TWI241168B - Adduct having an acidic solution of sparingly-soluble group IIA complexes - Google Patents

Abstract

An adduct that has an acidic solution of sparingly-soluble group IIA complexes (""AGIIS"") and at least one additive. The AGIIS can be prepared by mixing a mineral acid (such as sulfuric acid), and a group IIA hydroxide (such as calcium hydroxide) or a group IIA salt of a dibasic acid (such as calcium sulfate), or a mixture of the two group IIA compounds, followed by removing the solid formed. The additives can be an alcohol, an organic acid or a surface active agent. The composition has various uses, including cleaning, food production, decontamination, bioremediation, agricultural application, medical application, and detoxification of substances.

Description

1241168 V. Description of the invention (1) " ------ Technical background This application is a serial number of 09/253, 241, which was filed on February 19, 1999, and will be re-applied. It is incorporated herein by reference. The present invention relates to an adduct, that is, a composition containing a slightly soluble Group I IA complex sanguo solution (AGIIS) and at least one additive, and also relates to a preparation method and use thereof. In the late 1970s and early 1990s, researchers in Japan developed strongly ionized water ("SIW") as a disinfectant. This SIW was confirmed to have a pH of 2.7 or lower, which has a pH of 1.0. 〇〇mv or higher oxidation-reduction potential energy, chlorine concentration is 0.8 ppm or higher. SI w is prepared by electrolyzing water. "Electrolytic tap water has been used to prepare" strongly acidic water "and" strongly alkaline " Water ", both of which are claimed to have antiseptic properties.

U.S. Patent No. 5,830,838 to Wurzb Urger et al. Describes a blue solution. The solution is prepared by mixing hydroxide and potassium hydroxide with water in water, and then passing the solution through an over-thinning of 10 microns; the obtained concentrated substance can be based on the surface oxygen of the metal to be treated. 5, 895, 78 2 describes a cleaning gold solution. = Solution of gold such as copper, brass, and high-strength alloys. Medium = Hydroxide and hydroxide are prepared with the same amount of sulfuric acid in ϋ: 5 The solution is prepared through a 10 micron filter. Rake or use after dilution. The paid substance can directly make the international publication WO 94/09798 describe a kind of pharmaceutical composition for treating diseases and damages 1241168 V. Description of the invention (2) Injury and other upset pharmaceutical compositions. The pharmaceutical composition includes a complex comprising a calcium-containing component and a sulfate-containing component in a pharmacologically acceptable carrier. This reference teaches the separation of inorganic components from natural substances such as peat. The inorganic group is an alkaline extract including a peat, an aqueous extract or an organic extract or a mixture thereof. At a temperature below room temperature up to the boiling point of the solvent ', peat is extracted using water> valley, organic solutions or water-miscible organic solvents. Preferred extraction solvents are those having a pH of at least 9. Χ-ray powder diffraction analysis was used to determine the biologically active component of the fractionated peat component.

CaS04 · 2Η20 (gypsum), cas〇 4 · K2S04 · 2Η20 (potassium gypsum, also called double salt of gypsum) and K3Na (S04) 2 (potassium mirabilite). This reference also describes the synthesis of potassium gypsum. Chemists describe and measure the ability of a substance to provide a proton [H +] to a chemical reaction as the pKa of the substance. Here, HA + H20 — H30 + + A- Although the hydrogen ion is usually represented by H + or H3〇 +, its true molecular formula Is uncertain. The aggregate can be h5o2 +, h7o3 +, or even H904 +. The ability to generate large amounts of positively charged water is important in many applications where water is the reaction medium. Positively charged water has the ability to donate protons [H +]. Proton donation is usually an intermediate step in any acid hydrolysis reaction. Acids are usually chemical reagents used to provide protons in aqueous solutions. If water can be a source of [H +], very few undesirable by-products (poisons) are produced from the reaction and the use of these products is less harmful. Use strong acids to neutralize and remove lime or quicklime from bricks and mortar. Strong

1241168

V. Description of the invention (3) Acids, such as hydrogen acid ’一-人 _v ^ J 4 ~,‘ Yueyou cup bath eight block, windows, glass, bathroom, urinals, mirrors and other surface knife hard water stains. Hydrochloric acid can also be used to dewater water towers and heat exchangers to adjust the pH of wastewater effluents. Very strong inorganic acids, such as hydrogen, decompose many objects, including metals. In addition, a low suppression of about 0.5 may cause burns to human skin within seconds. This acid releases smoke = chloric acid film, which is also very harmful. If placed near other chemically sensitive sticks such as bleach, hydrochloric acid will interact with them: plastic bottles like Lepin. θ through a prisoner

邛 The main moon 艸 艸 隹 里 Lili sexual source or H3〇 +, ρ has these undesired defects and can reduce the danger with acid ^ =. Preferably, the "acidic" source should be re-contaminated without mutagenesis of antibacterial properties, without changing the v 迢, color or odor of the mouth: no strangeness in the water within the range of degrees It is effective. When it is excessive, it can be neutralized afterwards, without carcinogenicity and mutagenicity. It is almost harmless in water and environment. It does not affect the plastic, ",, t

Stored for a long time, and will not decompose or transform into harmful: Wuya and in many practical situations, it is necessary to control the growth of microorganisms, and the entire research of ::: has been in agriculture, medicine and food; science :: !! Controlling growth means preventing microbial growth. One of the basic ways to implement: (" By killing micro: objects Λ (2) By inhibiting the growth of microorganisms. Physical or chemical tests to control growth, or to die or prevent microorganisms from growing, use Jiang 4 branch dead cells Try

1241168 V. Description of the invention (4) It is called "killing is called" static "" bacteriostatic "refers to" fungicide "sterile or does not include the use of heat and methods in sterilized objects. Microbial membranes" Adhesive materials and instruments show the true meaning of viruses, viruses, and concerns. The product in question is a film of required materials or a solid waste that can reflect the purification of nutrients. As it is here, or to promote life, examples of human food include drinks, food additives, flavor enhancers, and other substances. Nutrition 'agents; inhibitors of cytokines. The term "killing inhibits the growth of bacterial cells and kills the true essence." All survival on sterilization or above is sterile, where no radiation or chemicals or migration of heterogeneous microbial aggregates on different surfaces are formed. Protozoa in biofilms. Thanks to eating anything that helps solve the problem. Eliminate and control existing health goals. Also as the organism cannot survive, the term Chang and Restorative organic organisms and animal feeds are all ingredients, food additives, agents, feed additives, fillers, food condiments can be derived from plant growth without killing them. "Reagent bacteria" refers to killing bacteria, while "fungicide" kills bacteria, "is to completely destroy or destroy the organism in question. The object may be extinct. The sterilization step is the physical removal and reproduction of microorganisms, which is called "raw. Biofilm can be used in food, words of microorganisms can include bacteria, and the safety of the material is the best choice in China. Many harmful problems related to food production hide the harmful microorganism "The hope of sewage production is to make water and nutrition safe by lowering the pH value to the level" refers to the natural depleting substances that nourish and treat. Examples of nutritional products. Other nutritional products Feed additives, beverages, beverage additives, condiments, flavors, music products, biological products and their, animal or synthetic. Currently in ^

Page 9 1241168 V. Description of the invention (5) Used in the field, ammonia, organic iron di and herbicide products include chlorine 'type, which can be detected by imitation of sigma / dagger. Hope there is a way to exist. In addition, 2 acid hydrolysis eliminates these residues without harmful chemicals, which is expected to produce very small amounts of harmful volatile gases. It grows and kills microbiotics. It can control the production of microorganisms. For example, it can simultaneously destroy the microorganisms produced by the microorganisms or have an outline of the invention with the microorganisms. Content 11 ^ # ~ 成 物 'It is a species containing The composition of the acidic solution ("AGIIS") of the microparticle Λ and the additive 4 added 刎 to a certain extent enhances the effectiveness of AGIIS, and has a multiplicative effect on the efficacy of AGI IS>. Other aspects of the invention relate to different methods by which the safety, cleanliness, and environmental sensitivity of chemical production, pharmaceutical production, cleaning, food production, purification, biomedicine, agricultural applications, medical applications, and disinfection of various substances can be improved. . Detailed description of the invention

One aspect of the present invention is an addition of an acidic or low-p Η bath (AG 11S) containing a sparingly soluble Group A complex and an additive. The solution may be a suspension of very fine particles, the term " "Low suppression" means that the pH is below 7 "in the acidic range. The dehydration effect of the AG I I S of the present invention having a certain acid equivalent concentration is different from that of a sulfuric acid solution saturated with calcium sulfate having the same acid equivalent concentration. In other words, the AGIIS of the present invention having a certain acid equivalent concentration Page 10 1241168 V. Description of the invention (6) It is not as easy to carbonize to sucrose as a saturated solution of calcium sulfate in sulfuric acid with the same equivalent concentration. In addition, AG I I S is not volatile at room temperature. It is less corrosive to human skin than sulphuric acid saturated with calcium sulfate at the same acid equivalent concentration. Without wishing to be bound by theory, one approach to AG IIS can be considered to include near-saturated, saturated, or supersaturated calcium, sulfate anions or their variants, and / or calcium-, sulfate-containing complexes, and / or their Variants. The term "complex" as used herein means a composition in which the individual components are interrelated. "Interrelated, means that the components are bonded to each other by covalent or non-covalent bonds, and the latter is the result of hydrogen bonding or other intermolecular forces. The components can be ionic, non-ionic, hydrated or other Form exists. An acidic solution of slightly soluble Group IIA complex salt ("AG 丨 丨 s ,,") can be prepared in several ways. Some methods include the use of Group IA hydroxides, while some synthetic methods avoid the use of any added Group A hydroxides, although small amounts of Group IA metals may be present as "impurities". Adding a Group I-A hydroxide to the mixture is not the preferred way to prepare AG 11 S. As implied in this paragraph, AGI IS is strongly acidic, ionic, and has a pH below about 2. WurZburger et al., U.S. Patent No. 5,83,838, describe an acidic solution prepared by the "oxygen M / potassium hydroxide method". This solution was first added with 2 moles of concentrated sulfur in 2 liters of deionized water. Separately, pass through 20 liters of deionized dressing solution with stirring. Then, the acid solution is dissolved with the water particles of the test: // Λ 溶 test. According to the degree of emulsification of the surface of the metal to be treated: t; ㈣ particles or potassium sulfate particles, the obtained concentrated solution can be

1241168 V. Description of the invention (7) 3 Do not use 5 or dilute with water. It is possible to use sodium hydroxide instead of hydroxide. 厶 = use hydrated calcium oxide instead of calcium hydroxide. Another source of alkali is, in some cases, the obtained solution is a strongly acidic solution. This is an embodiment. The strongly acidic solution can be diluted with water, i.e., the pH to a desired higher value, for example, weakly acidic. Including the other method of Ϊ: Ϊ raw solution is through the "calcium metal method", 1 packet is slowly added to 1 Mo cut ΐ $ Under stirring, the solution is slowly dissolved in the sulfuric acid solution. / Shavings. Continuous stirring was continued until substantially a mixture of all gold was cleared for about 5 to 6 hours, and 0.5 was obtained. Then, the pH value of the served product is about H. The concentrated sound of dilute hydronium ions with deionized water is used. The pH value is, for example, about i or about ^. The compound ϊ, which is required by the master, is the reaction of concentrated sulfuric acid in hydrogen and hydrogen in water, and is mixed under stirring; ^ Dilute 1 mole of concentrated sulfuric acid with 4 ° mole of deionized water. ; Stir until 1 mole of calcium hydride is slowly added to the mash solution. Continuous feed = 5 to: "Base: completely dissolved. Qiu Qi of the paid material: lye. Released from this. It can be further diluted by the calcium-metal method, or the" calcium-hydride method ". f ^. --- •• M; 3 ^ page 121241168 V. Description of the invention (8) The "calcium-metal method" and "calcium-hydride method" have some defects. In each of these methods, Because concentrated sulfuric acid reacts with calcium metal or hydrogenated hydrogen to generate a large amount of heat, it is very difficult to perform thermal control. The difficulty in the thermal control of the reaction makes the reaction difficult to reproduce and difficult to control. The preferred method for preparing AGI IS includes inorganic acids and Group IIA hydroxides are mixed, or mixed with a group 1 1 A salt of a dibasic acid, or a mixture of two Group IIA materials. When mixed, a Group 1 IA salt is also formed. Preferably, the selected The starting Group IIA substance will produce or form a slightly soluble Group A salt in water. The preferred inorganic acid is sulfuric acid, the preferred Group IA hydroxide is calcium hydroxide, and the preferred diacid is 1 1 Group A salts are calcium sulfate. Examples of other Group I salts include oxygen Hua Ma, Carbonated Mai and Carbonated Rat's Bow. Therefore, for example, AGI IS can be prepared by mixing the raw materials given in one of the following classification tables, which has good reproducibility: '(1) H2S04 and Ca (OH ) 2; (2) H2S04, Ca (OH) 2 * CaC03; (3) H2S04, Ca (OH) 2, CaC03 and C02 (gas); (4) H2S04 and CaC03; (5) H2S. 4.CaC03 and Ca (OH) 2; (6) H2S04, CaC03 and C02 (gas); (7) H2S04 and CaS04; (8) H2S04, Ca (OH) 2 * CaS04; (9) ) H2S04, CaS04 * CaC03; (10) H2S04, CaS04, CaC03, and Ca (OH) 2; (11) H2S04, CaS04, CaC03, and C02 (gas), and

Page 13 1241168 V. Description of the invention (9) (12) H2S04, CaS04, CaC03, C02 (gas) and Ca (OH)

Therefore, it is preferred to prepare AGIIS by mixing calcium hydroxide with concentrated sulfuric acid, with or without adding an optional diacid group IIA salt (such as calcium sulfate) to the sulfuric acid. Before adding calcium hydroxide to the mixture, optional sulfuric acid may be added to concentrated sulfuric acid. The addition of sulfuric acid to concentrated sulfuric acid seems to reduce the amount of calcium hydroxide required for the preparation of AG 11 S. Other optional reagents include acid breaks and gases that can be blown into the mixture. Although any optional reagent can be used, the use of calcium hydroxide has been found to be most suitable. A preferred method for preparing AG IIS can be briefly described as follows: In a reaction vessel, add concentrated sulfuric acid in cold water (8 to 12 ° C), and then add calcium sulfate to the acid in the cold water with stirring to obtain a mixture. . Temperature control is essential for this method. Then in this stirred mixture

Add an aqueous slurry of hydroxide. The solids formed are then removed from this mixture. This method involves the use of sulfuric acid, sulphuric acid, and hydroxide, and has several unexpected advantages. First, the reaction is not violent and does not release a large amount of heat. In addition to being easy to control and easy to reproduce, each ingredient used in this reaction has been approved by the U.S. Food and Drug Administration ("U ς fda") and has been identified as "Q ra S," ). Therefore, each ingredient can be directly added to the food, when the bran has a certain limit. At the appropriate concentration T ', each ingredient can be used as a processing aid and can be used in food contact agents. Their 庳Use is limited only by production adaptability and commercial manufacturing practices ("GMP"). Because 1241168 V. Description of the invention (10) This' AG IIS prepared in this way is safe for animal consumption and is a processing aid It is safe and safe in food contact agents. In addition, AG IIS reduces biological contaminants not only by inhibiting microbial growth or killing microorganisms but also by destroying toxins formed and produced by microorganisms. The formed AG IIS can be stored, Or extend the shelf life of consumables such as plants, animals, drugs or biological products. It can also preserve or improve the Sensory quality. It also has a certain healing and therapeutic use. The sulfuric acid used is usually 95 to 98% FCC grade (about 35 to 37N). The content of concentrated sulfuric acid is about 0. 005M to about 18M (about 0. 1 N to about 3 6 N), preferably about 1 M to about 5 M. It depends on the application. The term "%" used refers to a molar concentration or mole / liter.

Normally, a slurry (about 50% W / V) of finely ground calcium hydroxide suspended in water is the preferred way to gradually add argon calcium oxide to a stirred sulfuric acid solution (with or without calcium sulfate). In general, the reaction is carried out at a temperature of 40 or less, preferably at a temperature lower than room temperature, and more preferably at or below 0 t. The time for adding the hydroxide is about 1 to 4 hours. The stirring speed is about β 00 to about 700 r pm or higher. After mixing, the mixture was filtered through a 5 micron filter. Ran Jun left the filtrate and liquid overnight 'and removed the fine sediment by decantation. 1 The calcium hydroxide used is usually about 98% of 1 ^ (: grade. For each mole of concentrated acid such as sulfuric acid, the molar amount of dicalcium hydroxide used is according to the application 'and its range is about 0.1. Up to about 1. Optional calcium carbonate is usually 1? (:(: grade) with a purity of about 98%. As described above, when used with calcium hydroxide, for each mole of concentrated acid such as sulfur

Page 15 1241168 V. Description of the invention (11) The amount of acid and calcium carbonate used varies from about 0 () 01 to about 0.2 according to the amount of calcium hydroxide used. The optional carbon dioxide is bubbled into the slurry of calcium hydroxide at a speed of about 1 to about 3 pounds. Carbon dioxide was bubbled into the slurry for about 1 to 3 hours. Then, the slurry was added to a reaction vessel containing concentrated sulfuric acid. ^ Other optional components are calcium sulfate, a group IA salt of a dibasic acid. Usually, dihydrate of calcium sulfate is used. The word "thionite calcium or molecular formula" CaS04 "used in this application refers to anhydrous or hydrated calcium sulfate. The purity of the calcium sulfate (dihydrate) used is usually 95 to 98% 1? (: (: Grade. Calcium sulfate content (mole / liter) in concentrated sulfuric acid is about 0.0005 to 0.15, preferably about 0.007 to 0.07, and more preferably about 0.07 It is based on the application and the test data is known. The generated slope represents the ratio of calcium hydroxide to concentrated sulfuric acid required for the final desired acid concentration of AGIIS, see Figure 1. The slope of Figure 1 is Titrate a given amount of acid to the required final acid equivalent concentration, and the two sets of data points are obtained. The accuracy is determined by the chemical method. The final acid equivalent concentration of the final product is about 丨 · 2 to 29. For production For 1 liter of 1 · 2N AGIIS, it is found that for each mole of concentrated sulfuric acid, calcium hydroxide is required. In order to prepare 1 liter of 27N_IIS, it is found that for each mole of 2.12 moles of hydroxide, the data is then plotted on the seatpost.

The axis represents! Mole concentrated thiosulfate II VY axis Table :: acid equivalent concentration of agricultural end, X f emulsified about the number of moles, of which K45, (U) / α ^) obtained 2. , 7: ^ is the formula for women's acres using the slope w-78-18. The straight line is given by the equation

1241168 V. Description of the invention (12) ----- Y--mx + b means, where mx is the slope and 13 is the ¥ wearing distance. The highest acid equivalent concentration is 36 · 65, so the equation is Y = -78 · 18X + 36 · 65. AGI IS solution This concentration is useful for preparing the desired acid equivalent. In a nutshell, having the most required method includes the steps given below. Calculate the number of moles of acid (concentrated sulfuric acid) and base (ratio to acid per mole). The steps are as follows: Preparation of AGIIS with a final acid equivalent concentration. The final volume of AGI IS is 1 liter.

(a) Determine the molar amount of inorganic acid (eg,% sulfuric acid) required to prepare AGIIS at the final acid equivalent concentration ("N") by using the relationship given by the following formula: E1 = (N / 2) + (N / 2 + B) where is the amount of acid (mole) required before modifying the purity or purity adjustment; N is the required final acid equivalent concentration ·, B is the I IA group required to obtain "115 with N The molar ratio of hydroxide to inorganic acid, for the desired final N'B is a preform that depicts the relationship between inorganic acid and ί 丨 a hydroxide.

得 ，，，，. And (b) Purity adjustment of the inorganic acid used. The correction of the purity of the acid used is achieved using the following formula ...

E2 = E! / C where E2 is the amount of acid (mole) required after correction of purity or purity adjustment; E! Has the same meaning as above; and c is the purity adjustment factor for the acid used. Correct

Page 17 1241168 V. Description of the invention (13) For concentrated sulfuric acid, the average acid strength is about 96.5%, so C is 0.96 5; (c) determine the amount of water (ml) added to the acid After the reaction, the acid solution will obtain the desired final acid equivalent concentration N. The relationship is as follows:

G II J-E2-I where G is the amount of water that needs to be added to the inorganic acid solution to obtain the desired final acid equivalent concentration; J is the final volume of the aqueous inorganic acid solution; I is the volume of the required ΠΑ hydroxide (See below); e2 has the same meaning as above; (d) G is added to obtain the final aqueous solution of the inorganic acid, where G and E2 have the same definitions as above; (e) the reaction is prepared to have the desired final acid equivalent concentration N The amount of alkali (eg calcium hydroxide) required for the AG I IS (molar). For example, the molar ratio of calcium hydroxide to concentrated sulfuric acid at a certain final acid equivalent concentration can be calculated from the straight line in FIG. The required quantities (in moles) are:

F ^ N / 2 XB where Fi is the required alkali content (mole) and N * B has the above meaning; (f) The purity correction used in the test is achieved by the following equation:

F2 = F1 / D where F2 is the verification (mole) required after modifying the purity or purity adjustment of the base used; D is the purity adjustment factor of the verification used. The average purity of sodium hydroxide is about 98%, so in this case D is 0.98; (g) the amount of water (ml) required to prepare the alkaline slurry. The relationship is as follows:

Page 18 1241168 V. Description of the invention (14) H-F2 X 1.5. Where Η is the volume (ml) of water required to prepare the alkali slurry, which in turn will be used to obtain the desired final acid equivalent concentration AGIIS of Ν. F 2 has the same meaning as above. The Η given is approximate and should be adjusted to the desired final weight volume. So, for example, the final volume of 50 grams of base should be adjusted to 100 milliliters, because the slurry used is a 50:50 mixture of solids and water; (h) sure to be added to the acid solution to obtain Volume (ml) of alkaline slurry or solution of AGI IS with the desired final acid equivalent concentration N. The relationship is as follows: I-F2 X 2 where I is the volume (ml) of the alkaline slurry or solution added in the acid solution, and F2 has the above meaning; (i) Η is added to F 2 to obtain the final water content of the test. A slurry or solution, where is it? 2 Both have the above meanings; (j) adding the final aqueous solution or slurry (i) to the final aqueous solution (d) of the inorganic acid; (k) making the final aqueous solution or slurry and the inorganic acid The final aqueous solution (j) is reacted; and (l) the solid formed by reaction (k) is removed. In the case where sulfuric acid is used in the reaction by adding calcium sulfate to a concentrated sulfuric acid solution, the content of sulfuric acid (in grams / liter, based on the final volume of the solution) follows the following relationship:

1241168 V. Description of the invention (15) Calcium sulfate content (g / 5 4 3 2

Acid equivalent concentration of final AGI IS N I- 5 6-10 II- 15 16-20 21-36

The acid equivalent concentration of the obtained AGI IS ranges from about 0.05 to about 31; the pH is below 0; the boiling point is about 100 to about 106 ° C; the freezing point is about -8 to 0t. The analysis results (average) of AGI IS obtained by using the reaction of H2S04 / Ca (0H) 2 / CaS04 are as follows: The final acid equivalent concentration is 1.2N and the pH is -0.88 AGIIS Η30 +, 2.2%; Ca, 602 ppm; S04, 73560 ppm; K, 1.36 ppb; impurities, 19.68 ppm; no Na or Mg was detected.

The final acid equivalent concentration was 29N and the pH was -1.46 AGIIS H30 +, 30.68%; Ca, 52.9 ppm; S04, 73 5560 0 ppm; κ, 3 8 · 0 2 ppb; no Na or M g was detected .

In addition to concentrated sulfuric acid ', other polybasic acids can also be used, such as dishic acid, phosphonic acid, chloric acid, iodic acid or other acids.

Likewise, other qualitative or qualitative aqueous solutions can be used, such as a Group I A hydroxide solution or slurry and a Group I A A hydroxide solution or slurry.丨 A and I IA are two families in the periodic table. Preferably, a Group IA hydroxide is used. It is preferred that the salt formed by the group I I A hydroxide used in the reaction is slightly soluble in water. It is also preferred to add IA using only Group IIA hydroxide as a base

1241168 V. Description of the invention (16) Group NOx. ), Obtained with a relatively low Qiu value (generally below pH1 J 4 Valley liquid can be diluted with deionized water to the desired pH value, for example, the pH is about 1 or 1.8. Very concentrated AGns_, and then Ϊ: ΐ ϋ diluted to obtain a solution with the desired final acid equivalent concentration. Through the method described in this application, the AGI IS solution with the final desired acid acid is prepared. This eliminates the need to dilute the product before use.

As discussed above, at the same sulfuric acid concentration, AGIIS has lower dehydration properties (such as carbohydrate) compared to saturated solutions of calcium sulfate. In addition, the fact that the AGI IS of the present invention is stable and non-corrosive can be proved by the fact that a person puts his hand in an AGHS solution with a pH lower than 0.5 without any irritation and damage to the hand. On the other hand, if a person puts his or her hand in a sulfuric acid solution with a pH lower than 0.5, it is irritating in a relatively short time. A 28N sulfuric acid solution saturated with calcium sulfate will cause chemical burns on human skin after a few seconds of contact. In contrast, A G 11 S solutions with the same equivalent concentration did not cause chemical burns on human skin even after 5 minutes of contact. The AG I I S of the present invention does not appear to be corrosive when in contact with the environmental protection layers of plants and animals (plant epidermis and animal skin). AGIIS is non-volatile at room temperature. Even at a concentration of 29N, AG I I S is odorless, does not emit smoke in the air, and does not pungent when smelling the concentrated solution. The "additives" of the present invention appear to enhance the effectiveness of AG I I S and also appear to have a multiplicative effect on the effectiveness of AG I I S. Examples of the additive include alcohol,

Page 21 1241168 V. Description of the invention (17) Organic acids, iodic acid and surfactants. The amount of the additive added to the AGI IS varies depending on the final weight% of the desired additive in the final addition composition. The weight% of the additive required in the addition composition of the present invention is about 0.009 to 99.9 g based on the total weight of the final addition composition. On the one hand, if an additive is added to AG I I S with a low pH value, the amount of the additive must be adjusted to further dilute with water to increase the pH of the final addition composition. Preferred alcohol additives for the present invention include methanol, ethanol, propanol, isopropanol, and other lower alkyl alcohols.

The organic acid additive j of the present invention includes a carboxylic acid. A carboxylic acid is an organic compound containing a -carbonyl group, that is, a carbonyl group on the bond 6 to L group. Preferred organic acids of the present invention include lactic acid, acetic acid, propionic acid, oxalic acid and peracetic acid. Primitive surfactants are surfactants. It is usually composed of two knives, organic compounds: one is the hydrophobic part, which usually includes long hydrocarbons. Sister: = make the compound fully dissolved or dispersed in water or other polar solvents, " ’° minutes. Surfactants are generally divided into ... (1) anionic surfactants, which are composed of 2 * sundial ^ ^ ^ "The hydrophilic part of a knife is negatively charged; (2) cationic surfactants, and are composed of 2丄, 、, 的 with a positively charged portion of the knife; and (3) non-isolated f tf sex agent 'It does not dissociate, but usually from polyhydroxy or polyethoxy

:, Ren Ke Yi 丨 the hydrophilic part of the daggers. Other surfactants include zwitterionic surfactants called k: and zwitterionic surfactants. The preferred surfactant of the present invention is urethoxy ether (Tween 80).

The amount of each ingredient or component of the present invention is based on the final ^^, usually after further dilution to obtain the desired pH of about 1.8, J '' Percent based. AG I I S at a pH of about 1.8

1241168 V. Description of the invention (18) Further dilution with water before using animal or plant products. One method of preparing an AGIIS concentrate with an ethanol additive and a lactic acid additive is to make 634mL of 20 standard strength (proof) FCC ethanol (16.5% by weight) at room temperature under stirring; 75mL 85% Lactic acid (1.9% by weight); 1536mL of AGIIS solution (40% by weight) with a pH of about 0.2-0.4; and 1595mL of deionized water (41.5% by weight) were mixed. The pH value of the obtained AG I IS concentrate with two additives was about 1.65-1.8. One method of preparing an AG I IS concentrate with ethanol, lactic acid, and Tween 8 0 (T wee η 8 0) additives is to make 634 mL of 200 proof FCC ethanol at room temperature under stirring ( 16.5% by weight); 75mL 85% lactic acid (1.9% by weight); i 9 20mL human 0118 solution (50% by weight) with a pH value of about 0.2_0.4; 255111 [Tween 80 (6.6 % By weight); mixed with 95.7 mL of deionized water (25% by weight). The obtained AGI IS concentrate having three additives had a pH of about 1.45 to 1.7. Biofouling refers to biological organisms, or products of biological organisms, such as toxins, or both, all of which pollute the environment and useful products. Biological contaminants can be harmful to the environment or products. Biological contaminants such as bacteria, fungi, mold, mildew, spores and viruses have potentially active substances in their cell walls / membrane; however, they hide in cells (viruses and some bacteria) and / or secrete biofilms (most bacteria : Fungi, molds, and mildew) to protect them from environmental damage. Bacteria form or synthesize intracellular and extracellular toxins. Toxins are toxic or toxic substances formed or synthesized during bacterial generation and growth: they are (丨) fine

1241168 V. Description of the invention (19) The whole part of the bacteria indicates that these two emotions 'the chemical group of the essence itself' and the disinfectant which is toxic to the product, such as endotoxin, has no effect on releasing humans and animals from bacteria, resulting in production, The small number of "purification" of medical devices is not enough to destroy the poison of bacteria and destroy the growth of toxins in the fixtures and equipment, such as toxins). The composition of ^ is usually and comes from the harm if the quaternization is in fact caused by severe and other bacterial infections. Both biological and environmental pollution are necessary and must be eliminated in addition to the extracellular products (exotoxin) of bacteria or (3) :. Often toxins are quite complex antigens that are unknown. The harmful effects of bacteria not only come from toxins produced by bacteria. The toxic I produced by bacteria is greater than and at least the same as that of the bacteria themselves. Conventional a substances will kill bacteria, but for bacterial toxins and men, many disinfectants actually exacerbate the problem by eliminating endotoxins. Bacterial toxins and endotoxins have adverse effects. Endotoxin is a major factor in the contamination of food, pharmaceutical and medical products. Therefore, when the amount of f0 is $, it is only necessary to simply kill or reduce the bacteria to obtain a safe and purified product, and it must also be f. Whether it is killing microorganisms alone or only 2 ',. In order to be more effective, when reducing nutrition, it is necessary to control and reduce biological organisms to remove and / or destroy the products of biological organisms (for example, the epidermis of animals, and the outer skin of plants to prevent the growth of microorganisms).

: Spear / or enter the interior of a complex organism. One of the methods used by plants or animals to prevent microbial growth is to maintain the surface pH or secrete a coating that does not promote microbial adhesion and proliferation. After harvesting plant products or processing animal products' these products have lost their ability to prevent microbial infection. By spraying the composition of the invention and prescribed additives on the harvested fruits, vegetables and whole plants, or by washing or filling animal products in the composition

Page 24 1241168 V. Description of the invention (20)

X reduces the growth and proliferation of microorganisms in these products. For example, when the product or animal product is loaded into the composition, the extra-maxillary advantages can be overcome when the product is heated, because the pH value of the composition, the pH value of the same product is low, thus giving the composition an increased Destroy the potential of any microorganism, their toxins or other harmful substances. The composition of Benefit = ^ was found to be "preservative". 'However the combination speaks ... raw' It can create a loop where harmful microorganisms cannot survive and proliferate = 4 The use of preservative methods can eliminate the need to preserve chemicals in foods or other substances because of the inherent anti-corrosion of the mixture: into Preservative Zip thus improves the taste and avoids residual sensation and eliminates the preservative gas = body: feel-based-a kind of print It adds 5 Hai composition to the long-stitched σ juice and fermented beverage (wine) middle product, fresh fruit Or compare the taste of the drink. The group of people, Tongsi served the taste than the original taste enhancer will be used to produce: species ::::: beverage preservatives and, in addition, the composition can be added; Wang 5: satisfactory products. In sensitive products, to increase it = Pleasure and other preservatives can be used as a component to adjust the queen of the printed product and extend the shelf life. It also produces biopharmaceuticals and vaccination equipment: altered yeast and bacterial production: Bu has always been problematic. The remaining bioreactive complexes in the basic process are very useful in the preliminary cleaning of the 4 :; sensation admixture or group after the production is stopped. 1241168 V. Description of the invention (21) , And can be cleaned and rinsed. Composition and elimination of related inventions in other cleaning products will not damage the mold. The composition can be used to remove excess chemical, heat or wet packaging, preservatives. The composition of the present invention is used for solution cultivation control. Lam and Jian must be cooked before entering. Before the fine harvest of the fruit tree, the rice, the combination fruit of the present invention and a row of several times are used in combination to fully pick the destroying bacteria, true, and harvesting composition wheat and its key components in the finished product medicine can be left or left Ultrasound in assembled materials such as sutures in water pH can help some fruit trees, because spray products should only be created and welded under the condition that the container is completely removed or the bacteria are made of plastic. In the welding material of this hair, the residue is set in the field of clothing. The center of the hair is used in combination with the composite material to quickly and product defects from the combination of non-metallic parts. Precision injection of medical equipment materials effectively cleans the residue. Parts and acid etchants can be used to clean surfaces. The composition can be used as a final culture. And other tooling methods. This injection molding, and in addition, the or cleaning department> to be carried out if the equipment is packaging-proof: industrial applications are particularly beneficial. The ability to control plant value will affect fruit production and disease. Synchronization of harvest and completeness of harvest. Olives are picked by mechanical vibration. This vibration step Fruit and stem do not always mature at the same time. During picking, the tree's activity can make the stem and the product quickly require 1 or 2 vibrations, thus reducing the picking cost and

Loquats, yeasts, and molds can reduce plant yields or affect crop quality during or after harvest. Prevents mold and mildew when processing crops under humid conditions. This is indeed the case in the production of other cereal sorghum. Talent

Page 26 1241168 V. Description of the invention (22) Drying of raisins. If persistent mold 'causes the product composition, grape bunches are picked, as well as mold. Can adopt sex. The group of the present invention, the taste of fermented beverages, mycotin on stored cereals, contamination of consumption, poisoning, organ damage, protection from plants, any harmfulness left at harvest, in the composition of the agent or in storage containers, military water. Currently used to place iodine tablets, and to show the composition, that one. Used in battlefields where conditions are a problem. Rescue flushing solution, grapes are picked, and in Portuguese are wet weather, then cannot be used. The same method is used to immerse the grape bunches during the picking and wash the strips before packaging to ensure that the compound can be used to control the damage of P and other pests, the residue of product seeds, and the growth of medium seeds. The amount of food dilution that survives disinfection and the fungal infection of the animals of the present invention is reduced or dead, but the food or feed room here creates an environment. A variety of drinking water is available over time. If the time is obvious, other cooking sources of the cooking solution are used to remove the poisonous or dry on the paper or oil cloth between the vines. During the drying process, the raisin will send two sprays on the grape. Treat the oil cloth and spray the dried raisin Avoiding raisin hair during winemaking and regulating the wine and other hair products have the same purpose. Storage Mycotoxin. These mycotoxins are very harmful. Die in mycotoxins. Chemicals containing mercury and iodine There are no preservatives designated as unanticipated grains. Clams can be exposed to or without the addition of these microorganisms. The main purpose is to purify and drink 3 dyes. The method includes adding a small amount of hair to the fruit in the water tank to shorten the hair. Here, iodine-containing battlefield waste purification is not needed. It is used for health, wounds and disinfection of acute and hazardous substances. ,as well as

Page 27 1241168 V. Description of the invention (23) Equipment cleaning and disinfection. When cleaning with hot water, this is right and wrong: the food supply under the item cannot be taken into consideration. Biological pollutants refer to% + substances, or both, so the production of biological pollutants can make the environment or products that pollute the environment and useful products. Bacteria, fungi, mold. Potentially active κ mi ew in the cell wall / membrane and viruses in their cells (viruses and some bacteria) and shellfish: while, daggers hide in cells, bacteria, mold and mildew) to kill organisms Membrane (most bacteria, true outermost, that is, protected from the environment. The second part of the second method of growth and / or access to complex organic carvings, and the outer skin of plants to prevent the growth of microorganisms. Plant growth Adhesion and proliferation = reed 1: pH or secretion-species that do not promote the product, the ability of some products to mourn plant products or processed animals to infect fruit, vegetables and whole post-harvest plant organisms. Animal products in 哕 α humans; 贳 coated with A G11 s and the prescribed addition of low microorganisms in these products; services or loaded into them, can be reduced into the composition into the composition, then when two, t: fruit plants or animal products Benefit, because the PH value of the composition :: = A can be obtained when the composition has greater damage, the ⑽ value of ^^^ is reduced, thereby making the ability of harmful substances all u organisms, their toxins or other It was found that the composition of the present invention has no rot I Biogenic daggers can create harmful micro-environments to prolong the storage period of products. Anticorrosiveness ". However, the new compound can not survive and proliferate in the ring.

1241168

The low pH inherent in adding other compounds to foods or other substances to be preserved is preservative. Due to helmet two, chemicals, because of mixing chemicals, taste and avoidance have been improved. Sensory tests of previously stored foods have shown that adding new stores and ways to eliminate preservative odor. The term “sensory” is a kind of impression based on the perception that taste can improve the taste. Adding 7% or other whole ingredients to other fresh fruit juices and fermented beverages (7%) can agree with the group to obtain a taste that is better than the taste of the original or control drink (= 1 wine). The two uses of consistent preservatives and taste enhancers are to make one, and the mash is a satisfactory product ... In addition, the composition can be added to make it sensitive to preservatives to improve their safety: Musical objects and their duration. It can also be used as an ingredient to adjust the product ρΗ value. And prolonged storage Δρ X τ 〇, ′; ,,,, and resistance can be ridiculed-A? S added a small amount of polar organic molecules, additives to eliminate. ::: 'Ethyl acetic acid, ceramic acid and surfactants (such as polyethoxy _ (spitting,,) can enhance the activity of the composition and improve the composition' speed and effectiveness of biological properties. In the composition of the invention, the addition of one, two, or all of the above-mentioned types of additives to the aqueous solution of AGIIs can be considered to enhance the penetration or contact of the reaction surface incorporated between the t π wash targets. In summary: Xi's A common application method is to combine the aqueous solution of AG I IS with ethanol, lactic acid, and ethoxy ether 80 (also known as Tween 80). The composition not only cleans the surface of inorganic residues, but also kills Dead organisms up to 108. When heated, other compositions will remove glass, metal and plastic surfaces

Page 1241168

Toxins without damaging the effective cleaning of the drug in situ. Defective dismantling expensive equipment. Processing equipment and initial package required. These surfaces. This energy may be biologically processed and prepared for cleaning. Lowering endotoxin is a drug that helps the composition I production equipment. This ability is low for vaccines and medicines, and for the safe use of vaccines. Biologically modified products and vaccines are subject to genetically altered yeast strains. The ability of this group of substances to completely remove residues will be certain. <, ′ In addition to the pollution that may occur in biological drugs or vaccine products, and its cleanliness is a key production area, it is a precision injection molding method for plastics and composite materials used in key parts of medical equipment and other industrial products. This Zhiming 2 composition can quickly and effectively clean the injection mold between runs without damaging the mold or leaving residues that cause product defects. In addition, the composition can be used to remove remaining material from parts and acid etched or cleaned parts before cracking and welding. The composition of the present invention can be used for cleaning the surface of a non-metallic part to be subjected to chemical, heating or ultrasonic welding. Moreover, the adducts of the present invention can remove excess stickies and routinely eliminate them before packaging the medical device. If the instrument is wet-packed, such as suture material, the composition can be used as a packaging preservative. The agricultural application of the adduct or composition of the present invention is particularly beneficial

Page 1241168

1241168 For food rooms or in the environment created by the toilet, there is also a separate piece of matter. The situation in that field is to wash the cleaning solution and water cleaning. A variety of these kinds of drinking water. So when it comes to purification, the problem food, dilution and > Xiao poison. At that time, this is a step-by-step illustration of the basis of each given pair in this embodiment. V. Description of the invention (27) Residues are designated for use in the composition of the processing agent during harvesting, or growing in storage containers, military purification of drinking water on the battlefield. Iodine tablets are currently placed in boxes and waiting for the adduct or combination of the present invention will not require iodine tablets. Contamination purification, spillage for sanitary wounds and disinfection of first aid flushes, and equipment should not take into account the heat of the equipment in the following examples. However, it should be understood for illustrative purposes only. Unless stated otherwise, the weight percent of the final composition is a preservative. Tritium uses for exposure to grains with or without added microorganisms. t The method of contamination, if added in water, it will obviously shrink other applications. The source of the cooking solution to remove toxic or in the reduced field conditions is the main invention and the specific details of the invention. Water enters a small amount of M, including battlefield waste, for the supply of food under hazardous substances. The selection system of the present invention is designed to content

Example 1 AGIIS X with an acid equivalent concentration of 3 was prepared by the method (112804 / 〇3 (011) 2) (19.2 mol in c, e, and f, under stirring In each reaction flask a, b, 16.868 liters of RO / DI water, slowly add 1 05 5 ml in pure

1241168 V. Description of the invention (28) After adjusting the degree and considering the amount of acid neutralized by the base) concentrated sulfuric acid (F cc grade, purity 95-98%). The amount of water has been adjusted to a volume suitable for the acid and calcium hydroxide slurry. The mixture in each flask was thoroughly mixed. Each reaction flask was quenched in an ice bath, and the temperature of the mixture in the reaction flask was about 8 to i 2 ° C. The mixture was continuously stirred at a speed of about 700 r pm. In addition, 4 kg of calcium hydroxide (F CC grade, purity 98%) was added with RO / DI water to a final volume of 8 liters to obtain a slurry. The molar ratio of calcium hydroxide and concentrated sulfuric acid was determined from the figure j to be 0.45 to 1. The slurry was a 50% (W / V) mixture of hydroxides in water. The slurry was mixed well with a high-shear mixer until the slurry appeared homogeneous. The slurry was then quenched in ice 'valley to about 8 to 12 C' and continuously searched at about 700 r pm. In each reaction flask, 150 ml of calcium hydroxide slurry was added every 20 minutes until 1.26 liters (that is, 6 38 g dry weight, 8.61 moles of hydroxide) was added to each reaction flask. calcium). While adding, mix thoroughly at a speed of about 700 rpm. After the completion of the addition of hydroxide to the reaction mixture of each reaction vessel, the mixture was filtered through a 5 micron filter. The filtrate was allowed to stand for 12 hours, and the clear solution was decanted to remove all of the formed antiseptics. The obtained product was AG I IS with an acid equivalent concentration of ½ · 2 to 1.5. Example 2 Preparation of an acid equivalent concentration of 2 by the method of [12804 / ^ 3 (0) 1) 2/03504

AGIIS To prepare 1 liter of 2 N AGI IS, stir in a 2 liter reaction flask

1241168 V. Description of the invention (29) of 853.93 ml of RO / DI in water. In the adjustment of purity and consideration of neutralization by alkali ^ 9 · 54 * liters (1.44 moles, grade, purity 95 to 98%). Then after =) concentrated sulfuric acid (FCC 5 grams of sulfuric acid about (FCC grade, purity 95 r :), slowly add 1 L. of the reaction flask to the reaction flask, ^ ^ ^ stomach _ 0) ° to fully mix the mixture. The temperature of the acid shown in this Ka-Tong Φ when the bottle is in the ice-cooled intermediate reaction flask is about 8 to 12 ° C. The mixture is continuously stirred at a speed of about 70 rpm.-Xi r Bu ργ at 33. 26 89 g (0. "Mole 'after purity adjustment) of calcium hydroxide (FCC grade, purity 98%) was added 49 89 ml of rO / di water to a final volume of 66.5 3 ml' to obtain a slurry. From Figure 1 confirms that the molar ratio of emulsified calcium and concentrated sulfuric acid of tick lice is 044 to 1. Using a high-shear stirrer, the slurry is thoroughly mixed until the solution looks homogeneous. Then the polymer solution is quenched in an ice bath To about 8 to 12 ° C, and continuous stirring at about 700 rpm. Over a period of 2 to 3 hours, slowly add the slurry to the mixture, still chill in an ice bath and at about 700 rpm With stirring.

After the slurry was added to the mixture, the product was filtered through a 5 micron filter. It is often found that the mixture loses 20% of its volume due to the retention of the salt in the solution and the removal of the salt. The filtrate was left to stand for 12 hours, and the clear solution was decanted to remove all the sunken objects formed. The product obtained was AG I I S with an acid equivalent concentration of 2. Example 3A method of preparing an acid equivalent concentration of 12 by the method of 〇4 / 〇3 (01〇2 / 〇3804)

1241168 V. Description of the invention (30)

AGI IS To prepare 1 liter of 1 2N AG I IS, under stirring, slowly add 4 3 4 · 17 ml (7 · 86 mol) of 28 4 · 60 ml of RO / DI water in a 2 liter reaction flask. After taking into account the amount of neutralized acid tested, concentrated sulfuric acid (FCC grade, purity 95 to 98%). Then, 3 g of calcium sulfate (FCC grade, purity 95%) was slowly added to the reaction flask with stirring. The mixture was thoroughly mixed at a temperature of another calcium oxide, the final body was oxidized, and the slurry was allowed to settle in an ice bath at 2 to 3 in an ice bath. The reaction flask was quenched in an ice bath, and the reaction flask was mixed ...

About 8 to 12 ° C. The mixture was continuously stirred at 70 0 rpm. '1 40.61 g (1.86 mol, after purity adjustment) | (FCC grade, purity 98%) was added with 20.192 ml RO / DI Water made the volume to 281.23 ml, thereby obtaining a slurry. It is confirmed from FIG. 1 that the molar ratio of Wu and concentrated sulfuric acid is 0.31. Mix the liquid with high shear force until the slurry looks homogeneous. The slurry was then cooled in the center to about 8 to 12 C and stirred continuously at about 700 r p m. During the hour, the slurry was slowly added to the mixture, then, still chilled and mixed at a speed of about 700 r pm. After the slurry was added to the μ compound, it was filtered through a 5 micron filter. It is generally found that ~ 20% of the loss is due to the retention of the salt in the solution and removal of the salt. %

The filtrate was left to stand for 12 hours, and the clear solution was decanted to remove all formed. The product obtained was AGIIS with an acid equivalent concentration of 2. Example 4

1241168 V. Description of the invention (31) Whether the solution with a pH of 1.8 can reduce the contamination of each bud with incubation with E. coli.

The solutions of Group 8 were mixed by AGIIS with 0.05% lactic acid and 0.5% ethanol, respectively. 〇 :, 4〇. 〇 and 45. (: E. coli M "used to sterilize 1 10! 3 colony forming units (" CFU "). ^ 丄 X incubated alfalfa sprout seeds. (-Up to f35 ° C 'use the above containing AGIIS and additives , 仃 treatment, reduced E. coli 0157: 耵 contamination level> 6 :: ', Xiao: treatment at in 5 °' treatment at 4 ° ° C did not significantly improve = j no effect. However, in The treatment at 45 t is significantly different, with a level of clever dyeing> 8 logarithmic levels. T is lower than that of Example 5 and rn f test to determine the pH consisting of AG 1 1 S and three additives (lactic acid, ethanol and vomit =). Does the 1.8 solution sterilize alfalfa sprouts incubated with E. coli 〇 5 7: H. Humans, with 〇5% lactic acid, 0.5% ethanol and 0.2% Tween 8 〇Mixing: the main, and the solution of ρΗ1.8 is used at 35, 40, and 45, respectively.

Sink == 1 · 1 × 10 n CFU of E. coli 0157: Η 7 alfalfa seeds incubated together. Humans at 3 5 C and 40 C, using the above-defined AG 丨 s and additive group II = reduce the E. coli 0157: H7 pollution level> 6 logarithmic levels. = Slave, the treatment at 45 ° C is significantly different, which reduces the pollution level > 8 logarithmic levels.

Page 1241168

V. Description of the invention (32) Example 6 Test to determine whether a solution consisting of AG II S and three additives (lactic acid, ethanol temperature 8 0) with a ρ Η of 1 · 8 can reduce the Salmonella spp. Fouling of incubated alfalfa bud seeds from AGIIS with 0.05% lactic acid, 0.5% ethanol and 0.2% σ ^

The combined solution of ρ Η1 · 8 was sterilized at 3 5 t :, 40 ° C, and 4 5 ° C A ^ to sterilize alfalfa #bud species 1 " At 35X: and 4 ° C, the AGns and Tim as defined above are used. The combined treatment reduces the level of Salmonella contamination by> 3 logarithms. The treatment at 45 ° C is significantly different, which reduces the Pollution level > 4 ^ 4 Example 7 studies to evaluate the use of pH 1.8 including AGI Is, 0.05% acetic acid and 0.2% Tween 80 at different temperatures. The level of aerobic microorganisms associated with alfalfa sprouts (products) in solution treatments at ^ 氚 明 明 当 当 使用 使用 使用 使用 AGIIS, 0.5% ethanol, 0.05% lactic acid and

The pH 1.8 solution per temperature of 80 was reduced at about 25t when they were treated for 15 minutes. Here, borrowing from the sensory horns to borrow the teeth has a clear effect. However, budnaz treated at 40 ° C looked soft and visually not as attractive as alfalfa teeth treated at room temperature17. Muju

1241168 V. Description of the invention (33) Example 8 A study was conducted to evaluate the use of a pH of 1.8% solution including agii yeast, 0.05% lactic acid and 0.2% Tween 80 at different temperatures. (: The effect of the storage period of the alfalfa sprouts under storage. / The treatment of the alfalfa sprouts at 2 5 at 4 0. (: The lower treatment i for 5 minutes makes the alfalfa ^ look more, but the alfalfa sprouts can not go through heating, and the spoilage is cleaner. All the samples were withered, and it was proved that Tween δo = the sensory performance was adversely affected at the time of death. Example 9 of the eye buds was added with AGIIS, 0.5% ethanol, 0.05% lactic acid and 0 ° C. A solution of pH 80 on pH 8.8 of the microbiological zone of ground beef. The purpose of the vomiting study was to determine a solution of pH i. 8 containing AGns, 0.005% lactic acid% 5 alcohol, and 0.2% Tween 80 and ground beef. (Hanbao., 3 = whether B reduces and / or controls the level of meat-associated microflora a. This & can judge that the sensory performance of processed and untreated hamburgers is not worse. However, when meat is digested The samples were tested and the microbial level of each sample was measured. The related microbial population of meat treated with AGI IS / additive solution was 50% lower than that of meat treated with saline. Therefore, it can be judged that A (H IS / The solution can reduce the level of microbial contamination and prolong the storage β period of the processed meat. Study to evaluate a square containing AG I I S, 0 · 5% lactic square, square and square-5% ethanol

Page 38

1241168 V. Description of the invention (34) The ability of the solution of 2ΛTUΛ80 / 13111 · 4 to reduce mold / fungal contamination and growth on raisins. : Yue. Hai = Reduction of raisin-related mold and fungal contamination, and seems to inhibit its further growth. From a sensory perspective, the treatment removes more dirt and residues than washing with water, and the treated raisins look more attractive because they are darker and fresher. Example 11 A solution of PG1.4 composed of A G I IS, 0.05% CO, nc ;, ν · / 〇pore, 0.5% ethanol, and 0.2% Tween 80 was used at 4%. The effect of plant #? Audit # 4 was called J and Hexin 隹 L treatment on the viability of organisms E. coli 157: Η7. At 45. (Next, E. coli 0157 was treated with a cold liquid of pH 14 consisting of AGns, 0.05% lactic acid, 0.5% ethanol, and 0.2 Tween 80, and stored in a cold solution of τ 田 丄 乂 πρΗ1.4. H7 organism IX10. The serial dilution of the treatment substance was plated to determine the effect on the viability of the organism E. coli 0157: 117. This treatment killed 100% of the organism, ie the CFU / ml was reduced from i X to / Zero 0-Example 12 A study was conducted to evaluate the treatment of AG IIS, 0.5% ethanol, and η nc 〇 / > pH solution of 8 to yy 20% of the period of storage at 25 ... Influence. ”The health of the eyes and teeth is treated in a container that prevents the purchase of alfalfa sprouts. After a period of 16 to 16 hours, in terms of sensory performance, go away: ^: 1 mile. In 1 2 2 water and untreated clover

1241168 V. Description of the invention (35) ^ Bud has obvious sour taste. It can be concluded that since there is not enough water from alfalfa, they deteriorate quickly. It was further noted that Tween 80 was an unfavorable factor during the storage period of the order. It was also observed that alfalfa sprouts treated with a solution of 8 or less length were bleached. Although it looks powerful or spoiled, it is treated with (Protonium) solution. ^ No rotten sour taste. Example 1 3 The effects of the treatment with AGIIS, 0.5% ethanol, 0.05% lactic acid, and / or the first = ΐΓΗ 1.4-1.8 solution on the shelf life of the primary teeth stored at 25 ° C were evaluated. If the buds and the first alfalfa buds treated with deionized water look brown and somewhat discolored, the treatment with a lower pH AGIIS solution (< 1.8) is only excessive. bleach. After treatment in the 4 control group and the eyes, the alfalfa perforated rot * catty i-ion water treated

A solution of PHl.8 ^ AGnV ^ M) is most effective in 1-dose ethanol (lactic acid (0.055% hour alfalfa shelf life. After returning to the chamber after treatment), AGIIS, 0 R, and just bought As fresh. Therefore, a solution containing alfalfa sprouts of alcohol and 0.05% lactic acid in pH 1.8 can be extended

1241168

V. Description of the invention (36) Example 14 Studies show that, unlike physically removing pollutants, a solution containing AGIIS, 0.05% ethanol, and 0.05% lactic acid in PH 1.8 can kill Enterobacter contaminated bud seeds. E. coli 01 57: H7 CFU contaminated seed samples (25 g each) were used with 1 X 1 06 or 1 X 1 013. The seed samples were treated with a solution containing AGIIS, 0.5% ethanol, and 0.05% lactic acid at a pH of 1.8 for 10 minutes. A 1 mL aliquot of each seed suspension was removed and serially diluted after treatment. After inoculating each series of dilutions, seed-related wCFlI numbers were counted. This treatment reduced the number of seed-related microorganisms by 4 to 5 logarithms. Bacteria are killed, not just washed away. Example 15 A test was performed to determine whether treatment with a solution of AG IIS, 0.5% ethanol, 0.5% lactic acid, and 0.2% Tween 80 at a pH of 1 · δ could reduce and / or kill tomatoes. Surface-associated microbial organisms.

The normal level of microbial contaminants associated with tomato surfaces is 1 X 106 °. After treatment, surface-related organisms have been shown to decrease by 3 to 4 $ logarithmic. A reduction of 3 to 4 logarithms is sufficient to extend the shelf life and reduce the possibility of contamination of tomato products such as salsa. Example 16 Studies on the effects of treatment with AGIIS, 0.5% ethanol, 0.05% lactic acid, and 0.2% Tween 80 at pH 1 · 8 on the effects on microbial contamination and sensory performance.

Page 41 1241168 Five 'Explanation of invention (37). One dozen chicken drumsticks purchased from a local grocery store were packaged separately in a solution or disinfected saline containing Qi 丨 8 containing AG 丨 Is, ^ 5% ethanol, 0.005% lactic acid, and 0.2% Tween 80 (control ) Soak for 10 minutes. All chicken legs were then incubated at room temperature for 24 hours. The number of drumsticks-associated bacteria soaked in sterile saline after a 24-hour incubation was about 7 × 10 ig, with AfIIS, 0.5% ethanol, 0.05% lactic acid, and 0.2 % Tween 80's solution of {) 111.8 is about 6 x 〇07 for leg drums. In terms of sensory performance, the leg drums soaked in saline had a strong rotten odor after 24 hours of incubation, while those with AGIIS, 0.5% ethanol, 0.05% lactic acid, and 0.2% Tween 80 The solution-treated leg drums of ρΗ1 · 8 emit the same new g odor as when purchased. In addition, the treatment maintains the fresh appearance of the chicken. boom

It can be concluded that treatment with a solution containing AG 丨 S, 0.5% ethanol, 0.5% 0.5% Tween 80 and ρ11.8 can extend the shelf life of fresh meat chicken. Will be different Example 1 7

A solution containing AGIIS, 0.5% ethanol, 0.05% lactic acid, and pH 80 at a temperature of 80 was used to treat the spit, one, and nine J ... The influence of the bio-dyeing and sensory performance of Diwangchengcheng is based on a large headless shrimp purchased from a local grocery store at a pH of 1.11%, 0.05% lactic acid, and 0.2% Tween 80. The solution of 8 was soaked in water alone (control) for 10 minutes. Then incubate the sterilized ravioli at room temperature

1241168 V. Description of Invention (38) 24 hours. After 24 hours of incubation, the number of bacteria in the toilets soaked in the sterilized saline was about 3.8 × 101Q ′ and the pH was 1 with AGI is, n /, about u · 5% acetic acid, 0.05% lactic acid, and m Tween. The blemishes of the .8 solution treatment are approximately 1.4 x 1.09. In terms of organoleptic properties, the treated and untreated ^ are the same. In another test, the shelf life of the entire shrimp at 25 ° C (body appearance) was increased from about 0.75 days to 1.5 days. ’口 实施 例 1 8

Test the ability of a solution containing AGIIS, 0.5% ethanol, 0.05% lactic acid, and 0.2% Tween 80 at pH 1 · 8 to disinfect E. coli and 5 7 · · H7 to sterilize guar and chicken . One thousand chickens incubated with E. coli 0157: H7 in a solution containing AGnS, 0.5 benzyl alcohol, 0.05% lactic acid, and 0.2% Tween 80. Or disinfection: soak for 10 minutes in secondary school. After soaking, half of the chickens were put in plastic bags with culture & shells and incubated at 37 t for 2 hours. The titer of E. coli 0157: H7 was determined at the turn of 2 hours of incubation. Spit, and w j use AGIIS, 0.5% ethanol, 0.05% lactic acid and 0.2%

A solution of M: 1 ^ 1 · 8 reduces the growth of E. coli 〇1 57: H7 by about 1 superordinate, that is, from 1.5 x 2 × 9 to 2 x 2 × 8. No difference in sensory performance was observed. Example 1 9 Study 9 to evaluate ρΗ1 · containing AG IIS, 0.5% ethanol and lactic acid

1241168 V. Description of the invention (39) The ability of a solution of 8 to extend the shelf life of fruits and vegetables, quince, berries: berry, cranberry and grape vinegar ^ 5% 5% alcohol and 0.05% lactic acid at pH 1.8 Solution =: Prevents fruit-loading-associated fungi from replicating, but agglomerates retain their shape and appear to be better overall. Treatment has no effect on strawberries. Whole melon: Whole Roman melon was soaked in a solution containing AGI is, 0.5% ethanol, and 0.05% milk P.II.8 for 30 minutes, slowly decaying (observed 48 hours after treatment). Cut fruits: ▲ A quarter of Roman melon and honeydew melon are soaked in a solution containing AG 丨 丨 s, 0.5% ethanol, and 0.05% lactic acid at a pH of 1.4 to suppress rot. Fruits treated with a solution containing AGIIS, 0.5% ethanol, and 0.05% lactic acid at pH 14 are stored frozen or at room temperature and retain their color and fresh odor after 24 hours. Fruits treated with disinfectant have rot odor. Cut fruit salad (mixture of apple, pear, peach, and melon): Treat the cut fruit salad with a solution of ρΗ1.4 containing AGIIS, 0.5% ethanol, and 0.05% lactic acid, 2 hours after processing ( Room temperature), it still looks fresh 'and the fruit salad treated with water turned brown and started to rot. Cut lettuce: use a solution of pH 1.8 in AGIIS, 0.5% ethanol, and 0.05% lactic acid

1241168 V. Description of the invention (40) Liquid position ... The incubation incubation at room temperature or at a price will have no effect on the decay of the blade edges. However, the chicory leaves treated with a solution of p H i .8 containing AGI IS, 0.5% ethanol and 0% lactic acid were incubated at room temperature for 6 hours. 5 The intact water-treated leaves were drilled, and Already rotten. Fan% · Use of a solution containing AGIIS, 0.5% ethanol, and 0.05% lactic acid at pH 1.8 or water-treated cherry Fanyou has no difference in appearance. However, as shown above, the shelf life was significantly extended when the tomatoes were immersed in AGIIS. #

Example 20 Ability of the adduct to wash blueberries and cranberries The fruit was treated with a solution containing AGns, 〇5 = a solution by soaking for 15 minutes. Simultaneously autoclave ^ Use 1 ml / g saline to digest the treated and untreated: 目 mesh = two and the number of inoculated plates. The two groups of two--so concluded that the test effect is not obvious. Example 2 1

_ 2 Research Λ to determine whether the treatment with a solution containing AGIIS, 0.5% ethanol and 0.05% lactic acid in. Will reduce the microbial contamination of cut fruit. : Fruit Roman Melon and Melon Cut! Up to 15 inches stand up to E. coli 〇57: H7 organisms with a salt width of 2.5 × 9 °. After 10 minutes, use AGIIS, 0.5% ethanol

1241168 V. Description of the invention (41) and a solution of 0.05% lactic acid at pH 1.2 or a sterilized saline solution are treated by soaking them for 10 minutes. After the treatment, the pieces were digested and the bacteria concerned were determined. The number of E. coli 〇1 ·· related to Roman melon pieces is 7.2 x 103, while the number of melons treated with saline is 3.4 x 10.5, which reduces the pollution level by about 98. %. The number of E. coli 0157: H7 CFUs related to honeydew melon pieces is 5.3 > < 103, while the number of melon pieces treated with saline is 1.4 \ 105, which means that the treatment reduces the pollution level About 95%. Example 22 2 A study was conducted to determine whether treatment with a solution containing AGI IS, ethanol, and lactic acid prevented oxidation of purslane. The potatoes are peeled and placed in a solution or water containing aghs, 0.05% alcohol, 0.05% lactic acid, and 0.2% Tween 80 for 5 minutes. After the treatment ', the potatoes were taken out and incubated at room temperature for several hours on the open: = shelf and incubated for 24 hours. The water-treated mash potato started in 30 minutes, and it was dark, while the horse feng treated with the A G I I S solution was significantly different after 24 hours of treatment. Example 2 3 AGIIS (pH2), 0.2%, and 0.1% were used. n ± 0 soil temperature 8 0 surfactant solution to clean the previously painted-W surface of the house built in 895. Remove all surfaces > Dyeable and visually dryer than the corresponding area cleaned with ammonia cleaning such as, main, cut + θ peak agent. Dry the clean surface and apply acrylic paint on the surface. After one week 'the coating appeared normal and free of bubbles or peeling.

1241168 V. Description of the invention (42) Example 2 4 Use AGI IS at pH 2 and 0.2% Tween 80 surfactant to clean the old road with oil stains. Clean two pieces of the same area. The area treated with the AG I I S solution is whiter than the area where only the detergent is used, and it is judged to be cleaner by the observer. Example 2 5

A small portion of the new concrete sidewalk was sprayed with a mixture of AGIIS pH 8. 8 and 0.05% lactic acid. After the area is dry, the sidewalk is sealed with concrete sealant. The area pickled with AG I I S has a different appearance than the surrounding concrete; however, the seal adheres to the concrete and is impervious to water. Example 2 6

The green pepper plant has 3 bell peppers on the plant at different stages of growth. The plants were spray-coated with a mixed solution of PEG 1 · 8 AGIIS and 0.5% lactic acid every other day 'for 6 consecutive sprays. The largest pepper immediately turned red. Small peppers increase in size quickly and start to turn red after the third use. At the end of the treatment, these peppers are different in size but have a uniform red color. Example 2 7 'Drinking water contains non-coliform organisms. Add in this water? 〇。 1} 1.4 agI IS and 0.05% lactic acid mixture so that ρΗ is 2.0. No country when cultivating water

State ill Page 47 1241168 V. Description of the Invention (43) '" " " " "'-" The organism grows and can drink the water without side effects. Example 28 A test was performed to determine whether a solution of pj 1 · 1 consisting of $ AGI IS, 0.5% ethanol, and 0.05% lactic acid disrupted the survival of the field bacteria present in water collected from street mud puddles. ability. Collect water from a mud puddle in the corner in front of the laboratory. The pH of this water was measured to be 7.4. The mud water was titrated using a solution consisting of AGns, 0.5% ethanol, and 0.05 / lactic acid at pH 1.1, or sterile saline, and treated at room temperature. After treatment, aliquots of AGIIS and saline-treated water were serially diluted and plated to determine the number of viable organisms: relative to the control saline, the water used to treat the water was agi is 0.5% =, 05% ΡΗ1 · i solution consisting of ceramic acid effectively reduced survival organic Example 2 9 Experiments to prove that the muscles composed of the AGITS method σ-4- temperature 56 56 = 二 二 加加加 / 酸酸 甲醇 and 吐 吐 斯Agrobacterium tumefaciens-incubation: Γ :: 4 AGm, 0.05% lactic acid, 0.5% ethanol, and 0.2% vomiting 20 groups were immersed with a solution of PH 1.56 and Listeria monocytogenes *% Bud seeds. Incubation with mononuclear cells increased and mononuclear cells treated with Sagittatum spp. Treated with saline solution and treated with non-additive composition; 4 Li 5 = Λ 夕 夕 r 生 斯特 defined by j囷 Decreased clever dyeing level 1241168

V. Description of the invention (44) Example 30 In the following three tests, the following provisions were adopted in the test:. Concentrated AGIIS (Ca (OH) / HJCVCaSO4 method) was added to deionized water to adjust the pH to the desired value. Horizontally then add peracetic acid to make a solution. 2. Cultivate bacteria until just before they have a stable phase. 3. Prepare and label multiple sterile 15 liter con tubes. In the first ring

Add 4 ml of the solution prepared according to step 丨 to the tubes, and add 4 ml of sterile saline to all the remaining tubes. 4 · Set the timer to 60 seconds. 5. Add 丨 ml of bacterial culture to the first tube and start timing. j. Transfer the milliliters to the next tube immediately after 60 seconds. Spin and transfer 1 liter to the next tube. Continue to complete serial dilutions. 7 ^ By transferring 0.1 ml from each tube to three different culture plates, dip into Erping, inoculate, and repeat three times. Each plate was incubated overnight, and the number of colonies on the female plates of the 24-hour crossing was used to determine the number of survivors after treatment. 8 · To determine the number of treated bacteria,

Column dilution 'and plated 0.1 ml from each dilution in triplicate. The bacteria were contaminated with > 1 X 〇7 CFU by immersing the tomato in Salmonella, and then they were dried in the air. The treated tomatoes were immersed in an adjuvant solution of human 0118 (mouth 10.2, 0.0 6 3 3 0) mixed with 80? Mouth 111 peracetic acid for 1 minute. After the treatment, the tomatoes were digested and one

Page 49 1241168, Description of the Invention (45) Aliquots were plated to determine the number of relevant organisms. In summary, the use of 4 adduct treatment reduced the number of related organisms > 4 logarithmic orders. Example 3 1-> 1 X 100 CFU of this bacterium was stained with blueberries by immersing them in Salmonella, and then they were dried in the air. The treated blueberries were immersed in an adduct solution containing AGIIS (pH 1.2, 0.03 N) mixed with 0.48 mL / L, or 80 ppm peracetic acid for 1 minute. After processing, the blueberries were digested and an aliquot was plated to determine the number 7 of the organisms of interest. In summary, the use of this adduct treatment reduced the number of related organisms by> 5 levels. ^ Example 3 2 Apples were cut into 4 pieces through apple stems. The apple flakes were contaminated with > XI 109 CFU by immersing the apple flakes in Salmonella, and then they were dried in the air. The treated apples were immersed in an addition solution containing AGns (pH 12, 2, Q 〇63 for 1 minute) mixed with ..., 0.48 mL / L, or 80 ppm peracetic acid. After the treatment, the saline was thoroughly rinsed with I1Γ; Aliquoting the bleaching solution to determine the related organisms = pair = adult treatment to reduce the number of related organisms Example 33 By cultivating broccoli in Salmonella, take, master ten red you " Men's Immersed in 囷 to make> i χ 107 CFU

1241168 V. Description of the invention (46) The bacteria contaminate the broccoli, and then they are dried in the air. The treated broccoli was immersed in an adduct containing AGI IS (pH 1.2 · 0.063N) mixed with 0.48 mL / L or 80 ppm peracetic acid for 1 minute. After treatment, the broccoli was digested and plated in aliquots to determine the number of organisms involved. In short, the use of the adduct treatment reduced the number of related organisms by> 5 logarithmic orders.

Page 51 1241168 Brief Description of Drawings Figure 1 shows the relationship between the desired final acid equivalent concentration of AG I I S and the molar ratio of calcium hydroxide to sulfuric acid, expressed in moles of calcium hydroxide per mole of sulfuric acid.

Page 52

Claims (1)

1241168 Case No. 89102558 6. Scope of patent application Additives ′ The additive pole I A! -V D, e human heart M includes a mixture of alcohol, acid, surfactant or dagger. For example, it is stated that the composition sulfuric acid in the scope of patent No. 5 contains preliminarily calcium sulfate. Each of the 2T patents targets a composition around item 5, wherein the alcohol includes a lower aliphatic alcohol having 6 or fewer carbon atoms. 8. The composition as claimed in claim 5 wherein the acid is milk. Acetylpropane I, oxalic acid, peracetic acid and periodic acid, or a mixture thereof s 2 is a composition as described in item 5 of the Shine patent, wherein the surfactant is an anionic, anionic, nonionic surfactant, or a mixture thereof. The report of item 5i is the composition of item 5 in which the concentrated AGIIS with a certain acid concentration is more corrosive in sulfuric acid than the saturated solution of acid dan and Quyou L in sulfuric acid. It is small, and AGIIS has a lower efficiency in the laboratory, and it is non-volatile under the rot / dish and lifting pressure on animal skin. 11 · For each mole of sulfuric acid used in the scope of the patent application, the hydroxide of the hydroxide = mouth, which is relative to that used. For example, I is from 0.1 to 0.5 mole. 2001.11.01. η 1 2 · As for the composition in the fifth item of the patent application, the content of AGIIS is from 0.01 to 99 99%, and the content of the additive is from 0 1 to 99.99% based on the final weight of the composition. 13. A method of lowering the pH of a solution comprising adding an effective amount of a mixture containing AGI IS and additives to the solution. 14. A method of adding and mixing ingredients including AG 11S and an additive to decrease the pH value of a mixture, wherein the "Is" is obtained by mixing (a)-inorganic acid and (b) -A IA group hydroxide or a dibasic acid I ^ A bismuth salt or a mixture prepared from a mixture of components; and wherein the additive comprises an alcohol, an acid, a surfactant Or a mixture thereof; the method includes heating the mixture. _ 1 5 · A method for reducing biological pollution in plant products, comprising mixing a mixture prepared by adding ingredients including AG I IS and an additive with the Plant product contact, where the IS is prepared by mixing ingredients including (a) an inorganic acid and (b) a group IIA salt of a group IIA hydroxide or a diacid or a compound thereof Isolated from a mixture; and pot to Shihe, eight to eight additives include an alcohol, an acid, a surfactant or a mixture thereof. 1 6 · The method according to item 5 of the patent application, wherein the Plant products Page 55 2001.11.01.051 1241168 __Case No. 89102558_ Year H 俨 τ 6. The scope of patent application is fresh fruits, vegetable products, harvested plants, seeds, preserved plants or packed plants. 17. A method for reducing biological contamination of animal meat products, comprising contacting a mixture prepared by additively mixing ingredients including AG 11S and an additive with animal meat product A, wherein "Is Isolated from a mixture comprising (a)-an inorganic acid and (b)-a group IIA argon oxide or a group IIA salt of a diacid or a mixture of the two; and wherein the additive includes an alcohol , An acid, a surfactant, or a mixture thereof. A I8. The method according to item 17 of the patent application, wherein the animal meat product is an animal before slaughter, an animal skeleton before dismemberment, an animal skeleton that is dismembered and processed, and dried. Animal products, animal smoked products, preserved animal products, animal products. ^ 1 9 · A method for reducing biological pollution in equipment, which comprises preparing the ^ species from ingredients including A G11S and an additive 2 The aqueous mixture is contacted, wherein the ^ 113 is a mixture of (IA) a mineral acid and (b) a Group A IA salt of a Group A hydroxide or a diacid or a mixture of these two. A mixture of ingredients was prepared isolated: additive comprises an alcohol, a •, a surfactant or Shang; Page 56 2001.11.01.052 1241168 Case No. 89102558 VI. Patent Application Range / Performance 20 · If the method of applying for the patent scope item 19 is used, 'where household H is plant harvesting equipment, plant packaging equipment, animal slaughtering equipment, skeleton processing preparation, Equipment for dismembering and processing animal skeletons or articles. 2 1 · The method according to item 19 of the scope of patent application, wherein the J-backed food supply equipment, injection molding equipment, welding equipment, packaging equipment or equipment requiring acid cleaning. 22. The method of claim 19 in which the device is a medical device. 2 3 · A method for reducing biological contamination in a packaging material, comprising contacting the packaging material with an aqueous mixture prepared by additively mixing ingredients including AGI IS and an additive, wherein the AG IIS (A) —- an inorganic acid and (b) — a group IA salt of a hydroxide or a diacid or a mixture of the two, or a mixture of the two, and the additive is isolated from a mixture, and the additive includes an alcohol , An acid, a surfactant or a mixture thereof. ^ Packaging materials for animal or animal products. A method for preserving a consumer product, comprising Page 57 2001 · 11 · 01. 053 1241168 Case No. 891025RS 6. The scope of the patent application includes: a mixture prepared by adding and mixing the ingredients of an additive, the second is where the AGIIS is from the mixture including (a) or two Of a ΠΑ salt of a carboxylic acid or a mixture of the two, i, i: ii; and wherein the additive includes a surfactant or a mixture thereof. The method described in item 25 of the scope of patent application includes Fenkou, botanical products, animal products, ⑽ is a business product, animal I mouth, medical products for humans, veterinary fields / mouth, biological products, Drugs or medical devices. 2. The method of reducing the amount of biotoxins in the medium by using the medical 2JJ heart seed, the sentence "k-quality" and an IU group salt including or without AGnS and a messenger IU group hydroxide or a diacid or without = ^ b 的 物 的 组合 物 的 组合 成分 嗖 二。 Additives include monoalcohol'a •, a surfactant or them :: 奏 ： 8. If you set it up, please package specially installed profits = ^^ ^ Pin Qi 丨 1, Increasing Flavor, 29 · The method of applying for item 28 in the scope of patent application, in which nutrient B feed, beverage, food admixture, feed admixture, food and beverage condiment, medicine, biological product, seasoning Agents, spices, and glutamate coffee Page 58 1241168 _ Case No. 89102558 VI. Patent application agent or filler. Date _ 30. If the method of patent application No. 27, wherein the toxin is an animal toxin, Bacterial toxins, botulinum toxins, cholera toxins, shiga like toxin, a streptococcus erythrogenic toxin, didinellin, diphtheria toxin, erythema toxin, extracellular hormone, fatigue toxin (Fatigue to xin), endotoxin, scarlet fever erythema toxin, or Tunnicliff toxin. 31. The method according to claim 27, wherein the toxin includes endotoxin. 3 2. The method according to claim 27, wherein the toxin includes mycotoxins 33. A method for reducing the number of spores in a medium, comprising contacting the medium with a mixture prepared by additively mixing ingredients including AG 11S and an additive, wherein the AG 11S is obtained from the mixing including (a) — An inorganic acid and (b) — a mixture prepared from the ingredients of a group IIA hydroxide or a group IIA salt of a diacid or a mixture of the two; and wherein the additive includes an alcohol, an acid, A surfactant or a mixture thereof. 34. The method according to item M of the application, wherein the medium is a nutrient, equipment, packaging material, water or soil. Page 59: 2001.11.01.055 1241168 89102558 6. Scope of applying for patents 035. For the method of applying for the scope of patent No. 34, the nutritional products are food ^ feed, beverage, food admixture, feed admixture, beverage plus U = flavor 、 · 品, 生物 产品, Flavoring Agents, Spices, Increasing Spoon # + &A; Method for Improving the Bioavailability of Nutrients in Nutrients' its = + is prepared by adding AG1IS and-eight ingredients of additives A mixture of ^^^ 13 from a mixture i, and the mixture is a mixture of 11 human salts including (a) an inorganic acid and (b) an 11A or diacid or a mixture of the two And where the additives include -alcohol, -acid, -surfactant or mixtures thereof. Servant 1J · Rugao applied for a patent. A method according to item 36, wherein the nutrient is a carbohydrate, a protein, a peak, or an acid-stable vitamin. 38. The method according to item 36 of the application for a patent, wherein the nutrition product is a product, feed, beverage, food admixture, feed adjuvant, beverage admixture, agent, food seasoning, albeit loyal, > 4 you rape a 4. . Agents or fillers. '' Bioproducts ^ Flavourings, Spices, Fragrances Page 60 2001 · 11.01.056 1 9 ·· A method for adding a mixture to nutrition products, which includes · adding the mixture to a suitable carrier to obtain, a premix 1241168, j; Wu Zheng case number 89102558 VI. Patent application for composite products' wherein the mixture is prepared by adding ingredients including AGIIS and an additive, wherein the AGIIS is prepared from a mixture comprising (a) an inorganic acid and (b)-I IA hydroxide Or a dibasic acid, a group A salt, or a mixture of the two, and is isolated from a mixture; and wherein the additive% additive includes an alcohol, an acid, a surfactant, or a mixture thereof ^ Mix the premix product with nutritional products. 40. The method according to claim 39, wherein a suitable carrier is methylcellulose, plantain, bran, rice husk or corn flour. 41. For the method of applying for item 39 of the scope of the patent, i. Means imported products, feed, beverages, food admixtures, feed admixtures, food additives, food additives, food condiments, medicines, biological products, flavoring agents, spices , Agent or filler. θ 42. A method of cleaning a product, comprising contacting the product with a mixture prepared by additively mixing ingredients including AGI IS and an additive, wherein the AGIIS is obtained by mixing (a) _inorganic acid * (b ) _IIA Group osmium oxide or a diacid group IIA salt or a mixture of the two components, and is prepared from the mixture @; and wherein the additive comprises an alcohol, an acid, a surfactant or both mixture. 43. The method of claim 42 in which the product is a tissue, microelectronic or structural product. Page 61 2001.11.01.057 1241168 _Case No. 89102558 々 Application for patent scope 44. For the method of patent application No. 43, the structured product is new or reprocessed. 4 5 · A method for extending the shelf life of a nutrient product, which comprises preparing a nutrient product with / mixed with ingredients including AGI IS and an additive: contacting a full compound 'wherein the AGIIS is obtained from the mixture including (a ) An inorganic acid and (b) a group IIA hydroxide or an iia salt of a dibasic acid or a component of the b compound; and 5 wherein the ′% Agents include-Xiao'a acid'-surfactants or their sigma mix ::, plus ... feed two people, where nutrition is food two =, beverage, food admixture, feed admixture, beverage admixture, gen Condiments, medicines, biological products, spices or fillers. A method for increasing the desired part of a plant at the same time in Biedu Village by adding incense and planting. The method includes adding a mixture and mixing the part with a mixture prepared from ingredients including AGIIS and -additive, wherein the "115 It is a mixture prepared by mixing the components of the bite ---, the present acid, and (b) -IIIA hydroxide or a mixture of IIA salts of a diacid, a mixture prepared by mixing them: two additives including one # ， 一 酸 ， —surfactant or 2001.11.01.058 1241168 _ Case No. 89102558 _ year month day _ amendment _ VI. Patent application scope 48 ·-A method for preserving or improving the sensory quality of a required part of a plant, which includes bringing IIS is contacted with a mixture prepared by additively mixing the ingredients of an additive, wherein the AG 11 S is a mixture of a Group IIA salt comprising (a)-an inorganic acid and (b)-11 A hydroxide or a diacid or A mixture prepared from the ingredients of the mixture of the two is isolated, and wherein the additive includes an alcohol, an acid, a surfactant or a mixture thereof. 49. A method according to item 48 of the patent application, wherein contact with a desired part of the plant is carried out before harvest, during harvest, during processing, or after harvest to protect the seed or a method for improving the sensory quality of nutrition, including: Preparation IM and a mixture prepared by adding ingredients including AG 11 S and an additive to a compound 1IA salt of a / x group lice oxide or a diacid, or an ingredient of this product Divide one thing.丨 Know the method of item 50, one acid, one surfactant, or mixtures, feeds, and beverages of which the nutritional products are foods, foods, food additives, and feed additives , Beverage additives or filling; ασ, music products, biological products, flavoring agents, spices, fragrant incense 1241168 Amendment 5 2 · A method for reducing biological pollution in water, comprising: adding a sufficient amount of a mixture prepared by adding ingredients including AG 11S and an additive in water, wherein the AG IIS is obtained from the mixing including ( a) — an inorganic acid and (b) a group IA hydroxide or a diacid group IA salt or a mixture of the two components, and the additive includes an alcohol, An acid, a surfactant or a mixture thereof. 5 3 · The method according to item 52 of the patent application, wherein the water is drinking water, storm water or sanitary sewage. 54 · A method for preparing an adduct having a desired final acid equivalent concentration, including: (a) The amount of the required inorganic acid is determined by the following formula: Ε1 = (Ν / 2) + (Ν / 2 + B) where E1 is the amount of inorganic acid in moles required before the purity adjustment; N is the final acid equivalent concentration required; and B is the Group 11A hydroxide and inorganic acid required to obtain AGIIS with N For the required N, B is obtained from a pre-made curve depicting the relationship between the inorganic acid and the group 11A hydroxide; (b). Use the following formula to adjust the purity of the used inorganic acid. At · That is, E2 = E1 / C where E 2 is the molar acidity of the inorganic acid required after the purity adjustment Page 64 2001.11.01.060 1241168 _Case No. 89102558_ Year Month Day __ Amendment ___ 6. The scope of patent application; E1 is the same as above; C is the purity adjustment factor of inorganic acid; (c) Water, 4 ml, added to the mineral acid: G = J-E2-I where G is the final volume of the water-containing inorganic acid solution in milliliters of water that needs to be added to the mineral acid; I is given below The required volume of the group I j A hydroxide; E2 has the same meaning as above; and (d) • Add G to E2 to obtain the final aqueous solution of the inorganic acid, where G and E2 have the same definitions as above;… (e) Determine the required amount of Group IIA hydroxide, in moles, by the formula: Fl = N / 2 XB where F1 is the molar amount of Group IIA hydroxide required before the purity adjustment, and N and B have The above meanings; (f) · Purity adjustment Ar by the Π a group hydroxide used by the following equation. That is, F2 = F1 / D where F2 is the content of the group IIA hydroxide required after the purity adjustment, in moles The meaning of F1 is as above; the purity adjusting factor of DsIIA hydroxide; (g) Determining the amount of water required for the preparation of Shu〗 hydroxide solution or slurry of the group A, in milliliters: H = F2 X 1. 5 wherein the amount of water required is Η Group I ΙΑ hydroxide solution or slurry preparation, Page 65 2001.11.01.061 1241168 ____ Case No. 89102558_ Year, month and month 6. The scope of patent application is in milliliters; F2 has the same meaning as above; (h) · Determined by the following formula to be added to the inorganic acid solution to & 4 Find the amount of Group IIA hydroxide aqueous solution or dressing solution with the desired final acid equivalent concentration in milliliters: I = F2 X 2 where I is the amount of Group IIA hydroxide solution or slurry in milliliters; F2 Has the above meanings; ° '(i) · Add Η to F2 to obtain the final aqueous solution or slurry of Group Π A hydroxide, where both Η and F 2 have the above meanings; (j) · Add Group 11A The final aqueous solution or slurry (i) of the hydroxide is added to the final aqueous solution (d) of the inorganic acid; (k) reacting the final aqueous solution or slurry of the Group 11A hydroxide with the final aqueous solution (j) of the helmet acid; And (1) removing the solid formed by reaction (k) to obtain a final AGns solution; and (m) adding a predetermined amount of an additive to the final AGI IS solution. 55. The method of claim 54 further comprising adding a group I a salt of a dibasic acid to the final inorganic acid aqueous solution (d). Jealousy 5 6 · The method according to item 54 of the patent application, in which the inorganic acid is sulfur, and the group A hydroxide is calcium hydroxide, and the group A salt of the dibasic acid is sulfuric acid. 1241168 _Case No. 89102558_ Year Month Amendment_ VI. Patent Application Range 5 7. An adduct with the required final acid equivalent concentration prepared by a method such as the patent application No. 54. Page 67 2001.11.01.063