A7 1297273 ___B7 —_ 五、發明說明（I) 發明之詳細說明 [發明所屬之技術領域] 本發明係關於油中水型乳化組成物以及使用該組成物 之乳化化粧料。更詳細的說，係關於油中水型乳化組成物 及使用該組成物之乳化化粧料其呈現良好乳化狀態，且不 會因溫度或時間而產生變化，安定性佳且不會有黏腻感， 具淸爽之良好使用觸感。 [習知技術] 先前，油中水型(W/0)乳化組成物係藉由於外相（油相) 中配合大量之固形•半固形型油分使黏度提高，故造成油 腻且黏腻之使用感，作爲化粧料之評價很低。 [發明欲解決之課題] 本發明之目的爲解決該課題，而提供一種安定性佳且 不會有黏腻感，具淸爽之良好使用觸感之油中水型乳化組 成物以及使用該組成物之乳化化粧料。 [用以解決課題之方法] 爲解決上述課題，本發明提供一種油中水型乳化組成 物，其含有⑷有機變性黏土礦物0.1〜20重量％、（b)油分 10〜70重量％、（c)HLB爲7以下之乳化劑0.01〜10重量％及 (d)將具膠化能力之親水化合物以水或水性成分溶解後，放 置冷卻使固化成膠再將該凝膠粉碎得到之平均粒徑爲 (請先閱讀背面之注意事項再填寫本頁) «· --線. 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1297273 μ _____Β7______ 五、發明說明（V ) 0·1〜1000 // m之微凝膠0.1〜90重量°/〇。 並且，在上述(d)成分中，具膠化能力之親水性化合物 以擇自洋菜、角叉菜膠、卡德蘭熱凝膠(curdlan)、明膠、 結蘭膠(gelangum)、褐藻酸中之1種或2種以上爲較佳。 又，（d)成分之微凝膠其平均粒徑以1〜3〇〇μπι爲較佳 〇 又本發明係提供乳化化粧料，其含有上述油中水型乳 化組成物。 [發明之實施形態]/ 以下詳述本發明。 (a)成分之有機變性黏土礦物只要是一般在化粧品等可 用者則不特別限制而可任意使用。本發明中較適者爲將水 膨潤性黏土礦物以第4級銨鹽型陽離子界面活性劑處理之 陽離子變性黏土礦物。 在此之上述水膨潤性黏土礦物比如有屬於蒙脫石屬之 層狀矽酸鹽礦物，一般較佳者爲比如下述通式(I) (X，Y)2_3(Si，Al)401G(0H)2Z1/3 · n H20 (I) (式中 X 表示 A1、Fe(III)、Mn(III)或 Cr(III);Y 表示 Mg、Fe(II)、Ni、Zn、Li 或 Mn(II);Z 表示 K、Na、l/2Ca 或l/2Mg)所示之具三層構造之膠體(colloid)性含水矽酸銨 等之黏土礦物。具體而言，可適用者有蒙脫石、巷石、鋰 蒙脫石等之天然或合成品[爲將式⑴中之(0H)基以氟元素取 代者]之蒙脫石群[市售品有畢加姆(邦達皮魯特社製）、庫尼 本纸張尺度適@國國家標準（CNS)A4規格（210 X 297公釐）~" (請先閱讀背面之注意事項再填寫本頁) 』：OJIWM MM MM MM 蓮 ϋ ml i n n i I I n in ϋ 1297273 A7 B7 五、發明說明（ 皮亞（庫力米聶工業社製）、拉波乃特（拉波魯帖社製）等]， ===克麥卡或是以_鋰帶雲母聞名之合成雲母[ 1 _ 壞社製)等]等。水膨潤性黏土礦 物可使用1種或2種以上。 處理上述水膨潤性黏土碥 面活性劑爲以下麵式(II) Μ第4 _麵陽離子界 (II) (式中，R!爲碳原子數1(Κ2 、 或碳原子數10〜22之烷基;^及2之院基卖卞基;R2爲甲$ 1〜3之烷基或羥基烷基;X爲_ 立’爲碳原子! 表示之化合物。具體而言，比$ 基硫酸鹽殘基)戶 、肉豆蔻基三甲基銨氯化物、j有月栓甲基銨氯化导 硬脂基三甲基銨氯化物、院基二 甲基銨氯化物 基三甲基魏化物、肉豆甲基賴㈣、二十二$ 烷基二甲基乙基銨氯化物、硬^甲基乙基銨氯化物、十) 烷基二甲基乙基銨氯化物、二^基二甲基乙基銨氯化物 物、肉豆蔻基二乙基甲基鞍一纟兀基〜甲基乙基銨氯4 土攻取化物、十六柃 銨氯化物、硬脂基二乙基甲其〜— $基二乙基甲3 錢氯化物、二十：院基二乙&氯化物、镜基：乙基μ 肉豆蔻基銨氯化物、苄基二‘基^化物、苄基二甲- 二甲基硬脂基銨氯化物、苄錾2十/、k基銨氡化物、苄㈢ 〜甲基一十=烷基銨氯化导 本紙張尺度用中國國家標準（CNS)A4規格（21〇 (請先閱讀背面之注意事項再填寫本頁) . ;線_ 1297273 A7 __ B7___ 五、發明說明αρ) 、苄基甲基乙基十六烷基銨氯化物、苄基甲基乙基硬脂基 銨氯化物、二硬脂基二甲基銨氯化物、二-二十二烷基二羥 基乙基銨氯化物，及上述各化合物中將氯化物以溴化物取 代者等，及二棕櫚基丙基乙基銨甲基硫酸鹽等。可任意由 該等第4級銨鹽型陽離子界面活性劑中選用1種或2種以 上。 將上述水膨潤性黏土礦物以第4級銨鹽型陽離子界面 活性劑處理以得到陽離子變性黏土礦物之方法比如有於水 、丙酮或低級醇等之低沸點溶劑中，將上述水膨潤性黏土 礦物與第4級銨鹽型陽離子界面活性劑進行分散攪拌處理 ，並除去低沸點溶劑以得到。又，將上述水膨潤性黏土礦 物與第4級銨鹽型陽離子界面活性劑加以配合，於處方中 進行有機變性亦可，以此法得到者亦可適用。再者，依需 要亦可將第4級銨鹽型陽離子界面活性劑與非離子性界面 活性劑倂用。 第4級銨鹽型陽離子界面活性劑之用量較佳爲對水膨 潤性黏土礦物l〇〇g爲60〜140毫當量(meq)。又，與非離子 界面活性劑倂用時，其使用量較佳爲對水膨潤性黏土礦物 100g爲5〜100g，更佳爲15〜50g。 將水膨潤性黏土礦物以第4級銨鹽型陽離子界面活性 劑處理之陽離子性變性黏土礦物其代表者有比如二甲基鏡 鋰蒙脫石、苄基二甲基硬脂基銨鋰蒙脫石、以氯化二硬脂 基一甲基銨處理之政酸銘鎂等。市售品有便頓38(以二硬 基一甲基錢氯化物處理之蒙脫石:那修那魯雷得社製）。 ~;-------- _ Τ、紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）一一 " ---- (請先閱讀背面之注意事項再填寫本頁) 雄 ·. •線. 1297273 a7 ____B7____ 五、發明說明（Γ ) 、./ 成分(a)之配合量較佳爲占油中水型乳化化粧料全量中 之0.1〜2〇重量％，更佳爲〇_1〜10重量。/。。〇.丨重量。/。未滿則 不易得到足夠安定性’另一方面，達20%爲止之配合量可 得到足夠安定性，而若配合更多則在使用性上會變硬，安 定性也會下降，故不佳。可使用（a)成分1種或2種以上。 (b)成分之油分爲形成外相者，只要是一般可用於化粧 品者則無特別限制，比如液體油脂、固體油脂、蠟類、碳 氫化油、高級脂肪酸、高級醇、合成酯油、矽酮油等，可 任意使用。 液體油脂比如有鍔梨油、山茶油、龜油、昆士蘭果油 、玉米油、薄荷油、橄欖油、菜籽油、卵黃油 '芝麻油、 杏仁油、小麥胚芽油、山茶花油、篦麻子油 '亞麻仁油、 葵花油、綿實油、蓴麻油、大豆油、落花生油、茶實油、 榧油、米糠油、中國桐油、日本桐油、荷荷巴油、胚芽油 、三甘油、三辛酸甘油、三異棕櫚酸甘油等。 作爲固體油脂者，例如有可可脂、椰子油、馬脂、硬 化椰子油、棕櫚油、牛脂、羊脂、硬化牛脂、棕櫚核油、 豬脂、牛骨脂、木蠟核油、硬化油、牛蹄脂、木蠟、硬化 篦麻油等。 作爲蠟類者，例如有蜜蠟、小燭樹蠟、綿蠟、巴西棕 櫚蠟、月桂子蠟、蟲蠟、鯨蠟、褐煤蠟、糠蠟、含水羊毛 脂、木棉蠟、醋酸含水羊毛脂、液狀含水羊毛脂、甘蔗蠟 、含水羊毛脂脂肪酸異丙酯、月桂酸己酯、還原含水羊毛 脂、喬喬巴(jojoba)蠟、硬質含水羊毛脂、蟲膠蠟、p〇e含 本紙張尺度刺巾關家辟（CNS)A4祕（21G x 2977公爱）~" (請先閱讀背面之注意事項再填寫本頁) -----訂---------線—A7 1297273 ___B7 —_ V. DESCRIPTION OF THE INVENTION (I) DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to an aqueous emulsified composition in oil and an emulsified cosmetic using the same. More specifically, it relates to an aqueous emulsified composition in oil and an emulsified cosmetic using the same, which exhibits a good emulsified state, does not change due to temperature or time, has good stability and does not have a sticky feeling. , with a good touch of good use. [Prior Art] Previously, the water-type (W/0) emulsified composition in oil was caused by a large amount of solid/semi-solid oil in the external phase (oil phase) to increase the viscosity, resulting in a greasy and sticky feeling of use. As a cosmetic material, the evaluation is very low. [Problem to be Solved by the Invention] An object of the present invention is to solve the problem and to provide a water-based emulsified composition which is excellent in stability and does not have a sticky feeling, has a good feeling of use, and is used in the composition. Emulsifying cosmetic material. [Means for Solving the Problem] In order to solve the above problems, the present invention provides an oil-in-water emulsified composition comprising (4) an organically modified clay mineral in an amount of 0.1 to 20% by weight, and (b) an oil component of 10 to 70% by weight, (c) An emulsifier having an HLB of 7 or less 0.01 to 10% by weight and (d) a hydrophilic compound having a gelling ability dissolved in water or an aqueous component, placed in a cooling state to be solidified into a gel, and then the gel is pulverized to obtain an average particle diameter. (Please read the note on the back and fill out this page) «· -- Line. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1297273 μ _____Β7______ V. Invention description (V) 0 · 1~1000 // m microgel 0.1~90 weight ° / 〇. Further, in the above component (d), the hydrophilic compound having gelling ability is selected from acacia, carrageenan, curdlan, gelatin, gelangum, alginic acid. One or two or more of them are preferred. Further, the microgel of the component (d) preferably has an average particle diameter of 1 to 3 μm. Further, the present invention provides an emulsified cosmetic comprising the above-mentioned oil-in-oil emulsified composition. [Embodiment of the Invention] / The present invention will be described in detail below. The organically modified clay mineral of the component (a) is not particularly limited as long as it is generally used in cosmetics, and can be used arbitrarily. A suitable one in the present invention is a cationically modified clay mineral which is treated with a water-swellable clay mineral as a fourth-order ammonium salt type cationic surfactant. Here, the water-swellable clay mineral is, for example, a layered niobate mineral belonging to the genus Montmorillonite, and is generally preferably of the following formula (I) (X, Y) 2_3 (Si, Al) 401G ( 0H) 2Z1/3 · n H20 (I) (wherein X represents A1, Fe(III), Mn(III) or Cr(III); Y represents Mg, Fe(II), Ni, Zn, Li or Mn ( II); Z represents a clay mineral having a three-layered colloidal aqueous ammonium citrate represented by K, Na, l/2Ca or l/2Mg). Specifically, the montmorillonite group of natural or synthetic products such as montmorillonite, alley stone, and hectorite [for the substitution of the (0H) group in the formula (1) with a fluorine element] is commercially available [commercially available]. The product has Picam (made by Bonda Piruth), and the Cunben paper size is suitable for the National Standard (CNS) A4 specification (210 X 297 mm)~" (Please read the note on the back first) Fill in this page) 』:OJIWM MM MM MM Lotus ϋ ml inni II n in ϋ 1297273 A7 B7 V. Description of invention (Pia (Kulimi Nie Industrial Co., Ltd.), La Bonet (La Bolude) Etc.], ===Kemika or synthetic mica known as _lithium mica [1 _ bad society system], etc. One type or two or more types of water-swellable clay minerals can be used. The water-swellable clay surfactant is treated by the following formula (II) Μ 4th _ cation boundary (II) (wherein R! is a carbon number of 1 (Κ2, or an alkane having 10 to 22 carbon atoms) The base of the ^; and 2 is sold as a thiol group; R2 is an alkyl group or a hydroxyalkyl group of A$1 to 3; X is a compound represented by a carbon atom! Specifically, it is more than a residue of the base sulfate. Base, nutmegyl trimethylammonium chloride, j-monthly methylammonium chloride, stearyltrimethylammonium chloride, yard-based dimethylammonium chloride-trimethyl-wide, meat Bean methyl ray (tetra), twenty-two alkyl dimethyl ethyl ammonium chloride, hard methyl ethyl ammonium chloride, ten) alkyl dimethyl ethyl ammonium chloride, dimethyl dimethyl Ethyl ammonium chloride, myristyl diethylmethyl saddle-methyl-methylethyl ammonium chloride 4 soil extract, hexadecane ammonium chloride, stearyl diethyl ketone ~ - $ Diethyl 3-methyl chlorate, twenty: yard-based diethyl ether & chloride, mirror base: ethyl μ myristyl ammonium chloride, benzyl di-based compound, benzyl dimethyl-dimethyl Base stearyl ammonium chloride, benzamidine 2, / k base Telluride, benzyl (III) ~ methyl dec = alkyl ammonium chlorinated paper size with the Chinese National Standard (CNS) A4 specifications (21 〇 (please read the back of the note before filling this page). ; Line _ 1297273 A7 __ B7___ V. Description of the invention αρ) , benzylmethylethyl cetyl ammonium chloride, benzyl methyl ethyl stearyl ammonium chloride, distearyl dimethyl ammonium chloride, two - The dodecyldihydroxyethylammonium chloride, and the above compounds, wherein the chloride is substituted with a bromide, and dipalmitylpropylethylammonium methyl sulfate. One or more of these fourth-order ammonium salt type cation surfactants may be optionally used. The above water-swellable clay mineral is treated by treating the water-swellable clay mineral with a fourth-order ammonium salt type cationic surfactant to obtain a cationically modified clay mineral such as a low boiling point solvent such as water, acetone or a lower alcohol. It is obtained by dispersing and stirring a fourth-stage ammonium salt type cation surfactant, and removing a low boiling point solvent. Further, the water-swellable clay mineral may be blended with a fourth-order ammonium salt-type cationic surfactant to carry out organic denaturation in a prescription, and the method may be applied. Further, a fourth-stage ammonium salt type cationic surfactant and a nonionic surfactant may be used as needed. The level 4 ammonium salt type cationic surfactant is preferably used in an amount of 60 to 140 milliequivalents (meq) to the water-swellable clay mineral. Further, when it is used in combination with a nonionic surfactant, it is preferably used in an amount of 5 to 100 g, more preferably 15 to 50 g, per 100 g of the water-swellable clay mineral. Cationic denaturing clay minerals treated with a water-swellable clay mineral as a fourth-order ammonium salt type cationic surfactant are represented by, for example, dimethyl mirror hectorite, benzyl dimethyl stearyl ammonium montmorillonite Stone, Zhengan Ming magnesium treated with distearyl monomethylammonium chloride. Commercially available products include Benton 38 (montmorillonite treated with di-hard-methyl-chloride chloride: manufactured by Nakhon Naruide). ~;-------- _ Τ, paper scale applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) one by one ----- (Please read the back of the note before you fill out this Page) Xiong··• Line. 1297273 a7 ____B7____ V. Inventive Note (Γ), ./ Component (a) is preferably added in an amount of 0.1 to 2% by weight of the total amount of water-based emulsified cosmetic material. Good for 〇_1~10 weight. /. . 〇.丨 weight. /. If it is not full, it is not easy to obtain sufficient stability. On the other hand, the blending amount up to 20% can be sufficiently stabilized, and if it is combined, it will become hard in use and the stability will be lowered, so it is not good. One type or two or more types of (a) components can be used. The oil of the component (b) is divided into the outer phase, and there is no particular limitation as long as it is generally used for cosmetics, such as liquid fat, solid fat, wax, hydrocarbon oil, higher fatty acid, higher alcohol, synthetic ester oil, fluorenone oil. Etc., can be used at will. Liquid oils such as avocado oil, camellia oil, turtle oil, Queensland fruit oil, corn oil, peppermint oil, olive oil, rapeseed oil, egg butter 'sesame oil, almond oil, wheat germ oil, camellia oil, castor oil' Linseed oil, sunflower oil, cotton oil, castor oil, soybean oil, peanut oil, tea oil, oyster sauce, rice bran oil, Chinese tung oil, Japanese tung oil, jojoba oil, germ oil, triglycerin, tricapry glycerol , triiso palmitic acid glycerin, etc. As solid fats, for example, cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow, sheep fat, hardened tallow, palm kernel oil, lard, beef bone fat, wood wax nuclear oil, hardened oil, Cow's fat, wood wax, hardened castor oil, etc. As waxes, for example, beeswax, candelilla wax, cotton wax, carnauba wax, laurel wax, insect wax, cetyl wax, montan wax, wax, water-containing lanolin, kapok wax, acetic acid-containing lanolin, Liquid aqueous lanolin, sugar cane wax, water-containing lanolin fatty acid isopropyl ester, hexyl laurate, reduced aqueous lanolin, jojoba wax, hard water-containing lanolin, shellac wax, p〇e containing paper Scale jade towel Guan Jia Pi (CNS) A4 secret (21G x 2977 public love) ~ " (Please read the back of the note and then fill out this page) -----Book--------- line -
A 1297273 a7 _B7 _ 五、發明說明（^ ) 水羊毛脂醇醚、POE含水羊毛脂醇乙酸酯、POE膽固醇醚 、含水羊毛脂脂肪酸聚乙二醇、POE加氫含水羊毛脂醇醚 等。 作爲碳氫化油有例如，液體石蠟、地蠟、角鯊烷、 鯊肝油烷、石蠟、角鯊烯、凡士林、微晶性蠟等。 作爲高級脂肪酸有例如月桂酸、肉豆蔻酸、棕櫚酸、 硬脂酸、辣木子油酸、12-羥基硬脂酸、十一烷烯酸、妥爾 酸(tall acid)等。 作爲高級醇有例如，十六醇、硬脂醇、辣木子醇、肉 豆蔻醇、油烯酸醇等。 作爲合成酯油者有例如，肉豆蔻酸異丙酯、辛酸十六 酯、肉豆蔻酸辛基十二酯、棕櫚酸異丙酯、硬脂酸丁酯、 月桂酸己酯、肉豆蔻酸肉豆蔻酯、油烯酸癸酯、二甲基辛 酸己基癸酯、乳酸十六酯、乳酸肉豆蔻酯、醋酸含水羊毛 酯、硬脂酸異十六酯、異硬脂酸異十六酯、12-羥基硬脂 酸膽固醇、二一 2—乙基己酸乙二醇、二一戊赤蘚醇脂肪酸 酯、單異硬脂酸N-烷二醇、二癸酸新戊二醇、蘋果酸二 異硬脂醇、二一 2-庚基十一酸甘油、三—2-乙基己酸三 羥甲基丙烷、三異硬脂酸三羥甲基丙烷、四一 2—乙基己酸 戊赤蘚醇、三-2-乙基己酸甘油、三辛酸甘油、三異棕櫚 酸甘油、三異硬脂酸三甲氧基丙烷、十六基-2-乙基己酸 酯、2—乙基己基棕櫚酯、三異肉豆蔻酸甘油、三一2—庚 基十一酸甘油酯、篦麻子油脂肪酸甲基酯、油烯酸油酯、 乙醯硬酯醇、乙醯甘油酯、棕櫚酸2-庚基十一酯、己二 ___8___— 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 瓣. . -線· 1297273_3： — 五、發明說明（^ ) 酸二異丁酯、N-月桂基一 L 一谷氨酸〜2〜辛基十二院基 酯、己二酸二2—庚基十一酯、乙基月桂酷、癸二酸二一2 一乙基己酯、肉豆蔻酸2—己基癸酯、棕櫚酸2一己基癸酯 、己二酸2—己基癸酯、癸二酸二異丙酯、號班酸2一乙基 己酯、乙酸乙酯、乙酸丁酯、檸檬酸三乙酷等。 作爲石夕酮油有例如’二甲基聚砂氧烷、甲基苯基聚石夕 氧院、甲基氫聚氧5夕院等鏈狀砂酮油;十二甲基環己砂氧院 、八甲基環四矽氧烷、十甲基環戊矽氧烷、四甲基四氫聚 矽氧烷等之環狀環狀矽酮油等。 (b)成分之配合量較佳爲佔油中水型乳化化粧料全量之 10〜70重量％。 作爲⑷成分之乳化劑係HLB爲7以下者。HLB若超 過7則親水性升筒，不易得到安定之油中水型乳化組成物 〇 本發明中HLB係以下述數學式1計算出。 [數學式1] HLB=7+11.7 · log(MW/MO) (惟，MW表示親水基部份之分子量，MO表示親油基 部份之分子量） HLB爲7以下之乳化劑比如有界面活性劑之山梨糖醇 酐單月桂酯、山梨糖醇酐單異硬脂酯、山梨糖醇酐三硬脂 酯等之山梨糖醇酐脂肪酸酯類;甘油單硬脂酯、甘油單油酯 等之甘油脂肪酸酯類；POE(5)硬化篦麻子油、Ρ〇Ε(7·5)硬化 篦麻子油、ΡΟΕ(ΙΟ)硬化箆麻子油等之聚環氧乙烷篦麻子油 _______ _2______ 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂-- 線· 1297273 a7 ____B7 _ 五、發明說明（^ ) ;聚乙醚變性矽酮系界面活性劑、二甲基矽油多元醇等。 (0成分之配合量較佳爲佔本發明乳化組成物全量之 0.01〜10重量％，更佳爲〇· 1〜5重量。/。。配合量若過少無法 得到安定之乳化物，另一方面，配/合量過多則會產生黏腻 及不濕潤等使用性上之問題。（c)成分可任意選擇1種或2 種以上使用。 再者，（c)成分亦可以被吸附於(b)成分之有機變性黏土 礦物之狀態而包含於本發明組成物中。亦即，在製造本發 明之油中水型乳化組成物或乳化化粧料時，可將有機變性 黏土礦物以可作成(c)成分之HLB7以下之界面活性劑做處 理，使HLB7以下之乳化劑吸附於有機變性黏土礦物之狀 態來配合(c)成分。 外相（油相）除上述必需成分外，在不損害本發明效果 之範圍內可以任意添加配合成分。比如可配合通常用於化 粧品、準醫藥品成分之其他油性成分、油溶性高分子、粉 末、高分子顆粒等。 (d)成分之微凝膠係將平均粒徑0.1〜ΙΟΟμπι且具膠化能 力之親水性化合物以水或水性成分溶解後，放置冷卻使固 化形成凝膠，再將該凝膠粉碎得到。該(d)成分係包含於內 相(水相）。 上述(d)成分中具膠化能力之親水性化合物只要是具膠 化能力之水溶性化合物，且可在化粧料、醫藥品領域可使 用者則不特別限定。具體而言，比如有明膠、膠原蛋白等 具膠化能力之親水性蛋白質或是，洋菜、卡德蘭熱凝膠、 ___ίο —___ · 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) m: · --線- 1297273 a7 __ B7_______ 五、發明說明（) 蘇庫雷羅（skurelo)葡聚糖、希索非蘭(sizofiran)、結蘭膠、 褐藻酸、角叉菜膠、甘露聚糖、果膠、透明質酸等親水性 多糖類等。其中又以明膠、洋菜、卡德蘭熱凝膠、結蘭膠 、褐藻酸、角叉菜膠爲特別較佳被使用者。具膠化能力之 親水性化合物可使用1種或2種以上。 接著，將該等具膠化能力之親水性化合物溶解於水或 水性成分後，形成凝膠。上述化合物可藉混合、加熱等使 溶解於水或水性成分。又，成膠化可藉溶解後停止加熱， 再將其放置（徐冷）到比成膠化溫度爲低之溫度等之常法來 進行。 ， 水性成分只要可在化粧料、醫藥品領域可使用者則不 特別限定。比如二丙二醇、丙二醇等二醇類，或甲醇、乙 醇、丙醇等低級醇，其他也可含有一般作爲化粧料之水相 成分之配合成分。具體而言有比如偏磷酸鹽、依地酸鹽等 之鰲合劑或pH調整劑、防腐劑等，但並不限定於舉例者 〇 上述凝膠之凝膠化強度只要可維持凝膠本身之形狀， 且可得到下一製程中之微凝膠即可而無特別限定。本發明 中比如膠(jelly)強度在30g/cm2(日寒水式測定)左右之相當 弱之凝膠強度下亦可得到微凝膠。 其次，將上述形成之凝膠以均質機、分散器、機械式 攪拌器破碎以得到所欲之微凝膠。微凝膠之平均粒徑爲 0.1〜ΙΟΟΟμπι，較佳爲1〜300μηι，更佳爲10〜200μιη左右。 破碎之程度爲使所得微凝膠之平均粒徑不脫離上述本發明 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)A 1297273 a7 _B7 _ V. Description of the invention (^) Hydrool ether, POE aqueous lanolin acetate, POE cholesterol ether, aqueous lanolin fatty acid polyethylene glycol, POE hydrogenated aqueous lanolin ether, and the like. Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, shark hemane, paraffin, squalene, petrolatum, microcrystalline wax, and the like. As the higher fatty acid, for example, lauric acid, myristic acid, palmitic acid, stearic acid, moringoic acid, 12-hydroxystearic acid, undecylenic acid, tall acid, and the like can be mentioned. As the higher alcohol, for example, cetyl alcohol, stearyl alcohol, moringacohol, myristyl alcohol, oleic acid alcohol or the like can be mentioned. As the synthetic ester oil, for example, isopropyl myristate, hexadecyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristic acid nutmeg Ester, decyl oleate, hexyl decyl dimethyl octoate, hexadecyl lactate, myristyl lactate, aqueous lanolin acetate, isohexadecyl stearate, isohexadesyl isostearate, 12- Hydroxy stearic acid cholesterol, di-2-ethylhexanoic acid ethylene glycol, diamyl erythritol fatty acid ester, monoisostearic acid N-alkylene glycol, dinonanoic acid neopentyl glycol, malic acid II Isostearyl alcohol, di- 2-heptyldecanoic acid glycerol, tris-ethylhexanoic acid trimethylolpropane, triisomethylstearate tristearate, tetraam-2-ethylhexanoate Erythritol, tris-2-ethylhexanoic acid glycerol, tricaprylic glycerol, triisopalmitic acid glycerol, triisopropoxylated trimethoxypropane, hexadecyl-2-ethylhexanoate, 2-ethyl Hexyl palmitate, triisomyristate, triam-2-heptyldecanoate, castor oil fatty acid methyl ester, oleic acid oil ester, acetaminophen, acetamidine , 2-heptyl undecyl palmitate, hexamethylene ___8___— This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page). - Line · 1297273_3: - V. Description of the invention (^) diisobutyl acrylate, N-lauryl-L-glutamic acid ~ 2 ~ octyl 12-yard ester, di-2-heptyl adipic acid Monoester, ethyl laurel, diamyl-2-hexyl phthalate, 2-hexyl decyl myristate, 2-hexyl decyl palmitate, 2-hexyl decyl adipate, azelaic acid Isopropyl ester, 2-ethylhexyl acid, ethyl acetate, butyl acetate, triethyl citrate, and the like. As the oleic acid oil, there are chain gargle oils such as 'dimethyl oxalate, methyl phenyl polyoxan, methyl hydrogen polyoxy 5 cesium; twelve methyl cyclohexane A cyclic cyclic fluorenone oil such as octamethylcyclotetraoxane, decamethylcyclopentaoxane or tetramethyltetrahydropolysiloxane. The compounding amount of the component (b) is preferably from 10 to 70% by weight based on the total amount of the water-based emulsified cosmetic. The emulsifier having the component (4) has an HLB of 7 or less. If the HLB is more than 7 and is hydrophilic, it is difficult to obtain a water-based emulsified composition in a stable oil. HL In the present invention, the HLB system is calculated by the following mathematical formula 1. [Math 1] HLB=7+11.7 · log(MW/MO) (However, MW represents the molecular weight of the hydrophilic moiety, MO represents the molecular weight of the lipophilic moiety) Emulsifier having an HLB of 7 or less, such as interface activity A sorbitan fatty acid ester such as sorbitan monosodium laurate, sorbitan monoisostearyl ester or sorbitan tristearate; glycerol monostearyl ester, glycerol monooleate, etc. Glycerol fatty acid esters; POE (5) hardened castor oil, Ρ〇Ε (7.5) hardened castor oil, ΡΟΕ (ΙΟ) hardened castor oil, etc. Polyethylene oxide castor oil _______ _2______ Zhang scale applies China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) Order -- Line · 1297273 a7 ____B7 _ V. Invention description (^); Polyether A denatured anthrone-based surfactant, a dimethyl hydrazine polyol, or the like. (The compounding amount of the component 0 is preferably 0.01 to 10% by weight, more preferably 〇·1 to 5 parts by weight based on the total amount of the emulsified composition of the present invention. If the amount is too small, a stable emulsion cannot be obtained. If the amount of the compound is too large, it may cause problems such as stickiness and non-wetting. (c) The component may be used singly or in combination of two or more. Further, the component (c) may be adsorbed to (b). The state of the organically modified clay mineral of the component is included in the composition of the present invention. That is, in the production of the water-type emulsified composition or the emulsified cosmetic in the oil of the present invention, the organically-modified clay mineral can be made into (c) The surfactant of the component below HLB7 is treated to make the emulsifier below HLB7 adsorb to the state of the organic denatured clay mineral to match the component (c). The external phase (oil phase) does not impair the effect of the present invention except the above-mentioned essential components. The compounding component can be arbitrarily added in the range, for example, it can be blended with other oily components, oil-soluble polymers, powders, polymer particles, etc. which are usually used for cosmetics and quasi-drugs. (d) The microgel of the component will be averaged. 0.1~ΙΟΟμπι and a hydrophilic compound having a gelling ability are dissolved in water or an aqueous component, and then left to cool to form a gel, which is then pulverized. The component (d) is contained in the internal phase (aqueous phase). The hydrophilic compound having a gelling ability in the component (d) is not particularly limited as long as it is a water-soluble compound having a gelling ability, and can be used in the field of cosmetics and pharmaceuticals, and specifically, for example, gelatin. , hydrophilic protein with gelatinization ability such as collagen, or acacia, cardran thermal gel, ___ίο —___ · This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please Read the notes on the back and then fill out this page) m: · --Line - 1297273 a7 __ B7_______ V. Description of invention () skurelo dextran, sizofiran, ylang gum , brown alginic acid, carrageenan, mannan, pectin, hyaluronic acid and other hydrophilic polysaccharides, etc. Among them, gelatin, agar, Kadland thermogel, garland, alginic acid, horn Vegetable gum is particularly preferred by users. One or two or more kinds of hydrophilic compounds can be used. Next, the hydrophilic compound having gelation ability is dissolved in water or an aqueous component to form a gel. The above compound can be dissolved by mixing, heating, or the like. Water or water-based ingredients. In addition, gelation can be carried out by dissolving and then heating, and then placing it (cold) to a temperature lower than the gelatinization temperature. The water-based component can be used as a cosmetic. In the pharmaceutical field, the user is not particularly limited. For example, a glycol such as dipropylene glycol or propylene glycol, or a lower alcohol such as methanol, ethanol or propanol may contain other components which are generally used as an aqueous phase component of the cosmetic. For example, there are a chelating agent such as a metaphosphate or an edetate, a pH adjuster, a preservative, etc., but it is not limited to the example, and the gelation strength of the gel can maintain the shape of the gel itself. Further, the microgel in the next process can be obtained without particular limitation. In the present invention, a microgel can also be obtained under a relatively weak gel strength such as a jelly strength of about 30 g/cm2 (measured by the daily cold water type). Next, the gel formed above was crushed by a homogenizer, a disperser, and a mechanical stirrer to obtain a desired microgel. The average particle diameter of the microgel is from 0.1 to ΙΟΟΟμm, preferably from 1 to 300 μm, more preferably from about 10 to 200 μm. The degree of fragmentation is such that the average particle size of the obtained microgel does not deviate from the above-mentioned paper size of the present invention. The Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applied (please read the notes on the back and fill out this page). )
-------^ ---------I 1297273 A7 ___ B7_____ 五、發明說明（10 ) 之範圍內可依目的調整，當需要使用性較滑時以高速攪拌 使充分破碎使成細小粒徑之微凝膠，另一方面，需要有微 凝膠觸感時則以輕微攪拌使破碎程度小以成爲稍大粒徑之 微凝膠。 藉此所得到之微凝膠其黏度、比如以洋菜作爲具有膠 化能力之親水性化合物時，當洋菜濃度爲0.5〜2%左右時， 以B型黏度計（旋轉數0.6rpm、25 t：)測定得 2,000〜l，000,000mPa · s左右者較佳。藉使微凝膠之黏度落 於上述範圍，可得到滑潤性、濕潤性(保濕感）良好之使用 感。若黏度過低常會使滑潤性、濕潤性(保濕感)不佳。 (d)成分之配合量較佳爲佔本發明乳化組成物全量之 0.01〜90重量％，更佳爲1〜80重量％。配合量若過少無法 得到濕潤之使用感，另一方面，配合量過多則會產生黏腻 之使用性上之問題。（d)成分可任意選擇1種或2種以上使 用。 再者，本發明之油中水型乳化組成物比如用於乳化化 粧料時，於上述必需成分之外，在不損及本發明目的之限 度下，可依需要配合通常配合於化粧料之其他成分。該種 成分比如有聚乙二醇、甘油、1，3-丁二醇、赤蘚醇、山 梨糖醇、木糖醇、麥芽糖醇等之保濕劑；L-精胺酸、β-丙胺 酸、L-精胺酸鹽酸鹽、L-天冬胺酸1水合物、L-天冬醯胺 鈉1水合物、L-天冬醯胺酸鉀2水合物、L-天冬醯胺酸、 L-吉魯托林（chitodin)、L-谷胺酸、L-谷胺酸鹽酸鹽、L-谷 胺酸鈉1水合物、L-谷胺酸鉀1水合物、L-谷醯胺、甘胺 ---- 1?__^__ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -tr°J· .線- A7 1297273 ----- --BZ_ 五、發明說明（1丨） 酸、三甲基甘胺酸、L-組胺酸、L-組胺酸鹽酸鹽1水合物 、L-羥基脯胺酸、L-異白胺酸、L-白胺酸、L-離胺酸、L-離胺酸鹽酸鹽、L-鳥胺酸、L-脯胺酸、L-苯丙胺酸、L-絲 胺酸、L-蘇胺酸、L-色胺酸、L-酪胺酸、L-纈胺酸、L-多 巴、L-α-胺基丁酸等之L-胺基酸及其鹽類或其水合物；乙 醇等低級醇；丁基羥基甲苯、生育酣、植酸鈣鎂等之抗氧 化劑;苯甲酸、水楊酸、山梨酸、對羥基苯甲酸院基酯（對 羥基苯甲酸乙酯、對羥基苯甲酸丁酯等）、雙三氯酚等抗菌 •防腐劑;對胺基苯甲酸(PABA)、PABA單甘油酯、N，N-二 丙氧基PABA乙酯r N，N-二乙氧基PABA乙酯、N，N-二甲 基PABA乙酯、N，N-二甲氧基PABA 丁酯等苯甲酸系紫外 線吸收劑；同孟(110111011^1111^1)基一^^—乙醯基憩酸等憩酸 系紫外線吸收劑；戊基水楊酸酯、孟基水楊酸酯、同孟基 水楊酸酯、辛基水楊酸酯、苯基水楊酸酯、苄基水楊酸酯 、對異丙醇苯基水楊酸酯等水楊酸系紫外線吸收劑;辛基桂 皮酸酯、乙基一 4 一異丙基桂皮酸酯、甲基一 2,5 —二異丙 基桂皮酸酯、乙基―2,4—二異丙基桂皮酸酯、甲基一 2,4 -二異丙基桂皮酸酯、丙基-對甲氧基桂皮酸酯、異丙基 -對甲氧基桂皮酸酯、異戊基一對甲氧基桂皮酸酯、辛基 一對甲氧基桂皮酸酯、2-乙基己基一對甲氧基桂皮酸酯、 2—乙氧基乙基-對甲氧基桂皮酸酯、環己基一對甲氧基桂 皮酸酯、乙基一 a-氰基一 β-苯基桂皮酸酯、2一乙基己 基一 a-氰基一 β-苯基桂皮酸酯、甘油單一 2 一乙基己醯 基一二對甲氧基桂皮酸酯、3,4,5-三甲氧基桂皮酸3-甲基_ _________η —____ 本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐)----- (請先閱讀背面之注意事項再填寫本頁) 麟. .. ••線- 1297273 a7 —^______B7________ 五、發明說明（卜） 4-[甲基雙（三甲基矽氧烷基）甲矽烷基]丁酯等桂皮酸系紫外 線吸收劑；2,4 一二羥基二苯甲酮、2,2’一二羥基一 4 一甲氧 基二苯甲酮、2,2’一二羥基一 4,4’一二甲氧基二苯甲酮、 2,2’，4,4’一四羥基二苯甲酮、2—羥基一4一甲氧基二苯甲 酮、2 —羥基一 4一甲氧基一 4’一甲基二苯甲酮、2 —羥基一 4一甲氧基二苯甲酮一 5—磺酸鹽、4一苯基二苯甲酮、2 — 乙基己基一 4’一苯基—一苯甲酮一 2—竣酸酯、2—經基一4 一正辛氧基二苯甲酮、4 一羥基一 3-羧基二苯甲酮等之二 苯甲酮系紫外線吸收劑;3 -（4’ -甲基苯亞甲基）一 d，l-樟腦 、3—苯亞甲基一 dyl-樟腦、尿刊酸、尿刊酸乙基酯、2 — 苯基一 5—甲基苯并噁唑、2,2’一羥基一 5 -甲基苯基苯并 三唑、2-（2’一羥基一 5’一特辛基苯基）苯并三唑、2-（2’ —羥基一 5’一甲基苯基）苯并三唑；二苄連氮（dibenzaladine) 、二對甲氧苯基甲烷、4一甲氧基一 4’一特丁基二苯甲醯基 甲烷、5 —（3,3—二甲基一2—降冰片烷基亞甲基）一3 —戊烷 -2-酮、特雷斐他立頓(terephytaririden)二樟腦磺酸等之 紫外線吸收劑；醯基肌氨酸(比如月桂醯基肌氨酸鈉）、谷胱 甘肽、檸檬酸、蘋果酸、酒石酸、乳酸等之有機酸;維生素 A及其衍生物、維生素B6鹽酸鹽、維生素B6三棕櫚酸酯、 維生素B6二辛酸酯、維生素B2及其衍生物、維生素B12、 維生素B15及其衍生物等之維生素B類、抗壞血酸、抗壞 血酸硫酸酯(鹽）、抗壞血酸磷酸酯(鹽）、抗壞血酸二棕櫚酸 酯(鹽)等之維生素C類、α-生育醇、β-生育醇、γ-生育 醇、維生素Ε醋酸酯等之維生素Ε類、維生素D、維生素 ____L1._；______ "^3尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) " (請先閱讀背面之注意事項再填寫本頁)-------^ ---------I 1297273 A7 ___ B7_____ V. In the scope of invention (10), it can be adjusted according to the purpose. When it is required to be slippery, it will be fully broken by high-speed stirring. The microgel having a fine particle size is formed on the other hand, and when it is required to have a microgel touch, the degree of breakage is small with a slight agitation to become a slightly larger particle size microgel. The viscosity of the microgel obtained by this method, for example, when acacia is used as a hydrophilic compound having gelatinizing ability, when the concentration of the amaranth is about 0.5 to 2%, the viscosity is measured as a B-type viscometer (rotation number 0.6 rpm, 25) It is preferable that t:) is measured to be about 2,000 to 1,000,000 mPa·s. When the viscosity of the microgel falls within the above range, a feeling of use in which the smoothness and the wettability (moisturizing feeling) are good can be obtained. If the viscosity is too low, the slipperiness and moistness (moisturizing feeling) may be poor. The amount of the component (d) is preferably from 0.01 to 90% by weight, more preferably from 1 to 80% by weight based on the total amount of the emulsified composition of the present invention. If the blending amount is too small, the feeling of moistening cannot be obtained. On the other hand, if the blending amount is too large, there is a problem in the usability of stickiness. The component (d) can be used singly or in combination of two or more. Further, when the water-based emulsified composition of the present invention is used for emulsification of a cosmetic, for example, in addition to the above-mentioned essential components, the other components which are usually blended with the cosmetic may be blended as needed without impairing the object of the present invention. ingredient. Such ingredients are, for example, humectants such as polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, etc.; L-arginine, β-alanine, L-arginine hydrochloride, L-aspartic acid monohydrate, L-aspartate sodium monohydrate, L-aspartate potassium hydrate 2, L-aspartic acid, L-gilotolin, L-glutamic acid, L-glutamine hydrochloride, sodium L-glutamine monohydrate, L-glutamate monohydrate, L-glutamine ,Glyamine---- 1?__^__ This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill in this page) -tr°J· . Line - A7 1297273 ----- --BZ_ V. Description of the invention (1丨) Acid, trimethylglycine, L-histidine, L-histamine hydrochloride 1, hydrate Proline, L-isoleucine, L-leucine, L-lysine, L-isoamine hydrochloride, L-ornithine, L-valine, L-phenylalanine, L - L-amino acids such as serine, L-threonine, L-tryptophan, L-tyrosine, L-proline, L-dopa, L-alpha-aminobutyric acid and the like Its salt or its hydrate ; lower alcohol such as ethanol; antioxidants such as butylhydroxytoluene, fertility strontium, calcium phytate, etc.; benzoic acid, salicylic acid, sorbic acid, terephthalic acid ester (ethyl p-hydroxybenzoate, p-hydroxyl group) Antibacterial and preservatives such as butyl benzoate and dichlorophenol; p-aminobenzoic acid (PABA), PABA monoglyceride, N,N-dipropoxy PABA ethyl ester r N,N-diethoxy a benzoic acid-based ultraviolet absorber such as PABA ethyl ester, N,N-dimethyl PABA ethyl ester or N,N-dimethoxy PABA butyl ester; Tong Meng (110111011^1111^1) base one ^^-B A phthalic acid-based ultraviolet absorber such as thioglycolic acid; pentyl salicylate, menthyl salicylate, homoamyl salicylate, octyl salicylate, phenyl salicylate, benzyl Salicylic acid-based ultraviolet absorbers such as salicylate and p-isopropanol phenylsalicylate; octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-two Isopropyl cinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl Base-p-methoxycinnamate, different a pair of methoxycinnamate, octyl methoxycinnamate, 2-ethylhexyl methoxycinnamate, 2-ethoxyethyl-p-methoxycinnamate Cyclohexyl a pair of methoxycinnamate, ethyl-a-cyano-β-phenyl cinnamate, 2-ethylhexyl-a-cyano-β-phenyl cinnamate, glycerol single 2 Ethylhexyl fluorenyl-di-p-methoxycinnamate, 3,4,5-trimethoxycinnamic acid 3-methyl _ _________η —____ This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm)----- (Please read the notes on the back and fill out this page) Lin. .. •• Line - 1297273 a7 —^______B7________ V. Description of invention (b) 4-[Methyl double ( A cinnamic acid-based ultraviolet absorber such as trimethylphosphonylalkyl)carbamyl]butyl; 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone 2,2'-dihydroxy- 4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2-hydroxy-1,4-methoxy 2 Benzophenone, 2-hydroxy-1,4-methoxy- 4'- Methyl benzophenone, 2-hydroxy-4-methoxybenzophenone 5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzene a benzophenone-based ultraviolet absorber such as ketone-2-oxonate, 2-bromo-4-isooctyloxybenzophenone or 4-hydroxy-3-carboxybenzophenone; 3 -( 4'-methylbenzylidene)-d,l-camphor, 3-benzylidene-dyl-camphor, urinary acid, uric acid ethyl ester, 2-phenyl- 5-methylbenzo Oxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole, 2-(2'-hydroxy-5'-tert-octylphenyl)benzotriazole, 2-(2'-hydroxyl a 5'-methylphenyl)benzotriazole; dibenzaladine, di-p-methoxyphenylmethane, 4-methoxy- 4'-tert-butyl benzhydryl methane, 5 - (3,3-dimethyl- 2 -norbornylalkylmethylene)- 3 -pentan-2-one, terephytaririden dicamphorsulfonic acid, etc.; Sarcosine (such as sodium lauryl sarcosinate), glutathione, citric acid, malic acid, Organic acids such as sulphuric acid and lactic acid; vitamin A and its derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives, vitamin B12, vitamin B15 and Derivatives such as vitamin B, ascorbic acid, ascorbyl sulfate, ascorbyl phosphate, ascorbyl dipalmitate, etc., vitamin C, α-tocopherol, β-tocopherol, γ- Vitamins such as tocopherols, vitamins and acetates, vitamin D, vitamins _L1._; ______ "^3 scales apply to China National Standard (CNS) A4 specifications (210 X 297 mm) " (Read first Note on the back and fill out this page)
-*II i I n n I^flJI ! n n n n n n I ϋ 1297273 a7 __B7 ___ 五、發明說明（丨^j) Η、泛酸、雙泛酸硫乙胺等之維生素類;菸鹼酸醯胺、菸鹼 酸苄酯、γ-谷維醇、尿囊素、甘草酸(鹽）、甘草次酸及其 衍生物、日扁柏醇、甜沒藥醇、桉油醇、百里香酚、肌醇 、柴胡巷苦、胡蘿萄官苦、絲瓜島苦、無患子巷穿等之巷 苷類、泛酸基乙基醚、乙炔雌二醇、凝血酸、熊果苷、頂 花防己鹼、胎盤萃取物等之各種藥劑;羊蹄、苦蔘、川骨、 柳橙、鼠尾草、鋸齒草、錢葵、當藥、百里香、當歸、唐 檜、銀杏、杉菜、絲瓜、七葉樹、虎耳草、山金車花、百 合、艾草、芍藥、蘆薈、梔子、椹等之植物萃取物;色素; 山梨糖醇酐單月桂酯、山梨糖醇酐單棕櫚酸酯、山梨糖醇 酐倍半油酸酯、山梨糖醇酐三油酸酯、山梨糖醇酐聚環氧 乙烷單月桂酸酯、山梨糖醇酐聚環氧乙烷單硬脂酸酯、聚 乙二醇單油酸酯、聚環氧乙烷烯烴基醚、聚二醇二醚、月 桂醯基二乙醇醯胺、脂肪酸異丙醇醯胺、麥芽糖醇羥基脂 肪酸醚、烷基化多糖、烷基葡萄糖苷、糖酯等之非離子性 界面活性劑;氯化硬脂基三甲基銨、氯苄烷銨、月桂基胺氧 化物等陽離子性界面活性劑;棕櫚酸鈉、月桂酸鈉、月桂基 硫酸鈉、月桂基硫酸鉀等、烷基硫酸三乙醇胺醚、礦化篦 麻油、直鏈十二烷基苯磺酸、聚環氧乙烷硬化篦麻子油順 丁烯二酸、醯基甲基牛磺酸等陰離子性界面活性劑;兩性界 面活性劑;香料;顏料;精製水等。 再者，本發明之油中水型乳化化粧料比如有美容化粧 料、毛髮化粧料、皮膚保養化粧料、防曬化粧料等，但並 不限定於舉例者。 (請先閱讀背面之注意事項再填寫本頁) · •線 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1297273 a7 _B7___ 五、發明說明（if) 以下詳述本發明，但本發明並不限定於該等。又，配 合量爲重量％。 在實施例前，先對各實施例、比較例中使用之試驗方 法、評價基準作說明。 <使用性官能試驗> 使男女各30位(共60位)之評審員實際使用各實施例 、比較例所得到之各試料，對於平滑感、濕潤感及黏腻感 各以下述評價基準評價。 [肌膚平滑度之評價基準] ◎:感覺肌膚平滑之評審員30位以上。 〇:感覺肌膚平滑之評審員10〜29位。 △:感覺肌膚平滑之評審員5〜9位。 X:感覺肌膚平滑之評審員4位以下。 [肌膚濕潤感之評價基準] ◎:感覺肌膚濕潤之評審員30位以上。 〇:感覺肌膚濕潤之評審員10〜29位。 △:感覺肌膚濕潤之評審員5〜9位。 X:感覺肌膚濕潤之評審員4位以下。 [皮膚黏腻度之評價基準] ◎:感覺肌膚不黏腻之評審員30位以上。 〇:感覺肌膚不黏腻之評審員10〜29位。 _16________ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -laj. |線- 1297273 A7 __________ B7___ 五、發明說明（(f ) 感覺肌膚不黏腻之評審員5〜9位。 X:感覺肌膚不黏腻之評審員4位以下。 <乳化性〉 於實施例、比較例所得到之各試料的乳化性依下述評 價基準來評價。 〇:對油中水型(W/0型)之乳化被均勻的實施。 △:對油中水型(W/0型)之乳化被認爲有一部份水滴或 油滴(乳化不良） X:對油中水型(W/0型)無法乳化。 <安定性> 將實施例、比較例所得到之各試料分別以〇°c、室溫 (25t)、37t、50°c之溫度條件下保存30日之安定性依下 述評價基準來評價。 〇:認爲完全沒有分離。 △:認爲有分離。 X:認爲有顯著分離。 (水相部之調製） 水相部1〜3:將下述表1所示水相部1〜3之各成分混合 ’接著加熱至90°C使溶解後，使放置冷卻(徐冷），並形成 凝膠。將該凝膠以均質機粉碎以得到微凝膠（平均粒子徑 l〇〇|Lim) 〇 (請先閱讀背面之注意事項再填寫本頁) . 一5J·. 線·-*II i I nn I^flJI ! nnnnnn I ϋ 1297273 a7 __B7 ___ V. Description of invention (丨^j) Vitamins such as bismuth, pantothenic acid, bis-pantothenate thioethylamine; niacin amide, nicotinic acid benzyl Ester, γ-glutenol, allantoin, glycyrrhizic acid (salt), glycyrrhetinic acid and its derivatives, hinokitiol, sweet bisabolol, eucalyptol, thymol, inositol, Bupleurum alleviation, Various agents such as glucoside, bitter gourd, bitter melon, etc., such as glucosides, pantothenate ethyl ether, ethinyl estradiol, tranexamic acid, arbutin, dexamethasone, placenta extract, etc.; Sheep's hoof, bitter buckwheat, Sichuan bone, orange, sage, sawtooth, money sunflower, medicine, thyme, angelica, tang, ginkgo, cedar, loofah, horse chestnut, saxifrage, arboreal, Plant extracts of lily, wormwood, peony, aloe vera, wolfberry, medlar, etc.; pigment; sorbitan monolaurate, sorbitan monopalmitate, sorbitan sesquioleate, sorbose Alcoholic trioleate, sorbitan polyethylene oxide monolaurate, sorbitan polyethylene oxide monostearate, poly Ethylene glycol monooleate, polyethylene oxide alkene ether, polyglycol diether, lauryl diethanolamine, fatty acid isopropanolamine, maltitol hydroxy fatty acid ether, alkylated polysaccharide, alkane Nonionic surfactants such as glucosides and sugar esters; cationic surfactants such as stearyl trimethylammonium chloride, benzalkonium chloride, laurylamine oxide; sodium palmitate, sodium laurate, Sodium lauryl sulfate, potassium lauryl sulfate, etc., triethanolamine alkyl sulfate, mineralized castor oil, linear dodecylbenzenesulfonic acid, polyethylene oxide hardened castor oil, maleic acid, sulfhydryl An anionic surfactant such as methyl taurine; an amphoteric surfactant; a fragrance; a pigment; a purified water. Further, the oil-type emulsified cosmetic in the oil of the present invention is, for example, a cosmetic cosmetic, a hair cosmetic, a skin care cosmetic, a sunscreen cosmetic, etc., but is not limited thereto. (Please read the precautions on the back and fill out this page.) · • Line paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1297273 a7 _B7___ V. Description of invention (if) The following detailed description of the invention However, the invention is not limited to these. Further, the compounding amount is % by weight. Before the examples, the test methods and evaluation criteria used in the respective examples and comparative examples will be described. <Use-Functional Tests> Each of the samples obtained in each of the examples and the comparative examples was used by the panelists of 30 males and 60s in each of the men and women, and the following evaluation criteria were used for the smoothness, the moist feeling, and the sticky feeling. Evaluation. [Evaluation criteria for skin smoothness] ◎: 30 or more judges who feel smooth skin. 〇: The judges who feel the smooth skin are 10~29. △: 5 to 9 judges who feel smooth skin. X: The judges who feel the smooth skin are below 4 digits. [Evaluation criteria for moisturizing feeling of skin] ◎: 30 or more judges who feel moist skin. 〇: The judges who feel the skin moist are 10~29. △: 5 to 9 judges who feel the skin moist. X: The judges who feel the skin moist are below 4 digits. [Evaluation criteria for skin viscosity] ◎: 30 or more judges who feel that the skin is not sticky. 〇: The judges who feel the skin is not sticky are 10~29. _16________ This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) -laj. |Line - 1297273 A7 __________ B7___ V. Invention Description (f The judges who feel the skin are not sticky are 5 to 9. X: The judges who feel the skin are not sticky are 4 or less. <Emulsifying property> The emulsification of each sample obtained in the examples and the comparative examples is as follows The evaluation criteria are evaluated. 〇: The emulsification of the water type (W/0 type) in the oil is uniformly performed. △: The emulsification of the water type (W/0 type) in the oil is considered to have a part of water droplets or oil droplets. (Efficacy of emulsification) X: The water type (W/0 type) in the oil could not be emulsified. <Stability> Each sample obtained in the examples and the comparative examples was 〇°c, room temperature (25t), 37t. The stability of storage at a temperature of 50 ° C for 30 days was evaluated according to the following evaluation criteria. 〇: It was considered that there was no separation at all. △: Separation was considered. X: It was considered that there was significant separation. Preparation) Water phase parts 1 to 3: Mixing the components of the water phase parts 1 to 3 shown in Table 1 below, and then heating to 90 ° C to dissolve them, and then placing them. But (Xu cold), and form a gel. The gel is pulverized by a homogenizer to obtain a microgel (average particle diameter l〇〇|Lim) 〇 (please read the back of the note first and then fill out this page). 5J·. Line·
A7 1297273 五、發明說明（[(：) / 水相部4〜5:將下述表1所示水相部4、5之各成分混 〆 合’ h吊溫放置12小時以調製水相部。再者，水相部4所 ('tf先閱讀背面之注意事項再填寫本頁) 用之雙基乙烯基聚合物、水相部5所用之(夾)氧雜愨膠皆 〜.，… ..... ..... , 〜一—________·„·:〜.〉、 爲fF具膠化能力之增黏性化合物〇 m 1]A7 1297273 V. INSTRUCTIONS ([(:) / Water phase parts 4 to 5: Mixing the components of the water phase parts 4 and 5 shown in Table 1 below] h and immersing for 12 hours to prepare the water phase part In addition, the water phase department 4 ('tf first read the back of the precautions and then fill out this page) used in the double-base vinyl polymer, the water phase part 5 used in the (clip) oxon rubber ~.,... ..... ..... , ~1—________·„·:~.〉, a viscosity-increasing compound for fF with gelling ability〇m 1]
水相部1 水相部2 水相部3 水相部4 水相部5 洋菜 2.0 0.5 0.05 雜 羧基乙烯基聚合物 - • 0.6 (夾)氧雜憩膠 _ 讎 1.0 甘油 5.0 5.0 5.0 5.0 5.0 二丙二醇 5.0 5.0 5.0 麵 -------- 二丁二醇 / • 5.0 5.0 對羥基苯甲酸甲酯 適量 適量 適量 適量 「適量 TEA • - 讎 適量 適量— 離子交換水 殘餘 殘餘 殘餘 殘餘 殘餘 水相部之調製方法 粉碎(微凝膠) 粉碎(微凝膠) 粉碎®凝膠) 混合放置 混合"Sf" 黏度(mPa · s/25°C) 80,000 2,500 500 80,000 2,000 J (實施例1〜4) 如下表2所示，在已混合(2)〜(5)之油相部中將（1)加入 並均勻分散，再徐徐添加(6)或(7)之水相部，並以分散混合 器使均勻乳化分散，得到油中水型乳化組成物。又，表2 中「有機變性黏土礦物n」使用「便頓38」（國際雷得社製 )。 將實施例1〜4所得到之各試料，以上述試驗方法、評 價基準爲準，對於使甩性(平滑感、濕潤感、黏腻感）、乳 化性、安定性進行評價。結果如表2所示。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1297273 A7 _____B7 " 7\ 五、發明說明（f ) [表2] 實施例1 實施例2 實施例3 實施例4 ⑴有機變性黏土礦物(*) 2.0 2.0 2.0 2.0 (2)二甲基砂油多元醇 3.0 3.0 3.0 3.0 (3)十甲基環戊矽氧烷 20.0 10.0 20.0 10.0 ⑷二甲基聚矽氧烷黏度(6mPa · s/25°C) 5.0 - 5.0 5.0 (5)辛酸十六醋 5.0 - 5.0 5.0 ⑹水相部1 65.0 85.0 - •- ⑺水相部2 - - 65.0 85.0 使用感 平滑感 ◎ ◎ ◎ ◎ 潤濕感 ◎ ◎ 〇 ◎ 黏腻感 ◎ ◎ ◎ ◎ 乳化性 / 剛製造後 〇 〇 〇 〇 安定性(保存30曰） o°c 〇 〇 〇 〇 室溫 〇 〇 〇 〇 37〇C 〇 〇 〇 〇 50°C 〇 〇 〇 〇 (請先閱讀背面之注意事項再填寫本頁) —線- (比較例1〜4、實施例5) 如下表3所示，在已混合(2)〜(5)之油相部中將（1)加入 並均勻分散，再徐徐添加(6)〜(1〇)任一者之水相部，並以分 散混合器使均勻乳化分散，得到油中水型乳化組成物。再 者，表3中「有機變性黏土礦物(+)」使用「便頓38」（國際 雷得社製）。 將比較例1〜4、實施例5所得到之各試料，以上述試 驗方法，依評價基準爲準，對於使用性(平滑感、濕潤感、 黏腻感）、乳化性、安定性進行評價。結果如表3所示。 ； ___ 1Q —_— __ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1297273 A7 B7 五 、發明說明（（Γ) [表3] 比較例1 比較例2 實施例5 比較例3 比較例4 (1)有機變性黏土礦物Η 2.0 2.0 2.0 2.0 2.0 (2)二甲基政油多元醇 1.0 1.0 3.0 3.0 3.0 (3)十甲基環戊矽氧烷 5.0 5.0 20.0 20.0 20.0 (4)二甲基聚矽氧烷 黏度(6mPa · s/25°C) - 5.0 5.0 5.0 (5)辛酸十六酯 - - 5,0 5.0 5.0 ⑹水相部1 92.0 - • - - ⑺水相部2 - 92.0 - - - ⑻水相部3 - 一 65.0 - (9)水相部4 - - - 65.0 - ⑽水相部5 - - - - 65.0 使用感 平滑感 〇 〇 Δ 〇 〇 潤濕感 〇 〇 △ Δ Δ 黏腻感 Δ Δ 〇 X X 乳化性 剛製造後 Δ Δ 〇 Δ 〇 安定性(保存30曰） o°c Δ Δ 〇 Δ Δ 室溫 Δ Δ 〇 Δ Δ 37〇C Δ X 〇 X Δ 50°C X X 〇 X Δ (請先閱讀背面之注意事項再填寫本頁) . --線· (實施例6:保濕乳霜） (配合成分） 有機變性黏土礦物 (「便頓38」（國際雷得社製)） (2) 二甘油二異硬脂酸 (3) 十甲基環戊矽氧烷 70 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (重量％) 2.0 1.0 10.0 1297273 A7 B7 a 五、發明說明（L ) (4)凡士林 5.0 (5)角鯊烷 15.0 (6)洋菜 1.0 (7)二丙二醇 5.0 (8)對羥基苯甲酸甲酯 0.2 (9)精胺酸 0.1 (10)抗壞血酸磷酸鎂 2.0 (11)維生素A 0.1 (12)香料 適量 (13)離子交換水 殘餘 (請先閱讀背面之注意事項再填寫本頁) 裝·. (製法） 線· 將(4)、（5)、（11)、（12)混合’於50°C加溫溶解後，加 入⑴進行均勻分散(油相部分）。另—方面，另外將⑹〜(10) 加入（13)中，於90°C加溫溶解，冷卻固化後，以分散混合 器粉碎爲平均粒徑ΙΟΟμιη之微凝膠(水相部分）。將此水相 部分(微凝膠）一面徐徐添加至前述油相部分’一面以分散 混合器分散以得到保濕乳霜。 (實施例7:防曬乳霜） (配合成分） (重量％) (1)有機變性黏土礦物 2.0 (「便頓38」（國際雷得社製)） (2)二甲基矽油多元醇 2.0 -----21-- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） A7 B7 發明說明（〆） (3)十甲基環戊矽氧烷 10.0 (4)三甲基矽氧基矽酸 5.0 (5)疏水化氧化鈦 5.0 (6)辛基一對甲氧基桂皮酸酯 10.0 (7)洋菜 1.5 (8)L-精胺酸鹽酸鹽 1.0 (9)1，3-丁二醇 5.0 (10)對羥基苯甲酸甲酯 0.2 (11)月見早油 0.3 (12)球狀聚乙烯 1.0 (13)抗壞血酸葡萄糖苷 2.0 (14)生育酚醋酸酯 0.3 (15)維生素A乙酸酯 0.1 (16)香料 適量 (17)離子交換水 殘餘 (製法） 將（1)〜(6)、（11)、（12)、（14)〜(16)均一分散以調製油相 1297273 ----------------- (請先閱讀背面之注意事項再填寫本頁) --線- 部分。另一方面，另外將(7)〜(10)、（13)加入（17)中混合， 並於90°C加溫溶解，冷卻固化後，以分散混合器粉碎爲平 均粒徑60μπι之微凝膠(水相部分）。將此水相部分(微凝膠) 一面徐徐添加至前述油相部分，一面以分散混合器分散以 得到防曬遮光劑。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 1297273 B7 五 、發明説明（V^ [發明之效果] 如以上所詳述’依本發明可提供油中水型乳化組成物 及使用該乳化組成物之乳化化粧料，其呈現良好之乳化狀 態，且不會因溫度或時間而變化，有良好安定性，且，無 黏腻感，具有淸爽之使用感。 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂.· 丨線· 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）Water phase part 1 Water phase part 2 Water phase part 3 Water phase part 4 Water phase part 5 Acacia 2.0 0.5 0.05 Heterocarboxy vinyl polymer - • 0.6 (inter) oxalate _ 雠 1.0 Glycerin 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 5.0 5.0 5.0 Noodle --- Dibutylene glycol / • 5.0 5.0 Methylparaben. Appropriate amount of appropriate amount of "Equivalent amount of TEA • - 雠 Appropriate amount - Ion exchange water residual residual residual residual water Phase preparation method pulverization (microgel) pulverization (microgel) pulverization® gel) mixing and mixing "Sf" viscosity (mPa · s / 25 ° C) 80,000 2,500 500 80,000 2,000 J (Example 1~ 4) As shown in the following Table 2, (1) is added and uniformly dispersed in the oil phase portion which has been mixed (2) to (5), and then the aqueous phase portion of (6) or (7) is gradually added and dispersed. The mixer was uniformly emulsified and dispersed to obtain a water-in-oil emulsified composition. Further, in Table 2, "organic modified clay mineral n" was used as "Benton 38" (manufactured by International Reid). Each sample obtained in each of Examples 1 to 4 was evaluated for its sturdiness (smoothness, moist feeling, sticky feeling), emulsifiability, and stability in accordance with the above test methods and evaluation criteria. The results are shown in Table 2. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1297273 A7 _____B7 " 7\ V. Inventive Note (f) [Table 2] Example 1 Example 2 Example 3 Example 4 (1) Organic Modified Clay Minerals (*) 2.0 2.0 2.0 2.0 (2) Dimethyl Sand Oil Polyol 3.0 3.0 3.0 3.0 (3) Decamethylcyclopentaoxane 20.0 10.0 20.0 10.0 (4) Dimethylpolysiloxane viscosity ( 6mPa · s/25°C) 5.0 - 5.0 5.0 (5) Caprylic acid vinegar 5.0 - 5.0 5.0 (6) Water phase part 1 65.0 85.0 - •- (7) Water phase part 2 - - 65.0 85.0 Smooth feeling of use ◎ ◎ ◎ ◎ Moisturizing ◎ ◎ 〇 ◎ sticky feeling ◎ ◎ ◎ ◎ Emulsifying property / 〇〇〇〇 stability after storage (save 30 曰) o °c 〇〇〇〇 room temperature 〇〇〇〇 37 〇 C 〇〇〇 〇50°C 〇〇〇〇(Please read the notes on the back and fill out this page) —Line - (Comparative Examples 1 to 4, Example 5) As shown in Table 3 below, in the mixed (2) ~ (5 (1) Add and evenly disperse in the oil phase portion, and then slowly add the water phase portion of either (6) to (1〇) and use a dispersing mixer The emulsion is uniformly emulsified to obtain an aqueous emulsified composition in oil. In addition, in Table 3, "Organic Denatured Clay Minerals (+)" used "Petton 38" (International Reed). Each of the samples obtained in Comparative Examples 1 to 4 and Example 5 was evaluated for usability (smoothness, moist feeling, sticky feeling), emulsifying property, and stability according to the evaluation criteria based on the evaluation method. The results are shown in Table 3. ; ___ 1Q —_— __ This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1297273 A7 B7 V. Inventive Note ((Γ) [Table 3] Comparative Example 1 Comparative Example 2 Example 5 Comparative Example 3 Comparative Example 4 (1) Organically modified clay minerals 2.0 2.0 2.0 2.0 2.0 (2) Dimethyl political oil polyol 1.0 1.0 3.0 3.0 3.0 (3) Decamethylcyclopentaoxane 5.0 5.0 20.0 20.0 20.0 (4) Dimethylpolysiloxane viscosity (6 mPa · s / 25 ° C) - 5.0 5.0 5.0 (5) Cetyl octanoate - - 5,0 5.0 5.0 (6) Aqueous phase 1 92.0 - • - - (7) Water Phase 2 - 92.0 - - - (8) Water phase 3 - A 65.0 - (9) Water phase 4 - - - 65.0 - (10) Water phase 5 - - - - 65.0 Smooth sensation 〇〇 〇〇 〇〇 Wetting 〇〇 △ Δ Δ sticky feeling Δ Δ 〇 XX emulsification just after manufacture Δ Δ 〇 Δ 〇 stability (save 30 曰) o °c Δ Δ 〇 Δ Δ room temperature Δ Δ 〇 Δ Δ 37〇C Δ X 〇X Δ 50°CXX 〇X Δ (Please read the notes on the back and fill out this page) . --Line · (Example 6: Moisturizing Cream) (Ingredients) Organic Modified Clay Minerals ("Petton 38" (International Rhodes Co., Ltd.)) (2) Diglyceryl diisostearic acid (3) Decylcyclopentanoxane 70 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (weight %) 2.0 1.0 10.0 1297273 A7 B7 a V. Description of invention (L) (4) Vaseline 5.0 (5) Squalane 15.0 (6) Acacia 1.0 (7) Dipropylene glycol 5.0 (8) Methylparaben 0.2 (9) arginine 0.1 (10) magnesium ascorbyl phosphate 2.0 (11) vitamin A 0.1 (12) the right amount of spices (13) ion exchange water residue (please read the back of the note before you fill out this page) loading ·. ) Line · Mix (4), (5), (11), (12) with warmth at 50 °C, then add (1) for uniform dispersion (oil phase). On the other hand, (6) ~ ( 10) Adding to (13), dissolving at 90 ° C, cooling and solidifying, and then pulverizing into a microgel (aqueous phase portion) having an average particle diameter of ΙΟΟμηη by a dispersing mixer. The aqueous phase portion (microgel) One side is slowly added to the aforementioned oil phase portion, and one side is dispersed by a dispersing mixer to obtain a moisturizing cream. (Example 7: sunscreen cream) (combination component) (% by weight) (1) Organically modified clay mineral 2.0 ("Petton 38" (International Reed)) (2) Dimethyl eucalyptus polyol 2.0 - ----21-- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) A7 B7 Description of invention (〆) (3) Decamethylcyclopentaoxane 10.0 (4) Top A Base oxime oxime 5.0 (5) Hydrophobized titanium oxide 5.0 (6) Octyl methoxy cinnamate 10.0 (7) Amaranth 1.5 (8) L-spermine hydrochloride 1.0 (9) 1,3-butanediol 5.0 (10) methylparaben 0.2 (11) months see early oil 0.3 (12) globular polyethylene 1.0 (13) ascorbyl glucoside 2.0 (14) tocopheryl acetate 0.3 ( 15) Vitamin A acetate 0.1 (16) Proper amount of flavor (17) Ion exchange water residue (preparation method) Disperse (1) to (6), (11), (12), (14) to (16) uniformly Modulation of oil phase 1297273 ----------------- (Please read the notes on the back and fill out this page) -- Line - section. On the other hand, (7) to (10), (13) are added to (17) and mixed, and dissolved at 90 ° C, cooled and solidified, and then pulverized into a microcoagulation having an average particle diameter of 60 μm by a dispersing mixer. Glue (water phase part). This aqueous phase portion (microgel) was gradually added to the aforementioned oil phase portion, and dispersed in a dispersing mixer to obtain a sunscreen sunscreen. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). A7 1297273 B7 V. Invention Description (V^ [Effects of the Invention] As described above, water emulsification in oil can be provided according to the present invention. The composition and the emulsified cosmetic using the emulsified composition exhibit a good emulsified state, do not change due to temperature or time, have good stability, and have no sticky feeling, and have a feeling of use. --- (Please read the note on the back and fill out this page) Order.· 丨 Line · This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm)