TWI277505B - Method for processing surface of a fiberglass reinforced plastic composite material - Google Patents

Method for processing surface of a fiberglass reinforced plastic composite material Download PDF

Info

Publication number
TWI277505B
TWI277505B TW95104347A TW95104347A TWI277505B TW I277505 B TWI277505 B TW I277505B TW 95104347 A TW95104347 A TW 95104347A TW 95104347 A TW95104347 A TW 95104347A TW I277505 B TWI277505 B TW I277505B
Authority
TW
Taiwan
Prior art keywords
glass fiber
reinforced plastic
fiber reinforced
plastic material
treatment method
Prior art date
Application number
TW95104347A
Other languages
Chinese (zh)
Other versions
TW200730337A (en
Inventor
Sz-Shu Sung
Li-Fang Shr
An-Jou Liu
Original Assignee
Carbonlab Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carbonlab Inc filed Critical Carbonlab Inc
Priority to TW95104347A priority Critical patent/TWI277505B/en
Application granted granted Critical
Publication of TWI277505B publication Critical patent/TWI277505B/en
Publication of TW200730337A publication Critical patent/TW200730337A/en

Links

Abstract

This invention relates to a method for processing surface of a fiberglass reinforced plastic composite material, so as to render plural fiberglass patterns, colors or pattern variations. The method for processing surface of a fiberglass reinforced plastic composite material of this invention includes the steps of: firstly, providing a fiberglass reinforced plastic sheet, coating a surface shaping plastic film on the fiberglass reinforced plastic sheet; secondly, placing the two in a mold; thirdly, heat pressing the two under a vacuumed state to bond and join the two, thereby forming a fiberglass reinforced plastic sheet having a predetermined shaping on a surface thereof; and then cooling the fiberglass reinforced plastic sheet, opening the mold to remove the processed fiberglass reinforced plastic sheet.

Description

1277505 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種玻璃纖維補強塑膠複合材料,尤其 是關於一種於該玻璃纖維補強塑膠複合材料表面進行處 理,藉以呈現多種玻璃纖維紋路顏色或圖案變化之方法。 【先前技術】 在一般複合材料中,以玻璃纖維作為補強材 (reinforcement)係其中最為普遍之一種成型方式,事實 上,藉其所成型之玻璃纖維補強塑膠(flber glass rdnf〇rced plastics,FGRP)亦是複合材料製品中用途最為廣泛的一 種。藉由玻璃纖維之加入補強,可使原本剛性或強度不高 之塑膠,大幅改善其物性,而得用作結構材料,加上其具 有質量輕、強度佳、可塑性強,且能耐潮、抗腐蝕等絕佳 特f生,舉凡航太、船舶、運輸、建材、電子、電哭等役備 結構中皆有其應用。 玻璃纖維補強塑膠的原材主要包括:基材(matrix)、 作為補強·材(reinf0rcement)之玻璃纖維與副資材。玻璃 、、截維係在使成品具有高強度與高剛性(彈性係數),而基 材則係形成所欲形狀結構之形塑材料,其包覆並保護玻璃 ^維免於磨損或受破壞,並於玻賴維間傳遞、分散所承 党之負荷,使成品具有耐壓強度。基材係由不同的的脂 種類或比例,加入填料後加工形成各式各樣的塑膠類型, 而麵成之轉-般可分為熱塑性_㈤刪咖s㈣ 5 1277505 或熱固性塑膝(thermosetting plastics )。 €知破璃纖維補強塑膠係將玻璃纖維與樹脂以手積 曰去(hand lay,)或樹脂注入法(代如㈣⑽丨加,RJ)等 f式加以結合,經常溫或加熱等步驟,最後固化成型。於 邊成型過程中,玻璃纖維因吸收樹脂而呈半透明狀,因而 使該種玻璃纖維㈣_無法呈現出原錢維編織或鋪 *之、文路而喪失其纖維紋路所能呈現之特殊表面造型。 ^此’為了表賴述玻璃纖維所編織錢排之特殊紋路, 冒有將玻璃纖維加以染色之發明創作,然而該種方式,僅 =合補強材之原色加以呈現,故其所得表現之紋路或顏 色,化係相當有限且鮮調。後來雖進—步有於樹脂中添 藉以改變整體之外觀顏色,但其結果卻導致樹脂 明又降低,故仍然無法有效凸顯玻璃纖維之紋路與色 維^此^知玻璃纖維補強卿複合材料,其在玻璃纖 而不現上亚不理想,致使其美觀性與特殊性不足, =易被進—步剌於外觀性要求較高 件應用範圍無法獲得擴張或延 更八 【發明内容】 紋路=!::Γ:補強塑膠複合材料,其玻璃纖維 :壬継之缺點,使該破螭纖維所編織钱排之纹路 造型得以清楚呈現,並同時1右〜域#之、,文路 _ τ,、有多種顏色或圖幸變化,太 务明將提供一種於破j离纟'、 之方本μ目主戴、、隹補強塑膠表面進行加工處理 之方法,猎由一具表面造型之 』膠,專胰,改進原本無法清 ^277505 1 纖維fif路之缺點’並藉由該表面造型之塑膠薄膜 使纖維紋路呈現不因里9田该表面造型之塑膠薄膜, 膠複合材料得進_二二’使破璃纖維補強塑 同時藉由其所達成之纖維呈現:= 冗品,^ 1 ^材枓’而得減低製程中原材所需之成本。 發明玻璃纖維補強塑膠材 列步驟:⑴跡杨處财法,包括下 義涵二 纖維補強塑膠板;(2)於該玻璃 、截、,隹補強塑膠板上方覆蓋 所表面造型塑膠賴;⑶將 二内,於真空狀態下進行熱壓,使所述 _ ί雜Γ相接合,形成—表面具有預定造型之玻璃纖維補 望恥材,(4)冷卻該玻璃纖維補強塑膠材;以及(5)開 啟該模具,將該玻璃纖維補強塑膠材取出。其中,該玻璃 纖維補強瓣板係-玻璃纖維熱雜轉,而該表面 造型塑膠薄膜亦係-熱塑性塑膠,但並不以此為限,其亦 可同時選自熱固性塑膠。當該玻璃纖維補強塑膠板與該表 面造型塑膠薄膜皆係熱塑性塑膠時,該玻璃纖維補強塑膠 板可為一玻璃纖維補強聚對苯二甲酸乙二醇酯 (polyethylene terephthalate,PET)之複合材料,而該表面 造型塑膠薄膜則可為一聚對苯二曱酸乙二醇醋,但並不以 此為限’其他例如·丙細猜-丁二稀丙稀-苯乙稀共聚物 (acrylonitrile butadiene_styrene,ABS)樹脂、聚丁烯對苯 二甲酸酯(polybutylene terephthalate,PBT)、聚笨硫_ (polyphenylene sulfide,PPS)、聚醚酰亞谬(polyether imide,PEI )、聚丙稀(polypropylene,PP )、聚酿胺 1277505 (polyamide,nylon)、聚乙稀(polyethylene,PE)、聚苯乙 稀(polystyrene,PS )、聚氯乙烯(polyvinyl chloride,PVC ) 或聚碳酸酯(polycarbonate,PC)等亦可作為本發明方法 之加工材料。 藉由本發明之處理方法,僅需將所欲呈現造型之造型 塑膠薄膜,覆蓋於玻璃纖維補強塑膠板後進行熱壓,無庸 透過黏合劑,即可將所述二者以自行鍵結(self-bonding) 之方式相互接合,在工序上係相當簡單,所需成本亦相當 低。經接合後之玻璃纖維補強塑膠材,透過造型塑膠薄膜 所呈現之顏色或圖案,配合以玻璃纖維補強塑膠板之纖維 紋路,不但可清楚呈現出原有纖維之紋路,更可呈現出玻 璃纖維整體特殊顏色、漸層色或圖案之表現變化,使本發 明方法得以產製具多種表面效果之玻璃纖維補強塑膠 材’使其應用範圍更為廣闊。 以下將配合圖式進一步說明本發明的實施方式,下述 • 所2舉的實施例係用以_本發明,並非用以限定本發明 之範圍’任何熟習此技藝者,在不脫離本發明之精神和範 當可做些許更動與潤飾,因此本發明之保護範圍當 ~ 視後附之申請專利範圍所界定者為準。 【實施方式】 請时參閱第-圖料二圖,第—_本發明實㈣ ^法之流程不賴’而第二_本發明實關 強塑膠材表面處理方法之示咅圖。 歎、,隹汗 丁心園本發明之玻璃纖維補5 1277505 舜·^_表面處理方法’主要係將—表面造型塑膠薄膜10 =盖;—_纖維補強塑膠板2()上後,進行熱壓加工處 本么月貫知例之處理方法,包括下列步驟:(1)提供 玻离:::隹補強塑膠板sl〇; (2)於該玻璃纖維補強塑膠 扳上方覆蓋以—表面造型塑膠薄膜S20; (3)將所述二者 置於一模具内,於真空狀態下進行熱壓S3G,使所述二者 鍵結相接合,形成—表面具有預定造型之麵纖維補強塑 膠材,(4)冷卻S40該玻璃纖維補強塑膠材;以及(5)脫 模⑽,將該玻璃纖維補強塑膠材由該模具中取出。其中, 熱壓、冷卻與脫·步驟,係—㈣界制之技術,於此 並不進一步說明。 於本發明實施例中,由於玻璃纖維補強歸板盘表面 造型塑膠薄膜間,無庸透過黏合劑而僅需以加埶方式,即 ^將二者以自行鍵結之方式相域合,故在工序上相當簡 单’所需成本亦相#低。經接合後之玻璃纖維補強塑膠 材’即可作為各種類型產品之材料,其再經二次加工熱壓 成=S60成預定之形狀後’即可產製出具有所欲顏色或圖 案、交化表面之玻璃纖維補強塑膠產品。 本發明實施例中,玻璃纖維補強塑膠板2〇係一玻璃 纖維補強?請苯二甲酸乙二醇g旨(pET)之複合材料,而 表面,型塑膠薄膜U)其材質則為—聚對苯二曱酸乙二醇 酯,前述二者基材皆為熱塑性塑膠,但本發明並不以此為 限’ 5亥—者亦得同屬熱固性塑膠。 ' 9 1277505 ’ 玻璃纖維補強塑膠板20,其並不僅限於PET材質, 其亦可為其他工程塑膠(engineering plastics),例如·丙 烯腈-丁二烯丙烯-苯乙烯共聚物(acrylonitrile butadiene-styrene,ABS )樹脂、聚丁烯對苯二甲酸酯 (polybutylene terephthalate,PBT )、聚苯硫醚 ” (polyphenylene sulfide,PPS )、聚醚酰亞膠(polyether imide,PEI),或其他如聚丙烯(p〇iypr〇pylene,pp)、聚臨 胺(polyamide,nylon)、聚乙稀(polyethylene,PE)、聚苯 # 乙烯(polystyrene,PS )、聚氯乙烯(polyvinyl chloride, PVC)、?武碳酸酯(polycarbonate,PC)等熱塑性塑膠,或 是環氧樹脂(epoxy)、乙烯酯(vinyl ester)樹脂、不飽和 聚酯(polyester)樹脂等熱固性塑膠。 玻璃纖維補強塑膠板20中玻璃纖維紋路之成型方 式,可經由紗束(roving)系之加工方式,以切股(ch〇pped strand)、切股亶毛(chopped strand mat)、編紗束(w〇ven 馨 r〇ving)或針縫材等方法,形成均勻分散或織布狀之纖維 紋路;或是以編紗(yarn)系之加工方式,以平織(piah 、 weave)、目扳平織、斜紋織(twill weave)或锻織(stain weave)等方式(前述編紗束亦有此些織法),形成具織布 狀纖維紋路之玻璃布或玻璃帶’但並不僅限於前述。 表面造型塑膠薄膜10,亦並不僅限於PET材質,其 可選用與玻璃纖維補強塑膠板20同種類,如前所述之塑 膠材質。除此之外,表面造型塑膠薄膜10並可為呈透明 、 狀、染以顏色、印刷有圖案,或仿麂皮、紡織布面等效果 10 1277505 之塑膠,茲藉由以下實施例進行說明。 請芩閱第三圖,該圖係本發明實施例玻璃纖維補強塑 膠材表面處理後之刳視示意圖。本實施例中,表面造型塑 膠薄膜10係選自一屬PET材質之透明聚酯薄膜u,而玻 璃纖維補強塑膠板20亦係一屬PET材質而呈透明狀之玻 1 璃纖維補強塑膠板21。藉此,由所形成之玻璃纖維補強塑 , 膠材表面即可清楚觀察到其中玻璃纖維所編織、舖排之紋 路,並藉由透明聚酯薄膜U增加塑膠材之厚度,產生纖 •、維紋路立體化之效果。 請參閱第四圖,該圖係本發明玻璃纖維補強塑膠材表 面處理後第二實施例之剖視示意圖。本實施例中,表面造 =塑膠薄膜1G係選自-屬PET材質而染有顏色之染色聚 -曰薄膜12而玻璃纖維補強塑膠板%仍係一屬pet材質 ,壬透明狀之玻璃纖維補強塑膠板21。藉此,不但可清楚 觀察到其中玻璃纖維所編織、鋪排之紋路,更可使玻璃纖 • 維補強塑膠板21之纖維紋路呈現出染色聚酯薄膜12之色 澤:當該玻璃纖維係呈織布狀之紋路,並同時配合以近黑 、 之染色聚酯薄膜12時,其所呈現出之外觀即與碳纖 • 彳__相當,故可藉此取代成本高、原料取得不易之 ,纖維翻娜餘,,目品不但可大崎低製造成 更可維持與<纖維相當之纖維紋路外觀,以及高強 度、高剛性之特性。 料閱第五圖’該_本發明玻璃纖維補強塑膠材表 -自處理後第二貫施例之剖视示意圖。本實施例中,表面造 1277505 型塑膠薄骐10係選自-屬PET材質之透 而破璃纖維補強塑膠板20則係一屬騎薄膜11 ’ 纖維染有色料或賴(sputtering)以金屬貝’亚於玻璃 ,色或金屬色澤之染色玻璃纖維補強塑膠:_ ,可由_纖維觀塑雜表面清•察^ 22。错此’ 居色或金屬光澤之玻璃纖維紋路,並具特殊 増加=敎較,產钱敝敎^薄膜η 請參_六圖,係本發财 =第四,之剖視示意圖。本實施 薄膜月貫施例中,玻璃纖維補強_材其透明聚酿 =11表面印刷以-印刷圖案層3G。該印刷圖案層 I、明聚醋薄膜u與染色玻璃纖維補強塑膠板、22接人 二:預先:熱轉印方式,於透明聚醋薄膜n表面印: 之二=名稱或其他之酵或文字,使在所呈現纖維紋路 月不,凸顯所印刷之圖案,或透過該印刷圖案盥输 紋路產生特殊之視覺效果。 '〜、、、、 4苓閱第七圖,該圖係本發明玻璃纖維補強塑膠材表 处理後苐五貫施例之剖視示意圖。本實施例中,表面、生 型塑膠薄膜1G係選自一屬PET材質之聚酯紡織纖維= 13 ’、而破璃纖維補強塑膠板2〇則係一屬PET材質而呈透 明狀之破璃纖維補強塑膠板21。聚酯紡織纖維布13係一 由聚酯(polyester)纖維所成型’並係一仿麂皮或紡織布 面紋路之PET紡織布匹,故其表面得呈現出麂皮或布面 視覺效果。 Ϊ2775051277505 IX. Description of the Invention: [Technical Field] The present invention relates to a glass fiber reinforced plastic composite material, in particular to a surface of the glass fiber reinforced plastic composite material, thereby exhibiting various glass fiber grain colors or patterns The method of change. [Prior Art] Among the general composite materials, glass fiber is used as the reinforcing material, which is the most common molding method. In fact, the glass fiber reinforced plastics (FGRP) formed by the glass fiber reinforced plastics (FGRP) It is also the most widely used one of composite products. By adding fiberglass, the original rigid or low-strength plastic can greatly improve its physical properties, and it can be used as a structural material, plus its light weight, good strength, strong plasticity, and resistance to moisture and corrosion. Such as the excellent special f, for the aerospace, ship, transportation, building materials, electronics, electric crying and other structures have their applications. The raw materials of glass fiber reinforced plastic mainly include: matrix, glass fiber and auxiliary material as reinforcing material (reinf0rcement). The glass, the truncation system is used to make the finished product have high strength and high rigidity (elastic coefficient), and the substrate is a shaped material which forms a desired shape structure, which covers and protects the glass from wear or damage. And transfer and disperse the load of the party under the Bolivian, so that the finished product has compressive strength. The substrate is made up of different types or ratios of fats. After adding the fillers, it can be processed into a variety of plastic types. The surface can be divided into thermoplastics. _ (5) espresso s (4) 5 1277505 or thermosetting plastics (thermosetting plastics) ). The glass fiber and the resin are combined by hand-drawing or resin injection (such as (4) (10), RJ), etc., and are usually heated or heated. Curing molding. During the edge forming process, the glass fiber is translucent due to the absorption of the resin, so that the glass fiber (4) can not exhibit the original surface of the original Qianwei weaving or paving, and lose the special surface of the fiber texture. modeling. ^This 'in order to express the special texture of the money woven by the glass fiber, the invention of dyeing the glass fiber, but this way, only = the original color of the strong material is presented, so the texture of the performance or Color, chemical system is quite limited and fresh. Later, although the step was added to the resin to change the overall appearance color, but the result was that the resin was reduced, so it still could not effectively highlight the texture and color of the glass fiber. It is not ideal in the glass fiber, but it is not ideal, which makes it less beautiful and special. = It is easy to be advanced - the appearance is higher than the requirements. The application range cannot be expanded or extended. [Inventive content] !::Γ: Reinforced plastic composite material, its glass fiber: the shortcomings of the enamel, so that the texture of the money woven by the broken fiber can be clearly presented, and at the same time 1 right ~ domain #,, Wen Road _ τ, There are a variety of colors or maps fortunately changing. Taiwu Ming will provide a method for processing the surface of the plastic surface of the broken surface, the surface of the plastic, and the surface of the plastic surface. , special pancreas, improve the original can not clear ^ 277505 1 fiber fif road's shortcomings ' and through the surface of the plastic film to make the fiber texture is not because of the 9 surface of the surface of the plastic film, plastic composite material into the _ 22 'Make Glass fiber reinforced plastic At the same time, by the fiber it achieves: = redundant, ^ 1 ^ material 枓' to reduce the cost of raw materials in the process. Invented glass fiber reinforced plastic material steps: (1) Trace Yang financial method, including Xiyi culvert two fiber reinforced plastic plate; (2) covering the surface of the glass, cut, and reinforced plastic plate over the surface of the plastic plastic Lai; (3) will be two Hot pressing under vacuum, joining the _ Γ Γ, forming a glass fiber viscous material having a predetermined shape on the surface, (4) cooling the glass fiber reinforced plastic material; and (5) opening the The mold is taken out of the glass fiber reinforced plastic material. Wherein, the glass fiber reinforced flap-glass fiber is thermally mixed, and the surface-shaped plastic film is also a thermoplastic plastic, but not limited thereto, and may also be selected from thermosetting plastics at the same time. When the glass fiber reinforced plastic board and the surface plastic film are thermoplastic, the glass fiber reinforced plastic board can be a glass fiber reinforced polyethylene terephthalate (PET) composite material. The surface-shaped plastic film may be a polyethylene terephthalate vinegar, but not limited thereto. Others such as acrylonitrile butadiene_styrene (acrylonitrile butadiene_styrene) , ABS) resin, polybutylene terephthalate (PBT), polyphenylene sulfide (PPS), polyether imide (PEI), polypropylene (polypropylene, PP) ), polystyrene 127755 (polyamide, nylon), polyethylene (PE), polystyrene (PS), polyvinyl chloride (PVC) or polycarbonate (PC), etc. It can also be used as a processing material for the method of the present invention. According to the treatment method of the present invention, the plastic film of the desired shape can be covered by the glass fiber reinforced plastic plate and then hot pressed, and the two can be self-bonded without self-bonding (self- The bonding method is mutually compatible, and the process is relatively simple and the cost is relatively low. After joining, the glass fiber reinforced plastic material, through the color or pattern of the plastic film, combined with the fiber fiber reinforced plastic fiber board, can not only clearly show the original fiber texture, but also the glass fiber overall The change of the performance of the special color, the gradient color or the pattern enables the method of the invention to produce a glass fiber reinforced plastic material with various surface effects', which makes the application range wider. The embodiments of the present invention will be further described with reference to the accompanying drawings. The embodiments of the present invention are intended to be illustrative of the present invention and are not intended to limit the scope of the invention. The spirit and the scope of the invention may be modified and retouched, and the scope of the invention is defined by the scope of the appended claims. [Embodiment] Please refer to the second picture of Fig. 2, the first method of the present invention (4), the process of the method is not bad, and the second method of the present invention is a schematic diagram of the surface treatment method of the strong plastic material. Sigh, 隹汗丁心园 The glass fiber of the invention is supplemented 5 1277505 舜·^_The surface treatment method is mainly - the surface molding plastic film 10 = cover; - _ fiber reinforced plastic plate 2 (), after hot pressing The method of treating the case is as follows: (1) Providing the glass::: 隹 reinforcing the plastic plate sl〇; (2) covering the glass fiber reinforced plastic plate with the surface-shaped plastic film S20 (3) placing the two in a mold, performing hot pressing S3G under vacuum, and bonding the two bonds to form a surface-reinforced plastic material having a predetermined shape on the surface, (4) Cooling S40 the glass fiber reinforced plastic material; and (5) demolding (10), removing the glass fiber reinforced plastic material from the mold. Among them, the hot pressing, cooling and de-stepping steps are based on the technique of (4), which is not further explained here. In the embodiment of the present invention, since the glass fiber is reinforced on the surface of the plate and the plastic film is formed, it is only necessary to use a bonding method by means of a bonding agent, that is, the two are combined in a self-bonding manner, so in the process The above is quite simple 'the required cost is also low. After joining, the glass fiber reinforced plastic material can be used as the material of various types of products, and after being subjected to secondary processing and hot pressing into S60 into a predetermined shape, the desired color or pattern can be produced. Surface glass fiber reinforced plastic products. In the embodiment of the present invention, the glass fiber reinforced plastic plate 2 is a glass fiber reinforced, the phthalic acid PEG g (pET) composite material, and the surface, the plastic film U) is made of a poly-pair Ethylene phthalate, both of which are thermoplastics, but the invention is not limited to '5 hai', but also belongs to the same thermosetting plastic. ' 9 1277505 ' Glass fiber reinforced plastic sheet 20, which is not limited to PET material, it can also be other engineering plastics, such as acrylonitrile butadiene-styrene (acrylonitrile butadiene-styrene, ABS) resin, polybutylene terephthalate (PBT), polyphenylene sulfide (PPS), polyether imide (PEI), or other such as polypropylene ( P〇iypr〇pylene,pp),polyamide,nylon,polyethylene (PE), polystyrene (PS), polyvinyl chloride (PVC), Thermoplastic plastics such as polycarbonate (PC), or thermosetting plastics such as epoxy, vinyl ester, and unsaturated polyester. Glass fiber reinforced plastic sheet 20 The molding method can be processed by a roving system, with a ch〇pped strand, a chopped strand mat, a braided strand, or a braided strand. Sewing materials and other methods to form a uniformly dispersed or woven fabric; or in the form of yarns, weaving (piah, weave), weaving, twill weave or forging (stain weave) and the like (the above-mentioned braided yarn also has such weaves) to form a glass cloth or a glass ribbon with a woven fabric-like texture, but is not limited to the above. The surface-shaped plastic film 10 is not limited to PET. The material can be selected from the same type as the glass fiber reinforced plastic plate 20, as described above. In addition, the surface molding plastic film 10 can be transparent, shaped, dyed with color, printed with a pattern, or The plastic of effect 10 1277505, such as suede and woven fabric, is illustrated by the following examples. Please refer to the third drawing, which is a schematic view of the surface of the glass fiber reinforced plastic material after the surface treatment of the embodiment of the present invention. In this embodiment, the surface molding plastic film 10 is selected from a transparent polyester film u of a PET material, and the glass fiber reinforced plastic plate 20 is also a transparent glass fiber reinforced plastic plate. 21. By this, the formed glass fiber is reinforced, and the surface of the rubber material can be clearly observed, and the thickness of the plastic material is increased by the transparent polyester film U to produce the fiber. The effect of the three-dimensional dimension of the line. Please refer to the fourth drawing, which is a schematic cross-sectional view showing a second embodiment of the surface treatment of the glass fiber reinforced plastic material of the present invention. In this embodiment, the surface film = plastic film 1G is selected from the group consisting of - PET material dyed with colored dyed poly-ruthenium film 12 and the glass fiber reinforced plastic board is still a pet material, 壬 transparent glass fiber reinforcement Plastic plate 21. Thereby, not only can the grain of the glass fiber woven and laid out be clearly observed, but also the fiber grain of the glass fiber reinforced plastic sheet 21 exhibits the color of the dyed polyester film 12: when the glass fiber is woven When the texture is similar to that of the black polyester film 12, the appearance is the same as that of the carbon fiber 彳__, so it can replace the high cost and the raw material is difficult to obtain. , the product can be manufactured not only by Osaki, but also by the appearance of the fiber texture equivalent to the fiber, and the high strength and high rigidity. Referring to the fifth figure, the glass fiber reinforced plastic material table of the present invention is a cross-sectional view of the second embodiment after self-treatment. In this embodiment, the surface of the 1277750 type plastic thin crucible 10 is selected from the group consisting of - the material of the PET material and the glass fiber reinforced plastic board 20 is a genus riding film 11 ' fiber dyed with color or sputtering with metal shell 'A glass fiber, color or metal color dyed glass fiber reinforced plastic: _, can be _ fiber view plastic surface clear • check ^ 22. Wrong this 'color or metal luster glass fiber texture, and special 増 plus = 敎 comparison, production money 敝敎 ^ film η Please refer to _ six maps, this is the fortune = fourth, the cross-sectional schematic. In the present embodiment of the film, the glass fiber reinforced material was transparently patterned to have a surface printed with a pattern layer 3G. The printing pattern layer I, the bright polyester film u and the dyed glass fiber reinforced plastic board, 22 pick two: pre-: thermal transfer method, printed on the transparent polyester film n surface: the second = name or other leaven or text In order to make the printed grain pattern not appear, the printed pattern is highlighted, or the printed pattern is used to create a special visual effect. '~,,,, 4, 4, which is a cross-sectional view of the five-fifth embodiment of the glass fiber reinforced plastic material of the present invention. In this embodiment, the surface and the raw plastic film 1G are selected from a polyester textile fiber of the genus PET material = 13 ', and the glass fiber reinforced plastic plate 2 系 is a transparent material of the PET material. Fiber reinforced plastic sheet 21. The polyester woven fabric 13 is made of polyester fibers and is a PET woven fabric of suede or woven fabric, so that the surface has a suede or cloth surface visual effect. Ϊ277505

並可藉由表面造型塑膠薄膜10, ’增加塑膠材之厚度, 如述表面造型塑膠薄臈10與玻璃纖 合類型僅係麻,並不以此為限,^ 層色或金屬光澤, 路,並可藉*矣品 _時赵纖敎路立體化之效果,使本發财法所^造 出之玻璃纖維補強塑膠材具有多變之表面造型,進而二其 在結構材之應用外,能夠延伸應用於日常家電用品、容 器、包裝盒、家具、飾品當中,使其在利用與使用上更2 普及。 【圖式簡單說明】 第一圖係本發明實施例方法之流程示意圖。 _ 第二圖係本發明實施例玻璃纖維補強塑膠材表面處理方 法之不意圖。 、 第三圖係本發明實施例玻璃纖維補強塑膠材表面處理後 之剖視不意圖。 第四圖係本發明玻璃纖維補強塑膠材表面處理後第二實 施例之剖視示意圖。 苐五圖係本發明玻璃纖維補強塑膠材表面處理後第三實 施例之剖視示意圖。 13 1277505 第六圖係本發明玻璃纖維補強塑膠材表面處理後第四實 施例之剖視不意圖。 第七圖係本發明玻璃纖維補強塑膠材表面處理後第五實 施例之剖視不意圖。 .· 【主要元件符號說明】 ίο 表面造型塑膠薄膜 11 透明聚酯薄膜 12 染色聚酯薄膜 13 聚酯紡織纖維布 20 玻璃纖維補強塑膠板 21 透明玻璃纖維補強塑膠板 22 染色玻璃纖維補強塑膠板 30 印刷圖案層 S10 提供一玻璃纖維補強塑膠板 S20 覆蓋以一表面造型塑膠薄膜 S30 真空熱壓 S40 冷卻 S50 脫模 S60 二次加工熱壓成型And by the surface molding plastic film 10, 'increasing the thickness of the plastic material, such as the surface molding plastic thin 10 and the glass fiber type is only numb, not limited to this, ^ layer color or metallic luster, road, And the effect of the three-dimensional effect of Zhao Dian Road can be used to make the glass fiber reinforced plastic material produced by this financial method have a variety of surface shapes, and in addition, It is extended to everyday household appliances, containers, packaging boxes, furniture, and accessories, making it more popular in use and use. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a schematic flow chart of the method of the embodiment of the present invention. The second figure is not intended to be a surface treatment method for a glass fiber reinforced plastic material according to an embodiment of the present invention. The third drawing is a cross-sectional view of the glass fiber reinforced plastic material of the embodiment of the present invention after surface treatment. The fourth drawing is a schematic cross-sectional view showing a second embodiment of the glass fiber reinforced plastic material of the present invention after surface treatment. Figure 5 is a schematic cross-sectional view showing a third embodiment of the glass fiber reinforced plastic material of the present invention after surface treatment. 13 1277505 The sixth drawing is a cross-sectional view of the fourth embodiment after the surface treatment of the glass fiber reinforced plastic material of the present invention. The seventh drawing is a cross-sectional view of the fifth embodiment after the surface treatment of the glass fiber reinforced plastic material of the present invention. .. [Description of main components] ίο Surface plastic film 11 Transparent polyester film 12 Dyed polyester film 13 Polyester textile fiber cloth 20 Glass fiber reinforced plastic sheet 21 Transparent glass fiber reinforced plastic sheet 22 Stained glass fiber reinforced plastic sheet 30 Printed pattern layer S10 provides a glass fiber reinforced plastic sheet S20 covered with a surface molding plastic film S30 vacuum hot pressing S40 cooling S50 stripping S60 secondary processing hot forming

Claims (1)

1277505 ’ 十、申請專利範圍: 卜一種玻璃纖維補強塑膠材之表面處理方法,包括下列步驟: (1) 提供一玻璃纖維補強塑膠板; (2) 於该玻璃纖維補強塑膠板上方覆蓋以一表面造型塑膠 薄膜; , (3)將所述二者置於一模具内,於真空狀態下進行熱壓, 使所述—者鍵結相接合,形成一表面具有預定造型之 籲 玻璃纖維補強塑膠材; (4) 冷卻該玻璃纖維補強塑膠材;以及 (5) 開啟該模具,將該玻璃纖維補強塑膠材取出。 2、如申请專利範圍第1項所述之玻璃纖維補強塑膠材之表面 處理方法,其中該玻璃纖維補強塑膠板係一玻璃纖維補強 熱塑性塑膠,而該表面造型塑膠薄膜亦係一熱塑性塑膠。 _ 3、如申請專利範圍第2項所述之玻璃纖維補強塑膠材之表面 處理方法,其中該玻璃纖維補強塑膠板係一玻璃纖維補強 聚對苯二甲酸乙二醇酯(PET)之複合材料,而該表面造 - 型塑勝薄膜其材質則係一聚對苯二曱酸乙二醇g旨。 4、 如申請專利範圍第1項所述之玻璃纖維補強塑膠材之表面 處理方法,其中該玻璃纖維補強塑膠板中之玻璃纖維係染 有一色料。 5、 如申請專利範圍第丨項所述之玻璃纖維補強塑膠材之表面 15 1277505 處理方法’其中該玻璃纖維補強塑膠板中之玻璃纖維係賤 鍍有一金屬。 6、 如申請專利範圍第4或5項所述之玻璃纖維補強塑膠材之 表面處理方法,其中該表面造型塑膠薄膜係呈透明狀。 7、 如申請專利範圍第4或5項所述之玻璃纖維補強塑膠材之 表面處理方法,其中該表面造型塑膠薄膜係包括有形成預 定顏色之一色料。 8、 如申請專利範圍第4或5項所述之玻璃纖維補強塑膠材之 表面處理方法,其中該表面造型塑膠薄膜其表面係預先印 刷有一印刷圖案層。 9、 如申請專利範圍第4或5項所述之玻璃纖維補強塑膠材之 表面處理方法,其中該表面造变塑膠薄膜係一聚g旨纖維纺 織布。 161277505 ' X. Patent application scope: A surface treatment method for a glass fiber reinforced plastic material, comprising the following steps: (1) providing a glass fiber reinforced plastic plate; (2) covering a surface of the glass fiber reinforced plastic plate Forming a plastic film; (3) placing the two in a mold, performing hot pressing under vacuum, so that the bonding is joined to form a glass fiber reinforced plastic material having a predetermined shape on the surface. (4) cooling the glass fiber reinforced plastic material; and (5) opening the mold to remove the glass fiber reinforced plastic material. 2. The surface treatment method of the glass fiber reinforced plastic material according to claim 1, wherein the glass fiber reinforced plastic plate is a glass fiber reinforced thermoplastic plastic, and the surface plastic film is also a thermoplastic plastic. _ 3. The surface treatment method of the glass fiber reinforced plastic material according to the second aspect of the patent application, wherein the glass fiber reinforced plastic board is a composite material of glass fiber reinforced polyethylene terephthalate (PET). The surface-type plastic film is made of a polyethylene terephthalate. 4. The surface treatment method of the glass fiber reinforced plastic material according to claim 1, wherein the glass fiber in the glass fiber reinforced plastic board is dyed with a coloring material. 5. The surface of the glass fiber reinforced plastic material as described in the scope of the patent application. 15 1277505 Treatment method ‘In the glass fiber reinforced plastic sheet, the glass fiber 贱 is plated with a metal. 6. The surface treatment method for a glass fiber reinforced plastic material according to claim 4 or 5, wherein the surface plastic film is transparent. 7. The surface treatment method for a glass fiber reinforced plastic material according to claim 4 or 5, wherein the surface molding plastic film comprises a coloring material which forms a predetermined color. 8. The surface treatment method for a glass fiber reinforced plastic material according to claim 4, wherein the surface of the plastic film has a printed pattern layer pre-printed on the surface. 9. The surface treatment method for a glass fiber reinforced plastic material according to claim 4 or 5, wherein the surface morphing plastic film is a fiber woven fabric. 16
TW95104347A 2006-02-09 2006-02-09 Method for processing surface of a fiberglass reinforced plastic composite material TWI277505B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW95104347A TWI277505B (en) 2006-02-09 2006-02-09 Method for processing surface of a fiberglass reinforced plastic composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW95104347A TWI277505B (en) 2006-02-09 2006-02-09 Method for processing surface of a fiberglass reinforced plastic composite material

Publications (2)

Publication Number Publication Date
TWI277505B true TWI277505B (en) 2007-04-01
TW200730337A TW200730337A (en) 2007-08-16

Family

ID=38625946

Family Applications (1)

Application Number Title Priority Date Filing Date
TW95104347A TWI277505B (en) 2006-02-09 2006-02-09 Method for processing surface of a fiberglass reinforced plastic composite material

Country Status (1)

Country Link
TW (1) TWI277505B (en)

Also Published As

Publication number Publication date
TW200730337A (en) 2007-08-16

Similar Documents

Publication Publication Date Title
CN100534783C (en) Method of processing the surface of glass fiber strengthened plastic material
CN104781317B (en) Fiber-reinforced resin sheet material, integrated molding and their manufacture method
CN105073403A (en) Sandwich laminate, sandwich structure and unified molded product using same and processes for producing both
JP2006044264A (en) Decorative molded article and its production method
TWM331441U (en) Structure combining composite material and plastic material
JP5970908B2 (en) Decorative sheet for carbon fiber reinforced plastic and decorative composite material
JP6163970B2 (en) Decorative molded product and method for producing decorative molded product
TWI327959B (en)
CN101384418A (en) Method of manufacturing a product part by using a composite fibre sheet and applying plastic to this sheet
US20220410505A1 (en) Fiber reinforced thermoplastic composite sheet and method for preparing the same
TWI277505B (en) Method for processing surface of a fiberglass reinforced plastic composite material
JP5395459B2 (en) Resin molded body of carbon fiber fabric sheet
TW201311478A (en) Composite material rim using single longitudinal-weaved carbon fiber and manufacturing method thereof
JP3098478B2 (en) Manufacturing method of carbon fiber composite molded product
JP3035409B2 (en) Manufacturing method of carbon fiber composite molded product
TW201113154A (en) Fiberlaminate structure having fabric touch feeling and preparing method thereof
GB2516157A (en) Coloured carbon-fibre composite materials
JP2013202921A (en) Decorative sheet for carbon fiber-reinforced plastic, decorative composite material, and method of manufacturing the same
CN101457483B (en) Fibrous reinforcing sheet, process for production thereof, and dress-up sheet made by using the sheet
TW201113150A (en) Continuous fiber laminate and preparing method thereof
JP5935441B2 (en) Decorative composite material manufacturing method
JP5935440B2 (en) Decorative composite material manufacturing method
JP3065974B2 (en) Carbon fiber composite molded article and method for producing the same
CN219727494U (en) Composite material structure, shell, decoration and electronic equipment
TWM367806U (en) Combined structure on surface of composite material

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees