TWI324046B - Malodor and pesticide counteractant agent and fabrication method thereof - Google Patents

Description

1324046 Revision IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a composition for removing pesticides and a process for the preparation thereof, and more particularly to a composition for effectively decomposing a pesticide and a method for preparing the same. [Prior Art] In order to avoid pests, farmers usually spray pesticides on fruits and vegetables and tea trees. However, most pesticides are toxic to humans, such as organic phosphorus agents commonly used in leafy vegetables and fruit trees, such as "malathion". It is used on strawberries with a base nitrogen and heterocyclic compound "iprodine" or "pyridaben" on tea trees. These pesticides are all organic compounds. They have poor solubility in water and are not easily washed with water. Therefore, they remain in fruits and vegetables, leafy vegetables and tea leaves. If you eat too much residual pesticide, it will destroy the brain, cause cancer or cause vomiting and nausea, which will seriously harm human health. In particular, the accumulation of pesticides in the human body will cause genetic mutations, resulting in cancer. An example of a “cancer village” found on the mainland is the long-term consumption of crops containing residual pesticides by local residents. If farmers do not harvest crops according to the safe harvest period, the pesticide residue will be more serious: it will be very harmful to human health. For example, if the tea contains residual pesticides, the consumer will directly soak the tea in hot water, and the precipitated pesticide will directly enter the tea water, posing a threat to the health of the drinker. Although fruits and vegetables or leafy vegetables can be washed with water to remove residual pesticides, the effect is extremely limited; the other is washed with saline, and the effect is unknown because there is no objective experimental evidence; if the detergent is used, the surfactant and other components contained therein Chemical constituents may remain in fruits and vegetables or leafy vegetables, which may cause odor and cause secondary toxicity. The common odors are usually divided into two categories: odor and smoke. The general source of odor is amine odor (Zhao odor and sweat odor), trimethylamine odor (salt), hydrogen sulfide odor (corrupted egg), methyl mercaptan (cooking rancid), fragrant smell, etc. The odor molecules are nitrogen-containing and sulfur-containing compounds. In order to deodorize, the deodorant on the market can be roughly classified into "fragrance to cover odor", "adsorption odor" and "acidity to neutralize and deodorize" according to the principle of action. Among them, the fragrance-covered deodorant can cover the odor, but it cannot decompose the odor molecules, so it often remains 5 1324046 to correct the odor; the adsorption type deodorization _ adsorption capacity is limited, time-long or odor is too strong, adsorption capacity Bribes are low or lost; the neutralization of the deodorant in acid testing is limited to substances that can be combined with acidity, and their duties are mixed. In addition to fine, such as "citric acid and maleic acid" can not remove the odor of thiol. As for various sources of smoke, including cigarette smoke, barbecue soot and kitchen fumes, the main chemical component of cigarette smoke is "nic〇tine", and the main chemical damage of barbecue smoke contains acrylamide. (acryiamjde), taste saliva (imjdaz〇|e), quinoline (quinoline), etc.; the main chemical components of kitchen smoke contain 茚 (丨ndene), naphthalene (naphthalene), phenanthrene (Phenanthrene) and other three ( Reference Borgerding, M., Klus, H. Experimental and Toxicologic

Pathology 2005, 57, 43 73; Brage, C.; Yu, Q.; Chen, G.; Sjostrom, K. Biomass and Bioenergy 2000, 18, 87 91; Preuss, R., Angerer, H., Drexler, H Int. Arch. Occup. Environ. Health 2003, 76, 5561576). These smoke-flavoring molecules are harmful to the human body. However, there is no suitable smoke-removing agent on the market, which can effectively decompose the chemical main components of the smoke source to achieve the purpose of removing smoke. Regardless of whether it is a pesticide or an odor, the prior art cannot effectively decompose and remove pesticides or odors, so that the human body is very harmful. In view of this, the present invention proposes a composition for removing pesticides and odors and a method for preparing the same, which makes pesticides and odors When the smoked molecules come into contact with the composition, they are decomposed, thereby achieving the effects of removing pesticides, odors and smoke. SUMMARY OF THE INVENTION The main object of the present invention is to provide a herbicide-containing composition and a method for preparing the same, thereby preparing a sacrificial agent, an additive or a spray agent of various concentrations and uses, and the composition has the function of destroying and decomposing pesticides. In order to effectively achieve the purpose of eliminating pesticides. Another object of the present invention is to provide a pesticide-free composition and a preparation method thereof, which can be used for washing fruits and vegetables to remove pesticide residues on the surface of fruits and vegetables, especially for vegetables and not The fruit that needs to be peeled off, the invention can be 1324046 to amend the pesticide on the vegetables such as leeks, korean vegetables, green peppers, etc. :::= carambola, lotus, grape, apple, plum, peach, to use residual poison, especially material Because of its pits, it is difficult to wash with water, and it is very fragile and cannot be washed. The i-purpose of the institute is to provide a composition for removing pesticides and a method for preparing the same, and the spray prepared by the invention can effectively decompose the residual pesticides on the crops, and can also eliminate the body, such as odor, sweat odor, foot odor, bad breath. , head odor, physiological smell, etc., or pets such as tracing, dog n birds, etc., or direct spray; good for everyday appliances, air conditioning ^ nets, clothing 'masks, masks, gloves, protective clothing, condoms, medical equipment, etc. Items, or applications in home indoors and outdoors, inside the car, fish (four), toilets, meals, restaurants, kitchens, rotisserie, Internet cafes and smoking areas, such as odor or smoke pollution. The pesticide-removing composition of the present invention is mainly composed of a catalyzed ionic compound having a weight ratio of 1 and a weight ratio of 4 〇 4 to 4 - a buffering reagent, a weight ratio of 2 to 200, and a reducing coenzyme. It is produced by mixing with a mixture of an oxidizing agent or an ionic compound or a sulfide. The catalytic compound ionic compound has the general formula M+ax-b, wherein the M system is selected from the group consisting of nickel (N|), cobalt (c〇), iron (Fe), copper (CU), and charm (Μη). Chromium (Cr), Titanium (Ti), Ming (AI), Record (Sb), Tin (Sn), Wr (Pb), Platinum (Pt), Pd (Pd), Hungry (〇s), Ruthenium (Ru) , cadmium (Cd), rhodium (Rh), strontium (lr) or ammonium (NHU), X is selected from the group consisting of sulphur, gas, desert, sulphate, nitrate, sulphate, sulphite, acetate, Oxalate, succinate, phosphate, pyrophosphate, percarbonate, gluconate, ascorbate, ethylenediaminetetraacetate, butenedioate or lactate, and a = 1 to 6 and b=1~6. The general formula of the buffer reagent is RYZ, wherein R is selected from the group consisting of a chain (Li), sodium (Na), potassium (K), magnesium (Mg), calcium (Ca) or zinc (Zn), and the lanthanide is selected from chlorine. a compound, a nitrate, a sulfate, a hydrogencarbonate, a phosphate, a dihydrogen phosphate, a hydrogen phosphate or an oxalate, and z = 1 to 2. The mixture of a reducing coenzyme and an oxidizing agent or an ionic compound or a sulfide, wherein the reducing coenzyme is a reduced riboflavin single nucleotide (FMNH2), a reduced riboflavin adenosine dinucleotide ( FADH2), reduced nicotine serotonin dinucleotide dinucleotide (NADH) or reduced nicotine guanamine gland 7 1324046 to correct the poor dinuclear salt (nadph); oxidizing reagent can be hydrogen peroxide or stupid. 1 aging compound; ionic compound has the general formula NX, N is selected from the group consisting of Zhong (4) and Nacheng (K), and X is selected from the group consisting of fluoride, vapor, bromide, iodide, sulfite, and acid salt. , acaproate, pyroate, perchlorate, gluconate, ascorbate, ethylenediaminetetraacetate, butyl L or lactate; the chemical formula of the sulfide is RSH, R = C1 ~ C6 alkyl An aryl or aryl group, and the sulfide system may be a hemi-, an acid, a reduced glutamic acid, a dithiothreitol or a homocysteine. The purpose, technical contents, features, and effects achieved by the present invention will become more apparent from the detailed description of the embodiments and the accompanying drawings. [Embodiment] The present invention discloses a pesticide-removing composition which can be used as a detergent or an additive or a spray for decomposing pesticides, odors and smoke taste molecules, and the detergent can be used for washing fruits and vegetables to remove Pesticides remaining on the surface of fruits and vegetables; sprays can be applied to remove pesticides remaining on unrecovered crops before spraying, or applied to common supplies, utensils, air conditioning filters, clothing, masks, masks, Gloves, protective clothing, condoms, medical equipment, or body parts such as hands, feet, head, membrane fossa, reproductive organs and oral cavity, or pets, such as | seedlings, dogs, rabbits, birds, etc., or It is used in indoor and outdoor homes, inside the car, fish tanks, galleries, restaurants, restaurants, kitchens, rotisserie, internet cafes and smoking areas, and is contaminated by odor and smoke. The composition of the present invention in addition to agricultural music and odor removal can be prepared into any type by different ratios and different concentrations of the three main components. The pesticide-removing composition of the present invention mainly comprises an ionic compound having a catalytic function (A), a buffering agent (B), and (C) a mixture of a reducing coenzyme and an oxidizing agent or an ionic compound or a sulfide. , the weight ratio of its composition is (A) · · (B): (C) = 1 : 40~4,000 : 2~200, the preferred ratio is (A) : (B) : (〇== 1 : 500~ 2,000 : 1〇~1〇〇. Each component is described in detail as follows: (A) Catalytic ionic compound with the formula M+ax-b, where M is nickel (Ni), cobalt (Co ), magnesium (Mg), iron (Fe), copper (Cu), manganese (Μη), chromium (Cr), calcium 8 1324046 Revision (Ca>, Chin (Ti), |g(AI), 锑 (Sb>; tin (Sn), wrong (Pb), zinc (Zn), #(Pt), palladium (Pd), hungry (Os), ruthenium (Ru), cadmium (Cd), ruthenium (Rh), ruthenium (丨) r) or ammonium (NH4), X may be fluoride, chloride, bromide, moth, nitrate, sulfate, sulfite, acetate, oxalate, carboxylate, succinate, phosphate , pyrophosphate, percarbonate, gluconate, ascorbate, ethylenediaminetetraacetate, butenedioate or lactate And a = 1 to 6 and b = 1 to 6 » (B) The component is a buffer reagent 'its general formula is ryz, wherein r is lithium (u), sodium (Na), potassium (K), magnesium (Mg ), about (Ca) or zinc (Zn), Y is selected from the group consisting of chlorides, nitrates, sulfates, carboxylates, hydrogencarbonates, phosphates, dihydrogen phosphates, hydrogen phosphates or oxalates, and z=1~2 » (C) a mixture of a reducing coenzyme and an oxidizing reagent or an ionic compound or sulfide, wherein the coenzyme is a reduced riboflavin mononucleotide (FMNH2), a reduced riboflavin adenosine dinuclear Glycosylate (FADH2), reduced nicotinic adenine adenosine dinucleotide (NADH), reduced nicotinamide adenosine dinucleotide (NADPH); the oxidizing reagent is hydrogen peroxide or benzene Diketones such as azu|eneqUjnone and its derivatives; the ionic compound of the other component (C) has the general formula NX, where N is bell (Li), sodium (Na) or potassium (K) X is fluoride, vapor, bromide, iodide, sulfite, acetate, succinate, pyrophosphate, peroxyacid salt, gluconate, ascorbate, ethylenediaminetetraacetate, Butenedioate or lactate The chemical formula of the sulfide in component (c) is RSH, wherein R = C1 ~ 〇6 alkyl, aryl or aralkyl, for example, the sulfide may be cysteine, reduced lysine, dithio Threitol or homocysteine. The above three components are mixed in proportion to obtain the "pesticide and odor-removing composition" of the present invention, which can decompose pesticides, odors and smoke molecules, and the composition When the spray is made into a spray, it is evenly sprayed onto the surface of the target or the environmental space. The specially made composition can immediately react with oxygen in the air, thereby decomposing the main chemical components contained in the pesticide, odor and smoke to achieve removal. The function of pesticides, odors and smoke. When the composition is formulated into a detergent or an additive, the pesticide contained in the solution or the modified odor molecule of 9 1324046 can be decomposed. The principle of destroying the pesticide and the odor is the same as described above. The composition ratio, concentration and amount of the composition of the present invention have a special relationship with the effective period thereof, and the composition sprayed on the surface of the crop can be used for an effective period of up to 3-7 days; sprayed in an environmental space for up to 12-72 hours (depending on the environment) Spray) for daily necessities, utensils, clothing, masks, masks, gloves, protective clothing, condoms, medical equipment or pets up to 6-12 hours; for human body deodorant to eliminate the stench from the human body, Sweat, foot odor, hair odor, physiological odor, etc., which can last for 4-8 hours. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The detailed description of the embodiments of the present invention is intended to be illustrative only and is not intended to be a limitation of the remainder of the disclosure. Without further elaboration, the skilled person in the art can apply the invention to the maximum limit in accordance with the description herein. The preparation method of the composition of the present invention is described in detail as follows: Step 1, compounding the ingredients (A>: adding the vaporized nickel of 〇·ι〇克 to the reverse osmosis (RO) water of 5 〇 liters' disturbing at room temperature 15 Minutes until the aqueous solution is transparent and there is no precipitation. Step 2, formulate the ingredients (Β): add 15 grams of sodium hydrogen phosphate and 15 grams of bisulphate dihydrogen to the 190 liters of R. 〇. water, cake to After the solute is completely dissolved, add 120 g of gasification sodium, 4 g of potassium bicarbonate, 5 g of sulfuric acid and 5.0 g of magnesia. This must be fast at room temperature for 6 minutes until R 〇 ice There is no suspended matter in the solution. Step 3 'Configure the ingredients (〇: add 1 〇 3 of 过% of nitrogen peroxide to 5 〇 liters of RO water' plus 5.G mg of stupid bribes at room temperature Stir for 30 minutes until the aqueous solution is homogeneous. At this time, add the coenzyme NADpH 2 gram, the amount depends on the concentration of the last (4) 岐, about 2 () minutes, until the mist of the aqueous solution disappears into a transparent and clear shape. Step 4 'Add ingredient (A) to ingredient (6) and spoil for 15 minutes at room temperature The mixture into the wound (B) was added into the wound (A) and (c) scrambling the fully stirred to obtain 1,324,046 2〇 minutes Revised

When used in detergents or additives, the concentration used is higher than the concentration of the spray, preferably at a concentration of about. After the description of the technical contents of the present invention, in order to demonstrate the ability of the present invention to form a "destruction of pesticide and odor-removing composition" which can effectively decompose pesticide odor and smoke, etc., the three parts are Experiments were carried out and described in detail below. [Experimental Example 1] This experimental example is used to demonstrate that the "components of pesticides for removing odors" obtained by the above examples have the ability to decompose pesticides, and the test pesticides are controlled by 17 kinds of pesticides. The effects of "tap water" and "10% salt water" were compared. The experimental example 1 includes the use of organophosphorus pesticides (such as "Da Lisong", "Tofusong, "Ou Xiongsong", "Jia Phossai", "Yi Songsong", "Mei Wensong"), organic nitrogen and miscellaneous Pesticides (such as "Free J, "Destroy", "Destroyed J"), Carbamate Pesticides (eg, Nanet), "Butyl", "Beffen") Urea pesticides (such as "Bin clone \ triazole pesticides (such as "Fickley"), dithiocarbamate pesticides (such as Duobao), "Petan" and "rotation", etc. The chemical structure is summarized into the following seven categories: organophosphorus pesticides (6 in total): *

-〇 S - Da Lisong Tofusson Ou Songsong

Jia Phosai Sai Yisong Mei Wensong 11 1324046 Amendment p , organic nitrogen and heterocyclic pesticides (3 in total):

N N-N N ) 派 派 灭 C. Amino phthalate pesticides (3 in total) 0 Ν"

Butyl extinction

D. Urea pesticides (1 species) C1

ΝΌΝΌ 宾克隆 Ε. Triazole pesticide (1 species)

C1 F. Dithiocarbamate pesticides (2 in total): 11

ΗΝ Ν Ο Η Η Ύ γ0, S ο 曱 基多保净 G. Other pesticides (1 species): 〇 rot

HjN human S 八Y^S and NHj human Pedan 12 1324046 Amendment The composition of the present invention was prepared by the following examples of the above-mentioned pesticides 10 ml (concentration: 10 ppm) and 10 ml (concentration: 0.0050%), respectively. After 5.0 minutes of action, the degree of decomposition of the pesticide was determined by high-resolution liquid chromatography (HPLC), and compared with the effects of other similar pesticide removal methods of "tap water" and "10% saline". The experimental results show that the present invention has an excellent decomposition effect on pesticides, and the decomposition rate is 2,300 to 14,000 times that of tap water, and is 1,9 〇〇 to 11,000 times that of 彳〇% saline, which is far superior to other similar pesticides. method. From the results of the first chart and Table 1, it can be seen that among the seventeen pesticides, "Tofusong", "Ouson" and "Fickley" are best decomposed by the present invention, so that it can be clearly seen The present invention is indeed effective in decomposing pesticides. Table 1. The "composition" of the present invention decomposes the pesticides such as "Tofusong", "Ouson", and "Fickley". The pesticide is decomposed in a ratio of 5.0 minutes after the pesticide name is compared. The composition of the present invention is compared with the composition of the present invention. 10%) Composition of the present invention / tap water Composition of the present invention / Tofusone of salt water 93.4% 0.007% 0.008% 13,343 11,675 Oxa 83.7% 0.009% 0.010% 9,300 8,370 Fickley 73.1% 0.007% 0.007% 10,443 10,443 [Experimental example 2] This Experimental Example 2 was used to demonstrate that the composition of the present invention produced in the above examples had the ability to destroy odor molecules and to compare the decomposition rates. This experimental example includes the use of "Tofosson", "Da-Song", "Fickley" and "Butylamine-modified, odorous nitrogen-containing or sulfur-containing compounds as test targets.

TOEFLSON / CI

Da Lisong

Fickley

The composition of the present invention obtained by the examples of the butyl chlorhexidine 0 50 such that the nitrogen-containing or sulfur-containing odor molecules are 9·50 ml (concentration: 10 PPm) and _ml is 0.025%, respectively. After being subjected to =1.0, 3·〇 and 5_〇 minutes, the degree of destruction was analyzed by gas chromatography (GC), and the results are shown in the second figure. 8. From the experimental results in the first figure, it can be seen that the composition of the present invention can effectively decompose "TOEFL", "Daison", "Philippine" when the reaction time of the composition of the present invention is not 1.0 3.0 and 5. Nitrogen or sulfur-containing odors such as Klee and butyl chlorhexidine. The present invention has a destruction rate of 91% for "Tofosson" in 5.0 minutes, 87% for "Daison", 85% for "Fickley", and 76% for "butyl". Therefore, this correction can effectively decompose astringent molecules. [Experimental Example 3] This Experimental Example 3 was used to demonstrate that the composition of the present invention prepared in the above examples has the ability to destroy the smoke-smelling molecules and to decompose the main chemical components in different sources of smoke. Comparison of decomposition rates. The experimental example 3 includes the use of a fragrant smoked barbecue charcoal and kitchen fumes, and the selection of nicotine, Windene, and naphthatene from the towels to perform a chemical test 1324046. This Experimental Example 3 also included the use of the present invention at different concentrations to test the rate at which it destroyed the main ingredient "nicotine" in cigarettes. The main chemical components of various types of non-flavored sources are as follows: A. The main chemical components of cigarette smoke:

Nicotine B. The main chemical constituents of barbecue smoke (including 3 types): Π a imidazole

Phenanthrene 〇 h2c=:c-c-nh2 Η acrylamide C·The main chemical components of kitchen smoke (including 3 types):

Indene (naphthalene) naphthalene (naphthalene) The chemical constituents of these different flavours are 9.9 ml (concentration of 1 〇〇ppm) and 0.10 ml of the composition of the present invention respectively at a concentration of 0 025 〇 / 〇 and 〇. 〇〇 5 After 3.0/0, the effect is determined by using a gas chromatograph (GC) to determine the degree to which the chemical constituents of the smoke are decomposed. The experimental results are shown in the third and fourth figures. As is apparent from the results of the second figure, the present invention decomposes the main chemical components of the flavors of the savory, barbecue and kitchen, including nicotine, anthraquinone and naphthalene. When the reaction time is 3 〇 minutes and the composition concentration is 0.025%, the present invention can decompose the main chemical components in the above-mentioned smoke odor, and the destruction rate can reach more than 90%, especially for the main component of the cigarette "nicotine" The damage rate can be as high as 99% or more. And the reaction time and the degree of damage of the fourth graph show that the reaction time is within 2.0 minutes, and the present invention can achieve an effective score of 15 corrections. Therefore, the present invention is tan "nicotine", which decomposes the degree of "nicotine" >99 % # can effectively decompose smoke molecules. In summary, when pesticides, odors, and smoke-flavoring molecules are tested with the present invention, the molecules are destroyed by the biochemicals contained in the hybrids. And the effect of deodorant, _ and other odors. The above-mentioned embodiments are merely illustrative of the technical idea and features of the present invention, and those skilled in the art can understand the contents of the present invention and implement the 'when the patent of the present invention cannot be limited thereto. The scope, that is, the homogenization or modification of the spirit according to the disclosure of the present invention, should still be covered in the present (4) [Simple Outline] The first figure is the composition of the present invention and the tofosson, chlorpyrifos and phenanthrene The decomposition rate curve of pesticides such as Klee. The second graph is a bar graph comparing the extent to which the composition of the present invention destroys nitrogen-containing or sulfur-containing odor molecules such as butyl chlorpheniramine, tofusone, and desalination at different times. The third figure is a histogram of the decomposition degree of nicotine, nodules and naphthalene of the main components of the composition of the present invention at different dilution concentrations and smoke taste. The fourth figure is a graph of the decomposition rate of nicotine at different concentrations of the composition of the present invention. 0 [Main component symbol description]

Claims (1)

1324046 Amendment to this X. Patent application scope: 1. A composition other than pesticides, including: (A) - a compound having a catalytic ionic ion, which has the formula M+axb, wherein the ruthenium nickel (Νι), Ming (Co ), iron (Fe), copper (Cu), 猛 (Μη), chromium (〇), titanium (Ti), Shao (Α|), recorded (Sb), tin (Sn), wrong (Pb), turned ( Pt), (Pd), iron (〇s), nail _ recorded, silver (8) or recorded _4), X is selected from fluoride, chloride, desertification, salt, sulfate, sulfurous acid Salt, acetate, oxalate, _acid salt, Wei salt, pyrophosphate, percarbonate, gluconate, ascorbate, ethylenediaminetetraacetate, succinate or lactate' and a =1~6 and b=1~6; (B) - a buffering agent having the formula RYz, wherein R is selected from the group consisting of lithium (u), sodium (Na), potassium (), magnesium (Mg), and calcium ( Ca) or zinc (Zn), Y is selected from the group consisting of chloride, nitrate, sulfate, carbonic acid, hydrogen salt, phosphate, dihydrogen phosphate, hydrogen phosphate or oxalate, and Z = 1 to 2; (C) a reducing coenzyme with a mixture of oxidizing agents, or an ionic compound, or a sulfide The coenzyme is selected from the group consisting of reduced riboflavin mononuclear acid (FMNh2), reduced riboflavin adenosine diphosphate (FADH2), reduced nicotine adenine dinucleotide (nadh) or reduced nicotinamide Adenosine dinucleotide sulphate (NADPH); the oxidizing agent is selected from hydrogen peroxide or benzodiazepine compounds; and the ionic compound has the formula Νχ, wherein N is selected from lithium (Li) , sodium (Na) or potassium (Κ), X is selected from the group consisting of fluoride, bromide, iodide, sulfite, acetate, succinate, pyrophosphate, perchlorate, gluconate, ascorbate Ethylenediaminetetraacetate, butenedioate or lactate; wherein the weight ratio of the above composition is (A): (B): (C) = 1 : 40 to 4,000: 2 to 200. 2. If the composition of the pesticide is described in the first paragraph of the patent application, the preferred weight is (A): (B): (C) = 1: 500~2,000: 10~1〇〇. 3. A composition for removing pesticides as described in claim 1, wherein the chemical formula of the sulfide is RSH, wherein RsCi-Ce is an alkyl group, an aryl group or an aralkyl group. 4' The composition of the pesticide according to claim 1, wherein the sulfide is selected from the group consisting of hemi-amic acid, reduced lysine, dithiothreitol or homocysteine. The pesticide-removing composition described in item 1 of the patent application can be made into a washing 17 1324046 modified Benlong additive or spray. 5 The composition of the pesticide according to claim 5, wherein the water and the vegetable; and the spray can be sprayed on the crop before harvesting, or applied inside and outside, inside the vehicle, in the fish tank, in the temple. , restaurant,; = ^ Internet cafes and bribes, etc., or _ in daily necessities, appliances, clothing, σ ^ face ^ meat hand t protective clothing, condoms, air conditioning filters, medical equipment, or body parts or pets I 7 The method for preparing a pesticide-removing composition comprises the following steps: an ionic compound containing a Wei, a buffered test bottle, a mixture of a chemical compound, or an ionic compound, or a sulfide, etc. The catalyzed Wei Zhixuan compound is M+aX_b, which is +, ^(CO) ^ «(Fe) - ^(CU). β(Μη), , (Cr). J〇: :(^b;): tin ( Sn), wrong (Pb), initial (Pt), put (Pd), hungry (〇s), nail pottery, tin (Cd), silver (1") or recorded (_, X is selected from fluoride, chlorine Compound, pure product, broken nitrate), sulfate, sulfite, acetate, oxalate, succinate, phosphate, pyrophosphate, percarbonate, gluconate, ascorbate, ethylene Amine tetraacetate , butenedioic acid or lactate, and a = 1 to 6 and b = 1 to 6; the buffer reagent has the general formula RYz, wherein R is selected from lithium (Li), sodium (Na), potassium (K) ), magnesium (Mg), calcium (Ca) or Zn (Zn), γ is selected from the group consisting of a compound, a nitrate, a sulfate, a hydrogencarbonate, a phosphate, a dihydrogen phosphate, a hydrogen phosphate or an oxalate, and z=1~2; the reducing coenzyme is selected from the group consisting of reducing riboflavin mononuclear acid (FMNH2), reducing riboflavin adenosine dinucleotide (FADH2), and reducing nicotine indole adenosine dinuclear Acid (NADH) or reduced nicotine guanamine dinucleotite phosphate (nadph); the oxidizing agent is selected from the group consisting of argon peroxide or a stilbene compound; and the ionic compound is NX ' Wherein N is selected from lithium (Li), sodium (Na) or potassium (K), and X is selected from the group consisting of fluoride, desertified 'diiodide, sulfite, acetate, succinate, pyrophosphate, a peroxyacid salt, a gluconate, an ascorbate, an ethylenediaminetetraacetate, a butenedioate or a lactate; and the catalyzing ionic compound, the buffering agent, and the reducing coenzyme a mixture of sexual agents, or The sub-compound, or the sulfide, is sufficiently mixed according to the weight ratio i · 1324046, 40 to 4,000: 2 to 200. 8. The method for the removal of pesticides (4) as described in the seventh paragraph of the patent application garden, wherein the chemical function is The ionic compound, the buffering contact, and the mixture of the compounding agent and the oxy-compounding agent, or the ionic compound or the sulfide are preferably 2,000:10 to 1 〇〇. 1 * gw~ LT Huashen 7 The method for preparing a pesticide-removing composition, wherein the chemical formula of the sulfide is RSH 'where R = Ci~C6 silk, and the aryl group according to the seventh aspect of the method for preparing a pesticide, wherein the sulfide system It is selected from the group consisting of + acid test, reduced valine acid, dithiothreitol or homohemohamine.