1293075 九、發明說明： 【發明所屬之技術領域】 本發明係有關於-種油性磁流體之製備方法，其尤指—種油性磁流體 可吸附流體中之有機物質、油性物質及金屬離子，再藉由外加磁場的作用， 使其自流體中分離’而達到處理或淨化之為用者。 【先前技術】 按’磁性物質在過去已被廣泛使躲錄音帶、磁碟、磁帶等雜記憶材 • 料的製備及油墨與油漆、塗料等建材，及電磁開關、軸封等麵用途上。 近年來由紐學家在製備方法的獨靖，許乡_應⑽域亦逐漸發展 出來’例如藥品、蛋白質、眶的純化等生物醫學應用及環境廢棄物的處理， 如美國專利US 4, 687, 748 (1987)揭示利用將磁性顆粒混合於極性的碳水化 錄溶液巾，製成雜小於誦nm雜崎，可制於細_分離、純化 等。此種利用磁性分離的技術針對所欲處理的物質特性可分成二種型式， ⑴利用外加磁場分離本身具有磁性的物f，⑵將不具磁性的㈣先與磁 性材料反紐結合-起，再顧外加磁場進行錄。其巾為使非磁性物質 能有效與磁性材料結合，不同磁性材料的種類與製備方式將扮演極重要的 | 關鍵角色。 有關磁性物質’根據應用對象及需求不同會有不同的製備方法，最常 見為⑴機械研磨方式’例如美國專利us 4 6H 222 (娜)揭示利用混合 有機載體’如甘醇(glyC〇1)、醋(ester)，磁性粒子及陽離子界面活性劑等 ，質進行機雖研雜成離频，·改善計算機_設計的電導性及 在封效果，⑵氧化反應方式，例如美國專利us 614〇 〇〇1 (纖)揭示使 用亞鐵溶液（ferr〇us s〇luti〇n)與璘酸鹽化合物如鱗酸納（磁⑽ 咐h〇Ph〇sphate)及鹼性氫氧化物反應生成氫氧化鐵⑻，再通入氧氣進行 氧化反應’使生成鐵氧磁性粉體。及⑶化學共沉法，例如美國專利咫 6, 743’ 371 (2GG4)揭示彻雜鐵粉如轉及鱗等鐵氧化合物與金、銀、 1293075 銅！呂石墨等導電性粒子混合製成磁性流體應用於電磁間開關。由於磁 I*生粒子本身會互相吸引而聚集，因此在製備過程中需進行顆粒的表面處 理，使顆粒間能有效隔離，則可得粒徑較小之粉體，如此亦較容易分散於 溶劑中成流體狀態。同時為使製備完成的油性磁流體具有親油或親水的特 性’通常表面處理的方式會不一樣。 針對油性油性磁流體的製備，美國專利us 5，124，麵⑽2)亦揭示 使用低彿點有機溶劑加入含有親水基之有機分散劑中，使磁性顆粒分散於 其中，再_蒸發方式將低沸點有機溶劑去除，如此製得油性磁流體可應 驗真錄器之密封設計。又如美國專利US 6, G68, 785 (2GGG)揭示直接混 合 a-Fe2〇3 粉體、油（Ampro Typen〇il)和界面活性劑（p〇iy〇iefin a_Hde)形成泥漿狀，再_研射式製成雜磁趣。由於直接使用 磁性顆粒進行機械式研磨，使油與界面活性_著漏性顆粒表面上，因 此彼此間結合力較小，表面結合物質可能會有容易脫落之虞，使用效率亦 可能受影响。 磁性流體在-般民生X業上，常應用於磁性記憶材料、機械轴封設計 等，但針對水中浮油或微量有機成分的去除及無機廢水中金屬離子的處理 則較少應用，含有機成分之廢水在過去通常使用熱處理或化學氧化破壞的 φ 方式’不但成本③，需添加化學試劑，會有二次廢水的問題。對於含金屬 離子之廢水，除傳統加藥沉澱處理方式外，亦有制薄膜分離等物理處理 之方式，雖然不必加人化學試劑，但所需設備成本昂貴，^技術需求性較 高。 為使油性磁流體具有親油的界面及與磁性氧化粉體間有強烈的結合 力，本發明利用於製備鐵氧金屬氧化物的過程中加入含幾基官能基的界面 活性劑，使二者同時反應生成表面含缓基官能基的鐵氧磁性物質，再利用 架橋反應與另-製備完成的油性物質反應生成油性磁流體。由於磁性物質 與此化合W乃糊化學反應形成麟，目此具有較強的結合力，穩定性 亦較高。 (§) 6 1293075 【發明内容】 本發明之主要目的，在於提供—齡 物之官能基的架橋作用形成化輸之&備方法，利用化合 人-被，㈣n i _能更有效的與齡物質結 使油性磁流 而達到處理或淨化 。（臟-穩疋的油性磁流體，再藉由外加磁場的作用，1293075 IX. Description of the Invention: [Technical Field] The present invention relates to a method for preparing an oily magnetic fluid, which particularly relates to an oily magnetic fluid capable of adsorbing organic substances, oily substances and metal ions in a fluid, and then By the action of an external magnetic field, it is separated from the fluid to achieve treatment or purification for the user. [Prior Art] According to the 'magnetic material, it has been widely used in the past for the preparation of miscellaneous memory materials such as tapes, magnetic disks, and magnetic tapes, and for building materials such as inks, paints, and paints, and electromagnetic switches and shaft seals. In recent years, the neo-instructor's method of preparation, the Xuxiang_Ying (10) domain has also gradually developed, such as the biomedical applications of pharmaceuticals, proteins, and purines, and the treatment of environmental wastes, such as US 4, 687. , 748 (1987) discloses the use of a carbon hydration recording solution towel in which magnetic particles are mixed in a polar phase to prepare a miscellaneous amount smaller than 诵 nm, which can be prepared for fine separation, purification, and the like. Such a technique utilizing magnetic separation can be divided into two types according to the characteristics of the substance to be treated, (1) separating the magnetic substance f itself by using an external magnetic field, and (2) combining the magnetic material (4) with the magnetic material, and then taking care of it. An external magnetic field is recorded. In order for non-magnetic materials to be effectively combined with magnetic materials, the types and preparation methods of different magnetic materials will play an important role. The related magnetic materials 'have different preparation methods depending on the application object and the demand, and the most common ones are (1) mechanical grinding methods'. For example, the US patent us 4 6H 222 (Na) discloses the use of mixed organic carriers such as glycol (glyC〇1), Ester, magnetic particles and cationic surfactants, etc., although the quality of the machine is mixed into frequency, improve the electrical conductivity of the computer _ design and the sealing effect, (2) oxidation reaction, such as the US patent us 614 〇〇〇 1 (Fiber) reveals the use of a ferrous solution (ferr〇us s〇luti〇n) to react with a phthalate compound such as sodium chlorate (Magnesium (10) 咐h〇Ph〇sphate) and an alkali hydroxide to form iron hydroxide (8) Then, oxygen is introduced to carry out the oxidation reaction to generate ferrite magnetic powder. And (3) chemical co-precipitation method, for example, U.S. Patent No. 6, 743' 371 (2GG4) reveals iron oxides such as iron powder and scales, and gold, silver, and 1293075 copper! Conductive particles such as lum graphite are mixed to form a magnetic fluid for use in an electromagnetic switch. Since the magnetic I* particles themselves are attracted to each other and aggregate, the surface treatment of the particles is required during the preparation process, so that the particles can be effectively separated, and the powder having a smaller particle size can be obtained, so that it is easier to disperse in the solvent. Medium fluid state. At the same time, in order to make the prepared oily magnetic fluid have oleophilic or hydrophilic properties, the surface treatment is usually different. For the preparation of oily oily magnetic fluids, U.S. Patent No. 5,124, No. (10) 2) also discloses the use of a low-point organic solvent in an organic dispersant containing a hydrophilic group to disperse magnetic particles therein, and the evaporation method will lower the boiling point. The organic solvent is removed, and the oily magnetic fluid can be prepared to meet the seal design of the real recorder. Another example is the US patent US 6, G68, 785 (2GGG) which reveals the direct mixing of a-Fe2〇3 powder, oil (Ampro Typen〇il) and surfactant (p〇iy〇iefin a_Hde) to form a slurry. The shooting type is made of magnetic. Since the mechanical grinding is directly performed using the magnetic particles, the oil and the interface are on the surface of the leaking particles, and therefore the bonding force to each other is small, the surface-bound substance may be easily peeled off, and the use efficiency may be affected. Magnetic fluids are commonly used in magnetic memory materials and mechanical shaft seal designs in the same industry. However, the removal of oil or trace organic components in water and the treatment of metal ions in inorganic wastewater are less applicable. In the past, wastewater was usually treated by heat treatment or chemical oxidation. The cost is not only cost 3. It requires chemical reagents and there is a problem with secondary wastewater. For the metal ion-containing wastewater, in addition to the conventional dosing and precipitating treatment method, there is also a physical treatment method such as film separation, and although it is not necessary to add a chemical reagent, the required equipment cost is high, and the technical demand is high. In order to make the oil magnetic fluid have an oleophilic interface and a strong binding force with the magnetic oxidized powder, the present invention utilizes a surfactant containing a certain group of functional groups during the preparation of the ferrite metal oxide, so that the two At the same time, the reaction generates a ferromagnetic substance containing a slow-acting functional group, and then reacts with another oil-based substance to form an oily magnetic fluid by using a bridging reaction. Since the magnetic substance forms a lining with the chemical reaction of this compound, it has a strong binding force and a high stability. (§) 6 1293075 SUMMARY OF THE INVENTION The main object of the present invention is to provide a method for forming and controlling the bridging action of a functional group of a aging body, and using the compound--, (4) n i _ can be more effective The material junction causes oily magnetic current to be treated or purified. (dirty-stable oily magnetic fluid, by the action of an external magnetic field,
之目的 體吸附流體巾之錢物質或金屬離子後自流體中分離 本!x月之人要目的，在於提供_種油性磁流體 流體具有磁性及流體的流動性，與_物:廢水)進行混合時， =有機物質及與金屬離子結合，且與水_互溶。在處理擁中不必添 加催化劑、氧侧及其它任何化學藥品，不但節省處理_，也不需進行 催化獻回收同時侧磁力轴可迅速將此—吸附有機物與金屬離子之 油性磁流體與水相分離，不殘留任何油相物質，操作上非常簡便。 【實施方式】 效為使貝審查委員對本發明之結構特徵及所達成之功效有更進一步 之瞭，與·、識’謹佐以較佳之實施例及配合詳細之說明，說明如後·· I首先’明參照第-圖，其係為本發明之一較佳實施例之油性磁流體之 製備，程圖’·如圖所示，本發明之油性磁流體之製備方法，於步驟S10中， 將雙胺基化合物加入油性物質以獲得雙胺基油性化合物；於步驟S12中， 將羧基化合物加入該雙胺基油性化合物以獲得羧基雙胺基結合油；於步驟 S14中’取鐵離子溶液混合絲化合物以獲得絲磁性鐵氧化合物，·於步驟 S16中’將該羧基雙胺基結合油加入該羧基磁性鐵氧化合物即獲得油性磁流 體，其粒徑範圍約60〜1〇〇奈米。 ‘ 7 ⑻The purpose of the body is to absorb the money or metal ions of the fluid towel and separate it from the fluid! The purpose of the person is to provide the magnetic fluid fluid with magnetic and fluid fluidity, mixed with _ matter: wastewater At the time, = organic matter and combined with metal ions, and water-miscible. It is not necessary to add catalyst, oxygen side and any other chemicals in the process, which not only saves the treatment, but also does not need to carry out catalytic recovery. At the same time, the side magnetic axis can quickly separate the oil-based magnetic fluid adsorbing organic matter and metal ions from the water phase. It does not leave any oil phase material and is very easy to operate. [Embodiment] The effect is to further improve the structural features and the achieved effects of the present invention, and the descriptions of the preferred embodiments and the detailed descriptions are as follows. First, a reference to a first embodiment, which is a preparation of an oily magnetic fluid according to a preferred embodiment of the present invention, is shown in the figure, a method for preparing the oily magnetic fluid of the present invention, in step S10, Adding a bisamine compound to the oily substance to obtain a bisamine based oily compound; in step S12, adding a carboxyl compound to the bisamine based oily compound to obtain a carboxydiamine based binding oil; in step S14, 'taking an iron ion solution to mix The silk compound is used to obtain a silk magnetic ferrite. In the step S16, the carboxyl bisamine-based binding oil is added to the carboxyl magnetic ferrite to obtain an oily magnetic fluid having a particle size ranging from about 60 to 1 nanometer. ‘ 7 (8)