TW594062B - Color filter - Google Patents

Color filter Download PDF

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Publication number
TW594062B
TW594062B TW090107760A TW90107760A TW594062B TW 594062 B TW594062 B TW 594062B TW 090107760 A TW090107760 A TW 090107760A TW 90107760 A TW90107760 A TW 90107760A TW 594062 B TW594062 B TW 594062B
Authority
TW
Taiwan
Prior art keywords
layer
light
color
scattering
color filter
Prior art date
Application number
TW090107760A
Other languages
Chinese (zh)
Inventor
Katsumi Fukaya
Original Assignee
Dainippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of TW594062B publication Critical patent/TW594062B/en

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133553Reflecting elements
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09GARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G2320/00Control of display operating conditions
    • G09G2320/02Improving the quality of display appearance
    • G09G2320/0242Compensation of deficiencies in the appearance of colours

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Filters (AREA)
  • Liquid Crystal (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Materials For Photolithography (AREA)

Abstract

The purpose of the present invention is to provide a color filter with high brightness, without parallax (a blurred image) and without the need of a forward scattering plate, so as to prevent deterioration of color characteristics and realize the excellent color characteristics. The color filter contains at least a substrate and a coloring layer comprising coloring patterns with a plurality of colors and contains light scattering fine particles and colorants for correcting the color characteristics.

Description

594062 A7 _ B7 五、發明説明(1 ) (發明之背景) 發明之技術領域 本發明係有關彩色濾光片,尤指反射型或半透過型之 液晶顯示裝置的彩色濾光片者。 背景技術 近年來,以彩色的液晶顯示裝置作爲平面顯示器係令 人囑目的,此彩色液晶顯示裝置係可分爲反射型及透過型 。反射型之彩色液晶顯示裝置,例如使由多數色(通常爲 紅色(R),綠色(G),藍色(B)之三原色)而成的 著色層(視必要時亦具有黑色基質或平坦化層)與透明電 極層之彩色濾光片,與由鋁等金屬而成的反射電極層及薄 .膜電晶體(T F T元件)之T F T陣列基板,使具有指定 的間隙並對正,使於此間隙部上形成液晶層,同時於彩色 濾光片上(觀測者側)設置著位相差板,偏光板及前方散 射板之構造。上述的前方散射板係具有光散射功能者,使 於已入射至反射型液晶顯示裝置之光生成適度的散射並爲 確保足夠的辨識性而予設置著。 然而,在習用的反射型彩色液晶顯示裝置,藉由前方 散射板之存在,有引起液晶顯示裝置之亮度降低,色特性 降低的問題。此爲由前方散射板之附上顏色而引起者。又 由於前方散射板之存在,亦有視差(影像模糊)發生的問 題存在。上述的亮度降低,係在配設前方散射板於彩色濾 光片上(觀測者側)之習用的反射型彩色液晶顯示裝置係 本紙張尺度適用中國國家標準(CNS)A4規格(210X297公釐) 7^ "" ~ (請先閱讀背面之注意事項再填寫本頁) ,裝· 、11 經濟部智慧財產局員工消費合作社印製 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(2 ) 不可避免的問題。 對此種問題,藉由使於彩色濾光片內含有光散射性微 粒子,對彩色濾光片本身賦與光散射性即被視作一提案被 提出。由而可使前方散射板成不需要,故欲以某種程度解 決伴隨著前方散射板之上述問題一事即成爲可能的。 然而,藉由光散射性微粒子欲賦與足夠的光散射性功 能時,則結果會生成光散射性層成爲厚膜之情形。例如通 常的保護膜等係膜厚在2 // m以下,惟光散射功能膜之情 形亦可成爲0 . 5〜2 0 // m程度的膜厚之情形。此時, 形成各該層之組成物中即使過少,亦對彩色濾光片之色特 性給予惡劣影響之著色成分若存在時,則愈形成厚膜時, 此著色現象愈予以強調著。在此,至於著色成分,可被視 作樹脂成分或聚合引發劑等,此等並不限於熱硬化型或光 硬化型,需具有由淡黃色至紅色之一事係爲人所知的。 發明之槪要 本發明係有鑑於上述實情而完成者,以提供使前方散 射板成爲不需要,同時高亮度且無視差(影像模糊),防 止顏色特性之劣化並可實現優越的色特性之彩色濾光片爲 目的。 爲達成此種目的,本發明係至少含有由基板及多數色 的著色圖型而成的著色層而成之彩色濾光片,藉由含有光 散射性微粒子及顏色特性之補正而用的色材而成爲特徵之 彩色濾光片。 (請先閱讀背面之注意事項再填寫本頁)594062 A7 _ B7 V. Description of the invention (1) (Background of the invention) Technical field of the invention The present invention relates to color filters, especially those of reflective or transflective liquid crystal display devices. 2. Description of the Related Art In recent years, the use of a color liquid crystal display device as a flat display has been ordered. This color liquid crystal display device can be classified into a reflective type and a transmissive type. A reflective color liquid crystal display device, for example, has a colored layer made of a plurality of colors (usually three primary colors of red (R), green (G), and blue (B)) (if necessary, it also has a black matrix or flattening) Layer) and color electrode with transparent electrode layer, reflective electrode layer made of metal such as aluminum and thin TFT array substrate of film transistor (TFT element), with specified gap and alignment, so that A liquid crystal layer is formed on the gap portion, and a phase difference plate, a polarizing plate, and a front scattering plate are provided on the color filter (observer side). The aforementioned front-scattering plate has a light-scattering function, and is provided for appropriately scattering light that has been incident on the reflective liquid crystal display device and ensuring sufficient visibility. However, in the conventional reflective color liquid crystal display device, the presence of a front scattering plate causes a problem that the brightness of the liquid crystal display device is lowered and the color characteristics are lowered. This is caused by the color attached to the front diffuser. In addition, due to the presence of the front scattering plate, there are also problems with parallax (image blur). The above-mentioned decrease in brightness is due to the conventional reflective color liquid crystal display device equipped with a front scattering plate on the color filter (observer side). This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm). 7 ^ " " ~ (Please read the notes on the back before filling in this page), 11 · Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 594062 A7 B7 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs SUMMARY OF THE INVENTION (2) Inevitable problems. To solve such a problem, by including light-scattering microparticles in the color filter, imparting light-scattering property to the color filter itself is considered as a proposal. This makes the front scattering plate unnecessary, so that it is possible to solve the above-mentioned problems accompanying the front scattering plate to some extent. However, when a sufficient light-scattering function is to be imparted by the light-scattering fine particles, the light-scattering layer may become a thick film as a result. For example, the thickness of a common protective film is less than 2 // m, but the light scattering function film can also have a thickness of about 0.5 to 2 0 // m. At this time, if there is too little coloring component in the composition forming each layer, if there is a coloring component that adversely affects the color characteristics of the color filter, the thicker the film, the more this coloring phenomenon is emphasized. Here, as for the coloring component, it can be regarded as a resin component, a polymerization initiator, etc., and these are not limited to a thermosetting type or a photocuring type, and it is known to have a color ranging from light yellow to red. Summary of the Invention The present invention has been made in view of the above-mentioned facts, so as to provide a color that eliminates the need for a front scattering plate, and has high brightness and no parallax (image blur), prevents deterioration of color characteristics, and achieves excellent color characteristics. Filter for the purpose. In order to achieve such an object, the present invention is a color filter including at least a coloring layer composed of a substrate and a coloring pattern of a plurality of colors, and a coloring material for containing light-scattering fine particles and correcting color characteristics. It becomes a characteristic color filter. (Please read the notes on the back before filling this page)

T 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 594062 經濟部智慧財產局員工消費合作社印製 A7 __B7_五、發明説明(3 ) 在此,上述彩色瀘光片宜爲具有含有前述光散射性微 粒子及前述色材之兩者的層。又曇霧値在1 0〜9 0之範 圍內,全光線透過率在3 0 %以上爲宜。 至於本發明之較佳態樣之第一態樣,係前述基板爲透 明的,再具有經予層合於著色層之外側上的透明電極層而 成,前述光散射性微粒子係使含有於前述透明基板及前述 著色層之間作爲光散射層而成的彩色濾光片。 至於本發明之較佳態樣之第二態樣,係前述基板爲透 明的,再具有經予層合於前述著色層之外側上的透明電極 層而成,前述光散射性微粒子係經予含有於前述著色層上 而成的彩色濾光片。 至於本發明之較佳態樣之第三態樣,係前述基板爲透 .明的,再具有經予層合於前述著色層之外側上的平坦化層 ,及經予層合於該平坦化層之外側上的透明電極層而成, 前述光散射性微粒子係使含有於前述平坦化層而成的彩色 濾光片。 至於本發明之較佳態樣之第四態樣,係於前述基板及 前述著色層之間,再具有經予層合於前述基板上的驅動元 件層及經予層合於反射電極層之間作爲光散射層而成的彩 色濾光片。 至於本發明之較佳態樣之第五態樣,係於前述基板及 I 前述著色層之間,再具有經予層合於前述基板上的驅動元 件層及經予層合於反射電極層而成,前述光散射性微粒子 係使含有於前述著色層而成的彩色濾光片。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -6 - (請先閲讀背面之注意事項再填寫本頁) C· 、11 594062 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明(4 ) 至於本發明之較佳態樣之第六態樣,係於經予層合於 前述著色層之外側的平坦化層及前述基板與前述著色層之 間,再具有經予層合於前述基板上的驅動元件層及經予層 合於該驅動元件層上的反射電極層而成,前述光散射性微 粒子係使含有於前述平坦化層而成的彩色濾光片。 至於本發明之較佳態樣之第七態樣,係於前述基板爲 透明的再具有經予層合於前述著色層之外側的透明電極層 而成,前述光散射性微粒子係使含有於前述透明基板及前 述著色層之間作爲光散射層,且亦使含有至少一色以上的 前述著色圖型之彩色瀘光片。 至於本發明之較佳態樣之第八態樣,係前述基板爲透 明的,再具有經予層合於前述著色層之外側的平坦化層及 經予層合於前述平坦化層之外側的透明電極層而成,前述 光散射性微粒子係使含有前述平坦化層及至少一色以上的 前述著色圖型之彩色瀘光片。 至於本發明之較佳態樣之第九態樣’係前述基板爲透 明的,再具有經予層合於前述著色層之外側的平坦化層及 經予層合於前述平坦化層之外側的透明電極層而成,前述 光散射性微粒子係使含有於前述透明基板及前述著色層之 間作爲光散射層,且亦使含有於前述平坦化層而成的彩色 濾光片。 至於本發明之較佳態樣之第十態樣’係前述基板及前 述著色層之間,再具有經予層合於前述基板上的驅動元件 層,經予層合於該驅動元件層上之反射電極層而成,前述 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -7 - (請先閱讀背面之注意事項再填寫本頁) 594062 A7 ___ B7__ 五、發明説明(5 ) (請先閱讀背面之注意事項再填寫本頁) 光散射性微粒子係使含有於前述反射電極層及前述著色層 之間作爲光散射層,且亦使含有於至少一色以上的前述著 色圖型而成的彩色瀘光片。 至於本發明之較佳態樣之第十一態樣,係於經予層合 於前述著色層之外側的平坦化層及前述基板與前述著色層 之間,再具有經予層合於前述基板上的驅動元件層,經予 層合於該驅動元件層之反射電極層而成,前述光散射性微 粒子係使含有於前述平坦化層,且亦使含有於至少一色以 上的前述著色圖型而成的彩色濾光片。 至於本發明之較佳態樣之第十二態樣,係於經予層合 於前述著色層之外側的平坦化層及前述基板與前述著色層 之間,再具有經予層合於前述基板上的驅動元件層及經予 .層合於該驅動元件層上的反射電極層而成,前述光散射性 微粒子係使含有於前述反射電極層及前述著色層之間作爲 反射電極層,且亦使含有於前述平坦化層而成的彩色濾光 片。 經濟部智慧財產局員工消費合作社印製 又依本發明之另外的較佳態樣時,係提供由上述第一 〜第三之任一態樣之彩色瀘光片,及於透明的基板上依序 層合有驅動元件層,反射電極層及透明電極層,光散射性 微粒子係使含有於前述反射電極層及前述透明電極層之間 作爲光散射層.而成的電極基板,經予挾持液晶層而成之液 晶顯示裝置。 又若依本發明之再另一較佳態樣時,係提供由上述第 四〜第六之任一態樣之彩色濾光片,及於透明的基板上經 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) _ 8 - 594062 A7 _B7_____ 五、發明説明(β ) 6 (請先閱讀背面之注意事項再填寫本頁) 予層合透明電極層,光散射性微粒子係使含有於前述透明 基板及透明電極層之間作爲光散射層而成的顯示側基板’ 經予挾持液晶層而成之液晶顯示裝置。 發明之具體說明 以下具體的說明本發明之彩色瀘光片。 彩色濾光片 經濟部智慧財產局員工消費合作社印製 本發明之彩色濾光片係反射型或半透過型之液晶顯示 裝置用的彩色濾光片,至少含有由基板及多數色著色圖型 而成的著色層而成。因此,於此彩色濾光片內,使含有光 散射性微粒子,及供補正色特性而用的色材。如此以使於 彩色瀘光片內含有光散射性微粒子,對彩色濾光片可賦與 光散射功能。因此,可不需於彩色濾光片上(觀測者側) 配設前方散射板。而且,藉由使於彩色濾光片內含有供補 正色特性而用的色材,可確實的補充伴隨光散射微粒子之 添加而引起的色特性之降低,故可實現優越的色特性。因 此,隨著附加習用的前方散射板引起的視差(影像模糊) 及亮度與色特性之降低可予消除,欲實現高畫質的液晶顯 示裝置即成爲可能的。 又藉由使含有色材,賦與所期待的色特性,可容易的 對應於各種分光規範。再者,隨著厚膜之著色性並不受拘 限,可廣泛範圍的選擇於製造之材料,故有所謂可提高生 產性之優點。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -9 - 594062 A7 B7 五、發明説明(7) (請先閲讀背面之注意事項再填寫本頁) 且本發明之彩色瀘光片係予構成可與前方散射板合倂 使用般亦可。於此情形,以彩色瀘光片本身的色特性補正 可確實的補充伴隨前方散射板之附加而引起的亮度及色特 性之降低,故彩色濾光片製造及以另外的步驟製造的反射 型彩色濾光片液晶顯示裝置,顯示影像亦成爲亮度高且色 特性優越者。 使含有光散射性微粒子,及爲補正色特性而用的色材 之層並未予特別限定,可使各自含於彩色濾光片內的至少 一層內。又亦可使含有光散射微粒子及/或色材二層以上 〇 若依本發明之較佳的態樣時,則成爲含有光散射性微 粒子及色材之二者的層之構成。由而,可以一層進行光散 射性及色特性之補正,故由以一步驟可形成一事生產性良 好,由可容易的控制分光特性之點係較宜的。 (a )基板 經濟部智慧財產局員工消費合作社印製 至於本發明之基板,並未予特別限定,惟在反射型彩 色液晶顯示裝置內對液晶層有經予配設於觀測者側之型式 的彩色濾光片之情形,則需爲透明的。且在反射型彩色液 晶顯示裝置內對液晶層有經予配設於與觀測者側成相對側 之型式的彩色濾光片之情形,基板則不一定需爲透明的。 (b )著色層 於本發明之著色層係由多數色之著色圖型而成者。至 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ' — -10- 594062 Α7 Β7 五、發明説明(8 ) (請先閱讀背面之注意事項再填寫本頁) 於多數色之著色圖型,以由紅色著色圖型,綠色著色圖型 及藍色著色圖型構成的係較通常的。此種著色圖型係利用 公知的顏料分散法,染色法,電著法等可予形成,又各著 色圖型,亦可採用條帶型,鑲嵌片三角型,四像元配置型 等,並未予特別限定。 且本發明之彩色濾光片係具有黑色基質者至使位於構 成著色層或光散射性著色層之各著色圖型之間亦可。此時 ’黑色基質係可由遮光性樹脂,鉻等金屬予以形成。 (C )光散射性微粒子 經濟部智慧財產局員工消費合作社印製 於本發明之光散射性微粒子,係具有光散射作用之微 粒子,較宜的例子可舉出有:二氧化矽,氧化鋁,硫酸鋇 等無機物,丙烯酸酯系樹脂,二乙烯基苯系樹脂,苯胍系 樹脂,苯乙烯系樹脂,三聚氰胺系樹脂,丙烯酸酯一苯乙 烯系樹脂,聚碳酸酯系樹脂,聚乙烯系樹脂,聚氯乙烯系 樹脂等有機物,或此等的二種以上的混合系等之微粒子。 此等之中,以三聚氰胺系樹脂,苯胍系樹脂,及其混合系 樹脂或共聚物在透明性,耐久性之點係較宜的。此等的微 粒子係平均粒徑0 · 1〜5 . 0 // m,宜爲0 · 1〜 4 _ 0//m,較宜爲〇 · 1〜2 · 0//m之範圍,平均粒 徑未滿0 . 1 // m時,幾乎未有散射效果。且,光散射性 微粒子爲提高散射效果,宜爲球狀。 (d )供色特性之補正用的色材 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ:Ζ97公釐) -11 - 594062 A7 ___B7 五、發明説明(。) 9 (請先閲讀背面之注意事項再填寫本頁) 至於本發明之供色特性之補正用的色材,並未予特別 限定,惟可使用有機顏料,無機顏料,染料等,通常使用 的色材。又組合有機或無機之顏料及染料使用亦可。且色 材之添加量,若予適當決定至可實現所期待的色特性般即 可,並未予特別限定。 至於有機顏料之較佳例子,可舉出下述者。至於i ) 藍色顏料,可舉出·· C.I.Pigment Blue 15,C.I.Pigment Blue 15:3, C.I.Pigment Blue 15:4, C.I.Pigment Blue 15:6, C.I.Pigment Blue 22, C.I.Pigment Blue 60, C.I.Pigment Blue 64等,至於i i )紫色顏料,可舉出·· C.I.Pigment Violet 19, C.I.Pigment Violet 23, C.I.Pigment Violet 29, C.I.Pigment Violet 30, C.I.Pigment Violet 31, C.I.Pigment Violet 36, C.I.Pigment Violet 37, C.I.Pigment Violet 38, C.I.PigmentT This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 594062 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __B7_ V. Description of the invention (3) Here, the above color calenders should have A layer containing both the light-scattering fine particles and the color material. The fog is in the range of 10 to 90, and the total light transmittance is more than 30%. As for the first aspect of the preferred aspect of the present invention, the substrate is transparent, and further has a transparent electrode layer laminated on the outer side of the colored layer. The light-scattering fine particles are contained in the substrate. A color filter formed as a light scattering layer between a transparent substrate and the colored layer. As for the second aspect of the preferred aspect of the present invention, the substrate is transparent, and further has a transparent electrode layer laminated on the outer side of the colored layer, and the light-scattering fine particles are contained A color filter formed on the colored layer. As for the third aspect of the preferred aspect of the present invention, the aforementioned substrate is transparent, and further has a planarization layer pre-laminated on the outer side of the colored layer, and pre-layered on the planarization The transparent electrode layer on the outer side of the layer is a color filter in which the light-scattering fine particles are contained in the planarizing layer. As for the fourth aspect of the preferred aspect of the present invention, it is between the aforementioned substrate and the aforementioned colored layer, and further includes a driving element layer pre-laminated on the aforementioned substrate and a reflective electrode layer. A color filter formed as a light scattering layer. As for the fifth aspect of the preferred aspect of the present invention, it is between the aforementioned substrate and the aforementioned colored layer, and further has a driving element layer laminated on the aforementioned substrate and a reflective electrode layer, Preferably, the light-scattering fine particles are a color filter including the coloring layer. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -6-(Please read the precautions on the back before filling this page) C ·, 11 594062 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (4) As for the sixth aspect of the preferred aspect of the present invention, it is between a flattening layer pre-laminated on the outer side of the colored layer, and between the substrate and the colored layer, and further has The driving element layer on the substrate is pre-laminated and the reflective electrode layer is pre-layered on the driving element layer. The light-scattering fine particles are a color filter formed by including the planarization layer. As for the seventh aspect of the preferred aspect of the present invention, the substrate is transparent and has a transparent electrode layer pre-laminated on the outside of the colored layer. The light-scattering fine particles are contained in the foregoing. As a light scattering layer between the transparent substrate and the coloring layer, a color phosphor sheet containing the coloring pattern of at least one color is also used. As for the eighth aspect of the preferred aspect of the present invention, the substrate is transparent, and further has a planarization layer pre-laminated on the outer side of the colored layer and a planarization layer pre-laminated on the outer side of the planarization layer. The light-scattering fine particles are made of a transparent electrode layer, and the light-scattering fine particles are a color phosphor sheet containing the flattening layer and at least one color of the coloring pattern. As for the ninth aspect of the preferred aspect of the present invention, the aforementioned substrate is transparent, and further has a planarization layer pre-laminated on the outside of the colored layer and a substrate pre-laminated on the outside of the planarization layer. The light-scattering fine particles are made of a transparent electrode layer, and are a color filter made of a light-scattering layer contained between the transparent substrate and the colored layer, and also contained in the planarizing layer. As for the tenth aspect of the preferred aspect of the present invention, there is a driving element layer pre-laminated on the substrate between the substrate and the colored layer, and the driving element layer is pre-laminated on the driving element layer. Reflective electrode layer, the aforementioned paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -7-(Please read the precautions on the back before filling this page) 594062 A7 ___ B7__ 5. Description of the invention (5 ) (Please read the precautions on the back before filling in this page) The light-scattering microparticles are used as the light-scattering layer contained between the reflective electrode layer and the colored layer, and the colored pattern containing at least one color is also used. Made of color calenders. As for the eleventh aspect of the preferred aspect of the present invention, it is between the planarizing layer pre-laminated on the outer side of the colored layer and the substrate and the colored layer, and further has the layer laminated on the substrate. The driving element layer is formed by pre-layering a reflective electrode layer on the driving element layer. The light-scattering fine particles are contained in the planarizing layer, and the coloring pattern is also contained in at least one color. Into a color filter. As for the twelfth aspect of the preferred aspect of the present invention, it is between the flattening layer pre-laminated on the outer side of the colored layer and the substrate and the colored layer, and further has pre-laminated on the substrate And a reflective electrode layer laminated on the driving element layer. The light-scattering fine particles are used as a reflective electrode layer contained between the reflective electrode layer and the colored layer, and also A color filter formed by including the planarizing layer. When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and according to another preferred aspect of the present invention, a color phosphor film provided by any of the first to third aspects described above is provided, and the transparent substrate is provided on the transparent substrate. The driver element layer, the reflective electrode layer, and the transparent electrode layer are laminated in this order. The light-scattering microparticles are electrode substrates that are formed between the reflective electrode layer and the transparent electrode layer as a light-scattering layer. Layered liquid crystal display device. In accordance with yet another preferred aspect of the present invention, a color filter in any of the fourth to sixth aspects is provided, and the Chinese national standard (CNS) ) A4 size (210X297 mm) _ 8-594062 A7 _B7_____ 5. Description of the invention (β) 6 (Please read the precautions on the back before filling out this page) Pre-laminate the transparent electrode layer. The light-scattering particles are contained in A liquid crystal display device in which a display-side substrate formed as a light-scattering layer between the transparent substrate and the transparent electrode layer is provided with a liquid crystal layer. DETAILED DESCRIPTION OF THE INVENTION The color phosphor film of the present invention will be specifically described below. Color filter The color filter of the present invention is a color filter for reflective or semi-transmissive liquid crystal display devices printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The color filter includes at least a substrate and a plurality of coloring patterns. Into a colored layer. Therefore, in this color filter, light-scattering fine particles and a coloring material for correcting color characteristics are contained. In this way, light-scattering fine particles are contained in the color phosphor, and a light-scattering function can be imparted to the color filter. Therefore, it is not necessary to provide a front diffuser on the color filter (observer side). In addition, by including a color material for correcting the color characteristics in the color filter, it is possible to surely supplement the decrease in color characteristics caused by the addition of light-scattering fine particles, so that excellent color characteristics can be achieved. Therefore, the parallax (blurred image) and the decrease in brightness and color characteristics caused by the addition of a conventional front diffuser can be eliminated, and a liquid crystal display device with high image quality becomes possible. In addition, by including a color material and imparting desired color characteristics, it can easily correspond to various spectroscopic specifications. In addition, as the coloring properties of thick films are not limited, materials can be selected from a wide range of materials, so there is an advantage of improving productivity. This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -9-594062 A7 B7 V. Description of the invention (7) (Please read the precautions on the back before filling this page) and the color luminescence of the invention The sheet system may be used in combination with a front scattering plate. In this case, the correction of the color characteristics of the color phosphor film itself can surely supplement the decrease in brightness and color characteristics caused by the addition of the front scattering plate. Therefore, the color filters are manufactured and the reflective color manufactured by another step The filter liquid crystal display device also displays a high brightness and excellent color characteristics. The layer containing light-scattering fine particles and a coloring material for correcting color characteristics is not particularly limited, and each layer may be contained in at least one layer in a color filter. Two or more layers containing light-scattering microparticles and / or color materials may be used. 〇 According to a preferred aspect of the present invention, the layer may include a layer containing both light-scattering microparticles and color materials. As a result, correction of light scattering and color characteristics can be performed in one layer. Therefore, it is possible to form the product in one step, which is good in productivity, and it is preferable to control the spectral characteristics easily. (a) The substrate printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is not specifically limited, but the reflective liquid crystal display device has a liquid crystal layer that is arranged on the observer's side. In the case of color filters, they need to be transparent. Furthermore, in the reflective color liquid crystal display device, the liquid crystal layer may be provided with a color filter of a type disposed on the side opposite to the observer side, and the substrate does not necessarily need to be transparent. (b) Coloring layer The coloring layer in the present invention is a coloring pattern of a plurality of colors. To this paper size, the Chinese National Standard (CNS) A4 specification (210X297 mm) is applicable. — -10- 594062 Α7 Β7 V. Description of the invention (8) (Please read the precautions on the back before filling this page) The coloring pattern is generally composed of a red coloring pattern, a green coloring pattern, and a blue coloring pattern. This coloring pattern can be formed by the well-known pigment dispersion method, dyeing method, electrograph method, etc., and each coloring pattern can also use a strip type, mosaic triangle type, four-pixel configuration type, etc., and It is not particularly limited. In addition, the color filter of the present invention may have a black matrix so as to be located between each of the colored patterns constituting the colored layer or the light-scattering colored layer. In this case, the black matrix is formed of a light-shielding resin, a metal such as chromium. (C) Light-scattering microparticles The light-scattering microparticles printed on the present invention by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs are microparticles with light-scattering effects. Preferred examples include: silicon dioxide, alumina, Inorganic substances such as barium sulfate, acrylate resins, divinylbenzene resins, benzoguanide resins, styrene resins, melamine resins, acrylate-styrene resins, polycarbonate resins, polyethylene resins, Organic matter such as polyvinyl chloride resin, or fine particles of a mixture of two or more of these. Among these, melamine-based resins, benzoguanide-based resins, and mixed resins or copolymers thereof are preferable in terms of transparency and durability. The average particle size of these fine particles is 0 · 1 ~ 5. 0 // m, preferably 0 · 1 ~ 4 _ 0 // m, and more preferably in the range of 0 · 1 ~ 2 · 0 // m. When the diameter is less than 0. 1 // m, there is almost no scattering effect. The light-scattering microparticles are preferably spherical in order to improve the scattering effect. (d) Color materials used for correction of color characteristics The paper size is applicable to Chinese National Standard (CNS) A4 specifications (210 ×: Z97 mm) -11-594062 A7 ___B7 V. Description of the invention (.) 9 (Please read the back first Please note this page, please fill in this page) As for the color material for correcting the color supply characteristics of the present invention, it is not particularly limited, but organic pigments, inorganic pigments, dyes, etc., which are commonly used color materials, can be used. It can also be used in combination with organic or inorganic pigments and dyes. The addition amount of the color material is not particularly limited as long as it is appropriately determined so that the desired color characteristics can be achieved. As a preferable example of an organic pigment, the following can be mentioned. As for i) blue pigments, CIPigment Blue 15, CIPigment Blue 15: 3, CIPigment Blue 15: 4, CIPigment Blue 15: 6, CIPigment Blue 22, CIPigment Blue 60, CIPigment Blue 64, etc. As for ii) purple pigments, CIPigment Violet 19, CIPigment Violet 23, CIPigment Violet 29, CIPigment Violet 30, CIPigment Violet 31, CIPigment Violet 36, CIPigment Violet 37, CIPigment Violet 38, CIPigment

Violet 40, C.I.Pigment Violet 42, C.I.Pigment Violet 47, C.I.Pigment Violet 48, C.I.Pigment Violet 49, C.I.Pigment Violet 50 等,至於i i i )綠色顏料,可舉出: C.I.Pigment Green 7, C.I.Pigment Green 10, C.I.Pigment 經濟部智慧財產局員工消費合作社印製Violet 40, CIPigment Violet 42, CIPigment Violet 47, CIPigment Violet 48, CIPigment Violet 49, CIPigment Violet 50, etc., as for iii) Green pigments, including: CIPigment Green 7, CIPigment Green 10, CI Pigment Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Green 36等,至於i v )紅色顏料,可舉出有:C.I .Pigment Red 5, C.I.Pigment Red 9, C.I.Pigment Red 10, C.I.Pigment Red 17,C.I.Pigment Red 23,C.I.Pigemtn Red 88,C.I.Pigment Red 97, C.I.Pigment Red 119, C.I.Pigment Red 122, C.I.Pigment Red 123, C.I.Pigment Red 144, C.I.Pigment Red 149, C.I.Pigment Red 155, C.LPigment Red 166, C.I.Pigment Red 168, C.I.Pigment Red 177, C.I.Pigment Red 179, 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -12- 594062 A7 B7 五、發明説明(Green 36, etc. As for iv) red pigments, CI: Pigment Red 5, CIPigment Red 9, CIPigment Red 10, CIPigment Red 17, CIPigment Red 23, CIPigemtn Red 88, CIPigment Red 97 , CIPigment Red 119, CIPigment Red 122, CIPigment Red 123, CIPigment Red 144, CIPigment Red 149, CIPigment Red 155, C.LPigment Red 166, CIPigment Red 168, CIPigment Red 177, CIPigment Red 179, This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -12- 594062 A7 B7 V. Description of the invention (

1CT 經濟部智慧財產局員工消費合作社印製 C..Pigment Red 180, C.I.Pigment Red 190, C.I.Pigment Red 192, C.I.Pigment Red 198, C.LPigment Red 207, C.I.Pigment Red 209, C. I.Pigment Red 215, C.I.Pigment Red 216, C.I.Pigment Red 217, C.I.Pigment Red 220, C.LPigment Red 223,C.I.Pigment Red 224, C.LPigment Red 226, C.I.Pigment Red 227, C.I.Pigment Red 228, C.I.Pigment Red 240, C.LPigment Red 250, C.I.Pigment Red 254, C.I.Pigment Red 48:1, C.I.Pigment Red 48:2, C.LPigment Red 48:3, C.I.Pigment Red 48:4,C.I.Pigment Red 52:2 等。又至於 v ) 橙色顏料,可舉出 C.I.Pigment Orange 31,C.I.Pigment Orange 36, C.I.Pigment Orange 43, C.LPigment Orange 51, C.I.Pigment Orange 55, C.I.Pigment Orange 59, C.I.Pigment Orange 61,C.I.Pigment Orange 71 等,至於 v i )黃色顏料 ,可舉出:C.I.Pigment Yellow 1,C.I.Pigment Yellow 3, C.I.Pigment Yellow 12, C.I.Pigment Yellow 13, C.LPigment Yellow 14, C.I.Pigment Yellow 16, C.LPigment Yellow 17, C.I.Pigment Yellow 20, C.I.Pigment Yellow 24, C.I.Pigment Yellow 55, C.I.Pigment Yellow 60, C.I.Pigment Yellow 65, C.LPigment Yellow 73, C.I.Pigment Yellow 74, C.I.Pigment Yellow 81, C.LPigment Yellow 83, C.LPigment Yellow 86, C.I.Pigment Yellow 93, C.I.Pigment Yellow 95, C.I.Pigment Yellow 97,C.I.Pigment Yellow 98,C.I.Pigment Yellow 99, C.I.Pigment Yellow 100, C.LPigment Yellow 101, C.I.Pigment Yellow 104, C.I.Pigment Yellow 106, C.I.Pigment Yellow 108, (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -13- 594062 A7 B7 五、發明説明(Ή) (請先閲讀背面之注意事項再填寫本頁) C.I.Pigment Yellow 109, C.I.Pigment Yellow 110, C.I.Pigment Yellow 113, C.I.Pigment Yellow 114, C.I.Pigment Yellow 116, C.I.Pigment Yellow 117, C.I.Pigment Yellow 119, C.I.Pigment Yellow 120, C.I.Pigment Yellow 125, C.I.Pigment Yellow 126, G.I.Pigment Yellow 127, C.I.Pigment Yellow 128, C.I.Pigment Yellow 129, C.I.Pigment Yellow 137, C.I.Pigment Yellow 138, C.I.Pigment Yellow 139, C.I.Pigment Yellow 147, C.I.Pigment Yellow 148, C.I.Pigment Yellow 150, C.I.Pigment Yellow 151, C.I.Pigment Yellow 152, C.I.Pigment Yellow 153, C.I.Pigment Yellow 154, C.I.Pigment Yellow 156, C.I.Pigment Yellow 166, C.I.Pigment Yellow 168,C.I.Pigment Yellow 175 等,至於 v ii)褐色顏料,可舉出:C.I.Pigment Brown 23, C.I.Pigment 25,C.I.Pigment Brown 26 等,至於 v i i i ) 黑色顏料,可舉出:C.I.Pigment Black 7等。 經濟部智慧財產局員工消費合作社印製 至於無機顏料之較宜的例子,可舉出下述者。至於i )白色顏料,可舉出:硫酸鋅,氧化鋅,硫酸鋇,碳酸鋇 ,碳酸鈣,氧化鉛,黏土,滑石粉,二氧化矽,硫化鋅, 二氧化鈦,鈦酸鉛等,至於i i )黑色顏料,有碳黑等, 至於i i i )黃色顏料,可舉出鉛黃,鋅黃,鉻酸鋇等, 至於i v )橙色顏料,有赤口黃鉛,朱砂鉻等,至於v ) 紅色顏料,有紅色氧化鐵,鉛丹等,至於v i )紫色顏料 ,有鈷紫,錳紫等,至於vi i)藍色顏料,有普魯土藍 等,至於v i i i )綠色顏料,有鉻綠,氧化銘,鈷錄等 ,再者亦可採用,螢光顏料或蓄光顏料等。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) '~ -14- 594062 A7 ____ _B7______ 五、發明説明(12) (請先閲讀背面之注意事項再填寫本頁) 至於染料之較佳例,可舉出有··偶氮系染料,酞菁系 染料,蒽醌系染料,甲川系染料,腭啡系染料,碳鑰系染 料,醌亞胺系染料,苯並醌系染料,萘醌系染料,三苯基 甲烷系染料,靛系染料,茈酮(pei*ynon)系染料,萘醯亞 胺系染料,喹啉系染料,及前述染料之含金屬錯鹽系染料 於本發明,含有色材之層並未予特別限定,亦可使包 含於彩色濾光片內之任一層內。尤其於使光散射微粒子含 於著色層的情形,使含於著色層爲宜,又於採用光散射層 或光散射性平坦化層之情形,使含於光散射層或光散射性 平坦化層爲宜。 至於本發明之彩色濾光片的較宜態樣,雖可舉出以下 的第一〜第十二態樣,惟本發明並非此等所限定者。 第一〜第六態樣之彩色濾光片 本發明之第--第六態樣之彩色濾光片,係使光散射 經濟部智慧財產局員工消費合作社印製 性微粒子含有彩色濾光片內之僅一層內的態樣。此等態樣 之中,第一〜第三態樣之彩色濾光片,在反射型彩色液晶 顯示裝置內對液晶層係配設於觀測者側的型式之彩色濾光 片。又第四〜第六態樣之彩色濾光片,在反射型彩色液晶 顯示裝置內對液晶層係配設於觀測者側及相對側的型式之 彩色濾光片。 第一態樣之彩色瀘光片 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -15- 594062 A7 B7 五、發明説明(13) 第1圖係表示本發明之第一態樣之彩色濾光片之槪略 縱截面圖。第1圖所示的彩色濾光片1 ,係具有透明基板 (請先閲讀背面之注意事項再填寫本頁) 2,設於此透明基板2上的光散射層3,經予層合於光散 射層3上的著色層4及透明電極層5,著色層4係由紅色 著色圖型4 R,綠色著色圖型4 G及藍色著色圖型4 B所 構成的。 至於構成上述的彩色濾光片之透明基板2,可採用石 英玻璃,派熱司玻璃,合成石英板等無可撓性的透明硬質 材,或透明樹脂薄膜,光學用樹脂板等具有可撓性的透明 軟質材。 構成彩色濾光片1之散射層3,係使已入射於反射型 液晶顯示裝置之光生成適度的散射,並確保足夠的辨識性 者,使光散射性微粒子分散於透光性樹脂中者。 至於上述透光性樹脂,可舉出有丙烯酸酯系樹脂,環 氧系樹脂,聚乙烯醇系樹脂,聚醯亞胺系樹脂,聚乙烯基 醚系樹脂,若考慮折射率,透明基板2或著色層4之附著 性等,可單獨使用一種或使用二種以上的混合物。 經濟部智慧財產局員工消費合作社印製 又至於光散射性微粒子,可採用前述(c )所舉出者 。光散射層3之微粒子的含有量爲0 . 5〜7 0重量%, 宜爲1.0〜50重量%之範圍,光散射層3之厚度爲 0 . 5〜20#m,宜爲1 . 0〜l〇//m程度。 在此爲作成由光散射層3引起的散射光之強度足夠者 ,有提高曇霧値(曇霧値=〔擴散光線透過率)/(全光 線透過率)X 1 0 0〕之必要。爲使高曇霧値(高渾濁度 本紙張尺度適用中國國家標準( CNS ) A4規格(210X297公釐) -16- 594062 A7 B7 五、發明説明(14) (請先閱讀背面之注意事項再填寫本頁) )成爲可能,有增高微粒子濃度或光散射層之厚度的必要 ,惟此時全部光線透過率及擴散光線透過率會降低並不宜 。例如採用公知的二氧化鈦或碳酸鈣作爲一般的微粒子時 ,若增加微粒子濃度或光散射層之厚度時,則粒子所具的 遮光性會顯現出,全部光線透過率會顯著降低。在本發明 之彩色濾光片1 ,藉由將光散射層3所用的微粒子作成上 述的材料,可將曇霧値設成10〜90,宜爲25〜80 ,較宜爲.3 0〜7 0之範圍,全部光線透過率設成3 0 % 以上,擴散光線透過率設成1 0%以上。且在本發明,曇 霧値係採用東洋精機製作所(股)製造的直讀曇霧計予以 測定者。採用前方散射板之方式,係隨著曇霧値之變大, 雖可予調整視差(影像模糊),惟在本發明以於彩色濾光 片內含有光散射層,即使爲高曇霧亦不生成視差。 在此於光散射層3內加入光散射性微粒子,使再含有 供補正色特性用之色材。由而,可有效的防止由添加光散 射性微粒子引起的著色。至於供補正色特性而用的色材, 可採用前述(d)所舉者。 經濟部智慧財產局員工消費合作社印製 且於本態樣,供補正色特性而用的色材,亦可爲使含 於光散射層3以外的層之構成。 著色層4係利用公知的顏料分散法,染色法,電著法 等可予形成,又各著色圖型(4R,4G,4B)亦爲條 帶型鑲嵌片型,三角型,四像元配置型等,並未予特別限 制。 再者,構成彩色濾光片1之透明電極層5係採用氧化 本紙張尺度適用中g|國家標準(CNS ) A4規格(210X297公瘦) ~ — -17- 594062 A7 B7 五、發明説明(15) (請先閲讀背面之注意事項再填寫本頁) 銦錫(I T〇),氧化鋅(Ζ η ◦),氧化錫(S η〇) 等及其合金等,利用濺鍍法,真空蒸鍍法,C V D法等一 般的成膜方法可予形成。此種透明電極層5之厚度爲 0 · 01 〜l//m,宜爲 〇 · 03 〜0. 5//m 程度。 此種彩色濾光片1係以補正色材引起的色特性可確實 的防止光散射層3之著色,故使用彩色瀘光片1並以其他 步驟製造的反射型彩色液晶顯示裝置,亦幾乎不生成伴隨 光散射層而引起的色特性之降低。又於彩色濾光片1內具 有光散射層3,於彩色濾光片1上(觀測者側)配設以留 用的反射型彩色液晶顯示裝置所使用的前方散射板即成爲 不需要的,高亮度之反射型彩色液晶顯示裝置即成爲可能 。再者依光散射層3可將透明基板2及著色層4間之附著 性製成較高者。 第二態樣之彩色瀘光片 經濟部智慧財產局員工消費合作社印製 第2圖係表示本發明之.第二態樣之彩色瀘光片之槪略 縱截面圖。第2圖所示的彩色濾光片1 1 ,係具有透明基 板1 2,設於此透明基板1 2上的光散射層1 4,設於此 光散射性著色層1 4上的透明電極層1 5,光散射性著色 層1 4係由紅色著色圖型1 4R,綠色著色圖型1 4G及 藍色著色圖型1 4 B所構成的。 構成上述的彩色濾光片1 1之透明基板1 2,透明電 極層1 5,係與於上述的彩色濾光片1之透明基板2,透 明電極層5相同,在此省略說明。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -18 - 594062 A7 B7 五、發明説明(16) (請先閱讀背面之注意事項再填寫本頁) 構成彩色濾光片1 1之光散射性著色層1 4,係設成 與習用的反射型彩色液晶顯示裝置之著色層相同作用,同 時使已入射於反射型彩色液晶顯示裝置之光生成適度的散 射,並確保足夠的辨識性者。 此光散射性著色層1 4係利用公知的顏料分散法,染 色法,電著法等可予形成的著色層中使光散射性微粒子分 散者。至於光散射性微粒子,可使用上述(c )舉出的微 粒子。此等微粒子於光散射性著色層1 4中的含有量爲 0 · 5〜70重量%,宜爲1 . 0〜5 · 0重量%之範圍 ,光散射性著色層1 4之厚度可設定成爲0 · 0 5〜1 5 //m,宜爲0 . 5〜15//m,較宜爲0 . 5〜10//m 之範圍。 於此彩色濾光片1 1,藉由將光散射性著色層1 4所 用的微粒子設成上述的材料時,可將曇霧値設成1 0〜 經濟部智慧財產局員工消費合作社印製 90,宜爲25〜80,較宜爲30〜70之範圍,全部 光線透過率可設成3 0 %以上,擴散光線透過率設成1 0 %以上。在採用前方散射板之方式,隨著曇霧値之變大, 雖可調整視差(影像模糊),惟在本發明以於彩色濾光片 內含有光散射層,即使爲高曇霧亦不生成視差。 在此於光散射性著色層1 4內加入光散射性微粒子, 使再含有供補正色特性用之色材。由而,可有效的防止由 添加光散射性微粒子引起的著色。至於供補正色特性而用 的色材,可採用前述(d )所舉者。 且於本態樣,供補正色特性而用的色材,亦可爲使含 本i氏張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) " -19- 594062 A7 B7 五、發明説明(17) 於光散射性著色層1 4以外的層之構成。 (請先閱讀背面之注意事項再填寫本頁) 且,光散射性著色層1 4之各著色圖型(1 4 R, 14G, 14B)亦爲條帶型,鑲嵌片型,三角形,四像 元配置型等,並未予特別限制。 此種彩色濾光片1 1係以利用光分散性著色層1 4之 製造階段的色材補正色特性可確實的防止使光散射性微粒 子之光散射性著色層1 4之色特性的劣化,且利用微粒子 含有量之調整對各色微妙的控制光散射程度之事即成爲可 能的。因此使用彩色濾光片1 1並於以另外步驟製造的反 射型彩色液晶顯示裝置,亦幾乎不生成伴隨光散射引起的 色特性之降低,又於彩色濾光片1 1內具有光散射性著色 層1 4,故於彩色濾光片上(觀測者側)則不需配設習用 的反射型彩色液晶顯示裝置所使用的前方散射板,高亮度 之反射型彩色液晶顯示裝置即成爲可能。 第三態樣之彩色瀘光片 經濟部智慧財產局員工消費合作社印製 第3圖係表示本發明之第三態樣之彩色濾光片之槪略 縱截面圖。第3圖所示的彩色濾光片2 1 ,係具有透明基 板2 2,經予層合於此透明基板2 2上的著色層2 4,光 散射性平坦化層2 6,及透明電極層2 5,著色層2 4係 由紅色著色圖型2 4 R,綠色著色圖型2 4 G及藍色著色 圖型2 4 B所構成的。 構成上述的彩色濾光片2 1之透明基板2 2,著色層 2 4,透明電極層2 5,係與於上述的彩色濾光片1之透 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -20- 594062 A7 ___B7_ 五、發明説明(18) 明基板,透明電極層5相同,在此省略說明。 (請先閲讀背面之注意事項再填寫本頁) 構成彩色濾光片2 1之光散射性平坦化層2 6,係減 少著色層2 4之表面的微小的凹凸,並於透明電極層形成 用上形成平坦面,同時使已入射於反射型液晶顯示裝置之 光生成適度的散射,並確保足夠的辨識性者。 此光散射性平坦化層2 6係使光散射性微粒子分散於 例如丙烯酸酯系樹脂,環氧系樹脂,乙烯基醚系樹脂,聚 醯亞胺系樹脂,丙烯系樹脂等樹脂中者。至於光散射性微 粒子,可使用上述(c )舉出的微粒子。微粒子於光散射 性平坦化層2 6之含有量爲0 . 5〜7 0重量%,宜爲 1 · 0〜5 0重量%之範圍,光散射性平坦化層2 5之厚 度爲0 . 5〜20//m,宜爲1 · 〇〜l〇//m程度。 於此彩色濾光片2 1,藉由將光散射性平坦化層2 6 所用的微粒子設成上述的材料,可將曇霧値設成1 0〜 經濟部智慧財產局員工消費合作社印製 90,宜爲25〜80,較宜爲3 0〜70之範圍,全部 光線透過率設成3 0 %以上,擴散光線透過率設成1 0 % 以上。且在採用前方散射板之方式,隨著曇霧値變大,雖 可強調整視差(影像模糊),惟在本發明以於彩色濾光片 內含有光散射層,即使爲高曇霧亦不生成視差。 在此,於光散射性平坦化層2 6內,加入光散射性微 粒子,使再含有供補正色特性用之色材。由而,可有效的 防止由添加光散射性微粒子引起的著色。至於供補正色特 性而用的色材,可採用前述(d )所舉者。 且於本態樣,依補正色特性而用的色材,亦可爲使含 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -21 - 594062 A7 ___B7 五、發明説明(m) 19 於光散射性平坦化層2 6以外的層之構成。 (請先閱讀背面之注意事項再填寫本頁) 此種彩色瀘光片2 1係可利用色材之色特性補正可確 實的防止光散射性平坦化層2 6的顏色附著。因此,即使 於使用彩色濾光片2 1並以另外步驟製造的反射型彩色液 晶顯示裝置,亦幾乎不生成伴隨光散射的色特性之降低。 又於彩色濾光片2 1內具有光散射性平坦化層2 6,故於 彩色濾光片上(觀測者側)則不需配設習用的反射型彩色 液晶顯示裝置所使用的前方散射板,高亮度之反射型彩色 液晶顯示裝置即成爲可能。再者,藉由設置光散射性平坦 化層2 6提高強度,利用間隔件之間隙(液晶層之厚度) 控制即成爲較容易。 第四態樣之彩色濾光片 經濟部智慧財產局員工消費合作社印製 第4圖係表示本發明之第四態樣之彩色濾光片之槪略 縱截面圖。第4圖所示的彩色濾光片3 1 ,係具有設於基 板3 2上的驅動元件層3 3,依序經予層合於此驅動元件 層33上反射電極層34,光散射層35,著色層36, 透明電極層38,著色層36係由紅色著色圖型36R, 綠色著色圖型3 6 G及藍色著色圖型3 6 B所構成的,反 射電極層3 4及透明電極層3 8係予導通至各著色圖型上 〇 構成彩色濾光片3 1之基板3 2係可使用各種玻璃基 板,金屬基板,樹脂基板,由此等二種以上的材料而成之 複合基板等,其厚度係考慮彩色濾光片3 1之用途等並可 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ297公釐) -22- 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(2〇) 予適當設定,例如可設成〇 · 3〜1 0 m m程度。 構成彩色濾光片3 1之驅動元件層3 3,係由經予形 成指定的圖型之薄膜電晶體(T F T )及汲,源,閘之各 電極而成的。又,反射電極層3 4係經予連接於汲電極之 像元電極,介由絕緣層可予形成於驅動元件層3 3上,並 施予鏡面加工。又採用後述的半透型彩色液晶顯示裝置之 情形,可將反射電極層3 4作成穿半鏡型電極層或開孔型 電極層。此反射電極層3 4係以鋁,鉻,金,銀,銅等的 金屬薄膜予以形成,可設定厚度爲5 〇 〇〜1 〇 〇 〇 〇A •,宜爲1 0 0 0〜3 0 0 0A之範圍。此種反射電極層 3 4係可利用蒸鍍法,濺鍍盪,C V D法,離子植入法等 公知的薄膜形成方法予以形成。 構成彩色濾光片3 1之光散射層3 5,係使已入射於 反射型彩色液晶顯示裝置之光生成適度的散射,並確保足 夠的辨識性者,使光散射性微粒子分散於透光性樹脂中而 成者。 至於上述的透光性樹脂,可舉出丙烯酸酯系樹脂,環 氧系樹脂,聚乙烯醇系,聚醯亞胺系樹脂,乙烯基醚系樹 脂等,考慮折射率,與反射電極層3 4或著色層3 6間之 附著性等,可單獨使用一組或使用二種以上的混合物。 又至於光散射性微粒子,可採用前述(c )舉出者。 微粒子於光散射層35之含量爲0.5〜70重量%,宜 爲1 · 0〜5 0重量%之範圍,光散射層3 5之厚度爲 0 · 5〜20/zm宜爲1 · 〇〜l〇/zm之程度。 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -23- 594062 A7 B7 五、發明説明(2彳) 於此彩色濾光片3 1 ,亦藉由將光散射層3 5所用的 微粒子作成上述的材料,可將曇霧値設成1 〇〜9 〇,宜 爲2 5〜8 0,較宜爲3 0〜7 0之範圍,全部光線透過 率爲3 0 %以上,擴散光線透過率爲1 · 〇以上。在採用 前方散射板之方式,隨著曇霧値變大,雖可予強調視差( 影像模糊),惟在本發明,於彩色濾光片內含有光散射層 ,即使爲高曇霧値亦不致生成視差。 在此,於光散射層3 5內加入光散射性微粒子,使再 含有供補正色特性用之色材。由而,可有效的防止由添加 光散射性微粒子引起的著色。至於供補正色特性而用的色 材,可採用前述(d )所舉者。 且於本態樣,係補正色特性而用的色材,亦可爲使含 於光散射層以外的層之構成。 著色層3 6係可依公知的顏料分散法,染色法,電著 法等予以形成,又各著色圖型(36R,36G,36B )亦可爲條帶型,鑲嵌片型,三角型,四像元配置型等, 並未予特別限制。 此種彩色濾光片3 1 ,係可利用色材之色特性補正可 確實的防止光散射層3 5之顏色附著,因此即使於使用彩 色濾光片3 1並以另外步驟的反射型彩色液晶顯示裝置, 亦幾乎不生成色特性之降低。又於彩色濾光片2 1內具有 光散射層3 5,故在習用的反射型彩色液晶顯示裝置即成 爲不需配設於觀測者側之前方散射板’高亮度之反射型彩 色液晶顯示裝置即成爲可能。再者,藉由設置光散射層 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 、言 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 594062 A7 B7 五、發明説明(。。) 22 3 5,可製成反射電極層3 4及著色層3 6間之附著性較 尚者。 第五態樣之彩色濾光片 第5圖係表示本發明之第五態樣之彩色濾光片之槪略 縱截面圖。第5圖所示的彩色濾光片4 1 ,係具有設於基 板4 2上的驅動元件層4 3,依序經予層合於此驅動元件 層4 3上的反射電極層4 4,光散射性著色層4 6,透明 電極層4 8,而光散射性著色層4 6係由紅色著色圖型 46R,綠色著色圖型46G及藍色著色圖型46B所構 成的。 構成上述彩色濾光片4 1之基板4 2之驅動元件層 4 3,反射電極層4 4,透明電極層4 8係與於上述的彩 色濾光片3 1之基板3 2,驅動元件層3 3,反射電極層 3 4,透明電極層3 8相同,在此省略說明。 構成彩色濾光片4 1之光散射性著色層4 6,係成爲 與習用的反射型彩色液晶顯示裝置之著色層具有相同的作 用,同時使已入射於反射型液晶裝置之光生成適當的散射 ,並確保足夠的辨識性者。 此光散射性著色層4 6係於利用公知的顏料分散法, 染色法,電著法予以形成的著色層中使光散射性微粒子分 散者。至於光散射性微粒子,可使用上述(c )舉出的微 粒子。此微粒子於光散射性著色層4 6中的含有量爲 0 . 5〜70重量%,宜爲1 . 0〜50重量%之範圍, ^紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁)1CT Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs C..Pigment Red 180, CIPigment Red 190, CIPigment Red 192, CIPigment Red 198, C.LPigment Red 207, CIPigment Red 209, CIPigment Red 215, CI Pigment Red 216, CIPigment Red 217, CIPigment Red 220, C.LPigment Red 223, CIPigment Red 224, C.LPigment Red 226, CIPigment Red 227, CIPigment Red 228, CIPigment Red 240, C.LPigment Red 250, CIPigment Red 254, CIPigment Red 48: 1, CIPigment Red 48: 2, C.LPigment Red 48: 3, CIPigment Red 48: 4, CIPigment Red 52: 2, etc. As for v) orange pigments, CIPigment Orange 31, CIPigment Orange 36, CIPigment Orange 43, C.LPigment Orange 51, CIPigment Orange 55, CIPigment Orange 59, CIPigment Orange 61, CIPigment Orange 71 can be cited. Etc. As for the vi) yellow pigment, CIPigment Yellow 1, CIPigment Yellow 3, CIPigment Yellow 12, CIPigment Yellow 13, C.LPigment Yellow 14, CIPigment Yellow 16, C.LPigment Yellow 17, CI Pigment Yellow 20, CIPigment Yellow 24, CIPigment Yellow 55, CIPigment Yellow 60, CIPigment Yellow 65, C.LPigment Yellow 73, CIPigment Yellow 74, CIPigment Yellow 81, C.LPigment Yellow 83, C.LPigment Yellow 86, CIPigment Yellow 93, CIPigment Yellow 95, CIPigment Yellow 97, CIPigment Yellow 98, CIPigment Yellow 99, CIPigment Yellow 100, C.LPigment Yellow 101, CIPigment Yellow 104, CIPigment Yellow 106, CIPigment Yellow 108, (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 regulations Grid (210X297mm) -13- 594062 A7 B7 V. Description of the invention (Ή) (Please read the notes on the back before filling this page) CIPigment Yellow 109, CIPigment Yellow 110, CIPigment Yellow 113, CIPigment Yellow 114, CIPigment Yellow 116, CIPigment Yellow 117, CIPigment Yellow 119, CIPigment Yellow 120, CIPigment Yellow 125, CIPigment Yellow 126, GIPigment Yellow 127, CIPigment Yellow 128, CIPigment Yellow 129, CIPigment Yellow 137, CIPigment Yellow 138, CIPigment Yellow 139, CIPigment Yellow 147, CIPigment Yellow 148, CIPigment Yellow 150, CIPigment Yellow 151, CIPigment Yellow 152, CIPigment Yellow 153, CIPigment Yellow 154, CIPigment Yellow 156, CIPigment Yellow 166, CIPigment Yellow 168, CIPigment Yellow 175, etc., as for v ii) brown pigments, including: Cipigment Brown 23, CIPigment 25, CIPigment Brown 26, etc., as for viii) black pigment, Examples include: CIPigment Black 7 and the like. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs As a more suitable example of inorganic pigments, the following can be cited. As for i) white pigments, zinc sulfate, zinc oxide, barium sulfate, barium carbonate, calcium carbonate, lead oxide, clay, talc, silicon dioxide, zinc sulfide, titanium dioxide, lead titanate, etc., as for ii) Black pigments include carbon black, etc. As for iii) yellow pigments, lead yellow, zinc yellow, barium chromate, etc., and iv) orange pigments, red yellow lead, cinnabar chromium, etc., as for v) red pigments, there are Red iron oxide, lead dan, etc., as for vi) purple pigments, such as cobalt violet, manganese violet, etc., as for vi i) blue pigments, including protoblue, etc., as for viii) green pigments, there are chrome green, oxidation inscriptions, Cobalt, etc., can also be used, fluorescent pigments or light storage pigments. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) '~ -14- 594062 A7 ____ _B7______ 5. Description of the invention (12) (Please read the precautions on the back before filling this page) As for the comparison of dyes Good examples include: azo-based dyes, phthalocyanine-based dyes, anthraquinone-based dyes, mesochuan-based dyes, perylene-based dyes, carbohydrate-based dyes, quinone imine-based dyes, benzoquinone-based dyes, Naphthoquinone-based dyes, triphenylmethane-based dyes, indigo-based dyes, pei * ynon-based dyes, naphthalene-imine-based dyes, quinoline-based dyes, and metal-containing salt-containing dyes of the aforementioned dyes In the invention, the layer containing the color material is not particularly limited, and it may be contained in any layer in the color filter. In particular, when the light-scattering particles are contained in the colored layer, it is preferable to include the colored layer, and when the light-scattering layer or the light-scattering planarization layer is used, the light-scattering layer or the light-scattering planarization layer is included. Better. As for a preferable aspect of the color filter of the present invention, although the following first to twelfth aspects can be cited, the present invention is not limited thereto. Color Filters of the First to Sixth Aspects The color filters of the sixth aspect to the sixth aspect of the present invention are those in which the printed particles of the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Ministry of Light Scattering contain the color filters. It's just a state in one layer. Among these aspects, the color filters of the first to third aspects are color filters of the type arranged on the observer's side for the liquid crystal layer in the reflective color liquid crystal display device. In the fourth to sixth aspects of the color filter, the liquid crystal layer is arranged in the reflective color liquid crystal display device on the observer side and the opposite side. The first aspect of the color matte film is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -15- 594062 A7 B7 V. Description of the invention (13) Figure 1 shows the first aspect of the invention A schematic longitudinal sectional view of a sample color filter. The color filter 1 shown in FIG. 1 has a transparent substrate (please read the precautions on the back before filling this page) 2. The light scattering layer 3 provided on this transparent substrate 2 is pre-laminated on the light The colored layer 4 and the transparent electrode layer 5 on the scattering layer 3, and the colored layer 4 are composed of a red colored pattern 4 R, a green colored pattern 4 G, and a blue colored pattern 4 B. As for the transparent substrate 2 constituting the above-mentioned color filter, quartz glass, Pyrex glass, synthetic quartz plate and other non-flexible transparent hard materials, or transparent resin films, optical resin plates, etc. can be used. Transparent soft material. The scattering layer 3 constituting the color filter 1 is one that appropriately diffuses the light that has been incident on the reflective liquid crystal display device and ensures sufficient visibility, and disperses the light-scattering fine particles in the translucent resin. Examples of the translucent resin include acrylic resin, epoxy resin, polyvinyl alcohol resin, polyimide resin, and polyvinyl ether resin. In consideration of the refractive index, the transparent substrate 2 or The coloring layer 4 may be used singly or in a mixture of two or more kinds. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs As for the light-scattering particles, the ones listed in (c) above can be used. The content of the fine particles of the light scattering layer 3 is 0.5 to 70% by weight, preferably in a range of 1.0 to 50% by weight, and the thickness of the light scattering layer 3 is 0.5 to 20 # m, preferably 1.0 to l0 // m degree. Here, it is necessary to make the intensity of the scattered light caused by the light scattering layer 3 sufficient, and it is necessary to increase the haze (昙 fog 値 = [diffused light transmittance) / (total light transmittance) X 1 0 0]. In order to make high fog (high turbidity, this paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -16- 594062 A7 B7 V. Description of the invention (14) (Please read the precautions on the back before filling This page)) is possible, and it is necessary to increase the particle concentration or the thickness of the light scattering layer, but at this time, it is not appropriate that the total light transmittance and the diffused light transmittance are reduced. For example, when a known titanium dioxide or calcium carbonate is used as a general fine particle, if the concentration of the fine particle or the thickness of the light-scattering layer is increased, the light-shielding property of the particle will appear, and the total light transmittance will be significantly reduced. In the color filter 1 of the present invention, by using the fine particles used in the light scattering layer 3 as the above-mentioned material, the mist can be set to 10 to 90, preferably 25 to 80, and more preferably 3 to 7 In the range of 0, the total light transmittance is set to 30% or more, and the diffuse light transmittance is set to 10% or more. In the present invention, the haze is measured by a direct reading haze meter manufactured by Toyo Seiki Seisakusho Co., Ltd. The method of adopting a front scattering plate is used as the fog becomes larger. Although the parallax (image blur) can be adjusted, in the present invention, the color filter contains a light scattering layer, even if the fog is high. Generate parallax. Here, light-scattering fine particles are added to the light-scattering layer 3 so as to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-diffusing fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. The color material printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and used in this case for correcting the color characteristics may also be a layer composed of layers other than the light scattering layer 3. The colored layer 4 can be formed by the well-known pigment dispersion method, dyeing method, electrograph method, etc., and each coloring pattern (4R, 4G, 4B) is also a strip-type mosaic sheet type, a triangular type, and a four-pixel configuration. There are no particular restrictions on the type. In addition, the transparent electrode layer 5 constituting the color filter 1 is made of oxidized paper. Applicable medium g | National Standard (CNS) A4 specification (210X297 male thin) ~--17- 594062 A7 B7 V. Description of the invention (15 ) (Please read the precautions on the back before filling this page) Indium tin (IT〇), zinc oxide (Z η ◦), tin oxide (S η〇), etc. and their alloys, etc., by sputtering, vacuum evaporation It can be formed by a general film-forming method such as the CVD method and the CVD method. The thickness of such a transparent electrode layer 5 is 0 · 01 to 1 // m, and preferably 0 · 03 to 0.5 // m degree. This type of color filter 1 can reliably prevent the coloring of the light scattering layer 3 by correcting the color characteristics caused by the color material. Therefore, the reflection type color liquid crystal display device manufactured by using the color calender 1 and other steps has almost no effect. A decrease in color characteristics due to the light scattering layer is generated. In addition, a light scattering layer 3 is provided in the color filter 1, and a front scattering plate used for a reserved reflective color liquid crystal display device disposed on the color filter 1 (observer side) becomes unnecessary, and the height is high. A reflection-type color liquid crystal display device of brightness becomes possible. Furthermore, depending on the light scattering layer 3, the adhesion between the transparent substrate 2 and the coloring layer 4 can be made higher. Color matte film of the second aspect Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 2 is a schematic longitudinal sectional view of the color matte film of the second aspect of the present invention. The color filter 1 1 shown in FIG. 2 includes a transparent substrate 12, a light-scattering layer 14 provided on the transparent substrate 12, and a transparent electrode layer provided on the light-scattering colored layer 14. 15. The light-scattering colored layer 14 is composed of a red colored pattern 14R, a green colored pattern 14G, and a blue colored pattern 14B. The transparent substrate 12 and the transparent electrode layer 15 constituting the above-mentioned color filter 11 are the same as the transparent substrate 2 and the transparent electrode layer 5 of the above-mentioned color filter 1, and description thereof is omitted here. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -18-594062 A7 B7 V. Description of invention (16) (Please read the precautions on the back before filling this page) Composition of color filters 1 1 The light-scattering coloring layer 14 is set to have the same function as the coloring layer of a conventional reflective color liquid crystal display device, and at the same time, the light that has entered the reflective color liquid crystal display device has a moderate scattering and ensures sufficient identification. Sex. This light-scattering colored layer 14 is one in which light-scattering fine particles are dispersed in a coloring layer which can be formed by a known pigment dispersion method, a coloring method, an electro-texting method, or the like. As the light-scattering fine particles, the fine particles listed in (c) above can be used. The content of these fine particles in the light-scattering colored layer 14 is from 0.5 to 70% by weight, preferably in the range of 1.0 to 5.0% by weight. The thickness of the light-scattering colored layer 14 can be set to 0 · 0 5 to 1 5 // m, preferably 0.5 to 15 // m, and more preferably 0.5 to 10 // m. When the color filter 11 is made of the fine particles used in the light-scattering colored layer 14 as described above, the fog can be set to 10 ~ printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 90 It should be in the range of 25 to 80, and more preferably in the range of 30 to 70. The total light transmittance can be set to more than 30%, and the diffuse light transmittance can be set to more than 10%. In the method of using a front scattering plate, as the haze becomes larger, although the parallax (image blur) can be adjusted, in the present invention, the color filter contains a light scattering layer, which does not generate even a high haze. Parallax. Here, light-scattering fine particles are added to the light-scattering coloring layer 14 so as to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-scattering fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. And in this aspect, the color material used for correcting the color characteristics can also be used to make the Chinese standard (CNS) A4 specification (210X297 mm) with this i-scale. &Quot; -19- 594062 A7 B7 V. Invention (17) The structure of layers other than the light-scattering colored layer 14 will be described. (Please read the precautions on the back before filling in this page.) Moreover, each coloring pattern (1 4 R, 14G, 14B) of the light-scattering coloring layer 1 4 is also a strip type, mosaic type, triangle, and four images. The meta-configuration type and the like are not particularly limited. Such a color filter 11 uses the color material correction color characteristics in the manufacturing stage of the light-dispersible coloring layer 14 to reliably prevent the color characteristics of the light-scattering fine particle light-scattering coloring layer 14 from deteriorating. And it is possible to finely control the degree of light scattering for each color by adjusting the content of fine particles. Therefore, the reflective color liquid crystal display device manufactured by using the color filter 11 and manufactured in another step hardly generates a decrease in color characteristics due to light scattering, and has light-scattering coloring in the color filter 11 The layer 14 is a high-brightness reflective color liquid crystal display device, which does not need to be equipped with a front scattering plate for a conventional reflective color liquid crystal display device on the color filter (observer side). The third aspect of the color phosphor film is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 3 is a schematic longitudinal sectional view showing the third aspect of the color filter of the present invention. The color filter 2 1 shown in FIG. 3 includes a transparent substrate 22, a coloring layer 2 4, a light-scattering planarization layer 26, and a transparent electrode layer pre-laminated on the transparent substrate 22. 25. The colored layer 24 is composed of a red colored pattern 2 4 R, a green colored pattern 2 4 G, and a blue colored pattern 2 4 B. The transparent substrate 22, the coloring layer 24, and the transparent electrode layer 25 constituting the above-mentioned color filter 21 are transparent to the above-mentioned color filter 1. The paper standard is applicable to the Chinese National Standard (CNS) A4 specification. (210X297 mm) -20- 594062 A7 ___B7_ V. Description of the invention (18) The substrate and transparent electrode layer 5 are the same, and the description is omitted here. (Please read the precautions on the back before filling this page.) The light-scattering flattening layer 2 6 constituting the color filter 21 is used to reduce the minute unevenness on the surface of the coloring layer 24 and is used for forming transparent electrode layers. A flat surface is formed thereon, and at the same time, light that has been incident on the reflective liquid crystal display device is appropriately scattered, and sufficient visibility is ensured. This light-scattering flattening layer 26 is one in which light-scattering fine particles are dispersed in resins such as acrylate resin, epoxy resin, vinyl ether resin, polyimide resin, and acrylic resin. As the light-scattering fine particles, the fine particles listed in (c) above can be used. The content of the fine particles in the light-scattering planarization layer 26 is 0.5 to 70% by weight, preferably in the range of 1.0 to 50% by weight, and the thickness of the light-scattering planarization layer 25 is 0.5. It is preferably about 20 // m, preferably about 1.0 to 10 // m. Here, the color filter 21 is made of the fine particles used in the light-scattering planarization layer 2 6 as the above-mentioned material, and the mist can be set to 10 ~ printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 90 It should be in the range of 25 to 80, more preferably in the range of 30 to 70. The total light transmittance is set to more than 30%, and the diffuse light transmittance is set to more than 10%. In addition, in the method of using a front scattering plate, as the haze becomes larger, although the parallax (image blur) can be adjusted strongly, in the present invention, the color filter contains a light scattering layer, even if it is a high haze. Generate parallax. Here, light-scattering fine particles are added to the light-scattering flattening layer 26 to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-scattering fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. And in this aspect, the color material used to compensate for the color correction characteristics can also be used to make the paper size applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -21-594062 A7 ___B7 V. Description of the invention (m) The structure of a layer other than the light-scattering planarizing layer 26. (Please read the precautions on the back before filling out this page.) This type of color matte film 2 1 can be used to correct the color characteristics of the color material to ensure the color adhesion of the light scattering flattening layer 26. Therefore, even in a reflective color liquid crystal display device manufactured using a color filter 21 and manufactured in a separate step, a decrease in color characteristics accompanying light scattering is hardly generated. The light-scattering flattening layer 26 is also provided in the color filter 21, so it is not necessary to equip the color filter (observer side) with a front-scattering plate used in a conventional reflective color liquid crystal display device. , High-brightness reflective color liquid crystal display device becomes possible. Furthermore, by providing the light-scattering planarization layer 26 to increase the strength, it becomes easier to control the gap (thickness of the liquid crystal layer) by the spacer. Color filter in the fourth aspect Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Figure 4 is a schematic longitudinal sectional view showing the color filter in the fourth aspect of the present invention. The color filter 3 1 shown in FIG. 4 includes a driving element layer 3 3 provided on a substrate 32, and is sequentially laminated with a reflective electrode layer 34 and a light scattering layer 35 on the driving element layer 33. The colored layer 36, the transparent electrode layer 38, and the colored layer 36 are composed of a red colored pattern 36R, a green colored pattern 3 6 G, and a blue colored pattern 3 6 B. The reflective electrode layer 34 and the transparent electrode layer. 3 8 series pre-conducted to each coloring pattern. 0 substrates constituting the color filter 3 1 3 2 series can use various glass substrates, metal substrates, resin substrates, composite substrates made of two or more materials, etc. , Its thickness is based on the consideration of the use of color filters 31, etc. and this paper size can apply Chinese National Standard (CNS) A4 specifications (210 × 297 mm) -22- 594062 A7 B7 2. Description of the invention (20) It is appropriately set, for example, it can be set to about 0.3 to 10 mm. The driving element layer 3 3 constituting the color filter 31 is made of a thin film transistor (T F T) having a predetermined pattern and electrodes of a source, a gate, and a gate. In addition, the reflective electrode layer 34 is a pixel electrode pre-connected to the drain electrode, and can be formed on the driving element layer 33 through an insulating layer, and is mirror-finished. In the case of a transflective color liquid crystal display device described later, the reflective electrode layer 34 can be formed as a transflective electrode layer or an open-hole electrode layer. The reflective electrode layer 34 is formed of a metal thin film such as aluminum, chromium, gold, silver, copper, or the like, and the thickness can be set to 50,000 to 100,000. A, preferably 100 to 300. 0A range. Such a reflective electrode layer 34 can be formed by a known thin film forming method such as a vapor deposition method, a sputtering method, a C V D method, or an ion implantation method. The light-scattering layer 3 5 constituting the color filter 31 is for appropriately scattering the light that has entered the reflective color liquid crystal display device, and ensuring sufficient visibility to disperse the light-scattering fine particles in the light-transmitting property. Made of resin. Examples of the light-transmitting resin include acrylic resin, epoxy resin, polyvinyl alcohol resin, polyimide resin, vinyl ether resin, and the like, considering the refractive index, and the reflective electrode layer 3 4 Or the adhesion between the colored layers 36 can be used alone or as a mixture of two or more. As for the light-scattering fine particles, those mentioned in (c) above can be used. The content of the microparticles in the light scattering layer 35 is 0.5 to 70% by weight, preferably in a range of 1 · 0 to 50% by weight, and the thickness of the light scattering layer 35 is 0 · 5 to 20 / zm preferably 1 · 0 to 1 〇 / zm。 Degree. (Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -23- 594062 A7 B7 V. Description of the invention (2 彳) Color filter 3 1, and also by using the fine particles used in the light scattering layer 3 5 to make the above-mentioned material, the mist can be set to 1 0 ~ 9 〇, preferably 2 5 ~ 8 0, more preferably 3 0 ~ 7 0 Range, the total light transmittance is 30% or more, and the diffuse light transmittance is 1 · 0 or more. In the method of using a front scattering plate, as the haze becomes larger, although parallax (image blur) can be emphasized, in the present invention, a light scattering layer is included in the color filter, even if it is high haze. Generate parallax. Here, light-scattering fine particles are added to the light-scattering layer 35 to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-scattering fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. Further, in this aspect, the color material used for correcting the color characteristics may have a configuration including layers other than the light scattering layer. The coloring layer 36 can be formed according to the well-known pigment dispersion method, dyeing method, electrograph method, etc., and each coloring pattern (36R, 36G, 36B) can also be a strip type, a mosaic sheet type, a triangular type, The pixel arrangement type is not particularly limited. Such a color filter 3 1 is a reflection-type color liquid crystal that can prevent the adhesion of the color of the light scattering layer 3 5 by using the color characteristic correction of the color material. The display device also hardly produces a reduction in color characteristics. It also has a light-scattering layer 35 in the color filter 21, so the conventional reflective color liquid crystal display device becomes a reflective high-brightness color liquid crystal display device that does not need to be arranged on the front side diffuser of the observer. That becomes possible. Furthermore, by setting the light-scattering layer, the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling this page). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and Industry 594062 A7 B7 V. Description of the invention (...) 22 3 5, can be made into the reflective electrode layer 3 4 and the coloring layer 36 which have relatively low adhesion. Color Filter in Fifth Aspect FIG. 5 is a schematic longitudinal sectional view showing a color filter in a fifth aspect of the present invention. The color filter 4 1 shown in FIG. 5 has a driving element layer 4 3 provided on a substrate 4 2, and a reflective electrode layer 4 4 is sequentially laminated on the driving element layer 4 3. The scattering coloring layer 46, the transparent electrode layer 48, and the light scattering coloring layer 46 are composed of a red coloring pattern 46R, a green coloring pattern 46G, and a blue coloring pattern 46B. The driving element layer 4 3, the reflective electrode layer 4 4, and the transparent electrode layer 4 8 constituting the substrate 4 2 of the above-mentioned color filter 41 are connected to the substrate 3 2 and the driving element layer 3 of the color filter 31 described above. 3, the reflective electrode layer 34, and the transparent electrode layer 38 are the same, and the description is omitted here. The light-scattering coloring layer 46 constituting the color filter 41 has the same function as a coloring layer of a conventional reflective color liquid crystal display device, and at the same time, appropriately diffuses light that has entered the reflective liquid crystal device. And make sure they are sufficiently recognizable. This light-scattering colored layer 46 is one in which the light-scattering fine particles are dispersed in a coloring layer formed by a known pigment dispersion method, dyeing method, or electric writing method. As the light-scattering fine particles, the fine particles listed in (c) above can be used. The content of the fine particles in the light-scattering coloring layer 46 is 0.5 to 70% by weight, preferably in the range of 1.0 to 50% by weight. ^ The paper size applies the Chinese National Standard (CNS) A4 specification (210X297). Li) (Please read the notes on the back before filling this page)

-25- 594062 A7 ____B7_ 五、發明説明(23) 光散射性著色層46之厚度爲〇 . 5〜15//m,宜爲 0 . 5〜10#m之範圍。 (請先閱讀背面之注意事項再填寫本頁) 於此彩色濾光片4 1 ,藉由將光散射性著色層4 6所 用的微粒子設成上述的材料,可將曇霧値設成1 0〜9 0 ,宜爲2 5〜80,較宜爲3 0〜70之範圍,全部光線 透過率設成3 0 %以上,擴散光線透過率設成1 0 %以上 。且在採用前方散射板之方式,隨著曇霧値變大,雖可強 調視差(影像模糊),惟在本發明以於彩色濾光片內含有 光散射層,即使爲高暴霧亦不生成視差。 在此,於光散射性著色層4 6內,加入光散射性微粒 子,使再含有供補正色特性用之色材。由而,可有效的防 止由添加光散射性微粒子引起的著色。至於供補正色特性 而用的色材,可採用前述(d )所舉者。 且於本態樣,係補正色特性而用的色材,亦可爲使含 於光散射性著色層以外的層之構成。 經濟部智慧財產局員工消費合作社印製 且,光散射性著色層46之各著色圖型(46R, 46G,46B)亦可爲條帶型,鑲嵌片型,二角型,四 像元配置型等,並未予特別限制。 此種彩色濾光片4 1 ,係可利用色材於光散射性著色 層4 6之製造階段的色特性補正可確實防止使光散射性微 粒子分散的光散射性著色層之色特性的劣化,且利用微粒 子含有量之調整對各色微妙的控制光散射程度一事即成爲 可能的。因此使用彩色濾光片4 1並於以另外步驟製造的 反射型彩色液晶顯示裝置,亦幾乎不生成伴隨光散射引起 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -26- 594062 A7 B7 五、發明説明(24) (請先閲讀背面之注意事項再填寫本頁) 的色特性之降低。又於彩色濾光片4 1內具有光散射性著 色層4 6,故於習用的反射型彩色液晶顯示裝置即成爲不 需配設於觀測者側之前方散射板’高亮度之反射型彩色液 晶顯示裝置即成爲可能。 第六態樣之彩色濾光片 第6圖係表示本發明之第六態樣之彩色濾光片之槪略 縱截面圖。第6圖所示的彩色濾光片5 1係具有設於基板 5 2上的驅動元件層5 3,依序經予層合於此驅動元件層 5 3上的反射電極層5 4,著色層5 6,光散射性平坦化 層5 7及透明電極層5 8,著色層係由紅色著色圖型 56R,綠色著色圖型56G及藍色著色圖型56B所構 成的。 經濟部智慧財產局員工消費合作社印製 構成上述彩色濾光片5 1之基板5 2,驅動元件層 5 3,反射電極層5 4,著色層5 6及透明電極層5 8係 與於上述的彩色濾光片3 1之基板3 2,驅動元件層3 3 ,反射電極層3 4,著色層3 6及透明電極層相同,在此 省略說明。 構成彩色濾光片5 1之光散射性平坦化層5 7,係減 少著色層5 6之表面的微小的凹凸,並使液晶層之厚度呈 均勻狀,同時使已入射於反射型彩色液晶顯示裝置之光生 成適度的散射,並確保足夠的辨識性者。 此光散射性平坦化層5 7係使光散射性微粒子分散於 例如丙烯酸酯系樹脂,環氧系樹脂,乙烯基醚系樹脂,聚 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 一 -27- 594062 A7 ___ B7_ 五、發明説明(%) Ζο (請先閲讀背面之注意事項再填寫本頁) 醯亞胺系樹脂,丙烯系樹脂等樹脂中者。至於光散射性微 粒子,可使用上述(C )舉出的微粒子。微粒子於光散射 性平坦化層5 7之含有量爲0 . 5〜7 0重量%,宜爲 1 · 0〜5 0重量%之範圍,光散射性平坦化層5 7之厚 度爲0 . 5〜20//m,宜爲1 . 〇〜l〇//m程度。 於此彩色濾光片5 1 ,藉由將光散射性平坦化層5 7 所用的微粒子設成上述的材料,可將曇霧値設成1 0〜 9〇,宜爲25〜80 ,較宜爲30〜70之範圍,全部 光線透過率設成1 0 %以上。且在採用前方散射板之方式 ,隨著曇霧値變大,雖可強調視差(影像模糊),惟在本 發明以於彩色濾光片內含有光散射層,即使爲高曇霧亦不 生成視差。 在此,於光散射性平坦化層5 7內,加入光散射性微 粒子,使再含有供補正色特性用之色材。由而,可有效的 防止由添加光散射性微粒子引起的著色。至於供補正色特 性而用的色材,可採用前述(d )所舉者。 經濟部智慧財產局員工消費合作社印製 且於本態樣,依補正色特性而用的色材,亦可爲使含 於光散射性平坦化層5 7以外的層之構成。 此種彩色瀘光片5 1係可利用色材之色特性補正可確 實的防止光散射性平坦化層5 7之顏色附著,於已使用彩 色濾光片5 1之反射型彩色液晶顯示裝置方面不致生成隨 著光散射之色特性引起的降低。又於彩色濾光片5 1內具 有光散射性平坦化層5 7,故在習用的反射型彩色液晶顯 示裝置即成爲不需配設於觀測者側之前方散射板,高亮度 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -28- 594062 經濟部智慧財產局員工消費合作社印製 A7 ___ B7_五、發明説明( 26 之反射型彩色液晶顯示裝置即成爲可能。再者,藉由設置 光散射性平坦化層5 7引起的強度提高,可使由間隔件引 起的間隙(液晶層之厚度)控制即成爲較容易的。 第7〜第1 2之態樣的彩色濾光片 下示的本發明之第7〜第1 2態樣之彩色濾光片,係 於彩色濾光片內的二層內含有光散射性微粒子而成的態樣 。如此藉由使分成二層而含有光散射性微粒子,可減少每 一層之光散射性微粒子之量,即使降低各層的曇霧値,亦 可保持彩色瀘光片全體之曇霧値,故可將各層予以薄膜化 ,較使光散射性微粒子含於一層的情形,亦成可容易控制 膜厚。又此等的第7〜第1 2之態樣,供補正色特性而用 的色材,係作成與光散射性微粒子與二層同時含有的構成 亦可,惟與光散射性微粒子同時,或與光散射性微粒子另 外僅使含有一層的構成亦可。 此等態樣之中,由第7〜第9態樣之彩色瀘光片,在 反射型彩色液晶顯示裝置內,對液晶層經予配設於觀測者 側的型式之彩色濾光片。又由第1 0〜第1 2態樣之彩色 濾光片,在反射型彩色液晶顯示裝置內’對液晶層經予配 設於觀測者側及相對側的型式之彩色濾光片。 第7態樣之彩色濾光片 本態樣之彩色濾光片係於第1圖所示的前述第一態樣 之彩色濾光片,不僅光散射層3,亦於著色層4內使含有 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) -29- 594062 A7 __B7 五、發明説明(27) (請先閲讀背面之注意事項再填寫本頁) 光散射性微粒子者。亦即,本態樣之彩色濾光片係成爲以 第二態樣之光散射性著色層1 2取代第一態樣之著色層4 的構成。因此,本態樣所用的光散射性微粒子係與第二態 樣所用的微粒子者相同。且於本態樣使含於光散射層及光 散射性著色層之光散射性微粒子,若予分配成二層至結果 可得最適的曇霧値時即可,於各層之含有量並未予特別限 定。 於本態樣,光散射性微粒子係使含有各著色圖型( 4R,4G,4B)之中至少一色的著色圖型時即可,使 含有量依各色而變化亦可。由而,於未能均勻的獲得曇霧 値時,具有可微調整的優點至曇霧値可得均等般的優點。 又光散射性微粒子亦可含於著色圖型之全色係理所當然的 第八態樣之彩色濾光片 經濟部智慧財產局員工消費合作社印製 本態樣之彩色濾光片係於第3圖所示的前述第三態樣 之彩色濾光片,不僅光散射性平坦化層2 6,亦於著色層 4內使含有光散射性微粒子者。亦即,本態樣之彩色濾光 片係成爲以弟一*悲樣之光散射性者色層1 4取代第三態樣 之著色層2 4的構成。因此,本態樣所用的光散射性微粒 子係與第二態樣所用的微粒子者相同。且於本態樣使含於 光散射層及光散射性著色層之光散射性微粒子,若予以分 配成二層至結果可得最適的曇霧値時即可,於各層之含有 量並未予特別限定。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -30- 594062 Α7 Β7 五、發明説明(28) (請先閱讀背面之注意事項再填寫本頁) 於本態樣,光散射性微粒子係使含有各著色圖型( 24R,24G,24B)之中至少一色的著色圖型時即 可,使含有量依各色而變化亦可。由而,於未能均勻的獲 得曇霧値時,具有可微調整的優點至曇霧値可得均等般。 又光散射性微粒子亦可含於著色圖型之全色係理所當然的 第九態樣之彩色濾光片 本態樣之彩色濾光片係於第1圖所示的前述第一態樣 之彩色濾光片,不僅光散射層3,亦於著色層4及透明電 極層5之間設有與前述的第三態樣之光散射性平坦化層 2 6相同的層者。由而,利用光散射層3,可將透明基板 2及著色層4間之附著性作成較高者,藉由光散射性平坦 化層2 6 ,有所謂可得降低著色層4之表面的凹凸且可得 平坦面之優點。且於本態樣使含於光散射層及光散射性平 坦化層的光散射性微粒子,若予以分配成二層至結果可得 最適的曇霧値時即可,於各層之含有量並未予特別限定。 經濟部智慧財產局員工消費合作社印製 第十態樣之彩色濾光片 本態樣之彩色濾光片係於第4圖所示的前述第四態樣 之彩色濾光片,不僅光散射層3 5,亦於著色層3 6內使 含有光散射性微粒子者。亦即,本態樣之彩色濾光片係成 爲以第五態樣之光散射性著色層4 6取代第四態樣之著色 層3 6的構成。因此,本態樣所用的光散射性微粒子係與 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ297公釐) 一 一 -31 - 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(29) 於第五態樣所用的微粒子者相同。且於本態樣使含於光散 射層及著色層之光散射性微粒子,若予分配成二層即可, 於各層之含有量並未予特別限定。 於本態樣,光散射性微粒子係使含有各著色圖型( 36R’ 36G,36B)之中至少一色的著色圖型時即 可,使含有量依各色而變化亦可。由而,於未能均勻的獲 得曇霧値時,具有可微調整的優點至曇霧値可得均等般的 優點。又光散射性微粒子亦可含於著色圖型之全色後理所 當然的。 第十一態樣之彩色濾光片 本態樣之彩色爐光片係於弟6圖所不的則述第六態樣 之彩色濾光片,不僅光散射性平坦化層5 7,亦於著色層 5 6內使含有光散射性微粒子者。亦即,本態樣之彩色濾 光片係成爲以第五態樣〜光散射性著色層4 6取代第六態 樣之著色層5 6的構成。因此,本態樣所用的光散射性微 粒子係與於第五態樣所用的微粒子者相同。且於本態樣使 含於光散射層反著色層之光散射性微粒子,若予分配成二 層即可,於各層之含有量並未予特別限定。 於本態樣,光散射性微粒子係使含有各著色圖型( 56R,56G,56B)之中至少一色的著色圖型時即 可,使含有量依各色而變化亦可。由而,於未能均勻的獲 得曇霧値時,具有可微調整的優點至曇霧値可得均等般的 優點。又光散射性微粒子亦可含於著色圖型之全色後理所 (請先閲讀背面之注意事項再填寫本頁} 、可-25- 594062 A7 ____B7_ V. Description of the Invention (23) The thickness of the light-scattering colored layer 46 is 0.5 to 15 // m, preferably in the range of 0.5 to 10 # m. (Please read the precautions on the back before filling in this page.) Here, the color filter 4 1 can be set to 1 0 by setting the fine particles used in the light-scattering coloring layer 4 6 to the above materials. ~ 9 0, preferably from 25 to 80, more preferably from 30 to 70, the total light transmittance is set to 30% or more, and the diffuse light transmittance is set to 10% or more. In addition, in the method of using a front scattering plate, as the haze becomes larger, although parallax (image blur) can be emphasized, in the present invention, the color filter contains a light scattering layer, which does not generate even a high storm fog. Parallax. Here, light-scattering fine particles are added to the light-scattering colored layer 46 to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-scattering fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. Further, in this aspect, the color material used for correcting the color characteristics may be constituted by a layer other than the light-scattering colored layer. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and each coloring pattern (46R, 46G, 46B) of the light-scattering coloring layer 46 can also be a strip type, a mosaic type, a two-corner type, or a four-pixel configuration type. There are no particular restrictions. Such a color filter 4 1 is capable of correcting the color characteristics of the light-scattering coloring layer 46 at the manufacturing stage of the color material by using a color material, and can surely prevent the color characteristics of the light-scattering coloring layer from dispersing the light-scattering fine particles. In addition, it is possible to finely control the degree of light scattering of each color by adjusting the content of fine particles. Therefore, the reflection-type color liquid crystal display device manufactured using the color filter 41 and produced in a separate step hardly generates the paper standard that is accompanied by light scattering and is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -26- 594062 A7 B7 V. Description of the invention (24) (Please read the precautions on the back before filling this page). In addition, a light-scattering colored layer 46 is provided in the color filter 41, so the conventional reflection-type color liquid crystal display device becomes a high-brightness reflection-type color liquid crystal which does not need to be arranged on the front side scattering plate of the observer. The display device becomes possible. Color Filter in a Sixth Aspect FIG. 6 is a schematic longitudinal sectional view showing a color filter in a sixth aspect of the present invention. The color filter 51 shown in FIG. 6 has a driving element layer 53 provided on the substrate 52, and a reflective electrode layer 54 and a colored layer are sequentially laminated on the driving element layer 53 in this order. 5 6. The light-scattering planarization layer 57 and the transparent electrode layer 58. The colored layer is composed of a red colored pattern 56R, a green colored pattern 56G, and a blue colored pattern 56B. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the substrate 5 2, the driving element layer 5 3, the reflective electrode layer 5 4, the coloring layer 5 6 and the transparent electrode layer 5 8 constituting the above-mentioned color filter 51. The substrate 32 of the color filter 31, the driving element layer 33, the reflective electrode layer 34, the coloring layer 36, and the transparent electrode layer are the same, and description thereof is omitted here. The light-scattering flattening layer 57 constituting the color filter 51 is to reduce the minute unevenness on the surface of the coloring layer 56, to make the thickness of the liquid crystal layer uniform, and to make it incident on the reflective color liquid crystal display. The light from the device generates moderate scattering and ensures adequate discrimination. This light-scattering flattening layer 5 7 disperses the light-scattering fine particles in, for example, acrylic resin, epoxy resin, vinyl ether resin, and the size of the paper is applicable to Chinese National Standard (CNS) A4 (210X297). 1) -27- 594062 A7 ___ B7_ 5. Description of the invention (%) ZO (please read the notes on the back before filling out this page) 者 Among the resins such as imine resin and acrylic resin. As the light-scattering fine particles, the fine particles listed in (C) above can be used. The content of the fine particles in the light-scattering planarizing layer 57 is 0.5 to 70% by weight, preferably in the range of 1.0 to 50% by weight. The thickness of the light-scattering planarizing layer 57 is 0.5. ~ 20 // m, preferably about 1.0 to 10 // m. Here, by setting the fine particles used for the light-scattering planarization layer 5 7 to the above-mentioned material, the mist can be set to 10 to 90, preferably 25 to 80, and more preferably The range is 30 to 70, and the total light transmittance is set to 10% or more. In addition, in the method of using a front scattering plate, as the haze becomes larger, although the parallax (image blur) can be emphasized, the color filter in the present invention contains a light scattering layer, which does not generate even a high haze. Parallax. Here, light-scattering fine particles are added to the light-scattering flattening layer 57 to further contain a coloring material for correcting color characteristics. As a result, the coloring caused by the addition of light-scattering fine particles can be effectively prevented. As for the color material for correcting the color characteristics, those mentioned in (d) above can be used. The color material printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and used in the present state to supplement the color correction characteristics may also be a layer other than the light-scattering flattening layer 5 7. This type of color phosphor 51 can use the correction of the color characteristics of the color material to reliably prevent the color adhesion of the light-scattering flattening layer 57, and it is used in the reflective color liquid crystal display device using the color filter 51. No reduction in color characteristics due to light scattering is generated. It also has a light-scattering flattening layer 5 7 in the color filter 51. Therefore, the conventional reflective color liquid crystal display device does not need to be arranged on the front side scattering plate on the observer side. China National Standard (CNS) A4 specification (210X297 mm) -28- 594062 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ___ B7_ V. Description of the invention (26 reflective color liquid crystal display device becomes possible. By increasing the intensity caused by providing the light-scattering planarization layer 57, it is easier to control the gap (thickness of the liquid crystal layer) caused by the spacer. The color filters of the seventh to twelfth aspects The color filter of the seventh to twelfth aspects of the present invention shown below the light sheet is a state in which light-scattering fine particles are contained in two layers in the color filter. In this way, it is divided into two The layer contains light-scattering fine particles, which can reduce the amount of light-scattering fine particles in each layer. Even if the haze of each layer is reduced, the haze of the entire color film can be maintained. Therefore, each layer can be thinned. Scatter light When the microparticles are contained in one layer, the film thickness can be easily controlled. In the seventh to twelfth aspects, the color material for correcting the color characteristics is made simultaneously with the light-scattering microparticles and the two layers. The composition may be included, but it may be a composition containing only one layer at the same time as the light-scattering microparticles or the light-scattering microparticles. Among these aspects, the 7th to 9th aspects of the color phosphor film are possible. In the reflection type color liquid crystal display device, the liquid crystal layer is provided with a color filter of a type arranged on the observer side. The color filters of the 10th to 12th aspects are also used in the reflection type color. In the liquid crystal display device, a color filter of the type in which the liquid crystal layer is arranged on the observer side and the opposite side is provided. The color filter of the seventh aspect The color filter of this aspect is shown in FIG. The aforementioned first aspect of the color filter is contained not only in the light-scattering layer 3 but also in the coloring layer 4 (please read the precautions on the back before filling this page) The paper size applies to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) -29- 594062 A7 __B7 V. Invention Ming (27) (Please read the precautions on the back before filling in this page) Those who have light-scattering particles. That is, the color filter in this aspect has become the light-scattering colored layer 12 in the second aspect in place of the first. The constitution of the colored layer 4 in one aspect. Therefore, the light-scattering microparticles used in this aspect are the same as those used in the second aspect. In this aspect, the light contained in the light-scattering layer and the light-scattering colored layer is used. The scattering fine particles may be divided into two layers until the optimum fogging result is obtained, and the content of each layer is not particularly limited. In this aspect, the light scattering fine particles contain each coloring pattern ( 4R, 4G, 4B) is only necessary for the coloring pattern of at least one color, and the content may be changed according to each color. Therefore, when the haze can not be obtained uniformly, it has the advantage of being finely adjustable to the same advantage as the haze. The light-scattering fine particles can also be included in the full-color system of the coloring pattern. The eighth aspect of the color filter is printed by the employee property cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The color filter of the third aspect shown above includes not only the light-scattering flattening layer 26 but also the light-scattering fine particles in the colored layer 4. That is, the color filter of this aspect has a constitution in which the color scattering layer 14 of the third aspect is replaced with the light scattering layer 14 of the third aspect. Therefore, the light-scattering microparticles used in this aspect are the same as those used in the second aspect. In this state, the light-scattering microparticles contained in the light-scattering layer and the light-scattering coloring layer may be divided into two layers so that the optimal fog can be obtained. The content of each layer is not particularly limited. limited. This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -30- 594062 Α7 Β7 V. Description of the invention (28) (Please read the precautions on the back before filling this page) In this state, the light scattering property The fine particle system may be a coloring pattern containing at least one of the colored patterns (24R, 24G, 24B), and the content may be changed depending on each color. Therefore, when the haze can not be obtained uniformly, it has the advantage of being able to be finely adjusted until the haze can be obtained uniformly. The light-scattering particles can also be included in the color filter of the ninth aspect, which is taken for granted in the full color system of the coloring pattern. The color filter in this aspect is the color filter in the first aspect shown in FIG. 1. In the light sheet, not only the light scattering layer 3 but also the same layer as the light scattering flattening layer 26 of the third aspect described above is provided between the colored layer 4 and the transparent electrode layer 5. Therefore, by using the light scattering layer 3, the adhesion between the transparent substrate 2 and the colored layer 4 can be made higher, and the light scattering flattening layer 2 6 can reduce the unevenness on the surface of the colored layer 4. And the advantage of a flat surface can be obtained. In this state, the light-scattering microparticles contained in the light-scattering layer and the light-scattering flattening layer can be divided into two layers so that the optimal fog can be obtained. The content of each layer is not changed. Specially limited. The tenth aspect of the color filter printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The color filter of this aspect is the color filter of the fourth aspect shown in FIG. 4, not only the light scattering layer 3 5, and those containing light-scattering fine particles in the colored layer 36. That is, the color filter of this aspect has a structure in which the light-scattering colored layer 46 of the fifth aspect replaces the coloring layer 36 of the fourth aspect. Therefore, the light-scattering microparticles used in this aspect and the paper size are applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) -31-594062 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Note (29) The particles used in the fifth aspect are the same. In this aspect, the light-scattering microparticles contained in the light-scattering layer and the coloring layer may be divided into two layers, and the content in each layer is not particularly limited. In this aspect, the light-scattering fine particle system may include a coloring pattern containing at least one of the coloring patterns (36R '36G, 36B), and the content may be changed depending on each color. Therefore, when the haze can not be obtained uniformly, it has the advantage of being finely adjustable to the same advantage as the haze. It is a matter of course that the light-scattering fine particles may be included in the full color of the coloring pattern. The color filter of the eleventh aspect The color furnace light of this aspect is the color filter of the sixth aspect, which is not described in the sixth figure. It is not only the light scattering flattening layer 5 7 but also the coloring. The layer 56 contains a light-scattering fine particle. That is, the color filter of this aspect has a configuration in which the coloring layer 56 of the sixth aspect is replaced with the light-scattering colored layer 46 of the fifth aspect. Therefore, the light-scattering microparticles used in this aspect are the same as those used in the fifth aspect. In this aspect, the light-scattering microparticles contained in the anti-coloring layer of the light-scattering layer may be divided into two layers, and the content in each layer is not particularly limited. In this aspect, the light-scattering fine particle system may include a coloring pattern containing at least one color of each coloring pattern (56R, 56G, 56B), and the content may vary depending on each color. Therefore, when the haze can not be obtained uniformly, it has the advantage of being finely adjustable to the same advantage as the haze. Light scattering particles can also be included in the full color of the coloring pattern (please read the precautions on the back before filling in this page).

本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -32- 594062 A7 B7 五、發明説明(3〇) 當然的。 (請先閲讀背面之注意事項再填寫本頁) 第十二態樣之彩色濾光片 本態樣之彩色濾光片係於第4圖所示的前述第四態樣 之彩色濾光片,不僅光散射層3 5,亦於著色層3 6及透 明電極層3 8之間.,設有與前述第六態樣之光散射性平坦 化層5 7相同的層者。由而,利用光散射層3 5,可將透 明基板3 2及著色層3 6間之附著性作成較高者,藉由光 散射性平坦化層2 6,有所謂可得降低著色層3 6之表面 的凹凸且可得平坦面之優點。且於本態樣使含於光散射層 及光散射性平坦化層的光散射性微粒子,若予以分配成二 層至結果可得最適的曇霧値時即可,於各層之含有量並未 予特別限定。 反射型彩色液晶顯示裝置 其次舉出已採用本發明之彩色濾光片的反射型彩色液 晶顯示裝置之例。 經濟部智慧財產局員工消費合作社印製 第7圖爲表示已採用第1圖所示的本發明之彩色濾光 片的反射型彩色液晶顯示裝置之槪略縱截面圖。於第7圖 ,反射型彩色液晶顯示裝置6 1係於觀測者側配設本發明 之彩色濾光片1,於此彩色濾光片1之透明基板2上具有 位相差板6 2及偏光板6 3,在與基板6 5上經予形成驅 動元件層6 6,反射電極層6 7之對向電極基板與上述彩 色濾光片1之間形成有液晶層6 8者。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -33 - 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(31) 又,第8圖係表示已採用第5圖所示的本發明之彩色 濾光片4 1的反射型彩色液晶顯示裝置之槪略縱截面圖。 於第8圖,反射型彩色液晶顯示裝置7 1係於透明基板 7 2之一面上具有透明電極層7 3,於另一面上介由指定 的間隙使具有位相差板7 4及偏光板7 5之對向基板與本 發明之彩色濾光片4 1對向配合,於間隙部形成液晶層 7 8者。在此反射型彩色液晶顯示裝置7 1 ,本發明之彩 色濾光片4 1係介由液晶層7 8並位於與觀測者側相對側 上。 本發明之彩色濾光片係除上述的反射型彩色液晶顯示 裝置外,亦可使用於半透過型彩色液晶顯示裝置上。 半透過型彩色液晶顯示裝置係經予開發成兼具透過型 及反射型的各彩色液晶藏不裝置之長處者,於一*個像兀之 中’形成透過顯不部分及反射顯不部分,具有使向只顯示 原理之不同的液晶顯示模式之透過/反射之液晶顯示模式 呈對立的顯示模式者。 以第7圖所示的構造製作半透過型彩色液晶顯示裝置 時,以上述的本發明之彩色濾光片3 1 ,4 1 ,5 1之各 反射電極層3 4,44,5 4作爲半鏡型之電極層或開孔 型之電極層。半鏡型電極層係使導電性薄膜本身具有使部 分光線透過而將其餘反射的半透過特性者,藉由控制蒸鍍 法,濺鍍法,C V D法,離子植入法等公知的成膜製程, 可予形成。又開孔型電極層係將一個像元呈面積性的分成 透過部(開孔部)及反射部者,藉由上述的成膜方法形成 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁) -34- 594062 A7 B7 五、發明説明(32) 金屬薄膜後,將此予以佈配成圖型後設置指定的微細開口 予以形成。 (請先閲讀背面之注意事項再填寫本頁) 實施例 以下舉出實施例再詳細說明本發明。 實施例A 1 準備厚度0 · 7 m m之玻璃基板(無鹼玻璃)作爲基 板。於此玻璃基板上利用旋塗法塗布下述組成之光散射層 用塗佈液並使乾燥,其後進行曝光,顯影,後烘烤( 200 °C,30分鐘)並形成光散射層(厚度l〇//m) 光散射層用塗布液 •環氧基丙烯酸酯 35重量分 (東亞合成化學公司製造;EF450) •多官能丙烯酸酯單體 15重量分 經濟部智慧財產局員工消費合作社印製 (曰本化藥(股)製造;D Ρ Η A ) •三聚氰胺珠粒(平均粒徑0 . 7//m) 1 0重量分 •聚合引發劑 4重量分 (Ciba Geigy 公司製造的 Irgacure 184) •稀釋溶劑 3 6重量分 (丙二醇單乙基乙酯) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -35- 594062 A7 B7 五、發明説明(33) (請先閲讀背面之注意事項再填寫本頁) 其次利用旋塗法塗布光著色圖型用之感光性著色材料 (富片軟片Orlin股份有限公司製造的Color Mosaic CR-7 000 )於光散射層上,介由指定的光罩並使塗膜曝光,其 後採用顯影液(富士軟片Orlin股份有限公司製造的C D ) 並予顯影,保持玻璃基板於2 0 0 °C 3 0分鐘並使著色 層硬化而形成紅色的著色圖型。 同法,使用綠色著色圖型用之感光性著色材料(富士 軟片Orlin (股)製造的Clor mosaic CG-7000 )及藍色著色 圖型用感光性著色材料(富士軟片Orlin (股)製造的 Color Mosaic CG-7000 ),與上述同法形成綠色的著色圖型 ,藍色的著色圖型並成爲著色層。 其次,於上述的著色層上依常用方法形成透明電極( I T 0 )層,於此透明電極層上形成聚醯亞胺樹脂之定向 膜(厚度0.05//m),而得第1圖所示的構造之彩色 瀘光片(實施例A 1 )。 經濟部智慧財產局員工消費合作社印製 在此,於上述光散射層用塗布液內,藉由添加供補正 色特性而用的色材,防止伴隨光散射性微粒子之添加的色 特性之劣化,可賦與彩色濾光片優越的色特性。 實施例A 2 準備厚度0 . 7 m m之玻璃基板(無鹼玻璃)作爲基 板。於此玻璃基板上利用旋塗法塗布使於紅色著色圖型用 之感光性著色材料(富士軟片Orlin (股)製造的Color Mosaic CR-7000 )內含有光散射性微粒子之平均粒徑 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -36- 594062 A7 B7 五、發明説明(34) (請先閲讀背面之注意事項再填寫本頁) 0 . 7//m之三聚氰胺珠粒2 7重量%之塗布液,介由指 定的光罩使塗布膜曝光,其後採用顯影液(富士軟片Orlin (股)製造的C D )並予顯影,將玻璃基板保持於 2 0 0 °C 3 0分鐘並使著色層硬化,形成紅色的著色圖 型。 同樣的使用旋塗法塗布使於綠色著色圖型用之感光性 著色材料(富士軟片Orlin (股)製造的Color Mosaic CG-7000 )內含有平均粒徑〇 . 7 //m之三聚氰胺珠粒2 7重 量%之塗布液及於藍色著色圖型用之感光性著色材料(富 士軟片Orlin (股)製造的Color Mosaic CB-7000 )內含有粒 徑0 . 7 //m之三聚氰胺珠粒2 7重量%之塗布液,與上 述同法形成綠色之著色圖型,藍色之著色圖型,作爲光散 射性著色層。 其次,以與實施例A 1同法形成透明電極(I T〇) 層,定向膜,而得如第2圖所示構造之彩色濾光片(實施 例 A 2 )。 經濟部智慧財產局員工消費合作社印製 在此,於上述三種光散射性著色層用塗布液內,藉由 添加供補正色特性而用的色材,防止伴隨光散射性微粒子 之添加的色特性之劣化,可賦與彩色濾光片優越的色特性 實施例A 3 準備厚度〇 . 7 m m之玻璃基板(無鹼玻璃)作爲基 板,於此玻璃基板上與實施例A 1同法而形成著色層。 本紙張尺度逍用中國國家標準(CNS ) A4規格(210 X297公釐) -37- 594062 A7 _B7_ 五、發明説明(35) (請先閲讀背面之注意事項再填寫本頁) 其次於著色層上藉由旋塗法塗布下述組成之光散射性 平坦化層用塗布液並使乾燥,其後進行曝光,顯影,後烘 烤(2 0 0 °C,3 0分鐘),而形成光散射性平坦化層( 厚度 1 0 // m )。 光散射性平坦化層用塗布液 •環氧基丙烯酸酯 35重量分 (東亞合成化學公司製造;E A4 5 0 ) •多官能丙烯酸酯單體 15重量分 (日本化藥(股)製造;DPHA) •三聚氰胺珠粒(平均粒徑0 . 7//m) 10重量分 •聚合引發劑 4重量分 (Ciba Geigy 公司製造的 Irgacure 184) •稀釋溶劑 3 6重量分 (丙二醇單乙基乙酯) 經濟部智慧財產局員工消費合作社印製 其次以與實施例A 1同法於光散射性平坦化層上形成 透明電極(I T〇)膜,定向膜,而得第3圖所示的構造 之彩色濾光片(實施例A 3 )。 在此,於上述光散射層用塗布液內,藉由添加供補正 色特性而用的色材,防止伴隨光散射性微粒子之添加的色 特性之劣化,可賦與彩色濾光片優越的色特性。 於上述製作的各彩色濾光片(實施例A . 1〜A 3 )之 玻璃基板上層合位相差板及偏光板。又於厚度〇 . 7 m m 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -38- 594062 A7 B7 五、發明説明(36) (請先閲讀背面之注意事項再填寫本頁) 之玻璃基板上形成由T F T驅動元件層及鋁而成的反射電 極層,再形成聚醯亞胺樹脂之定向膜(厚度〇 . 〇 5 //m )作爲對向電極基板,使此對向電極基板及彩色濾光片之 各定向膜對向,設置向列性液晶層(厚度5 · 0 // m )而 製作反射型彩色液晶顯示裝置。 實施例A 4 準備厚度0 · 7 m m之玻璃基板(無鹼玻璃)作爲基 板,於此玻璃基板上形成由T F T驅動元件層及鋁而成的 反射電極層。其次於反射電極層上藉由旋塗法塗布與實施 例A 1相同組成之光散射層用塗布液並使乾燥,其後進行 曝光,顯影,後烘烤(2 0 0 °C,3 0分鐘)並形成光散 射層(厚度8 · 0//m)。 其次於光散射層上與實施例A 1同法形成著色層。 其次於著色層上形成透明電極(I T ◦)層,再者形 成聚醯亞胺樹脂之定向膜(厚度0.05/zm),而得第 4圖所示的構造之彩色濾光片(實施例A 4 ) ° 經濟部智慧財產局員工消費合作社印製 在此,於上述三種光散射性著色層用塗布液內,藉由 添加供補正色特性而用的色材,防止伴隨光散射性微粒子 之添加的色特性之劣化,可賦與彩色濾光片優越的色特性 實施例A 5 準備厚度〇 · 7 m m之玻璃基板(無鹼玻璃)作爲基 -39 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 594062 A7 B7 ___ 五、發明説明(37) 板。於此玻璃基板上形成由T F T驅動元件層及鋁而成的 反射電極層。 (請先閲讀背面之注意事項再填寫本頁) 其次於反射電極層上藉由旋塗法塗布使於紅色著色圖 型用之感光性著色材料(富士軟片Orlin (股)製造的 Color Mosaic CR-7000 )內含有光散射性微粒子之平均粒徑 0 . 7//m之三聚氰胺珠粒2 7重量%之塗布液,介由指 定的光罩使塗布膜曝光,其後採用顯影液(富士軟片Orlin (股)製造的C D )並予顯影,將玻璃基板保持於 2 0 0 °C 3 0分鐘並使著色層硬化,形成紅色的著色圖 型。 經濟部智慧財產局員工消費合作社印製 同樣的使用旋塗法塗布使於綠色著色圖型用之感光性 著色材料(富士軟片Orlin (股)製造的Color Mosaic〔Ον 000 ) 內 含有平均粒徑 〇. 7 //m 之三聚氰 胺珠粒 2 7 重 量%之塗布液及於藍色著色圖型用之感光性著色材料(富 士軟片Orlin (股)製造的Color Mosaic CB-7000)內含有平 均粒徑0 . 7 // m之三聚氰胺珠粒2 7重量%之塗布液, 與上述同法形成形成綠色之著色圖型,藍色之著色圖型, 作爲光散射性著色層。 其次以與實施例A 4同法於光散射性著色層上形成透 明電極層,再形成定向膜,而得如第5圖所示構造之彩色 濾光片(實施例A 5 )。 在此,於上述三種光散射性著色層用塗布液內,藉由 添加供補正色特性而用的色材,防止伴隨光散射性微粒子 之添加的色特性之劣化,可賦與彩色濾光片優越的色特性 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -40- 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(38) 實施例A 6 準備厚度〇 . 7mm之玻璃基板(無鹼玻璃)作爲基 板,於此玻璃基板上形成由T F T驅動元件層及鋁而成的 反射電極層。 其次於反射電極層上與實施例A 1同法形成著色層。 其次於著色層上藉由旋塗法塗布與實施例A 3相同組 成之光散射性平坦化層用塗布液並使乾燥,其後進行曝光 ,顯影,後烘烤(2 0 0 °C ’ 3 0分鐘)並形成光散射性 平坦化層(厚度8 . 0//m)。 其次於光散射性平坦化層上與實施例A 4同法形成透 明電極層,再者形成定向膜,而得如第6圖所示的構造之 彩色濾光片(實施例A 6 )。 在此,於上述光散射性平坦化層用塗布液內,藉由添 加供補正色特性而用的色材,防止伴隨光散射性微粒子之 添加的色特性之劣化,可賦與彩色濾光片優越的色特性。 因此於厚度0 · 7 m m之玻璃基板之一面上形成透明 電極(I TO)層,再者形成聚醯亞胺樹脂之定向膜(厚 度0 . 0 5 #m),於玻璃基板之另一面上層合以位相差 板及偏光板並形成對向基板。使此對向基板與上述製作的 各彩色濾光片(實施例A4〜A6 )之定向膜對向,設置 向列形液晶層(厚度5 · 0 # m )並製作反射型彩色液晶 顯示裝置。 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -41 - 594062 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(39) 比較例A 1 除不設置光散射層外,餘以與實施例A 1同法製作彩 色濾光片。因此於此彩色濾光片(比較例)之玻璃基板上 層合以已內藏有位相差板及前方散射層之偏光板(日東電 工(股)製造的AGS I )。又於厚度0 · 7mm之玻璃 基板上形成由T F T驅動元件層,鋁而成的反射電極層’ 再者形成聚醯亞胺樹脂之定向膜(厚度〇 . 〇 5 // m )作 爲對向電極基板,使此對向電極基板之定向膜及彩色濾光 片之定向膜對向,設置向列性液晶層(厚度5 · 0 // m ) 並製作反射型彩色液晶顯示裝置。 如上述般以下述方法測定各自採用本發明之彩色濾光 片(實施例A 1〜A 6 )及比較彩色濾光片(比較例A 1 )的各反射型彩色液晶顯示裝置之顯示影像的亮度,結果 示於下表1。 亮度之測定方法 將亮度計(Topcon (股)製造的B Μ 7 )設置於正面 ,使光源入射角度變化成1 5 ° ,2 0 ° ,3 0 ° , 45° ,並測定反射率(正面亮度)。 又,以東洋精機製作所(股)製造的直讀式曇霧計測 定本發明之彩色瀘光片(實施例A 1〜A 3 )及比較之彩 色濾光片(比較例A 1 )的曇霧値,全部光線透過率,擴 散光線透過率,結果示於下表1。 本紙張尺度適用中國國家標準(CNS ) A4規格( 210X297公釐) (請先閲讀背面之注意事項再填寫本頁) -42 - 594062 Β7 五、發明説明(4〇) 表1 彩色濾光片 反射率(%) 彩色濾光片單體之} 則定結果 15。 20。 30。 45。 曇霧値 全部光線 透過率 擴散光線 透過率 實施例Α1 34 21 16 4 58 50 29 實施例Α2 34 21 16 4 57 51 29 實施例A3 33 21 15 4 57 50 28 實施例Α4 33 20 15 3 辑 實施例Α5 32 20 15 3 垂 一 實施例Α6 32 20 15 3 峰 誠 比較例Α1 28 15 6 <1 26 46 12 (請先閲讀背面之注意事項再填寫本頁) 、τ Γ 經濟部智慧財產局員工消費合作社印製 t( CNS ) ( 210Χ297^ )善 594062 A7 B7 五、發明説明(41) 實施例B 1 檢查由添加色材至彩色濾光片引起的分光特性之變化 。且,在本實施例,爲降低散射光並使計測容易,又若生 計算已加在光散射性微粒子時的分光特性之變化時,則因 可導出已添加光散射性微粒子及色材時之分光特性,故藉 由製作由光散射層形成材料去除光散射性微粒子之光散射 層用塗布液,進行分光特性之測定。 首先設想已分散各種顏料於光散射層及光散射性平坦 化層內的情形,以下述的配合比製備出不含配合例1〜3 之光散射性微粒子之光散射層用塗布液。在此,雖於顏料 之分散方面採用塗料震動器,惟顏料分散方面可採用輥輪 分散裝置的各種分散機。 配合例1 •環氧基丙烯酸酯(EA450,東亞合成) 5 0重量分 •多官能丙烯酸酯單體(DPHA日本化藥) 經濟部智慧財產局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 2 0重量分 •光聚合引發劑(Irgacure 907日本化藥) 5重量分 •P.R.209紅色顏料 1重量分 •分散材(Disperbykl61 BYK Chemie Japan) 5 重量分 配合例2 •環氧基丙烯酸酯(EA4 5 0,東亞合成) 本紙張尺度適用中國國家標準(CNS ) A4規格(210x297公釐) '- -44- 594062 A7 B7 五、發明説明( 5 0重量分 •多官能丙烯酸酯單體(DPHA日本化藥) (請先閲讀背面之注意事項再填寫本頁) 2 0重量分 •光聚合引發劑(Irgacure 907日本化藥) 5重量分 •P.B 15:3藍色顏料 1重量分 •分散材(Disperbykl61 BYK Chemie Japan) 5 重量分 配合例3 . •環氧基丙烯酸酯(EA450,東亞合成) 5 0重量分 •多官能丙烯酸酯單體(DPHA日本化藥) 2 0重量分 •光聚合引發劑(Irgacure 907日本化藥) 5重量分 •P.V 23,紫色顏料 1重量分 •分散材(Disperbykl61 BYK Chemie Japan) 5 重量分 經濟部智慧財產局員工消費合作社印製 其次,與實施例A 3同法製作至著色層爲止,於所得 的著色層上塗布不含上述配合例1之光散射性微粒子的光 散射層用塗布液至1 0 // m之膜厚,並使乾燥,其後進行 曝光,顯影,後烘烤(2 0 0 t,3 0分鐘),而得彩色 濾光片。又對已使用配合例2之塗布液的彩色濾光片,已 使用配合例3之塗布液的彩色濾光片及由配合例1去除色 材之塗布液的彩色瀘光片,亦與上述同法製作。 對已製作的彩色濾光片,利用顯微分光光裝置(機種 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -45- 594062 A7 B7 五、發明説明(43) 名·· OSP-SP 200,OLYMPUS光學公司製造),測定反射分 光色度座標(D 6 5光線)。 (請先閱讀背面之注意事項再填寫本頁) 各自顯示出第9圖採用配合例1之塗布液的情形之測 定結果,第1 0圖採用配合例2之塗布液的情形之測定結 果’第1 1圖採用的配合例3之塗布液的情形之測定結果 ’第1 2圖無添加色材的情形之彩色濾光片之測定結果。 亦即,各自表示第9圖已添加紅色顏料之情形的測定結果 ’第1 0圖已添加藍色顏料之情形的測定結果,第1 1圖 已添加紫色顏料之情形的測定結果,第1 2圖未添加色材 之情形的測定結果於色度座標上。 且圖中〇記號,□記號,△記號,位於座標中央之△ 記號,+記號係各自對應於藍色,紅色,白色,標準光 D65之色度座標上。 經濟部智慧財產局員工消費合作社印製 由第9圖〜第1 2圖得知,若依採用本發明之色材的 態樣時,對以相同條件已形成著色層之彩色濾光片(第 12圖),可賦與紅色(第9圖),藍色(第10圖)及 紫色(第1 1圖)與所期待的分光特性。亦即,欲使本發 明之彩色濾光片對應於各種各樣的分光特性規範一事即成 爲可能的。 實施例B 2 藉由添加色材於彩色瀘光片內,進行光散射層之色補 正對彩色濾光片本身略帶有黃色之問題正進行著改善。亦 即,如前述般光散射層爲發揮其功能,有必要製成5 // m 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -46- 594062 A7 B7 五、發明説明(44) 以上之較厚的膜厚之情形。於此種材料內若對彩色濾光片 之色特性有惡劣影響之著色成分存在時,則有彩色濾光片 本身略帶有黃色之問題,本實施例係解決此問題者。 且,於本實施例,爲降低散射光並使容易計測,又故 事先計算出已加入光散射性微粒子時的分光特性之變化時 ,因可導出已添加光散射性微粒子及色材時之分光特性, 故藉由製作出由光散射性層形成材料去除光散射性微粒子 之光散射層用塗布液,進行分光特性之測定。 首先設想已分散各種顏料於光散射層及光散射性平坦 化層內的情形,以下述的配合比製備出配合例4〜6之光 散射層用塗布液。在此雖於顏料之分散方面採用塗料震動 器,惟顏料分散方面可採用輥輪分散裝置的各種分散機。 配合例4 •環氧丙烯酸酯(EA450東亞合成) 50重量分 •多官能丙烯酸酯單體(D Ρ Η A日本化藥) 2 0重量分 經濟部智慧財產局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) •光聚合引發劑(Irgacure 907日本化藥) 5重量分 配合例5 •環氧丙烯酸酯(EA450東亞合成) 50重量分 •多官能丙烯酸酯單體(DPHA日本化藥) 2 0重量分 •光聚合引發劑(Irgacure 369日本化藥) 5重量分 本紙張尺度適用中國ϋ家標準(CNS )八4規格(210><297公釐) 一 '~" ' -47 - 594062 A7 ____B7 _ 五、發明説明(45) 配合例6 (請先閲讀背面之注意事項再填寫本頁) •環氧丙烯酸酯(EA450東亞合成) 50重量分 •多官能丙烯酸酯單體(D Ρ Η A日本化藥) 2 0重量分 •光聚合引發劑(Irgacure 369日本化藥) 5重量分 ‘PV23紫色顏料 0.5重量分 •分散材(Disperbyk 161 BKY Chemie Japan) 5 重量分 在此,於配合例5及6所用的光聚合引發劑(Irgacure 3 69 )係高靈敏度且可有效的進行光聚合,反之在可見光領 域具有吸收,故在著色成黃色方面有問題。另一方面,於 配合例4所用的光聚合引發劑(Irgacure 907 )係於可見光 領域不具有吸收,反之係低靈敏度,故製造過程上曝光時 間變成,有使生產性降低的問題。 經濟部智慧財產局員工消費合作社印製 其次,除不形成光散射層外,與實施例A 1同法製作 彩色濾光片。於所得的彩色濾光片上利用旋塗法塗布上述 配合例4之光散射層用塗布液並使乾燥,其後進行曝光, 顯影,後烘烤(2 0 0 °C,3 0分鐘)並形成光散射層。 如此而得附有色補正光散射層之彩色濾光片。又對使用配 合例5之塗布液的彩色濾光片,及已使用配合例6之塗布 液,亦以同法製作。對已製作的彩色濾光片,與實施例 B 1同法測定反射分光色度座標(D 6 5光源)。 各自顯示出第1 3圖採用的配合例4之塗布液的情形 本紙張尺度適用中國國家標準(CNS ) A4規格(210X:297公釐) -48 - 594062 A7 _B7 五、發明説明(46) 之測定結果,第1 4圖採用的配合例5之塗布液的情形之 測定結果,第1 5圖採用的配合例6之塗布液的情形之測 定結果。亦即第1 3圖顯示不含使彩色濾光片之色特性降 低的成分(Irgacure 369 )之情形。第1 4圖顯示出含有使 彩色濾光片之色特性降低的成分(Irgacure 369 )之情形, 第1 5圖顯示出含有使彩色濾光片之色特性降低的著色成 分之情形(第1 3圖係表示添加色材進行色補正的情形) 〇 由第1 3圖〜第1 5圖得知,若依採用本發明之色材 進行色補正之態樣(第1 5圖)時,即使含有使附有色補 正散射層之彩色濾光片的色特性降低的著色成分之材料的 情形(第1 4圖),欲得所謂與不含有使色特性降低的著 色成分之材質的情形(第1 3圖)約略相等的足夠色特性 一事亦成爲可能的。因此,若依具有供補正色而用的色材 之本發明時,在不使色特性降低下,可充分活用光聚合引 發劑(在本實施例爲Irgacure 369 )所具的靈敏度。 如以上詳述般,若依本發明之彩色濾光片時,在不需 前方散射板下,同時可實現高亮度無視差(影像模糊), 且防止色特性之劣化的優越色特性。 又賦與所期待的色特性,可使容易的對應於各式各樣 的分光規範。再者並不受伴隨厚膜之著色性所拘限下,可 廣泛幅度的選擇適於製造的材料,故亦有可提高生產性之 優點。 再者於光散射層上設置著色層之情形,尤其於容易進 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 -49 - 594062 A7 ___B7_ 五、發明説明(47) (請先閱讀背面之注意事項再填寫本頁) 行色補正,又設置光散射性著色層之情形,因可綜合形成 光散射層及著色層,故製造步驟之簡略化即成可能,又於 設置光散射性平坦化層之情形,亦可附加用作保護層,平 坦化膜之功能。再者在具有反射電極層之本發明的彩色濾 光片,藉由將反射電極層設成半鏡型之電極層或開孔型之 電極層,亦使半透過型彩色液晶顯示裝置成爲可使用。 圖式之簡單說明 第1圖爲表示本發明之第一態樣的彩色濾光片之一例 的槪略縱截面圖。 第2圖爲表示本發明之第二態樣的彩色濾光片之一例 的槪略縱截面圖。 第3圖爲表示本發明之第三態樣的彩色濾光片之一例 的槪略縱截面圖。 第4圖爲表示本發明之第四態樣的彩色濾光片之一例 的槪略縱截面圖。 經濟部智慧財產局員工消費合作社印製 第5圖爲表示本發明之第五態樣的彩色濾光片之一例 的槪略縱截面圖。 第6圖爲表示本發明之第六態樣的彩色濾光片之一例 的槪略縱截面圖。 第7圖爲表示採用本發明之彩色濾光片之反射型彩色 液晶顯示裝置之一例的槪略縱截面圖。 第8圖爲表示採用本發明之彩色濾光片之反射型彩色 液晶顯示裝置之另外側的槪略縱截面圖。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -50- 594062 A7 _B7 五、發明説明(48) 第9圖爲表示已添加紅顏料於彩色濾光片時的反射分 光色度座標之一圖例。 (請先閲讀背面之注意事項再填寫本頁) 第1 0圖爲表示已添加藍顏料於彩色濾光片時的反射 分光色度座標之一圖例。 第1 1圖爲表不已添加紫顏料於彩色濾光片時的反射 分光色度座標之一圖例。 第1 2圖爲表示不添加色材於彩色濾光片時的反射分 光色度座標之一圖例。 第1 3圖爲表示於不含有使彩色濾光片降低色特性之 著色成分時之反射分光色度座標之一圖例。 第1 4圖爲表示含有使彩色濾光片降低色特性之著色 成分時之反射分光色度座標之一圖例。 第1 5圖爲表示含有彩色濾光片降低色特性之著色成 分時,添加色材並進行色補正時之反射分光色度座標之一 圖例。 符號說明 經濟部智慧財產局員工消費合作社印製 1 彩色濾光片 2 透明基板 3 光散射層 4 著色層 4 R 紅色著色圖型 4G 綠色著色圖型 4 B 藍色著色圖型 -51 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -32- 594062 A7 B7 V. Description of invention (3〇) Of course. (Please read the precautions on the back before filling out this page) Color filter in the twelfth aspect The color filter in this aspect is the color filter in the fourth aspect shown in FIG. 4, not only The light-scattering layer 35 is also provided between the colored layer 36 and the transparent electrode layer 38, and the same layer as the light-scattering planarizing layer 57 of the sixth aspect is provided. Therefore, by using the light scattering layer 35, the adhesion between the transparent substrate 32 and the coloring layer 36 can be made higher. The light scattering flattening layer 26 can reduce the coloring layer 36. The surface has unevenness and the advantage of obtaining a flat surface. In this state, the light-scattering microparticles contained in the light-scattering layer and the light-scattering flattening layer can be divided into two layers so that the optimal fog can be obtained. The content of each layer is not changed. Specially limited. Reflection-type color liquid crystal display device Next, an example of a reflection-type color liquid crystal display device using the color filter of the present invention will be described. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. Fig. 7 is a schematic longitudinal sectional view showing a reflective color liquid crystal display device using the color filter of the present invention shown in Fig. 1. In FIG. 7, a reflective color liquid crystal display device 61 is provided with a color filter 1 of the present invention on the observer side. A phase difference plate 62 and a polarizing plate are provided on a transparent substrate 2 of the color filter 1. 6 3. A liquid crystal layer 6 8 is formed between the driving element layer 6 6 and the counter electrode substrate 6 7 of the reflective electrode layer 67 and the color filter 1. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -33-594062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (31) In addition, Figure 8 shows that the Fig. 5 is a schematic longitudinal sectional view of a reflective color liquid crystal display device of a color filter 41 according to the present invention. In FIG. 8, a reflective color liquid crystal display device 7 1 has a transparent electrode layer 7 3 on one surface of a transparent substrate 7 2, and a phase difference plate 7 4 and a polarizing plate 7 5 on the other side through a designated gap. The opposite substrate is mated with the color filter 41 of the present invention to form a liquid crystal layer 78 at a gap portion. Here, the reflection type color liquid crystal display device 7 1 and the color filter 41 of the present invention are located on the side opposite to the observer side through the liquid crystal layer 78. The color filter of the present invention can be used in a transflective color liquid crystal display device in addition to the reflective color liquid crystal display device described above. The semi-transmissive color liquid crystal display device has been developed to have the advantages of various transmissive and reflective color liquid crystal storage devices, forming a transmission display portion and a reflection display portion in a * image. Those who have a liquid crystal display mode in which the transmission / reflection of different liquid crystal display modes to the display-only principle are opposed to each other. When a transflective color liquid crystal display device is manufactured with the structure shown in FIG. 7, each of the reflective electrode layers 3 4, 4, 5 and 4 of the color filters 3 1, 4 1, and 5 1 of the present invention is used as a half Mirror type electrode layer or aperture type electrode layer. The semi-mirror type electrode layer is a conductive film that has a semi-transmissive property that allows a part of light to pass and reflects the rest, and is controlled by a known film-forming process such as a vapor deposition method, a sputtering method, a CVD method, and an ion implantation method Can be formed. The open-hole electrode layer divides an image element into a transparent portion (opening portion) and a reflective portion. The above-mentioned film formation method is used to form the paper. This paper applies the Chinese National Standard (CNS) A4 specification (210X297). (Mm) (Please read the precautions on the back before filling in this page) -34- 594062 A7 B7 V. Description of the invention (32) After forming the metal film, set it into a pattern and set the designated fine openings to form it. (Please read the notes on the back before filling out this page.) Examples The following examples will be used to explain the present invention in detail. Example A 1 A glass substrate (alkali-free glass) having a thickness of 0 · 7 mm was prepared as the substrate. On this glass substrate, a coating solution for a light scattering layer with the following composition was applied and dried by a spin coating method, followed by exposure, development, and post-baking (200 ° C, 30 minutes) to form a light scattering layer (thickness). l〇 // m) Coating solution for light scattering layer • 35 parts by weight of epoxy acrylate (manufactured by Toa Synthetic Chemical Co., Ltd .; EF450) • 15 parts by weight of multifunctional acrylate monomer Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Manufactured by Benhua Pharmaceutical Co., Ltd .; D Ρ Η A) • melamine beads (average particle size 0.7 // m) 1 0 weight points • polymerization initiator 4 weight points (Irgacure 184 manufactured by Ciba Geigy) • Diluted solvent 3 6 weight points (propylene glycol monoethyl ethyl ester) This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -35- 594062 A7 B7 V. Description of the invention (33) (Please read the back first Please fill in this page for the matters needing attention.) Next, use a spin coating method to apply a photosensitive coloring material (Color Mosaic CR-7 000 manufactured by Rich Film Orlin Co., Ltd.) on the light scattering layer through the specified method. Mask and expose the coating film With its developer (manufactured by Fujifilm Corp. Orlin C D) to the developing and, holding the glass substrate to form a red colored pattern on 2 0 0 ° C 3 0 minutes and the colored cured layer. In the same way, a photosensitive coloring material for green coloring patterns (Clor mosaic CG-7000 manufactured by Fujifilm Orlin Co., Ltd.) and a coloring material for blue coloring patterns (Color manufactured by Fujifilm Orlin Co., Ltd.) are used. Mosaic CG-7000), in the same way as above, forms a green coloring pattern and a blue coloring pattern and becomes a coloring layer. Secondly, a transparent electrode (IT 0) layer is formed on the above-mentioned coloring layer according to a common method, and an orientation film (thickness: 0.05 // m) of polyimide resin is formed on the transparent electrode layer to obtain the figure 1 The structure of the color phosphor film (Example A 1). It is printed here by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In the coating liquid for the light scattering layer, a color material for correcting the color characteristics is added to prevent deterioration of the color characteristics accompanying the addition of the light scattering particles. Can give superior color characteristics to color filters. Example A 2 A glass substrate (alkali-free glass) having a thickness of 0.7 mm was prepared as a substrate. On this glass substrate, the average particle diameter of light-scattering microparticles contained in a photosensitive coloring material (Color Mosaic CR-7000 manufactured by Fujifilm Orlin Co., Ltd.) used for red coloring patterns was applied by a spin coating method. Paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) -36- 594062 A7 B7 V. Description of the invention (34) (Please read the precautions on the back before filling this page) 0. 7 // m melamine beads 27% by weight of the coating liquid, the coating film was exposed through a designated photomask, and then a developing solution (CD manufactured by Fujifilm Orlin Co., Ltd.) was used and developed, and the glass substrate was maintained at 200 ° C 3 After 0 minutes, the colored layer is allowed to harden to form a red colored pattern. Similarly, a photosensitive coloring material (Color Mosaic CG-7000 manufactured by Fujifilm Orlin (Stock)) coated with a green coloring pattern was coated by a spin coating method, and contained an average particle diameter of 0.7 // m of melamine beads 2 7% by weight of the coating solution and the photosensitive coloring material used for blue coloring patterns (Color Mosaic CB-7000 manufactured by Fujifilm Orlin Co., Ltd.) contained melamine beads with a particle diameter of 0.7 / m 2 7 The coating solution of weight% forms a green coloring pattern and a blue coloring pattern in the same manner as the above, and serves as a light-scattering coloring layer. Next, a transparent electrode (ITO) layer and an alignment film were formed in the same manner as in Example A 1 to obtain a color filter having a structure as shown in FIG. 2 (Example A 2). It is printed here by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In the above-mentioned three kinds of coating liquids for light-scattering colored layers, by adding color materials for correcting color characteristics, the color characteristics accompanying the addition of light-scattering fine particles are prevented. Degradation can impart excellent color characteristics to the color filter. Example A 3 A glass substrate (alkali-free glass) having a thickness of 0.7 mm was prepared as a substrate, and a color was formed on this glass substrate in the same manner as in Example A 1 Floor. The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X297 mm) -37- 594062 A7 _B7_ V. Description of the invention (35) (Please read the precautions on the back before filling this page) Next on the coloring layer The coating liquid for a light-scattering flattening layer having the following composition was applied by a spin coating method and dried, followed by exposure, development, and post-baking (200 ° C, 30 minutes) to form light-scattering properties. Planarization layer (thickness 10 / m). Coating solution for light-scattering flattening layer: 35 parts by weight of epoxy acrylate (manufactured by Toa Synthetic Chemical Co., Ltd .; E A4 50) • 15 parts by weight of polyfunctional acrylate monomer (manufactured by Nippon Kayaku Co., Ltd .; DPHA ) • Melamine beads (average particle size 0.7 // m) 10 parts by weight • Polymerization initiator 4 parts by weight (Irgacure 184 manufactured by Ciba Geigy) • Dilution solvent 3 6 parts by weight (propylene glycol monoethyl ethyl ester) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, followed by forming a transparent electrode (IT0) film and an orientation film on the light-scattering planarization layer in the same manner as in Example A 1 to obtain the color of the structure shown in FIG. 3 Filter (Example A 3). Here, in the coating liquid for a light scattering layer, by adding a color material for correcting color characteristics, the deterioration of color characteristics accompanying the addition of light scattering fine particles can be prevented, and a superior color can be imparted to a color filter. characteristic. A phase difference plate and a polarizing plate were laminated on the glass substrate of each of the color filters (Examples A.1 to A3) prepared as described above. At the thickness of 0.7 mm, this paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) -38- 594062 A7 B7 V. Description of the invention (36) (Please read the precautions on the back before filling this page) A reflective electrode layer made of a TFT driving element layer and aluminum is formed on a glass substrate, and an orientation film (thickness: 0.005 // m) of polyimide resin is formed as a counter electrode substrate to make the counter electrode Each of the alignment films of the substrate and the color filter faces each other, and a nematic liquid crystal layer (thickness 5 · 0 // m) is provided to produce a reflective color liquid crystal display device. Example A 4 A glass substrate (alkali-free glass) having a thickness of 0.7 mm was prepared as a substrate, and a reflective electrode layer made of a TFT driving element layer and aluminum was formed on the glass substrate. Next, a coating solution for a light-scattering layer having the same composition as that of Example A 1 was applied and dried on the reflective electrode layer by spin coating, followed by exposure, development, and post-baking (200 ° C, 30 minutes). ) And form a light scattering layer (thickness 8 · 0 // m). Next, a colored layer was formed on the light scattering layer in the same manner as in Example A1. Next, a transparent electrode (IT) layer was formed on the colored layer, and an orientation film (thickness: 0.05 / zm) of polyimide resin was formed to obtain a color filter having a structure shown in FIG. 4 (Example A). 4) ° It is printed here by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. In the above-mentioned three light-scattering coloring layer coating liquids, color materials for correcting color characteristics are added to prevent the addition of light-scattering particles. Degradation of color characteristics can give superior color characteristics to color filters. Example A 5 A glass substrate (alkali-free glass) with a thickness of 0.7 mm was prepared as the base -39-This paper is compliant with Chinese National Standards (CNS) A4 specification (210X297 mm) 594062 A7 B7 ___ 5. Description of the invention (37) board. A reflective electrode layer made of a TFT driving element layer and aluminum was formed on the glass substrate. (Please read the precautions on the back before filling in this page.) Secondly, apply a photosensitive coloring material for red coloring pattern (Color Mosaic CR-Made by Fujifilm Orlin) to the reflective electrode layer by spin coating. 7000) containing a coating solution with an average particle diameter of 0.7 // m of melamine beads 27.7% by weight, a coating solution, the coating film is exposed through a designated photomask, and a developing solution (Fuji film Orlin CD produced by the company) and pre-developed, the glass substrate was held at 200 ° C for 30 minutes, and the colored layer was hardened to form a red colored pattern. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs using the same spin-coating method to apply a photosensitive coloring material used for green coloring patterns (Color Mosaic [0ν 000] manufactured by Fuji Film Orlin Co., Ltd.) contains an average particle size. . 7 // m of melamine beads. 27% by weight of the coating liquid and the photosensitive coloring material used for blue coloring patterns (Color Mosaic CB-7000 manufactured by Fuji Film Orlin) has an average particle size of 0. 7 // m coating solution of 27% by weight of melamine beads is formed in the same manner as above to form a green coloring pattern and a blue coloring pattern as a light-scattering coloring layer. Next, a transparent electrode layer was formed on the light-scattering colored layer in the same manner as in Example A 4 and an orientation film was formed to obtain a color filter having a structure as shown in FIG. 5 (Example A 5). Here, by adding color materials for correcting color characteristics to the above-mentioned three kinds of coating liquids for light-scattering colored layers, the color characteristics can be prevented from deteriorating with the addition of light-scattering fine particles, and a color filter can be added Superior color characteristics This paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm) -40- 594062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (38) Example A 6 Preparation thickness A 7 mm glass substrate (alkali-free glass) is used as a substrate, and a reflective electrode layer made of a TFT driving element layer and aluminum is formed on the glass substrate. Next, a colored layer was formed on the reflective electrode layer in the same manner as in Example A1. Next, a coating solution for a light-scattering flattening layer having the same composition as in Example A 3 was applied and dried on the colored layer by a spin coating method, followed by exposure, development, and post-baking (2 0 ° C '3 0 minutes) and a light-scattering planarization layer (thickness 8. 0 // m) was formed. Next, a transparent electrode layer was formed on the light-scattering planarization layer in the same manner as in Example A 4 and an orientation film was formed to obtain a color filter having a structure as shown in FIG. 6 (Example A 6). Here, in the coating liquid for a light-scattering planarization layer, by adding a color material for correcting color characteristics, the color characteristics can be prevented from deteriorating with the addition of light-scattering fine particles, and a color filter can be provided. Superior color characteristics. Therefore, a transparent electrode (I TO) layer was formed on one surface of a glass substrate having a thickness of 0.7 mm, and an orientation film (thickness of 0.05 mm) of polyimide resin was formed on the other surface of the glass substrate. The phase difference plate and the polarizing plate are combined to form an opposite substrate. This opposing substrate was opposed to the alignment film of each of the color filters (Examples A4 to A6) produced as described above, and a nematic liquid crystal layer (thickness 5 · 0 # m) was provided to produce a reflective color liquid crystal display device. (Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -41-594062 A7 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (39) Comparative Example A 1 A color filter was produced in the same manner as in Example A 1 except that a light scattering layer was not provided. Therefore, on the glass substrate of this color filter (comparative example), a polarizing plate (AGS I manufactured by Nitto Denki Co., Ltd.) with a phase difference plate and a front scattering layer built-in was laminated. On the glass substrate with a thickness of 0 · 7mm, a reflective electrode layer made of TFT and aluminum is formed. Furthermore, an orientation film of polyimide resin (thickness 0.05 // m) is formed as a counter electrode. The substrate, the alignment film of the counter electrode substrate and the alignment film of the color filter are opposed to each other, a nematic liquid crystal layer (thickness 5 · 0 // m) is provided, and a reflective color liquid crystal display device is fabricated. As described above, the brightness of the display image of each reflective color liquid crystal display device using the color filter (Example A 1 to A 6) and the comparative color filter (Comparative Example A 1) of the present invention was measured by the following method. The results are shown in Table 1 below. Method for measuring brightness Set a brightness meter (B MG 7 manufactured by Topcon) on the front side, change the incident angle of the light source to 15 °, 20 °, 30 °, 45 °, and measure the reflectance (front brightness ). In addition, the haze of the color phosphor (Example A 1 to A 3) and the comparative color filter (Comparative Example A 1) of the present invention were measured with a direct-reading haze meter manufactured by Toyo Seiki Seisakusho Co., Ltd. Alas, the total light transmittance and diffused light transmittance are shown in Table 1 below. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) -42-594062 Β7 V. Description of the invention (4〇) Table 1 Color filter reflection The ratio (%) of the color filter alone determines the result 15. 20. 30. 45.昙 雾 値 All light transmittance diffused light transmittance Example A1 34 21 16 4 58 50 29 Example A2 34 21 16 4 57 51 29 Example A3 33 21 15 4 57 50 28 Example A4 33 20 15 3 Series implementation Example A5 32 20 15 3 Example A6 32 20 15 3 Fengcheng Comparative Example A1 28 15 6 < 1 26 46 12 (Please read the notes on the back before filling out this page), τ Γ Intellectual Property Bureau, Ministry of Economic Affairs Printed by employee consumer cooperatives t (CNS) (210 × 297 ^) shan 594062 A7 B7 V. Description of the invention (41) Example B 1 Examine the change in the spectral characteristics caused by the addition of color materials to color filters. In addition, in this embodiment, in order to reduce scattered light and facilitate measurement, if the change in the spectral characteristics when the light-scattering fine particles have been added is calculated, the spectrometry when the light-scattering fine particles and the color material are added can be derived. Characteristics, a coating solution for a light-scattering layer in which light-scattering fine particles are removed by a light-scattering layer-forming material is prepared to measure the spectral characteristics. First, a case where various pigments are dispersed in a light-scattering layer and a light-scattering flattening layer is assumed, and a coating solution for a light-scattering layer that does not contain the light-scattering fine particles of Examples 1 to 3 is prepared at the following mixing ratio. Here, although a paint shaker is used for pigment dispersion, various dispersers using a roller disperser can be used for pigment dispersion. Application example 1 • Epoxy acrylate (EA450, East Asia Synthetic) 50% by weight • Multifunctional acrylate monomer (DPHA Nippon Kayaku) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back first) Refill this page) 2 0 weight points • Photopolymerization initiator (Irgacure 907 Japanese chemical) 5 weight points • PR209 red pigment 1 weight point • Dispersion material (Disperbykl61 BYK Chemie Japan) 5 Weight distribution example 2 • Epoxy Acrylate (EA4 50, East Asia Synthetic) This paper size applies the Chinese National Standard (CNS) A4 specification (210x297 mm) '--44- 594062 A7 B7 V. Description of the invention (50 weight points • Multifunctional acrylate Monomer (DPHA Japanese Chemical) (Please read the notes on the back before filling out this page) 2 0% by weight • Photopolymerization initiator (Irgacure 907 Japanese Chemical) 5% by weight • PB 15: 3 blue pigment 1% Dispersion material (Disperbykl61 BYK Chemie Japan) 5 Weight distribution example 3. • Epoxy acrylate (EA450, East Asia Synthetic) 5 0% by weight • Multifunctional acrylate monomer (DPHA Nippon Kayaku) 2 0 weight points • Photopolymerization initiator (Irgacure 907), 5 weight points • PV 23, purple pigment 1 weight point • Dispersion material (Disperbykl61 BYK Chemie Japan) 5 weight points Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The coating solution for the light-scattering layer containing no light-scattering fine particles of the above-mentioned compounding example 1 was coated on the obtained colored layer to the coloring layer in the same manner as in Example A 3 to a film thickness of 10 / m, and After drying, exposure, development, and post-baking (200 t, 30 minutes) were performed to obtain a color filter. For the color filter that has been used with the coating solution of Example 2, the color filter has been used. The color filter of the coating liquid of Example 3 and the color calender of the coating liquid from which the color material was removed by blending with Example 1 were also produced in the same manner as above. The prepared color filter was made using a micro-spectroscopy device ( The paper size of this model applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -45- 594062 A7 B7 V. Description of the invention (43) Name · OSP-SP 200 (manufactured by OLYMPUS Optical Co., Ltd.) to measure the reflectance chromaticity Coordinates (D 6 5 light) (Please read the precautions on the back before filling in this page.) Figure 9 shows the measurement results of the case where the coating liquid of the blending example 1 is used, and Figure 10 shows the measurement results of the case where the coating liquid of the blending example 2 is used. Fig. 11 shows the measurement results of the case where the coating solution of Example 3 is used. Fig. 12 shows the measurement results of the color filter when no coloring material is added. That is, the measurement results in the case where a red pigment has been added in FIG. 9 are shown in FIG. 10, and the measurement results in the case where a blue pigment has been added in FIG. 10, FIG. The measurement results in the case where no color material is added are shown on the chromaticity coordinates. In the figure, the 0 mark, the □ mark, and the △ mark are located at the center of the coordinates. The △ mark and the + mark respectively correspond to the chromaticity coordinates of blue, red, white, and standard light D65. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs from Figures 9 to 12 shows that if the color material of the present invention is used, the color filter (No. Figure 12), red (Figure 9), blue (Figure 10) and purple (Figure 11) can be assigned with the desired spectral characteristics. That is, it is possible to make the color filter of the present invention correspond to various specifications of spectral characteristics. In Example B2, by adding a coloring material to the color calender, the color correction of the light scattering layer was performed to improve the problem that the color filter itself was slightly yellow. That is, in order to perform its function, the light-scattering layer must be made into 5 // m as described above. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -46- 594062 A7 B7 V. Description of the invention ( 44) In the case of the above thick film thickness. If there is a coloring component in this material that has a bad influence on the color characteristics of the color filter, there is a problem that the color filter itself is slightly yellow. This embodiment is to solve this problem. Moreover, in this embodiment, in order to reduce scattered light and make it easy to measure, the story first calculates the change in the spectral characteristics when light-scattering fine particles have been added, because the light-dispersing when the light-scattering fine particles and color materials have been added can be derived Characteristics, a coating solution for a light-scattering layer in which light-scattering fine particles are removed by a light-scattering layer-forming material is prepared, and the spectral characteristics are measured. First, a case where various pigments are dispersed in the light-scattering layer and the light-scattering flattening layer is assumed, and the coating liquids for the light-scattering layers of the blending examples 4 to 6 were prepared at the following blending ratios. Although a paint shaker is used for the pigment dispersion here, various dispersers of a roller dispersing device can be used for the pigment dispersion. Compound Example 4 • Epoxy acrylate (EA450 East Asia Synthetic) 50% by weight • Multifunctional acrylate monomer (D P Η A Nippon Kayaku) 20% by weight Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read first) Note on the back page, please fill in this page again) • Photopolymerization initiator (Irgacure 907), 5 weight distribution example 5 • Epoxy acrylate (EA450 East Asia Synthesis) 50 weight points • Multifunctional acrylate monomer (DPHA Japan Chemical medicine) 20 weight points • Photopolymerization initiator (Irgacure 369 Japanese chemical medicine) 5 weight points The paper size is applicable to China Standards (CNS) 8-4 specifications (210 > < 297 mm) 1 '~ " '-47-594062 A7 ____B7 _ 5. Description of the invention (45) Example 6 (Please read the precautions on the back before filling out this page) • Epoxy acrylate (EA450 East Asia Synthesis) 50 weight points • Multifunctional acrylate single Body (D Ρ Η A Japanese chemical) 20 weight points • Photopolymerization initiator (Irgacure 369 Japanese chemical drugs) 5 weight points' PV23 purple pigment 0.5 weight points • Dispersion material (Disperbyk 161 BKY Chemie Japan) 5 weight points this Photopolymerized in Example 5 and 6 with the initiator (Irgacure 3 69) based high sensitivity and can be effectively photo-polymerization, whereas having absorption in the visible field, so there are problems in terms of yellow colored. On the other hand, the photopolymerization initiator (Irgacure 907) used in the compounding example 4 does not have absorption in the visible light field, and on the other hand, it has low sensitivity. Therefore, the exposure time during the manufacturing process is changed, which reduces the productivity. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Second, except that a light scattering layer is not formed, a color filter is produced in the same manner as in Example A1. On the obtained color filter, the coating solution for the light scattering layer of the above-mentioned compounding example 4 was applied and spin-coated on the obtained color filter, followed by exposure, development, and post-baking (200 ° C, 30 minutes). A light scattering layer is formed. In this way, a color filter with a color correction light scattering layer was obtained. The color filter using the coating liquid of Formulation 5 and the coating liquid of Formulation 6 were also prepared in the same manner. The color filter of the prepared color filter was measured in the same manner as in Example B 1 (D 65 light source). Each shows the coating solution of Compatibility Example 4 used in Figure 13 This paper size applies the Chinese National Standard (CNS) A4 specification (210X: 297 mm) -48-594062 A7 _B7 V. Description of the invention (46) The measurement results are the measurement results in the case of the coating liquid of the compounding example 5 used in FIG. 14 and the measurement results in the case of the coating liquid of the blending example 6 used in FIG. 15. That is, Fig. 13 shows the case where the component (Irgacure 369) that reduces the color characteristics of the color filter is not included. Fig. 14 shows the case where the component (Irgacure 369) is used to reduce the color characteristics of the color filter, and Fig. 15 shows the case where the color component is included to reduce the color characteristics of the color filter (Igacure 369) The figure shows the situation where color materials are added for color correction) 〇 From Figures 13 to 15 it can be seen that if color correction is performed using the color material of the present invention (Figure 15), In the case of a material that reduces the color characteristics of a color filter with a color correction scattering layer (Figure 14), it is desired to obtain a material that does not contain a coloring component that reduces the color characteristics (Figure 1 3). (Figure) It is also possible to have approximately equal enough color characteristics. Therefore, according to the present invention having a color material for correcting the color, the sensitivity of the photopolymerization initiator (Irgacure 369 in this example) can be fully utilized without reducing the color characteristics. As detailed above, if the color filter according to the present invention does not require a front scattering plate, it can achieve high brightness, no parallax (image blur), and excellent color characteristics that prevent degradation of color characteristics. By giving desired color characteristics, it can easily correspond to various spectroscopic specifications. Furthermore, without being limited by the coloring properties associated with thick films, materials suitable for manufacturing can be selected in a wide range, so it has the advantage of improving productivity. Furthermore, the case of setting a coloring layer on the light scattering layer is particularly easy to enter the paper size. The Chinese National Standard (CNS) A4 specification (210X297 mm) is applicable (please read the precautions on the back before filling this page). Order the Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives -49-594062 A7 ___B7_ V. Description of the Invention (47) (Please read the precautions on the back before filling this page) Color correction, and the setting of light-scattering coloring The light-scattering layer and the coloring layer are formed comprehensively, so that the simplification of the manufacturing steps becomes possible, and when a light-scattering planarization layer is provided, it can also be used as a protective layer and a planarization film. Furthermore, in the color filter of the present invention having a reflective electrode layer, by setting the reflective electrode layer as a semi-mirror-type electrode layer or an open-hole-type electrode layer, a semi-transmissive color liquid crystal display device is also usable. . Brief Description of the Drawings Fig. 1 is a schematic longitudinal sectional view showing an example of a color filter according to a first aspect of the present invention. Fig. 2 is a schematic longitudinal sectional view showing an example of a color filter according to a second aspect of the present invention. Fig. 3 is a schematic longitudinal sectional view showing an example of a color filter according to a third aspect of the present invention. Fig. 4 is a schematic longitudinal sectional view showing an example of a color filter according to a fourth aspect of the present invention. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Fig. 5 is a schematic longitudinal sectional view showing an example of a color filter according to a fifth aspect of the present invention. Fig. 6 is a schematic longitudinal sectional view showing an example of a color filter according to a sixth aspect of the present invention. Fig. 7 is a schematic longitudinal sectional view showing an example of a reflection type color liquid crystal display device using the color filter of the present invention. Fig. 8 is a schematic longitudinal sectional view showing the other side of a reflective color liquid crystal display device using the color filter of the present invention. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -50- 594062 A7 _B7 V. Description of the invention (48) Figure 9 shows the reflectance chromaticity when red pigment has been added to the color filter Legend of one of the coordinates. (Please read the precautions on the back before filling out this page.) Figure 10 shows an example of the spectrophotometric chromaticity coordinates when the blue pigment has been added to the color filter. Figure 11 shows an example of the spectroscopic chromaticity coordinates of reflection when a purple pigment has been added to a color filter. Fig. 12 is an example of the chromaticity coordinates of the reflection spectrum when no color material is added to the color filter. Fig. 13 is a diagram showing one example of the spectroscopic chromaticity coordinates of reflection when a coloring component that reduces the color characteristics of a color filter is not included. Fig. 14 is a diagram showing one example of the chromaticity coordinates of reflection spectrometry when a coloring component is used to reduce the color characteristics of a color filter. Fig. 15 shows an example of the chromaticity coordinates of reflection spectrometry when a coloring material is added and color correction is performed when a coloring component containing a color filter is used to reduce color characteristics. Symbol description Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 Color filter 2 Transparent substrate 3 Light scattering layer 4 Colored layer 4 R Red colored pattern 4G Green colored pattern 4 B Blue colored pattern -51-This paper Applicable to China National Standard (CNS) A4 (210X297 mm)

Claims (1)

594062 A8 B8 D8 六、申請專利範圍 9tll〇f補充 1 . 一種彩色濾光片,其特徵在於至少含有基板及由 多數色之著色圖型而成的著色層而成的彩色濾光片,含有 由光散射性微粒子及供補正色特性而用的色材而成。 2 ·如申請專利範圍第1項之彩色濾光片,係具有前 述光散射性微粒子及前述色材之兩者的層。 3 ·如申請專利範圍第1項或第2項之彩色濾光片’ 係曇霧値爲1 0〜9 0之範圍內,全部光線透過率爲 3 0 %以上。 (請先閲讀背面之注意事項再填寫本頁) Φ tr 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)594062 A8 B8 D8 VI. Patent Application Scope 9tll0f Supplement 1. A color filter, which is characterized by containing at least a substrate and a coloring layer made of coloring patterns of most colors, containing a color filter Light-scattering fine particles and color materials for correcting color characteristics. 2. The color filter according to item 1 of the scope of patent application, which is a layer having both the aforementioned light-scattering fine particles and the aforementioned color material. 3. If the color filter of item 1 or item 2 of the patent application range is within the range of 10 ~ 90, the total light transmittance is above 30%. (Please read the notes on the back before filling out this page) Φ tr Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210X297 mm)
TW090107760A 2000-04-05 2001-03-30 Color filter TW594062B (en)

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KR101980186B1 (en) * 2017-03-30 2019-05-20 동우 화인켐 주식회사 A blue colored photosensitive resin composition, color filter and image display device produced using the same
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