TW583654B - Optical recording medium - Google Patents

Optical recording medium Download PDF

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Publication number
TW583654B
TW583654B TW91105340A TW91105340A TW583654B TW 583654 B TW583654 B TW 583654B TW 91105340 A TW91105340 A TW 91105340A TW 91105340 A TW91105340 A TW 91105340A TW 583654 B TW583654 B TW 583654B
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Taiwan
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recording
record
laser beam
recording medium
groove
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TW91105340A
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Chinese (zh)
Inventor
Takashi Horai
Syuji Tsukamoto
Shirou Ootsuki
Hiroyuki Arioka
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Tdk Corp
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  • Optical Record Carriers And Manufacture Thereof (AREA)
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Abstract

The object of the present invention is to provide an optical recording to realize multi-level recording in five stages or more with reduced error rates. An optical recording medium (10) is adapted such that information is recorded by forming recording marks on a recording layer (12) that covers grooves (16) of an optical transparent substrate (14). In the recording layer (12), contiguously defined along a feed direction S of irradiation are virtual recording cells (40) which have an arbitrary unit length in the feed direction S of irradiation along the groove 16 and an arbitrary unit width in the direction orthogonal thereto. In addition, the groove width W is set so that 0.25x(lambda/NA) < W < 0.55x(lambda/NA), where lambda is the wavelength of a laser beam to be irradiated with and NA is the numerical aperture of the objective lens for the laser beam in an irradiation optical system. The irradiation time is set in five stages or more to radiate with the laser beam, thereby making it possible to record information in multi-levels.

Description

經濟部智慧財產局員工消費合作社印製 583654 A7 B7 五、發明説明(:) 技術領域 本發明係有關,因應供作記錄之資料,於記錄層形成 多種記錄標示,作資訊之多階記錄之光記錄媒體。 先行技術 以往之光記錄媒體係變化播放信號之長度(反射信號 調變部之長度)爲多階,以作資料之記錄,相對於該方法 ,將播放信號之深度(反射信號之調變度)作多階交換, 以相同長度之各信號記錄多數資料之記錄方法,其相關硏 究已多有進行。 以該光記錄方法,較之僅以坑之有無以記錄二値資料 者,因可於深度方向記錄多數資料,分配於一定長度之信 號量可增加,因此,線記錄密度可予提升。目前,如此之 記錄媒體,有利用全像照相或多層記錄層之提議。 而在此多階記錄係指,將反射信號調變度相互不同之 多種記錄資料加以記錄。 另一方面,有關這些多階記錄之光記錄方法,有記錄 時雷射光束之功率加大,且隨形成之反射信號深度加深, 播放時信號品質劣化之問題。其理由目前尙在未知。 例如,利用習知手法爲記錄媒體記錄資訊量之高密度 化而縮短記錄標示,其中,雷射光束之功率多階交換以作 多階記錄時,其信號品質之劣化明顯。易言之,若採用多 階記錄則記錄標示難以高密度化,有陷於不相容狀況之問 題。 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) &quot; -4 - (請先閱讀背面之注意事項再填寫本頁jPrinted by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy 583654 A7 B7 V. Description of the Invention (:) Technical Field The present invention is related to the information provided for recording. Various record marks are formed on the recording layer, which is the light of multi-level recording of information. Recording media. The prior optical recording media used to change the length of the playback signal (the length of the reflection signal modulation unit) is multi-level for data recording. Compared with this method, the depth of the playback signal (the modulation of the reflection signal) is changed. For multi-level exchanges, the recording methods of recording most data with each signal of the same length have many related researches. With this optical recording method, as compared with only the presence or absence of pits to record secondary data, since most data can be recorded in the depth direction, the amount of signals allocated to a certain length can be increased, so the linear recording density can be increased. At present, such a recording medium has been proposed using a hologram or a multi-layered recording layer. Here, the multi-level recording refers to recording a plurality of types of recording materials whose modulation degrees of the reflected signals are different from each other. On the other hand, with regard to these multi-level recording optical recording methods, there is a problem that the power of the laser beam increases during recording, and as the depth of the formed reflected signal deepens, the signal quality deteriorates during playback. The reason for this is currently unknown. For example, conventional methods are used to shorten the recording mark to increase the density of information recorded on the recording medium. Among them, when the laser beam power is multi-level exchanged for multi-level recording, the signal quality deteriorates significantly. In other words, if a multi-level recording is adopted, it is difficult to increase the density of the recording marks, and there is a problem of incompatibility. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) &quot; -4-(Please read the precautions on the back before filling in this page j

經濟部智慧財產局員工消費合作社印製 583654 A7 B7 五、發明説明() 又,以往將雷射光束功率作階層交換以作多階記錄之 光記錄方法,其想法之前提係,記錄標示之長度大於記錄 時聚光光束(光束腰部)之直徑。即’多階調變記錄標示 本身之光反射率,以讓反射率之直接讀取’實現多階記錄 〇 一般聚焦光束之直徑係以Κλ/ΝΑ (K :常數,λ :雷射波長,N A :透鏡開口數)表之。利用於C D之檢 取一般係λ = 780奈米,ΝΑ=0 · 45,聚焦光束之 直徑約爲1 . 6微米。此時,若記錄標示長度近乎1 . 6 微米,則上述信號劣化之問題顯現,難爲5階以上之多階 記錄。 以上問題應係雷射光束之功率設定’記錄媒體之特性 等所有要素錯雜糾葛之結果,就本發明人所知,其原因目 前尙在未知,高密度多階記錄包含其記錄方法尙未達成仍 係實情。 本發明係鑒於上述問題而完成,其目的在提議新穎多 階記錄方法,以達成高密度之多階記錄。 本發明人就光記錄媒體一再精心探討,發現多階記錄 之記錄方法,確認以該方法,可於光記錄媒體作5階以上 之高密度多階記錄。 即,以如下之本發明可達成上述目的。 (1 )於具特定溝之透光性基板,至少覆蓋上述之溝 形成主要係由酞菁色素所成之記錄層,以雷射光束照射, 至少於上述記錄層形成記錄標示,可作資訊之記錄之光記 本&amp;張尺度適用中國國家標準(〇~$)人4規格(210父297公釐) ' (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583654 A7 B7 V. Description of the Invention () In addition, in the past, the optical recording method that used laser beam power as a hierarchical exchange for multi-level recording, the idea was previously mentioned, and the length of the record mark Larger than the diameter of the focused beam (beam waist) during recording. That is, the "multi-level modulation record indicates the light reflectivity of the record itself to allow direct reading of the reflectance" to achieve multi-level recording. The diameter of the general focused beam is κλ / ΝΑ (K: constant, λ: laser wavelength, NA : Number of lens openings). The detection used in CD is generally λ = 780 nm, NA = 0.45, and the diameter of the focused beam is about 1.6 microns. At this time, if the record mark length is approximately 1.6 micrometers, the above-mentioned problem of signal degradation becomes apparent, and it is difficult to record at 5 or more levels. The above problem should be the result of the intricate entanglement of all the factors such as the power setting of the laser beam and the characteristics of the recording medium. As far as the inventors know, the reason is currently unknown. High-density multi-level recording includes its recording method. Department of truth. The present invention has been made in view of the above problems, and an object thereof is to propose a novel multi-level recording method to achieve high-density multi-level recording. The present inventors have repeatedly carefully studied the optical recording medium and found a recording method for multi-level recording. It is confirmed that with this method, high-density multi-level recording of 5 levels or more can be performed on the optical recording medium. That is, the above-mentioned object can be achieved by the following invention. (1) On a translucent substrate with a specific groove, at least the above grooves are covered to form a recording layer mainly composed of a phthalocyanine pigment, which is irradiated with a laser beam, and at least a recording mark is formed on the above recording layer, which can be used as information. Record of light &amp; Zhang scales apply Chinese national standard (〇 ~ $) person 4 specifications (210 father 297 mm) '(Please read the precautions on the back before filling this page)

583654 Α7 Β7 五、發明説明(^ (請先閲讀背面之注意事項再填寫本頁) 錄媒體,其特徵爲,上述記錄層中沿上述之溝,於用以記 錄播放之雷射照射行進方向,連續定出沿該行進方向之任 意單位長度及其正交方向之任意單位寬度所成之虛擬記錄 胞,同時,以上述雷射光束之波長爲λ (奈米),上述雷 射光束照射光學系之物質開口數爲Ν Α時,設定上述溝寬 W (奈米)爲 〇 · 25χ (λ/ΝΑ) &lt;W&lt;〇 · 55x ( λ / N A ),將照射時間或照射功率之至少其一設定成5 階以上,以上述雷射光束照射,可於上述虛擬記錄胞形成 5種以上大小不同之記錄標示,基於上述記錄標示對於該 虛擬記錄胞之面積比調變光反射率,以作資訊之多階記錄 〇 (2 )上述(1 )之光記錄媒體,其中上述溝寬W係 設定爲0·30χ (A/NA)&lt;W&lt;〇.5〇x ( λ/ΝΑ),較佳者爲 Ο · 32x (λ/ΝΑ) &lt;W&lt; 0·45χ (又/NA)。 經濟部智慧財產局員工消費合作社印製 (3)上述(1)或(2)之光記錄媒體,其中上述 之溝係大致平行多數形成,相鄰之上述溝之間距Ρ (奈米 )係設定爲Ο . 65χ (λ/ΝΑ) &lt;Ρ,較佳者爲 0·7χ (λ/ΝΑ)&lt;Ρ&lt;1 ·2χ (λ/ΝΑ)。 本發明人發現,藉對虛擬記錄胞之記錄標示之占有比 率之新穎調變手法,可作多階記錄。該結果可飛躍提升記 錄密度。 但是,僅以照射時間或照射功率之調變形成記錄標示 ,則有時無法切實讀取該記錄標示。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 583654 Α7 Β7 五、發明説明(j 其理由之一應係,虛擬記錄胞中非設定高精度之多階 光反射率不可,多階記錄容易受到特別是光記錄媒體的構 造之影響。具體而言,如本發明形成多階記錄標示時,因 可形成小於雷射光點之記錄標示,可設定比以往窄之溝寬 ,另一方面,若溝寬W在0·25χ (λ/ΝΑ)以下, 則虛擬記錄胞中各階之光反射率誤差突然加大,以上經本 發明人之多方探討已有所知。其理由之一應係,受制於溝 寬記錄標示無法成長至預定大小而調變度下降。 又再,理由雖尙不明,但知隨溝寬之變窄,預定成具 相同反射率階層之多數虛擬記錄胞間,有實際反射率階層 變異(即重複再現性降低)之現象發生,信號品質明顯下 降(錯誤値惡化)。 而反之,軌距不變溝寬在055χ (λ/ΝΑ)以 上時,受相鄰溝之記錄標示影響,易於產生串訊(相鄰溝 之記錄標示與本來應予讀寫之記錄標示同時爲所讀寫之現 象)。其防止即須擴大溝之間距(下稱軌距),但不必要 之軌距加大卻反使記錄密度下降。 又,理由雖仍不明,但知爲使虛擬記錄胞爲低反射率 階層而形成相對較大記錄標示時,其反射率之變異加大。 因之仍有錯誤値惡化等之信號品質惡化隨著發生。 亦即,有如目前之二値記錄方法,不僅須依記錄層之 種類等設定溝寬,爲作多階記錄必須設定合乎該目的之溝 寬,若疏於設定如此之溝寬,則導致多階持有之信號品質 劣化之結果。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) «1 *11 經濟部智慧財產局員工消費合作社印製 583654 A7 B7 五、發明説明(g (請先閲讀背面之注意事項再填寫本頁) 此一傾向固亦取決於目前發展中之記錄線速,必須依 記錄線速選擇溝寬,而因有愈高速(例如相對於c D - R 等之標準線速1 . 2米/秒之8倍以上’以至於2 0倍左 右)則適用之溝寬範圍(邊距)變窄之傾向’若以某程度 之高速記錄爲前提作設計,則低速記錄之範圍應亦可涵括 0 以上可確認在光反射率調變爲5階以上而記錄資訊時 ,(較之以下階數時)尤爲明顯有用。 而上述之本發明亦可作以下附加。 其特徵爲,沿上述記錄層設雷射光導用溝,於該溝內 設定上述虛擬記錄胞,並且上述單位寬度約等於上述溝寬 之光記錄媒體。 其特徵爲,記錄有呈示係爲多階記錄媒體之特定資訊 之光記錄媒體。 其特徵爲,沿上述記錄層設雷射光導用溝,該溝部份 中斷之光記錄媒體。 經濟部智慧財產局員工消費合作社印製 而在此所謂溝寬,指得自溝與溝間所夾基面之最高點 ,與溝底最低點之最大溝深,大致二等分處之溝寬,係一 般稱作半値寬之値。如此定義乃爲考慮當溝(或基面)之 截面形狀爲梯形之情況。 發明之較佳實施形態 以下參照圖面詳細說明本發明之實施形態例。 本發明之實施形態例有關之光記錄媒體(光碟)1 〇 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -8- 583654 A7 B7___ 五、發明説明(g ,係記錄層1 2用到色素材料之C D 一 R。C D - R者係 含例如透明基材所成之基板1 4,覆蓋形成於該基板1 4 之一面(第1圖中之上面)之雷射光導用溝16之塗布色 素所成之上述記錄層1 2,該記錄層1 2之上側以職鍍等 形成之金或銀等之反射膜1 8,及覆蓋該反射膜1 8外側 之保護層2 0而形成。 用於上述記錄層1 2之色素,主要以使用酞菁系色素 及萘菁系色素,下述一般式〔化1〕之所有酞菁系色素之 有機色素爲佳。其具體例有例如下述〔化2〕等。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 1化 11583654 Α7 Β7 V. Description of the invention (^ (Please read the precautions on the back before filling out this page) recording medium, which is characterized in that the recording layer along the above-mentioned groove is used to record the direction of laser irradiation for recording and playback. A virtual recording cell formed by an arbitrary unit length in the direction of travel and an arbitrary unit width in an orthogonal direction is continuously determined, and at the same time, the wavelength of the laser beam is λ (nanometer), and the laser beam irradiates the optical system. When the number of substance openings is Ν Α, the groove width W (nano) is set to 0.25 × (λ / ΝΑ) &lt; W &lt; 0.55 × (λ / NA), and at least one of the irradiation time or irradiation power is set. Set to 5 or more levels, and irradiate with the laser beam to form more than 5 kinds of record marks with different sizes on the virtual record cell. Based on the area ratio of the record mark to the virtual record cell, adjust the light reflectance for information. (2) The optical recording medium of the above-mentioned (1), wherein the groove width W is set to 0 · 30χ (A / NA) &lt; W &lt; 0.50x (λ / ΝΑ), which is preferable 0 × 32x (λ / ΝΑ) &lt; W &lt; 0 · 45χ (also / NA) (3) The optical recording medium of the above (1) or (2) is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, wherein the above-mentioned grooves are formed in a substantially parallel majority, and the distance P (nanometre) between the adjacent grooves is set. 65 × (λ / ΝΑ) &lt; P, more preferably 0 · 7χ (λ / ΝΑ) &lt; P &lt; 1 · 2χ (λ / ΝΑ). The present inventors have found that by virtue of the records of the virtual record cell The novel modulation method of the occupation ratio of the label can be used for multi-level recording. This result can greatly increase the recording density. However, only when the recording label is formed by the modulation of the irradiation time or the irradiation power, it is sometimes impossible to actually read the label. . This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 583654 Α7 Β7 V. Description of the invention (j One of the reasons should be that the multi-order light reflectivity of the virtual record cell cannot be set with high accuracy. Multi-level recording is easily affected by the structure of optical recording media in particular. Specifically, when the multi-level recording mark is formed in the present invention, a record mark smaller than the laser light spot can be formed, and a narrower groove width than in the past can be set. On the one hand, if If the width W is less than 0 · 25χ (λ / ΝΑ), the light reflectance error of each order in the virtual recording cell suddenly increases, and the above has been known by the inventors. One of the reasons is that it is restricted by the groove. The wide record mark cannot grow to a predetermined size and the modulation degree decreases. Furthermore, although the reason is unknown, it is known that as the groove width becomes narrower, most virtual record cells with the same reflectance hierarchy are scheduled to have actual reflectance hierarchy. The phenomenon of mutation (reduced reproducibility) occurs, and the signal quality is significantly reduced (errors and deterioration). Conversely, when the track width is constant and the groove width is more than 055 × (λ / NA), it is easy to generate crosstalk due to the recording marks of adjacent grooves (the recording marks of adjacent grooves and the recording marks that should be read and written at the same time are Read and write). This prevents the gap between grooves (hereinafter referred to as the track pitch) from being enlarged, but the increase of unnecessary track pitches actually decreases the recording density. In addition, although the reason is still unknown, it is known that when a relatively large record mark is formed in order to make the virtual record cell into a low reflectance layer, the variation of the reflectance increases. As a result, signal quality deterioration, such as errors and deterioration, occurs. That is, like the current two-line recording method, not only must the groove width be set according to the type of recording layer, etc., but for multi-level recording, a groove width suitable for the purpose must be set. If this groove width is neglected, multi-level The result of the deterioration of the signal quality held. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (please read the notes on the back before filling this page) «1 * 11 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 583654 A7 B7 V. Invention Explanation (g (Please read the notes on the back before filling this page) This tendency also depends on the current recording line speed. You must select the groove width according to the recording line speed, and because there is a higher speed (for example, compared to c D-R and other standard line speeds of 1.2 times / m 8 times or more (to about 20 times), then the applicable groove width (margin) tends to become narrower. For design, the range of low-speed recording should also include 0 or more. It can be confirmed that it is particularly useful when recording information when the light reflectance is adjusted to 5 or more (compared to the following order). And the present invention described above It can also be added as follows. It is characterized in that a laser light guide groove is provided along the recording layer, and the virtual recording cell is set in the groove, and the unit width is approximately equal to the groove width of the optical recording medium. Presented It is an optical recording medium for specific information of a multi-level recording medium. It is characterized in that a laser light guide groove is provided along the recording layer, and the optical recording medium is partially interrupted by the groove. The so-called groove width refers to the groove width obtained from the highest point of the base surface sandwiched between the groove and the groove, and the maximum groove depth at the lowest point of the groove bottom, which is roughly equal to two equal divisions. This is to consider the case where the cross-sectional shape of the groove (or base surface) is trapezoidal. Preferred Embodiments of the Invention The following describes embodiments of the present invention in detail with reference to the drawings. Optical recording media (optical discs) related to the embodiments of the present invention ) 1 〇 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -8-583654 A7 B7___ V. Description of the invention (g, CD-R for pigment material used in recording layer 12. CD-R The recording layer 12 includes a substrate 14 formed of, for example, a transparent base material, and a coating pigment covering the laser light guide groove 16 formed on one surface (upper surface in FIG. 1) of the substrate 14, The recording layer 1 of 2 A gold or silver reflective film 18 formed on the upper side by professional plating and the like and a protective layer 20 covering the outside of the reflective film 18 are formed. The pigment used for the recording layer 12 is mainly a phthalocyanine pigment And naphthalocyanine pigments, organic pigments of all phthalocyanine pigments of the following general formula [Chemical Formula 1] are preferred. Specific examples include the following [Chemical Formula 2], etc. (Please read the precautions on the back before filling in this Page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 11

〔化1〕中Ql、Q2、Q3及Q4各表構成苯瓌或 -9- 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 583654 A7 B7 五、發明説明([Chemical 1] The tables of Ql, Q2, Q3 and Q4 constitute benzene or -9- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 583654 A7 B7 V. Description of the invention (

(請先閲讀背面之注意事項再填寫本頁)(Please read the notes on the back before filling this page)

583654 A7 B7 五、發明説明(g (請先閲讀背面之注意事項再填寫本頁) 乙基)己氧基、6 —(全氟己基)己氧基等),·取代或無 取代芳氧基(苯氧基、對硝基苯氧基、對三級丁基苯氧基 、3 -氟苯氧基、五氟苯氧基、3 一三氟甲基苯氧基等) ;取代或無取代之烷硫基(甲硫基、乙硫基、三級丁硫基 、己硫基、辛硫基、三氟甲硫基等);取代或無取代之芳 硫基(苯硫基、對硝基苯硫基、對三級丁基苯硫基、3 -氟苯硫基、五氟苯硫基、3 -三氟苯硫基等)等。 這些取代基之中,以烷基、烷氧基爲較佳。烷基以碳 原:ί數1至1 2之取代烷基爲特佳,其可係直鏈或分枝狀 〇 此時之取代基係以氟原子等鹵素原子爲佳。又,烷氧 S以碳原子數1至1 2之取代烷氧基爲佳,其烷基部份可 係直鏈或分枝狀。此時之取代基係以氟原子等之鹵素原子 爲佳。 經濟部智慧財產局員工消費合作社印製583654 A7 B7 V. Description of the invention (g (Please read the notes on the back before filling this page) Ethyl) hexyloxy, 6- (perfluorohexyl) hexyloxy, etc.), · Substituted or unsubstituted aryloxy (Phenoxy, p-nitrophenoxy, p-tert-butylphenoxy, 3-fluorophenoxy, pentafluorophenoxy, 3-trifluoromethylphenoxy, etc.); substituted or unsubstituted Alkylthio (methylthio, ethylthio, tertiary butylthio, hexylthio, octylthio, trifluoromethylthio, etc.); substituted or unsubstituted arylthio (phenylthio, p-nitrate Phenylthio, p-tert-butylphenylthio, 3-fluorophenylthio, pentafluorophenylthio, 3-trifluorophenylthio, etc.). Among these substituents, an alkyl group and an alkoxy group are preferred. The alkyl group is particularly preferably a substituted alkyl group having 1 to 12 carbon atoms, which may be linear or branched. 0 The substituent at this time is preferably a halogen atom such as a fluorine atom. The alkoxy S is preferably a substituted alkoxy group having 1 to 12 carbon atoms, and the alkyl portion thereof may be linear or branched. The substituent at this time is preferably a halogen atom such as a fluorine atom. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Ml所表之中心原子有氫原子(2Η)或金屬原子。 此時之金屬原子可係週期表1至14族(1A至7A族、 8族、1B至4B族)之金屬原子等,具體有Li 、Na 、K、Mg、Ca、Ba、Ti 、Zr、V、Nb、Ta 、Cr、Mo、W、Mn、Tc、Fe、Co、Ni 、The central atom represented by Ml is a hydrogen atom (2Η) or a metal atom. The metal atom at this time may be a metal atom of Groups 1 to 14 (Groups 1A to 7A, Group 8, 1B to 4B) of the periodic table, and specifically, Li, Na, K, Mg, Ca, Ba, Ti, Zr, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Fe, Co, Ni,

Ru、Rh、Pd、〇s、Ir、Pt、Cu、Ag、Ru, Rh, Pd, 0s, Ir, Pt, Cu, Ag,

Au、Zn、Cd、Hg、Al、In、Tl、Si、Au, Zn, Cd, Hg, Al, In, Tl, Si,

Ge、Sn、Pb 等。其中以 Li 、Ti 、V、Cr、Ge, Sn, Pb, etc. Among them Li, Ti, V, Cr,

Mn、Fe、Co、Ni 、Cu、Zn、Al 、Si 等爲 佳,S i爲特佳。 本紙張尺度適用中國國家標準(CMS ) A4規格(21〇X 297公釐) -11 - 583654 A7 B7 五、發明説明(g - 而〔化1〕中之R 1至R 4通常係同一,但亦可不同 〇 (請先閱讀背面之注意事項再填寫本頁) γ 1所表之配位基有氫原子、氧原子、鹵素原子、羥 基、烷基、烷氧基、醯氧基或〔化3〕之基。 【化3】Mn, Fe, Co, Ni, Cu, Zn, Al, Si, etc. are preferred, and Si is particularly preferred. This paper size applies the Chinese National Standard (CMS) A4 specification (21〇X 297 mm) -11-583654 A7 B7 V. Description of the invention (g-R1 to R4 in [Chemical 1] are usually the same, but It can also be different. (Please read the precautions on the back before filling out this page) γ 1 The ligands listed in the table are hydrogen, oxygen, halogen, hydroxyl, alkyl, alkoxy, fluorenyl, or 3] 的 基。 [化 3]

〔化3〕中R5、R6各表烷基、芳基、烷氧基或芳 氧基,可係相同或不同。 Y1所表之國素原子、院基、院氧基、R5、R6所 表之院基、芳基、烷氧基、芳氧基之具體例有r 1至^4 之基。 Y 1所表醯氧基有乙醯氧基、丙醯氧基等。 γ 1以〔化3〕之基爲佳,R 5、R 6以取代或無取 代之碳原子數1至6之烷基、苯基等芳基爲佳。 〔化1〕中以〔化2〕之化合物爲佳。 經濟部智慧財產局資工消費合作社印製 〔化 2〕中 Rl'RS'RS'Re'p'Q'r、 S 、t 、U、V及w各與〔化1〕同義,較佳者亦同。〔 化2〕中R5或R6間,或R5A及R6通常係同,但有 時亦可不同。 〔化2〕之具體例以R 1至R 5,P至w之組合如_ 1所示。 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇'〆297公釐) -12- 583654 A7 B7 五 、發明説明(&amp; 〔表 化合物 No. R1 ( = R2-R3-R4) R5 ( = R6) P (二q=r=s) τ (二 11 = v = w) 2-1 -CF2CF3 -Ph(苯基) 1 1 2-2 -CF2CF3 + Ph(苯基)- 0 1 2-3 -OCH2CF3 C4H6 1 1 2-4 -CF2CHF3 -Ph(苯基) 1 1 2-5 -OCH2CF3 -Ph(苯基)- 1 1 2-6 -OCH2CF3 C4H9 1 1 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局Μ工消費合作社印製 於上述光記錄媒體1 0之多階記錄,係以如第2圖之 光記錄媒體30爲之。 該光記錄裝置3 0係C D - R / R W燒錄機,經轉軸 伺服裝置3 1以轉軸馬達3 2於一定線速之條件旋轉驅動 光記錄媒體(光碟)1 〇,以來自雷射3 6之雷射光束將 資訊記錄於光記錄媒體(光碟)1 0。 雷射驅動器3 8隨欲予記錄之資訊,對第1圖虛擬記 錄胞(詳如後敘)4 0各一之雷射光束照射時間,例如輸 入上述雷射3 6之雷射脈衝數加以控制。 第2圖符號4 2係包含物鏡4 2 Α及半鏡4 2 Β之照 射光學系。物鏡4 2 A由焦點追踪伺服裝置4 4控制,將 雷射光束聚焦於光碟1 〇之記錄餍1 2。而物鏡4 2A及 半鏡4 2 B由輸送伺服裝置4 6,與光碟1 0之旋轉同步 ,從其內周往外周以特定速度控制移動。 本纸張尺度適用中國國家標準(CNS ) Α4規格(21〇χ297公釐) -13- 583654 A7 ____B7 五、發明説明(^ (請先閲讀背面之注意事項再填寫本頁) 上述轉軸伺服裝置3 1、焦點追踪伺服裝置4 4、輸 送伺服裝置4 6係由控制裝置5 0控制。欲記錄於記錄層 1 2之資料(資訊)係輸入於控制裝置5 0。 如第3圖所示,雷射驅動器3 8具電路胞時間設定部 6 0、記錄照射時間設定部6 2,及分配處理部6 4。In [Chemical Formula 3], each of R5 and R6 is an alkyl group, an aryl group, an alkoxy group, or an aryloxy group, and may be the same or different. Specific examples of the atom, the aryl group, the aryl group, the aryl group, the aryl group, the alkoxy group, and the aryloxy group represented by Y1 include the groups r 1 to ^ 4. Examples of the fluorenyloxy group represented by Y 1 include ethynyloxy and propionyloxy. γ 1 is preferably a group of [Chemical Formula 3], and R 5 and R 6 are preferably substituted or unsubstituted aryl groups such as an alkyl group having 1 to 6 carbon atoms and a phenyl group. Among the compounds of [Chemical Formula 1], [Chemical Formula 2] is preferable. Rl'RS'RS'RS'Re'p'Q'r, S, t, U, V, and w printed in [Chemical 2] by the Intellectual Property Consumer Cooperative of the Ministry of Economic Affairs are synonymous with [Chemical 1], whichever is better The same. In [Chemical Formula 2], R5 or R6, or R5A and R6 are usually the same, but sometimes they may be different. A specific example of [Chemical Formula 2] is represented by R 1 to R 5, and the combination of P to w is shown as -1. This paper size applies the Chinese National Standard (CNS) A4 specification (21〇'297 mm) -12-583654 A7 B7 V. Description of the invention (&amp; table compound No. R1 (= R2-R3-R4) R5 ( = R6) P (two q = r = s) τ (two 11 = v = w) 2-1 -CF2CF3 -Ph (phenyl) 1 1 2-2 -CF2CF3 + Ph (phenyl)-0 1 2- 3 -OCH2CF3 C4H6 1 1 2-4 -CF2CHF3 -Ph (phenyl) 1 1 2-5 -OCH2CF3 -Ph (phenyl)-1 1 2-6 -OCH2CF3 C4H9 1 1 (Please read the precautions on the back first (Fill in this page) The multi-level record printed on the optical recording medium 10 by the Intellectual Property Bureau of the Intellectual Property Bureau of the Ministry of Economic Affairs is based on the optical recording medium 30 shown in Figure 2. The optical recording device 30 is a CD- R / RW burner, through the spindle servo device 3 1 with a spindle motor 3 2 to rotate and drive the optical recording medium (disc) 1 〇 at a certain line speed, and the information is recorded on the light with a laser beam from the laser 36 Recording medium (optical disc) 1 0. Laser drive 3 8 According to the information to be recorded, the laser beam irradiation time of each of the virtual recording cells in the first picture (detailed later) 4 0, for example, enter the above laser 3 Laser Pulse of 6 The symbol 4 2 in Fig. 2 is an irradiating optical system including an objective lens 4 2 A and a half mirror 4 2 Β. The objective lens 4 2 A is controlled by a focus tracking servo device 4 4 and focuses the laser beam on the optical disc 1 〇 Record 餍 1 2. The objective lens 4 2A and half mirror 4 2 B are synchronized with the rotation of the optical disc 10 by the conveying servo device 46, and the movement is controlled at a specific speed from the inner periphery to the outer periphery. This paper standard applies Chinese national standards (CNS) A4 specifications (21 × 297 mm) -13- 583654 A7 ____B7 V. Description of the invention (^ (Please read the precautions on the back before filling out this page) The above-mentioned rotary servo device 3 1. Focus tracking servo device 4 4 The conveying servo device 46 is controlled by the control device 50. The data (information) to be recorded in the recording layer 12 is input to the control device 50. As shown in Figure 3, the laser driver 3 has 8 circuit cell times. The setting section 60, the recording irradiation time setting section 62, and the distribution processing section 64.

電路胞時間設定部6 0連續規定特定之電路胞時間T (Tl 、T2、T3 ' T4、T5、T6 .........)。結果 ,例如對雷射3 6光記錄媒體1 0之移動速度(線速度) 爲v時,於該光記錄媒體1 0上連續規定長度Η爲“ v X Τ ”之虛擬記錄胞4 0。The circuit cell time setting unit 60 continuously specifies a specific circuit cell time T (Tl, T2, T3, T4, T5, T6 ...). As a result, for example, when the moving speed (linear velocity) of the laser 36 optical recording medium 10 is v, the virtual recording cell 40 of a predetermined length Η “v X Τ” is continuously recorded on the optical recording medium 10.

記錄照射時間設定部6 2於上述電路胞時間Τ以內規 定5階以上(在此係t Α至t G之7階)之照射時間t A .........t G。此時,可先將照射時間t A ......... t G記錄 於記憶體,再將之讀取而規定,亦可讀取已寫入光記錄媒 體1 0之記錄照射時間資訊。 經濟部智慧財產局員工消費合作社印製 分配處理部6 4調變儲存在控制裝置5 0之原資訊, 設定多階記錄用之位元系列分配於各電路胞時間。該多階 用之位元系列,在此因有7階(A、B、C、D、E、F ' G )記錄標示存在,故係例如丨B、E、D、C、G、 G .........丨等。各該數値代表形成於各記錄電路胞4 0之 記錄標示之階層。因此,對應上述位元系列之各階層,上 述照射時間t A至t G即分配於各電路胞時間τ 1、T 2 如第1圖,光記錄媒體1 0在上述溝1 6內,於光碟 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) -14- 583654 A7 _____ B7 五、發明説明(^ 3 4之圓周方向s連續規定虛擬記錄胞4 0。各虛擬記錄 胞4〇圓周方向S之單位長度爲Η (二vxT),係設定 成短於光束徑(光束腰部之直徑)D (參照第4圖)。而 相鄰溝1 6間形成有基面1 7。 虛擬記錄電路胞4 0,其正交於上述單位長度Η (= νxT)方向之單位寬度約與上述溝16之寬度W—致。 上述雷射3 6之雷射光束波長爲λ,照射光學系4 2 之物鏡4. 2Α之開口數爲ΝΑ時,上述溝1 6之寬度W係 設定爲 0 · 25χ (λ/ΝΑ) &lt;W&lt;〇 . 55χ ( λ / Ν A )。例如,本實施形態中λ = 7 8 5 (奈米), ΝΑ二〇 · 5,故溝寬W係設定於〇 · 39&lt;W&lt; 〇 · 86 (微米)之範圍內。而較佳者係設定成溝寬W爲 0 . 3〇χ (λ/ΝΑ) &lt;W&lt;〇 . 50χ (λ/ΝΑ), 上述條件下即0 · 47&lt;W&lt;〇 · 79 (微米),更佳者 爲0·50&lt;W&lt;0·71(微米)。 較佳之溝深在5 0至3 0 0奈米,更佳者在5 0至 2 0 0奈米左右。此所謂溝深指溝最深處與基面最高處正 交方向之高度差(深度)。 本實施形態中相鄰溝1 6之間隔(軌距)P係設定爲 0 · 65χ (λ/ΝΑ)&lt;ρ,以 〇·7χ (λ/ΝΑ) &lt; Ρ &lt; 1 · 2 χ ( λ / N A )爲佳。以雷射光束逐一照射各 虛擬記錄胞4 0,隨欲予記錄之資訊,形成示意例之記錄 標示48A至48G。 具體係包含以下步驟形成記錄標示4 8A至4 8 G。 本紙張尺度適用中國國家標準(CNS ) A4規格(2】OX297公釐) (請先閱讀背面之注意事項再填寫本頁) *訂 經濟部智慧財產局員工消費合作社印製 -15- 583654 A7 B7 五、發明説明(h 將實資訊記錄於光記錄媒體1 〇之際,以電路胞時間 τ之設定,如上述連續規定虛擬記錄胞4 0,設定對該虛 擬記錄胞4 0之雷射光束照射時間t A至t G。 結果,如第5圖之時間圖,對應原資訊調變而得之位 元列丨B、E、D、C、G、G .........丨於各電路胞時間 Τ 1、T 2、T 3 .........分配照射時間{ t B、t E、 t D、t C、t G、t G .........丨。而在此係呈示從各電 路胞時間T之開頭設定照射時間t之情形(即前端標準) ,亦可於各電路胞時間T之中央設定照射時間(中間標準 ),或以各電路胞時間T之後端爲標準設定照射時間(後 端標準)。 依該時間圖,若照射時間t內以雷射光束照射,實際 形成記錄標示4 8A至4 8 G,即可將各記錄電路胞4 0 設定爲所欲之光反射率。 該記錄標示4 8 A至4 8 G不於雷射光束之光點全部 而於中心部形成(雷射光束係圓形,光碟1 〇 —面旋轉一 面以雷射光束照射,故記錄標示隨照射時間之長度成爲長 圓形)。 經聚焦之雷射光束一般係呈高斯分布,於記錄層1 2 ,僅只雷射光束之照射能量超越某閥値之部份進行記錄, 故從中心依序朝外側擴展,形成記錄標示4 8 A至4 8 G ,此即其原因。藉此,例如第4圖所示,可形成對虛擬記 錄胞4 0之占有率不同之7階記錄標示4 8A至4 8 G。 此時各記錄標示4 8 A至4 8 G之大小,係設定爲以 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) -訂The recording irradiation time setting unit 62 defines the irradiation time t A ......... t G of 5 steps or more (here, 7 steps of t A to t G) within the above-mentioned circuit cell time T. At this time, the irradiation time t A ......... t G can be recorded in the memory first, and then read and specified, or the recorded irradiation time written in the optical recording medium 10 can be read. Information. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The distribution processing section 64 modulates the original information stored in the control device 50, and sets the bit series for multi-level recording to be allocated to each circuit cell time. This multi-level bit series, because there are 7-level (A, B, C, D, E, F'G) records indicating the existence, so for example 丨 B, E, D, C, G, G. ........ 丨 etc. Each of these numbers represents a hierarchy of record marks formed on each recording circuit cell 40. Therefore, corresponding to each level of the above-mentioned bit series, the above-mentioned irradiation time t A to t G is allocated to each circuit cell time τ 1 and T 2 as shown in FIG. 1. The optical recording medium 10 is in the groove 16 and is on the optical disc. This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -14- 583654 A7 _____ B7 V. Description of the invention (^ 3 The circumferential direction s of 4 continuously specifies virtual record cells 40. Each virtual record cell 4 〇The unit length of the circumferential direction S is Η (two vxT), which is set to be shorter than the beam diameter (the diameter of the beam waist) D (refer to FIG. 4). A base surface 17 is formed between adjacent grooves 16. Virtual The recording circuit cell 40 has a unit width orthogonal to the direction of the unit length Η (= νxT) approximately the same as the width W of the groove 16. The wavelength of the laser beam of the laser 36 is λ, and the optical system 4 is irradiated. When the number of openings of the objective lens 2 and 2A is NA, the width W of the groove 16 is set to 0 · 25χ (λ / ΝΑ) &lt; W &lt; 0.555 (λ / ΝΑ). For example, this embodiment Middle λ = 7 8 5 (nanometer), ΝΑ / 2 · 5, so the groove width W is set to a range of 0.39 &lt; W &lt; 86 · (micron) The better is to set the groove width W to 0.30χ (λ / ΝΑ) &lt; W &lt; 0.50 (λ / ΝΑ), which is 0. 47 &lt; W &lt; 〇 · 79 ( Micron), more preferably 0.50 &lt; W &lt; 0.71 (micron). The preferred groove depth is 50 to 300 nm, and the more preferable is 50 to 200 nm. This is called The trench depth refers to the height difference (depth) in the orthogonal direction between the deepest part of the trench and the highest part of the base surface. In this embodiment, the interval (gauge) P between adjacent trenches 16 is set to 0 · 65χ (λ / ΝΑ) &lt; ρ, 〇7χ (λ / ΝΑ) &lt; P &lt; 1 · 2 χ (λ / NA) is preferred. Each virtual recording cell 40 is irradiated with a laser beam one by one, and the information to be recorded is formed as a schematic diagram. For example, the record marks 48A to 48G. The specific steps include the following steps to form the record marks 4 8A to 4 8 G. This paper size applies to Chinese National Standard (CNS) A4 specifications (2) OX297 mm) (Please read the precautions on the back first (Fill in this page again) * Subscribe to the printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-15- 583654 A7 B7 V. Description of the invention (h Record the real information on the optical recording medium 1 and use the circuit cell Τ between the set, as the continuous recording predetermined virtual cell 40, is set to the virtual cell recording laser beam irradiation time of 40 t A to t G. As a result, as shown in the time chart of FIG. 5, the bit sequence corresponding to the original information modulation 丨 B, E, D, C, G, G ......... 丨 at each circuit cell time T 1 , T 2, T 3 ......... Allocate irradiation time {t B, t E, t D, t C, t G, t G ......... 丨. In this case, it is shown that the irradiation time t is set from the beginning of the time T of each circuit cell (ie, the front-end standard). The irradiation time (intermediate standard) can also be set at the center of the time T of each circuit cell, or the time T of each circuit cell is set. The rear end is the standard setting irradiation time (back end standard). According to the time chart, if the laser beam is irradiated within the irradiation time t, and the recording marks 4 8A to 4 8 G are actually formed, each recording circuit cell 40 can be set to a desired light reflectance. This record indicates that 4 8 A to 4 8 G is not formed at the center of the laser beam. (The laser beam is circular. The disc is rotated on the side of the 0-plane and irradiated with the laser beam. The length of time becomes oblong). The focused laser beam generally has a Gaussian distribution. In the recording layer 12, only the portion of the laser beam whose radiant energy exceeds a certain valve is recorded. Therefore, it sequentially expands from the center to the outside to form a record mark 4 8 A. To 4 8 G, which is the reason. Thereby, for example, as shown in FIG. 4, 7-level records labeled 4 8A to 4 8 G with different occupation rates of the virtual record cell 40 can be formed. At this time, each record is marked with a size of 4 8 A to 4 8 G, which is set to apply the Chinese National Standard (CNS) A4 specification (210X297 mm) at this paper size (please read the precautions on the back before filling this page)- Order

經濟部智慧財產局員工消費合作社印製 -16- 583654 A7 B7 五、發明説明(h 雷射光束照射讀取虛擬記錄胞4 0時,儀射光之光反射率 分成7階。上述光反射率係記錄標示愈小愈大,無記錄標 示形成之虛擬記錄胞反射率最大,形成有最大記錄標示 4 8 G之虛擬記錄胞反射率最小。更詳言之,上述光反射 率,包含各記錄標示4 8A至4 8 G之透光率,應係以對 虛擬記錄胞4 0之占有率決定。 而記錄標示4 8A至4 8 G本身之透光率,隨記錄層 1 2之構成材料因雷射光束照射分解變質,其折射率起變 化、或隨記錄層1 2厚度方向之變化而有不同。若形成之 記錄標示部份之透光率爲零,此可不予考慮,僅依上述占 有率。 利用上述實施形態之光記錄媒體1 0,控制照射時間 即可達成5階以上之多階記錄。 特別是,溝寬W及軌距P係設定於特定範圍內,可高 精度、高密度形成記錄標示4 8 A至4 8 G。此即意味, 對各階層之目標光反射率,實際光反射率之誤差減少。 第6圖示本發明人之分析結果。具體而言,溝寬W係 定義爲泠X ( λ / N A ),準備Q値各不同之光記錄媒體 ,即溝寬不同之多數光記錄媒體,對各記錄媒體作多階記 錄,分析此時虛擬記錄胞之光反射率變異所產生之S D R 値。 所謂 S D R (Sigma to Dynamic Range)値,係由多階 之各階反射率及動態範圍(最大反射率與最小反射率之差 )求出,各階之信號變異。具體而言,係將反射率之標準 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) -訂 經濟部智慧財產局員工消費合作社印製 17- 經濟部智慧財產局員工消費合作社印製 583654 A7 __ —_ B7__ 五、發明説明(、 偏差CT ’以動態範圍正規化之値,該變異小則當然可作良 好信號之記錄播放。據本發明人之實驗,該S D R値以5 %以下爲佳,3 %以下爲更佳。而目標係2 %以下。 由此結果知,若溝寬W在/3二〇 · 2 5以下,則 S D R變大。其理由應係,若溝寬W過窄則記錄標示4 8 A至4 8 G無法充分形成,或者,同一反射率階層之虛擬 記錄胞間實際反射率階層變異等現象使信號品質明顯下降 ,對主要係由記錄標示4 8 A至4 8 G對虛擬記錄胞4 〇 之占有率決定之光反射率造成影響。 反之若溝寬W大,有低反射率階層之記錄標示(大記 錄標不)形成之虛擬記錄胞4 0,其反射率變異加大,信 號品質隨之惡化。 軌距P設定爲例如1 · 0微米之狀態,上述Q値設定 爲0 · 5 5之光記錄媒體,其多階記錄後狀況之示意圖, 如第7圖所示。如此,因溝寬W已充分確保,形成所欲或 以上之大記錄標示4 8 A至4 8 G之可能性高。相對地, 因基面寬度L變窄,讀取相鄰之溝1 6時有雷射光點D之 跨越,同時讀取相鄰溝1 6內之記錄標示4 8 A至4 8 G 之可能性高,難得所欲之光反射率。 亦即,不僅如目前之二値記錄方法,依記錄層之種類 等設定溝寬,爲作多階記錄,必須設定所須溝寬W,若疏 於如此之溝寬W設定,則結果導致多階持有之信號品質劣 化,惟如本實施形態之精確設定方才可得所欲之光反射率 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-16- 583654 A7 B7 V. Description of the Invention (h When the laser beam is irradiated to read the virtual record cell 40, the light reflectance of the instrument's light is divided into 7 orders. The above light reflectance is The smaller the record mark, the larger the reflectance of the virtual record cell formed without the record mark is the largest, and the reflectance of the virtual record cell with the largest record mark of 4 8 G is the smallest. More specifically, the above-mentioned light reflectance includes each record mark 4 The light transmittance of 8A to 4 8 G should be determined based on the occupancy of the virtual record cell 40. The light transmittance of the record label 4 8A to 4 8 G itself depends on the laser light of the constituent material of the recording layer 12 The light beam decomposes and degenerates, and its refractive index changes or changes with the thickness direction of the recording layer 12. If the light transmittance of the formed recording mark portion is zero, this may not be considered, and it is only based on the above occupation rate. By using the optical recording medium 10 of the above embodiment, it is possible to achieve multi-level recording of 5 or more steps by controlling the irradiation time. In particular, the groove width W and the track pitch P are set within a specific range, and recording can be performed with high accuracy and high density. Mark 4 8 A To 4 8 G. This means that the error of the target light reflectance and actual light reflectance of each layer is reduced. The sixth figure shows the analysis results of the inventors. Specifically, the groove width W is defined as Ling X ( λ / NA), prepare Q 値 different optical recording media, that is, most optical recording media with different groove widths, make multi-level recording for each recording medium, and analyze the SDR generated by the light reflectance variation of the virtual recording cell at this time 値The so-called SDR (Sigma to Dynamic Range) 値 is obtained from the multi-order reflectance and dynamic range (the difference between the maximum reflectance and the minimum reflectance) of each order, and the signal variation of each order. Specifically, the reflectance is Standard This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)-Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 17- Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the employee's consumer cooperative 583654 A7 __ —_ B7__ V. Description of the invention (, the deviation CT 'is normalized by the dynamic range, and the small variation can of course be used for recording and playing good signals. According to the inventor In experiments, the SDR 値 is preferably 5% or less, and more preferably 3% or less. The target is 2% or less. From this result, it is known that if the groove width W is / 3/20 · 25 or less, the SDR becomes large. The reason should be that if the groove width W is too narrow, the record marks 4 8 A to 4 8 G cannot be fully formed, or the actual reflectance level variation between virtual record cells of the same reflectance level significantly reduces the signal quality. It affects the light reflectance mainly determined by the record marks 4 8 A to 4 8 G on the occupancy of the virtual record cell 4 0. Otherwise, if the groove width W is large, there is a record mark with a low reflectance level (large record marks are not ) The formation of the virtual record cell 40, the reflectance variation increases, and the signal quality deteriorates. The track pitch P is set to, for example, a state of 1.0 micron, and the above-mentioned Q 値 is set to 0. 55 for a light recording medium. A schematic diagram of the state after multi-level recording is shown in FIG. 7. In this way, since the groove width W is sufficiently ensured, it is highly possible to form a desired large record mark of 4 8 A to 4 8 G. In contrast, because the width L of the base surface is narrowed, there is a possibility that the laser light spot D is crossed when the adjacent groove 16 is read, and the record marks 4 8 A to 4 8 G in the adjacent groove 16 are read at the same time. High, rare light reflectivity. That is, not only the current two recording methods, the groove width is set according to the type of recording layer, etc., for multi-level recording, the required groove width W must be set. If this groove width W setting is neglected, the result will be more The quality of the signal held by the stage is degraded, but the desired light reflectance can only be obtained if the precise setting of this embodiment is used. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back first) (Fill in this page again)

-18- 583654 A7 B7 五、發明説明(1 又,若如上抑制光反射率之誤差(滑移),階寬縮小 總階數(此爲A至G之7階)可予增加,光記錄媒體之記 錄密度得以更加提高。 本實施形態例,如第4圖,即使形成讀取雷射之聚焦 光束直徑D以下之長或寬之記錄標示(在此係所有記錄標 示4 8 A至4 8 G ),亦可充分讀取資料,故較之以往單 位面積之記錄密度飛躍提升。 而本實施形態之例係顯示使所有記錄標示均成爲聚焦 光束之直徑D以下之情況,但本發明不限於此,亦包含僅 有記錄標示之一部份在直徑D以下,或所有記錄標示均在 聚焦光束直徑D以上之情況。 又,上述光記錄裝置3 0顯示利用雷射驅動器3 8設 定雷射光束照射時間之情況,但亦可藉照射功率形成大小 不同之記錄標示。本發明只要能控制雷射光束之照射即爲 充分,例如使用可調變光束之穿透度之光門,控制雷射光 束之照射時間或照射功率亦可。 上述實施形態例中,記錄層1 2有菁等有機色素之使 用,但本發明不限於此,可用上述以外之有機色素或無機 材料、或適當使用其它材料亦可。但使用如上之有機色素 時,對應於雷射光束之5階以上之照射時間,可切實變化 記錄標示之大小而作記錄,可於極高精度讀取各記錄標示 〇 又,以上述光記錄裝置形成記錄標示之際,設定於記 錄層1 2上之虛擬記錄胞4 0之大小,不限於實施形態例 本紙張尺度適用中周國家標準(CNS ) A4規格(210X297公釐) --.-------赛—I (請先閲讀背面之注意事項再填寫本頁) I-訂 經濟部智慧財產局員工消費合作社印製 -19- 583654 A7 B7-18- 583654 A7 B7 V. Description of the invention (1 Also, if the error (slip) in the light reflectance is suppressed as above, the total number of steps width reduction (this is the 7th order from A to G) can be increased, and the optical recording medium The recording density can be further improved. As shown in FIG. 4 in this embodiment, even if a record mark of a length or width below the focused beam diameter D of the read laser is formed (all record marks here are 4 8 A to 4 8 G ), Can also fully read the data, so the recording density per unit area is greatly improved compared to the past. The example of this embodiment shows the case where all the recording marks are below the diameter D of the focused beam, but the invention is not limited to this It also includes the case where only a part of the recording marks are below the diameter D, or all the recording marks are above the diameter of the focused beam D. In addition, the above-mentioned optical recording device 30 displays the use of a laser driver 38 to set the laser beam irradiation. Time, but it is also possible to form record marks of different sizes by the irradiation power. The present invention is sufficient as long as it can control the irradiation of the laser beam, such as the use of an optical gate with adjustable beam penetration The irradiation time or irradiation power of the light beam may also be used. In the above embodiment, the recording layer 12 is used with organic pigments such as cyanine, but the present invention is not limited to this, and organic pigments or inorganic materials other than the above may be used, or other appropriate ones may be used. Materials can also be used. However, when using the above organic pigments, corresponding to the irradiation time of the laser beam 5th order or more, the size of the record mark can be changed and recorded, and each record mark can be read with high precision. When the above-mentioned optical recording device forms a recording mark, the size of the virtual recording cell 40 set on the recording layer 12 is not limited to the embodiment. The paper size is applicable to the China National Standard (CNS) A4 specification (210X297 mm)- -.------- Sai—I (Please read the notes on the back before filling out this page) I-Order Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-19- 583654 A7 B7

五、發明説明(W 者。此雖示虛擬記錄胞4 0之寬約與溝寬W —致之情況, 但若可例如壓縮至小於雷射光束之腰部直徑,則其在溝 1 6之寬度W以下亦無妨。長度Η亦同。另一方面,以多 於8階等之多階形成記錄標示時,亦可將虛擬記錄胞4 0 之大小設定於雷射光束腰徑以上。此時可係部份記錄標示 其大小在光束腰徑以上。 又,上述雷射光束,在記錄層1 2之位置係使其爲圓 形,但亦可如第8圖,例如於物鏡4 2 Α加光束整形稜鏡 4 2 C,開口以使光束形狀成爲記錄媒體1 〇之輸送方向 短,正交方向長之長圓形、或線形。此時因記錄標示4 9 縮短,虛擬記錄胞可更爲縮短。亦即記錄密度得以提升。 又再,該光記錄媒體1 0,如第1圖之符號5 2所示 ,可預先形成信號調變階數之多數反射率不同的坑、或於 該光記錄媒體之一部份先以本發明之光記錄方法作多階記 錄。於這些多數坑5 2及/或經多階記錄部份之記錄標示 5 4,亦可記錄有該記錄媒體之個別識別資訊,識別其係 多階記錄用光記錄媒體之資訊,用以決定記錄播放該記錄 媒體所須雷射光束照射時間之資訊,關於溝寬W之資訊等 特定資訊。該特定資訊可藉該光記錄媒體之播放及/或記 錄時之讀寫,切實識別其係多階記錄用之光記錄媒體,更 可作其個別識別,可更切實進行多階記錄、播放。 通常,CD — R/RW或DVD - R/RW用之媒體 ,係以記錄溝之蛇行(晃動)輸入信號。該信號稱作位址 信號,記錄裝置藉讀取該信號,可將記錄頭移往特定位置 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇X297公釐) (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 -20- 583654 A7 ____ B7____V. Description of the invention (W. This shows the fact that the width of the virtual recording cell 40 is about the same as the groove width W, but if it can be compressed to be smaller than the waist diameter of the laser beam, for example, it is in the width of the groove 16 It does not matter if it is below W. The same applies to the length 另一方面. On the other hand, when the record mark is formed in more than eight steps, the size of the virtual record cell 40 can be set above the laser beam waist. Part of the record indicates that its size is above the beam diameter. In addition, the laser beam described above is made circular at the position of the recording layer 12, but it can also be as shown in Fig. 8, for example, the objective lens 4 2 Α 加Beam shaping 稜鏡 4 2 C, opening to make the shape of the beam become a short transport direction of the recording medium 10, an oval or a long line in the orthogonal direction. At this time, because the recording mark 4 9 is shortened, the virtual recording cell can be more Shortened. That is, the recording density is improved. Furthermore, the optical recording medium 10, as shown by the symbol 5 2 in FIG. 1, can form a plurality of pits with different reflectances in the order of signal modulation in advance, or the optical recording medium. A part of the recording medium is firstly subjected to multi-level recording using the optical recording method of the present invention. These multiple pits 5 2 and / or the multi-level recording part of the recording mark 5 4 can also record the individual identification information of the recording medium, identifying the information that it is a multi-level recording optical recording medium, to determine the recording playback Information such as the laser beam irradiation time required by the recording medium, information about the groove width W, and other specific information. The specific information can be effectively identified as a multi-level recording by playing and / or reading and writing during the recording of the optical recording medium. The optical recording medium used can be used for individual identification, and multi-level recording and playback can be more reliably performed. Generally, the media used for CD-R / RW or DVD-R / RW is input by recording the serpentine (sloshing) of the groove. This signal is called an address signal. By reading this signal, the recording device can move the recording head to a specific position. The paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) (please read the back first) Please note this page before filling in this page) Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-20- 583654 A7 ____ B7____

五、發明説明(A 〇 (請先閱讀背面之注意事項再填寫本頁) 例如於C D - R / r w,該位置信號係記錄位置以時 間取代之分、秒時間碼。記錄裝置讀取該時間碼,將頭移 往導入部,即可讀寫各種資料。 本發明之多階光記錄媒體,使用CD - R/RW之記 錄裝置(以記錄、播放)時,可採用晃動之位址信號。但 不同於通常之C D - R / R W之時間碼,係採用位址碼等 之信號方式。通常之記錄裝置無法讀取不同於CD - R/ R W之位址信號,頭無法移往特定位置。(此時多階記錄 光媒體自記綠裝置退出)。 另一方面,用於多階記錄之記錄裝置,若設定成可辨 識該特殊位址,即可將頭移往導入部,讀取信號。 即,多階光記錄媒體因採用與通常不同之位址,可與 其它光記錄媒體區別。 利用上述晃動之記錄,例如第9圖所示,係以調變位 於光記錄媒體1 0之導入區1 0 2之溝1 0 4 A至 104C之晃動而進行。 經濟部智慧財產局員工消費合作社印製 具體而言,如第1 0圖所示,晃動振幅Wb不變,變 更各溝104A、104B、104C之晃動週期Τα、 Τ Β、T C。以例如第9圖所示之使用者區1 0 6之溝1 6 之晃動週期Τ〇爲基本週期,藉較長之晃動週期ΤΒ爲“ 1 ”,較短之晃動週期T A、T C爲“ 〇 ”之二値信號記錄上 述各種資訊。因此,例如當晃動週期係如上,從光記錄媒 體之內周側起爲“ 0 ” 、 “ 1 ” 、 “ 0 ”時,即表示該光 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) ' -21 - 583654 A7 B7V. Description of the invention (A 〇 (Please read the notes on the back before filling out this page) For example, in CD-R / rw, the position signal is the minute and second time code of the recorded position. Time is read by the recording device. When the head is moved to the lead-in section, various data can be read and written. The multi-level optical recording medium of the present invention can use a shaking address signal when using a CD-R / RW recording device (for recording and playback). However, unlike the ordinary CD-R / RW time code, it uses a signal method such as an address code. The ordinary recording device cannot read an address signal different from the CD-R / RW, and the head cannot move to a specific position. (At this time, the multi-level recording optical media exits from the self-recording green device.) On the other hand, if the recording device used for multi-level recording is set to recognize the special address, the head can be moved to the lead-in section to read the signal. That is, the multi-level optical recording medium can be distinguished from other optical recording media because it uses a different address. The recording using the above shaking, for example, as shown in FIG. 9, is located in the lead-in area of the optical recording medium 10 with modulation. 1 0 2 Ditch 1 0 4 A to 104C shaking. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Specifically, as shown in Fig. 10, the shaking amplitude Wb is unchanged, and the shaking periods τα, ΤΒ, of each groove 104A, 104B, 104C are changed. TC. Take, for example, the wobble period T0 of the groove 16 in the user area 10 6 shown in FIG. 9 as the basic period, and the longer wobble period T B is “1”, and the shorter wobble periods TA and TC are The “0” bis signal records the above-mentioned various kinds of information. Therefore, for example, when the shaking period is the same as above, and it is “0”, “1”, “0” from the inner peripheral side of the optical recording medium, it means that the optical paper Standards apply to Chinese National Standard (CNS) A4 specifications (210X 297 mm) '-21-583654 A7 B7

五、發明説明(A 記錄媒體1 0乃多階記錄用者。 (請先閱讀背面之注意事項再填寫本頁) 又,以如上之預先決定之資訊作爲記錄開始位置資訊 ,以之爲基礎,可從使用者區1 0 6之特定位置開始記錄 。此亦係虛擬記錄胞4 0之開始位置之資訊。 又,上述各種資訊之其它記錄方法有例如第1 1圖所 示,將上述各種資訊搭載於各溝1 6間之基面1 7上形成 之基面預坑1 7 A,作例如基面預坑間週期短時爲“ 1 ” ,長時爲“ 0 ”之二値記錄。 又另一例係如第1 2圖或第1圖之符號5 6所示’使 溝1 6中斷,使中斷之溝長,以例如短者爲“ 1 ’’ ’長者 爲“〇”表示。 上述第9、1 1、1 2圖所示資訊記錄手段之資訊’ 使之亦可藉習知二値記錄型播放裝置讀取’於該多階光記 錄媒體誤裝於二値記錄型播放及/或記錄裝置時,亦可容 易判別其係多階型。 經濟部智慧財產局員工消費合作社印製 又再,上述各種資訊,可預先多階記錄於例如第1 3 圖所示之導入區1 〇 2。此時,於第1 3圖中最初5個虛 擬記錄胞4 0 1至4 0 5之記錄標示,可記錄有其係多階 記錄媒體,及多階記錄之階數,於其次5個虛擬記錄胞 4 0 6至4 1 0之記錄標示,可記錄用以記錄或播放之建 議雷射功率等。這些方法可單獨或組合利用。 利用本發明之光記錄媒體,可隨供記錄之資料作多階 記錄,並且可使讀取自其記錄標示之信號具良好特性。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -22- 583654 A7 B7 五、發明説明()0 圖面之簡單說明 (請先閱讀背面之注意事項再填寫本頁} 第1圖係本發明之實施形態例有關之光記錄媒體重要 部位之部份剖視側視圖。 第2圖係用以於同光記錄媒體利用雷射光束記錄資訊 之光記錄裝置之方塊圖。 第3圖係同光記錄裝置所含雷射驅動器之構造方塊圖 〇 第4圖係以同光記錄裝置於記錄層形成記錄標示之際 ,該記錄標示與虛擬記錄胞及其光反射率間關係之示意圖 〇 第5圖係以同光記錄裝置於記錄層形成記錄標示之際 ,雷射光束照射之時間圖產生過程之線圖。 第6圖係對溝寬不同之光記錄媒體作多階記錄後. S D R値變化之線圖。 第7圖係溝寬過大之光記錄媒體經多階記錄後狀態之 側視圖。 經濟部智慧財產局員工消費合作社印製 第8圖係照射虛擬電路胞之雷射光束具其它形狀時之 槪略側視圖。 第9圖係本發明之光記錄媒體已預先記錄各種資訊後 ,晃動之放大示意圖。 第1 0圖係,同晃動之晃動週期與二値信號之關係之 線圖。 第1 1圖係本發明光記錄媒體已記錄各種資訊之基面 預坑與二値信號之關係之示意圖。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -23- 583654 A7 _____B7 五、發明説明(4 第1 2圖係本發明光記錄媒體已記錄各種資訊之中斷 溝長度與二値信號之關係之示意圖。 (請先閱讀背面之注意事項再填寫本頁) 第1 3圖係本發明光記錄媒體已記錄各種資訊之虛擬 記錄胞及記錄標示之示意圖。 〔圖式元件說明〕 10:光記錄媒體 12:記錄層 1 4 :基板 18:反射膜 16:雷射光導用溝 2 0 :保護層 4 0 ·虛擬錄電路胞 5 :圓周方向 Η:單位長度 W :溝寬 48Α〜48G:記錄標示 經濟部智慈財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) -24-V. Description of the invention (A recording medium 10 is for multi-level recording. (Please read the precautions on the back before filling out this page). Also, use the pre-determined information as above as the starting position information for recording. Recording can be started from a specific position in the user area 106. This is also a virtual recording of the starting position of the cell 40. In addition, other recording methods of the above-mentioned various information include, for example, as shown in FIG. The basal plane pre-pits 17 A formed on the basal planes 17 between the 16 grooves are recorded for example. The period between the basal plane pre-pits is "1" for short periods and "0" for long periods. Another example is shown in FIG. 12 or the symbol 5 6 in FIG. 1 'interrupt the trench 16 and lengthen the discontinued trench. For example, the short one is “1” and the old one is “0”. 9, 1 1, 12 The information of the information recording means shown in the figure 'makes it possible to read by the conventional Erji recording-type playback device' misinstalled in Erji recording-type playback and / or on the multi-level optical recording medium When recording the device, it is also easy to determine whether it is a multi-level type. Cooperatives print and again, the above-mentioned various information can be recorded in multiple levels in advance in, for example, the lead-in area 1 02 shown in Figure 13. At this time, the first 5 virtual record cells 4 0 1 to 4 in Figure 13 The record mark of 0 5 can be recorded as a multi-level recording medium and the order of the multi-level record. The next 5 record record marks of the virtual record cells 406 to 4 1 0 can be recorded for recording or playback. Recommended laser power, etc. These methods can be used alone or in combination. With the optical recording medium of the present invention, multi-level recording can be performed with the data for recording, and the signals read from its recording mark have good characteristics. This paper The dimensions are applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) -22- 583654 A7 B7 V. Description of the invention () 0 Brief description of the drawing (please read the precautions on the back before filling this page) Figure 1 A partial cross-sectional side view of an important part of an optical recording medium according to an embodiment of the present invention. FIG. 2 is a block diagram of an optical recording device for recording information using a laser beam on the same optical recording medium. Laser included in the same optical recording device The block diagram of the actuator structure. Figure 4 is a schematic diagram of the relationship between the recording mark and the virtual recording cell and its light reflectance when the recording mark is formed on the recording layer by the same light recording device. Figure 5 is the same light recording When the device forms a recording mark on the recording layer, a line chart of the time chart generation process of the laser beam irradiation is performed. Figure 6 is a multi-level recording of optical recording media with different groove widths. SDR 値 line chart of change The picture is a side view of the state of the optical recording medium with an excessively wide groove after multi-level recording. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 8 is a schematic side view of a laser beam irradiating a virtual circuit cell with other shapes. Figure 9 is an enlarged schematic diagram of shaking after the optical recording medium of the present invention has recorded various information in advance. Fig. 10 is a line diagram of the relationship between the shaking period of the shaking and the second signal. FIG. 11 is a schematic diagram showing the relationship between the pre-pit and the second signal of the base information in which the optical recording medium of the present invention has recorded various information. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -23- 583654 A7 _____B7 V. Description of the invention (4 The 12th figure is the length of the gap and the length of the interruption groove in which the optical recording medium of the invention has recorded various information Schematic diagram of the relationship of signals. (Please read the notes on the back before filling out this page.) Figure 1 3 is a schematic diagram of the virtual record cell and record label of the optical recording medium of the present invention that has recorded various information. [Schematic element description] 10 : Optical recording medium 12: Recording layer 1 4: Substrate 18: Reflective film 16: Laser light guide groove 2 0: Protective layer 4 0Virtual recording circuit cell 5: Circumferential direction: Unit length W: Groove width 48A ~ 48G : The record indicates that the paper printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is compliant with the Chinese National Standard (CNS) A4 specification (210 × 297 mm) -24-

Claims (1)

經濟部智慧財產局員工消費合作社印製 583654 A8 B8 C8 _ D8 々、申請專利範圍 1 1 · 一種光記錄媒體,係於具特定溝之透光性基板, 至少覆蓋該溝,形成主要由酞菁色素所成之記錄層,以雷 射光束照射至少於該記錄層形成記錄標示而記錄資訊者, 其特徵爲: 於上述記錄層上,沿上述溝,於用以記錄播放之雷射 照射進行方向,而虛擬記錄胞沿著該進行方向被連續規定 之任意單位長度及與其正交方向之任意單位寬度之虛擬記 錄胞,並且 以上述雷射光束之波長爲λ,在該雷射光束照射光學 系統之物鏡開口數爲Ν Α時,上述溝寬W係設定爲 Ο · 25χ (λ/ΝΑ) &lt;W&lt;〇 · 55χ (λ/ΝΑ), 將照射時間或照射功率之至少其一設定爲5階段以上 ’藉上述雷射光束之照射以能於上述虛擬記錄胞形成5種 以上大小不同之記錄標示,基於該記錄標示對該虛擬記錄· 胞之面積比來調變光反射率而可作資訊之多階記錄。 2 _如申g靑專利範圍第1項之光記錄媒體,其中上述 溝寬W係設定爲 〇 . 30χ (λ/ΝΑ) &lt;W&lt;〇 · 50x (λ/ΝΑ)。 3 ·如申請專利範圍第1或2項之光記錄媒體,其中 上述溝形成多條而互相呈大致平行之狀態,相鄰之上述溝 之間距Ρ係設定爲〇 · 6 5χ (λ/ΝΑ) &lt;Ρ,較佳爲 設定成 Ο · 7χ (λ/ΝΑ) &lt;Ρ&lt;1 · 2χ (λ/ΝΑ) (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583654 A8 B8 C8 _ D8 々, patent application scope 1 1 · An optical recording medium, attached to a light-transmitting substrate with a specific groove, covering at least the groove, forming mainly by phthalocyanine The recording layer formed by the pigment is irradiated with a laser beam at least on the recording layer to form a recording mark to record information, and is characterized in that: on the recording layer, along the groove, in the direction of laser irradiation for recording and playback; And the virtual recording cell is continuously specified along the proceeding direction with an arbitrary unit length and an arbitrary unit width orthogonal to the virtual recording cell, and the wavelength of the laser beam is λ, and the laser beam is irradiated to the optical system When the number of objective lens openings is Ν Α, the groove width W is set to 0 · 25χ (λ / ΝΑ) &lt; W &lt; 〇 55χ (λ / ΝΑ), and at least one of the irradiation time or irradiation power is set to 5 Above the stage ', the above-mentioned laser beam can be used to form 5 or more different record marks on the virtual record cell. Based on the record mark, the virtual record Volume ratio of light reflectance modulation can be used for many information recording order. 2 _ The optical recording medium according to item 1 of the patent scope, wherein the above-mentioned groove width W is set to 0.30x (λ / ΝΑ) &lt; W &lt; 50x (λ / ΝΑ). 3. If the optical recording medium according to item 1 or 2 of the patent application scope, wherein the above-mentioned grooves are formed in a plurality and are substantially parallel to each other, the distance P between adjacent above-mentioned grooves is set to 0.65χ (λ / ΝΑ) &lt; P, preferably set to 0 · 7χ (λ / ΝΑ) &lt; P &lt; 1 · 2χ (λ / ΝΑ) (Please read the precautions on the back before filling this page) 本紙浪尺度適用中國國家標準(CNS) μ说格(210Χ297公釐) 25The scale of this paper applies the Chinese National Standard (CNS) μ scale (210 × 297 mm) 25
TW91105340A 2001-03-30 2002-03-20 Optical recording medium TW583654B (en)

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TWI402829B (en) * 2010-10-29 2013-07-21 Nat Univ Tsing Hua Multilevel recording method and system thereof

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EP1475793B1 (en) 2003-04-15 2007-12-05 Ricoh Company, Ltd. Write-once-read-many optical recording medium and process for recording and reproducing of the optical medium
US7706242B2 (en) 2004-02-25 2010-04-27 Ricoh Company, Ltd. Optical disk, signal generation method, clock signal generation method, and optical disk device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI402829B (en) * 2010-10-29 2013-07-21 Nat Univ Tsing Hua Multilevel recording method and system thereof

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