TWI225500B - Styrene resin films - Google Patents

Abstract

Styrene resin films having been imparted antistatic properties to both film surfaces and good adhesion properties of the films to envelope paper, and a process for producing the same. In these styrene resin films, the surface tension of the front surface of the film base differs from the surface tension of the back surface owing to a hydrophilic treatment and modifiers having almost the same compositions are applied onto the respective surfaces each in an adequate weight.

Description

V. Description of the invention (1) The present invention relates to the hydrophilization treatment of films made of styrene-based resins and the coating of modifiers to improve antistatic properties and anti-slip properties. More details are related to receiving bag-making equipment. And mechanically processed films such as sealing and pasting devices, especially those which are suitable for sealing and pasting styrene resin films. In the prior art, styrene ethyl resin film has strong elasticity and good transparency. Therefore, it is mostly used as food packaging film for lettuce, raw mushrooms, or bananas, and for sealing and pasting. Mouth use) the use of film. The reason why styrene resin film is used as a film for food packaging is that it has good transparency, high food recognition, and good water vapor permeability, and can maintain the freshness of foods with large evapotranspiration (such as raw mushrooms) for a long time. In particular, the reason why envelope film is often used is that non-elastic substrates such as polyethylene and polypropylene are prone to wrinkles during envelope processing and are not used. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Japanese Unexamined Patent Publication No. 8-2303, No. 3 discloses a styrene-based resin film, such as a food packaging bag for maintaining the freshness of a styrene-based resin film. This bag-making is performed in a thin sheet shape, and the food is inserted into a thin film in the bag by hand. However, this film does any treatment on the surface. Therefore, for the automatic filling of shiitake mushrooms, especially when the bag is filled at high speed, the film is smooth and the bag is easy to open (when food is packed in a bag). The difficulty of opening) is bad, which causes the problem of bag deformation. In addition, recently, the packaging bag for bananas is a single-layer styrene-based resin film that has been dissolved and sealed to make a bag. However, when packaging bananas with a large volume, the bag opening must be large. Therefore, the rubbing of the upper and lower films during bag making applies to the Chinese national standard (CNS) A4 specification (210 X 297 mm) -4- 1225500 A7 B7 V. Description of the invention (2) The styrene resin film is charged with static electricity. It is not easy to open, which makes it difficult to put bananas in the bag. • In order to solve this problem, it is known to apply a styrene resin film such as a coating modifier to the surface of the film. However, the following problems still occur. In this way, after the surface of the styrene-based resin film substrate which is suitable for envelope sealing and pasting is subjected to mechanical processing, the surface of the film is improved in smoothness, and static electricity is prevented. For example, the surface of the styrene resin film substrate is subjected to a hydrophilization treatment such as corona treatment, so that the surface tension is made on the surface of the substrate to be 4 0 ~ 5 5 0 AN / cm, and the coating anti-turbidity agent and polysand are used. The modifier of oxygen oil is disclosed in JP-A-Sho 5 3-1 1 5 7 8 1. In this technology, a person who performs corona treatment on one side of the surface of a thin film substrate is treated with corona treatment. Modifier coating on the surface of the substrate. Further, Japanese Patent Application Laid-Open No. 10-1 19.9.78 is disclosed as a coater who applies an antistatic agent on both sides of the substrate surface. In addition, the speed of the bag making machine, especially the sealing and pasting machine and the book automatic inserting machine, for the advanced technology of 400 sheets per minute to 600 sheets per minute, can exceed 100 sheets per minute. Processing at high speed. Along with this increase in speed, films for sealing and pasting are expected to have both the antistatic function attached to both surfaces of the film and the antistatic function attached to the opposite side of the antistatic function to the paper. If the film described in Japanese Patent Application Laid-Open No. 10-1 1 9 9 7 8 is concerned about the electrostatic trouble, it is indeed reduced, but there is concern about the damage of the film, and it is impossible to eliminate the appearance of the film after attachment. Wrinkles, deformed position. That is, this paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back 3 to write this page) I! Packing-Line-Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives System-5- 1225500 A7 B7 5. Description of the invention (3) As a reduction of static electricity troubles To improve the prevention of static electricity, as long as a large amount of static prevention agent is attached to the surface of the film substrate, only the reverse side is heavy. : Prevent electrostatic agent from blocking the surface of the adhesive film substrate, causing wrinkles and deformation. In addition, Japanese Unexamined Patent Publication No. 2-7 2 0 50 discloses a styrenic resin film containing a wax-type antiblocking agent, and Japanese Unexamined Patent Publication No. 2-7 2 0 51 discloses an adhesive containing an anti-blocking agent. For styrene resin films, the films of these two publications can be easily damaged to reduce the damage. However, the problem of static electricity is easy to occur. In addition, in the electrostatic prevention treatment of the single-sided treatment disclosed in JP-A-Sho 5 3-1 1 5 7 8 1, it is extremely difficult to perform the treatment with a sealer. That is, when the styrene-based resin roller-shaped film of the device for sealing and pasting is used to adhere the film to the envelope paper, the unrolled film from the roller shape to the film is in contact with the metal roller and the rubber roller, and the film is in contact with the roller. The contact is a plurality of rollers. Therefore, if the two surfaces of the film are in contact with the rollers, the two surfaces of the film are static. After the film is cut to a predetermined length and before the envelope is adhered, if it is not on the two surfaces of the film, the film is wrapped around each other ’, which causes a problem of continuous production. Therefore, Japanese Unexamined Patent Publication No. 10-119 9 78 discloses a two-sided coater in a thermoplastic resin film for envelope openings. However, the disclosed double-sided coater causes the following problems. That is, the film used in the sealing and pasting machine disclosed in the publication is not hydrophilized on both sides of the film, and the two sides of the film are coated with an electrostatic preventive agent in almost the same amount and then rolled into a roll shape. In the sealing and pasting machine, the paper size of the roller is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) (please read the precautions on the back first to write this page) slt --line-Intellectual Property Bureau, Ministry of Economic Affairs Printed by the employee consumer cooperative-6-1225500 V. Description of the invention (4) After the film is installed, the unwinding and rewinding coiling tension, other conditions: the storage temperature of the film, the same amount of anti-static coating as the corner protection, and a large amount of migration In part, the pole is almost copied on the reverse side. The directions are quite different. The present invention aims to provide a film suitable for high-speed printers and bags, especially for improving the adhesion between paper and film. A7 B7 is also used as a film at the same time. However, after the coating is applied, the environmental temperature, humidity, and humidity of the roller tube are also affected. When the film is unrolled, any side of the antistatic agent is stopped. As a result of the antistatic agent on one side of the film, the antistatic agent and the roller are curled far away. The adhesion of the surface of the antistatic agent to the antistatic agent results in the film and the seal. There are two types of antistatic function on the two sides of the film. The high-speed sealing and pasting machine is processed by mechanical processing for lifting the envelope sealing and pasting machine. The styrene resin film and its manufacturing method are required. Please read the precautions on the back first and then this page. Houyi's Secret Department refined the water line intimately. The person who explained the problem by borrowing the lesson explained that the basic hair material is thinner than the printed version of the printed material issued by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economy. After the same progress, the appropriate amount of the eye can be expressed in terms of its difference from the appropriate surface. The two surfaces of the base surface after the material are thinner than the surface. Zhang group. Facial Agent Minghua Department {Water outside the surface and the surface agent agent into the base surface of the film and the two electric thin materials are static, the film contains a thin film with a thin film attached with a thin film of ethyl oligobenzene to the surface of the It is made of two benzene-based materials, and its group is, that is, the surface of the surface is smoothed with α-force C, the surface of the tension surface}} B) (Α surface, the base film is thin, should be reversed A The surface ratio should be 5 moderate rule J Zhang Ji centimeter 97 2 X 10 (2 standard gauge A4 S) N (C quasi standard bidder 1225500 A7 __ B7 V. Description of the invention (5) 1 · 72 Surface tension (stone) of 350 / iN / cm ~ 450eN / cm and surface tension (α) of 400 / iN / cm ~: 6 0 0 // N / cm, the adhesion amount of the surface (B) composition A styrene-based resin film having an adhesion amount of 25 to 95% by weight of the surface (A) composition. The present invention is such that the surface tension (α) of the film substrate surface (A) is 400 to 600 // N / cm, the surface tension (/ 3) of the film substrate surface (B) is 350 ~ 450 // N / cm, and the surface tension ratio (α // 5) is 1 · 15 ~ 1 · 72 After the hydrophilization treatment, it is performed on the surface (A). The coater contains a modifier composition solution containing at least an antistatic agent and an external lubricant. After drying, the styrene resin film is rolled up in a roll shape, and the modifier composition on the surface (A) is restored. The method for manufacturing a styrene resin film is characterized by the surface (B). [Best Embodiment of the Invention] The following is a detailed description of the present invention. The film base material is a styrene resin as a main component, and contains 50% by weight or more of a styrene resin in the constituent resin composition of the film. The styrene resin of the present invention means 50% by weight or more. Transparent polymers of styrene monomers, such as: polystyrene, styrene-acrylonitrile copolymer, styrene-methyl methacrylate copolymer, styrene-butadiene-methyl methacrylate ternary Copolymers and other well-known polymer resins, as well as synthetic rubber dispersed as a soft component of the polymer, that is, this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -8- 12 25500 A7 _____ B7 V. Description of the invention (6) (Please read the notes on the back before filling this page) Butadiene, styrene-butadiene random copolymer, styrene-butadiene block copolymer, etc. , All rubbers become polystyrene resins, block copolymers of styrene and conjugated: diene, etc. Among them, the general synthetic polystyrene (GPPS), or general polystyrene synthetic rubber is dispersed resin The rigid and transparent side is regarded as the ideal one. The surface of the phenethyl resin film of the thin Θ substrate is hydrophobic. Therefore, when a solution containing a water-based modifier such as an antistatic agent and anti-turbidity agent in water is applied to the surface, the modification is included. The aqueous solution of the agent is in the form of droplets and cannot be uniformly applied. In addition, when the envelope is manufactured, the adhesive on the film surface and the envelope paper is an aqueous emulsion. Therefore, it must reach the substrate earlier than this adhesive. After the surface is cured, the film surface must be hydrophilized. As described later, the hydrophilization treatment is performed by an acid treatment such as sulfuric acid, nitric acid, or a primer treatment such as a corona treatment. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The surface tension ratio (α / / 3) on the surface of the styrene resin film substrate in the present invention must be hydrophilized in a specific range. In particular, when sealing and pasting, it is suitable for sealing and pasting machines and automatic book insertion machines (hereinafter referred to as sealing and pasting machines). Be sure to set the difference in the degree of hydrophilization treatment on both sides. That is, when "the styrene resin film is used for sealing of envelopes, sheets, etc.", the "styrene resin film is affixed to the inside of the adherend such as an adhesive", and its film surface (A >) is the innermost side of the envelope. After the film surface (A /) is electrostatically charged during the sealing process, the film surface (a —) and the object to be adhered are attracted by static electricity, and the seal becomes difficult to open, and it is difficult to insert books automatically. In addition, the books contained in the inside of the adherend are in contact with the inner surface of the adherend, and are sealed or placed inside. After the friction is generated, the size of the paper is in accordance with China National Standard (CNS) A4 (210 X 297). (Mm) -9-1225500 A7 B7 V. Description of the invention (7) (Please read the note on the back 3 to write this page) The surface (A /) is not only electrostatic, but even the books themselves. In particular, in a book insertion machine that is too strict, the film surface (A >) is charged with static electricity, and even the book itself is charged with static electricity. Therefore, it is impossible to perform book or other interpolation operations under static electricity. Therefore, the surface of the film (A /) must be fully protected against static electricity. In addition, when the thin film surface (B /) with static function is used to roll multiple rollers under the sealing and pasting machine, in order to prevent discomfort caused by static electricity, the film must be wrapped with each other, and it must be equipped with electrostatic properties. Adhesive and film adhesion performance. For this purpose, the film surface (B /) is made of the film surface (A /) with a specific proportion of electrostatic function, which must fully meet the adhesive performance of the adhesive. For this reason, in the present invention, it is necessary to make the surface tension (yS) of the film substrate surface (B) and the surface tension (α) of the film substrate surface (A). The ratio (α / Α) of each other is 1. 15 ~ 1 · 7 2 of the limited scope. The specific reason is as follows. When the surface tension ratio is 1 · 1 5 ~ 1 · 72, even if the roll tension, temperature and humidity during storage are affected when the roll is printed by the consumer co-operative cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the roll will be unrolled. When forming a thin film, it is necessary to increase the amount of the modifier composition on the surface of the film (A >), and the two sides are moderately electrostatically preventive to maintain the arrival time of the adhesive. The ideal surface tension ratio is 1 · 2 0 ~ 1. 60. When the surface tension ratio is less than 1 · 15, the take-up tension when the film is rolled in a roll shape, the temperature and humidity during storage are the same as those when the substrate is not hydrophilized (A >), the amount of the modifier composition on the surface of the film (B >) is within an appropriate range. Conversely, when the surface tension ratio is greater than 1 · 72, the film size of the paper conforms to the Chinese National Standard (CNS) A4 (210 X 297 mm) -10- 1225500 A7 despite the modifier.

Excessive peeling force to each other 'is very difficult to unwind roll-shaped film. -------------- Installation—— (Please read the precautions on the back first to write this page) Also, the film substrate surface (A) and the film substrate surface (B) are not on both sides. When hydrophilizing treatment is performed on both sides, it is not possible to predict how much the film surface (A —) or film surface (β /) adheres to, such as JP-A-1 ◦-1 1 9 9 7 Example 3 and implementation Example 5 proves this. As mentioned above, those with different properties on the film surface (A /) and (B-) can also be used as food packaging films. For example, JP-A-8-223 0 9 3 3 when laminated with a styrene resin film and other resin films, when the surface (B /) is used as the surface of the laminated film, the amount of adhesion is reduced. The surface does not reduce the bonding strength during lamination, and the film surface (A-) with good lubricity and antistatic properties can suppress the occurrence of bag deformation during automatic bag making. In bags with large openings such as banana packages, the surface of the film (A /) is the inside of the bag, and the bag can be easily opened after being equipped with an antistatic device. • Line-In the following, the specific surface tension of the substrate surface is limited by the following reasons, so that the solution to the problem of the present invention can be easily achieved. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The surface tension (α) of the film substrate surface (A) is in the range of 400 // N / cm ~ 6 0 0 // N / cm and is hydrophilized. When it is maintained within this range, the modifier surface can be more uniformly adhered to the surface of the substrate, and at the same time, the activation of the surface of the film substrate is in a suitable range. Therefore, it is difficult for the films to adhere to each other (the peeling force between the films becomes higher) ). It is preferably 430 / iN / cm ~ 580 // N / cm, and more preferably 450eN / cm ~ 5 50 # N / cm. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -11-1225500 A7 B7 V. Description of the invention (9) The surface tension of the substrate surface (A) and the opposite surface (B) (/ 3) is in the range of 3 5 Ο / ζN / cm to 4 5 0 // N / cm. When the ratio is more than 3 5 0 # N / cm, the affinity between the film surface and the adhesive becomes better, and the adhesive can be quickly fixed on the surface of the substrate. Therefore, it is extremely effective to increase the bonding force between paper and the adhesive and shorten the bonding time, especially for high-speed sealing and pasting of more than 1,000 pieces per minute. The better is 3 8 0 // N / cm or more. The upper limit of the surface tension (/ 3) of the film substrate surface (B) is 4 5 0 // N / cm. When the surface tension of the surface of the film substrate (B) is greater than 450eN / cm, (limited by the surface tension ratio, the surface tension of the surface of the film substrate (A) is at least 5 1 5 // N / cm), then The roll-shaped rewinding film will not be easy to unwind, especially the sealing and pasting at a high speed of more than 1000 pieces per minute is more difficult to use. This is because the coating amount of the film surface (B /) is less than that of the film surface (A >). The surface activity of the surface of the film substrate (B) after the hydrophilization treatment is too high. After the multiplication of the surface of the substrate (A), the peeling force of the films becomes too high. The surface tension (Θ) of the surface (B) of the film substrate is preferably 4 3 0 // N / cm or less. After the hydrophilization treatment, the multiplication effect between the surface of the activated film substrate (A) and the surface of the film substrate (B), the peeling force between the film substrate and the film becomes higher, and the peeling force from the adherend is increased. Force has also been considered. In the following, a composition (hereinafter referred to as a modifier composition) containing at least an antistatic agent and an external lubricant attached to the surface of the film substrate (A) and the surface of the film substrate (B) is described in detail. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back first to write this page)

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -12-12500500 A7 ------- B7 V. Description of the invention (1Q) As an antistatic agent such as carbon black, nickel powder, etc. 塡Examples of surfactants such as filling materials and antistatic properties. (Please read the precautions on the back page first to write this page) 'The former is to cause static electricity to leak after the conductive particles are in contact with each other' and the latter is to attract static electricity by hygroscopicity and ionicity. Since it is necessary to cause static electricity to leak through the surface contact of fine particles, it is necessary to perform coating in a large amount, and the transparency is significantly deteriorated. Therefore, it is preferable to use a surfactant described later. The external lubricant is for the purpose of improving the lubricity, and the lubricity is attached to the surface by the lubricity existing on the surface and the roller principle. Examples of those with lubricity include silicone oil, wax, and surfactants described below. As the silicone oil, there are dimethyl silicone oil and the like. Among the waxes, such as ammonium stearate, erucamide, and stearic acid are included in the ester lubricant. Examples are butyl ester and monoglyceryl stearate. Furthermore, examples of the fine particles include dioxin, silicon dioxide, talc, and calcium carbonate. Although oil-soluble activators such as silicone oil and osmium are suitable for improving lubricity, they are not ideal because they reduce the sealing strength during bag making and impede the bonding with paper. Printed as an ideal antistatic agent by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, such as: surfactants with antistatic properties described later, polyethylene oxide alkylamine or polyethylene oxide polypropylene oxide Examples of alcohol ethers and ideal external lubricants include examples of inorganic particles described later and polyether-modified polysiloxanes. The addition of external lubricant is generally based on the weight ratio of antistatic agent 1 in the range of 0. 01 to 3, and more preferably in the range of 0. 05 to 2.5. The composition of the ideal modifier for the present invention If the following three groups of paper sizes are applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -13- 1225500 A7 B7 V. Description of the invention (11) Please read the notes on the back before filling in this page. . That is, it contains a surfactant as an antistatic agent, inorganic fine particles as an external lubricant, a first modifier containing more water-soluble polymers, a substance, and a surfactant as an antistatic agent. , A specific polyether denatured polysiloxane as an external lubricant, a second modifier composition containing more water-soluble polymers, and a specific polyethylene oxide alkylamine or polycyclic ring as an antistatic agent Ethylene oxide poly (propylene oxide glycol ether), as a third polyether modified polysiloxane modified external lubricant composition. In addition, the antistatic agent and external lubricant have functions besides this function. First, the first modifier composition in the present invention will be described. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. For the first modifier composition, it can be used as an antistatic agent if it has a surface active agent with antistatic properties. For example: carboxylate, sulfonate, sulfate, phosphate, phosphate and other anionic surfactants, betaine-type, imidazoline-type and other amphoteric surfactants, polyvalent alcohol-type fatty acid sorbitol Non-ionic surfactants such as anhydride esters, fatty acid sucrose esters, fatty acid alkanolamines, and polyethylene glycol condensation fatty acids, aliphatic alcohols, aliphatic amines, alkylphenols, and polypropylene glycols can be used. From the point of view of antistatic performance with stability, ampholytic or nonionic surfactants are preferred. Two or more types may be used in combination. Examples of the inorganic fine particles include fine particles of silica, fine particles of silicate type, fine particles of synthetic zeolite type, fine particles of calcium carbonate, and fine particles of magnesium carbonate. The lubricity of the film can be improved by the action of the inorganic fine particles, and the peeling force of the films after the roll-shaped rewinding can be reduced. The inorganic fine particles must be those having an internal surface area, preferably those having a specific surface area of 0. 5 to 4 m / g. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -14- 1225500 A7 __ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (12) Number of average particle size The diameter is 1 to 7 # m, and more preferably 2 to 5 μm. From the particle size and internal surface area, it is better to use silica particles. 'By having an internal surface area, some surfactants and water-soluble polymers are placed in the microparticles, and the anchoring power of the surfactants is higher than that when only water-soluble polymers are used. In addition, if the number average particle diameter is 1 to 7 // m, after contacting with the light tube of the sealing and pasting machine, the particles will not easily fall off, and the anchoring force with the surfactant will be improved. As a water-soluble polymer, there are polyvinyl alcohol, polyvinylpyrrolidone, sodium polyacrylate, sodium polystyrene sulfonate, methyl cellulose, etc., and polyvinyl alcohol is considered as the solubility and fixing power of water. Best. Moreover, the alkalinity of polyvinyl alcohol is preferably 40 ~ 99mo1%, more preferably 60 ~ 95 5 m ο 1%. The degree of alkalinity is maintained in this range. It is easy to turn into an aqueous solution, and it is not easy to cause a decrease in the strength of the film. As a result, the roller does not become contaminated even if it touches the roller. The molecular weight of the water-soluble polymer is generally 100 to 15,000, and more preferably 200 to 5 0 0. Addition of a water-soluble polymer has the effects described below, and at the same time has the effect of easily and uniformly coating the modifier composition. When it is necessary to start a high-speed printing machine, a bag making machine, and a high-speed sealing and pasting machine for the film of the present invention, the first modifier composition contains not only the above-mentioned surfactant, but also water-soluble polymers and inorganic fine particles. By adding aqueous polymer and inorganic fine particles, the surfactant is strongly fixed on the film surface. Not only the rollers of various devices are not contaminated, but also the water-soluble polymer and inorganic fine particles are multiplied. After that, the surface of the film has a feature of preventing the inorganic fine particles from falling off. This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back first \ ^ Write this page)! Loading # νδΊ · • Line--15- 1225500 A7 _ B7___ 5 Explanation of the invention (13) The optimal mixing ratio in the first modifier composition is as described above, and the weight ratio in (a) the surfactant, (b) the water-soluble polymer, and (c) the inorganic fine particles is ( a): (b): ((3) = 1: 0 · 〇3 ～ 3: 0 · 01 ～ 1.25. When the mixing ratio of the water-soluble polymer is 0. 〇3 ~ 3, the surfactant and High fixing power, not easy to peel off from the surface of the film. Moreover, the properties of surfactants are easy to appear, so it can improve the performance of preventing static electricity. When the mixing ratio of the inorganic fine particles is 0 · 〇1 ~ 1. 25, by water solubility The synergistic effect of polymer and inorganic fine particles is exerted by the fixation effect of the interfacial activity and the agent, and the inorganic fine particles are not easy to fall off the surface of the film. The static electricity prevention performance and the lubricant (dynamic friction coefficient) are different according to the requirements of different applications. For example: as a film for food packaging, When the bag is made at the same time as the filling, the high-speed dynamic friction coefficient between the film and the metal is 0.15 ~ 57. At a relative humidity of 25% at 20 ° C, the half-life with static voltage reduction is 3 0 0 When it is less than 2 seconds, the bag will not be deformed and can be filled automatically. For example, when the film of the present invention is used for sealing and pasting, the high-speed dynamic friction coefficient between the film and metal is 0 · 1 5 ~ 0. 3 5, 2 0 γ If the half-life with static voltage reduction in an atmosphere with a relative humidity of 25% is less than 90 seconds, the problem of wrinkles will not occur even at high speed processing of 1000 pieces per minute or more. To meet this requirement level The coating amount of the surface of each modifier film substrate is (a) = 2 · 0 ~ 15mg / m2, preferably 3 ~ η 〇 (Please read the precautions on the back to write this page) Order- · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Online Economy-16 · 1225500 Α7 __ Β7 V. Description of the invention (14) nig / rri, (1)) = 0.5 ~ 61 ^ Ji / 1 ^, the better is 〇.5 ~ 4mg / ni, (c) = 0.2 ~ 2.5mg / ni (Please read the precautions on the back before filling this page) It is preferably 0 · 3 ~ 2 · Omg / πί, and more preferably is 0 · 3 ~ 1 · 8 m g / ιτί. When the surfactant is 2 to 15 mg / i ri, the antistatic effect is sufficient, and the inorganic fine particles are not buried in the coating film layer of the surfactant, so the surfactant is appropriately coated on the inorganic fine particles. State, used for sealing and pasting machine still does not cause wrinkles and deformation of the film static electricity. The water-soluble polymer has the function of maintaining the inorganic fine particles on the surface of the thin film, and cooperates with the surfactant. The surfactant alone cannot fully maintain the function, so a stronger agent is added followed by a strengthening agent. In order to find this effect, a painting amount of 0 · 5 ~ 6 m g / πί can effectively appear. Within this range, the effect of the inorganic fine particles can be sufficiently maintained, and further, it is difficult to cause damage accompanying peeling from the surface of the inorganic fine particle film. In addition, it does not hinder the antistatic performance of the surfactant, and it does not cause the lubricant to be lowered because the film surface adhesion is too high. When the amount of inorganic fine particles printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is 0 · 2 ~ 2 · 5 mg / πί, the fine particles are dispersed in a protruding shape, exerting the effect of improving the lubricant, and showing the number of sufficient fine particles. The number of fine particles detached from the film is also reduced, and it is not easy to cause damage to the film at this time. Next, the second modifier composition will be described. The second modifier composition is one containing polyether-denatured polysiloxane, a surfactant, and a water-soluble polymer. One of the characteristics of this combination is that it can still enhance the lubricant without inorganic particles, so there is no need to worry about the removal of inorganic particles from the film. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -17-1225500 A7 B7 V. Description of invention (15) The risk of falling. The present inventors have found that a modifier that has a lubricant even without inorganic fine particles, that is, polyether-denatured polysiloxane, is coated with a second modifier composition (please read the precautions on the back first ^ write this page) Reveal: the shower. The polyether-denatured polysiloxane disclosed in the present invention is a structure represented by the following formula (1), and the methyl portion of dimethylpolysiloxane is carried out with polyethylene oxide group and polypropylene oxide alkyl group. Transgender. CH3 • Yan 3--ch3 'ch3 I CH3-SI-0— -Si-〇- Si 〇 | Si CH3 (1) CH3 -CH3 _ m _ C3H6 (C2H40) a (C3H6〇) bR1 _ nCH3 Formula (1 ), R 1 is a hydrogen atom or a lower alkyl group having 1 to 4 carbon atoms, an integer of m = 0 to 80, an integer of n = 1 to 30, an integer of m + n = 1 to 100, n / (n + m) = 〇 · 1 ~ 1 · 0, a integer of 5-30, b = 0-30, a + b = 5-6, and a: b ratio of 100: 0 ~ 100: 50 persons. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the better is an integer of ~ 30 in formula (1), η / (m + n) = 0.3 · 1 ~ 0, a + b = 5 ~ 15, a ·· b is a polyether-denatured polysiloxane having a ratio of 100: 0. After using polyether-denatured polysiloxane alone as a modifier, in order to meet the performance of both static prevention and lubricant, the coating amount applied to the film must be more than the surfactant. However, polysiloxane molecules have low surface tension. Therefore, the water resistance of the film surface is too good, which results in poor adhesiveness between the adhesive and the film when the paper is adhered to the film after the sealing and pasting machine is used. Therefore, this paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) -18-1225500 A7 B7 V. Description of the invention (16) The deformation of the attachment position. -------------- Packing --- (Please read the precautions on the reverse side and write this page first) Also, in the styrene resin film, most of the modifiers such as surfactants: After being coated, the film is used repeatedly. However, the polyether modified polysiloxane and the styrene resin are non-miscible. Therefore, the mixed amount of polyether modified polysiloxane is increased, the film is whitened, and the transparency is poor. Therefore, it is not easy to reuse. In the second modifier composition, the polyether-denatured polysiloxane and the surfactant are mutually used, so the amount of polyether-denatured polysiloxane can be reduced. In this case, as the surfactant, any of the aforementioned anionic, cationic, and nonionic ones can be used arbitrarily. Furthermore, in the second combination, after the above-mentioned water-soluble polymer is mixed, and the water-soluble polymer is fixed on the surface of the film substrate, the water-soluble polymer is to maintain a surfactant, and the surfactant is uniformly dispersed in the film After the surface of the substrate, it is stable and has antistatic properties. -Line- The ideal blending ratio in the second modifier composition is (a) a surfactant, (b) a water-soluble polymer, and (d) polyether modified polysiloxane (a): (b) (D) = 1.0: 0.03 to 2.0: 〇 · 1 to 5 · 7. This ratio is suitable for mechanical processing applications such as sealing and pasting machines. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the polyether denatured polysiloxane is 8 to 50 wt%, the surfactant is 15 to 90 wt%, and the water-soluble polymer is 3 to 30 wt%. %% of the composition is better. After the polyether-denatured polysiloxane is made to 10% by weight, a lubricant with moderate and sufficient lubricant and blocking resistance (decreased peeling force) can be obtained. As a result, when the seal is pasted, it is difficult to cause deformation of the adhered position of the object to be adhered to the film. Moreover, the adhesion with paper is also appropriate, and the recycled use does not affect the paper size. The Chinese national standard (CNS) A4 specification (210 X 297 mm) applies. -19- 1225500 A7 B7 V. Description of the invention (17) Transparent film Sex. In addition, when the surfactant is made 15% by weight or more, especially at low temperature (20 ° C, 20% R Η), it can provide good antistatic performance, and it is not easy to appear when the envelope is pasted. , The blocking of the film, the deformation of the paste position. In addition, the films have good frictional properties and anti-blocking properties, and it is difficult to cause film wrapping when the envelope is pasted. Moreover, the peeling force between the films is extremely suitable, and the film in the form of a stabilizer can be repeatedly taken out. In addition, when the water-soluble polymer is made 3 to 30% by weight, even if the polyether-denatured polysiloxane is a person with a low surface tension and the surfactant is uniformly dispersed, the surfactant can be obtained through a thin film base. The surface of the material is evenly fixed. This is due to the affinity of the water-soluble polymer and the surfactant. The film does not produce stickiness, uniform dispersion of surfactants, lubricants, and good balance of static electricity prevention. According to the above-mentioned performance balance, the compounding ratio of the polyether-modified polysiloxane is 40 to 60% by weight, the surfactant is 60 to 40% by weight, and the water-soluble polymer is 5 to 25% by weight. Those who are more ideal. The adhesion amount of the ideal modifier composition on the surface of the film substrate is preferably 2 to 3 Omg / m2, and more preferably 2 to 15 mg / rri. In this range, the antistatic property and the lubricant are sufficient. When used for sealing and pasting, the deformation of the attachment position will not occur, and the transparency and anti-blocking will not be affected when recycled. The third modifier composition will be described. The third modifier composition contains a polyether-modified polysiloxane represented by the above formula (1) and a polyethylene oxide alkylamine represented by the following formula (2) or a polycyclic ring represented by the formula (3) The size of oxyethylene paper is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back first ^ 5 ^ write this page) Printed by the cooperative -20 · 1225500 Α7 Β7 V. Description of the invention (18) Alkyl propylene oxide diol R2-N:

(C2H4〇) x-H (C2H4〇) y-H (2) In the formula (2), R2 is an alkyl group having 8 to 22 carbon atoms, an integer of χ = 1 〇, and an integer of y = 1 to 30. CH,

H0 (CH2CH2〇) d (CHCH20) e (CH2CH20) fH (3) (Please read the note on the back 3 to write this page) The compound represented by formula (3) has a molecular weight of 1,500 ~ 1 5,0 0 If it is 0, the repeating part of d and the repeating part of ί are 40% to 95% by weight in the molecule. Compared with the first and second modifier compositions, the third modifier composition does not need to worry about the shedding of inorganic fine particles because it does not contain inorganic fine particles. Furthermore, it does not contain a water-soluble polymer, so it can be characterized as a low-cost manufacturer. Among the surfactants printed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, there are many types of surfactants mentioned above, without using water-soluble polymers. When polyether denatured polysiloxane is used, the surfactant is used as the interface activity of formula (2) Agents are those who are characteristic. For example, after the combination of polyether modified polysiloxane and fatty acid ammonium disclosed in Japanese Patent Application Laid-Open No. 10-11119, the lubricant and anti-blocking characteristics of modified polysiloxane are hindered, and at the same time, Since the antistatic property of the fatty acid amidine is impeded, the purpose of the invention cannot be achieved. It is not necessary to add a water-soluble polymer to the third modifier composition for the purpose of improving workability. This is polyether denatured polysiloxane and polyethylene oxide alkylamine-21-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1225500 A7 _____ Β7 5. Description of the invention (19) The mutual solubility is good. Therefore, the surface of the film substrate can be uniformly coated without adding a water-soluble polymer. : The ethylene oxide alkylamine of the formula (2) disclosed by the present invention is through the additional reaction of an aliphatic amine having a carbon number of 8 to 22 and ethylene oxide, or the dehydration of an aliphatic amine and ethylene oxide. Acquired after the reaction. Among them, in terms of the antistatic property of the film and the affinity of the lubricant and polyether-denatured polysiloxane, the carbon number of the aliphatic amine is preferably 8 to 18, for example: laurylamine, myristylamine Saturated aliphatic amines such as stearylamine are used alone or as mixtures containing unsaturated aliphatic amines such as saturated aliphatic amines and oleyl amines (such as coconut oil, semi-fat, etc.) Amine) is a polyethylene oxide alkylamine formed from an aliphatic amine. More preferably, in the formula (2), the poly (ethylene oxide alkylamine) having an integer of X 2 to 1 to 15 and an integer of y to 1 to 15 is the poly epoxy of formula (3) disclosed in the present invention. Ethylene polypropylene oxide glycol ether is a high molecular weight non-ionic surfactant with polyethylene oxide group as the hydrophilic group and polypropylene oxide group as the hydrophobic group. After the numbers of a, c and b, a balance between hydrophilicity and hydrophobicity can be achieved. ------ Equipment --- (Please read the note on the back HI first to write this page) Thread · Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs + Poly-d-C ether poly-polymeric polystyrene The neutron's energy can be totally controlled, and the anti-viewing surface has a smooth and smooth surface with a moisturizer and a neutral bright hair, which is better than the% weight 5 9 1 ο 4 for the rate. % Of the content) f Weight 5 8 Poly} with} a} a paste b C stick C is mouth, ether seal oxy alcohol to silicon two is polyalkylated propion oxygen. Ether ring poly ο} academy · a B 9 C oxygen ~ ring 1 rate poly · ratio or ο amine: Ligand 1 alkane II want alkane > Lithium b oxygen C ring: This paper size applies to China Standard (CNS) A4 specification (21〇X 297 public love) -22- 1225500 Α7 _ Β7 V. Description of invention (20) When using for mechanical processing, the following mixing ratio is appropriate. That is, the polyether modified polysiloxane described above is composed of 8 5 to 10% by weight, and the polyethylene oxide alkylamine or polyethylene oxide polypropylene oxide glycol ether is composed of 15 to 90% by weight. The modifier composition should be appropriate. By making this mixing ratio, moderate lubricant, sufficient lubricant, and anti-blocking properties (reduced peeling force) can be obtained. As a result, there is no deformation of the attachment position and the film's winding during the sealing and pasting, and there is no obstacle to the adherence to the adherend, and the transparency of the film is not affected by recycling. In addition, when the polyethylene oxide alkylamine or polyethylene oxide polypropylene oxide glycol ether is made 15% by weight or more, it may be used under low temperature conditions (20 t, 20% RΗ). It has good antistatic performance, and it is not easy to cause film blocking and deformation of the sticking position when the envelope seal is pasted. In addition, if the content is less than 90% by weight, the friction and anti-blocking properties of the films can be improved, and the film cannot be easily entangled when the envelope is sealed. In addition, since the films have appropriate peeling degrees, the stable roll-shaped film can be repeatedly taken out. When these polyether denatured polysiloxanes and polyethylene oxide alkylamines or polyethylene oxide polypropylene oxide glycol ethers are separately coated, it is not easy to fully meet the antistatic properties, lubricants, and Anti-blocking, transparency, and if used, it can improve the uniform dispersion on the surface of the polyether modified polysiloxane film, improve the multiplication effect of the lubricant and the antistatic property. Adhesiveness. From the viewpoint of the above-mentioned performance balance, if the polyether-denatured polysiloxane is 40 to 60% by weight, the polyethylene oxide alkylamine or polyethylene oxide polypropylene oxide glycol ether is 6 A blending ratio of 0 to 40% by weight is more desirable. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm). Please read the note at the back.

I% Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs on this page-23- 1225500 A7 B7 V. Description of the invention (21) In addition, the amount of the modifier composition attached to the surface of the film substrate is on either side 2 ~ 3 Omg / πί is preferred, more preferably 2 ~ 1 5 nvg / nf. This range is the ideal range for preventing static electricity. When the bag is made, the envelope is not easily deformed when it is pasted. In addition, the adhesiveness with paper can be ensured, and the transparency and anti-blocking properties are not affected by recycling. Next, the total adhesion amount of the modifier composition of the present invention will be described in detail. The compounding ratio of the modifiers disclosed in the present invention is as described above, and when the film of the present invention is used for mechanical processing, especially for envelope sealing, the following are separately described below. The total adhesion amount of the film surface (A /) and (B >) of the modifier composition formed by the modifier is preferably in a specific range. The more the amount of modifier composition adheres, the better the antistatic performance and the anti-turbidity performance. However, when it is used for sealing and pasting envelopes, it should be attached in a limited range for the following reasons. Specifically, the film surface ( The adhesion amount of the modifier composition of A /) is 4.5 mg / ηί ~ 30 mg / πί, and the adhesion amount of the modifier composition of the film surface (B /) is 2.0 mg / m2 ~ 15 mg / rri person. When the amount of film surface (A /) attached to the film printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is within this range, it has sufficient antistatic properties and does not cause the film to be sticky. When the adhesion amount of the film surface (B /) is in the above range, not only the antistatic performance can be satisfied, but also the time for bonding the film to paper can be shortened. This is as described above, and is not caused by undue hindrance to the fixation of the modifier composition adhesive to the surface of the substrate. In addition, any of the modifiers of the film of the present invention having the above-mentioned composition is composed of any of the modifiers. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -24- 1225500 A7 __ B7 V. Description of the invention (22) In the above-mentioned blending ratio, when the total adhesion amount is obtained, it has the following physical properties. (Please read the precautions on the back before filling in this page): The electrostatic properties of each surface of the film are as described in JI s L 1 〇 9 4 half grief period, the measurement atmosphere is temperature 20 ° C, relative humidity 20% The medium film surface (A /) is 90 seconds or less, and more preferably 60 seconds or less. The film surface (B /) is 300 seconds or less. When the half-life of the film surface (A /) is within this range, the inner sealing of the automatic inner sealing device of envelopes and books and the like will not cause the film to be entangled with each other. The thickness of the surface of the film substrate (A) and (B) will be described in detail below. In the present invention, the center line average value 値 of the surface thickness parameter (hereinafter referred to as "surface roughness parameter 〃") is preferably made into a specific range. The surface roughness parameter is determined by using a surface shape analysis device (SAS-2 0 1 0 manufactured by Mingxin Industrial Machinery Co., Ltd.) and its modifier on the surface of the film substrate before being coated by a thickness curve on a specific straight line. After the extraction, the average deviation is obtained for the thickness and thickness curves of the film divided by 1 mm by 1 mm in the longitudinal and transverse directions, and the area around the centerline of the film is calculated. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A better form of the present invention is that the surface thickness parameter of the surface of the film substrate is 0 · 4 ~ 2 · 2 // m. More preferably, it is 0.42 ~ 2.0 μm. In the present invention, by modifying the composition of the modifier to improve the surface properties of the film, and for the easy-to-slip surface, it is possible to use the inorganic fine particles with a coating amount in a specific range under a specific range of diameters for modification (the first 1 composition), or this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -25- 1225500 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (23) Those who use polyether denaturation in a specific range of coating amount, and the film substrate itself has smoother unevenness: it is found that the effect is better under the condition of high speed running. That is, the surface thickness parameter is 0 · 4 ~ 2 When the surface is smooth and mechanically processed at high speeds, it has less borrow damage and good slippage. Therefore, for example, in envelopes, vacuum rollers that attract films It is also difficult to cause deformation of the position when the film is pasted. Generally, smoothness is evaluated by mechanical coefficients such as bag-making equipment and high-speed sealing and pasting machines based on the dynamic friction coefficient. If the smoothness is measured by the prior art, it is not ideal. In the present invention, when the dynamic friction coefficient between the film and the metal (made of stainless steel with a mirror surface) under 30 m is 0.1 to 5 · 0 · 3 5 as the surface thickness is greater than 2 · 2 // m, the dynamic In the high-speed dynamic friction coefficient, it is clear that when it is used for envelope mouth sticking, the two sides of the film with the above-mentioned high-speed dynamic friction coefficient are within the range of the high-speed dynamic friction coefficient. In other applications, these are not necessary conditions. For example, the high-speed dynamic friction coefficient of 0. in the automatic bag filling machine described above can still be used. When the surface thickness is made into the specific range, the rubber-modified polystyrene resin is appropriately adjusted in accordance with the tree line. At this time, the adjustment is modified mechanically according to the rubber-modified polystyrene polysiloxane. At 2 // m, the surface of the watch is affixed to the wrinkles of the high-speed film by a rubbing seal such as a metal roller. Indefinite, the measurement of the working hours per minute / minute is the reference friction system. The friction system of this hair is more 15 ~ In particular, the speed is lower than the speed of the clock after the high speed, the high speed, especially the number becomes larger, and the thin film is better. However, after adding the styrene resin grease into the resin, you can enter the rubber particles in the resin. Please read the note on the back first. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -26- 1225500 A7 B7 V. Description of the invention (24) The diameters are different. Generally, 3 ~ 24% by weight of rubber modified polystyrene resin is suitable. In addition, the rubber-modified polystyrene-based resin is dispersed as particles in a particle-like shape, for example, by blending a block copolymer that does not belong to ethylene aromatic hydrocarbons and a conjugated diene, or an organic or inorganic styrene-based resin. Fine particles can also be adjusted afterwards. The composition of the microparticles varies depending on the diameter of the microparticles and the composition of the resin composition, and it is generally preferred to use a compound in an amount of 1% to 10% by weight. The diameter of the fine particles is preferably from 0.5 to 10 // m. When the blending amount is within this range, the overall film is uniform and smooth unevenness can be achieved to achieve the desired dynamic friction coefficient. In addition, when the particle diameter in this range, the unevenness is also in an appropriate range. At the same time as the above combination, under the biaxial extension, there is a granular component in the film, which affects the film surface and can form smooth unevenness. In the following, the adhesion time is described in detail as an example with the adhesive film on the seal. (The method of measuring the bonding time is described later.) The bonding of the film and the envelope paper in the sealing and pasting machine is performed on the film, and the adhesive and the envelope paper are bonded almost simultaneously. Next, it is carried out on a metal cylinder. While the cylinder is rotating at a high speed, the envelope paper is fed in the connection direction of the cylinder, and the film is contacted with the envelope paper, and then it is continued. When the film is in contact with the envelope paper, it is simultaneously adhered by the shearing force of the cylinder wiring direction. Therefore, the adhesive on the film surface and the envelope paper is fixed in a shorter time, and the film and the sealing edge are fixed. Whether ectopic is the focus of high-speed sealing and pasting. Envelope paper is easy to absorb the adhesive of water-based emulsion, and it fixes very fast. Because of the presence of antistatic agent on the surface of the film, the adhesive reaches the thin paper. The standard of Chinese paper (CNS) A4 (210 X 297) is applicable. (Mm) Please read the notes on the back.% Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs on this page. 27- 1225500 A7 __ B7 V. Description of Invention (25) -------: ----,丨 β Pack (Please read the precautions on the back to write this page) The time until the surface of the film substrate is cured, that is, the next time is very important. In this case, it is preferable that the bonding time between the surface of the film substrate and the paper is 30 seconds or less. : In this range, the adhesive will be cured on the surface of the film substrate very quickly. Therefore, the film and the sealing edge will not be susceptible to eccentricity, and will not cause the envelope to deteriorate. The better is less than 25 seconds, more The best is less than 20 seconds. In addition, the difference between the adhesion time of the composition to the film surface (A /) and the paper and the adhesion time of the surface (A /) and the reverse film surface (B >) to the paper is 1 second or more, The surface (B >) and paper are preferably adhered to each other for 30 seconds or less. Hereinafter, the manufacturing method related to the present invention will be described in detail. Styrene-based resin or styrene-based resin is mixed with known additives such as heat stabilizers, oxidation inhibitors, and plasticizers as necessary, and then melted and kneaded in an extruder, and then subjected to a tenter method and a blow molding method. The stretching operation is performed to form a film of a predetermined thickness. --Line- When using the tenter method, you can arbitrarily choose biaxial simultaneous extension or biaxial progressive extension. The extension temperature ranges from the instant softening degree of the styrene resin + 2 0 t to the instant softening point + 4 0 ° C. The next performer should. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The rigidity of the film extended by the instant softening point is less than + 20 ° C. The rigidity of the film becomes higher. When the seal is pasted, the envelope paper and the film are damaged and deformed. When the instant softening point is less than + 40 t, the elasticity of the stretched film is weakened. When the bag is automatically filled, the film cannot be guided along the roller. Poor sealing. In addition, wrinkles may occur during the sealing and pasting operation. In the above extension temperature range, both the extension ratio and the aspect ratio are made to 2 ~ This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -28- 1225500 A7 ----B7 V. Description of the invention (26 ) 17 times, after attaching to the orientation, from the aspect of the strength and uniform extension of the film, especially 4 to 12 times is appropriate. The stretch ratio (longitudinal stretch ratio / horizontal stretch ratio) is preferably in the range of 1 to 1.3. In the blow molding method, the temperature at the elongation start point is the instantaneous softening point + 3 0 ° C ~ + 9 0 ° C, and the central part of the boiling is the instantaneous softening point + 2 0 ° C to the instantaneous softening point 60 ° C. The boiling is adjusted. While the temperature of the chamber is extended 2 to 17 times. From the point of view of the strength and uniform extension of the film after the orientation, especially 4 to 12 times is preferred. In the present invention, the thickness of the film subjected to the stretching operation is not particularly limited. Generally, food packaging is used in a range of 10 to 6 0 // m, preferably 15 to 50 V m. If it is less than 10 m, the strength will be insufficient, and the food will be easily damaged when it is packaged. On the contrary, when it is more than 60 m, the rigidity will be high and the sealing will not be good. In addition, when used as an envelope seal, the thickness should be 1 5 // m ~ 5 0 // m. When the thickness of the film is less than 1 5 // m, the thickness is too thin and rigidity is low, and wrinkles occur when the seal is pasted. On the other hand, when it is larger than 50 μm, the rigidity is deformed with the envelope paper when the seal is pasted. The more ideal is 2 0 // m ~ 4 0 // m. After the above method, the substrate is subjected to a hydrophilic treatment with a predetermined thickness on one side of the substrate film subjected to the stretching operation. As the hydrophilization treatment method, known methods such as chemical methods such as concentrated sulfuric acid and concentrated nitric acid, and corona treatment can be used, and corona treatment that can be hydrophilized at a high speed at one-sided continuity is most suitable for the present inventors. After the surface tension ratio of the surface of the film substrate (A) (B) is hydrophilized, the concentration of concentrated sulfuric acid and concentrated nitric acid and the corona treatment are adjusted. The paper dimensions are subject to Chinese National Standards (CNS) A4 specifications (210 X 297 mm) (Please read the note on the back 3 to write this page) Order ·--· Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -29-1225500 Α7 __Β7 V. Description of the invention (27 ) Out. When using a chemical method, such as: · heating 30 t: purity 96% nitric acid, immersing the substrate film for 10 seconds, the surface tension of the impregnated surface is 480N / cm, 60 6 1 〇 / N /

c m. For example, when using a corona treatment to hydrophilize, if a 4-pole electrode is used, the distance between the substrate film and the electrode is made 1 mm, and the output of the film substrate (A) is 4W / rrf / mi η, and for the film The surface of the substrate (B) is 2 W / m 2 / mi η. When treated separately, the surface tension is expected. Then, it is dissolved in water by known methods such as roller coating, spray coating, and pneumatic doctor coater. After coating the modifier composition of a solvent such as isopropyl alcohol, the solvent is dried, and then the reverse side of the modifier composition coating is hydrophilized, and then rolled up in a roll shape. Alternatively, the film substrate may be subjected to hydrophilization treatment on both surfaces. In addition, a method of drying by hot air at 70 ° C to 140 tons is preferred. When rewinding in a roll shape, the take-up tension is usually performed at 2 k g · m ~ 10 k g · m. When rolling in a roll shape, after the film substrate surface (A) contacts the film substrate surface (B), the modifier composition of the film substrate surface (A) is copied (internally printed) on the substrate surface ( B) After the roll-shaped film is unrolled and used, the film surface (A /) and the film surface (B /) are completed. The ideal surface pressure range in the form of the roller is 0 · 〇 5 ~ 100 k g / c π ί, after holding at room temperature for more than 4 hours, the photocopying on the surface of the substrate (B) at the desired ratio during use. If it is maintained within the surface pressure range, it will maintain uniform copying of any roller shape, and the winding tension will not easily cause problems such as damage to the paper roll. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) Please read the back & note on this page Printed by the Intellectual Property Bureau Staff Consumer Cooperatives -30-1225500 A7 B7 V. Description of the invention (28) In more detail, after the film to be coated is rolled up in a roll shape, after being kept for a certain period of time, it is slitted lengthwise and rolled back in accordance with its use. After rewinding, $ Kun tube can be used after being stored for a certain period of time. That is, the innermost part of the roll-shaped film of the coated film is reproduced after being moderately rolled. At the time of rewinding, the outermost part of the coated film is the innermost layer, so it is also appropriately reproduced. Hereinafter, the present invention will be described using examples and comparative examples. First, the detailed methods used in the examples and comparative examples will be described below. (1) Evaluation of surface tension It is calculated based on ASTM D 2578. After the modifier attached to the surface of the film was washed with pure water-isopropyl alcohol, etc., the surface was washed with pure water and then 'dried', and determined in accordance with the ASTM D 2578. (2) Measurement of the amount of modifier composition adhered The styrene resin film rolled up in a roll shape was stored for 2 weeks at a temperature of 2 5 t: and a relative humidity of 60%. After the unrolled film was made into a film for evaluation, the amount of the film-adhering modifier composition was measured. The measurement of the adhesion amount was performed by using isopropanol as a solvent to extract the modifier composition attached to one side of the film with about 0.5 μπι. The amount of the extracted residue was calculated to make the adhesion weight of the film area to m § / Find it after conversion. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Please read the back & note page printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs -31-1225500 A7 B7 V. Description of the invention (29 3 according to

Period of final evaluation S decay I half J

L-phase CC 〇2 degrees temperature and quasi-base is 4 9 〇1 ± fading-half face of the watchmaking film thin film} Quantities of shares Γν lr gas 8} Xiao 2 static (ο d take C1 and find C1 The lower C aerator gas and electricity% static ο tablet 2 with a wet gel. After the period of time, use the machine to use the sample BS S test room as a sample) I-type pole ο electric 1 '1-'-V 〇k 2 0 ^ 7 pieces of mm (mm) ο ο (please read the note on the back first (4) Evaluation of the time when the envelope paper and the film adhere to each other) The following describes the measurement sequence of the time. 1 · Cut width 2 A thin styrenic resin with a length of 0 mm and a length of 50 mm 'is fixed with a transparent film on the glass plate of the automatic coating device on the table. 2 · Cut the width of 30111111 and the length of 100111111. The slender handle sealing paper is fused with one end of the styrene resin film in the far direction of 1. 3. After the styrene resin film surface and the envelope paper surface are overlapped, the styrene resin film and envelope on top of the overlap surface After inserting 3 g of adhesive between paper, immediately start the coating device to coat the bar with a weight of 70 g to make benzene. The vinyl resin film is in contact with the envelope paper through an adhesive. 4. After the styrene resin film and the envelope paper are in contact with each other, it is left for 1 second, and the paper is extended horizontally at 200 gf. 5 · Extension For envelope paper, the envelope paper is not deformed after being adhered as the "adhered state". After 1 second, it is extended to repeat the operation until the adhered state. The accumulated time when the envelope is in the adhered state is used as the paper standard. China National Standard (CNS) A4 Specification (210 X 297 mm) Please fill out this page again) Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -32-1225500 A7 ____ B7 5. The description of the invention (3Q) is the next time. 6 · Envelope paper is generally made from Oji paper (stock). Please read the precautions on the reverse side and fill in the appearance of the company's page 7 5 · 5 g of kraft paper. The adhesive is made by Sunden Chemical Co., Ltd. Saibinol FB-408 (the main component is ethylene / vinyl acetate copolymer) in water-based emulsifier. The film surface (B >) was adhered to a time of 20 seconds or less as ◎, 2 1 to 30 seconds as 0, and X greater than 30 seconds. (5) Evaluation by a sealing and pasting machine The sealing and pasting machine (Winkler + Dunnebir company Helios 202 type) was used to make a 5 4mm wide and 5 4mm wide envelope with an opening of 50x90 mm. 9 4mm styrene-based resin film At a speed of 13,000 sheets per minute to obtain 2100 envelopes, seal and paste the envelopes for pasting. The following items are evaluated for the envelopes with seals. (a) Evaluation of position distortion Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs from 2 100 sheets of 50 envelopes sealed and pasted randomly, 50 sheets of 1 to 100 sheets, 90 to 1,000 sheets Randomly draw 50 sheets, 1900 ~ 2000 sheets randomly draw 50 sheets, the same as 1900 0 sheets ~ 2 0 0 0 0 sheets randomly draw 50 sheets, draw a total of 1 0 0 sheets for evaluation by the predetermined attachment position to 1 point below 0 mm, 0 point 5 mm to 1 mm, 0 point 5 mm, and greater than 1.0 mm point 0, when the total number of points in each 50 sheets is 50 points For -33- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1225500 A7 B7 V. Description of the invention (31) ◎, 48.0 ~ 49 · 5 points are 0, 8 or 46 points or less Is χ. 4 5 4.0 points (b) The number of times that the film is wound around each other is measured during the sealing and pasting of 2000 sheets. The number of times that the film is wound around each other is measured. The evaluation is △ for times and X for 3 times or more. (c) The evaluation of wrinkles is made by randomly extracting 100 envelopes from 100 sealed envelopes. Those with no wrinkles are ◎, those with less than 5 wrinkles are 0, which is more than judged above. A few wrinkles or a high frequency of occurrence are △, and a frequency of wrinkles that is too high to be impractical is evaluated as X. Please read the precautions on the back before writing this page. Printed by Zhang Pingji, Zhang Ping and Commentary of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The X base pumping turbidity seal cut% is intended to be the same as the medium turbidity. 5 The 3 sides are available for use on each side. Ο The previous double is determined by 3 1 with the ο sheet in the measurement ~% 1 industry ο 彳 値% 5 | 1 degree, 1 degree of turbidity in D mouth, 2 degree of turbidity of sealing ◎, Μ degree of opacity of the film is set to △ Τ Those who are viscous and thin are the meaning of S Chengzhi. % 1% based on a thin patch 5 System ο Each 1 of the posterior mucosa ο The thickness of the lip is set to rise by 2 degrees ο Glue seal 1T1 is measured ~ The turbidity is received by 1 mouth ο Line%,} from the sealing needle 2} 5 and d make}, 値 ·. (， Both before and after 1) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -34- 1225500 Α7 _ Β7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (32) Measurement (: 6) The centerline average of the surface thickness parameters 値 Using a surface shape analysis device (SAS-2010, manufactured by Mingxin Machinery Co., Ltd.), a specific thickness curve is drawn on the surface of the film substrate. For this curve The vertical and horizontal directions are randomly selected at three points respectively to determine the thickness deviation curve with a length of 1 mm and the length of the area surrounded by the center line by 1 mm. After calculating the average deviation, the average vertical and horizontal directions are obtained. The unit is // m, and the second decimal place is calculated as a significant figure. (7) The high-speed dynamic friction coefficient between film and metal uses a high-speed friction coefficient tester (tester industry (stock) AB-410), with a mirror surface A stainless steel travel code. After measuring at a speed of 30 m / min, determine it with the second decimal place as a significant figure. (8) Transparent styrenic tree of the coating modifier modifier After the fat film is melted with an extruder at 200 ° C, the wood chips are formed. The obtained wood chips are then hot-pressed and then melted at 2000 t for 1 minute, and then cooled to obtain a thickness of 3 mm resin plate. This is the measurement of turbidity 依 based on AST M-D 1003. The turbidity 値 of the resin plate obtained from a styrene resin film without a coating modifier is used as the evaluation standard. The difference between the turbidity and the turbidity is evaluated in the following 4 stages. The paper size is in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm). Please read the note on the back page-35- 1225500 A7 _B7__ V. Invention Explanation (33) ◎: Difference from standard turbidity S S 1 · 0% (good transparency) ◦: Difference from 1.0 ·% < standard turbidity 基准 S2 · 0% (Through the Intellectual Property of the Ministry of Economic Affairs) Printed by the Bureau's Consumer Cooperatives / (V% ο 3 VII Difference turbidity quasi-base V% ο N) / Good 2 Good and good: Big △ Sexuality, goodness, non-senseness, transparency Γ \% ο 3 > Poor The degree of turbidity) The quasi-good base does not agree with: Slightly X Xingming 9

C, two mi, one heavy film, thin product, wide width, non-stop, continuous temperature, sticky cut,} 111 5 8 degree wet phase, OC m ο ο 5 S k ο 5 £ 3 After loading, hold rll 1 1 dimension The percentage of the article will be moved away from the peeling surface when it is overloaded! Im anti-testing will be determined by sticking and borrowing. The review will be carried out when the time comes. Small base 5 base 1 remembered S VII VII heavy load 1 of the VII time weight JIf Lotus peeling ^ < · Hour g away ο Stripping 1 · * ·. ◎ 〇Good benign stop and prevent sticking S 5 Large bet stop and prevent sticking First read the back of the > I matter and then fill out this page > OK △ Liangliang does not prevent slight adhesion / iv g ο 3 VII peeling off under heavy load < S 5

Good non-stop anti-sticking / {\ 0 ο 3 > Stripping at the time of heavy load X quasi-base is 5 2 5 IX points D softened M time τ instant S) A ο proceed according to the evaluation of the machine package to fill the white loan Kai} Special 1 According to 8 2 3 ο 9 3 3 Aliphatic ethylenylbenzene is obtained from Γ7 and half semi-feu This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -36- 1225500 A / B7 5. Description of the invention (34) Laminated film of film and EVA. Then use Omori Machinery Industry Co., Ltd.'s super-speed wrapper S-5000JBX type to make a width of 1:50 mm, a height of 60 mm, and a length of 250 mm. At a speed of 1 minute, it is automatically filled with 1000g / bag of raw incense while making bags. In the longitudinal direction of the bag (250 mm), the end faces of the film are mutually deformed to 0, 2 mm or less, ©, 0.2 mm to 0.4, ^ 1111 is 0, and 0, 4 to 0, 6 mm is △ X is greater than 0 · 6 Him. [Example 1 and Comparative Example 1] The styrene resin film used in the present invention is a resin composition P 2 using the styrene resin shown in Table 1 and fed into a uniaxial 40 mm 0 extruder with a vent. Then, after dissolving and kneading at 18.6 ° C, extrude the thin sheet from the T die, make the extruded sheet contact the cooling roller, and then introduce it into the heating roller to flow at an extension temperature of 1 2 1 ° C. Perform 4x roll extension. At the same time of reheating the sheet, introduce the tenter, and extend it at 1 2 1 ° C to the horizontal side. Please read the notes on the back page on this page. ^ Table ο Material 3 is twice the thickness and thickness of the film, which can be taken from the surface. Membrane 4 membrane thin

By borrowing surface materials. The base film is thin and thin, so after N 5 enters, the first and second treatments are performed at the j location, and the rear electrode of the machine is used for the spring electrode 4 so that the system type D halo M electricity ο ο 6値 ο Force I Sheet I Side G Form A-6 Made by the Watchmaking Department} '' Copies of this paper are in accordance with China National Standard (CNS) A4 (210 X 297 mm) -37- 1225500 A7

BY V. Invention Description (35) Output 1 ~ 1 2 W / ηί / m i η for processing. For example: when the distance from the film is 1 mm and the output is 2 W / πί / m 1 η, the thickness is thin: the surface tension of the surface of the film substrate is 4 0 〇 " N / cm, and the distance from the film is 1 mm, whose output is 5000 // N / cm when processed at 4 · 2 W / πί / mi η. Using the film surface as the predetermined surface tension, using the surfactants in Table 2, the water-soluble polymers in Table 3, and the inorganic fine particles in Table 4, the modifier composition (the first combination) shown in Table 6 depends on Table 6 shows the coating amount ratio of each modifier. After each modifier is weighed, it is put into a 400 < stainless steel container and mixed with a three-blade stirrer while water is added. 50 to 200 times, to prepare the modifier composition. This modifier composition was air-scraped on the film surface (A) for a predetermined amount of coating work, dried at 90 ° C with hot air, and then wound up into a film of 8 · 5 kg · m. After being taken up by tension, a roll-shaped film is formed. As shown in Table 6, as long as the surface tension and the surface tension ratio specified in the present invention, the amount of modifier composition adhered to both surfaces of the film substrate can be managed in an ideal range. In addition, as shown in the experimental number of Comparative Example 1, if the surface tension is too high, the blocking resistance will be inferior. When the surface tension ratio is not in the range specified in the present invention as shown in Experiment Nos. 2 and 3 of Comparative Example 1, the difference in the amount of adhesion at the measurement portion of the thin film is large, making it difficult to manage the amount of adhesion. Furthermore, the obtained film is used to start the sealing and pasting machine to manufacture the sealed envelope. The results of the evaluation of the positional deformation of the envelope film and the mutual winding display of the film obtained in Table 7 were evaluated. Good results were obtained in Example 1. The implementation numbers 2 and 3 of Comparative Example 1 showed that the adhesion amount of the modifier was extremely uneven. The Chinese paper standard (CNS) A4 (210 X 297 mm) was selected for this paper size. Please First read the notes on the back and write on this page. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -38 1225500 A7 _I___B7____ V. Description of the invention (36) The part is deformed and enclosed. [Binshi Example A and Reference Example A] ^ Using the same substrate film as in Example 1, the surface tension of the substrate surface (A) was 5 5 0 // N / cm, and the surface tension of (B) was 4 50 v N / cm. After hydrophilizing treatment by corona treatment, the same modifier is applied in the same way. The modifiers a—1, b-1, and c-1 have a weight ratio of 7 8 · 1% by weight, 15 · 6% by weight, and 6 · 3% by weight. After changing the dilution ratio of water, adjust it to the table 8 total adhesion. This film was then dried and curled to obtain a roll-shaped film. The roll-shaped film will be obtained in an automatic filling mechanism bag, and the film with a seal will be manufactured on a paste-sealing machine. All films can be processed smoothly in the automatic filling machine. In addition, in the production of the sealing film, Example A showed completely good results, while the experimental number 1 and 2 of the reference example A had a small total adhesion amount, which caused a phenomenon of convolution, and the total adhesion amount of the experimental number 3 was too much. Problems occur with time and position distortion. (Please read the notes on the back first to write this page) __ Line "Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives 2 and then combined to form 9 The table is based on the same phase rnu IX as in the case of Zicaiji. With the example of the application of the quality display of the 2 9th table workers, such as coating fruit will end, its agent. The method of changing the quality is the same as that of the 15 examples of surface application, actual 3 and surface film, and thin 2 of the surface. The coating is made in the formula sheet, and the specific surface sheet is set to 2 Examples are as follows: -39-1225500 A7 B7 5. In the range of (37), the second modifier composition also shows good results. In addition, in Experiment No. 1 of Comparative Example 2, the surface tension 値 was too high, and the anti-blocking property was poor. In Experiment Nos., · 2 and 3, the modifier adhesion amount was extremely poor, and the adhesion amount could not be managed, and it was not available for practical use. [Example 3 and Comparative Example 3] The same substrate film as in Example 1 was used, and the modifiers shown in Table 2, Table 3, and Table 5 were applied after the combination shown in Table 10, and then the second The film of the modifier composition was obtained in the same manner as in Example 1. The results are shown in Table 10. As in Example 3, as long as the surface tension ratio and surface tension are set within the scope of the present invention, good results are also exhibited in the second modifier composition. Compared with Experiment No. 1 of Comparative Example 3, the surface tension 値 is too high, and the anti-blocking property is poor. Experiment Nos. 2 and 3 have a large difference in the amount of modifier attachment, and the amount of uncontrollable attachment is unavailable and practical. [Example 4 and Comparative Example 4 and Reference Example] The employee's cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the resin composition film contained in Table 1 as a film base material, and extruded it with a single-axis 40 mm 0 with a vent. After the resin is extruded by a circular slitting die, the temperature of the boiling chamber at a boiling center of 1 17 to 1 2 ° C is adjusted by a blow molding method, and the longitudinal direction is extended by 5 · 5 times. After extending 6 · 0 times in the direction, a film of 3 0 // m was obtained. The surface of these film substrates was hydrophilized in the same way as in Example 1. The distance between the single side of the film and the film was 1mm, and the output was 5 · 3W / nf. This paper is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -40- 1225500 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (38) / m 1 η, the distance between the reverse side and the film is 1 mm, and the output is 3.3 w / resistance / mi η After corona treatment, the surface tension of the substrate surface is 5 50 and 4 50 " N / cm. In addition, when the distance between the electrode and the film of the surface tension disclosed in the present invention is 1 mm, the strength of the corona treatment is as follows. 1 · 8 W / ni / m! At η 3 5 0 ν N / cm 2 · 〇W / nf / mi n at 400 // N / cm in at 45〇 # N / cm in at 460 // N / cm 500aN / cm in in, 52〇gN / cm in, 550 # N / cm in, 6 1 0 β N / cm on the surface of the substrate with a surface tension of 5.5 .5 0 // N / cm is the same as in Example 1. After applying the modifiers shown in Table 11 and drying, a roll-shaped film was obtained in the same manner as in Example 1. The roll-shaped film was then evaluated by an envelope sealer. The results are shown in Tables 1, 1, 12 and 13. As shown in Tables 1 and 12, using the first modifier composition to adjust the surface thickness and adhesion amount specified in the present invention, the sealing and pasting machine evaluation of the roll film of the example obtained and the automatic filling machine The evaluations were all good results. In addition, in Experiment No. 1 of Comparative Example 4, when the antistatic agent did not contain a surfactant, the half-life was greater than 3,000 seconds, and the sealer was 4 4 3 WX m / 5 W / m2 / 2 W / rri / 7 W / ni / 3 W / rri / 8 W / rri / This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 41-Please read the precautions on the back before this page 1225500 A7 B7 5 2. The assessment of invention description (39) also failed to reach the practical level. Comparative Example 4 Experiment No. 2 When the external lubricant does not contain inorganic particles, the same local velocity dynamic coefficient of friction is required: It is also not practical. In addition, if Reference Example 4 does not contain a water-soluble polymer, it is not suitable for sealing and pasting. However, when it is used for food packaging, it can be used in accordance with Experiment Nos. 1 and 2 of Reference Example 4 without deformation. For the surface thickness of Example 4, the experimental numbers 1 0 to 12 were used, and the experimental number 1 0 was used as the envelope seal below the lower limit ', while the experimental numbers 1 1 and 12 were larger than the upper limit, and the results were used as the seal paste The evaluation of the machine is inadequate, but as a film for food packaging, etc., it can be fully supplied to the practical person. In the experimental numbers 1 3 to 17 of Example 4 discussed for the high-speed dynamic friction coefficient, the envelope sealing user exceeded the ideal upper limit of 0.35, and the evaluation result in the evaluation of the sealing and pasting machine was insufficient, but as Food packaging films and the like can be fully used. [Example 5 and Comparative Example 5] After using P 2 in Table 1 as the film substrate for the resin composition, the same method as in Example 4 was used for the blow molding method to obtain a substrate film having a thickness of 30 m. The surface treatment method, the surface tension and the coating method, and the drying method were performed in the same manner as in Example 4. The second modifier composition shown in Tables 1 to 15 was applied to the film substrate to obtain a film. Each film composition was evaluated by an envelope sealer. The results are shown in Tables 1 to 15. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) Please read the notes on the back page printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs-42- 1225500 A7 B7 V. Description of the invention (4 (3) As shown in Table 14, after using the second modifier composition, the adhesion amount was made into the film of Example 5 in the direction of the invention. The sealing, pasting, and evaluation of food showed good results. Conversely, when the water-soluble polymer is not contained in the reference number 5 in the experimental example 1 in Table 1 and 5, it is judged as unsatisfactory in the sealing and pasting machine, and the film for food packaging can be fully used and practical. 1 Films without surfactants have poor antistatic properties and cannot be used for practical purposes. Similarly, films without polyether-denatured polysiloxane have poor lubricants and cannot be used for sealing and food applications. [Example 6 and Comparative Example 6] P 2 in Table 1 of the resin composition was used as a film substrate, and a substrate film having a thickness of 30 # m was obtained in the same manner as the blow molding method described in Example 4. , Surface treatment methods and surface tension The coating method and the drying method were performed in the same manner as in Example 4. The film was obtained by coating the third modifier composition shown in Tables 16 to 17 on the film substrate. The films were obtained after borrowing each film composition. The evaluation was performed by an envelope sealing and pasting machine. The results are shown in Table 1 6 to 17 ° As shown in Example 6, a surfactant having antistatic properties a-2, a was used in the third modifier composition. After-5 and a-7 ', the film for food packaging and the film for envelope sealing achieved good evaluation results. Conversely, the film without surfactant in Comparative Example 6 Experiment No. 1 had poor antistatic properties and could not be supplied. Practical. And 'Comparative Example 6 Experiment Nos. 2 and 3 increase the oxygen content of polyether denatured polysand more than this Experiment No. 1' This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please Please read the precautions on the back before filling this page.) Then fill in. “Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-43- 1225500 A7 ____B7 _ V. Description of the invention (41) The antistatic performance is still insufficient, and the transparency of the film is deteriorated. , Cannot be provided with practicality.More In addition, Experiment Nos. 7 and 8 of Comparative Example 6 are those using a-1,: a-3 and a-4 as surfactants, and in the oxygen compounding with polyether denatured polysilicon ^, there is no sufficient band. The surfactant with antistatic properties cannot be provided with practicality. In addition, the experimental number 9 of Comparative Example 6 and the polyether denatured polysand are mixed with oxygen because most of them contain an insufficient amount of surfactants with antistatic properties. Therefore, the lubricant is extremely reduced due to the fact that it has "a little static electricity prevention performance." [Industrial Applicability] The styrene-based resin film of the present invention provides a surface tension and If the amount of modifier composition adheres to a specific range, therefore, the high-speed running of the film simultaneously exceeds 600 sheets per minute of high-speed sealing and pasting, shortening the bonding time between the film and the envelope paper, and preventing the sealing edge of the film and the envelope. Positional deformation of styrene resin film. (Please read the note on the back 3 first to write this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -44-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) 1225500 V. Invention Explanation (42) [Table 1] Composition ratio of resin composition resin and additives (% by weight) Instantaneous softening point: No. GPPS HIPS oxidized SB crosslinked PS particles (° C) P 1 9 8 2 _ 10 6 P2 9 7 3 _ A 106 P 3 9 5 5 _ 10 5 P4 9 0 10 _ 1〇5 P 5 7 8 2 2 _ 10 3 P6 7 5 2 5 _ 10 3 P7 9 0 5 5 _ 10 5 P8 9 5 2 _ 3 106 P9 8 6 2 — 12 106 ----: 丨 »! (Please read the precautions on the back Θ to write this page) The abbreviations in Table 1 printed by the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

GPPS; general-purpose polystyrene (weight average molecular weight 28 thousand), instantaneous softening point 106 ° C Η IPS: high impact polystyrene, instantaneous softening point 9 4 ° C (rubber concentration 6% by weight, average rubber particle Diameter 3 β m) hydrogenated SB: hydrogenated styrene monobutadiene block copolymer (butadiene content 80% by weight) crosslinked PS particles: crosslinked polystyrene fine particles (average particle size 5 / zm) paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -45- 1225500 A7B7 V. Description of invention (43) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [Table 2] Surfactant No. Surfactant Type of agent: Properties at 20 ° C, a-1 Coconut oil fatty acid diethanolamine (Staform F manufactured by Yoshimoto Oil Co., Ltd.) Liquid a-2 polyethylene oxide alkyl (coconut oil) amine (Yoshimoto Mm-F-215, manufactured by Ozuki Corporation, liquid a — 3 diethanolamine laurate (Staform DL manufactured by Ben Fats Co., Ltd.) solid a — 4 polyethylene oxide sorbitan monolaurate (Reodoll TW-L120, manufactured by Kao Corporation) Liquid a-5 polyethylene oxide alkyl (tallow) amine (say Mmm T2-230 manufactured by Oils and Fats Co., Ltd.) solid a-6 hydroxyethyl laurylamine (mmm L-201 manufactured by Japan Oils and Fats Co., Ltd.) liquid a-7 polyethylene oxide polyglycidyl glycol ether ( First Industrial Pharmaceutical Co., Ltd. Epam 485) solid (please read the note on the back 3 to write this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -46- 1225500

7 7 AB V. Description of the invention (44) [Table 3] Water-soluble polymers N 〇. Types of water-soluble polymers, b-1 Polyvinyl alcohol b-2 Polyvinylpyrrolidone b-3 Sodium polyacrylate Intellectual property The paper size printed by the Bureau ’s Consumer Cooperatives applies the Chinese National Standard (CNS) A4 (210 X 297 mm) -47- 1225500 A7 B7 V. Description of the invention (45) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Table 4] Inorganic fine particles Type of inorganic fine particles. Is there an average particle size of the internal surface area? No. (β m) c-1 Silicon dioxide fine particles have 0.9 c-2 Silicon dioxide fine particles have 1.4 c — 3 dioxide Silica particles are 12.0 c-4 Synthetic zeolite particles are 4.5 c-5 Crosslinked polystyrene M J \ W 2.5. Please read the precautions on the back before filling out this page. The paper dimensions are applicable to Chinese national standards (CNS ) A4 specification (210 X 297 mm) 48 · 1225500 A7 B7 V. Description of the invention (46) [Table 5] Type viscosity of polyether-denatured polysiloxane water-soluble polymer (2 5 ° C) No, c S t d- 1 Toshiba Poly Oxygen produced T S F - 4 4 4 1 2 5 0 d-2 Toshiba poly silicon oxide manufactured by TSF - 4440 18 0 d -3-Etsu Chemical Co., Ltd. K F - 3 51 1 00 (Read precautions rear surface of the re-fill of this page)

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -49- 1225500 A7 B7. 5. Description of the invention (47) ◎ x

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Sampling sites are numbered 1 to 100 and numbered 19000 to 20000 as number 20. In addition, the deformation system represents the evaluation result of the positional deformation, and the winding system is the evaluation result of the films being entangled with each other. This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (please read the precautions on the back before filling this page) --line: -51-1225500 A7B7 V. Description of invention (49) Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives [Table 8] Experiment No. Attachment amount: film surface (A /) bottom: film surface (B >) Evaluation of film convolution, followed by time and position deformation evaluation by automatic filling machine Example of bag deformation evaluation A 1 7.6 ◎ ◎ ◎ ◎ 4.6 2 14.6 ◎ 〇〇 ◎ 8. 7 3 4. 6 ◎ ◎ ◎ ◎ 2.5 Reference Example A 1 2.5 X ◎ ◎ 〇 1.5 2 3. 8 X ◎ ◎ 〇 2. 2 3 2 8.5 ◎ XX ◎ 17.0 (Please read the precautions on the back before filling in this page). This paper size applies to China National Standard (CNS) A4 (210 X 297) (52%) -52- 1225500 A7 B7 V. Description of the invention (50) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by tiss & Bath one. ONgM bath I ^, 00 ^ Department 1ί1_ 0 τ ◎ ◎

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Order --------- Line I This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -54- 1225500 A7 B7 V. Description of Invention (52) Employees of Intellectual Property Bureau, Ministry of Economic Affairs Consumption cooperative print example 4 CJD 1 Ph 1 ο r ~ H (XI ο r—1 CM 1 o 00 rH Ln r— (1 1 03 Ο ο ι—Η c \) 00 rH 1 〇CO 00 LO 1 00 o 00 CO o BU CO σο 00 ◎ 〇 ◎ ◎ 00 inch Ph ο rH (XI ο r—Η (XI 1 O Ο rH CD 〇Cvl 1 03 ο 00 ο CD CXI n 00 11! ~ i (XI CO o rH CO 〇rH: CO 〇CO ◎ ◎ ◎ ◎ CD Ph CXI ⑦ ο CD 〇1 o ο rH ί- 〇 Cvl i 03 00 CXI CD TH 1 rO 00 rH LO y—i inch CO o CD Cvl o LO CXI CXI ◎ ◎ ◎ ◎ CD 00 03 BU 〇 CD CD 〇I o ο rH BU Ο c \] 1 03 inch 00 CV] CD tH 1 rQ 00 rH LO r—1 CD CXI o CD Cvl o 00 (XI BU CXI ◎ ◎ ◎ ◎ LO Dh CXI ο CXI ο o Inch 1 o 〇rH ο (XI 1 03 00 CXI ζ〇tH 1 00 rH LO tH H (XI o 00 CXI o XI Cvl ⑦ CXI ◎ ◎ ◎ ◎ LO ⑦ ⑦ rH CM ⑦ o CXI inch 1 o 〇rH 〇〇C \] I 03 inch 00 CXI CD iH 1 0 0 r— (LO rH CM 00 o CO 00 o ① Cvi 00 Cvl ◎ 〇 ◎ ◎ CO CO PLh CXI LO oo LO o 1 · • oo tH BU 03 1 03 00 (M CD tH 1 00 rH LO rH CN) CO o rH CO o 00 Cvl CD Cvl ◎ ◎ ○ ◎ CXI inch Pu o tH CXI 〇r—1 CXI 1 o 00 o LO ο rH 1 匁 CO BU CO 1 rO LO rH (XI Γ-f 00 CXI o ① CM o (XI CO CO ◎ ◎ ◎ ◎ r— \ Oh 〇t—H OJ o rH 1 o 00 o LO 〇1 03 CO BU 〇LO rH 1 LO rH (XI rH BU Cv) o 00 CM o BU CO LO CO ◎ ◎ ◎ ◎ \ / experiment number resin composition Να surface (A) i surface (B) type surface (A) surface (B) type surface (A) surface (B) type surface (A) surface (B) surface (A) Surface B) Surface (A) Surface (B) Deformation wrinkles caused by surface deformation Evaluation of bag thickness by automatic filling machine Surface roughness fine particles! Surfactant Water-soluble polymer High-speed dynamic friction coefficient ______ __ _ ____i The half-life is evaluated by an envelope sealer (please read the precautions on the back before filling this page) • Line: This paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) -55- 1225500 A7 B7 V. Description of the invention (53) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [S 1 ¥ Example 4 00 1—Η 1 Oh 1 ο y—i CXI 〇rH! O 00 ο LO Ο CO I 03 CO bu o LO τ—H 1 〇LO rH (XI H CD (XI 〇00 DO ο LO οο bu CO ◎ ◎ ◎ ◎ bu CO α. Inch ο τ—Η CXI o τ—H Cvl! u CD 00 (XI CO (XI 1 03 LO rH 〇0000 rH CXI j .n 00 τ " Η r— (CO CO o CO ο ① τ—Η LO: rH <) 〇 ◎ 〇CD rH 00 Dh inch ο τ—Η (XI 〇rH oa I o 〇 rH CD 〇 CM I 03 LO CXI τ-H (XI rH CXI 1 r〇CO CXI o (XI 〇o ο 00 ο ο CO and CXI ◎ ◎ <] 〇LO r—1 CO Oh ο τ-Η CM O τ—H LO 1 υ ο CD 〇 CXI 1 03 o 00 o CO Cvl 1 male 00 rH inch rH CO 00 〇rH 00 ο 00 CX1 Bu Cvl ◎ ◎ <] 〇1 ~ 1 CO cu ο r—1 CM 〇rH CO 1 CJ ο rH CD 〇 CXI 1 σ3 o 00 o CO CM 1 200 rH r—H o 〇ο inch ο CXI ⑦ CXI 〇〇〇〇CO τ—Η CO a. Inch ο rH C \] o rH rH 1 o ο rH CD 〇 C \] 1 cc o 00 o CD CM 1 knife 00 τ—H rH CO 00 o Bu 00 ο CJD (XI 00 CX! 〇〇 ◎ 〇 CXI r-Η 00 Oh 00 CO (XI ① CXI C \ 3 1 o ο τ—1 Bu 0 CM 1 03 inch 00 CXI CO r—H 1 00 rH LO rH ① CO o Bu 00 ο 00 CM 00 CXI < 〇 ◎ 〇rH r—Η LjO CU (XI LO CXI CO CM 1 o ο rH Bu 0 (XI 1 03 00 CXI CD rH 1 00 rH LO T—1 bu 00 o ο inch ο CD CM bu CM < < ◎ 〇ο τ—Η r—1 Ph o 00 o bu CO o 1 o ο rH ι > ο Cvl I 03 00 OJ CD rH 1 00 rH LO r—H 00 CO o Bu 00 ο o CO o (XI ◎ 〇 <] 〇 \ 1 / / experiment number resin composition Να surface (A) surface B) kind surface (Α) i Surface B) Type surface (A) Surface (B) Type surface (A) Surface B) Surface (A) Surface (B) Surface (A) 1 Surface B) Location deformation Wrinkle damage is automatically charged Evaluation of bag deformation by machine using surface roughness fine particle surfactant surfactant water-soluble polymer high-speed kinetic friction coefficient half-life evaluation of the adhesion amount by envelope sealing machine (please read the precautions on the back before filling this page)

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Is * 0N «®imB ringworm si _The size of this paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) i Code 纮 it -57- 1225500 A7 B7 V. Description of invention (55) Intellectual property of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperative [1 1 ¥ Example 5 rrH | CO CXI rH rH I CO 〇LO rH 1 00 τ ^ 1 LO tH 1 C \] o CD CXI o 1 CO CD CO ©! ◎ ◎ ◎ ◎ CD r— (i CD inch BU rH! 03 CO BU ο LO Η 1 00 rH LO rH BU τ—H o 00 rH o Cv] CD inch 〇 ◎ ◎ ◎ ◎ LO 00 1 00 03 LD CXI rH 1 cn CO BU ο LO rH 1 00 rH LO rH rH CXI o CXI 03 o CO CD CO ◎ ◎ ◎ ◎ ◎ ◎ C \]! 00 CXI LO CXI CO 1 σ3 CO BU LO t—H 1 00 τ—1 LO rH rH CXI o CXI CXI o rH CO ◎ ◎ ◎ ◎ ◎ ◎ CO (XI 1 Ό 00 CXI LO CXI inch! 00 BU 0 LO 1 r—1 I rO 00 τ—i LO tH ① rH o rH (XI o 00 00 ① 00 ◎ ◎ ◎ ◎ ◎ ◎ CXI r—Η " 〇 00 CXI LO CXI CD 1 ro CO Ο Ο LO CO 1 LO rH CXI rH r— (〇o CXI o CO CO 00 CO ◎ ◎ ◎ ◎ ◎ ◎ r--Η τ--Η 1 00 CXI LO CXI 1 j 00 BU 0 LO T—1 1 rO LO T—1 CXI t—H 00 rH O rH o LO CO Bu CO ◎ ◎ ◎ ◎ ◎ ◎ Experiment number type surface (A) surface (B) type surface (A) surface (B) Type Surface (A) Surface (B) Surface (A) Surface (B) Surface (A) Surface⑻ Transparent film Film adhesion prevention Wrinkle damage Damaged by automatic filling machine Evaluation of polyether denatured polysiloxane surfactants Water-soluble polymers High-speed kinetic friction coefficient half-life Evaluation of the amount of adhesion by an envelope sealer (please read the precautions on the back before filling this page) Order · This paper size applies Chinese national standards (CNS) A4 specifications (210 X 297 mm) -58- 1225500 A7 B7 V. Description of the invention (56)

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$ ivtK w} ile To 龆 suspect 杻 杻 Listen to this paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm) -59- 1225500 A7 B7 V. Description of invention (57) Employees of Intellectual Property Bureau, Ministry of Economic Affairs Example 6 printed by consumer cooperatives 〇r-1 rH! 4.9 LO 1 rH (XI 〇) ί-H bu c \] 00 CV3 00 1 ~ 1 〇00 ί—Η ο 〇 ◎ ◎ ◎ ◎ ① CX1 1 Ό rH (XI 1.9 LO 1 03 ⑦ 卜 CD (XI (XI CO 〇 (XI 〇ο (XI ο ◎ ◎ ◎ ◎ ◎ 00 CX1 1 4.9 4.7 LO 1) r-i (XI ① τ-Η LO 00 bu CO 00 rH 〇 卜 ι-Η ο 〇 ◎ ◎ ◎ ◎ rH 1 Ό τ—Η (XI rH CM! 03 4.9 bl LO CXI bl CXI rH CXI ο r—H CNJ ο ◎ ◎ ◎ ◎ ◎ CD rH 1 TD ① 1 BU CXI 1 03 rH CXI 1.9 CO CO LO C0 BU rH 〇00 ί—Η ο 〇 ◎ ◎ ◎ ◎ LO CO 1 T3 2.5 CO Cv3 CXI 1 03 LO CXI 00 CXI t—H (XI inch CXI 03 o τ —1 (Μ Ο ◎ ◎ ◎ ◎ ◎ inch CXI I Ό 2.5 CO CXI LO I CC 2.5 CO CXI o C0 rH (XI o (Μ CX1 〇 ◎ ◎ ◎ ◎ ◎ CO CXI! 2.5 CO (XI CXI 1 03 LO CXI CO CXI 00 CO 00 00 en > t H 〇rH CX1 〇 ◎ ◎ ◎ ◎ (XI! ~ 1 1 dead 2.5 2.3 LO 1 03 2.5 CO 03 o inch 〇〇o 03 o CD rH 〇 ◎ ◎ ◎ ◎ rH 1 TD ΙΩ (Μ CO (XI ( XI 1 03 ID CXI 2.3 LO CO BU 00 00 TH o rH ο ◎ ◎ ◎ ◎ ◎ \)! / 〇 surface (A) surface (B) 〇 surface (A) surface (B) surface (A) surface (B) Surface (A) Surface (B) Transparent film Film adhesion prevention position deformation film roll attached Evaluation of bag deformation by automatic filling machine [mg / rri] Amount [mg / πΐ] Half of static voltage Decay time [seconds] 1 High-speed motion i Friction coefficient (a) Polyether denatured polysiloxane (b) Type and quantity of single-side active agent coating composition Film Surface characteristics Evaluation of envelope sealing machine Please read the note on the back first matter

This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -60- 1225500 A7 B7 V. Description of the invention (58) Comparative Example 6 printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs CD C]]! T; τ—Η C \] CD r—1 1 CTj 4.9 BU ο rH τ-Η 00 CXI r— (0.6 1 0.6 3 ◎ X < < X 00 CO! Ό 2.5 2.3 CO CTj 2.5! 2.3 > 3 00 〇0000 Λ CX1 ο CD CXI o ◎ 〇XXX CO I 2.5 00 CXI rH I 03 2.5 2.3 ο ο C0 Λ ο ο CO Λ 00 CX1 ο CO CXI o ◎ XXX CD I 〇o CXI 1 03 ο ο rH 9.8 rrH LO τ—I (XI 〇CXI 〇 ◎ X ◎ < X LO I ο o CXI 1 03 5.0 00 ί CD 00 CO bu CXI ο 00 CXI o ◎ X ◎ 〇X inch I ο o CM 1 cc LO (XI 2.3 00 LO LO CO CO ο CO CO o ◎ < < 3 ◎ X CO 1—I 1 10.0 9.8 1 ο 〇 ① Λ Ο ① Λ rH ο ① tH o <] ◎ < ◎ <] (XI TH 1 TD 5.0 4.8 1 ο ο Ο ο CX1 Λ ο ο (XI Λ rH CXI o 0.2 1 〇 ◎ < ◎ X rH t—H 1 LO CX1 2.3 1 ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο 00 Λ LO CXI o inch 〇 ◎ 〇X ◎ X \ / / 〇 Surface (A) Surface (B) 〇 Surface (A) Surface (B) Surface (A) Surface (B) Surface (A) Surface (B) Film transparency Anti-adhesion of the film The evaluation of the deformation of the bag making machine (mg / nf) The amount [mg / rrf] The half-life time of the static voltage [second] High-speed dynamic friction coefficient (a) Polyether-denatured polysiloxane (b) Single-sided active agent 5 _ _ _ Evaluation of the surface characteristics of the film on the envelope sealing machine (Please read the precautions on the back before filling this page)

Order --------- line This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -61-Announcement

Appendix I Patent Application No. 89114751 Revised Chinese Specification Sheet '' One Application Date July 24, 89 Case No. 89114751 Class Co ^ CrW% L. ^ (The above columns are filled out by this Office) ^ ^ ^ Republic of China 93 Corrected beta charge on July 21, 〇ηΊ / 〇ι Α4 C4 New ί Patent Specification 25525255 00 Styrene oleoresin film Chinese invention new name English

Styrene resin films Name Nationality 1 Kogaku Shoumanuma attached to Yasuda Tanaka (2) (3) (1) Inventor and creator of Ichi-Mizumi Hirata Nakamachi, Mika, Mie Prefecture, Japan (2) Suzuka, Nie Prefecture, Japan 120,190, Kishioka-cho, Shizuoka City, Japan (3) One-third, one-name (name) of Hirata Nakacho, Mika-shi, Mie Prefecture, Japan Gongxiaof Cooperative printed national residence and residence (office) Name of representative (1) Japan (1) No.6, Dojima, Yoshinoshima, Kita-ku, Osaka City, Osaka Prefecture, Japan (1) Yamamoto unary paper size applicable to China Standard (CNS) A4 size (210 X 297 mm)

Claims (1)

21 1225500 ABCD 々 、 Appendix 3 of Patent Application Scope ·· 89 1 1 475 Patent Application No. 1 Chinese Patent Application Amendment (please read the precautions on the back before filling this page) Amended on July 21, 1993 · A styrenic resin film, characterized in that both sides of the styrenic resin film substrate that has been hydrophilized are adhered to both sides of the treated surface and containing at least a styrenic resin containing a composition with an antistatic agent and external lubricant For a film, the surface tension (α) of the surface (A) of the film substrate and the surface tension (yS) ratio (α // 3) of the surface (A) and the reverse surface (B) are 1. 15 to 1.72 And the surface tension (cold) is 3 50 # N / cm to 450 / iN / cm, and the surface tension (α) is 40 0 # N / cm to 600 // N / cm, the surface (B ) The adhesion amount of the above composition is 25 to 95% by weight of the composition amount of the surface (A), wherein the composition attached to the surface of the film substrate (A) and the surface of the film substrate (B) contains Surfactants are used as antistatic agents, inorganic particles are used as external lubricants, and those containing water-soluble polymers 〇 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 · A kind of styrenic resin film, characterized by the two sides of the styrenic resin film substrate that has been hydrophilized, and the two sides of the treated surface are attached with at least static electricity. The ratio of the surface tension (α) of the surface (A) of the film substrate to the surface (B) of the reverse surface (B) of the surface of the film (a) is a ratio of α / cold) is 1 · 15 ~ 1 · 72, and the surface tension (/ S) is 3 50 # N / cm ~ 450 // N / cm, and the surface tension (α) applies to the Chinese National Standard (CNS) ) A4 specification (210 × 297 mm) 1225500 A8 B8 C8 D8 6. The scope of application for patents is 400 # N / cm ~ The adhesion amount of the above composition is 95% by weight. Among them, the composition shirt on the surface of the material (B) Agent, containing the following formula (1), and also contains a water-soluble polymer surface meter, the author attaches the substance C into \ group N of ^ \) / ο A ο (6-sided BC as a surface agent for surface materials The base mask is thinner and contains-5 2 base stop film to prevent thinning and static electricity) Band A mE ,, RH 咅 咅 is the oxygen-silicone polyether ether ch3 CH3-Si-〇—-? h3--Si—〇— | ch3 _CH3 _ m _ R 6.0) b Η C3 a H4 C2 c 6 H3I—3H c— s— c H3 C 3 | 3 HI—HC——s · IC (Please read the precautions on the back before filling out this page): Installed · Printed by the Intellectual Property Bureau Employee Consumer Cooperatives ( 1), R 1] m = an integer of 0 to 40, an integer of 60 to 5 η / (an integer of 5 to 15, b = an integer of 60, a: ΐ). 3. — A kind of styrene-based styrene resin film base that contains at least a lipid film with an antistatic agent. The surface of the film substrate (A) is 1 · 1 5 to 1 · 3 5 0 // N / cm ~ 4 is 4 00 // N / cm ~ 5 1-I group II alkane n grade + low m, 4 number ~ whole 1 · number ο ο carbon 2 II or or η m 2 rH o 5 τ ±-ο 5 II b + a number ο 5 ο 〇ι—I- ο ο ο 1 is a ratio ratio resin film, which is characterized by the rain surface of the material being hydrophilized and treated on the surface The ratio of the surface tension (α) of the surface of the styrene-based tree (A) to the surface tension (stone) of the (B) (α / 72), and the surface tension (β) is 50 // N / cm, surface tension (α) 6〇 // N / cm, surface (B) This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1225500 A8 B8 C8 D8 6. The adhesion amount of the composition on the scope of the patent application is 95% by weight. Among them, the composition of the surface of the positive material (B) is alkylamine or the following formula (3) is used as a static prevention agent. Polysilicone is used as the external base 5 membrane 2 thin and the amount} with A and C on the surface of the surface to form the basis of the assembly} film A thin C on the surface Γ U >-Γ ethanol polyoxide ring structure Polypropylene Oxygenation} Ring 1 Condensation {} Alkanes 2 Acetylene C Oxygen} Formula A Rings A may have a structure containing a binder EE 'CH3 " CH3-1 CH3-f — 0 — -Si-o- ch3 -CH3 _ m H3-3H 〇R 60) b Η 3 (c H4 C2 H3 C H3I—H3 C—S— CC, please read the notes on the back before filling in this tribute); install. / (C2H4〇) x—H R2—N, (2) (C2H4〇) y—H ch3 I HO (CH2CH2〇) d (CHCH2〇) e (CH2CH2〇) fH (3) In formula (1), R 1 is a hydrogen atom or a lower alkyl group having 1 to 4 carbon atoms, an integer of ~ 4 0 'n == an integer of 1 to 2 0, rn + n = an integer of 1 to 60, and n / (n + m) = 〇 · 2 to 1 · 〇, a = an integer of 5 to 15, b = an integer of 0 to 15, a + b = an integer of 5 to 60, and the ratio of a: b is 100: 0 to 100: 50 In formula (2), R2 is an alkyl group having 8 to 22 carbon atoms, X is an integer of 1 to 20, and y is an integer of 1 to 20. Among the compounds represented by formula (3), the weight of d is The unit and weight of this paper are in accordance with the Chinese National Standard (CNS) A4 specification (2) 0 × 297 mm. Order Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1225500 ABCD VI. Scope of patent application The total weight of the covered unit accounts for 40 ~ 95% of the total molecules. (Please read the precautions on the back before filling out this page) 4 · If the styrene resin film in the first patent application scope, the centerline average of the surface thickness parameters of both surfaces of the film substrate is 値The range of 0. 4 to 2. 2 // m. 5 · If the styrene-based resin film in item 1 of the patent application scope, the two sides of the styrene-based resin film substrate are hydrophilized, and the two sides of the treated surface are attached with at least an antistatic agent and an external lubricant. In the case of vinyl resin film, the surface tension (α) of the surface (A) of the film substrate and the surface tension (B) of the film substrate surface (B) opposite to the surface (A) are compared (α / point) It is 1.15 ~ 1.72, and the surface tension (泠) is 3 5 Ο / iN / cm ~ 450 // N / cm, and the surface tension (α) is 4〇0 # N / cm ~ 6 00 // For N / cm, the amount of adhesion composition on the surface of the film substrate (A) is 4.5 mg / rrf ~ 30 mg / m2, and the amount of adhesion composition on the surface of the film substrate (B) is 2.0 mg / m2 ~ 1 5 mg / m2 styrene-based resin film, the adhesion time of the surface (A <) to which the composition is attached, and the difference between the adhesion time of the surface (A /) and the reverse film surface (B /) and the paper It is 1.0 seconds or more, and the surface (B /) and paper are printed in 30 seconds or less printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 6. The styrenic resin film for sealing and pasting according to item 3 of the scope of patent application, wherein the component (a) of the composition adhered to the surface of the film substrate (A) and the surface of the film substrate (B) is (a) below formula (1) The structure of polyether modified polysiloxane is 8 5 to 10% by weight and (b) the polyethylene oxide alkylamine or polyethylene oxide polypropylene oxide glycol structure of the formula (2) below is 1 5 ~ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 1225500 Α8 Β8 C8 D8_ VI. The composition of 90% by weight of the patent application, the surface of the film substrate (Α) and (Β ) Attach 2 ~ 30 mg / m2 respectively. The high-speed dynamic friction coefficient of the two surfaces of the film to which the composition is attached to the metal is 0.15 to 0.35 at 20 ° C relative humidity of 20%. With a static voltage reduction half-life of less than 60 seconds, ch3 I ch3-y-〇-CH〇ch3-1 * ch3 C; _ ^ 1 O; jTN cj > i (J… 丨 · Ο _ch3 ^ m C3H6 (C2H4 〇) a (C3H6〇) bR1 _ H3 H3 c—s · —c a—i / --- > a 3 c (Please read the notes on the back before filling this page) (C2H4〇 ) Plant Η (2) R2-N, (C2H4〇) yH ch3 HO (CH2CH2〇) d (CHCH2〇) e (CH2CH20) tH (3) In the formula (1), R 1 is a hydrogen atom or a carbon number of 1 ~ Lower alkyl of 4, 111 = 0 ~ 40 integer, 11: = 1 ~ 2 0 integer, 111 + 11 = 1 ~ 60 integer, n / (n + m) = 0.2 · 1 ~ 0, a = integer printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs from 5 to 15, b = an integer from 0 to 15, a + b = an integer from 5 to 60, and the ratio of a: b is 10: 0: 1 to 10 : 50, in the formula (2), R2 is an alkyl group having 8 to 22 carbon atoms, x = 1 to 2 0 integer, y = i to 20 integer, in the compound represented by formula (3), the weight of d is The total weight of the repeating unit and the repeating unit accounts for 40 ~ 95% of the total molecules. This paper size applies to the Chinese National Standard (CNS) Α4 specification (210 X 297 mm) 1225500 A8 B8 C8 D8 VI. Application Patent Scope 7 · If the styrene-based resin film in the first scope of the patent application, the surface tension (α) of the surface (A) of the film substrate is 4,000 ~ (Please read the precautions on the back before filling in this page ) 6 0 0 # N / cm to make the surface tension of the film substrate surface (B) (/ 3) is 350 to 450 from N / cm, and the surface tension ratio (α // 5) is 1 · 1 5 to 1 · 7 2 After hydrophilizing treatment, at least a band is formed on the surface (A). After coating the composition solution of the antistatic agent and the external lubricant, after drying, the styrene resin film is rolled up in a roll shape, and the composition on the surface (A) is copied on the surface (B). 8 · If the styrene-based resin film according to item 2 of the patent application scope, the surface tension (α) of the film substrate surface (A) is 400 to 60 μN / cm, and the surface of the film substrate surface (B) The surface tension (/ 3) is 350 to 450 // N / cm, and the surface tension ratio (α / / 3) is 1.15 to 1.72. After hydrophilizing treatment, the surface (A) is subjected to A coater containing at least a composition solution with an antistatic agent and an external lubricant. After drying, the styrene resin film is rolled up in a roll shape, and the composition on the surface (A) is copied on the surface (B). 9 · If the styrene-based resin film in item 3 of the patent application scope, the surface tension (α) of the surface of the film substrate (A) is 400 ~ printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 6 0 Ο / iN / cm, so that the surface tension (cold) of the film substrate surface (B) is 350 ~ 450 // N / cm, and the surface tension ratio (α / stone) is 1. 15 ~ 1.7 2 After the treatment, the surface (A) is coated with a composition solution containing at least an antistatic agent and an external lubricant. After drying, the styrene-based resin film is rolled up in a roll shape, and the surface (A) The composition is reproduced on the surface (B). This paper size applies to China National Standard (CNS) A4 (210 X 29 * 7 mm)