TW581789B - Reactive dye for fiber - Google Patents
Reactive dye for fiber Download PDFInfo
- Publication number
- TW581789B TW581789B TW88119501A TW88119501A TW581789B TW 581789 B TW581789 B TW 581789B TW 88119501 A TW88119501 A TW 88119501A TW 88119501 A TW88119501 A TW 88119501A TW 581789 B TW581789 B TW 581789B
- Authority
- TW
- Taiwan
- Prior art keywords
- fiber
- patent application
- reactive dye
- scope
- item
- Prior art date
Links
Landscapes
- Coloring (AREA)
Abstract
Description
581789 A7 B7 五、發明說明(/ ) 本發明係關於一種染料,尤其是一種纖維反應性染料, 其適用於水性浴中纖維素纖維染色,以及纖維素纖維印染。 、纖維反應性染料在染整業界已應用多年,其最主要特徵 為:在染料分子上帶有可以與纖維上基團反應而形成共價鍵 的反應性基團,例如,在美國專利us 4,7〇3,112、us 5,484,899 及英國專利GB L3 53J99,曾揭露應用於浸染、連續染色或 印柒上的纖維反應性染料,其具有良好染深性等的優良染整 特性,而廣為染整業界所使用。 本發明之染料,係一種如下式(j )之反應性染料, 4^ V C -----------— 嗾------. 丨訂---------鎿丨 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製581789 A7 B7 V. Description of the invention (/) The present invention relates to a dye, especially a fiber-reactive dye, which is suitable for cellulose fiber dyeing in aqueous baths and cellulose fiber printing and dyeing. Fiber-reactive dyes have been used in the dyeing and finishing industry for many years. The most important feature is that the dye molecules carry reactive groups that can react with groups on the fiber to form covalent bonds. For example, in US patent US 4 No. 7,03,112, us 5,484,899 and British patent GB L3 53J99, have disclosed fiber-reactive dyes used in dip dyeing, continuous dyeing or printing ink, which have excellent dyeing and finishing characteristics, such as good dyeing, and are widely used. Used by the dyeing and finishing industry. The dye of the present invention is a reactive dye of the following formula (j), 4 ^ VC ------------- 嗾 ------. 丨 order -------- -鎿 丨 (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs
NR—D2NR—D2
N=NN = N
Z為鼠原子或一N=N—Zi,其中Z!為 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(> )Z is a rat atom or N = N—Zi, where Z! Is the paper size applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (>)
或or
•S02—Y 其中X為氯原子、氟原子、羥基c^4烷氧基、——NHCN、 / \ \_/°、N,N-二-石-羥基乙基胺基(N,N-di_y5 _ hydroxyethylamino)、3-羧基 〇比啶-1-基(3-carboxypyridin-l yi)、經磺酸基或一so2(ch2)2oso3h取代的苯基胺基 (phenylamino ),或其他取代或未取代氨基; Y為一0H、乙烯基或一CH2—CH2—W,其中W為用驗處理可 N··• S02—Y where X is chlorine atom, fluorine atom, hydroxy c ^ 4 alkoxy group, ——NHCN, / \ \ _ / °, N, N-di-stone-hydroxyethylamino group (N, N- di_y5 _ hydroxyethylamino), 3-carboxypyridin-1-yl (3-carboxypyridin-l yi), phenylamino substituted with sulfonic acid group or monoso2 (ch2) 2oso3h, or other substituted or unsubstituted Substituted amino group; Y is a 0H, vinyl or a CH2—CH2—W, where W is a test treatment can be N ··
離去之基團,較佳的,W為C卜一0S03H或v CC>C)H , I為磺酸基、烷氧基或c^4烷氧羰基; P為0 2或3 ;The leaving group, preferably, W is Cb_0S03H or v CC> C) H, I is a sulfonic group, an alkoxy group or a c ^ 4 alkoxycarbonyl group; P is 0 2 or 3;
Q 為一S02-YQ is a S02-Y
-CONH - (CH2)n - S02 - Y 經濟部智慧財產局員工消費合作社印製 —(ο)。一(CH2)m—CONH—(CH2)n—S02—Υ 、或一ΝΗ—CO—Τ,其中 Υ定義如前所述,Τ為α,冷-鹵丙醯基(halopropionyi)或α -鹵丙烯醯基(haloacryloyl ),η和m各自獨立為1到6的整 數;p定義如上述;〇為〇、1、2或3;-CONH-(CH2) n-S02-Y Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy — (ο). -(CH2) m-CONH- (CH2) n-S02-Υ, or ΝΗ-CO-T, where Υ is defined as described above, and T is α, cold-halopropionyi (halopropionyi) or α-halogen Acrylofluorenyl (haloacryloyl), η and m are each independently an integer of 1 to 6; p is defined as above; 0 is 0, 1, 2 or 3;
D2 為 \ — 7^0 或 及Y定義如上述; ‘紙張尺度適用中國國家標準(CNS)A4規格(210 χ 297公釐)D2 is \ — 7 ^ 0 or Y is as defined above; ‘Paper size applies Chinese National Standard (CNS) A4 specification (210 χ 297 mm)
S〇2—Y ,其中 I、ρ、Q、 ---— — — — — — — — — — ·1111111 ---I I I I I · I ------------ (請先閱讀背面之注意事項再填寫本頁) 581789 A7 ------ B7___ 五、發明說明(今) R為氫原子、0^〜4烷基、或被齒素原子、羥基、氰基(cyano)、 C!〜4烧氧基、C〗〜4烧氧毅基(alkoxycarbonyl)、緩基 (carboxyl)、磺酸基、或硫酸根絡(sUlfat〇)所取代的CV4 烷基; D為氫原子或如下式所代表的基,S〇2—Y, of which I, ρ, Q, ----- — — — — — — — — — · 1111111 --- IIIII · I ------------ (Please read first Note on the back, please fill out this page again) 581789 A7 ------ B7___ V. Description of the invention (today) R is hydrogen atom, 0 ^ ~ 4 alkyl group, or halogen atom, hydroxyl group, cyano C! ~ 4 alkoxy, C〗 ~ 4 alkoxycarbonyl, carboxyl, sulfonate, or sUlfat〇 substituted CV4 alkyl; D is a hydrogen atom Or the base represented by
其中X及R定義如上述; 為帶有反應基或不帶有反應基的發色團,其中該反應基可 以為一或多個各自獨立分別選自如上所定義的q基,該發色 團係選自包括下列族群之一者: ⑷甲嗯發色團(formazan chromophore) Ψ bL ·〆> w I--------------------訂----------線 <請先閱讀背面之注咅?事項再填寫本頁)X and R are as defined above; are chromophores with or without a reactive group, wherein the reactive group may be one or more independently selected from the q group as defined above, the chromophore It is selected from one of the following ethnic groups: ⑷ 甲 嗯 色 色 团 (formazan chromophore) Ψ bL · 〆 > w I -------------------- Order- --------- line < read the note on the back first (Fill in this page again)
經濟部智慧財產局員工消費合作社印製 581789 A7 B7 五、發明說明(彳)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 581789 A7 B7 V. Description of Invention (彳)
其中G為經CV4烧基或續酸基取代的苯撐(phenylene ) (c)西太花青(phthalocyanine); (S〇2W)〇Where G is phenylene substituted with a CV4 alkyl group or a continuous acid group (c) phthalocyanine; (S〇2W).
Pc S02-NH-E— 其中Pc為銅西太花青基(copper phthalocyanine )或鎳西太花 青基(nickel phthalocyanine ),W 為-0H 和 /或-NH2,E 為苯 撐或乙撐(ethylene ); 〇定義如上述; (d)三苯二 0惡口井(triphendioxazine )Pc S02-NH-E— where Pc is copper phthalocyanine or nickel phthalocyanine, W is -0H and / or -NH2, and E is phenylene or ethylene ( ethylene); 〇 as defined above; (d) triphendioxazine
ClCl
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) •馥--------π---------f β-------------1--------- (請先閱讀背面之注意事項再填寫本頁) 581789 A7 B7 五、發明說明(t ) 或 C1This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) • 馥 -------- π --------- f β --------- ---- 1 --------- (Please read the notes on the back before filling out this page) 581789 A7 B7 V. Description of Invention (t) or C1
(e)單偶氮基(monoazo)(e) Monoazo
(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(bThis paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (b
OHOH
(HOsS)^ (Y_〇2S)0(HOsS) ^ (Y_〇2S) 0
——N=N——N = N
p (R2)p (R2)
(HOsS)^ \r-N=N (Y-02S)((HOsS) ^ \ r-N = N (Y-02S) (
OHOH
(S〇3H)0(S〇3H) 0
(請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明((Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (
(請先閱讀背面之注意事項再填寫本頁) 或(Please read the notes on the back before filling this page) or
經濟部智慧財產局員工消費合作社印製 其中 h為CV4烷基、Cw烷氧基、羧基、磺酸基或-S02-Y,Y定 義如上述; 112為烷基,C1M烷氧基,胺基,乙醯基胺基 (acetylamino ),月尿基(ureido )或石黃基; 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(S ) R3為院酿氧基或苯曱醯基(benzoyl ); R4為Ci~4烧基或叛基; 化5和化6為Cm烧基; R7為氫,胺基曱醯或磺甲基; 其中m、η、〇及p定義如上述; (f)多偶氮基(polyazo)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs where h is CV4 alkyl, Cw alkoxy, carboxyl, sulfonic or -S02-Y, Y is as defined above; 112 is alkyl, C1M alkoxy, amine , Acetylamino, ureido or ruthenium; this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 581789 A7 B7 V. Description of the invention (S) R3 is oxo or benzoyl; R4 is Ci ~ 4 or phenyl; C5 and C6 are Cm; R7 is hydrogen, amine or sulfomethyl; m, η, 0 and p are as defined above; (f) polyazo
OHOH
(請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)
或 581789 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(Ί) (HO和 (Y-〇2S) p (Rg),Or 581789 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy V. Invention Description (Ί) (HO and (Y-〇2S) p (Rg),
!-\ N=N!-\ N = N
q N=N-q N = N-
JL •(OH) t (S〇3H)r (S〇3H) u 其中 118為CV4烷基、CV4烷氧基、羧基、磺酸基、乙醯基(acetyl) 乙酿基胺基、月尿基或一S〇2 —Y; q、r、s、t及u各自獨立分別選自0 Ri、Y、m、η、〇及p定義如上述; 或(g)金屬錯合物偶氮基。JL • (OH) t (S〇3H) r (S〇3H) u where 118 is CV4 alkyl, CV4 alkoxy, carboxyl, sulfonic acid, acetyl ethyl ethylamino, lunar urine Or S02-Y; q, r, s, t and u are each independently selected from 0 Ri, Y, m, η, 0 and p are as defined above; or (g) metal complex azo group .
Di可以更具體的列舉如下所示 so3h ο"vCu\nX7 11 1 N N ho3sDi can be more specifically listed as follows so3h ο " vCu \ nX7 11 1 N N ho3s
2或3 ; nh2 o 'o o-c (請先閱讀背面之注意事項再填寫本頁) ho3s*2 or 3; nh2 o 'o o-c (Please read the notes on the back before filling this page) ho3s *
N 'N^^^SOsHN 'N ^^^ SOsH
S03HS03H
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(β) 經濟部智慧財產局員工消費合作社印製 0 nh2This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (β) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 0 nh2
nhch2ch2cooh 。NHtX nh2nhch2ch2cooh. NHtX nh2
12 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(12 (Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (
S〇3H)xS〇3H) x
S〇2NH2)yS〇2NH2) y
4-Cu-N V4-Cu-N V
Ο S-NH-Ο S-NH-
NH2)zNH2) z
aa
NH2NH2
ClCl
ClCl
NH(CH2)2NH2 a so3h Cl H2N(CH2)2HN 丄众丄.N.NH (CH2) 2NH2 a so3h Cl H2N (CH2) 2HN
ClCl
NH(CH2)2NH2 dS03H OH 卜 N=N—^ 、NH (CH2) 2NH2 dS03H OH BU N = N— ^,
ys〇3H OH -N=Nys〇3H OH -N = N
H3C〇-^~^-n=n (請先閱讀背面之注意事項再填寫本頁) 訂· ·H3C〇- ^ ~ ^ -n = n (Please read the notes on the back before filling this page) Order · ·
H3CH3C
HO3SHO3S
NH2NH2
-線·-line·
H3OH3O
N=N-N = N-
OH CH3 1 NH NH CH3 Η3〇ο--^~^~ν=νOH CH3 1 NH NH CH3 Η3〇ο-^ ~ ^ ~ ν = ν
HO3SOH2PH2PHO3SOH2PH2P
HOOC OH NH2HOOC OH NH2
S03H OH NH2S03H OH NH2
H03S·H03S ·
S03H 13 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) 581789 經濟部智慧財產局員工消費合作社印製 A7 _B7 五、發明說明(、>)S03H 13 This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) 581789 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7 V. Description of the invention (&>)
14 -------------暾 (請先閱讀背面之注意事項再填寫本頁) 一-0、· ϋ ϋ n n 1 ϋ ϋ I ϋ ϋ 1 n ϋ ϋ ^1 I ϋ ϋ I ϋ I I I ϋ ϋ ϋ I ^1 ϋ ϋ . 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B714 ------------- 暾 (Please read the precautions on the back before filling out this page)-0, · ϋ ϋ nn 1 ϋ ϋ I ϋ ϋ 1 n ϋ ϋ ^ 1 I ϋ ϋ I ϋ III ϋ ϋ ϋ I ^ 1 ϋ ϋ. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7
五、發明說明(G5. Description of the invention (G
OCH3 (請先閱讀背面之注意事項再填寫本頁) ΦOCH3 (Please read the notes on the back before filling this page) Φ
so3Hso3H
N=N~^ΝΗ2 NHCOCH3 I^^VnH2 S03H .N=N—NH2 NHCOCH3N = N ~ ^ ΝΗ2 NHCOCH3 I ^^ VnH2 S03H .N = N—NH2 NHCOCH3
h〇3S ^KXohh〇3S ^ KXoh
訂---------線J 經濟部智慧財產局員工消費合作社印製Order --------- Line J Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy
h3Cn_ N=Nh3Cn_ N = N
nh2 nh2 、so3h so3h 15 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 Α7 Β7 五、發明說明(介nh2 nh2 、 so3h so3h 15 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 Α7 Β7 V. Description of the invention (introduction
OHΗ3"ά HOsS HOOC N=N- Vnf Μ Ν、·人〜· ΝΗ2OHΗ3 " ά HOsS HOOC N = N- Vnf Μ Ν, · 人 ~ · ΝΗ2
s〇3H HOOCs〇3H HOOC
ΝΗ2ΝΗ2
νη2νη2
(請先閱讀背面之注意事項再填寫本頁) -餐(Please read the notes on the back before filling this page)-Meal
訂----------線II 經濟部智慧財產局員工消費合作社印製Order ---------- Line II Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
16 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(6 )16 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention (6)
HC^SHC ^ S
y°(CH2)2〇H〇H NH2y ° (CH2) 2〇H〇H NH2
SO3H acH^sOSO^ NH2SO3H acH ^ sOSO ^ NH2
SO3H 〇(CH2)2〇S〇3^h Nh2SO3H 〇 (CH2) 2〇S〇3 ^ h Nh2
NHCO视3S〆 經濟部智慧財產局員工消費合作社印製NHCO sees 3S 印 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs
HO3S so^ H03s 、S〇3H ^^-Ν=Ν— V-N: HC^S CH3 H< \M=KIHO3S so ^ H03s, S〇3H ^^-N = Ν— V-N: HC ^ S CH3 H < \ M = KI
SO3H HO3SSO3H HO3S
17 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) (請先閱讀背面之注意事項再填寫本頁) --------訂---------線« N=N—</ V-N=N—/ V-NH2 581789 A7 B717 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) -------- Order -------- -Line «N = N— < / VN = N— / V-NH2 581789 A7 B7
五、發明說明(A5. Description of the invention (A
S03HS03H
N=N—^ ^- N=NN = N— ^ ^-N = N
NH2NH2
NH2H^CNH2H ^ C
nh2 H03Snh2 H03S
nh2nh2
0——Cu-O (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製0——Cu-O (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs
NH2 0——Cu-0 0-Cu-0 -N=NNH2 0——Cu-0 0-Cu-0 -N = N
HO3J SO3HHO3J SO3H
N=NN = N
NH CH3NH CH3
HO3S SO2CH2CH2OSO3H NH2 本紙張尺度適用中國國家標季(CNS)A4規格(210 X 297公釐) 581789 A7 B7五、發明說明(A ) 經濟部智慧財產局員工消費合作社印製HO3S SO2CH2CH2OSO3H NH2 This paper size applies to China National Standard Season (CNS) A4 specification (210 X 297 mm) 581789 A7 B7 V. Description of invention (A) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy
19 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)19 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)
-· ϋ ϋ ·ϋ H ϋ ϋ ^1 一δ, · ϋ *·ϋ 1 ammme ϋ· I ϋ I ϋ ϋ ϋ ϋ ϋ ·ϋ 11 H _ϋ ϋ I ί I n — ϋ ϋ ϋ an I I 581789-· Ϋ ϋ · ϋ H ϋ ϋ ^ 1 aδ, · ϋ * · ϋ 1 ammme ϋ · I ϋ I ϋ ϋ ϋ ϋ ϋ · ϋ 11 H _ϋ ϋ I ί I n — ϋ ϋ ϋ an I I 581789
本發明為了說明方便,在說明書中化合物皆以自由酸 的形式表示,但本發明中的染料在被製造或使用時,常會 以水浴性鹽的形式存在,合適的鹽可以是鹼金屬、鹼土金 屬'銨鹽或有機胺鹽,其中較佳者為鈉鹽、鉀鹽、鋰鹽、 叙鹽或二乙醇胺(triethanolamine)鹽。 、本發明,染料,可以習知的方法製備,其製備的反應順 序並沒有很嚴格的限制,可以是先將發色團製備好,然後再 合成所需要的染料;也可以在染料的製備過程中,才合成發 色團,如以先製備好發色團,然後再合成染料為例,可 下述方法被例舉出來·· 百 a、取Ζι—ΝΗ2 (ζι定義如上述)之偶氮鹽,使與4〜氨烏 (2—緩酸)乙基胺苯續酸 ethyl)amin〇 benzene suif0nic acid)偶合,即可得 式(II)之式(I)染料。 f ·如下 -------------f (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 I I ·11111111 —AVI — — — — — — — — — — — — — — — — — — — —In the present invention, for convenience of explanation, the compounds are expressed in the form of free acid in the specification. However, when the dyes in the present invention are manufactured or used, they usually exist in the form of water bath salts. Suitable salts may be alkali metals, alkaline earth metals. 'Ammonium or organic amine salts, of which sodium salts, potassium salts, lithium salts, salt salts, or triethanolamine salts are preferred. In the present invention, the dye can be prepared by a conventional method, and the reaction sequence of the preparation is not strictly limited. The chromophore can be prepared first, and then the required dye can be synthesized. It can also be used in the dye preparation process. In order to synthesize a chromophore, for example, if the chromophore is prepared first and then a dye is synthesized, the following method can be used as an example: a. Take the azo of Zι-ΝΗ2 (ζι is defined as above) By coupling the salt with 4-ammonium (2-acid) ethylamine benzoic acid ethyl) amin benzene suif0nic acid), a dye of formula (I) of formula (II) can be obtained. f · The following ------------- f (Please read the precautions on the back before filling this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs II · 11111111 —AVI — — — — — — — — — — — — — — — — — — —
A7 B7 五、發明說明(θ (II) 其中A定義如上述; b 取4乱基-2-(2德酸)乙基胺笨橫酸,使先與如下式⑷之 鹵三口井(halotriazinp、v 杜 使再與!VNHR (D及r仃/ 一次縮合反應,所得產物 次縮合反應化合物進行第二 ^ 有必要,則可再選擇適當的化合物,使 再進行第三次縮合反應,即可得到如下式(ΙΠ) 所得產物使再“氨基·2二) = ::=反應’ 二次縮合反應,如有必要,同樣可再選;:碩馱進灯第 使與所得產物行第三次縮合反應 ^的化合物’ 之式⑴染料。 也可得到如下式(III) Ν- Λ 、人丨 (Α) X 人A7 B7 V. Description of the invention (θ (II) where A is defined as above; b takes 4 ranyl-2- (2 Germanic acid) ethylamine stearic acid, so that it is first connected with three halogen wells (halotriazinp, v Du Shi and VNHR (D and r 仃 / primary condensation reaction, the second condensation reaction of the product obtained is necessary for the second ^ If necessary, you can choose an appropriate compound, and then conduct the third condensation reaction, you can get The following formula (ΙΠ) gives the product "amino · 2 2) = :: = reaction 'secondary condensation reaction, if necessary, it can also be re-selected; The compound of formula ^ is a dye of formula ⑴. The following formula (III) can also be obtained: Ν-Λ, person 丨 (Α) X person
DiNR/^N/^HN· nhch2ch2c〇〇h -S〇3hDiNR / ^ N / ^ HNnhch2ch2c〇〇h -S〇3h
(HI 21 本紙張尺度適用中國國豕標_ (CNS)A4規格(210 χ 297公髮) 581789 A7 B7 五、發明說明(^ ) 其中Xl為氣或氟’ X、D丨及R定義如上述; 取式(in)化合物’使肖Ζι_ΝΗ2(Ζι定義如上幻之偶 氮鹽偶合’即可得到如下式UV)之式⑴染料; 同樣的,切以先取Ζι挪2(Ζι定義如上述)之偶氮鹽, 使與4m(2_㈣)乙基胺苯料偶合,㈣使所得 產物與如< (A)之幽三。井進行第—次縮合反應,所 產物使再與IV職(DJR定義如上述)化合物進行 第-杨合反應,如有必要,則可再選擇適當的化合物, 使與所得產物再進行第三次縮合反應,即可得到如下式 (IV)之式(I)染料; & Γ卜2可以先"i-nhr(dar定義如上述)化合 =使與如式(A)之齒三口井進行第—次縮合反應,所 物使再與zrNH2(Zi定義如上述)之偶氮鹽與心氨 土 2(2肢)乙基胺苯錢行偶合反應所得產物進行第 二次縮合反應,如有必要,同樣可再選擇適當的化合物, 使與所彳Μ物進行第三讀合反應,也 (IV)之式⑴染料 』如下式 NHCH2CH2C〇〇h « 丄(HI 21 This paper size applies to China's national standard _ (CNS) A4 specification (210 x 297) 581789 A7 B7 V. Description of the invention (^) where Xl is gas or fluorine 'X, D 丨 and R are defined as above ; Take the compound of formula (in) 'make Xiao Zι_ΝΗ2 (where Z is defined as the coupling of azo salt as above) to obtain the dye of formula VII; similarly, cut to take the first Z 2 No 2 (the definition of Z is as above) Azo salt, coupled with 4m (2-㈣) ethylamine benzene material, ㈣ made the resulting product and the like (A) Zhisan. The first condensation reaction is carried out, and the product is then made with the IV position (DJR definition As described above, the compound is subjected to the first-yang compound reaction, and if necessary, an appropriate compound can be selected and a third condensation reaction with the obtained product can be performed to obtain a dye of formula (I) of the following formula (IV); & Γ 2 can be combined with "i-nhr (dar is defined as above) = to perform the first condensation reaction with the three wells of formula (A), so as to react with zrNH2 (Zi is defined as above) The second condensation reaction of the product of the coupling reaction of azo salt and ammonium earth 2 (2 limbs) ethylamine benzidine, such as Necessary, the same can then select the appropriate compound, so that the third read together with the left foot Μ reaction was also (IV) of the dye of formula ⑴ "following formula NHCH2CH2C〇〇h« Shang
DiNR" 、HN-DiNR ", HN-
-S03H N=N—Zi 本紙張尺—用令 22 (IV) 五、發明說明(d 其中X、D,、2丨及R定義如上述,· 製備本發明之染料’ .反應條件,例如偶合反肩!:用的反應方法為-般所習知的 H η- 〜,疋在微酸性到中性酸鹼值,及〇〜25 C,皿度下進行;與鹵三口 性酸驗值,例如酸驗:=仃:第:次縮合反應,是在酸 應;與鹵三口井所進行 下,例如0〜1〇t下反 驗值之間,例如酸驗值反應,是在微酸到中性酸 溫度下反應;與·: = 以及中溫’例如°销 一井所進订的第三次縮合反應,是在中性 及中到高溫’例如5〇〜8(TC溫度下反應。 :發明之染料適用於纖維材料,尤指纖維素纖維材料, :::纖維素纖維之纖維材料的染色或印花。此纖維材料並 ’、、、、限制,可以是天然或再生的纖維素纖維,例如棉、麻、 亞麻、大麻、宇麻、黏液嫘榮,或是含纖維素线維的纖維 材料。本發明之染料同樣也適用於含經基纖維的纖維捧混織 物的染色和印花。 本發明之染料可以用各種方式固色於纖維上,特別是以 水性染料溶液和印染糊形式《/並以浸染、連染、冷壓染、印 染等方式進行染色與印花。 本發明之染色或印染可照一般習知、慣用的方法進行 浸染法(exhaustion dyeing )是採用熟知的無機中性鹽(如 無水硫酸鈉及氣化鈉)及熟知的酸結合劑(如碳酸鈉、氫氧| 化鈉)單獨或混合使用。無機中性鹽和驗的用量並不是仿重 23 本紙張尺度適用中國國家標率(CNS)A4規格(21〇 x 297公釐) 581789 A7-S03H N = N—Zi This paper rule—Use order 22 (IV) V. Description of the invention (d where X, D, 2 and R are as defined above, · Preparation of the dye of the present invention '. Reaction conditions, such as coupling Back shoulder !: The reaction method used is generally known as H η- ~, 疋 is performed at a slightly acidic to neutral pH value, and 0 ~ 25 C, the degree of pH; For example, acid test: = 仃: the first condensation reaction is in acid reaction; and the three test wells in halogen, for example, between 0 ~ 10t reverse test value, for example, the acid test value reaction is between slightly acid to Reaction at neutral acid temperature; and ·: = and medium temperature 'for example, the third condensation reaction ordered by a pin-well is a reaction at neutral and medium to high temperature' such as 50-8 ° C. : The dyes of the invention are suitable for fiber materials, especially cellulose fiber materials, ::: cellulose fiber fiber materials for dyeing or printing. This fiber material is not restricted to natural, or regenerated cellulose fibers. , Such as cotton, linen, flax, hemp, jute, slime, or fiber materials containing cellulose thread. Dyeing of the present invention The material is also suitable for dyeing and printing of fiber blended fabrics containing warp-based fibers. The dyes of the present invention can be fixed on the fibers in various ways, especially in the form of aqueous dye solutions and printing pastes. Dyeing and printing by means of dyeing, cold press dyeing, printing and dyeing, etc. The dyeing or printing and dyeing of the present invention can be carried out by conventional dyeing methods (exhaustion dyeing) using well-known inorganic neutral salts (such as anhydrous sodium sulfate and Sodium gasification) and well-known acid binders (such as sodium carbonate, hydroxide | sodium hydroxide) are used alone or in combination. The amount of inorganic neutral salt and test is not imitation weight 23 This paper is applicable to China National Standards (CNS) A4 size (21 × 297 mm) 581789 A7
I I 訂 請 先 閱 讀 背 面 之 注 意 事 項 再 填 寫 本 頁 線I I order Please read the notes on the back side before filling out this page.
五、發明說明(θ ) 經濟部智慧財產局員工消費合作社印製 因此也適用於棉/聚酯摻混織物的举 ^ v耵木色。本發明的染料也適 用於印染’特別適用於棉或含有毛 ,七或絲的摻混織物。在纖維 素纖維材料上所進行的染色和印染可以得到各種染色特性良 好的染物;尤其在染深性及水洗牢度,可得高品質的染色、 印染或壓染產品。 為方便更進-步說明起見,將列舉以下實關作更具體 的說明。 【發明的較佳實施例】 以下貫^例為本發明之具體說明,但不會因此而限定本 發明的範圍,其中化合物是以游離酸的形式表示,但其實際 的形式有可能是金屬鹽,更可能是鹼金屬鹽,尤其是鈉鹽, 除非有特別說明,否則實施例中所使用的份數或百分比皆以 重量為單位,溫度以攝氏溫度。c為單位。 實施例1 取8·3份的三聚氰氯(Cyanuric chi〇ride)分散於80份 冰/水混合物中,然後將2-甲胺基-5-签酚-7-磺酸(2-methylamine_5-naphthol_7-sulfonic acid) 10.8 份溶於 80 份 水中’並在攪拌下加入上述溶液中,然後在6〜10。〇下攪拌 至反應完全。 另外’將胺-1,5 -二績酸(2-naphthylamine -1,5- 25 本紙張尺度適用中國國家財(CNS)A4規格(21G X 297公爱) -------------.·.-------訂.! (請先閲讀背面之注意事項再填寫本頁) ·· I ϋ ϋ ϋ n 1 ι ϋ· n ϋ n ϋ n aeae ϋ amMmm ·ϋ n ϋ I n i 581789V. Description of the invention (θ) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs So it is also applicable to cotton / polyester blended fabrics. The dyes of the present invention are also suitable for printing ', particularly for cotton or blended fabrics containing wool, hemp, or silk. Dyeing and printing on cellulosic fiber materials can obtain various dyeing materials with good dyeing characteristics; especially in the depth of dyeing and washing fastness, high-quality dyeing, printing, or pressure dyeing products can be obtained. For the convenience of further explanation, the following facts will be enumerated for a more specific explanation. [Preferred Embodiments of the Invention] The following examples are specific descriptions of the present invention, but will not limit the scope of the present invention. The compound is expressed in the form of a free acid, but its actual form may be a metal salt. It is more likely to be an alkali metal salt, especially a sodium salt. Unless otherwise specified, the parts or percentages used in the examples are by weight, and the temperature is in degrees Celsius. c is the unit. Example 1 8 · 3 parts of cyanuric chiride was dispersed in 80 parts of an ice / water mixture, and then 2-methylamine-5-hydoxy-7-sulfonic acid (2-methylamine_5 -naphthol_7-sulfonic acid) 10.8 parts dissolved in 80 parts of water 'and added to the above solution with stirring, then at 6-10. Stir until the reaction is complete. In addition, 'Naphthylamine 1,2,5-dicarboxylic acid (2-naphthylamine -1, 5- 25) This paper size applies to China National Finance (CNS) A4 specifications (21G X 297 public love) --------- ----. · .------- Order ...... (Please read the notes on the back before filling in this page) ·· I ϋ ϋ ϋ n 1 ι n · n ϋ n ϋ n aeae ϋ amMmm · ϋ n ϋ I ni 581789
、發明說明(1) disulfonic acid) 11份用習用方式重氮化後加入上述溶液中, 並將酸鹼值保持在6〜6.5,溫度8〜12°C下攪拌至反應完全。 然後,將4-氨基-2-(2-羧酸)乙基胺苯磺酸11 ·2份溶於3〇 份水中’再加入上述反應液裡,並升溫至4〇〜45。〇,以及 保持酸鹼值在4〜4·5,反應結束後。將反應所得溶液喷乾, 可得如下式(1 )之橘色染料,人max=489nm,經染色後可得 特性優良之橘色染物。(1) Disulfonic acid) 11 parts are diazotized in a conventional manner and added to the above solution, and the pH value is maintained at 6 to 6.5, and the temperature is stirred at 8 to 12 ° C until the reaction is complete. Then, 11.2 parts of 4-amino-2- (2-carboxylic acid) ethylaminebenzenesulfonic acid was dissolved in 30 parts of water 'and added to the above reaction solution, and the temperature was raised to 40-45. 〇, and to maintain the pH value of 4 to 4.5, after the end of the reaction. The solution obtained by the reaction is spray-dried to obtain an orange dye of the following formula (1), human max = 489nm, and an orange dye with excellent characteristics can be obtained after dyeing.
S03H NH〇t〇^C〇2H (1) 實施例2、 取16.5份的三聚氰氯分散於no份冰/水混合物中,然 後將 1-氨基-8-秦紛_3,6_二績酸(l-amino-8_naphthol-3,6-disulfonic acid) 27.5份溶於60份水中,並在攪拌下加入上 述溶液中,然後在6〜10°C下攪拌至反應完全。 另外’將鄰氛基苯續酸(2-aminobenzezesulfonic acid ) 14 _ 8份用習用方式重氮化後加入上述溶液,並將酸驗值保持 在6〜6_2,溫度8〜15°C下攪拌至反應完全。 然後’將23份的4-氨基-2-(2-竣酸)乙基胺苯續酸溶於 26 —— — — — — — — — — — I — — — — — — — II — — — — — — — — — I — — — — — — — — - ϋ n I — — — — — — — — — 1. (請先閱讀背面之注意事項再填寫本頁)S03H NH〇t〇 ^ C〇2H (1) Example 2, 16.5 parts of melamine chloride was dispersed in no parts of ice / water mixture, and then 1-amino-8-Qinfan_3,6_ 二27.5 parts of l-amino-8_naphthol-3,6-disulfonic acid was dissolved in 60 parts of water, and the solution was added with stirring, and then stirred at 6 to 10 ° C until the reaction was completed. In addition, 14- 8 parts of 2-aminobenzezesulfonic acid (2-aminobenzezesulfonic acid) are diazotized in a conventional manner, and the above solution is added, and the acid value is maintained at 6 ~ 6_2, and the temperature is stirred at 8 ~ 15 ° C until The reaction is complete. Then 'dissolve 23 parts of 4-amino-2- (2-endic acid) ethylamine benzoic acid in 26 —— — — — — — — — — — — — — — — — — — — — — — — — — — — — — — —--------------- — — — — — — I — — — — — — — — — ϋ n I — — — — — — — — — 1. (Please read the notes on the back before filling this page)
so3hso3h
S03H 經濟部智慧財產局員工消費合作社印製S03H Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
581789 A7 -- B7 五、發明說明(/ ) 50份水中後,加入上述的反應液,並升溫至40〜45°C,以 及保持酸鹼值在4〜4·5,反應結束後。將反應所得溶液喷乾 可得如下式(2)之玫瑰紅色染料,又max =5 15.5nm,經染色 後可得特性優良之玫瑰紅色染物。581789 A7-B7 V. Description of the invention (/) After 50 parts of water, add the above reaction solution and raise the temperature to 40 ~ 45 ° C, and keep the pH value at 4 ~ 4.5. After the reaction is completed. The reaction solution was spray-dried to obtain a rose red dye of the following formula (2), and max = 5 15.5 nm. After dyeing, a rose red dye with excellent characteristics was obtained.
實施例3、 以習用的方法將4-(2-硫酸根絡乙基磺醢基)苯胺(4_ (2-sulfatoethylsulfonyl) aniline) 6.4 份重氮化後,將 4-氨 基-2-(2-竣酸)乙基胺苯續酸5.90份加入,並維持酸驗值為 4.5-5.0,反應結束後,以氯化鈉20份鹽析,經過濾乾燥後可 得如下式(3 )之橘色染料,Amax=451.5nm,經染色後可得 特性優良之橘色染物。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製Example 3: 4- (2-sulfatoethylsulfonyl) aniline (4- (2-sulfatoethylsulfonyl) aniline) was diazotized in a conventional manner, and 4-amino-2- (2- Complete acid) 5.90 parts of ethylamine benzoic acid was added, and the acid test value was maintained at 4.5-5.0. After the reaction, salted out with 20 parts of sodium chloride, filtered and dried to obtain the orange color of the following formula (3) Dyes, Amax = 451.5nm, orange dyes with excellent characteristics can be obtained after dyeing. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
27 本紙張尺度適用中國國家標準(CNS)A4規格(210 χ 297公釐) 訂-------- ά—φ--------------------- 經濟部智慧財產局員工消費合作社印製 581789 A7 -^-----B7______ 五、發明說明(於) 實施例4、 取6-(2-硫酸根絡乙基績酿基)-2-氨基-察續酸(6-(2_ sulfatoethylsulfonyl ) -2-amino-1-naphthylsulfonic acid) 8.22 伤知的方法重氣化後’加入4 -氨基-2-(2·缓酸)乙基胺苯 石黃酸5.18份,並維持溫度在15°C、酸鹼值為4 5_5 〇,反應 結束後,以氣化鈉20份鹽析,經過濾乾燥後可得如下式(4 ) 之橘色染料,Amax=471nm,經染色後可得特性優良之橘色染 物027 This paper size applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) Order -------- ά—φ ------------------ --- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 581789 A7-^ ----- B7______ V. Description of the Invention (Yu) Example 4 Take 6- (2-Sulfuryl Ethyl Acetate)- 2-amino-dipic acid (6- (2_ sulfatoethylsulfonyl) -2-amino-1-naphthylsulfonic acid) 8.22 Injury method After heavy gasification, '4-amino-2- (2 · latent acid) ethylamine is added 5.18 parts of benzyl flavonic acid, maintaining the temperature at 15 ° C, and the acid-base value of 4 5-50. After the reaction, salting out with 20 parts of gasified sodium, filtering and drying to obtain the orange color of the following formula (4) Dyes, Amax = 471nm, orange dyes with excellent characteristics can be obtained after dyeing 0
H03SOC2H402SH03SOC2H402S
實施例5、 將 7-氨基-1,3,6-三確酸基-奈(7-amino-l,3,6_trisulf〇nic acid-naphthalene) 19_17份以習知的方法重氮化後,另外, 將間-胺基苯基月尿(m-Aminophenyl urea ) 7.56份均勻分散於 50份水中,然後加入至上述重氮鹽成分中,並保持在溫度 8〜10°C、酸鹼值為4.0,反應完全後再將分散在冰水中的三 聚氰氣9.22份加入至上述溶液中,並保持在溫度5〜8。^、 酸驗值為5.0〜5.5 ’反應完全後再將4-氨基-2-(2-敌酸)乙某 28 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) • ί I I I ϋ ϋ ϋ n ϋ / ϋ ϋ n H ϋ 1 一 δν ( ϋ ϋ ^1 ϋ ϋ ϋ ϋ I mt .^1 n n ·ϋ H ·ϋ ί I I ί I I n ϋ n n I ϋ ϋ I I (請先閱讀背面之注意事項再填寫本頁) 581789 A7 B7 五、發明說明(y)) 胺苯磺酸12.87份加入至上述反應液中,並保持在酸鹼值為 6·〇〜6.5,溫度45°C,反應完全後降溫至7〜1(TC。再將14.2 •份的4-(2-硫酸根絡乙基磺醯基)苯胺以習知的方法重氮化後 的重氮鹽加入至上述溶液中,並調酸鹼值至6.0,反應結束 後。將所得溶液去鹽並喷乾,可得如下式(5 )之金黃色染 料,Amax=428nm,經染色後可得特性優良之金黃色染物。Example 5: After diazotizing 19-17 parts of 7-amino-1,3,6-trisanoic acid-naphthalene (19-17 parts by a conventional method), 7.56 parts of m-Aminophenyl urea were uniformly dispersed in 50 parts of water, and then added to the above diazonium salt component, and maintained at a temperature of 8 ~ 10 ° C and an acid-base value of 4.0 After the reaction is completed, 9.22 parts of melamine dispersed in ice water is added to the above solution and maintained at a temperature of 5-8. ^. The acid test value is 5.0 ~ 5.5 'After the reaction is completed, 4-amino-2- (2-antimonic acid) B will be 28. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) • ί III ϋ ϋ ϋ n ϋ / ϋ ϋ n H ϋ 1 aδν (ϋ ϋ ^ 1 ϋ ϋ ϋ I mt. ^ 1 nn · ϋ H · ϋ ί II ί II n ϋ nn I ϋ ϋ II (please first Read the notes on the back and fill in this page) 581789 A7 B7 V. Description of the invention (y) 12.87 parts of amine benzene sulfonic acid was added to the above reaction solution, and kept at a pH value of 6.0-6.5, temperature 45 ° C. After the reaction is completed, the temperature is lowered to 7 ~ 1 (TC. 14.2 • parts of 4- (2-sulfoethylsulfonyl) aniline are diazotized in a conventional manner and added to the above. In the solution, adjust the pH value to 6.0, and after the reaction is completed, desalinate and spray dry the solution to obtain a golden yellow dye of the following formula (5), Amax = 428nm. After dyeing, a golden yellow with excellent characteristics can be obtained Dye.
SO3HSO3H
NH—^Nv[pNH NVN NHCONH2 丁 N=N ClNH— ^ Nv [pNH NVN NHCONH2 but N = N Cl
NHCH2CH2COOH SO3H —^~y-S〇2CH2CH2〇S〇3H (5) 經濟部智慧財產局員工消費合作社印製 實施例6、 將8·75份的三聚氰氣分散於50份冰水混合物中,然後將 4-氨基-2-(2-羧酸)乙基胺苯磺酸12.14份溶於70份水中,並 在攪拌下加入上述溶液中,然後在5〜fC、酸鹼值為6〇〜6,5 下持續攪拌60分鐘。另外將4-氨基-2-(2-羧酸)乙基胺苯磺 酸12.14份溶於70份水中,然後再加入上述溶液中,並升 溫至40°C,保持ρΗ=6·0〜6.5攪拌至反應完全,然後在溫度 5〜10C下,將26.76份的4-(2-硫酸根絡乙基磺醯基)苯胺以 習知的方法重氮化後的重氮鹽加入至上述溶液中,並調酸鹼 值至6.0,反應結束後。將所得溶液去鹽並喷乾,可得如下 29 本紙張尺度適用中國國家標準規格(210 X 297公爱丁 (請先閱讀背面之注意事項再填寫本頁)NHCH2CH2COOH SO3H — ^ ~ yS〇2CH2CH2〇SO3H (5) The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy printed Example 6. Disperse 8.75 parts of melamine in 50 parts of ice-water mixture, then 12.14 parts of 4-amino-2- (2-carboxylic acid) ethylaminebenzenesulfonic acid was dissolved in 70 parts of water, and added to the above solution with stirring, and then at 5 ~ fC and pH value of 60 ~ 6, Stir continuously for 5 minutes at 60 ° C. In addition, 12.14 parts of 4-amino-2- (2-carboxylic acid) ethylaminebenzenesulfonic acid was dissolved in 70 parts of water, and then added to the above solution, and the temperature was raised to 40 ° C, and ρΗ = 6.0 · 6.5 Stir until the reaction is complete, and then add 26.76 parts of 4- (2-sulfatoethylsulfonyl) aniline diazotized in a conventional manner to the above solution at a temperature of 5 to 10C. , And adjust the pH value to 6.0, after the reaction is over. Desalted the solution and spray-dried to get the following 29 This paper size is applicable to Chinese national standard specifications (210 X 297 male eding (please read the precautions on the back before filling this page)
581789 A7 B7 五、發明說明(β 式(6)之金黃色染料,Amax=435nm,經染色後可得特性優 良之金黃色染物。 HOOCH2CH2CHN NHCH2CH2COOH HO3S—^ \~NH—^ ^—NI HO3SOH2CH2O ^581789 A7 B7 V. Description of the invention (β-formula (6) golden yellow dye, Amax = 435nm, after dyeing, excellent golden yellow dyes can be obtained. HOOCH2CH2CHN NHCH2CH2COOH HO3S— ^ \ ~ NH— ^ ^ —NI HO3SOH2CH2O ^
Ν=Ν I η Cl I II ΝγΝΝ = Ν I η Cl I II ΝγΝ
SO^CH2CH2〇S〇3H (6) 經濟部智慧財產局員工消費合作社印製 實施例7 將9·32份的三聚氰氣分散於5〇份冰水中,再將卜氨基 二磺酸-8_羥基-萘15.97份溶於6.0ml水中,並加入至上述分 月欠液中’然後保持溫度6〜8 °C直至反應完全,然後,將13 77 份的4-(2-硫酸根絡乙基磺醯基)苯胺以習知的方法重氮化後 的重氮鹽加入至上述溶液中,調整酸鹼值至6〇,然後授掉 至反應完全。再將4-氨基-2-(2-羧酸)乙基胺苯績酸1274份 加入至上述反應液中,並控制酸鹼值為6·〇〜6·5,且升溫至4〇 °C,授拌至反應完全後降溫至5〜1(TC。然後再將ι4 〇5份的 4-(2-硫酸根絡乙基績醯基)苯胺,以習知的方法重氮化後的 重氮鹽加入至上述溶液中,並調酸鹼值至5·5〜6〇。等反應 結束後將所得溶液去鹽並喷乾’可得如下式(7 )之桃纟色 染料,久max=502nm,經染色後可得特性優良之桃紅色染物。SO ^ CH2CH2〇S〇3H (6) Printed by Employee Consumption Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Example 7 Disperse 9.32 parts of melamine in 50 parts of ice water, and then diaminosulfonic acid-8 _15.97 parts of hydroxy-naphthalene are dissolved in 6.0 ml of water and added to the above-mentioned liquid phase, and then the temperature is maintained at 6 ~ 8 ° C until the reaction is complete. Then, 13 77 parts of 4- (2-sulfate Disulfosulfanyl) aniline is added to the above solution by diazotized diazotization in a conventional manner, the pH value is adjusted to 60, and then the reaction is allowed to complete. Then, 1274 parts of 4-amino-2- (2-carboxylic acid) ethylamine benzoic acid was added to the above reaction solution, and the acid-base value was controlled to be 6.0-6.5, and the temperature was raised to 40 ° C. After mixing until the reaction is completed, the temperature is lowered to 5 to 1 (TC.) Then, 405 parts of 4- (2-sulfosulfoethylphenyl) aniline is diazotized by conventional methods. Nitrogen salt is added to the above solution, and the pH value is adjusted to 5 · 5 ~ 60. After the reaction is completed, the resulting solution is desalted and spray-dried 'to obtain the peach ochre dye of the following formula (7), max max = 502nm, a pink dye with excellent characteristics can be obtained after dyeing.
—I--1-------·1111111 — I------ (請先閱讀背面之注意事項再填寫本頁) 581789—I--1 ------- · 1111111 — I ------ (Please read the precautions on the back before filling this page) 581789
五、發明說明(4 )V. Description of the invention (4)
--------------餐· II (請先閱讀背面之注意事項再填寫本頁) 實施例8、 將卜氨基_3,6·二磺酸-S_羥基萘i5 %份置入2〇份水中, 調整酸鹼值至6.5-7.0使全溶,然後將溶液溫度降到,並 加入醋酸酐7.13份,並攪拌至確認反應完畢。 --線· 另外,將吐士酸(2_氨基_泰磺酸;2amin〇naphthyl sulfonic aCid)1M6份以習知的方.法重氮化,然後將上述溶 液倒入此重氮化溶液中,並調整酸鹼值至7·8〜8·2,確認反應 完全後,調整酸鹼值至12〜13並昇溫至75°C,直至確認反 應το全,然後加入氣化鈉50份並調整酸鹼值至6·8〜7.2後過 濾。 經濟部智慧財產局員工消費合作社印製 將過滤物以1,000份水溶解,然後快入至已經在3〇份 冰水中分散完畢的9.1份三聚氰氣溶液中,並維持酸鹼值在 6.5〜7.0、溫度在5〜8°C,等確認反應完畢後再加入4-氨基_ 2-(2-竣酸)乙基胺苯績酸11 ·〇ι份,並維持酸驗度在7·〇〜8 〇, 且將溫度升到35〜40°C,直至確認反應完全· 另外以習用的方法將4-(2-硫酸根絡乙基磺醯基)苯胺 11.94份在200份冰/水中重氮化,然後倒入上述溶液中,並維 31 本纸張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(y ) 持酸鹼度在5.5〜6_0,直到反應結束。然後將所得溶液去鹽 並噴乾,可得如下式(8)之桃紅色染料,Amax=514nm,經 .染色後可得特性優良之桃紅色染物。 C1-------------- Meal · II (Please read the precautions on the back before filling this page) Example 8: Put amino_3,6 · disulfonic acid-S_hydroxynaphthalene I 5% part was put into 20 parts of water, adjusted the pH value to 6.5-7.0 to make it completely soluble, then the solution temperature was lowered, and 7.13 parts of acetic anhydride was added, and stirred until the reaction was confirmed to be complete. --Line · In addition, 1M6 parts of toastic acid (2-amino_tetrasulfonic acid; 2aminonaphthyl sulfonic aCid) were diazotized in a conventional manner, and then the above solution was poured into the diazotized solution. , And adjust the pH value to 7 · 8 ~ 8 · 2, after confirming the reaction is complete, adjust the pH value to 12 ~ 13 and raise the temperature to 75 ° C until the reaction is complete, then add 50 parts of sodium gasification and adjust Filter after pH value reaches 6 · 8 ~ 7.2. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, dissolve the filter with 1,000 parts of water, and then quickly enter the 9.1 parts of melamine solution that has been dispersed in 30 parts of ice water, and maintain the pH value at 6.5 ~ 7.0, the temperature is 5 ~ 8 ° C, after confirming the reaction is completed, add 11 · 00 parts of 4-amino_ 2- (2-endic acid) ethylamine benzoic acid, and maintain the acidity test at 7 〇 ~ 8 〇, and raise the temperature to 35 ~ 40 ° C until it is confirmed that the reaction is complete. In addition, 11.94 parts of 4- (2-sulfoethylsulfonyl) aniline in 200 parts of ice / Diazotize in water, then pour into the above solution, and keep it 31. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 581789 A7 B7 V. Description of the invention (y) The pH is between 5.5 ~ 6_0 until the end of the reaction. Then, the obtained solution is desalted and spray-dried to obtain a pink dye with the following formula (8), Amax = 514nm. After dyeing, a pink dye with excellent characteristics can be obtained. C1
NN
實施例9-11 依實施例1-2所述方法,製備如下式染料 (請先閱讀背面之注意事項再填寫本頁)Example 9-11 According to the method described in Example 1-2, a dye of the following formula was prepared (please read the precautions on the back before filling this page)
Di—NR NHCH2CH2COOH -so3hDi—NR NHCH2CH2COOH -so3h
經濟部智慧財產局員工消費合作社印製 其中D^R及X之定義如表一所述 32 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 κι Β7 五、發明說明(々丨) 表一 實施例編號 D.-NHR X 9 so3H /, Ν=Ν_^ΝΗ2 NHCONH2 Cl 10 NHCONhfe F 11 OH NH2 Cl (請先閱讀背面之注意事項再填寫本頁) .¾ 線· 實施例12_18 依實施例3-4所述方法,製備如下式染料:Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, where the definitions of D ^ R and X are as described in Table 1. 32 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 581789 κι B7 V. Description of the invention (々 丨) Example No. D.-NHR X 9 so3H /, Ν = Ν_ ^ ΝΗ2 NHCONH2 Cl 10 NHCONhfe F 11 OH NH2 Cl (please read the precautions on the back before filling this page). ¾ Line · Implementation Example 12-18 According to the method described in Example 3-4, a dye of the following formula was prepared:
NHCH2CH2COOH 經濟部智慧財產局員工消費合作社印製 h2n——so3h N=N-Zi 其中Zi定義如表二所述。 33 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(多>) 經濟部智慧財產局員工消費合作社印製 表二 實施例編號 Zt-NH2 12 och3 HO3SOH2CH2CO2S—nh2 h3co 13 ch3 HO3SOH2CH2CO2S—^ ^)—nh2 h3co 14 OCH3 ho3soh2ch2co2s 15 S〇3h HQjSOHfHfQzSH^^K NH2 16 SO3H 17 rryNH2 H〇3SOH2CH2C〇2S/^^s^ 18 ^I)-nh2 ho3soh2ch2co2s 實施例19-94 34 (請先閱讀背面之注意事項再填寫本頁) .¾ · 線. 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(於) 依實施例5-8所述方法,製備如下式染料NHCH2CH2COOH Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs h2n——so3h N = N-Zi where Zi is defined as described in Table 2. 33 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 581789 A7 B7 V. Description of the invention (multiple >) Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Example number Zt-NH2 12 och3 HO3SOH2CH2CO2S—nh2 h3co 13 ch3 HO3SOH2CH2CO2S— ^ ^) — nh2 h3co 14 OCH3 ho3soh2ch2co2s 15 S〇3h HQjSOHfHfQzSH ^^ K NH2 16 SO3H 17 rryNH2 H2 ^ 2H2S2 ^ Example 19-94 34 (Please read the precautions on the back before filling this page). ¾ · Thread. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of the invention ( In) According to the method described in Example 5-8, a dye of the following formula is prepared
NHNH
NHCH2CH2COOH so3hNHCH2CH2COOH so3h
N=N-Z!其中01、1^、又及21之定義如表三所述 (請先閱讀背面之注意事項再填寫本頁) 表 5 3N = N-Z! The definitions of 01, 1 ^, and 21 are as described in Table 3. (Please read the precautions on the back before filling this page) Table 5 3
實施例 編號 DrNHR X z,—nh2 19 SOaH ?H VH2 氣 Cl nh2 Φ S02CH2CH20S03H 20 so3h H〇3S"^^^S03H nhconh2 Cl ^^ΝΗ2 S02CH2CH20S03H 21 S03H —. N=N^J_NH: H03S^^v^!^S〇3H NHCONH2 〔:〕 1 nh2 Φ S02CH2CH20S03H 22 H03s 0 ch3 \—. H2N-CxJsyN=N-/^ O^N^OH NH2 C2H5 Cl nh2 Φ CONH(CH2)2SQ2(CH2)2〇S〇3H 23 ho3s 0 ch3 V-. η2ν-〇、^Ι^ν=ν—^^^ο3η O^N^OH NH2 C2H5 Cl nh2 Φ SO2CH2CH2OSO3H 本紙張尺度適用中國國家標準(CNS)A4規格(210 χ 297公爱) 581789Example number DrNHR X z, -nh2 19 SOaH? H VH2 gas Cl nh2 Φ S02CH2CH20S03H 20 so3h H〇3S " ^^^ S03H nhconh2 Cl ^^ ΝΗ2 S02CH2CH20S03H 21 S03H —. N = N ^ J_NH: H03S ^ ! ^ S〇3H NHCONH2 〔:〕 1 nh2 Φ S02CH2CH20S03H 22 H03s 0 ch3 \ —. H2N-CxJsyN = N-/ ^ O ^ N ^ OH NH2 C2H5 Cl nh2 Φ CONH (CH2) 2SQ2 (CH2) 2〇S. 3H 23 ho3s 0 ch3 V-. Η2ν-〇, ^ Ι ^ ν = ν — ^^^ ο3η O ^ N ^ OH NH2 C2H5 Cl nh2 Φ SO2CH2CH2OSO3H This paper standard applies Chinese National Standard (CNS) A4 specification (210 χ 297) Public love) 581789
經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
24 CH H〇3S\ O^N^OH NH2 c2h5 F φ2 S02CH2CH20S03H 25 SO3H HO3S—〈 ^~·N=N—^ 》—NH2 NHCONH2 F ςτ CONH(CH2)2SQ2(CH2)2〇SQ3H 26 nhcoch3 so3h Cl φ2 SO2CH2CH2OSO3H 27 so3H SO3H Cl φ2 SO2CH2CH2OSO3H 28 SO3H 0 肩<xr N N XS〇3H F φ2 SO2CH2CH2OSO3H 29 NH2 OH HO^S HQBSOH^CH2CQ2S~^^-N=N-|^Y/^pN=N~^^ HQ3S人人人御 Cl H〇3S h2n-Q SO3H 30 ^S03H 〇H h3c_^_n=n_^Y^ HOsS^ H03S^^^NH2 $ SQ2CH2CH2pS〇3H φ2 SO2CH2CH2OSO3H 31 so3h 〇H Nh2 HO3S— Cl nh2 φ SO2CH2CH2OSO3H 32 SO3H H03SOH2CH2C〇2S—^~y-N=N—^~~y-NH2 h2n OH φ2 S02CH2CH2〇S03H 33 SO3H 0(CH2)2〇S031^h NH2 f"^~N=N —^"~^-Ν=Ν—^γ^| HO 尸匕册sAAAS〇3H Cl φ2 S02CH2CH20S03H --------訂---------線-m·(請先閱讀背面之注意事項再填寫本頁) 36 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) 8 5 9 824 CH H〇3S \ O ^ N ^ OH NH2 c2h5 F φ2 S02CH2CH20S03H 25 SO3H HO3S— <^ ~ · N = N— ^》 —NH2 NHCONH2 F ττ CONH (CH2) 2SQ2 (CH2) 2〇SQ3H 26 nhcoch3 so3h Cl φ2 SO2CH2CH2OSO3H 27 so3H SO3H Cl φ2 SO2CH2CH2OSO3H 28 SO3H 0 shoulder < xr NN XS〇3H F φ2 SO2CH2CH2OSO3H 29 NH2 OH HO ^ S HQBSOH ^ CH2CQ2S ~ ^^-N = N-P = HQ3S Everyone Royal Cl H〇3S h2n-Q SO3H 30 ^ S03H 〇H h3c _ ^ _ n = n_ ^ Y ^ HOsS ^ H03S ^^^ NH2 $ SQ2CH2CH2pS〇3H φ2 SO2CH2CH2OSO3H 31 so3h 〇H Nh2H2CH3SO-Cl n 32 SO3H H03SOH2CH2C〇2S— ^ ~ yN = N— ^ ~~ y-NH2 h2n OH φ2 S02CH2CH2〇S03H 33 SO3H 0 (CH2) 2〇S031 ^ h NH2 f " ^ ~ N = N — ^ " ~ ^- Ν = Ν— ^ γ ^ | HO Corpse Book sAAAS〇3H Cl φ2 S02CH2CH20S03H -------- Order --------- Line-m · (Please read the precautions on the back before filling (This page) 36 This paper is sized for China National Standard (CNS) A4 (210 x 297 mm) 8 5 9 8
7 7 A B 經濟部智慧財產局員工消費合作社印製7 7 A B Printed by Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs
--線- (請先閱讀背面之注意事項再填寫本頁) -1 ml ϋ · . 581789 A7B7 五、發明說明(吵 44 —SO3H 〇h h3co~(^-n=n~j^y^ H〇3Sx^>^Ss^S"NH2 F nh2 Φ S02CH2CH20S03H 45 so3h 0H NHCOCH2CH3 0-n=nyVS Cl nh2 Φ S02CH2CH20S03H 46 ho3s HOOC N=N— ~[f N、N 人 OH NH2 Φ so3h F nh2 <rS03H SO2CH2CH2OSO3H 47 nh2 0 j0cVCXTs〇3H h〇3s^^ N N Cl NH2 CONH(CH^2S〇2(CH2)2〇SO^ 48 so3h nh2 oh ho3s ^NH2 so3h F $ SO2CH2CH2OSO3H 49 —S03H 0H H3CO-(^~N=:N nh2 Φ S02CH2CH20S03H nh2 Φ S02CH2CH20S03H 50 so3h oh Nh2 Cl s〇2CH2CH2〇s〇3H 51 〇(ch2)2oh 〇h NHz h〇3S^ Ihz HOaS^^^SOaH Cl φ2 SO2CH2CH2OSO3H 52 ^so3H 0H W N=NtY\ ho3s/^^^nh2 Cl nh2 Φ S02CH2CH20S03H 53 ^SO3H 〇H Η3〇〇~《"Ύ-Ν=Ν-^γ^ HOaS-V^NH ch3 Cl nh2 Φ CONH(CH2)2S〇2(CH2)2PSO^ 訂: ·,線. 8 3 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公爱) 581789 A7 B7 五、發明說明(W ) 經濟部智慧財產局員工消費合作社印製--Line- (Please read the notes on the back before filling this page) -1 ml. ·. 581789 A7B7 V. Description of the invention (Noise 44 —SO3H 〇h h3co ~ (^-n = n ~ j ^ y ^ H 〇3Sx ^ > ^ Ss ^ S " NH2 F nh2 Φ S02CH2CH20S03H 45 so3h 0H NHCOCH2CH3 0-n = nyVS Cl nh2 Φ S02CH2CH20S03H 46 ho3s HOOC N = N— ~ [f N, N Human OH NH2 Φ so3h F n rS03H SO2CH2CH2OSO3H 47 nh2 0 j0cVCXTs〇3H h〇3s ^^ NN Cl NH2 CONH (CH ^ 2S〇2 (CH2) 2〇SO ^ 48 so3h nh2 oh ho3s ^ NH2 so3h F $ SO2CH2CH2OSO3H 49 --S03H 0H H3 N =: N nh2 Φ S02CH2CH20S03H nh2 Φ S02CH2CH20S03H 50 so3h oh Nh2 Cl s〇2CH2CH2〇s〇3H 51 〇 (ch2) 2oh 〇h NHz h〇3S ^ Ihz HOaS ^^ SOaH Cl φ2SO2H2CH2O2O2H2CH2O NtY \ ho3s / ^^^ nh2 Cl nh2 Φ S02CH2CH20S03H 53 ^ SO3H 〇H Η3〇〇 ~ 《" Ύ-N = N- ^ γ ^ HOaS-V ^ NH ch3 Cl nh2 Φ CONH (CH2) 2S〇2 ( CH2) 2PSO ^ Order: ·, line. 8 3 This paper size applies to China National Standard (CNS) A4 (210 x 297 public love) 581789 A7 B7 V. Description of invention (W) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs system
54 so3h nhconh2 Cl nh2 H"srS N^N 人/a P S02CH2CH20S03H 55 S03H OH NH2 Cl NH2 人蝴 V CONH(CH2)2SQ2(CH2)2〇SO^ 56 0 nh2 C&rS03H ϊ ΐΗγγδ〇3Η ^^nh2 Cl nh2 Φ S02CH2CH20S03H 57 /0H OH NH2 w ν=ντΓΫ1 02N/ H03Sy^^^S02H 1/2鉻錯合物 Cl nh2 Φ S02CH2CH20S03H 58 OH NH2 HO3SOH2CH2CO2S—/ \-Ν=Ν-Υί!^Υη h〇3sx^^^so3h NH? SQP^CH^OSO^ nh2 Φ S02CH2CH20S03H 59 SO3H OH NH2 Cl nh2 Φ S02CH2CH20S03H 60 SO3H 〇H NH2 H〇3S-^y~N=N-|^Y^ H〇3Sx^^^S〇3H F NHo Φ CONH(CH2bS〇2(CH2)2〇S〇3H 61 SO3H 0(CH2)2〇H 〇h 0~-^-NtVrNH2 HO 尸 H03sAA^ Cl nh2 Φ SO2CH2CH2OSO3H 62 —,S〇3H OH w N=NtVl Cl nh2 φτδ03Η S〇2(CH2)2〇S〇3H 39 ------------- (請先閱讀背面之注意事項再填寫本頁) 訂---------線. 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 B7 五、發明說明(W ) 經濟部智慧財產局員工消費合作社印製54 so3h nhconh2 Cl nh2 H " srS N ^ N person / a P S02CH2CH20S03H 55 S03H OH NH2 Cl NH2 person butterfly V CONH (CH2) 2SQ2 (CH2) 2〇SO ^ 56 0 nh2 C & rS03H ϊ ΐΗγγδ〇2Η ^^ Cl nh2 Φ S02CH2CH20S03H 57 / 0H OH NH2 w ν = ντΓΫ1 02N / H03Sy ^^ S02H 1/2 chromium complex Cl nh2 Φ S02CH2CH20S03H 58 OH NH2 HO3SOH2CH2CO2S— / \ -Ν = Ν-Υί! ^ X h h ^^^ so3h NH? SQP ^ CH ^ OSO ^ nh2 Φ S02CH2CH20S03H 59 SO3H OH NH2 Cl nh2 Φ S02CH2CH20S03H 60 SO3H 〇H NH2 H〇3S- ^ y ~ N = N- | ^ Y ^ H〇3Sx ^^^ S 〇3H F NHo Φ CONH (CH2bS〇2 (CH2) 2〇S〇3H 61 SO3H 0 (CH2) 2〇H 〇h 0 ~-^-NtVrNH2 HO corpse H03sAA ^ Cl nh2 Φ SO2CH2CH2OSO3H 62 —, S〇3H OH w N = NtVl Cl nh2 φτδ03Η S〇2 (CH2) 2〇S〇3H 39 ------------- (Please read the precautions on the back before filling this page) Order ---- ----- Line. This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 B7 V. Description of Invention (W) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs
63 OH NH2 HO3SOH2CH2CO2S—/ HOaS^^^^sOaH Cl nh2 H〇3SrS N^N 人 N^CI P S02CH2CH20S03H 64 ^SO3H 0H h3c〇~^(^-n=n-|<;;^Y^ h〇3s卜7 HO3S入人^nh2 F NH〇 Φ SO2CH2CH2OSO3H 65 SO3H OH NH2 so3h F nh2 Φ SO2CH2CH2OSO3H 66 0 nh2 0¾^ if T A NH? 0 2 ^^S03H OH HN^^' 、0H nh2 Φ S02CH2CH20S03H 67 (%S0ZH)X 1 1 N-Ni — N 1 -fs〇2NHCH2CH2NH2)z N—^ \=N (jrS〇m X+y:1:2 F nh2 Φ S02CH2CH20S03H 68 OH NH2 HO3SOH2CH2CO2S—/ /"Ν=Νπ^Υη Γ2 Φ SO^CH^OSO^ nh2 rVs〇3H 69 S03H OH NH2 picAX s〇3H Cl nh2 Φ S02CH2CH20S03H 70 OH NH2 HO3SOH2CH2CO2S-/ / Ν=ΝΠ^Υι Cl nh2 Φ CONH(CH2bSQ2(〇H2)2〇SQ3H 71 S03H 〇H h3C_^_n=n^Y^ H03S^ F nh2 Φ SO2CH2CH2OSO3H 40 ---------------------^---------^ . (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 _B7 五、發明說明(^) 經濟部智慧財產局員工消費合作社印製 72 OH NH2 C>-n=nVtS h〇3S^^x^^s〇3H Cl nh2 Φ S02CH2CH20S03H 73 SO2CH2CH2OSO3H OH NH2 &;^ώδ〇3Η nh2 (5l ^^so3h nh2 Φ S02CH2CH20S03H 74 0 nh2 〇Χτ; 〇 nh^L,nh2 V so3H Cl nh2 Φ S02CH2CH20S03H 75 { \s〇3H)x n^1n (¾十卜力 N-^ V=N _z ^^S02NH2)y X+㈢ Cl nh2 Φ S02CH2CH20S03H 76 SO3H oh Nh2 w n=nVyS NH2 Φ SOSCH^OSO^I nh2 Φ S02CH2CH20S03H 77 nh2 0 Avcxi N N X Cl nh2 Φ S02CH2CH20S03H 78 SO3H OH NH2 oioiX Cl nh2 Φ CONH(CH2)2Sp2(CH2)2〇SC^ 79 SO3H 〇H C^n=nyS^ H〇3S^>\^NH ch3 Cl NH2 V CONH(CH2)2SO^(CH2)2pSO^ 80 SO3H 〇H Nh2 W n=nyVi ho3sx^^n^vso3h F nh2 Φ SO2CH2CH2OSO3H 41 --------------1 (請先閱讀背面之注意事項再填寫本頁) 訂:--------線 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 經濟部智慧財產局員工消費合作社印製63 OH NH2 HO3SOH2CH2CO2S— / HOaS ^^^^ sOaH Cl nh2 H〇3SrS N ^ N Human N ^ CI P S02CH2CH20S03H 64 ^ SO3H 0H h3c〇 ~ ^ (^-n = n- | <;; ^ Y ^ h 〇3s Bu 7 HO3S entry ^ nh2 F NH〇Φ SO2CH2CH2OSO3H 65 SO3H OH NH2 so3h F nh2 Φ SO2CH2CH2OSO3H 66 0 nh2 0¾ ^ if TA NH? 0 2 ^^ S03H OH HN ^^ ', 0H nCH2% S02 S0ZH) X 1 1 N-Ni — N 1 -fs〇2NHCH2CH2NH2) z N— ^ \ = N (jrS〇m X + y: 1: 2 F nh2 Φ S02CH2CH20S03H 68 OH NH2 HO3SOH2CH2CO2S— // / " N = Νπ ^ Υη Γ2 Φ SO ^ CH ^ OSO ^ nh2 rVs〇3H 69 S03H OH NH2 picAX s〇3H Cl nh2 Φ S02CH2CH20S03H 70 OH NH2 HO3SOH2CH2CO2S- / / Ν = ΝΠ ^ Υι Cl nh2 Φ CONH (〇22SQ) SQ3H 71 S03H 〇H h3C _ ^ _ n = n ^ Y ^ H03S ^ F nh2 Φ SO2CH2CH2OSO3H 40 --------------------- ^ -------- -^. (Please read the notes on the back before filling out this page) This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 _B7 V. Description of Invention (^) Bureau of Intellectual Property, Ministry of Economic Affairs Printed by Employee Consumption Cooperative 72 OH NH2 C > -n = nVtS h〇3S ^^ x ^^ s〇3H Cl nh2 Φ S02CH2CH20S03H 7 3 SO2CH2CH2OSO3H OH NH2 & ^ ώδ〇3Η nh2 (5l ^^ so3h nh2 Φ S02CH2CH20S03H 74 0 nh2 〇 × τ; 〇nh ^ L, nh2 V so3H Cl nh2 Φ S02CH2CH20S03H 75 {n1 ^ 3 Ten Forces N- ^ V = N _z ^^ S02NH2) y X + ㈢ Cl nh2 Φ S02CH2CH20S03H 76 SO3H oh Nh2 wn = nVyS NH2 Φ SOSCH ^ OSO ^ I nh2 Φ S02CH2CH20S03H 77 nh2 0 Avcxi NNX SCHH2Φ2H2 OH NH2 oioiX Cl nh2 Φ CONH (CH2) 2Sp2 (CH2) 2〇SC ^ 79 SO3H 〇HC ^ n = nyS ^ H〇3S ^ > \ ^ NH ch3 Cl NH2 V CONH (CH2) 2SO ^ (CH2) 2pSO ^ 80 SO3H 〇H Nh2 W n = nyVi ho3sx ^^ n ^ vso3h F nh2 Φ SO2CH2CH2OSO3H 41 -------------- 1 (Please read the precautions on the back before filling this page) Order : -------- The paper size of the paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 581789 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
B7 發明說明(々。) 81 so3h oh nh2 H〇3SOH2CH2C〇2S"^5^x^5^ F NH2 Φ CONH(CH2)2SQ2(CH2)2〇SQ3H 82 0 nh2 翁: 〇 NH^i^SOaH H3C^Y^CH3 nh2 F nh2 Φ SO2CH2CH2OSO3H 83 so3h fv J^n=n-^Jknh2 NHCONH2 NH2 S〇2CH^>^OSQ^ nh2 Φ S02CH2CH20S03H 84 so3h oh nh2 S03H NH2 Φ SO^CH^OSO^ nh2 Φ S02CH2CH2OSO3H 85 SO3H 〇H Nh2 H3C〇~^(^- H03S^^^^S〇3H g" NHo Φ SO2CH2CH2OSO3H 86 S03H OH NH2 p6r^6s〇3H so3h F ,VNH2 pr CONH(CH2)2SQ2(CH2)2〇SO^H 87 OH >40350ΙΗ2αΗ2(:〇23—^"^-Ν=Ν— ho3s 入〆^^nh2 0 1 nh2 rVs〇3H 88 OH NH2 HOOC—(~^-Ν=Ν— HO3S 人^^^so3h Cl ,VNH2 pT CONH(CH2)2SQ2(CH2)2〇SO^H 89 SO3H OH NH2 jf^xVN=N^xb H〇3SOH2CH2C〇2S^^^5^ so3H Cl nh2 gs03H N=N—^~^-ε〇3Η 90 NH2 oh HO3S、 H03s—^""~^-N=N—^Y^pN=N—^^ ho3s^^^so3h ^^nh2 F nh2 Φ S02CH2CH20S03H 91 S03H y_, 則p^NH2 NHCOCH3 so3h nh2 Φ S02CH2CH20S03H nh2 Φ S02CH2CH20S03H -------------(請先閱讀背面之注意事項再填寫本頁) 訂---------線 42 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 581789 A7 ______B7 五、發明說明(如)B7 Description of the invention (々.) 81 so3h oh nh2 H〇3SOH2CH2C〇2S " ^ 5 ^ x ^ 5 ^ F NH2 Φ CONH (CH2) 2SQ2 (CH2) 2〇SQ3H 82 0 nh2 Weng: 〇NH ^ i ^ SOaH H3C ^ Y ^ CH3 nh2 F nh2 Φ SO2CH2CH2OSO3H 83 so3h fv J ^ n = n- ^ Jknh2 NHCONH2 NH2 S〇2CH ^ > ^ OSQ ^ nh2 Φ S02CH2CH20S03H 84 so3h oh nh2 S03H NH2OS2 CH2 ^ SO ^ 85 SO3H 〇H Nh2 H3C〇 ~ ^ (^-H03S ^^^^ S〇3H g " NHo Φ SO2CH2CH2OSO3H 86 S03H OH NH2 p6r ^ 6s〇3H so3h F, VNH2 pr CONH (CH2) 2SQ2 (CH2) 2SO ^ H 87 OH > 40350ΙΗ2αΗ2 (: 〇23 — ^ " ^-N = Ν- ho3s 〆 ^^ nh2 0 1 nh2 rVs〇3H 88 OH NH2 HOOC— (~ ^ -Ν = Ν— HO3S people ^^ ^ so3h Cl, VNH2 pT CONH (CH2) 2SQ2 (CH2) 2〇SO ^ H 89 SO3H OH NH2 jf ^ xVN = N ^ xb H〇3SOH2CH2C〇2S ^^^ 5 ^ so3H Cl nh2 gs03H N = N— ^ ~ ^ -ε〇3Η 90 NH2 oh HO3S, H03s — ^ " " ~ ^ -N = N— ^ Y ^ pN = N — ^^ ho3s ^^^ so3h ^^ nh2 F nh2 Φ S02CH2CH20S03H 91 S03H y_, then p ^ NH2 NHCOCH3 so3h nh2 Φ S02CH2CH20S03H nh2 Φ S02CH2CH20S03H ------------- (Please read the precautions on the back before filling this page) Order --------- line 42 Paper scale applicable Chinese National Standard (CNS) A4 size (210 X 297 mm) 581789 A7 ______B7 V. invention will be described (as)
S03H oh NHCOCH2CH3 - nh2 92 (J^n=nVyS Λ Λ h2n^ HOaS^^^^sOaH r V 55Π〇ΓίΗ〇ΡΝ〇Π9Π<ιΗ S〇3h ~ 93 Cl nh2 ό S03h H3COCHN H03sX^^'v^V,S03H V S02CH2CH20S03H 94 NH2 0 j&VCXl H03S^5^^N N N X Cl ςτ s〇2CH2CH2〇s〇3H ------------ (請先閱讀背面之注意事項再填寫本頁) 實施例95、 取尿素100份,間硝基苯磺酸鈉鹽(m-nitr〇benzene sulfonic acid sodium salt) 10 份,小蘇打 2〇 份,海藻酸鈉 55 份,溫水81 5份合計1000份,經攪拌配製可得助劑糊。 取3份實施例1中所製備的染料,灑於上述助劑糊i 〇〇 份中,並快速攪拌。以l〇〇mesh的45度斜紋版印花網版覆 蓋在一適當大小的絲光棉斜紋布上,再將上述色糊置於網版 上並刮過。 將刮好的布放到65°c烘箱内5分鐘烘乾;將烘乾好的 布放入蒸箱以常壓飽和蒸氣1024 〇5l蒸處1〇分鐘。 然後將所得到橘色染物先經冷水洗,再經沸騰熱水洗1 〇 分鐘,然後再以沸騰之非離子清潔劑皂洗1〇分鐘,最後再 用冷水洗清一次,乾燥後可得到橘色的染物具備優良的染深 性及上色率。 訂---------線 « 經濟部智慧財產局員工消費合作社印製 43S03H oh NHCOCH2CH3-nh2 92 (J ^ n = nVyS Λ Λ h2n ^ HOaS ^^^ sOaH r V 55Π〇ΓίΗ〇ΡΝ〇Π9Π < ιΗ S〇3h ~ 93 Cl nh2 ό S03h H3COCHN H03sX ^^ 'v ^ V , S03H V S02CH2CH20S03H 94 NH2 0 j & VCXl H03S ^ 5 ^^ NNNX Cl ςτ s〇2CH2CH2〇s〇3H ------------ (Please read the precautions on the back before filling this page) Example 95: Take 100 parts of urea, 10 parts of m-nitr〇benzene sulfonic acid sodium salt, 20 parts of baking soda, 55 parts of sodium alginate, 81 parts of warm water, and a total of 1,000 A part of the auxiliary paste is prepared by stirring. 3 parts of the dye prepared in Example 1 are sprinkled on the 100 parts of the auxiliary paste, and quickly stirred. Printed at 100 mesh at a 45-degree twill printing plate. The screen is covered with a suitable size of mercerized cotton twill, and then the color paste is placed on the screen and scraped. Put the scraped cloth in a 65 ° C oven for 5 minutes to dry; dry the cloth Put it in a steam box for 10 minutes at 1024 005l of saturated steam at normal pressure. Then the obtained orange dye was washed with cold water and then with boiling hot water for 10 minutes. Soap with a boiling non-ionic detergent for 10 minutes, and finally wash it with cold water again. After drying, you can get orange dyes with excellent depth and coloring rate. Order -------- -Line «Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 43
經濟部智慧財產局員工消費合作社印製 581789 ^Ϊ 五、發明說明(今r) 貫施例96、 取尿素100份,間-硝基苯磺酸鈉鹽10份,小蘇打20 。❶海藻酸鈉55份,溫水8丨5份合計丨〇〇〇份,經攪拌配製 可得助劑糊。 取3份貫施例2所製備的染料灑於上述} 〇〇份的助劑糊 中,並快速攪拌。以10〇mesh的45度斜紋版印花網版覆蓋 在-適當大小的絲光棉斜紋布上,再將上述色糊置於網版上 並刮過。 將刮好的布放到65t烘箱内5分鐘烘乾;將烘乾好的 布放入蒸箱以常壓飽和蒸氣1〇2〜1〇5<^蒸處1〇分鐘。 然後將所得到玫瑰紅色染物先經冷水洗,再經沸騰熱水 洗10分鐘,然後再以沸騰之非離子清潔劑皂洗1〇分鐘,最 後再用冷水洗清一次,乾燥後可得到玫瑰紅色的染物具備優 良的染深性及上色率。 貫施例97、 取3份實施例3所製備的染料溶於loo毫升水中,配製 成30份/升壓染液;取鹼劑25毫升(使用苛性鈉38(^^15 毫升/升和芒硝30份/升)加入於壓染液中均勻攪掉,所得a 合液倒入羅拉(Roller)壓染器中,然後將棉織物經過羅拉壓 染後,再捲成轴狀。此形態棉織物在室溫下儲存4 本紙張尺度適用中國國家標準(CNS)A4規格(210 --------------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 44 581789 A7Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 581789 ^ Ϊ 5. Description of the Invention (present r) Implementation Example 96: Take 100 parts of urea, 10 parts of m-nitrobenzenesulfonic acid sodium salt, and 20 parts of baking soda. 55 parts of sodium alginate, 8 parts of warm water, 5 parts in total, and 1000 parts, can be prepared by stirring to obtain an auxiliary paste. 3 parts of the dye prepared in Example 2 was sprinkled on the above-mentioned auxiliary paste and stirred quickly. Cover with a 45-degree twill printing screen of 100 mesh on a mercerized cotton twill of an appropriate size, and then place the above color paste on the screen and scrape it. Put the scraped cloth in a 65t oven for 5 minutes to dry it; put the dried cloth into a steam box with normal pressure saturated steam 102 ~ 105 and steam for 10 minutes. Then the obtained rose red dye is washed with cold water, then with boiling hot water for 10 minutes, and then soaped with boiling non-ionic detergent for 10 minutes, and finally washed with cold water once. After drying, the rose red dye can be obtained. The dyeing material has excellent dyeing depth and coloring rate. In Example 97, 3 parts of the dye prepared in Example 3 were dissolved in loo ml of water to prepare 30 parts / pressurization dye solution; 25 ml of an alkali agent (using caustic soda 38 (^^ 15 ml / L and Glauber's salt 30 parts per liter) was added to the dyeing solution and stirred evenly. The resulting a mixture was poured into a Roller press dyeing device, and then the cotton fabric was pressed and dyed by the roller and then rolled into a shaft shape. This form of cotton The fabric is stored at room temperature. 4 paper sizes are applicable to China National Standard (CNS) A4 specifications (210 -------------------- Order -------- -Line (Please read the notes on the back before filling this page) 44 581789 A7
經濟部智慧財產局員工消費合作社印製 五、發明說明(衫) 後,將所得到橘色染物先經冷水洗,再經彿騰熱水洗1〇分 鐘,然後經沸騰之非離子清潔劑皂洗1〇分鐘,最後再用冷 水诜清一次,乾燥後可得到橘色的染物具備優良的染深性^ JL色率。 實施例98、 取3份實施例4所製備的染料溶於1〇()毫升水中,配製 成30份/升壓染液;取鹼劑25毫升(使用苛性鈉38沱^15 毫升/升和芒硝30份/升)加入於壓染液中均勻攪拌,所得混 合液倒入羅拉(Roller)壓染器中,然後將棉織物經過羅拉壓 染後’再捲成軸狀。此形態棉織物在室溫下儲存4小時。然 後’將所得到橘色染物先經冷水洗,再經沸騰熱水洗丨〇分 鐘’然後經沸騰之非離子清潔劑皂洗10分鐘,最後再用冷 水洗清一次,乾燥後可得到橘色的染物具備優良的染深性及 上色率。 貫施例99、 取0.25份實施例5所製備的染料溶於250毫升水中做 成母液,取上述母液40毫升置於染色瓶中,然後放入棉織 物2伤,再放入芒頌2.4份,最後放入32%純驗溶液2·5毫 升;將染瓶放入60°C之水平震盪染色機中,保溫60分鐘。 然後將所得到金黃色染物先經冷水洗,再經沸騰熱水洗1〇 本紙張尺度適(CNS)A4規格⑽x 297公爱)-----〜-- — — — — — — — — — — — — — — — — — I— ^ 1111111 (請先閱讀背面之注意事項再填寫本頁) 581789 經濟部智慧財產局員工消費合作社印製 A7 、發明說明(斜 A、 J後乂沸騰之非離子清潔劑皂洗1 〇分鐘,最後再用 t良洗α—次,乾燥後所製得的金黃色染物具備優良 性、上色率及水洗牢度。 衣 實施例1〇〇、 、取〇·25份實施例6所製備的染料溶於25〇毫升水中做 成母^,取上述母液4〇毫升置於染色瓶中,然後放入棉織 物2伤,再放入芒硝2·4份,最後放入32%純鹼溶液毫 升/將染瓶放入60t:之水平震盪染色機中,保溫6〇分鐘。 然後將所得到金黃色染物先經冷水洗,再經沸騰熱水洗ι〇 分鐘,然後經沸騰之非離子清潔劑皂洗丨〇分鐘,最後再用 冷水洗清一次,乾燥後所製得的金黃色染物具備優良的染深 性及上色率。 實施例101、 取0.25份實施例7所製備的染料溶於25〇毫升水中做 成母液,取上述母液40毫升置於染色瓶中,再放入棉織物 2份,然後放入芒硝2.4份,最後放入32%純鹼溶液2_5毫 升;將染瓶放入60°C之水平震盪染色機中,保溫6〇分鐘。 然後將所得到桃紅色染物先經冷水洗,再經沸騰熱水洗1〇 分鐘,然後經沸騰之非離子清潔劑皂洗1〇分鐘,最後再用 冷水洗清一次’乾餘後所製付的桃紅色染物具備優良的染深 ---------tx---------$· (請先閱讀背面之注意事項再填寫本頁) 46 581789 A7 —----^L· __ 一 五、發明說明(柊) 性及上色率。 .實施例102、 取〇·25份實施例8所製備的染料溶於25〇毫升水中做成母 液,取上述母液40毫升置於染色瓶中,再放入棉織物2份, 然後放入芒罐2.4份,最後放入32%純鹼溶液2·5毫升;將 木瓶放入60 C之水平震盪染色機中,保溫6〇分鐘。然後將 所得到桃紅色染物先經冷水洗,再經沸騰熱水洗分鐘, 然後經沸騰之非離子清潔劑皂洗1 〇分鐘,最後再用冷水洗 清一次,乾燥後所製得的桃紅色染物具備優良的染深性、上 色率及水洗牢度。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (shirt). The orange dyes were washed with cold water, then with hot water for 10 minutes, and then soaped with boiling non-ionic detergent. After 10 minutes, rinse with cold water again at the end. After drying, an orange dye with good dyeing depth ^ JL color ratio can be obtained. Example 98: Dissolve 3 parts of the dye prepared in Example 4 in 10 (ml) water to prepare 30 parts / pressurization dye solution; take 25 ml of alkali agent (using caustic soda 38 沱 15 ml / liter) And Glauber's salt 30 parts / liter) were added to the dyeing solution and stirred uniformly. The obtained mixed solution was poured into a Roller dyeing device, and then the cotton fabric was rolled and rolled into a shaft shape after the roller was dyed. This form of cotton fabric was stored at room temperature for 4 hours. Then 'wash the obtained orange dye first with cold water, and then with boiling hot water for 0 minutes', then soap with a boiling non-ionic detergent for 10 minutes, and finally wash it with cold water once. After drying, you can get an orange dye. The dyeing material has excellent dyeing depth and coloring rate. In Example 99, 0.25 parts of the dye prepared in Example 5 was dissolved in 250 ml of water to make a mother liquor. 40 ml of the above mother liquor was placed in a dyeing bottle, and then the cotton fabric was wounded. Then 2.4 parts of Manson were added. Finally, put 2.5 ml of a 32% pure test solution; put the dyeing bottle in a horizontal shaking dyeing machine at 60 ° C and keep it for 60 minutes. Then the obtained golden-yellow dye was washed with cold water and then with boiling hot water. 10 paper size (CNS) A4 size ⑽ x 297 public love) ----- ~-— — — — — — — — — — — — — — — — — I— ^ 1111111 (Please read the notes on the back before filling out this page) 581789 The Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 and the description of the invention. Ionic detergent was soaped for 10 minutes, and finally washed with t for α times, and the golden dye produced after drying had excellent properties, coloring rate, and washing fastness. 衣 实施 例 100 , 取 取。 · 25 parts of the dye prepared in Example 6 was dissolved in 25 ml of water to make a masterbatch. 40 ml of the above mother liquor was placed in a dyeing bottle, then the cotton fabric was wounded, and then Glauber's salt was placed in 2.4 parts. Finally, put 32% soda ash solution in ml / place the dyeing bottle in a 60t horizontal shaking dyeing machine, and keep it for 60 minutes. Then, wash the obtained golden yellow dye first with cold water, then with boiling hot water for 0 minutes, and then Soap with boiling non-ionic detergent 丨 0 minutes, and then use cold Wash it once, and the golden-yellow dye obtained after drying has excellent dyeing depth and coloring rate. Example 101: 0.25 parts of the dye prepared in Example 7 is dissolved in 25 ml of water to make a mother liquor, and the above is taken. Put 40 ml of mother liquor in the dyeing bottle, then put 2 parts of cotton fabric, then 2.4 parts of thenardite, and finally put 2_5 ml of 32% soda ash solution; put the dyeing bottle in a horizontal shaking dyeing machine at 60 ° C, and keep warm 60 minutes. Then the obtained pink dye was washed with cold water, then with boiling hot water for 10 minutes, then with boiling non-ionic detergent soap for 10 minutes, and finally washed with cold water once. The produced pink dyeing material has excellent dyeing depth --------- tx --------- $ · (Please read the precautions on the back before filling this page) 46 581789 A7 — ---- ^ L · __ 15. Description of the invention (柊) Properties and coloring rate. Example 102: 0.25 parts of the dye prepared in Example 8 was dissolved in 25 ml of water to make a mother liquor. 40 ml of the above mother liquor was placed in a dyeing bottle, and then 2 parts of cotton fabric was placed, then 2.4 parts of awning pot, and finally 32% soda ash solution 2.5 ml; put the wooden bottle in a horizontal shaking dyeing machine at 60 C, and hold it for 60 minutes. Then the obtained pink dye is washed with cold water, then with boiling hot water for minutes, and then cleaned with boiling non-ion Soap for 10 minutes, and then wash with cold water again. The pink dyed product after drying has excellent dyeing depth, coloring rate and washing fastness. (Please read the precautions on the back before filling in this Page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW88119501A TW581789B (en) | 1999-11-08 | 1999-11-08 | Reactive dye for fiber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW88119501A TW581789B (en) | 1999-11-08 | 1999-11-08 | Reactive dye for fiber |
Publications (1)
Publication Number | Publication Date |
---|---|
TW581789B true TW581789B (en) | 2004-04-01 |
Family
ID=32960447
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW88119501A TW581789B (en) | 1999-11-08 | 1999-11-08 | Reactive dye for fiber |
Country Status (1)
Country | Link |
---|---|
TW (1) | TW581789B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112759947A (en) * | 2020-12-31 | 2021-05-07 | 湖北丽源科技股份有限公司 | Yellow reactive dye and preparation method and application thereof |
CN116178986A (en) * | 2022-12-30 | 2023-05-30 | 上海雅运新材料有限公司 | Reactive red dye compound and preparation and application thereof |
-
1999
- 1999-11-08 TW TW88119501A patent/TW581789B/en not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112759947A (en) * | 2020-12-31 | 2021-05-07 | 湖北丽源科技股份有限公司 | Yellow reactive dye and preparation method and application thereof |
CN116178986A (en) * | 2022-12-30 | 2023-05-30 | 上海雅运新材料有限公司 | Reactive red dye compound and preparation and application thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW454030B (en) | Reactive bis-, tris- or tetrakisazo dyes containing 2,4-diaminobenzene sulfonic acid as the bis-coupling component, their preparation and use | |
TW466263B (en) | Fiber-reactive black dye mixtures and use thereof for dyeing hydroxy-and/or carboxamido-containing fiber material | |
CN101121827B (en) | Chemically-reactive dyes with thioalkyl-s-triazine reactive group | |
US7326777B2 (en) | Fiber reactive dyestuffs | |
TWI235169B (en) | Fiber-reactive disazo compounds | |
TW581789B (en) | Reactive dye for fiber | |
JP2003518188A (en) | Reactive dye mixture | |
US20090018317A1 (en) | Reactive dyestuffs with alkylthio group and beta-sulfatoethysulfone group | |
US3202650A (en) | Metal-containing reactive azo dyes | |
TW450987B (en) | Phthalocyanine fibre-reactive dyestuffs, methods of their production and their use as fibre-reactive dyestuffs in dyeing and printing process | |
JPH01221460A (en) | Fiber reactive phthalocyanine monoazo compound | |
US2931794A (en) | Complex metal compounds of monoazodyestuffs | |
TW568941B (en) | Monoazo reactive dyes | |
GB2081734A (en) | Improvements in or relating to organic compounds | |
TW483925B (en) | A reactive dye of water-soluble disazo compounds having arylcarboxamide diazo components, preparation thereof and use thereof | |
TW411357B (en) | Reactive azo dyes and their preparation | |
TWI327588B (en) | Reactive red dye composition and application thereof | |
CN102732051B (en) | reactive dyes | |
TWI274776B (en) | Fiber reactive dyestuffs | |
TW400364B (en) | Azo dye mixtures, azo dyes, processes for their preparation, and their use | |
JP3090487B2 (en) | New azo black dye | |
US6762288B2 (en) | Reactive azo dyes | |
TWI326295B (en) | Reactive dyes containing an alkylthio-s-triazinyl reactive grouping | |
TWI597328B (en) | Reactive dye | |
JPS6028875B2 (en) | New reactive chromium complex dyes, their production methods and uses |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4A | Expiration of patent term of an invention patent |