587148 經濟部智慈財產局員工消費合作社印製 A7 B7 五、發明説明（1 ) 【發明所屬之技術領域】 本發明，係有關冷藏庫在冷氣之循環經路內用以配置 脫臭裝置將庫內進行脫臭。 【先前之技術】 由習知技術，家庭用之冷藏庫中，係起因於庫內之食 品的各種臭氣低減或爲了用以防止移味到其他食品，被進 行將白金觸媒進行配置於除霜加熱器之近傍。又，近年之 家庭用冷藏庫中，係被提供將冷藏室及冷凍室以個別設置 冷卻之冷卻器，用以設定更高冷藏室內之濕度使食品之鮮 度保持效果提高。如此用以提高冷藏室內之濕度，則由於 更容易感覺臭氣，或在冷藏室內容易使雜菌繁殖，所以前 述冷藏庫中，係被導入脫臭裝置藉由臭氧之氧化分解作用 具有強力的脫臭效果。 但是，利用臭氧之氧化分解作用之方法，也由於臭氣 成分係未完全被氧化分解而停留於中間分解生成物。又， 以利用臭氧之氧化力的方法，係不能完全分解促進青水果 之老化的乙烯。 【發明所欲解決之問題】 相對地，本申請人，係用以發明冷藏庫將組合臭氧之 氧化分解作用及藉由紫外線之光觸媒作用的脫臭裝置配置 於庫內，首先提出申請（日本專利（案）特願2000-1 8 1 5 1 8)。前述脫臭裝置，係在被配置於冷藏庫內 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ΊΊ^--：丨-φ-裝----.丨If------Φ (請先閱讀背面之注意事項再填寫本頁) -4 - 587148 經濟部智慧財產局員工消費合作社印製 ΑΊ Β7 五、發明説明（2 ) 之循環經路的箱內，被構成用以配置空間放電機構，光觸 媒模組，臭氧分解觸媒過濾器。 該情形，前述空間放電機構，係被考慮由被配置於光 觸媒模組之前後的一對網眼狀電極加以構成。如此，根據 一對之電極藉由進行構成能挾持光觸媒模組可使光觸媒有 效激勵。又，將電極藉由進行構成爲網眼狀，可將管道內 之壓力損失儘可能抑制爲最小。 但是，空間放電機構中爲了取得穩定之放電係有必要 以固定用以保持一對網眼狀電極間之距離。可是，網眼狀 電極係因爲皆非常的薄而強度小，所以固定困難，使電極 間之距離會有部分性差異之虞。 又，光觸媒模組係有構造上，厚度尺寸之偏差大的情 形。因此，將光觸媒模組以一對網眼狀電極做爲挾持構成 ，則依然，難以固定用以保持電極間之距離。如此使電極 間之距離局部性的差異，則產生局部性的放電而不能取得 有效的脫臭性能。 本發明係有鑑於上述情形而被發明，其目的在於··提 供具備脫臭裝置之冷藏庫將放電裝置由一對網眼狀電極進 行構成時，以固定用以保持前述網眼狀電極間之距離可取 得穩定之放電。 【解決問題之手段】 本發明申請專利範圍第1項之冷藏庫，係被構成在冷 氣之循環經路內用以配置脫臭裝置爲了進行庫內之脫臭的 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ^ ^ ^-裝 „ 訂 : (請先閱讀背面之注意事項再填寫本頁) -5- 587148 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（3 ) 冷藏庫中，其特徵爲：前述脫臭裝置，係具備光觸媒組合 被構成以一體用以組裝具備被配置成平行之一對網眼狀電 極藉由高壓電放電使產生臭氧及紫外線之放電裝置，及藉 由被照射前述紫外線根據產生光觸媒作用進行被含於冷氣 中之臭氣成分和有害物質等之分解的光觸媒模組，以及用 以收容前述放電裝置及前述光觸媒模組之箱所構成，同時 將前述網眼狀電極分別被固定於前述箱。 若依據上述構成，則因爲可防止被配置成平行之一對 網眼狀電極不穩使前述網眼狀電極間之距離部分性的進行 變動，所以由放電裝置可取得穩定之放電。又，網眼狀電 極係使厚度尺寸非常小且強度性弱，光觸媒模組係非常脆 弱會有容易損壞的情形，但若依據上述構成，則在光觸媒 組合之狀態下可將放電裝置和光觸媒模組組裝於脫臭裝置 。因此，在組裝作業時可防止光觸媒模組和網眼狀電極之 破損。 該情形，將前述箱，由第1箱及第2箱進行構成，並 將一對網眼狀電極，分別構成能挾入於前述第1箱及前述 第2箱爲佳（申請專利範圍第2項之發明）。若依據上述 構成，則將一對網眼狀電極可確實進行固定於箱。 又，將第1及第2箱中之至少一方，具備凹狀之收容 部加以構成，在前述收容部將一對網眼狀電極之中的一方 ，光觸媒模組，他方之網眼狀電極，及他方之箱依順序組 裝用以構成光觸媒組合也是良好的構成（申請專利範圍第 3項之發明）。 (請先閲讀背面之注意事 項再填< :寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -6- 587148 A 7 B7 五、發明説明（4 ) (請先閲讀背面之注意事項再填寫本頁} 若依據上述構成，則使光觸媒組合之組裝作業性進行 提高。又，以一對網眼狀電極因爲使光觸媒模組被挾入之 構成，所以藉由放電裝置中之高電壓放電將產生之紫外線 可有效進行照射於光觸媒模組。 進而，在一對網眼狀電極及光觸媒模組之間，分別設 置緩衝構件也是良好的構成（申請專利範圍第4項之發明 )。該情形，前述緩衝構件，係由矽膠所構成（申請專利 範圍第5項之發明），或由發泡體所構成（申請專利範圍 第6項之發明），或構成爲中空狀（申請專利範圍第7項 之發明）爲佳。 若依據上述構成，則一對網眼狀電極，係分別藉由緩 衝構件在被壓緊於第1及第2箱之狀態下被固定於前述箱 。因此，將網眼狀電極間之距離僅可用以確保第1箱及第 2箱之間的距離。又，藉由前述緩衝構件可用以吸收前述 光觸媒模組之厚度尺寸的偏差。 經濟部智慧財產局員工消費合作社印製 又，前述緩衝構件中在光觸媒模組側之面，設置凹凸 也是良好的構成（申請專利範圍第8項之發明）。若依據 上述構成，則可用以縮小緩衝構件及光觸媒模組之接觸部 分，所以在緩衝構件挾入光觸媒模組時可防止前述光觸媒 模組進行破損。 而且，在前述箱，設置內部確認用之窗部爲佳（申請 專利範圍第9項之發明）。若依據上述構成，則被收容於 箱內之放電裝置及光觸媒模組之零件是否有欠缺通過前述 窗部可進行確認。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -7- 587148 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（5 ) 【發明之實施形態】 以下，將本發明第1實施形態參考圖1至圖1 〇並力口 以說明。首先，圖1，係顯示有關本實施例冷藏庫之縱剖 側面圖。該圖1中，由隔熱箱體所構成冷藏庫本體1之內 部，係藉由隔熱間隔壁2被間隔成上部冷藏室3及下部冷 凍室4。有關本實施例之冷藏庫，係使前述冷藏室3及冷 凍室4藉由前述隔熱間隔壁2被分離，分別藉由專用之冷 卻器（冷藏室用冷卻器3 a、冷凍室用冷卻器4 a )根據 被生成冷氣使內部被冷卻形成構成。本實施例中，係在前 述冷藏室3內之冷氣循環經路被配設有脫臭裝置5 ,以下 ，將前述冷藏室3之構成爲中心加以說明。 即，在前述冷藏室3內之下部，係藉由間隔板6被形 成有蔬菜室7，在前述蔬菜室7之後部係藉由間隔壁8被 形成有冷藏室用冷卻器室9。在前述蔬菜室7內，係被收 容有搭載於下箱1 0及該下箱1 〇之上部的上箱1 1。在 前述上箱1 1之上面係使具有冷氣流出孔1 2 a之箱蓋 1 2被安裝成可開關，在前述箱蓋1 2及前述間隔板6之 間被形成有冷氣通路1 3。 在前述冷藏室3內之下部，係被配設有冷藏箱14, 在前述冷藏箱1 4及前述間隔板6之間被形成有冷氣通路 1 5。進而，在前述冷藏室3內之後部及上部，係藉由略 呈L字狀之管道蓋1 6被形成有冷氣管道1 7。在前述管 道蓋1 6，係被形成有複數之冷氣吐出孔19。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事 4 項再填< 裝— 寫本頁) 、?! -8 - 587148 A7 B7 五、發明説明（6 ) 又，在前述冷卻器室9內係被配設有冷藏室用扇裝置 (請先閲讀背面之注意事項再填寫本頁) 1 9，對應於該扇裝置1 9在前述間隔壁8之上部係被設 有圓筒狀之冷氣吐出部2 0。前述冷氣吐出部2 0之前端 開口部，係定位於前述上箱1 1內。相對地，在前述冷卻 器室9內之下部係被配設有前述冷藏室用冷卻器3 a。而 且，在前述間隔壁8之下部的前部，係被設有天窗狀之冷 氣吸入口 2 2。 又，在冷藏庫本體1之下部係被形成有機械室2 3 , 在其內部係被配設有冷卻循環之壓縮機2 4。前述壓縮機 2 4係將壓縮機馬達做爲驅動源之往復式發動機。 另外，在前述間隔板6之右後部係被配設有前述脫臭 裝置5。以下，參考圖2至圖7對於脫臭裝置5之構成加 以說明。脫臭裝置5，係由箱本體2 5及由覆蓋該箱本體 2 5之上面開口部之蓋2 6所構成單元箱2 7，以及被配 置於前述箱本體2 5內之昇壓變壓器2 8，光觸媒組合 2 9 ,臭氧分解觸媒3 0被構成。 在前述箱本體2 5內之左部，係被構成藉由間隔壁 經濟部智慧財產局B工消費合作社印製 3 1被形成有變壓器室3 2，在該變壓器室3 2之內部被 配置前述昇壓變壓器2 8。 前述昇壓變壓器2 8，係將1次線圈，2次線圈，磁 鐵心等（皆未圖示）藉由合成樹脂根據進行模型成形被構 成。前述昇壓變壓器2 8，係通過給電線3 3由未圖示1 次側端子被給電被構成。又，在前述昇壓變壓器2 8之圖 2中右部係使一對2次側端子3 4 a、3 4 b進行突出， 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -9- 587148 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（7 ) 並被設有】字狀之包圍部3 5 a、3 5 b能包圍各2次側 端子34a、34b之周圍三方。進而，在前述昇壓變壓 器2 8之圖2中右部之上下部，係被設有爪部3 6 a、 3 6 b 〇 前述箱本體2 5內之中前述變壓器室3 2以外之空間 係被做爲冷氣流通室3 7，在其底部之前部係被立設有延 伸於左右方向之防護壁3 8。前述防護壁3 8之高度尺寸 ，係被設定成前述箱本體25約高度尺寸的一半。又，前 述冷氣流通室3 7之中前後方向的中央部，係被構成被配 置前述光觸媒組合2 9，箱本體2 5底部之中在光觸媒組 合2 9之配置部分係被設有定位用之肋3 9。 又，在冷氣流通室3 7之最後部，係形成被配置有前 述臭氧分解觸媒3 0，並在其配置部分之底部係被設具有 多數矩形狀之通氣孔4 0 a之格子框部4 0。用以構成前 述格子框部4 0之各框部，係使與臭氧分解觸媒3 0之下 部進行接觸之面積儘量變小被構成爲剖面三角形狀（參考 圖3及圖7 )。 前述臭氧分解觸媒3 0，係譬如將氧化錳基礎之陶瓷 製蜂窩結構（成形品）或金屬蜂窩結構成形爲矩形板狀做 爲鐵心材，被構成用以固定觸媒成分。如此做爲蜂窩構造 ，將臭氧分解觸媒3 0及臭氧或臭氣成分之接觸面積進行 更大確保，使分解效率提高。前述臭氧分解觸媒3 0，係 藉由蜂窩形狀使通氣方向成爲上下方向被配置於格子框部 4 0上。 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -10 - 587148 A7 B7 五、發明説明（8 ) (請先閱讀背面之注意事項再填寫本頁) 尙有，前述臭氧分解觸媒3 0之鐵心材係非常脆弱， 在組裝作業時不注意碰到會有破損之虞。因此，在本實施 例係在前述臭氧分解觸媒3 0之外周部捲繞軟帶3 0 a， 在組裝作業用以防止破損。又，箱本體2 5之中將臭氧分 解觸媒3 0之配置部分做爲格子框部4 0。因此，在組裝 於箱本體（單元箱2 7 )內之臭氧分解觸媒3 0會誤碰， 可用以防止手指附著觸媒成分，或破損。 另外，前述蓋3 0，係被構成將被立設於其下面之輪 轂部4 1進行插通於被設在箱本體2 5之孔部4 2藉由用 以螺插螺釘4 3被安裝於前述箱本體2 5。在前述蓋3 0 之前部，係使延伸於下方之天窗4 4以一體被設置，將前 述蓋3 0安裝於箱本體2 5時被構成有使前述天窗4 4之 下端部在箱本體2 5之前端部由上方進行擋接。藉由前述 天窗4 4，在單元箱2 7內形成使異物被防止進行侵入。 經濟部智慧財產局員工消費合作社印製 又，蓋3 0之下面之中在前述天窗4 4之近後方部， 係被設有延伸於左右方向爲止之防護壁4 5。如圖3所示 ，前述防護壁45及箱本體25側之防護壁38,係在單 元箱2 7內在前後進行偏置被配置。藉此，不會妨礙冷氣 流通室3 7內之冷氣流通，被構成能用以防止異物之侵入 。進而，將前述蓋3 0之下面中之蓋3 0安裝於箱本體 25時在定位於臭氧分解觸媒30之上方部分，係被設有 延伸於下方之3個臭氧擴散構件4 6。進而又，在前述蓋 3 0之後部，係被設有延伸於下方之肋4 7 ,在該肋4 7 之左右方向的中央部被設有孔部4 8。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -11 - 587148 A7 B7 五、發明説明（9 ) 其次，對於前述間隔板6之構成參考圖2及圖3並力口 &說明。在前述間隔板6之右部的靠後部分，係爲了組裝 ^臭裝置5被形成有矩形容器狀之安裝凹部4 9。前述間 _板6之中在前述安裝凹部4 9之兩側，係將庫內之循環 &氣不通過脫臭裝置5由冷藏室爲了使直接流入到蔬菜室 7被設有流通口 5 0。在前述安裝凹部4 9之後半部被構 成能被設置前述單元箱27，在其底部係被設有圓形狀之 排水孔5 1及矩形狀之開口 5 2。前述開口 5 2，係被配 置單元箱2 7時進行定位於前述格子框部4 0之下部。 又，在前述安裝凹部4 9之前部係被設有傾斜面5 3 。進而，在前述安裝凹部49之底部中使單元箱27之天 窗4 4定位之部位的前部，係被形成有長圓狀之排水孔 5 4。前述排水孔5 4，係使用者錯誤在庫內使水等溢出 時，爲了用以防止該水等侵入到單元箱2 7內。進而，在 前述安裝凹部4 9之後半部的周緣部，係被形成有肋5 5 。前述肋5 5 ,也爲了用以防止由周邊部使水等侵入到單 元箱2 7內。 前述單元箱2 7 ,係將前述蓋3 0之孔部4 8，合對 於被設在安裝凹部4 9之後側的孔（未圖示）由上方藉由 用以插入固定器5 7，使前述單元箱2 7被安裝於安裝凹 部4 9。 其次，對於光觸媒組合2 9之構成加以說明。圖8係 顯示光觸媒組合2 9之分解斜視圖，圖9係顯示用以連結 光觸媒組合2 9及昇壓變壓器2 8之狀態的斜視圖，此等 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 -12- 587148 A7 B7 五、發明説明（1〇) 圖8及圖9中，光觸媒組合29，係由第1箱58及第2 箱5 9所構成箱6 0，及被收容於前述箱6 0內之放電裝 置的第1及第2電極構件6 1及6 2，緩衝構件之隔板 6 3及6 4，以及光觸媒模組6 5被構成。前述第1電極 構件6 1，係由以矩形框6 6 a被緣取之網眼狀電極6 6 及被設於前述矩形框6 6 a之圖8中左上部之端子板6 7 被構成。又，第2電極構件6 2，係由比以矩形框6 8 a 被緣取之前述網眼狀電極6 6更粗眼的網眼狀電極6 8及 被設於前述矩形框6 8 a之圖8中左下部之端子板6 9被 構成。 前述隔板6 3、6 4，係皆由難燃性之矽膠被構成， 被構成爲具有並列於左右之2個矩形狀的窗部6 3 a、 6 4 a之框狀。前述隔板6 3、6 4，係與白色之光觸媒 模組6 5能容易進行區別，被著色成黑色。除了用以區分 前述隔板63、64之中前述窗部63a、64a部分的 部分之外，係與前述第1及第2電極構件6 1及6 2之矩 形框6 1 a及6 2 a被構成略同形狀。前述隔板6 3、 6 4之中在光觸媒模組6 5側之面，係被設有多數之凸部 7 0 (在圖8係僅示隔板6 3之凸部7 0 )。 前述光觸媒模組6 5 ,係在由多孔質狀之陶瓷（氧化 鋁，二氧化矽等）所構成矩形板狀之鐵心材的表面用以塗 布氧化鈦等之光觸媒材料，使乾燥或燒結藉由加以固定被 構成。前述第1第2電極構件6 1及6 2之網眼狀電極 66及68，隔板63及64，光觸媒模組65之左右方 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁} 裝· 訂 經濟部智慧財產局員工消費合作社印製 -13- 587148 經濟部智慈財產局員工消費合作社印製 A7 B7五、發明説明（11 ) 向及上下方向的長度尺寸，皆被設定成略同。 前述第1箱5 8，係被構成具有開口於上方之收容凹 部7 1，及被設於該收容凹部7 1之圖8中左部的一對凹 狀之端子配置部7 2、7 3。在前述收容凹部7 1，係被 構成使第1電極構件6 1之網眼狀電極6 6，隔板6 3， 光觸媒模組6 5，隔板6 4，第2電極構件6 2之網眼狀 電極6 8依順序被收容。又，在前述端子配置部7 2、 7 3 ,係被構成使第1電極構件6 1及第2電極構件6 2 之端子板6 7及6 9分別被配置。在前述收容凹部7 1之 圖8中，下面部，係使與前述隔板6 3及6 4之窗部 6 3 a及6 4 a對應之略矩形狀的窗部7 1 a被設置並例 於左右。 又，前述第1箱5 8之中在收容凹部7 1之圖8中前 後側部，係使定位凹部7 4及1對嵌合部7 5分別被設置 (圖8中係僅示前側部之定位凹部7 4 )。進而，在第1 箱5 8之收容凹部7 1之圖8中右側部，係被設有定位凹 部7 6。前述嵌合部7 5，係在其左右部被設有切口 7 5 a被構成可彈性變形。 進而又，第1箱58之中在各端子配置部72、73 之圖8中前後側部之左端部，係分別被設有嵌合部7 7、 7 8。前述嵌合部7 7、7 8 ,係在其右部分別被設有切 口 7 7 a、7 8 a被構成可彈性變形。 前述第2箱5 9，係被構成在第1箱5 8由圖8中上 方能嵌入，由對應於前述收容凹部7 1在下方成凸之收容 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -14- 587148 A7 B7 五、發明説明（12 ) 凸部7 9，及對應於各端子配置部72、7 3在下方成凸 之端子配置部8 0、8 1被構成。在前述收容凸部7 9之 圖8中下面部，係使對置於前述窗部7 1 a之矩形狀的窗 部7 9 a被設置並列於左右。又，第2箱5 9之中在前述 收容凸部7 9之圖8中前後側部及右側部，係在前述定位 凹部7 4、7 6分別被設有對應之定位凸部8 2、8 3。 進而，第2箱5 9之中在收容凸部7 9之圖8中前後側部 及各端子配置部8 0、8 1之前後側部，係被設有對應於 前述嵌合部75、77、78之爪部84〜86。在前述 爪部8 4〜8 6之左右部，係分別被設有切口 8 4 a〜 8 6 a，被構成可彈性變形。 _ 且說，在前述第1箱5 8之端子配置部7 2用以配置 第1電極構件6 1之端子板6 7同時在收容凹部7 1依順 序用以配置第1電極構件6 1之網眼狀電極6 6，隔板 6 3，光觸媒模組6 5，隔板6 4，第2電極構件6 2之 網眼狀電極6 8，進而將第2電極構件6 2之端子板6 9 配置於端子配置部7 3之後，將第2箱5 9嵌入於第1箱 58，使爪部84〜86在嵌合部75、77、78分別 藉由嵌合被構成光觸媒組合2 9。 此時，通過前述嵌合部7 5被構成可用以視認箱6 0 內。因此，在組裝光觸媒組合2 9之後也可容易確認有無 缺品。 又，使定位凸部8 2、8 3藉由被卡止於定位凹部 7 4、7 6，在收容凹部7 1及收容凸部7 9之間使預定 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) -裝· 、-** 經濟部智慧財產局員工消費合作社印製 -15- 587148 A7 B7 五、發明説明（13 ) (請先閲讀背面之注意事項再填寫本頁) 空間被確保。前述空間，係將網眼狀電極6 6，隔板6 3 ，光觸媒模組6 5，隔板6 4，網眼狀電極6 8與重疊之 厚度尺寸被設定成略同，該結果，網眼狀電極6 6 ,隔板 6 3，光觸媒模組6 5，隔板6 4，網眼狀電極6 8係不 會過壓縮被挾持於第1及第2箱5 8及5 9間之狀態下被 固定。藉由上述構成，使非常脆弱容易損壞光觸媒模組 6 5，將第2箱5 9嵌入於第1箱5 8時可儘力防止破損 〇 圖1 0，係顯示光觸媒組合2 9之中以收容凹部7 1 及收容凸部7 9將被挾持之部分以模式性的縱剖面圖。如 該圖1 0所示，在收容凹部7 1及收容凸部7 9之間的空 間，係在被配置成平行之網眼狀電極6 6、6 8之間使光 觸媒模組6 5進行定位。而且，使前述空間由於被設定成 上述之尺寸，所以各網眼狀電極6 6、6 8，係藉由隔板 63、64分別被壓緊於第1及第2箱58及59。因此 ，網眼狀電極6 6、6 8係使其間之距離不會部分性的差 異被保持成平行。 經濟部智慈財產局員工消費合作社印製 但是，光觸媒模組6 5係使構造上，厚度尺寸之偏差 變大。可是，在本實施例，係隔板6 3、6 4之中在與光 觸媒模組6 5接觸之面因爲設有凸部7 0 ,所以可用以吸 收光觸媒模組6 5之厚度尺寸的偏差，由此點也使網眼狀 電極6 6、6 8間之距離可防止部分性的差異。 又，如圖2及圖9所示在光觸媒組合2 9之左部係將 端子配置部7 2和端子配置部8 0及端子配置部7 3和端 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -16- 587148 經濟部智慈財產局員工消費合作社印製 A7 B7_五、發明説明（14 ) 子配置部8 1分別進行嵌合被構成成爲一對端子部8 7 ' 8 8。此時，在前述端子部8 7、88之前端，係使前述 昇壓變壓器2 8之2次側端子34a、34b被插入與前 述第1及第2電極構件6 1及6 2之端子板6 7、6 9被 連接使端子插入口（未圖示）被形成。 因此，將前述昇壓變壓器2 8之2次側端子3 4 a、 34b插入於前述端子插入口並將包圍部35a、35b 藉由嵌入於端子部8 7、8 8 ,使前述2次側端子3 4 a 、3 4 b及端子板6 7、6 9分別被連接之狀態下，使昇 壓變壓器2 8及光觸媒組合2 9被連結。此時，前述昇壓 變壓器2 8之爪部3 6 a、3 6 b係被構成進行定位於光 觸媒組合2 9之端子部8 7、8 8之外側被卡止於切口 7 7 a、7 8 a。 前述昇壓變壓器2 8及光觸媒組合2 9，係以被連結 之狀態下使第1箱5 8定位於前部被配置於變壓器室3 2 及冷氣流通室3 7。此時，冷氣流通室3 7之中在前述光 觸媒組合2 9之右部係使冷氣不通過該光觸媒組合2 9爲 了使朝向後方成爲形成分流8 9 (參考圖4 )。 尙有，被配置於冷氣流通室3 7之光觸媒組合2 9， 係使嵌合部7 5形成定位於其上部。因此，將光觸媒組合 2 9設置於冷氣流通室3 7之後，可用以再度確認有無箱 6 0內之缺品。 而且，在網眼狀電極通過昇壓變壓器2 8使高壓電壓 被外加藉由被進行放電，使紫外線（波長3 8 0 n m以下 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐厂 (請先閲讀背面之注意事項再填寫本頁) 一裝. 訂 -17- 587148 A7 _ _B7 五、發明説明（15 ) )和臭氧被產生。 其次，對於本實施例之作用參考圖1、圖3、圖4及 圖7並加以說明。本實施例之冷藏庫中，藉由未圖示控制 裝置關於冷藏室3之溫度設定資訊和溫度資訊，冷藏用冷 卻器3 a之溫度資訊，關於冷凍室4之之溫度設定資訊和 溫度資訊，根據冷凍用冷卻器4 a之溫度資訊等使壓縮機 2 4和脫臭裝置5等之運轉被控制。而且，用以判斷進行 冷藏室3之冷卻運轉時，則前述控制裝置係由前述壓縮機 2 4將被吐出之冷媒進行供給到冷藏用冷卻器3 a ,同時 用以開始前述冷藏用扇裝置19及前述脫臭裝置5之運轉 〇 於是，冷卻器室9內之冷氣的一部分，係如圖1箭頭 所示，由冷氣吐出部2 0被吐出於上箱1 1內並通過冷氣 流出孔1 2 a被放出於冷氣通路1 3內。被吐出於冷氣通 路1 3內之冷氣係沿著下箱1 0之前面及下面流動，並通 過冷氣吸入口 2 2被反回到冷卻器室9內。 相對地，冷卻器室9內之冷氣殘留，係通過冷氣管道 17進行上昇，由冷氣吐出孔18及冷氣管道17之上端 部被吐出到冷藏室3內。被吐出於冷藏室3內之冷氣，係 通過冷藏箱1 4之下方的冷氣通路1 5，大部分係通過被 形成於間隔板6之流通口 5 0和排水孔5 1直接進行流入 到蔬菜室7。而且，通過冷氣通路1 5之冷氣殘留係通過 天窗4 4進行流入到脫臭裝置5之冷氣流通室3 7。 流入到冷氣流通室3 7之冷氣的一部分，係通過光觸 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 【裝· 訂 經濟部智慧財產局員工消費合作社印製 -18- 587148 A7 ____B7 五、發明説明（16 ) 媒組合2 9之後，到達臭氧分解觸媒3 0。又，流入於冷 胃流通室37之冷氣殘留，係通過分流89到達臭氧分解 觸媒3 〇。 光觸媒組合2 9中，係在網眼狀電極6 6、6 8間通 @昇壓變壓器2 8使高壓電壓被外加並藉由放電被進行， 使紫外線（波長3 8 0 n m以下）和臭氧進行產生。而且 ，使該紫外線被照射於光觸媒模組6 5 ,則使氧化鈦接受 該紫外線之光能源帶有活性形成光觸媒作用，用以分解被 含有冷氣之氨等之臭氣成分和乙烯氣體。特別，在本實施 例，係在網眼狀電極6 6、6 8間用以配置光觸媒模組 6 5，所以使無指向性之紫外線在光觸媒模組6 5有效產 生作用。 又，藉由高電壓放電產生之臭氧，係通過光觸媒組合 2 9之冷氣及通過分流8 9之冷氣一起到達臭氧分解觸媒 3 0。此時，使光觸媒組合2 9方面比臭氧分解觸媒3 0 幅度尺寸較小，但藉由被設於蓋2 6下面之臭氧擴散構件 4 6，以光觸媒組合2 9產生之臭氧係被擴散到臭氧分解 觸媒3 0之全體。以臭氧分解觸媒3 〇，係使臭氧被分解 並使活性氧進行產生，藉由該活性氧之氧化力使被含於冷 氣之胺系和氨等之臭氣成分被氧化分解。即冷氣中之乙烯 氣體係在光觸媒模組6 5中，胺系和氨等之臭氣成分係在 光觸媒模組6 5及臭氧分解觸媒3 0之兩方中被分解。 但，在本實施例，係在冷氣流通室3 7內設有分流 8 9僅使通過冷氣流通室3 7內之冷氣的一部分構成能進 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐)' (請先閲讀背面之注意事項再填寫本頁) -裝. 訂 經濟部智慧財產局員工消費合作社印製 -19- 587148 A7 B7 五、發明説明（17 ) (請先閲讀背面之注意事項再填寫本頁) 行通過光觸媒組合2 9。此係，設有光觸媒組合2 9能堵 塞冷氣流通室3 7內之全體，則可加大光觸媒模組6 5， 但使冷氣流通室3 7內之壓力損失變大因爲使風量進行下 降，所以使綜合性的脫臭性能進行下降。相對地，本實施 例，係設有分流8 9使冷氣流通室3 7內之風量增加，所 以可達成脫臭裝置5之脫臭性能的提高。 脫臭裝置5中被脫臭之冷氣，係通過格子框部40之 通氣孔4 0 a及開口 5 2流入到蔬菜室7。而且，通過冷 氣通路1 3，沿著下箱1 0之前面及下面流動之後，通過 冷氣吸入口 2 2被返回到冷卻器室9。 若依據如此構成之本實施例，則將一對之網眼狀電極 66、68以隔板63、64能壓緊於第1及第2箱58 及5 9並加以固定，所以可儘力避免使一對之網眼狀電極 6 6、6 8不穩使該網眼狀電極6 6、6 8間之距離進行 變動。因此，由網眼狀電極6 6、6 8可取得穩定性的放 電，所以可達成脫臭性能和氧化分解性能之提高。 經濟部智慧財產局員工消費合作社印製 但，使網眼狀電極6 6、6 8間局部性的靠近，則在 該部分引起局部性的放電，形成產生部分性的摩耗。若依 據上述構成，則ΐ防止產生如此局部性的放電，所以可提 高長期信賴性。 隔板6 3、6 4之材料的矽膠係提高難燃性之水準貝ίΐ 有變硬之性質，但在本實施例係在隔板6 3、6 4設有凸 部7 0，使隔板6 3、6 4及光觸媒模組6 5將接觸面積 抑制很小。因此，在箱6 0內組裝光觸媒模組6 5等時， 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） -20- 587148 A7 _B7_____ 五、發明説明（18 ) 在光觸媒模組6 5全體難以加上大的力量，所以可防止光 觸媒模組6 5之破損。 (請先閱讀背面之注意事項再填寫本頁) 進而，在本實施例，在第1箱58設有收容凹部71 ，在前述收容凹部7 1內依順序組裝網眼狀電極6 6 ,隔 板6 3，光觸媒模組6 5，隔板6 4，網眼狀電極6 8， 第2箱5 9之收容凸部7 9用以構成光觸媒組合2 9。因 此，可提高光觸媒組合2 9之組合作業性。 進而又，在本實施例，係在單元箱27內之變壓器室 3 2及冷氣流通室3 7分別用以配置昇壓變壓器2 8及光 觸媒組合2 9用以構成脫臭裝置5。因此，由冷藏庫本體 1用以取出前述單元箱27可進行脫臭裝置5之修理，檢 查等之作業，可達成作業性之提高。 經濟部智慧財產局員工消費合作社印製 又，冷氣流通室3 7之中在臭氧分解觸媒3 0之上流 用以配置光觸媒組合2 9，同時構成由冷氣流通室3 7將 流出冷氣之通氣孔4 0 a能堵塞臭氧分解觸媒3 0。因此 ，以光觸媒組合2 9將產生之全部的臭氧使朝向有效臭氧 分解觸媒3 0可進行分解，所以使臭氣由脫臭裝置5可儘 力防止進行流出到庫內。 將昇壓變壓器2 8藉由模型成形加以構成。因此，光 觸媒組合2 9中由於產生之臭氧使前述昇壓變壓器2 8之 各零件不會被腐食。因此，可用以近接配置昇壓變壓器 2 8及光觸媒組合2 9，該部分，可將脫臭裝置5進行小 形化。又，將脫臭裝置5內區分成變壓器室3 2及冷氣流 通室3 7，並在前述變壓器室3 2用以配置昇壓變壓器 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -21 - 587148 A 7 B7 五、發明説明（19) (請先閲讀背面之注意事項再填寫本頁) 2 8。因此，由昇壓變壓器2 8將延伸之給電線3 3由流 通冷氣流通室3 7內之臭氧可進行分離。因此，使給電線 由於臭氧被腐食可儘力防止進行惡化。 又，設有偏置配置於單元箱27內之防護壁38及 4 5。因此，譬如如圖3二點鎖線所示使金屬絲狀之異物 A被插入於單元箱27內，也可儘力防止該異物到達光觸 媒組合2 9之網眼狀電極6 6及6 8進行感電。 特別，脫臭裝置5中，將放電裝置之中的對極（低電 位側）設於使用者側（氣流流入側），將放電電極設於使 用者不直接接觸側（氣流出口停）加以構成，萬一，使用 者手碰到時（金屬絲之插入等）可防止感電。 圖1 1至圖1 4係顯示本發明其他幾項實施例之圖， 此等之實施例係與第1實施例使隔板之構成不同。即，圖 1 1所示第2實施例，隔板9 1，係被構成跨越光觸媒模 組6 5側之面的全體具備延伸之突條部9 2。又，圖1 2 所示第3實施例中，隔板1 0 1 ,係被構成在光觸媒模組 6 5側之面具備多數之凹部1 〇 2。 經濟部智慧財產局員工消費合作社印製 具備如此之突條部9 2和凹部1 0 2之隔板9 1、 1 0 1中，也可用以縮小與光觸媒模組6 5之接觸面積， 所以在箱6 0內組裝光觸媒模組6 5等時，可防止在光觸 媒模組6 5全體加上大的力量會進行破損。 又，圖1 3所示第4實施例中，係將隔板1 1 1構成 爲中空狀。該情形，前述隔板1 1 1係被構成與網眼狀電 極6 6及6 8之矩形框6 6 a及6 8 a略同形狀。若依據 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -22- 587148 A7 B7 五、發明説明（2〇 ) 上述構成，則可提高隔板1 1 1之彈性。因此，爲了提昇 矽膠之難燃性的水準可彌補使硬度變高之分。 (請先閲讀背面之注意事項再填寫本頁) 尙有，在中空狀之隔板1 1 1，係如圖14 (a)至 (c )所示也含一部分進行開口之剖面形狀者。該情形， 在圖1 4 ( a )至（c )中之上部用以配置光觸媒模組 6 5° 即，譬如圖1 4 ( a )或（b )中，係藉由定位於隔 板1 1 1之圖中下部的網眼狀電極6 6、6 8之矩形框 6 6 a、6 8 a使隔板1 1 1之開口部分因爲形成被堵塞 之狀態，所以被取得與第4實施例同樣之作用，效果。又 圖1 4 ( c )中，藉由定位於隔板1 1 1之側部的第1箱 5 8之收容凹部7 1使隔板1 1 1之開口部分因爲形成被 堵塞之狀態，所以被取得與第4實施例同樣之作用，效果 〇 又，本發明並非僅被限定於上述且記載於圖面之實施 例，譬如可如下之變形，擴張。 經濟部智慈財產局員工消費合作社印製 第1及第2箱之形狀係不被限定圖示之形狀。譬如， 在第1及第2箱之中的一方設置凹狀之收容部，將他方做 爲平板狀之蓋也可。 脫臭裝置之配置場所，係不限於冷藏室3之下部的間 隔板6可做適當變更。又，設於冷凍室內中之冷氣的循環 經路也可。 臭氧分解觸媒係能堵塞管道內之冷氣通路的一部分加 以構成也可。即，藉由放電裝置使產生之臭氧即使流出於 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -23- 587148 A7 B7 五、發明説明（21 ) (請先閲讀背面之注意事項再填寫本頁) 管道外之庫內但若有適量則安全上無問題。又，若依據如 此之構成，則藉由擴散於庫內之臭氧對庫內之食品因爲呈 現抗菌作用，對食品之鮮度保持有效。 【發明之效果】 由以上之說明明白顯示，若依據本發明之冷藏庫，則 將庫內使冷氣進行循環並流入於脫臭裝置內，該冷氣係通 過光觸媒組合，所以藉由高電壓放電根據產生之紫外線由 於光觸媒作用使乙烯及臭氧成分被分解。又，藉由高電壓 放電也產生臭氧，所以使該臭氧被分解藉由產生之活性氧 的氧化力使臭氣成分被分解。此時，將用以構成放電裝置 之網眼狀電極固定於光觸媒組合之箱，將網眼狀電極之距 離可保持於固定加以構成，所以由放電裝置可取得穩定之 放電，可達成脫臭性能和氧化分解性能之提高。 【圖式之簡單說明】 經濟部智慧財產局員工消費合作社印製 圖1係顯示本發明第1實施例之冷藏庫全體構成的縱 剖視視圖。 圖2係間隔板及脫臭裝置之分解斜視圖。 圖3係間隔板之中脫臭裝置周邊部分的縱剖側視圖。 圖4係脫臭裝置之上視圖。 圖5係顯示卸下蓋之狀態的脫臭裝置之斜視圖。 圖6係蓋之斜視圖。 圖7係沿著圖4中X 1 - X 1線脫臭裝置之縱剖前視 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ' -24- 587148 A7 ___B7__ 五、發明説明（22 ) 圖。 圖8係光觸媒組合之分解斜視圖。 (請先閱讀背面之注意事項再填寫本頁) 圖9係顯示連結昇壓變壓器及光觸媒組合之狀態的斜 視圖。 圖1 0係顯示將光觸媒組合之中收容凹部及收容凸部 之周邊部分的模式性縱剖面圖。 圖1 1係顯示本發明第2實施例隔板之平面圖（a ) 及沿著X 2 - X 2線之剖面圖（b )。 圖1 2係顯示本發明第3實施例隔板之平面圖（a ) 及沿著X 3 - X 3線之剖面圖（b )。 圖1 3係顯示本發明第4實施例隔板之平面圖（a ) 及沿著X 4 - X 4線之剖面圖（b )。 圖1 4係顯示本發明其他實施例之隔板剖面圖。 【元件編號之說明】 5 … 脫臭 裝 置 y 1 3 …冷 氣 通 路 (冷氣之循環經路）， 2 8 …昇 壓 變 壓 器， 2 9 …光 觸 媒 組 合， 5 8 …第 1 箱 5 9 …第 2 箱 6 0 …箱 經濟部智慧財產局員工消費合作社印製 6 1…第1電極構件（放電裝置）， 6 2…第2電極構件（放電裝置）， 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -25- 587148 A7 B7 五、發明説明（23 ) 6 3、6 4、9 1、1 0 1、1 1 1…隔板（緩衝構 件）， 6 6、6 8…網眼狀電極， 7 1…收容凹部（收容部）。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -26-587148 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to the use of refrigerators in the air-conditioning circulation path to configure deodorizing devices. Deodorization inside. [Previous technology] According to the conventional technology, in domestic refrigerators, various kinds of odors caused by the food in the warehouse are reduced or in order to prevent the transfer of taste to other foods, platinum catalysts are disposed in Near the frost heater. Furthermore, in recent years, household refrigerators have been provided with coolers that individually cool the refrigerating compartment and the freezing compartment to set a higher humidity in the refrigerating compartment to improve the freshness retention effect of the food. In this way, to increase the humidity in the refrigerating room, because the odor is more likely to be felt or the germs are multiplied easily in the refrigerating room, the aforementioned refrigerator is introduced into a deodorizing device and has a strong deodorization by the oxidative decomposition of ozone Stink effect. However, the method using the oxidative decomposition of ozone also stays in the intermediate decomposition product because the odor component system is not completely oxidatively decomposed. In addition, by using the oxidizing power of ozone, it is ethylene that cannot completely decompose and promote the aging of green fruits. [Problems to be Solved by the Invention] In contrast, the applicant used to invent a refrigerator to deploy a deodorizing device that combines the oxidative decomposition of ozone and the photocatalyst of ultraviolet rays in the refrigerator, and first filed an application (Japanese patent (Case) Special wishes 2000-1 8 1 5 1 8). The aforementioned deodorizing device is installed in the refrigerator. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm). ΊΊ ^-: 丨 -φ-pack ----. 丨 If --- --- Φ (Please read the precautions on the back before filling out this page) -4-587148 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ΑΊ Β7 V. The circular path of the invention description (2) is composed of Used to configure the space discharge mechanism, photocatalyst module, ozone decomposition catalyst filter. In this case, it is considered that the space discharge mechanism is constituted by a pair of mesh electrodes arranged before and after the photocatalyst module. In this way, the photocatalyst can be effectively excited by constructing a photocatalyst module capable of being supported by a pair of electrodes. Further, by forming the electrodes in a mesh shape, the pressure loss in the pipe can be minimized as much as possible. However, in order to obtain a stable discharge system in the space discharge mechanism, it is necessary to fix the distance between the pair of mesh electrodes. However, since mesh electrodes are extremely thin and have low strength, fixing is difficult, and there may be some differences in the distance between the electrodes. In addition, the photocatalyst module has a structure that has a large variation in thickness. Therefore, it is still difficult to fix the photocatalyst module with a pair of mesh-shaped electrodes to maintain the distance between the electrodes. In this way, a local difference in the distance between the electrodes results in a partial discharge, and an effective deodorizing performance cannot be obtained. The present invention has been made in view of the above circumstances, and an object thereof is to provide a refrigerator having a deodorizing device. When a discharge device is composed of a pair of mesh electrodes, it is fixed to hold the space between the mesh electrodes. Distance can achieve stable discharge. [Means for solving the problem] The refrigerator in the first patent application scope of the present invention is configured in the air-conditioning circulation path to be equipped with a deodorizing device. The paper standard for deodorization in the warehouse applies Chinese national standards. (CNS) A4 specification (210X297 mm) ^ ^ ^ -Packing Order: (Please read the precautions on the back before filling out this page) -5- 587148 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Explanation (3) The refrigerator is characterized in that the aforementioned deodorizing device is provided with a photocatalyst combination and is integrally configured to assemble with a pair of mesh-shaped electrodes arranged in parallel to generate ozone by high-voltage electric discharge and A discharge device for ultraviolet rays, and a photocatalyst module for decomposing the odor components and harmful substances contained in the cold air by irradiating the ultraviolet rays according to the photocatalyst-generating effect, and a photocatalyst module for containing the discharge device and the photocatalyst module In the case of the case, the mesh-shaped electrodes are fixed to the case, respectively. According to the above-mentioned configuration, it is possible to prevent the meshes from being arranged in parallel as a pair. The electrode instability causes the distance between the mesh electrodes to be partially changed, so a stable discharge can be obtained by the discharge device. Moreover, the mesh electrode system has a very small thickness and weak strength, and the photocatalyst module system is very Fragile may be easily damaged, but according to the above structure, the discharge device and the photocatalyst module can be assembled in the deodorizing device in the state of the photocatalyst combination. Therefore, the photocatalyst module and the mesh shape can be prevented during the assembly operation. The electrode is damaged. In this case, it is preferable that the aforementioned box is composed of the first and second boxes, and a pair of mesh electrodes are configured to be able to be inserted into the aforementioned first and second boxes (application The invention according to the second aspect of the patent). According to the above configuration, a pair of mesh electrodes can be reliably fixed to the box. At least one of the first and second boxes is provided with a concave receiving section. It is also good that one of the pair of mesh-shaped electrodes, the photocatalyst module, the mesh-shaped electrodes of the other, and the other box are assembled in order to form a photocatalyst combination in the aforementioned storage portion. Configuration (patent scope of the invention of item 3). (Read back surface of precautions reloading <: write this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -6-587148 A 7 B7 V. Description of invention (4) (Please read the precautions on the back before filling this page } According to the above configuration, the assembling workability of the photocatalyst combination can be improved. Furthermore, the photocatalyst module is formed by a pair of mesh electrodes, so it will be generated by high voltage discharge in the discharge device. Ultraviolet rays can be effectively irradiated to the photocatalyst module. Furthermore, it is also a good structure to provide a buffer member between a pair of mesh-shaped electrodes and the photocatalyst module (invention in the scope of patent application No. 4). In this case, the aforementioned buffer The component is made of silicone (invention of patent application No. 5), or foam (invention of patent application No. 6), or is hollow (invention of patent application No. 7) According to the above configuration, a pair of mesh-shaped electrodes are respectively fixed to the aforementioned boxes by the buffer members while being compressed in the first and second boxes. Therefore, the net The distance between the shape electrodes can only be used to ensure the distance between the first box and the second box. In addition, the buffer member can be used to absorb the deviation of the thickness and size of the photocatalyst module. In addition, it is also a good structure to provide concavities and convexities on the surface of the photocatalyst module side of the aforementioned buffer member (invention of patent application No. 8). According to the above structure, it can be used to reduce the contact portion of the buffer member and photocatalyst module Therefore, it is possible to prevent the photocatalyst module from being damaged when the buffer member is inserted into the photocatalyst module. Moreover, it is better to provide a window for internal confirmation in the box (invention No. 9 in the scope of patent application). If it is based on the above structure , The parts of the discharge device and photocatalyst module contained in the box can be confirmed through the aforementioned window. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -7- 587148 Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative A7 B7 V. Description of the invention (5) [Implementation mode of the invention] The first embodiment of the invention will be described with reference to FIGS. 1 to 10. First, FIG. 1 is a side view showing a longitudinal section of the refrigerator according to this embodiment. In FIG. 1, refrigerating is constituted by a heat-insulating box. The inside of the main body 1 is partitioned into an upper refrigerating compartment 3 and a lower freezing compartment 4 by a heat-insulating partition wall 2. In the refrigerator according to this embodiment, the aforementioned refrigerating compartment 3 and the freezing compartment 4 are insulated by the foregoing insulation. The partition wall 2 is separated, and the interior is cooled and formed according to the generated cold air by dedicated coolers (cooler 3 a for the refrigerating compartment, and cooler 4 a for the freezing compartment). In this embodiment, the aforementioned refrigeration is performed. A deodorizing device 5 is provided in the cold air circulation path in the room 3. Hereinafter, the structure of the refrigerating room 3 described above will be mainly described. That is, a vegetable compartment 7 is formed in the lower part of the refrigerating compartment 3 by a partition plate 6, and a cooler compartment 9 for the refrigerating compartment is formed in the rear part of the vegetable compartment 7 by a partition wall 8. In the vegetable compartment 7, an upper box 11 mounted on the lower box 10 and an upper portion of the lower box 10 is accommodated. A cover 12 having a cold air flow exit hole 12a is installed to be openable on the upper case 11, and a cold air passage 13 is formed between the cover 12 and the partition plate 6. A refrigerating box 14 is arranged in the lower part of the refrigerating compartment 3, and a cold air passage 15 is formed between the refrigerating box 14 and the partition plate 6. Further, a cold air duct 17 is formed in the rear part and the upper part of the refrigerating compartment 3 by a duct cover 16 having a substantially L shape. A plurality of cold air discharge holes 19 are formed in the pipe cover 16 described above. This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the notes on the back first and then fill in 4 items < Installation — write this page),?! -8-587148 A7 B7 V. Description of the invention (6) In addition, the above-mentioned cooler room 9 is equipped with a refrigerating compartment fan device (please read the note on the back first) Please fill in this page again) 19, corresponding to this fan device 19 is provided with a cylindrical cold air discharge portion 20 above the partition wall 8 above. The front-end opening of the cold air discharge portion 20 is positioned in the upper case 11. In contrast, the cooler 3a for the refrigerating compartment is arranged in the lower part of the cooler compartment 9. In addition, a front part of the lower part of the partition wall 8 is provided with a skylight-like cold air inlet 22. A machine room 2 3 is formed below the refrigerator body 1, and a compressor 24 for a cooling cycle is disposed inside the machine room 2 3. The aforementioned compressors 2 and 4 are reciprocating engines using a compressor motor as a driving source. The deodorizing device 5 is disposed on the right rear portion of the partition plate 6. Hereinafter, the configuration of the deodorizing device 5 will be described with reference to Figs. 2 to 7. The deodorizing device 5 is a unit box 2 7 composed of a box body 25 and a cover 2 6 covering the upper opening of the box body 25, and a step-up transformer 2 8 disposed in the box body 25. The photocatalyst combination 2 9 and the ozone decomposition catalyst 30 are constituted. In the left part of the box body 25, it is constituted to be printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Bureau of Industrial Property, B, Industrial Cooperative, and 31. A transformer room 3 2 is formed. The transformer room 32 is disposed inside the transformer room 32. Step-up transformer 2 8. The step-up transformer 28 is composed of a primary coil, a secondary coil, a magnetic core, and the like (none of which are shown) by molding a synthetic resin. The step-up transformer 28 is configured to be supplied with power from the primary-side terminal (not shown) via the power supply wire 3 3. Moreover, in the right part of FIG. 2 of the aforementioned step-up transformer 28, a pair of secondary-side terminals 3 4 a and 3 4 b are protruded, and this paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm). ) -9- 587148 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (7) and is provided with a] enclosing part 3 5 a, 3 5 b can surround each secondary side terminal 34a, 34b around the three parties. Further, in the step-up transformer 28 shown in FIG. 2 above and below the right portion, a claw portion 3 6 a, 3 6 b is provided, and a space other than the transformer room 32 inside the box body 25 is provided. As the cold air flow passage 37, a protective wall 38 extending in the left-right direction is erected before the bottom of the chamber. The height dimension of the protective wall 38 is set to about half of the height dimension of the box body 25. The central portion in the front-back direction in the cold air flow passage chamber 37 is configured to arrange the photocatalyst combination 29. The bottom portion of the box body 25 is provided with a positioning rib in the arrangement portion of the photocatalyst combination 29. 3 9. In addition, in the last part of the cold air flow passage chamber 37, the above-mentioned ozone decomposition catalyst 30 is disposed, and a lattice frame portion 4 having a plurality of rectangular ventilation holes 40a is formed at the bottom of the arrangement portion. 0. Each of the frame portions constituting the aforementioned lattice frame portion 40 is formed into a triangular shape in cross section so that the area in contact with the lower portion of the ozone decomposition catalyst 30 becomes as small as possible (refer to FIGS. 3 and 7). The ozone decomposing catalyst 30 is, for example, a manganese oxide-based ceramic honeycomb structure (molded article) or a metal honeycomb structure formed into a rectangular plate shape as a core material, and is configured to fix the catalyst component. In this way, as the honeycomb structure, the contact area between the ozone decomposition catalyst 30 and ozone or odorous components is more ensured, so that the decomposition efficiency is improved. The ozone decomposition catalyst 30 is arranged on the grid frame portion 40 with the honeycomb shape so that the ventilation direction becomes the vertical direction. (Please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 size (210X 297 mm) -10-587148 A7 B7 V. Description of the invention (8) (Please read the back Please fill in this page again for attention.) Yes, the iron core system of the aforementioned ozone decomposition catalyst 30 is very fragile, and it may be damaged during assembly. Therefore, in this embodiment, a soft tape 30 a is wound around the outer portion of the ozone decomposition catalyst 30 and is used to prevent breakage during the assembly operation. In addition, in the box body 25, the arrangement portion of the ozone decomposition catalyst 30 is used as the grid frame portion 40. Therefore, the ozone decomposition catalyst 30, which is assembled in the box body (unit box 27), may be accidentally touched, which can prevent fingers from adhering to the catalyst components or being damaged. In addition, the cover 30 is configured to insert a hub portion 41 that is erected below the hub portion 41 into a hole portion 4 2 provided in the box body 25, and is attached to a screw 4 3 Aforementioned box body 25. The front part of the cover 30 is integrally provided with the sunroof 44 extending below. When the cover 30 is mounted on the box body 25, the lower part of the sunroof 4 4 is formed on the box body 25. The front end is blocked from above. The aforementioned sunroof 44 is formed in the unit box 27 to prevent foreign matter from entering. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The cover 30 is located near the rear part of the skylight 44 and is provided with a protective wall 45 extending to the left and right. As shown in FIG. 3, the aforementioned protective wall 45 and the protective wall 38 on the side of the box body 25 are arranged in the unit box 27 and offset in the front and back. Thereby, the cold air flow in the cold air circulation chamber 37 is not hindered, and it is configured to prevent the invasion of foreign objects. Furthermore, when the cover 30 in the lower surface of the cover 30 is mounted on the box body 25, three ozone diffusion members 46 are provided at the upper portion of the ozone decomposition catalyst 30, which extend downward. Furthermore, a rib 4 7 extending below is provided at the rear portion of the cover 30, and a hole portion 48 is provided at a central portion in the left-right direction of the rib 47. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -11-587148 A7 B7 V. Description of the invention (9) Secondly, for the composition of the aforementioned spacer plate 6, please refer to Fig. 2 and Fig. 3 Instructions. In the rear part of the right part of the aforementioned partition plate 6, a rectangular container-like mounting recess 49 is formed for assembling the odor device 5. Among the above-mentioned compartments 6, the circulation & gas in the storage compartment is not passed through the deodorizing device 5 on both sides of the above-mentioned mounting recesses 49 and 9 through the refrigerating compartment. In order to flow directly into the vegetable compartment 7, a circulation opening 5 0 . The half of the rear part of the mounting recess 49 is configured so that the unit box 27 can be installed, and a circular drainage hole 51 and a rectangular opening 52 are formed at the bottom. The opening 5 2 is positioned below the lattice frame portion 40 when the unit box 27 is arranged. In addition, an inclined surface 5 3 is provided in front of the mounting recess 49. Further, an oblong drainage hole 54 is formed in the front portion of the portion where the sunroof 44 of the unit box 27 is positioned in the bottom of the mounting recess 49. The drainage holes 54 are used to prevent water and the like from entering the unit box 27 when the user accidentally spills water or the like in the warehouse. Further, ribs 5 5 are formed in the peripheral edge portion of the rear half of the mounting recess 49. The ribs 5 5 are also used to prevent water or the like from entering the unit case 27 from the peripheral portion. The unit box 27 is a hole portion 48 of the cover 30, and a hole (not shown) provided at the rear side of the mounting recess portion 49 is inserted from above to insert the holder 5 7 so that The unit box 27 is attached to the attachment recess 49. Next, the constitution of the photocatalyst combination 29 will be described. Fig. 8 is an exploded perspective view showing the photocatalyst combination 29, and Fig. 9 is a perspective view showing the state of the photocatalyst combination 29 and the step-up transformer 28. These paper standards are applicable to China National Standard (CNS) Α4 specifications (210 × 297 mm) (Please read the notes on the back before filling out this page) Order printed by the Intellectual Property Bureau Employee Consumer Cooperatives of the Ministry of Economic Affairs-12- 587148 A7 B7 V. Description of the invention (1〇) Figure 8 and Figure 9, The photocatalyst combination 29 is a box 60 composed of the first box 58 and the second box 59, and the first and second electrode members 6 1 and 6 2 of the discharge device housed in the box 60, and a buffer member. The partition plates 6 3 and 6 4 and the photocatalyst module 65 are configured. The first electrode member 61 is composed of a mesh-shaped electrode 6 6 edged with a rectangular frame 6 6 a and a terminal plate 6 7 provided at the upper left of FIG. 8 in the rectangular frame 6 6 a. The second electrode member 62 is composed of a mesh electrode 6 8 which is thicker than the mesh electrode 6 6 taken by a rectangular frame 6 8 a and a figure provided on the rectangular frame 6 8 a. The terminal plate 69 at the lower left in 8 is formed. Each of the partition plates 6 3 and 6 4 is made of flame-resistant silicone rubber, and is formed in a frame shape having two rectangular window portions 6 3 a and 6 4 a juxtaposed to the left and right. The partition plates 6 3 and 6 4 are easily distinguishable from the white photocatalyst module 65 and are colored black. The rectangular frames 6 1 a and 6 2 a are used for distinguishing the first and second electrode members 6 1 and 6 2 from each other, except for a portion for distinguishing the window portions 63 a and 64 a of the partition plates 63 and 64. Make up the same shape. Among the partition plates 6 3 and 6 4, a plurality of convex portions 70 are provided on the surface of the photocatalyst module 65 side (only the convex portions 7 0 of the partition plate 63 are shown in FIG. 8). The aforementioned photocatalyst module 65 is coated on the surface of a rectangular plate-shaped core material made of porous ceramics (alumina, silicon dioxide, etc.) to coat photocatalyst materials such as titanium oxide, so as to be dried or sintered. It is constructed by being fixed. The mesh electrodes 66 and 68, the spacers 63 and 64, and the photocatalyst module 65 of the aforementioned first and second electrode members 6 1 and 62 are applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm). ) (Please read the precautions on the back before filling out this page} Binding and ordering Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-13- 587148 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (11 The length dimension in the vertical direction and the vertical direction are all set to be the same. The first box 5 8 is configured to have a receiving recess 7 1 opened at the top, and left in FIG. 8 provided in the receiving recess 7 1. A pair of concave terminal arrangement portions 7 2 and 7 3. In the aforementioned accommodating concave portion 71, a mesh electrode 6 6 that is a first electrode member 61 1 is formed, a separator 6 3, and a photocatalyst module 6 5. The separator 6 4 and the mesh electrode 68 of the second electrode member 62 are housed in this order. The terminal arrangement portions 7 2 and 7 3 are configured so that the first electrode member 61 and the first electrode member 61 The terminal plates 6 7 and 6 9 of the 2 electrode members 6 2 are respectively disposed. In FIG. 8 of the aforementioned accommodating recess 7 1, the lower surface portion The slightly rectangular window portions 7 1 a corresponding to the window portions 6 3 a and 6 4 a of the partition plates 6 3 and 6 4 are provided and exemplified on the left and right sides. Also, among the aforementioned first boxes 5 8 In the receiving recess 71, the front and rear side portions of FIG. 8 are provided with positioning recesses 74 and a pair of fitting portions 75 respectively (the positioning recesses 7 4 are shown only in the front side portion in FIG. 8). The receiving recessed portion 7 of the 1 box 5 8 is provided with a positioning recessed portion 7 6 on the right side in FIG. 8. The fitting portion 7 5 is provided with cutouts 7 5 a at the left and right portions thereof to be elastically deformable. Furthermore, in the first box 58, the fitting portions 7 7, 7 are provided at the left end portions of the front and rear side portions of each of the terminal arrangement portions 72 and 73 in Fig. 8. The fitting portions 7 7, 7 are described above. 8, the system is provided with cutouts 7 7 a and 7 8 a at the right part, which are elastically deformable. The second box 5 9 is configured in the first box 5 8 and can be embedded in the upper part of FIG. 8. Corresponds to the above-mentioned accommodating recess 7 1 Convex storage below (please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -14- 587148 A7 B7 5 , Explanation (12) The convex portions 79 and the terminal arrangement portions 80 and 81 corresponding to each of the terminal arrangement portions 72 and 73 are formed downward. The lower portion in FIG. 8 that accommodates the convex portions 79 is described above. The rectangular window portions 7 9 a facing the window portion 7 1 a are arranged side by side. The second box 5 9 is the front and rear side portions of the receiving convex portion 7 9 in FIG. 8. And the right side portions are respectively provided with corresponding positioning convex portions 8 2 and 8 3 at the positioning concave portions 7 4 and 7 6. Furthermore, in the second box 59, the front and rear side portions and the front and rear side portions of each of the terminal arrangement portions 80 and 81 in FIG. 8 accommodating the convex portions 79 are provided corresponding to the fitting portions 75 and 77. , 78 claws 84 to 86. The left and right portions of the claw portions 8 4 to 8 6 are respectively provided with cutouts 8 4 a to 8 6 a and are configured to be elastically deformable. _ Furthermore, the terminal arrangement portion 7 2 of the first box 5 8 is used to arrange the terminal plate 6 1 of the first electrode member 61 1 and the meshes of the first electrode member 61 are arranged in the receiving recess 7 1 in order. The electrode 6 6, the separator 6 3, the photocatalyst module 6 5, the separator 6 4, the mesh electrode 6 8 of the second electrode member 62 2, and the terminal plate 6 9 of the second electrode member 6 2 is disposed on After the terminal arranging portion 73, the second box 5 9 is fitted in the first box 58 so that the claw portions 84 to 86 are fitted to the fitting portions 75, 77, and 78 to form a photocatalyst combination 29 by fitting. At this time, the aforementioned fitting portion 75 is configured to be visually recognized in the box 60. Therefore, the presence or absence of defective parts can be easily confirmed even after the photocatalyst combination 29 is assembled. In addition, the positioning convex portions 8 2 and 8 3 are locked to the positioning concave portions 7 4 and 7 6 so that the predetermined paper size is applied to the Chinese National Standard (CNS) between the storage concave portion 71 and the storage convex portion 7 9. A4 specifications (210X297 mm) (Please read the precautions on the back before filling out this page)-Equipment ·,-** Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -15- 587148 A7 B7 V. Description of the invention (13) (Please read the notes on the back before filling out this page) Space is guaranteed. In the aforementioned space, the mesh electrode 6 6, the separator 6 3, the photocatalyst module 6 5, the separator 6 4, and the mesh electrode 6 8 are set to have the same thickness as the overlap size. As a result, the mesh The shape electrode 6 6, the separator 6 3, the photocatalyst module 6 5, the separator 6 4, and the mesh electrode 6 8 are not held in the state between the first and second boxes 5 8 and 5 9 without being overcompressed. be fixed. With the above structure, the photocatalyst module 65 is very fragile and easily damaged. When the second box 5 9 is embedded in the first box 5 8, it is possible to prevent the damage as far as possible. FIG. 10 shows the photocatalyst combination 29 to accommodate the recess. 7 1 and the receiving convex portion 7 9 are schematic longitudinal cross-sectional views of a portion to be held. As shown in FIG. 10, in the space between the receiving recessed portion 71 and the receiving protruding portion 79, the photocatalyst module 65 is positioned between the mesh-shaped electrodes 6 6 and 6 8 arranged in parallel. . Further, since the above-mentioned space is set to the above-mentioned size, each of the mesh electrodes 66 and 68 is pressed against the first and second boxes 58 and 59 by the separators 63 and 64, respectively. Therefore, the mesh electrodes 66, 68 are kept in parallel so that the distance between them is not partially different. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. However, the photocatalyst module 65 series has a large variation in thickness and structure. However, in this embodiment, since the convex portion 70 is provided on the surface of the partition plate 6 3, 6 4 that is in contact with the photocatalyst module 65, it can be used to absorb the deviation of the thickness dimension of the photocatalyst module 65. This also allows the distance between the mesh electrodes 66, 68 to prevent partial differences. In addition, as shown in FIG. 2 and FIG. 9, the left side of the photocatalyst combination 29 is the terminal arrangement portion 72, the terminal arrangement portion 80, and the terminal arrangement portion 73, and the paper size of the terminal applies to the Chinese National Standard (CNS) A4. Specifications (210X 297 mm) -16- 587148 Printed by the Consumers ’Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs A7 B7_V. Description of the invention (14) The sub-arrangement sections 8 1 are fitted together to form a pair of terminal sections 8 7 '8 8. At this time, at the front ends of the terminal portions 87, 88, the secondary side terminals 34a, 34b of the step-up transformer 28 are inserted into the terminal plates 6 of the first and second electrode members 6 1 and 62. 7, 6 9 are connected so that a terminal insertion opening (not shown) is formed. Therefore, the secondary side terminals 3 4 a and 34 b of the step-up transformer 2 8 are inserted into the terminal insertion openings, and the surrounding portions 35 a and 35 b are inserted into the terminal portions 8 7 and 8 8 to make the secondary side terminals. In a state where 3 4 a and 3 4 b and the terminal plates 6 7 and 6 9 are connected respectively, the step-up transformer 28 and the photocatalyst combination 29 are connected. At this time, the claw portions 3 6 a and 3 6 b of the aforementioned step-up transformer 2 8 are configured to be positioned on the outside of the terminal portions 8 7 and 8 8 of the photocatalyst combination 2 9 and are locked to the cutouts 7 7 a and 7 8 a. The step-up transformer 28 and the photocatalyst combination 29 are arranged in a state where the first box 5 8 is positioned in the front part in the transformer room 3 2 and the cold air flow passage 37. At this time, in the cold air flow passage chamber 37, the cold air does not pass through the photocatalyst combination 29 in the right part of the photocatalyst combination 29 to form a shunt 89 toward the rear (see FIG. 4). In other words, the photocatalyst combination 29 disposed in the cold air flow passage 3 7 is formed so that the fitting portion 7 5 is positioned on the upper portion thereof. Therefore, after the photocatalyst combination 29 is set in the cold air flow passage 37, it can be used to confirm again whether there are any missing items in the box 60. In addition, the high-voltage voltage is applied to the mesh-shaped electrode through a step-up transformer 28 to discharge the ultraviolet rays (wavelengths below 380 nm. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm factory) (Please read the precautions on the back before filling out this page) One pack. Order -17- 587148 A7 _ _B7 V. Description of the invention (15)) and ozone are generated. Secondly, for the function of this embodiment, please refer to FIG. 1 and FIG. 3. Fig. 4 and Fig. 7 will be described. In the refrigerator of this embodiment, the temperature setting information and temperature information of the refrigerating compartment 3 and the temperature information of the refrigerating cooler 3a are used for the refrigerating unit. The temperature setting information and temperature information of the compartment 4 control the operation of the compressor 2 4 and the deodorizing device 5 based on the temperature information of the refrigerating cooler 4 a, etc. Furthermore, it is used to judge the cooling operation of the refrigerating compartment 3 At this time, the control device supplies the discharged refrigerant to the refrigerating cooler 3 a by the compressor 24 and starts the operation of the refrigerating fan device 19 and the deodorizing device 5 at the same time. As shown by the arrow in FIG. 1, a part of the cold air in the cooling chamber 9 is discharged from the upper box 11 by the cold air discharge portion 20 and is discharged from the cold air passage 13 through the cold air outlet 1 2 a. The cold air discharged from the cold air passage 13 flows along the front and bottom surfaces of the lower box 10, and is returned to the cooler chamber 9 through the cold air suction port 22. In contrast, the cold air in the cooler chamber 9 remains It is raised through the cold air duct 17, and is discharged from the cold air outlet 18 and the upper end of the cold air duct 17 into the refrigerating compartment 3. The cold air discharged from the refrigerating compartment 3 passes through the cold air passage below the refrigerating box 14 15. Most of them flow directly into the vegetable compartment 7 through the circulation openings 50 and drain holes 51 formed in the partition plate 6. Moreover, the cold air residues passing through the cold air passages 15 flow through the skylights 4 and 4 The cold air flow passage 3 of the odor device 5 7. A part of the cold air flowing into the cold air flow passage 3 7 is based on the standard of China Paper (CNS) A4 (210X 297 mm). (Please fill in this page for attention) Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-18- 587148 A7 ____B7 V. Description of the invention (16) After the media combination 29, it reaches the ozone decomposition catalyst 30. In addition, the cold air flowing into the cold stomach circulation chamber 37 remains, It reaches the ozone decomposition catalyst 3 through the shunt 89. In the photocatalyst combination 29, the mesh-shaped electrodes 6 6 and 6 are connected to the @boost transformer 2 8 so that the high voltage is applied and discharged by the discharge, so that Ultraviolet rays (wavelengths below 380 nm) and ozone are generated. In addition, when the ultraviolet rays are irradiated to the photocatalyst module 65, the titanium dioxide receives the ultraviolet light source to form an active photocatalyst, which is used to decompose Odor components such as cold air ammonia and ethylene gas. In particular, in this embodiment, since the photocatalyst module 65 is arranged between the mesh electrodes 66 and 68, non-directional ultraviolet rays are effectively produced in the photocatalyst module 65. In addition, the ozone generated by the high-voltage discharge reaches the ozone decomposition catalyst 30 through the cold air of the photocatalyst combination 29 and the cold air through the shunt 89. At this time, the width of the photocatalyst combination 29 is smaller than that of the ozone-decomposition catalyst 30, but the ozone system generated by the photocatalyst combination 29 is diffused to the ozone diffusion member 46 under the cover 26. The entire ozone decomposition catalyst 30. The ozone decomposition catalyst 30 is used to decompose ozone and generate active oxygen. The oxidizing power of the active oxygen causes odor components such as amines and ammonia contained in the air to be oxidized and decomposed. That is, the ethylene gas system in the cold air is decomposed in both the photocatalyst module 65 and the odor components such as amines and ammonia in the photocatalyst module 65 and the ozone decomposition catalyst 30. However, in this embodiment, a shunt 8 9 is provided in the cold air flow passage 3 7 so that only a part of the cold air passing through the cold air flow passage 3 7 can enter this paper. The Chinese standard (CNS) A4 specification (210X) is applied. 297 mm) '(Please read the precautions on the back before filling out this page)-Packing. Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-19- 587148 A7 B7 V. Description of the invention (17) (Please read the back first For the matters needing attention, please fill out this page again). This system is provided with a photocatalyst combination 29 which can block the entire inside of the cold airflow passage 37, so the photocatalyst module 65 can be enlarged, but the pressure loss in the cold airflow passage 37 is increased because the air volume is reduced, so Reduces the overall deodorization performance. In contrast, in the present embodiment, the branch flow 89 is provided to increase the air volume in the cold air flow passage chamber 37, so that the deodorizing performance of the deodorizing device 5 can be improved. The deodorized cold air in the deodorizing device 5 flows into the vegetable compartment 7 through the vent holes 40a and the openings 52 of the grid frame portion 40. Then, after passing through the cold air passage 13 along the front surface and the lower surface of the lower case 10, it is returned to the cooler chamber 9 through the cold air suction port 22. According to this embodiment configured as such, the pair of mesh-shaped electrodes 66 and 68 can be pressed and fixed to the first and second boxes 58 and 59 with the separators 63 and 64, so it is possible to try to avoid using The instability of the pair of mesh-shaped electrodes 66, 68 causes the distance between the mesh-shaped electrodes 66, 68 to change. Therefore, stable discharge can be achieved by the mesh electrodes 66, 68, so that the deodorizing performance and the oxidative decomposition performance can be improved. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. However, if the mesh electrodes 66, 68 are locally close to each other, a local discharge is caused in this part, which causes partial wear. According to the above configuration, such localized discharge can be prevented, so long-term reliability can be improved. The material of the separator 6 3, 6 4 is a silicone rubber which is a level of improving flame resistance. It has a hardening property, but in this embodiment, a convex portion 70 is provided on the separator 6 3, 6 4 to make the separator. 6 3, 6 4 and photocatalyst module 6 5 have a small contact area. Therefore, when the photocatalyst module 65 is assembled in the box 60, etc., this paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) -20- 587148 A7 _B7_____ V. Description of the invention (18) It is difficult to add a large force to the entire group 6 5, so that the photocatalyst module 65 can be prevented from being damaged. (Please read the precautions on the back before filling this page.) Furthermore, in this embodiment, a receiving recess 71 is provided in the first box 58, and the mesh electrode 6 6 is assembled in the receiving recess 7 1 in order, and the separator 6 3, a photocatalyst module 6 5, a separator 6 4, a mesh-shaped electrode 6 8, and a receiving protrusion 7 9 of the second box 5 9 are used to constitute a photocatalyst combination 29. Therefore, the combination workability of the photocatalyst combination 29 can be improved. Furthermore, in this embodiment, the transformer room 32 and the cold air flow passage room 37 in the unit box 27 are respectively used to configure a step-up transformer 28 and a photocatalyst combination 29 to form a deodorizing device 5. Therefore, the refrigerator main body 1 can be used to take out the unit box 27 to perform repairs, inspections, and the like of the deodorizing device 5, thereby improving workability. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the cold air flow chamber 3 7 flows above the ozone decomposition catalyst 30 to configure the photocatalyst combination 2 9, and at the same time, the cold air flow chamber 3 7 will form a vent hole for the cold air. 40 a can block ozone decomposition catalyst 30. Therefore, all the ozone generated by the photocatalyst combination 29 can be decomposed toward the effective ozone decomposition catalyst 30, so that the deodorization device 5 can try to prevent the deodorization device 5 from flowing out into the warehouse. The step-up transformer 28 is constructed by molding. Therefore, due to the ozone generated in the photocatalyst combination 29, the parts of the aforementioned step-up transformer 28 will not be rotten. Therefore, a step-up transformer 28 and a photocatalyst combination 29 can be arranged in close proximity, and this part can reduce the size of the deodorizing device 5. In addition, the deodorizing device 5 is divided into a transformer room 32 and a cold air flow passage 37, and the step-up transformer is configured in the aforementioned transformer room 32. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm). ) -21-587148 A 7 B7 V. Description of the invention (19) (Please read the precautions on the back before filling this page) 2 8. Therefore, the extended feed line 3 3 can be separated from the ozone in the cold air flow passage chamber 37 by the step-up transformer 28. Therefore, the power supply line can be rotten by ozone to prevent deterioration. In addition, protective walls 38 and 45 are arranged in the unit box 27 in an offset manner. Therefore, for example, as shown in the two-point lock line in FIG. 3, a wire-shaped foreign object A is inserted into the unit box 27, and it is possible to prevent the foreign object from reaching the mesh-shaped electrodes 66 and 68 of the photocatalyst combination 29 to perform electric induction. In particular, in the deodorizing device 5, the counter electrode (low potential side) of the discharge device is provided on the user side (air flow in side), and the discharge electrode is provided on the side where the user is not in direct contact (air outlet stop). In case, when the user touches the hand (insertion of metal wire, etc.), it can prevent electric shock. 11 to 14 are diagrams showing other embodiments of the present invention. These embodiments are different from the first embodiment in the configuration of the partition plate. That is, in the second embodiment shown in Fig. 11, the partition plate 91 is formed so that the entire surface of the photocatalyst mold group 65 is provided with an extended ridge portion 92 on the entire surface. In the third embodiment shown in FIG. 12, the partition plate 100 1 is formed on the surface on the photocatalyst module 65 side with a large number of recesses 102. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed a partition plate 9 1 and 101 having such a protruding portion 92 and a recessed portion 102, which can also be used to reduce the contact area with the photocatalyst module 65, so When the photocatalyst module 65 is assembled in the box 60, etc., it is possible to prevent the photocatalyst module 65 from being damaged by applying a large force to the entire photocatalyst module 65. In the fourth embodiment shown in Fig. 13, the partition plate 1 1 1 is formed in a hollow shape. In this case, the aforementioned separator 1 1 1 is configured to have a shape similar to that of the rectangular frames 6 6 a and 6 8 a of the mesh electrodes 66 and 68. If the Chinese National Standard (CNS) A4 specification (210X297 mm) -22- 587148 A7 B7 is applied in accordance with this paper standard V. Description of the invention (20) The above structure can improve the elasticity of the separator 1 1 1. Therefore, in order to improve the level of flame resistance of silicone, it can make up for the increase in hardness. (Please read the precautions on the back before filling out this page.) 尙 Yes, the hollow partition 1 1 1 is a cross-sectional shape including a part of the opening as shown in Figures 14 (a) to (c). In this case, the photocatalyst module 65 is arranged at the upper part in FIGS. 14 (a) to (c), that is, as shown in FIG. 14 (a) or (b), for example, it is positioned on the partition plate 1 1 The rectangular frame 6 6 and 6 8 of the mesh electrode 6 6 and 6 8 in the lower part of Fig. 1 make the opening portion of the separator 1 1 1 blocked because it is blocked, so it is obtained in the same manner as in the fourth embodiment. Effect, effect. In FIG. 14 (c), the receiving recess 7 1 of the first box 5 8 positioned on the side of the partition 1 1 1 makes the opening portion of the partition 1 1 1 blocked because it is blocked. The same effect as the fourth embodiment is obtained, and the effect is not limited to the embodiment described above and described in the drawings. For example, it can be expanded and expanded as follows. The shapes of the first and second boxes printed by the Consumer Cooperatives of the Intellectual Property Office of the Ministry of Economic Affairs are not limited to the shapes shown in the figure. For example, one of the first and second boxes may be provided with a concave receiving portion, and the other may be a flat cover. The location of the deodorizing device is not limited to the partition 6 in the lower part of the refrigerating compartment 3, and can be appropriately changed. It is also possible to circulate the cold air in the freezer. The ozone decomposition catalyst may be configured by blocking a part of the cold air passage in the pipe. That is, the ozone generated by the discharge device applies to the Chinese paper standard (CNS) A4 (210X 297 mm) even if it flows out of this paper. -23- 587148 A7 B7 V. Description of the invention (21) (Please read the back Note: Please fill in this page again.) In the warehouse outside the pipeline, if there is an appropriate amount, there is no safety problem. In addition, according to this structure, the ozone in the storehouse has an antibacterial effect on the food in the storehouse due to the ozone diffused in the storehouse, and is effective in maintaining the freshness of the food. [Effects of the invention] It is clear from the above description that if the refrigerator according to the present invention circulates the cold air in the refrigerator and flows into the deodorizing device, the cold air is combined by a photocatalyst, so by high-voltage discharge according to The generated ultraviolet rays decompose the ethylene and ozone components due to the photocatalyst. In addition, ozone is also generated by high-voltage discharge, so that the ozone is decomposed and the odorous components are decomposed by the oxidizing power of the generated active oxygen. At this time, the mesh-shaped electrode used to constitute the discharge device is fixed to the box of the photocatalyst combination, and the distance of the mesh-shaped electrode can be kept fixed. Therefore, the discharge device can obtain stable discharge and achieve deodorization performance. And oxidative decomposition performance. [Brief description of the drawings] Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Fig. 1 is a longitudinal sectional view showing the entire structure of the refrigerator in the first embodiment of the present invention. Fig. 2 is an exploded perspective view of a partition plate and a deodorizing device. Fig. 3 is a longitudinal sectional side view of a peripheral portion of the deodorizing device among the partition plates. Fig. 4 is a top view of the deodorizing device. Fig. 5 is a perspective view showing a deodorizing device in a state where a cover is removed. Figure 6 is a perspective view of the cover. Figure 7 is a longitudinal sectional front view of the deodorizing device taken along the line X 1-X 1 in Figure 4. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) '-24- 587148 A7 ___B7__ 5. Description of the invention (22) Figure. Figure 8 is an exploded perspective view of a photocatalyst combination. (Please read the precautions on the back before filling out this page.) Figure 9 is a perspective view showing the state of the booster transformer and photocatalyst combination. FIG. 10 is a schematic longitudinal cross-sectional view showing a peripheral portion of the receiving recessed portion and the receiving protruding portion in the photocatalyst combination. FIG. 11 is a plan view (a) and a cross-sectional view (b) along a line X 2-X 2 of a separator according to a second embodiment of the present invention. FIG. 12 is a plan view (a) and a cross-sectional view (b) of a partition plate according to a third embodiment of the present invention, taken along the line X3-X3. FIG. 13 is a plan view (a) and a cross-sectional view (b) along a line X 4-X 4 of a partition plate according to a fourth embodiment of the present invention. Fig. 14 is a sectional view showing a partition plate according to another embodiment of the present invention. [Explanation of component number] 5… deodorizing device y 1 3… cold air path (air-conditioning circulation path), 2 8… step-up transformer, 2 9… photocatalyst combination, 5 8… first box 5 9… second box 6 0… printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 6 1… the first electrode member (discharge device), 6 2… the second electrode member (discharge device), this paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -25- 587148 A7 B7 V. Description of the invention (23) 6 3, 6 4, 9 1, 1 0 1, 1 1 1 ... partition (buffer member), 6 6, 6 8 ... mesh Shaped electrode, 7 1 ... receiving recess (receiving portion). (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -26-