TWI262739B - Method of fabricating organic electroluminescent display - Google Patents

Method of fabricating organic electroluminescent display Download PDF

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Publication number
TWI262739B
TWI262739B TW91112915A TW91112915A TWI262739B TW I262739 B TWI262739 B TW I262739B TW 91112915 A TW91112915 A TW 91112915A TW 91112915 A TW91112915 A TW 91112915A TW I262739 B TWI262739 B TW I262739B
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Taiwan
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layer
forming
organic electroluminescent
electrode
sized substrate
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TW91112915A
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Chinese (zh)
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Seung-Jun Yi
Do-Hyum Choi
Kyung-Hee Choi
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Kin Hyung Se
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Priority claimed from KR10-2002-0014622A external-priority patent/KR100369575B1/en
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Publication of TWI262739B publication Critical patent/TWI262739B/en

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Abstract

Described is a method of fabricating an organic electroluminescent display (hereinafter abbreviated OELD) enabling to increase a throughput efficiency by carrying out a foregoing OELD process, dividing a large-scaled substrate, and carrying out a following OELD process in order. The present invention includes the steps of forming a first electrode layer on a large-scaled substrate, dividing the large-scaled substrate into a plurality of small substrates, forming an organic electroluminescent layer on the first electrode layer of at least one of the small substrates, and forming a second electrode layer on the organic electroluminescent layer.

Description

1262739 案號 91112915 修正 五、發纟月說明“(1) 【發明領域】 本發明係關於一種有機電致發 . ^ 1 , 1 · 知光顯不态(organic e :忖〇1㈣ineSCent dlsplay)(簡稱為〇el 關=一種有機電致發光顯示器的製造方法,藉由依序 一前段的0LED製程’分割一大尺寸的的基板f以及朵.一 後段0LED製程,而能夠增加生產率。土 貝也 【發明背景】 由於貢訊及通訊科技的大幅進步,對電子顯示裝置的 ,求隨著資訊社會的多元化大大地增加,同時對各種顯示 斋的要求也不斷地增加。為了滿足資訊社會對電子顯示元 件高解析度、大尺寸、高性能以及薄小化的特性要求,新 型的平面顯示器(flat panel display ;fpd)已被開發 來替代傳統的陰極射線管顯示器(CRT )。 目鈾的平面顯不器,包括有液晶顯示器(L c D )、發 光二極體顯示器(LED)、電漿顯示面板(pUsma Display Panel ;PDP)、真空螢光顯示器(Vacuuin1262739 Case No. 91911915 Amendment 5, 纟月月说明“(1) [Invention Field] The present invention relates to an organic electroluminescence. ^ 1 , 1 · Known light (organic e : 忖〇 1 (four) inesent dlsplay) For the manufacturing method of the organic electroluminescent display, the productivity can be increased by dividing the large-sized substrate f and the one-stage OLED process by the OLED process of the previous stage. Background] Due to the significant advancement of Gongxun and communication technology, the demand for electronic display devices has increased greatly with the diversification of the information society, and the requirements for various display formats have been increasing. To meet the information society's electronic display components. High resolution, large size, high performance and thinness requirements, the new flat panel display (fpd) has been developed to replace the traditional cathode ray tube display (CRT). Including liquid crystal display (L c D ), light-emitting diode display (LED), plasma display panel (PDP), vacuum fluorescent display ( Vacuuin

Fluorescence Display ;VFD)、電致發光顯示器(ELD) 等等。 相較於例如液晶顯示器之類的非放射性裝置,電致發 光顯示器被認為是一種新一代的平面顯示器(Flat panel D i s p 1 ay ; FPD )。電致發光顯示器比非放射性顯示器具有 較快的反應速度,而由於其能自行發光的特性使得電致發 光顯示器具有絕佳的亮度,且結構簡單易於製造,設計上 亦是既輕且薄。因此電致發光顯示器被廣泛地運用在各種 i °口口領域,例如LCD背光源、行動終端裝置、汽車導航系Fluorescence Display; VFD), Electroluminescent Display (ELD), etc. Compared to non-radioactive devices such as liquid crystal displays, electroluminescent displays are considered to be a new generation of flat panel displays (Flat panel D i s p 1 ay ; FPD ). Electroluminescent displays have a faster response speed than non-radioactive displays, and because of their self-illuminating properties, electroluminescent displays have excellent brightness, are simple in structure and easy to manufacture, and are also light and thin in design. Therefore, electroluminescent displays are widely used in various i° ports, such as LCD backlights, mobile terminal devices, and car navigation systems.

1262739 &五i發#1¾明 案號 (2) 91112915 統(car navigation 牆等等。 _年月日__ system ; CNS )、筆記型電腦、電視 由於發光層材料(luminescent layers)的不同,電 致發光顯示器通常可區為有機電致發光顯示器(0ELD ), 以及無機電致發光顯示器(inorganic electroluminescent display ; I ELD )兩種。 I ELD是藉由被一高電場加速的電子之碰撞而發光。根 據其薄膜厚度及驅動系統,IE L D可分為交流(A C )薄膜電 致發光顯示器、交流厚膜電致發光顯示器,以及直流 (DC )薄膜電致發光顯示器等。而〇ELD則是藉由電流而發 光,可分為低分子0ELD,以及高分子0LED。 「第4圖」緣示一種習知的〇 E L D剖視圖,在一透明基 板11上依序堆疊一透明陽極層12、一電洞注入層13、一電 洞輸送層14、一有機電致發光層15、一電子輸送層17以及 用金屬做成的一陰極層18。該有機電致發光層15藉由電流 而發光’而該電洞注入層13、該電洞輸送層14,以及電子 輸送層1 7 ’對該〇 E L D的發光效率則扮演著輔助性的角色。 該電洞注入層1 3、電洞輸送層1 4、有機電致發光層 1 5,以及電子輸送層丨7若為低分子材料,則是運用遮罩 (shadow mask )及真空沉積法加以形成。 並且電洞輸送層14以及有機電致發光層15若為高分子 材料,則是運用喷墨或印刷法加以形成。受限於該沉積或 印刷設備’基材的尺寸因而受到限制。而能夠用於現有沉 積或印刷設備的最大基板尺寸為3 7 0mm X 470mm或4〇〇mm x 4 0 0mm 〇1262739 & five i hair #13⁄4 Ming case number (2) 91112915 system (car navigation wall, etc. _ _ _ __ system; CNS), notebook computer, TV due to different luminescent layers Electroluminescent displays can generally be classified into organic electroluminescent displays (0ELD) and inorganic electroluminescent displays (ILDs). I ELD is illuminated by collision of electrons accelerated by a high electric field. Depending on its film thickness and drive system, IE L D can be divided into AC (A C) thin film electroluminescent displays, AC thick film electroluminescent displays, and direct current (DC) thin film electroluminescent displays. 〇ELD is emitted by current, which can be divided into low molecular 0ELD and polymer 0LED. FIG. 4 is a cross-sectional view showing a conventional 〇ELD in which a transparent anode layer 12, a hole injection layer 13, a hole transport layer 14, and an organic electroluminescent layer are sequentially stacked on a transparent substrate 11. 15. An electron transport layer 17 and a cathode layer 18 made of metal. The organic electroluminescent layer 15 emits light by current, and the hole injection layer 13, the hole transport layer 14, and the electron transport layer 17' play an auxiliary role in the luminous efficiency of the 〇 E L D . The hole injection layer 13 , the hole transport layer 14 , the organic electroluminescent layer 15 , and the electron transport layer 丨 7 are formed by a shadow mask and a vacuum deposition method if they are low molecular materials. . Further, if the hole transport layer 14 and the organic electroluminescent layer 15 are polymer materials, they are formed by inkjet or printing. The size of the substrate limited to the deposition or printing apparatus is thus limited. The maximum substrate size that can be used in existing deposition or printing equipment is 370mm X 470mm or 4〇〇mm x 4 0 0mm 〇

第7頁 1262739 案號 91112915 年 月 曰 修_ 依fe、發光材料的不同,OELD可分為下述二種。第一種 是如美國專利第4, 768, 292號,及美國專利第5, 294, 870號 所揭露的螢光顯示器。其中的有機電致發光層丨5是由一種 赏光發光材料所形成,例如a 1 um i num t r i s ( 8 -hydroxyquinoline)(Alq3)、 perylene 等。第二種則是如 美國專利第6, 0 97, 1 47號所揭露的磷光OELD,其有機電致 發光層 15 是由如 platinum 2,3,7,8,12,12,17,18-octaethyl-21H,23H-porphine platinum(PtOEP)、銀錯合 物{例如I r ( Ppy ) 3 }的其中一種磷光發光材料所形成。並 且在該電洞及電子輸送層14、17之間並以bathocuproine (BCP) 、cabazo 1 e bipheny1(CBP)或 Ν,Ν’-dipheny1 -N,Ν’ -bis-alpha-napthylbenzylidine(NPD)等其中一種形 成一阻障層。具體來說,高分子OELD在該透明陽極層12與 該陰極層18之間具有一電洞輸送層14/電致發光層15雙層 結構,如美國專利第5,3 9 9,5 0 2號以及美國專利第 5, 807, 627號中所述,其中使用共軛聚合體之導電高分子 材料。該導電高分子材料包括{poly(p-phenylenevinylene) ; PPV} 、 po1y(thiophene) 、 {poly (2, 5-dialkoxyphenylenevinylene ; PDMeOPV)}等。 具代表性的幾種有機電致發光材料的發光波長如表一 所示 表Page 7 1262739 Case No. 91112915 Month 曰 Repair _ Depending on fe and luminescent materials, OELD can be divided into the following two types. The first type is a fluorescent display as disclosed in U.S. Patent No. 4,768,292, and U.S. Patent No. 5,294,870. The organic electroluminescent layer 5 is formed of a light-emitting luminescent material such as a 1 um i num t r i s (8-hydroxyquinoline) (Alq3), perylene or the like. The second type is a phosphorescent OELD as disclosed in U.S. Patent No. 6,097,147, the organic electroluminescent layer 15 of which is composed of, for example, platinum 2,3,7,8,12,12,17,18- One of phosphorescent materials of octaethyl-21H, 23H-porphine platinum (PtOEP), silver complex (for example, Ir(Ppy) 3 }. And between the hole and the electron transporting layers 14, 17 and bathocuproine (BCP), cabazo 1 e bipheny1 (CBP) or Ν, Ν'-dipheny1 -N, Ν'-bis-alpha-napthylbenzylidine (NPD), etc. One of them forms a barrier layer. Specifically, the polymer OELD has a two-layer structure of a hole transport layer 14 / an electroluminescent layer 15 between the transparent anode layer 12 and the cathode layer 18, such as U.S. Patent No. 5,399,5 0 2 The conductive polymer material of the conjugated polymer is used as described in U.S. Patent No. 5,807,627. The conductive polymer material includes {poly(p-phenylenevinylene); PPV}, po1y(thiophene), {poly(2, 5-dialkoxyphenylenevinylene; PDMeOPV)}. The representative wavelengths of several organic electroluminescent materials are shown in Table 1.

第8頁 1262739 —^___為” 案號 91112915 年月曰 修正 i、發萌麗明(4) 有機電致發光材料 發光波長 4, 4-bis(2, 2’-diphenylethen-4-yl)-diphenyl 465nm Tr i s(8-hydroxyqu i no1i ne)a1um i num 520nm b i s(8 ~hydroxyqu i no1i ne)magnes i um 515nm Coumarine 6 503nm Rubrene 560nm po1y(p-pheny1enev i ny1ene), PPV 540nm 依照不同的驅動系統,OELD可分為主動式及被動式兩 種。若電流驅動的被動式OELD面板尺寸增加,則除了元件 可靠度會降低,且粍能效率也變低。為了解決上述問題, 對角線長1 0吋以上的面板,則使用多晶矽薄膜電晶體 (TFT )主動式OELD。不幸地,習知的OELD具有下述問題 或缺點。OELD的有機電致發光層是利用遮罩以沉積法或印 刷法形成,而受限於該沉積或印刷設備,基材的尺寸因而 受到限制,可用的最大基板尺寸為3 7 0 mm X 4 7 0 mm 或 400mm X 400mm 〇 於是這種對基板尺寸的限制,也同時限制了生產率,Page 8 1262739 —^___ 为” Case No. 91112915 Lunar Amendment i, Fa Meng Liming (4) Organic electroluminescent material emission wavelength 4, 4-bis(2, 2'-diphenylethen-4-yl)- Diphenyl 465nm Tr is(8-hydroxyqu i no1i ne)a1um i num 520nm bis(8 ~hydroxyqu i no1i ne)magnes i um 515nm Coumarine 6 503nm Rubrene 560nm po1y(p-pheny1enev i ny1ene), PPV 540nm according to different drive systems OELD can be divided into active and passive. If the size of the current-driven passive OELD panel is increased, the reliability of the component will be reduced, and the energy efficiency will be lower. To solve the above problem, the diagonal length is 10 吋. In the above panel, a polycrystalline germanium film transistor (TFT) active OELD is used. Unfortunately, the conventional OELD has the following problems or disadvantages. The organic electroluminescent layer of OELD is formed by a deposition method or a printing method using a mask. Due to the deposition or printing equipment, the size of the substrate is limited, and the maximum substrate size available is 370 mm X 4 70 mm or 400 mm X 400 mm. This is a limitation on the substrate size and is also limited. Productivity ,

梭 1262露 tShuttle 1262 exposed t

案號 91112915 丨⑸ 曰 修正 使生產成本增加。 【發明之目的及概述】 能 本發明提出一種有機電致發光顯示器的製造方 夠避免習知技術的諸多限制與缺點。 〆 大 本發明的目的在提出一種有機電致發光顯示器 (OELD )的製造方法,藉由依序實施一前製程; 尺寸基板,以及一後段製程,而能增進生產效率。 本發明的其它特徵及優點,將在接下來的說明 闡明’其中一部分會被明白地說明或可由發明所舉的=以 中獲知。而本發明的其它目的及優點,亦可由發明之二, 說明、其中的申請專利範圍以及附圖所具體提出的 = 加以瞭解得到。 /、耩中 為了達到上述及其它優點並與本發明的目的一致, 據本發明的一種有機電致發光顯示器的製造方法之實根 大體上包括下列步驟:在一大尺寸基板上形成一第一電Ρ 層,將該大尺寸基板分割成複數個小基板,形成一有機^ 致發光層在至少一該小基板的該第一電極層上,以及形▲ 一第二電極層在該有機電致發光層上。 另一方面本發明的有機電致發光顯示器的製造方法亦 包括下列步驟··在一大尺寸基板上形成一驅動部,其包括 有複數個電晶體以及至少一電容器,並具有一第一電極; 將該大尺寸基板分割成複數個小基板;形成一有機電致發 光層在至少一該小基板的該驅動部的第一電極層上;形成 一第二電極層在該有機電致發光層上。 為使對本發明的目的、構造特徵及其功能有進一步的Case No. 91112915 丨(5) 修正 Correction Increase production costs. OBJECT AND SUMMARY OF THE INVENTION The present invention provides an organic electroluminescent display that avoids many of the limitations and disadvantages of the prior art. SUMMARY OF THE INVENTION The object of the present invention is to provide a method for fabricating an organic electroluminescent display (OELD), which can improve production efficiency by sequentially performing a pre-process, a size substrate, and a back-end process. Other features and advantages of the invention will be set forth in the description which follows. Other objects and advantages of the present invention will be apparent from the second aspect of the invention, the scope of the claims, and the specifics of the drawings. In order to achieve the above and other advantages and in accordance with the purpose of the present invention, a solid method for fabricating an organic electroluminescent display according to the present invention substantially includes the steps of: forming a first on a large-sized substrate An electric layer, the large-sized substrate is divided into a plurality of small substrates, an organic light-emitting layer is formed on the first electrode layer of the at least one small substrate, and a second electrode layer is formed in the organic electrode On the luminescent layer. On the other hand, the manufacturing method of the organic electroluminescent display of the present invention also includes the following steps: forming a driving portion on a large-sized substrate, comprising a plurality of transistors and at least one capacitor, and having a first electrode; Dividing the large-sized substrate into a plurality of small substrates; forming an organic electroluminescent layer on the first electrode layer of the driving portion of at least one of the small substrates; forming a second electrode layer on the organic electroluminescent layer . In order to further improve the object, structural features and functions of the present invention

第10頁 /1262739 C n Q1119Q1R_年月日 修正 五、發明說明(6) 了解,茲配合圖示詳細說明如下: 【實施例詳細說明】 本發明之較佳實施例將以附圖中之實例加以詳細說明 以為茶考。整個說明書中相同的元件可能會以同樣的標號 來標示說明。並且本發明之實施例的技術與組成元件之材 料的細節部分,包括一切在習知技藝中已被使用的。 [第一實施例] 根據本發明的一種被動式有機電致發光顯示器(簡稱 OELD )的製造方法之第一個實施例如說明如下: 蒼考「第1 A圖」,在一大尺寸基板1〇〇上形成一氧化銦錫 層(ITO層)(圖中未繪示),該大尺寸基板1〇〇係由透 明塑膠或玻璃所製成。該基板1〇〇的尺寸例如74〇mm X 94 0mm。該ITO層上可先塗佈一光阻層,然後將該光阻層顯 景> ’再钱刻該I T 0層以形成條紋狀的一陽極層2 〇 〇。 然後在該陽極層200上形成一介電層,並於該介電層 71 〇上塗佈光阻層(圖中未繪示)以進行圖案化。對該光 阻層進行曝光與顯影用以形成一光阻圖案。利用該光阻圖 案蝕刻該介電層71 0,而在該介電層71 〇形成複數個開口 2 1 〇,用以使該陽極層2 〇 〇曝露預定要露出的部分。在此例 中,該陽電極2 0 0上的那些開口 21 〇以預設的間距彼此相分 隔0 土’該分隔體720被形成為與該陽極層200相垂直 。將一光阻塗覆於該介電層710上以進行分隔體的製 程。對該光阻進行曝光與顯影,然後在其上實施一高溫熱 ,烤製程以在該介電層上形成複數個分隔體72〇。在此例 Φ 5 Kh. 7 Ο Π ΤΤ^ wPage 10 / 1262739 C n Q1119Q1R_ Year Month Day Amendment 5, Invention Description (6) Understand the following detailed description of the drawings: [Detailed Description of the Embodiments] The preferred embodiment of the present invention will be exemplified in the accompanying drawings Explain in detail the tea test. The same elements throughout the specification may be labeled with the same reference numerals. And the details of the techniques of the embodiments of the invention and the materials of the constituent elements, including everything that has been used in the prior art. [First Embodiment] A first embodiment of a method for manufacturing a passive organic electroluminescent display (hereinafter referred to as OELD) according to the present invention will be described below as follows: "The first picture A" is used in a large-sized substrate. An indium tin oxide layer (ITO layer) (not shown) is formed thereon, and the large-sized substrate 1 is made of transparent plastic or glass. The size of the substrate 1 is, for example, 74 〇 mm X 94 0 mm. The ITO layer may be coated with a photoresist layer, and then the photoresist layer is etched >' to re-print the ITO layer to form a stripe-shaped anode layer 2 〇 〇. A dielectric layer is then formed on the anode layer 200, and a photoresist layer (not shown) is coated on the dielectric layer 71 to perform patterning. The photoresist layer is exposed and developed to form a photoresist pattern. The dielectric layer 70 0 is etched using the photoresist pattern, and a plurality of openings 2 1 〇 are formed in the dielectric layer 71 to expose the anode layer 2 to a portion to be exposed. In this case, those openings 21 该 on the anode electrode 200 are separated from each other by a predetermined pitch. The spacer 720 is formed to be perpendicular to the anode layer 200. A photoresist is applied to the dielectric layer 710 for the spacer process. The photoresist is exposed and developed, and then a high temperature heat is applied thereto to form a plurality of separators 72 on the dielectric layer. In this case Φ 5 Kh. 7 Ο Π ΤΤ^ w

第 〆:〜 .*· t:Jr. f *-r一 ^更 1262-31 91112915 Λ_Μ 修正 五、發明說明(7)The first 〜: ~ .*· t: Jr. f *-r one ^ more 1262-31 91112915 Λ _ Μ Amendment 5, invention description (7)

當該陽極層200、介電層710以及分隔體720形成後, 形成用以切割該大尺寸基板1〇〇的 <一分割道(scribing lane )(未繪示)。該分剖道的寬度可介於50 //m〜1 _ 之間。 將該740mm X 940mm的大尺寸基板1〇〇切割成四塊適於 沉積製程的370mm X 470mm小基板1〇〇,。可利用雷射、超 音波、鑽石等,切割該大尺寸基板丨〇 〇,之後並施以一清 潔製程以去除切割製程所產生的塵粒。該清潔製程可利用 溼清 >糸製程、紫外光(UV )或電聚(p 1 asma )乾清潔製 程,或兩者同時使用。 參考「第1 B圖」,利用一遮罩於該小基板! 〇 〇,上該複 數個開口 2 1 0所露出的該陽極層2 〇 〇上形成一電洞注入層 310 ’該電洞注入層310可由CuPC、m-MTDATA或之類的材料 开> 成’並且在該電洞注入層31 〇上亦利用一遮罩以形成 一電洞輸送層3 2 0。 有機電致發光層400亦利用一遮罩形成於該電洞輸送 層3 2 0上,且包括紅、綠、藍三種畫素。在本例中,該紅 色晝素使用Alq3 + DCJTB或類似的材料形成,該綠色晝素使 用A1 q 3 + Q d 2或類似的材料形成,而該藍色晝素則使用After the anode layer 200, the dielectric layer 710, and the separator 720 are formed, a <Scribing lane (not shown) for cutting the large-sized substrate 1'' is formed. The width of the subsection can be between 50 //m~1 _. The 740 mm X 940 mm large-sized substrate 1 was cut into four 370 mm X 470 mm small substrates suitable for the deposition process. The large-sized substrate 丨〇 can be cut by laser, ultrasonic, diamond, etc., and then subjected to a cleaning process to remove dust particles generated by the cutting process. The cleaning process can be performed using a wet cleaning > 糸 process, an ultraviolet (UV) or a poly (p 1 asma) dry cleaning process, or both. Refer to "Figure 1 B" and use a mask on the small substrate! 〇〇, a hole injection layer 310 is formed on the anode layer 2 exposed on the plurality of openings 2 10 . The hole injection layer 310 can be opened by CuPC, m-MTDATA or the like. And a mask is also used on the hole injection layer 31 to form a hole transport layer 320. The organic electroluminescent layer 400 is also formed on the hole transport layer 320 by means of a mask, and includes three kinds of pixels of red, green and blue. In this example, the red pigment is formed using Alq3 + DCJTB or the like, which is formed using A1 q 3 + Q d 2 or a similar material, and the blue halogen is used.

Blq + perylene或類似的材料形成。而=該&機電致發光層 400上,亦利用一遮罩並使用^吆或類似材質形成一電子 輸送層3 3 0。Blq + perylene or similar material is formed. On the & electroluminescent layer 400, an electron transport layer 330 is also formed using a mask and using a material or the like.

第12頁 接著,在該電子輸送層330上則形成一電子注入層 3)0。然後以真空沉積法在該電子注入層34〇上形成金曰屬 i如紹)之一陰極層5 0 0。該電子注入層34〇係用以防止 l- 案號 91112915 曰 修兔 (8) 電洞流入該陰極以及改善該陰電極的電子注入效率,藉以 增加發光效率。此外,較佳來說可使用有機或無機材料在 該陰極層500上形成一保護層(未繪示),或者是在該陰 極層500上形成一金屬或玻璃上蓋,該上蓋並附著有一吸 溼(或吸氧)劑。 另外’對於高分子OELD,其有機電致發光層及辅助層 的薄膜是利用喷墨法、印刷法或旋轉塗佈法加以形成,而 其材料可包括前面所提及的材料。而低分子之OELD薄膜材 料亦可包括前面所提及的材料。 另一方面,上述本發明的第一個實施例中,該陰極層 500亦可先於該陽極層200而形成。 [第二實施例] 根據本發明第二貫施例之一種具有輔助電極的被動式 有機電致發光顯示器的製造方法說明如下。「第2A圖」為 本發明第二實施例之被動式OELD的俯視圖。「第2B圖」為 「第2A圖」之被動式OELD在a-a,方向的剖視圖,其中分隔 體則未被顯示出。 參考「第2A圖」’由透明塑膠或玻璃所做成的一大尺 寸基板1 0 0經過清〉糸後’再以錢鍵法(s p u t ^ e r i n g )將一 金屬層沉積在該大尺寸基板100上。該大尺寸基板100可為 740 mm X 940 mm,而該金屬層例如為cr、w、Mo、MoW、A1 等。在該金屬層上塗佈光阻然後加以曝光顯影以形成一光 阻圖案。利用該光阻圖案為罩幕(mask) #刻該金屬層以 形成條紋狀辅助電極6 0 0,輔助電極6 〇 〇係用以使後續形成 的陽極層2 0 0的電阻降低。Page 12 Next, an electron injecting layer 3)0 is formed on the electron transporting layer 330. Then, a cathode layer 500 of one of the metal enamels is formed on the electron injecting layer 34 by vacuum deposition. The electron injecting layer 34 is used to prevent the leakage of the electron injection into the cathode and improve the electron injection efficiency of the cathode electrode, thereby increasing the luminous efficiency. In addition, it is preferable to form a protective layer (not shown) on the cathode layer 500 by using an organic or inorganic material, or to form a metal or glass cover on the cathode layer 500, and the upper cover is attached with a moisture absorption. (or oxygen) agent. Further, for the polymer OELD, the film of the organic electroluminescent layer and the auxiliary layer is formed by an inkjet method, a printing method or a spin coating method, and the material thereof may include the materials mentioned above. The low molecular OELD film material may also include the materials mentioned above. On the other hand, in the first embodiment of the present invention described above, the cathode layer 500 may be formed prior to the anode layer 200. [Second Embodiment] A method of manufacturing a passive organic electroluminescence display having an auxiliary electrode according to a second embodiment of the present invention will be described below. Fig. 2A is a plan view of a passive OELD according to a second embodiment of the present invention. "Picture 2B" is a cross-sectional view of the passive OELD in "A2" in the direction of a-a, in which the separator is not displayed. Referring to "2A" "a large-sized substrate made of transparent plastic or glass 100 is cleared", a metal layer is deposited on the large-sized substrate 100 by a sput ering method. on. The large-sized substrate 100 may be 740 mm X 940 mm, and the metal layer is, for example, cr, w, Mo, MoW, A1, or the like. A photoresist is coated on the metal layer and then exposed and developed to form a photoresist pattern. The photoresist pattern is used as a mask to etch the metal layer to form a stripe-shaped auxiliary electrode 600, and the auxiliary electrode 6 is used to lower the resistance of the subsequently formed anode layer 200.

在具有一辅助電極6 0 0之大尺寸基板丨ο 〇上形成一氧化 銦錫層_(ΙΤΟ層)後,該ITQ層上可先塗佈一光阻層(圖 中未繪示),對該光阻層進行曝光與顯影用以形成一光阻 圖案(圖中未繪示)。然後將該光阻層顯影,再蝕刻該 ΙΤΟ層以在辅助電極6 0 0中形成一陽極層2〇〇。其中,陽極 層2 0 0形成類似條紋狀以便與辅助電極6 〇 〇並行。 並且使用與第一實施例相同的方法,在具有該陽極層 2 0 0的該大尺寸基板丨00上依序形成一介電層71 〇以及分隔 體720。然後,形成用来切割該大尺寸基板丨〇〇的一切割道 (未緣示),該切割道的寬度在50 〜1_之間。 將該740mm X 940mm的尺寸基板分割成四塊37〇_ χ 4 70mm的小基板1〇〇’ ,以適合於沉積製程。可利用雷射、 超音波、鑽石等,切割該大尺寸基板丨〇 〇,之後並施以一 清潔製程以去除切割製程所產生的塵粒。該清潔製程可利 用/£ β ’糸‘程、备、外光(U V )或電漿(p 1 a s m a )乾清潔製 程,或兩者同時使用。 接下來與第一實施例相同,在該37〇mm χ 47〇mm小基 板10 0’上形成電洞注入層31 〇、電洞輸送層32〇、電致發光 層400、電子輸送層330以及電子注入層340。可利用真空 /儿積法’以形成低分子材料之上述膜層,或者可利用喷 墨、印刷或旋轉塗佈法,以形成高分子材料之上述膜層。 而在該電子注入層34〇上則以真空沉積法形成一陰極層 5〇〇。接著再形成一保護層或封裝層。 曰 另一方面,該第二實施例中的陽極層2〇〇可先於該辅 助電極6 0 0,而形成於該大尺寸基板100上。 人After forming an indium tin oxide layer (ΙΤΟ layer) on the large-sized substrate 丨ο 具有 having an auxiliary electrode 600, the photoresist layer (not shown) may be coated on the ITQ layer. The photoresist layer is exposed and developed to form a photoresist pattern (not shown). The photoresist layer is then developed and the germanium layer is etched to form an anode layer 2 in the auxiliary electrode 600. Among them, the anode layer 200 is formed in a stripe shape so as to be in parallel with the auxiliary electrode 6 〇 . And, in the same manner as in the first embodiment, a dielectric layer 71 〇 and a spacer 720 are sequentially formed on the large-sized substrate 丨00 having the anode layer 200. Then, a scribe line (not shown) for cutting the large-sized substrate , is formed, and the width of the scribe line is between 50 〜1 _. The 740 mm X 940 mm size substrate was divided into four small substrates 1 〇〇 〇 70 4 70 mm to suit the deposition process. The large-sized substrate 丨〇 can be cut by laser, ultrasonic, diamond, etc., and then subjected to a cleaning process to remove dust particles generated by the cutting process. The cleaning process can be carried out using /£β'糸'process, preparation, external light (U V ) or plasma (p 1 a s m a ) dry cleaning process, or both. Next, as in the first embodiment, a hole injection layer 31 〇, a hole transport layer 32 〇, an electroluminescence layer 400, an electron transport layer 330, and the like are formed on the 37 〇mm χ 47 〇m small substrate 10 0 ′. Electron injection layer 340. The above-mentioned film layer of a low molecular material may be formed by a vacuum/integration method, or the above film layer of a polymer material may be formed by inkjet, printing or spin coating. On the electron injecting layer 34, a cathode layer 5 is formed by vacuum deposition. A protective layer or encapsulation layer is then formed. On the other hand, the anode layer 2 of the second embodiment can be formed on the large-sized substrate 100 before the auxiliary electrode 600. people

Ulj案號91112915 年月日 修正 至、發明說明(10) 根據本發明之第一與第二實施例中的被動式OELD的操 作如下所述:當施加一電壓於該陽極與陰極電極,電洞被 注入並通過該電洞輸送層而在該電致發光層而與通過該電 子輸送層的注入電子相結合,然後電子降落至基態而發射 出光。 該第一與第二實施例中,依照OELD的尺寸大小,在分 割自該74 0mm X 940mm大基板的該3 70mm X 470mm小基板 上,至少製作一OELD。 並且上述實施例中的大尺寸基板的尺寸可大於或小於 74 0mm X 9 40mm。另外,依照沉積設備的不同,該小尺寸 基板的尺寸亦可大於或小於3 7 0 X 4 7 0 mm,另外小基板的 分割數亦不限定為四塊,而可大於或小於四塊。且該基板 除了為透明基板外,亦可為一晶圓。 [第三實施例] 根據本發明第三實施例之一種主動式有機電致發光顯 示器的製造方法說明如下。依照結構的不同,主動式OELD 的電晶體與電容器的數目與安排方式亦不同。接下來,對 一種具有驅動電晶體(driving transistors)、開關電 晶體(switching transistors)以及電容器的主動式 OELD的製造方法加以說明。 第3 A、3 B圖,繪示根據本發明第三個實施例的一種主 動式OELD的製程剖視圖。 以氧化矽在一大尺寸基板丨〇〇上形成一介電層(未繪 示),而一多晶矽之主動層8 1 〇則被形成於該介電層上, 其中該介電層可利用濺鍍法或化學氣相沉積法(CVD )形Ulj Case No. 91112915 Revised to the Invention (10) The operation of the passive OELD according to the first and second embodiments of the present invention is as follows: when a voltage is applied to the anode and cathode electrodes, the hole is The electron transport layer is injected and passed through the electron transport layer to combine with the injected electrons passing through the electron transport layer, and then the electrons are dropped to the ground state to emit light. In the first and second embodiments, at least one OELD is formed on the 3 70 mm X 470 mm small substrate divided from the 74 mm x 940 mm large substrate in accordance with the size of the OELD. And the size of the large-sized substrate in the above embodiment may be larger or smaller than 74 0 mm X 9 40 mm. In addition, depending on the deposition apparatus, the size of the small-sized substrate may be greater than or less than 370×470 mm, and the number of divisions of the small substrate is not limited to four, but may be larger or smaller than four. And the substrate may be a wafer in addition to the transparent substrate. [Third Embodiment] A method of manufacturing an active organic electroluminescence display according to a third embodiment of the present invention will be described below. The number and arrangement of transistors and capacitors of active OELDs vary according to the structure. Next, a method of manufacturing an active OELD having driving transistors, switching transistors, and capacitors will be described. 3A and 3B are cross-sectional views showing a process of an active OELD according to a third embodiment of the present invention. A dielectric layer (not shown) is formed on the large-sized substrate by using yttrium oxide, and an active layer 8 1 多 of a polysilicon is formed on the dielectric layer, wherein the dielectric layer can be splashed. Plating or chemical vapor deposition (CVD)

第15頁 7 1262739 案號 91112Q15 五、發明說明(li) 修正 成’而該主動層810則是利用濺鍍或CVD法沉積一矽層而 得,然後對該矽層施以一雷射退火處理以形成一多晶石夕 層0 然後利用黃光微影(photolithography)製程,將該 主動層81 0圖案化成島狀。以濺鍍法或CVI)在該主動層81〇 上形成一匣極緣絕層8 2 0。利用濺鍍法或CVD在該匣極絕緣 層8 2 0上形成一金屬層,然後將該金屬層圖案化以形成厘 極8 3 0。其中該匣極83 0係形成於對應該主動層81〇的匣極 絕緣層8 2 0上。 在該主動層810實施離子摻入以及熱處理製程,用以 在該主動層8 1 0定義出源極以及汲極區域(未繪示)。接 著,在該包括匣極絕緣層820以及匣極830的該基板1〇〇上 形成一第二介電極840,選擇性地蝕刻該第二介電極84〇與 該E極絕緣層8 2 0對應該源極區域與汲極區域的部分,以 形成適當的接觸口。 接下來’在一驅動薄膜電晶體的對應該源極區域與該 /及極區域的接觸口分別形成訊號極(bus electr〇de ) 9⑽ 以及陽極層2 0 0。在一開關薄膜電晶體的一源極區域之一 電訊極上形成一訊號線,而在該驅動元件的該匣極以及該 開關元件的該汲極則形成一儲極(st〇rage electr〇de) 如此而被連接至一電容器。其中該陽極層2〇〇係做為有機 電致發光之陽極層。 介 出 為了在該製做好的驅動部上形成一顯示部,先形成一 電層7 1 0在該驅動部結構上,然後蝕刻該保護層以曝露 部分的該陽極層2 0 0。Page 15 7 1262739 Case No. 91112Q15 V. Description of the invention (li) Corrected as 'the active layer 810 is obtained by sputtering a layer of CVD or CVD, and then applying a laser annealing treatment to the layer To form a polycrystalline layer 0 and then use a yellow photolithography process to pattern the active layer 81 0 into an island shape. A crucible layer 820 is formed on the active layer 81A by sputtering or CVI. A metal layer is formed on the gate insulating layer 820 by sputtering or CVD, and then the metal layer is patterned to form a PCT 830. The drain 83 0 is formed on the drain insulating layer 820 corresponding to the active layer 81A. An ion doping and heat treatment process is performed on the active layer 810 to define source and drain regions (not shown) in the active layer 810. Next, a second dielectric electrode 840 is formed on the substrate 1B including the drain insulating layer 820 and the drain 830, and the second dielectric electrode 84 is selectively etched and the E-electrode insulating layer is 80 2 0. The source area and the bungee area should be part of the area to form the appropriate contact. Next, a signal electrode (9) and an anode layer 200 are formed at the contact openings of the corresponding source regions and the/and the regions of the driving thin film transistor, respectively. Forming a signal line on a telecommunications pole of a source region of a switching thin film transistor, and forming a drain electrode at the drain of the driving element and the drain of the switching element. This is connected to a capacitor. The anode layer 2 is used as an anode layer of organic electroluminescence. In order to form a display portion on the driving portion which is completed, an electric layer 710 is formed on the driving portion structure, and then the protective layer is etched to expose a portion of the anode layer 200.

(1262739 _ 0,1— ^_ 案號 91112915_年月曰 _修正 五、發明說明(12) 當該主動層810、匣極絕緣層820以及該匣極830隨之 被形成在該大尺寸基板1 〇 〇後,形成一切割道(圖中未緣 示)以用來切割該大尺寸基板1 〇 〇,該切割道的寬度在 5 0 // m〜1 mm之間。 將該740mm X 940mm的尺寸基板分割成四塊37〇麗χ 470mm的小基板1〇〇,,以適合於沉積製程。可利用雷射、 超S波、鑽石專’切割該大尺寸基板1 Q 〇,之後並施以一 清潔製程以去除切割製程所產生的塵粒,該清潔製程可利 用溼清潔製程、紫外光(UV)或電漿(plasmaf乾清潔製 程,或兩者同時使用。 接下來與本發明之第一及第二實施例相同,在該 370mm χ 470mm小基板100’上形成電洞注入層31〇、電洞輸 送層320、電致發光層400、電子輸送層33()以及電子注入 層340。可利用真空沉積法,以形成低分子材料之上述膜 層,或者可利用喷墨、印刷或旋轉塗佈法,以形成高分子 材料之上述膜層。而在該電子注入層34〇上則以真空沉積 法形成一陰極層5 0 0。接著再形成一保護層或封裝層。如 此即製成如「第3B圖」所示之具有驅動部的主動式〇EL])。 在本發明第三實施例中,依照該主動式⑽汕的尺寸大 小,在分割自該740mm χ 940mm大基板的該37〇mm χ 47〇nim 小基板上,至少製作一OELD。 而上述第三實施例中的大尺寸基板的尺寸可大於或小 於740mm χ 94 0mm。另外,依照沉積設備的不同,該小尺 寸基板的尺寸亦可大於或小於37〇 χ 47〇_,另外小基板 的分割數亦不限定為四塊’而可大於或小於四塊。亦可先(1262739 _ 0,1— ^_ Case No. 91911915_年月曰 修正 Revision 5, Invention Description (12) When the active layer 810, the drain insulating layer 820, and the drain 830 are formed on the large-sized substrate After 1 ,, a scribe line (not shown) is formed for cutting the large-sized substrate 1 〇〇, the width of the scribe line is between 50 // m~1 mm. The 740 mm X 940 mm The size of the substrate is divided into four pieces of 37 〇 470 470mm small substrate 1 〇〇, to suit the deposition process. Laser, super S wave, diamond can be used to 'cut the large size substrate 1 Q 〇, then apply The cleaning process can be used to remove the dust particles generated by the cutting process, and the cleaning process can be performed by a wet cleaning process, ultraviolet light (UV) or plasma (plasmaf dry cleaning process, or both). As in the second embodiment, a hole injection layer 31, a hole transport layer 320, an electroluminescence layer 400, an electron transport layer 33 (), and an electron injection layer 340 are formed on the 370 mm 470 mm small substrate 100'. Vacuum deposition may be utilized to form the above-described film layer of low molecular material, or The above-mentioned film layer of the polymer material may be formed by inkjet, printing or spin coating, and a cathode layer 500 is formed by vacuum deposition on the electron injecting layer 34. Then a protective layer is formed. Or an encapsulation layer. Thus, an active 〇EL having a driving portion as shown in "FIG. 3B" is formed.] In the third embodiment of the present invention, in accordance with the size of the active (10) ,, it is divided At least one OELD is formed on the 37 mm mm χ 47〇nim small substrate of the 740 mm 940 940 mm large substrate. The size of the large-sized substrate in the third embodiment described above may be larger or smaller than 740 mm χ 94 0 mm. The size of the small-sized substrate may be greater than or less than 37〇χ 47〇_, and the number of divisions of the small substrate is not limited to four pieces but may be larger or smaller than four pieces.

第17頁 ie-s- 案號 91112915 年月曰_修正 做該陰極層5 0 0,然後再做ITO陽極層2 0 0,並且該基板除 了為透明基板外,亦可為一晶圓。 根據本發明之該第三實施例中的主動式0ELD的操作如 下所述:當施加一電壓於被一薄膜電晶體所選定晝素的陽 極與陰極,電洞被注入並通過該電洞輸送層而在該電致發 光層而與通過該電子輸送層的注入電子相結合,於是被激 發的電子降落至基態而發射出光。 據此,根據本發明的〇ELD製造方法具有下述優點:本 發明主要被分成不需要有機發光層及其輔助層沉積或印刷 設備的前製程’以及需要有機發光層及其輔助層沉積或印 刷設備的後段製程。該大尺寸基板經過適當的準備與前段 製程後’被分割成尺寸適合沉積或印刷設備的小基板,用 以形成形成電致發光層或辅助層。 十如此之0ELD製造方法,克服了因沉積或印刷設備的爐 管尺寸而對基板所造成的尺寸限制,而能夠在一大尺寸基 板上貫施則述的製程。於是本發明能夠增進生產並 生產成本。 刖述貫施例僅用以舉例說明而非用以限制本發明的範 圍,而所教述之内容亦可運用在其它形式的裝置上,熟 該項技術者在不脫離本發明之精神下當可做適當之修改盥 潤飾;故凡依本發明申請專利範圍所作的均等變化與修” 飾’皆為本發明專利範圍所涵蓋。Page 17 ie-s- Case No. 91112915 曰 修正 Amendment This cathode layer 500 is made, and then the ITO anode layer 200 is made, and the substrate can be a wafer in addition to the transparent substrate. The operation of the active OLED according to the third embodiment of the present invention is as follows: when a voltage is applied to the anode and cathode of the halogen selected by a thin film transistor, a hole is injected and passed through the hole transport layer. In the electroluminescent layer, in combination with the injected electrons passing through the electron transporting layer, the excited electrons then fall to the ground state to emit light. Accordingly, the 〇ELD manufacturing method according to the present invention has the advantage that the present invention is mainly divided into a front process that does not require an organic light-emitting layer and its auxiliary layer deposition or printing apparatus, and that an organic light-emitting layer and its auxiliary layer are required to be deposited or printed. The back-end process of the device. The large-sized substrate is divided into small substrates sized to be suitable for deposition or printing equipment after appropriate preparation and front-end processing to form an electroluminescent layer or an auxiliary layer. Ten such OLED manufacturing methods overcome the size constraints imposed on the substrate by the size of the tube of the deposition or printing apparatus, and can be applied to a large-scale substrate. Thus, the present invention can increase production and production costs. The description of the present invention is intended to be illustrative only and not to limit the scope of the present invention, and the teachings may be applied to other forms of the device without departing from the spirit of the invention. Appropriate modifications and modifications may be made to the invention; therefore, the equivalent changes and modifications made in accordance with the scope of the patent application of the present invention are covered by the scope of the invention.

第18頁 案號 91112915_年月日__ ... -_____________ — .、♦— 一'....一、 圖式簡單說明 為使對本發明有更進一步的認識,說明書中併入附圖 並配合詳細說明以對本發明之實施例加以解說,並解釋本 發明的原理。 第1 A圖繪示根據本發明第一個實施例的一種被動式 OELD的俯視圖。 第1 B圖繪示根據本發明第一個實施例的一種被動式 OELD的剖視圖。 第2 A圖繪示根據本發明第二個實施例的一種被動式 OELD的俯視圖。 第2B圖繪示根據本發明第二個實施例的一種被動式 OELD的剖視圖。 第3A、3B圖繪示根據本發明第三個實施例的一種主動 式OELD的製程剖視圖。 第4圖繪示一種習知的0 E L D的剖面示意圖。 【圖式符號說明】 11 透 明 基 板 12 陽 極 層 13 電 洞 注 入層 14 電 洞 輸 送層 15 電 致 發 光層 17 電 子 輸 送層 18 陰 極 層 100 基 板 100’ 小 基 板Page 18 Case No. 91112915_年月日日__ ... -_____________ — . ♦ — a '.... I. BRIEF DESCRIPTION OF THE DRAWINGS In order to further understand the present invention, the description incorporates the drawings. The embodiments of the present invention are explained in conjunction with the detailed description and the principles of the invention are explained. Fig. 1A is a plan view showing a passive OELD according to a first embodiment of the present invention. Fig. 1B is a cross-sectional view showing a passive OELD according to a first embodiment of the present invention. 2A is a top plan view of a passive OELD in accordance with a second embodiment of the present invention. 2B is a cross-sectional view of a passive OELD in accordance with a second embodiment of the present invention. 3A and 3B are cross-sectional views showing a process of an active OELD according to a third embodiment of the present invention. FIG. 4 is a schematic cross-sectional view showing a conventional 0 E L D . [Illustration of the symbol] 11 transparent substrate 12 anode layer 13 hole injection layer 14 hole transmission layer 15 electroluminescent layer 17 electron transport layer 18 cathode layer 100 base plate 100' small substrate

第19頁 案號 91112915 年 月 修正 1262739 C~ 1( \ 圖式簡單說明 200 陽 極 ( 1丁0 )層 210 開 α 310 電 洞 注 入 層 320 電 洞 fm 送層 330 電 子 ¥m 送 層 340 電 子 注 入 層 400 電 致 發 光 層 500 陰 極 層 600 輔 助 電 極 710 介 電 層 720 分 隔 體 810 主 動 層 820 匣 極 絕 緣 層 830 匣 極 840 第 二 介 電 極 900 訊 號 層Page 19 Case No. 91911915 Revised 1262739 C~ 1 ( \ Schematic description 200 anode (1 butyl 0) layer 210 open α 310 hole injection layer 320 hole fm delivery layer 330 electron ¥m delivery layer 340 electron injection Layer 400 electroluminescent layer 500 cathode layer 600 auxiliary electrode 710 dielectric layer 720 separator 810 active layer 820 gate insulating layer 830 bungee 840 second dielectric electrode 900 signal layer

第20頁Page 20

Claims (1)

案號 91112915Case number 91112915 六、申請專利範圍 1 · 一種有機電致發光顯示器的製造方法,至少包含下列步 形 將 形 一電極 形 2. 如申請 造方法 形 層; 形 IT0層 形 並垂直 3. 如申請 造方法 而該小 4. 如申請 造方法 石其中 5·如申請 該 以及 成複數個 該I TO層。 專利範圍 ,其中該 基板的尺 專利範圍 ,其中該 之一加以 專利範圍 造方法,在分割 施一清潔步驟。 成一第一電極層在一大尺寸基板上; 該大尺寸基板分割成複數個小基板; 成一有機電致發光層在至少一該小基板上的該第 層上;以及 成一第二電極層在該有機電致發光層上。 專利範圍第1項所述之有機電致發光顯示器的製 ,在分割該大尺寸基板前,更包含下列步驟·· 成一 IT0層在該大尺寸基板上以做為該第一電極 成一具有複數個開口的介電層,以曝露出部分 分隔體(separators )在該介電層上, 弟1項所述之有機電致發光顯示器的製 大尺寸基板的尺寸為740mm X 940_, 寸為 370mm x 47 0mm。 第1項所述之有機電致發光顯示器的製 大尺寸基板係利用雷射、超音波以及鑽 分割。 第1項所述之有機電致發光顯示器的製 該大尺寸基板的步驟後後,更包含有實Sixth, the scope of application for patents 1 · A method of manufacturing an organic electroluminescent display, comprising at least the following steps to form an electrode shape 2. If the application method is formed; the shape of the IT0 layer is vertical and 3. If the application method is applied Small 4. If you apply for a method stone, 5, if you apply for it, and a plurality of the I TO layer. The patent scope, wherein the substrate is within the patent range, one of which is patented by the method of manufacture, in the division of a cleaning step. Forming a first electrode layer on a large-sized substrate; dividing the large-sized substrate into a plurality of small substrates; forming an organic electroluminescent layer on the first layer on the at least one small substrate; and forming a second electrode layer On the organic electroluminescent layer. The method of the organic electroluminescent display of claim 1, further comprising the steps of: forming an IT0 layer on the large-sized substrate as the first electrode and having a plurality of layers before dividing the large-sized substrate. An open dielectric layer is formed on the dielectric layer to expose a portion of the organic electroluminescent display having a size of 740 mm X 940 _ and an inch size of 370 mm x 47 0mm. The large-sized substrate of the organic electroluminescence display according to the first aspect is divided by laser, ultrasonic wave, and drill. The step of manufacturing the large-sized substrate of the organic electroluminescent display according to Item 1 is further included 第21頁 1262739 :案號 91112915Page 21 1262739: Case No. 91112915 介、申谱專利範圍 6. 如申請專利範圍第1項所述之有機電致發光顯示器的製 造方法,其中該第-及第二電極層可為相配合之陽極或 陰極層。 7.如中請專利範®第1、項所述之有機電致發光顯示器的製 造方法,更包含形成一輔助電極層在該第一電極層之上 或之下的步驟。 8 ·如申请專利範圍第1項所述之有機電致發光顯示器的製 造方法,其中該有機電致發光層包括電洞注入層、電洞 輸送層、電致發光層、電子輸送層以及電子注入層。 9 ·如申清專利範圍第1項所述之有機電致發光顯示器的製 造方法,更包含在該第二電極層上形成一保護層或封裝 層的步驟。 10· —種有機電致發光顯示器的製造方法,至少包含下列 步驟: 在一大尺寸基板上形成一驅動部,該驅動部包括 複數個電晶體以及至少一電容器並具有一第一電極 層; 將該大尺寸基板分割成複數個小基板; 形成一有機電致發光層在至少一該小基板的該驅 動部的該第一電極層上;以及 形以一第二電極層在該有機電致發光層上。 11如申讀專利範圍第10項所述之有機電致發光顯示器的 制造方法’其中並備有用來分割該大尺寸基板的切割 =,該切割道寬度在50 〜lmm之間。The method of manufacturing an organic electroluminescent display according to claim 1, wherein the first and second electrode layers are a matching anode or cathode layer. 7. The method of fabricating an organic electroluminescent display according to claim 1, further comprising the step of forming an auxiliary electrode layer above or below the first electrode layer. The method of manufacturing an organic electroluminescence display according to claim 1, wherein the organic electroluminescent layer comprises a hole injection layer, a hole transport layer, an electroluminescence layer, an electron transport layer, and an electron injection Floor. 9. The method of fabricating an organic electroluminescent display according to claim 1, further comprising the step of forming a protective layer or an encapsulation layer on the second electrode layer. 10. A method of fabricating an organic electroluminescent display, comprising the steps of: forming a driving portion on a large-sized substrate, the driving portion comprising a plurality of transistors and at least one capacitor and having a first electrode layer; The large-sized substrate is divided into a plurality of small substrates; an organic electroluminescent layer is formed on the first electrode layer of the driving portion of at least one of the small substrates; and a second electrode layer is formed in the organic electroluminescence On the floor. 11. The method of manufacturing an organic electroluminescence display according to claim 10, wherein a cut = for dividing the large-sized substrate is provided, and the width of the scribe line is between 50 mm and 1 mm. 第22頁 1262739 案號 91112915 年 修正 六、申請專利範圍 1 2 ·如申請專利範圍第1 0項所述之有機電致發光顯示器的 製造方法’其中該大尺寸基板上的該驅動部包含一驅 動電晶體、一開關電晶體(switching transistor ) 以及一電容器。 1 3 ·如申請專利範圍第1 〇項所述之有機電致發光顯示器的 製造方法’其中該形成該驅動部的步驟包含: 在該大尺寸基板上依序形成一介電層以及一主動 層; 形成一 S極絕緣層在該介電層以及該主動層上 形成一匣極在對應該主動層的該匣極絕緣層上 形成一源極以及一汲極於該主動層; 形成一第二介電層在包括有該匣極以及該匣極 緣層的該大尺寸基板上; 選擇性#刻該第二介電極以及該匣極絕緣層,以 形成對應該源極與没極的接觸口; 刀別在該驅動電晶體對應該源極以及該汲極的接 觸口形成訊號極以及第一電極;以及 开/成一訊號線在該開關電晶體源極的該訊號極 上,以及形成一儲極在該驅動電晶體匣極以及該開關 電晶體汲極,用以被連接至該電容器。 14. 15. 電致發光顯示器的 苐二電極層可為相 如申请專利範圍第1 0項所述之有機 製造方法,其中該第一電極層以及 配合之陽極或陰極層。 如申請專利範圍第丨0項所述之有機 電致發光顯示器的</ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; A transistor, a switching transistor, and a capacitor. The method for manufacturing an organic electroluminescence display according to the first aspect of the invention, wherein the step of forming the driving portion comprises: sequentially forming a dielectric layer and an active layer on the large-sized substrate Forming an S-pole insulating layer, forming a drain on the dielectric layer and the active layer, forming a source and a drain on the drain insulating layer corresponding to the active layer; forming a second a dielectric layer on the large-sized substrate including the drain and the drain-edge layer; selectively etching the second dielectric electrode and the drain insulating layer to form a contact port corresponding to the source and the gate a knife forming a signal electrode and a first electrode at a contact opening of the driving transistor corresponding to the source and the drain; and opening/forming a signal line on the signal electrode of the switching transistor source, and forming a reservoir The driving transistor drain and the switching transistor drain are connected to the capacitor. 14. The second electrode layer of the electroluminescent display can be an organic manufacturing method as described in claim 10, wherein the first electrode layer and the combined anode or cathode layer. For example, the organic electroluminescent display of claim No. 0 ·.......&gt; . •-仏. f臟麵 r η k q 案號91112915_年月曰 修正:_ —w’、…‘申ifmu 製造方法,其中該有機電致發光層包括電洞注入層、 電洞輸送層、電致發光層、電子輸送層以及電子注入 ^L· 〇 1 6.如申請專利範圍第1 0項所述之有機電致發光顯示器的 製造方法,更包含在該第二電極層上形成一保護層或 封裝層的步驟。·..&gt; . •-仏.f dirty surface r η kq Case No. 91112915_年月曰 Correction: _ —w′,... '申ifmu manufacturing method, wherein the organic electroluminescent layer includes a hole injection layer, a hole transport layer, an electroluminescence layer, an electron transport layer, and an electron injection layer. 6. The method for manufacturing an organic electroluminescence display according to claim 10, further comprising A step of forming a protective layer or an encapsulation layer on the second electrode layer. 第24頁Page 24
TW91112915A 2002-03-18 2002-06-13 Method of fabricating organic electroluminescent display TWI262739B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9136491B2 (en) 2008-08-27 2015-09-15 Sumitomo Chemical Company, Limited Organic electroluminescent element and method for producing the same
TWI552403B (en) * 2010-12-20 2016-10-01 京東方科技集團股份有限公司 Large area light emitting electrical package with current spreading bus

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9136491B2 (en) 2008-08-27 2015-09-15 Sumitomo Chemical Company, Limited Organic electroluminescent element and method for producing the same
TWI552403B (en) * 2010-12-20 2016-10-01 京東方科技集團股份有限公司 Large area light emitting electrical package with current spreading bus

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