TWI292423B - Flame retardant resin composition - Google Patents

Description

1292423 A7 B7 V. INSTRUCTION DESCRIPTION (j) The present invention relates to a fire resistant carbonate polymer. (Please read the precautions on the back and fill out this page.) BACKGROUND OF THE INVENTION Polycarbonate resins have been used in a wide range of fields including electrical, electronic, and office automation (0A), and as engineering plastics, they have excellent transparency characteristics and resistance. Punching characteristics, heat resistance and electrical properties. In the fields of electrical, electronic and 〇A, high fire resistance (UL94V) or impact resistance is required, as in the outer package parts of personal computers. Polycarbonate resin is a plastic material with high fire resistance and self-extinguishing properties. However, in the fields of electrical, electronic and 〇A, it is still necessary to meet a higher degree of safety and a higher degree of fire protection, corresponding to UL94V or 94V-1. Printed by the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumer Cooperatives. Therefore, in the past, a large number of polycarbonate derivatives, bisphenol A bromide oligomers or polymers, were blended with polycarbonate to improve polycarbonate. Fire protection characteristics. However, the problem is to reduce the impact resistance and to easily grow cracks in the molded product. At the same time, because the ingredients contain a large amount of bromine-based halogen compounds, there are environmental considerations, and a halogen-containing gas is generated during combustion. Phosphate esters and oxime resins are known as fire retardant agents that do not contain halogens. For example, in the patent publication, Japanese Patent Publication No. S 2 - 6 2 - 2 5 7 0 6, it has been proposed to add a phosphate ester to a polycarbonate resin. However, this causes a problem in that if a phosphate ester is added to the polycarbonate composition in the preparation of the molding material, heat resistance or impact resistance characteristics are lowered. For this reason, when the ruthenium compound has high heat resistance, the 逍 -4- -4- paper size is used in the Chinese National Standard (CNS) A4 specification (210 X297 mm) 1292423 A7 B7 V. Invention Description (2) As a fire retardant for thermoplastic resins such as polycarbonate. When burning, it does not generate harmful gases, and in addition, the stability characteristics of the resin material are also high. The ruthenium compound used as a fireproofing agent is a polymer which is formed by polymerizing at least one of four oxoxane units (M unit, D unit, T unit, Q unit) as shown below. Μ unit D unit T unit

R ! R - Si - ΟΙ R

(n3SiO〇.sJ

R I —〇—Si—Ο—I R R ). ~o~—Si— ο ο I IRSiO^s)

Q unit I 〇I ·〇—Si—I 0 1 tSi〇2,〇J Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed in another reference, Japanese Patent Publication Sho 62-60421, reveals a fireproof resin composition And an antimony resin containing more than 80% by weight of T units is added thereto. Japanese Patent No. Hei 5-86295 discloses a fireproof resin composition such as a polycarbonate containing a bismuth resin, and the enamel resin contains T to 30 to 99 mol%, D unit 0 to 80 mol%, Μ unit 1 to 70 mol% and Q units 0 to 50 mol%. In prior art references, a large amount of tantalum resin was required to meet the stringent fire protection standards associated with electrical and electronic machines. As a result, other properties of the thermoplastic composition such as molding characteristics, kneading characteristics and characteristics required for other thermoplastic resins are affected, and further, it becomes impractical in terms of cost. In addition, when trying to improve the effect of the fire retardant compound itself, and in addition (please read the notes on the back and fill out this page)

This paper scale applies to China National Standard (CNS) Α4 specification (210Χ 297 mm) -5 1292423 A7 B7 5. Inventive Note (3), in order to reduce the amount of bismuth compound required, he has proposed to use metal salts together with bismuth compounds. Use. For example, Japanese Patent Application Sho 56-1 0085 3 discloses a fireproof resin composition in which ruthenium contains D units and a second group metal salt of carbonic acid having 14 to 20 carbon atoms, and the fire retardant resin is composed. The compound is compounded with a polymer such as polycarbonate. In another publication, Japanese Patent No. Hei 3-48947, discloses a fireproof resin composition in which a ruthenium resin containing oxime units and Q units is compounded with a second group metal salt of other oxime resins and carbonic acid. Even the ruthenium compound is used in combination with a metal salt, and the amount of the ruthenium resin is still high to provide a satisfactory fireproof effect. Additionally, it is also desirable to use an inorganic fireproofing material such as aluminum hydroxide or a halogen or phosphorus compound. Thus, the addition of tantalum resin as a fire retardant in the prior art failed to achieve a sufficient fireproofing effect unless a high amount was added. Further, various properties of the resin composition such as molding properties, appearance of the molded product or mechanical strength, etc., if a large amount of sand resin is added, will be adversely affected. In addition, when the sand resin material itself is high in cost, it also has high material cost. There is still a need for an antimony resin additive having a high fireproof effect, or an additive for an effective fireproofing property which can be used together with an indole resin. Japanese Patent No. Hei 8- 1 76425 discloses a fireproof composition in which an organopolyoxane containing an epoxy group and an alkali metal salt of an organic sulfonic acid is added. Japanese Patent No. Hei 8- 1 76427 discloses a fireproof composition comprising a polycarbonate resin denatured by an organopolysiloxane, which contains a phenolic hydroxide group and an organic alkali metal salt, and has been published. Meanwhile, in Japanese Patent No. Hei 9- 1 699 14, a composition has been published with an improved fire protection effect & Zhang scale applicable Chinese National Standard (CNS) A4 specification (210X297 mm) 7〇1 ~ eml. ϋ··— memmmmet iMJt emammmmmmm ·11 —ι_ϋ aw (please read the note on the back and fill out this page) Order the Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1292423 A7 B7 V. Invention Description (4) Yes, this effect This is achieved by using petroleum heavy oil or bitumen species in combination with hydrazine compounds. However, in such cases, high cost resins are required and adequate fire protection is not achieved, based on barriers involved in the manufacturing stage. In addition, the dispersion characteristics and compatibility with polycarbonate resins are unsatisfactory. In Japanese Patent No. Hei 1 0-39964, the molecular weight (weight average MW) is between 10,000 and 270,000, wherein the ruthenium resin contains a fire retardant composition of D and T units shown in the following formula, and aromatic Polycarbonate ingredients. fPlease read the notes on the back and fill out this page) R, I FT Surface - SrI R·

R °+-sr°y

R n R·τ~. Seven sl-η· Ο R* Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing At the same time, Japanese Patent No. Hie 1 1 - 140294 discloses a fire-retardant polycarbonate resin composition, in which the resin-containing resin contains 50 to 90 mole % units, 10 to 50 mole % D units, and wherein the proportion of phenyl groups in all of the organic substituent groups is greater than 80 mole %. However, in both of these references, the combustion period is long, and in addition, the drip characteristics are insufficient, and the fire prevention characteristics occurring in the UL94-based combustion test have been extensively evaluated and are still unsatisfactory. . In another reference, Japanese Patent No. Hei 1 1-217494 discloses a fireproof polycarbonate resin composition in which a sand compound has a structure showing the following, in other words, it has a D unit as a main structural unit, the paper scale Applicable to Chinese National Standard (CNS) A4 Specification (210X297 mm) -7 - 1292423 A7 B7 V. Inventive Note (5) and also includes D unit and T unit and / or Q unit, and in addition, it has an aromatic group Group as an organofunctional group, and a metal salt of an aromatic sulfur compound and a polymer co ——Q « ·>-'S· Please read the precautions of the back

X

I

• Si—O 1 In the above formula, R and X mean an organofunctional group. Also seen in the above reference, the eucalyptus resin containing such a D unit as an essential component has a significantly lower softening point. Therefore, the resin is more easily converted into a liquid form at room temperature, making the formulation of the polycarbonate resin extremely difficult. At the same time, since the molecular weight is high, a solid ruthenium resin is obtained at room temperature, and even if it exhibits a D unit in the form of a D unit, it is present as an indispensable component. Therefore, a long period of polymerization is required to increase the molecular weight of the eucalyptus fat, and the fire prevention effect is low. Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, Printed in Japan, Japanese Patent No. Hei 1 1 -222559, discloses a fireproof resin composition, which has been disclosed to contain 100 parts by weight of synthetic resin, which contains an aromatic ring such as an aromatic polycarbonate in the molecule. A resin, a phenyl group represented by the formula R^R^SUOI^'MOHhOH-..., and 0.1 to 10 parts by weight of an organic alkoxy group containing an alkoxy group. In the formula, R1 means a phenyl group, R2 means a monovalent hydrocarbon group and excludes a phenyl group having 1 to 6 carbon atoms, and R3 means a monovalent hydrocarbon group having 1 to 4 carbon atoms. And the paper scale applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -8 - 1292423 Α7 Β7 5. The invention description (6) The range is 0.5 < 2 m &lt;= 2.0, 〇 &lt;= n &lt; = 〇.9,0.42 &lt;= p &lt;= 2.5 ' 0 &lt;= q &lt;= 0·35 ' 〇·92 &lt;= +m + n + p + q .&lt;= 2.8 〇 (please first At the same time, Japanese Patent Application No. 2000-1 59996 discloses a fireproof resin composition containing an aromatic polycarbonate, a bismuth salt and a fire retardant such as a metal base. Group 'halogen group, or inorganic group fire retardant, compound containing triazine column, oxime resin, eucalyptus oil, cerium oxide, aramid resin, polyacrylonitrile fiber, fluororesin , phenolic enamel resin, etc.: r ^ (〇)p R1° Si-ο--r4

V I J (〇)q n r3 Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Printed In the above formula, R1 to R4 mean a hydrocarbon having 1 to 20 carbon atoms, and R1 and R4 may form a ring. p and q are 〇 or 1 and cannot be 0 at the same time. η is an integer greater than one. However, in such prior art fireproof resin compositions, enamel does not provide a material which satisfies fireproof properties, flowability characteristics, and molded materials having various satisfactory characteristics such as heat resistance, hydrolysis resistance or impact resistance. Features, etc. This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 mm) -9 - 1292423 A7 B7 5. Inventive Note (8), the ratio of the phosphate compound (C) is from 1 to 30 parts by weight. The amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2) is 100 parts by weight, and the ratio of the epoxy stabilizer (D) is 0.01 to 10 parts by weight. 100 parts by weight of the total of the polycarbonate resin (A-1) and the thermoplastic resin (A-2), wherein the oxime resin (B), the phosphate compound (C), and the epoxy stabilizer (D) are provided. A multiplication effect. In a specific embodiment, the thermoplastic resin (A-2) is selected from the group consisting of the following: a) a polymer containing (a) an aromatic vinyl monomer component as a structural component; b) a copolymer containing therein (a) an aromatic vinyl monomer component and (b) a vinyl cyanide monomer component as a structural component thereof; c) a copolymer containing therein (a) an aromatic vinyl monomer component, (b) a vinyl cyanide monomer component, and (c) a rubber polymer as its structural component d) an aromatic polyester; e) a polyphenylene ether; An amine; and g) a polyphenylene sulfide.

In another embodiment, the thermoplastic resin (A-2) is selected from the group consisting of ABS resin, AES resin, ACS resin, AAS resin, and polystyrene resin. This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) _ 11 _ (Please read the note on the back and fill out this page) Ding Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 1292423 A7 __ B7 _ five (Invention) (9) (Please read the note on the back and then fill out this page). In another embodiment, the enamel resin (B) is an enamel resin containing at least two types of siloxane units. The decane unit is selected from the group consisting of oxime units (T units) exhibited by RSi〇i.5, and RsSiCh. Deuterated oxygen units (D units), decane units (M units) exhibited by R3Si〇〇.5, and decane units (Q units) exhibited by SiCh.o, where R means 1 Monovalent substituted or substituted hydrocarbon groups up to 10 carbon atoms. The above-mentioned one type of ruthenium resin (B) is intended to be expressed as a ruthenium resin containing T units and oxime units, or a unit containing T units and oxime units and consisting of Si 〇 2. Shown is a decane resin unit (Q unit, wherein R means a monovalent substituted or substituted hydrocarbon group having 1 to 10 carbon atoms). In yet another embodiment, the aromatic group is present in a proportion of at least 20 mole % of the organofunctional group R and is contained in the above-described base resin (B). Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, in another embodiment, the phosphate compound (C) is bisphenol A-tetraphenyl diphosphate or bisphenol A tetracresyl diphosphate; epoxy The stabilizer (D) is 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexane residue or bis-(3, substituted hydrocarbon group 4-epoxycyclohexyl) In the present invention, the drip preventive agent (E) is polytetrafluoroethylene (PTFE) and is present in a proportion of from 1 to 1 part by weight, based on the polycarbonate resin (A- 1) or 100 parts by weight of the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). The invention also relates to an article comprising an electrical and electronic device and a cover, which are formed via the fire resistant resin composition described above. DETAILED DESCRIPTION OF THE INVENTION The fire-retardant resin composition of the present invention has characteristics in accordance with the Chinese National Standard (CNS) A4 specification (210×297 mm) including the paper size. “12 - 1292423 A7 B7 V. Invention Description (10) Polycarbonate tree. Fat (A-1), thermoplastic resin (A-2), enamel resin (B), phosphate compound (C) and epoxy stabilizer (D). Fill out this page again) Polycarbonate resin (A-1). The polycarbonate tree used in the present invention (A) is an aromatic homopolycarbonate or derived from an aromatic dihydroxy compound. An aromatic copolycarbonate which is reacted between carbonate precursors. Polycarbonate resins generally have a repeating structural unit represented by the following formula (1) - (0-A ... (1) where A is two The valency residue group is derived from an aromatic dihydroxy compound. The aromatic dihydroxy compound is present as a monocyclic or polycyclic aromatic compound and contains 2 units of a radical group as a functional group and wherein each of the radical groups has Direct bonding to the carbon atom of the aromatic ring. Bisphenol synthesis shown by the following formula (2) The material can be used as an example of an aromatic dihydroxy compound. The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed in which Ra and Rb may be the same or different, each being a halogen atom or a monovalent hydrocarbon group, and m and η are integers from 0 to 4. .

Rc Rc

I I III .

Rd Rd Rc -13- This paper size applies to the Chinese national standard (〇 secretion) eight 4 specifications (210, 乂 297 public |) 1292423 A7 B7 five, invention description (Ή)

(Please read the precautions on the back side and fill out this page) and Rc and Rd are hydrogen atoms or monovalent hydrocarbon groups, Rc and Rd form a ring structure and Re is a divalent hydrocarbon group. An example of these types of aromatic dihydroxy compounds exhibited by the above formula (2), including bis(hydroxyaryl)alkanes such as bis(4-hydroxyphenyl)methane, is printed by the Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative. 1,1-bis(4-hydroxyphenyl)ethane, 2,2-bis(4-hydroxyphenyl)propane (referred to as bisphenol A), 2,2-bis(4-hydroxyphenyl)butane , 2,2-bis(4-hydroxyphenyl)octane, bis(4-hydroxyphenyl)phenylmethane, 2,2-bis(4-hydroxy-1-methylphenyl)propane, 1,1 - bis(4-hydroxy-tris-butylphenyl)propane, 2,2-bis(4-hydroxy-3-bromophenyl)propane, 2,2-bis(4-hydroxy-3,5-di Bromophenyl)propane or the like; bis(hydroxyaryl)cycloalkane such as 1, L·bis(4-hydroxyphenyl)cyclopentane, 1,1-bis(4-hydroxyphenyl)cyclohexane, etc.; Hydroxyaryl ethers such as 4,4\dihydroxybiphenyl ether, 4,4^dihydroxy-3,3乂biphenyl ether, etc.; dihydroxydiaryl sulfides such as 4,4^dihydroxydiphenyl a sulphide, 4,4'-dihydroxy-3,3'-biphenyl sulfide, etc.; a dihydroxydiaryl sulphate such as 4,f dihydroxybiphenyl phenylene, 4,^-dihydroxy- 3,3^ Master phenyl and the like; an aryl group by a large group, such as 4,4 '- biphenyl group by code, 4,4-dihydroxy-biphenyl ^ Master like. However, it is noted that the aromatic dihydroxy compound is not limited to the above examples. In a specific embodiment, the aromatic dihydroxy compound is 2,2-bis(4-hydroxyphenyl)propane (referred to as bisphenol A). Meanwhile, an aromatic dihydroxy compound exhibited by the following formula (3) can be used as an addition to those exhibited by the above formula (2)

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 7T7Z 1292423 A7 B7 V. Inventive Note (12) The aromatic aromatic dihydroxy compound other than the one shown. (^) 〇

Printed by the Ministry of Economic Affairs, the Intellectual Property Bureau, and the Consumer Cooperatives. Each of the R1 departments is independently C! to C!. A hydrocarbon group, a halogen atom, or a g-hydrocarbon group wherein at least one of the hydrocarbon groups has been substituted with a halogen atom, and P is an integer of 0 to 4. Examples of such compounds include resorcinol; substituted isophthalenes such as 3·methyl resorcinol, 3-ethyl resorcinol, 3-propyl resorcinol, 3-butyl M-phenylene phenol, 3-di-butyl-isophthalic acid, 3-phenylisophthalene, 3-anisyl resorcinol, 2,3,4,6-tetrafluoroisophthalene, And 2,3,4,6-tetrabromoresorcinol; catechol; and hydroquinone and substituted hydroquinones such as 3-methylhydroquinone, 3-ethylhydroquinone, 3-propylhydroquinone, 3-butylhydroquinone, 3-tert-butylhydroquinone, 3-phenylhydroquinone, 3-fenylhydroquinone, 2,3,5,6-tetramethylhydroquinone, 2,3,5, 6-tetra-tert-butylhydroquinone, 2,3,5,6-tetrafluorohydroquinone, and 2,3,5,6-tetrabromohydroquinone. In addition to those of the above formula (2), another aromatic dihydroxy compound which can be used is 2,2,2',2^tetrahydro-3,3,3',3^tetramethylspiro-[H -1-mercapto]-7,7'-diol is represented by the following formula:

This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) -15- (Please read the note on the back and fill out this page) 1292423 A7 B7 V. Invention Description (13) Ministry of Economic Affairs Intellectual Property Office Staff Consumption The cooperative printed such aromatic dihydroxy compounds may be used alone or in combination of two or more types. This polycarbonate is linear or branched. It can also be a blend of linear polycarbonate and branched polycarbonate. A branched polycarbonate can be obtained by reacting a polyfunctional aromatic compound with an aromatic dihydroxy compound and a carbonate precursor. Representative examples of such polyfunctional aromatic compounds are listed in U.S. Patents 3, 28,385, 3,334,1 54, 4.01,124, and 4,131,576. Specific examples thereof include 1,1,1-tris(4-hydroxyphenyl)ethane, 2,2',2&quot;-tris(4-hydroxyphenyl)diisopropylbenzene, (α-methyl) - α,α',α'-tris(4-hydroxyphenyl)-1,4-diethylbenzene, α ',α tris(4-hydroxyphenyl)-1,3,5-triisopropyl Benzene, fluoroglycine, 4,6-dimethyl-2,4,6-tris(4-hydroxyphenyl)heptane-2,1,3,5-tris(4-hydroxyphenyl)benzene, 2, 2-bis-[4,4-(4,4'-dihydroxyphenyl)-cyclohexyl]-propane, trimellitic acid, 1,3,5-benzenetricarboxylic acid, and pyromellitic acid. Among such, it is preferred to use 1,1,1-tris(4-hydroxyphenyl)ethane, ^, 〇: ', 〇:"-tris(4-hydroxyphenyl)-1,3,5- Triisopropylbenzene, or the like. The inherent viscosity of the polycarbonate-based resin is not particularly limited as measured at 25 ° C in dichloromethane, and it may be appropriately desired. Application and moldability options, but usually at least d·26 dL/g, and preferably between 30·30 and 0.9 8 dL/g, and even more preferably 〇·34 to 0·64 dL/g. Calculate the viscosity average molecular weight, which is usually 10, 〇〇〇, and should be between 1 2,000 and 50,000, and further preferably between 14,000 and 30,000. He may also use the paper size for the Chinese National Standard (CNS) A4 specification (210X297 mm) -16 - (please Read the precautions on the back and fill out this page.) • Install · Book L·. 1292423 A7 B7 V. Inventions (14) (Please read the notes on the back and fill out this page) Polycarbonate with different intrinsic viscosity A mixture of resins. Viscosity average molecular weight (Mv) is measured by measuring the intrinsic viscosity (restricted viscosity [number]?// in methylene chloride at 20 ° C and then calculated by Mark-Houwink viscosity equation: 7 ? = K x (Mv) a (K = 1.23 X 10·4, a = 0.83) The polycarbonate-based resin used in the present invention is produced by a known method. Examples thereof include the following. A method in which a polycarbonate (melting method) is synthesized by transesterifying an aromatic dihydroxy compound with a carbonate precursor such as a carbonic acid diester under melting. (2) A method in which a solution is used Lithium aromatic dihydroxy compound and carbonate Reactant (e.g., phosgene) reaction (interfacial method). Such a manufacturing method is discussed, for example, in Japanese Patent Applications H2- 1 75723 and 112_1 24 934, U.S. Patents 4,001,184, 4,238, 5 69, 4,238,597, and 4,474,999, and Other than thermoplastic resin (A-2) other than polycarbonate resin. In the present invention, a thermoplastic resin other than polycarbonate (hereinafter simply referred to as a thermoplastic resin) may be present together with the above-mentioned polycarbonate. Any thermoplastic resin other than polycarbonate may be used as the thermoplastic resin (A-2), which is not particularly limited, but is preferably one or more types of resins selected from the group consisting of: (1) Polymerization (4) Aromatic vinyl monomer component as a structural component. This paper scale is used in Chinese National Standard (CNS) A4 specification (210 X 297 mm) -17-1292423 A7 _ B7 ___ V. Description of invention (15) (2) The copolymer contains (a) an aromatic vinyl monomer component and (b) a vinyl cyanide monomer component as a structural component. (3) The copolymer contains (a) aromatic vinyl as a structural component. Base monomer component, (b) vinyl cyanide monomer component, and (c) rubber polymer (4) aromatic polyester (5) polyphenylene ether (6) polyether quinone imine (7) poly benzene All of the above-listed resins of the base sulfides are commercially available, and are not particularly limited in the production method and the like. &amp;polymer (1). First, a polymer containing the U) aromatic vinyl monomer component (1) will be described. Examples of the aromatic vinyl monomer component (a) include styrene, α-methylstyrene, o-, m-, or p-methylstyrene, vinyl xylene, monochlorostyrene, dichloro Styrene, monobromostyrene, dibromostyrene, fluorostyrene, p-tert-butylstyrene, ethylstyrene, and vinylnaphthalene. The polymer used in the present invention may be a homopolymer of one of these, or a copolymer of two or more different monomers. Among such monomers, styrene and α-methylstyrene are particularly suitable. In a specific embodiment, a styrenic resin is used. There is no particular limitation on the method of producing the (co)polymer, and any generally known methods such as bulk polymerization, solution polymerization, bulk suspension polymerization, suspension polymerization, and emulsion polymerization can be used. The desired (co)polymer may also be obtained by blending separately polymerized resins. A total of cattle not (2). Next, the description of the copolymer contains (a) an aromatic vinyl paper. The scale of the paper applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) ~\〇1 _.-- ί--*---^^- (Please read the precautions on the back and fill out this page), 1Τ b. Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives, Printing 1292423, Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumers Cooperatives, Printing A7 B7 V. Inventions (16) Monomers And (b) a vinyl cyanide monomer component (2). The examples of the aromatic vinyl monomer component (a) are the same as above. Examples of the vinyl cyanide monomer component (b) include acrylonitrile and methacrylonitrile. One or more types of such ingredients may be included in the copolymer. The composition ratio (a)/(b) is not particularly limited, and its choice should be based on the application. (a)/(b) preferably makes (a) 50 to 95 wt% and (b) 5 to 50 wt%, and further preferably (a) 65 to 92 wt% and (b) ) accounts for 8 to 35 wt%. A suitable example of the above polymer is a SAN resin (styrene-acrylonitrile copolymer). The method for producing the copolymer is not particularly limited, and any generally known methods such as bulk polymerization, solution polymerization, bulk suspension polymerization, suspension polymerization, and emulsion polymerization can be used. The desired copolymer may also be obtained by blending a polymer which is polymerized. Copolymer (3). Next, a group of copolymers will be described which comprise (a) an aromatic vinyl monomer component, (b) a vinyl cyanide monomer component, and (c) a rubber polymer (3). The examples of the aromatic vinyl monomer component (a) and the vinyl cyanide monomer component (b) are the same as above. Examples of the rubber polymer (c) include polybutadiene, polyisoprene, styrene-butadiene heterocyclic copolymer and block copolymer, butadiene-isoprene copolymer, And other diene-based rubbers; ethylene-propylene hetero-distribution copolymers and block copolymers, copolymers of ethylene and α-olefins, ethylene-methyl acrylate, ethylene-butyl acrylate, and other ethylene and unsaturated carboxylic acids Copolymers of esters; acrylate-butadiene copolymers, such as butyl acrylate-butadiene copolymers, and other acrylic elastomer polymers; ethylene-vinyl acetate and other ethylene and fatty acid vinyls [salts] Copolymer; Ethylene-propylene-hexadiene copolymer paper size applicable to China National Standard (CNS) Α4 specification (210Χ297 mm) -19 : I (please read the note on the back and fill out this page) Clothing. 1Τ f 1292423 Α7 Β7 V. Inventive Note (17) (Please read the note on the back and fill out this page) and other ethylene propylene unconjugated diene terpolymer; butene-isoprene copolymer, And chlorinated polyethylene. This type can be used alone or in combination. The preferred rubber polymer is a bismuth-trimer, a double-fibre rubber, and an acrylic elastomer polymer, which are polybutadiene and benzene. Ethylene-butadiene copolymers are particularly suitable. In a specific embodiment, the styrene is 50 w% or less. The copolymer (3) is preferably a graft copolymer obtained by graft polymerization of other components in the presence of the rubber polymer (c). Particularly suitable for a resin and selected from the group consisting of ABS resin (acrylonitrile-butadiene-styrene copolymer), AES resin (acrylonitrile-ethylene-styrene copolymer), ACS resin (acrylonitrile) - chlorinated polyethylene-styrene copolymer), and AAS resin (acrylonitrile-acrylic elastomer-styrene copolymer). The above (co)polymer (1) and the copolymers (2) and (3) preferably have a weight average molecular weight (Mw) of from 30,000 to 200,000, more preferably from 30,000 to 150,000, and from 30,000 to 110,000. Good. The Intellectual Property Intellectual Property Office employee consumption cooperative is printed in a specific embodiment of the present invention, and each monomer copolymerizable with the above components (a), (b), and (c) may also be The (co)polymer (1) and the various components in the copolymers (2) and (3) are copolymerized. Examples of the copolymerizable monomer include acrylic acid, methacrylic acid, and other 6K, yS-unsaturated carboxylic acids, methyl (meth) acrylate, ethyl (meth) acrylate, and (meth) acrylate Ester, butyl (meth)acrylate, 2-ethyl (meth)acrylate, 2-ethylhexyl methacrylate, and other α,々-unsaturated carboxylic acid esters; dehydrated malic anhydride, decomposed aconitic anhydride And other α,Θ-unsaturated dicarboxylic anhydride; and cis-butenylene diimide, Ν-methyl cis-butenylene diimide, Ν-ethyl cis-butene, paper size applicable to China Standard (CNS) Α4 size (210X297 mm) -20 - 1292423 Α7 Β7 V. Description of invention (18) Diimine, N-phenylcis butylenediamine, N-o-chlorophenyl cis Butylene diimine, and other α,/3-unsaturated dicarboxylic acid quinone imine compounds. These monomers can be used alone or in combination. The method for producing the copolymer is not particularly limited, and the production thereof may be carried out via bulk polymerization, bulk suspension polymerization, or solution polymerization. Aromatic polyester (4). Aromatic polyesters are known per se and are a group of polyesters having an aromatic ring in the chain unit of the polymer. Such polymers and copolymers are derived from a polycondensation reaction in which the main component is an aromatic dicarboxylic acid and a diol (or a derivative thereof). Examples of the aromatic dicarboxylic acid include p-nonanoic acid, m-decanoic acid, o-nonanoic acid, 1,5-naphthalene dicarboxylic acid, naphthalene-2,5-dicarboxylic acid, naphthalene-2,6-dicarboxylic acid, Biphenyl-2,2,dicarboxylic acid, biphenyl-3,3'-dicarboxylic acid, biphenyl-4,4,-dicarboxylic acid, biphenyl--4,4,-dicarboxylic acid, Phenylisopropylidene-4,4f-dicarboxylic acid, 1,2-bis(phenoxy)ethane-4,4'-dicarboxylic acid, indole-2,5-dicarboxylic acid, hydrazine-2 6,6-dicarboxylic acid, p-tertiary phenyl-4,4'-dicarboxylic acid, and pyridine-2,5-dicarboxylic acid. Preferably, citric acid is preferred. Such aromatic dicarboxylic acids may also be used in a mixture of two or more. Meanwhile, as long as the amount is small, one or more aliphatic dicarboxylic acids such as adipic acid, sebacic acid, dodecanedioic acid, and sebacic acid, or one or more alicyclic dicarboxylic acids such as cyclohexyl The alkanedicarboxylic acid may be mixed with the above aromatic dihydroxy acid. Examples of the alcohol component include ethyl alcohol, propylene glycol, butanediol, hexyl alcohol, neopentyl alcohol, 2-methylpropane-oxime, 3-diol, diethylene glycol, and trisole. Glycol, and other aliphatic diols, and cyclohexane-1,4-dimethanol, and other alicyclic diols, and mixtures thereof. At the same time, as long as the amount is small _:---ί------^^-- (please read the note on the back and fill out this page), 1Τ b. Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative Paper scale applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -21 - 1292423 A7 B7 V. Invention description (19), or more types of long-chain diols with molecular weights between 400 and 6000 Polyethylene glycol, polypropylene glycol, or polybutylene glycol can be used for copolymerization. (Please read the precautions on the back and fill out this page.) Specific examples of aromatic polyester resins include polyethylene terephthalate (PET), polypropylene terephthalate, and polybutylene terephthalate. (PBT), polyethylene naphthalate, polybutylene naphthalate, polyfluorene, 2-bis(phenoxy)ethyl _4,4, ethylene glycol dicarboxylate, and poly-pair Dimethyl oxalate. In a specific embodiment, PBT or PET is used. ^ m (5) 0 Polyphenylene ether (PPE) is a known resin having a substituted or unsubstituted extended phenyl ether unit. Particular examples include poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2-A) -6-ethyl-M-phenylene ether, poly(2-methyl-6-propyl-1,4-phenylene) ether, poly(2,6-dipropyl-M-stretch Phenyl)ether, poly(2-ethyl-6-propyl-1,4-phenylene)ether, poly(2,6-dimethoxy-1,4-phenylene)ether, poly( 2,6-Dichloromethyl-indole, 4-phenylene ether, poly(2,6-dibromomethyl-1,4-phenylene) ether, poly(2,6-biphenyl) 1,4-phenylene ether, poly(2,6-dimethylphenyl-1,4-phenylene) ether, poly(2,6-dichloro-M-phenylene)ether, poly(2 , 6-dibenzyl-M-phenylene)ether, and poly(2,6-dimercapto-1,4-phenylene)ether. The PPE copolymer printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs may be a copolymer containing an alkyl-trisubstituted phenol, such as 2,3,6-trimethylphenol, repeated in some phenyl ethers. In the unit. It may also be a copolymer in which a styrene compound has been grafted onto the PPE. The styrene compound-grafted polyphenylene ether comprises a copolymer obtained by graft polymerization of one of the above PPEs with a styrene compound such as styrene, α-methylstyrene, vinyl Toluene, or chlorostyrene. PPE is commercially available from G Ε Ρ 1 a s t i c s J a p a η, which is commercially available under the trademark Ν 〇 r y 1 . This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) _ 22 - 1292423 A7 __ B7__ V. Description of invention (2〇) Polyether sulfimide (6). Polyetherimine is a known resin, and examples thereof are trademarks of Ultem, GE Plastics Japan. (Please read the notes on the back and fill out this page) Polyphenylene sulfide (7). Polyphenylene sulfide (PPS) is a known resin having a substituted or unsubstituted extended phenyl sulfide repeating unit. Examples include those commercially available from Phillips Petroleum, Tosoh Susteel, Tohpren, Kureha Chemical, and the like. The copolymers (1) and (3) are preferably used as the thermoplastic resin used in the present invention, and are even more suitable for use of a resin selected from the group consisting of HIPS (High Impact Polystyrene), ABS resin (acrylonitrile-butadiene-styrene copolymer), AES resin (acrylonitrile-ethylene-styrene copolymer), ACS resin (acrylonitrile-chlorinated polyethylene-styrene copolymer), and AAS resin (Acrylonitrile-acrylic elastomer-styrene copolymer). ABS resin and HIPS are particularly suitable. The weight ratio (Al: A-2) of the thermoplastic resin (A-2) to the polycarbonate-based resin (A-1) is preferably from 99:1 to 1:99, preferably from 30:70 to 70:30. Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, printed component B-矽 resin. The eucalyptus which is used as the component (B) in the present invention is not particularly limited. In a specific embodiment, the oxime resin used herein contains at least two types of decane units, which are selected from the group consisting of siloxane units (T units) exhibited by RSiOu, R3SiCh. Deuterated oxygen units (D units), units of deuterium (Q units) exhibited by Si〇2.〇, and R 3 S i 0. · 5 shows the unit of aerobics (]V [units] (wherein R means a monovalent substituted or substituted hydrocarbon group with 1 to 10 carbon atoms). The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) ^23 - ' 1292423 A7 B7 V. INSTRUCTIONS (21) The organic groups constituting the sand resin may be the same or different. In a specific embodiment, the user is an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, etc., and an alkenyl group such as a vinyl group, an allylic group A group or the like, an aryl group such as a phenyl group, a tolylmethyl group or the like. Among such types of organic groups R, in particular, an anthracene resin having a methyl group and/or a phenyl group as an organic group R is desired, which is a dispersion property of a polycarbonate resin. And the view of fire protection characteristics, and because in this case it is the purchase of sand resin. In particular, an anthracene resin having a phenyl group has excellent fireproof properties, in addition to its superior compatibility with polycarbonate, and in addition, the transparency of the polycarbonate can be improved. The phenyl group is desirably present in the ruthenium resin in a proportion of more than 20 mol%, taking into account all of the organic groups, and more desirably, the ratio is desired to be greater than 40 mol%, considering all organic Group. The molecular weight of the oxime resin used in the fireproof resin composition of the present invention is desirably in the range of from 1,000 to 50,000, more desirably, in the range of from 2,000 to 20,000, and particularly intended for use in the fireproof resin composition of the present invention. The molecular weight of the lieugen resin should be between 3,000 and 10,000. If the molecular weight becomes less than 1000, it will become difficult to maintain the state in the use conditions, and the workability obtained is poor, and if the molecular weight exceeds 50,000, the dispersion characteristics to the polycarbonate become poor and poor. Nature. In a specific embodiment, an enamel resin containing T and oxime units, or an oxime resin containing ruthenium, osmium and Q units is used as the oxime resin used in the present invention. The unit is intended to be contained in the resin. The content is in the range of 〇.〇3 to 1 This paper size applies to the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) -24 : — Clothing -- (Please read first Note on the back of the page) m ^ϋ—ϋ Lr— · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1292423 A7 B7 V. Invention description (22) Moer, consider 1 mole T unit, agree The content of the ground is in the range of 〇·〇5 to 〇·3. Meanwhile, when the Q unit is contained in the enamel resin, such a q unit is required to be in the range of 0.001 to 0.5 mol, considering a molar unit of 1 m, and desirably, it is used in an amount of 0.01 to 0.05 mol. The q unit with high oxidation is still at a high content, which is good for achieving fireproof properties. However, if the amount of Q units in the oxime becomes high, the dispersion characteristics of the polycarbonate resin become unsatisfactory. The quality of materials that become inorganic microparticle types becomes super strong. Based on this, it is necessary to control the proportion of the ingredients so that they become within the above range. Considering the balance between fireproof properties, workability and properties of molded products, it is advisable to select the above range of the content of the siloxane unit so that the proportion occupied by the T unit becomes 50 to 97 mol%, accounting for all 矽The weight of the resin. This type of oxime resin can be synthesized by a conventional method. For example, it can be obtained by subjecting an organochlorosilane or an organoalkoxydecane to a hydrolysis condensation reaction using an excess amount of water. In a specific embodiment, the oxime resin containing a sterol group is prepared by subjecting a decane compound formed from T, Q and D units to hydrolysis condensation reaction using water, and then, if the oxime resin The preparation can be carried out by subjecting the sterol group to a triorganotoximation process, which uses a compound formed from a fluorene unit, and then it is easier to control the molecular weight in this case, and this is easier to control the molecular weight system. As the implementation of the case is what I want. In an embodiment of a method for producing a ruthenium resin formed of ruthenium and osmium units, one of 5 to 100 parts by weight of (R^Si^Z exhibits ruthenium compound (b) (wherein R1 is a unit price) Substituted or terminally substituted hydrocarbon groups, which may be the same or different from each other 'a is an integer from 1 to 3'. When a is 1 then Z is the gas original paper scale applicable to China National Standard (CNS) A4 specification (210X297 mm) :25 - &quot; — ^^衣-- (Please read the notes on the back and fill out this page)

1T Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1292423 A7 B7 V. Inventions (23) Sub, halogen atom, hydroxide group or hydrolyzed nature group, and when a is 2, it is -〇- , -NX- or -S-, and when a is 3, it is -N-. (Please read the precautions on the back and fill out this page.) At the same time, X is a hydrogen atom, a monovalent hydrocarbon group with 1 to 4 carbon atoms. 'With the formation of 1 〇〇 part by weight of the decyl group. The reaction is carried out from (a) [RSi〇15] T unit of hydrazine resin. The above-mentioned oxime resin containing the component (a) sterol group can be synthesized by a known method. For example, it can be obtained by subjecting an organic chlorodecane or an organoalkoxydecane to hydrolysis condensation reaction using an excess amount of water. In this type of reaction, the resin having different degrees of polymerization can be obtained by adjusting the amount of water or by controlling the amount and type of the hydrolysis catalyst, the time or temperature of the condensation reaction, and the like. The oxime resin thus obtained generally contains a sterol group (_Si〇H). Τ.b. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed The bismuth compound shown by (RSSi)aZ of component (b) is a compound in which the sterol group present in component U) has been decanolated. Considering examples of the hydrolyzable group Z, an alkoxy group such as a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a halogen such as Wind, desert, etc., a oxy group such as a propyloxy group, a ethoxy group such as an ethoxy group, a benzhydryl group, etc., an organic sulfonium group such as acetone a group, a butanone group, an organic aminooxy group such as a dimethylaminooxy group, a diethylaminooxy group, etc., an organic amino group such as a dimethylamino group, a cyclohexylamino group An organic guanamine group such as an N-methyl acetamidine group or the like. Considering the examples of the component (b), a hydrodiene decane such as trimethyl sulphate, triethyl decane or the like, a chlorodecane such as trimethylchloromethane, triethyl chlorin, phenyl chlorocyclohexane, etc. may be mentioned. Sterols such as trimethyl decyl alcohol, etc., alkoxy oxime, such as this paper size, using Chinese National Standard (CNS) A4 specification (210X297 mm) -26 - 1292423 A7 B7 V. Invention description (24) (Please first Read the precautions on the back and fill in this page) Trimethyl methoxy decane, triethyl methoxy decane, etc., amino decane such as (CH3)3SiNHCH3, (CH3)3SiNHC2H5, (CH3)3SiNH(CH3)2, ( CH〇3SiNH (C2H, etc., decyloxydecane such as (CH3)3Si〇C〇CH3, etc., diazane alkane such as [(Cth)3Si]NH, 1,3-divinyltetramethyldiazepine Iso-trioxane alkane such as nonamethyltriazane [(CH3)3Si]3N, etc. Meanwhile, among such examples, it is suitable to use a decazane species or a chlorocycloalkane type because it is easy to control the reaction or Removal of unreacted compounds. The Ministry of Economic Affairs' Intellectual Property Office employee consumption cooperative prints the reaction between the above ingredients U) and (b). Executed under conditions to convert sterols to decyl groups. For example, when component (b) is decazane or chlorodecane, the reaction can be easily carried out, and the components (a) and (only) are mixed by heating. b) and heating it. In the meantime, it is preferably used in a ratio of from 5 to 100 parts by weight, based on 100 parts by weight of the component (a). Further, if the proportion of the component (b) becomes less than 5 parts by weight, Then, the sterol group of the component (a) will not be satisfactorily decylated, and a defect such as gelation will occur during the reaction. Meanwhile, if the proportion of the component (b) exceeds 100 parts by weight, it is found in the raw material. The economic characteristics of the viewpoint will become poor because a large amount of unreacted components will remain as a residual material, and a long period of time is required to remove the unreacted component (b) due to the complexity of the method. The oximation reaction must be carried out desirably in the organic solvent to control the reaction temperature to control the occurrence of dehydration condensation side reactions. Considering the examples of organic solvents of this type which should be used, hydrocarbon group solvents such as toluene and xylene may be proposed. Hexane, Industrial use of gasoline, mineral oil, kerosene, etc., ether group solvents such as tetrahydrofuran, dioxane, etc., chlorinated hydrocarbon solvents such as dichloromethane, dichloroethane, etc. There are no special restrictions on the reaction temperature, Paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) -27 - 1292423 A7 ___ B7 V. Invention description (25) (Please read the note on the back and fill in this page) and fit at room temperature Up to 12 (between TC. Hydrochloric acid, ammonia, ammonium chloride, alcohol, etc. obtained by this reaction can be removed by washing with water or can be removed simultaneously with the solvent. The oxime resin obtained from the above method is generally present in the form of a liquid or a solid substance at room temperature. The base resin to be compounded with the polycarbonate resin is preferably present in a solid state because it can be uniformly dispersed in the polycarbonate resin, and in particular, it is suitable to use a solid resin which has a softening point of higher than 40 ° C. The ground is 70 to 250 °C. Further, the softening point of the enamel resin can be adjusted by mixing more than two types of enamel resins having different softening points. The molecular weight of the oxime resin can be controlled by controlling the molecular weight of the oxime resin which is used as the sterol group of the component (a), and the sterol group will undergo decaneization, and will become a decane-based reagent via control. The type of ingredient (b). Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the consumer consortium. If the enamel resin used in the present invention has D units, the softening point obtained therefrom is remarkably lowered because it is easily converted into a liquid state material at room temperature. This result makes it difficult to formulate the ingredients with polycarbonate. Meanwhile, if the molecular weight is high, an anthracene resin which is in the form of a solid material at room temperature can be obtained, even if it exhibits a resin having a D unit form. However, in this case, the polymerization period required to increase the molecular weight will be extended, and the fire prevention effect will be lowered when compared to the enamel resin containing T and oxime units or the ruthenium resin containing ruthenium, osmium and Q units. The case. The oxime resin used in the present invention may contain a small amount of sterol groups, however, the amount of sterol groups is preferably small, when considering stability characteristics, stability characteristics in a fusion method, or fire resistance characteristics The point of view. The content of the sterol group contained in the enamel resin is preferably less than 〇·5 % by weight, and more desirably, the paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297 羡1 “28 -~&quot ~ 1292423 A7 ___ B7 V. Inventive Note (27) If the hydrocarbon group is contained, the resulting resin composition will have a particularly remarkable fire resistance. X is a white oxygen atom and/or a nitrogen atom (^ To a divalent organic group. This X is, for example, -OY^o- (wherein γΐ is a substituted or unsubstituted aromatic hydrocarbon group, and preferably a 1,4-phenylene group, 1,3_ a phenyl group, etc.) or _ ◦ -YRY-0- (wherein γ2 and Υ3 are divalent substituted or unsubstituted aromatic hydrocarbon groups', and the examples thereof include substituted or unsubstituted phenylene a group; and R6 is a 0 to C8 divalent hydrocarbon group or an oxyhydrocarbon group (_r6_〇_; wherein 匕 to C8 monovalent hydrocarbon group), and more specifically a C 1 to C 9 divalent aliphatic hydrocarbon group , such as a 2,2'-propenyl group. This X may be an organic group and one of the nitrogen atoms is directly bonded to the phosphorus atom, and an example thereof is a 1,4-hexahydropyridinediyl group ( Type): (Please read the notes and then fill in the back of this page)

m is an integer from 0 to 5. Examples of the phosphoric acid ester printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs include bisphenol A tetraphenyl diphosphate (BPADP), phenyl phosphate, tricresyl phosphate, cresyl biphenyl phosphate, Bisphenol A tetramethyl phenol diphosphate, resorcinol tetrakis(2,6-dimethylphenyl) phosphate, and tetramethylphenyl hexahydropyridine phosphoramide decylamine. Among such, bisphenol A tetraphenyl diphosphate (BPADP) and bisphenol A tetracresyl diphosphate are preferred as the phosphate. If the phosphate compound (C) and the above-mentioned base resin (B) are added together, a molded product can be formed and the film has excellent impact resistance and heat resistance characteristics. The paper scale is applicable to the Chinese National Standard (CNS) A4 specification. (210X297 mm) -30: 1292423 A7 B7 V. INSTRUCTIONS (29) (Please read the notes on the back and fill out this page) Base-3,4-Epoxy.Cyclohexylcarboxylate, N-butyl Base-2,2 dimethyl-3,4-epoxycyclohexylcarboxylate, cyclohexyl-2-methyl-3,4-epoxycyclohexylcarboxylate, N-butyl-2_ Isopropyl-3,4-epoxy-5-methylcyclohexylcarboxylate, octadecyl-3,4-epoxycyclohexylcarboxylate, 2-ethylhexyl 3 4'-ring Oxycyclohexyl carboxylate, 4,6-dimethyl-2,3-epoxycyclohexyl-3',4'-epoxycyclohexylcarboxylate, 4,5-epoxy anhydrous four Hydrogen o-decanoic acid, 3-tert-butyl-4,5-epoxy anhydrous tetrahydro-o-decanoic acid, diethyl-4,5-epoxy-cis-1,2-cyclohexyl carboxylate Di-n-butyl-3-th-butyl-4,5-epoxy-cis-1,2-cyclohexylcarboxylate. In a specific embodiment, the epoxy stabilizer (D) is an alicyclic epoxy resin. In another embodiment, it is 3,4-epoxycyclohexylmethyl-3', 4^epoxycyclohexanecarboxylate or bis(3,4-epoxycyclohexyl) Adipate. This alicyclic epoxy stabilizer is commercially available from Asahi Denka Kogyo Kabushiki Kaisha (Asahi Electrochemicals) under the trade name R-51, or from Daicel Kagaku Kogyo Kabushiki Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative.

Kaisha (Daicel Chemical Industries) is commercially available under the trade name Celoxide 202 1P or Celoxide 2080. It has been found that the hydrolysis resistance of the resin composition can be improved with the addition of an epoxy stabilizer. In a specific embodiment, the epoxy stabilizer is added in an amount of about 0.01 to 10 parts by weight, and 100 parts by weight of the polycarbonate resin (A-1) is used, when polycarbonate is used alone. The resin (A-1) is used, or (A-1) and (A-2) are used in an amount of 1 part by weight, and the polycarbonate resin (A-1) and the thermoplastic resin (A-2) are used in combination. In a specific embodiment, the amount is 〇.1 to 5 by weight. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -32 - 1292423 A7 B7 5. Invention Description (31)

Glass (Kabushiki Kaisha (Asahi Glass)). (Please read the precautions on the back and fill out this page.) The drip preventive reagent should be added in an amount of 0.01 to 10 parts by weight. This is based on polycarbonate resin (A-1) and thermoplastic resin (A- 2) The total amount is desirably from 5 to 2 parts by weight, and more desirably, from 100 to 2 parts by weight, and more desirably, from 0.1 to 0.5 parts by weight. If the amount of the component (E) becomes less than the above range, a polycarbonate resin composite material having excellent fireproof properties cannot be obtained, and if it becomes higher than the above range, the flowability property will be lost. At the same time, the molecular weight of the polytetrafluoroethylene should be greater than 500,000, desirably between 1,000,000 and 5,000,000. In the resin composite material in which the polytetrafluoroethylene has been compounded, the drip can be controlled during combustion. Further, if the polytetrafluoroethylene and the terpene resin are used in combination, the drip can be further controlled, and in addition, the burning time can be shortened as compared with the case of adding only the polytetrafluoroethylene. Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printed in the Invention The liquid prophylactic agent, polyphenylene ether (p p E), can be used in combination with the above-mentioned polytetrafluoroethylene. Examples of PPE may include poly(2,6-dimethyl-1,4-phenylene)ether, poly(2,6-diethyl-1,4-phenylene)ether, poly(2) -Methyl-6-ethyl-1,4-phenylene)ether, poly(2-methyl-6-propyl-1,4-phenylene)ether, poly(2,6-dipropyl) -1,4-phenylene ether, poly(2,6-biphenyl-1,4-phenylene)ether, poly(2,6-dimethylphenylmercapto-1,4-phenylene) Ether, etc. A particularly preferred P P E type resin is poly(2,6-dimethyl-1,4-phenylene) ether. Meanwhile, for the polyphenylene ether copolymer, the copolymer has a mesogenic trisubstituted anthracene in a phenyl ether repeating unit, for example, a part having 2,3,6-trimethylhydrazine. In one embodiment, there is a copolymer in which the styrene compound is grafted on the poly-34-paper scale for the Chinese National Standard (CNS) A4 specification (210X297 mm) 1292423 Α7 Β7 5. Description of the invention (32) (Please read the notes on the back and fill out this page) Phenyl ether. Considering the styrene compound grafted polyphenylene ether, it is possible to propose a copolymer derived from a styrene compound such as styrene, α-methylstyrene 'vinyl toluene, chlorostyrene Etc., graft polymerization is carried out in the above polyphenylene ether. Further, for the drip prevention agent, the inorganic group drip preventive agent can also be used together with the above-mentioned polytetrafluoroethylene. Considering the above-mentioned inorganic group dropping prevention agent, it is possible to propose cerium oxide, quartz, aluminum silicate, mica, alumina, alumina, calcium carbonate, talc, tantalum carbide, tantalum nitride, titanium oxide, iron oxide, Carbon black and so on. . Even its ingredients. The resin composition of the present invention may further contain a UV absorber, a hindered phenol-based antioxidant, a mold lubricant, or the like. Examples of the UV absorber include a benzotriazine-based UV absorber, a benzophenone-based UV absorber, and a salicylate-based UV absorber. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumers' Cooperatives. When mixing the resin composition or molding, well-known additives may be added to the fire-retardant resin composition of the present invention, corresponding to the objectives and conditions without losing the material properties. For example, colorants (cosmetics, dyes such as carbon black, titanium oxide, etc.), chelating agents, reinforcing agents (glass fiber, carbon fiber, talc, clay, mica, glass flakes, honed glass, glass beads), lubrication Agent, plasticizer, fire retardant, flow property improver, etc. The method for producing the resin composition of the present invention is not particularly limited, and any conventional method can be used. However, it is particularly preferable to use a melt mixing method. A solvent may also be added in a small amount in the production of the resin composition. For the devices that can be used, in particular, extrusion forming machines, impact mixers, rolling presses, kneaders and the like. Can be used as an example, and this type can be applied to the Chinese National Standard (CNS) Α4 specification (210X297 mm) 1292423 A7 B7 in the combination -35- paper scale. 5. Inventive Note (33) Method or operate in a continuous method. . In the meantime, there is no particular limitation on the order of mixing of the components. (Please read the precautions on the back and fill out this page.) The fire retardant resin composition of the present invention has excellent fireproofing properties and does not generate dripping when burned. For example, the fire retardant resin composition of the present invention satisfies the UL-94 V-0 rating in the UL-94 V evaluation, and the evaluation is performed in accordance with Under Writer L aboratory I ncorporati ο η listed in B1 ete η 9 4 &quot; A test method for a classified combustion test &quot; (hereinafter referred to as UL-94) in which a test plate having a thickness of 1/16 inch was prepared. In addition, the standards for each V grade in UL-94 are listed in Table 1 below: Table 1 Grade V-0 Vl V-1 The residual flame period of each test specimen is less than 10 seconds less than 30 seconds less than 30 seconds 5 The total residual flame period of the test specimen is less than 50 seconds, less than 250 seconds, less than 250 seconds, and the cotton thread is ignited via dripping. 姐 j j w There is the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed with the fire retardant resin composition of the present invention. Molding is done in any desired form by using any desired type of molding process, such as injection molding, extrusion molding, blow molding, and the like. The molded product thus obtained has excellent impact resistance and high heat resistance, and in addition, has excellent fireproof properties. Because of this, the molded product of the resin composition of the present invention can be suitably used as the 〇A device or the household paper size applicable to the Chinese National Standard (CNS) A4 specification (21 OX 297 mm) _ 36 - 1292423 A7 B7 V. Description of the invention (34) Electrical appliances outside the board or as housing material parts, electrical and electronic machine parts. (Please read the precautions on the back and fill out this page.) The fire retardant resin composition of the present invention has high fireproof properties without losing the impact resistance or molding properties, when it contains a specific phosphate ester and an anthracene resin, and further, it is not worried. A halogen-containing gas is produced, which is derived from a corresponding type of fire retardant. When it is burned, it does not contain chlorine, bromine compounds, etc., and thus has excellent functionality from the viewpoint of environmental protection. Further, when a specific epoxy stabilizer has been added thereto, the hydrolysis resistance of the polycarbonate resin itself is improved, and a product in which the molded article can have excellent impact resistance can be produced. Therefore, the fireproof resin composition is extremely useful for applications requiring high heat resistance characteristics, such as household electrical appliances such as televisions, printers, photocopiers, facsimile machines, personal computers, etc., housing materials and parts of the 0A device, this material It can be used for internal devices such as battery packs, liquid crystal reflectors, and automobiles. Example. The invention has been described in further detail below with the aid of actual embodiments. However, the invention is not limited to such actual embodiments. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed In addition, in each practical example, parts are parts by weight and % is % by weight unless otherwise mentioned. Further, the following compounds were used as the respective components. Polycarbonate resin (PC): polycarbonate of bisphenol A: LEX AN (trade name, Nippon GE Plastics Kabushiki Kaisha (manufactured by Japan GE Plastics), intrinsic viscosity measurement in dichloromethane at 250 ° C =: 0.4901/8, viscosity average molecular weight (1^) = 21760 (calculated) ABS resin: a material with rubber content = 20%, MI = 2.5 g / 10 0 seconds -37- This paper scale is common Chinese national standard (CNS) VIII 4 specification (210X297 mm) 1292423 A7 __B7 _ V. Description of invention (35) Phosphate compound (C) compound · Bisphenol A-tetraphenyl phosphate, CR741S (trademark, Daihachi Kagaku Kabushiki Kaisha (Daihachi Chemical Co., Ltd.) Epoxy Stabilizer: 3, epicyclohexylcyclohexylmethyl-3\4'-epoxycyclohexyl carbonate (Celoxide 2021P, trademark, Daicel Kagaku Kogyo Kabushiki Kaisha (Daicel Chemical) Industries)) Polytetrafluoroethylene (PTFE): Polyflon D-2C (trademark, Daikin Kagaku Kogy o (Kabushiki Kaisha (Daikin Chemical Industries)). This material is emulsified to disperse PTFE in water, and With The PTFE content is 60% by weight. In addition, P〇lyfl〇n D-2C is added in an amount of 0.5% by weight, relative to the polycarbonate resin, since PTFE is actually added (content is 0.3%). In the preparation of the resin composition, water will volatilize. Resin: A resin material is used, which has the composition as shown in Table 2. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Office Employees' Consumption Cooperatives Printed Table 2 矽 resin A-1 Α-2 Β-1 Characteristic structural unit T and Μ Τ and Μ Τ, D, Μ Ph/ Me Mobi ratio 65/35 70/30 70/30 Weight average molecular weight 7800 7500 75000 Softening point (°C) 160 140 85 〇H residue group 0 0 0 This paper scale applies to China National Standard (CNS) A4 specification (210X297 public) 1292423 A7 ____ B7 V. Invention description (36)

Ph/Me molar ratio: The molar ratio of the phenyl group to the methyl group present in the oxime resin, except for the oxime units (T, D units). (Please read the notes on the back and fill out this page.) tMLLlJ takes 90 parts by weight of polycarbonate, 10 parts by weight of ABS resin, 1 part by weight of enamel resin (A-1), and 6 parts by weight of phosphate (CR741S). ), 〇·3 parts by weight of epoxy stabilizer and 〇.5 parts by weight of PTFE mixed, and using a two-way extrusion forming machine (TEX44aln of Nippon Sei Kojo (Kabushiki)

Kaisha) (produced by Japan Steel Manufacturing Works Co., Ltd.) is used for extrusion, using a number of screw rotations of 300 rpm and a barrel temperature of 250 to 260 ° C, and pellets of specific length can be prepared by cutting. The use of such pellets can be used to form test panels of a specific size, which are passed through a 1 ton injection molding machine at a barrel temperature of 260 ° C and a metal mold temperature of 50 (TC molding conditions. In the manner mentioned below) The obtained molded product was subjected to characteristic test. (1) Evaluation of impact resistance characteristics The cantilever beam impact strength evaluation was performed using a test plate having a thickness of 1/8 inch, based on ASTM-1. (2) Load elastic temperature (resistance Thermal Characteristics) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative printed and measured the deflection temperature under a load of 18.6 kg, using a 1/4 inch thick test board based on ASTM-D-648. (3) Resistance to hydrolysis. Measurement The weight average molecular weight of the polycarbonate in the resin composition prepared, and the weight average molecular weight of the polycarbonate in the resin composition measured after 48 hours under the environment of 100 RH and 121 ° C. The measurement of molecular weight is carried out by GPC. In addition, the weight average molecular weight is low, meaning that the hydrolysis resistance is low. (4) Evaluation of fire resistance characteristics. The molded product of 1.6 mm thickness is taken according to the above -39 - paper scale for China country Standard (CNS) A4 size (210X297 mm) 1292423 A7 ___ _ B7 V. Invention description (37) The UL-94 test described measures the fire resistance characteristics, in other words, according to the Under Wiiter Laboratory Incorporation listed in Bleten 94 '' The test method of the classified combustion type g (hereinafter referred to as UL - 9 4). In addition, the burning time is the total burning time of the five test materials. The results are shown in Table 3. Example 2-3. In actual example 1, the oxime resin (A-2) or (B-1) is a substituted oxime resin (A-1), and the reaction performed is similar to that of the actual embodiment 1, based on the obtained The particles were evaluated for characteristics. The results are shown in Table 3. Comparative Examples 1 to 4. The compositions shown in Table 3 were used. Except for this change, the execution of the reaction was similar to that performed in Practical Example 1, based on The obtained granules were evaluated for characteristics. The results are shown in Table 3. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Employees, Consumer Cooperatives, Printed Paper Scale, Applicable to China National Standard (CNS) A4 Specifications (210X297 public ) -40 - 1292423 A7 _ B7 V. INSTRUCTIONS (39) As shown in Table 3, the resin composition of the present invention has a short burning time, and a high epoxy stabilizer and a drip preventive agent have been added with a polycarbonate resin. Among them, and in addition, the oxime resin and the phosphate compound (C) compound can control the generation of the dropping liquid and have high fireproof property (UL-94 V-0). Meanwhile, the resin composition of the present invention has excellent hydrolysis resistance characteristics due to He does not hydrolyze even under heating. As in Comparative Example 1, the resin composition containing no antimony resin and epoxy stabilizer had insufficient fireproof properties and hydrolysis resistance. Meanwhile, as in Comparative Example 2, the resin composition containing no oxime resin, such as the resin composition, was insufficient in fireproof properties. Further, as in Comparative Example 3, the resin composition not containing the epoxy stabilizer was insufficient in hydrolysis resistance. Further, as in Comparative Example 4, the resin composition not containing a phosphate ester had low fireproof properties even if the amount of the oxime resin was increased. Therefore, it is a matter of course that the multiple fireproofing properties of the resin composition can be achieved by combining a phosphate ester with a fluorene resin and adding a polycarbonate resin. Ϋ'-ιϋ m »....... Jn —ϋ ϋϋ 1^1 I (please read the notes on the back and fill out this page first) Customs Department of Intellectual Property Intellectual Property Bureau Employees Cooperatives Printed on this paper scale China National Standard (CNS) A4 Specification (210X297 mm) _ 42 -

No. 90,129,447, Patent Application, Chinese Manual, Replacement Page, December 17, 1992, Amendment Application, Issue, November 28, November, Date, Supplementary Case No. 90129447 Category A4 C4 (The above are filled by this Council) Book refractory resin composition Chinese invention new name English

Flame retardant resin composition (1) Ma Shiping Ma, Sh i ping Name Nationality Invention creator ¢1) 106, 2-choraei, Takasei-cho,. Moka-shi5l, Takashiro-cho, Takashiro-cho, Mokamachi, Tochigi, Japan Tochigi-ken 321-4341, Japan Name of residence and residence (name) Nationality (1) Tongyu Electric Chicken Yinfen Gastric Company General Electric Company • Line Applicant Residence, Residence (Company) Representative Name

(1) United States (I) New York, USA if {♦ Scheneta Riverside Road 1 Kiver R.oad, Schenectady^ 12345, USA

(1) Lei Chassin Chaskin, Jay L This paper wave scale applies to China National Standard China (CNS) MC grid (210X 297 mm)

[29240S 2A No. 90129447 Chinese manual Replacement page number Patent application Republic of China October 3, 1996 Amendment 5, invention description (7) The applicant has surprisingly discovered a resin composition with high level of fire protection characteristics, and in addition, All of the above problems have been solved by multiplying the use of an anthracene resin and a phosphate having a specific structure, and further, by combining an epoxy stabilizer and a drip preventive agent, and compounding the same with a polycarbonate resin. . The composition of the present invention has heat resistance characteristics, excellent impact resistance and hydrolysis resistance, and in addition, it has excellent fireproof properties. SUMMARY OF THE INVENTION The present invention relates to a fire resistant polycarbonate composition comprising a polycarbonate (A-1); a thermoplastic resin (A-2) other than polycarbonate; an anthracene resin (B); Demonstrated phosphate compound (C):

(Please read the notes on the back and fill out this page) 0—R4 Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the employee consumption cooperatives, where R1, R2, R3 and R4 respectively mean that the hydrocarbon has a carbon atom of 1 to 30, X Means a divalent organic group having 1 to 30 carbon atoms and may even contain an oxygen atom and/or a nitrogen atom, and m means an integer of 0 to 5; and an epoxy stabilizer (D), the composition It is characterized in that the ratio of the weight of the polycarbonate resin (A-1) to the thermoplastic resin (A-2) is (Al: A-2) between 99:1 and 1:99, and further, the 矽The ratio of the resin (B) is 0.1 to 15 parts by weight, which is based on the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2) as the 100-weight paper scale applicable to the Chinese national standard ( CNS ) A4 size (21〇X297 mm) -10- 12924®ϊ 2Α 90129447 Chinese manual replacement page number Patent application Liang Guo 96 years October 3 曰 Amendment 5, invention description ^), the content of the content should be less than 0.3% by weight. The amount of the resin component to be used in the fireproof resin composition of the present invention should be from 1 to 15 parts by weight, based on the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). The parts by weight are desirably 1 to 5 parts by weight based on the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A·2) as 100 parts by weight. If the amount of the oxime resin becomes less than 0.1 parts by weight, satisfactory fireproof properties cannot be obtained, and if the amount exceeds 15 parts by weight, not only an improved fireproof property but also an appearance of the external molded product is expected. Deterioration effects, as well as deteriorating effects on optical transparency or intensity. In addition, harmful gases are produced when one of such enamel resins is burned. Phosphate compound (C)_. The compound represented by the following formula is used as a phosphate or a phosphate. 〇〇 (Please read the notes on the back and fill out this page) R1——Ο—— OR2 一X——OR3 -0——R4 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed in this formula, R1, R2 And R3, and R4 are each independently a hydrocarbon group and have 1 to 30 carbon atoms 'and preferably 1 to 5, and preferably a substituted or unsubstituted aromatic hydrocarbon group. If substituted, examples of the substituent include an alkyl group, an alkoxy group, an alkylthio group, a halogen, an aryl group, and an aryloxy group. Examples of R1, R2, R3, and R4 herein include a phenyl group, a toluonic acid group, a methyl group (such as a 2,6-xylyl group), and a trimethylphenyl group. a group, an ethylphenyl group, an anisyl group, and a butylphenyl group. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210X297 public) -29-

And excellent fire protection. The phosphate compound (C) compounded in the fireproof resin composition of the present invention should be used in an amount of from 1 to 30 parts by weight, based on the total of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). The amount is desirably 1 to 10 parts by weight per 100 parts by weight, and this is considered to be 100 parts by weight based on the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). If the amount of the phosphate compound (C) becomes less than 1 part by weight (sufficient fireproofing property is not obtained), and if it exceeds 30 parts by weight, the heat resistance property will be lost. Epoxy stabilizer (D). This epoxy stabilizer (D) can be further added to the fireproof resin composition of the present invention. Examples of such epoxy stabilizers include epoxidized soybean oil, epoxidized linseed oil, phenyl glyceryl ether, allyl glyceryl ether, tert-butylphenyl glyceryl ether, 3,4-epoxy Cyclohexylmethyl-3',4'-epoxycyclohexylcarboxylate, 3,4-epoxy-6-methylcyclohexylmethyl-3',4'-epoxy-6&quot; -Methylcyclohexylcarboxylate, 253-epoxycyclohexylmethyl-3',4'-epoxycyclohexylcarboxylate, 4-(3,4-epoxy-5-methylcyclo) Hexyl)butyl-3',4'-epoxycyclohexylcarboxylate, 3,4-epoxycyclohexylethylene oxide, cyclohexylmethyl-3,4-epoxycyclohexylcarboxylic acid Ester, 3,4-epoxy-6-methylcyclohexylmethyl-6&quot;-methylcyclohexyl carboxylate, bisphenol A diglyceryl ether, tetrabromobisphenol A glyceryl ether, o-decanoic acid Diglyceryl ether, diglyceryl ether of hexahydrophthalic acid, di-epoxydicyclopentadienyl ether, di-epoxy ethylene glycol, di-epoxycyclohexyl adipate, Butadiene diepoxide, tetraphenyleneethyl epoxide, octyl epoxy phthalate, epoxidized polybutadiene, 3,4-dimethyl-1 2-epoxycyclohexane, 3,5-dimethyl-1,2-epoxycyclohexane, 3-methyl-5-tri-butyl-1,2-epoxycyclohexane Alkane, octadecyl-2,2-dimethyl paper size applicable to China National Standard (CNS) A4 specification (210X 297 mm) gutter (read the first note on the back and fill out this page) -31 -

1292423 A7 ___ B7 V. Inventive Note (4 parts. For the optimization of hydrolysis resistance, the amount of epoxy stability test should be greater than 1 part by weight of 〇·〇. However, if the amount exceeds 1 〇, it is molded. The mechanical strength of the product will be affected. Dropping Prophylactic Reagent (E). The resin composition of the present invention may comprise an anti-dripping agent. The anti-separating agent is an additive used to suppress dripping during combustion, and any known In one embodiment, an anti-drip agent is used which forms a fine fiber structure in a polycarbonate-based resin, typically via polytetrafluoroethylene (PTFE) and a tetrafluoroethylene copolymer. (e.g., polytetrafluoroethylene/hexafluoropropylene copolymer). Among various types of polytetrafluoroethylene (PTFE), it is preferred that one has excellent dispersibility, such as emulsified and dispersed in aqueous solution of PTFE. Or a similar one, or a mixture in which PTFE has been encapsulated with a resin and the resin is typically a polycarbonate and a styrene-acrylonitrile copolymer, or a precursor of PTFE, and the resin is typically polycarbonate and benzene. Ethylene-propylene The nitrile copolymer because it will give a good surface appearance of the molded article composed of the polycarbonate composition, and is not particularly limited, if a material in which PTFE has been emulsified in a solution such as water or the like is dispersed. However, PTFE materials having an average particle size of less than 1 micron are desirable, in particular, using less than 0.5 microns. Considering the examples of commercially available PTFE materials, Teflon 3 0 J (trademark, M Itsubishi D u ρ ο n F1 u ο 1· 〇C li emica 1 s (K abushiki Kaisha (Mitsubishi Dupon Fluoro Chemicals)) Polyfl〇n D-2C (trademark, Daikin Kagaku Kogy〇 (Kabushiki Kaisha (Daikin Chemical Industries) )), Aflon D 1 (trademark, Asahi This paper scale applies to Chinese National Standard (CNS) A4 specification (21 〇 X 297 mm) Gutter (please read the note on the back and fill out this page) -33- 1292423 ' Jl: Μ Β7 5, invention description (j £, only "_zhong; 03 true '1 Gan 1, -7 Chang, 11 Xiaomeng, 2 乍土. ^

Co嗽Comparative Example 4 〇1 UO 1 1 un ο CO ο 120 240 C&lt;l 1 &gt; 45000 43000 Comparative Example 3 〇MD ΐ 1 { 1 un ο 1 s 106 &lt; ( ο 1 &gt; 45000 29000 Comparative Example 2 〇\〇1 1 1 υο Ο CO ο wo 106 τ—( 1 &gt; 45000 42000 Comparative Example 1 〇1 1 1 Ι/Ί Ο 1 uo 106 Vl 45000 30000 Example 3 〇VO 1 1 r _·Η ν〇 Ο CO ο 〇pq 106 m CO ο 1 &gt; 45000 42000 Example 2 〇1 r—H 1 ι/Ί Ο CO ο oo 109 V-0 45000 43000 Example 1 〇1~I 1 1 un Ο CO ο 106 Oo V-0 45000 93000 U ABS CR741S (phosphate) 矽 resin (Α-1) 矽 resin (A-2) 矽 resin (Bl) PTFE i epoxy stabilizer impact 撃 characteristics IZOD (kg / cm) load elastic Temperature (°C) UL94-1.6” Burning time-second UL rating starts from aging and constitutes hydrolysis resistance siisLU9.I® ίι9·ΐ (Γ --------- 衣----- -IT------^ (Please read the notes on the back and fill out this page.) This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm).

Claims (1)

1292423 A8 B8 C8 D8 Patent application scope 1 Annex 4A: Patent application No. 90 1 29447 Chinese patent application scope Replacement of the Republic of China October 3, 1999 Revision 1. A fire protection composition, including: a) Polycarbonate resin (A-1); b) thermoplastic resin (A-2) other than polycarbonate; oxime resin (B); d) phosphate compound (C) of the following formula: 〇•0——R4 (Please read the notes on the back and fill out this page) R1-Ο- OR2 R1, R2, R3, and R4 are each independently unsubstituted or trans-base, alkoxy, alkylthio a halogen, aryl or aryloxy substituted arene; χ is a C3 〇 divalent organic group which may contain an oxygen atom and/or a nitrogen atom: and m is an integer from 0 to 5; and e) a ring Oxygen Stabilizer (D), the ratio of the weight ratio of the polycarbonate resin (A-1) to the thermoplastic resin (A-2) (Al: A-2) is 99, printed by the Ministry of Economic Affairs, Intellectual Property Office, and the Consumer Cooperative. ··1 to 1: 99, the content of the oxime resin (B) is 0.1 to 15 parts by weight, which is considered as 1 in the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). 〇〇Parts of weight This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) A8 B8 C8 D8 1292423 VI. Patent scope 2 The content of the phosphate compound (C) is 1 to 30 parts by weight. The total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2) is taken as 1 part by weight, and the epoxy stabilizer (D) is contained. The amount is from 0.01 to 10 parts by weight. This is considered to be 1 part by weight based on the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). 2. The fire-retardant composition of claim 1, wherein the thermoplastic resin (A-2) is selected from the group consisting of: a) a polymer containing (a) an aromatic vinyl monomer component as a structural component thereof; b) a copolymer comprising (a) an aromatic vinyl monomer component and (b) a vinyl cyanide monomer component as a structural component thereof; c) a copolymer comprising (a) an aromatic vinyl monomer component , (b) a vinyl cyanide monomer component and (c) a rubber polymer as its structural component; d) an aromatic polyester; e) a polyphenylene ether; f) a polyether quinone imine; and g) a poly phenylene Base sulfide. 3. The fire-retardant composition of claim 1, wherein the thermoplastic resin (A-2) is selected from the group consisting of ABS resin (acrylonitrile-butadiene-styrene copolymer), AES resin (propylene) Nitrile-ethylene-styrene copolymer), ACS resin (acrylonitrile-chlorinated polyethylene-styrene copolymer), and AAS resin (acrylonitrile-acrylic elastomer-styrene copolymer). This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) I-:---一------------1T------Φ- (please first Please read the note on the back and fill in this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives Printed -2- 1292423 A8 B8 C8 D8 VI. Application for Patent Scope 3 (please read the «Precautions on the back page and fill in this page) [4] The fire-retardant composition of claim 1, wherein the oxime resin (B) contains at least two types of siloxane units, the siloxane unit selected from the group consisting of: a) 矽 oxygen exhibited by RSiCh” Alkane unit (T unit), b) Sand oxime unit (D unit) not exhibited by R2SiOi.G, c) 5 氧 oxygen unit (Μ unit) and e by R 3 S i 0 〇. A unit (Q unit) represented by Si〇2.〇, wherein R means a monovalent unsubstituted or substituted hydrocarbon group having 1 to 10 carbon atoms. 5. The fire-retardant composition of claim 4, wherein the resin (Β) is a) an anthracene resin comprising an anthracene unit and an anthracene unit, or b) an anthracene unit and an anthracene unit and a unit represented by the Q unit. An oxirane unit of oxime resin. 6. The fire-retardant composition of claim 4, wherein the thermoplastic resin (Α-2) is selected from the group consisting of ABS resin (acrylonitrile-butadiene-styrene copolymer), AES resin (acrylonitrile) Ethylene-styrene copolymer, ACS resin (acrylonitrile-chlorinated polyethylene-styrene copolymer), and AAS resin (acrylonitrile-acrylic elastomer-styrene copolymer). Printed by the Intellectual Property Office of the Ministry of Economic Affairs, Employees' Consumption Cooperatives 7. For the fire protection composition of Clause 4 of the patent application, the molecular weight of the bismuth resin is about 1000 to 50,000. 8. The fire-retardant composition of claim 5, wherein the aromatic group is present in a proportion of at least 20 mol%, based on the monovalent hydrocarbon group R contained in the above-mentioned oxime resin (B). 9. The fire-retardant composition of claim 1 wherein the phosphate compound (C) is bisphenol A-tetraphenyl diphosphate or bisphenol A tetracresyl diphosphorus. The paper scale is applicable to the Chinese national standard ( CNS ) A4 size (210X297 mm) -3- 1292423 A8 B8 C8 D8 VI. Patent application range 4 acid ester. (Please read the «Precautions on the back side and fill out this page again.) 10·If you apply for the fire protection composition of item 1 of the patent scope, the epoxy stabilizer (D) is 3,4-epoxycyclohexylmethyl- 3',4'-Epoxycyclohexanecarboxylate or bis-(3, substituted hydrocarbon group 4-epoxycyclohexyl) adipate. 11 • A fire protection composition according to item 1 of the patent application, further comprising an anti-drip agent (E). 1 2_ The fire-retardant composition of claim 1 of the patent scope, wherein the content of the anti-drip agent (E) is about 1 to 1 part by weight, and 1 part by weight of the polycarbonate resin is considered. (A-1) or 1 part by weight of the total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2). 1 3. The fireproof composition of claim 1, wherein the anti-drip agent (E) is polytetrafluoroethylene (PTFE). 14. An article comprising the fire-retardant composition of claim 1 of the patent application. 15. A method of making a fire-retardant composition comprising combining and mixing the following ingredients into a complex: f) a polycarbonate resin ( A-1); Ministry of Economic Affairs Intellectual Property Bureau employee Xiaohuang Cooperative printed g) Thermoplastic resin (A-2) other than polycarbonate; h) Neodymium resin (B); i) Phosphate compound of the following formula ( C): This paper scale applies to China National Standard (CNS) A4 specification (210X29*7 mm) -4- 1292423 A8 B8 C8 D8 VI. Patent application scope 5 0 R1-0-P* •X_ 〇-〇-R4 OR2 (please read the notes on the back and fill out this page) OR3 R1, R2, R3, and R4 are each independently unsubstituted or trans-chamber, alkoxy, alkylthio, halogen, aryl or aryloxy Substituted aryl aryl; χ is Ci to C3. a monovalent organic group which may contain an oxygen atom and/or a nitrogen atom; and m is an integer of 0 to 5; and e) an epoxy stabilizer (D), wherein the polycarbonate resin (A-1) The weight ratio of the thermoplastic resin (A-2) (Al: A-2) is from 99:1 to 1:99, and the content of the oxime resin (B) is from 0.1 to 15 parts by weight, which is considered to be polycarbonate. The total amount of the resin (A-1) and the thermoplastic resin (A-2) is 100 parts by weight of the Ministry of Economic Affairs, and the content of the phosphate compound (C) is 1 to 30 parts by weight. The total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2) is 1 part by weight, and the epoxy stabilizer (D) is contained in an amount of 0.01 to 10 parts by weight. The total amount of the polycarbonate resin (A-1) and the thermoplastic resin (A-2) was taken as 100 parts by weight. The method of claim 15, wherein the method further comprises the step of reducing the composition to form a particulate form. This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) -5 - 1292423 as B8 C8 __ _ D8 __ VI. Patent application scope 6 17 · The method of claim 15 of the patent scope, in which resin ( B) containing at least 2 types of oxoxane units selected from the group consisting of a) decane units (τ units) exhibited by RSiOu, b) decane units represented by RdiCh. (D unit), c) The decane unit (M unit) and j) shown by R3Si〇〇.5 are composed of Si〇2·. Shown in oxoxane units (Q units), wherein R means a monovalent terminally substituted or substituted hydrocarbon group having from 1 to 10 carbon atoms. 18. The method of claim 15, wherein the epoxy stabilizer (D) is 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexyl carboxylate or double _(3, substituted hydrocarbon group 4-epoxycyclohexyl) adipate. The method of claim 15, wherein the thermoplastic resin (A-2) is selected from the group consisting of ABS resin (acrylonitrile-butyl phthalate benzene acetal copolymer), AFS resin (acrylonitrile- Ethylene-styrene copolymer), ACS resin (acrylonitrile-chlorinated polyethylene-styrene copolymer), and AAS resin (acrylic acid acrylate copolymer). (Please read the notes on the back and fill out this page.) Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs -6 - This paper scale applies to the Chinese National Standard (CNS) A4 specification (210X297 mm)