TWI291855B - Active compound combinations having insecticidal and acaricidal properties - Google Patents

Description

1291855 A7 "_ ""R7 ---------- V. INSTRUCTIONS (1) ^ ^ The present invention relates to the inclusion of known cyclic ketoenols on the one hand and other A novel active compound composition of an insecticidal active compound which is highly suitable for controlling animal pests, such as insects and unwanted aphids. 5 Certain cyclic ketoenols are known to have herbicidal, insecticidal and killing agents. The nature of hydrazine. Although the activity of these substances is good, they are sometimes unsatisfactory at low application rates. Bicyclic 3-aryl-pyrrolidine with herbicidal, insecticidal or acaricidal effects - 2,4_2 Ketone derivatives (EP-A-355 599 and EP-A-415 211) and substituted monocyclic 3_aryl-pyrrole-2,4-dione derivatives (EP-A, 377 893 and EP) -A-442 077) is also known. It is also known as polycyclic 3-aryl-pyrrolidine 2,4-dione derivatives (EP-Α-442 073) and 1Η-aryl hydrazine. Rolanedione derivatives (ΕΡ_Α-456 063, ΕΡ-Α-521 334, ΕΡ-Α·596 298, ΕΡ-Α-613 884, ΕΡ-Α-613 15 885, WO 94/01 997, WO 95 /26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/3 5 646 WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43 275, WO 98/05 638, WO 98/06 721, WO 98/25 928, WO 99/16 748 WO 99/24 437, WO 99/43 649, WO 99/48 869 and 20 WO 99/55 673 〇 Further, a variety of heterocyclic compounds, organotin compounds, benzammonium and pyrethroids are known. Pyrethroids have insecticidal and acaricidal properties (see, WO 93/22 297, WO 93/10 083, DE-A-2 641 343, EP-A-347 488, ΕΡ-Α·210 487, US 3 364 177 and EP-A-234 045). However, the activity of these 25 substances may not be entirely satisfactory. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first) Matters fill out this page) Order----------: Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives Printed! 291855 A7 B7 V. Inventions (Currently found compounds of formula (1)

(I) B' Yl-i 广 / \M 5 where X represents dentate, alkyl, alkoxy, dentate, dentate or cyano, and W, Y and Z each independently represent hydrogen , dentate, alkyl, alkoxy, halogen, dentate, alkoxy or cyano, A represents hydrogen, in each case any acyl-substituted alkyl, alkoxyalkyl, saturated Any optionally substituted cycloalkyl group wherein at least one ring atom is optionally replaced by a hetero atom, B represents hydrogen or an alkyl group, and A and B together with the carbon atom to which they are attached represent a saturated or unsaturated, a substituted or substituted ring optionally containing at least one hetero atom, D representing hydrogen or an optionally substituted group selected from the group consisting of alkyl, alkenyl, alkoxyalkyl, saturated naphthenes a base in which any one or more ring atoms are replaced by a hetero atom, 2〇AU and its ship-connected liver-calling-saturated or unsaturated ring, which is unsubstituted or _ in the A ' D portion And optionally containing at least one hetero atom, (5 represents hydrogen (a) or represents one of the following base rings 10 15 (c), /SO^R3 •4· paper Zhang 钱 钱 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ l#, rS (8), Ϊ291855 A7 B7, invention description, the intellectual property of the hammer department, X consumer cooperation, social printing 10152025 R° VN: E(f) where E represents a metal ion or an ion, L represents oxygen or sulfur , M represents oxygen or sulfur, and R 1 represents an alkyl group, an alkenyl group, an alkoxyalkyl group, an alkylalkyl group, a polyalkoxyalkyl group or any of which is substituted by a cyano group in each case. a cycloalkyl group substituted with an alkyl group or an alkoxy group, which may be inserted by at least one hetero atom, in each case optionally substituted phenyl, phenylalkyl, heteroaryl, phenoxyalkyl or a heteroaryloxyalkyl group, R2 represents an alkyl group, an alkenyl group, an alkoxyalkyl group, a polyalkoxyalkyl group or a ring which is optionally substituted in each case in any case. An alkyl group, a phenyl group or a benzyl group, R3 represents an arbitrary alkyl group substituted by a dentate or an optionally substituted phenyl group, and R4 and R5 each independently represent each case. Any alkyl, alkoxy, alkylamino, dialkylamino, alkylthio 'enylthio' cycloalkylthio group substituted by halogen or an optionally substituted benzene in each case a group, a phenoxy group or a phenylthio group, and R and R7 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkoxy group, an alkoxy group, which is independently substituted by a halogen in each case. An alkyl group, which represents an optionally substituted phenyl group, which represents an optionally substituted ilino group or an N atom to which it is attached represents an optionally substituted or

V (g), (please read the notes on the back and fill out this page) «^1 ·ϋ ϋ ϋ ϋ n n*^OJe n ϋ I n 1 ϋ 1 ,

National Standard (CNS) A4 specification (210 X 297 mm) 1291855

A7 _ B7_ V. Ring of invention (4), which can be optionally inserted by oxygen or sulfur, and pyrethroids, preferably 1 · acrinathrin is disclosed in ΕΡ-Α·048 186 and / or 10 2. alpha_cypermethrin (Please read the notes on the back and fill out this page)

Printed by the Intellectual Property Office of the Ministry of Economic Affairs and the Consumer Cooperatives. Revised in EP-A-067 461 and / or 3 · β-Secretary (betacyfluthrin)

-6- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm)

I 291855 A7 B7 V. INSTRUCTIONS (and/or 4. cyhalothrin)

CN Revealed in DE-A-2 802 962 and / or 10 5 · cypermethrin

15 Revealed in DE-A-2 326 077 and / or 6· (5 - mitre (deltamethrin) (please read the note on the back and fill out this page) Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs 20

Revealed in DE-A-2 326 077 and / or 25 7- esfenvalemte This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 〇Ο [291855 A7 B7 V. Invention Description (6) 10

Revealed in DE-A-2 737 297 and/or 8. ethofenprox °Ό

(Please read the notes on the back and fill out this page)

Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

Revealed in DE-A-3 117 510 and / or 9 fenpropathrin 15 disclosed in DE_A-2 231 312 and / or 20 10 fenvalerate 25 disclosed in DE-A-2 335 347 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 V. Description of invention (7 and / or 11 · Flucythrinate 10 15

揭示 Revealed in DE_A_2 757 066 and / or 12 · again - lambda-cyhalothrin H3C \ /CH,

13. Permethrin (please read the note on the back and fill out this page) Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs 20 25 and/or

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) [291855 V. Description of the invention (8) A7 B7 14. Taufluvalinate

°Ό 5 Revealed in EP-A-038 617 and/or 15. tralomethrin 10

XJ (please read the note on the back and then fill out this page) Revealed in DE-A-2 742 546 and / or 16. ^ _ Zepo-cypermethrin 15

Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs, 20 25 Rev. EP-A_026 542 and/or 17. Cyfluthrin

10- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 _ B7 V. Invention description (9) and/or 18·二凡旋 (bifenthrin)

Revealed in EP-A_049 977 and / or 19. cydoprothrin

Revealed in DE-A-2653189 and / or 20, eflusilanate (please read the notes on the back and fill out this page)

I I · .1 n n n n n n-^°4 n ϋ n n ϋ I Printed by the Intellectual Property Office of the Ministry of Economic Affairs

Revealed in DE-A_36 04 781 and / or 25 21. fUbfenprox -11- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 V. Description of invention (1 ())

5 Revealed in DE-A_37 08 231 and / or 22. 吼 ( (pyrethrin)

(Please read the notes on the back and then fill out this page) R=-CH3 or ·0:Ο2(:Η3, ^ or·<:η3 or -ch2ch3 Revealed in the Pesticides Handbook, 1997, 11th edition, 1056 pages and / or

Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives 20 The mixture disclosed in GB-A-1 168 797 has excellent insecticidal and acaricidal properties. Surprisingly, the insecticidal and acaricidal activity of the active compound compositions according to the invention is significantly greater than the sum of the activities of the individual active compounds. Therefore, there is a real synergistic effect that is unpredictable, not just 25. -12- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) I291855

V. DESCRIPTION OF THE INVENTION (η) Printed by the Ministry of Economic Affairs, Intellectual Property Office, Employees' Cooperatives The active compound composition according to the present invention comprises at least one active compound of Compounds 1 to 23 in addition to at least one tongue compound of the formula (1). 5 Preferred active compound compositions are those comprising a compound of the formula (I), wherein each group is defined as follows: ^ preferably represents hydrogen, CrCr alkyl, CrCV methoxy, gas, bromine or fluorine, and X preferably represents Ci_C4 -Acetyl-CVC4-alkoxy, C1-C4--glycol, fluorine, gas or bromine, 1〇Y and Ζ each independently represent hydrogen, CrC4-alkyl, halogen, CrC4-alkoxy or CrC4· Haloalkyl, A represents hydrogen or in any case substituted by halogen;: broad (: 6-alkyl or c3_c8_cycloalkyl, B preferably represents hydrogen, methyl or ethyl, 15 A, B together with the carbon atom to which it is attached represents a saturated cycloalkyl group, wherein any one of the ring atoms is replaced by oxygen or sulfur and any of them are calcined by CrCV, trimethyl or CrCr alkoxy Or disubstituted, D preferably represents hydrogen, in each case any Cl_20 alkyl group substituted by fluorine or gas, C3_C4_alkenyl or C3-C6-cycloalkyl, A and D are preferably represented on each In the case of any of the c3_CV alkanediyl groups substituted by a methyl group, wherein any one of the methyl groups is replaced by a sulfur, G preferably represents hydrogen 0) or represents one of the following groups 25 9 L 2 R4(9),(6),/so?~r3 (6),7/',# (e), (Please read the notes on the back and fill out this page) Order --------- t. -13· 1291855 A7 V. INSTRUCTIONS (12) E(f) or Vv' R6 v (g) 10 15 Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs 20 25 Special Representatives (a), (b), (c) or (g) wherein, E represents a metal ion or a monoammonium ion, L represents oxygen or sulfur, and yttrium represents oxygen or sulfur, and preferably represents any CrCi〇_alkyl group C2_Ci〇 substituted by a functional element in each case. _ dilute, C1-C4-alkoxy "Cl-C4-alkyl" C1-C4-sulphur sulfur S_Ci_C4·alkyl or any substituted by fluorine 'gas' C1-C4-alkyl or CrCV alkoxy C3-C6-cycloalkyl, representing any fluorine, gas, bromine, cyano, nitrate, CrO alkyl, > CrC4-alkoxy, trifluoromethyl or trifluoromethoxy substituted phenyl And represents a pyridyl or thienyl group substituted by any gas or methyl group in each case, and R2 represents an arbitrary CrCi〇-alkyl-C2-C1G-dilute group substituted by fluorine or gas in each case. , C1-C4-alkoxy-C2-C4-alkyl group represents any Methyl or methoxy substituted C5_c6_cycloalkyl, or any of the fluorine, chlorine, bromine, cyano, nitro, Crc4-alkyl, CrCr alkoxy, trifluoromethyl groups in each case Or a trifluoromethoxy substituted phenyl or benzyl group, R3 preferably represents any fluorine substituted by CrC4_alkyl or represents any fluorine, gas, desert, C1-C4-alkyl, C1-C4-burned Oxyl, trifluoromethyl, trifluoromethoxy, cyano or nitro substituted phenyl, • 14· R1 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --- ---------- (Please read the note on the back and fill out this page) Order: 1291855 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (13) R4 should be represented on each In any case, any Ci-C4·Huan group substituted by gas or gas, CrC4_^oxy group, C1-C4-alkylamino group 'C1-C4-sulfuryl group or any fluorine which is represented in each case , gas, bromine, nitro, fluorenyl, crc4-decyloxy, trifluoromethoxy 'crc4-sulphur-based 'C" 5 C4__sulfuryl, CrCV or trifluoromethyl substituted benzene Phenoxy or phenylthio R5 preferably represents CVC4-alkoxy or CrCV, and R6 represents CrC6-alkyl, C3-C6-cycloalkyl, CrC6-alkoxy, C3·Ce-cation, Ci-C/r The base-Ci-C4-alkyl group 10 R7 preferably represents CVC6-alkyl, CrC6-alkenyl or CrC4-alkoxy-CrCr alkyl, and R6 and R7 are preferably represented by an arbitrary methyl or ethyl group. C3-C6, alkylene, wherein any one carbon atom may be replaced by oxygen or sulfur, W is particularly suitable for hydrogen, methyl, ethyl, gas, bromine or methoxy, 15 X is particularly suitable for gas, Bromine, methyl, ethyl, propyl, isopropyl, methoxy 'ethoxy or trifluoromethyl, Y and Z each independently represent hydrogen, fluorine, gas, bromine, methyl, ethyl, propyl , isopropyl, trifluoromethyl or methoxy, A particularly suitably represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl 20, t-butyl, t-butyl, ring a propyl group, a cyclopentyl group or a cyclohexyl group, B is particularly suitably represented by a hydrogen, a methyl group or an ethyl group, and A 'B is particularly suitably represented by a carbon atom to which it is attached, which represents a saturated c6_cycloalkyl group, wherein any one ring An atom can be replaced by oxygen and its The meaning of 25 is methyl, ethyl, methoxy, ethoxy, propoxy or butoxy-15^ This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 锖Read the notes on the back and fill out this page)

1291855 A7 B7 V. INSTRUCTIONS (14) Monosubstituted, 〇 particularly suitable for hydrogen, representing methyl, ethyl, propyl, isopropyl, butyl 'isobutyl, allyl, cyclopropyl, ring The pentyl or cyclohexyl group, VIII and D together are particularly suitable for representing any C3_C4-alkanediyl group substituted by a methyl group, and G is particularly suitably represented by hydrogen (a) or one of the following persons (b), human 2(6) , Ge 0 (9), Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative 10 where M stands for oxygen or sulfur, 'R1 is particularly suitable for CrCr base, CrCV alkenyl, methoxymethyl, ethoxymethyl , ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl, 15 represents any fluorine, gas, bromine, cyano, nitro, methyl, ethyl 'methoxy, trifluoromethyl or A trifluoromethoxy-substituted phenyl group, which represents any pyridyl or thienyl group substituted by a gas or a methyl group in each case, and R2 is particularly suitably represented by a CrC alkyl group, a C^Cr alkenyl group, a methoxy group B. a group, 20 ethoxyethyl or representing a strepyl or benzyl group, R6 and R7 are each independently suitably suitably represent a methyl or ethyl group, or a It represents an alkyl group in which the methyl group is replaced by oxygen. W is most suitable for hydrogen or methyl, X is most suitable for gas, bromine or methyl, and 25 Y and Z are each independently suitable for hydrogen, gas, bromine or methyl, -16·

------------— (Please read the notes on the back and fill out this page) - Order:

P 1291855 A7 B7 V. INSTRUCTIONS (15) A 'B and the carbon atom to which it is attached _ is most suitable for the saturation of the ring-ring group' where 'any ring element can be replaced by oxygen and its armor Mono, methoxy, ethoxy, propoxy or butoxy is monosubstituted, D is most suitable for hydrogen, and G is most suitable for hydrogen (a) or one of the following

〇A R1 (b), person (g). 10 15 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 20 Among them, M stands for oxygen or sulfur, Han is the most suitable and represents Ci-Cs-burning 'CrCir thin base, methoxy Methyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl, or ' represents any fluorine, gas, methyl, methoxy, trifluoromethyl 'Trifluoromethoxy, cyano or nitro substituted stupyl, representing any acridinyl or thienyl group substituted by a gas or methyl group in each case, R2 most preferably represents crc8-alkyl, crc4- Alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl, R6 and R7 each independently independently represent methyl, ethyl or together represent a C5-alkylene group, wherein the C3-extension The methyl group is replaced by oxygen. 17- X 297 mm) (Please read the notes on the back and fill out this page) IP®· A7 1291855 Β7 V. Invention description T )

Particularly suitable active compound compositions are those containing the following formula (1) _ example number WXYZRG melting point °c 1-1 Η Br 5-CH3 H OCH3 CO-1-C3H7 122 1-2 Η Br 5-CH3 H OCH3 C〇2 -C2H5 140-142 1-3 Η ch3 5-CH3 H OCH3 H >220 Μ Η ch3 5-CH3 H 〇CH3 C〇2-C2H5 128 1-5 ch3 ch3 3-Br H OCH3 H >220 1- 6 ch3 ch3 3-C1 H OCH3 H 219 1-7 Η Br 4-CH3 5-CH3 OCH3 CO-1-C3H7 217 1-8 Η ch3 4-C1 5-CH3 OCH3 C〇2C2H5 162 1-9 Η ch3 4 -CH3 5-CH3 OCH3 r~\ CO—N Ο Oil 1-10 ch3 ch3 3-CH3 4-CH3 OCH3 H >220 Ml Η ch3 5-CH3 H OC2H5 r~\ CO—N 0 \ / Oil 1- 12 ch3 ch3 3-Br H 〇c2h5 CO-1-C3H7 212-214 1-13 Η ch3 4-CH3 5-CH3 oc2h5 CO-n-Pr 134 1-14 Η ch3 4-CH3 5-CH3 oc2h5 CO-i -Pr 108 1-15 Η ch3 4-CH3 5-CH3 oc2h5 CO-c-Pr 163 The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, prints and at least one of the active compounds in compounds 1 to 23. In addition, the active compound composition may also contain other fungicidal, acaricidal or insecticidal active ingredients. If the active compound is present in the active compound composition according to the invention in a specific weight ratio, the synergistic effect is particularly pronounced. However, -18- This paper scale is applicable to China National Standard (CNS) A4 specification (210 297 297 mm) 1291855 Α7 Β7 5. Inventive Note π) The weight ratio of the active compound in the active compound composition can be quite large. Changes between scopes. In general, the composition according to the present invention contains the active compound of the formula (I) and the mixed component in a preferred and particularly preferred mixing ratio as shown in the following table. The mixing ratio is based on the weight ratio. It should be understood that the ratio refers to the active compound of the formula (I): the mixed component of the mixed component is preferably a mixing ratio which is particularly suitable, the mixing ratio of enalapril 20:1 to 1:50 10:1 to 1:1 α-plug Pomeranian 50:1 to 1:5 10:1 to 1:1 cold-plug cycloid 50:1 to 1:5 10:1 to 1:1 squirrel 50:1 to 1:5 10:1 to 1:1 Sippod 50:1 to 1:5 10:1 to 1:1 5 - Flavor 50··1 to 1:5 10:1 to 1:1 Evan Verre 50:1 to 1: 5 10:1 to 1:1 Idovaph 10:1 to 1:10 5:1 to 1:5 Van Pupa 10:1 to 1:10 5··1 to 1:5 Van Ville 20: 1 to 1:5 10:1 to 1:1 fluoro-Serm 50:1 to 1··5 10:1 to 1:1 λ - Halogen 50:1 to 1:5 10:1 to 1:1 Pu Mi Xuan 10:1 to 1:10 5:1 to 1:5 Tafirui 20:1 to 1:5 10:1 to 1:2 Chuanlong Mi 50:1 to 1··5 10:1 To 1:1 f - Sippo 50:1 to 1:5 10:1 to 1:2 Swing 50:1 to 1:5 10:1 to 1] 2:10:1 to 1:10 10:1 to 1:1 Circumference 10:1 to 1:10 5··1 to 1:5 Eflurane 10:1 to 1:10 5··1 to 1:5 Feng Fanpu 10:1 To 1:10 5:1 to 1:5 -19- The paper scale With China National Standard (CNS) A4 size (210 X 297 mm) (Please read the cautions on the back of - · I I Page) Light · Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed 1291855 A7

V. INSTRUCTIONS INSTRUCTIONS 0) The mixing ratio of the mixed components is particularly suitable for Quinbi. You can rotate 50:1 to 1:1〇5:1 to 1:1 瑞咪旋------- 50:1 to 1:10 5:1 to 1:1 Ministry of Economic Affairs Intellectual Property Office Staff Consumption Cooperative Printed The active compound composition according to the invention is suitable for controlling animal pests, especially arthropods and nematodes, especially in agriculture, in animals. Health, in the forest, in the protection of stored products and substances and in insects and spiders found in the health category. It is active against five classes of generally sensitive and resistant species and is active for all or individual stages of development. The above pests include: Isopoda, for example, 〇niseusaseUus, Armadillidium vulgare and Porcellic scacalc. Ίο倍足目, for example, Blaniulus guttulatus 〇 lip-foot, for example, eating fruit, home. Comprehensive outlines, for example, there is no point in the family. Two-tailed, for example, western piranha. 15 The tail of the bullet, for example, the thorns. Orthoptera, for example, family baboons, baboons, Asian locusts, long-necked scorpions, and swarms. Insects are not eye-catching, for example, Oriental lynx, American cockroach, Madhya, German cockroach. 20 Genus, for example, the European ball. Isoptera 'for example, termites. Attention, for example, head lice, beast 虱, long 颚虱, feather 虱, Amarine -20 - table paper scale for T-country national standard (CNS) A4 specification (215 x 297 public) * - ( Please read the notes on the back to write this page. Η Η 订 - - 1291855 A7 B7 V, invention description p) (Damalinia spp). Thysanoptera, for example, greenhouse thrips, mangkin horses, brown horses, thrips 0 Heteroptera, for example, Chinese brown-bone bee, Dysdercus 5 intermedius, beet nets , bed bugs, South American bed bugs, bloodsucking scorpions. Homoptera, for example, pinch whitefly, cotton dustpick, greenhouse whitefly, cotton aphid, cabbage, medlar, scorpion, broad bean, apple stalk, apple scorpion, peach scorpion, big scorpion (Phylloxera vastatrix), 瘿 蚜 蚜, wheat long tube 蚜, tumor front 蚜, menthol frontal 蚜, millet tube 蚜, leaf 蝉, two leaf 蝉, 10 black-tailed 蝉, 蚧 wax 蚧, helmet 蚧, rice ash fly虱, rice brown planthopper, red round 蛉, Aspidiotus hederae, powder correction, hibiscus. Lepidoptera, for example, red bollworm, pine mites, Cheimatobia brumata, Lithocolletis blancardella, cherry nest moth, diamondback moth, larvae, Euproctis chrysorrhoea 15 , poisonous moth; cotton leaf perforated moth, orange fine moth, night moth, cutting rootworm, brown moth, Egyptian diamond, cotton bollworm, cabbage moth, Panolis flammea, sticky insect, pink Noctuid moth, apple moth, pink butterfly, rice mold, Pyraru ta (Pyrausta nubilalis), Ephestia kuehniella, Great wax mites, Coat Moth, Nettle 2 moth 'Brown moth Cacoecia podana, Capua reticulana, spruce leaf moth, grape fruit moth, lobster moth, green leaf moth, rice vertical filling, rice negative worm. Coleoptera 'for example, home plagiarism, Rhizopertha dominica, covered bean, soy elephant, family beetle, Agelastica alni, potato aphid, cochlear leaf, Leaf, Amaranth Blue-21- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back -11· 1""" this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1291855 A7 B7 V. Invention description β) Jumping armor 'Mexican bean ladybug, Atomaria spp, saw chest thief, weevil, valley elephant, longitudinal groove elephant A, banana 蛀 曱 曱, 甘 荚 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲, Valley 5 Pirates, Yellow Powder A, Armor, Golden Needle, Horned Golden Tortoise, June Golden Turtle, Costelytra zealandica, Rice Weevil. Hymenoptera 'for example, horned bee, leaf bee, field ant, kitchen ant, big wasp. Diptera, for example, Aedes, Anopheles, Culex, Lepidoptera, housefly, scorpion fly, red-headed fly, green fly, round scorpion, reins, stomach rope, reins 10 (Hyppobosca spp·) , sling rope, nose rope, skin snail, burdock, small leaf roller moth, Bibio hortulanus, Swedish straw rope, glass fly, beet leaf miner, Mediterranean fruit fly, olive fruit fly, European big mosquito, Fly, leper. Attention, for example, Oriental groin, Mao Lian. 15 Arachnidae 'For example, Scorpio maurus, and black widow ball spider, thick feet full of 'hidden monument, ear wreckage, chicken skin thorns, grape 瘿 ' 'orange rust worm, dish蜱, fan 蜱, 蜱, Hyalomama spp, hard 蜱, itchy, 恙螨, 蚧螨, 螨, 苜蓿 moss, Xenopus, 螨, 半, 螨. 20 Plant-parasitic nematodes include, for example, the genus Pratylenchus spp. 'Perennial nematode, Ditylenchus dispsaci, semi-penetrating nematode, Heterodera, Coccidia, C. elegans 'C. elegans, Longidorus spp., S. cerevisiae, Trichodonus spp., Bursaphelenchus spp. -22- This paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) (please read the notes on the back n >_1 I · ϋ ϋ item fi! Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Ministry of Economy, Intellectual Property Office, Staff and Consumers Cooperative, Printed 1291855 Δ7 Α7 Β7 V. Description of the Invention π) The active compound composition can be converted into a conventional preparation, for example, a solution, an emulsion, a wettable powder, a suspension, a powder, Powder, paste, soluble powder, granules, suspension-emulsion concentrate, natural and synthetic substances infused with active compounds, and microcrystalline gel 5 capsules in polymeric materials. These formulations are prepared in a known manner, for example by mixing the active compound with a extender, which is a liquid solvent and/or a solid carrier, optionally using a surfactant which is an emulsifier and/or dispersant And/or a bead forming agent. 10 If the extender used is water, an organic solvent such as an organic solvent may also be used. Essentially, the following are suitable liquid solvents: aromatics, for example, xylene, toluene or alkylnaphthalene, gasified aromatic or gasified aliphatic hydrocarbons such as benzene, vinyl chloride or aerobic, Aliphatic hydrocarbons, for example, cyclohexane or paraffin, for example, mineral oils, mineral oils and vegetable oils, alcohols 15 such as butanol or ethylene glycol and ethers and esters thereof, ketones such as acetone , methyl ethyl ketone, decyl isobutyl ketone or cyclohexanone, a strong polar solvent such as dimethylformamide and dimethyl sulfoxide, or water. Suitable solid carriers are: for example, money salts and ground natural minerals such as kaolin, clay, talc, 20 chalk, quartz, activated clay, montmorillonite or diatomaceous earth, and ground synthetic materials, for example, highly dispersed Vermiculite, alumina and citrate; suitable solids for granules are: for example, crushed and graded natural rock, for example, calcite, marble, pumice, sepiolite and dolomite, or inorganic and organic powders Synthetic granules, and particles of organic matter, for example, wood chips, 25 coconut shells, corn cobs and tobacco rods; suitable emulsifiers and/or foams -23- This paper scale applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm)

1291855 A7 B7 V. INSTRUCTIONS f The Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives are: for example, non-ionic and anionic 彳L1匕 swords, examples of ethyl fatty acid esters, polyoxyethylene ethyl esters Alcohol ethers, such as private gifts = PEG-based, pharmaceutically acceptable acid esters, alkyl phthalate aryl esters or protein hydrolysates; suitable dispersing agents are: for example 〃 5 - sulfite waste Liquid and methylcellulose £ Adhesives can be used in the formulation, for example, carboxymethylcellulose and natural and synthetic polymers, which can be in powder, granule or lattice form, such as acacia, polyvinyl alcohol and poly Ethyl acetate, or natural fat, such as cephalin and lecithin, and synthetic phospholipids. Other additives may be _ 10 oils and vegetable oils. Dyes such as inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal titanium cyanine dyes, and micronutrients such as iron, may also be used. Sewing, shed, copper, beginning, key and zinc salts. 15 Formulations usually contain 0.1 and 95 weights. The active compound in the daytime is preferably between 0.5 and 90%. The active compound compositions according to the invention can be present in the form of commercially available ones and in the form of use prepared from these formulations, which are in combination with other active compounds, such as insecticides, attractants, fungicides, A mixture of bacteria 20, acaricide, nematicide, fungicide, growth regulating substance or herbicide. The insecticides include, for example, acid esters, amine carbamates, carboxylates, chlorinated hydrocarbons, phenylureas, and substances produced by microorganisms. It may also be a mixture with other known active compounds, such as herbicides or with fertilizers and growth regulators. -24- This paper size is applicable to China National Standard (CNS) A4 specification (210x297 mm). Arylsulfonic acid lignin (please read the notes on the back first. Line · 1291855 A7 B7 V. Invention description ί3 ) In the case of insecticides, the active compound compositions according to the invention may also be presented in the form of a commercially available formulation and a use form prepared from these formulations, which is a mixture comprising a synergist. A synergistic agent is a compound which enhances the action of the active compound, and the added synergist itself does not necessarily have to be active. The active compound content of the use forms prepared from commercially available formulations can vary over a wide range. The active compound concentration of the use form may range from 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight. 10 This compound is used in the usual manner suitable for use. When used to combat pests of sanitary pests and stored products, the active compound composition is distinguished by good residual action on wood and clay and good stability to alkali on the lime material. The active compound composition according to the invention is active not only against 15 pests of the plant, but also for pests of sanitary pests and stored products, and also for veterinary use for animal parasites (exoparasites), such as hard-walled, soft-walled虱, 蚧螨, autumn harvest locusts, flies (thorns and crickets), parasitic flies larvae, chaos, head wind, birds 5L and are active. These parasites include: chaos, for example, bloody wind, long wind, wind (pedieuius Spp), chaos 20 (Phtirus spp·), blind wind. The genus and the obtuse and suborders, for example, the flamingo, the short-horned bird, the giant hair, the 'Werneckiella spp·', and the Lepikentron spp. 'Damaiina Spp.', Trichodectes spp., Felic〇la spp. 25 pairs of eye-catching and line-headed suborders and short-horned suborders, for example, Aedes aegypti, Anopheles mosquitoes, library-25- This paper scale applies to China National Standard (CNS) A4 specifications (21〇X 297 public) (please Read the notes on the back ^^ Write this page) Order: Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed 1291855 A7 ________B7 Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed five, invention instructions f) mosquitoes, cockroaches, true cockroaches, white蛉, 罗蛉, mosquito, flower bud, Hybomitra spp·, Atylotus spp., black burdock, blind pheasant, Philipomyia spp·, bee Rope, home rope, tooth rope, reins, horn rope, Morellia spp., reins, tongue rope, 5 rope, green rope, gold rope, dirt can, meat rope, nose rope, leather Rope, stomach rope, coiled rope, fat rope (Lipoptena spp.), woven, eye-catching, for example, genus, scorpion scorpion, squirrel, scorpion, genus, genus, for example, bed bug, bloodsucking wax sister , cone 蝽, full cone 蝽. Attention, for example, the East _ 蠊, the American cockroach, the German cockroach, the disc. 10 蜱 (Aphis gossypii) and post-and mid-valve suborders, for example, concealed, blunt edge, deafness, hard palate, calyx, calf, leather monument, blood-stained sputum (Haemophysalis spp· ), long beard, fan head, prickly thorns, deafness, lung thorn end, side gas end (Sternostomaspp·), tile _. Radiation insects (pre-valve sub-mantle) and powder worms (no valve sub-mantle), examples 15 such as 螨, 攫螨, 螫螨, 螨, 疥螨, Demodex, 恙螨, 桃'Powder snail, brewed scorpion, Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., itch, skin, ear螨, to (Notoedres spp·), 疥螨 (Knemidocoptes spp·), 拖 待 ( (Cytodites 20 spp·), chicken 螨. The active compound compositions according to the invention are also suitable for controlling agricultural livestock, such as cattle, sheep, goats, horses, pigs, magnetics, road rides, buffalo, rabbits, chickens, turkeys, ducks, geese, bees, other livestock, For example, dogs, depictions, caged birds, water tank fish and so-called laboratory animals, such as the big cheeks, the day 25 moles 'big mouse and small mouse arthropods. By controlling these movements -26· (please read the notes on the back first)

__良i I · Reference paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 V. Invention description zhang 5 5 10 5 1 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 20 The reduction in death and production (in meat, milk, wool, hides, eggs, honey, etc.) can be made more economical and more simplistic by the use of the active compound compositions according to the invention. The active compound composition according to the invention is in a known manner by means of tablets, capsules, beverages, veterinary drugs, granules, pastes, granules, ingestion-passing methods, suppositories Internal administration, for example by injection (intramuscular, subcutaneous, intravenous, transabdominal, etc.), implantation, nasal administration, for example, infiltration or medicated bath, spraying, pouring, dipping, main washing, The type of dusting and transdermal administration by means of a molding containing the active compound, such as a loop, an ear tag, a tail tag, a limb band, a chest pocket, a marker device or the like. When used in cattle, poultry, livestock, etc., the active compound composition may contain from 1 to 80% by weight of the active compound formulation or directly after dilution of 100 to 10,000 times (eg, powder, emulsion, fluid) Used, or it can be used as a chemical immersion liquid. Furthermore, it has been found that the active compound composition according to the present invention exhibits an insecticidal action against insects which are industrially resistant to soiling. The following insects are mentioned as examples and are preferred, but are not intended to be limiting: beetles, such as the family beetle, the geranium, the cockroach, the Xestobium rufovillosum, the tianbi worm (ptiiinUs pecticomis), 丹宾波尼虫 (0如〇1^1»11?61^11^), erbin mulberry pentium 111 (^118 111〇1), 湃bica worm (Priobium) Carpini), European bamboo meal, African bamboo meal, Lyctus linearis, Lyctus pubescens 'Trogoxylon aequale, Minsruco -27- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back II first!! again) · .线 - 1291855 A7 Ministry of Economic Affairs Intellectual Property Bureau staff consumption Cooperative printing _____B7___ V. Invention description 矽) (Minthes rugicollis), Otaru, Tryptodendron spec·, Apate monachus, Bostrychus capucins, Heterophyllum , Sinoxylonspec (Sinoxylonspec), bamboo long scorpion. The leather is eye-catching, such as the 5-steel tree bee, the giant tree bee, the Urocerus gigas taignus, and the Urocerus augur. Such as super-objectives, such as termites, Cryptotermes brevis, Heterotermes indicola, termites, Reticulitermes santonensis, Reticulitermes lucif Ugixs , Australian termites 'Zotermopsis nevadensis, white bay-like termites, bristles, for example, western piranha. Industrial materials should be understood in this context to refer to non-living substances. For example, 15 should be polymers, binders, adhesives, paper and board, leather, wood, wood products and coatings. Substances that need to be protected against insect damage, especially wood and wood products 0 can be protected with a composition according to the invention or a mixture thereof. 20 should be understood, for example: construction timber, wooden beams, railway sleepers , bridge components, jetties, wooden carts, boxes, rafters, containers, telephone poles, wooden slats, wooden windows and wooden doors, plywood, clip-on notes, fine woodwork, or wood often used for building or building wood products product. 25 The active compound composition can be used as such, in the form of a concentrate or -28- (please read the note on the back of the page IIII). Order: --Line - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 297 297 mm) 1291855 A7 Β7 V. Inventive Note P) 5 ο il 5 lx Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 20-I-formed formulas such as powders, _, solutions, suspensions, emulsions Or use as a slurry. The aforementioned formulations may be prepared in a manner known per se, for example, by combining the active compound with at least one solvent or diluent, emulsifier, dispersant and/or binder or chelating agent, if desired, It is stable with desiccant and υν, and if you want to mix with dyeing pigments and other preparations. The insecticidal composition or concentrate for the protection of wood and wood products comprises from 0.0001 to 95% by weight, in particular from 〇〇1 to 6 重量%, of the active compound according to the invention. The amounts of the compositions and concentrates used are based on the type and number of insects and on the basis of the medium. The optimum amount to be used in each case can be determined by the test series at the time of application. However, it is usually sufficient to use 0.0001 to 20% by weight, preferably 〇·_ to 1% by weight, of the active compound, depending on the substance to be protected. Suitable solvents and/or diluents are organic chemical solvents or solvent mixtures and/or oily or oily organic chemical solvents or low volatility solvent mixtures and/or polar organic chemical solvents or solvent mixtures and/or water, and, if appropriate , emulsifiers and / or wetting agents. The organic chemical solvent to be preferably used is an oily or oily solvent having an evaporation number greater than 35 and a scintillation point greater than 3 (rc, preferably greater than 45. These oily and oily solvents are insoluble in water and are Low volatility and its user's being a suitable mineral oil or its aromatic or mineral oil-containing solvent, preferably petroleum solvent, petroleum and / or alkyl benzene. Mineral oil is more conducive to use For those with 170 to 22 〇t; fulfilment -29- (please read the note on the back again - page) - line · This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printing V. Illustrated V) Scope: 170 to 22 (TC solvent range, petroleum solvent, with a boiling range of 250 to 350 ° C, with 16 〇 Petroleum and aromatic to the boiling point range of 28〇〇c, oil of tripentyne, etc. In a preferred embodiment, a liquid aliphatic hydrocarbon having a range of from 18 to 21 (r) can be used or has 18高 to 22 (TC high boiling point mixture of aromatic and aliphatic tobaccos at the boiling point of TC and/or Sub-oil and/or mono-naphthalene, preferably mono-naphthalene. Low volatility and organic oil or oil-based solvent with a number of evaporation greater than 35 and a flash point greater than 3 〇〇c, preferably greater than 45 C Substituted by a high or medium 10 volatile organic chemical solvent, but the solvent mixture also has an evaporation number greater than 35 and a flash point greater than 3 (rc, preferably greater than 45 〇c), and the mixture is soluble or emulsifiable In this solvent mixture, in a preferred embodiment, some organic chemical solvents or solvent mixtures may be replaced by an aliphatic polar organic chemical solvent or solvent mixture. It is preferred to use a trans- and/or vine-based and/or Or an ether-based aliphatic organic chemical solvent, for example, a glycol ether, an ester, etc. The organic chemical dryness agent used for the purpose of the present invention is a synthetic resin and/or a dry dry oil known per se and It may be diluted with water and/or dissolved or dispersed or emulsified in the organic chemical solvent used, in particular, or contains the following dot-polymers, acrylic resin, ethylene-based resin, for example, polyvinyl acetate acetate, Poly vine tree Fat, polycondensation or polyaddition resin, polyurethane urethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin, such as / coumarin _ fat, Shi Xi _ fat, dry Phyto and/or dry oils and/or physical dry-drying agents (based on natural and/or synthetic resins) 15 20 >5 (Please read the note on the back I ϋ I 1 I item wSBR page) - Line - -30- 1291855 A7 Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Printed B7______ V. INSTRUCTIONS V) The synthetic resin used as a binder can be used in the form of an emulsion, a dispersion or a solution. Up to 10% by weight of bitumen or bituminous material can also be used as the binder. Further, dyes, pigments, water repellents, deodorants, and inhibitors or preservatives, etc., may be used, all of which are known per se. According to the invention, the composition or concentrate preferably comprises at least one alkyd resin or modified alkyd resin and/or dry vegetable oil as an organic chemical binder. Alkyd resins which are preferably used in accordance with the invention are those having an oil content of more than 45% by weight, preferably from 50 to 68% by weight. Some or all of the above binders may be replaced by a fixing agent (mixture) or a plasticizing agent (mixture). These additives are used to prevent the volatility of the active compound, as well as crystallization or precipitation. It is preferred to replace 0. 01 to 30% of the binder (based on 100% of the binder used). The plasticizer is derived from the chemical species of phthalate esters, such as dibutyl phthalate, dioctyl phthalate or benzyl butyl phthalate, phosphates, such as, for example, tributyl phosphate. An adipate such as bis-(2 ethylhexyl)-adipate sulphate, for example, butyl stearate or pentyl stearate oleate, for example , butyl oleate, glycerol ethers or higher molecular weight glyceryl ethers, glycerides and oxime sulfonates. The fixing agent is a polyvinyl alkyl ether as a chemical substrate, for example, a poly(vinyl)methyl group, or a ketone such as benzophenone and vinylbenzophenone. Further suitable solvents or diluents are, in particular, water, if appropriate, a mixture with one or more of the abovementioned organic chemical solvents or diluents, emulsifiers and dispersing agents. Particularly effective wood protection methods are achieved by industrial scale impregnation procedures such as vacuum, double vacuum or pressurized procedures. -31- This paper size applies to the Chinese National Standard (CNS) A4 regulations x 297 metric tons) --- "~ face (please read the notes on the back - order: -- line. -n 1· III - 1291855 A7 B7 V. INSTRUCTIONS Ρ) It is also possible to use the active compound composition according to the invention to protect objects which are in contact with water or water, such as hulls, screens, nets, buildings, mooring systems and signalling systems, Anti-adhesion. Due to oligochaetes, such as Serpulidae, and due to shellfish 5 and Ledamorpha species (goose attachments), for example, various types of Lepas and Skapi (Scalpellum) species, or the Balanomorpha species (acorn attachment), for example, the attachment of Balanus or Pollicipes, will increase the friction of the vessel and It will result in increased operating costs due to more energy consumption and will result in additional recurring residency at dry terminals. In addition to the attachment caused by steaming, for example, Eet〇carpus species and Ceramium species, the Entomostraka group is derived from the name Chripedia. The attachment system caused by the genus (the crustacean) is extremely important. Surprisingly, it has now been found that the active compound compositions according to the invention have exceptional anti-adjunct effects. When the active compound composition according to the invention is used, it is possible to dispense with a J heavy metal such as a bis(dialkyltin) sulfide, tri-n-butyltin ruthenium, and a tri-n-butyl ketal. Cuprous oxide (1), triethyltin chloride compound, tri-n-butyl (2-phenyl-4_gas phenoxy) kick, tribasic tin oxidation|material '=can' oxygen (four)' polymerization Purified butyl titanate, phenyl biguanide, bis-n-butyltin fluoride, bis-dithioamino U zinc di-flydithiocarbamic acid 8 Thioamine g A day '2' sulfur and gamma oxide zinc salt and copper salt, didimethyl ^ I _ -32- t paper size applicable @ (CNS) A4 specifications (2W χ tear public meal? ---

1291855 A7 --------- Β7 Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing 5, Invention Description C1) Dithiocarbamylcarbenyl zinc bisthiocarbamate, zinc oxide , copper (I) vinyl bis bis dithiocarbamate, copper thiocyanate, copper naphthenate and tributyl tin dentate, or can substantially reduce the concentration of these compounds. If appropriate, the ready-to-use anti-adhesion coating may additionally comprise other 5 active compounds, preferably algicides, fungicides, herbicides, molluscicides, or other anti-adhesion active compounds. A suitable component to be incorporated in the anti-adhesion composition according to the present invention is: an algicide such as 10 2 -t-butylamino- butyl propyl propylamino-6 thiol-1,3, 5-three tillage, dichlorophen, diuron, endothal, fentine acetate, isopr〇turon, methabenzthiazuron, 〇xyfluorfen, quinoclamine and terbutryn; 15 fungicides, such as benzo[b]thiophenecarboxylic acid cyclohexyl decylamine S, S-dioxide, Dichlorfluanid, fluorfolpet, 3-iodo-2·propynylbutylcarbamate, phenylphenyl fluoride and sputum, such as azaconazole, Cyproconazole, hexaconazole, hexaconazole, metconazole, propiconazole and tebuconazole; molluscicides such as fen Butyl acetate, methazine, methocarb, niclosamid, thiodicarb and trimethacarb; 25 or conventional Anti-adhesive active compounds, such as -33- (please read the precautions on the back and write this page first) a. π 订 -· • Line · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 V. INSTRUCTIONS (2) 4,5-dioxa-2·octyl-4-isothiazolyl-3-one, diiodomethyl to paratryl base, 2-(N, N-dimethylthioaminomethyl sulfhydryl)-5-nitrothiazyl (thiazyl), 2-pyridylsulfurate 1-potassium potassium, copper, sodium and zinc salts, bite-triphenyl Boronate, stannoxane, 2,3,5,6-5 tetrakis-4-(methylsulfonyl)-pyridine, 2,4,5,6_tetraisoindole Nitrile, tetramethyl thiuram disulfide and 2,4,6-trisylphenylmaleimide. The anti-adhesion composition used comprises from 0.001 to 50% by weight, particularly from 0. 01 to 20% by weight, of the active compound composition according to the invention. Further, the anti-adhesion composition according to the present invention contains conventional components, such as those disclosed in Ngiri, Chem. Ind. 1985, 37, 730-732 and Williams, anti-adhesive marine coating, Noah. , Park Ridge, 1973. In addition to the algicidal, fungicidal, molluscicidal active compound and insecticidal active compound according to the invention, the anti-adhesion coating comprises, in particular, a binder. Examples of the identified binders are polyvinyl chlorides in a solvent system, chlorinated rubbers in a solvent system, acrylic resins in a solvent system, especially in an aqueous system, vinyl gas/ Ethylene Acetate Copolymer 2〇 system 'in aqueous dispersion or in organic solvent system type, butadiene styrene/acrylonitrile rubber, dry oil, such as linseed oil, resin vinegar or modified hardened resin' Combined with tar or dice blue 'tar and epoxy compounds, a small amount of gas rubber, gasified polypropylene and vinyl. If appropriate, the coating may also contain inorganic dyes, organic dyes or pigments, which are preferably soluble in salt water. Materials may also be included in the coating, for example -34- This paper scale is applicable to China National Standard (CNS) A4 specification (21〇X 297 mm) (please read the notes on the back 1· ϋ I again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1291855 A7 __B7 V. Invention Description 5 10 5 11 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 20 25 Rosin to control the release of active compounds. Further, the coating may contain a plasticizer, a modifier to affect the flow characteristics and other conventional components. The compound according to the invention or the aforementioned mixture may also be incorporated into an automatic retouching anti-adhesion system. The active compound compositions are also suitable for controlling animal pests, particularly insects, arachnids and mites, which are found in areas such as 'homes, factory areas, offices, cars and the like. It can be used in household insecticidal products to control these pests. It is effective against sensitive and resistant species and against all stages of development. These pests include: Odonata, for example, Buthus occitanus. Attention, for example, Persian sharp edge, pigeon sharp edge, moss, chicken skin hedgehog, home sweet food medium, white blunt edge, blood red fan head, Ashizhen true turn, Newpiou end ^6111 :1<01111^111&&111:1111111&1丨8), house dust worm, dust _. The spider's eye, for example, Li Gula lacks 7 spiders, spiders. The genus Anopheles, for example, Pseudoscorpiones chelifer, Psendoscorpiones cheiridium, Opileones phalangium, Isopoda, for example, Oniscus Asellus) 'P〇reellio scacalc 〇 亚 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' The lip and the eye, such as the soil. Zygentoma, for example, scorpionfish, western squid, Lepismodes inquilinus. Attention, such as Oriental 蜚蠊, German 蠊, Shahi Naha, Madeira 35- (please read the notes on the back and write this page first) · Ben··-Line - This paper size applies to China National Standard (CNS) A4 Specification C210 X 297 mm) 1291855 A7 B7 V. Description of Invention (4) Suspected 'panchl〇ra spp.', parco bata moth (pare〇biatta spp·) Australia is a big suspicion, the Americas are too big, the brown moth, the smoke is too big, the long beard. Jumping, for example, the family. 5 leather, such as the European ball. Such as super-heads 'for example, termites, oriental termites. Calling insects, for example, Lepinatus spp., Book. Sheath super-eyes, for example, skin lice, black skin mites, skin mites, long-headed pirates, Guogong worms, spider mites, Dominican pea elephants, valley elephants, rice elephants, corn elephants, medicinal herbs valley 10 thieves. Double-eyed, for example, Aedes aegypti, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Red-headed scent*, Yuma-Ji's Culex pipiens, Culex pipiens, Culex pipiens, Drosophila, yellow Abdominal toilet flies, house flies, white pelicans, carnivorous flies, cockroaches, cockroaches, European mosquitoes. 15 scales, such as small wax mites, large wax mites, Indian glutinous rice, Tineacloacella, nettle moth, sacking moth. Attention, for example, the dog's head licking, the cat's head licking, the cockroach, the skin squatting, the eastern groin. Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, printed film super-eye, for example, Penang black ant, black grass ant, common black ant, dark ant 20 (Lasius mnbratiis), kitchen ant, Paravespula spp , paving ants. Attention, for example, head lice, body lice, haze. Exotic suborders, for example, tropical bedbugs, temperate bed bugs, South American bed bugs, Triatoma infestans 〇25 are used in aerosols, non-pressure spray products, such as pumps and sprayers -36- paper scale Applicable to China National Standard (CNS) A4 specification C210 X 297 public) 1291855 A7 ___ B7 V. Invention description 0) Spray, automatic fogging system, humidifier, bubble, gel, evaporator product, which has Evaporator sheet made of fiber or polymer, liquid evaporator, gel and membrane evaporator, propeller-driven evaporator, energy-free, or passive evaporation system, moth paper, moth bag and moth glue, granules Or powder, on 5 bait or in the bait area. According to the invention, all plants and parts of plants can be treated. It is meant herein that a plant refers to all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants can be obtained by the method of cultivation and the best method 10 or can be obtained by biotechnology and genetic engineering methods or a combination of these methods, including plants for gene transfer and including plant breeders, the rights can be protected or not Protected plant plants. It should be understood that the part of the plant refers to all above-ground and underground parts and tissues of the plant, for example, buds, leaves 'flowers and roots, and may be mentioned as leaves, needles, stems, stems, flowers, fruits. 15 bodies, fruits and seeds as well as roots, tubers and rhizomes. Portions of the plant also include harvestable plants as well as vegetal and productive reproductive materials such as seedlings, tubers, rhizomes, branches and seeds. According to the present invention, the use of the active compound for the treatment of plants and plants is carried out by the Ministry of Economic Affairs, the Intellectual Property Office, the employee consumption cooperative, printed directly or according to the conventional treatment method, and the building or storage area, for example, borrowing In the case of collapse, spray, evaporation, fogging, dissemination, application, and in the case of a thin material, particularly in the case of seeds, one or more layers of coating may be applied. As mentioned in the text, 'which can treat all plants according to the invention and 25 = a better specific cost, is to deal with wild plant species and plant strains, or those derived from borrowing biological breeding methods, such as hybrid or native -37-

1291855 A7 B7 V. INSTRUCTIONS INSTRUCTIONS 10 15 Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives 20 25 Quality Fusion, and its parts. In another preferred embodiment, the genetically engineered gene transfer plants and plant strains are processed, and if appropriate, the methods can be combined with the methods of Genetically Modified Organisms and their fractions. ''Parts',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Or the plant of the plant strain used. Depending on the plant species or plant strain, its location and growth conditions (soil oxygenation, growth period, nutrient arrangement), the treatment according to the invention may also produce a For example, it is possible to achieve an increase in the application rate and/or an increase in the activity spectrum and/or an increase in the activity of the substances and groups used according to the invention, a preferred plant growth, an increase in the high temperature or low temperature. The resistance of the 'tolerance' improves the tolerance to dryness or salt content in the soil, increases the flowering performance, facilitates the harvest, accelerates the ripening, and compares the yield of the harvested product with the better quality and/or High nutritional value, better storage stability of the harvest product and/or better harvest product processability, which exceeds the actual expected efficacy. The preferred and will be treated according to the invention for gene transfer plants or plant changes (that is Some of the genetically engineered products include all plants that have been subjected to the excellent utilization characteristics that can be imparted to these plants in the base towel. These characteristics are preferred for plant growth, for high temperatures or for Resistant to the succulent or increased salt content of water or soil, the improved flowering performance, the easier harvest, the higher yield of the cultivating m Γ, the better quality and / or higher Better storage stability and / or better harvest -38- <Please read the following notes on the back page: Booking · Line · —国国1291855 A7 ______________ B7 Ministry of Economic Affairs Intellectual Property Office staff Printed by the Consumer Cooperatives V. Inventives F) 5 10 5 11 20 25 Product processing. Other examples of these characteristics and special emphasis are on plants against animal and microbial pests, for example, against insects, mites, plant pathogens. Good resistance to mold, bacteria and/or viruses, and increased tolerance of plants to specific compounds to be removed. Examples of gene transfer plants that may be mentioned are important crop plants, for example, cereals (small) , rice), corn, soybeans, potatoes, cotton, oil rafts and fruit plants (including fruit apples, pears, citrus fruits and grapes), and special emphasis on waxy corn, soybeans, potatoes, cotton and oil 芸A special emphasis on the plant's enhanced defense against insects by the toxins formed by the plant, especially those formed by genetic material from Bacillus thuringiensis (for example, by the gene CrylA (a) ), CrylA(b), CrylA(c), CryllA, CrylllA, CryIIIB2, Cry9c / Ciy2Ab, Cry3Bb and CrylF, and combinations thereof (hereinafter referred to as "Bt plants"). It is also necessary to specifically emphasize the specific elimination of plants. The increased resistance of the active compound, for example, astringent, sulfonamide, glyph〇sate or phosphinotricin (eg, the "PAT" gene). The genes that are discussed to confer the desired characteristics can also be combined with another one on the gene transfer plant. Mention may be made of "Bt plants, such as corn varieties, cotton varieties 'soybean varieties and potato varieties, which are sold under the trade name, YIELD GARD® (eg, corn, cotton, soybeans), Kn〇 Ck〇ut13 (for example, corn), StarLink® (for example, corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato) are sold. It can be mentioned that the herbicide-tolerant plants are Maize varieties, cotton varieties and soybean varieties, which are tolerant to glyphosate under the trade name R〇undup Ready%, for example, corn, cotton, soybean), Liberty Link❿ (resistant to phosphino-trisin) Responsive, for example, oil 芸-39- (please read the notes on the back and then.%!) Page -----Book---------Line · This paper scale applies to Chinese national standards (CNS) A4 specification (210 X 297 public) 1291855 A7

V. INSTRUCTIONS P) 110_^_§_125 Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Cooperative, 'IMI8 (for the taste side) and STS8 (for the performance of the urea and the object) (4) Plants cultivated by sex) include strains sold under the trade name 2 (for example, corn). Of course, the statement is also used for /, plant variants with these characteristics or genetic characteristics to be developed' These plants will be developed and/or marketed in the future. The plants listed can be treated according to the invention with a particularly advantageous mixture according to the invention. The preferred range of the abovementioned mixtures also applies to & The special active insecticidal and killing effects of the active compound compositions according to the invention can be understood from the following examples, although individual active compounds are shown to be useful in the art and in the treatment of plants. A weak scent that acts as a scent, and the scented scent shows more than the sum of the effects of the simple action. When the effect of the active compound composition exceeds the sum of the effects of the individual application of the active compound, it will always present The synergistic effect of insecticidal and butterfly-killing insects. Using the following SR·Keby, Weedsil (1967), formula 20-22, the desired effect of the composition of the two active compounds given to hydrazine can be calculated: The lethality when using the active compound A at an application rate of 1 g/ha or m is indicated by % of the untreated control group, and Y is used at a concentration of 〇g/ha or n卯(5). The lethality rate of active compound B is expressed as % of the untreated control group, and E is the application rate of i and g/ha or [and ^ ppm concentration of -40- (please read the back) Note I Page: - Line · This paper size applies to China National Standard (ONS) A4 specification (21" 297 mm) 1291855 A7 B7 V. Description of invention) Lethality of active compounds A and B If the % of the treatment control group is expressed, then E=X + Y- XY ioo-5 If the actual insect killing rate exceeds the calculated value, the role of the character is added, that is, the synergy is presented. Effect. In this case, the actual observed fatality rate must exceed the use of the above listed The expected lethality (E) is calculated. After the desired period, the mortality rate is determined. 100% of the animals with 掮10 are killed; 〇% means no animals are killed. Read the back of the article >1 and then I page); Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -4 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 1291855 A7 B7 V. INSTRUCTION DESCRIPTION 4 use the actual 4L example cotton aphid test solvent: emulsifier: 3 parts by weight of dimethylformamide 1 part by weight of alkyl aryl polyglycol ether in order to form a suitable active compound preparation, 1 part by weight of the active compound is combined with the amount of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. The cotton leaf (Gossypium hirSUtUm), which is seriously infected with Aphis gossypii, is immersed in the active compound preparation of the desired concentration. After the desired period, determine the % of death. 100% of all animals were killed; 〇% means that no cotton aphid was killed. The measured lethality was calculated using the Kirby formula. In this test, for example, the following active compound compositions according to the invention have synergistic and enhanced activity when compared to the individual active compounds: 15 (Please read the notes on the back 丨l1^^· 11 pages) ·--Line· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed-42- 1291855 A7 B7

V. INSTRUCTIONS INSTRUCTIONS )1) Table A Tests for insects that are harmful to plants. Test compound active compound concentration (ppm) Mortality after six days % Examples 1-10 are known in WO 97/36868 1.6 0 75 Example 1-10+ Plug Cyclotron (1:1) According to the invention 1.6 + 1.6 Measured value* Calculated value ** 95 75 * Measured value = measured activity 5 ** Calculated value = activity calculated using the Kirby formula (Please read the following notes on the back wfW to write this page) ·. --Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -43- This paper scale applies China National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 V. INSTRUCTIONS 5 10 15 Example g Tumor forehead test solvent: 3 parts by weight of decyl decyl lining agent: 1 part by weight of aryl aryl polyethylene glycol is called for generation - appropriate For the preparation of the active compound, i parts by weight of the active compound are combined with the amount of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. The cabbage leaf (B_ica 〇ι_), which is seriously infected with Taocai (Peach Red), is treated by dipping in the active compound preparation of the desired concentration. After the desired period, the lethality is determined. 1%% refers to All animals were killed; 0 was difficult to predict which animals were killed. The measured lethality was calculated using the Kirby formula. In this test 'for example' the following active compound compositions according to the invention黯 ( ( 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四-4 • 121 ( /V grid 1291855 A7 B7

V. INSTRUCTIONS INSTRUCTIONS <3) Table B Insectomas harmful to plants. Test for active compound concentration of active compound (ppm) % of death after one day Example 1-10 is known from WO 97/36868 1.6 0 Know 1.6 25 Example 1-10+ Plug Cyclotron (1:1) According to the invention 1.6+1.6 Measured value* Calculated value # 65 25 * Measured value = measured activity 5 ** Calculated value = calculated using the Kirby formula Ministry of Active Economy, Intellectual Property Bureau, Staff Consumer Cooperative, Printed 45-

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1291855 A7 B7 V. Description of invention (44)

Example C Critical Concentration Test / Soil Insect-Gene Transfer Plant Treatment Test See Insect · Cucumber Leaf Leaf Aphid Solvent in Soil Solvent: 7 parts by weight of acetone 5 emulsifier · 1 part by weight of alkyl aryl group Glycol ether To form a suitable active compound preparation, 1 part by weight of the active compound is mixed with the amount of solvent, the amount of emulsifier is added and the concentrate is diluted with water to the desired concentration. The active compound preparation is poured into the soil. Herein, the concentration of the activated 10-compound in the preparation is practically irrelevant, and the relevant is only the weight of the active compound per unit volume of soil (it is stated in ppm (mg/L) that h is filled with 025 liters of the tank. And after standing at 20 ° C, immediately put 5 YIELD GUARD (trademark of Monsanto, USA) into the pre-germinated corn for 15 in each jar. After 2 days, the relevant The test insects were placed in the treated soil. After 7 days, the exposed corn plants were counted to determine the efficacy of the active compound (1 plant = 20% efficacy). -46- This paper scale applies to Chinese national standards ( CNS)A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) Order---------^ Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1291855 Ministry of Economics Intellectual Property Bureau employee consumption cooperative printed A7 ------- B7__- _ V. Invention description (45)

Example D Treatment of plants of the American tobacco moth, the gene transfer plant: 7 parts by weight of acetone emulsifier · 1 part by weight of alkyl aryl polyethylene glycol y 5 In order to produce a suitable active compound preparation, 1 Parts by weight of the active compound are mixed with the amount of solvent and the amount of emulsifier and the concentrate is diluted with water to the desired concentration. The large bean sprout (Glycine max) of the Roundup Ready strain (trademark of Monsanto, USA) was treated by dipping in the active compound preparation of the desired concentration 10 and was implanted with tobacco, the tobacco budworm, while the leaves were still wet. Determine the lethality of the insects after the desired time. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page)

Claims (1)

£ 12 Tm _, this % 8·3i year Q replenishment without A8 B8 Six application patent scope κχ Patent application No. 90115342 = ROC Patent Appln. No. 90115342 The text of the patent application scope without correction after the correction - Annex (3) Amended Claims in Chinese - Rnd (TTR (Submitted on August 31, 2007) (Submitted on August 31? 2007) A composition for controlling animal pests, which comprises a compound of formula (I) 5 G (I) ο 1X 5 1X Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed clothing 20 WXYZRG Η Βγ 5-CH3 H 〇CH3 CO-1-C3H7 Η Βγ 5-CH3 H OCH3 C〇2-C2H5 Η ch3 5- CH3 H OCH3 H Η ch3 5-CH3 H och3 C02-C2H5 CH^ ch3 3-Br H och3 H ch3 ch3 3·α H 0CH3 H Η Βγ 4-CH3 5-CH3 OCH3 CO-i-C3H7 Η ch3 4-Cl 5-CH3 OCH3 c〇2c2h5 Η ch3 4-CH3 5-CH3 OCH3 r~\ CO-N^一〇ch3 ch3 3-CH3 4-CH3 OCH3 H Η ch3 5-CH3 H oc2h5 r~\ CO—一〇ch3 Ch3 3-Br H 〇c2h5 CO-i-C3H7 Η ch3 4-CH3 5-CH3 oc2h5 CO-n-Pr Η ch3 4-CH3 5-CH3 oc2h5 CO-i-Pr Η ch3 4-CH3 5-CH3 oc2h5 CO -c-Pr and a mixture of at least one of the following compounds: acrinathrin -48 - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 90253B-connected to I 5 5 , 8 IX .9 2 .,1 8 8 8 8 AB c D VI. Patent application α-cypermethrin β-cyperthrin γ- cyhalothrin 塞波 17米旋(cypermethrin) 5 δ-味旋(deltamethrin) 凡普巴旋(fenpropathrin) λ-塞卤(Lambda-cyhalothrin) ζ · Seppo taste spin (zeta-cypermethrin) plug brush rotation (cyfluthrin). 10 2. The composition of claim 1, which comprises a compound of formula (I), 15 Z G (I) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 20 Among them, ▽, 乂, 丫, verb, 11 and 0 are each defined as follows. WXY z RG Η ch3 5-CH3 H OCH3 H ch3 ch3 3-CH3 4-CH3 OCH3 H 3 · A method for controlling animal pests, characterized by the action of a composition as defined in claim 1 or 2 On animal pests and / or their habitat. -49 - This paper size is applicable to China National Standard (CNS) A4 specification (210x 297 mm)