層剥之多孔性聚四氟乙烯薄膜及其 織物、多孔性聚四氟乙烯薄膜防污及抗層剝之加工處理方法J,亦是一種 以更為簡單快速之製造方法所製成之具防污及抗層剝之多孔性聚四氟乙 稀薄膜及其義,其絲得乡紐聚四氣乙_職經塗覆或浸漬方式 層合或結合防污及抗層剝組成物,再以一適溫烘乾取得之成品,進而獲 致不破壞原有純雛之聚四氟乙稀_結構外,同時兼具透氣性、透 濕氣性、防撥水、防撥油、防污及耐水洗之效果,更可經由再加工之過 程結合於織物上,據以達缝體之製程更為簡單、快速及效果之提昇者。 【先前技術】 按’習知之聚四氟乙_將四氟乙烯⑽4)經聚合作騎形成,主 要由♦原子和氟原子組成不含氫,所以不會和氧發生反應,其特性具借 耐熱、耐低溫、耐紐、不沾祕、低磨擦係數及自潤性等多項特性, 除此之外該聚四款乙烯不易與其他物質融合,而其他物質亦不易沾枯 於上’ _為糊業者所運用之材料之一。 四氟乙婦具備了如上所叙種種優點,於是便有業者將其加工 而製成所謂的聚喊乙烯薄片或則,並為多孔之特性,再加以層合於 織物或非織物上而作為·器材或其他用途者,如美國專利第5 2 3 4 6080472'5750242號、台灣專利公告第5 3 8 164'592783號所揭之内容。 。由此可知’聚吨乙烯經加工處雜已被歧的運躲工業及民生 用品上’於是針對聚四氟乙烯經由各相關業者所欲使用或運用之領 域而產生製程上之差異性,並為專利之保護,如美國專利第6 7 〇 2 9 71、6852223、5098625、6228477、6410 084、6676993、6854603、409622 7號所揭之 内容。 藉由上述所揭之製程及製程所產製之製品不難得知最後所得之聚四 氟乙烯薄片或膜m多孔性之訴求重點,且加以運用於衣物上並得 一透氣、透濕氣及防撥水之效果。 而上述所揭之技術内容皆未考量到防污、防撥油及抗層剝之效果, 但以衣_污最難纽的雜,仍以絲油污及污垢滲人衣物之清潔最 令人頭痛,除不易清潔外還需轉殊且專用之清潔劑加以清潔,此種清 潔劑亦對人體之皮膚於長時間接觸搓揉下產生刺激,而為人體皮膚受損 之潛在不良因素。 若於長時間下,僅能針對衣物表面進行清潔,從其表面看來是已潔 白乾淨,但其實不然,尤以強調透氣、透濕氣功能之衣物,其因污垢滲 入衣物之微孔内或因長時間的層積,而產生微孔阻塞之不良情形,進而 降低原有衣物之透氣及透濕氣效果者。 不僅如此,經由長時間的水洗搓揉下,衣物表面或纖維組織通常會產 1325008 生層剝之不良情形,進而降低防撥水的效果。 再者,先前專利中另有一種防污薄膜之專利在案,如美國專利第6 4 1 9 8 0 4號及台灣專利第I 2 3 2 2 2 9號,此些專利由内容及專 利範圍可看出為一防污膜之形成方法及防污材料,並廣泛被應用於表面 處理業、建築業、汽車業(鋁圈、車殼)、光學工業、精密機械業、資訊 業(DVD、CD、VCD)及瓣或橡膠製品(輪胎)等,而此防污 薄膜確具如專利所述之防污效果,但卻不具透氣、及透濕氣之效果。 由上述習知之技術内容中不難得知,若要具備防污功能之薄膜或成 品則會喪失透氣及透濕氣之功能,相對的若要具備透氣及透濕氣之功能 則無法同時兼具防污及抗層剝之功能。 為此如何針對上述兩種不同特性之薄膜,其所產生效果上之個別優 異f生加以整合’便獲致同時兼具透氣、透濕氣、防撥水'防撥油及防污 之效果外更具抗層歡妓,並簡化餘之繁似提昇製品之穩定性並 降低不良率,乃為各相關業者之努力與發展的方向。 有鐘於上述所未臻至善之處,本㈣明人遂以從事該行業多年之經 驗’累積相關加工處理製程、g己方及製品之技術,並致力於該等配方、 製程、製程所需物料與製賴需制之設備之整合運用加时析其加 工處理製程、物料、配方與製程之設備之_性,並本著精益求精 之精神’積極研發改善,遂有本發明「防污及抗層剝組成物、具防污及 層之多孔!·生聚四敦乙稀薄膜、多孔性聚四氟乙稀薄膜防污及抗層剝 7 1325008 . 之加工處理方法」之產生。 【發明内容】 本發明「防污及抗層剝組成物、具防污及抗層剝之多孔性聚四氣乙缔 薄膜及其織物、多孔性聚四氟乙烯薄膜防污及抗層剝之加卫處理方法」,其 主要目的在於提供-種具備了疏水、疏油及耐水洗特性之防污及抗層剩組 成物’該防污及抗層剝之組成物被加以結合運用於多孔性聚四敦乙稀薄膜 及其織物後,而能同時兼具透氣、透濕氣、防撥水、防撥油、防污及抗層 I 剝暨耐水洗之特性。 本發明「防污及抗層敝祕、具防狀抗層叙乡孔性聚四氣乙稀 薄膜及其織物、纽性聚四氣乙烯細防污及抗層剝之加工處理方法」,其 -人-主要目的在於提供一種已具備多孔特性之聚四說乙稀薄膜,該特性所 提供之效糊為透氣、透濕氣及防撥水,在不破獅有概下,又得以衍 生出防污、防撥油及抗層剝暨耐水洗之效果,可運用於織物、服飾或其他 需具備上述多種效果之複合物上,其中,污暨可將_於該具防污及抗 Φ 層剥之多孔性聚四氟乙烯薄膜及其織物上之一般污垢輕易去除,僅使用清 水擦拭即可除去殘垢,而_狀垢通綠__為油垢,轉明所產製 之具防污及抗層剝之多孔性聚四氟乙烯薄膜及織物,即在提供一經滴油測 試後,可令油液凝聚成珠狀而停於具防污及抗層剝之多孔性聚四氟乙烯薄 膜之表面’進而獲贿_之絲,而額-般具吸祕之紙或布則可將 該油滴吸除,若為-般含雌之雜諸後,亦是以濕布擦拭即可輕易去 除’再者,本發明具防污及抗層剝之多孔性聚四氟乙烯薄膜及其織物,即 在提供一經耐水洗測試後,可於多次水洗之狀態下防止層剝之不良情形, 1325008 進而獲致抗層剝之效果,並維持高度之透氣、透濕氣、防撥水、防撥油及 • 防污之效果者》 . 本發明「防污及抗層剝組成物、具防污及抗層剝之多孔性聚四氟乙烯 薄膜及其織物、多孔性聚四氟乙烯薄膜防污及抗層剝之加工處理方法」,其 主要特徵在於將微多孔特性之聚四氟乙烯薄膜以塗覆或浸潰之加工方式’ 將防污及抗層剝組成物結合於多孔性聚四氟乙烯薄膜上,再施以烘乾之程 序而獲得一成品,該成品則使原有之多孔性聚四氟乙烯薄膜因特性而產生 • 之透氣'透濕氣及防撥水效果增其附加之效果,其係因防污及抗層剝組成 物之結合特性’而產生防污、防撥油及抗層剝暨耐水洗之功能,於整體結 構之特吐所產生之效果則同時具備了透氣、透濕氣、防撥水、防撥油、防 污及抗層剝之多種功能者。 综上所述,本發明訴求明朗而簡單,為預期可達,效能所具之高 等精進創作’當能凸顯本案之新穎性及進步性雙重要件;為便於責審查 委員能進—步瞭解有關本發明為達上述目的、特徵所顧的技術手段及其 暑功效,兹例舉較佳實施例並配合圖式說明如下。 【實施方式】 首先針對多孔特性之聚四敦乙婦薄膜加以分析,此膜利用高倍率電子 』微鏡觀看’可4知錢㈣㈣顯的雜觸闕組成,闕不同的溫 度及延伸倍率,而導致纖維與節點會有明顯的不同’較大倍率的延伸,非 將已有的纖維長度延伸,而是將連結於纖軸纖賴之_再度分裂成更 微之纖維與更小的節點,藉由分糾形成所謂微米級纖维之薄膜或奈米 級纖維之_,_⑽膜普遍被運驗織㈣衣物上,使織物或衣物具 1325008 備了透氣、透濕氣及防撥水的效果。 因此本發明專利之重點乃在於將上述該等特性之多孔性聚四氟乙烯薄 膜結合本發明之防污及抗層剝組成物,並經由防污及抗層剝之加工處理 後,而得一除透氣、透濕氣及防撥水效果外,更增加防撥油、防污及抗層 剝效果之具防污及抗層剝之多孔性聚四氟乙烯薄膜及其織物,並藉由製程 之簡化以期達到量產及降低不良率之目的者。IX. Description of the Invention: [Technical Field] The present invention relates to a polytetrafluoroethylene film having microporous properties, and more particularly to an antifouling and anti-stripping composition, having antifouling and anti-stripping porous The PTFE film and its woven fabric, the porous PTFE film antifouling and anti-stripping processing method J, is also a more simple and rapid manufacturing method for antifouling and anti-layer Peeling porous polytetrafluoroethylene film and its meaning, its wire is obtained from the four-gas, coated or impregnated layer or combined with anti-fouling and anti-stripping composition, and then baked at a suitable temperature The obtained finished product is obtained, and the effect is that it does not destroy the original Teflon _ structure of the original pure chick, and at the same time has the effects of gas permeability, moisture permeability, water proofing, oil proofing, antifouling and water washing resistance. It can be combined with the fabric through the process of re-machining, so that the process of reaching the seam body is simpler, faster and the effect is improved. [Prior Art] According to the conventional Teflon®, the tetrafluoroethylene (10) 4) The formation of a cooperative ride is mainly composed of ♦ atoms and fluorine atoms. Hydrogen, so it does not react with oxygen. Its properties are characterized by heat resistance, low temperature resistance, resistance to New Zealand, non-sticking, low friction coefficient and self-lubricity. In addition, the four kinds of ethylene are not easy to be combined with other substances. Convergence, and other substances are not easy to get rid of on one of the materials used by the paste industry. PTFE has the advantages described above, so the industry has processed it to make the so-called poly-ethylene A sheet or a porous material which is laminated to a woven or non-woven fabric for use as a device or other use, such as U.S. Patent No. 5 2 3 4 6080472 '5750242, Taiwan Patent Publication No. 5 3 8 164 The contents disclosed in '592783. It can be seen that 'poly ton of ethylene has been mistreated in the processing industry and livelihood supplies', so it is aimed at the areas that PTFE is used or used by various related industries. Produces differences in process and is protected by patents, such as those disclosed in U.S. Patent Nos. 6 7 〇 2 9 71, 6852223, 5098625, 6228477, 6410 084, 6667993, 6854603, 409622. Process The products produced by the process are not difficult to know the final focus of the polytetrafluoroethylene sheet or film m porosity, and are applied to the clothes to obtain a breathable, moisture-permeable and water-repellent effect. The technical contents of the disclosure have not considered the effects of anti-fouling, anti-oiling and anti-stripping. However, it is most difficult to clean the clothes with the dirt and dirt. In addition to cleaning, special cleaning agents are needed to clean the skin. This kind of cleaning agent also stimulates the skin of the human body for prolonged contact with the underarms, which is a potential adverse factor for human skin damage. It can only be cleaned on the surface of the clothes. It is white and clean from the surface, but it is not. Especially the clothing that emphasizes the function of breathable and moisture-permeable, which is infiltrated into the pores of the clothes due to dirt or stratified for a long time. , and the occurrence of microporous obstruction, thereby reducing the breathability and moisture permeability of the original clothing. Not only that, after a long time of washing and washing, the surface of the clothes or the fibrous structure usually produces 1325008 raw layer peeling, which reduces the effect of water proofing. Furthermore, a patent for an antifouling film is disclosed in the prior patents, such as U.S. Patent No. 6 4 1 8 8 4 and Taiwan Patent No. I 2 3 2 2 2 9, which are subject to content and patent scope. It can be seen as an anti-fouling film forming method and anti-fouling material, and is widely used in surface treatment industry, construction industry, automobile industry (aluminum ring, car shell), optical industry, precision machinery industry, information industry (DVD, CD, VCD) and petals or rubber products (tires), etc., and this antifouling film has the antifouling effect as described in the patent, but it has no effect of being breathable and moisture permeable. It is not difficult to know from the above-mentioned technical contents that if a film or a finished product having an antifouling function is lost in the function of venting and moisture permeable, the relative function of venting and moisture permeable cannot simultaneously prevent The function of dirt and anti-stripping. For this reason, how to integrate the above-mentioned two kinds of different characteristics of the film, the effect of the individual excellent f-integration' will result in both breathable, moisture-permeable, anti-water-repellent oil-proof and anti-fouling effects. It is the direction of the efforts and development of all relevant industry players to have the anti-layers and to simplify the stability of the products and reduce the non-performing rate. With the above-mentioned unsatisfactory best, this (4) Mingren has accumulated years of experience in the industry to accumulate the relevant processing technology, technology and products, and is committed to the materials required for such formulations, processes and processes. The integration with the equipment required by the system requires the analysis of the processing equipment, materials, formulas and processes of the equipment, and in the spirit of excellence, the company actively develops and improves the anti-fouling and anti-layer. Peeling composition, anti-fouling and porous layer! · Production of Si Dun Ethylene film, porous polytetrafluoroethylene film antifouling and anti-layer stripping 7 1325008 . SUMMARY OF THE INVENTION The present invention "anti-fouling and anti-stripping composition, anti-fouling and anti-peeling porous polytetraethylene acetylene film and its fabric, porous polytetrafluoroethylene film antifouling and anti-stripping The main purpose of the method is to provide an antifouling and anti-layering composition having hydrophobic, oleophobic and water-repellent properties. The antifouling and anti-stripping compositions are combined for use in porosity. After the four-diene film and its fabric, it can combine the characteristics of breathable, moisture-permeable, anti-water-repellent, anti-oil, anti-fouling and anti-layer I peeling and water-washing. The invention relates to an anti-fouling and anti-layer anti-layer, a anti-layer anti-layer, a polycrystalline silicon film and a fabric thereof, a processing method for processing fine anti-fouling and anti-stripping of a polytetraethylene, and - The main purpose is to provide a polysilicon film which has porous properties. The properties provided by this property are breathable, moisture permeable and water-repellent, and can be decontaminated without breaking the lion. The effect of anti-picking oil and anti-stripping and water-washing can be applied to fabrics, clothing or other composites which need to have the above various effects. Among them, the stain can be used for the anti-fouling and anti-Φ layer peeling. The general dirt on the PTFE film and its fabric is easily removed, and only the water can be wiped to remove the residual scale, while the _-like scale is green __ is the grease stain, and the anti-fouling and anti-stripping strip produced by the transfiguration The porous polytetrafluoroethylene film and fabric, after providing a drip test, can condense the oil into beads and stop on the surface of the porous PTFE film with antifouling and anti-stripping. Take a bribe _ the silk, and the amount of paper-like cloth or cloth can be used to drop the oil Absorbing, if it is a mixture of females, it can be easily removed by wiping with a damp cloth. Further, the porous polytetrafluoroethylene film and fabric thereof having antifouling and anti-stripping are isolated. After providing a water-resistant wash test, it can prevent the peeling of the layer in multiple washing conditions, 1325008, and then achieve the effect of resisting stripping, and maintain a high degree of breathability, moisture permeability, water proofing, anti-oil and • Anti-fouling effect. The anti-fouling and anti-stripping composition, the anti-fouling and anti-stripping porous polytetrafluoroethylene film and its fabric, and the porous polytetrafluoroethylene film are anti-fouling and anti-fouling. A method for processing a stripping process, the main feature of which is to combine a microporous polytetrafluoroethylene film into a porous polytetrafluoroethylene film by coating or impregnating the film. Then, a drying process is performed to obtain a finished product, which makes the original porous PTFE film have the effect of ventilating 'moisture-permeable gas and anti-water-repellent effect. It is a combination of antifouling and anti-stripping compositions. Sexuality produces anti-fouling, anti-oil and anti-stripping and water-washing functions. The effect of the special structure of the spit is also breathable, moisture permeable, anti-water, anti-oil, anti-fouling. And a variety of functions that resist layering. In summary, the present invention appeals to the present invention in a clear and simple manner, for the purpose of achieving high performance, and for the purpose of highlighting the novelty and progress of the case; The invention is directed to the technical means and the heat effect of the above-mentioned objects and features, and the preferred embodiments are described below with reference to the drawings. [Embodiment] Firstly, the polytetracyclite film of porous characteristics is analyzed, and the film is observed by a high-magnification electron micromirror, which can be used to observe the composition of the hetero-touch, the different temperature and the stretching ratio. The result is that the fiber and the node will have a distinct difference. The extension of the larger magnification will not extend the length of the existing fiber, but will split the fiber to the smaller fiber and the smaller node. _, _ (10) film formed by the division of the so-called micro-scale fiber film or nano-fiber, is generally processed on the clothing (4), so that the fabric or clothing 1325008 is made of breathable, moisture-permeable and water-repellent. Therefore, the focus of the present invention is to combine the above-mentioned porous polytetrafluoroethylene film with the antifouling and anti-stripping composition of the present invention, and to process it through antifouling and anti-stripping treatment. In addition to the breathable, moisture permeable and anti-water-repellent effects, it also increases the anti-fouling and anti-stripping effect of the anti-fouling and anti-stripping porous polytetrafluoroethylene film and its fabric, and the process The simplification is aimed at achieving mass production and reducing the rate of non-performing.

本發明「防污及抗層剝組成物、具防污及抗層剝之多孔性聚四氟乙烯 薄膜及其織物、多孔性聚四氟乙烯薄膜防污及抗層剝之加工處理方法」,其 中,該防污及抗層剝組成物係由具疏油性之P U樹脂佔2%〜2 、疏 水性化合物注劑佔2%〜2 0%及溶劑所組成,並經攪拌時間約i 〇〜3 〇m 1 η後混合喊,又該疏水性化合物闕可树婦或齡疏水劑或 其混合之製劑’該賴可為頂、甲苯、_、水或二甲基甲_或其混 合之製劑,藉⑽污及抗組錢具職及疏水之雛,並⑽等調配The invention relates to an antifouling and anti-stripping composition, a porous polytetrafluoroethylene film with antifouling and anti-peeling, a woven fabric thereof, a porous polytetrafluoroethylene film for antifouling and anti-stripping treatment, Wherein, the antifouling and anti-stripping composition is composed of oleophobic PU resin 2%~2, hydrophobic compound injection 2%~20% and solvent, and the stirring time is about i 〇~ 3 〇m 1 η after mixing and shouting, and the hydrophobic compound 阙 can be a woman or an aged hydrophobic agent or a mixed preparation thereof, which can be a top, toluene, _, water or dimethylform or a mixture thereof, (10) Sewage and anti-group money with a job and a hydrophobic chick, and (10)

比例之範圍,經-適當之_及烘乾溫度之㈣條件下,以溫度介於工2 〇 18 0 C施以3 0〜18 0 s e C之烘乾而加工於多孔性聚四氟乙稀 薄膜’使其具備了防污、雜油及抗層娜耐水洗之效果。 請參閲第-圖所示,係為本發明「防污及抗層剝組成物、具防污及抗 、多孔性聚四氟乙烯薄膜防污及抗 層剝之多孔性聚四氟乙烯薄膜及其織物 0經防污及抗層 層剝之加卫處理方法」之流程圖’其主要流程係將薄膜丄 剥處理2 0後,再藉由·3 〇而得—成品4 ◦之輸出,其中聽乾3 〇 至成品4 0輸出間’係可利用捲取5 〇之程序,將其成品4 〇捲繞成一定 U25008 尺寸大小之筒狀。 請配合參閱第-、二圖所示,係為本發明「防污及抗層剝組成物、具 * 防污及抗層剝之多孔性聚四氟乙稀薄膜及其織物、多孔性聚四氣乙稀薄膜 防污及抗層剝之加工處理方法」之流程圖及該流程所需使用之設備,該製 程所需之薄膜1 〇為具多孔性之聚四氟乙_膜H般習知所能賭得 之連續料帶’將薄膜1 〇藉由進料設備i Q,經防污及抗層剝處理2 〇 , 而該防污及抗層峨理2 Q可為塗覆2 1之加工方式進行,藉由塗覆設備 • 2 1以-預設範圍之塗佈量介於6〜2 〇 g//m2將防污及抗層剝組成 物塗佈於多孔性聚四氟乙稀薄膜i 〇之上或下表層,亦或是上及下表層, 再經祕乾設備3 0’以-預設範@之時間介於3 q〜! 8 Q s e c及溫 度介於1 2 0〜1 8 0 C施以烘乾3 0之加工,最後利用捲取設備5 〇, 進行捲取5 G並獲致具H及抗層剝之纽性聚四氣乙稀雜及其織物成 品4 0之輸出。 請配合參閱第一、三圖所示,係為本發明「防污及抗層剝組成物、具 # 防污及抗層剝之多孔性聚四氟乙烯薄膜及其織物、多孔性聚四氟乙烯薄膜 防污及抗層剝之加工處理方法」之流程圖及該流程所需使用之設備,為另 一實施本發明加工處理之方法,其係將上述具多孔性之聚四氟乙烯薄膜丄 0藉由進料設備10經防污及抗層剝處理2 0,而該防污及抗層剝處理 2 0可為浸潰2 2之加工方式進行,藉由浸潰設備2 2,以一預設範圍之 固著里介於6〜2 0 g/m2將防污及抗層剝組成物固著結合於多孔性聚 四氟乙烯薄膜10之中,再經由烘乾設備3〇,以一預設範圍之時間介於 1325008The range of the ratio is processed under the conditions of (the appropriate) and the drying temperature (4), and the temperature is between 2 〇18 0 C and 3 0~18 0 s C for drying and processing in the porous polytetrafluoroethylene. The film 'has the anti-fouling, miscellaneous oil and anti-layer washable effect. Please refer to the figure-picture, which is the anti-fouling and anti-stripping composition, the anti-fouling and anti-porous, porous polytetrafluoroethylene film anti-fouling and anti-layering porous polytetrafluoroethylene film. The flow chart of the fabric and its anti-fouling and anti-layer peeling treatment method is the main process of the film stripping treatment 20, and then by the 3 〇 - the output of the finished product 4 ,, Among them, the dry 3 〇 to the finished 4 0 output room can be wound up into a cylinder of U25008 size by using the procedure of winding 5 〇. Please refer to the first and second figures for the "anti-fouling and anti-stripping composition, porous anti-fouling and anti-stripping porous polytetrafluoroethylene film and its fabric, porous poly 4 The flow chart of the anti-fouling and anti-peeling processing method of the ethylene-thin film and the equipment required for the process, the film 1 required for the process is a porous polytetrafluoroethylene film H-like The continuous strip that can be gambling 'film 1 〇 is treated by the feeding device i Q, anti-fouling and anti-stripping treatment 2 〇, and the anti-fouling and anti-layer treatment 2 Q can be coated 2 1 The processing method is carried out, and the antifouling and anti-stripping composition is applied to the porous polytetrafluoroethylene by the coating equipment. 2 1 with a predetermined range of coating amount of 6 to 2 〇g//m2 The film i 〇 above or below the surface layer, or the upper and lower layers, and then through the secret equipment 3 0 'to - preset fan @ time is between 3 q ~! 8 Q sec and the temperature between 1 2 0~1 8 0 C to dry the processing of 30, and finally use the winding equipment 5 〇, to take up 5 G and get the H and anti-layer stripping The gas is dilute and the output of the finished fabric is 40. Please refer to the first and third figures for the "anti-fouling and anti-stripping composition, porous anti-fouling and anti-stripping porous polytetrafluoroethylene film and its fabric, porous polytetrafluoroethylene. The flow chart of the method for processing the anti-fouling and anti-peeling of the vinyl film and the equipment required for the process are another method for processing the present invention, which is the porous polytetrafluoroethylene film 0, the anti-fouling and anti-stripping treatment 20 is performed by the feeding device 10, and the anti-fouling and anti-stripping treatment 20 can be performed in the processing mode of the impregnation 2 2, by dipping the device 2 2 to The anti-fouling and anti-stripping composition is fixedly bonded to the porous polytetrafluoroethylene film 10 in the fixing range of 6 to 20 g/m2, and then passed through the drying device 3 The preset range time is between 1325008

3 0〜1 8 〇 s e c及溫度介於1 2 0〜1 8 0°C施以烘乾3 0之加工, 最後利用捲取設備5 〇’進行捲取5 〇並獲致具防污及抗層剝之多孔性聚 四氟乙稀薄膜及其織物成品4 〇之輸出,其中,該浸潰設備2 2,與塗覆 設備21之差異性在於塗覆設備2Γ為一可控制防污及抗層剝組成物 出量之設備而均勻塗覆於薄膜1 0上,而該浸潰設備2 2,藉由一羅拉2 2 1導入薄膜1 0後,經由浸潰槽2 2 2,内之下壓滾輪2 2 3,將薄 膜10壓制於浸潰槽2 2 2,之防污及抗層剝組成物液面下,再經由擠壓 滚輪2 2 4,將預設固著量範圍以外之防污及抗層剝組成物去除,令該防 污及抗層剝組成物能均勻分佈固著於薄膜1〇上。 針對上述加工處理方法及設備關聯性之說明與應用,於加工處理方法 之各程序中的加工控制條件如下所述: 薄膜.係為一可取得之多孔性聚四氟乙烯薄膜,膜厚介於〇 〇 2〜〇 0 4 mm間; 防π及抗層剝處理:針對上述取得之薄膜,經由塗覆或浸潰之加工處 理方式將防/亏及抗㈣組成物以6〜2 Q以@2之塗佈量或固著量對薄 膜進行防污及抗層剝處理之作業; 供乾:係將上述經由防污及抗層剝處理後之薄膜以3◦〜丨8 〇 s e c的時間範圍,並控制溫度介於! 2 G〜i 8烤將錄之水份 及溶劑析出’進而獲致成品之輸出; #成品:經由上狀加从理後,所得之胁污及抗層歡多孔性聚四 既乙_膜及其織物厚度介於Q. ◦ 3〜Q Q 6軸間。3 0~1 8 〇sec and the temperature between 1 2 0~1 8 0 °C is applied to dry the processing of 30, and finally the winding device 5 〇' is used for winding 5 〇 and obtained antifouling and anti-layer The output of the peeled porous polytetrafluoroethylene film and the finished fabric thereof, wherein the impregnation device 22 is different from the coating device 21 in that the coating device 2 is a controllable antifouling and anti-layer The device for peeling off the composition is evenly applied to the film 10, and the dipping device 2 2 is introduced into the film 10 by a roller 2 2 1 , and then passed through the dipping groove 2 2 2 Roller 2 2 3, the film 10 is pressed into the dipping tank 2 2 2, the antifouling and anti-stripping composition liquid surface, and then through the pressing roller 2 2 4, the anti-fouling outside the preset fixing amount range And the anti-stripping composition is removed, so that the antifouling and anti-stripping composition can be uniformly distributed and fixed on the film. For the description and application of the above-mentioned processing method and equipment correlation, the processing control conditions in each processing method of the processing method are as follows: The film is a achievable porous polytetrafluoroethylene film, and the film thickness is between 〇 〇2~〇0 4 mm; anti-π and anti-stripping treatment: For the film obtained above, the anti-deficient and anti-(4) compositions are treated with 6~2 Q by coating or impregnation. The coating amount or the amount of fixation is used for the antifouling and anti-stripping treatment of the film; for drying: the film after the antifouling and anti-stripping treatment is in a time range of 3 ◦ 丨 8 〇 sec, And control the temperature between! 2 G~i 8 roasting will record the moisture and solvent precipitation' and then get the output of the finished product; #finished product: after the superficial addition, the obtained threatening and anti-layered porous poly-four-yield film The fabric thickness is between Q. ◦ 3~QQ 6 axes.

12 1325008 , 藉由上述加工處理後之具防污及抗層剝之多孔性聚四氟乙烯薄膜及其 . 織物成品4 〇,除保有原先多孔性聚四氟乙烯薄膜之透氣、透濕氣及防撥 * 水之效果外’更增加了防污、防撥油及抗層剝㈣水洗之特性,而可被應 用於各種、織物或衣物之製品上。 請參閱第四、五圖所示,為本發明「防污及抗層剝組成物、具防污及 抗層剝之乡孔雌四氣乙稀触及其麟、彡祕聚四氣乙戦膜防污及 抗層到之力trJL處理方法」,之薄膜1 〇防污及抗層剝力^工處理前與防污及抗 • 層剝加工處理後之顯微照片,從其照片中可看出,薄膜丄〇於防污及抗層 剝加工處理前係呈現節點與纖維之多孔性聚四氟乙婦薄膜(如第四圖所 •不),祕防污及抗層剝加卫處理後之频污及抗⑽之彡錄聚四敗乙稀 薄膜及其織物成品4 0由照>}巾可看ib仍呈現塗佈或JU著有防污及抗層剝 組成物之纖維與節點’並保有原防污及抗層剝處理加工前之多孔特性,除 具原透氣、透肩、氣、防撥水外,同時兼具了防污、防撥油及抗層剝暨对水 洗之效果(如第五圖所示),實提昇了產品的附加功能。 參 凊參閱第六圖所示,為本發明「防污及抗層剝組成物、具防污及抗層 創之夕孔陡聚四氟乙稀薄膜及其織物、多孔性聚四氟乙稀薄膜防污及抗層 剝之加工處理方法」’其係將原具多孔性聚四氣乙稀薄膜1 〇經塗覆2 1或 /X凊2 2之加JL過程’以—預設範g之塗佈量或固著量介於6〜2 〇 g/ m2將防污及抗層剝組成物塗佈或固著於多孔性聚四氟乙稀薄膜丄〇之 中、上或下表層,亦或是上及下表層,令該防污及抗層剝組成物能均勻塗 佈或固著於該夕孔性聚讀乙稀細丨Q,進㈣成—具防污及抗層剝之12 1325008, the porous polytetrafluoroethylene film with antifouling and anti-stripping after processing as described above, and the finished fabric of the fabric, in addition to retaining the breathability and moisture permeability of the original porous polytetrafluoroethylene film Anti-dial* The effect of water is added to the characteristics of anti-fouling, anti-picking and anti-stripping (4) water washing, and can be applied to various products of fabrics or clothing. Please refer to the fourth and fifth figures for the purpose of the invention: "anti-fouling and anti-stripping composition, anti-fouling and anti-stripping." Anti-fouling and anti-layering force trJL treatment method", film 1 〇 anti-fouling and anti-stripping force ^ before processing and anti-fouling and anti-stripping processing micrographs, can be seen from the photo Out, the film is made of a porous polytetrafluoroethylene film with nodes and fibers before the anti-fouling and anti-stripping treatment (as shown in the fourth figure), after the anti-fouling and anti-stripping treatment The frequency pollution and resistance (10) 彡 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四'Contains the original anti-pollution and anti-stripping treatment before the porous characteristics, in addition to the original breathable, transparent shoulder, gas, anti-water, but also has anti-fouling, anti-oil and anti-stripping and washing The effect (as shown in the fifth image) enhances the additional functionality of the product. Refer to the sixth figure, which is the anti-fouling and anti-stripping composition of the present invention, the anti-fouling and anti-layering, the thin-walled polytetrafluoroethylene film and its fabric, porous polytetrafluoroethylene Film anti-fouling and anti-stripping processing method"'s the original porous poly-ethylene film 1 〇 coated 2 1 or /X凊2 2 plus JL process 'to-predetermined van g The coating amount or the amount of fixation is between 6 and 2 〇g/m2, and the antifouling and anti-stripping composition is coated or fixed in the upper, upper or lower layer of the porous polytetrafluoroethylene film. Or the upper and lower layers, so that the antifouling and anti-stripping composition can be evenly coated or fixed on the smattering of the fine-grained fine 丨Q, into the (four) into - with anti-fouling and anti-stripping

13 1325008 , 夕孔性聚四氟乙烯薄膜及其織物之成品40,於該側面圖示中可看出其關 聯性,由成品4 0之表面形成一塗佈面41並為防污及抗層剝組成物之塗 •佈或固著於中間層’中間層則為PTFE面42並為多孔性聚四氟乙稀薄 膜,可經由一次加工或二次加工方面結合於織物上,而於底層形成織物面 4 3。 凊參閱第七圖所示,為本發明經防污及抗層剝加工處理後所得之具防 污及抗層剥之多孔性聚四氟乙烯薄膜及其織物成品4 〇(Sample cl〇)與未 參祕污及抗層剝加JL處理之雜丨Q於取樣測試數據上之差異,而未經防 >可及抗層剝加X處理之薄膜1 Q於防撥關試下是不麟該項效果,本發 明經防污及抗詹剝加工處理所得之具防污及抗層剝之多孔性聚四敦乙烯薄 膜及其織物成品4 0經由透氣、透濕氣j方撥水之測試及防撥油之滴油測 •試後祕之數值,均介於-容許之範_,並能有效侧上述透氣、透濕 氣、防撥水及防撥油之效果,進而獲致整體具備防污之特性者。 請參閱第人騎示’為本發鴨防污及抗層剝加讀理後所得之具防 # 污及抗層剝之多孔性聚四氟乙稀薄膜及其織物成品4 0於耐水洗暨抗層剥 取樣之測試數據’由數據中可知悉因厚度之不同(如數據中之也⑽職 欄位)’及經由縣經水制試所得謂水洗及㈤水壓數值_5 χ、i 5 X、2 5 X之水洗後所得之耐水洗及耐水壓數值(如數據中之water resistance欄位)’仍介於5 〇 〇 〇〜]_ 5 〇 〇 〇數值間,處於一高標準之 狀態,此測試之數據標準係依A A T c c _工3 5耐水洗測試及;i s 一 L1092:1998-6.1-(a)耐水壓測試所得。 14 1325008 • 上述所測得之各項數值之測試方法’並不限制本發明所得之數值,任 何以其他方法測得之數值換算成本發明所使用之測試方法而介於所得之數 值間’均於申請專利範圍中受到保護。 藉由上述之說明而可獲致將一種已具備多孔性聚四氟乙烯薄膜,在不 破壞原有之特性及該特性所產生透氣、透濕氣及防撥水之效果下,又得以 衍生出防污、防撥油及抗層剝暨耐水洗之效果,並加以運用於織物、非織 物、服飾或其他需具備上述多種效果之複合物上。 • 藉由上述之說明而可獲致本發明具備防污、防撥油及抗層剝暨耐水洗 效果之成品4 0,防污暨可將沾附於該成品4〇上之一般污垢輕易去除, 僅使用清水擦拭即可除去殘垢,而一般污垢通常較難處理的為油垢本發 明所產製之成品4 0,即在提供-經滴油測試後,可令油液凝聚成珠狀而 停於該成品4 0之表面,進而獲致防撥油之效果,並使用一般具吸收性之 紙或布則可將該油滴吸除,若為一般含油性之殘垢沾附後,亦是以濕布擦 拭即可輕易去除,而抗層剝則在於強調該成品4 〇可經數次水洗,避免防 • Θ及抗層剝組成物於表面或包覆層產生層剝之不良情形,進而獲致一經多 次水洗後仍可維持正常透氣、透濕氣、防撥水、防撥油、防污及抗層剝效 果之成品4 0者。 综上所述’本發明「防污及抗層剝組成物、具防污及抗層制之多孔性 聚四氟膜及其織物、多孔性聚四氟乙稀薄膜防污及抗層剝之加工處 理方法」,的確能藉由上述所揭露之結構、方法及製程,達到所述之功效目 的,且許夕專利均係為解決同一問題所研發者,雖使用不同之專利技術, € 15 1325008 ' "達成之目的功能或效果’卻大同小異,亦即所謂之「殊途同歸」,因此 m 基於專利法之iL法精神,係在鼓勵創新發明,故「巾請專利範圍」所保護 的内谷般均係專指創新技術的本身,而非此一技術所達成的目的、功 能或效果’意即係保護解決問題所使用之技術手段或過程,而非實施專利 所產生之結果,否則,倒因為果,即有違專利法之精神,再者,本發明申 請前未見於最縣公開,誠6符合發明專狀_性進步性等要 件。 • 惟,上述所揭之圖式及說明,僅為本發明之實施例而已,非為限 定本發明之實施例;大凡熟悉該項技藝或技術之人士,其所依本發明之特 徵範鳴,所作之其它等效變化或修飾,皆應涵蓋在以下本案之申往專利矿 圍内。 1325008 【圖式簡單說明】 第一圖係本發明之流程實施例示意圖。 第二圖係本發明之流程所使用之設備實施例示意圖。 第三圖係本發明之流程所使用之另一設備實施例示意圖。 第四圖係未經防污及抗層剝加工處理之多孔性聚四氟乙稀薄膜之顯微 圖片結構實施例示意圖。13 1325008, the finished product of the porphyritic PTFE film and its fabric 40, the correlation can be seen in the side view, forming a coated surface 41 from the surface of the finished product 40 and forming an antifouling and anti-stripping composition The coating or cloth is fixed in the middle layer. The middle layer is a PTFE surface 42 and is a porous polytetrafluoroethylene film. It can be bonded to the fabric through one processing or secondary processing to form a fabric surface on the bottom layer. 4 3.第七 Referring to the seventh figure, the anti-fouling and anti-stripping porous polytetrafluoroethylene film obtained by the antifouling and anti-stripping processing of the present invention and the finished fabric thereof (Sample cl〇) The difference between the sampling test data and the non-destructive and anti-layer stripping plus JL treatment, and the anti-layer stripping and X-treated film 1 Q is not suitable for the anti-flood test. The effect of the invention is that the anti-fouling and anti-Jan stripping processing of the porous polytetrazide film obtained by the antifouling and anti-Jan stripping processing and the finished fabric of the fabric are tested by the gas permeable and moisture permeable gas. And the value of the anti-dumping oil test and the post-test secret are all in the range of - allowable, and can effectively prevent the above-mentioned breathable, moisture-permeable, anti-water and anti-dumping effects, thereby achieving overall protection. The characteristics of the pollution. Please refer to the first person riding the show 'this is the anti-fouling and anti-peeling of the hair of the duck. The anti-staining and anti-stripping porous polytetrafluoroethylene film and its finished fabric 40 are in the washable cum The test data of the anti-layer stripping sample 'is known from the data due to the difference in thickness (such as the data in the (10) job field)' and the water test by the county water test and (5) water pressure value _5 χ, i 5 The water wash resistance and water pressure resistance values (such as the water resistance field in the data) obtained after washing with X, 2 5 X are still between the values of 5 〇〇〇~]_ 5 〇〇〇, at a high standard. The data standard for this test is based on the AAT cc _ _ 3 355 washable test and is a L1092: 1998-6.1-(a) water pressure test. 14 1325008 • The test methods for the various values measured above do not limit the values obtained by the present invention. Any values measured by other methods are converted to the test methods used in the invention and are between the values obtained. Protected from the scope of patent application. According to the above description, it is possible to obtain a porous polytetrafluoroethylene film which can be degraded without damaging the original characteristics and the characteristics of the breathable, moisture permeable and water repellent effects. Stain, anti-oil and anti-stripping and water-washing effects, and applied to fabrics, non-woven fabrics, clothing or other composites that require these various effects. • By the above description, the finished product of the invention having antifouling, anti-oiling and anti-stripping and water-washing effects can be obtained, and the antifouling can easily remove the general dirt adhering to the finished product. The residue can be removed only by wiping with water, and the dirt which is generally difficult to be treated is generally the finished product of the present invention 40, that is, after the supply-drip test, the oil can be agglomerated into beads and stopped. On the surface of the finished product 40, the effect of preventing oil repellency is obtained, and the oil or the cloth which is generally absorbent is used to remove the oil droplets, and if it is adhered to the general oily residue, It can be easily removed by wiping with a damp cloth, while the anti-layering is to emphasize that the finished product can be washed several times, avoiding the problem of preventing peeling of the surface or coating on the surface or the coating. After repeated washing, the product can maintain normal ventilation, moisture permeability, water proofing, anti-oil, anti-fouling and anti-stripping effect. In summary, the present invention "anti-fouling and anti-stripping composition, anti-fouling and anti-layer porous PTFE film and its fabric, porous polytetrafluoroethylene film anti-fouling and anti-stripping The processing method can achieve the above-mentioned effects by the structures, methods and processes disclosed above, and the Xuzhou patents are developed to solve the same problem, although using different patented technologies, € 15 1325008 '"The purpose or effect of the achievement is similar, that is, the so-called "the same way", so m is based on the spirit of the iL law of the patent law, is to encourage innovative inventions, so the "clothing scope" protected by the valley They all refer to the innovation technology itself, rather than the purpose, function or effect achieved by the technology. It means to protect the technical means or process used to solve the problem, rather than the result of implementing the patent. Otherwise, it is because If it is contrary to the spirit of the patent law, the invention is not disclosed in the most prefecture before the application of the invention, and Cheng 6 meets the requirements of the invention _ sexual progress and other requirements. The drawings and the descriptions of the present invention are merely exemplary embodiments of the present invention, and are not intended to limit the embodiments of the present invention; those who are familiar with the art or technology, according to the features of the present invention, Other equivalent changes or modifications made shall be covered in the patent application section of the following case. 1325008 [Simplified description of the drawings] The first figure is a schematic diagram of an embodiment of the process of the present invention. The second drawing is a schematic diagram of an embodiment of the apparatus used in the flow of the present invention. The third figure is a schematic diagram of another apparatus embodiment used in the flow of the present invention. The fourth figure is a schematic view of the microscopic structure of the porous polytetrafluoroethylene film which has not been treated by antifouling and anti-stripping treatment.

第五圖係本發明經防污及抗層剝加工處理之多孔性聚四氟乙烯薄膜之 顯微圖片結構實施例示意圖。 第六圖係本發明經防污及抗層剝加工處理之多孔性聚四氟乙烯薄膜及 其織物之側面顯微圖片結構實施例示意圖。 第七圖係本發明經防污及抗層剝加卫處理之多孔性聚四氟乙稀薄膜與 未經防污及抗層剝加X處理之多孔性聚四氟乙稀薄狀透氣、透濕 氣、防撥水及防撥油測試數據對照表。Fig. 5 is a schematic view showing an embodiment of a microscopic picture structure of a porous polytetrafluoroethylene film treated by the antifouling and anti-stripping treatment of the present invention. Fig. 6 is a schematic view showing an embodiment of a microscopic picture structure of a porous polytetrafluoroethylene film and a fabric thereof treated by the antifouling and anti-stripping treatment of the present invention. The seventh figure is a porous polytetrafluoroethylene film treated by antifouling and anti-stripping treatment according to the present invention, and a porous polytetrafluoroethylene film which is not treated by antifouling and anti-stripping and X-raying is permeable and moisture permeable. Gas, anti-water and anti-dumping oil test data comparison table.

第八圖係本發明經防污及抗層剝加工處理之多孔性聚四氟乙稀薄膜與 未經防污及抗層修卫處理之多錄聚四氟乙_膜之财洗測試數 據對照表。 【主要元件符號說明】 薄膜.......10 防污及抗層剝處理· 2 0 塗覆.......2 1 浸潰.......2 2The eighth figure is a comparison of the porous polytetrafluoroethylene film treated by the antifouling and anti-peeling treatment of the present invention with the multi-recorded tetrafluoroethylene film of the non-fouling and anti-layer repair process. table. [Explanation of main component symbols] Film....10 Antifouling and anti-stripping treatment · 2 0 Coating.... 2 1 Immersion.... 2 2

17 132500817 1325008

烘乾..... ••30 成口口..... ..40 塗佈面···· ••41 P T F E 面·· ••42 織物面···· ..43 捲取..... ••50 進料设備··· ••10, 塗覆設備··· ••21, 浸潰設備··· ••22, 羅拉..... ••221, 浸潰槽* · · * ••2 2 2, 下壓滚輪· _ · ••2 2 3, 擠壓滾輪··· ••2 2 4, 供乾δ又備· · · ..30, 捲取設備··· • . 50,Drying..... ••30 into the mouth.......40 coated surface····••41 PTFE surface··••42 fabric surface····..43 coiling. .... ••50 Feeding Equipment··· ••10, Coating Equipment···••21, Immersion Equipment···••22, Rolla....••221, Immersion Slot* · · * ••2 2 2, lower roller · _ · ••2 2 3, squeezing roller ··· •• 2 2 4, for dry δ and preparation · · · ..30, take-up equipment ··· • . 50,

Claims (1)

13250081325008 申請專利範圍 1、 一種「防污及抗層聽成物」,該防污及抗層剝組成物係由具疏油性之阳樹 脂佔2%~20%、疏水性化合物注劑佔2%^2〇%及溶劑混合後經—攪拌之程序所構成系 成物,其中該疏水性化合物注劑可為矽利康或氟素疏水劑或其混合之製劑。 上 2、 依申請專利顧第1項所述之「防污及抗層聽成物」,其中,該溶劑可為 丁酮、甲苯、丙酮、水或二甲基甲醯胺或其混合之製劑。 3、 -種「具防污及抗層剝之多孔性聚㈣乙_膜所加工之織物」,其係將原 具多孔性聚讀乙稀賴經塗覆之加工過程,以―預設細之塗佈量介於6〜如咖 將防污及抗㈣組成物塗佈於多孔性聚四氟乙_膜之上或下表層,麵是上及下表 層,亦可將原具多孔性聚讀乙烯薄膜經浸潰之加工過程,以—舦範 於㈣g/m2將防污及抗組成物固著結合於多孔性聚四氣乙稀薄膜之中,令該= 及抗層剝組成物能均勻塗佈或固著於該多孔性聚四氟乙稀薄膜,進而形成―:污^ 抗層剝之多孔性聚四氟乙烯薄膜所加工之織物。 八^ 4、 依申請專職圍第3 _述之「具防污及抗職之多錄聚喊乙稀薄膜所 加工之_」’其巾,_及____性之pu_ 、 疏水性化合物注劑佔編0%及溶劑所組成,其疏水性化合物注劑可為判康 疏水劑或其混合之細,其溶劑可為丁_、甲苯 之製甲基甲醯胺或其混合 再藉由烘乾 多孔性聚四氟乙烯薄膜防污及抗層剝之加卫處理方法」,其中,該方 法係將具備多孔性聚四氟乙稀薄膜藉由進料設備經防污及抗層剝處理後,,、〜 19 1325008 設備烘乾而得-具防污及抗層剝之多孔性聚四㈣薄膜成品之輸出,該成品在不破 壞原有多孔性聚讀⑽細結構下,同時兼具透·、透崎性、防撥水、防撥油、 p方污及抗層㈣耐水洗之效果,據以達祕體之製程更為簡單、快速及效果之提昇, 並可被應用於各種衣物、織物或纖維(非織物)之製品上者。 6、依申請專娜㈣5項所述之「多孔性聚吨⑽薄膜防污及抗層剝之加工Patent application scope 1. An anti-fouling and anti-layering composition, the anti-fouling and anti-stripping composition is composed of 2% to 20% of oleophobic cation resin and 2% of hydrophobic compound injection. 2%% and the solvent are mixed and stirred to form a system, wherein the hydrophobic compound injection may be a formulation of a kelicon or a fluorohydrophobic agent or a mixture thereof. 2, "Anti-fouling and anti-layer listener" according to the application of the patent, wherein the solvent may be butanone, toluene, acetone, water or dimethylformamide or a mixture thereof . 3. - "Polyesters with anti-fouling and anti-stripping porous poly (4) B-membrane processed fabrics, which are processed by the original polyporous polyethylene-coated process, with a preset The coating amount is between 6~, and the antifouling and anti-(4) composition is coated on the porous polytetrafluoroethylene film or the lower surface layer, and the surface is upper and lower layers, and the original porous polyg After the process of immersing the vinyl film in the process of impregnation, the antifouling and anti-components are fixedly bonded to the porous polytetraethylene film by the method of (4) g/m2, so that the = and the anti-layering composition can The porous polytetrafluoroethylene film is uniformly coated or fixed to form a fabric processed by a porous polytetrafluoroethylene film which is peeled off.八^4, according to the application for full-time syllabus 3 _ described "the anti-fouling and anti-disciplinary multi-recorded smashed film processed by _" 'the towel, _ and _ physical pu_, hydrophobic compound note The agent is composed of 0% and a solvent, and the hydrophobic compound injection can be a fine agent of the hydrophobic agent or a mixture thereof, and the solvent thereof can be methyl methacrylate or the mixture thereof prepared by baking the mixture of toluene and toluene. Dry porous PTFE film anti-fouling and anti-stripping treatment method, wherein the method is to have a porous polytetrafluoroethylene film by means of anti-fouling and anti-stripping treatment of the feeding equipment ,,,~ 19 1325008 Equipment drying - the output of the porous polytetra (tetra) film finished with anti-fouling and anti-stripping, the finished product does not destroy the original porous poly-reading (10) fine structure, and at the same time ······························································ , fabric or fiber (non-woven) products. 6. According to the application for the treatment of “Porous Polyton (10) Film Antifouling and Anti-stripping as described in 5 (5) 處理方法」,其中,於烘乾至成品輸出間,係可彻捲取之程序,將其成品捲繞成一 適當尺寸大小之筒狀者。 7、依申請專利範圍第5項所述之「多孔性聚四氟乙烯薄臈防污及抗層剝之加工 處理方法」’其巾,祕污及抗處理可為塗覆之加卫方式進行,藉由塗覆設備以 -預設範圍之塗佈量介於6~2Gg/m2將防污及抗·域物塗佈於纽性細氟乙稀 薄膜之上或下表層,亦或是上及下表層,再經由烘乾設備以—預設範圍之時間介於 30〜180sec及溫度介於130〜18(TC施以烘乾之加工。 8、依申睛專利範圍第5項所述之「多孔性聚四氟乙烯薄膜防污及抗層剝之加工 鲁處理方法」,其中,該防污及抗層剝處理可為浸潰之加工方式進行,藉由浸潰設備以 一預设範圍之固著量介於6~20g/m2將防污及抗層剝組成物固著結合於多孔性聚四氟 乙烯薄膜之中’再經由烘乾設備以一預設範圍之時間介於3〇〜18〇sec及溫度介於 130〜180°C施以烘乾之加工。 9、依申請專利範圍第7項所述之「多孔性聚四氟乙烯薄膜防污及抗層剝之加工 處理方法」’其中,該塗覆設備為一可控制防污及抗層剝組成物出量之設備而均勻塗 覆於薄膜上。 20 1325008 10、依申請專利範圍第8項所述之「多孔性聚四氟乙烯薄膜防污及抗層剝之加工 處理方法」,其中,該浸潰設備包括有一羅拉、浸潰槽、下壓滾輪及擠壓滾輪所構成, 藉由一羅拉導入薄膜後,經由浸潰槽内之下壓滾輪將薄膜壓制於浸潰槽之防污及抗層 剝組成物液面下,再經由擠魏輪賴設gj著量範_外之防污及抗賴組成物去 除’令該防污及抗層剝組成物能均勻分佈固著於薄膜上。 U、依申請專利範圍第5項所述之「多孔性聚四1乙烯薄膜防污及抗層剝之加工 I處理方法」,其中,該 薄膜:係為一可取得之多孔性聚四氟乙烯薄膜,膜厚介於0.02〜0.04mm間; '防污及抗層爾理:針對上述取得之賴,經由塗覆或浸潰之加王處理方式將防污及 -抗層敝成物以6〜2Gg/m2之塗佈量或固著量對薄膜進行防污及抗層鑛理之作業; -烘乾:係'將上述經由防污及抗層剝處理後之薄膜以30〜180sec的時間範圍,並控制溫 度介於120〜180。(:間烘烤,以將多餘之水份及溶劑析出,進而獲致成品之輸出; φ成品:經由上述之加工歧後,所得之具防污及抗層剝之多孔性聚四氣乙稀薄膜厚度 介於 0.03~0.06mm 間。 12、依中物咖第7、8、9、1()或u項所述之「多孔性細氣乙稀薄膜防 π及抗層剝之加工處理方法」,其中,該防污及抗層剝組成物係由具疏油性之pu樹 如佔2/〇~20%、疏水性化合物注劑佔2%^〇%及溶劑經麟後混合喊,其疏水性化 合物注劑可為侧康或氟素疏水劑或其混合之製劑,其溶劑可為丁_、甲苯、賴、 21 1325008 水或二甲基曱醯胺或其混合之製劑。The treatment method, wherein, in the process of drying to the output of the finished product, the product can be wound up into a cylinder of an appropriate size. 7. According to the fifth paragraph of the patent application scope, the "porous PTFE thin anti-fouling and anti-stripping processing method", the towel, the secret treatment and the anti-treatment can be carried out for the coating method. Applying antifouling and anti-domain materials to the top or bottom layer of the neodymium fluoride film by coating equipment with a coating range of -2 Gg/m2 in a predetermined range, or on the surface And the lower layer, and then through the drying device - the predetermined range of time is between 30~180sec and the temperature is between 130~18 (TC is applied to the drying process. 8. According to the fifth aspect of the patent scope "Processing method for processing anti-fouling and anti-peeling of porous polytetrafluoroethylene film", wherein the anti-fouling and anti-stripping treatment can be carried out for the processing method of impregnation, by dipping the device to a predetermined range The amount of fixation is between 6 and 20 g/m2, and the antifouling and anti-stripping composition is fixedly bonded to the porous polytetrafluoroethylene film, and then passed through the drying device for a predetermined range of time between 3〇. ~18〇sec and temperature between 130~180 °C for drying. 9. According to the scope of the patent application, the porous polytetrafluoroethylene Film processing method for antifouling and anti-stripping treatment"", wherein the coating device is uniformly applied to the film by a device capable of controlling the amount of antifouling and anti-stripping composition. 20 1325008 10. Patent application The method for processing an anti-fouling and anti-layering treatment of a porous polytetrafluoroethylene film according to the eighth aspect, wherein the impregnation device comprises a roller, a dipping groove, a pressing roller and a pressing roller. After introducing the film by a roller, the film is pressed into the anti-fouling and anti-stripping composition liquid layer of the dipping tank through the lower pressing roller in the dipping groove, and then the gj is measured by the squeezed Wei wheel. The external antifouling and anti-glare composition removal enables the antifouling and anti-stripping composition to be evenly distributed and fixed on the film. U. The porous polytetraethylene film according to item 5 of the patent application scope Anti-fouling and anti-stripping processing I treatment method, wherein the film is a permeable porous polytetrafluoroethylene film with a film thickness of between 0.02 and 0.04 mm; 'anti-fouling and anti-layering: For the above-mentioned gains, it is treated by coating or dipping The antifouling and anti-layering composition is used for antifouling and anti-layering operation of the film with a coating amount or fixing amount of 6~2Gg/m2; - drying: the above is carried out through antifouling and The film after the stripping treatment is in a time range of 30 to 180 sec, and the temperature is controlled to be between 120 and 180. (: Baking is performed to precipitate excess water and solvent, thereby obtaining the output of the finished product; After the above-mentioned processing, the obtained thickness of the porous polytetraethylene film having antifouling and anti-stripping is between 0.03 and 0.06 mm. 12. According to the Chinese food, the seventh, eighth, ninth, and one (1) or The method for processing anti-π and anti-layer stripping of the porous fine air thin film described in item u, wherein the antifouling and anti-stripping composition is composed of an oleophobic pu tree such as 2/〇~ 20%, the hydrophobic compound injection accounts for 2%^〇% and the solvent is mixed with the lining, and the hydrophobic compound injection can be a side or a fluorinated hydrophobic agent or a mixed preparation thereof, and the solvent thereof can be D-, Toluene, Lai, 21 1325008 water or dimethyl decylamine or a mixture thereof.
TW95127345A 2006-07-26 2006-07-26 Composition of anti-fouling and anti-delamination porous polytetrafluoroethylene film with antifouling and anti-delamination capabilities and the method of producing thereof TW200806740A (en)

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