TWI296633B - Supramolecular structures and method for forming the same - Google Patents

Description

1296633 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to the fact that a super-deformation formed by a kind of 韶 关于 关于 一种 一种 关于 , , , , , , , , , , , , The researchers gathered & Γ 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 After that, by (t^plate), it becomes the pole for manufacturing optoelectronic devices (such as solar cells) and the potential "sounds to the 11* for the two sexes, it can also play the interface" ίίί if The development potential of the nanostructures, by making a large number of the same non-meter-like structure, can provide sufficient basic design and manufacture the next world. In view of this, it is still necessary to synthesize new amphiphilic light-weight molecules. It has uniform Ik size, good stability, high photoelectric efficiency and a simpler process to meet the needs of the industry.卞,,, 口口 [Summary of the Invention] 1296633 In view of the above-mentioned background of the invention, Yin and the structure provide the requirements of the -____ recording, the method of forming the present invention. ._ a total of molecules of the molecule of the supramolecular knot, t, J g bond #, a hydrophilic segment of the disk, a domain of the ancient Ab, the above-mentioned hydrophobic coplanar section has at least two Lu Lun, the segment ?i i hydrophobic shared segment and hydrophilic segment =. The position of the pound is formed by a twist in the same curve by the turning structure so that the two sexes can form a primary supramolecular structure with a circular disc shape, and another purpose of the moon is to a metal _, an inorganic ^ turn and a gel (5) _Gel) and the above two ^ ϋ '纟t structure ' and the two-dimensional super ^ ^ ^ direct sub-construction, the size of the secondary supramolecular structure "primary super according to the above For the purpose of the present invention, the present invention discloses a supramolecular structure which is an annular disc structure, and the two if is 1〇11111 to 6011111. In addition, the present invention also discloses a metal or inorganic salt sol and gel and amphoteric The total number of vehicles is “formed as a knife Μ冓, which is also an annular disk structure. The diameter is approximately lake (10) to 3 〇〇. [Embodiment] The direction of the invention discussed herein is 1296633 by amphoteric conjugated molecules. It will be presented in the following description of the towel. In order to understand the special features of this exercise, the artisan in the field of organic synthesis is not familiar with the well-known group reduction process. To avoid making the invention unnecessary Restrictions. The present invention will be described in detail below, but in addition to the detailed description, the present invention may be widely practiced in other embodiments, and the scope of the present invention is not limited, and the scope of the following patents is quasi.

A first embodiment of the present invention discloses an amphoteric conjugated molecule comprising a hydrophobic conjugated segment, a hydrophilic segment and a linking functional group, wherein 'the hydrophobic shared bond segment has at least two aromatic ring structures , which further includes one of the following families or any combination thereof: '

t 7 1296633

Ring-shaped filament, if ## or any combination thereof: hydrogen atom, silk, alkoxy group, di-aGs1 cleavage group and heterocyclic group; 乂 and ¥ may be the same or different, and the series $ s^n'^ contains the following Among the groups - ^ -S^.NS ^ .CS^S^. .CS^CS^^-CS^ ; PM,;;henyl group, Ar is an aromatic group. In addition, "the formation of a joint: a twist between the hydrophobic conjugated segment and the hydrophilic segment. In the present embodiment, the above-mentioned hydrophilic segment further comprises one of the following groups or a combination thereof :polyethylene glyed;) methyl ether, a copolymer of ethylene oxje and propylene 〇xide, and a polymer having a hydroxyl group or an amine group in the main chain. Further, the above-mentioned linking functional group further includes one of the following groups (wherein R is Alkyl): ~CH? 0 II -S--CRr, 〇 In another preferred embodiment of the present embodiment, the preferred chemical formula of the amphiphilic molecule is as follows: -ch2ch2o-s

Ch3〇-{ch2ch2〇)-c wherein, mgl, n^l, R are alkyl groups, aromatic groups and heterocyclic groups

Example 1 provides an amphoteric conjugated molecule with the following chemical formula (abbreviation j 1296633 - peo17-opv3):

Ch3o{ch2ch2o)^-ch2ch2o~s wherein the PEO segment has hydrophilic properties and the 〇pv segment has hydrophobic properties. Referring to the first figure, there is no resonance peak of 5=6 5~68{){)'111 on the nuclear magnetic resonance spectrum, so it can be inferred that the PPV trimer has a coplanar cis bond Om^linkage ). In addition, the second figure simulates the 3D structure of pE〇lr〇pV3 by Cerius 2 Energy Minimization. It can be found that the length of the 〇pv segment is about 2 nm, 〇·5 rnn is wide, and the length of the PEO segment is about 6 nm. On the other hand, the most notable part is due to the fact that the sulfonic acid group has a tetrahedral shape, with the above-mentioned 〇pv segment having a flat = and a common structure, and relative to the soft pE 〇 segment In other words, the ppV segmentation ^ is relatively rigid. Thus, the sulfonic acid group in the amphoteric conjugated molecule forms a twist between the PEO segment and the 〇pv segment. The second embodiment discloses a method for forming an amphoteric molecule. First, a first starting material is provided, which has the general formula as follows, and R1 is an alkyl group, and X1 is a group VIIA element. f times, a first substitution reaction is carried out on the first starting material to form a first olefinated product, the general formula of which is as follows:

f is the second starting material, wherein the general formula of the second starting material is as follows, "X is a group VIIA element, and the reactivity of X3 is greater than X2. Ο x2'l\_jcu^3 ο Ν^' The second starting material is subjected to a second substitution reaction with the first olefinated product to obtain a first alkylated product of 7%, and the general formula is as follows: 1296633

Hunting is carried out by P〇iy(ethyiene giycol) methyl ether with a second-acetation reaction, then a fine molecule, wherein the above two are catalyzed by pyridine. The general formula of the above-mentioned amphiphilic molecules is as follows: ch3o{ch2ch2o)^-ch2ch2o-s

A third embodiment of the present invention discloses a method for forming an amphoteric molecule. First, a first starting material is provided. The general formula is as follows, and R1 is alkane and χ1 is a Group VIIA element. The alumina r1O~C^X1 undergoes a first scalification reaction with a first starting material by a first acid salt P(〇R2)3 to form a first intermediate, the general formula of which is as follows, and the R2 system Laugh

R2 is subjected to a first olefination reaction by a Lewis base, a compound of the disk and the first intermediate to form a first olefination product, wherein the Lewis test of the upper & Ί-butoxide U-BuOK). The general formulas of the above-mentioned compound and the first alkylated product are as follows, and R3 is a burnt group, and R1, r2 and R3 may be the same or different. Soil,

0

(R30) 2HC

II

CH R1 provides a second starting material, wherein the general formula of the second starting material is as follows, χ2 and χ3 are elements of group VIIA, and X3 is more reactive than X2. ” 1296633

A second scalar reaction is carried out by a second phosphate P(R4)3 with a second starting material to form a second intermediate having the general formula as follows and R4 is an alkyl group.

A second olefination reaction is carried out by an intermediate, a second intermediate, and a Lewis base to form a second olefination product, which is generally as follows. The above-mentioned Lewis base further contains potassium rbutoxide (>BuOK).

The esterification reaction is carried out by a second olefination product with p〇ly (ethylene glyc〇1) to form an amphiphilic molecule, wherein the esterification reaction is catalyzed by pyridine, and the general formula of the above amphiphilic molecule is as follows And i.

a· Dib^yl(4_tert_butylphenyl)methylphosphonate ^ Refer to the scheme below for 2 mL (10 mmol) of l4ert-butyl_4_(chloromethyl)benzene and 8 g (30 mmol) of tributy^ phosphate in a reaction tank, followed by magnet stirring It. Next, the mixture was heated to 160 ° C under a nitrogen atmosphere, stirring was continued and the mixture was heated under reflux for 12 hours. After cooling the reaction to room temperature, the reaction was heated to 2 ° C, and a vacuum concentration procedure was performed to remove the remaining tributyl phosphate, thereby forming a yellow oily product (without further purification). The rate is 80 〇 / 〇. 1296633 !H NMR (500 MHz, CDC13): δ /ppm: 7.08-7.32 (m9 4H)9 3.99 (t9 4H), 3.77 (m, 2H), 1.57 (m, 4H), 1.45 (m, 4H), 1·34 (s,9H),0·91 (t,6H)· b· 4-(4-tert-butylstyryl)benzaldehyde 2 was synthesized as 3.44 g (16 mmol) '(diethoxymethyl) benzaldehyde with 4.8 g (14 mmol) product 1, which was placed in a reaction tank containing 30 mL of THF' and stirred with a magnet. Next, a potassium hbutoxide solution (1.8 g of potassium i-butoxide dissolved in 60 mL of THF) was added dropwise to the reaction vessel. Next, the mixture was continuously stirred under a nitrogen atmosphere at room temperature for 18 hours. Then, 5 〇 mL of 37.5 % HCl was added to the mixture and stirring was continued for 3 hours. After completion of the reaction, the reactant was placed in 5 mL of ethanol water/cold solution (1:1 by volume) to form a yellow crude product precipitate. The crude product is then subjected to multiple filtration and washing procedures by water and ethanol. Finally, the filtered crude product was dissolved in dichlorohydrazine/ethanol and subjected to a recrystallization procedure to form a high-purity yellow solid in a yield of 70%. 4 NMR (500 MHz, CDC13)··PPm·· 9·97 (s,1H),7·84 (d,2H), 7·62 (d,2Η),7·47 (d, condition), 7·40 (d, 2Η), 7·23 (d'lH), 7·1〇(d,1Η), 1.33(s,9H). c· Dibutyl (4-sulfonyl chloride_pheny) Synthesis of methyl-phosphone 3 1 g (3·7 mmol) of 4_(bromo_methyl) benzene-l-sulfonyl chloride and 3 g (12 mmol) of tributyl phosphate were placed in a reaction tank and stirred with a magnet. Next, the mixture was heated to 160 ° C under a nitrogen atmosphere, and the mixture was continuously stirred and heated to reflux for 12 hours. After cooling the reaction to room temperature, the reaction was heated to 200 ° C and concentrated under reduced pressure to remove the remaining tributyl 1296633 phosphate ', whereby a brown oily product was formed (without further purification). It is 90%. lH NMR (500 MHz, CDC13): ά/ppm: 7.03-7.40 (m? 4H)5 4.〇〇(m,4H),3·03 (m,2H),1.61 (m,4H),1.59 ( m,4H),0.89 (t,6H)· d.OPV dimer with tert_butyl and sulfonyl chloride groups 4 at the end. 〇25 g (1·9 mmol) aldehyde 2 and 0·5 g ( 2·5 mmol) phosphonate3, both were placed in a reaction tank containing 3 mL of THF and mixed with a magnet tax. Next, a p〇tassium solution (0·34 g potassium rbutoxide dissolved in 50 mL of THF) was added dropwise. Next, the mixture was continuously stirred under a nitrogen atmosphere at room temperature for 18 hours. Then, 20 mL of 37.5 % HCl was added to the mixture and stirring was continued for 3 hours. After the reaction was completed, the reactant was placed in a 500 mL aqueous ethanol solution (1:1 by volume) to form a dark yellow crude product precipitate. The crude product is then subjected to multiple filtration and washing procedures by water and ethanol. Finally, the filtered crude product was dissolved in chloroform and subjected to a recrystallization procedure to form a dark brown solid with a yield of 65%. lR NMR (500 MHz, CDC13): 5/ppm: 8.15 (d5 2H)5 7.59 (d5 2H)? 7.43 (d, 2H), 7.38 (d, 2H), 7.21 (m, 4H), 7·11 ( d,4H), L31 (s, 9H). The synthesis of e. PE017-0PV3 5 takes 0·3 g (0.4 mmol) p〇ly(ethylene glycol) methyl ether (Mw=750 g/mol) and 0.22 g (0.5 mmol) OPV trimer 4, both were placed in a reaction vessel containing 150 mL of dry-treated chlorinated benzene, and stirred with a magnet under a nitrogen atmosphere. Pyridine (1 g in 20 mL dry 1296633 dichloromethane) was dropped into the reaction tank. Next, the mixture was continuously mixed for 36 hours at room temperature. After the completion of the reaction, it was recrystallized by 50 mL of water, and then the reaction mixture was applied three times, and then dried over magnesium sulfate. The <solvent' was removed by a vacuum drying procedure to afford a crude product as a black viscous oil. The crude product is further purified by chromatography; the column is subjected to purification treatment, and the extract is ethyl acetate. Finally, the yield of the purified product as a pale yellow oil was obtained. H NMR (500 MHz, CDC13): ά/ppm: 7.05-8.05 (m5 16H)? 3.61 (m,68H),3·33 (s,3H),1·33 (s,9H).

Pyridine / CH2C12 j CH30 female CH2CH2〇)y^CH2CH2OH ch3o{ch2ch2o: 16

Scheme 1 A fourth embodiment of the present invention discloses a supramolecular structure having an annular disk shape 1296633 jring-like, which comprises a bisexual mound molecule, and further comprises a 7C_e_gated segment and a hydrophilic chain. Domain-connecting functional group, wherein the selection of the above household is the same as that of the first embodiment, and the above-mentioned ί ί 职 疏水 疏水 疏水 录 录 疏水 疏水 疏水 疏水 疏水 疏水 疏水 疏水 疏水 疏水 疏水 。 。 。 。 。 。 。 。 。 。 \1External transition (twlst) in the hydrophobic common segment and the hydrophilic chain = learning = in the preferred embodiment of this embodiment, two molecules

〇^3〇*{〇12〇12〇)^〇12〇12〇| 2古=!_’ ‘R is a silk, an aromatic group and a heterocyclic group. The diameter of the m-tree smudged is about 丄 u nm main 60 nm 〇

Example 3 is abbreviated as 咖二Ρ;) has the following chemical formulas (4)^

The CH3°'(CH2CH2〇)i?CH2CH2〇-| bond segment has hydrophilic properties and the 0PV segment has hydrophobic properties. The reference 'pe〇17_opv3 can also be regarded as having a rod-rolled cymbal (1Od_cx) il mGleeule) 'self-assembled into a supramolecular knot; ^' PE〇lr〇PV3 has an amphoteric nature and a rod-curled form The same (four) color. It is speculated that the shape of the supramolecular structure having a cyclic acid shape is 妓/a^下丄? £:〇17""01^3 forms a twist in the hydrophobic, between the segment and the hydrophilic segment, the PEQ17_QPV3 can be rπ-stacked with the same curvature (CUmtUre); b · There is a high interfacial tension between the hydrophilic base 296633 material (for example, mica) and the hydrophobic 〇ρν segment, and PE〇17_OPV3 is V-induced in order to reduce the interface area; Γ-7Γ stacked area Tilt, horizontally and vertically arranged to bend. Eight; ίί: A fifth embodiment discloses a super-sub, ,, The domain method of the first cypress, the first symbiotic seed in the -, - bisexual solution, wherein the composition of the solvent comprises water and sulphur (tetmhydrofuran; THF), and the volume ratio of the two is about = = a total of The concentration of the amphiphilic molecules of the molecular solution towel is greater than W_5 Μ. The enthalpy drop procedure is to deposit and deposit the above-mentioned two-sex co-molecular solution on the - parent material, and the hydrophilicity is in a horizontal position. New, a static ft is performed to make the two-sex co-molecular molecules in the solution of the amphiphilic co-molecules, wherein the above-mentioned standing procedure takes more than 36 hours. In addition, the two-two-sex co-molecule solution silk program, in addition to the job removal method = ί on the two sexes, listen to the level of Wei heterobase. J ί于社? (10) The super-molecular telluride of the secret tree-shaped disc. The above-mentioned amphoteric co-molecular molecules further comprise two 2========================================================================== _ human, between the above metal oxide or a hydrophilic chain of a non-chain conjugated molecule, wherein the metal element and the non-metal element in the upper part further comprise the following family, .Li, Na, Κ, Rb, Cr, Cu, Er, Fe, Ta, v, Zn, Zr, r Ba, Tl, Te, and Pb. A1, Si, Ge, Sn 1296633 The functional group of the two groups, in the example, the general formula of the two-sex vehicle is as follows: ☆ one of the practical ones is better CH3〇{cH2CH2〇);;rCH2CH2〇-|-

Example 4 Ship 17 〇 ^) has the following chemical formula two molecules # (abbreviated as

The thickness of the PE0lr0PV3/Silica hybrid supramolecule is approximately equal to the width of the coplanar OPV segment (see the second figure). This phenomenon indicates that the ^Ε〇17-〇Ρν3 molecule plays a similar template role in the formation of PEOn-OPWSilica hybrid supramolecules. A seventh embodiment of the present invention discloses a method for forming a super-substructure having an annular disk shape, first mixing a metal alkoxide or a non-metal alkoxide, ethanol, water and hydrochloric acid to form a salt precursor solution. Wherein the pH of the above-mentioned f-type precursor solution ranges from about 2 to 4. Next, a suspension of two sex = yoke 1296633 is formed to form a solution of amphoteric co-molecules, wherein the above solvent is more (tetrahydrofuran; THF). Next, the salt precursor is dissolved in the second = conjugated molecular solution to form a mixed solution, and then the mixture is heated to a temperature of about thief to 9 G t, preferably at a temperature of 6 (TC heating for 90 minutes. 2. In the embodiment, after the heating process is completed, adding ethanol and water to the first group to prepare the first one release procedure and forming a product solution, wherein, each ugly vehicle乂5 ratio, alkoxide or non-metal alkoxide: Solvent: water: hydrochloric acid: two dioxin?: alcohol = 1. 〇: 77 : 69 : 〇.13 : 0.19 : 51H owes, solvent and water to carry out a The second dilution procedure is carried out, and the formation is: Γ Γ 广, Γ Γ Γ Γ Γ Γ 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四 第四Interaction, (4) The soil if the private order is greater than 36 hours. Then, carry out - remove the charm = J ^ class, the threat is greater than (10) t, the financial line is the lower line of the temperature of the whole or inorganic salt sol and gel (SOK }el),1中ΐ心 Ba, rTtct"f, K, Rb, Cs, Be,, ca,

Al>Si>Ge^Sn^Pb;(U2) numerator, the above two ugliness ugly eight / / ~, () one or two common vehicles ^ : i; ^ re (" conjugated) segment, hydrophilic segment and connected above The hydrophobic conjugated chain 戦 "base 4 is the same as the brother - in addition to the embodiment. In addition, 1296633 = butterfly segment, and on

It is the same as the disk of the hydrophilic ship's f Compared with silk, the two molecules of the two molecules are as follows: CH3°*(CH2CH2〇)irCH2CH2〇-s- where 'R#weiji, keji and heterocyclic groups. Ma?? Really cleansing towel, this (4) - the purpose is to provide a = base, r, the above-mentioned hydrophobic wire = two connection functional groups respectively bonded hydrophobic co-OPV chain substrate 'by hydrophilic substrate and hydrophobic Πΐ The interface tension (infinity), the bisexual ping-pong is in the area, thus causing the bending of the stacking region to form a primary supramolecular structure having a dome-shaped disc shape. The purpose of the machine is to use a metal alcohol. Salt, non-sigma metal alkoxide or Sd_Gel and the above-mentioned amphoteric conjugated molecule to form a graded supramolecular structure' and the diameter of the secondary supramolecular structure depends on the size of the second molecule In the above description, the present invention discloses a knive structure formed by a bisexual co-molecular molecule, the supramolecular structure The invention has a diameter of about i. In addition, the present invention also discloses a super-divided 1296633 substructure formed by a metal alkoxide, a non-Meng private salt or a thermal salt sol and a gel and amphoteric co-molecules. It is also a ring-like disk having a diameter of about 1 〇〇 nm. Obviously, the invention may have many modifications and differences as described in the above embodiments. Therefore, it is necessary to have a force σ. It is to be understood that the invention may be practiced broadly in the embodiments of the invention in addition to the above detailed description. The foregoing is only a preferred embodiment of the invention. The application of the following is the same; any other equivalent modification of the modified version disclosed in the invention shall be included in the following patent application [simplified description] spectrum; the first figure is PE〇 The second picture of 17-〇PV3 amphiphilic Gongyi molecule NMR 氲 is the molecular simulation of ΡΕΟπ-OPV3 amphoteric conjugated molecule

The fourth figure is an atomic force microscope image of the molecular structure of ρεο17 - 0PV3. The second-order super-form formed by the primary super 0PV3 amphoteric conjugated molecule formed by the OPV3 amphoteric conjugated molecule

Claims (1)

1296633 X. Patent Application Scope 1. An amphoteric conjugate molecule comprising: • A hydrophobic conjugated (π-conjugated) segment, wherein the hydrophobic conjugated segment has at least two aromatic ring structures, the hydrophobic conjugated segment comprising any one of the following groups: 1296633 sW further comprises the following groups or any combination thereof: hydrogen atom, alkyl group, alkoxy group, cyclic alkyl group, aryl dough group and heterocyclic group; hydrazine; Ph or different, and scales; It also includes _= combinations in the following groups: 0-, -S-, -NS1-, _CS1S2_, _csl=csL and -cslg are phenyl groups, Ar is an aromatic group; - hydrophilic segment 'this hydrophilic The segment contains one of the following groups - or any combination thereof · · poWethylene glycol) (4) a copolymer of her sinking, e-mail propylene oxide, and a high-member having a hydroxyl group or an amine group in the main chain; a towel, the joint secretary is divided into the hydrophobic co-bond segment and the hydrophilic segment, and the linking functional group forms a twist in the hydrophobic conjugate segment in the amphiphilic molecule Further, between the hydrophilic segments, the linking functional group comprises one of the following groups (wherein the alkyl group is an alkyl group): -S--CHr, _CR2_, ΰ · 2 ·---------- The general formula for conjugated molecules is as follows: Wherein m^l, n^l, and R are a cyclic alkyl group, an acyclic alkyl group, an aromatic group and a heterocyclic group. Ch3o{ch2ch2o)^-ch2ch2o~s 0 3·- a method for forming an amphiphilic molecule, the method for forming the amphiphilic molecule comprises: providing a first starting material, wherein the general formula of the first starting material is as follows, and I296633 R1 Is an alkyl group, X1 is a group VIIA element; a first substitution reaction is performed on the first starting material to form a first olefination product, wherein the general formula of the first olefination product is as follows: a second starting material, wherein the general formula of the second starting material is as follows, the parent and the X system are elements of the VIIA group, and the reactivity of X3 is greater than X2; ο /=χ χ2^ V/^CH2X3 The starting material and the first thinned product undergo a second substitution reaction to form a second alkylated product in %, and the general formula of the second alkylated product is as follows; The amphiphilic molecule is formed by performing an esterification reaction with the second alkylated product by poly(ethylene glycol) methyl ether, wherein the amphiphilic molecule has the general formula as follows, and m-1. 4. The method for forming an amphoteric molecule according to claim 3, wherein the esterification reaction is catalyzed by a pyridine. 5. - a molecular structure having a singularity of the singularity of the singularity of the singularity of the singularity of the singularity of the singularity of the singularity of the singularity of the singularity The forming of the transition structure is such that the amphoteric co-molecular molecule is π-π(tetra)(10) in a phase-like alcohol (clear surface) to a primary supramolecular structure having a shape of a cloth-shaped disc. 6. The primary supramolecular structure having the shape of a circular disk as described in claim 5, wherein the primary supramolecular structure having the % <form disk shape described above has a diameter of about 10 nm to 60 nm. 7. As defined in the fifth paragraph of the patent application, the primary supramolecular, and the mouth structure having a %-shaped disc shape, wherein the chemical formula of the above-mentioned amphoteric conjugated molecule is as follows: Performing a sedimentation procedure to deposit and deposit the amphoteric co-molecule solution on a hydrophilic hydrazine substrate and maintaining the hydrophilic substrate in a horizontal position; and performing a hydrazine-station procedure to cause the two sexes in the amphoteric co-light molecule solution The yoke molecules interact; /, the enthalpy-removal procedure to remove the amphoteric co-light molecular solution 296633 solution on the hydrophilic substrate, and maintain the hydrophilic substrate in a horizontal position; and perform thermal annealing And forming a primary supramolecular structure having the shape of an annular disk on the hydrophilic substrate. 9. The method for forming a primary supramolecular structure having a ring shape as described in the eighth item, wherein the composition of the solvent comprises water and tetrahydrofuran (THF) and both The volume ratio is approximately work. The primary supramolecule having a ring-shaped disc, as described in item 8 of the patent scope of Guarshen 4, . The method for forming a structure, wherein the concentration of the amphoteric conjugated molecule in the amphoteric conjugated molecule solution is greater than 1 〇·5 Μ. U. For example, the method for forming a primary supramolecule having a ring-shaped disk shape as described in Item 8 and the method for forming a mouth structure is more than 36 hours. The primary supramolecules having the shape of a circular disk as described in item 8 of the patent scope of claim 4, . The formation method of the structure, wherein the temperature of the above heating annealing process is greater than 1 Torr. Hey. 13. The method for forming a primary supramolecular structure having the shape of a ring disk as described in claim 8, wherein the heating procedure has a degree of vacuum lower than 1 (T3t〇rr. 14) an annular disk shape a secondary supramolecular structure, which is obtained by translating the first member of the amphoteric co-ordination as described in the patent application, based on the transition structure formed in the amphiphilic molecule, so that the gender is co-consumed The molecules are η-stacked with the same curvature (π-shirt also (4), and borrowed = added - metal oxide or non-metal oxide, so that the metal oxide or non-earth oxide is transparent to the two sexes The polar interaction between the hydrophilic chains of the molecules, 5 1296633 forms the secondary supramolecular structure having the shape of an annular disk, wherein the metal oxide or non-metal oxide is located between the hydrophilic segments of the amphoteric conjugated molecule 15. The formulation for forming a secondary supramolecule having the shape of an annular disk as described in claim 14, wherein the metal oxide and the metal oxide in the non-metal oxide are The non-metallic element further comprises one of the following groups: Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Ti, several, Cr, Cu, segment, R, office, V, Zn, Zr, P, B, w, Si, Ge, Sn, and pb. 16. The secondary supramolecular structure having an annular disk shape as described in claim 14, wherein the above has the shape of a circular disk The diameter of the supramolecular structure is about 100 nm to 300 nm. 17. The secondary supramolecular structure having the shape of a circular disc as described in the 14th patent of the Japanese Patent Application, the chemical formula of the above-mentioned two-sex composite molecule is as follows ·· The metal oxide or non-metal oxide is a dioxide chopped, and the secondary supramolecular structure having an annular disk shape has a diameter of about 15 Gnm and a thickness of about _ feet. CH3〇{cH2CH2〇)^CH2CH2〇--S is a method for forming a secondary supramolecular structure having an annular disk shape as described in claim 14 of the patent scope, which comprises: ethanol, water and hydrochloric acid to form Mixing a metal alkoxide or a non-metal alkoxide precursor solution with a salt; suspending the amphiphilic molecule in a / granule to form an amphoteric conjugate molecule 6 1296633 solution; mixing the salt precursor solution with the salt Amphoteric solution; a common cholesteric solution to form a mixture of the mixed solution - heating procedure; and formation - production:: alcohol and water in the mixed solution - the first - dilute solution of the combined product solution, utilization Solvent and water are used to form a coating solution; a dilute private order 'sub-comprising a t-coating procedure to coat the coating solution on a hydrophilic substrate, and to maintain 4 hydrophilic substrates Horizontal position; advancement - static material 'to make _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ; with the eight-inlet heating annealing process, the fine forming material has a circular circle Pie shaped of two super sub-structure on the hydrophilic substrate. The method of the second-order super-distribution of the annular disk shape described in Item No. I8 of the month is as follows: the circumference of the towel-like fine precursor solution is about 2 to 4. The method of forming a second-order supramolecule having a ring-shaped disc shape as described in Item 8 of the patent, wherein the above solvent further comprises tetrahydrofuran 7 1296633 (tetrahydrofuran; THF). The method for forming a secondary supramolecular L structure having an annular disk shape, wherein the heating process has a temperature range of about 4 Torr to 90 ° C. 22. As described in claim 18 The method for forming a secondary supramolecular structure having a ring-shaped disc, wherein the molar ratio of each component in the product solution is a metal alkoxide or a non-metal alkoxide: solvent: water: hydrochloric acid: amphoteric conjugate molecule: ethanol = 1·0 : 77 : 69 : 0·13 ·· 0.19 : 51.9. 23. A method for forming a secondary supramolecular structure having a ring-shaped disc shape as described in the patent application scope f 18, wherein the above coating is used The composition volume ratio of the solution is the fourth solution: the first solvent··water=1:3··6. 24. The formation of the secondary supramolecular structure having the shape of a circular disk as described in claim 18 of the patent scope of the application Method, wherein the above static standing The order is greater than 36 hours. 25. The method for forming a secondary supramolecular structure having an annular disk shape as described in claim 18, wherein the temperature of the above heating annealing process is greater than l〇0〇c. The method for forming a two-stage supramolecular structure having an annular disk shape as described in Item 18 of the patent, wherein the heating annealing process has a vacuum of less than 1〇3 torr.