1241731 本發明涉及一種金屬—处 ^ ^ 上 工乳電池，特別是一種易於製迕祓 可擴充以提供所需的輸出電壓和能量的全屬上:： 金麗~ ★各兩、 不月匕里的金屬一空氣電池。 - 工*電池通常用於長時 示了-種傳統的Hf、“ 的供$斜』闡 fi9^ 工礼電池的結構，其中包括一位於容 置匡1 6 2内的辞正極1 β /枝1 6 1。該容置E 1 Θ 2有兩個基 本透工的面163，各透处 ,合边工面上覆盍有一空氣負極16 ^ 1 6 2内充滿電解液’令辞極浸入其中。該空 氣負極1 6 4為—張塗有空氣負極材料-如活性碳一的金 屬’祠工虱負極工6 4的内側貼附一不織布製成的隔層。 因：二只有空氣可以流經空氣負極1 6 4，而電解液可保 持牡合置匣1 62内。以此配置’容置匣工62内會產生 化學反應’並經正、負導線166，167將電能引出。 因為在-矩形的容置E1 62上設置空氣負極丄“較為 ，難’所，傳統金屬—空氣電池不易製造。而且，為獲 :不同於單個電池規格的能量和冑出電Μ，須將多個電池 、〜接起來，並且需要較大的空間來放置這些電池，使得這 種金屬一空氣電池的使用也不甚方便。因此，需要對上述 的金屬一空氣電池作出改進。 本發明的一個目的在於提供一種模組化的金屬一空氣 也池，其包含多個電池模組，使之易於擴充以提供所需的 輪出電壓和能量。 本發明的另一目的在於提供一種模組化金屬一空氣電 池的製造方法，該電池包含多個便於製造的電池模組。 本發明的技術方案在於提供一種模組化金屬—空氣電 1241731 池’其特徵在於，包括： 至少-塊金屬板模組，其具有一封裝於一框體内的金 屬正極’該金屬模塊的框體的厚度大於該金屬正極的厚 度； 和一第二空氣板模組，其各有一封裝在 框體 第 内的空氣負極，各空氣板模組的框體的厚度大於該空 極的厚度； 、 …該第-空氣板模組，該至少為一塊的金屬板模組和該 第-空氣板模組以框體緊固結合在一起而至少形成兩個空 腔的方式組合成該金屬—空氣電池；以及 可^擇地被注入到該至少為兩個的空腔中的電解液。 ^前述的模組化金屬一空氣電池，其特徵在於，必要時 還可以依據使用之要求，調整設計並配置成為包括，至少 一塊再生板模組，其具有一封裝在框體中的金屬網，該再 生板模組的框體的厚度大於該金屬網的厚度，該至少一塊 再生板模組，該第一和第二空氣板模組和該至少一塊金屬 板杈組以該至少一塊再生板模組和至少一塊金屬板模組的 框體，被緊固土也夾持在第-和第二空氣板模組之間的方式 組合成該金屬一空氣電池。 前述的模組化金屬一空氣電池，其特徵在於，各空氣 負極貼附有一隔層，使空氣得以流入並可防止短路。 則述的模組化金屬一空氣電池，其特徵在於，該金屬 網的各面貼附有一隔層。 荊述的模組化金屬一空氣電池，其特徵在於，各框體 1241731 可=依據使用之要求，調整設計並配置成為具有進氣槽， 排氣槽，電解液注入槽和電極漿排放槽，或是以上各槽之 不同組合。 前述的模組化金屬一空氣電池，其特徵在於，還包 括，至少一正極導線，至少一個負極導線和可以至少一個 再生導線分別經過框體内適當的導電體和金屬正極，空氣 負極以及金屬網相連接。 前述的模組化金屬一空氣電池，其特徵在於，各空氣 板板組的空氣負極設置在其框架的側面。 前述的模組化金屬一空氣電池，其特徵在於，各空氣 板模組可以依據使用之要求，調整設計並配置成為設有突 出部一體形成在其框體上。 前述的模組化金屬一空氣電池，其特徵在於，各空氣 板模組的框體可以依據使用之要求，調整設計並配置成為 具有進氣道與框體的進氣槽連通，令空氣得以流入空腔 内，各再生板模組的框體可以依據使用之要求，調整設計 並配置成為具有棑氣道與框體的排氣槽連通，令氧氣和煙 霧得以棑出該空腔，煙霧則可被導入適當的凝結設備中去 除水分，可防止其中的大部分從電池系統中漏出，因此， 使得電池系統内的電解液濃度可以在更長的時間裏保持於 適當的範圍内，各金屬板模組的框體可以依據使用之要 求，調整設計並配置成為具有電解液注入道與框體的電解 液注入槽連通，令電解液得以注入空腔内，各金屬板模組 的框體可以依據使用之要求，調整設計並配置成為具有電 1241731 極漿排放道與框體的電極漿排放槽連通，令電極漿得以排 出空腔外。 W述的模組化金屬一空氣電池，其特徵在於，各空氣 板模組的框體可以依據使用之要求，調整設計並配置成為 具有進氣迢與框體的進氣槽連通，令空氣得以流入空腔 内，各再生板模組的框體可以依據使用之要求，調整設計 並配置成為具有排氣口與框體的排氣槽連通，令氧氣和煙 務得以排出σ亥空腔，煙霧則可被導入適當的凝結設備中去 除=分，可防止其中的大部分從電池系統中漏出，因此， 使得電池系統内的電解液濃度可以在更長的時間裏保持於 適田叫範圍内，各金屬板模組的框體可以依據使用之要 求，調整設計並配置成為具有電解液注X 口與框體的電解 液注入槽連通，令電解液得以注人空腔内，各金屬板模植 的框體可以㈣制之要求，調整設計並配置以具有電 極聚排放口與框體的電極紫棑放槽連通，令電極漿得以排 出空腔外。 則述的模組化金屬—空氣電池，其特徵在於，該至少 :塊金屬板模組包括一塊第一和一塊第二金屬板模組，而 違至少-塊再生板模組包括—塊再生板模組，該金屬一* 氣電:也由第一空氣板模組，第一金屬板模組，再生板： 組二金屬板模組和第二空氣板模組依次組合而成。 W述的模組化金屬一空氣電池，其特徵在於，該至少 一塊金屬板模組包括_塊金屬板模組，而該至少—塊再生 板模組包括一塊第一和一塊第二再生板模組，該金屬—空 1241731 氣電池由第一空氣板模組，第一再生板模組，金屬板模 弟一再生板模組和弟一空氣板模組依次組合而成。 前述的模組化金屬一空氣電池，其特徵在於，該至少 一塊金屬板模組包括一塊第一，一塊第二和一塊第三金屬 板模組，而該至少一塊再生板模組包括一塊第一和一塊第 二再生板模組，該金屬一空氣電池由第一空氣板模組，第 一再生板模組，金屬板模組，第二再生板模組和第二空氣 板模組依次組合而成。 前述的模組化金屬一空氣電池，其特徵在於，可以依 據使用電力與使用條件，採用該金屬板模組，該再生板模 、、且，該空氣板模組依次組合而成，不以上述之實施案例組 合為限。 本發明的技術方案又提供了一種模組化金屬一空氣電 池的製造方法，其特徵在於，包括： 一製造一空氣板模組的工序，其步驟包括： 從一薄臈卷展開一片薄膜； 在該片薄膜上沖出一透孔； 從一金屬網卷中切出一片金屬網； 將該金屬網貼附於該片薄膜上，使透孔被金屬網蓋 住； 將空氣負極材料塗在貼附於薄膜的金屬網上； 從一隔層卷中切出一片隔層； 將隔層貼附於金屬網上； 從薄膜卷上將薄膜切斷；以及 1241731 將薄膜裝設於一框體；以及 一製造一金屬板模組的工序，其步驟包括： 從一金屬網卷展開一片金屬網； 在該金屬網上塗以金屬粉末； 壓緊金屬網上的金屬粉末形成一塊金屬板； 從金屬網卷上將該金屬網切斷； 將金屬網裝設於一框體。 前述的模組化金屬一空氣電池製造方法，其特徵在 於’還包括一製造一再生板模組的工序，其步驟包括： 從一金屬網卷展開一片金屬網，該金屬網有兩個面； 從一隔層卷上切出兩片隔層； 將兩隔層分別貼附於金屬網的兩面； 從金屬網卷上將該金屬網切斷； 將金屬網裝設於一框體。 前述的模組化金屬一空氣電池製造方法，其特徵在 於’各片薄膜可由聚酯或其他適當之材料製成。 前述的模組化金屬一空氣電池製造方法，其特徵在 於’各片薄膜可由聚醯胺或其他適當之材料製成。 本發明的優點在於這種模組化的金屬_空氣電池，可 通過方便地將多個電池組合在—起進行擴充以提供所需的 輸出電壓和能量。 以下結合附圖進一步說明本發明的具體結構特徵和目 的，本發明以所附圖式配合較佳實施例之詳細說明後，其 實施方式、原理將對熟於此項技藝之第三人而言已屬充ς 1241731 揭露，然m，可被瞭解的是本發明之較佳實施例並非用以 限制本發明之實财式，故*舉切本發明之較佳實施例 作基礎而進行的任何改變、修飾或等效取代，只要不脫離 本發明之精神及所附申請專利範圍界定之内容者，均當屬 於本發明之專利範疇。 (一）圖式部份： 第一圖為本發明之模組化金屬一空氣電池的分解圖； 第二A圖為第一圖中一個金屬—空氣電池模組的立體 圖； 第一Bug第一圖中金屬—$氣電池模組另一形式的 立體圖； 第二A圖為第二a圖中金屬—空氣電池模組沿a a，的 剖視圖； 第一 B圖為第二A圖中金屬一空氣電池模組沿B B，的 剖視圖； 第四A圖為第一圖中所示之空氣板模組的立體圖； 第四B圖&第一目中所示之空氣板模組替代形式的立 體圖； 第五A圖為第四A圖中空氣板模組沿A A，的剖視圖； 第五B圖為第四A圖中金屬板模組沿B B，的剖視圖； 第六圖為本發明之模組化金屬—空氣電池的立體圖； 第七圖為第六圖所示之模組化金屬一空氣電池的剖視 Γ^Ί · 圖， 第八圖顯示了一由兩塊本發明之模組化金屬一空氣電 1241731 池組合成的電池組； 第九圖為本發明再生板模組的立體圖； 第十A圖為第九圖中再生板模組沿a a，的剖視圖； 第十B圖為第九圖中再生板模組沿B B，的剖視圖； 第十一圖為本發明之可充電式模組化金屬—空氣電池 的立體圖； ^ 弟一圖為第十一圖所示之可充電式模組化金屬一空 氣電池的剖視圖； 弟十二圖顯示了本發明之空氣板模組的製造過程； 第十四圖顯不了本發明之金屬板模組的製造過程； 第十五圖顯不了本發明之再生板模組的製造過程； 第十六圖為傳統鋅一空氣電池的立體圖。 一）圖號部份： 1〇)金屬一空氣電池 11)金屬板模組 (1 1 2 )框體 (1 2 )第一空氣板模組 (1 2 2 )框體 (1 2 5 )突出部 (1 3 )第一空氣板模組 (1 3 2 )框體 < 1 3 3 1 )薄膜 (134)金屬網卷 (1 3 5 )空氣負極材料 (1 〇 ’）金屬一空氣電池 (1 1 1 )金屬正極 (113)空間 (1 2 1 )空氣負極 (1 2 3)空間 (1 2 8)隔層 (1 3 1 )空氣負極 (1 3 3 )薄膜卷 (1 3 3 2 )透孔 (1 3 4 1 )金屬網 (1 3 6)隔層卷 I241731 (1 3 6 1 )隔層 (1 4)再生板模组 (1 4 2 )框體 (144)金屬網卷 (1 4 5 )金屬粉末 (1 4 7 )框體 (1 5 2 )框體 (1 5 3 1 )金屬網 (1541)隔層 (1 5 5 )框體 (211)進氣道 (2 2 1 )排氣道 (2 3 1 )電解液注入道 (2 4)電極漿排放槽 (2 4 2 )電極漿排放口 (6 2)負極導線 (71)空腔 (8 〇)空腔 (1 3 7)框體 (141)金屬網 (1 4 3 )空間 (1 4 4 1 )金屬網 (1 4 6 )金屬板 (15)第二金屬板模組 (1 5 3 )金屬網卷 (1 5 4)隔層卷 (1 5 4 2)隔層 (21)進氣槽 (2 2)排氣槽 (2 3)電解液注入槽 (232)電解液注入口 (2 4 1 )電極漿排放道 (6 1 )正極導線 (6 9 )再生導線 (7 2)隔層 第一圖為本發明之模組化金屬〜空氣電池的分解圖。 該電池包括一金屬板模組1 1，一第一空氣板模組1 2， 以及一第二空氣板模組1 3 ’二者的形狀與大小相同。參 看第二圖，金屬板模組1 1有一封裝在框體1 1 2内的至 少一個金屬正極111。框體112/112各界定有至 11 1241731 至少一個電解1241731 The present invention relates to a metal-based ^ ^ upper working milk battery, in particular to a genus that is easy to manufacture and expandable to provide the required output voltage and energy :: Jinli ~ Metal-air battery. -Industrial battery is usually used for a long time to show a kind of traditional Hf, "for the supply of oblique" to explain the structure of fi9 ^ Gongli battery, which includes a positive electrode 1 β / branch located in the housing 1 6 2 1 6 1. The accommodation E 1 Θ 2 has two substantially through-worked surfaces 163, each of which is covered with an air negative electrode 16 ^ 1 6 2 is filled with electrolyte, and the electrode is immersed in it. The air negative electrode 1 64 is a sheet of metal coated with an air negative electrode such as activated carbon 1. The inner side of the temple lice negative electrode worker 6 4 is attached with a non-woven separator. Because: only air can flow through the air The negative electrode is 164, and the electrolyte can be kept in the box 1 62. In this configuration, a chemical reaction will be generated in the box 62, and the electric energy is drawn out through the positive and negative wires 166, 167. Because the in-rectangle An air negative electrode is provided on the housing E1 62, which is "difficult and difficult." Traditional metal-air batteries are not easy to manufacture. Moreover, in order to obtain different energy and output power than a single battery specification, multiple batteries must be connected together, and a large space is required to place these batteries, making the use of this metal-air battery Very convenient. Therefore, there is a need to improve the above-mentioned metal-air battery. An object of the present invention is to provide a modular metal-air cell, which includes a plurality of battery modules, which can be easily expanded to provide the required wheel-out voltage and energy. Another object of the present invention is to provide a method for manufacturing a modular metal-air battery. The battery includes a plurality of battery modules which are easy to manufacture. The technical solution of the present invention is to provide a modular metal-air power 1241731 cell 'characterized in that it includes: at least-a metal plate module having a metal positive electrode enclosed in a frame' the frame of the metal module The thickness of the body is greater than the thickness of the metal positive electrode; and a second air plate module, each of which has an air negative electrode enclosed in a frame body, and the thickness of the frame body of each air plate module is greater than the thickness of the air electrode; ... the first air plate module, the at least one metal plate module and the first air plate module are combined into a metal-air battery in a manner that the frame body is fastened together to form at least two cavities. And an electrolyte that is optionally injected into the at least two cavities. ^ The aforementioned modular metal-air battery is characterized in that, if necessary, the design and configuration can be adjusted to include, at least one recycled board module, which has a metal mesh enclosed in a frame, The thickness of the frame of the recycled plate module is greater than the thickness of the metal mesh. The at least one recycled plate module, the first and second air plate modules, and the at least one metal plate branch group are based on the at least one recycled plate mold. The group and the frame of at least one metal plate module are assembled into the metal-air battery in such a manner that the fastened soil is also sandwiched between the first and second air plate modules. The aforementioned modular metal-air battery is characterized in that each air negative electrode is attached with a separator to allow air to flow in and prevent a short circuit. The modular metal-air battery described above is characterized in that a spacer is attached to each side of the metal mesh. Jingshu's modular metal-air battery is characterized in that each frame body 1241731 can be adjusted and designed to have an air intake groove, an exhaust groove, an electrolyte injection groove, and an electrode slurry discharge groove according to the requirements of use. Or different combinations of the above slots. The aforementioned modular metal-air battery further includes at least one positive lead, at least one negative lead, and at least one regenerable lead, which can pass through appropriate electrical conductors and metal positives, air negatives, and metal meshes in the frame, respectively.相 连接。 Phase connection. The aforementioned modular metal-air battery is characterized in that the air negative electrode of each air plate group is disposed on the side of its frame. The aforementioned modular metal-air battery is characterized in that each air plate module can be adjusted in design and configured according to the requirements of use so as to be provided with a protrusion integrally formed on its frame. The aforementioned modular metal-air battery is characterized in that the frame of each air plate module can be adjusted and designed according to the requirements of use and configured to have an air inlet communicating with the air intake groove of the frame, so that air can flow in In the cavity, the frame of each regeneration board module can be adjusted and designed according to the requirements of use, and configured to have a radon air channel communicating with the exhaust groove of the frame, so that oxygen and smoke can escape from the cavity, and the smoke can be removed. Introduction of appropriate condensation equipment to remove moisture can prevent most of it from leaking out of the battery system, so that the concentration of the electrolyte in the battery system can be maintained within an appropriate range for a longer period of time, each metal plate module The frame can be adjusted and designed according to the requirements of use, and configured to have an electrolyte injection channel in communication with the electrolyte injection tank of the frame, so that the electrolyte can be injected into the cavity. The frame of each metal plate module can be used according to the use. It is required to adjust the design and configure the electrode slurry discharge channel with electrical 1241731 electrode slurry discharge channel to the frame electrode discharge groove, so that the electrode slurry can be discharged out of the cavity. The modular metal-air battery described in W is characterized in that the frame of each air plate module can be adjusted and designed according to the requirements of use and configured to have an air inlet and a communication with the air inlet groove of the frame, so that air can be obtained. Flowing into the cavity, the frame of each regeneration board module can be adjusted and designed according to the requirements of use, and configured to have an exhaust port communicating with the exhaust groove of the frame, so that oxygen and smoke can be discharged from the σHAI cavity and smoke. It can be introduced into the appropriate coagulation equipment to remove = minutes, which can prevent most of them from leaking out of the battery system, so that the electrolyte concentration in the battery system can be maintained in the Shida range for a longer time. The frame of each metal plate module can be adjusted and designed according to the requirements of use, and configured to have an electrolyte injection X port to communicate with the electrolyte injection tank of the frame, so that the electrolyte can be injected into the cavity. The frame can be manufactured according to requirements. The design and configuration are adjusted so that the electrode poly discharge port is in communication with the electrode purple chute discharge slot of the frame, so that the electrode slurry can be discharged out of the cavity. The modular metal-air battery described above is characterized in that the at least: metal plate module includes a first and a second metal plate module, and at least-the regeneration plate module includes-a regeneration plate Module, the metal one * Pneumatic power: It is also composed of the first air plate module, the first metal plate module, and the regeneration plate: the two metal plate modules and the second air plate module are sequentially combined. The modular metal-air battery described in the above, wherein the at least one metal plate module includes a metal plate module, and the at least one regeneration plate module includes a first and a second regeneration plate module. The metal-air 1241731 gas battery is composed of a first air plate module, a first regeneration plate module, a metal plate mold, a regeneration plate module, and a brother-air plate module. The aforementioned modular metal-air battery is characterized in that the at least one metal plate module includes a first, a second and a third metal plate module, and the at least one recycled plate module includes a first And a second regeneration board module, the metal-air battery consists of a first air board module, a first regeneration board module, a metal plate module, a second regeneration board module, and a second air board module to make. The foregoing modular metal-air battery is characterized in that the metal plate module, the regeneration plate mold, and the air plate module can be combined in sequence according to the use of electricity and conditions of use, without using the above. The implementation case portfolio is limited. The technical solution of the present invention further provides a method for manufacturing a modular metal-air battery, which is characterized by comprising: a process of manufacturing an air plate module, the steps including: unrolling a film from a thin roll; A through hole is punched out of the film; a piece of metal mesh is cut from a metal mesh roll; the metal mesh is attached to the film so that the through hole is covered by the metal mesh; the air negative material is coated on the paste A metal net attached to the film; a piece of the interlayer cut out from a roll of the interlayer; affixing the interlayer to the metal net; cutting the film from the roll of the film; and installing the film on a frame 1241731 And a process for manufacturing a metal plate module, the steps include: unrolling a piece of metal mesh from a metal mesh roll; coating the metal mesh with metal powder; compacting the metal powder on the metal mesh to form a metal plate; and from the metal mesh The metal mesh is cut on a roll; the metal mesh is mounted on a frame. The aforementioned method for manufacturing a modular metal-air battery is characterized in that it further includes a process of manufacturing a recycled board module, the steps including: unrolling a piece of metal mesh from a metal mesh roll, the metal mesh has two sides; Cut out two sheets of interlayers from one interlayer roll; attach the two interlayers to the two sides of the metal mesh respectively; cut the metal net from the metal mesh roll; install the metal net in a frame. The aforementioned method for manufacturing a modular metal-air battery is characterized in that each film may be made of polyester or other appropriate materials. The aforementioned method for manufacturing a modular metal-air battery is characterized in that each of the thin films may be made of polyamide or other appropriate materials. The advantage of the present invention is that this modular metal-air battery can be expanded by conveniently combining multiple batteries together to provide the required output voltage and energy. The specific structural features and objectives of the present invention will be further described below with reference to the accompanying drawings. After the present invention is combined with the detailed description of the preferred embodiments with the accompanying drawings, the implementation and principle of the present invention will be for a third person familiar with the art It has been disclosed 1241731, but m, it can be understood that the preferred embodiment of the present invention is not intended to limit the real money of the present invention, so * anything based on the preferred embodiment of the present invention Changes, modifications, or equivalent substitutions, as long as they do not depart from the spirit of the present invention and the contents defined by the scope of the attached patent application, shall all belong to the patent scope of the present invention. (A) Schematic part: The first diagram is an exploded view of the modular metal-air battery of the present invention; the second diagram A is a perspective view of a metal-air battery module in the first diagram; the first bug is the first A second perspective view of the metal- $ gas battery module in the figure; the second A is a cross-sectional view of the metal-air battery module along the line aa in the second a; the first B is the metal-air in the second A A cross-sectional view of the battery module along BB ′; FIG. 4A is a perspective view of the air plate module shown in the first diagram; FIG. 4B is a perspective view of an alternative form of the air plate module shown in the first diagram; The fifth diagram A is a cross-sectional view of the air plate module along AA ′ in the fourth A; The fifth diagram B is a cross-sectional view along the BB ′ of the metal plate module in the fourth A; The sixth diagram is the modularization of the present invention A perspective view of a metal-air battery; the seventh figure is a cross-sectional view of the modular metal-air battery shown in the sixth figure, and the eighth figure shows a modular metal Battery pack composed of air power 1241731 battery; the ninth figure is a perspective view of the regeneration board module of the present invention; the tenth A The figure is a cross-sectional view of the recycled board module along the line aa in the ninth figure; the tenth B is a cross-sectional view of the recycled board module along the line BB in the ninth figure; the eleventh figure is a rechargeable modular metal of the present invention —A perspective view of the air battery; ^ Figure 1 is a cross-sectional view of the rechargeable modular metal-air battery shown in Figure 11; Figure 12 shows the manufacturing process of the air plate module of the present invention; Figure 4 does not show the manufacturing process of the metal plate module of the present invention; Figure 15 does not show the manufacturing process of the recycled plate module of the present invention; Figure 16 is a perspective view of a conventional zinc-air battery. A) Drawing number part: 10) Metal-air battery 11) Metal plate module (1 1 2) Frame body (1 2) The first air plate module (1 2 2) Frame body (1 2 5) protrudes (1 3) first air plate module (1 3 2) frame < 1 3 3 1) film (134) metal mesh roll (1 3 5) air negative material (1 0 ') metal-air battery ( 1 1 1) metal positive electrode (113) space (1 2 1) air negative electrode (1 2 3) space (1 2 8) interlayer (1 3 1) air negative electrode (1 3 3) film roll (1 3 3 2) Through-hole (1 3 4 1) metal mesh (1 3 6) barrier roll I241731 (1 3 6 1) barrier (1 4) recycled board module (1 4 2) frame (144) metal mesh roll (1 4 5) metal powder (1 4 7) frame (1 5 2) frame (1 5 3 1) metal mesh (1541) compartment (1 5 5) frame (211) air inlet (2 2 1) Exhaust duct (2 3 1) Electrolyte injection duct (2 4) Electrode slurry discharge groove (2 4 2) Electrode slurry discharge port (6 2) Negative lead wire (71) Cavity (80) Cavity (1 3 7 ) Frame (141) metal mesh (1 4 3) space (1 4 4 1) metal mesh (1 4 6) metal plate (15) second metal plate module (1 5 3) metal mesh roll (1 5 4 ) Partition roll (1 5 4 2) Partition (21) Intake tank (2 2) Exhaust tank (2 3) Electrolyte Injection tank (232) Electrolyte injection port (2 4 1) Electrode slurry discharge channel (6 1) Positive lead (6 9) Regenerated lead (7 2) Interlayer The first picture shows the modular metal ~ air battery of the present invention Exploded view. The battery includes a metal plate module 1 1, a first air plate module 12, and a second air plate module 1 3 ′, both of which have the same shape and size. Referring to the second figure, the metal plate module 11 has at least one metal positive electrode 111 enclosed in a frame body 1 12. Frames 112/112 each define up to 11 1241731 at least one electrolytic
屬正極1 1 1的各面界定有一空間丄工3。第三B圖一沿 第二A圖中b B，的金屬板模組丄丄的剖視圖一顯示了框體 少一個進氣槽2 1，至少一個排氣槽2 2， 液注入槽2 3和至少一個電極漿排放槽2 4 沿第二2 A圖中A A，的金屬煸馑鈿1 沾立 1 1 2在至少一個電解液注入槽2 3和空間丄^ 3之間具 有=少一個電解液注入道2 3 i，使得電解液注入槽2 3 與空間1 1 3連通。而且，框體i X 2在至少一個電極漿 棑放槽2 4和空間1 i 3之間具有至少一個電極漿排放道 2 4 1，使得電極漿排放槽2 4和空間1 1 3連通。如第 二B圖所示，在另一替代形式中，在框體丄i 2上形成至 少一個電極漿排放口 2 4 2。該電極漿排放口 2 4 2用以 4代％極浆排放道2 4 1使電極漿排放槽2 4和空間1 1 3連通。類似地在框體1 1 2上形成至少一個電解液注入 口 232 ’用以替代電解液注入道231使電解液注入槽 2 3與空間1 1 3連通。 第四圖顯示了第一空氣板模組1 2的立體圖。該空氣 板模組1 2具有一封裝在一框體1 2 2中的至少一個空氣 負極1 2 1。框體1 2 2上各界定有至少一個進氣槽2 1 ’至少一個排氣槽2 2，至少一個電解液注入槽2 3和 至少一個電極漿排放槽2 4。第五A圖一沿第四A圖中a A的弟一空氣板模組1 2之剖視圖一顯示了框體1 2 2的 厚度大於空氣負極1 2 1的厚度，從而在空氣負極1 2 1 12 1241731 的各面界定有一空間丄2 3。第五B圖—沿第四a”b B的第一空氣板模組丄2之剖視圖—顯示了框體丄2 2在 進氣槽2 1和空間i 2 3之間具有至少一個進氣道2工 1，使得在進氣槽2 1和空間丄2 3連通。與金屬板模組 1 1的框體1 1 2類似，在另一替代形式中，框體工2 2 上形成至少一個進氣口（未顯示），用以替代進氣道21 1使進氣槽2 1和空間i 2 3連通。也未限制該空氣負極 1 2 1須封裝在框體丄2 2内，將其設置在框體丄22的 側面亦可。第四B圖顯示了空氣板模組1 2的另一形式， 其中，在框體1 2 2的一侧面界定有突出部丄2 5 一體形 成在框體1 2 2上，而空氣負極1 2 ]_則設置在框體1 2 2的另一側面。 複請參看第一圖，第二空氣板模組丄3包括有封裝在 框體1 3 2内的至少一個空氣負極丄3丄，其結構與第一 空氣板模組1 2相同。 金屬板模組1 1被夾持在第一空氣板模組1 2和第二 空氣板模組13中，組成以框體122，112，132 緊固地結合在一起的金屬—空氣電池，如第六圖所示。各 框體122，112，132的進氣槽21成一直線。同 樣，各棑氣槽2 2 '電解液注入槽2 3和電極漿排放槽2 4都分別成一直線。因此，如第七圖一第六圖中金屬—空 氣電池的剖視圖一所示，該金屬一空氣電池内形成兩個由 金屬正極1 1 1隔開的空腔7 1。電解液經由電解液注入 槽2 3和電％液注入道2 3 1 (或電解液注入口 2 3 2) 13 1241731 注入這兩個空腔7 1内，同時金屬一空氣電池在排放過程 中產生的電極漿經由電極漿排放道2 4 1 (或電極漿排放 口 2 4 2 )和電極漿排放槽2 4排出。另外，可以看見各 空氣負極1 2 1，1 3 1貼附有一隔層7 2，令空氣可流 入空腔71同時防止電解液從空氣負極121，131流 出。 複請參看第六圖，該金屬一空氣電池設有分別穿過框 體1 2 2，1 1 2，1 3 2的至少一個正極導線6 1和至 少一個負極導線6 2。正極導線6 1經由至少一個適當的 導電體與金屬正極1 1 1電連接，負極導線6 2經由至少 一個適當的導電體與空氣負極121，131電連接。因 而，可以通過該各至少一個之正負極導線6 1，6 2獲得 電池的能量。 上述的金屬一空氣電池提供了預設的輸出電壓和能量 值。然而，如果需要不同的值，可以方便地將兩塊或更多 的金屬一空氣電池以類似於將空氣板模組1 2，1 3和金 屬板模組11組合的方式組合在一起。將上述金屬一空氣 電池10和一相同的金屬一空氣電池1〇,的組合如第八圖 所示，第一金屬一空氣電池1 〇的框架1 2 2附裝在第二 金屬一空氣電池10,的框架132上而將兩電池10，1 0,組合在一起。新鮮空氣可以經由進氣槽2丄和進氣道2 1 1進入兩電池4 0，1 0 ’之間的空腔8 〇内。 該金屬一空氣電池10可以通過包含一個或多個再生 板模組1 4轉換成一可充電電池。再生板模組1 4的結構 14 1241731 如第九圖所示。與金屬板模組i丄和空氣板模組丄2，工 3類似，該再生板模組丄4有一封裝在框體丄4 2内的金 屬網1 4 1。框體1 42各界定有至少一個進氣槽2 1、，' 至少一個排氣槽2 2，至少一個電解液注入槽2 3和至少 —個電極漿排放槽2 4。第十A圖一沿第九圖中AA，的^ 生板杈組1 4之剖視圖一顯示了框體丄4 2的厚度大於金 =網1 4 1的厚度，從而在金屬網丄4 的各面界定有一 空間1 4 3。第十B圖一沿第九圖*βΒ，的再生板模組工 4之剖視圖-顯示了框體丄4 2在棑氣槽2 2和空間η !之間具有至少一個排氣道2 2 1，使得排氣槽2 2與空 1143連通。與金屬板模組1 1的框體1 ip類似， 另一替代形式中，框體i 4 2形成至少—個排氣口（未顯 不），用以替代排氣道221使排氣槽22和空間143 連通。 第十一圖為一可充電式金屬—空氣電池的立體圖，該 f池包括依次組合的第-空氣板模組1 2，第-金屬板模 :1 1，再生板模組1 4，第二金屬板模組1 5，和第二 :氣《組1 3。參看第十二圖，該可充電式金屬一空氣 “ 疋有四個工腔71，電解液注入其中。金屬網14 1的兩面分別貼附有兩隔層1 2 8，防止充電過程中產生 =路復參看第十—圖，該可充電式金屬—空氣電池設有 :卿 122，112，142，152，132的至 再生V線6 9 °該再生導線6 9經由至少一個適當 的導電體與金屬網1 4 1電連接。因❼，該電池可以通過 15 1241731 至7個正極導線6 1和至少一個再生導線6 g進行充 ^充包過私中產生的氧氣和煙霧可以通過排氣槽2 2和 一氣C 2 2 1排出。然後煙霧可導入適當的凝結設備中去 除水刀，可防止其中的大部分從電池系統中漏出。因此， 電池系統内的電解液濃度可以在更長的時間裏保持於適當 的範圍内。 可充電式金屬一空氣電池並不限於上述結構。也可依 人由第一空氣板模組、第一再生板模組、金屬板模組、第 =再生板模組和第二空氣板模組組合成可充電式金屬一空 ，電池，或者依次由第一空氣板模組、第一金屬板模組、 第再生板模組、第二金屬板模組、第二再生板模組、第 二金屬板模組和第二空氣板模組組合而成。 此外，兩塊或更多的上述可充電式金屬一空氣電池可 以方便地經由各個框體内的適當的導電體組合起來獲得所 需的輸出電壓和電池能量。 上述的金屬一空氣電池或可充電式金屬—空氣電池的 結構適用於大規模生產。第十三圖顯示了生產空氣板模組 的過程。首先從一聚酯、聚醯胺或類似材料製成的薄膜卷 1 3 3中展開一片薄膜1 3 3 1。在該片薄膜上沖出一透 孔1 3 3 2。然後，從一金屬網卷丄3 4中切出一片金屬 網1341。該片金屬網1341貼在該片薄膜1331 上亚蓋住該透孔1 3 3 2。再將空氣負極材料丄3 5塗布 在貼附於薄膜1 3 3 1上的金屬網丄3 4丄上。隨後，從 一隔層卷1 3 6中切出一片隔層丄3 6 ，將該隔層工 16 1241731 6 1貼在金屬網1 3 4 1上。最後，將薄膜1 3 3 1從薄 膜卷1 3 3上切斷並封裝在一框體1 3 7内而組成一空氣 板模組。因為該薄膜卷尤其適用於自動化生產，所以可以 對空氣板模組12進行大規模製造。 第十四圖顯示了金屬板模組的製造過程。首先從一金 屬網卷1 4 4中展開一段金屬網1 4 4 1。將金屬粉末1 4 5塗抹在該金屬網1 4 4 1上。然後將金屬網1 4 4 1 上的金屬粉末1 4 5壓緊，而形成一金屬板丄4 6。最 後，將金屬網1 4 4 1從金屬網卷i 4 4上切斷並封裝在 一框體1 4 7内而組成一金屬板模組。 第十五圖顯示了再生板模組的製造過程。首先從一金 屬網卷1 5 3中展開一段金屬網1 5 3 1。從隔層卷；[5 4上刀下兩片隔層1541，1542。將隔層BA 1，1 5 4 2分別貼附在該金屬網丄5 3丄的兩面。最 =，將金屬網5 3工從金屬網卷丄5 3上切斷並封裝在 一框體1 5 5内而組成一金屬板模組。 17Each side of the positive electrode 1 1 1 defines a space masonry 3. FIG. 3B is a cross-sectional view of the metal plate module 沿 along bB in FIG. 2A, which shows that the frame has one less intake groove 21, at least one exhaust groove 22, and a liquid injection groove 23 and At least one electrode slurry discharge tank 2 4 A2 along the metal A1 in the second 2 A diagram 1 dipped 1 1 2 has at least one electrolyte injection tank 2 3 and a space 丄 ^ 3 with one less electrolyte The injection channel 2 3 i communicates the electrolyte injection tank 2 3 with the space 1 1 3. Further, the frame body i X 2 has at least one electrode slurry discharge channel 2 4 1 between at least one electrode slurry discharge groove 24 and the space 1 i 3, so that the electrode slurry discharge groove 24 and the space 1 1 3 communicate with each other. As shown in FIG. 2B, in another alternative form, at least one electrode slurry discharge port 2 4 2 is formed in the frame 丄 i 2. The electrode slurry discharge port 2 4 2 is used to communicate the electrode slurry discharge groove 24 and the space 1 1 3 with a 4th generation% electrode slurry discharge channel 2 4 1. Similarly, at least one electrolyte injection port 232 'is formed on the frame body 1 12 to replace the electrolyte injection channel 231 so that the electrolyte injection tank 2 3 communicates with the space 1 1 3. The fourth figure shows a perspective view of the first air plate module 12. The air plate module 12 has at least one air negative electrode 1 2 1 enclosed in a frame 1 2 2. Each of the frames 1 2 2 defines at least one air inlet groove 2 1 ′, at least one exhaust gas groove 22, at least one electrolyte injection groove 23, and at least one electrode slurry discharge groove 24. Fifth A. A cross-sectional view of a younger air plate module 12 along a A in the fourth A. A shows that the thickness of the frame 1 2 2 is greater than the thickness of the air negative electrode 1 2 1, so that the air negative electrode 1 2 1 12 1241731 defines a space on each side 丄 2 3. Fifth B—a cross-sectional view of the first air plate module 丄 2 along the fourth a ″ b B—shows that the frame 丄 2 2 has at least one air inlet between the air intake groove 21 and the space i 2 3 2 works 1 so that the air inlet 21 and the space 丄 2 3 communicate. Similar to the frame 1 1 2 of the metal plate module 1 1, in another alternative form, at least one inlet is formed on the frame 2 2. An air port (not shown) is used to replace the air inlet 21 1 to connect the air inlet groove 21 and the space i 2 3. The air negative electrode 1 2 1 is not restricted to be enclosed in the frame 丄 2 2 and is set. It can also be on the side of the frame 丄 22. Figure 4B shows another form of the air plate module 12, wherein a protrusion 丄 2 5 is defined on one side of the frame 1 2 2 and is integrally formed in the frame. 1 2 2 ， and the air negative electrode 1 2] _ is located on the other side of the frame 1 2 2. Please refer to the first figure. The second air plate module 丄 3 includes a package inside the frame 1 3 2 At least one air negative electrode 丄 3 丄 has the same structure as the first air plate module 12. The metal plate module 11 is sandwiched between the first air plate module 12 and the second air plate module 13, Composed of frame 122, 112,132 metal-air batteries fastened together, as shown in the sixth figure. The air inlet grooves 21 of each frame body 122, 112, 132 are aligned. Similarly, each tritium air groove 2 2 'electrolyte is injected The grooves 2 3 and the electrode slurry discharge grooves 2 4 are respectively aligned. Therefore, as shown in the first cross-sectional view of the metal-air battery in FIG. 7 to FIG. 6, two metal positive electrodes 1 1 are formed in the metal-air battery. 1 spaced cavity 7 1. The electrolyte is injected into the two cavities 7 1 through the electrolyte injection tank 23 and the electric liquid injection channel 2 3 1 (or the electrolyte injection port 2 3 2) 13 1241731. The electrode slurry generated during the discharge process of the metal-air battery is discharged through the electrode slurry discharge channel 2 4 1 (or the electrode slurry discharge port 2 4 2) and the electrode slurry discharge groove 24. In addition, each air negative electrode 1 2 1 can be seen, 1 3 1 is attached with a partition 7 2 to allow air to flow into the cavity 71 and prevent electrolyte from flowing out of the air negative electrodes 121 and 131. Please refer to the sixth figure. The metal-air battery is provided through the frame 1 respectively. 2 2, 1 1 2, 1 3 2 at least one positive lead 6 1 and at least one negative lead 6 2 The positive lead 61 is electrically connected to the metal positive electrode 1 1 1 via at least one suitable electrical conductor, and the negative lead 61 is electrically connected to the air negative electrodes 121, 131 via at least one appropriate electrical conductor. Therefore, each of the at least one The positive and negative leads 6 1 and 6 2 obtain the energy of the battery. The above-mentioned metal-air battery provides a preset output voltage and energy value. However, if different values are required, two or more pieces of metal can be easily converted into one. The air battery is assembled in a manner similar to the combination of the air plate modules 12, 13 and the metal plate module 11. The combination of the above-mentioned metal-air battery 10 and an identical metal-air battery 10 is shown in the eighth figure. The frame 1 2 2 of the first metal-air battery 10 is attached to the second metal-air battery 10 The two frames 10, 1 0, are combined on the frame 132. Fresh air can enter the cavity 80 between the two batteries 40,1 0 'via the air inlet groove 2 丄 and the air inlet 2 1 1. The metal-air battery 10 can be converted into a rechargeable battery by including one or more regeneration board modules 14. The structure 14 1241731 of the regeneration board module 14 is shown in the ninth figure. Similar to the metal plate module i 丄 and the air plate module 丄 2, 3, the recycled plate module 丄 4 has a metal net 1 4 1 enclosed in a frame 丄 4 2. The frames 1 42 each define at least one air inlet groove 2 1, 'at least one air exhaust groove 22, at least one electrolyte injection groove 23, and at least one electrode slurry discharge groove 24. The tenth figure A is a cross-sectional view of the raw plate branch group 1 4 along AA in the ninth figure. It is shown that the thickness of the frame 丄 4 2 is greater than the thickness of gold = net 1 4 1. The surface defines a space 1 4 3. Fig. 10B-A cross-sectional view of the regeneration panel module 4 along the ninth diagram * βB, showing that the frame 丄 4 2 has at least one exhaust duct 2 2 between the radon tank 2 2 and the space η! , So that the exhaust groove 22 is in communication with the empty 1143. Similar to the frame 1 ip of the metal plate module 11, in another alternative form, the frame i 4 2 forms at least one exhaust port (not shown) to replace the exhaust duct 221 and the exhaust groove 22 Connect with space 143. The eleventh figure is a perspective view of a rechargeable metal-air battery. The f cell includes a first air plate module 12 and a second metal plate mold: 1 1, a regeneration plate module 1 4 and a second plate. Sheet metal module 15 and second: gas "group 1 3". Referring to the twelfth figure, the rechargeable metal-air "has four working chambers 71, and the electrolyte is injected into it. Two sides of the metal mesh 14 1 are attached with two compartments 1 2 8 to prevent the charging process from occurring = Lu Fu refers to the tenth-picture, the rechargeable metal-air battery is provided with: Qing 122, 112, 142, 152, 132 to the regenerative V line 6 9 ° The regenerative wire 6 9 is connected to The metal mesh 1 4 1 is electrically connected. Because of this, the battery can be charged by 15 1241731 to 7 positive lead wires 6 1 and at least one regenerative lead wire 6 g. Oxygen and smoke generated during private use can be passed through the exhaust tank 2 2 and Yiqi C 2 2 1 are discharged. Then the smoke can be introduced into a suitable condensation device to remove the water knife, which can prevent most of it from leaking out of the battery system. Therefore, the electrolyte concentration in the battery system can be maintained for a longer period of time. Keep it in the proper range. The rechargeable metal-air battery is not limited to the above structure. It can also be used by the first air plate module, the first regeneration plate module, the metal plate module, and the third regeneration plate module. Combination with the second air plate module Rechargeable metal empty, battery, or in order by the first air plate module, the first metal plate module, the first regeneration plate module, the second metal plate module, the second regeneration plate module, and the second metal plate mold And the second air plate module are combined. In addition, two or more of the above-mentioned rechargeable metal-air batteries can be conveniently combined through appropriate electrical conductors in each frame to obtain the required output voltage and Battery energy. The above-mentioned metal-air battery or rechargeable metal-air battery structure is suitable for large-scale production. The thirteenth figure shows the process of producing air plate modules. First, a polyester, polyamide, or similar A roll of film 1 3 3 1 is unrolled from a film roll 1 3 3 made of a material. A through-hole 1 3 3 2 is punched out of the film. Then, a piece of metal mesh 1341 is cut out from a metal mesh roll 3 4 The sheet of metal mesh 1341 is pasted on the sheet of film 1331 to cover the through holes 1 3 3 2. The air anode material 负极 3 5 is coated on the metal mesh affixed to the film 1 3 3 1 丄 3 4 丄Next, cut out a partition from a partition roll 1 3 6 36, affix the spacer 16 1241731 6 1 to the metal mesh 1 3 4 1. Finally, cut the film 1 3 3 1 from the film roll 1 3 3 and encapsulate it in a frame 1 3 7 An air plate module is formed. Because the film roll is particularly suitable for automated production, large-scale manufacturing of the air plate module 12 can be performed. The fourteenth figure shows the manufacturing process of the metal plate module. First from a metal mesh roll Expand a section of metal mesh 1 4 4 1 in 1 4 4. Apply metal powder 1 4 5 to the metal mesh 1 4 4 1. Then press the metal powder 1 4 5 on the metal mesh 1 4 4 1 to form One metal plate 丄 4 6. Finally, the metal mesh 1 4 4 1 is cut from the metal mesh roll i 4 4 and packaged in a frame 1 4 7 to form a metal plate module. Figure 15 shows the manufacturing process of the recycled board module. First, a metal mesh 1 5 3 1 is unfolded from a metal mesh roll 1 5 3. Roll from the compartment; [5 4 up and down two compartments 1541, 1542. The spacers BA 1, 1 5 4 2 are respectively attached to both sides of the metal mesh 丄 5 3 丄. At most, the metal mesh 5 3 was cut from the metal mesh roll 5 3 and packaged in a frame 1 5 5 to form a metal plate module. 17