1224032 五、發明說明（1) 【發明所屬之技術領域】 本發明屬廢棄物資源化處理技術領域，特別係指一種 將廢玻璃材料資源化再生為具隔熱保溫功效的瓷化壁碑、 地磚之處理方法，以運於各種建築物，以資源化再利用 者。 【先前技術】 按，隨著電子業的發展，跟隨而來的環保問題也令業 者及相關主管單位頭痛萬分。例如映像管（如電視機、電 腦螢幕、液晶螢幕等）内含有重金屬氧化物鍍膜，又如廢 燈管、廢燈泡、廢玻璃容器等，現在一般的回收處理式，_ 係直接壓碎後出售，惟因為映像管内含重金屬氧化物，在 使用時易造成污染，且也無法回收供玻璃業生產中使用， 僅能用於低層次的、不須計較污染的行業中使用，且不能 用丟棄或掩埋方式處理，或當砂粒用於鋪路，因為會造成 重金屬氧化物的污染。 再者，國内經歷9 2 1、3 3 1大地震後，對於建材之抗震 性要求日益重視。國内新建築物所採用的磁、璧碑比重約 2-2. 1噸/ M3，因為比重大，建築物重量負荷亦大，相對的· 大震損害亦il重。 0 此上即為現行廢棄映像管回收處理及輕骨質建材之缺失， 為業界亟待克服的難題。 【發明内容】 本發明發明人鑑於習用技術對廢棄玻璃材料回收處理 之種種缺失，深知唯有將廢棄玻璃材料予以資源化處理以1224032 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention belongs to the technical field of waste resource treatment, and particularly refers to a kind of resource for recycling waste glass materials into porcelain murals and floor tiles with thermal insulation effect. The processing method is to transport to various buildings to recycle resources. [Previous technology] According to the development of the electronics industry, the following environmental protection problems have also caused headaches for the industry and related authorities. For example, image tubes (such as televisions, computer screens, LCD screens, etc.) contain heavy metal oxide coatings, such as waste lamps, waste bulbs, waste glass containers, etc., which are now generally recycled and treated. _ Is directly sold after crushing However, because the image tube contains heavy metal oxides, it is easy to cause pollution during use, and it cannot be recycled for use in the glass industry. It can only be used in low-level, pollution-free industries, and it cannot be discarded or Burial treatment, or when sand is used for paving, because it will cause pollution of heavy metal oxides. Furthermore, after the 9 2 1 and 3 31 earthquakes in China, more and more attention has been paid to the seismic requirements of building materials. The proportion of magnetic and monuments used in new domestic buildings is about 2-2. 1 ton / M3, because the specific gravity is large, the building weight load is also large, and the relative large earthquake damage is also heavy. 0 This is the current waste video tube recycling process and the lack of lightweight bone building materials, which is an urgent problem for the industry to overcome. [Summary of the Invention] The inventors of the present invention are aware of the lack of conventional glass recycling technology for waste glass materials.
1224032 五、發明說明（2) 再利用為最佳的處理方法，將廢棄玻璃材料之重金屬氧化 物鍍膜與玻璃分離，後再分級後處理再利用，可將之百分 之百資源化，雖然資源化處理的費用成本較高些，但可令 業者無後顧之憂，且為後代子孫留下一片淨土，應是值得 選擇的一種方式。在先前提出用於金屬氧化物色料原料 【九十年五月三十日申請，申請案號為：〇九〇--三〇 一七號】及用於耐火斷熱之材料處理方法【九十年十二月 四曰申請，申請案號為：〇九〇一三〇一六五號，已獲准 專利】專利申請案後，再提出運用於隔熱保溫瓷化磚的處 理方法，可運用於各種建築物，可減輕建築物整體重量，_ 但無損其結構強度（康寧公司的發泡玻璃以玻璃原料為 主，強度差）。 緣是，本發明之主要目的即在提供一種「廢玻璃資源 化再生為隔熱保溫瓷化磚方法」，其主要係將廢棄玻璃材 料（如廢家電、CRT、TFT、廢燈管、廢、燈泡、廢玻璃容器 等）加黏土材料.（來源可為淨水廠沉澱後淤泥、·水庫淤泥 等）及發泡劑，經攪拌研磨混合後.乾燥造粒..，.後以成型.機. 利用模具壓製成各種尺寸，再入.窯爐.發泡燒結，最後經熱 處理、冷卻後出窯即成具隔熱保溫功效的瓷化.壁磚、地 應 磚，若需精緻加工，可再經彩飾上釉及切、磨邊（面）成_ 特殊的裝飾作用，以運於各種建築物建材，以資源化再利 用者。 【實施方式】 本發明廢玻璃資源化再生為隔熱保溫瓷化磚方法，包1224032 V. Description of the invention (2) Recycling is the best treatment method. Separate the heavy metal oxide coating of waste glass material from glass, and then classify and reprocess it. It can be 100% resourced. The cost is higher, but it can make the industry worry-free and leave a clear land for future generations. It should be a worthwhile choice. Previously filed for the raw materials of metal oxide colorants [application on May 30, 1990, the application number is: 2009-2017] and the material treatment method for refractory and heat insulation [90] The application was filed on December 4th, and the application number is: 20090305, which has been granted a patent.] After the patent application, a treatment method for thermal insulation ceramic tiles can be proposed, which can be used for Various buildings can reduce the overall weight of the building, but it does not damage its structural strength (the glass foam of Corning Company is based on glass raw materials, and the strength is poor). The reason is that the main purpose of the present invention is to provide a "recycling method of waste glass into thermal insulation ceramic tiles", which is mainly used to waste glass materials (such as waste appliances, CRT, TFT, waste light tubes, waste, Bulbs, waste glass containers, etc.) Add clay materials. (The source can be sludge after sedimentation in water purification plants, reservoir sludge, etc.) and foaming agent, after mixing, grinding, drying, granulating, ... . It is made into various sizes by mould pressing, and then re-entered. Kiln. Foaming and sintering. Finally, after heat treatment and cooling, it will be out of the kiln to become porcelain with thermal insulation. Wall tiles, floor tiles, if you need delicate processing, you can It is then glazed, cut, and edging (face) into a special decorative effect to transport it to various building materials and to reuse it as a resource. [Embodiment] The method for regenerating waste glass into thermal insulation ceramic tiles according to the present invention, including
苐5頁 1224032 五、發明說明（3) 括有如下之步驟： (1 )玻璃材料製備：玻璃材料可為廢家電、CRT、 T F T、廢燈管、廢燈泡、廢玻璃容器等； 搓磨：由於廢映像管玻璃表面有一層深色鍍膜，使用 搓磨機進行廢映像管表面搓磨處理，使其表面鍍膜脫離 (不具鍍膜玻璃材料可略此步驟）； 破碎：廢映像管玻璃經搓磨後以破碎機破碎至0 . 2〜 lmm： 篩選：廢映像管玻璃破碎後粒徑大小不一，經篩選處 理將粒徑過大（大於1 mm )之廢映像管玻璃篩選出，送回前 製程再破碎； 粉碎：將前製程廢棄映像管經粉碎成預定大小粉料； (2 )添加黏土材料：若要提高製成品的隔熱保溫性 能，可按照需求以適當比例添加黏土材料（例如：來源可 為淨水廠沉澱後淤泥、’水庫淤泥等）； (3 )添加發·泡劑.：按照需求以適當比例添加發泡劑； ..(4 )密.閉混合研磨：將玻璃粉料、黏土材料添力α發泡 劑後混合研磨至更小粉料，並乾燥造粒； (5 )成型：以成型機利用模具壓製成各種尺寸，並視 實際需要上釉藥； (6 )發泡燒成：入窯爐按事先設定的燒成曲線，發泡 燒成： (7 )徐冷退火：按事先設定的徐冷曲線徐冷退火，冷 卻後出窯即成具隔熱保溫功效的瓷化壁磚、地磚：苐 Page 5 of 1224032 5. Description of the invention (3) Including the following steps: (1) Preparation of glass materials: glass materials can be waste household appliances, CRT, TFT, waste light tubes, waste light bulbs, waste glass containers, etc .; Because there is a dark coating on the surface of the waste image tube glass, use a rubbing machine to polish the surface of the waste image tube to remove the surface coating (this step can be skipped if there is no coated glass material); Broken: The waste image tube glass is rubbed After being crushed by a crusher to 0.2 ~ 1mm: Screening: The particle size of the waste image tube glass is different after crushing. After screening, the waste image tube glass with an excessively large particle size (greater than 1 mm) is screened out and returned to the previous process. Re-crushing; Crushing: pulverizing the waste image tube from the previous process into a powder of a predetermined size; (2) adding clay material: to improve the thermal insulation performance of the finished product, the clay material can be added in an appropriate proportion according to demand (for example: source It can be sludge after sedimentation of water purification plant, 'reservoir sludge, etc.); (3) Add foaming agent .: Add foaming agent in appropriate proportion according to demand; .. (4) Closed and closed mixing grinding: glass powder ,sticky After adding the α-foaming agent to the material, it is mixed and ground to a smaller powder, and dried and granulated; (5) molding: using a molding machine to press the mold into various sizes, and glazing medicine according to actual needs; (6) foaming burning Finish: Enter the kiln according to the preset firing curve and foam firing: (7) Xu cold annealing: follow the preset Xu cold curve to slowly cool and anneal, and after cooling, leave the kiln to form porcelain with heat insulation effect. Wall and floor tiles:
1224032 五、發明說明（4) (8 )加工處理：可再經彩飾、上釉或切、磨邊（面） 成特殊的裝飾作用。 前述搓磨及破碎製程可以集塵機收集粉塵，收集之粉 塵可提供密閉混合研磨製程使用。 如此而達本發明研發目的，可有效解決環保及廢棄物 的問題，更能做到資源再生利用的綠色環保工業循環。 本發明之特點再闡明如後： 1. 本發明具隔熱保溫功效的瓷化壁磚、地碑比重約 0. 3〜1噸/ M3，可減輕建築物整體重量，但無損其結構強 度，此種建材材質使用原料原係由國内垂手可得之電視或φ 電腦廢棄映像管等玻璃材料作為主要原料，原因在於映像 管材質與陶瓷主要原料長石非常接近，不同種類之映像管 經添加其他原料作配方調整後，即可做成上述建材。 2. 本發明隔熱保溫功效的全磁化壁碑、裝飾磚吸水率 1 %以下（習用全磁化磚吸水率為卜5 % )，可杜絕過去產 品之缺點，真正達到降低建築.材料重量功效，不吸水所以 強度不.受水泥影響。 ' 3 .本發明主要係以廢棄映像管為原料，大.幅降.低原料 成本，並解決廢映像管所衍生之環保污染問題。國内廢家 電以及廢資訊回收處理業，在拆解廢電視及廢電腦營幕 後，已產生上萬噸之廢映像管玻璃，面臨無處可去的窘 境，本發明之開發可完全解決廢家電以及廢資訊業者之映 像管廢棄物問題，將廢家電、廢資訊映像管回收處理與建 材結合，提供絕佳通路。1224032 V. Description of the invention (4) (8) Processing: It can be colored, glazed or cut, edging (face) for special decoration. The aforementioned grinding and crushing processes can collect dust with a dust collector, and the collected dust can be used in a closed mixed grinding process. In this way, the research and development purpose of the present invention can effectively solve the problems of environmental protection and waste, and better achieve a green environmental protection industrial cycle of resource recycling. The features of the present invention are further clarified as follows: 1. The present invention has a thermal insulation effect of porcelain wall tiles and monuments with a specific gravity of about 0.3 to 1 ton / M3, which can reduce the overall weight of the building without compromising its structural strength, This building material uses raw materials originally made of glass materials such as televisions or φ computer discarded video tubes that are readily available in China as the main raw material. The reason is that the material of the video tube is very close to the main raw material of ceramic feldspar. Different types of video tubes are added with other raw materials. After adjusting the formula, the building materials mentioned above can be made. 2. The water absorption rate of the fully magnetized murals and decorative bricks of the thermal insulation effect of the present invention is less than 1% (the water absorption rate of conventional fully magnetized bricks is 5%), which can eliminate the shortcomings of previous products and truly reduce the weight of buildings. Does not absorb water so strength is not affected by cement. '3. The present invention mainly uses waste video tubes as raw materials, which greatly reduces the cost of raw materials and solves the environmental pollution problem derived from waste video tubes. In the domestic waste household appliances and waste information recycling and treatment industry, after dismantling the waste television and waste computer camps, tens of thousands of tons of waste video tube glass have been generated, facing the dilemma of nowhere to go. The development of the invention can completely solve the waste household appliances As well as the waste management problem of waste information industry's image tube, the recycling of waste household appliances and waste information image tube with building materials provides an excellent way.
第7頁 1224032 五、發明說明（5) 4. 本發明可直接以生產磁磚之原設備、生產線，直接 投入量產。 5. 本發明隔熱保溫功效的全磁化壁磚貼於外牆或屋頂 時，可阻擋太陽熱能被混凝土的吸收，可降低冷氣能源的 消耗，且冬天時亦阻絕暖氣之流失，又因比重輕，建物重 量負荷亦輕，則地震損害亦相對降低。 綜上所述，本發明所揭露之一種「廢玻璃資源化再生為 隔熱保溫瓷化碑方法β為昔所無，亦未曾見於國内外公開 之刊物上，理已具有「新穎性」之專利要件，又本發明確 可摒除習用技術缺失，並達成本發明設計目的，亦已充分φ -符合發明專利之「利用自然法則之技術思想之高度創作」 專利要件，並具產業上利用價值，爰依專利法第十九條之 規定提出申請，謹請貴審查委員惠予審查，並賜與本案 專利，實感德便。 惟以上所述者厂謹為本發明之一可行實施例而已，舉 凡利用本發明說明書或申請專利範圍所做之替代性製造方 法，理應包括於本發明之專.利範疇内·。. ..Page 7 1224032 V. Description of the invention (5) 4. The present invention can be directly put into mass production with the original equipment and production line for producing tiles. 5. When the fully-magnetized wall tiles of the present invention are applied to external walls or roofs, the solar heat energy can be blocked from being absorbed by concrete, which can reduce the energy consumption of cold air, and also prevent the loss of heating in winter. , The weight of the building is also light, and the earthquake damage is relatively reduced. To sum up, a method "recycling waste glass to regenerate it into a thermal insulation porcelain stone monument β, which has not been seen in the past, has not been seen in domestic and foreign publications, and it has a patent of" newness ". Requirements, and the present invention can indeed eliminate the lack of conventional technology and achieve the purpose of cost invention design, which is also fully φ-in line with the patent requirements of "highly creative technological ideas using natural laws" patents, and has industrial use value, The application is made in accordance with the provisions of Article 19 of the Patent Law, and I would like to ask your reviewing committee to review it and grant the patent in this case. However, the above-mentioned factory is only a feasible embodiment of the present invention. For example, any alternative manufacturing method using the description of the present invention or the scope of patent application should be included in the scope of the present invention. ..
第8頁 1224032 圖式簡單說明Page 12 1224032 Simple illustration