五、 、1243〇98 發明說明（1 ) is關中請案資料 本申請案爲美國專利申請案第〇9/092,480號，於 1998年6月5日歸檔，標爲”紋理釋放板，外加製造紋理 裝飾積層板之方法，及包括這種板之裝飾積層板疊放物Η 之部份延續，該案目前正申請中。 發明背景 1 ♦發明範園 本發明係關於裝飾積層板〇更特別地，本發明係關於一 種使用鑄造聚丙烯剝離板製造光澤裝飾積層板、以及控制 積層板光澤之方法。 2·先前技藝敘述 目前製造具平滑光澤表面、紋理表面、或深刻雕刻及浮 雕表面之高壓裝飾積層板。如一般背景，由熱及蜃力合併 製備之裝飾積層板已商業上生產數年，且在建築及家具工 業中如栅台及桌面、浴室及廚房之工作表面、壁鑲板、錄 地板產品、隔板及門廣泛地接受。這些裝飾積層板可敘述 爲含一些合併之薄板以形成支持表面裝飾品之單一結構。 表面裝飾物可由如齊一顏色一般簡單變化至如浮雕模擬木 材紋理塗工一般複雜。 裝飾積層板一般包括在熱及壓力下形成單一結構之鍵結 多層浸透合成樹脂紙板。在正常實行中，裝飾積層板組合 由下至上包括一或多片浸透樹脂板之心，其位於裝飾浸透 蜜胺之板上。裝飾板可進一步以浸透蜜胺覆蓋物覆蓋。該 心或基礎功能爲給予積層板剛性且通常包括一個固體基 -4 · 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）^~ --- ----------裝— (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 1243098 發明說明（ 經濟部智慧財產局員工消費合作社印製 板，此基板可在最初層合步驟前已形成或未形成。在堆疊 前，心元件之板以酚甲醛之水醇溶液浸透，在熱烘箱中乾 燥及部份硬化，以及最後切割成形。 該心可包括大多數90-1 50磅浸透酚系樹脂牛皮紙板及 基板。牛皮紙完全浸透並與實質上完全硬化且已在最初層 合步骤中轉化爲熱固性之紛系樹脂鍵結。基板可爲預硬化 塑性積層板，如玻璃纖維強化熱固性樹脂積層板及其類似 物，一種木製品，如硬板、木廢料或粒子板、三爽板及其 類似物’一種礦物基材板，如水泥-石轉板、片石、石膏 板、及其類似物，或基板組合。 裝飾板提供有吸引力外觀之積層板◊裝飾板亦決定裝飾 積層板之表面特性。例如，裝飾板組成決定裝飾積層板對 化學試劑、熱、光、震動及磨損之抵抗力。裝飾板一般由 高品質50-125令重、充填色料、汉纖維素紙浸透蜜胺甲 酸樹脂之水醇溶液製造。浸透樹脂之裝飾板隨後乾燥、部 份硬化、且最後切割成板。裝飾板之充填色料、α纖維素 紙可包括一種齊一顏色、一種裝飾設計，或一種光照像複 製天然材料，如木材、大理石、皮革等。纖維素祇之美術 特徵由在整個裝飾積層板上之積層板裝飾設計顯現。 裝飾積層板一般由將浸透樹脂之心及裝飾板置於鋼板間 並將積層板堆疊受在約800-1600 psi範園内之溫度一段 足以合併積層板及硬化樹脂之時間（一般約25分鐘至一 小時）製造。壓力及熱使紙板内之樹脂流動、硬化且合併 紙板成爲在技藝界中稱爲高壓積層板之均句層合塊。最 .装 i I (請先閱讀背面之注意事項再填寫本頁) ?事項再1 il 本紙張尺度適用中國國家標準（CNS)A4規格⑽χ 297公爱） 1243098 A7 B7 五、發明說明（3) -----------裝—— (請先閱讀背面之注意事項再填寫本頁) 後，形成之裝飾積層板鍵結至強化基板上’如三夾板、硬 板、石綿板、粒子板或其類似物。 一般一次形成超過一片積層板。多重積層板由插入多數 組合板至一堆疊中形成。剥離板位於組合板間以分離堆疊 在一起之種種積層板。在合併後，剝離板讓個別之積層板 分離。 在最近幾年中，紋理裝飾積層板已變得極受歡迎。紋理 表面由極淺之下沈，如紋理（如：緞、暗淡或半光澤的） 表面，變化至具有引人注目的三維效應之相當深的雕刻或 浮雕表面，如木紋、皮革、石板、抽象圓案、創作的設計 等。在製造光澤紋理裝飾積層板之情況中，目前要求極昂 貴之技術以確保給予裝飾積層板要求之紋理及光澤。 儘管物理特性、容易製造及費用已長期地使聚丙缔作爲 在製造裝飾積層板中作爲剥離板之合適材料，聚丙烯剌離 板在歷史上已產生展現有限光澤之裝飾積層板。例如，鑄 造聚丙烯剝離板在歷史上已生產展現積層板光澤少於六之 相當模糊的裝飾積層板。相似地，膨脹之聚丙烯剝離板一 般僅產生約10至12左右之光澤。 經濟部智慧財產局員工消費合作社印製 由此，有對生產展現極佳光澤特性之裝飾積層板之方法 及裝置之需要存在。本發明提供這樣之方法及裝置。 發明概要 因此，本發明之目的爲提供一種形成光澤裝飾積層板之 方法。此法爲堆疊具有一頂層之裝飾積層板組合，鑄造一 個聚丙烯剝離板其中該聚丙晞剝離板以用改良產生裝飾積 -6- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） 1243〇98 Α7 Β7 i、發明說明（4) 層板之光澤特徵之方法處理冷輥加工，將該聚丙烯剝離板 置於裝飾積層板組合上，施加熱及壓力至該裝飾積層板組 合及聚丙缔剝離板至足以鍵結裝飾積層板及可釋放地鍵結 聚丙烯板至該裝飾積層板组合之頂層，並由裝飾積層板組 合之頂層移除聚丙烯剝離板以顯現展現合宜之光澤特性之 裝飾積層板。 本發明之目的亦爲提供一種包括一個具頂層之裝飾積層 板組合及一片應用於此裝飾積層板组合頂層之聚丙烯剝離 板之裝飾積層板疊放物，聚丙烯剥離板爲以用改良產生裝 飾積層板光澤特性之方法處理之冷輥加工之鏵造聚丙烯剝 離板β 提供根據上面敘述之方法製造之裝飾積層板亦爲本發明 之進一步目的。 本發明之其他目的及優點由下面之詳細敘述當以相關之 伴隨附圖觀察時將變得明顯，這些圖式陳述特定之本發明 具體實施例。 圖式簡述 圖1爲包括根據本發明聚丙晞剝離板之積層板疊放物之 經濟部智慧財產局員工消費合作社印製 -----------裝 i· (請先閱讀背面之注意事項再填寫本頁} 圖示。 圖2爲經壓及加熱後之積層板疊放物之圖示。 圖3爲產生之裝飾積層板之圖示。 較佳具體實施例之敘述· 在此揭示本發明之詳細具體實施例。然而，應了解揭示 之具體實施例僅爲本發明之典型，其可由種種形式具體 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1243098 A7 B7 五、發明說明（5) -----------裝--- (請先閱讀背面之注意事項再填寫本頁) 化。因此，在此揭示之細節不解釋爲限制，但僅作爲申請 專利範圍之基礎及作爲指導熟諳此藝者如何製造及/或使 用本發明。 參考圖1 ’揭示包括裝飾積層板组合10及一片聚丙婦 剝離板12之裝飾積層板組合疊放物丨。装飾積層板疊放 物1用於製造根據本發明之光澤裝飾積層板18。 經濟部智慧財產局員工消費合作社印製 裝飾積層板疊放物1首先藉堆疊具頂層14之裝飾積層 板組合10組成。換言之，用於生產裝飾積層板之板堆疊 準備用於合併積層板之加熱及壓力步驟。亦鑄造聚丙埽剝 離板12。聚丙烯剝離板12用改良產生裝飾積層板之光澤 特性之方法塗钸冷輥處理。之後聚丙烯剝離板12置於積 層板组合10之頂層14上以形成積層板疊放物丨，並施以 熱及廢力積層板组合/聚丙烯剝離板16至足以鍵結多層裝 飾積層板組合10，及可釋放地鍵結聚丙缔剝離板至裝飾 積層板組合10之頂層14(見圖2)。最後，聚丙婦剝離 板1 2由形成之裝飾積層板1 8之頂層14移除以顯現展現 要求光澤特性之裝飾積層板（見圖3)。在大部份例子中 控制光澤以產生在約10至30之範園内的光澤積層板。然 而，因爲積層板要求光澤之變化，光澤可由任何合適之方 法控制且不需產生約10至30之積層板光澤以維持在本發 明之精神内。 裝飾積層板18可爲技藝界中一般人所知許多樹脂基裝 飾積層板之任一種。根據本發明之具體實施例，及如上所 述，裝飾積層板18包括一種裝飾板，或頂層14及一個心 -8- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1243098 A7 B7 五、發明說明（6 ) 如圖3所示。 (請先閱讀背面之注意事項再填寫本頁) 更特別地，裝飾積層板18包括由一或多層浸透酚系樹 脂之牛皮紙2 0 a組成之心2 0及由圖案層2 2組成之裝飾 板14及合併AI2O3以抗磨損之蜜胺覆層24。如上面之討 論，隨後可鍵結一塊基板至最終裝飾積板1 8以加強積層 板之堅固性，例如，基板可選擇種種材料，即三夾板、粒 子板、膠合板、中密度纖維板等，雖然上面揭示之較佳裝 飾積層板，可應用寬範圍之裝飾積層板而不違背本發明之 精神。 如技藝界一般技巧者所熟知，铸造聚丙烯剥離板藉擠 壓、軋、冷卻及切割聚丙烯釋放板製造。根據本發明，聚 丙晞剥離板12 —般可敘述爲丙烯單質聚合物或聚丙晞及 其他α -烯烴之共聚合物。 根據本發明利用之聚丙晞之溶融流動指數係選擇提供要 求之物理性質需要以產生展現高光澤之紋理裝飾積層板。 一般，熔融流動指數將在約1至約20之範Μ内，這利用 A S T M D - 1 2 3 8測量。熔融流動指數以在約5至約1 5之 經濟部智慧財產局員工消費合作社印製 範圍内較佳，而以約7至約12之範園内更佳，這利用 ASTM D-1238 測量。 適合用於本發明之聚丙烯非限制商業實例包括EOD97-06及EOD 96-01，可購自法納（Fina)(德州達拉斯）及 艾斯科林（ESCORENE〉聚丙稀PD 4443，可購自艾索 (Exxon)化學公司。ε〇〇97·06 及 EOD96-01 具有 12 克/10分鐘之熔融流動（ASTM D-1238條件"L")，密度 -9 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公楚） 1243098 A7 B7 五、發明說明（7) (請先閱讀背面之注意事項再填寫本頁) 爲0·91克/毫升（ASTM D-1505)，抗張強度爲5 800磅/ 平方吋（ASTMD-638)，伸長率在降伏點爲10%，抗張模 數爲280,000磅/平方吋，弩曲模數爲270,000磅/平方 吋（ASTM D-790)，熔點爲333 °F (DSC)，且再結晶點 爲261°F。艾斯克林聚丙烯PD 4443具有7·25克/10分 鐘之熔融流動（ASTM 1 238)，密度爲0·90克/立方公分 (ASTM D792)，機械加工方向之抗張強度爲3,300磅/ 平方吋，降伏點之伸長率在機械加工及橫斷方向均爲5 %，破裂時之抗張強度在機械加工方向爲8,000磅/平方 吋及在橫斷方向爲7,000磅/平方吋，破裂時之伸長率在 機械加工及橫斷方向均爲660%，霾爲2/5%，光澤爲85 %及摩擦係數爲0.3。 如技藝界一般人所熟知，有許多方法及催化劑生產聚丙 烯。因此，打算利用種種方法及催化劑而不違背本發明之 精神。 經濟部智慧財產局員工消費合作社印製 例如，傳統戚格勒-納塔（Ziegler-Natta)催化劑系統 可根據本發明利用。戚格勒-納塔催化劑系統利用鋁烷基 共催化之過渡金屬化合物。自從1950年代早期問世以 來，戚格勒-納塔形式聚烯烴催化劑之一般製造方法，以 及製造及隨後使用之一般方法，在聚合技藝界中已熟知。 更特別地，戚格勒-納塔形式聚合催化劑基本上爲由南 化過渡金屬，例如：鈥、鉻或Μ，及典型上爲有機鋁化合 物之金屬氫化物及/或燒基金屬衍生之錯合物。催化劑組 份通常包括在與烷基鋁錯合之鎂化合物載體上之齒化鈦， •10- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) ' 1243098 A7 B7 五、發明說明（8) 甚至可包括電子供體。這類催化劑系統顯示在下列美國專 利中：4，107,413; 4,294,721; 4,439,540; 4,115,319; 4,220,554; 4,460,701;及 4,562，173;這些專利所揭示之 内容在此以提及之方式併入本文。這些僅爲主要設計作爲 聚合丙烯及乙締之催化劑及催化系統相關之數百項頒予專 利之少部份。 "金屬烯"催化劑亦可根據本發明使用。"金屬烯”催化劑 包括一個金屬烯及一個鋁烷基組份。金屬烯催化劑系統之 過渡金屬化合物具有二或多個環戊二晞基環配體。因此， 鈦烯、錘烯及給晞皆已利用作爲在這類含生產聚烯烴之催 化系統的"金屬烯"中之過渡金屬元素。 如上面所討論，傳統鑄造聚丙烯剝離板受擠壓通過模具 並以冷輥處理以在受控制之條件下冷卻經擠壓之板，本發 明以預定之方法使用冷輥處理以給予經擠壓之聚丙烯剥離 板要求之硬度及平滑特性。當這些聚丙烯剝離板在製造裝 飾積層板中使用時，產生之裝飾積層板展現受控制之光 澤0 特別地，已發現在高溫浴中（例如1 2 0 T )冷鉻輥製造 之聚丙晞剝離板產生高光澤積層板。此處紋理首先應用至 冷輥（如下面將詳細討論者），鉻塗佈處理包括以微細平 滑、光澤之工具雕刻經拋光之輥（在雕刻過程中不使用 酸）。 另一方面，已發現以共沈積鐵弗龍、聚四氟乙烯及無電 鍍鎳處理之冷輥產生理想結果之聚丙烯剝離板6相似地， •11- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----------裝--- (請先閱讀背面之注意事項再填寫本頁) - 經濟部智慧財產局員工消費合作社印製 1243098 A7 B7 五、發明說明（9) ----------41^·裝--- (請先閱讀背面之注意事項再填寫本頁) 以電拋光處理之冷輥亦提供理想之結果。此外’以鎳底 層，及一共沈積鐵弗龍與無電鍍鎳處理之冷輥改良由簡單 以共沈積鐵弗龍及無電鍵錄處理之冷輕提供之結果。 根據本發明較佳之具體實施例，共沈積之鐵弗龍及無電 鍍鎳塗層，以及鎳底層與共沈積之鐵弗龍及無電鍍鎳塗 層，以使用密西根州瓦林之安杜拉塗料公司（ENDURA COATINGS Inc.，Warren，Michigan)之 200 系列"注入母材 "(Infused Matrix)塗佈技術。200系列”注入母材"塗料揭 示於所附之小册中，在此以提及之方式併入本文。關於電 拋光冷輥，電拋光用”電拋光，應用、品質標準及規格用 者指南"中所述之技術進行。此書爲1998年1月第八版， 德星公司出版（Delstar Corporation)，在此以提及之方式併入 本文。 經濟部智慧財產局員工消費合作社印製 每一上面討論之冷輥給予鑄造聚丙烯剝離板一個平滑之 細微表面。相信處理冷輥以增加產生聚丙烯剝離板之硬度 及平滑特性將高光澤裝飾積層板之生產最佳化。事實上， 相信錡造聚丙烯剝離板之硬度及平滑特性對產生裝飾積層 板之光澤爲重要的。由此，及上面之討論，鑄造聚丙缔剝 離板應具有在約1至約20之利用ASTMD-1238測量之溶融 流動指數。溶融流動指數利用ASTM D-1238測量以約1至約 2 0較佳。熔融流動指數以在約5至約1 5之範圍内較佳， 而以在約7至約1 2之範園内更佳。 此外，產生之聚丙烯剝離板應展現沒有不規則之平滑微 細表面。如技藝界中一般人將確定地察知，只要產生之聚 •12- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） !243〇98 A7 B7 五、V., 1243〇98 Description of the invention (1) is the information requested in the application. This application is US Patent Application No. 09 / 092,480, filed on June 5, 1998, and marked as "texture release plate, plus manufacturing texture." A method for decorating a laminated board, and a part of a decorative laminated board stack including such a board is continuing, and the case is currently in the process of application. BACKGROUND OF THE INVENTION 1 ♦ Invention Fanyuan This invention relates to decorative laminated boards. More specifically, The present invention relates to a method for manufacturing a glossy decorative laminated board by using a cast polypropylene peeling board, and a method for controlling the gloss of the laminated board. 2. The prior art describes the current manufacture of high-pressure decorative laminated boards with smooth glossy surfaces, textured surfaces, or deeply carved and embossed surfaces. As a general background, decorative laminates produced by combining heat and pressure have been commercially produced for several years, and have been used in the construction and furniture industries such as grids and tabletops, work surfaces in bathrooms and kitchens, wall paneling, and recording floors. Products, partitions, and doors are widely accepted. These decorative laminates can be described as a single structure with a combination of sheets to support surface decorations. The decoration can be changed from simple color like uniform to as complicated as relief wood texture coating. Decorative laminated board generally includes bonded multi-layer impregnated synthetic resin cardboard which forms a single structure under heat and pressure. In normal practice, decorative laminate The board combination from bottom to top includes one or more resin-impregnated boards that are located on the decorative melamine-impregnated board. The decorative board can be further covered with a melamine-impregnated cover. The core or basic function is to give the laminate rigidity and usually Including a solid base-4 · This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ^ ~ --- ---------- installation— (Please read the note on the back first Please fill in this page for further information.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1243098 Invention Description (Printed boards of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. This substrate can be formed or not formed before the initial lamination step. Before stacking The core element board is saturated with phenol formaldehyde in water and alcohol solution, dried and partially hardened in a hot oven, and finally cut and formed. The core can include most 90-1 50 lb dipping Phenolic resin kraft board and substrate. Kraft paper is fully saturated and bonded with a resin that is substantially completely hardened and has been converted to thermosetting in the initial lamination step. The substrate can be a pre-hardened plastic laminate, such as glass fiber reinforced thermosetting resin Laminated boards and the like, a wood product such as hard board, wood waste or particle board, Sanshuang board and the like 'a mineral substrate board, such as cement-stone turn board, chip stone, gypsum board, and the like Or the combination of substrates. Decorative boards that provide attractive appearance. Decorative boards also determine the surface characteristics of decorative laminates. For example, the composition of decorative boards determines the resistance of decorative laminates to chemical agents, heat, light, vibration and abrasion. .Decorative board is generally made of high-quality 50-125 ream, filled with colorant, han cellulose paper impregnated with melamine formic acid aqueous solution. The resin-impregnated decorative panel is then dried, partially hardened, and finally cut into panels. Filling materials for decorative boards, alpha cellulose paper may include a uniform color, a decorative design, or a natural material such as wood, marble, leather, etc., which is reproduced by light. The artistic features of cellulose are revealed by the decorative design of the laminates throughout the decorative laminates. Decorative laminates generally consist of placing the heart impregnated with resin and decorative plates between steel plates and stacking the laminates at a temperature of about 800-1600 psi for a period of time sufficient to combine the laminates and hardened resin (typically about 25 minutes to one Hours). Pressure and heat cause the resin in the cardboard to flow, harden, and merge. The cardboard becomes a homogeneous laminated block known in the art as a high-pressure laminated board. Install i I (please read the notes on the back before filling this page)? Matters need 1 il This paper size applies the Chinese National Standard (CNS) A4 specifications ⑽χ 297 public love) 1243098 A7 B7 V. Description of the invention (3) ----------- Installation—— (Please read the precautions on the back before filling in this page), and then form the decorative laminated board bonded to the reinforced substrate, such as triple plywood, rigid board, asbestos board , Particle board or the like. Generally, more than one laminate is formed at a time. Multi-layer boards are formed by inserting most of the combination boards into a stack. The release boards are located between the composite boards to separate the various laminated boards stacked together. After merging, the peeling plates separate the individual laminates. In recent years, textured decorative laminates have become extremely popular. Textured surfaces change from very shallow sinks, such as textured (such as satin, matte, or semi-gloss) surfaces, to fairly deep carved or embossed surfaces with dramatic three-dimensional effects, such as wood grain, leather, slate, Abstract circles, creative designs, etc. In the case of manufacturing glossy textured decorative laminates, extremely expensive techniques are currently required to ensure the texture and gloss required for decorative laminates. Although physical properties, ease of manufacture, and cost have long made polypropylene a suitable material for release boards in the manufacture of decorative laminates, polypropylene laminates have historically produced decorative laminates that exhibit limited gloss. For example, cast polypropylene release boards have historically been produced as decorative laminates that exhibit a rather fuzzy appearance of less than six laminates. Similarly, expanded polypropylene release boards generally produce a gloss of only about 10 to 12 or so. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Therefore, there is a need for a method and a device for producing decorative laminates exhibiting excellent gloss characteristics. The present invention provides such a method and apparatus. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a method for forming a glossy decorative laminate. This method is to stack a decorative laminated board combination with a top layer, and cast a polypropylene peeling board, wherein the polypropylene peeling board is used to improve the decorative product. 6- This paper size is applicable to China National Standard (CNS) A4 (210 X 297) (Public love) 1243〇98 Α7 Β7 i. Description of the invention (4) The method of gloss characteristics of the laminated board is processed by cold roll processing. The polypropylene release board is placed on the decorative laminated board combination, and heat and pressure are applied to the decorative laminated board. Combination and polypropylene release board enough to bond the decorative laminate and releasably bond the polypropylene board to the top layer of the decorative laminate panel, and remove the polypropylene release board from the top layer of the decorative laminate panel to show the proper display Decorative laminate with gloss characteristics. The object of the present invention is also to provide a decorative laminated board stack including a decorative laminated board assembly with a top layer and a polypropylene peeling board applied to the top layer of the decorative laminated board assembly. The polypropylene peeling board is used for improving decoration. Laminated polypropylene peeling plate processed by cold roll processing by the method of gloss characteristics of laminated board It is a further object of the present invention to provide decorative laminated board manufactured according to the method described above. Other objects and advantages of the present invention will become apparent from the following detailed description when viewed in conjunction with the accompanying drawings, which illustrate specific embodiments of the invention. Brief Description of the Drawings Figure 1 is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, including the laminated board stack of polypropylene peeling plates according to the present invention. Note on the back then fill out this page} icon. Figure 2 is a diagram of the laminates after pressing and heating. Figure 3 is a diagram of the decorative laminates produced. Description of the preferred embodiment The detailed embodiments of the present invention are disclosed here. However, it should be understood that the disclosed specific embodiments are only typical of the present invention and can be embodied in various forms. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). ) 1243098 A7 B7 V. Description of the invention (5) ----------- install --- (Please read the precautions on the back before filling this page). Therefore, the details disclosed here are not explained For the purpose of limitation, but only as the basis of the scope of patent application and as a guide for those skilled in the art to make and / or use the present invention, please refer to FIG. 1 'disclose the decorative laminated board combination including the decorative laminated board combination 10 and a polypropylene peeling board 12 Stacks 丨. Decorative laminate stack 1 for manufacturing The glossy decorative laminate 18 according to the present invention is produced. The decorative laminate laminate 1 printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is first composed of the decorative laminate combination 10 with the top layer 14. In other words, it is used to produce decorative laminate The plate stack is prepared for combining the heating and pressure steps of the laminated board. The polypropylene peeling board 12 is also cast. The polypropylene peeling board 12 is coated with cold rolls by improving the gloss characteristics of the decorative laminated board. After that, the polypropylene peeling board 12 is placed on the top layer 14 of the laminated board combination 10 to form a laminated board stack, and heat and waste laminated board combination / polypropylene peeling board 16 is applied to bond the multilayer decorative laminated board combination 10, and can be released The ground-bonded polypropylene release board is connected to the top layer 14 of the decorative laminate assembly 10 (see FIG. 2). Finally, the polypropylene laminate 12 is removed from the top layer 14 of the formed decorative laminate 18 to reveal the desired gloss characteristics. Decorative laminates (see Figure 3). In most examples, gloss is controlled to produce a glossy laminate in a range of approximately 10 to 30. However, because laminates require changes in gloss, light It can be controlled by any suitable method and does not need to produce a gloss of about 10 to 30 to maintain the spirit of the present invention. The decorative laminate 18 can be any one of many resin-based decorative laminates known to those skilled in the art. According to In the specific embodiment of the present invention, and as described above, the decorative laminated board 18 includes a decorative board, or a top layer 14 and a heart. 8- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1243098 A7 B7 V. Description of the invention (6) As shown in Figure 3. (Please read the notes on the back before filling out this page) More specifically, the decorative laminate 18 includes kraft paper impregnated with one or more layers of phenolic resin 2 0 a The composition heart 20 and the decorative plate 14 composed of the pattern layer 22 and the melamine coating 24 incorporating AI2O3 to resist wear. As discussed above, a substrate can be subsequently bonded to the final decorative laminate 18 to strengthen the rigidity of the laminate. For example, the substrate can be selected from various materials, such as triple plywood, particle board, plywood, medium density fiberboard, etc., although the above The disclosed preferred decorative laminates can be applied to a wide range of decorative laminates without departing from the spirit of the invention. As is known to those skilled in the art, cast polypropylene release boards are manufactured by extrusion, rolling, cooling, and cutting polypropylene release boards. According to the present invention, the polypropylene release sheet 12 may be generally described as a propylene simple polymer or a copolymer of polypropylene and other α-olefins. The melt flow index of polypropylene used in accordance with the present invention is selected to provide the required physical properties needed to produce a textured decorative laminate that exhibits high gloss. Generally, the melt flow index will be in the range of about 1 to about 20, which is measured using AS T M D-1 2 3 8. The melt flow index is preferably within the range of about 5 to about 15 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and more preferably within the range of about 7 to about 12, which is measured using ASTM D-1238. Non-limiting commercial examples of polypropylenes suitable for use in the present invention include EOD97-06 and EOD 96-01, available from Fina (Dallas, Texas) and ESCORENE (Polypropylene PD 4443), available from Exxon Chemical Company. Ε〇〇97 · 06 and EOD96-01 have a melt flow of 12 g / 10 minutes (ASTM D-1238 conditions " L "), density -9-This paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 Gongchu) 1243098 A7 B7 V. Description of the invention (7) (Please read the precautions on the back before filling this page) It is 0 · 91 g / ml (ASTM D-1505). Tensile strength is 5 800 pounds per square inch (ASTMD-638), elongation is 10% at the fall point, tensile modulus is 280,000 pounds per square inch, and crossbow modulus is 270,000 pounds per square inch (ASTM D-790 ), With a melting point of 333 ° F (DSC) and a recrystallization point of 261 ° F. Eskolin polypropylene PD 4443 has a melt flow of 7.25 g / 10 minutes (ASTM 1 238) and a density of 0.90 g / Cubic centimeter (ASTM D792), the tensile strength in the machining direction is 3,300 lbs / in2, and the elongation at the drop point is 5% in both the machining and the transverse direction The tensile strength at the time of rupture is 8,000 psi in the machining direction and 7,000 psi in the transverse direction. The elongation at the time of rupture is 660% in both the machining and transverse directions, and the haze is 2/5 %, Gloss is 85% and friction coefficient is 0.3. As is generally known in the art world, there are many methods and catalysts for the production of polypropylene. Therefore, it is intended to use various methods and catalysts without violating the spirit of the present invention. Employees, Bureau of Intellectual Property, Ministry of Economic Affairs Printed by consumer cooperatives For example, traditional Ziegler-Natta catalyst systems can be utilized in accordance with the present invention. Qiegler-Natta catalyst systems utilize aluminyl-co-catalyzed transition metal compounds. Since their introduction in the early 1950s Since then, the general manufacturing method of Qiegler-Natta form polyolefin catalysts, as well as the general methods of manufacturing and subsequent use, have been well known in the polymerization arts. More specifically, the Chigler-Natta form polymerization catalysts are basically Derivatives derived from south chemical transition metals, such as: ', chromium, or M, and metal hydrides and / or alkyl-based metals that are typically organoaluminum compounds The catalyst component usually includes toothed titanium on a magnesium compound carrier that is incompatible with an alkyl aluminum. • 10- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) '1243098 A7 B7 V. Invention Note (8) may even include electron donors. Such catalyst systems are shown in the following U.S. patents: 4,107,413; 4,294,721; 4,439,540; 4,115,319; 4,220,554; 4,460,701; and 4,562,173; the disclosures of these patents are here Incorporated by reference. These are just a few of the hundreds of patents awarded that are primarily designed as catalysts and catalytic systems for polymerizing propylene and ethylene. " Metalene " catalysts can also be used according to the invention. " Metalene " catalysts include a metalene and an aluminyl component. The transition metal compounds of the metalene catalyst system have two or more cyclopentadienyl ring ligands. Therefore, titaniumene, hammerene, and amidine Both have been used as transition metal elements in " metal olefins " in such polyolefin-containing catalyst systems. As discussed above, conventional cast polypropylene release sheets are extruded through a die and processed with cold rolls to The extruded boards are cooled under controlled conditions. The present invention uses a cold roll process in a predetermined method to give the extruded polypropylene release boards the required hardness and smoothness. When these polypropylene release boards are used in the manufacture of decorative laminates In use, decorative laminates produced exhibit a controlled gloss. 0 In particular, it has been found that polypropylene release sheets made from cold chrome rolls in high temperature baths (eg 120 T) produce high-gloss laminates. The texture here is first Applied to cold rolls (as discussed in more detail below), the chrome coating process involves engraving polished rolls with fine, smooth, shiny tools (no acid is used in the engraving process). On the other hand, it has been found that polypropylene peeling plates with co-deposited Teflon, polytetrafluoroethylene and electroless nickel-treated cold rolls that produce the desired results are similar. • 11- This paper size applies Chinese National Standards (CNS) A4 specification (210 X 297 mm) ----------- install --- (Please read the precautions on the back before filling out this page)-Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 1243098 A7 B7 V. Description of the invention (9) ---------- 41 ^ · Installation --- (Please read the precautions on the back before filling this page) The cold roller treated with electropolishing also provides ideal results In addition, the improvement of cold rolls with a nickel base layer and a co-deposited Teflon and electroless nickel treatment is provided by a simple cold-light treatment with co-deposited Teflon and electroless keying. According to a preferred embodiment of the present invention , Co-deposited Teflon and electroless nickel coatings, and nickel substrates and co-deposited Teflon and electroless nickel coatings to use ENDURA COATINGS Inc., Warren, MI (Michigan) 200 Series "Infused Matrix" Coating Technology 200 Series "preform injection " of the coating reveals the appended brochure, which is hereby incorporated herein by way of reference. Regarding electro-polishing cold rolls, electro-polishing is performed using the techniques described in "Electric Polishing, Application, Quality Standards and Specifications User's Guide". This book is the eighth edition of January 1998, published by Delstar Corporation. This article is hereby incorporated by reference. The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints each of the cold rolls discussed above to give the cast polypropylene release sheet a smooth, fine surface. It is believed that the cold rolls are treated to increase the production of polypropylene. The hardness and smoothness of the release board optimizes the production of high-gloss decorative laminates. In fact, it is believed that the hardness and smoothness of the fabricated polypropylene release boards are important to produce the gloss of the decorative laminates. Thus, and above In discussion, the cast polypropylene release sheet should have a melt flow index measured from ASTM D-1238 of about 1 to about 20. The melt flow index measured from ASTM D-1238 is preferably from about 1 to about 20. The melt flow index is It is preferably in the range of about 5 to about 15 and more preferably in the range of about 7 to about 12. In addition, the resulting polypropylene release sheet should exhibit smooth micro-fineness without irregularities. Surface as art community in general will surely perceived the, as long as the produce of polyethylene • 12- This paper scales applicable Chinese National Standard (CNS) A4 size (210 X 297 male love)! 243〇98 A7 B7 V.
發明說明（1G -裝--- (請先閱讀背面之注意事項再填寫本頁) 丙缔展現上面討論之要求性質可使用種種冷輥塗層及/或 處理技術。 亦可利用冷輥之溫度控制根據本發明製造產生積層板之 光澤。例如，冷輥溫度在可接受範固内之增加將提供根據 本發明製造產生積層板在光澤上之增加。在此法中，積層 板光澤之稍爲改變可容易地藉簡單增加或減少冷輥之溫度 控制。相信溫度之改變影響產生聚丙烯剝離板之結晶結 構，及使用聚丙烯剝離板製造積層板之光澤。 上面討論之聚丙烯剝離板亦可用於同時給予裝飾積層板 紋理。一般承認之美國專利申請案第〇9/〇92,480，標題爲，· 紋理剝離板，製造紋理裝飾積層板之方法，及包括這類板 之裝飾積層板之疊放物”，歸檔於1998年6月5日，揭示 可同時使用本發明光澤法以產生具紋理及光澤裝飾積層 板，其在此以提及之方式併入本文。 然而，紋理可同時藉能形成紋理剝離板以將紋理加至裝 飾積層板之任何適當加工方法施加光澤。根據本發明較佳 具體實施例，使用擠壓及鑄造產生高光澤及紋理均較隹。 經濟部智慧財產局員工消費合作社印製 簡言之，聚丙烯在熔融態下強迫通過一個擠壓模且隨後 以熔融之壓出物通過冷輥間冷卻形成一板D冷輥提供要求 之紋理至板之前表面。製造之紋理板具有平滑之背面。 當此產生紋理之技術根據本發明使用時，冷輥首先產生 紋理以給予經處理之聚丙烯板要求之紋理。之後具紋理之 冷輥藉應用鉻或塗佈共沈積之鐵弗龍、聚丙烯及無電鍍鎳 上最後一道塗工。相似地，冷輥可塗佈鎳底層及共沈積之 _ ·13· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) " Ϊ243098 A7 B7 五、發明說明（11 鐵弗龍與無電鍍鎳。另一方面，冷輥可單獨以電拋光處 理，或可在應用鎳/鐵弗龍共沈積或鉻之前以電拋光處 理〇 不論形成紋理剝離板之方法，一般在聚丙烯仍在軟化溫 度之上給予聚丙烯剥離板爲重要的，以在仍高於熔點溫度 較佳。產生之紋理剝離板將具有具紋理之前表面及平滑之 背面。 本發明產生紋理之方法可用於任何可想像的形式、尺寸 或圖案。通常，紋理表面之峰至谷之高度R2可爲任何適 當之高度，但以大於100微吋較佳，以大於約200微吋 更佳，而甚至以大於約300微吋更佳。 本發明紋理剝離板之厚度可在寬範園之限制内變化。若 板太薄，紋理將傾向無法轉移。經濟之因子傾向設定板厚 度之上限。通常，紋理剝離板之厚度至少爲1密爾，以至 少1·5密爾較佳，而以至少2密爾更佳。 紋理聚丙烯剥離板提供紋理表面至裝飾積層板且亦作爲 傳統裝飾積層板疊放物間之剝離板。考慮到此，本發明之 聚丙晞板可用於積層板之聯合加工或用於製造單一積層板 之簡單給予要求之紋理及光澤。不論是否應用本發明聚丙 烯剝離板加紋理至裝飾積層板，以下列方法應用聚丙烯板 至裝飾積層板。 典型之裝飾積層板組合包括支持一浸透熱固性樹脂之裝 飾層之數層浸透熱固性樹脂心材料（以牛皮紙較佳），該 裝飾層可進一步以浸透熱固性樹脂之覆板覆蓋。使用之熱 • 14- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ~~" (請先閱讀背面之注意事項再填寫本頁) 裝 訂： 經濟部智慧財產局員工消費合作社印製 1243〇98 A7 B7 五、發明說明（12) 固性樹脂心材料以酚系樹脂較佳，裝飾及覆蓋板以明亮之 蜜胺甲醛樹脂較佳。剥離板之紋理表面面向爲裝飾板或覆 蓋板之裝飾積層板組合之最頂層，而紋理剝離板之背面位 在相鄰疊放物或鋼板之心材料上。 由適當積層板壓板間之緊壓，紋理剝離板給予紋理至第 一疊放物之最頂層，並作爲第一疊放物與相鄰疊放物間之 剝離。如積層板技藝界所熟知之滾筒重壓組合在層合時提 供必要之熱及/或壓力。 實際上，當要求及/或需要時，可利用：抗氧化劑、抗 結塊劑、滑動劑、交聯劑、安定劑、紫外線吸收劑、潤滑 劑、起泡劑、抗靜電劑、有機或無機火焰抑制劑、塑化 劑、染料、色料、滑石、碳酸鈣、碳黑、雲母、玻璃纖 維、碳纖維、芳醯胺樹脂、石綿，以及其他技藝界所知之 填料。 經濟部智慧財產局員工消費合作社印製 ---------裝--- (請先閱讀背面之注意事項再填寫本頁) 本發明中利用之之聚丙烯可進一步與一或多種其他熱塑 性物攙混或結合。適當之其他熱塑性物包括聚烯烴，特別 是聚乙缔、其他聚丙烯、聚酯、聚丙烯醯胺、聚醯胺、聚 碳酸酴、聚胺基甲酸乙酯、聚丙缔腈及丁二缔苯乙烯。較 隹之聚乙烯包括線性低密度聚乙烯。 儘管已顯示並敘述較佳具體實施例，應了解不打算藉這 類揭示限制本發明，但打算將所有修正及替代之結構包括 在所附之申請專利範園定義之本發明的精神及範圍内。Description of the Invention (1G-Loading --- (Please read the precautions on the back before filling out this page). Crypto shows the required properties discussed above. Various cold roll coating and / or processing techniques can be used. The temperature of the cold roll can also be used. Controlling the gloss of laminates produced according to the present invention. For example, an increase in cold roll temperature within an acceptable range will provide an increase in gloss of laminates produced according to the present invention. In this method, the gloss of laminates is slightly The change can be easily controlled by simply increasing or decreasing the temperature of the cold roll. It is believed that the change in temperature will affect the crystalline structure of the polypropylene release board and the gloss of the laminated board using the polypropylene release board. The polypropylene release board discussed above can also be used. The texture of the decorative laminate is given at the same time. The generally recognized U.S. Patent Application No. 09 / 〇92,480, entitled, "Texture Peeling Panel, Method for Manufacturing Textured Decorative Laminate, and Stacking of Decorative Laminates Including Such Panels" "File", filed on June 5, 1998, reveals that the gloss method of the present invention can be used simultaneously to produce textured and glossy decorative laminates, which are mentioned herein The method is incorporated herein. However, the texture can be applied with gloss by any suitable processing method capable of forming a texture peeling plate to add texture to the decorative laminate. According to a preferred embodiment of the present invention, high gloss is achieved using extrusion and casting and The textures are relatively rough. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics In short, polypropylene is forced through an extrusion die in the molten state and then cooled by the molten extrudate through the cold rolls to form a plate D cold roll. Provide the required texture to the front surface of the board. The manufactured texture board has a smooth back. When this texture-producing technique is used in accordance with the present invention, the cold roll first produces the texture to give the treated polypropylene board the desired texture. It is then textured The cold roll can be coated with chrome or coated with co-deposited Teflon, polypropylene and electroless nickel. Similarly, the cold roll can be coated with a nickel base layer and co-deposited _ · 13 · This paper standard applies China National Standard (CNS) A4 specification (210 X 297 mm) " Ϊ243098 A7 B7 V. Description of the invention (11 Teflon and electroless nickel. On the other hand, cold rolls Electropolishing alone, or electropolishing before nickel / Teflon co-deposition or chromium can be applied. Regardless of the method of forming the textured release sheet, it is generally important to give the polypropylene release sheet above the softening temperature of polypropylene. It is better to still be above the melting point temperature. The resulting textured release sheet will have a textured front surface and a smooth back surface. The method of generating texture according to the present invention can be used in any conceivable form, size or pattern. Generally, textured surfaces The peak-to-valley height R2 can be any suitable height, but is preferably greater than 100 micro inches, more preferably greater than about 200 micro inches, and even more preferably greater than about 300 micro inches. Thickness of the texture release sheet of the present invention Can be changed within the limits of Kuanfanyuan. If the board is too thin, the texture will not be transferred. The economic factor tends to set the upper limit of the board thickness. Generally, the thickness of the texture release sheet is at least 1 mil, preferably at least 1.5 mils, and more preferably at least 2 mils. The textured polypropylene release sheet provides a textured surface to the decorative laminate and also serves as a release sheet between conventional decorative laminate laminates. With this in mind, the polypropylene sheet of the present invention can be used in the joint processing of laminated boards or used to make a single laminated board simply to give the required texture and gloss. Regardless of whether or not the polypropylene release sheet of the present invention is applied to add texture to a decorative laminate, a polypropylene sheet is applied to the decorative laminate in the following manner. A typical decorative laminated board combination includes several layers of impregnated thermosetting resin core material (preferably kraft paper) supporting a decorative layer impregnated with thermosetting resin. The decorative layer may be further covered with a cover sheet impregnated with thermosetting resin. Heat of use • 14- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) ~~ " (Please read the precautions on the back before filling this page) Binding: Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by Consumer Cooperatives 1243〇98 A7 B7 V. Description of the invention (12) The solid resin core material is preferably a phenol resin, and the decorative and cover board is preferably a bright melamine formaldehyde resin. The textured surface of the peeling plate faces the topmost layer of the decorative laminated board combination which is a decorative plate or a cover plate, and the back surface of the textured peeling plate is located on the adjacent stack or the core material of the steel plate. The texture peeling plate gives the texture to the topmost layer of the first stack by proper pressing between the laminated plates, and serves as the peel between the first stack and the adjacent stack. Roller presses, as is well known in the art of laminates, provide the necessary heat and / or pressure during lamination. In fact, when required and / or needed, antioxidants, anti-caking agents, slip agents, cross-linking agents, stabilizers, UV absorbers, lubricants, foaming agents, antistatic agents, organic or inorganic Flame inhibitors, plasticizers, dyes, colorants, talc, calcium carbonate, carbon black, mica, glass fiber, carbon fiber, aramide resin, asbestos, and other fillers known in the art. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs --------- install --- (Please read the precautions on the back before filling this page) The polypropylene used in the present invention can be further used with one or more Other thermoplastics are blended or combined. Suitable other thermoplastics include polyolefins, in particular polyethylene, other polypropylenes, polyesters, polypropylene amides, polyamides, polycarbonates, polyurethanes, polyacrylonitrile and succinylbenzene Ethylene. Higher polyethylenes include linear low density polyethylene. Although a preferred embodiment has been shown and described, it should be understood that it is not intended to limit the invention by such disclosure, but it is intended to include all modifications and alternative constructions within the spirit and scope of the invention as defined by the appended patent claims. .