TW593606B - Preparation of coating for moistureproof/waterproof paper - Google Patents

Preparation of coating for moistureproof/waterproof paper Download PDF

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Publication number
TW593606B
TW593606B TW90126247A TW90126247A TW593606B TW 593606 B TW593606 B TW 593606B TW 90126247 A TW90126247 A TW 90126247A TW 90126247 A TW90126247 A TW 90126247A TW 593606 B TW593606 B TW 593606B
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Taiwan
Prior art keywords
paper
water
waterproof
moisture
coating
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TW90126247A
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Chinese (zh)
Inventor
Yuan-Shing Peng
Fu-Ji Chen
Jr-Yuan Li
Je-Ming Jiang
Ching-Shiang Shiu
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Long Chen Paper Co Ltd
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Priority to TW90126247A priority Critical patent/TW593606B/en
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Publication of TW593606B publication Critical patent/TW593606B/en

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Abstract

A preparation of a coating for moistureproof/waterproof paper capable endowing a piece of paper with moistureproof/waterproof functions mainly includes 80.6% to 34% of a filling material and 19.4% to 66% of a coating material, based on the matrix material of the paper. The filling material is prepared by subjecting water, a dispersion agent, a mica powder, and a liquid alkali to mixing and swelling treatments. The coating material is prepared by subjecting starch, polyvinyl alcohol, an anti-hydration agent, a cross-linking agent, a latex, a stabilizer, a water repellent, a surfactant, a lubricant, and a wetting agent to mixing. When the invented preparation is coated on a piece of raw paper, the preparation permeates into the fibers easily and fills up the capillaries therein, thereby endowing the paper with non-water-absorbency, water repellent, strong binding with the raw paper and forming a thin coating with sufficient moistureproof/waterproof functions. The invented preparation provides desired functions to paper without excessively increasing the thickness of paper.

Description

593606 修正593606 Fix

本發明係一種防潮、防水紙塗 紙具有防潮、防水之功⑧,不必’乃使欲達成 案號9012防47 五、發明說明(1) 方V而以本發明獨特之防潮1水塗;;之 、耐用之防水防濕驢,達到更佳之實 +用:一、 傳統式之防水方式及其缺點 ,傳統式 列兩種方 」,茲述 黏貼防水 預先製造 於紙之表 防水膜, 度,尤其 增加極多 、可撓性 未黏貼之 紙受「摺 由「摺線 然正、背 ,仍未予 之虞,此 主因。 f至:具有防水、防潮之功效,不外 ί黏貼防水膜」、另-為「塗佈 種方式及缺點: 」狀 述, 厚度 正、 紙不 。又 不具 會有 入濕 貼防 故仍 具有 按 乎有下 防水劑 一 、Γ 係 膜黏貼 ⑴其 厚 度 硬 其 (2) 當 成 (3) 縱 j 份 之 欲使紙 式:一 明此兩 膜」者 「薄膜 面;上 必有~ ,紙之 ,而使^ 太差) 面’即 」時, 」處ϋ及 面皆黏 封閉, 乃為何 之防水 其實存 ,黏貼 背面黏 方便使 ,如因 有防潮 破壞( 氣、水 水膜, 會有由 防水膜 膜(膠膜 在有下列 於紙上時 貼兩層防 用(例如 會增厚而 、防水之 破裂)防 份之虞。 但,其紙 四周厚度 之紙四周 ),再將防水 缺點: ’必增加紙之 水膜時,其厚 •太笨重、太 /、黏貼'一面, 功能。 水膜之虞,造 之「四周厚度 吸入濕氣、水 會有潮濕現像The present invention is a kind of moisture-proof and waterproof paper coated paper which has the functions of moisture-proof and waterproof. It is not necessary to achieve case number 9012 to prevent 47. V. Description of the invention (1) Party V uses the unique moisture-proof 1 water coating of the present invention; The durable and waterproof and moisture-proof donkey achieves better practical use. First, the traditional waterproof method and its disadvantages, the traditional method is two ways. In particular, the increase of a lot of flexible and non-adhesive paper is affected by the "folding line", the main reason is that the folding line is straight and back. F to: It has the effect of waterproofing and moisture-proofing, but it is also sticking waterproof film. Another-for the "coating method and disadvantages:" State description, thickness is positive, paper is not. It does not have a wet-proof paste, so it still has the following waterproofing agent. I, Γ series film is adhered. Its thickness is hard. (2) It is regarded as (3). The number of vertical j parts is to make a paper type. The "film surface; there must be ~, paper, and ^ is too bad) When the surface is" that ", the place and the surface are glued and closed, but why the waterproofing actually exists, and the back surface is easy to stick. Moisture-proof (air, water, and water film, there may be a waterproof film (adhesive film when the following on the paper is affixed to two layers of anti-use (such as thickening and waterproof crack)) may be protected. However, the paper around Thickness of the paper around), then the waterproofing disadvantages: 'When the water film of the paper must be increased, its thickness is too bulky, too /, and sticky' side, function. The risk of water film, "the thickness of the surrounding area sucks moisture, water Wet appearance

第6頁 593606 案號 90126247 年 月 曰 修正 五、發明說明(2) 二、「塗佈防水劑」者 係為了改善「黏貼 在紙表面塗佈「混合黏 下列之缺點: (1)其雖可呈較薄塗佈 之效果不佳,可謂 防水膜造成『增厚』」之問題,而 劑、撥水劑」之防水劑;惟,仍有 於紙面,但,防水劑滲入紙纖維中 是表面塗著,又,其黏著力並不佳 一段時間後、或受不當之皺摺、溫度,即會有消失 之虞。 (2 )亦即,其非是與紙 耐用,而不適合做 一種短時間、暫時 厂Page 6 593606 Case No. 90126247 Amendment V. Description of the Invention (2) 2. The "coating water-repellent agent" is to improve the "adhesion to the surface of the paper, and" mix and stick the following disadvantages: (1) Although it can be The effect of thin coating is not good, it can be said that the waterproof film causes the problem of "thickening", and the water-repellent agent of water-repellent agent; However, it is still on the paper surface, but the water-repellent agent penetrates into the paper fiber is the surface If it is coated, its adhesion is not good for a period of time, or if it is improperly wrinkled or temperature, it may disappear. (2) That is, it is not durable with paper, not suitable for a short-term, temporary factory

LL

纖維滲合、結合力不強,故,較不 長時間之防潮、防水用途,可謂是 間之防水功能。 ------------1 本發明之技術、目的綱要I : ____________I 緣是,本發明乃針對上述傳統式之缺點而改良創作, 提供一種前所未有之防潮、防水塗料,其主要技術、目的 為: 其一 其 ’設成由「填料」 由塗料,得可加強 呈紙纖維整體不吸 得在紙表面再形成 濕氣、防水侵入紙 有極強之結合力’ ,因有上述之極佳 、「塗料」混合而成之防水劑,藉 滲入紙纖維中,充填其毛細孔,而 濕氣、不吸水之作用,藉由填料, 一阻隔、不附著水之隔層,加強防 纖維之作用,且,水阻隔層塗料具 而得提高防濕、防水之耐用性。 功效,而可呈液狀塗佈於紙面,並Fiber penetration and binding force is not strong, so it is a waterproof function for a short time to prevent moisture and water. ------------ 1 Outline of the technology and purpose of the present invention I: ____________I The reason is that the present invention is an improvement of the traditional shortcomings described above, and provides an unprecedented moisture-proof and waterproof coating. The technology and purpose are as follows: Firstly, it is “set to be made of“ filler ”and made of paint, which can strengthen the paper fibers as a whole, not absorb the moisture on the paper surface, and have a strong binding force to prevent water from entering the paper. It is an excellent waterproofing agent mixed with "coating". It penetrates into the paper fibers and fills its pores, and the effect of moisture and non-absorption is strengthened by the filler, a barrier that does not adhere to water The role of fibers, and the water barrier coating can improve the durability of moisture and water. Effect, and can be applied to the paper surface in a liquid state, and

第7頁 593606 案號 90126247 曰 修正 五、發明說明(3) 得呈極薄之狀態,達到幾乎不增厚紙之厚度,且可承 受彎摺,不會有破裂之虞,達到極佳之實用功效。 為讓 鈞局貴審核委員及習於此技藝人士,對本發明 之功效完全瞭解,茲配合圖式、舉一實施例,詳細說明於 下: 請參閱圖一,係將防潮、防水之紙塗料,設成由填料 、塗料混合而成;其中, 填料: 係以34. 6 %〜54· 95 %之水、0· 05 %〜0· 4 %之分散劑 、45%〜65%之雲母粉混合而成,並以ΡΗ值在9 〜10. 5之 液鹼,予「膨潤」作用,使雲母粉得軟化,即以儲存槽儲 存之; 塗料: 係以3 %〜1 5 %之澱粉及聚乙烯醇、0 · 5 %〜4 %之耐 水化劑、0. 5 %〜4 %之架橋劑、1 5 %〜4 0 %之乳膠、安定 劑、撥水劑、界面活性劑等混合劑、0. 2〜1. 5 %之潤滑劑 、0 · 2〜1 · 5 %之CMC /濕強劑混合而成; 再混合: 係將上述之塗料,混入填料,且依原紙材之性質需要 ,以80. 6 %〜34 % : 19. 4 %〜66 %之比例混合均勻,亦即 ,取上述填料之8 0. 6 %,再混合上述各劑比例所混合之塗 料,即製成防潮、防水之水阻隔層塗料,即可提供立即使 用塗佈於紙表面,或以儲存槽儲存; 藉由上述之構成,本發明之使用、功效,茲再細節說明於Page 593606 Case No. 90126247 Amendment V. Description of the Invention (3) It must be extremely thin, reach the thickness of almost no thick paper, and can withstand bending without the risk of cracking, achieving excellent practicality efficacy. In order to allow Jun Bureau's review members and those skilled in this art to fully understand the effects of the present invention, the following is a detailed description with drawings and an example: Please refer to Figure 1, which is a moisture-proof and waterproof paper coating. It is set to be a mixture of a filler and a paint; among them, the filler: is mixed with 34.6% ~ 54.95% water, 0.05% ~ 0.4% dispersant, and 45% ~ 65% mica powder. It is made with liquid alkali with a pH value of 9 ~ 10.5 to give a "swelling" effect to soften the mica powder, that is, to store it in a storage tank; Coating: 3% ~ 15% starch and polymer Vinyl alcohol, 0.5% ~ 4% water resistance agent, 0.5% ~ 4% bridging agent, 15% ~ 40% latex, stabilizer, water-repellent agent, surfactant and other mixed agents, 0.2 ~ 1.5% of lubricant and 0 · 2 ~ 1 · 5% of CMC / wet strength agent; Remix: Mix the above-mentioned coatings with fillers, and according to the nature of the original paper, Mix at 80.6% ~ 34%: 19.4% ~ 66%, that is, take 80.6% of the above fillers, and then mix the coatings mixed with each of the above agent ratios to make Tide, water waterproof barrier coatings can immediately provide the paper coating surface, or in a storage tank storing; by the above-described configuration, the present invention is used, the effect is hereby described in further detail

IfIf

593606 案號 90126247 年 月 修正 五、發明說明(4) 下: 使用時, 曰用糟中、再 ’其塗佈量控 得具有防濕、 又,本發 「填料」方面 水係可調 吸水、吸濕性 成平均分佈於 上形成一水阻 又,液驗 係將上述製 連接至塗佈 制在6〜1 2 g 防水之紙成 明各細節之 和分散劑、 ,且,當塗 紙面之效果 隔層,而得 方面,乃一 成之防潮、防水塗料,予輸送至 機,而將塗料塗佈於原紙之表面 / m2. s,即可予乾燥、捲收,而 品 ° 功效、作用,兹一 一說明如下: 母粉可謂是一極微小之雲 之作用,即 極佳之結合 題。 產生膨 母粉( 彎折之 「塗料 其 具有黏 用,而 劑、安 成一光 體結合 「實用 鬆軟化 片)可 剝離問 」方面 澱粉及 著性之 乳膠則 定劑乃 滑、不 ,達到 性」方 聚乙烯醇, 作用,其耐 可加強塗料 可使各劑能 沾著水份之 更佳之防濕 面:593606 Case No. 90126247 Amendment V. Description of the invention (4) Under: When in use, it should be used in the process, and then its coating amount can be controlled to prevent moisture, and the water system of the "filler" of the hair can be adjusted to absorb water. The hygroscopicity is evenly distributed on the surface to form a water resistance. The liquid test system connects the above-mentioned system to a 6 to 12 g waterproof paper coated with a dispersant, and when the coated surface is The effect of the barrier, and the aspect, is a 10% moisture-proof and waterproof coating, which is conveyed to the machine, and the coating is coated on the surface of the base paper / m2. S, which can be dried and rolled up, and the product ° Here are the explanations as follows: The mother powder can be described as a tiny cloud, which is an excellent combination. In the case of bulking powder (bending "the paint has a sticky effect, and the agent, Ancheng Yiguang combined with" practical softening tablets) can be peeled off ", the starch and the characteristic latex are slippery, no, reachability" Polyvinyl alcohol, function, its resistance can strengthen the coating can make each agent can get better moisture-proof surface:

雲母粉、液驗,而雲母粉係不具 佈於紙面時配合其分散劑,得形 ,故,藉由雲母粉,恰似在紙面 防止水份之侵入。 種可使雲母片軟化之化學劑,雲 母片,以液鹼作用之,得使雲母 是所謂之「膨潤處理」,俾使雲 於紙面、並呈可撓性,防範紙受 可得再增進充填紙纖維毛細孔及 水化劑、撥水劑可得排斥水之作 黏著於紙面之結合力,又,架橋 充份混合,潤滑劑則可在表面形 作用,故可呈由紙材之内、外一 、防水性。Mica powder, liquid test, and mica powder is not dispersant with the dispersant when the paper surface, so the shape of the mica powder, just like to prevent the invasion of water on the paper surface. A chemical agent that can soften mica flakes. Mica flakes are treated with liquid alkali to make the mica a so-called "swelling treatment", so that the mica is on the surface of the paper and is flexible, preventing the paper from becoming available and increasing the filling. Paper fiber pores, hydrating agents and water-repellent agents can obtain the binding force that repels water to adhere to the paper surface. In addition, the bridge is fully mixed, and the lubricant can act on the surface, so it can be made of paper. Outside, waterproof.

593606 a 修正 案號 90126247 五、發明說明(5) 由上述之說明,本發明之塗料,具有極佳之防渴、防 水功效,及其與紙面之結合力強,尤其,係參入紙纖維毛 、細孔t,因λ,可# μ、外阻絕濕氣、水份之作用。並且 ,因具有上述之功效,而得呈極薄塗佈於紙面(塗佈量約 6〜12g/nf.S),故可得不過份增厚紙厚度之功效,又因 係滲入紙纖維毛細孔中之防濕、防水作用,而可得耐用性 佳、可供皺摺,達到極佳之實用功效。 另,依上述之技術、配方、創意,本發明亦可實施呈 :先取出80· 6 %〜34 %之經膨潤處理之填料,再依序各別 混合3 %〜1 5 %之殿粉及聚乙細醉、0.5%〜4%之耐水化 劑、0 · 5 %〜4 %之架橋劑、1 5 %〜4 %之乳膠、安定劑、 撥水劑、界面活性劑、〇 · 2 %〜1 · 5 %之潤滑劑、〇 · 2 %〜 1 · 5 %之CMC /濕強劑,亦屬本發明等效實施之創意範脅内 綜上所述’本發明於「防水紙」物品領域,確實是t 所未有之創作,而所達成之實用性,亦確實具有極二=^ 業貫用價值,誠符合專利法之規定,懇請賜准專利,本咸 德便。 貝欢 第10頁593606 a Amendment No. 90126247 V. Description of the invention (5) From the above description, the coating of the present invention has excellent thirst-proofing and waterproofing effects, and has strong binding force with the paper surface, especially the paper fiber , Pores t, due to λ, can # μ, externally block the effects of moisture and moisture. In addition, because of the above-mentioned effect, it can be coated on the paper surface very thinly (the coating amount is about 6 ~ 12g / nf.S), so the effect of not excessively thickening the thickness of the paper can be obtained, and it is due to the penetration of the paper fiber capillaries The moisture-proof and water-proof effect in the holes, and it has good durability and can be wrinkled to achieve excellent practical effects. In addition, according to the above-mentioned technologies, formulas and ideas, the present invention can also be implemented as follows: first take out 80.6% ~ 34% of the swelling filler, and then mix 3% ~ 15% of the powder and Polyethyl alcohol, 0.5% ~ 4% water resistance agent, 0.5% ~ 4% bridging agent, 15% ~ 4% latex, stabilizer, water-repellent agent, surfactant, 0.2% ~ 1.5% of lubricant, 0.2% ~ 1.5% of CMC / wet strength agent, also belong to the creative scope of the equivalent implementation of the present invention. In summary, the invention is in "waterproof paper" articles. The field is indeed an unprecedented creation of t, and the practicability achieved is indeed extremely valuable. It is in line with the provisions of the Patent Law, and I would like to ask for a patent. Behuan Page 10

II 593606 _案號90126247_年月日 修正 圖式簡單說明 圖式簡單說明: 圖一,係本發明之配方及製成之流程方塊圖II 593606 _Case No. 90126247_ Year, Month, and Day Amendment Brief description of the diagram Brief description of the diagram: Figure 1 is a block diagram of the formula and process of the present invention

Claims (1)

593606 修正 ____索號 90126247 _±__^日 六、申請專利减圍 ’係將防潮、防水之 ;其中, 1 · 一種防潮 '防水紙塗料之配製 紙塗料’設成由填料、塗料混合而成 填料· 係以34· 6 %〜54· 95 %之水、〇 · 〇5 %〜〇· 4 %之分散劑 、45 %〜65 %之雲母粉混合而成,並以ph值在9〜1〇.5^ 液鹼,予「膨潤」作用,使雲母粉得軟化,即以儲存槽儲 存之; 塗料· 係以3 %〜15 %之澱粉及聚乙烯醇、〇· 5 %〜4 %之耐 水化劑、0.5%〜4 %之架橋劑、15 %〜4〇%之乳膠、安定 劑、撥水劑、界面活性劑等混合劑、〇· 2〜1· 5 %之潤滑劑 、0 · 2〜1 · 5 %之C M C /濕、強劑混合而成; 再混合: 係將 ,以 8 0 · 6 ,取上述 料,即製 用塗佈於 藉由上述 毛細孔中 2.如 配製;其 〜34 %之 之澱粉及 上述之塗 % 〜3 4 % 填料之8 0 成防潮、 舐表面, ,得製成 之防濕、防 申請專利 中,該填 經膨潤處 聚乙烯醇 :19· 4 % 〜66 .6 %,再混合 防水之水阻隔 或以儲存槽儲 一具有與紙面 水塗料者。 範圍第1 項戶斤 料與塗料之混 理之填料,再、0 · 5 % 〜4 % ’且依原紙材之性質需要 /之比例混合均勻,亦即 上述各劑比例所混合之塗 層塗料,即可提供立即使 存; 極強結合力、渗入紙纖維 述之防潮、防水紙塗料之 合’可設成先取出80. 6% 依序各別混合3 %〜1 5 %之耐水化劑、0. 5 %〜4 %593606 Amend ____ cable number 90126247 _ ± __ ^ Day six, the patent application for "encirclement protection" will be moisture-proof and waterproof; among them, 1 · A moisture-proof 'waterproof paper coating formulation paper coating' is set by mixing fillers and coatings Filler · Mixed with 34 · 6% ~ 54.95% water, 0.005% ~ 0.4% dispersant, 45% ~ 65% mica powder, and a pH value of 9 ~ 10.5 ^ liquid alkali, give "swelling" effect, soften mica powder, that is, store it in a storage tank; Coatings · 3% ~ 15% starch and polyvinyl alcohol, 0.5% ~ 4% Water-resistant agent, 0.5% ~ 4% bridging agent, 15% ~ 40% latex, stabilizer, water-repellent agent, surfactant and other mixed agents, 0.2 ~ 1.5% lubricant, 0 · 2 ~ 1 · 5% of CMC / wet and strong agent mixed; Remixing: Take the above material at 80 · 6 and apply it to the capillaries through the above 2. If prepared ; Its ~ 34% of starch and the above coating% ~ 3 4% of 80% of the filler into a moisture-proof, concrete surface, which can be made into a moisture-proof and anti-patent application. Polyvinyl alcohol: 19.4% ~ 66.6%, mixed with waterproof water barrier or stored in a storage tank with water paint on paper. The first filler in the range is mixed filler with paint, and then 0.5% to 4%, and it is mixed uniformly according to the nature of the original paper. , Can provide immediate storage; strong binding force, penetration of paper fiber, moisture-proof, waterproof paper coatings can be set to take out 80. 6%, respectively, sequentially mix 3% ~ 15% of the water-resistant agent 0.5% ~ 4% 593606593606 第13頁Page 13
TW90126247A 2001-10-24 2001-10-24 Preparation of coating for moistureproof/waterproof paper TW593606B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113605140A (en) * 2021-07-13 2021-11-05 美盈森集团股份有限公司 Polylactic acid waterproof coating material, preparation method and paper pulp molding

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113605140A (en) * 2021-07-13 2021-11-05 美盈森集团股份有限公司 Polylactic acid waterproof coating material, preparation method and paper pulp molding

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