1250180 玖、發明說明： 【發明所屬之技術領域】 本發明係首創-種將含有漠化環氧樹脂與坡璃纖維之廢棄品加 入 化鹽類及破璃纖維等工業原料的方 熔融的無機鹽類中，來熱裂解出漠 法及裝置者 【先前技術】 按’眾所週^ ’環氧樹脂是—種相當好用的填細，但其缺點是 易燃，故為二提高其耐燃性，目前均是將該環氧樹脂經過溴化處理來 取得耐燃性高的漠化環氧樹脂(dgetba)，且由於該漠化環氧樹脂亦具 «佳的_性及·與金屬_著力等特性，所以目_產業界經 常—溴化環氧樹脂作為接著劑’其除了用來與破璃纖維相黏合 以製成工_板外’ _亦被大猶職各_產品上，例如 做為電氣上的縣㈣、電路板、雌它特賴偶；惟，該含 有溴化環_旨的I龍職職赫，—頭驗雜，其結構 中可回收再觸使用的__，並餘以焚倾方式細收處理， 且右將贿棄品加熱至該坡璃_呈細狀態來回收時，則必需設置 可加熱至上千度。c以上的高溫設備方能達成，根本不符合經濟效益， 另若以驗解的方式來回收縣品中的義賴，其過程中該漠化環 氧樹脂又會產生嚴重污染誠倾_)，所以近年來對於含有漠 _氧樹I旨的工麵膠㈣其它產触絲^中，回收赫纖維根本 疋不可行的’其僅能任其肆意職，而此不僅誠Μ誠費，且該 廢棄如強_以分賴職更是祕纖的殺手。 1250180 【發明内容】 本發明之主要目的是利用熔融無機鹽可直接與溴反應的特性，將 該含有溴化環氧樹脂的廢棄品中放入熔融的無機鹽類，使其反應後可 產生安絲害的溴餘類(如溴錢），及可當燃料做域能回收的有機 氣體，同時又可裂解回收純淨的坡璃纖維，並供做為工業原料之再循 環使用者。 本發明之又-目的，是以溫度300t至500t的榕融無機鹽類即可 熱裂解出高純度的坡璃纖維，根本不需要使用具有加熱至上千度。c以 上的加熱設備，令整_收處理破__過程更為簡易及降低處理 之成本，並符合回收的經濟效益者。 本發明之另—目的，是在可完全燃燒設備裝置，得在該熘 融無機鹽__化環氧樹料，將職生之錢_完全燃燒後， 轉化成對_無害的水蒸氣及二餘碳者。 【實施方式】 、首先’請參閱第—圖所示，本發明「對含有溴化環氧樹脂及破璃 "'、、廢棄PP的處理錄」’其是將—含補化魏樹織坡璃纖維之 廢棄品H)投人至_的無機鹽聲使麵嶋鹽則直接與 漠化環氧樹脂中_產生反應，並對該廢棄品1G產生熱裂解，而造成 化環氧樹贿咖_财料自健生_，蠢得溴化 7 11、純淨的坡璃纖維12及有機氣體13 ;其中，該溴化鹽類U係 2境安全無害而可直接排放，誠淨的__關可供做為工業 、5再循環使用’該有機氣體13係使用-完全燃燒設備裝置，將其 1250180 完全燃燒_傾_難額水絲131及二氧倾132 ; 、，本發明中之無機鹽20係可為硝酸鉀、或硝酸敍、或亞硝酸納、或 _納’或上述讎以上之混合物，而主要成分係為強氧化劑硝酸系 列，可以符合溴化環氧樹脂裂解溫度在3 〇 〇〜6 〇 〇t間之材料，， 如果使用硝酸鈉可以清楚在306.8t開娜解，38『c以上開始 分解，故為確實取得分離的效果，f際操作溫度需達4 〇的左右， 比較適合反應溫度高低影響反應速率； 至於無機鹽20處靴例之_，硝__要遠大於溴化環氧樹 脂含溴的_，讓溴在分解時可職來完全吸收，處理方式是將破璃 纖維I2混合誠_人迦顧猶液巾料絲分解反應，反應後 之破璃纖維12混合物亦會帶出少量硝酸鈉及溴化鈉成分，所以在運轉 時，必需再適時補充硝酸鈉來平衡系統的穩定性。 而該有機氣體13係包括：氫氣㈣、水_、-氧化碳(C0)、二 氧化碳(c〇2)、甲燒㈣、乙燒卿、乙稀(卿、乙块咖)、甲醇 (CH3OH)'乙醇(C2H5OH)、c3(丙烷、丙烯、丙酮、丙醇等)、。(丁烷、 丁烯、丁酮、丁醇等）、C5、c6.·.··.等等。 其次，請參閱第二圖所示’本發明「對含有溴化環氧樹脂及坡璃 纖維之絲跳處理方法及錄置」，其巾，傾麵品1G鄕融無 機鹽20行熱裂解的裝置，係包括—爐體3G及—加_4〇 ; 該爐體30上具有一入料口 3卜一鉦_ -、、機鹽卸出閥門32、一坡璃纖維 出料牽引器33及一出料口 34;其巾， 弁T通入料口 31係探外門及內門的 1250180 雙〜又# ’其是將M含有溴傾麵脂與咖_之廢棄品⑺及 鹽20先行放入至外門中，再開啟內門將其導放入該爐體3〇後，可藉 由通內、外門的互鎖保護’其具有防止_氣體外流及工作的安全性. 該無機鹽卸出閥鬥32則於熱裂解反應後，將細容融之無機鹽20 排放到該爐體30外； 涵坡璃纖維出料牽引器33係將熱裂解反應後純淨的破璃纖維η 牽引到該出料口 34處’再由該出料口 34送出該爐體3〇外進行清洗， 即可得到純淨的坡璃纖維12 ; 通加熱器40是將該無機鹽20加熱至3〇(TC至5〇0°C之間，使該無 機鹽20呈熔融狀態； 藉由上述的裝置，可使該廢棄品1〇與熔融的無機鹽2〇於該爐體 3〇中產生熱裂解，並分別獲得溴化鹽類Π、純淨的坡璃纖維12及有 機風體13，其中，薇溴化鹽類11及純淨的坡璃纖維12係由該破璃纖 維出料牽引器33 _至麵30 #，再以清水錄財璃_ 12上漠 化鹽類11，而獲得一純淨的坡璃纖維12，可供做為工業原料之再循環 使用； 而，該有機氣體13則需再使用一氣體完全燃燒裝置5〇，將其完全 燃燒後轉化_職無賴水蒸氣131及二氧化碳132。 再請參閱第二圖所示，本發明「對含有溴化環氧樹脂及玻璃纖維 之廢棄品的處理裝置」，更包括—用於完全燃燒該有機氣體13的氣體 TG全燃燒裝置5〇，其具有一循環反應器S1、一增氧助燃反廯器52、一 1250180 空氣反應緩衝停留器53 —二次加熱燃燒器54、—鼓風機％、一空氣 熱交換器56、-爐體冷卻器57、-空氣除污冷卻器％及—壓力平衡 器59 ; 其中，該循環反應器51係設置於該壚體3〇中，其係以馬達的傳 動速度來_贿綠K) W關無_ 2G的反應_，以確保玻 璃纖維的品質不被破壞； 該增氧助燃反應器52係設置於該爐體3〇內，其係提供壓縮的氧 氣，來增加該有機氣體13的完全燃燒； 該空氣反應緩衝停留器53係設置於該爐體％ ， 、 〒’其具有安定爐 體內之氣體及快速與熱空氣中的氧結合的作用，· 該二次加熱燃燒器54係設置於該爐體3〇上， , 上用來糙咼爐體30內 的反應溫度，令該有機氣體13在進行二次 Λ賴時，_保燃燒更加完 王，並同時產生水蒸氣131及二氧化碳132 ; 該鼓《 55錄置減體3〇上，大朗綠送入至爐 體30內，使該有機氣體13可以快速完全㈣， 〜^ I燃燒，兀全革除氣體燃燒不 7G全等現象產生； 該钱«絲56錄餅職3G±，妓⑽溫來將進入爐 進而咸的概先咖卿，咖3咖射_活性更強， 而减夕、燃料的耗損及增加反應速度等多項增益； 該麵冷卻器57係設置_體3q ± 5 水與爐溫做熱交換，來降低該爐體30的溫度；，、、將冷卻 1250180 孩全氣除污器58是將燃燒後的氣體透過除塵及吸附等作用再排放 至外界，防止二次污染的產生； 平衡器59疋利用壓力來撿知測量該爐體3〇内的負壓值， 再以壓力㈣模控制_器來直健载軻力，賴剌平衡爐體 3〇內壓力的作用，且同時讓該有機氣體13得依單-方向進行處理； 至於該有機氣體13之成分，可由附件—之化學式帽知：溴化環 氧樹脂除魅_合外，其㈣為錢化合物，且是大的分子 結構中，η的常數方可因前反應的條件不同而變化，在液態時，η為〇 2的,、'Ρ構樹，翻化後，η可以擴張到1 5的酿樹脂。亦可以由 子結構上判斷出熱分解後的碳氫化合物形式可能為：氫氣㈤）、水 ()氧化奴(CO)、—氧化碳(c〇2)、甲燒(CH4)、乙焼⑽报）、 乙快（C2H2)、_(αΒ〇Η)、乙醇（C_H)、C3 ⑽、丙稀、 丙酮、丙醇等）、C4( 丁燒、頂、丁二烯、丁酮、丁醇等⑽、叫.... 等。當提r«反魅_ ’龍分子會單純化、單—分子化、及再提 ㈣活性賴，侧虹義簡錢二氧傾⑽厕咖) 2：珉終處理結果。故只要騎多次職處理，再·❹之增氧助燃 反應裝置52，藉_交換原理，提蚊_高活性氧«分，以確保 反應效果，便可達到無污染的效果保證。 由上述得知’該氣體完全燃燒装置50確實能將熱裂解後的有機氣 體U轉化水蒸氣131及二氧化碳132，其過程中齡何龍境有害的 物質排出，完全合符環保的各項規定。 1250180 31-入料口 33-坡璃纖維出料牽引器 40-加熱器 51-循環反應器 53-空氣反應缓衝停留器 55-鼓風機 57-爐體冷卻器 59-壓力平衡器 132-二氧化碳 32-無機鹽卸出閥門 34-出料口 50-氣體完全燃燒裝置 52-增氧助燃反應器 54-二次加熱燃燒器 56-空氣熱交換器 58-空氣除污冷卻器 131-水蒸氣 121250180 玖, 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明In the class, the ones that are thermally cracked out of the method and the device [prior art] According to the 'publicity' ^ epoxy resin is a kind of quite easy to use, but its shortcoming is flammable, so it is to improve its flame resistance. At present, the epoxy resin is subjected to bromination treatment to obtain a deserted epoxy resin (dgetba) having high flame resistance, and since the desertified epoxy resin also has a good quality and a metal, Characteristics, so the industry - often the brominated epoxy resin as an adhesive 'in addition to being used to bond with the glass fiber to make the work outside the board _ is also used in the _ product, for example as The county (four), the circuit board, and the female special latitude; but the brominated ring _ the purpose of the I Long job, the first check, the structure can be recycled and reused __, and In the way of incineration, the treatment will be finely collected, and the right will heat up the bribes to the slope. When it is received, it must be set to heat up to thousands of degrees. The high-temperature equipment above c can be achieved, and it does not meet the economic benefits at all. If the method of reconciliation is used to recover the righteousness of the county products, the desertification epoxy resin will cause serious pollution in the process. Therefore, in recent years, in the production of the surface glue (4) of the other products, it is not feasible to recover the Hee fiber, which is not only acceptable, but not only sincerely, but also Abandoning such as strong _ to rely on the job is the killer of the secret fiber. 1250180 SUMMARY OF THE INVENTION The main object of the present invention is to utilize a property in which a molten inorganic salt can be directly reacted with bromine, and to put a waste product containing a brominated epoxy resin into a molten inorganic salt to cause an anti-reaction after the reaction. The bromine residue of silk damage (such as bromide), and the organic gas that can be recovered as a fuel field, can also be cracked and recovered into pure glass fiber, and used as a recycling user of industrial raw materials. Further, the object of the present invention is to thermally crack high-purity glass fibers by melting the inorganic salts at a temperature of 300t to 500t, without using heating to thousands of degrees. More than c heating equipment makes the whole process easier and reduces the cost of processing and meets the economic benefits of recycling. Another object of the present invention is to convert the device into a pair of _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The remaining carbon. [Embodiment] First, please refer to the figure - "The treatment of containing brominated epoxy resin and broken glass", and the disposal of waste PP" The waste of the glass fiber H) the inorganic salt sound of the pesticide to the surface salt directly reacts with the desertified epoxy resin, and thermally cracks the waste product 1G, causing the epoxy bond _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ It can be used as industrial, 5 recycling, 'the organic gas 13 series use-complete combustion equipment, and its 1250180 is completely burned _ tilt _ difficult amount of water wire 131 and dioxic 132;, the inorganic salt in the present invention The 20 series may be potassium nitrate, or nitric acid, or sodium nitrite, or _na' or a mixture of the above, and the main component is a strong oxidizing agent nitric acid series, which can meet the cleavage temperature of the brominated epoxy resin at 3 〇〇. ~6 〇〇t between the materials, if using sodium nitrate can be clearly at 306.8t Kaina solution, 38 c begins to decompose above, so in order to achieve the effect of separation, f operating temperature needs to reach about 4 ,, more suitable for the reaction temperature affects the reaction rate; as for the inorganic salt 20 boots, __ is much larger than bromine The epoxy resin contains bromine _, which allows the bromine to be completely absorbed during the decomposition. The treatment method is to mix the broken glass fiber I2. The decomposition reaction of the glass fiber is carried out. A small amount of sodium nitrate and sodium bromide will also be brought out. Therefore, when operating, it is necessary to replenish sodium nitrate in time to balance the stability of the system. The organic gas 13 includes: hydrogen (four), water _, - carbon oxide (C0), carbon dioxide (c 〇 2), 甲烧(四), 乙烧卿, ethylene (qing, 乙块咖), methanol (CH3OH) 'Ethanol (C2H5OH), c3 (propane, propylene, acetone, propanol, etc.). (butane, butene, butanone, butanol, etc.), C5, c6..... Next, please refer to the second section of the present invention, "The method and the recording method for the hopping of the brominated epoxy resin and the glazed fiber," and the towel, the sloping surface 1G smelting inorganic salt, 20 lines of thermal cracking The device comprises: a furnace body 3G and a _4 〇; the furnace body 30 has an inlet port 3, a __, a machine salt discharge valve 32, a slate fiber discharge tractor 33 and a discharge port 34; its towel, 弁T through the feed port 31 is the outer door and the inner door of the 1250180 double ~ # # It is the M containing bromine dumplings and coffee _ waste (7) and salt 20 first Put it into the outer door, and then open the inner door and put it into the furnace body 3〇, it can be protected by the interlocking of the inner and outer doors. It has the safety of preventing _ gas outflow and work. The inorganic salt The discharge valve bucket 32 discharges the finely fused inorganic salt 20 to the outside of the furnace body 30 after the thermal cracking reaction; the culvert glass fiber discharge tractor 33 is used to pull the pure glass fiber η after the thermal cracking reaction. At the discharge port 34, the furnace body 3 is sent out of the discharge port 34 for cleaning, and the pure glass fiber 12 is obtained; the heater 40 is used to The salt 20 is heated to 3 Torr (TC to 5 〇 0 ° C to make the inorganic salt 20 in a molten state; by the above device, the waste product 1 〇 and the molten inorganic salt 2 can be immersed in the furnace body Thermal cracking occurs in 3〇, and bromide-based bismuth, pure glazed fiber 12 and organic wind body 13 are respectively obtained, wherein the brominated salt 11 and the pure glazed fiber 12 are out of the broken glass fiber. Feeder 33 _ to face 30 #, and then use the clear water to record the _ 12 upper desertification salt 11 to obtain a pure glazed fiber 12, which can be used as recycling of industrial raw materials; The gas 13 needs to be further used in a gas complete combustion device 5, which is completely burned and then converted into a steam-free steam 131 and carbon dioxide 132. Referring to the second figure, the present invention "has a brominated epoxy resin and A treatment device for waste of glass fiber, further comprising: a gas TG total combustion device 5 for completely burning the organic gas 13, having a circulation reactor S1, an aeration-assisted combustion reactor 52, and a 1250180 air Reaction buffer stayer 53 - secondary heating burner 54, - blower %, empty a gas heat exchanger 56, a furnace body cooler 57, an air decontamination cooler %, and a pressure balancer 59; wherein the circulation reactor 51 is disposed in the body 3〇, which is driven by a motor Speed to _ bribe green K) W off _ 2G reaction _ to ensure that the quality of the glass fiber is not destroyed; the oxygen-enhanced combustion-supporting reactor 52 is placed in the furnace body 3, which provides compressed oxygen, To increase the complete combustion of the organic gas 13; the air reaction buffer stayer 53 is disposed in the furnace body %, 〒' which has the function of calming the gas in the furnace body and quickly combining with oxygen in the hot air, The secondary heating burner 54 is disposed on the furnace body 3, and is used to roughen the reaction temperature in the furnace body 30, so that the organic gas 13 is burned more completely when the secondary gas is used for the second time. At the same time, water vapor 131 and carbon dioxide 132 are generated; the drum is recorded on the lower side of the body, and the large green is sent into the furnace body 30, so that the organic gas 13 can be quickly and completely (four), ~^I burned, and the whole body is removed. Gas burning is not caused by the phenomenon of 7G congruence; the money «丝56 recorded cake job 3G ±, 妓 (10) To enter the furnace and then the salty first coffee, the coffee 3 _ _ more active, and reduce the eve, fuel consumption and increase the reaction speed and other gains; the surface cooler 57 is set _ body 3q ± 5 water and The furnace temperature is exchanged for heat to reduce the temperature of the furnace body 30; and, the 1250180 child gas decontaminator 58 is cooled to discharge the burned gas through the functions of dust removal and adsorption to the outside to prevent secondary pollution. The balancer 59 疋 uses the pressure to know the negative pressure value in the furnace body 3, and then uses the pressure (four) mode control _ to directly load the force, and the balance of the pressure inside the furnace body 3 At the same time, the organic gas 13 is treated in a single-direction; as for the composition of the organic gas 13, it can be known from the chemical cap of the accessory: the brominated epoxy resin is in addition to the charm, and the (iv) is a money compound, and In a large molecular structure, the constant of η may vary depending on the conditions of the pre-reaction. In the liquid state, η is 〇2, and 'Ρ 树 tree, after tumbling, η can be expanded to 15 styling resin. It is also possible to judge from the substructure that the form of hydrocarbons after thermal decomposition may be: hydrogen (5), water () oxidized slave (CO), carbon monoxide (c〇2), smoldering (CH4), acetamidine (10). ), B fast (C2H2), _ (αΒ〇Η), ethanol (C_H), C3 (10), propylene, acetone, propanol, etc.), C4 (butyl, top, butadiene, butanone, butanol, etc.) (10), call .... etc. When mentioning r «anti-magic _ 'long molecule will be simplistic, single-molecularization, and re-raise (four) active Lai, side rainbow Yi Jian Qian Dioxo (10) toilet coffee) 2: 珉Final processing results. Therefore, as long as riding a number of occupations, then the 增 增 增 增 助 助 助 52 52 52 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 增 交换 交换 交换 交换 交换 交换 交换 交换From the above, it is known that the gas complete combustion device 50 can convert the organic gas U after the thermal cracking into the water vapor 131 and the carbon dioxide 132, and the harmful substances in the middle of the process are discharged, which fully complies with the environmental protection regulations. 1250180 31-Inlet 33 - Spherical fiber discharge tractor 40 - Heater 51 - Circulation reactor 53 - Air reaction buffer damper 55 - Blower 57 - Furnace cooler 59 - Pressure balancer 132 - Carbon dioxide 32 - Inorganic salt discharge valve 34 - Discharge port 50 - Gas complete combustion device 52 - Oxygen booster combustion reactor 54 - Secondary heating burner 56 - Air heat exchanger 58 - Air decontamination cooler 131 - Water vapor 12