TWI250378B - Photosensitive resin composition - Google Patents

Abstract

Photosensitive compositions comprising (A) an alkali soluble compound; (B) at least one compound of formula I or II, R1 inter alia is C4-C9cycloalkanoyl, C3-C12alkenoyl, or benzoyl which is unsubstituted or substituted; Ar1 is either C6-C20aryl or C6-C20aryloyl each of which is unsubstituted or substituted; x is 2 or 3; M1 when x is 2, inter alia is a group phenylene or naphthylene, each of which optionally is substituted i.a. by OR3, SR4 or NR5R6; or M1, when x is 3, is a trivalent group, optionally substituted; R3 is for example hydrogen or C1-C12alkyl; C2-C6alkyl which is for example substituted by -OH, -SH, -CN, C3-C6alkenoxy, or -OCH2CH2CN; R4 is for ex-ample hydrogen, C1-C12alkyl, C3-C12alkenyl, cyclohexyl, or phenyl which is unsubstituted or substituted; R5 and R6 independently of each other inter alia are hydrogen, C1-C12alkyl, C2-C4hydroxyalkyl, C2-C10alkoxyalkyl, C3-C5alkenyl, C3-C8cycloalkyl, phenyl-C1-C3alkyl, C1-C4alkanoyl, C3-C6alkenoyl. Benzoyl or phenyl which is unsubstituted or substituted; and (C) a photopolymerizable compound; exhibit an unexpectedly good performance, in particular in photoresist technology.

Description

1250378 A7 B7 V. INSTRUCTION DESCRIPTION OF THE INVENTION (The present invention is directed to a light-sensitive composition of a lipid compound which is photo-initiated from the US Patent No. 3 2 5 5 5 1 3*4 5 by alkali, including an expectorant. 558309, 42 0 2697, 4 90 1 45, a rouge derivative is known as a photoinitiator. It is disclosed in Japanese Kokai Hei 8-272095, which contains i-phenyl-1,4-propanedione-2. 0-benzonitrile and 1-phenyl-1,2-propanedione-2- 2-0-ethoxycarbonyl ruthenium as a light-initiating agent for solder resist ink composition. In Japan Kofcai Hei8-33908 1 Using a similar composition of 1 -phenyl-1,2-propanedione-one in a light-concentrating imaging formulation is easy to handle, and the high demand is surprising, including (A) at least (B) at least 2 - 0 B In the oxycarbonyl domain, still, and the composition of the analytical reaction mixture is good, such as thermal stability and surprise, a base has been found. However, it is necessary to be particularly suitable for being reversible. Astringent, alkali can be imaged, quality, and in line with industrial storage stability for properties. Light-sensitive composition (please read the notes on the back and fill out this page) 0 -------Book·-------I 1 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints one of the bases Soluble adhesive resin, prepolymer or monomer component; a compound of formula I or II,

Ar,—C—Η (I) Μ;

0-R1 i 1 N II -C—H -5 This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (ll), Ϊ250378 A7 B7 V. Invention description ( )) - C9 naphthenic Sulfhydryl, C3 - Ci2 olefinic group; Ci-C20 alkanoyl group, which is unsubstituted or substituted by one or more halogens, CN or phenyl; or 1^i is a benzamidine group, Is unsubstituted or substituted by one or more Ci-Cs alkyl, halogen, CN, OR3, SR4 or NRs R6; or Ri is C2-ci2 alkoxy or benzyloxycarbonyl; Phenoxycarbonyl* which is unsubstituted or substituted by one or more Cl-C6 alkyl or dentate;

Ar i is (6-C2 aryl or C6 - 〇2 aryl), both unsubstituted, or halogen, Ci-C2o alkyl, benzyl, Ci-C2 o alkane a C3-C8 cycloalkyl group substituted 1 to 12 times; or the Ce-C2 aryl group or Ce-C2 aryl aryl group is substituted via a phenyl or benzhydryl group, each of which is a selective Substituted by one or more of 0R3, SR4 or NR5 Rs; or the C6-C2 aryl or Cs-C2 aryl aryl group is substituted via Cz-C^2 alkoxycarbonyl, this C2 - Ci 2 oxime a carbonyl group is optionally interrupted by one or more 0's, and/or optionally substituted with one or more hydroxy groups; or the -Cz 0 aryl group or C6 —(:2 〇 aryl aryl group is a phenoxycarbonyl group, OR3, SR3 > S 0 R 4 , SO2 R4 or NR5 Rg substituted wherein the substituent OR3, SRs or NRsRs via a Rs, R4, a 5 and/or 6 substituent and a C6 - C2 The carbon atom of the aryl group on the aryl or Cs-C2 fluorene ring selectively forms a 5- or 6-membered ring; or Ar ! is a 〇3 - C9 heteroaryl group, if Ri is an ethylenic group, The -6 - the paper Applicable to Chinese national standards (CN^A4 specifications (MO Χ 297 mm) (please read the notes on the back and fill out this page) Order---------Line! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printed 1250378 A7 B7 V. Description of the invention (3 C3 - C9 heteroaryl is unsubstituted or via halogen, Ci-C20 alkyl, benzyl, Ci-C20 alkanoyl, or C3-C8 cycloalkyl Substituted 1 to 7 times; or the C3 - c9 heteroaryl group is substituted via a phenyl or benzhydryl group, each of which is optionally substituted with one or more ORs, SR4 or NR5 R6; C3 - C9 aryl is substituted via C2 - Ci 2 alkoxycarbonyl, and this C2 - Ci 2 alkoxycarbonyl is interrupted via one or more 0's, and/or by one or more hydroxyl groups Substituted; or the c6 aryl or ce-c2 indenyl is substituted via phenoxycarbonyl, or3*SR4, SORR4, S02R4 or nr5r6; X is 2 or 3; when X is 2, M i is

(Please read the notes on the back and fill out this page.) Printed by the Consumer Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs.

Order ---------Line 丨 _ This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 V. Invention Description (>) Each of which is selective halogen , Ci-Ci 2 alkyl, C3-C3 cycloalkyl, benzyl substituted 1 to 12 times; phenyl, which is unsubstituted or substituted by one or more OR3, SR4 or NR5 R6; a benzhydryl group which is unsubstituted or substituted by one or more of 0 R3 • or NR 5 R 6 ; Ci — Ci 2 alkyl fluorenyl; C 2 — Ci 2 alkoxycarbonyl, which is optionally via one or Multiple one-to-one interrupted, and/or selectively substituted with one or more of 0H, phenoxycarbonyl* 0 R 3 , SR4 , S02R4 or NR5Re; or when X is 3, Mi is (please read first) Note on the back side of this page) ο-1 or

〇 丨 丨 ^ Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed each of them by halogen, (: i -Ci 2 alkyl, C3 - C8 cycloalkyl substituted 1 to 12 times; phenyl, which is not Substituted or substituted by one or more of 0R3, SR4 or NRs R6; benzyl, benzhydryl, C!-Ci 2 alkanoyl; C2-Ci 2 alkoxycarbonyl-8 - paper scale Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _B7 V. Inventive Note (y) base, which is selectively interrupted by one or more ones, and/or selective Substituted by one or more hydroxyl groups, phenoxycarbonyl, OR3, SR4, S0R4, S〇2R4 or NR5Re; M2 is a direct bond, a 0-, an S-, an SS-, an NR3-, a (C 0 ) one, Ci-Ciz alkylene, cyclohexene, phenylene, one by one (CO) 0 - (C2 - Ci2 alkylene) - 0 (CO) one, one (C 0 ) 0 - ( C Η 2 C Η 2 Ο ) η - (CO) one or one (CO) - (Cz - Ci2 burnt) - (CO) -; or M2 is C4 - Ci 2 alkylene or C4 - Ci 2 alkylene Oxyl, each of which Selectively interrupted by 1 to 5 - 0 -, 1 - and / or NR 3 -; M3 is a direct key, a CHz -, a 0 -, an S -, an SS -, an NR3 - Or one (C0) —; (please read the note on the back and fill out this page); 0 H ϋ nnnn one-· n ϋ nn in ni I n , Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed R 3 is hydrogen Or C 1 -C 2 0 alkyl; or R 3 is C 2 -C 2 2 alkyl, which is via a 〇Η > - S Η 9 - C Ν 9 C 3 - c 6 alkenyloxy group, C Η 2 C Η 2 CN $ -0 C Η 2 C Η 2 ( c 0 ) 0 ( C 1 — C 4 alkyl) — 〇 (C 0 ) — C 1 — c 4 焼 9 — 〇 (C 〇 a phenyl f — ( C 0 ) 〇Η f a (c 0 ) 〇-9-

This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm). Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1250378 A7 _B7 V. Invention description (έ)

(C1-C4 alkyl), a NiCi-C* alkyl) 2 , a N (C Η 2 C Η 2 Ο Η ) z , a N [CH 2 CH 2 〇 1 (C 0) — Ci — C 4 alkyl] 2 Or morpholinyl substituted; or Rs is C2 - Ci 2 alkyl, which is interrupted by one or more 0's; or R3 is a (CH2CH2〇) n + iH, an i C Η 2 C Η 2 0 ) n (CO) a Ci-C8 alkyl group,

Ci-C8 alkanoyl, C3 - alkenyl, C3 - Cs olefin, C3 - C8 cycloalkyl; or Rs is benzinyl, which is unsubstituted or via one or more Ci-C6 alkane a group, a halogen, a 0H or a Ci_C4 alkoxy group; or R3 is a phenyl group, or a naphthyl group; each of which is unsubstituted, or via a halogen, an OH, a Ci-C! 2 alkyl group, Ci-Ci 2 alkoxy, phenyl-Ci-C3-alkoxy, phenoxy, Ct-Ci 2 alkylsulfonyl, phenylsulfonyl-N (Ci-Ci2 alkyl) 2, diphenyl Amine or a (CO) R7 substituted; or R3 is phenyl-Ci-Cs alkyl, or Si(C!-Cs alkyl)r(phenyl)3_r; r is 0,1,2 or 3; η is 1 to 20; R4 is hydrogen, Ci-Czo alkyl, C3-C12 alkenyl, C3-C8 cycloalkyl, phenyl-Ci-C3 alkyl; C2-C8 alkyl, which is via 0H , a SH, a CN, a C3 - C6 alkenyloxy group, an OCH2CH2CN, an OCH2CH2 (C 0 ) 0 (Ci_C4 alkyl group), a 0 (C0) - (: ^ 〇 4 alkyl group, a - -10- The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back first) Note: Please fill in this page again) 0 mmmmf *1 mnn··- n HI I. Mouth, · An In nm tmt a-- i·-· I mmm 1 1250378 A7 B7 V. Description of invention (7) 〇 (C 0) a phenyl group, a (CO) 0H or a (C0) 0 (

Cl -C4 alkyl) substituted; or R4 is C2 - Ci 2 alkyl, which is interrupted by one or more 0- or one S-; or R4 is -CtCHzCHzO) η + ιΗ, one (CHzCHzO n(CO) - Ci - Cs alkyl, C2 - C8 alkyl fluorenyl, C3 - 2, C3 - Cs, or R4, phenyl or naphthyl, unsubstituted or halogenated , Ci —Ci 2 alkyl,

Ci-Ci2 decyloxy or one (CO) R7 substituted;

Rs and R6 are mutually exclusive, hydrogen, Ct - 2 decyl, C 2 - C 4 hydroxyalkyl, C 2 - Ci 0 alkoxyalkyl, C 3 - C 5 alkenyl, C 3 - C 8 cycloalkyl, Phenyl-Ci-C3 alkyl, Ci-C4 alkanoyl, C3-ci2 olefin, benzhydryl; or phenyl or naphthyl, each of which is unsubstituted or via C i - Ci 2 alkyl or CA — Cl 2 alkoxy substituted; or Rs and Rs — C are C 2 —Ce alkylene, which is selectively interrupted by a 0 — or a NR 3 — and/or selectivity Substituted by hydroxyl group, Ci-C4 alkoxy group, C2-C4 alkanoyloxy group or benzylideneoxy group (please read the back note first and then fill in this page) Order --------- line! Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing base, alkane ο ο 2 a C, I base 1 benzene C, ' hydrogen hydrogen is from 7 through R is C 1 2 C is or

Η S

Ν C

Its J I base CO alkane C

ο 氧 烯 ο ο 4 c ( C olefin C ο 2 4 Η C C I ο 1

ο C

2 Η Η ) ο Co) 0 C ο 1 ( c, ο ( Ν I I C, , 2 } benzyl benzene C alkane I

Η c C or 2 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 Α7 5. Invention description u) CO) O (Ci 〇4 alkyl) substituted; or R7 is c2 -

Cl 2 alkyl, which is interrupted by one or more 0's; or R7 is a (CH2CH2C)) n + iH, a (C Η 2 C Η 2 0 ) n (CO)-Ci-Cs alkane a C3 -C12 alkenyl group, a C3 -C8 cycloalkyl group; a phenyl group which is optionally subjected to one or more halogens, one to one (: 12 alkyl group, Ci-C12 alkoxy group, phenoxy group, Cl one Ci 2 is a phenyl group, a N ( Ci-(:12 alkyl) 2 , or diphenylamino group substituted; and a photopolymerizable compound; there is unpredictable good performance .

Ci-C2 decyl group is linear or branched, for example Ci-C 1 8 one, Ci-C14 one, Ci-Ci-C, one Ci

Cs —, Ci — Ce — or Ci—C4—alkyl or C4

Ci 2 — or C 4 — C8 alkyl. Examples are methyl, ethyl, propyl, isopropyl, n-butyl, second monobutyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, 2,4,4 a Methyl amyl, 2-ethylhexyl, octyl, decyl, decyl, dodecyl, tetradecyl, pentadecyl, hexadecyl, octadecyl and decyl. Ci-Cl 2 alkyl,

Cl—C6 alkyl, C 2 —Ce alkyl and Ci—C 4 alkyl have the same meaning as the above Ci 1 (: 20 alkyl having the same number of carbon atoms. C 2 — C 2 decyl, which is via one or more Interrupted by a 0 - for example, by a 0 - interrupt 1 - 9, 1 - 5, 1 - 3 or once or twice. Two 0 - the atom is composed of at least two beacons, that is, B Separated by the support. The alkyl group is linear or contains a bond, for example, the underarm structure unit-12- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first) Fill in this page) Order---------Line! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Ministry of Printing and Economy Ministry Intellectual Property Bureau Staff Consumer Cooperatives Printed Clothing 1250378 A7 _B7__ V. Invention Description (7) :- CH2 - CH2 -0 - CH2CH3 , a CC Η 2 C Η 2 Ο ] y — CH3 , where y=l — 9, —(CHzCHzO)? - CH2CH3 , -C Η 2 a CH ( C Η 3 ) a 0 - CHz - CH2 CH3 or a C ϋ 2 - CH ( C Η 3 ) - 0 - C Η 2 - C Η 3. Examples of C2 - C6 alkyl interrupted by 1 or 2 - 0 - · · · CH2 CH2 - 〇-CH2 CH2 - OCHz CH3 or a CH2 CHz - 〇-CH2 CH3 〇C2 - C4 hydroxyalkyl means C2-C4 alkyl substituted by one or two 0-atoms, which may be linear or branched Examples of the bond are 2-hydroxyethyl, 1-hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 3-cysopropyl, 1-monobutyl*4-butylbutyl* 2 Hydroxybutyl, 2-hydroxybutyl, 3-hydroxybutyl, 2,3-dihydroxypropyl, or 2,4-dihydroxybutyl. Examples of C3-C8 cycloalkyl are cyclopropyl, cyclobutyl Base, cyclopentyl, cyclohexyl, cyclooctyl, especially cyclopentyl and cyclohexyl.

Ci-C4 alkoxy is linear or branched, such as methoxy, ethoxy, propoxy, isopropoxy, n-butoxy, second-butane, isobutoxy, Tert-butoxy. C2 - Ci decyloxyalkyl is C2 - Ci 〇 alkyl interrupted via a 0-atom, C2 - Ci 〇 alkyl has the same definition of the number of C atoms as the above Ci-C2 decyl group, for example Methoxymethyl-13- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) 0 —i 1>1 n ϋ lm9 n A τ I nn If n ϋ mmMmmm I fl ϋ i Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 A7 __B7___ V. Invention description (/.), methoxyethyl, methoxypropyl, ethoxylate Base, ethoxyethyl, ethoxypropyl, propoxymethyl, propoxyethyl, propoxypropyl.

Ci-c2 0 alkyl fluorenyl is linear or branched, examples are c2 - C l 8 -, C2 - Ci4 - C2 - Ci2 - 'C2 - C8 -, C2 - C6 - or Cz - C4 alkyl fluorenyl , or c4 a '2' or a C4-c8 alkane group. Examples are methyl, ethyl, propyl, butyl, isobutyl, pentyl*hexyl, decyl, octyl, decyl, decyl, dodecyl fluorenyl, tetradecane Mercapto, pentadecyl fluorenyl, hexadecane decyl, octadecyl stanyl, decane fluorenyl, preferably ethyl fluorenyl. Ci-Ci 2 alkyl fluorenyl, C! - C8 alkyl fluorenyl,

The Ci-C4 alkano group and the C2-C4 alkano group have the same definition of the same number of carbon atoms as the aforementioned Cz-c2 decane. Examples of the C4-C9 cycloalkanyl group are a cyclopropenyl group, a cyclobutenyl group, a cyclopentyl group, a cyclohexyl group, and a cyclooctyl group. Examples of the C2-C4 alkoxy group are linear or branched, and are, for example, ethoxylated, propyloxy, butoxy, isobutyloxy, preferably ethoxylated.

Cz - C i 2 alkoxycarbonyl is linear or branched, such as methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, n-butoxycarbonyl, isobutoxycarbonyl, 1, 1 Dimethylpropoxycarbonyl, pentyloxycarbonyl, hexyloxycarbonyl, heptyloxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, decyloxycarbonyl or dodecyloxycarbonyl, especially methoxy Carbonyl, ethoxycarbonyl, propoxycarbonyl, n-butoxycarbonyl or iso-butoxycarbonyl-14- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please first Read the precautions on the back and fill out this page. Order --------- 丨 1250378 A7 B7 i, description of the invention ( ί / ), preferably methoxycarbonyl. The C2-C2 alkoxycarbonyl group interrupted by one or more than one is linear or branched, and the two oxygen atoms are separated by at least two methylene groups, i.e., ethylene.

Examples of Cs - C2 fluorenyl are phenyl, 1-naphthyl, 2-naphthyl, S-carbyl, 9-phenanthryl, 1-indenylnaphthyl, 2-indenylnaphthalene, 1 dinaphthyl Phenyl or 3-naphthyl, preferably phenyl or naphthyl. Ci 〇 — C 2 〇 aryl and C s — C! 2 aryl has the same definition of the same number of carbon atoms as the former 逑C6 — C 2 〇 aryl. Examples of C6 - C2 fluorene fluorenyl are benzamidine, 1-naphthoquinone, 2-naphthoquinone, 9-fluorenylcarbonyl, 9-phenanthrylcarbonyl, 1-indenylenecarbonyl, 2-insulphnetyl, 1 Perylene or quinone carbonyl, preferably benzamidine or naphthoquinone. The Ci 〇 —C 2 fluorene fluorenyl group has the same definition of the same number of carbon atoms as the above C 6 — C 2 fluorene fluorenyl group. The substituted aryl Ar i and Α γ 2 are substituted 1 to 12 times, and it is apparent that the defined aryl group has a substituent number which cannot exceed the number of free positions on the aryl ring, and these substituents are substituted 1 Up to 12 times, such as 1 to 9 times, 1 to 6 times, 1 to 4 times, especially 1, 2 or 3 times. Examples of C3 - C9 heteroaryl are 2-furyl, 3-furyl, 2-pyrrolyl, 3-pyrrolyl, 2-thiol, 3-oxo, 2-thiazolyl, 2-benzo Furanyl, 3-benzofuranyl, 2-hydrazone, 3-mercapto, 2-benzothiophene, 3-benzophenanyl, -15- This paper scale applies to Chinese national standards (CNS) )A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) 磡定---------Line - Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 V. Invention Description (ί2) 2 - benzothiazolyl, 2-pyridyl, 3-( ftridinyl, 2- porphyrinyl, 3-quinolinyl, 4-hydroxyl, 1 -isoquinolinyl, 3 - Isoquinolinyl, 4-isoquinolyl.

The I substituted indene-based carbonyl group is substituted one to four times, for example one, two or three times, especially two or three times. The substituent on the phenyl ring is preferably at the 4th or 3, 4, 3, 4, 5 -, 2, 6 -, 2, 4 or 2, 4, 6-position of the phenyl ring, Especially in the 4 or 3, 4 position. Examples of the phenyl-C i -C3 alkyl group are benzyl, phenylethyl, α-methylbenzyl, or ct,α-dimethylbenzyl, especially benzyl. ! C2 — C2 0 alkenyl may be mono- or polyunsaturated, for example c2 —

Ci2 —, C 2 — C 6 —alkenyl, such as allyl, allyl, 1, 1 dimethylallyl, 1 -butenyl, 3-butenyl, 2-butanyl, 1 , 3-pentyl, 5-hexenyl, 7-octyl or dodecenyl, tetradecenyl, pentadecenyl, hexadecenyl, octadecyl and anthracene, especially It is a propyl group. The C3 - Ci 2 alkenyl group and the C3 - C5 alkenyl group have the same definition of the same number of carbon atoms as the above C 2 - C 2 0 alkenyl group. Examples of C2 - C2 〇 fast radicals are C2 - Cl 2 - C6 - alkynyl, and may be mono- or polyunsaturated, for example ethynyl 'propane-16- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back and fill out this page) n 1_1 ϋ I n ϋ« n I. δτ I n II ·ϋ l_i 1« n I eMam i Ministry of Economic Affairs Intellectual Property Office Staff Consumption Co-operative printing 1250378 A7 ____B7____ V. Description of invention (6) alkynyl, 1-butynyl, 3-butynyl, 2-butynyl, 5-hexynyl, 7-octynyl or dodecynyl , tetradecynyl, pentadecynyl, hexadecenyl, octadecynyl or decynyl. C3 - Cealkenyloxy may be mono- or polyunsaturated, examples being allyloxy, methallyloxy, butenyloxy, pentenyloxy, 1,3-pentanedioxyloxy, 5- Hexenyloxy. C3 - C6 olefinic group may be mono- or polyunsaturated, examples being propylene fluorenyl, 2-methyl-propenyl decyl, butenyl, 1,3-pentadienyl, 5-hexenyl . The fangs are fluorine, chlorine, bromine and iodine, especially fluorine, chlorine and bromine, preferably fluorine and chlorine. Suppose the OR3, SR4 and NRs Rs substituents on the phenyl ring form 5 or 6 via R3, R4, Rs and/or Re and other substituents on the phenyl ring, or with a carbon atom on the phenyl ring. The elemental ring can be obtained by a structure containing two or four rings (including a benzene ring or a Chua, a love- or a Philippine ring). For example (please read the note on the back and fill out this page) n n n n n n ·ϋ 一:OJa i n n n ϋ ϋ ϋ f i - Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative

The oxime esters of formulae I and II are prepared according to the methods described in the literature. -17- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). 1250378 A7 B7 V. Description of invention (w) , for example, from an equivalent enthalpy (Ri = H) and a hydrazine base, or an anhydride, in an inert solvent (eg, tert-butyl methyl ether, tetrahydrofuran (THF) or dimethylformamide (DMF) It is prepared by reacting in the presence of a base (for example, triethylamine or pyridinium) or a basic solvent (like pyridine).

〇-H N Ar-C-H > CI~R1 or R factory base <

0-R1 N Ar-C-H (I) (Please read the notes on the back and fill out this page) 0-H N • C a R. (III) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed 0-R,

NA "i~C - R2 This reaction is well known to those skilled in the art and is generally carried out between 15 and 50 t:, preferably between 0 and 253⁄4. The enthalpy of matter can be obtained from various methods described in standard chemistry textbooks (for example, J. March, Advanced Organic Chemistry, 4th Edition, Wiley Interscience, 1992), or in specific articles such as SR Sandler & W. Karo, Organic Functional group preparations, V o 1 . 3,Academic

Press. One of the most convenient methods is, for example, the reaction of an aldehyde or a ketone with a hydroxylamine or a salt thereof in a polar solvent such as an aqueous solution of ethyl acetate or ethyl acetate. In this case, a base such as sodium acetate or pyridine can be added to control the reaction mixture. -18- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1250378 A7 ___B7___ V. Description of invention (li :) (Please read the notes on the back and fill out this page) p Depreciation. It is a well-known fact that the reaction rate and the p Η value are relative, and the base can be added for reading at the beginning of the reaction or during the reaction. An alkaline solvent, like pyridine, can also be used as a base and/or solvent, or as a cosolvent. The reaction temperature is generally the reflux temperature of the mixture, usually 60 - 1 20 t!. Another convenient method for synthesizing hydrazine is K nitrous acid or alkyl nitrite I nitration "activated fluorene. Alkaline conditions, as described in Organic

Syntheses coll. Vol. VI (J. Wiley & Sons, New York, 1988), PP 199 and 840, and acidic conditions, as described, for example,

Organic Syhthesis coll. vol V, pp32 and 373, coll, vo 1. III, pp 191 and 513, coll, vol, II, pp. 2 0 2 , 2 0 4 and 363, all suitable for use in the preparation of the present invention The beginning of the substance. Nitrous acid is generally produced by sodium nitrite, which may be, for example, methyl nitrite, ethyl nitrite, isopropyl nitrite, butyl nitrite, or isoamyl nitrite. . There are two configurations (Z) or (E) for each of the oxime esters printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs. These isomers can be separated by conventional methods, but it is also possible to use a mixture of isomers as light. Starting materials, therefore, the invention also relates to mixtures of the isomers of the compounds of the formulae I and II. According to the invention, it is especially advantageous to use the compounds of the formulae I and I I as constituents of the photoinitiator. A preferred composition comprises a compound of formula I or I I as a component (Β), wherein:

Rl is C2 — Cs sulphide or C 2 — C 5 alkoxycarbonyl; or -19 1 paper size applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 i, invention description (It )

Ri is benzoyl, which is unsubstituted or substituted via one or more Ci-C6 alkyl or halogen; ΑΓ1 is phenyl or naphthyl, each of these substituents is unsubstituted, or Substituting halogenous, C i -C 2 decyl, benzyl or Ci -C 2 decane fluorenyl for 1 to 5 times; or the phenyl or naphthyl group is substituted by phenyl or benzamidine, wherein each - One is optionally substituted by one or more of 0R3, SR4 or NRs Re; or the phenyl or naphthyl group is substituted by a C2-ci2 alkoxy group, and the C2-ci2 alkoxycarbonyl group is selective Substituted by one or more 0 0 - and / or selectively substituted by one or more 0H; or the phenyl or naphthyl group is substituted by OR3, SR4 or NRs R6, wherein the substituents 0R3, SR4 or NR5R6 is selectively formed via R3, R4, Rs and/or Rs and other substituents on the phenyl or naphthyl ring, or with a carbon atom on the phenyl or naphthyl ring. 5- or 6-membered ring or oxime Is a furyl group, a pyrrolyl group, a thiol group, a benzofuranyl group, a fluorenyl group, a benzothienyl group or a pyridyl group, but the premise is that R i is an ethyl group; Each of the substituents is unsubstituted, or halogen, C i -C 2 decyl, benzyl, C 3 -C 8 cycloalkyl, phenyl, Ci -C 2 decane fluorenyl, benzamidine, C2—Ci 2 alkoxycarbonyl, phenoxycarbonyl, ORs, SR4, S0R4, S〇2R4 or R6 substituted 1 to 4 times; X is 2; -20- This paper scale applies to Chinese National Standard (CNS) A4 Specifications (210 x 297 mm) -------------# (Please read the notes on the back and fill out this page)

^—«1 Λ*ϋ i i_iei ie_— I 1 a of 0 n I I n 11 m —a— I iMm I Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 B7 V. Invention Description (Η ) Μ 1 Yes

, each of which is optionally substituted 1 to 4 times with halogen*Ci-Ci 2 alkyl, benzyl, ORs, SR4 or NR5 R6 or substituted by a phenyl group which is unsubstituted or Substituted by one or more of 0 R 3 , SR 4 or NR 5 R 6 ; or substituted by benzamyl, the benzhydryl group is unsubstituted or substituted by one or more OR3, SR4 or NR5 Rs Or substituted by Ci-O 2 alkyl 2; or substituted by C 2 -C 2 alkoxycarbonyl, this C 2 —C 2 alkoxycarbonyl is selectively interrupted by one or more And/or optionally substituted by one or more hydroxyl groups; M2 is a direct bond, a 0-, an S-, an SS-, an NR3-, a (C0)-, a Ci-Ciz alkylene, Benzene, one (C0) 〇 - (C2 - ci2 alkylene) - C (C0) -, one (C 0 ) 〇 - ( C Η 2 C Η 2 Ο ) π - (CO) one or one (CO) a (C2 - Ci2 burnt) one (C〇) one; or M2 is a C4-Ci 2 alkylene or a C4-Ci 2 alkylene dioxy group, each of which is selectively 1 to 5 to 0. , one S - and / or one NR3 - in Of; --21-- this paper scale applicable Chinese National Standard (CNS) A4 size (210 X 297 mm) (Please read the notes and then fill in the back of this page)

______丨丁丨J___L—丨丨• — — — II ^ -111 III Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed r — — — — — — — — — — — — — — — — — — — — — _ 1250378 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention Description (β) M3 is a direct 鐽, a CHz —, a Q —, an S —, —NR 3 one or one (C0) -; R3 is hydrogen or Ci-C2 decyl; or R3 is (:2 - Ci 2 m group, which is composed of an OH, a SH, a 0 (CO) - C χ - C 4 alkyl group, a 0 (CO )-phenyl, one (CO) 0 (C ! ~ C 4 alkyl) • one N (Ci-C4 alkyl) 2 , one N (CH 2 CHz 〇 H) 2 , - N [CH 2 CH 2 〇 1 (C 0 ) - C i -C 4] 2 or morpholinyl substituted; or R 3 is C 2 - C ! 2 alkyl, which is interrupted by one or more 0's; or R3 is -(CH2CH2O) η + 1 Η » 1 (C Η 2 C Η 2 0 ) η (CO) — C! A C8 alkyl group, phenyl-C!—C3 alkyl group, C2—C8 alkyl fluorenyl group, C3—Ci2 alkenyl group or C3 — Cs olefinic group; or R3 is benzamidine, which is unsubstituted or consists of one or more Ci-Cs alkyl, halogen or Ci-C4 alkoxy substituted; or R3 is phenyl or naphthyl, each of which is unsubstituted, or halogen, Ci-Ci 2 alkyl, Cl-Ci 2 Alkoxy, phenyl-Ci-C3 alkoxy, phenoxy, Ci-C12 alkanesulfonyl, phenylsulfonyl, a N ((: 1-(:12 alkyl) 2 , diphenyl Amine or a (CO) R7 substituted; η is 1 to 20; R4 is hydrogen, C!-C2 alkyl, C3 - C12 alkenyl, phenyl mono C3 alkyl; C2 - C8 alkyl, It is composed of a 0H, a SH, a 0 (C 0 )-Ci-C4 alkyl group, a 0 (C〇) -22- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back and fill out this page) 0 ϋ ^^1 m Hal n ϋ·· 一 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Phenyl or mono (CO) hydrazine (Ci-C4 synthyl) substituted; or R4 is C2 - Ci 2 alkyl, which is interrupted by one or more, one, one, one, S; or R4 is one (CHz CH2 0) η + 1 Η , one (C Η 2 C Η 2 0 ) η (C0) - Ci - C8 alkane , C2 -Cs fluorenyl, C3 - Ci 2 susceptile, C3 - Ce olefin 4 or R4 is phenyl or naphthyl, each of which is unsubstituted, or dentate, Ci-Ci2 alkyl , Ci-ci2 alkoxy or one (C 〇) R 7 substituted; R5 and R6 are each independently hydrogen, Ci—C 2 decyl,

Cz-c4 hydroxyalkyl, c2 - Ci 0 alkoxyalkyl, phenyl-Ci-C3 alkyl, Ci-C4 alkyl fluorenyl, C3 - Cl2 olefin, benzamidine; or phenyl or naphthyl , each of which is unsubstituted, or substituted by Ci-Ci 2 alkyl or Ci-Ci 2 alkoxy; or R5 and 1-6 are c2-C6 alkylene, which is selective 〇—or an NR3—interrupted, and/or optionally substituted with a hydroxy group, a Ci-C4 alkoxy group, a C2-C4 alkane or a benzhydryloxy group; and R7 is a hydrogen, Cr-C2 〇 An alkyl group; or a C2—C8 alkyl group which is a halogen, a phenyl group, a 0H, a SH, a C3—C6 alkenyloxy group, a 0 (C 0 )- 0^—04 alkyl group, a 0 (C0) — —phenyl or mono(C 0 ) 0 (Ci—C4 alkyl) substituted; or R 7 is C 2 —Ci 2 alkyl, which is interrupted by one or more — 0 — or R 7 is 1 ( CHzCHzCMn + iH, one (C Η 2 C Η 2 0 ) n (C0) - Ci - C8 alkyl, or -23 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please Read the notes on the back and fill out this page. · #订---------线丨. Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 B7 V. Invention Description (〆) C3 2 alkenyl; or phenyl, which is selectively oxidized by one or more dentates, Cl-Cl 2 a group of 'Ci-Cl 2 'oxyl' yloxy, Ci-Ciz alkylsulfonyl, phenylsulfonyl, a N (Ci-Ci 2 alkyl) 2 or a diphenylamino group. A good light-sensitive composition is one in which the component (B) is a compound of the formula I.

Ri is Cz — 〇4 burning base;

Ar i is phenyl, or naphthyl, each of which is unsubstituted or substituted by halogen, C!—C8 alkyl, NRs Re or OR3, wherein the substituent ORs is via R3 and a phenyl or naphthyl ring. The other substituents above form a 5- or 6-membered ring selectively; or Ar i is a 2-furyl group, a 2-pyrrolyl group, a 2-mercapto group, a 3-mercapto group, but the premise is R i Is an ethylene group; X is 2; R3 is a Ci-C2 decyl group; or R3 is a C2-Ci 2 alkyl group, which is via 0H, a 0 (CO)-Ci-C4 alkyl group, a N (C-I) C4 alkyl)2,-N(CH2CH20H)2, a N CCHz GHz 0 - (C0)-C! a 4-alkyl or morpholinyl-substituted; or R3 is a C2-ci 2 alkyl group, which is One or more 0-interrupted; -24- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) 0 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed ϋ ϋ —^1 ϋ n ammt One I Imm i-ϋ ϋ ^^1 I _ϋ n a-ϋ nnn ι_ϋ l__i n ϋ n ·ϋ ϋ ϋ I ϋ an 1_1 n -ϋ ϋ 1250378 A7 __B7__ V. Invention description (vl) (please Read the back of the note first and then fill out this page) or R3 is a (CH2CH2O) n + i or a (C Η 2 C Η 2 Ο ) n (co) — Ci—C4 alkyl; n is 1 to 3; R5 and R6 are Ci_C4 alkyl groups. The compounds of the formulae I and II can be used as the ethylenically unsaturated compound or as a photoinitiator which is a photopolymerization of a mixture of these compounds. In the composition of the present invention, the component (A) is a monomer, an oligomer Or a polymer which is soluble in an aqueous alkaline imaging solution. An example of a suitable component (A) printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs is an oligomer or polymer having a molecular weight of from about 500 to 2,000,000. Preferably, it is from 1 000 to 1,000,000. An example of an alkali-developable adhesive is an acrylic polymer having an acid functional group as an alkali-soluble side bond, as is conventionally derived from an ethylenically unsaturated carboxylic acid. Acrylic acid, 2-carboxyethyl (meth)acrylic acid, 2-carboxypropyl (meth)acrylic itaconic acid, crotonic acid, maleic acid and fumaric acid, and one or more monomers selected from Acrylic esters, such as methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, benzyl (meth) acrylate, 2 - Ethylhexyl (meth) acrylate, via base ( Acrylate, hydroxypropyl (meth) acrylate; vinyl aromatic compound, like styrene, α-methyl styrene, vinyl toluene, P - chlorostyrene; guanamine type unsaturated compound, (A ) acrylamide acetophene propylene amide, hydrazine-methyl acrylamide, hydrazine-butoxy propylene acrylamide; and polyolefin type compounds such as butadiene, isoprene, pentadiene chloride And -25- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention (/) Analogs; methacrylonitrile, methyl isopropenone, ethylene acetate Copolymerization of esters, ethylene propionates, or ethylene trimethyl acetate. Examples of copolymers are acrylates and methacrylates and acrylic or methacrylic acid, and styrene or substituted styrenes. a phenol resin such as a novolac, a copolymer of (poly)hydroxystyrene, and a copolymer of hydroxystyrene and alkylpropene oxime·acrylic acid and/or methacrylic acid. A preferred example of the copolymer is formazan acrylic acid. Ester/methacrylic acid Copolymer, copolymer of benzyl methacrylate/methacrylic acid, copolymer of methyl methacrylate/ethyl acrylate/methacrylic acid, copolymer of benzyl methacrylate/methacrylate/styrene, Copolymer of benzyl methacrylate / methacrylic acid / hydroxyethyl methacrylate, copolymer of methyl methacrylate / butyl methacrylate / methacrylic acid / styrene, methyl methacrylate / benzyl methacrylic acid a copolymer of ester/methacrylate/hydroxyphenyl methacrylate. If compound (A) is also a quinone-soluble monomer compound, the concentration in the above formulation can be as high as to make the entire formulation alkaline. The developer may also be soluble. The functional group which causes good alkali solubility in the compound (A) is preferably a carboxyl group. However, it may also be other functional groups which can be dissolved in an alkaline solvent, and examples of such functional groups are a phenol group, a sulfonic acid group and an anhydride group. In addition, the compound (A) can be an alkali-soluble polyamine precursor, such as a poly(amino ester) compound, which optionally has a photopolymerizable side chain group, which can be kinked to the backbone of the molecule or On the ester base, and the foot K releases the phenolic group or the carboxyl group-26- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page)

-ni ϋ— 1 «Hi··. 一 一 I ·ϋ ΛΜΜ§ imam ϋ_· §_ I Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 _B7 V. Inventions (v)) (Please read the back of the note first) The matter is further filled out in this page) so that the substance is soluble in an aqueous alkaline solution, or it can be, for example, a poly(amino acid). Examples of the other alkali-soluble compound (A) include a co-polymer of hydroxystyrene and styrene, an alkyl acrylate, acrylic acid, alkyl methacrylate and methacrylic acid. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives. An example of the other component (A) is an oligomer or polymer obtained by the reaction of a saturated or unsaturated polybasic anhydride epoxy compound and an unsaturated monocarboxylic acid reaction product. The most advantageous epoxy compounds which can be used in the preparation of the preparation are phenolic type ring compounds. The above-mentioned activating energy ray hardening resin is a reaction product obtained from a phenolic type epoxy compound (as described above) and an unsaturated monocarboxylic acid, and a dibasic acid anhydride such as a peptide anhydride or an aromatic polycarboxylic acid. Reacts like benzene trimellitic anhydride or pyromellitic anhydride. In this case, * when the resin is produced, the amount of the aforementioned acid anhydride used is more than 0 ♦ 15 m / per hydroxy group present in the phenolic type epoxy compound and the unsaturated carboxylic acid reaction product is particularly suitable. The acid value of the obtained resin is suitably between 45 and 160 mg, preferably 50 to 140 mg/g (the acid value is expressed by the number of milligrams of potassium carbonate required to neutralize one milligram of the resin) . When the number of ethylenically unsaturated oxime present in the oxime-activated energy ray-hardening resin molecular unit is small, since the photocuring process is slow, a phenolic type epoxy compound can be used as a starting material. In order to reduce the viscosity of the ink, a bisphenol-ruthenium epoxy compound may be used instead. The phenolic type epoxy compound is represented by a phenolic phenolic type epoxy resin and a phenolic phenolic type epoxy resin, and these compounds are basically prepared by reacting a surface fermentation with a phenolic resin. The basic example of the above acid anhydride is dibasic acid -27- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 __B7_____ V. Invention description (#) (Please read the note on the back first) Fill in this page) Anhydrides such as, for example, maleic anhydride, succinic anhydride, itaconic anhydride, peptide anhydride, tetrahydropeptide anhydride, hexahydropeptide anhydride, methyl hexahydropeptide anhydride, internal bridge-methylenetetrahydropeptide Anhydride, methyl-internal bridge-methylenetetrahydropeptide anhydride, chloroalic anhydride, and methyltetrahydropeptide anhydride; aromatic polycarboxylic anhydrides, such as, for example, benzene trimellitic anhydride and pyromellitic anhydride, benzophenone a tetradecanoic acid dianhydride; and a polyzole acid Ιί derivative such as 5-(2,5-dioxotetrahydrofuranyl)-3-methoxy-3-cyclohexene-1,2-dicarboxylic anhydride. An example of the other component (Α) is obtained by adding a carboxyl group derived from a copolymer containing an epoxy group-containing acrylate or a methacrylate compound to a part of acrylate or methacrylate and acrylic acid or methacrylic acid. Examples of such compounds can be prepared according to a general method, such as a liquid polymerization method, and can be represented by the following formulas (1) and (2): CH=C-COORb (1), wherein the Ministry of Economic Affairs Intellectual Property Office employee consumption cooperative prints system

Ra is a hydrogen atom or a methyl group, Rb is a fatty acid hydrocarbon group having 1 to 6 carbon atoms, and acrylic acid and/or methacrylic acid of the following formula (2), CH=C-COOH (2) -2 8 - This paper scale applies to China National Standard (CNS) A4 specification (2KU 297 mm) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250378 A7 _B7__ V. Invention Description (W) where R a has the definition as described above. Preferably, the molar ratio of acrylate and/or methacrylate to acrylic acid and/or methacrylic acid is from 30:70 to 70:30. Each of the ester groups of the acrylate and/or methacrylate may be appropriately selected from the aliphatic group having 1 to 6 carbon atoms. The reaction product can be obtained by adding a copolymer of the obtained acrylate and/or methacrylate (having a terminal epoxy group represented by the following formula (3): CH=C-COO-Rc-(3) Where R a has the definition as described above,

Rc is an aliphatic hydrocarbon group or an aromatic hydrocarbon group having 1 to 12 carbon atoms. In order to obtain a reaction product suitable for the present invention, a compound of the formula (3) is added to the monomers of the former formulas (1) and (2) in a proportion of from 1 to 40 mol%, which is obtained by ultraviolet curability. Copolymer. The resulting reaction product preferably has an average molecular weight of from 20' to 70,000, and the softening point is suitably from 35 to 130 Å. The acid value is from 50 to 150. The other ingredients (Α) have α, /3 - unsaturated double 鐽-29 on the side chain. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back first) Fill in this page again, 0 --- order --------- line! Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250378 A7 B7 V. Invention (") resin with an acid value of 50 - 200. Photopolymerizable resin, for example, 70-95% by weight of ethylene-containing yttrium a saturated bond component, and a copolymerizable component thereof, which comprises a carboxyl group-containing resin having an acid value of less than 500, preferably less than 600, particularly less than 620 (having a number average molecular weight of 1 〇〇〇) - 100000, preferably 3000 - 70,000) and an addition product formed by an unsaturated compound having an alpha, /3 - unplaned and double bond and an epoxy group. The ethylenically unsaturated acid component is photopolymerizable here. The resin contains 70 to 95% by weight of the carboxyl group, so the photopolymerizable resin (Α) is in the water even after the addition of an unsaturated compound having an oc, an unplaned and a double bond and an epoxy group. Or it does not become insoluble in a dilute aqueous solution, and can maintain its solubility. An example of such a resin is described in JP -8 - 33908 1 - 含 0 carboxyl-containing resin (A) is, for example, 70 - 95% by weight, preferably 78 88% by weight, especially 80-85% by weight of ethyl hydrazine unsaturated acid monomer, and 5-30% by weight, preferably 12-25% by weight, especially 1 5 - 2 0% The weight percentage of the copolymerizable monomer is dissolved in a suitable unreacted solvent, and the thermal polymerization is carried out at a K temperature of 45 - 1 20 ° 0 in the presence of a thermal polymerization initiator * Therefore, it has an acid value of less than 500 and has an amount The carboxyl group-containing resin with an average molecular weight of 1 000 - 1 00 ◦ 00 can be produced with high safety and high stability. It is suitable for the production of carboxyl group-containing resin (A) containing ethylenically unsaturated bond monomer - 30 - The paper size is applicable to China. Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) I# Order---------Line — . Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative 1250378 A7 __B7__ V. Specific examples of inventions (>Ί) include acrylic acid, methacrylic acid, crotonic acid, iso-crotonic acid, ane 1 icacid, tig 1 icacid, 2 - B Acrylic acid, 3-propyl acrylic acid, 3 - different Propylacrylic acid, succinic acid mono-hydroxyethyl acrylate, peptidic acid mono-hydroxyethyl acrylate, dihydropeptidic acid mono-hydroxyethyl acrylate, tetrahydropeptidic acid mono-hydroxyethyl i propylene brewing , hexahydropeptide monohydroxyethyl acrylate, acrylic acid dimer, acrylic acid trimer, ω-carboxy-polycaprolactone monoacrylate and ω-carboxy-polycaprolactone monomethacrylate. Among these monomers, preferred are acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, chalk acid, hydrazine acid, 2-ethylacrylic acid, 3-propylacrylic acid, 3-isopropylacrylic acid, ω- Carboxyl-polycaprolactone monoacrylate, ω-carboxy-polycaprolactone monomethacrylate, and the like; particularly preferred are acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, leucovoric acid, tiglic acid, 2 - ethacrylic acid, 3-propylacrylic acid, 3-isopropylacrylic acid * ω - carboxy-polycaprolactone monoacrylate and ω-carboxy-polycaprolactone monomethacrylate. These monomers may be used singly or as a mixture of two or more. Suitable monomers for copolymerization are acrylates, methacrylates, ethylene 1-based steroids, styrenic monomers, and cyclic ester monomers. Specific examples include hydroxymethacrylate, hydroxymethylmethacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-diapropyl acrylate, 2-hydroxypropyl methacrylate Ester, ethylene glycol monomethyl ether acrylate, ethylene glycol monomethyl ether methacrylate, ethylene glycol monoethyl ether acrylate, ethylene glycol monoethyl methacrylate, glycerol acrylate, C Alcohol _3 Bu ^ paper scale applicable to China National Standard (CNS) A4 regulations ^ (210 χ 297 mm) ' (Please read the back of the note before filling this page) Order --------- line! 1250378 A7 B7 V. INSTRUCTIONS (j) Methacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentaacrylate, dimethylaminoethyl acrylate, dimethylaminoethyl-ethyl Acrylate, tetrahydrofuran acrylate, tetrahydrofuranyl methacrylate, decyl acrylate, decylamine methacrylate, acrylonitrile, methacrylonitrile, methacrylate, methyl methacrylate, ethyl acrylate, B Acrylate, butyl acrylate, butyl methacrylate * isobutyl acrylate, isobutyl methacrylate, 2-ethylhexyl acrylate * 2-ethylhexyl monomethacrylate, phenyl methacrylate, benzene Methyl methacrylate, acrylic acid carbamide, methacrylic acid carbamic acid, ξ-caprolactone-modified tetrafuran acrylate, ξ-caprolactone-modified tetrafuranyl methacrylate, diethyl Diacetate acrylate, isodecyl acrylate, isodecyl methacrylate, octyl acrylate, octyl methacrylate, lauryl acrylate * lauryl methacrylate, tridecyl propylene Acid esters, tridecyl methacrylate, stearyl acrylate, stearyl methacrylate and the like. These monomers may be used singly or as a mixture of two or more. Suitable thermal polymerization initiators are, for example, 2,2'-azobis(2,4-dimethylpentane) (usage temperature 45-, 70 °C), 2

, 2' - azobis (isobutyl) (use temperature 60 - 90tM, 2,2' - azobis(2-methylisobutyronitrile) (use temperature 60- 953⁄4), uncle Based on octanoate (using temperature 75 - 10 03⁄4), 1,1'-azobis (cyclohexane-1 carbon) (using temperature 80-110 °C) or 1 [(1 one or two) Nitrogen 1-1 - 32- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) Order---------Line Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7

B7______ V. Description of the invention (W) Methylethyl)azo]-carbamamine (use temperature 95-1203⁄4). At least one of the above compounds is used. The carboxyl group-containing resin obtained by the above method is then modified to a photopolymerizable resin in which a carboxyl group is esterified via an unsaturated compound having an ot, a hydrazine-unsaturated double bond and a post group, wherein the side chain group has α, /3 — Unsaturated meal key. Examples of suitable compounds having an alpha, a eu-unsaturated double bond and an epoxy group are those listed below. At least a portion selected from the group consisting of epoxypropyl propyl acrylate, epoxy propyl acetoacetate, a compound of the following formula 4, 5, 6, CH, 0 CH, | 3|| I 3 —CH== C - C - C - C - C - CH2 (4); CH2 - d n0 \ / 2 o where Ri' is argon or methyl, and n' is an integer from 1 to 10; R2, 〇 "o' I II II CH=C—C—0—(CH2)—C (Please read the notes on the back and fill out this page)

· - Line · Ministry of Economic Affairs Intellectual Property Bureau member X consumer cooperation du printing system where Rz 'is hydrogen or methyl, and n 〃 is an integer of 1-3. Among these compounds, compounds having an acyclic structure of an epoxy group are particularly preferable because these compounds have high reactivity with respect to a carboxyl group-containing resin, and thus the reaction time is short. These compounds do not further cause the reaction to be applied to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). The Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250378 A7 _ B7__ V. Invention Description (P) Gelatinization, the reaction is stable. In other words, epoxy propyl acrylate and epoxy propyl methacrylate are advantageous from the viewpoints of sensitivity and thermal resistance because of their low molecular weight and high esterification conversion ratio. . The photopolymerizable resin obtained by the above method has an α,/3 -unsaturated double bond in its side chain, and has an acid value of 50 to 200, preferably 70 to 150, particularly 85 to 1 20. The number average molecular weight is 7,000 - 1 0000, and the glass transition point (hereinafter referred to as Tg) is 30-12 Å. When such a photopolymerizable resin is used as a solder resist, an acid value of not more than 70 is preferable because other additive components may be added to the composition. An inert organic solvent is used in the esterification and preparation of the photosensitive resin composition. Commercially available unplaned and monomeric, oligomeric and polymeric components (A) (as previously described) are, for example, M- 5 3 0 0 , M 54 0 0 , M- 5 6 0 0 (TOAGOSEI) ), EB3800, EB9692, EB9694, EB9695, EB-9696 (UCB Chemicals), KAYARAD TCR 1025 (Nippon Kayaku Co., LTD.), NE0P0L8319 (ϋ-Pica), EA- 6 3 4 0 (Shin N akamura Cheiica 1 Co., Ltd.), ACA2 0 0 M , ACA 2 5 0 (Daicel Industries, Ltd.) 〇 Particularly advantageous are photosensitizing compositions wherein compound (A) is an oligomeric polymeric or polymeric compound. Preferred is a composition in which the oligomer or polymer (A) is -34- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first) Fill in this page again) 0 Order---------Line! Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250378 A7 _B7 V. INSTRUCTIONS (W) An adhesive polymer, especially a copolymer of (meth) acrylate and (meth) acrylate, or one obtained from saturated or unsaturated a resin obtained by reacting a polybasic acid anhydride with a reaction product of an epoxy compound and an unsaturated monodecanoic acid, or a carboxyl group-containing resin and an unsaturated group having an α, a mono-unsaturated biguanide and an epoxy group The addition product formed by the compound. The compound (C) suitable for use in the composition of the present invention is a photopolymerizable ethylene type monomer, and a representative example of the photopolymerizable ethylene type monomer is a hydroxyalkyl acrylate such as 2-hydroxyethyl acrylate Cool, 2-hydroxybutyl acrylate, etc.; single or diacrylate of glycols, such as ethylene glycol, methoxytetraethylene glycol, polyethylene glycol, propylene glycol, etc.; acrylamide, like hydrazine , Ν-dimethyl methacrylate, hydrazine-methanol acrylamide, etc.; aminoalkyl acrylates such as hydrazine, hydrazine-dimethylaminoethyl acrylate, etc.; polyvalent alcohols or ethylene oxides thereof Or a polyvalent acrylate of a propylene oxide adduct, such as hexanediol, trimethyl propane propane, pentaerythritol, dipentaerythritol, trimethylolethyl isofluoride, etc.; phenoxy acrylate, Bisphenolphthalein diacrylate and ethylene oxide or propylene oxide adduct of these phenols; acrylates of glycidyl ether, like glyceride diglycidyl ether, triethanol propane triglycidyl ether, three Epoxy propyl ether isoflurane, and the like, and melamine acrylate, and / or relative to the above acrylic Methyl acrylate. Other examples of component (C) are high molecular weight polyunsaturated compounds, such as oligomers or polymers, which are acrylated epoxies, acrylate-containing, vinyl ether- or epoxy-based polyesters, Including polyurethane and polyether. Other examples of unsaturated oligomers are unsaturated polyester resins, a 35-paper scale applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) / -* -------Book---------Line 丨-II ·1 n I n ·1 II n ϋ nt- nn «I nn ϋ I ϋ - 1250378 A7 B7 V. Invention Description (θ) It is usually prepared from maleic acid, peptidic acid, and one or more diols having a molecular weight of from about 500 to about 3,000. In addition, it is also possible to use vinyl ether monomers and oligomers, and maleate-terminated oligomers, having polyester, polyurethane, poly, polyvinyl ether and epoxy groups. Home. Particularly suitable are compositions having a vinyl ether based oligomer and a polymer, as described in W090/0 1 5 1 2 . However, copolymers of vinyl ether and maleic acid monofunctional monomers are also suitable. Such unsaturated oligomers are also known as prepolymers. The compound (C) which is photo-crosslinkable as described above may be used singly or as a mixture of two or more. A suitable amount is from 5 to 300 parts by weight, preferably 10 to 150 parts by weight (calculated based on 100 parts by weight of the component (A)). If the photocrosslinkable compound (C) is a low viscous liquid, it can be used to dilute the components of the mixture so that it can be easily coated. Another purpose is to improve the efficiency of photocrosslinking. As described above, a preferred photo-sensitive composition is one in which the photopolymerizable compound (C) is a liquid. The photopolymerization reaction can be accelerated by the addition of other photosensitizers or co-initiators (component (D)) which can transfer or broaden the spectral sensitivity, especially aromatic compounds such as benzophenone and its derivatives. , thioxanthone and its derivatives, anthraquinone and its derivatives, coumarin and phenothiazine and its derivatives * and 3 - (aryl carbene) thiazoline, Rhodanine, 樟 brain pro-3 6 ~ This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------·· (Read first Note on the back of the page and fill in this page) -------

Line L Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Ministry of Printing and Economy Ministry Intellectual Property Bureau Employees Consumption Cooperatives Printed 1250378 A7 _ B7 __ V. Invention Description (〇) (camphorquinoiie), also includes eosine, rhodamine ( Rhodamine), erythrosine, xanthene, thioxanthene * acridine, such as 9-phenyl acridine, 1,7-bis(9-acridinyl) Heptane, 1,5-bis(9-acridinyl)pentane, cyanine and bierocyanine dyes 0 Specific examples of these compounds are: 1 · Thiaxane ton class: thiazan Meng, 2 - isopropyl thiaxanone, 2 - sedative ketone ketone, 1 atmosphere - 4-propoxy thioxanthone, 2 - dodecyl thioxanthone, 2, 4 Diethyl sulfonium ton, 2,4 dimethyl chlorene ton _, 2 - methoxycarbonyl thioxanthone, 2-ethoxycarbonyl chlorpyrifos, 3 - (2-methoxyl Ethoxycarbonyl)-thioxanthone, 4-butoxycarbonyl chlorphenone, 3-butoxycarbonyl-7-methylthiaxanone* 1 monocyano-3-enylation_mountain ketone 1-ethoxycarbonyl-3-oxothioxanthene, 1-ethoxycarbonyl-3-ethoxythiaxanone, 1-ethoxycarbonyl-3-aminothioxanthone, 1 Monoethoxycarbonyl-3-phenylthiononyloxyxanthene, 3,4,1-2,2-(2-methoxyethoxy)ethoxy group, a sleeping mountain 曜, 1, 3-Chloro- 2 -transyl- 9H-thiazole-ton-9-indole, 2-ethylhexyl ether, 1-ethoxycarbonyl-3-(1-methyl-morpholinoethyl)-sleep Shantuan, 2 - methyl-6-dimethoxymethyl-thiaxanone, 2-methyl-6-(1,1-dimethoxybenzyl) sleepy ton, 2 — Morpholinylmethyl Sleep-37- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) --------- Order ---------Line-' 1250378 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (π)

T. ketone, 2-methyl- 6-morpholinylmethyl _ ton _, N-allyl thioxanthone-3,4 bis carbodiimide, N-octyl thioxanthone 3,4 bis carboxy quinone imine, bis(1,1,3,3-tetramethylbutyl)-thiaxanone-3,4-dicarboxy quinone imine, 1-phenoxy thiophene Tons of ketone, 6-ethoxycarbonyl-2-methoxy oxanthone, 6-ethoxyindol-2-methylthiaxanone, thiaxanone-2-carboxylic acid polyethylene glycol Ester, 2-hydroxy- 3 - (3,4 - dimethyl - 9 - oxo - 9H - thiaxanone - 2 - yloxy) - N, N, N - trimethyl - 1 -propane chlorination Ammonium; 2 · Benzobenzoquinone benzophenone, 4-phenylbenzophenone, 4-methoxybenzophenone, 4,4'-dimethoxybenzobenzophenone, 4,4 '-Dimethyl benzophenone, 4,4'-dichlorobenzophenone, 4,4'-double (dimethylamino)benzophenone, 4,4' one pair (two Benidobenzoxil, 4,4'-bis(methylethylamino)benzophenone, 4,4, mono-(P-isopropylphenoxy)benzophenone, 4 Monomethylbenzene Benzophenone, 2,4,6-trimethylbenzophenone, 4-(4-methylthiophenyl)benzophenone, 3,3'-dimethyl-1,4-methoxybenzene Benzophenone, methyl-2-phenylene benzoate, 4-(2-hydroxyethylhydrazine)-un-biphenyl, 4-(4-methylphenylsulfonate) and 嗣'1 1 4-(4-monobenzylidene-phenylsulfamosole)-phenyl]-2-methyl-2-(toluene-4-sulfonate)-propane-1-one, 4-benzoic acid-N, N,N-trimethylphenylmethane chloride, 2-hydroxy-3-(4-benzene-38- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the back first) Note: Please fill out this page) Order---------Line! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 _B7 V. Invention Description (U) formazanyloxy)-N,N , N-trimethyl-1,4-propane ammonium monohydrate, 4-(13-acryloyl-l,4,7,10,13-pentaoxatridecyl)-benzophenone , 4 - benzamidine - N, N - dimethyl - N - [2 - (1 Monooxo-2-propenyloxy]ethyl-phenylmethane chloride; 1 3 · Coumarin coumarin 1, coumarin 2, coumarin 6, coumarin 7, coumarin 30, Coumarin 102, Coumarin 106, Coumarin 138, Coumarin 152, Coumarin 153, Coumarin 307, Coumarin 314, Coumarin 314T, Coumarin 334, Coumarin 337 coumarin 500,3 - benzamidine coumarin, 3 - benzamidine-7 methoxy coumarin, 3 - benzamidine-5,7-dimethoxycoumarin, 3 - benzamidine-5,7-dipropoxycoumarin, 3-benzamide-6,8-di-n-flavored coumarin, 3-benzamide- 6-chlorinated mono- crotonin, 3 , 3'-carbonyl-double [5,7-bis(propoxy)coumarin]*3,3'-carbonyl-double (7-methoxycoumarin), 3,3'-carbonyl pair (7-diethylamino coumarin), 3-isobutyl coumarin, 3-benzamide-5,7-dimethoxy-monocrotonin, 3-benzamide-5, 7- Diethoxycoumarin, 3-benzonitrile-5,7-dibutoxycoumarin, 3-benzyl-5,7-bis(methoxyethoxy) Base) a coumarin, 3-benzamide-5,7-bis(allyloxy)coumarin,3-benzamide-7-dimethylaminocoumarin,3-benzamide 7-diethylamino coumarin, 3-isobutyl decyl-7-dimethylamino coumarin, -39- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back and then fill out this page) ------Book ·--------*5^ 丨_ 1250378 A7 B7 V. Invention description () 5,7-Dimethoxy Base 1 - (1 - naphthyl) monofon, 5, 7 - diethoxy - 3 - (1 - naphthyl) monocrotonin, 3-benzylidene benzo[f] Bean, 7-diethylamino-3-thionium coumarin, 3-(4-cyanobenzidine)-5,7-dimethoxycoumarin, 3-(4-cyanoquinone) Benzobenzine)-5,7-dipropoxycoumarin, 7-dimethylamino-3-phenyl coumarin, 7-diethylamino-3-phenyl coumarin, Revealed at 09-1 7 9 2 9 9 4 and 』? 〇9 - 3 2 5 2 0 9-Pills of coumarin derivatives, such as 7-[(4-chloro-6-(diethylamino)-s-triazin-2-yl)amino] 3-phenyl coumarin; 4.3-(aryl fluorenyl) thiazoline 3 - methyl -2- benzoyl carbene mono quinone naphthozoline, 3 - methyl 1-2 benzoyl Indolyl benzothiazoline, 3-ethyl-2-pyrenemethyl/9-naphthylthiazoline; 5 ·Rhodanine 4-dimethylaminobenzylidene rhodamine, 4-12 Ethylaminobenzylidene rhodamine, 3-ethyl-5-(3-octyl-2-oxothiazolinium)-rudolin, rhodamine derivative, disclosed in JP - 08 - 30501 9 A compound of formula [1], [2], [7]; 6 · other compounds acetophenone, 3-methoxyacetone, 4-phenyl acetophenone, benzamidine, 4 , a pair of (dimethylamino)benzamide, 2-ethylcyanophthalene, 2-naphthaldehyde, dansyl acid derivatives, 9,10 - awakening, hydrazine, phthalocyanine , amine based II - 4 0 - This paper scale applies to China National Standard (CNS) A 4 specifications (210 X 297 mm) (Please read the notes on the back and fill out this page) ------- Order ------.1! Line! Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 A7 B7 V. Invention description (η) naphthalene, perylene, phenanthrenequinone, 9 fluoroketene, dibenzooctanedione, curcumin (curciifflin), mountain Tons of ketone, thioiaichler oxime, α-(4-dimethylaminobenzylidene) guanidines, such as 2,5-bis(4-diethylaminobenzamide)cyclopentanone, 2_ (4 — Dimethylaminoamino-p-phenylidene); 1 -1 嗣, 3 - (4 - dimethylamino-phenyl-phenyl) - 1 - 1berry - 5 - phenyl propylene, 3 - benzene Thiopeptide quinone imine, Ν-methyl-3,5-di(ethylthio)-peptide quinone imine, Ν-methyl-3,5-di(ethylthio)-peptide quinone imine, Phenothiazine, methylphenothiazine, amines such as fluorenyl-phenylglycine, triethanolamine, hydrazine-methyldiethanolamine, ethyl hydrazine-dimethylamino benzoate, 2-(dimethyl Ethyl benzoate, 2-ethylhexyl-p-dimethylamino benzoate, octyl one-to-one oxime, hydrazine-dimethylamino benzoate, hydrazine - (2 - hydroxyethyl)-indenyl-methyl p-Toluidine, butoxyethyl 4 -dimethylamino benzoate, 4 - dimethylamino acetophenone * triethylamine, methyl diethanolamine, dimethylaminoethanol , 2-(dimethylamino)ethyl benzoate, poly(propylene glycol)-tetra-(dimethylamino)benzoate and Michler's oxime. The action of amines can be enhanced by the addition of a benzoquinone type of aromatic hydrazine; examples of amines which can be considered as oxygen cleaners are substituted anthracene, quinone-dialkylanilines, as described in ΕΡ-339841. Other accelerators, co-initiators and autoenoxides are thiol thioethers, disulfides, phosphonium salts, phosphine oxides or phosphines as described, for example, ΕΡ438 1 23 , GB 2 1 80 358 and JP Kofcai Hei 6- 68309. The photopolymerizable composition includes a photo-sensitive agent compound as a further addition -41- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note before completing this page) - Order---------Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 B7 V. Invention Description (D), preferably selected from benzophenone and Its derivatives, thioxanthene and its derivatives, hydrazine and its derivatives, or coumarin derivatives. The component (D) is suitably used in an amount of from 0. 015 to 60 parts by weight, preferably from 0.03 to 30 parts by weight (calculated based on 100 parts by weight of the total of the compounds (A), (B) and (C)) . In some cases, it may be advantageous to use a sensitive compound in combination with a compound of formula I and I I. Accordingly, another subject of the invention is a composition comprising, in addition to components (A), (B) and (C), at least one photo-sensitive compound (D), and/or other additives (E). In addition to the photoinitiator and/or photo-sensitive compound, this photopolymerizable mixture may include various additives (E). The component (E) is, for example, a compound having an epoxy group, so that the composition has thermosetting properties. The epoxide that can be used is solid or liquid, and the use of the epoxy compound depends on the desired properties. For example, when the plating resistance is to be improved, a liquid epoxy resin can be used; when water resistance is required An epoxy resin having a large amount of a methyl group or a cycloalkyl ring on the benzene ring can be used. A preferred epoxy resin is a bisphenol S type epoxy resin such as BPS-200 (manufactured by Nippon Kayafcu Co., Ltd.), EPX-30 (manufactured by ACRCo Corporation), EXA-1511 ( Made from Dainippon Ink & Chemicals Inc.); Bisphenol A type epoxy resin, like Epidulon N- 3 0 5 0 , N- 7 0 5 0 , N-9 050 (produced by Dainippon Ink & Chemicals) ), XAC- 5 0 0 5, GT- 7 0 0 4, 6 4 8 4 T , 6 0 9 9 (by Ciba Specialty -42- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297厘) (Please read the notes on the back and fill out this page) —Book-----I! Line 丨 Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed ^ ϋ nn ϋ I ϋ n ϋ ϋ · 1 n fl — ϋ n I n ϋ -II 1· el - 1250378 A7 B7 V. Invention description 07 )

Chemicals Inc.); bisphenol F type of cyclic chlorine resin, like YDF-200, YDF2007 (manufactured by Tohto Kasei Co.); diglycidyl phenolate resin, like Bleniffler DGT (by Nippon Oil) And Fats Co.); heterocyclic epoxy resin, like TEPIC (produced by N issan C heaica 1 I ndustries, L td company), A ra 1 dite 1β <ACiba Specialty Chemicals Inc.); Phenol type epoxy resin, like YX-400 (manufactured by Yuka Shell Co.); bisphenol type epoxy resin, like YL-6059 (manufactured by Yuka Shell Co.); Epoxypropyl xylene oxime type resin, such as ZX- 1 0 6 3 (produced by Tohto Kasei Co., etc.); phenolic type epoxy resin, like EPPN-201, E0CN-103, EOCN - 1 0 2 0 , E0CN- 1 0 2 5 and BRRN (produced by Nippon Kayaku Co., Lt d ·), ECN- 2 7 8 , ECN-292 and ECN-299 (by Asahi Chemical

Industry Co . , L td ·, produced), 6 Y-118 0, ECN- 1 2 7 3 and ECN- 1 2 9 9 (manufactured by Ciba Specialty Cheibica 1 s Inc.), YDCN-220L, YDCN-220HH, YDCN-702, YDCN-704, YDPN-601 and YDPH- 6 0 2 (produced by Tohto Kasei Co.),

Epiculon- 6 7 3 , N- 68 0, N- 7 7 0 and N- 7 7 5 (produced by Dainippon Ink & Chemicals Inc., etc.); double age A phenolic type epoxy resin, like EPX- 8 0 0 1, EPX- 8 0 0 2 , EPPX-80 6 0 and EPPX-8 0 6 1 (甶Asahi Chefflical Industry Co., Ltd.), Epiculon N - 8 8 0 (by D ainipp ο η I nk & C hemica 1 s I nc · , etc.); chelating agent type epoxy resin, like EPX- 4 9 - 6 9 and EPX- 4 9 - 30 ( -43- This paper scale applies to Chinese national standards ( CNS)A4 specification (210 X 297 mm) (Please read the note on the back and fill out this page) Order---------Line Department of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 125〇378 A7 B7 i, invention description (π) produced by Asahi Denka Kogyo K. K · , et c); glyoxal type epoxy resin, like YDG-414 (produced by Tohto Kasei Co., etc); amine-containing ring Oxygen resins such as YH- 1 4 0 2 and ST-110 (manufactured by Tohto Kasei Co.); YL-931 and YL-933 (manufactured by Yufca Shell Co., etc.); rubber-modified epoxy Resin , like Epidulon TSR-601 (produced by Dainippon Ink & Chemicals Inc.) * EPXH2 and EPX- 4 0 6 1 (produced by Asahi Denfca Kogyo Κ·Κ·, etc); dicyclopentadiene phenol type ring Oxygen resin, like DCE-400 (manufactured by Sanyo-Kokusafcu Pulp Co., Ltd.); modified epoxy resin, like X-1359 (produced by Asahi Denka Kogyo Κ·Κ·etc·, company)— Caprolactone-modified epoxy resins such as Plaque G-402 and G-710 (manufactured by Dicel Cheiica 1 Industries, Ltd., etc.), and other similar products. In addition to this, some of the esterified compounds of these epoxides (e.g., esterified with (meth) acrylate) can also be used together. Accordingly, the subject matter of the present invention is a photosensitive inert composition as described above which additionally comprises an epoxy compound having at least two epoxy groups in the molecule. According to the present invention, a suitable amount of the thermosetting component to be used is from 10 to 150 parts by weight, preferably from 20 to 80 parts by weight (calculated based on 100 parts by weight of the component (A)). Preferably, the thermosetting component is a bisphenol-A*bisphenol-S.bisphenol-F or a phenolic type epoxy compound. An example of other additives (E) is a thermal inhibitor, the purpose of which is to apply the Chinese National Standard (CNS) A4 specification (210 X 297 public) for the anti-4 4 - paper scale (please read the notes on the back and fill in the form) This page) -0------! Order - I line! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Ministry of Printing and Economy Ministry Intellectual Property Bureau Staff Consumer Cooperatives Printed 1250378 A7 ___B7 V. Invention Description (W) Immature polymerization, examples are hydrogen·hydroquinone derivatives, p-A Oxyphenol, /3-naphthyl or sterically hindered phenol, like 2,6-di-tert-butyl-P-cresol. In order to increase the stability of storage in the dark, it is possible to use, for example, an antimony compound such as copper naphthate, stearate or octoate, m compound such as triphenylphosphine, tributylphosphine, triethylphosphorous acid Ester, tri-iphenyl phosphite or trityl phosphite; quaternary ammonium compound, such as tetramethylammonium chloride or trimethylbenzylammonium chloride; or hydroxylamine derivative, such as N- Diethylhydroxylamine. In order to exclude oxygen in the air during the polymerization reaction, it is possible to add an alkane hydrocarbon or a waxy substance which is insoluble in the polymer, and 迁移 migrates its surface at the beginning of the polymerization to form a transparent calendar to prevent the entry of air. It is also possible to apply an oxygen-impermeable layer. A small amount of a UV absorber may be added, such as those of the hydroxyphenylbenzotriazole, hydroxyphenyl-benzophenone-, ethanediamine or hydroxyphenyl-s-triazine type. These compounds may be used singly or in combination, with or without the addition of physic acid (HALS). Examples of such UV absorbers and light stabilizers are: 1 · 2 —( 2 , monohydroxyphenyl)-benzotriazole, like 2 —(2′-hydroxy-δ′-methylphenyl)-benzotriene Azole, 2 - (3', 5 - di-tert-butyl- 2'-p-phenyl)-benzotrisene, 2 -(5'-tert-butyl-hydroxyphenyl)benzotriene Azole, 2 — (2 / hydroxy- 5'-(1,1,3,3-tetramethylbutyl)phenyl)-benzotriazine, 2-(3',5'-two uncle Butyl-2/monohydroxyphenyl)-5-chloro-benzotriazole, 2 - (3'-t--4 5 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the note on the back and then fill out this page) Order: .线. 1250378 A7 ___B7 V. Description of the invention (P) 1-butyl-2'-hydroxy-5, monomethylphenyl)-5-one Benzotriazole, 2-(3,-sec-butyl-5,-tert-butyl- 2,- (Please read the back of the note first and then fill out this page) hydroxydecyl)-benzotriazole, 2 — (2'-hydroxy-4'-octyloxyphenyl)-benzotriazole, 2 (3',5'-di- untert-pentyl- 2, monohydroxyphenyl)benzotriazole, 2-(3',5'-one-one-lt;α·α-dimethyl group) 2'-Amphetylphenyl)-Zhu and Wow, 2-(3'-tert-butyl- 2'-hydroxy- 5'-(2-octyloxycarbonylethyl)phenyl)-5-chloro Monobenzotriazole, 2 - (3'-tert-butyl- 5'-[2-(2-ethylhexyloxy)-carbonylethyl]-2, monohydroxyphenyl)-5-chloro- Benzotriazole, 2-(3'-tert-butyl- 2'-hydroxy-(2-methoxycarbonylethyl)phenyl)-5-chloro-benzotriazole, 2 — (3< - tert-butyl- 2'-trans-yl- 5'-(2-methoxy ortho-ethyl)yl)-benzotrisene, 2-(3'-tert-butyl- 2'- Base 5'-(2-octyloxycarbonylethyl)phenyl)-benzotriazole, 2 - (3/1 - -1-butyl- 5'-[2-(2-ethylhexyloxy) Carbonylethyl]-hydroxyphenyl)-benzotriazole, 2 — (3<-10 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed Dialkyl One 2'-Hydroxy-5/-methylphenyl)-benzotriazole and 2-(3/-tert-butyl- 2'-hydroxy-5'-(2-isooctyloxycarbonylethyl)benzene a mixture of benzotriazoles, 2,-methyl-[4-(1,1,3,3-tetramethylbutyl)-6-benzotriazol-2-ylphenol]; C 3 / untert-butyl-5-(2-methoxycarbonylethyl)-hydroxy-phenyl-benzotriazole and -4 6 - This paper scale applies to Chinese National Standard (CNS) A4 Specification (210 X 297 mm) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 _B7 V. Invention Description (β) Polyesterification product of polyethylene glycol 300; [R — CH2CH2 — C 00 (CH2) 3 2), wherein R = 3, mono-tert-butyl- 4, monohydroxy-5, 2H-benzotriazole-2-phenyl-phenyl. 2 ♦ 2-hydroxybenzobenzene_, like 4-hydroxyl, 4-methoxy, 4-octyloxy, 4-methoxycarbonyl, 4-dodecyloxy, 4-monobenzyloxy, 4 * 2 χ A trihydroxy or 2'-hydroxy-, 4,4, monodimethoxy derivative. 3 ♦ Unsubstituted or substituted benzoic acid esters such as 4-tert-butylphenyl salicylate, phenyl salicylate, octylphenyl salicylate, benzhydrin resorcinol , bis(4-tert-butylbenzylammonium) resorcinol, benzamidine resorcinol, 3,5-di-tert-butyl- 4-hydroxybenzoic acid 2,4 one-two uncle Butyl phenyl ester, 3,5-di-tert-butyl- 4-hexadecyl benzoic acid, octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, 3,5-di-tert-butyl- 4-hydroxybenzoic acid 2-methyl 4,6-di-tert-butylphenyl ester. 4 ♦Acrylate, like α-fluoro-based, 0-diphenylethyl acrylate, or isooctyl ester, α-carboxy-cinnamic acid methyl ester, α-cyano->3- Ρ-Ρ-methoxy-cinnamic acid methyl ester, or butyl hydrazine, α-carbomethoxy-fluorenyl-methoxy-cinnamic acid methyl ester, Ν — (/3 - carbon methoxy-/ 3-cyanovinyl)-2-methylmonoporphyrin. 5 ♦ sterically hindered amines, like bis(2,2,6,6-tetramethyl-#pyridyl) sebacate, bis(2,2,6,6-tetramethyl-piperidinyl) Diester, bis(1,2,2,6,6-pentamethylacridinyl) 癸 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first) Please fill in this page again) * ------ - Order - I- Line! Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 _B7_ V. Invention Description (#) Diester, n-butyl- 3,5-di-tert-butyl- 4-hydroxyl-propyl-malonate a condensation product of (1,2,2,6,6-pentamethylpiperidinyl) ester, 1 monohydroxy-2,2,6,6-tetramethyl-4-hydroxyacridine and succinic acid, Ν ,! ^ / a pair of (2,2,6,6-tetramethyl-tetra-piperidinyl)hexamethylenediamine and 4-tert-octylamino- 2^-dichloro-1,3,5-s- Condensation product of triazine, tris(2,2,6,6-tetramethyl- 4-pyridyl)azintriacetate, tetrakis(2,2,6,6-tetramethyl- 4 piperidine 1,1,3,4-butane tetracarboxylate, 1,1'-(1,2-ethanediyl)-double (3,3,5,5-tetramethyl-piperazinium) ), 4-benzoyl hydrazine-2,2,6,6-tetramethylpyridinidine, 4-monostearyloxy- 2,2,6,6-tetramethyl-pyridine, bis (1,2, 2,6,6-pentamethylacridine)- 2 -n-butyl- 2 - (2-hydroxy-3,5-di-tert-butylbenzyl)malonate, 3-positive-octane Base 7,7,9,9-tetramethyl-1,3,8-tris[4,5]decane-2,4-dione, bis(1-octyloxy-2,2, 6,6-Tetramethylpyridinyl) sebacate, bis(1-octyloxy-2,2,6,6-tetramethylimidinyl)succinate, hydrazine, Ν'-double (2,2,6,6 - tetramethyl one 4 a condensed product of hexyl)hexamethylene and 4-monomorpholinyl-2,6-dichloro-1,3,5-triazine, 2-chloro-4,6-di(4-n-butylamino) a condensation product of 2,2,6,6-tetramethylpyridinyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 2-chloro- 4,6 - 2 (4 one plus one - 4 8 ~ This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page)

一-0' » ϋ ϋ nn II—III—in nn I ϋ nmnnn HI ϋ mi^in ·ϋ n ϋ 11 ϋ I 1250378 A7 _B7_ V. Description of invention (I) butylamine 1 , 2, 2, 6,6-pentamethylpiperidinyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane (please read the notes on the back and fill in the form) Page) Condensation product, 8-ethoxymethyl- 3 - 12-alkyl-7,7,9,9-tetramethyl-1,3,8-tris-spiral [4·5]decane-2,4 Monodecyl, 3-dodecyl-l-(2,2,6,6-tetramethyl-4-indolyl)pyrrolidine-2,5-dione, 3-dodecyl-1 One (1,2,2,6,6-pentamethyl- 4-indolyl)-pyrrolidine-2,5-dione. 6, diammonium oxalate, like 4, dioctyloxy-oxalyl aniline, 2,2'-diethoxy-oxalyl aniline, 2,2'-di-octyloxy-5 , 5, 1-2, tert-butyl-butyl oxalic acid, 2,2'-di(dodecyloxy)-5,5/-di-tert-butyl-p-phenylene anilide, 2-B Oxy- 2'-ethyl-monooxaquinone, hydrazine, hydrazine, a bis(3-dimethylaminoaminopropyl) ethanediamine, 2-ethoxy-5-tert-butyl A 2'-ethyl oxalic acid aniline, and its 2-ethoxylated 2'-ethyl-5,4, 1-2 untert-butyl oxazide aniline Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative The resulting mixture, a mixture of hydrazine- and hydrazine-methoxy-, and hydrazine- and ρ-ethoxy-di-substituted grass anilide. 7,2-(2-hydroxyphenyl)-1,3,5-triazine, like 2,4,6-tris(2-hydroxy-4-isooctyloxyphenyl)-1,3,5-three Oxazine, 2-(2-hydroxy-4-isooctyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2- (2,4 Di-dihydroxyphenyl)- 4,6-bis(2,4-dimethyl-49- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention (Μ) phenyl)-1,3,5-triazine, 2,4-bis(2-hydroxy-4-tetrapropoxyphenyl)-6-(2,4-dimethylphenyl)-1 '3,5-triazine, 2-(2-hydroxy-4-isooctyloxyphenyl)- 4,6-bis(4-methylphenyl)-1,3,5-triazine, 2- ( 2 monohydroxy-tetra-dodecyloxyphenyl)- 4,6-bis(2,4-12-mercapto)- 1,3,5-triazine, 2-[2-hydroxy- 4- (2-hydroxy-3-butoxy-propoxy)phenyl]- 4,6-bis(2-dimethylphenyl)-1,3,5-triazine, 2 —[2-hydroxyl- 4 Mono(2-hydroxy-3-octyloxy-propoxy)phenyl]- 4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2 - [4 Dodecyl mono-tridecyl monooxy-(2-hydroxypropyl)oxy-2-hydroxyl-phenyl]- 4,6-bis(2,4-dimethylphenyl)- 1,3,5-triazine. 8 ♦ phosphites and phosphonites such as triphenylphosphite, diphenylalkyl phosphite, phenyl dialkyl phosphite, tris(nonylphenyl) squarate, three Lauryl phosphite, tris(octadecyl)phosphite, distearyl pentaerythritol diphosphite, tris(2,41-2 di-tert-butylphenyl)phosphite, diisoindole Quaternary phosphonium diphosphite, bis(2,41-2 di-t-butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl- 4-a-methyl) Phenyl) pentaerythritol diphosphite, bis-isodecyloxy-pentaerythritol diphosphite, bis(2,4 1-2 tert-butyl-6-methylphenyl) pentaerythritol Phosphite, bis(2,4,6-tri-tert-butylphenyl)pentaerythritol diphosphorus-50- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back and fill out this page) ------—Book-------Line — ϋ Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 Α7 Β7 V. Invention Description ( w) acid ester Tristearyl-sorbitol triphosphite, tetrakis(2,4-di-tert-butylphenyl)-4,4,diphenylene diphosphinate, 6-isooctyloxy-2 ,4,8,10—Tetra-tert-butyl- 12H-dibenzo[d·g]-1,3,2-dioxaphosphine (P h 〇sph 〇cine), 6-fluoro-2 ,4,8,10 — Teic-tert-butyl- 12-methyl-dibenzo[d,g]-1,3,2-dioxaphosphine, double (2,4 one-two uncle Butyl-6-methylphenyl)methylphosphite, bis(2,4,2-di-tert-butyl-6-methylphenyl)ethylphosphite. In the photosensitive resin composition of the present invention, in order to improve properties such as adhesion, hardness and the like, an inorganic filler such as barium sulfate, barium titanate, cerium oxide powder, cerium oxide particles, amorphous vermiculite, talc may be used if necessary. , clay, magnesium carbonate, calcium carbonate, alumina, argon oxide, mica powder, etc. The filler is present in the formulation in a proportion of from 0 to 60% by weight, preferably from 5 to 40% by weight, of the photosensitive thermosetting resin composition. Furthermore, it is possible to use conventional additives such as conventional dyes such as Phthalocynine Blue, Phtha 1 ocyanine Green, Diazo Yellow, Crystall Violet, titanium oxide, carbon black, naphthalene black, etc. ο. These include other ingredients (Ε) such as epoxy hardening enhancers such as amine compounds, imidazole compounds, carboxylic acids, phenols, quaternary ammonium salts, or methyl alcohol containing compounds. The hardener is used in an amount of 0 to -5 1 - This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) ----- -IT------Line 丨 - Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed 1250378 A7 _._B7___ V. Invention Description) 10% by weight, preferably 〇♦ 05 to 5% by weight Light sensitive thermosetting resin composition. (Please read the notes on the back and fill out this page.) In order to accelerate photopolymerization, it is possible to add amines such as triethylamine, hydrazine-methyldiethanolamine, ρ-dimethylaminobenzoate or Michler. And the above compounds. The action of the amine can be reinforced by the addition of the benzophenone type of aromatics. An example of an amine cleaner which can be used as an oxygen cleaner is the substituted N-dialkylaniline as described in EP339841. Other accelerators, co-initiators and auto-oxidants are mercaptans, thioethers, disulfides, phosphonium salts, phosphine oxides, or phosphines as described, for example, in EP4381 23, and GB 2 1 80358 and JP Kokai Hei 6-68309. In addition to this, it is also possible to incorporate a conventional transfer agent from the prior art into the composition of the present invention. * Examples are thiol and amine compounds. This hardening procedure can be assisted by, in particular, dyed compositions (for example by titanium dioxide) or by the addition of free radicals under thermal conditions, such as azo compounds, like 2,2'-azobis (4). One methoxy Ministry of Economic Intelligence Bureau employee consumption cooperative printed a 2,4 dimethyl pentane), triazene (1:1»1320116), diazo disulfide, pentadiene or peroxidation Compounds such as hydrogen peroxide or peroxycarbonate, such as tert-butyl hydroperoxide, are described in EP-245639. The composition of the present invention may include, as one of the other additives (E), a photoreactive dye such as xanthene, benzoxanthene-benzothiazepine, thiazide, and pyro Pyronine, laver or acridine dye, and/or trihalomethyl compound, which can be cleaved by light irradiation. An example of a similar composition is described in E P44 56 2 -52- This paper scale is suitable for China National Standard (CNS) A4 specification (210 X 297 mm) ' 1250378 Α 7 Β 7 V. Invention description (θ ) 4 0 Other traditional additives (E) (depending on the purpose) is an optical brightener, wetting agent or leveling aid. In order to harden the thick and dyed coating, glass pellets or comminuted glass fibers may be suitably added as described in US 5,013,768. Accordingly, the subject matter of the present invention is a composition as described above, including other additives (E) selected from the group consisting of epoxy compounds, thermal polymerization inhibitors, inorganic fillers, dyes, epoxy hardeners, amine compounds, bond transfer Agent, thermal reaction based initiator, photo-reactive dye, optical brightener, viscosity agent, anti-foaming agent and leveling agent, especially inorganic filler. The choice of additive (E) is based on the field of application and the nature desired in the field. These additives are conventional in this field and are added in amounts that are commonly used in individual applications. The subject matter of the invention also relates to a composition additionally comprising at least one photoinitiator (Β 1 ). In certain cases, it may be advantageous to use a mixture of two or more novel photoinitiators, although it is of course possible to use a mixture with a conventional photoinitiator (Β 1 ), such as camphor, benzophenone derivatives, B. Anthraquinone, an acetophenone derivative such as α-hydroxyacetone, such as 2-hydroxy-2-methyl-1-phenylacetone, or α-aminoethyl benzoquinone, such as 4 monomethyl thiobenzhydrazide)-1-methyl-1-monomorpholine ethane, (4 morpholine benzamidine)-1-phenylmethyl-1,4-dimethylaminopropane, 4-aryl醢1,3 - Dioxane, Benzene Benzyl Alkenyl Ether and Benzene-53- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read first) Note on the back side of this page) 璿· Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printed and prepared! ! f _----------------------- 1250378 A7 _B7__ V. Invention description (θ) (Please read the notes on the back and fill out this page) Ketones, such as dimethylbenzhydrazide, phenylglycolose, and derivatives thereof, dimerized phenylglyoxylates, diethyl acetonide esters, such as benzophenone tetracarboxylic acid High esters, as described in EP126541, monophosphonium oxides, such as (2,4,6-trimethylbenzhydrazide) diphenylphosphine oxide, bisphosphine oxide, bis(2,6-dimethyl Oxyl-benzoic acid)-(2,4 •4-trimethyl-pentyl)phosphine oxide, bis(2,4,6-trimethylbenzhydrazide)-phenylphosphine oxide, double (2, 4,6-trimethylbenzhydrazide)-2,4-dipentyloxyphenylphosphine oxide, triterpene phosphine oxide, halogenated methyltriazine, such as 2-[2-(4-methoxy) Phenyl)-ethene]- 4,6-bis-trichloromethyl-[1,3,5]triazine, 2-(4-methoxy-phenyl)- 4,6-bis-trichloro Methyl-[1,3,5]triazine, 2-(3,4-dimethoxyphenyl)- 4,6-bis-trione-methyl-[1,3,5]3 Pyrazine, 2-methyl- 4,6-bis-trichloromethyl-[1,3,5]-triazine, 2-(4-N,N-bis(ethoxycarbonylmethyl)amine Phenyl)-4,6-bis(methyl chloride)-[1,3,5]triazine, 2-(4-methoxy-naphthyl)-4,6-bis-trichloromethane Jiyi [1,3 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing, 5] triazine, 2 - (1,3 - benzodiazepine-5-based) a 4,6 - double-trichloromethane Base-[1,3,5]triazine, 2-[2-[4-(pentyloxy)phenyl]vinyl]- 4,6-bis-trichloromethyl-[1,3,5 Triazine, 2-[2-(3-methyl-2-isofuryl)-vinyl]-4,6-bis-three-monomethylated methyl-[1,3,5]-triazine, 2- [2-(5-methyl-2-furan-54- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Invention description (w) base) monovinyl] a 4,6-double-three-stomrated methyl-[1,3,5]triazine, 2-[2- (2,4-dimethylene) Base-Phenyl) Ethylene (please read the note on the back and fill in this page). Base] 4,6 — Bis-trichloromethyl-[1,3,5]-three-in-one, 2--[2- (2-methoxy-phenyl)vinyl]-4,6-bis-three-monosylated methyl-[1,3,5]triterpene,2-[2-[4-isopropylidenephenyl) 】]-vinyl]- 4,6-bis-three-stomrated methyl-[1,3,5]triazine, 2-(2-(3-chloro-4-yl-methoxy-phenyl)ethtyl 〕 a 4,6 - bis-three-stomrated methyl-[1,3,5]triazine, 2 -[2-bromo-4,N-N-bis(ethoxymethyl)methyl) Phenyl]-4,6-bis-trichloromethyl-[1,3,5]triazine, 2—[2-oxo-4,N-N-bis(ethoxymethylmethyl)amine Base one base] one 4,6 - double one and three atmospheres methyl one [1,3,5] triazine, 2 - [3 - bromine - 4 - N, N - two Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Printing (ethoxycarbonylmethyl)amino-phenyl]-4,6-bis-trichloromethyl-[1,3,5]3 Pyrazine, 2 - [3 - chloro-4-yl oxime, hydrazine bis(ethoxycarbonylmethyl)aminophenyl-phenyl]-4,6-bis-trichloromethyl-[1,3,5] Triazines, or other halogenated methyl-triazine compounds, as described in G, Buhr, R. Daittiael and C. Liadley Poly®. Mater. Sci. Eng. 61, 269 (1989), and EP 0 2 6 2 7 88 ; Halogenated methyl-oxazole photoinitiators, as described in US437 1 606 and US4371607; 1, 2 - 2, as described in Ε·A. Bartiaaiin, Synthesis 5, 490 (1993); hexaaryl Biscarbazole, and hexaarylbiscarbazole/co-initiator systems, such as hexamethylene hexaphenyl-di-m-55- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 ___B7 V. INSTRUCTIONS (θ) (Please read the note on the back and fill out this page) Oxazole and 2 - pre-benzazole, ferrocene compound, or titanium alkene, such as bis(cyclopentadiene) Base) a pair of (2,6-difluoro- 3 -fluorenyl-phenyl) titanium. When the novel photoinitiator system employed is a hybrid system, in addition to the novel free reactive scavenger, a cationic photoinitiator* peroxide, like benzamidine peroxide (other suitable peroxidation) can be used. , as described in US Pat. No. 4,950,581, Item 19, lines 17-25), aromatic, iron or iodonium salts, as described in US Patent No. 4950581, Item 18, Line 60 To the 19th, 10th, or cyclopentadienyl, anthracene-iron (II) complex salt, such as -isopropyl benzene) (ns - cyclopentadiene) - iron (II) hexafluorophosphate Salts, and oxime sulfonates, are described, for example, in EP 7807 29. Pyridine and (iso)quinoline salts can also be used in combination with this novel photoinitiator as described in EP 497 531 and EP 441 232. The photoinitiator (B), regardless of the military alone or in combination with other conventional photoinitiators (B1) and photo-sensitizers (D), can be K-dispersed or emulsified in a water or aqueous solution. The Ministry of Economic Affairs Intellectual Property Office employee consumption cooperative printing photoinitiator (B) is usually added in an amount of 0 015 to 60 parts by weight, preferably 0 · 03 to 30 parts by weight (based on 100 parts by weight of the ingredients (A ) and (C) 缌 total weight). In case the mixture of starting surfaces is used, the amount added depends on the total amount of photoinitiator added. Therefore, this amount may be based on photoinitiator (B) or photoinitiator (B) + (B 1 ). . The invention also belongs to a composition comprising 100 parts by weight of ingredients - 5 6 ~ The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _______B7__ V. Invention description (〇) ( A), 0.015 to 120 parts by weight of ingredients (B), 5 to (please read the back note first and then fill out this page) 500 parts by weight, for example 5 to 300 parts by weight of ingredients (C), and 〇· 015 to 120 parts by weight of the ingredient (D). This novel light-sensitive composition can be applied to a negative resistance agent which is highly sensitive to light and which does not swell in an aqueous alkaline solution. It is suitable as a photoresist for mold components (electroless plating inhibitor, plating resist, etching group resist, solder resist, photoimageable green and dielectric layers). The composition can be uniformly applied to the substrate by conventional techniques such as spin coating, dip coating, knife coating, curtain pouring techniques, and brush application. ), sprays, especially electrostatic sprays, and reverse roll coating, can also be applied by electrophoretic deposition. It is also possible to apply this photo-sensitive layer to a temporary flexible support which can then be transferred by lamination by applying a final substrate, such as a slab coated circuit board. An example of a suitable organic solvent printed by the Intellectual Property Office of the Ministry of Intellectual Property, which is used to adjust the viscosity of the composition to make it suitable for coating techniques, such as ethyl methyl ketone, cyclohexanone, cyclopentane Ketone, 2-pentanone, 2-glycol, etc.; aromatic hydrocarbons such as toluene, xylene, tetramethylbenzene, etc.; diethanol ether, like methyl cellulose, ethyl cellulose, butyl cellulose , benzyl cellulose, phenyl cellulose, methyl carbitol, butyl carbamide, propylene glycol methyl ether, dipropylene glycol monomethyl ether, dipropylene glycol butyl ether, triethyl Diethyl ether, etc.; esters, such as ethyl acetate, butyl acetate, ethyl acetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, And the esterification product of the above glycol ether, -57- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 __ B7__ i, invention description (shake) (please read the back note first) Matters fill out this page) like cellulose acetate, butyl cellulose acetate, propylene glycol monomethyl ether acetate, carbamide Acid ester, butyl carbitol acetate; alcohol, like ethanol, propylene, n-butanol, Zhengyiji, Zhengyigeng, n-octanol, ethylene glycol, propylene glycol, etc.; fat carbon Hydrogen compounds such as octane, decane, etc.; petroleum type solvents such as petroleum ether, naphtha, hydrogenated naphtha, lysine naphtha, etc., and other compounds such as N-methylpyrrolidone and 7 Butanol acetone. This organic solvent is used to dilute the resin, so that the application amount (coating thickness) of the coating can be easily applied and the properties of the substrate (structural layer support) are determined depending on the intended application field. The thickness of the coating is generally from about 0 lam to over 100 um, such as from 0 ♦ 1/zm to 1 cm, preferably from 0 ♦ 5/im to 1 000/im. After the substrate is coated, the solvent is removed, typically by a dry process, leaving a thin film of photoresist on the substrate. "Imagewise" The meaning of exposure includes exposure through a reticle containing a predetermined pattern, such as a slide, a chrome mask, a stencil mask or Mr eticle exposure, and a laser or beam exposure For example, 'irradiation on a coated substrate under computer control, so that an image is produced, and the Ministry of Economic Affairs' Intellectual Property Office employee consumption cooperative prints and uses computer-controlled electron beam irradiation. It is also possible to use a reticle made of liquid crystal which can be positioned by a pixel to produce a digital image as described in A. Bertsch; JY Jezequel; J. C. Andre in Journal of Photoche through istry and Photobiology A : Chemistry 1 9 9 7 , 107 p275-281 and K. P · N ico 1 ay in Offset Printing This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm). 1250378 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints A7 B7 V. INSTRUCTIONS (u) 1 9 9 7 , 6, P 3 4 - 3 7 As described above, the composition of the present invention can be imaged in an alkaline aqueous solution. * Particularly suitable alkaline aqueous developer solution It is an aqueous solution of tetraalkylammonium hydroxide or an aqueous solution of an alkali metal ruthenate, phosphate, hydroxide or carbonate. A small amount of wetting agent and/or organic solvent may also be added to these fatigues if desired. Examples of the basic organic solvent which can be added in a small amount to the developer liquid are cyclohexanone, 2-ethoxyethanol, toluene, acetone, N-methylpyrrolidone, and a mixture of these solvents. The novel composition of the present invention has a light sensitivity of from about 150 nm to 600 nm, such as from 1 90 to 600 nm (UV-visible region). A suitable light source is light such as daylight or an artificial light source. Therefore, many different types of light sources can be used, and point sources and array light sources (light blankets) are suitable. Examples are carbon arc lamps, xenon arc lamps, super high ones, high ones* medium ones and low-pressure mercury lamps, selective bismuth metal halide coating (metal-halogen lamps), microwave-excited metal vapor lamps, excitation Excimer, super actinic fluorescent light, fluorescent light, argon white hot light, electronic flash light, photo floor lamp, light emitting diode (LED), electron beam and X-ray. The distance from the lamp to the exposed base sheet of the present invention is dependent on the application type and the rotation of the lamp* and may be, for example, 2 cm to 150 cm. Laser sources such as laser lasers, such as KrF laser (248 nm), ArF laser exposure (193 nm), and Fz laser exposure (157 nm) are also suitable. Lasers in the visible region can also be used. Therefore, the present invention provides a photopolymerization comprising at least one ethylene unplaned and -59- paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first and then fill out this page) ------II order-----I! line—

JB 1250378 A7 ______B7 V. INSTRUCTIONS (A) (Please read the notes on the back and then fill out this page) The method of double-bonding compounds, including adding at least one of the above compounds of formula I or II to the above compounds, and using electromagnetic The composition of the irradiation result is particularly irradiated with light having a wavelength of from 150 to 600 nm, that is, a method for photopolymerizing an ethylenically unsaturated biguanide compound, which comprises irradiating the composition with electromagnetic waves having a Μ wavelength of from 150 to 600 nm. The present invention is also directed to a coated substrate having at least one surface coated by a composition of the upper crucible and a method for producing a convex image for a photograph, wherein the coated substrate is based on The image, electromagnetic radiation having a wavelength ranging from 1 50 to 600 nm, and then a solvent removes the unexposed areas. The compositions of the present invention still have high sensitivity and resolution at low concentrations of photoinitiators (with or without sensitizers) and are particularly useful in applications where aqueous solutions of photopolymers can be imaged. The composition of the present invention has good thermal stability and low volatility. This novel radiation-sensitive composition can be used as a negative photoresist, has high sensitivity to light, can be imaged in an alkaline aqueous solution (without a bulking agent), and is suitable for photoresists for electronic components. Like electroplating photoresist, the Ministry of Commerce of the Ministry of Commerce, the Ministry of Commerce, the Intellectual Property Bureau, the Consumer Cooperative, which prints the fluorescent or the net-made resistance brush or the light-emitting plate and the printed plate of the plywood. Word electric pulping, dot body, electric board brushing, human body building agent, brushing, printing, blinding, anti-printing, manufacturing, resistance, making in the drawing, making or making, such as when I, welding, flat or 60, agent layer, grinding - Membrane-resistance brush-making, thin-light-junction, and the production of the stencil-printed stencil-printed embossing in the light-to-light coating method, wet color, convex, color plate brush, preparation of printing ticketing device The display board is printed with the light-resisting screen version. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1250378 A7 B7__ V. Description of the invention (door) (Please read the notes on the back and fill in the form) Page) Agent. The composition can further be used to fabricate coated or insulative coatings of computer wafers, printed circuit boards and other electrical or electronic components with a photo-patternable dielectric layer or coating. Possible structural layer coatings, as well as processing conditions for the coated substrate, vary from case to case. Since the photohardenable composition of the present invention has good thermal stability, it is particularly suitable for the manufacture of color filters or color decoration systems, as described in Ε Ρ 3 20264. Color filters are commonly used in the manufacture of LCDs, projection systems and image sensors. This color filter can be used, for example, in a television receiver* image monitor or a computer display and image scanner. Thus, one of the hallmarks of the present invention is a color luminescent photoresist comprising the composition as described above and which will be more closely depicted under the armpit. Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs. The color filter usually forms red, green and blue pixels and a black matrix on a glass substrate. Among these methods, the photohardenable composition of the present invention can be used. A particularly preferred method for this application involves coating the substrate with the composition of the present invention, drying the coating with a brief heat treatment, exposing the actinic radiation to image exposure, and allowing the image to be imaged in an alkaline developer. Imaging, and finally selective heat treatment. Next, a red, green, and blue coating is applied in any order, one layer over the other, in such a manner that a color filter having red, green, and blue pixels can be produced. The development is carried out by washing away the area where the unsuitable alkaline imaging solution is polymerized, and repeating this method to form an image having a color. In the photo-sensitive resin composition of the present invention, at least one or more of the paper-61-this paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A7 1250378 B7___ V. Invention Description (minutes) (Please Read the back of the back sheet and fill in the page. The image element can be used as a light-shielding light when the image element is formed on a transparent substrate and then exposed from one side of the transparent substrate to a portion where the image element portion is not formed. The cover, for example in the case of the entire exposure, is not required to adjust the position of the reticle, and consideration of positional sliding is also not required. In addition, it may also harden all the parts and the upper image will not form on it. In this case, some light may be used to mask the mask and remove the upper layer. The image element portion is formed. Since the gap is not formed between the image elements formed formally and the image elements formed thereafter, the composition of the present invention is suitable for, for example, forming a color light-emitting sheet material. Specifically, a dyeing substance, a dye, and red, green, and blue dyes are added to the light-sensitive resin composition of the present invention, and the steps of repeatedly forming an image form a red, green, and blue image element, and then Then, a black dye substance, a dye and a pigment are added to the light-sensitive resin composition, and added to the entire surface. The entire surface can then be exposed (or partially exposed through the light-shielding mask) to form a black circle image element in all spaces between the red, green and blue artifacts (or in addition to the partial area light-masking mask) All space). Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives, in addition to the step of applying the light-sensitive resin composition to a substrate and drying, the light-sensitive resin composition of the present invention can also be used as a structural layer transfer material, that is, The light-sensitive resin composition is provided directly onto the temporary support by a layered structure, preferably on a polyethylene peptidate film, or the light-sensitive resin composition is provided in a polyethylation On the peptidate film, an oxygen-masking layer and a peeling layer are provided thereon. Usually -62- L paper size applies to China National Standard (CNS) A4 specification (210 Χ 297 public love ^ ' "" Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 A7 ___B7 V. Invention description (illusion), A removable cover layer made of synthetic resin is applied over it as protection during operation. Further, a structural layer can be provided on which an alkali soluble thermoplastic resin on the temporary support is further provided. a layer and an intermediate layer, and other light-sensitive resin composition layers (JP5-17332OA). The cover layer is removed during use, and the light-sensitive resin composition layer is layered on a permanent support, followed by oxygen shielding When the layer and the release layer are provided, the structural layers are peeled off from the temporary support; when only the release layer and the oxygen shielding layer are provided, * the release layer and the oxygen-shielding layer are peeled off; and when the release layer and the oxygen-mask layer are both When not provided, the temporary support and the light-sensitive resin composition are peeled off, and the temporary support is removed. The metal support, the glass, the ceramic* and the synthetic tree film can be used as a branch of the color filter. Glass and synthetic resin films having transparency and excellent dimensional stability are particularly preferred. The thickness of the light-sensitive resin composition layer is usually from 1 to 50 μm, particularly from 1 to 5 μm. The aqueous solution is used as a developing solution of the photo-sensitive resin composition of the present invention, and may include a solution prepared by adding a small amount of water to a miscible organic solvent. Examples of suitable basic substances include ruthenium ruthenium hydroxide (for example) , sodium hydroxide and potassium hydroxide), alkali metal carbonates (for example, sodium carbonate and potassium carbonate), alkali gold bismuth hydrogencarbonate (for example, sodium hydrogencarbonate, and potassium hydrogencarbonate), alkali metal citrate ( For example, sodium citrate and potassium citrate), gold ruthenium citrate (for example, sodium citrate and potassium citrate), triethylamine, and the standard of paper on the second is applicable to the Chinese National Standard (CNS) A4. Specifications (210 X 297 mm) (Please read the note on the back and fill out this page) | Order · 丨 line. 1250378 A7 _ B7____-_ V. Invention description (k) (Please read the notes on the back and fill in On this page) Alcoholamine, ethanol , morpholine, tetraalkylammonium hydroxide (for example, tetramethylammonium hydroxide), or sodium triphosphate. The concentration of the alkali metal is 0. 01 to 30% by weight, and the pH is preferably 8 to 14. Suitable organic solvents that are miscible with water include methyl leaven, ethyl yeast, 2-propanol, 1-propanol, butanol, diacetone alcohol, ethylene glycol monomethyl ether, and ethylene; • Ethylene glycol mono-n-butyl ether, benzyl alcohol, acetone, methyl ethyl ketone, cyclohexane, e-caprolactone, 7-butanone, dimethylformamide, dimethylacetamide , hexamethylphosphonium, ethyl lactate, methyl lactate, 7-caprolactam, and N-methyl-3⁄4-aldolone. The concentration of organic solvent miscible with water is 0·1 Up to 30% by weight. Further, a wide range of conventional surface active agents can also be added. The concentration of the surface active agent is preferably from 0.001 to 10% by weight. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives. The use of the imaging solution can be in the form of a water bath solution or a spray solution. In order to remove the unmatured portion of the photosensitive resin composition, a method of wiping with a rotary brush or a damp sponge may be used in combination. Generally, the temperature at which the image is dissolved is preferably from room temperature to about 40 Å. The development time can be changed depending on the specific kind of photosensitive resin composition, the basicity and temperature of the developing solution, and the type and concentration of the organic solvent when added. In general, it is 10 seconds to 2 minutes. It is also possible to add a rinse step after the development procedure. The final heat treatment is preferably carried out after the development process. Therefore, a carrier having a layer photopolymerized by exposure (hereinafter simply referred to as a photothermalization layer) is heated in an electric furnace and a dryer, or the photo-curing layer is irradiated on an infrared lamp or heated on a hot plate. The heating temperature and time depend on the composition used and the shape of the -64- paper scale applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 ___B7___ V. Invention description (6丨) Depending on the layer thickness. Generally, heating is preferably carried out at a temperature of from about 1 2 Torr to about 25 Torr for from about 5 to about 60 minutes. (Please read the note on the back and then fill out this page.) In the composition of the present invention, the photoresist composition including the dyed color extinction film is preferably a processed pigment such as a powder or a paste. The product is obtained by finely dispersing a pigment to at least one resin; the resin is selected from the group consisting of acrylic resins, vinyl chloride-vinyl acetate copolymers, maleic acid resins and ethyl cellulose resins. The Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints red pigments, for example, containing separate quinone type pigments, separate northern type pigments, or at least one of them and a disazo type yellow pigment or iso-dihydroazapine type yellow. a mixture of pigments, in particular C·I·Pigment Red 177 alone, C. I. Pigment Red 155 alone or from at least one C. I·Pigment 177, C·I. Pigment Red 155 and C·I. A mixture of pigment yellow 83 or (:.1. pigment yellow 13 9 ("(3.1. <| is a colorimetric index, which is well known and widely available to those skilled in the art). Further of the pigment Suitable examples are C.I. Pigment Red 105, 144, 149, 176, 177, 185, 202, 209, 214, 222, 242 * 254, 255, 264, 272 and CI·Pigment Yellow 24, 31, 53, 83 , 93, 95, 109, 110, 128, 129, 138, 139, 166 and CI·Pigment Orange 43. Green pigments, for example, contain a separate cesium halide type pigment or with a disazo type yellow pigment or iso-dihydroaza a mixture of 茚 type yellow pigments, especially for singles C·I. Pigment Green 7, Separate CI Pigment Green 36, C. I. Pigment Green 37 alone or by at least one of CI Pigment Green 7, C·I·Pig Green 36, C·I·Pig Green 37 , C · I. Yan Ben paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _ B7___ V. Invention Description (&) Green 136 and C·I. Pigment Yellow 83 or CI A mixture of pigment yellow 13 9. Other suitable green pigments are C. I, pigment greens 15 and 25. (Please read the notes on the back and fill out this page.) Examples of suitable blue pigments are individual peptide types. a pigment, or a combination thereof with a dioxazine type violet pigment, for example, a combination of CI Pigment Blue 1 5:3 and CI Pigment Violet 23. A further example of a blue pigment is C. Γ·颞 Blue 15:3, 15:4, 15:6, 16 and 60, that is, peptide cyanine C·I. Pigment blue 1 5 : 3, or peptide cyanine C. I·Pigment 15:6. Other suitable pigments are CI Pigment Blue Color 22,28, C. I·Pigment Violet 14, 19, 23, 29, 32, 37, 177 and C·I · Pigment Orange 73. Black Body pigments photopolymerizable composition preferably comprises at least one selected from the group comprising carbon, titanium black and iron oxide. However, other pigments may also be used a mixture obtained in the overall black appearance. For example, a C. I. pigment can be used. Black 1 and 7 can be combined. In order to obtain any color, a combination of more than two pigments can be used, which is particularly suitable for use as a powder for color filter applications, which is prepared by finely dispersing the above pigment into the resin. The concentration of the pigment in the total solid composition (pigments and resins of different colors) printed by the Intellectual Property Office of the Ministry of Economic Affairs is, for example, 5% to 80% by weight, for example, 10% to 50% by weight, especially In the range of 20% to 45% by weight. The pigment in the color filter photoresist composition preferably has a mean particle diameter lower than the wavelength of visible light (400 nm to 700 Å). Particularly preferred is the average pigment diameter < 1 〇〇 nanometer. -66- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7_____ V. Invention description ((1)) (Please read the note on the back and fill in this page) If necessary, pigment Stabilization in the photosensitive composition can be used to pretreat the pigments with a dispersant which improves the dispersion stability of the pigment in the liquid formulation. Color filter photoresists, examples of such photoresist compositions and processing conditions are shown in T. Kudo and his research colleagues, Japanese Journal of Applied Physics (Jpn. J. ▲ipl· Phys·) Vol. 37 (1998) 3 5 9 4 ; Τ· Kudo and his research colleagues, Journal of Photopolymerization Science and Technology (J. Photopoly®· Sci·

Technol·) Volume 9 (1 9 9 6) 1 0 9, Κ· Kobayashi, Solid State Technology (Solid State Technol) 1 9 9 2, page S15-S18; US 5368976; US 5800952; US 5882843 US 5879855 ; US 5 8 6 6 2 9 8 ; US 58 6 3 6 7 8 ; JP 0 6 - 2 3 0 2 1 2 - A ; EP 3 2 0 2 6 4 5 JP 0 9 - 2 6 94 1 0 -A ; JP 1 0 - 2 2 1 84 3 -A; JP 0 1 - 0 9 0 5 1 6-A ; JP 10-171119-A, US 5821016, US 5847015, US 5882843, US 5 7 1 9 0 0 8,EP 881 54 1,WL EP 9 0 2 3 2 7 智慧Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed The photoinitiator of the present invention can be used in the color » light film light sister as exemplified above In the agent, a conventional photoinitiator may be partially or completely replaced in these photoresists. It will be understood by those skilled in the art that the use of the novel photoinitiator of the present invention is not limited to specific binder resins, crosslinkers and color filter photoresist formulations as described above, In combination with dyes or color pigments or latent pigments to any free radical polymerizable composition, K forms a photosensitive color calender) = {ink or color filter photoresist. Therefore, the object of the present invention is also a color "light sheet, which is prepared by using a red, green and blue (RGB) color-67-paper scale containing photosensitive resin and pigment for the Chinese National Standard (CNS) A4. Specifications (210 X 297 mm) 'l25〇378 A7 ------- ---B7 V. Invention description (蚪) (Please read the note on the back and fill out this page) Color unit and optional use The black matrix is placed on the transparent substrate, and the transparent electrode is placed on the surface of the substrate or the surface of the color filter layer, wherein the photosensitive resin comprises a polyfunctional acrylate monomer, an organic polymer binder and A photopolymerization initiator of formula I or II as described above. Monomer and binder composition* and suitable pigments are as described above. When preparing a color filter, a transparent electrode layer can be applied to the surface of the transparent substrate, or applied to red, green and blue. The picture unit and the surface of the black substrate. The transparent substrate can be, for example, a glass substrate having an additional electrode layer on the surface. It is preferred to apply a black matrix to a color region of a different color to improve the contrast of the color filter. The Ministry of Economic Affairs' Intellectual Property Office employee consumption cooperative prints a black matrix based on the use of a photosensitive composition, and lithographically patterns the black photosensitive composition by patterning exposure (that is, by a suitable mask). And forming a black pattern on the transparent substrate separate from the red, green and blue colored regions, it is also possible to use an inorganic black matrix. The inorganic black matrix is formed by depositing (ie, sputtering) a gold ruthenium (ie, chrome) film on a transparent substrate, which can be etched by an etch photoresist using an appropriate imaging process. The agent protects the inorganic layer in the region and then removes the etch photoresist. Many different methods of determining have been used in which the black matrix can be used in the manufacturing steps of the color filter. It can be applied directly to the transparent substrate as before, in the formation of red, green and blue (RGB) color extinction sheets, or after the RGB color filters are formed on the substrate. -6 8 - This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Invention description (Μ) (Please read the note on the back and fill out this page) According to US 5626796, In a different embodiment of the color filter used in the fatigue display, the black substrate can also be applied to the opposite substrate separated from the model by the liquid crystal layer and having the RGB color filter unit substrate, for example, as described in US. In 5650263, if the transparent electrode layer is deposited after application of the RGB color JT photocell unit and the selective black matrix, an additional overcoat film as a protective layer can be applied to the color calender sheet layer prior to deposition of the electrode layer. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumers' Cooperative. In order to form a cover on a colored calender, a light-sensitive resin or a thermosetting resin composition may be used. The light-sensitive composition of the present invention can also be used to form such a cover layer because the cured film of the composition is excellent in many aspects of underarming: flatness, hardness, chemical and thermal resistance, transparency (especially In the visible light region, adhesion to the substrate, and suitability for forming a transparent electrically conductive film thereon, such as an I TO film. When manufacturing the protective layer, the unnecessary portion of the protective layer must be removed from the substrate, such as the marking of the substrate, and the bonding pad of the solid image, as described in JP 57- 4 2 0 09-A, JP Bu 1 3 0 1 0 3 -A and JP1-134 3 0 6-A. In this regard, it is difficult to selectively form a protective layer using the above-described thermosetting resin. However, the light-sensitive composition can easily remove unnecessary portions of the protective layer by photolithography. It will be apparent to those skilled in the art that, irrespective of the differences in processing procedures and procedures described above, the additional layers that can be applied and the color filters that are designed, the photosensitive composition of the present invention Can be used to generate red, green-69- This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) A7 1250378 __B7 V. Invention description US) (Please read the back note first and then fill in this page And the blue color pixels and the black matrix to make a color filter. The use of the compositions of the present invention to form colored units is not limited by the varying degrees of design and manufacture of such colored calenders. It is required to be soluble in an alkaline aqueous solution and insoluble in water in the composition of the color calendering resist, and for example, one or more acid groups and one or more polymerizable groups may be used in the molecule. A homopolymer of a saturable bond of a polymerizable compound, or a copolymer of two or more types, and one or more copolymers having a polymerizable compound copolymerizable with these compounds and containing no acid groups. The compounds may be derived from one or more classes of low molecular weight compounds having one or more acid groups and one or more polymerizable unsaturated oximes in the molecule, and one or more unsaturated doubles having copolymerizable with these compounds. A copolymerizable compound which does not contain an acid group is copolymerized. Examples of the acid group are a COOH group * an SCU fluorenyl group, a SOzNHCO group, a phenolic hydroxyl group, a SO2 NH group, and a C0 - NH - C0 group. Among the above, a high molecular weight compound having a C00H group is particularly preferred. 0 The Ministry of Economic Affairs, the Intellectual Property Office, the employee consumption cooperative printed better, and the organic compound (A) in the color filter photoresist composition is organic. The polymer binder comprises an alkali soluble copolymer comprising at least one unsaturated organic acid compound such as acrylic acid, methacrylic acid and the like as a monomer unit capable of addition polymerization. It is preferred to use an unsaturated organic acid ester compound as a further comonomer balance for the polymer binder, such as alkaline solubility, adhesion stability, chemical resistance, etc., such as a methyl acrylate. Ester, ethyl (meth) acrylate, (-70- This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 Α7 Β7 V. Invention description (屻) Methyl acrylate styrene Base esters, styrene and similar. The organic polymer binder may be any copolymer or block copolymer, for example, in US 5 3 6 8 9 7 0, having one or more acid groups and one or more polymerizable unsaturated oximes in the molecule. Examples of the polymerizable compound include the following compounds: propyl gallic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, vinyl benzoic acid, and cinnamic acid having one or more C Ο in the molecule. An example of a polymerizable compound of a fluorenyl group and one or more polymerizable unsaturated bonds. Vinylbenzenesulfonic acid and 2-(meth)acrylamide- 2-methylpropenic acid are polymerizable compounds having one or more mono-S 3 fluorenyl groups and one or more polymerizable unsaturated bonds example. Ν —Methylsulfonyl (meth) acrylamide, hydrazine — ethyl sulfonyl (meth) acrylamide Ν — phenyl sulfonyl (meth) acrylamide, and Ν- (pair Methylphenylsulfonyl) (meth) acrylamide is an example of a polymerizable compound having one or more S02 NHCO- groups and one or more polymerizable unsaturated bonds. Examples of polymerizable compounds having one or more phenolphthalein hydroxyl groups and one or more polymerizable unsaturated hydrazines in the molecule include hydroxyphenyl (meth) acrylamide, dihydroxy phenyl (meth) acrylamide, Hydroxyphenyl-carbonyloxyethyl (meth)acrylate, hydroxyphenoxyethyl (meth)acrylate, hydroxyphenylthioethyl (meth)acrylate, dihydroxyl (meth)acrylate Phenylcarbonyloxyethyl ester, dihydroxyphenoxyethyl (meth)acrylate, and dihydroxymonophenylthioethyl (meth)acrylate. There are one or more S〇2 NH-based groups in the molecule and one or more - 71- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 χ _ _ _ _ _ 1 · 1 (please read the back of the note first) Matters fill out this page) - - - Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed Economy Ministry Intellectual Property Bureau Staff Consumer Cooperatives Printed 1250378 A7 ^_B7__ V. Invention Description (β) Aggregation of Polymerizable Unsaturated Bonds Examples of the compound include compounds represented by the formula (a) or (b): CHz = CHAi - Υι - A2 - S〇2 - NH - A3 CH2 = CHA4 - Yz - As - NH - S02 - As —----- ----------------(b) where Yi and 丫2 represent a COO-, a CONA7 one, or a military one; Ai and A4 represent Η or CH3, respectively; As represents a Ci-Ci 2 alkylene group optionally having a substituent, a cycloalkylene group, an arylene* or an aralkylene group, or an ether group and an oxime ether group, a cycloalkylene group, an arylene group. Or an aralkylene group inserted into a C2 - Ci 2 alkylene group; A3 and A6 each represent a hydrazine or a Ci alkyl group optionally having a substituent, a cycloalkyl group, an aryl group or an aralkyl group; And Α7 represents Η or a C i -Ci 2 alkyl group optionally having a substituent, a cycloalkyl group, an aryl group or an aralkyl group, which optionally has a substituent, a cycloalkyl group, an aryl group or an aromatic group Examples of the polymerizable compound having one or more mono-C0-NH-CO groups and one or more polymerizable unsaturated oximes include maleimide and N-propenyl acrylamide. The polymerizable compound becomes a high molecular weight compound containing a C ◦-NH-C0 group, wherein the ring is formed by polymerization together with the main chain. Further, each C0-NH may be used. C0-based methacrylic acid derivatives and acrylic acid derivatives. These methacrylic acid derivatives and acrylic acid derivatives such as -72- are applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read first) Precautions on the back side of this page. Line A7 B7 1250378 V. Description of invention (β) Includes a methacrylamide derivative such as N-acetylisobutyl decylamine, N-propenyl methacrylamide, N - Butyric acid isobutylene decylamine, N-pentamethylene butyl Indoleamine, n-methyl propyl decylamine, N-dodecyl decyl propylene amide, N-benzhydryl methacrylamide, N — (p-methylbenzoguanidino) propylene Indoleamine, N-(p-chlorobenzoyl) methacrylamide, W-(naphthylcarbonyl)methacrylamide, N-(phenylethenyl)propenylamine, and 4-propenylhydrazine Aminoimine, and acrylamide having a cypress substituent as described above. These polymerizable compounds are polymerized to form a compound having a C0-NH-CO- group in the side. Examples of having one or more polymerizable unsaturated bonds and not containing an acid group include compounds having a polymerizable unsaturated oxime and selected from (meth)acrylic sugars, (meth)acrylamides, acrylic compounds, Vinyl ethers, vinyl esters, styrenics, and crotonates, and particularly including (meth) acrylates such as alkyl (meth) acrylate or substituted (meth) acrylate Base esters (eg methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, Amyl (meth)acrylate, hexyl (meth)acrylate, cyclohexyl (meth)acrylate, ethylhexyl (meth)acrylate, octyl (meth)acrylate, (meth)acrylic acid Third octyl ester, ethyl (meth) acrylate, allyl (meth) acrylate, 2-hydroxy-ethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate , 4-hydroxybutyl (meth)acrylate, ( Base 2,2-dimethyl-3 -3 -3 - 3 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page) · · • 线 线 线 线 线 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 5-hydroxypentyl acrylate, trimethylolpropyl mono(meth)acrylate, pentaerythritol mono(meth)acrylate, benzyl (meth)acrylate, (meth)acrylate Oxybenzyl ester, chlorobenzyl (meth) acrylate, decyl (meth) acrylate, tetrahydrofurfuryl (meth) acrylate, phenoxy (meth) acrylate) , and (aryl) (meth) acrylate (such as (meth) acrylic acid Ministry of Commerce, Intellectual Property Bureau employees consumption cooperatives printed phenyl ester, (meth)acrylic acid tolyl ester, and (meth) methacrylate (meth) acrylamide such as (meth) propylene-fluorene , N-alkyl (meth) acrylamide (the alkyl group includes, for example, methyl, ethyl, propyl, butyl, tert-butyl, heptyl, octyl, ethylhexyl, cyclohexyl, hydroxyethyl And benzyl), N-aryl(meth)acrylamide (which includes, for example, phenyl, tolyl, nitrophenyl, naphthyl, and hydroxyphenyl), N, N - II Alkyl (meth) propylene-decylamine (the alkyl group includes, for example, methyl, ethyl, butyl, isobutyl, ethylhexyl, and cyclohexyl) *N,N-diaryl (methyl) Acrylamide (for example, including phenyl), N-methyl-N-phenyl(meth)propenyl-decylamine, N-hydroxyethyl-N-methyl(meth)acrylamide, N — 2 —Ethylaminoethyl-N-ethenyl(meth)acrylamide, N —(phenylsulfonyl)(meth)acrylamide, and N—(p-methylphenyl) Sulfhydryl) (meth) acrylamide; allyl compound such as allyl ester (eg allyl acetate, allyl hexanoate, allyl octyl ester, allyl laurate, brown Allyl citrate , allyl stearate, allyl benzoate * allyl acetate - 74 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 (please First read the notes on the back and then fill out this page) · -- Line · Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed five, invention description (, and lactic acid vinyl ether, sulfhydryl, 1 methyl group, hydroxyl · butyl Alkylamine (the aryl phenyl, vinyl ester vinyl vinyl vinyl acid vinyl acetoacetate curtain, cyclohexyl ester, chlorophenenyl cool; styrenic styrene cumene, fluorenyl Phenylstyrene, alkoxyphenylstyrene oxime) allyl ester), and such as alkyl vinyl ethylhexyl, methoxy-2,2-diethoxyethyl, diyl Z-based, benzene The methyl group includes, for example, a phenylnaphthyl group, and a mercapto group such as vinyl butyrate, vinyl acetate vinyl acetate, vinyl butoxyacetate, vinyl carboxylic acid vinyl ester Base ester,

Such as styrene, alkyl, trimethylstyrene ethylene, butyl styrene, benzyl phenyl ethoxymethyl styrene (such as methoxy, and dimethoxy phenyl allyoxyethanol; ether (The alkyl group is, for example, ethylethyl, ethoxypropyl*2-ethylaminoethyl, and tetrahydroindenyl), tolyl, phenyl phenyl ester, ethylene isobutyric acid diethyl ester , borate ester, dichloroethylene vinyl acetate, phenyl vinyl ester * b - , benzoic acid vinyl tetrachlorobenzoic acid ethylene styrene (eg, methyl, ethyl styrene * ene * hexyl styrene B), Chloromethyl phenylene, and ethoxylated styrene, 4-ethylene), and halogen-75- including hexyl, octylethyl, decylethyl, butyl, hydroxyethyldiethylaminoethyl And vinyl aryl, 2,4-diyl ester, trimethylvinyl ester, hexanoate, vinyl methoxyacetate, vinyl phenyl butyrate, vinyl laurate Base ester, and ethyl styrene naphthoate, dimethyl diethyl styrene, cyclohexyl styrene ethylene, trifluoromethyl methyl styrene) , methoxy-3-methylstyrene (for example, the size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7__ V. Invention description (p) (Please read the notes on the back first) Fill in this page) Styrene, Dichlorostyrene, Trichlorostyrene, Tetrastyrene Styrene, Pentachlorostyrene, Bromostyrene, Dibromostyrene, Iodostyrene, Fluorostyrene, Trifluorostyrene, 2 - bromo-4-trifluoromethylstyrene, and 4-fluoro-3-trifluoromethyl-styrene); crotonates such as alkyl crotonate (eg butyl crotonate, crotonic crotonate) • and monocrotonin); dialkyl itaconate (eg dimethyl itaconate, diethyl itaconate, and dibutyl itaconate); maleic acid or Dialkyl fumarate (e.g., dimethyl methacrylate and dibutyl fumarate); and (meth) acrylate. Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

It is also possible to use a homo- or co-polymer of hydroxystyrene or a phenolic resin of the phenolic resin type, such as poly(hydroxystyrene) and poly(hydroxystyrene-co-vinylcyclohexanyl)* phenolic resin, Phenolic phenolic resin, and halogenated phenolic phenolic resin. More particularly, it includes, for example, a methacrylic acid copolymer, an acrylic acid copolymer, an itaconic acid copolymer, a crotonic acid copolymer, a maleic anhydride copolymer such as K styrene as a comonomer, and a maleic acid. a diacid copolymer, and a partially esterified maleic acid copolymer, such as, for example, JP 5 9 -44615-B4 (the term "JP-B4" as used herein means reviewed Japanese Patent Notice), JP 5 4 - 3 4 3 2 7 -B4, JP 5 8 - 1 2 5 7 7-B4, and JP 54_ 2 5 9 5 7 - B4, JP 5 9 - 5 38 3 6 - A, JP 5 9 - 7 1 0 4 8-A, JP 60 - 1 5 9 7 4 3 - A, JP 6 0 - 2 5 8539 - A, JP 1 - 2 5 2 4 4 9 -A, JP 2 - 1 9 9 4 0 3 - A and JP 2 - 1 9 9 4 0 4 - A, and the copolymers can be further reacted with an amine, for example as disclosed in US 5,650, 263; China National Standard (CNS) A4 Specification (210 X 297 mm) 125〇378 Five Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Β7 Β7 Invention Description (γ) Even, fibers with carboxyl groups on the side sill can also be used. (meth)acrylic acid a copolymer of benzyl ester and (meth)acrylic acid, a benzyl (meth)acrylate, a copolymer of (meth)acrylic acid and other monomers, as disclosed in, for example, US 4,139,391, JP 59-44615-B4, JP 60-159743-A and JP 60-258539-A. In the case of having a carboxylic acid group in the above organic binder polymer, some or all of its carboxylic acid groups may be related to glycidyl (meth)acrylate or epoxy (meth)acrylate. The reaction thus gives a photopolymerizable organic binder polymer and is useful for improving the photosensitivity to the substrate, coating film strength, coating solvent and chemical resistance and adhesion. Examples are shown in JP 50-34443-B4 and JP 50-34444-B4, US 5153095, T. Kudo and his research colleagues in the Journal of Applied Physics (J. Appl. Phys.), Vol. 37 (1998), No. 3594 The weight average molecular weight of the binder of -3603, US 5677385, and 0S 5650233 is preferably from 500 to 1' 000 / 000, for example from 3' 000 to 00 〇 / 000, more preferably from 5' 000 to 400' 000. These compounds may be used singly or as a mixture of two or more kinds. The content of the binder in the photosensitive resin composition is preferably from 10 to 95% by weight, based on the total solids, more preferably from 15 to 90% by weight. As the compound (C), the color filter photoresist composition of the present invention additionally includes at least one compound which can be added with a polymerizable monomer. For example, the following compounds may be used alone or in combination with other monomers, and in the present invention -77- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note first) Fill in this page again. -1 line · 1250378 B7 V. Inventive Note (n) (Please read the note on the back side and fill out this page) It is an addition polymerizable monomer with an oxime and a double bond. In particular, they include (meth)propionic acid third base BS'l (meth)acrylic acid ethylene glycol, (meth)acrylic acid 2-hydroxypropyl ester, di(meth)acrylic acid triethyl Glycol ester trimethylol propyl tris(meth)acrylate, 2-ethyl-2-butane propylene glycol di(meth)acrylate, tris(methyl) propyl quinone pentaerythritol ester 'four (a) Pentaerythritol acrylate, dipentaerythritol hexa(meth)acrylate, dipentaerythritol penta(meth)acrylate, polyoxyethylated tris(methyl) propyl (meth)acrylate, Isocyanuric acid ginseng (2 - (meth) propylene oxiranyl ethyl ester), 1,4-diisopropenyl benzene, 1,4-dihydroxyphenyl (meth) acrylate, Ministry of Economic Affairs Intellectual Property Bureau Employees' consumption cooperatives print methylene glycol di(meth)acrylate, styrene, diallyl methacrylate, triallyl trimellitate, lauryl (meth)acrylate , (meth) acrylamide, and xylene bis(meth) acrylamide. Furthermore, a reaction product of a compound having a hydroxyl group and a diisocyanate may also be used; the compound having a hydroxyl group is, for example, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, and Mono(meth)acrylic acid polyglycolide, such as hexamethylene diisocyanate, tolyl diisocyanate, and xylyl diisofluoride. Particularly preferred are pentaerythritol tetraacrylate, dipentaerythritol hexaacrylate, dipentaerythritol pentaacrylate, and (2-methoxyethyl) isocyanurate. In the color filter photoresist composition, the total weight of the monomers contained in the photopolymerizable composition is preferably from 5 to -78 based on the total composition of the composition. The paper size is applicable to the Chinese National Standard (CNS). ) A4 size (210 X 297 mm) 1250378 A7 B7 V. Description of invention (7r) 80% by weight, especially 10 to 70% by weight. (Please read the notes on the back and fill out this page.) Moreover, the total solid composition of each color in a color film may contain an ionic impurity scavenger, such as an organic compound with an epoxy group. The concentration of the ionic impurity scavenger in the total solid composition generally ranges from 0♦1% by weight to 10% by weight. Examples of color filters, especially the combination of pigments and ionic impurity scavengers mentioned above, are shown in EP 32Q264. It is to be understood that the photoinitiators of the present invention, i.e., the compounds of Formulas I and II, can be substituted for the triazine starter compound in the color extinction tablet formulation described in EP 320264. The composition of the present invention may additionally comprise a K-acid-activated crosslinking agent, such as those described in JP 1 0 2 2 1 8 4 3-A, and a compound which can form an acid by thermal or actinic radiation. And the crosslinking reaction can be activated. Printed by the Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative The composition of the present invention may also comprise a latent pigment which can be converted to a finely divided pigment during heat treatment of a photosensitive pattern or coating comprising a latent pigment. These heat treatments can be carried out after exposure or after development of the photoimageable layer containing the latent pigment. Such latent pigments are soluble pigment precursors* which can be converted to insoluble pigments by chemical*thermal, photoinduced or radiant induced methods such as those described in U.S. Patent No. 5,879,985. The conversion of such latent pigments can be enhanced by the addition of a compound which forms an acid upon exposure to actinic light, or by the addition of an acidic compound to the composition. Thus, a color filter photoresist can be prepared which comprises a latent pigment in the composition of the present invention. After the substrate is coated, the solvent is usually removed by drying. -79- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1250378 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printing V. Invention The coating of the photoresist is left on the substrate. The light-sensitive composition of the present invention can be suitably used to form a color filter, but is not limited thereto, and can be used for other applications such as a recording substance, a photoresist, a display, a display element, a paint, and a printing ink. The light-sensitive composition of the present invention is also suitable for the manufacture of a sandwich or dielectric layer of a liquid crystal display, particularly a reflective type liquid crystal display, including an active matrix display having a thin film transistor (TFT) as an opening device. And passive matrix displays without switching devices. In recent years, the fatigue display has been widely used because of its small thickness and light weight, such as a pocket type TV* and a communication terminal device. Reflective liquid crystal displays that do not require backlighting are particularly desirable because of their ultra-thin and lightweight features, and which significantly reduce energy consumption. However, even if the backlight of the transmission type color liquid crystal display is now removed, and the light reflection plate has been applied to the lower surface of the display, it still causes a problem of low light utilization efficiency, and it is impossible to have actual The brightness of the application. In order to solve this problem, various reflective type liquid crystal displays have been proposed to improve light utilization efficiency. For example, a specific type of reflective liquid crystal display comprising a halogen element having a reflective function is provided. The reflective type of the microscopic display comprises an insulating substrate and an opposite substrate separated from the insulating substrate. The liquid crystal is filled between the two substrates. A gate is formed on the insulating substrate, and both the gate and the insulating substrate are coated with a gate insulating film. Then, a semiconductor layer is formed on the surface of the gate insulating film on the gate, and a source electrode and a drain current are also formed on the gate insulating film. (Please read the back of the front first. Please fill out this page again. « . -1 Line - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 ^____ Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Β7 Β7 Invention Description (γ A drain electrode contacts the semiconductor layer. The source electrode, the bleeder electrode, the semiconductor layer, and the gate are matched to each other to form a bottom gate type T F T opening device. An intermediate insulating layer is formed to cover the source electrode, the drain electrode, the semiconductor layer, and the gate insulating film. A contact hole is formed by the bleeder electrode passing through the intermediate insulating film, and a Pixel electrode formed of aluminum is formed between the intermediate insulating film and the inner wall of the contact hole. The bleeder electrode of the T F T is finally in contact with the arsenic electrode via the intermediate insulating film. This intermediate insulating film is generally designed to have a rough surface through which a phase electrode serving as a reflecting plate can generate a large viewing angle. This reflective type liquid crystal display significantly enhances light use efficiency by using a phase electrode as a light reflecting plate. In the upper reflective type liquid crystal display, the intermediate insulating film can be designed by photolithography to have protrusions and recesses, and the surface roughness* must be up to the micron level when forming and controlling the shape of the protrusions and recesses. In order to form contact holes, photolithography with positive and negative photoresist must be used. The composition of the present invention is particularly suitable for use in the photoresist 0. The light-sensitive composition of the present invention can be further used in the manufacture of spacers, and K controls the cell gap in the fatigued portion of the fatigued display panel because The nature of light transmission or reflection through the fatigue layer in liquid crystal displays is related to this cell gap, so thickness accuracy and uniformity on the pixel array are critical parameters for the performance of the liquid crystal display cell. In a liquid crystal cell, the spacing of the substrate is determined by the sparse dispersion of glass or polymer spheres having a diameter of about several micrometers as a separator* to maintain the substrate fixed distance. Therefore, the -81- paper scale is applicable to the Chinese national standard (CNS). )A4 size (210 X 297 mm) (Please read the note on the back and fill out this page) —Book · Line. 125〇378 A7 r^_ B7 $, Invention description (7Υ) (Please read the back Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing agent is fixed between the substrates to maintain the fixed distance of the substrate, which is determined by the diameter of the μ separator, and the spacer ensures the minimum between the substrates. The separation distance, that is, it prevents the distance between the substrates from decreasing. However, it does not prevent the substrates from being separated from each other, i.e., the distance between the substrates is increased. In addition, the method of using the dividing ball has the problem that the diameter of the dividing ball is not uniform, so it is difficult to uniformly disperse the dividing balls onto the substrate, so that the brightness is not caused according to the difference in the area of the spacer on the phase array. Uniform tendency and reduced brightness, and / or create a light gap. Recently, liquid crystal displays having a large area image display have been attracting more and more attention. However, an increase in the area of liquid crystal cells generally causes distortion of a substrate constituting a cell, and the structure of the liquid crystal layer is destroyed due to deformation of the substrate, and therefore, even if separation is used The agent maintains a fixed distance between the substrates, and a liquid crystal display having a large display area is still not feasible due to such interference. A method of forming a column as a separator between cells to replace the dispersion of the above-mentioned separator ball has been proposed. In this method, a resin column is formed in the region between the phase array and the opposite electrode as a separator to form a predetermined cell gap. For example, a photo-sensitive substance having an adhesive property is generally used in a method of producing a color filter for a lithograph. This method is easier to control at the separator position, number and height points compared to the traditional method of using a split ball. In a color-depressed display panel, the spacer is formed under a black matrix of a color filter element which is not developed, and therefore, a spacer formed using the light-sensitive composition does not reduce brightness and form a light gap. A light-sensitive composition having a separator protective layer for the production of a color filter is described in J Ρ 2000 — 8 1 70 1 — A, and the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1250378 A7 ____B7_ V. INSTRUCTIONS (Μ) (Please read the notes on the back and fill out this page.) Dry film photoresists for spacer materials are also described in JP 1 1 — 1 74 459 — A and JP1 1 — 174464 — A. As described in these documents, the light-sensitive composition, liquid and dry film photoresists include at least a base or acid soluble binder polymer, a reactive group polymerizable monomer, and a reactive group initiator. In some cases, thermally crosslinkable components, such as cycloaliphatic and carboxylic acids, may also be additionally included. The step of forming the separator using the light-sensitive composition is as follows: 陁 using a light-sensitive composition onto the substrate, such as a color filter, and after pre-baking the substrate, exposing through a reticle, and then the substrate is in an imaging agent The medium is imaged and patterned, and the desired separator is formed. When the composition contains some thermosetting components, it is usually subjected to a post-baking step to thermally harden the composition. The photohardenable composition of the present invention is highly sensitive and is therefore suitable for use in the manufacture of separators for the fatigue display (as described above). Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives The light-sensitive composition of the present invention is also suitable for use in the manufacture of arrays of microscopes Uicrolen for liquid crystal display panels, imaging sensors and the like. The microscope is a microscopic passive optical component that is attached to an active optoelectronic device such as a detector, display, and light-emitting device (transversal and vertical cavity lasers) M to improve its optical input. And output quality. It has a wide range of applications, including messaging technology technology, audio and video services, solar cells, detectors, solid state light sources and optical connectors. Modern optical systems use a variety of techniques, K effective coupling microscope and Micro-optical device. The microscope array is the phase element region used to condense the non-emissive display device (picture element -83- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 ____B7____ V. Description of invention (P)

(Please read the note on the back and then fill in the J regions of the page), like the phase element area of the fatigue display device to increase the brightness of the display, or to condense the incident light, or to form a device for use in, for example, a fax machine or A device similar to the image on the photoelectric conversion area of a line image sensor (ph 〇t 〇e 1 ectricc 〇nversi ο II regi 〇n), M improves the sensitivity of these devices, and is used to form a Printed on an image of a light sensitive device used in a fatigue meter or a light-emitting diode (LED) printer. The most common application is for improving the efficiency of solid-state image sensing devices like photo-coupled devices (C C D ) photodetection arrays. In a detection array, it is necessary to collect as much light as possible in each detector element or phase. If a microscope sheet is placed over each phase, the lens collects incident light* and focuses the focus on the active area (the size of this active area is less than the size of the lens). According to the prior art, a microscope sheet can be manufactured by various methods: (1) A method of manufacturing a convex lens in which a lens pattern of a flat plate configuration, a conventional photolithography or the like is drawn on a thermoplastic wax, and then the resin is heated. It is higher than the softening temperature of the resin to make it fluid, so that the edge of the pattern causes a sag (so-called 7 reflow / printed by the Ministry of Economic Affairs, Intellectual Property Bureau employee consumption cooperative) (see JP 60-38989-A) , JP 60-165623-A, JP 6 1 - 6 7 0 0 3 -A, and JP 2 0 0 0 - 3 9 5 0 3 -A). In this method, when the resin used is light sensitive, the pattern of the lens can be obtained by exposing the resin to the light source. (2) A method of forming a plastic or glass using a mold or a molding machine. As the lens material, a photohardenable resin and a thermosetting resin can be used in this method (see, for example, WO 99/38035). -8 4 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (w) (3) A light-sensitive resin has a desired pattern, and when an aligner is used to expose the light source, the unreacted monomer moves from the unexposed area to the exposed area, resulting in a method of expanding the exposed area to form a convex lens (see, for example, Journal of the Research). Group in Microoptics Japanese Society of Applied Physics, Colloquium in Optics, Vol. 5, No. 2, pp. 1 1 8- 1 2 3 ( 1 987 ) and Vo1, 6, No. 2, pp_ 8 7 - 9 2 ( 1 988)). Forming a light-sensitive resin on the upper surface of a supporting substrate, and then using different shadow masks, the upper surface of the light-sensitive resin layer is illuminated by a mercury lamp or a lamp-like light source, so that the light-sensitive resin layer is exposed to the light source, and as a result, The exposed region of the light-sensitive resin layer is expanded into the shape of a convex lens to form a photocondensable layer having a plurality of microscope sheets. (4) A method of manufacturing a convex lens * One of the light-sensitive resins is exposed to a light source by a proximity exposure technique in which the mask is not in contact with the resin, so that the edge of the pattern is blurred, so that the amount of the photochemical reaction product is It is distributed according to the degree of blurring of the edge of the pattern (see, for example, JP 61-153602-A). (5) A method for producing a lens effect, wherein a light-sensitive resin is exposed by a particularly densely distributed light source such that a distribution pattern of a refractive index is formed according to optical density (see, for example, JP 6 0 - 7 2 9 2 7 - A and JP 6 0 - 1 6 6 94 6 - A ) 0 The photosensitive composition of the present invention can be used in any of the above methods to form an array of microscope sheets using a photohardenable resin composition. There is a special technique focused on thermoplastic resin, like a photoresist on the shape -85- (please read the back note first and then fill out this page) Released • Line - This paper scale applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 1250378 Α7 Β7 V. Description of the invention (γ) A microscope, one of which is a reference documented by Popovic et al., SPIE 898, PP23-25 (1988). This technique, also known as re-flowing technology, includes defining a lens' footprint on a thermoplastic resin, such as a lithographic print on a photo-sensitive resin like a photoresist, and then heating the material to its reflow temperature. Step above. The surface tension causes the island of photoresist to be drawn into a spherical cap, the volume of which is equal to the original island before the flow. The cover is a flat plate and a convex lens. The advantages of this technique are simplicity, reworkability, and direct integration into the illuminating or light-detecting optoelectronic components. In some cases, a cover layer is formed on the patterned lens unit that is square before reflow to prevent the resin island from slacking in the middle and no longer flow into a spherical cap during the reflow step. The cover layer is a permanent protective layer which is also formed from a light sensitive composition. The microscope array can also be fabricated using a mold or a compression molding machine as described in EP-932256. A method for manufacturing a flat-panel microscope array is as follows: a molding agent is coated on a molding surface with a release agent having a dense arrangement of protrusions, followed by a photohardenable synthetic resin having a high refractive index. The molding surface is fixed, and then the glass substrate is pressed onto the synthetic resin material, thereby dispersing the synthetic resin material, and then the synthetic resin material is hardened by ultraviolet rays or heat, so that a convex microlens can be formed, and then the molding machine can be peeled off. Then, a light-hardenable synthetic resin material having a low praying index is additionally applied to the convex microlens as an adhesive layer, and then a glass substrate as a cover glass plate is extruded onto the synthetic resin material, and ~ 8 6 ~ This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back and fill out this page). i.···························· Printed 1250378

Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives Printed Jade, Invention Description (h) Disperse this resin material. This synthetic resin material is then hardened, and finally a flat-plate shaped microlens is formed. As disclosed in U.S. Patent 5,969,867, a similar method using a mold can be used to fabricate a three-layer laminate which is part of the backlight element of a color liquid crystal display panel. A three-layer laminate forming a three-column array is fixed to the light-emitting surface of the backlight. In order to manufacture a three-mirror layer, an active energy radiation hardenable composition is poured and dispersed in a lens mold formed of metal, glass or resin to form a three-row lens shape, followed by a transparent substrate. Placed thereon, and then an active energy radiation from the active energy radiation-emitting source is hardened by exposure through the laminate. The resulting lens is then peeled off from the lens mold to obtain a lens laminate. The active energy radiation hardenable composition used to form this lens region must have a variety of properties, including adhesion to a transparent substrate, and suitable optical properties. In the prior art, lenses having at least some photoresist were not suitable for some applications due to poor optical transparency at the blue terminal of the spectrum. Since the photohardenable composition of the present invention has low yellowing properties, including heat and photochemistry, it is suitable for use in the manufacture of a microlens array as described above. This novel radiation-sensitive composition is also suitable for the light-lithographic step of the plasma display panel (PD Ρ ) manufacturing method, particularly the barrier rib formation method, the phosphor layer and the electrode. PDP is a flat panel display that displays images and information via gas discharge. According to the structure and operation method of the display panel, it can be divided into two categories, -8 7 - This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297). () Please read the notes on the back and fill out this page.) Order: • Line. 1250378 A7 _B7_ V. Invention description (outside) This is the DC (DC) type and AC (Alternating Current) type. The principle of the D C type color PDP will be exemplified in the following. In a DC type color PDP, the interval between two transparent substrates (generally glass plates) is divided into a plurality of cells by a latticed barrier rib interposed between the transparent substrates, and sealed in each of the cells. A discharge gas such as He or X e. On the back wall of each cell, there is a phosphor layer that generates three main colors of visible light when excited by the ultraviolet light generated by the discharge of the xenon discharge gas. On the inner faces of the two substrates, the electrodes are placed opposite each other in each of the cells. Generally, the cathode is formed of a film of a transparent conductive material like NE SA glass. When a high pressure is applied between the electrodes formed by the front wall and the back wall, the discharge gas sealed in each of the cells induces a plasma discharge, and the ultraviolet light is irradiated, thereby stimulating the red, blue, and green color of the fluorescent light. Elements that make the image appear. In a full-color display system, the Intellectual Property Office of the Ministry of Economic Affairs printed by the Consumer Cooperatives (please read the notes on the back and fill out this page) • Line 'Three kinds of top, red, blue and green colored fluorescent elements together An image element. In a DC type PDP, the cells are separated by a lattice-blocking rib element, whereas in an AC-type PDP, the cells are separated by barrier ribs parallel to each other, in either case, the cells are obstructed by the barrier ribs. Separated. The purpose of these barrier ribs is to define the illuminating discharge in a fixed area, to eliminate incorrect discharge, or mutual interference of adjacent discharge cells, and to ensure an ideal display effect. The composition of the present invention is also directed to a light-sensitive thermosetting resin composition, and a method of forming a solder resist using the composition, and more particularly to a precision manufacturing method for manufacturing a printed circuit board, metal object, -88- Paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7___— V. Invention description (bamboo) Corrosion of glass and stone objects, relief of plastic objects, and novel light for preparation of printed boards a sensitive thermosetting resin composition, particularly as a solder resist for a printed circuit board, and via a selective bismuth-based actinic radiation, exposing a layer of resin composition through a patterned mask, and developing an unexposed area The step forms a method of soldering the impedance pattern. The soldering group resist is a material for soldering a specific portion to a printed circuit board to prevent the molten solder from adhering to an unrelated portion while protecting the circuit, and therefore, it must have a high adhesion. Insulation resistance, soldering temperature resistance, solvent resistance, alkaline resistance, acid resistance, and plating resistance. Accordingly, the subject matter of the present invention is directed to a solder resist comprising one of the above compositions. It is preferred to use a composition comprising the thermosetting member as a component of the present invention in an image forming process, such as a process for preparing a solder mask, wherein (1) mixing the components of the above composition, (2) The resulting composition is applied to the substrate (coating of the substrate), (3) if the solvent is present, it is evaporated at a high temperature* as in the case of 80-900 °C, (4) the coated substrate, According to the shape of the pattern, it is exposed to an electromagnetic radiation through a negative mask (so that the reaction of the acrylate is initiated), (5) the irradiated sample is developed, washed with an alkaline aqueous solution, and thus the unhardened is removed. Area, and -89- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back and fill out this page) i. - Line · Ministry of Economic Affairs Intellectual Property Bureau employees Consumer Cooperatives Printed 1250378 A7 B7 V. Invention Description (Pak) (6) Thermosetting samples, such as hardening at about 15 Ο. This method is another subject of the present invention. The heating step (6) is usually carried out at a temperature of > 10 Torr and < 20 Torr, preferably between 1 30 and 1 70 Torr, such as at 1 50 Torr. The present invention is described in more detail by way of example only, and the parts and percentages are by weight in the remainder of the description and in the claims. Wherein the alkyl group has more than 3 carbon atoms and does not indicate any particular isomer, in each case refers to a normal-isomer. Example 1: Synthesis of 2,5-dimethoxybenzaldehyde oxime-acetate In the formula (I): Ari = (Please read the back note first and then fill out this page) -traJ.

--Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed R 1 = C 0 C Η 3 1·3.·2,5-Dimethoxybenzaldehyde 肟 at a 16.6 g (99·9奄莫Ear) 2,5-Dimethoxybenzaldehyde is dissolved in the leaven of ethyl acetate (100 ml) and contains 7·64 g (169 奄mol) Η2Ν0Η — HC1 and 13 · 9 g (169 mmol) ) Naphthalate is dissolved in 50 ml Hz 0 -90- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Invention Description (η)

mixture. The mixture was heated to reflux temperature for 2 ♦ 5 hours. After the precipitated inorganic salt was dissolved by adding Hz 0, the ethanol was removed by evaporation under vacuum. The resulting white solid was filtered off, and Μ Η 20 0 washed. 1 4 · 9 g of white solid (82%) was obtained. iH NMR (CDCls) δ [ppm] : 3*79 (s, 3H) , 3*82(s, 3H ) , 6, 85 (d, lH) , 6, 92 (d, lH), 7*25 ( d,lH) ,8-00ls,lH), 8 ♦ 4 7 ( s,1 H ) 〇1 ♦ b ♦ 2,5-dimethoxybenzaldehyde 肟0-acetate 2*00 g (11 2,5-dimethoxybenzaldehyde oxime and 1 · 13 g (14 · 3 mmol) of acetamidine chloride were dissolved in 15 ml of tetrahydrofuran (THF). To this solution was slowly added 1 ♦ 67 g (16 · 5 mmol) of triethylamine (at ice bath temperature). After complete addition, the reaction mixture was stirred at room temperature for 3 hours, then water was added to dissolve the resulting white solid. The crude product was extracted with ethyl acetate. The organic layer was washed with saturated aqueous NaHCI 3 and then brine and then brine and then dried and then dried. Ethyl ester-hexane (1:4) gave 2 ♦ 03 g of a white solid, m.p. 55 - 57 °C (83%). The structure is consistent with the 1 H NMR spectrum (CDC13): δ [ppm] : 2 · 2 3 (s, 3H) , 3·81 (s, 3 Η), 3*83 (s, 3H), 6*87 (d ,lH) ,7,01 (dd,lH) ,7·47 (d,lH), -91~ This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back) Note: Please fill out this page again) | Order: -- Line _ Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 A7 _B7_ V. Invention description (shirt) 8 · 7 5 ( s, 1 Η ) 〇 Example 2 — 3〇 The compound of Example 2-30 was prepared according to the method of Example 1, from the relative aldehyde compound. The compound and its 1H NMR data are found in I 褰1. Table 1: Example 2 Structure (Please read the notes on the back and fill out this page)

丨定: .线 - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp [ C] 9 9-101 iH — NMR, 3 [pr> m] 2.27 (s , 3H) , 4 . 05 (s , 3H ), 6 · 84 ( d,1 Η ) , 7 · 54 (t,1 Η), 7.65(t, 1H), 7.81(d, 1H), 8.33(d, 1H), 8.64(d, 1H), 8 · 85 (s , 1H). This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 1250378 A7 _B7 V. Invention Description (吖) Structure

(Please read the notes on the back and fill out this page) Status / mp [ °C] Colorless liquid 1H~NMR, 5 Cppm] 2.23 (s , 3H) , 3.39(s, 3H), 3.94(s,3H), 6.88(d, 1H), 7.14 (d, 1H), TN39(s, 3H), 8.23(s, 1H). Example 4 structure

Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp C t:] Colorless Liquid-93- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _B7 V. Invention Description (^ ) Η ~ NMR > δ [ppm] 2.22 (s , 3H), 3. 85 ( s , 3H ), 6 · 93 ( d, 2H), 7 · 69 ( d, 2H) , 8 . 30 ( s , 1H) 〇

Example construction M 5 o: 〇

4 ] oms 1 p3( o p . [ 6 ] δ , V , fl) c R 3 p M , mNis 7 0 1 (please read the notes on the back and fill out this page) — order · line.

H 4 8

H 9 o d Η 6 3

H 8

H Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing case structure

C—〇 H /, 〆 , 〇 Nnc

CH -94- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Invention description ()丨) Status / mp CX:] Colorless fatigue i+r-NMR,^ [ppm] 2.22 (s, 3H), 3.87 (s, 3H), 6.92 (d, 1H), 6.98 (dd, 1H), 7.43 (dd, llO, 7.97 (d, 1H), 8.77 (s, lH) 〇Example 7 structure (please read the notes on the back and fill out this page)

Line Economy Ministry Intellectual Property Bureau Staff Consumer Cooperative Printed Status / m P [ °C] Colorless Liquid 1 Η ~ NMR » δ [ppm] 2.24 (s, 3H) , 7,38-7 · 52 (m, 3H) , 7.74 (d , 2H), 8·36 (s, 1H). -95- This paper size is applicable to China National Standard (CNS) A4 specification mo X 297 mm) 1250378 V. Invention description () Example 8 Structure A7 B7 〇, cXH3 .0 CH3

(Please read the notes on the back and fill out this page) Status / mp 〔t?] 54 — 56 1 Η - NMR, δ [ppm] 2.25(s, 3H) , 2.47(s, 3H), 7.21 - 7.26( m , 7.36(dt,1H), 7.84U, 1H), 8,62(s,1Η)〇Example 9 Structure 2H) --- Line 'Ministry of Commerce, Intellectual Property Bureau, Staff Consumption Cooperative, Printed H3C, y

〇〇-9 6 - This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _B7_ V. Description of invention (&) State / mp [°C] 83 — 84 'H-NMR ^SCppm] 2 _ 3 0 ( s,3 H ) , 7 · 5 0 - 7 · 5 9 (in, 2 H ), 7 · 6 5 (t , 1 H ) , 7 · 9 1 ( d, 2H) , 7.98(d, 2H), 8.57(d, 1H), 8.99(s, 1H). S M 10 knots (please read the notes on the back and fill out this page). 传 3

5 H 2 X bo H , , \ , 〇N=c ·定· State / mp [tJ] 58 - 59 1H~ NMR»5 Cppm] 1 . 23 (t , 3H), 2.49(q,2H), 3.85 (s, 3H), 6.93(d, 2H), 7.68(d, 2H) , 8.30(s, 1H) 〇

97- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) | Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 A7 _B7 V. Invention Description (7乂) Status / mp [I ] 103 — 106 'H-NMR^SCppm] 2.21 (s, 3H) , 3.03(s, 6 Η ), 6 · 68 (d, 2 Η ), 7 · 59 ( d, 2Η), 8·23(s , 1Η). Example 12 Structure (Please read the notes on the back and fill out this page)

Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp [Ό] 76 - 77 1 H-NMR, δ [ppm] 2.30 (s, 3H) , 4 . 00 (s , 3H), 7 · 28 ( d , 1 H ) , 7 · 40 (td , 1H) , 7.62 (td , 1H) , 7.78 (dd , 1H) , 7. 96 (d , 1H), - 98- This paper scale applies to China Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention (β) 9.04 (d, 1H), 9. 15 (s, 1H). Example construction

3 1X

〇, CH0 CIO H , / \ / 〇 nmc

CH n-CgHir〇" (Please read the notes on the back and fill out this page) t·· · Status / mp [t] 58 — 60 1 Η ~ NMR » δ [ppm] 〇. 88 (t , 3H) , 1.30 (ill, 8H), 1.46(tt, 2H), 1.86(tt, 2H), 2.22(s, 3H), 3.92(s, 3H), 4.05(t, 2H), 6.90(d, 1H), 7.11 (dd, 1H), 7.38 (d, 1H), 8.27 (s, 1H). • Line. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing example 14 structure n-C16H,

-99- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention state / mp [I] 81-84 4 NMR, 3 [ppm] β·ββ< 1, 3H) , 1. 26 (m, 24H) , 1. 5 0 ( m , 2H) , 1.86(tt, 2H), 2.22(s, 3H), 3.92(s, 3H), 4.05(t, 2H ), 6.87(d, 1H), 7.11(dd, 1H), 7.38(d, 1H), 8.24(s, lH)〇Example 15 Structure〇, cxh3 (Please read the back note and fill out this page) Petal · Order -- H0 (CH2CH20),

CK - Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp [t] 59 - 89 1 H - NMR, δ [ppm] 2.22 (s , 3H) , 2 . 65 (br , 1 H ), 3 · 69 ( m,2H),3·76 ( br, 2H), 3.91(s, 3H), 3.93(t, 2H), 4.21(t, 2H), 6.90(d, 1H), 7.11(dd, 1H), 7.39(d, 1H), 8.27(s, 1H). -1 0 0 - This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention (H)

(Please read the notes on the back and fill out this page.) 雄· State / mp [C] 77 — 78 'H-NMR^Sfppm】 2.24 (s, 3H), 7.13(dd, 2H), 7.74(dd, 2H ), 8.34(s, 1H) 〇Example 17 Structure Bu Zhu··Line· Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed. CH,

〇XXC

, H 101- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _B7 V. Invention description (? teeth) Status / mp [1] 68 — 71 ^-NMR^SCppm) 0.89 (t , 3H) , 1.2 0 - 1 . 4 6 (m, 14H) , 1.81 (m, 2H), 2.24 (s, 3H), 4.01 (t, 2H), 6. 90 (d, 1H), 6.96 (t, 1H), i 7.il(td, 1H), 7.97(dd, 1H), 8.77(s, lH)〇Example 18 Structure (please read the notes on the back and fill out this page). , 指9 C2Hs\ 〇

Nnc

CIO

H

CH l·订· • Line. Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp C t:] Liquid 1 H - NMR, δ [ppm] 1.42(t, 3H) , 1.42(s, 18H) , 2 ·23 ( s, 3H), 3 · 76 ( q, 2H), 7 · 57 (s, 2H) , 8 · 29 (s, 1H) 〇 Example 19 Structure -102- This paper scale applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) 1250378 A7 B7 V. Description of invention)

State / mp C °C ] 77 - 79 1 Η - NMR ^ δ [ppm] 1.50(t, 3fl), 2.24(s, 3H), 4.13(q, 2H), 7.90(s, 2H), 8.21(s , 1H) 〇Example 2 0 Structure (please read the notes on the back and fill out this page) Order: 丨线_

Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp ( ^ ] Liquid 1Η~ NMRf5 [ppm] A 103- This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm) 1250378 A7 _B7 V. DESCRIPTION OF THE INVENTION (r.) Ο . 88 (t, 3H) , 1.2 0 - 1 .4 6 (η, 14H) , 1 · 79 ( m , 2H), 2.22(s, 3H) , 3.99 (t, 2H) , 6·92 ( dd, 2H ), 7 · 66 ( dd, 2H), 8 · 29 (s, 1H) 〇 2 cases

/c丨〇H (Please read the notes on the back and fill out this page) Order: Status / mp [m 6 2-63 1 H — NMR, δ [ppm] 1 · 2 1 (t, 3 H ), 2 · 2 2 ( s, 3 H ), 3 · 5 3 ( q, 2 H ), 3 · 6 1 (in, 2 H ), 3 · 7 3 (in, 2 H ), 3. 9 1 ( s , 3 H ) , 3 · 9 3 (t , 2 H ) , 4 · 2 4 (t, 2 H ), 6.92 (d, 1H), 7.11 (dd, 1H), 7.39 (d, 1H), 8.27 (s , 1H) 0 Example 2 2 Structure ~ 1 Ο 4 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) • Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1250378 A7 B7 V. Description of the invention (〖.丨)

State / mp [tn fatigue 1 H-NMR, δ [ppm] 2 . 07 (s , 3H) , 2.22 (s, 3H), 3 . 7 5 - 3 . 8 5 ( m , 2H), 3 · 85 -3 · 95 (πι, 5H), 4.20-4.30U, 4H), 6.92 (d, 1H), 7.12(dd, 1H), 7.39(d, 1H), 8.28(s, 1H). Example 2 3 Structure (Please read the notes on the back and fill out this page). Line. Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative c.L h3c, h2

O-ch3 H, C, State / mp [I] Liquid 'H-NMR^SCppm】 -105- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 Β7 V. Invention Description ((Q) 2 · 0 1 ( s , 6 H ), 1 · 9 9 U, 2 Η ) , 2 · 7 4 - 2 · 7 8 ( π , 6 Η ), 2 · 2 2 ( s, 3 Η) , 3 . 91 (s, 3Η), 4·08 - 4· 1 4 ( m,6 Η ) , 6·89(d,1 Η ), 7.12(dd, 1Η), 7.38(d, 1H), 8e27 (s, lH) 〇 instance 2 4 structure

(Please read the notes on the back and fill out this page) -trOJ·. Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Status / mp CV ] Liquid 1 H-NMR, 3 [ppm] 2 · 0 5 U , 2 H ), 2 · 2 2 ( s, 3 H ) , 2 · 4 8 (in, 4 H ), 2 · 5 4 (t, 2 H ), 3.72 (dd, 4H), 3.91 (s, 3H), 4.13 (t, 2H), 6,90(d, 1H), 7 · 1 2 ( dd, 1 H ) , 7 · 3 9 ( d, 1 H ), 8 · 2 7 ( s , 1 H ). Example 2 5 Structure Π*^1〇^2Ϊ\

, ch3 -106- The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) • Line · 1250378 A7 B7 V. Invention Description Prison / in p 〔 t] 6 6-69 1 Η - NMR , δ [ppm] 〇.88(t, 3H), 1.2 0 - 1.4 0 (m, 12H) , 1 · 46 (sister, 2H), 1.86(ni, 2H), 2.22(s, 3H), 3.92( s, 3H), 4.05(t, 2H), 6.87{d, 1H), 7.11(dd, 1H), 7.38(d, 1H), 8,27(s, 1H) Example 2 6 Structure (please read the back first) Note: Please fill out this page again; Line _ Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed rvC, 2H25\

Oh,

〇^c^H3 I /〇N II state / mp [ °C] 7 1 7 3 -107- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 _B7 V. Description of invention (/^) 0 . 88 (t , 3H) , 1 . 2 0 - 1 . 5 0 (m , 18H), 1 . 8 6 (πι , 2 Η ), 2.22(s, 3Η), 3.92(s, 3Η), 4.05(t, 2H), 6.87(d, 1H), 7.12(d, 1H), 7.38(d, 1H), 8.27(s, lH)〇

Example 2 7 MM Η]. , 〆〇 (Please read the notes on the back and fill out this page)

l·订· State / mp [υ] 93 — 95 1 H - NMR, δ [ppm] 2.21(s, 3Η), 3.85(s, 6H), 6·44 ( s,1 Η ),6 · 52 ( Dd, 1H), 7.92(d, 1H), 8.68(s, 1H). Line. Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

-108 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7

5. Description of the invention (rO state / mp [Ό] 114 - 119 1 Η - NMR ^ δ [ppm] 2.25(s, 6H), 7.52(t, 1H), 7.89(dd, 2H), 8.06(dd, 1H ), 8.34(s, 2H) 〇Example 2 9 Structure (please read the notes on the back and fill out this page)

-丨线' Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing status / mp [t] liquid 1 H - NMR, δ [ppm] 2.22 (s, 3H), 6.53 (dd, 1H), 6 · 93 (d, 1 H ) , 7·28 ( d, 1H) , 8 . 22 (s, 1H) 〇-109- This paper size applies _ National Standard (CNS) A4 size (210 x 297 mm) 1250378 A7 B7 V. DESCRIPTION OF THE INVENTION (/4) Example 3 0 Structure C'H, o=c' \ 〇 /

(Please read the notes on the back and fill out this page.) 麟· State / mp 〔υ〕 10 6-111 1 Η - NMR, δ [ppm] 2.29(s, 3H), 7.28(a, 2H), 7 · 42 ( dd,1 H ) , 7 · 54 ( d, 1H), 8.14 (dd, 1H), 8.54 (s, 1H), 8.67 (br s, lH) 使用 The following light sensitivities were used in Examples 3 1 and 32 Agent: S—1 2—Isopropylthiosan ton _ and 4 isopropyl thioxanthene oxime mixture (RTM QUANTACURE, by

Provided by International Biosynthetics) S_2 4,4'-bis(diethylamino)benzoquinone (M ich 1 e r_ ) Example 3 1 Preparation of a photohardenable formulation by mixing the following composition -no - The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). ·- • Line. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1250378 A7 B7 V. Invention description ((called) Use: 2 〇0 ♦ 0 parts by weight of acrylated propylene-based copolymer (RTMACA200M, supplied by Daice 1 Industries) 1 5,0 parts by weight of dipentaerythritol hexaacrylate ((DPHA), supplied by UCB Chemicals) 1 0 0 · 0 parts by weight of acetone in the mixture, add 0 · 5% (according to the solid content) of the light sensitive agent and 2% (calculated according to the solid content) of the initiator, and stir to mix evenly. The operation was carried out under yellow light and the formulation was applied to an aluminum plate. The solvent was removed by heating in a conventional oven at 8 03⁄4 for 15 minutes. The thickness of the dried film was 25 microns. Acetic acid A film on which a standardized test with a different optical density (Stouffer step wedge) of 21 steps was placed. Sample K was covered with a second layer of UV transparent film and pressed onto the metal plate by vacuum. ^Metal halide lamp (01{(:,3«$3 0 0 0 model) at 60 cm distance, 40 seconds in the first test series, 80 seconds in the second series, and in the third series After 1 60 seconds, after exposure, the cover film and the reticle were removed and the exposed film was developed at 1300 C using a spray type developer (Walter Lefflnien, model T21) using a 1% aqueous solution of sodium carbonate for 180 seconds. The sensitivity of the initiator system is indicated by the maximum number of steps that can be maintained after development (i.e., by polymerization). The higher the number of steps, the more sensitive the system under test. The results are shown in Table 2. Table 2: -111- The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page). Book • Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250378 Ministry of Economic Affairs Intellectual Property Bureau staff consumption Co., Ltd. Printed A7 B7 V. Inventive Note (/4) Example Photoinitiator Sensitive Agent Repeated number of steps after exposure time 40 seconds 8 0 seconds 1 6 0 seconds 1 -- 10 12 14 1 S-1 11 13 15 2 S-1 11 13 15 3 S-1 10 13 14 4 S-1 9 12 14 5 S-1 10 12 14 6 S-1 9 11 13 7 S-1 8 10 12 8 S-1 8 10 12 12 — 9 11 13 12 S-1 11 13 15 13 S-1 11 13 15 14 S-1 10 13 14 15 S-1 10 12 14 17 S-1 10 12 14 18 S-1 9 11 13 19 S -1 9 11 13 2 1 S- 1 10 12 14 22 S- 1 9 11 13 •112 - (Please read the notes on the back and fill out this page) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A7 B7 V. Description of invention (β) 23 S-1 9 11 13 24 S-1 9 11 13 25 S-1 11 13 15 26 S-1 10 12 14 27 S-1 10 13 15 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Example 3 2 Preparation of poly(benzyl methacrylate-co-methacrylic acid) 24 g of benzyl methacrylate, 6 g of methacrylic acid and 0 · 525 g of azo diiso Butyronitrile (ΑΙΒΝ) is dissolved in 90 ml of propylene glycol 1 2- ether acetate (PGMEA). The resulting reaction mixture was placed in an oil bath preheated at 80 t:. After stirring at 803⁄4 for 5 hours, the resulting viscous solution was cooled to room temperature without further purification. The solids content is about 25 %. A photocurable composition is prepared by the following composition: · 240·0 parts of a heavy copolymer of benzyl methacrylate and methacrylic acid (benzyl methacrylate: methacrylic acid = 80: 20 (by weight), 25% propylene glycol 1-monomethyl ether 2-acetate (PGMEA) solution (prepared by the above method); 40 · 0 part by weight of dipentaerythritol hexaacrylate (DPHA), by UCB C he Provided by ia ica 1 s, - 113- (please read the notes on the back and fill out this page). · - Line · This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) A7 B7 1250378 5. Description of the invention (</〇) 2 ♦ part by weight of the photoinitiator, 1 · 2 parts by weight of the light sensitive agent, and

1 2 〇 · 0 parts by weight of PGMEA All operating systems are carried out under yellow light. The composition was applied to an aluminum plate using an electronic applicator having a wire wrap bar. The solvent was removed by heating in a conventional oven at 1 Ο 0P for 2 minutes. The dried film has a thickness of about 2 microns. A standardized test negative phase with a different optical density (Stouffer step wedge) of 21 steps was placed thereon, the gap between the film and the photoresist was about 100 μm, and the exposure system used a 250 W ultrahigh pressure mercury lamp (USHIO, USH-250BY) is carried out at a distance of 15 cm. The total exposure of the negative film in this test was measured by an optical dynamometer (ORC UV light, Mode·UV-M02 with UV-35 detector) and was 500 mJ / cm 1 2 . After exposure, the film was developed with a spray type developer (Walter Leinmen » Model T21) using a 1% aqueous sodium carbonate solution at 100 Torr for 100 seconds. The sensitivity of the initiator system used is indicated by the highest number of remaining steps (e.g., after polymerization) after development, and the greater the number of steps, the more sensitive the test system is. The results are shown in Table 3. Table 3 Example of photoinitiator photosensitizer 5 0 01J/cm 2 Number of regeneration steps after exposure (please read the note on the back and fill out this page) Bid: _ Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printing 1 - 10 -1 1 4 - 2 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 _B7 V. Invention Description (Ml) 12233445566 011223 5 67899 1i 1X IX ix lx ix 1i ix ix 1M 1x 1x 20201910391091000 1 11 1 1 1 1 1 1 1 1 1i 1 1 1 9 9 9 0 9 9 (Please read the note on the back and fill out this page) -装·丨订· •Line · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (β) 20 S -1 9 20 S-2 10 21 S-2 10 23 S-2 10 24 S- 1 9 24 S-2 10 25 S-2 9 26 S-2 9 27 S-1 10 27 S-2 11 28 S&gt ;2 9 30 S-2 10 -116- ----------------- (Please read the note on the back and fill out this page) 丨定: This paper size is suitable Chinese National Standard (CNS) A4 size (210 X 297 mm)

Claims (1)

1250378 A8 B8 C8 D8 The scope of the patent application or the phenyl and naphthyl groups are substituted by 〇R 3,SR 4 or NR 5 R 6 wherein the substituent 〇R3, SR4*NR5R6 via R3, R4, R5 and/or only 6 substituents and other substituents on the phenyl or naphthyl group, or a 5- or 6-membered ring selectively formed with a carbon atom on the phenyl or naphthyl ring; or A r ; l is a furanyl group , pyrrolyl, thiol, benzofuranyl, fluorenyl, benzothiophenyl or pyridyl, if R: is ethyl thiol, then furyl, pyrrolyl, thiol, benzofuran Base, fluorenyl, benzothiophenyl or pyridyl is unsubstituted or consists of halogen, C丄—C 20 alkyl, benzyl, C 1 —C 20 alkenyl, or C 3 — C 8 a cycloalkyl group substituted 1 to 4 times; or the furyl group, [ftyl, thiol, benzofuranyl, fluorene D, benzothiophenyl or Hu-based is via phenyl or benzamidine Substituted; or the furyl, succinyl, thiol, benzofuranyl, phenylthiophenyl or pyridyl group is substituted by a C 2 -C i 2 alkoxycarbonyl group; or the furan Base, 卩 略 基, 噻a benzofuranyl group, a benzyl group, a benzothiophenyl group or a pyridyl group, which is substituted by a phenoxycarbonyl group, 〇R3, SR4, S〇R4, S〇2R4 or NR5R6; (Please read the notes on the back and write this page first.) The age of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210 χ &amp; 97 mm) 1250378 - C8 D8 VI. Patent application scope (please read first) Note on the back side of this page) Each of which is selectively halogenated, C1-C i 2 alkyl, substituted with benzyl for 1 to 4 times; phenyl, which is unsubstituted or consists of one Or a plurality of 〇r3, s r4*n R 5 R 6 substituted; benzhydryl, which is unsubstituted or substituted by one or more hydrazines R 3 , SR 4 or NR 5 R 6 ; Ci — (: 12 alkanes A thiol group; a C2-C12 alkoxy ore group optionally interrupted by one or more ones, and/or selectively substituted by one or more hydrazines; Μ2 is a direct bond, a 〇 One, one S -, one SS -, one NR3 -, one (C 〇) -, c "c12 hospital support, phenylene, - (c〇) 〇 - (c2 - CI2 hospital support) - 0 (CO) - — —CO ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( C4-C12 alkylene dioxy, each of which Selectively interrupted by 1 to 5 - S - and / or NR3 - m3 is a direct bond, a ch2 -, a 〇, a S -, an SS -, an nr3 paper scale for China National Standard (CNS) A4 Specification (210 x 3297 mm) 1250378 哉C8 D8 VI. Application for Patent Scope—or one (CO)—; (Please read the notes on the back and write this page first) R3 is hydrogen or (: Plant C20 alkyl; or Ruler 3 is (: 2-C丨2 alkyl, which is via OH, -SH, 〇(C〇)-C--C4 alkyl, 〇(C〇)-benzene Base, one (C〇)〇((^*—(^4院基)' One N (G-C4 yard base) 2, one N (CH2 CH2〇H) 2, one N[CH2CH2〇一(C〇 a C!-C4 alkyl]2 or a morphinyl substituted; or R3 is a C2-c12 fen, which is interrupted by one or more ones; or R3 is a (CH2CH2〇) n+iH, one (CH2CH2〇)n (CO) —c 1 —C 8 院基 'C 1 —C 8 fluorenyl, C 3 —C 1 2 alkenyl, C 3 —C 6 olefinic group; Or R 3 is a benzamidine group which is unsubstituted or via one or more C i -C 6 alkyl groups, halogen or C 1 -C 4 alkane Oxy-substituted; or R3 is phenyl, or naphthyl, each of which is unsubstituted, or via a halogen, C1 to C i 2 alkyl, C i - C 1 2 alkoxy 'phenoxy 'C 1 -C i 2 hospital based sulphide, phenyl sulphide, a N (C i -c12 alkyl) 2, diphenylamino or mono(C〇)R7 substituted; or R3 is benzene Base-C 1 -C 3 courtyard; η is 1 to 20; R 4 is hydrogen, C 1 -C 2 decyl, C 3 -C i 2 alkenyl, phenyl-C 1 -C 3 alkyl ; C 2 — C 8 alkyl, which is a 〇H, a SH, a 〇(C〇)-Ci—C4. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 $ 297 mm) 1250378 C8 D8 Sixth, the scope of application for patents • Institute base, one (C〇) monophenyl or one (C〇) 〇 (C 1 -C 4 alkyl) substituted; or R 4 is C 2 - C 1 2, It is interrupted by one or more 〇- or one S-; or R4 is a (CH2CH2〇)n + 1H, a (CH2CH2〇) n (C〇)-Cf C 8 yard base, c 2 — C 8 醯 ,, C 3 —C i 2 alkenyl, C 3 —C 6 olefinic group; or R 4 is phenyl or phenyl, which is not Substituted or substituted by halogen, Ci-C12 alkyl, 〇1 - (: 12 alkoxy or one (C〇) R7; R 5 and R 6 are mutually unrelated, respectively, hydrogen, C 1 - C 2 Q Dean, C 2 - C 4 hydroxy 院 ' C 2 - ci ◦ 氧基 oxy, phenyl - C 1 - C 3, C 1 - C 4 醯, C 3 - C i 2 ene Anthracenyl, benzhydryl; or phenyl or naphthyl, each of which is unsubstituted or substituted with C 1 -C: 2 alkyl or C 1 -C i 2 alkoxy; or R 5 And R 6 - is a C 2 - C 6 scrub which is selectively interrupted by one or one NR 3 , and/or a selective hydroxyl group, a C 1 -C 4 alkoxy group, C 2 -C 4 alkanoyloxy or benzhydryloxy substituted; R 7 is hydrogen 5 Cl - C 20 or a C 2 -C8 alkyl group, which is via halogen, phenyl, mono H,-SH,C3-C6-alkenyloxy, mono-(C〇)-C-C4-alkyl, monoterpene (CO)-phenyl or mono(C〇)〇 (Ci-C4 alkyl) Or R 7 is a C 2 — C i 2 courtyard base, which is interrupted by one or more ones; or only one (CH2CH2〇)η + ιΗ, One (CH2CH2〇)n (C This paper scale applies to China National Standard (CNS) A4 specification (210$297 mm) ........................ ...fr-i........t (please read the notes on the back and write this page first) 1250378 - C8 D8 VI. Application for patents 〇) A C 1 - C 8{ Indenyl 'C 3 —C i 2 dilute, the radical 'which is selective via one or more halogens, C i (: 12 valence, (: 1 a (: 12 alkoxy, phenoxy, 〇1-ci 2 alkylsulfanyl, phenylsulfanyl, a N (C 1 -C i 2 alkyl) 2, or diphenylamino substituted; and (C) 5 to 500 A photopolymerizable compound by weight. .2 · The photo-sensitive composition of claim 1 of the patent scope, in addition to the components (A), (B) and (C), additionally comprising 15 to 120 parts by weight of at least one light-sensitive compound (D) . 3 · The photo-sensitive composition of claim 1 of the patent scope, including other additives (E), which are selected from the group consisting of epoxy compounds, thermal polymerization inhibitors, inorganic chelating agents, dyes, epoxy hardeners, amines , chain transfer agents, thermal reactive based initiators, photoreducible dyes, optical brighteners, thickeners, anti-foaming agents and leveling agents, especially inorganic chelating agents. 4. A solder resist agent comprising a composition as in claim 1 of the patent application. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X $97 mm) ......................•Installation....... (Read first Precautions on the back side of this page) -έ 1250378 - C8 D8 一--- VI. Patent Application 5 · A color filter optical impedance agent, including a composition as claimed in the patent scope. 6. A method of photopolymerizing a compound containing an ethylenically unsaturated double bond, comprising irradiating electromagnetic radiation having a wavelength of from 150 to 60 〇 nm as in the composition of claim 1 of the patent scope. 7 ‘· A coated substrate having at least one side coated with a composition as claimed in claim 1 of the patent application. 8 · A color filter for providing red, green and blue (r GB) color elements, and optionally providing a black matrix, all on a transparent substrate as claimed in the first The light-sensitive composition of the item and a transparent electrode provided on the surface of the substrate or on the surface of the color filter layer. 9. A method of forming an image comprising: (1) mixing all components of the composition as claimed in claim 1 (2) applying the resulting composition to a substrate (please read the precautions on the back) Write this page) The national standard (CNS) A4 specification (210>&lt;7297 mm) ~ 1250378 i C8 D8 6. The scope of application (3) 4) illuminating the coated substrate according to the image, (5) illuminating the sample after exposure with an alkaline aqueous solution, removing the unhardened portion, and (6) thermally hardening the sample. —fl---------------------!·装---------------Book-------- -------- Line (please read the note on the back and write this page first) This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1250378 A8 B8 C8 D8 1^1 Patent Application No. 1 - An alkali-visible light-sensitive composition comprising: (A) at least one part by weight of an alkali-soluble adhesive resin, prepolymer or monomer component; (B) 0· 015 to 120 parts by weight of at least one compound of formula I or II, I 1 N —C—Η (I) Mr ? 一巳Ν ιι C—Η (II), (please read the notes on the back and fill out this page) Wherein R is a C 1 -C 2 O 2 alkyl group; or the rule i is a benzamidine group which is unsubstituted or substituted by one or more C 1 -C 6 moieties or halogens; or R 1 is a C 2 —C 1 2 alkoxy group; 2 0 A: The line A r 1 is a phenyl or naphthyl group, both of which are unsubstituted or halogen, C 3 -C alkyl, benzene Methyl, c1 -C 2 Q alkyl fluorenyl substituted 1 to 5 times; or the phenyl and naphthyl groups are substituted via phenyl or benzhydryl group, each of which Optionally substituted with one or more hydrazines R3, SR4 or NR5R6; or the phenyl and naphthyl groups are substituted via a C2-C: 2 alkoxycarbonyl group, this C2-C: 2 alkoxycarbonyl group is selected Sexually interrupted by one or more - and/or selectively substituted by one or more hydroxyl groups; This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)