TW575648B - Adhesive components and process for manufacture - Google Patents

Description

75647 A7 B7 V. Description of the Invention (1) Technical Field of the Invention The present invention relates to grafted hydrocarbon resins and oligomer compositions, including (but not limited to) adhesives and tackiness of the grafted grafted composition. Ingredients, and methods of making and using such compositions. Prior art Lower molecular weight resins (usually having a Mη molecular weight of 400 to 1500) can be used in many applications, including tackifiers for adhesives, ink additives, polymer additives, road marking resins, sticky paper glues, and tube wraps. Certain commercial grades of tall pine esters (TOREs) or terpene phenol resins (TPRs) are used to improve the performance of ethylene vinyl acetate (EVA) -based hot melt adhesives (HMAs). However, TOREs suffer from color instability and odor-generating properties at application temperatures. Hydrocarbon resins, especially hydrogenated cycloaliphatic resins, have excellent color stability and odor-generating properties, but exhibit highly omnidirectional properties on polar surfaces, such as polyethylene terephthalate (PET) and Acrylic paint, TOREs are often used. The glue industry recognizes this problem but still needs to address it. Therefore, there is a need for a tacky component or a hydrocarbon resin having enhanced HMA properties without the instability and odor generation associated with TOREs or TPRs. U.S. Patent No. 47 19260 discloses a hot melt adhesive composition having improved adhesion to a substrate such as polyethylene, which includes an amorphous polymer including polypropylene and a polycyclic saturated aliphatic hydrocarbon resin and cis- Graft copolymer of butylene dianhydride. It does not disclose the use of an at least partially hydrogenated aromatic hydrocarbon resin. Further, it is generally known that aromatic resins are generally less compatible with saturated hydrocarbon polymers such as those described in US 47 1 9260 and do not exhibit adhesion to the substrate (this paper is again subject to the Chinese National Standard (CNS) A4 specification ( 210X297 mm) (Please read the precautions on the back before filling out this page), -ιτ Ρ printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs -4- 647647 A7 B7 printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Explain (2) the same advantages as polyethylene. US 3 1 6 1 620 discloses a method for reacting maleic anhydride with thermally prepared hydrocarbon resins. It does not disclose that the resin or oligomer is at least partially hydrogenated prior to reaction with cis-butene dianhydride. EP 0 088 5 1 0 discloses polar synthetic petroleum resins. In the specific examples disclosed therein, the cyclopentadiene oligomer mixture is reacted with a carboxylic acid or anhydride such as phthalic acid or maleic acid and then hydrogenated. The reaction proceeds via the acid group of the unsaturated reaction with the resin oligomer and thus forms an ester group at the point of attachment. The resulting resin products can generally be classified as norbornyl esters. The graft materials disclosed herein are produced via different pathways, i.e., via unsaturated bonds of acids or anhydrides, onto resins as defined herein which are preferably at least partially hydrogenated and more preferably substantially hydrogenated. The performance of hydrocarbon resins, especially hydrogenated aromatic cycloaliphatic resins, on polar surfaces can be improved by modifying these resins to include polar functional properties. Functional components are grafted to conventional hydrocarbon resins and / or resin oligomers and optionally combined with graft resins or graft oligomer materials and other tackifying resins or other tacky ingredients to improve performance and provide performance beyond TOREs And TPRs when used in hot melt and other adhesive formulations. In particular, the applicant has found that adhesive materials incorporating these grafting ingredients have improved compatibility with polar polymers such as EVA copolymers and exhibited good performance on difficult substrates such as coated packaging surfaces performance. SUMMARY OF THE INVENTION A specific embodiment of the present invention is an adhesive composition, which includes: (Please read the precautions on the back before filling out this page), 1T f This paper is applicable to the China National Standard (CNS) A4 specification (210 X 297 mm) -5- 575647 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (3) (a) At least one hydrogenated cyclopentanyl and substituted cyclopentyl-2 oligomerization. Wherein the oligomers of cyclopentadiene and substituted cyclopentadiene are substantially free of norbornyl ester groups and / or monoalkyl cis-butene including at least one after grafting with a graft monomer Diacids, anhydrides or derivatives thereof, or / 3-alkyl substituted propionic acids or derivatives thereof; (b) (i) D monomers; (U) C9 monomers; (m), C5 monomers and C9 Monomers; or (iv) oligomers of cyclopentadiene and / or substituted cyclopentadiene and monomers; or (c) any combination of (a) and (b). The oligomer preferably contains less than 1% olefin protons before grafting. A method for grafting oligomers is also disclosed. DETAILED DESCRIPTION Grafted hydrocarbon resins As used herein, grafted hydrocarbon resins, oligomers, and / or resin materials, or combinations thereof, indicate that they have been combined, contacted, and / or reacted with a grafted monomer. Grafting is a method of combining, contacting, or reacting a hydrocarbon resin, an oligomer and / or a resin material with a graft monomer material. Grafting hydrocarbon resins, oligomers, and / or resin materials, or combinations thereof, to include at least some polar functionality produces useful ingredients such as tacky formulations, especially HMA formulations. These formulations are often designed for use with polar polymers such as EVAs, ethylene methyl acrylates (EMAs), polyacrylates (PAs), polyfluorenyl acrylates (PMAs), and ethylene alkyl acrylates. Performs well on substrates such as PET, recycled paper, cardboard, and acrylic paint and on other substrates such as wood, glass, ceramics, asphalt, concrete, and metal. Therefore, the specific embodiments of the present invention include grafted and ungrafted hydrocarbon resins ((Please read the precautions on the back before filling this page). ·, 11 # 1. This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) -6-575647 A7 B7 V. Description of the invention (Class 4) and oligomers (Class) and compositions and mixtures thereof. Specific embodiments also include (but are not limited to): adhesives or tacky ingredients, including (1) grafted hydrocarbon resins; (ii) grafted oligomers, (lii) grafted oligomers + Graft resin (class), (iv) Grafted hydrocarbon resin + ungrafted resin (class), (V) Grafted hydrocarbon resin + ungrafted oligomer, (Vi) Grafted hydrocarbon resin + grafted oligomer (Vii) grafted oligomer + ungrafted oligomer or (V111) grafted hydrocarbon resin + grafted oligomer + ungrafted resin (type) and one or more other suitable combinations thereof. The specific embodiments described herein also include methods of making and using the foregoing materials. Suitable hydrocarbon resins that can be grafted include: aliphatic hydrocarbon resins, at least partially hydrogenated aliphatic hydrocarbon resins, aliphatic / aromatic hydrocarbon resins, at least partially hydrogenated aliphatic aromatic hydrocarbon resins, cycloaliphatic hydrocarbon resins , At least partially hydrogenated cycloaliphatic resin, cycloaliphatic / aromatic hydrocarbon resin, at least partially hydrogenated cycloaliphatic / aromatic hydrocarbon resin 'at least partially hydrogenated aromatic hydrocarbon resin, polyterpene resin, terpenes Ene-phenol resin 'and a mixture of two or more thereof. Turpentine can also be grafted. Preferably, the resin is at least partially hydrogenated, more preferably substantially hydrogenated, and more preferably contains aromatic monomers. Another specific embodiment of the graft oligomer is a kind including a graft oligomer (dimer, trimer 'tetramer, pentamer, hexamer type, and heptamer and octamer as required Material), preferably from petroleum distillates boiling in the range of 30-2 10 ° C. The oligomers can be obtained by any suitable method and are often obtained as by-products of resin polymerization, whether by thermal or catalytic reactions. Oligomers can be obtained from oligomerized and then grafted with the appropriate DCPD, (: 5 and / or C9 monomer feed (the following paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm)) (please Read the notes on the back before filling this page) Order the method of printing 575647 A7 B7 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (5). The appropriate oligomer flow is between 1 30-500. It is more preferably between 130-410, more preferably between 130-350, more preferably between 130-270, more preferably between 200-350, and more preferably a molecular weight between 200-320 ( Mn). In one embodiment, the oligomer includes cyclopentadiene and substituted cyclopentadiene monomers and may further include a C9 monomer. In another embodiment, the oligomer includes a C5 monomer And may further include a C9 monomer. Other monomers may also be present, including (: 4-(: 6 mono- and di-olefins and terpenes. The oligomers may also include C9 monomers alone. In each specific embodiment , Preferably at least partially hydrogenated before grafting with the grafting monomer, more preferably substantially hydrogenated oligomers. Appropriate individual cyclopentane Specific examples of diene and substituted cyclopentadiene monomers (including DCPD), C9 monomers and C5 monomers are described below. Suitable oligomers may also include one or more of the preferred as described herein. Mixture of oligomer materials. In a preferred embodiment, the hydrocarbon resin and / or oligomer has 1-60%, more preferably 1-40%, more preferably 1-20%, more preferably 1-15%. , Better 10-20%, better 15-20%, better 1-10%, and better 5-10% aromatic content, among which any upper limit and any lower limit of aromatic content can be combined into aromatic content In a specific embodiment, the hydrocarbon resin to be grafted has a softening point of 10-200 ° C, more preferably 10-160 ° C, more preferably 60-1 30 ° C, and more preferably 90- 1 30 ° C, better 80-1 20 ° C, better 80-1 50 ° C, and better 90-1HTC, in which the upper limit and any lower limit of any softening point can be combined into a better range of softening point. Softening The point (° C) is preferably measured as the ring and ball softening point according to ASTM E-28 (Revised 1996). If used herein, the aromatic content and olefin content are measured by 1H-NMR such as from directly 400 MHz (frequency equivalent)) The size of the magnetic paper is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) _ 8-(Please read the precautions on the back before filling this page) Clothing _ Order printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperative A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (6) 1H-NMR spectrum measurement obtained from a field intensity spectrometer. Aromatic content is the integral of aromatic protons to the total number of protons. The olefin proton or olefin proton content is the integral of the olefin protons to the total number of protons. The resin and / or oligomer is preferably at least partially hydrogenated and more preferably substantially hydrogenated. As used herein at least partially hydrogenated indicates that the material contains less than 90% olefin protons, more preferably less than 75% olefin protons, more preferably less than 50% olefin protons, more preferably less than 40% olefin protons, and even less Less than 15% olefin protons, more preferably less than 10% olefin protons, more preferably less than 10% olefin protons, more preferably less than 9% olefin protons, more preferably less than 8% olefin protons, more preferably less than 7% Olefin protons, and more preferably less than 6% olefin protons. As used herein, substantially hydrogenated means that the material after hydrogenation (and before reaction with the grafting monomer) contains less than 5% olefin protons, more preferably less than 4% olefin protons, and more preferably less than 3% olefin proton, more preferably less than 2% olefin proton, more preferably less than 1% olefin proton, more preferably less than 0.5% olefin proton, more preferably less than 0.1% olefin proton, and more preferably less than 0.05% Olefin protons. The degree of hydrogenation is typically performed to minimize and preferably avoid the hydrogenation of aromatic bonds. In a preferred embodiment in which the resin and / or oligomer is substantially hydrogenated, instead of forming a copolymer (resin / oligomer and graft monomer), the graft monomer is attached to the tree / Oligomer backbone due to the lack of terminal olefin linkages on the substantially hydrogenated resin / oligomer (as shown by the preferred low olefin proton measurement). As stated, the resins and oligomers preferably include one or more aromatic monomers. The data below show that aromatic materials produce better performance in adhesive compositions that include an aromatic-containing graft material. In addition, some grafting monomers, such as cis-butene dianhydride, have good solubility in aromatic-containing materials, and the paper size is applicable to China National Standard (CNS) A4 (210X 297 mm) -9- (Please read the precautions on the back before filling out this page) Clothing ·, 11 • 1 575647 Α7 Β7 Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) May allow more uniform sentences and may avoid Undesirable by-products during the grafting reaction. Monomers Preferred graft monomers include any unsaturated organic compound containing at least one olefinic bond and at least one polar group (e.g., carbonyl), including unsaturated acids and anhydrides and derivatives thereof. Preferably, the organic compound contains ethylenic unsaturation conjugated with a carbonyl group (-C = 0) and preferably contains at least one ^, / 3 olefin bond. Preferred grafting monomers include acids, alcohols, anhydrides, amines, amines, and derivatives thereof. Examples include carboxylic acids, fluorenyl halides or anhydrides, alcohols (phenols, monoalcohols, glycols, and polyalcohols), and derivatives thereof. Representative acids and acid derivatives include carboxylic acids, anhydrides, fluorenyl halides, esters, fluorenamines, fluorenimines and their salts, both metal and non-metal. Examples include cis-butenedioic acid, trans-butenedioic acid, acrylic acid, methacrylic acid, itaconic acid, aconitic acid, citraconic acid, dicycloheptenedipic acid, tetrahydrophthalic acid, crotonic acid, α -Methylcrotonic acid, and cinnamic acid. Maleic anhydride is a particularly preferred grafting monomer. Specific examples include, itaconic anhydride, citraconic anhydride, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, glycidyl acrylate, maleic acid monoethyl ester, cis-butyl Diethyl maleate, Dibutyl maleate, Dimethyl maleate, Dimethyl maleate, Dimethyl maleate, Diethyl maleate , Acrylamide, methacrylamide, maleimide monoamine, maleimide diamine, maleimide-N-monoethylammoniumamine, maleimide Diacid_ν, Ν-diethylamidamine, maleic acid-N_monobutylamidamine, maleic acid_N, Ν_ (Please read the notes on the back before filling this page ), ... !! f This paper is suitable for Chinese National Standards (CNS) A4 specifications (mm) -10- 575647 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (9) Some feeds, The refinery stream preferably removes impurities, usually by fractional distillation and processing purification. In some embodiments, the C5 feed stream may include at least some (preferably less than 2% by weight) cyclopentadiene (CPD) and substituted cyclopentadiene (eg, methylcyclopentadiene) components . These components are optionally separated from the monomer stream by hot impregnation, where the feed stream is heated to a temperature between 100 ° C and 1 60 ° C, preferably between 100 ° C and 1 50 ° C. Between 0.5 and 6 hours, the DCPD monomer is then separated to reduce the cyclopentadiene and / or dicyclopentadiene content in the monomer stream to preferably less than 2% by weight. Low temperature hot dipping is preferred in order to limit the co-dimerization of cyclodiene (cyclopentadiene and methylcyclopentadiene) and (: 5 linear conjugated diene (isoprene and pentadiene 1 , 3 cis · and trans-). The hot impregnation step is preferably dipolymerized cyclopentadiene and substituted cyclopentadiene to make it easier to separate from the C5 monomer stream. During fractionation and, if performed, heat After impregnation, the feed is preferably subjected to distillation to remove cycloconjugated diolefins (which are gel precursors) (cyclopentadiene and methylcyclopentadiene to be removed, such as dimers, trimers, etc. [0023] Examples of C5 monomer streams are steam cracking petroleum streams that boil in the range of -10 ° C to 100 ° C. Examples of commercially available samples of C5 monomer feed include stone from Lyondell Petrochemical Company of Houston, Texas Naphtha petroleum 3 pentadiene, general pentadiene concentrated liquid or higher pentadiene concentrated liquid, both can be obtained from Holland Hoogvilet Shell Chemical BV. Resin polymerization feed can also contain Cs-Cn) aromatics Hydrocarbon monomers (referred to herein as C 9 monomers) such as styrene, indene, derivatives of styrene, derivatives of indene, and Compounds. Particularly preferred aromatic olefins include styrene, α-methylstyrene, / 3-methylstyrene, indene, methylindenes and butenyltoluenes. An example of the C9 monomer flow is at -10 ° C to 21 ° C (if the C5 monomer and DCPD composition are not 1 paper size, the Chinese national standard (^: milk) 8 size 4 (210, 乂 297 mm) ~ ^ -12-(Please read the precautions on the back before filling out this page} • Pack. ， 11 Printed by Jilin Jilang Intellectual Property Bureau Employee Consumption Cooperative 575647 A7 B7 V. Description of Invention (1〇), 1 3 5 ° C to 210 ° C) boiling steam cracking petroleum stream. Examples of commercial C9 monomer feeds include LRO-90 from Lyondell Petrochemical Company of Houston, Texas, DSM C9 resin from DSM, Geleen, Netherlands Incoming materials, Ro_60 and RO-80 from Mich. Midland Dow Chemical Co., and Resin oil 60-L from T e 1. In addition, the non-polymerizable ingredients in the feed may include saturated hydrocarbons such as pentane, cyclopentane, or 2-methylpentane that can be codistilled with unsaturated ingredients. This monomer feed may be mixed with other daggers or Copolymerization of olefins or dimers. However, it is preferred to purify the feed to remove adversely affecting polymerization or Unsaturated materials (eg, isoprene) that cause undesired colors. This is usually done by fractional distillation. In a specific embodiment, the polymerization is performed using a Fridt-Craft polymerization catalyst such as on a carrier Lewis acids with or without support (for example, boron trifluoride (BF3), a complex of boron trifluoride, aluminum trichloride (AlCh), a complex of aluminum trichloride, or an alkyl aluminum halide , Especially chloride). Appropriate reaction conditions for Frid-Quarft polymerization include a temperature of -20 ° C to 100 ° C and a pressure of 100-2000 kPa. In a specific embodiment, C5 and (: 9 monomers are polymerized by this method. Typically, the feed stream includes 20-80% by weight monomer and 20-80% by weight solvent. Preferably, the feed stream includes 30-70% by weight monomer and 30- 70% by weight solvent. More preferably, the feed stream includes 50-70% by weight monomer and 30-50% by weight solvent. The solvent may include an aromatic solvent, which may be toluene, xylene, other aromatic solvents, aliphatic Solvent and / or one or more mixtures thereof. The solvent is preferably recovered. The solvent may include Polymerizable ingredients. The solvent usually contains less than 250 ppm water, preferably less than 1000 ppm water, and most preferably less than 50 ppm water. This paper size is applicable to China National Standard (CNS) A4 specifications (210X297) (Chu) ~ -13- --------- batch clothes ------, 玎 ------ ^ (Please read the precautions on the back before filling this page) 575647 A7 B7 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives V. Invention Description (11) In another specific embodiment, the feed stream includes 30-95% by weight (: 5 monomers, as described above and 5-70% by weight including at least A co-feed selected from the group consisting of pure monomers, c9 monomers, and terpenes. Preferably, the feed stream comprises about 50-85% by weight monomers and about 15-50% by weight co-feeds, including at least one member selected from the group consisting of pure monomers, C9 monomers, and terpenes. Typically, the obtained hydrocarbon resin has a number average molecular weight (Mη) of 400-3000, a weight average molecular weight (Mw) of 500-6000, a z-average molecular weight (Mz) of 700-1 5,000, and a polydispersity between 1.5 and 4. (Pd), as measured by Mw / Mn. As used herein, molecular weight (number-average molecular weight (Mη), weight-average molecular weight (Mw), and z-average molecular weight (Mz)) are penetrated by using a Water 1 50 gel that uses differential refractive index detection. Chromatograph and gel size analysis using polystyrene calibration standards. The samples were operated in tetragas sulfan (THF) (45 ° C). Molecular weights are reported as polystyrene-equivalent molecular weights and are usually measured in grams per mole. The monomer feed can be copolymerized with a C 4 or C 5 olefin or its olefin dimer as a chain transfer agent. A chain transfer agent of 40% by weight (preferably up to 20% by weight) may be added to obtain a resin having a lower and narrower molecular weight distribution than that obtained from a monomer used alone. In a way, the chain transfer agent stops the growth of the growing polymer chain by terminating the chain, and regenerates the starting position of the polymer. Ingredients, which serve as chain transfer agents in the reaction, include, but are not limited to, 2-fluorenyl- 丨 -butene, 2-methyl-2-butene, or dimers or oligomers of these kinds. The chain transfer agent may be added to the reaction in pure form or diluted in a solvent. DCPD resins and / or oligomers (also known as CDP oligomers) can be fed from an unsaturated monomer that includes DCPD and / or substituted DCPD (please read the precautions on the back before (Fill this page) Clothing. The size of the paper used in the edition is in accordance with Chinese National Standard (CNS) A4 (210X 297 mm) -14- 575647 A7 B7 Obtained or derived by polymerization. In a specific embodiment, the feed also includes an aromatic monomer as previously described. In this embodiment, (a) the DCPD stream is preferably a steam cracking petroleum distillate boiling in the range of 80-200 ° C (more preferably 140 ° C to 200 ° C), comprising cyclopentadiene and Dimers and co-dimers of methyl derivatives thereof, together with (b) C9 monomers, are preferably a steam cracking petroleum distillate boiling at 150-200 ° C, including methylstyrene, ethylene Toluene'indene and methylindene with other C9 and C !. A mixture of aromatic hydrocarbons at a weight ratio of U: b) between 90:10 and 50:50 in a batch polymerization reactor at a pressure of 9.8xl05-2CU105 bar (more preferably 9.8x10M1 · 7x105 bar) Under heating to 1 60-320T: After 1.2 to 4 hours (more preferably 1.5 to 4 hours). Where oligomer content is not required, the resulting polymerization product can be steamed to remove inert, unreacted, and low molecular weight oligomerization components to produce a resin having a softening point in the range of 80-1 20 ° C. As used herein, oligomers of cyclopentadiene include cyclopentadiene oligomers produced as a byproduct of the polymerization of a C5 monomer stream and oligomers produced as a byproduct of the polymerization of a CDPD stream both. Methods for making oligomers are not limited to those described herein. In a specific embodiment, the resin is preferably obtained or derived by thermal polymerization from a feed comprising a c5 monomer and a C9 monomer as previously described. In the specific embodiment, (a) c5 monomer is preferably a steam cracking petroleum distillate boiling in the range of 80-200 ° C, and (b) C9 monomer is preferably a 150-200 ° C boiling boiling steam cracked petroleum distillates, including α-methylstyrene, vinyltoluene, indene, methylindene and other C8-Cl. Mixtures of aromatic hydrocarbons in a weight ratio (a: b) between 90 ·· 10 and 50:50 in a batch polymerization reactor at 9.8 & 1 05- 20 \ 105 bar (more preferably 9.8 \ 105- 11.7 \ 105 bar) heating (please read the precautions on the back before filling this page)-order f This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -15- 575647 A7 B7 V. Description of the invention (13) to 1 60-3 20 ° C, after 1.2 to 4 hours (more preferably 15 to 4 hours). Where oligomer content is not required, the resulting polymerization product can be steamed to remove inert, unreacted, and low molecular weight oligomerization components to produce a resin having a softening point in the range of 80 to 120 ° C. The products of the polymerization process include resins and oligomers (dimers, trimers, tetramers, pentamers, hexamers) including the monomers (classes) of the feed, and heptamers and octamers selected as required Polymer) oligomer by-products. If used in the following, the resin material means resin, oligomer, or a mixture of the two. In a specific embodiment in which the oligomer by-product is produced by thermal polymerization of DCPD and substituted DCPD, the oligomer is typically a (preferably hydrogenated as described below) CDP and methyl CDP with a low content of Non-cyclic C5 diene such as a complex mixture of diels Alder trimer and tetramer of pentadiene-1,3 and isoprene. The resin material is then preferably hydrogenated to reduce staining and improve color stability. Any method known for the catalytic hydrogenation of resin materials can be used. In particular, the methods disclosed in US 5 1 7 1 793, US 4629766, US 5502104 and US 4328090 and WO 95/1 2623 are suitable. Excluded hydrotreating conditions include a temperature range of 100-350 ° C and a hydrogen pressure between about five atmospheres (506 kPa) and 300 atmospheres (and up to 400 atmospheres), for example, 10-275 atmospheres (1 0 1 3-27579 kPa). In a specific embodiment, the temperature is in a range including 1 80-330 ° C and the pressure is in a range including 1 5 1 95-20260 kPa hydrogen. The volume ratio of hydrogen to feed in the reactor under standard conditions (25 ° C, 1 atmosphere (101 kPa) pressure) typically ranges from 20: 1 to 200: 1; for water-white resin, 100: 1- 20Q: 1 is better. The hydrogenated product can be stripped to remove low molecular weight by-products and any solvents. This oligomerization by-product is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) at this paper scale. _-(Please read the precautions on the back before filling this page) Preparation 575647 A7 _ B7_ V. Description of the invention (M) 25 0-400 ° C Boiling and preferably substantially hydrogenated low viscosity almost colorless liquid. The hydrogenation of resin materials can be achieved by melt or solution-based methods. Batch or more generally continuous processes. The catalysts used for the hydrogenation of hydrocarbon resins are typically monometallic and dimetallic catalyst systems based on groups 6, 8, 9, 10, or 11 elements on a support. Catalysts such as nickel on a carrier (such as nickel on 'oxidized metal' nickel on charcoal, nickel on gravel, nickel on algae, etc.), palladium on a carrier (such as palladium on silica, palladium on charcoal , Palladium on magnesium oxide, etc.) and copper and / or zinc on the support (such as copper chromite on copper and / or manganese oxide, copper and zinc on alumina, etc.) are good hydrogenation catalysts . The support material is typically composed of such porous inorganic refractory oxides such as silica, magnesia, silica-magnesia, hafnium oxide, silica-oxidized pins, titanium oxide, silica-titanium oxide, alumina, silica- Alumina, alumina-silicate, etc., and a carrier containing r-alumina are excellent. Preferably, the support is substantially free of crystalline molecular coating materials. Mixtures of the foregoing oxides are also contemplated, especially when homogeneous preparations are possible. Useful carrier materials include those disclosed in U.S. Pat. Nos. 4,866,030, 4,846,961, 45,004 24, and 4,849,093. Suitable supports include alumina, silica, carbon, MgO, TiCh, Zr02, Fe203, or mixtures thereof. Another suitable method for hydrogenating resin materials is described in EP 0082726. EP 00 82726 describes a catalytic or thermal hydrogenation process using a nickel-tungsten catalyst on an r-alumina support, in which the hydrogen pressure is L47X10M.96X 1 07 bar and the temperature is in the range of 250-330 ° C. The reactor mixture can be flashed and further separated after hydrogenation to recover the hydrogenated resin material. In a specific embodiment, the paper size is applicable to the Chinese National Standard (CNS) 8-4 specification (21〇 > < 297 mm) (Please read the notes on the back before filling out this page)-Order f Printed by the Consumers 'Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -17- 575647 A7 B7 V. Description of the invention (15)' Steam distillation can be used to Isolation of oligomers is preferably performed at temperatures not exceeding 3 2 5 t: resin temperature. In a specific embodiment, the catalyst comprises nickel and / or cobalt and one or more molybdenum, tungsten on one or more oxide scale or gravel carrier, wherein the amount of nickel oxide and / or cobalt oxide on the carrier In the range of 2-10% by weight. The amount of tungsten oxide or molybdenum on the support after preparation ranges from 5 to 25% by weight. Preferably, the catalyst comprises 4-7 wt% nickel oxide and 18-22 wt% tungsten oxide. This method and suitable catalysts are disclosed in more detail in U.S. Patent No. 5 8 20749. In another embodiment, the hydrogenation can be performed by using the method and catalyst described in U.S. Patent No. 46 29766. In particular, a nickel-tungsten catalyst on 7-alumina is preferred. In a specific embodiment, the oligomer is stripped from the resin prior to hydrogenation. In this embodiment, the oligomer is preferably hydrogenated before grafting. In another embodiment, the oligomer is hydrogenated with the resin and then stripped from the resin to produce a hydrogenated resin and a hydrogenated oligomer. In another specific embodiment, at least some of the oligomers are stripped before hydrogenation and at least some of the hydrogenated oligomers are stripped after hydrogenation. In yet another specific embodiment, the hydrogenated resin / oligomer product can be further processed together into a single mixture as described below. In yet another specific embodiment, the oligomer may be derived from any suitable source and hydrogenated (if necessary) prior to grafting such that the oligomer is typically at least partially hydrogenated and preferably substantially hydrogenated prior to grafting . At least a part of the obtained resin material of the graft resin material 1 is preferably derived from a paper standard such as the above-mentioned paper standard applicable to China National Standards (CNS) A4 specifications (210X297). (Please read the precautions on the back before filling this page) ， 1Τ f Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 575647 A7 _ B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Method of Invention Description (16), which can then be combined and / or contacted with the graft monomer , Typically under appropriate reaction conditions and in a suitable mixing device. In a preferred embodiment, the reaction is performed without significant shear. In the specific embodiment according to the foregoing, the 'resin and oligomer can be grafted separately or simultaneously, and if separately, the grafted oligomer can then be optionally combined with a grafted resin, a non-grafted resin, or any of the above The other suitable resins, tacky ingredients or compositions are then mixed. The grafting of the graft monomer preferably takes place in the presence of a free radical initiator selected from the group consisting of organic peroxides, organic peresters, and azo compounds. Examples of such compounds include benzamyl peroxide, dichlorobenzyl peroxide, dicumyl peroxide, di-tertiary-butyl peroxide, 2.5-dimethyl- 2,5-bis (peroxybenzoate) hexyne-3,1,4-bis (tertiary-butylperoxyisopropyl) benzene, lauryl fluorenyl peroxide, peracetic acid tertiary-butane Ester, 2.5-dimethyl-2,5-di (tertiary-butylperoxy) hexyne-3,2,5-dimethyl-2.5-di (tertiary-butylperoxy) Hexane, tert-butyl perbenzoate, tert-butyl perphenyl acetate, tert-butyl perisobutyrate, tert-butyl per-octanoate, tert-butyl Tertiary-butyl valerate, cumene pervalerate 'tertiary-butyl hydroperoxide, tertiary-butyl perethyl acetate, azoisobutyronitrile, and azo Dimethyl isobutyrate. The peroxide preferably has a half-life of about 6 minutes and volatile non-aromatic decomposition products at 1 60 ° C and these minimize color formation. Preferred peroxides include di-tertiary-butyl peroxide and 2,5-difluorenyl-2,3-di (tertiary-butylperoxy) hexane. The amount of perfluorinated peroxide typically depends on the weight of the graft monomer. In a specific embodiment, the weight ratio of grafted monomer: peroxide in the reaction mixture can be between 1 and (please read the precautions on the back before filling this page). Order f This paper size applies Chinese national standards (CNS) A4 specifications (210 X 297 mm) _ 19 575647 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention (17) 20, more preferably between about 1 and 10, more It is preferably between about 1 and about 5, and even more preferably about 4. The grafting monomer can be combined with the resin material at 50-200 ° C, more preferably between 70-1 50 ° C, more preferably between 70-1 25 1 and even more preferably 140- 1 80Ϊ: between, more preferably between 1 40- 1 80 ° C, more preferably between 1 5 5-1 65 ° C or between 165-175 ° C. Temperature and pressure are typically one atmosphere but Use higher pressure if needed. In a specific embodiment, the reaction temperature is from 1 70 to 1 85 ° C. In another preferred embodiment, the grafting reaction is greater than 9 ° C, more preferably between 90 ° C and any of the above temperature limits, more preferably between 90 ° C and 150 ° C, and more preferably 9 (temperature between TC and 145 ° C. Generally, the lower limit of the reaction temperature is determined by the softening point of the resin, and it is preferred to perform the grafting reaction at a temperature above the softening point of the material to be grafted. Grafting can be combined Monomer so that the weight ratio of monomer: resin material grafted in the reaction mixture is less than 1, more preferably less than 0.5, more preferably less than 3: 10 and more preferably less than 3: 20. In a preferred embodiment, the reaction The mixture is maintained in a homogeneous state. The reaction mixture is preferably agitated or vigorously stirred. During the reaction, the free radical initiator is added all at once or is preferably combined with the resin material-graft monomer reaction mixture in a continuous or semi-continuous mode. During the reaction The residence time of the zone is preferably less than 75 minutes, more preferably less than 60 minutes, and even more preferably between 30-60 minutes. In specific embodiments where only the oligomer is grafted, the reaction temperature is preferably 50- Between 200 ° C, more preferably 70- 1 50 ° C, more preferably 70- 1 2 Between 5 ° C, more preferably between 140-1 80 ° C, more preferably between 140-1 80 ° C, more preferably between 15 5-1 65 ° C, and more preferably about 160 ° C In a specific embodiment, the reaction temperature (please read the precautions on the back before filling this page). Order «丨 · This paper size applies to China National Standard (CNS) A4 (210X297 mm) -20-575647 A7 B7 V. Description of the invention (18) The degree is 17 0-1 8 5 ° C. In another preferred embodiment, the grafting reaction occurs at a temperature greater than 9CTC, more preferably at 90 ° C and any of the above. Between temperature systems, more preferably between 90 ° C and 150 ° C, more preferably between 90 ° C and 145 ° C. Other preferred ranges may include any of the upper and lower temperature ranges described in this paragraph. The amount of grafting monomer added typically depends on the amount of oligomer. Better, oligomer: Molar ratio of grafting monomer is between 5 and 0.2, more preferably between 2 and 0.5, and even better Between about 1.5 and 0.67 and more preferably about 1. Thereafter, the ungrafted oligomers are stripped from the product and selectively recycled to the reaction zone. The resulting grafted oligomers typically have a pH in the range of 0- 120 ° C, better 25- 1 20 T: between, more preferably between 50-120 ° C and even more preferably between 80-11 (softening point between TC and 4-10 Garden color. Garden color, as used in this article, is used ASTMD-6166 measurement. The grafted oligomer product can then be recombined with the resin (grafted or ungrafted), derived from it with other resins, polymers, and / or other materials or combined and formulated into an adhesive Materials. In specific embodiments where only the resin is grafted, the reaction temperature is preferably between 50-200 ° C, more preferably between 70-15CTC, more preferably between 70-1 25 t, and more preferably 140-1 80 ° C, more preferably 140-1 80 ° C, more preferably 1 65-1 75 ° C, and more preferably about 170 ° C. In another preferred embodiment, the grafting reaction occurs at a temperature greater than 90 ° C, more preferably between 90 ° C and any of the above mentioned upper temperature limits. The amount of grafting monomer added typically depends on the amount of resin. The weight of the graft monomer: resin in the reaction mixture is preferably less than 1: 5, more preferably less than 1:10, more preferably less than 1:20, and even more preferably about 1:40. Generally, grafting causes the resin to have a softening point of less than 10 ° C, more preferably less than 5 ° C, and results in a graft resin having a color between 1-6 Garden. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Order f Printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economic Affairs 575647 Α7 Β7 V. Description of the invention ( 19) In another embodiment, the oligomer is not stripped from the resin product, and the resin and the oligomer are grafted simultaneously. The reaction conditions are similar to the aforementioned graft resin, but the weight ratio of graft monomer: resin material is generally kept below 0.5, more preferably below 0.25 and more preferably below 3:20. Upon completion of the grafting, the material may be further stripped if necessary to produce a resin at the desired softening point and / or remove unreacted oligomers. Isolation of the graft oligomer 'from the graft resin can also be performed if necessary, but the product can be used without further processing. In many specific examples including graft resins and graft oligomers, the weight ratio of graft oligomers: graft resin in the resin material will be greater than 0.005, and more preferably greater than 0.01. 'Better is greater than 0.02, more preferably greater than 0.05, and more preferably greater than 0.1. The grafting of the resin material can also be performed via a solution path, in which the resin material is dispersed in a solvent and combined with the graft monomer, contacts and / or reacts. Additionally or alternatively, the ' graft monomer may be dispersed in a solvent before being added to the resin material. These pathways allow lower reaction temperatures (as low as 80 ° C or 100 ° C) and allow the selection of different peroxides with a 6 minute half-life at low reaction temperatures. Suitable solvents include, but are not limited to, aliphatic solvents, cycloaliphatic solvents, aromatic solvents, and aromatic-aliphatic solvents. Typical examples include benzene, toluene, xylene, chlorobenzene, n-pentane, n-hexane, n-heptane, n-octane, n-decane, isoheptane'isodecane, isooctane, cyclohexane, alkane Cyclohexane, and a combination of two or more thereof. The Xianxin grafting monomer is grafted to the resin material via an olefin bond such as an α, / 5 olefin bond of the graft monomer. By using this route to graft oligomers, the formation of norbornyl ester groups in the graft resin material is minimized and preferably avoided. Therefore, the obtained graft resin material has substantially no norbornyl ester group, and the Chinese National Standard (CNS) A4 specification (210X297 mm) is applied to this paper size (please read the precautions on the back before filling this page). -ιτ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 575647 A7 _ B7 V. Description of the invention (20) Yes, it preferably contains less than 0.5% by weight, more preferably less than 0.1% by weight, and more preferably less than 0.05% by weight , More preferably less than 0.01% by weight of norbornyl ester group. The obtained graft oligomer and / or graft resin is preferably at least one of (i) monoalkylmaleic acid, anhydride or derivative thereof, or (Π) / 3-alkyl-substituted propionic acid Or its derivatives. The reaction product of the resin material and the graft monomer or the product of a combination of the resin material and the graft monomer may also include some oligomers of the graft monomer, which may or may not be removed before the final composition is formulated. The obtained graft resin material preferably has a temperature between 15-210 ° C, more preferably 15-17 ° C, more preferably 65-140 ° C, more preferably 65-13 (TC, more preferably 80-1 20 ° C, more preferably 90-1 to 10 ° C, and more preferably a softening point of about 85-1 to 10 ° C. The graft resin material preferably has a temperature of less than 120 ° C, more preferably less than 11 ° C, and more preferably 25 to 100. (: between, more preferably between 60 and 100 ° C, more preferably between 60 and 80 ° C, and more preferably between 35 and 70 ° C. Differential scanning calorimetry (DSC, ASTMD 34 1-8 8) is used to measure Tg. The obtained graft resin material preferably has more than 10, more preferably more than 12, more preferably more than 15, and more preferably more than 16 , More preferably more than 17, more preferably more than 18, more preferably more than 19, more preferably more than 20, more preferably more than 25 saponified saponins (mg KOH / g resin material). The obtained graft material preferably has more than 10, more preferably greater than 15, and more preferably greater than 20. In a specific embodiment, the graft oligomer material has between 50 and 0.5, more preferably between 10 and 2, and more preferably between 5 and Between 2, more preferably between 1.5 and 0.67, and more preferably about 1 oligomers: the molar ratio of graft monomer In some embodiments, the weight ratio of the grafted monomer: resin in the graft resin product is better than less than 1, in other embodiments between 0.00 1 and 1, and in other embodiments 0. · Between 0 1 and 1, in other specific embodiments between 0.0 1 and (please read the precautions on the back before filling out this page) Order P. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employees' Cooperatives This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) -23 575647 A7 B7 V. Description of the invention (21) Between 0 · 3, in other specific embodiments between 0 · 002 and 1 and in other specific embodiments Between 0.1 and 1 in other specific embodiments, between 0.33 and 1 in other specific embodiments, and between 0.1 and 0.2 in other specific embodiments, where the preferred range can be included in any of the descriptions in this paragraph The resin blend including the graft resin disclosed herein includes: (1) a portion of the grafted resin material stream in which only a portion of the resin material is grafted in a particular stream (Produce a mixture of grafted and ungrafted resin materials ); And (11) Blends of partially and fully grafted resin material streams and other tackifying resins. Suitable examples of other tackifying resins include: aliphatic hydrocarbon resins, at least partially hydrogenated aliphatic hydrocarbon resins , Aliphatic / aromatic hydrocarbon resin, at least partially hydrogenated aliphatic aromatic hydrocarbon resin, cycloaliphatic hydrocarbon resin, at least partially hydrogenated cycloaliphatic resin, cycloaliphatic / aromatic hydrocarbon resin, at least partially hydrogenated Of cycloaliphatic / aromatic hydrocarbon resins, aromatic hydrocarbon resins, at least partially hydrogenated aromatic hydrocarbon resins, polyterpene resins, terpene-phenol resins, turpentine, rosin acid, and grafted monomers Resin and any one or more of them. Suitable resins also include other resins having polar functional properties, whether or not produced by the methods described herein or other suitable methods. For example, a specific embodiment is a composition including 0.1-9% by weight of a graft resin material and 1-99.9% by weight of another resin. Other specific embodiments include a graft resin material between 0.1-50% by weight, a graft resin material between 0.30% by weight, and a graft resin material between Q · 1_20% by weight, '1-25% by weight. Grafting resin material, in the range of 1 -1 5 wt.%. The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm). (Please read the precautions on the back before filling this page.) Order the Ministry of Economy Printed by the Consumer Cooperative of the Property Bureau 575647 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ____ B7 V. Description of the invention (22) Resin materials, grafted resin materials between 1-10% by weight, between 5-10% Graft resin material between weight, and graft material between 10-3 0% by weight. In a preferred embodiment, the resin material includes graft resin and graft oligomer, between 0. 1 and 50% by weight Grafting oligomers, more preferably 0.1 to 30% by weight of grafted oligomers, more preferably 0.1 to 20% by weight of oligomers, more preferably 0.1 and 10% by weight of grafted oligomers , More preferably between 1 and 30% by weight, more preferably Grafting oligomers between 1 and 20% by weight, and more preferably between 1 and 10% by weight, based on the total weight of the resin blend. A preferred range also includes any of those described in this paragraph Between the upper limit and any lower limit. Any of the foregoing specific embodiments mixed in adhesive components and compositions can be combined with other adhesive components and formulated into pressure-sensitive adhesives for use in, for example, tapes, labels, and paper impregnation applications. , HM As, or pressure-sensitive adhesive. HM A applications include woodworking, packaging, binding or diapers. The specific embodiments described herein can also be formulated as sealants, rubber compounds, pipe wraps, carpet linings, pressure-sensitive adhesives. Agents, road signs, and / or tire compositions. When in the case of HM As, these compositions can be used directly without further dilution or they can be diluted to a suitable solvent to form solvent-based adhesives (SBAs) or dispersions. Resin emulsions that form water-based adhesives (WBAs) in water. Any of the foregoing embodiments can be combined or formulated into adhesives that include polar polymers. When used herein, polar polymers include the Wait Contains polar groups such as esters, ethers, ketones, ammoniums, ammoniums, alcohols. This paper size applies to China National Standard (CNS) A4 (2i0x297 mm) -25: (please first Read the precautions on the back and fill in this page). Order.! 575647 A7 — B7 V. Description of the invention (23) Phenols, halides, acids, anhydrides, sulfides, nitriles, isocyanates, aromatics Homopolymers, copolymers, and terpolymers of heteroaromatic groups. These polar substitutions can be found in the polymer backbone, the side chains of the polymer backbone or connected to the polymer backbone or Aryl groups on the side chains of the polymer backbone. Suitable examples include C2 to C20 olefins (such as ethylene and / or propylene and / or butene) and one or more polar monomers such as vinyl esters or alcohols, acids, anhydrides, propylene or methacrylic acid or esters Copolymers. The polar polymer also includes any thermoplastic copolymer containing a functional group capable of interacting with an unsaturated acid or an acid anhydride present in the resin material. Examples include, but are not limited to, polyesters, polyamides, polyureas, polycarbonates, polyacrylonitrile, polyacrylates, polymethacrylates, ethylene vinyl acetate , Halogenated polymers, polyvinyl chloride, polyethylene terephthalate, polybutylene terephthalate (PBT), polyacetal, acrylic or methacrylic acid, alkyl acrylate, or methyl Polymers (or copolymers) of acrylates, ethylene methyl acrylate, ethylene butyl acrylate and the like. Therefore, in a specific embodiment, the graft resin material can be formulated with a polar polymer such as E V A. It optionally includes other ingredients such as one or more waxes or oils. Any of the foregoing embodiments may be combined with a polyolefin (base polymer) to form an adhesive. Typical base polymers include polyethylene, with one or more C3 to C2. Linear, branched or cyclic α-olefin copolymerized ethylene, polypropylene 'with one or more kinds of ethylene and / or C4 to C2. Propylene 'polybutene copolymerized by straight chain, branched chain or cyclohexene, butene copolymerized with one or more C5 to linear, branched or cyclic α-olefin, low density polyethylene (lpde) (This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling out this page). Order printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economics -26- 575647 A7 _ B7 5 Description of the invention (24) density 0.915 to less than 0.9 35 g / cm3), linear low density polyethylene (LLPDE), ultra-low density polyethylene (density 0.86 to 0.908 g / cm3), very low density polyethylene (Density 0.90 to 0.9 15 g / cm3), medium and low density polyethylene (density 0.935 to less than 0.945 g / cm3), high and low density polyethylene (HDPE) (density 0.94 5 to 0.9 8 g / cm 3) ). Other hydrocarbon polymers (or copolymers) include: polybutene-1, polyisobutylene, polybutene, polyisoprene, polybutadiene, butyl rubber, amorphous polypropylene, ethylene propylene diene Monomer rubber, natural rubber, styrene butadiene rubber, copolymers and halogenated copolymers of isobutylene and p-alkylstyrene, elastomers such as ethylene-propylene rubber (EPR), vulcanized EPR, EPDM, nylon, polymer Carbonates, PET resins, aromatic monomers such as polymers of polystyrene, copolymers of isobutylene and para-alkylstyrene 'still molecular weight HDPE, low molecular weight HDPE, graft copolymers are usually' polyacrylonitrile homopolymers' Or copolymers, thermoplastic polyamides, polyacetals, polyvinylidine and other fluorinated elastomers, polyethylene glycols, polyisobutylene, or blends thereof. Preferred alpha-olefins include propylene, butene, pentene, hexene, heptene, octene, nonene, dodecene, cyclopentene, 3,5,5-trimethylhexene-1,3 Terpolymer of methylpentene-1,4-methylpentene-1 and the above monomers. In another specific embodiment, the copolymer includes ethylene glycol and / or (ii) C3 to C2. Terpolymer of comonomer, and (iii) a diene. Preferred dienes include butadiene, pentadiene, hexadiene, norbornene, ethylene norbornene, vinylidene norbornene, dicyclopentadiene, and substituted ones. The structure of these polymers may be linear, substantially linear, short-chain branched, long-chain branched, star-branched, or any other combination thereof. _ ^ The arms can be the same as or different from the main chain, such as branch-block copolymers or multi-arms | This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) _ 27-(please first Read the notes on the back and fill out this page), 11 f Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 575647 Α7 _B7 V. Description of the invention (25) polymer. (Please read the notes on the back before filling out this page) Suitable polymers also include block copolymers of styrene and one or more conjugated diene such as SI (styrene-isoprene), SB s (benzene Ethylene_butadiene_styrene), SB (styrene-butadiene), SIS (styrene-isoprene-styrene). Also suitable are basic block copolymers including tetrablock or pentablock copolymers selected from SISI, SISB, SBSB, SBSI, ISISI, ISISB, BSISB, ISBSI 'BSBSB, and BSBSI. These block copolymers can be completely or partially hydrogenated to produce a resulting SEBS (styrene-ethylene-butene-styrene) rice sigma. The structure of the fluorene copolymer includes straight chain, radial or multi-arm star, or multi-chain and may include various styrene, isoprene, or succinyl combinations, which can be hydrogenated or not hydrogenation. Any of the foregoing specific embodiments may be mixed with graft polymers or blends of graft polymers and / or non-grafted polymers. Examples of polymers and such blends include, but are not limited to, those described in US 5,936,058. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Any of the foregoing embodiments may be mixed with an elastomer to form an adhesive sealant. Preferred elastomers include natural rubber, polyisoprene, polybutadiene, copolymers of butadiene and styrene, copolymers of butadiene and acrylonitrile, butyl rubber, polyprene, ethylene / Propylene rubber and ethylene, propylene and non-conjugated di-elastomer copolymers, styrene block copolymers such as styrene and / or methyl styrene and alkadiene (such as isoprene or butadiene) Chain, radiation 'and / or tapered block copolymers. In a specific embodiment, the base polymer may be a polymer produced using a metallocene catalyst system. Typically, these metallocene homopolymers or copolymers use single- or bis-cyclopentadienyl-based transition metal catalysts and aluminum oxide-28-this paper size applies to China National Standard (CNS) A4 specifications (210X 297 mm) (Centi) 575647 A7 B7 V. Description of the invention (26) Solution, slurry, high pressure or gas phase of alumoxane and / or non-coordinating anion activator combination. The catalyst system may have a support, or there may be no support and the cyclopentadienyl ring may be substituted or unsubstituted. Hafnium, zirconium and zirconium are the preferred transition metals. Several commercial products made using these catalyst / activator compositions are 1% from the ExxonMobil Chemical Company of Baytown, Texas, under the trade names EXCEED® and EXACT®, or from the Dow Chemical Company under the trade name ENGAGE® And commercial products of AFFINITY®. The copolymer prepared by the above metallocene preferably has a polydispersity of less than 4 and a composition distribution width index (CDBI) of 50% or more, preferably 60% or more, and even more preferably 70% or more. In a specific embodiment, the CD BI is above 80%, even more preferably above 90%, even more preferably above 95%. In a specific embodiment, the polyethylene copolymer has a CDBI between 60-85%, and even more preferably between 65-85%. The Composition Distribution Width Index (CD BI) is a measure of the composition distribution of a monomer within a polymer chain and is measured by the procedure described in PCT Publication WO93 / 03093, published on February 18, 1993. The CDBI includes ignoring portions with a weight average molecular weight (Mw) of less than 15,000. Any of the foregoing specific embodiments may be present in a blend of a resin and a base polymer. A suitable ratio of resin: base polymer includes 1: 1000 to 2: 1, more preferably 1: 2 to 2: 1 and even more preferably between 3: 1 and 1: 3. Any of the foregoing embodiments may be combined with additives known in the art such as processing oils, performance oils, anti-blocking agents, antistatic agents, antioxidants, cross-linking agents, silica, carbon black, talc, pigments, fillers , Processing aids, UV stabilizers, neutralizers, lubricants, anti-slip agents, slip agents, surfactants (please read the precautions on the back before filling out this page) Order P. Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs The paper size for printing is applicable to Chinese National Standard (CNS) A4 (210X 297 mm) -29-575647 A7 B7 V. Description of the invention (27) (Please read the precautions on the back before filling this page) and / or Nuclear agent mix. Examples of common additives include, for example, Irganox® 1010, silicon dioxide, titanium dioxide, polydimethylsiloxane, talc, dyes, waxes, calcium stearate, carbon black, and glass beads. In HMA applications, suitable synthetic waxes include paraffin waxes and microcrystalline waxes with low melting points in the range of about 55 ° C to about 13CTC and low molecular weight polyethylene and Fisher- 雪 busch. The wax content is preferably from about 1 to about 35 weight percent of the total blended composition. In PS A applications, suitable oils include FLEXON® 876 or PRIMOL® 352 from ExxonMobil Chemical Company at concentrations of less than 50%. Any of the foregoing embodiments can be formulated as a pressure sensitive adhesive that can be applied to any conventional backing layer such as paper, foil, polymeric film, release liner, woven or non-woven backing material to make, for example, packaging tape, masking tape And tags. A specific example of hot melt pressure sensitivity includes 100 parts by weight of a base polymer, preferably a styrene block copolymer, 50-150 phr (parts per 100 parts by weight of the base polymer). Resin mentioned, 0-50 phr, more preferably 10-50 phr, more preferably 15-50 phr, more preferably 20-50phr, more preferably 25-50phr, more preferably 30-50phr, more preferably 3 5- 50 phr, more preferably 40-50 phr, more preferably 45-5 0 phr extender oil, and 0-5 phr antioxidant. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economy ), More preferably 10-50 phr, more preferably 15 phr or more, more preferably 15-50 phr, more preferably 20 phr or more, more preferably 20-50 phr, more than 25 phr, more preferably 25-50 phr, more preferably Above 30 phr, more preferably 30-50 phr, more preferably 35-50 phr, more preferably 40-50 phr, while maintaining the cohesive strength of the adhesive formulation (as shown in hot shear and SAFT measurements) . -30- This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm) 575647 A7 B7 V. Description of Invention (28) (Please read the notes on the back before filling this page) In the specific embodiment of HM A The ingredients selected as needed are plasticizers or other additives such as oils, tackifiers, surfactants, extenders, color concentrates, and the like. Preferred plasticizers include mineral oils, polybutenes, phthalates, and the like. Particularly good plasticizers include phthalates such as diisodecyl phthalate (DIOP), diisononyl phthalate (DINP), and dioctyl phthalate (DOP) ). Particularly preferred oils include aliphatic naphthenic oils. Another component of the HMA composition printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is a low-molecular-weight product such as osmium, oil, or a low Mn polymer, (low means 5,000 or less, preferably 4,000 or less, more Preferably below 3000, even more preferably below 2500). Preferred oils include aliphatic naphthenic oils, white oils, or the like. Preferred low Mn polymers include polymers of lower alpha olefins such as propylene, butene, pentene, and hexene. Particularly preferred polymers include polyisobutylene having an η of less than 1000. Examples of such polymers are available from ExxonMobil Chemical Company under the trade name PARAPOLtm 9 50. PARAP0Ltm 950 is a liquid polybutene polymer with a Mn of 950 and a dynamic viscosity (as measured by ASTM D 445) of 220 cSt at 100 ° C. Suitable specific examples of HMAs typically include 20-70% by weight of the resin materials or blends described herein, 30-80% by weight of the base polymer, and 0-35% by weight. HMAS embodiments can be used for disposable diapers and sanitary napkin bottom structures, disposable goods for 'converting, packaging, marking, binding, carpentry, and other assembly applications for resilience annex. Specific examples include: baby diaper leg elastic band, diaper front tape, diaper fixed leg cuffs, diaper bottom structure, diaper core stabilizing function. This paper applies the National Standard (CNS) A4 (210X297 mm) -31 _ 575647 A7 --- _ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (29) 'Liquid transfer layer for diapers, laminated structure for diaper outer cover, laminated structure for diaper elastic cuffs, core stabilizing effect of feminine tampons, Feminine tampon adhesive strips, industrial-moisture filter combination, industrial filter material laminated structure, filter cover laminated structure, surgical gown laminated structure, surgical cloth curtain laminated structure, and perishable product coating. Suitable specific examples of woodworking applications include 30-50% by weight of the base polymer 'preferably EVA, 15-35% by weight of the resin described herein, and 20-50% by weight of fillers such as calcium carbonate, sulfuric acid Barium, silica or titanium dioxide. Specific examples of suitable binding applications include 35-45% by weight of the base polymer, preferably EVA, 35-45% by weight of the resins described herein, and 10-25% by weight of wax. The resin material of the present invention can be used to improve the elongation properties of the adhesive forming the part. Compared to some conventional resins, when the adhesive is combined with a resin material or blend as described herein, an improvement in elongation properties is seen. It is believed that the resin material of the present invention can be used to reduce the setting time of the thermosol adhesive forming the part. Conventional HMAs have a setting time of about 2 seconds. The letter materials described herein can be reduced to 1.5 seconds or less, 1.4 seconds or less' 1.3 seconds or less, 1.2 seconds or less, 1 · 丨 seconds or less , Or even a set time of 1 second or less. Polymer Additive Γ1 _ 彳 The specific embodiments of the present invention have novel utility as polymer additives in many applications. Other materials exist depending on the application. Many kinds of polymers have been previously described herein. They can be used in polymer processing, for example, in various molding applications that require good spiral flow and need to retain physical properties. A wide range of polymers, from polypropylene to engineering thermoplastics (please read the notes on the back before filling out this page) Clothing · Order # 1 This paper size applies to Chinese National Standards (CNs) A4 (210X 297 mm)- 32- 575647 V. Description of the invention (30), in this category. The resin of the present invention also aids adhesion, stickiness, and tackiness. A wide range of polymers, such as polyolefin films, tire rubber components or rubber over-molded articles, fall into this category. They can also be added to ink formulations to aid ingredients and adhesion to substrates. Other applications are coating drying and concrete hardening. The addition of road signs can be configured into a thermoplastic road sign (TRM) composition in the specific embodiments disclosed herein. These formulations include resin, plasticizers or oils, pigments, fillers' glass beads. The graft material of the present invention can be used as a main resin for a road marking composition or as an additive to a road marking composition. The signpost composition containing the graft material of the present invention may additionally include EVA, polyisobutylene, including block copolymers of this ethylene storage and conjugated secondary storage such as isoprene or butadiene (including but not limited to SI, SIS, SB, and / or SBS), polyethylene fluorene, turpentine, turpentine derivatives, maleic acid / anhydride modified hydrocarbon resins. The graft materials of the present invention help disperse fillers and pigments to produce improved fluidity and color properties. A specific example of a TRM application comprises 10-40% by weight of a resin material or blend as described herein, 2-20% by weight pigment, such as Ti02, 10% by weight oil, 0-7% by weight The base polymer, and the balance contains rhenium fillers such as glass beads, sand, calcium carbonate, silica, or others as described herein.

Crosslinking and Reactivity Plus T Specific embodiments of the present invention have further advantages as polymer additives in inks and architectural and road marking applications. They can be adjusted by gluing (please read the notes on the back before filling this page)

， 1T Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) 33- 575647 A7 B7 V. Description of the invention (31) (Please read the precautions on the back before (Fill in this page) Another component of the formulation is cross-linked to produce and participate in the cross-linking in the composition medium. Preferred examples of acid anhydrides or acid groups on the resin can be crosslinked with them or with other polymers present in the composition medium. Some polymers containing negative amine or alcohol functionality will react directly with the graft resin material. For example, these polymers contain some vinyl alcohol groups. When a crosslinker is added, other polymers will crosslink. In these specific examples, the amount of crosslinker added typically depends on the amount of graft monomer present. Typical amounts are comprised between 1 Q 0: 1 and 1: 1 00, more preferably 1: 1 in parts of the crosslinking agent, each part of the grafting monomer (molar ratio) present in the formulation. These include such polymers containing some acrylic acids such as ethylene alkyl-acrylate acrylic terpolymers or polymers containing cis-butene dianhydride or acid groups such as ethylene-propylene diene grafted with cis-butene dianhydride rubber. Such cross-linking can be achieved in a number of ways, including the addition of a bifunctional agent that reacts with an acid or anhydride group. Examples of such materials are those containing alcohol and amine functional properties such as glycols, diamines, and especially primary amines. Materials with these functional groups can be mixed or have different substituents, such as diamines, where one group is primary and the other is tertiary. Weaker cross-linking can be achieved through interactions that do not form covalent bonds such as ions and hydrogen bonds. Examples of materials printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics that can be cross-linked in this way are divalent metal ions such as Ca + + or diamines containing quaternary amines. 0 has one or more ingredients containing those disclosed herein The film can be used as a single- or multi-layer film or laminate and may be manufactured by any conventional method, including simple blow molding, biaxial orientation (such as scaffolding, sandwich foam, or double-bubble-34- this paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) 575647 Α7 Β7 V. Description of invention (32) method), simple casting / board extrusion-lamination, co-extrusion, lamination, extrusion lamination, And co-extrusion lamination 'blow molding and casting. If a multilayer film is required, it can be obtained from a single-layer blown or cast film that can be combined with another layer via conventional techniques such as adhesive lamination or extrusion lamination. Monolayer and coextruded films can also be produced by biaxial orientation. Extrusion fit is another suitable method. A heat-sealing film comprising a sealing layer as described herein may be extruded and bonded to a substrate in the form of a single layer or a multilayer co-extruded substrate. Multiple extrudates can be prepared via multiple extruders on multiple stations in series. These layers can be co-pressed with other layers (etc.) of the multilayer film, or the sealing layer can be laminated on other layers (etc.) or substrates, including paper, foil, oriented polypropylene, polyamide, polyester, Polyethylene, polyethylene terephthalate, metal and metallized substrates and other substrates discussed herein. The film can be obtained by a flat film or tubular method, which can then be oriented uniaxially in the film plane or in two mutually perpendicular directions. One or more thin film layers may be oriented to the same or different degrees in the transverse and / or longitudinal direction. This orientation can occur before or after the individual layers. For example, a polyethylene layer can be extruded and laminated or laminated on an oriented polypropylene or oriented polyester layer or polyethylene and polypropylene can be co-extruded into a film and then oriented. Likewise, oriented polypropylene can be laminated to oriented polyethylene or oriented polyethylene can be cloth coated onto polypropylene and the composition can be further oriented as desired. Typically the film is oriented in a machine direction (MD) up to a ratio of 15 ', preferably between 5 and 7, and in a transverse (TD) orientation up to a ratio of 15, preferably 7 to 9. However, in another embodiment, the film is oriented to the same extent in both the MD and TD directions. The film layers may include any polyolefin, such as the polar polymers described herein, including paired disubstituted olefins, alpha-heteroatomic olefins, and / or styrene. This paper is sized to Chinese National Standard (CNS) A4 specifications ( 2ιχχ297 mm) (Please read the precautions on the back before filling out this page) Clothing · Order Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 575647 A7 B7 V. Description of the invention (33) Monomer polymer or copolymer Cationic polymer. Preferred paired disubstituted olefins include isobutene, isopentene, isoheptene, isohexane, isooctene, isodecene, and isododecene. Preferred alpha-heteroatomic olefins include vinyl ether and vinyl carbazole, and preferred styrene monomers include styrene, alkylstyrene, p-alkylene, alpha-methylstyrene, and chloro-styrene. , And bromo-p-methylstyrene. Examples of preferred cationic polymers include butyl rubber, isobutylene copolymerized with p-methylstyrene, polystyrene, and poly-α-methylstyrene. Other preferred layers can be paper, wood, and thick paper. Plates, metals, metal foils (such as aluminum and tin foils), metallized surfaces, glass (including silicon oxide (SiOx) coatings on the film surface with evaporated silicon oxide), fabrics, spunbond fibers' and Non-woven (especially polypropylene spunbond or non-woven), and substrates coated with inks, dyes, pigments, PVC and the like. [0079] The films may vary in thickness depending on the desired application, however films with a thickness of 1 to 250 microns are generally suitable. Films intended for packaging are typically between 10 and 60 microns thick. In many cases, the sealing layer should have a thickness between 5 and 60 microns, more preferably between 10 and 50 microns, and most preferably between 15 and 30 microns. The sealing layer may be on the inner and outer surfaces of the film or the sealing layer may be present only on the inner or outer surface. Film additives such as adhesives, anti-blocking agents, antioxidants, slip additives, pigments, fillers, processing aids, UV stabilizers, neutralizers, lubricants, surfactants and / or nucleating agents may also be used Exist in one or more films. Preferred additives include sand dioxide, dioxin, polydimethylsiloxane, talc, dyes, osmium, calcium stearate, carbon black, low molecular weight f. Please read the precautions on the back before filling this page} Clothing. Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. The paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) -36- 575647 A7 B7 V. Description of the invention (34) Resin and glass beads. In a specific embodiment, the layer (or the like) may include a cross-linking agent. Preferred crosslinking agents include alcohols, polyols, amines, diamines and / or triamines. Examples of the crosslinking agent which can be used in the present invention include polyamines such as ethylenediamine, diethylenetriamine, hexamethylenediamine, diethylaminopropylamine, and / or methanediamine. Preferred antioxidants include phenolic antioxidants, such as Irga a η X 1 0 1 0, Irganox, 1 076, both of which are available from Cibajiagi and 3,5 tertiary-butyl 4-hydroxytoluene. Preferred oils include paraffin or napthenic oils, for example, Primol 352, or Primol 876, available from ExxonMobil Chemical S.A., Paris, France. More preferred oils include aliphatic naphthenic oils, white oils or the like. Preferred plasticizers and / or adjuvants include mineral oils, polybutenes, phthalates and the like. Particularly good plasticizers include phthalates such as diisoundecyl phthalate (DIUP), diisononyl phthalate (DINP), and dioctyl phthalate ( DOP) and polybutenes, such as Parapol 950 and Parapol 1300 available from ExxonMobil Chemical Company of Houston, Texas. Preferred film processing aids, lubricants, rhenium, and / or oils include low molecular weight products such as waxes, oils, or low Mn polymers, (low indicates below 5Q00, preferably below 4000, more preferably below 3000, Even more preferred is Mη) below 2500. Preferred rheniums include polar or non-polar rhenium, functionalized rhenium, polypropylene rhenium, polyethylene rhenium, and wax modifiers. Preferred waxes include ESCOMER 101. Preferred low Mn polymers include lower alpha-olefins such as propylene, butene, pentene, hexene and similar polymers. Particularly preferred polymers include polybutenes having a Mn of less than 1,000. An example of this type of polymer is a trademark name derived from Exxon Chemical Company (please read the notes on the back before filling this page) ) A4 specifications (210X297 mm) 37 575647 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of invention (35) PARAPOL950. PARAPOL 9 50 is a M η and D 1 00 with a value of 9 50. 〇220cSt liquid polybutene polymer with dynamic viscosity (as measured by ASTMD 445). In another embodiment, one or more layers may be corona treated, electron beam radiation, r radiation, flame treatment or microwave modification. In the preferred embodiment, one or both of the surface layers are modified by corona treatment. The film can be used as a stretched and / or adhesive film. Stretch / bond films can be used in a variety of bundling, packaging, and stacking operations. To impart or improve the adhesion properties of special films, many known tackifying additives have been used. Common tackifier additives include polyisobutylene, terpene resins, and hydrogenated turpentine and turpentine. The adhesive properties of the film can also be modified by known physical methods known as corona discharge. Some polymers (such as ethylene methyl acrylate copolymers) do not require a tackifier additive and can be used as a tackifier without a tackifier. The stretch / bond film may include a slip layer that includes any suitable polyolefin or polyolefin (eg, polyethylene, polypropylene, ethylene and propylene copolymers) and is obtained from small amounts of other olefins (especially (: 4 to c! 2 olefin) copolymerized ethylene and / or propylene polymer composition. Particularly preferred are polypropylene and linear low density polyethylene (LLDPE). Suitable polypropylenes are normally solid and isotactic, that is, More than 90% hot heptane is insoluble and has a wide melt flow rate of about 0.1 to about 300 g / 10 minutes. In addition, the slip layer may include one or more anti-blocking (slip and anti-blocking) additives, It can be added during polyolefin manufacture or later to improve the slip properties of this layer. These additives are known in the art and include, for example, silica, silicate, diatomaceous earth, talc and various lubricants These additives are preferably from about 100 ppm to about 20,000 ppm, and more (please read the precautions on the back before filling out this page). Clothes, 11 This paper size is applicable to China National Standard (CNS) A4 specifications (210X297 mm) ) -38-575647 A7 B7 five 2. Description of the invention (36) It is preferably used in an amount based on the weight of the slip layer between about 500 ppm and about 100,000 ρριη. If necessary, the slip layer may also include one or more of the above as described above. Other additives. Examples of implementation In the following examples, HMAs were prepared as follows. The ingredients of the HMA formulation were introduced into a Z-blade mixer previously heated at 180 ° C under a nitrogen blanket. The radon and mixing were introduced after 10 minutes. Continue for another 60 minutes. Stop the mixer, stop the nitrogen layer and pour the blend into the dish. The blend is further cooled under a nitrogen layer and covered with release paper. Ingredients used in the examples include Escorene® UL40028, one obtained from ExxonMobil Chemical Co., Ltd. ethylene vinyl acetate copolymer with a melt index of 400 g / 10 minutes, a density of 0.937 g / ml, and a content of 28% vinyl acetate, commonly known as Np 鱲, obtained from TotalElfAtoFina Rockwell 68 ° C, and Fisher-Herbusch Polyethylene Wax (FT Wax), obtained from Schumman-Sasol Paraflint HI. Prepare HMA samples for testing as follows. The adhesive is introduced into the leak of the accumeter. Melt in a bucket and under nitrogen at 150 ° C. Cut and coat the desired substrate carrier strip with a melt adhesive (200 // thick polyethylene film, 100 // thick PET film, 90 / thick aluminum And / or acrylic-coated oriented polypropylene (0PP) film cardboard). For the T-peel test, HMA for testing was prepared by cutting coated and uncoated substrates into approximately 25 cm length and 10 cm width pieces. Samples. Unpainted (please read the precautions on the back before filling out this page). · Order the paper printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The paper size applies to the Chinese National Standard (CNS) A4 (210X: 297 mm) _ 39-575647 A7 ___ B7 V. Description of the invention (37) The cloth substrate is placed on the upper end of the coated substrate. The samples were wrapped in release paper, which was heat-pressed at a given temperature depending on the substrate (110 ° C for polyethylene acrylic coated OPP cardboard, 150 ° C for aluminum hydroxide, polypropylene, and polymer Ethylene terephthalate (PET)) was further laminated for 30 seconds under a pressure of 4,400 pounds (114 ps 1/7 83 kPa). Use a paper cutter to cut a 2 cm wide strip from the laminated sample (etc.) in the coating direction. The T-peel strength was measured with a tensile tester (Zw1Ck). Measure the F-average peel force (g / cm) (at least 3 test samples per laminate). When a sharp jump is indicated, 2/3 of the largest peak is recorded. The types of failures are also recorded in Tables 1-5: Adhesive Failure (AF), Cohesive Failure (CF), Jump or Not Jump, and Tear. The shear adhesive failure temperature (SAFT) and thermal shear test samples were prepared in the same way as the T-peel samples except that a 25x70 mm strip was used and placed on a pre-treated stainless steel plate. SAFT consists of attaching a coated substrate of a selected substrate to a stainless steel with a contact area of 12.5x25 mm, hanging the sample in an oven fixed at 25 ° C and suspending a weight of 500 grams from the bottom of the strip. The temperature was raised at 0.4 ° C / min and the combined destruction temperature was measured. Shear gummy failure temperature is the average of three tests. Hot shear was measured by hanging a 25-mm-wide strip of selected substrate coated with an adhesive formulation (adhered to a stainless steel plate with a contact area of 12.5 x 25 mm) and weighing 1,000 grams. The samples were placed in a ventilated oven at 40 ° C for 30 minutes. The temperature increased by 10 ° C during 30 minutes until stress failure occurred, up to 110 ° c. Record the time until stress failure occurs. Typically, these tests are performed and recorded individually to determine the reliability of the adhesion. As a result, the paper size at 6CTC is applicable to the Chinese National Standard (CNS) A4 specification (21〇 × 297 & ϋ-40 _ " (Please read the precautions on the back before filling this page) Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Clothing and Economy System 575647 A7 ______ B7 V. Description of the invention (38) The amount of minutes is equivalent, that is, when damage occurs, each 丨 〇. (: Increase by 60 ° C or more, add 30 minutes to this time. Saponification plutonium, if used Herein, the measurement was performed according to the following steps. 2 g of the powdered resin material to be evaluated was dissolved in 25 ml of toluene / isopropanol (1: 1 weight ratio) and 50 ml of a 0.1 N KOH alcohol solution was added via a pipette. After refluxing for 30 minutes and cooling to room temperature, a phenol indicator (phe η ο 1 phtha 1 eine) indicator was used to titrate the solution to 0 · 1 NHC1. A blank experiment was performed with no resin material. Then 5 6.1 (1 ^ 011 Approximate molecular weight) 1 standard 1 ^ (: 1 volume \ 1101 equivalent concentration divided by the weight of the resin material calculated saponified samarium (mg KOH / g resin). In the following examples, all parts, ratios unless otherwise indicated , And percent By weight. Acid acid, as used herein, is measured according to the following steps. 2 grams of the powdered resin material to be evaluated are dissolved in 30 ml of toluene / isopropanol (2: 1 weight ratio). After the sample is completely dissolved, it Titrate with 0.1N tetrabutylammonium hydroxide (TBAOH) potential under vigorous stirring, using Pt titrode and Ag / AgCl electrodes with saturated LiCl electrolyte in saturated ethanol. Blank experiments were performed without resin material. Then by 56.1 ( Approximate molecular weight of K0Η) multiplied by the TBAOH volume used to titrate the sample minus the TBAOH volume of the titration blank multiplied by the TBAOH equivalent concentration divided by the weight of the resin material. Expressed, (mg KOH / g resin). Example 1 (Comparative) A thermally polymerized hydrogenated aromatic hydrocarbon containing DCPD resin (Escorez® 5 600 available from ExxonMobil Chemical Co., Ltd., has a softening point of 103 ° C $ paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) ^ 41-" (Please read the precautions on the back before filling this page)

1T f Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 575647 A7 B7 V. Description of the invention (39), Mn 270, and Tg 5 5 ° C) are mixed in the HMA preparation according to Table 1. (Please read the precautions on the back before filling this page) Example 2 (Comparison) Sylvalite® RE100 (softening point 96 ° C, Mn 9 50, Mw 1 1 10, saponin 26, and acid値 5.5) The high pinoresin ester is mixed in the HMA formulation according to Table 1. Example 3 (comparative) Sylvalite® RE 100 (softening point 100 t :, Mn 810, Mw 1060, saponified rhenium 28, and acid hydration 13, 7) from Arizona Chemical Company was blended in accordance with Table 1 HMA formulation. Example 4 (Comparison) The terpene phenolic resin printed by Dertophene T (softening point 95 ° C, Mn 490, Mw 700, and initial color 4.5 Garden) from Resiniques Terpeniques, Consumer Cooperative of the Ministry of Economic Affairs, was mixed in accordance with the table 1 in HMA formulation. Examples 1-4 were then examined using polyethylene-to-polyethylene and PET-to-PET T-peel, and thermal shear and SAFT on polyethylene-to-stainless steel and PET to stainless steel. The results obtained from Examples 1-4 are shown in the table and used as a reference for comparison of later examples. Example 5 100 grams of a thermally polymerized hydrogenated aromatic hydrocarbon containing a DCPD resin, the same as the Escorez® 5600 resin tested in Example 1, but without antioxidants, containing 7.5% aromatic protons and 0.01% olefin protons, having a temperature of 103 ° C The softening point of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _42 _ '~ 575647 A7 B7 at this paper scale V. Description of the invention (40) Heat under nitrogen in a 250 ml flask equipped with a stirrer And maintained at 170 ° C. 5.5 grams of dibutyl maleate are added. Add aliquots of 0.75 ml of 2,5-dimethyl-2,5-bis (tertiary-butylperoxy) hexane (Luperox® 101) at 15-minute intervals. After the peroxide addition was complete, the mixture was further stirred under a stream of nitrogen for 75 minutes to remove volatile materials. The resulting reaction product 'was decanted from the reactor and cooled and analyzed. The graft resin product had a Gardner color of 3.5 (50% by weight in toluene), a softening point of 84 ° C, and a saponified samarium of 17. Example 6 100 grams of a thermally polymerized partially hydrogenated aromatic hydrocarbon containing DCPD resin, the same as the Escorez® 5600 resin tested in Example 1, but without antioxidants, with a softening point of 103 ° C, 7.5% aromatic protons, and 0.01% olefins The protons (indicated by W-NMR spectrum) were heated to and maintained at 170 ° C in a 500 ml flask equipped with a stirrer under nitrogen. When liquid, 1.23 grams of cis-butene dianhydride powder is added and mixed. Five 0.1 ml aliquots of 2,5-dimethyl-2,5-bis (tertiary-butylperoxy) hexafluoride (Luperox 101) were added to the stirred liquid at 15 minute intervals and the reaction was Continue for another 60 minutes under a nitrogen stream to remove volatile peroxide decomposition products and any remaining unreacted cis-butene dianhydride. The melt was decanted from the reaction flask and allowed to cool and solidify. The obtained graft resin product had a softening point of 105 ° C, a Gardner color of 3.5, and a saponification of 10%. Example 7 250 grams of thermally polymerized partially hydrogenated aromatics containing DCPD resin, which is the same as the Escorez® 5600 resin tested in Example 1, but without antioxidants. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm1) : 43-(Please read the precautions on the back before filling this page} 、 11 Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 575647 A7 _ _____ B7 _ V. Description of the invention (41) Softening point of 103 ° C, 7.5 % Aromatic protons and 0.01% olefin protons (indicated by H-NMR spectrum), heated to and maintained at 170 ° C in a 500 ml flask equipped with a stirrer under nitrogen. When liquid, 6.13 g of cis- Butene dianhydride powder and mixed. Five 0.25 ml aliquots of 2.5-dimethyl-2,5-di (tertiary-butylperoxy) hexane were added at 10 minute intervals and the reaction continued under nitrogen flow. 20 minutes to remove the volatile peroxide decomposition products and any residual unreacted cis-butenedi anhydride. The melt was poured from the reaction flask and allowed to cool and solidify. The resulting graft resin product had a softening of 105 ° C Points, 3.6 colors of Garden and 20 soaps値 Example 8 100 grams of thermally polymerized partially hydrogenated aromatics containing DCPD resin, the same as the Escorez® 5600 resin tested in Example 1, but without antioxidants, with a softening point of 103 ° C, 7.5% aromatic protons, and 0.01 % Olefin protons (indicated by ^ -NMR spectrum), heated to and maintained at 170 ° C in a 500 ml flask equipped with a stirrer under nitrogen. When liquid, add 4.9 g of cis-butadiene dianhydride powder and mix Add four 0.5 ml aliquots of 2.5-dimethyl-2,5-di (tertiary-butylperoxy) hexane at 15 minute intervals and continue the reaction under nitrogen flow for another 75 minutes to remove volatility Peroxide decomposition products and any remaining unreacted cis-butadiene anhydride. The melt is poured from the reaction flask and allowed to cool and solidify. The resulting graft resin product has a softening point of 112 ° C, a Gardner color of 8 and 40 Example 9-12 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) "44--(Please read the precautions on the back before filling this page) Clothing. Order the Ministry of Economic Affairs wisdom Printed by the Property Agency's Consumer Cooperatives 575647 A7 B7 Explanation of the invention (42) The graft resins obtained from Examples 5-8 were mixed in the HMA formulation according to Table 1. Then T-peeling of polyethylene to polyethylene and PET to PET was performed, and Stainless steel and PET heat-shear and SAFT inspection of stainless steel Examples 9-12. Results from Examples 9-12 are shown in Table 1 and Figures 1-6. Note T-Peel: Only indicates peel force (F-average) . When the sample has only a sharp jump, it is equivalent to zero adhesive force. These results show that most of the graft resins were adhered similarly to Reference Examples 1-4 on a polyethylene substrate. On the other hand, the thermal shear and SAFT of the graft resin are better than those of Reference Example 4, especially the examples in which the graft monomer is cis-butene dianhydride. Examples 6/10, 7/11, and 8/12. These results also show that compared to the unstretched graft resins of Example 1 and the high oleoresin esters of Examples 2 and 3 on polar substrates, these graft resins have better adhesion, which shows only a sharp jump. As shown in Figure 1-6, the results of hot shear and SAFT show that the graft resins of Examples 6/10, 7/11, and 8/12 are equal to or better than those of Reference Examples 1-4. Example 1 3700 grams of cyclopentadiene, methyl ring were removed from the overhead distillate stream of a product stripper in a commercial manufacturing process for a thermally polymerized aromatic hydrocarbon containing DCPD hydrocarbons at a ExxonMobil manufacturing plant in Notre Dame de Gravenchon, France. Pentadiene and C9-C !. A mixture of hydrogenated trimers and tetramers of oligomers of aromatic olefins. The resulting oligomers contained no antioxidants and contained 7.4% aromatic protons and 0% olefin protons. The oligomers were stirred in a 2 liter flask under nitrogen at 160 ° C with 70 g of cis-butene dianhydride powder. Add six 3 ml aliquots of 2,5-dimethyl-2,5-di (tertiary-Ding) at 0, 10, 20, 30, 45 and 75 minutes (please read the notes on the back before filling This page) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. The paper size is applicable to the Chinese National Standard (CNS) A4 (210X 297 mm) _ 45 _ 575647 A7 B7 V. Description of the invention (43) Base peroxy group) Hexane. The reaction was continued for another 45 minutes with nitrogen flowing under the flask to remove any volatile components. The reactor was cooled to 40 ° C and the product was poured into a cold paraffin solvent (available from ExxonMobil Chemical Co. Exxsol D) with a boiling point in the range of 1 60-1 92 ° C as measured by ASTM D-1 07 8. The insoluble product was filtered and washed with heptane to remove residual traces of unreacted oligomers and any peroxide decomposition products. The yield was 120 g of grafted oligomers with a softening point of 107 ° C, a garden color of 12 (acetone: toluene 1: 1 by weight), and a saponified samarium of 3 3 6. Examples 14-17 The graft oligomers obtained from Example 13 were mixed with a thermally polymerized hydrogenated aromatic hydrocarbon containing a DCPD resin (Escorez® 5 600) in various oligomer to resin ratios to form a resin material. The amount of grafted oligomer in the resin material varies between 5 and 30% by weight. The resin material was then mixed in the HMA formulation according to Table 1. T-peel from polyethylene to polyethylene and PET to PET, and thermal shear and SAFT from polyethylene to stainless steel and PET to stainless steel have been measured. Results from Examples 14-17 are shown in Tables 2 and 4 and Figures 7-12. The T-peel tests of Examples 15 and 17 were also performed on acrylic coated 0PP thick paperboard (indicated as AC) and compared with similar results produced by the HM A formulation prepared in Example 2. These results are shown in Table 2 and Figures 13-15. Table 2 and Figs. 7 to 12 illustrate the overall comparable behavior of a resin material containing a graft oligomer on a polyethylene substrate when compared with Reference Examples 1 to 4. These results also show that on polar substrates such as PET, resin materials containing grafted oligomers achieve significant advantages, especially adhesion. These results also show that this paper size applies to the Chinese National Standard (CNS) A4 specification (210X Μ? Mm) (Please read the precautions on the back before filling this page)

1T f Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 46 575647 V. Description of the Invention (44 When compared with Reference Examples 1-4, the shear and SAFT of resin materials containing graft oligomers are significantly higher. From The results in Table 5 and Figure π_15 also show that the resin material containing the grafted oligomer has performance, especially adhesion, higher than that of the high turpentyl ester tested on the acrylic coated oρρ cardboard in Example 2. It is clear from the foregoing description It can be seen that the prepared material and the method are particularly good specific examples of a wide range of inventions. It is obvious from the foregoing general description and special specific examples that at the same time the form of the present invention has been illustrated and described, and various modifications can be made without leaving. This invention is carried out within the spirit and scope of the present invention. Therefore, 'the present invention is not intended to be limited thereby. In the following application scope, which represents a specific embodiment of the present invention, each of the subordinate specific embodiments of the following independent specific embodiments may be one or The foregoing implementation of other appendage embodiments is restricted so as to represent other operational specific embodiments within the scope of the claimed invention. Brief description of the formula Figure 1 -6 illustrates the hot melt containing the graft resin on the polyethylene and PET substrates (please read the precautions on the back before filling this page). The material of the colloidal fusion is called the moon tree, and it contains the adhesive and the adhesive. The colloidal material is the material of the material, o / ^ 1 7- The sticky object of the tree sticks together in the heat Ethylene-soluble solvent and olefinic oligothermal branching materials include fat-containing species trees. They contain fused materials that include upper packaging material and TS agent E, viscose board, adhesive, thick body, and hot-melt acrylic material. Polyester-oriented material acid poly oligopropylene branch cloth is coated and covered in Baoming species said a 5 -1 containing 13 packs of drawings on the base paper standard applicable Chinese National Standard (CNS) A4 specifications (21〇 > < 297 mm) -47- 575647 A7 B7 V. Description of the invention (45) Comparative performance between the agent and hot-melt adhesives containing other resin materials. (Please read the precautions on the back before filling out this page) Order-Color ¾ Qi Langzhi ¾ Hourly Production ¾ Members X Consumption Itixi Printed This paper is of suitable size Chinese National Standard (CNS) A4 size (210X297 mm) - 48- 575647 A7 B7 V. invention is described in (46) Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed

Cn) CO ο ο < 1 " < > 200 sr ...... i cn vo CF PE tear oo CS CNl & CN1 CN CO ON Ό r—H 心 CO ο ο r—Η un Ο cn oo CNl O τ—H 1036 | O 1 no sudden jump On CN oo VO 〇 sharp jump CS CN un cn ON 〇0Π ο 〇 uo 菡 S \ < | 1045 1 δ no sudden jump 〇〇C ^ l ίο o Jump speed Ά OO VO On CO ο Ο τ—Η ^ Τ) s rH oo VD ON b No jump speed s Equal inch C \ 1 VO inch UO CO ο V / O oo SV 1 i 1 1306 1 Uh None Jump VD VD cn σ > csi | CF + Jump 1 S ID CO CSI CO LO CO ο ο 1 / ·} VO sr—H g No jump o Jump 〇〇CN CNl CO CO VO CN) $ CO ο ο τ—Η uo oo oo S τ—H 1098 δ No rapid jump o Rapid jump oo CN τ—H CN oo VD τ—Η up «• ο cn ο Ο uo ΙΟ oo ^ < j—i oo AF + CF None Quick jump c < \ o Quick jump un \ < CSI Examples (etc.) Ingredients (parts by weight) Resin Escorene® UL40028 FT 鱲 Irganox® 1010 Resin Cloud Point (° c) Tree Moon Softening Point (° c) T- Peel PE / PE (g / cm) Destruction type T-peel PE / PE (g / cm) Hot shear PE / ss (min at 60 ° C) SAFT PE / ss (° C) T-Peel PET / PET (g / cm) Destruction Type T-Peel PET / PET (g / cm) Hot Shear PET / ss (min. At 60 ° C) SAFT PE / ss (° C) (please first Read the notes on the reverse side and fill in this page). The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -49- 575647 A7 B7 V. Description of the invention (47) Employees ’consumption by the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative 〇υο cn 〇o > 〇 > 200 s T- < 1018 AF + CF PE tear without snap jump cn CO OO inch u without snap jump 〇〇to without snap jump CS 1— < > 113 § un cn oo > 200 s! -I 00 oo AF + CF PE tear without sudden jump cn oo \ D to On inch AF + CF tends to jump ^ OO o " cn CTn un IQ 〇cn o 0 1 i > 200 s ^ — < CTn CF PE tear without sharp jump δ O CF tends to jump sharply CTN inch g ^ — < CN no sudden jump \ 〇CN v〇cn oo T— (mo > 200 s \ I cn cn AF: PE tearing without rapid jump o Rapid jump 沄 CNI_ ^ CTn inch un cn oo vn 〇vn oo s \ < 1306 o No rapid jump M3 cn ON CN | δ S un cn IQ un cn oo wo tn s 1 ^ no rush to un \ oo 5 trillion + AF 〇〇CN CN wn \ < VO CN v〇cn oo wn oo oo s T— &10; u no jump s VO \ D o jump ss CN VO S 〇 jump CN ST—Η ο ο Λ-1 un cn oo vn oo '!-* Ί-i OO AF + CF No sudden jump CN CN δ o Rapid jump v〇cn CN VO Examples (etc.) Ingredients (parts by weight) Resin resin component grafted oligomerization (Wt%) Hydrocarbon resin (Wt%) Escorene® UL40028 Np wax FT wax Irganox® 1010 Resin cloud point (° c) Resin softening point (° c) T-peel PE / PE (g / cm) Destruction type T- Peeled PE / PE (gA: m) Hot-shear PE / ss (min. At 60 ° C) SAFT PE / ss (° C) T-peeled PET / PET (g / cm) Destruction type T-peeled PE / PE ( gfcm) hot shear PE / ss (min at 60 ° C) OO Ph 1 oo T-peel AC / AC (g / cm) failure type T-peel AC / AC (g / cm) hot shear AC / ss ( Minutes at 60 ° C) SAFTPE / ssfC) QU-l ^ / olcslIA-l ^ lsI-lslolool-l ^ l ^ l ^ lHIMl ^ l ^ gl ^ NMMl ^ dzl ^ lsgKtflallsTl ^ (Please read the notes on the back first (Fill in this page) This paper size applies to China National Standard (CNS) Α4 size (210X 297mm) -50-

Claims (1)

575642 Amendment and replacement of the scope of patent application for the year U ^ M A8 B8 C8 D8 Attachment 4a: No. 9 1 1 2 1 8 8 6 amended Chinese patent application with no underlined amendments. Replaced November 1, 1992, U.S. Amendment 1. · An adhesive composition, which includes a Monomer-grafted resin material, the resin material is selected from: (a) at least partially hydrogenated cyclopentadiene and substituted oligomers of cyclopentadiene, wherein cyclopentadiene and substituted Cyclopentadiene oligomers are substantially free of norbornyl ester groups and / or include at least one monoalkylcis-butenedioic acid, its anhydride or derivative, or Θ_ after grafting with a grafting monomer. Nominal substituted propionic acid or derivative thereof; (b) oligomers of: (1) cracked petroleum feeds containing C4, (: 5 and C6 paraffins, olefins and conjugated di-hexanes; (Π) Cs-C! 0 aromatic monomers; (in) cracked petroleum feeds containing C4, dagger and C6 paraffins, olefins and conjugated dicarbons, and C ^ C !. aromatic monomers; Or (iv) cyclopentadiene and / or substituted cyclopentadiene and cs_c :. aromatic monomer; or (c) any combination of (a) and (b). Item 1 A composition in which the oligomer contains 0 to 50% olefin protons before grafting. 3. A composition as described in item 2 of the patent application, wherein the oligomer contains 0 to 5% olefin protons before grafting. I Paper size applies Chinese National Standard (CNS) A4it (210X297) ^ (Please read the precautions on the back before filling out this page)-Installed · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Employee Cooperatives 575647 Ministry of Economic Affairs Printed by A8, B8, C8, _ ___ D8 of Intellectual Property Bureau. 6. Application scope of patent 4. The composition of scope 3 of patent application, in which the oligomer contains 0 to 1% olefin protons before grafting. 5 · For example, the composition of claim 1 includes: (i) the reaction product of one or more oligomers and graft monomers; or (Π) one or more oligomers and graft monomers Composition. 6. The composition as described in the scope of patent application No. .1, wherein the graft monomer is an unsaturated acid or an anhydride or derivative thereof. 7. The composition as described in the scope of patent application No. 6, wherein The graft monomer is cis-butene dianhydride. The composition of the scope of patent application item 1, wherein the grafting monomer has an olefinic bond before grafting, and is grafted to the oligomer via the bond. 9. The composition of the scope of patent application item 8, wherein the olefin is The bond is an α, / 3 olefin bond and the grafting monomer is grafted to the oligomer via an α, A olefin bond. 10. The composition as described in the first claim, wherein the oligomer is obtained from -10 Petroleum distillate boiling in the range of ° C to 210 ° C. 11. The composition according to item 1 of the patent application range, wherein the cracked petroleum feed is obtained from steam boiling in the range of -10 ° C to 1 oo ° c. Cracked petroleum distillate 〇 2 2. The composition as described in the first item of the patent application scope, wherein c 8-C1. Aromatic single systems are obtained from steam cracking petroleum saturated products that boil in the range of 135 t to 21 0 ° C. 13. The composition according to item 1 of the patent application scope, wherein cyclopentane;): Greek and substituted cyclopentadiene single system is obtained from steam cracking petroleum distillation boiling in the range of 40 ° C to 200 ° C. Out. This paper size applies the Chinese National Standard (CNS) A4 scale (210X 297 mm) '-(Please read the precautions on the back before filling out this page) -Packing-、 1T line 575647 8 8 8 8 ABCD Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives 6. Scope of Patent Application 1 4. If the composition of the scope of patent application item 1, the oligomer is cyclopentadiene and / or substituted cyclopentadiene and can be selected as required Cs-C " oligomers of aromatic monomers. 15. The composition according to item 1 of the scope of the patent application, wherein the oligomer is a cracked petroleum feed containing G, (: 5 and CO paraffins, olefins and conjugated diolefins, and optionally C 8 -C1. Oligomers of aromatic monomers. 1 6 · The composition according to item 1 of the scope of patent application, wherein the oligomers are oligomers of cs -Cu aromatic monomers. 1 7 · The scope of patent application The composition of item 1, wherein in the graft oligomer: the mole ratio of the oligomer: graft monomer is between 2: 1 and 1: 2. 18. As claimed in claims 1 to 17 of the scope of patent application The composition of any one of the foregoing, including at least one other resin selected from the group consisting of: aliphatic hydrocarbon resin, at least partially hydrogenated aliphatic hydrocarbon resin, aliphatic / aromatic hydrocarbon resin, at least partially hydrogenated lipid Family / aromatic hydrocarbon resin, cycloaliphatic hydrocarbon resin, cycloaliphatic resin at least partially hydrogenated, cycloaliphatic / aromatic hydrocarbon resin, cycloaliphatic / aromatic hydrocarbon resin at least partially hydrogenated, aromatic hydrocarbon resin , At least partially hydrogenated aromatic hydrocarbon resins, polyterpene resins, terpene-phenol resins, pine esters, rosin acid, resins grafted with graft monomers, and Any two or more mixtures. 19. The composition of any one of the scope of claims 1-17, including at least one polyolefin. 20 'The composition of the scope of claim 19, wherein丨 Greek smoke is selected from the group consisting of polyethylene, ethylene α-olefin (C3_C2.) Copolymer, polypropylene, propylene α-olefin (CVC20) copolymer, polybutene, butan j_ olefin (CvCm) Copolymers, polyisobutylene polymers, alpha and olefin di-sintering copolymers (please read the precautions on the back before filling this page) -Packing-Thread -3- 647647 ABCD Printed by the staff of the Intellectual Property Bureau of the Ministry of Economic Affairs 2. The scope of patent application includes block copolymers of styrene and conjugated diene, and mixtures of two or more of them. 21. If the composition of any one of items 1 to 17 of the scope of patent application, including At least one polar polymer 22. The composition according to item 21 of the patent application range, wherein the polar polymer is selected from the group consisting of: polyesters, polyamides, polyureas, polycarbonates 'Polyacrylonitrile, polypropylene Acid esters, polymethacrylates, ethylene vinyl acetate copolymers, polyvinyl chloride, polyethylene terephthalate_ 'polybutylene phthalate, polyacetal, ethylene methyl acrylate 'Ethylene butyl acrylate and a mixture of two or more thereof. 2 3. As a composition according to any one of claims 1 to 17 of the scope of patent application, 尙 includes a kind including ethylene or propylene j: Greek and having 50 to 1 〇 ％% CDBI and polydispersity polymer less than 4. 24. The composition according to any one of claims 1 to 17 of the scope of patent application, 尙 includes at least one 鱲 or oil. 2 5. 申请The composition according to any one of items 1 to 17 of the patent scope, which includes at least one crosslinking agent. 2 6 · A method of grafting oligomers, comprising contacting the following oligomers with a grafting monomer: (a) at least partially hydrogenated pentamidine and substituted cyclopentane 丨Greek oligomers, wherein the cyclopentadiene and substituted cyclopentadiene oligomers are substantially free of norbornyl ester groups and / or include at least one monoalkane after grafting with graft monomers Base cis-butenedioic acid, its anhydride or derivative, or 0 _ 丨 end-substituted propionic acid or its derivative; or this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -4- ^ -1T ------- line (please read the precautions on the back before filling this page) 575647 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 Γ, patent application scope (b) of the following substances Polymers: (i) C4, C5, and C6 chain hydrocarbons; f: cracked petroleum feedstocks of Greek hydrocarbons and conjugated diolefins, (11) Cs_Cl () monomers, (iii) C4, C5 and C6 paraffins, olefins and conjugated diolefins cracked petroleum feeds and C8-C1. Aromatic monomers; (iv) cyclopentadiene and / or substituted rings Diene and Cs-C !. Aromatic monomers; (c) Any combination of (a) and (b). 27. The method described in item 26 of the patent application 5R of the patent application 5R, wherein the graft monomer is An unsaturated acid or anhydride or derivative thereof. 28. The method according to item 27 of the patent application, wherein the graft monomer is cis-butene dianhydride. 29. Any one of items 26-28 of the patent application Item, wherein the oligomer contains 0 to 50% olefin protons. 30. The method according to item 29 of the patent application, wherein the oligomer contains 0 to 5% olefin protons. 31. As described in claim 30, A method in which the oligomer contains 0 to 1% olefin protons. 3 2. The method according to any one of claims 26 to 28 in the patent application scope, wherein the grafting monomer has an olefin bond before grafting, via This bond is grafted to the oligomer. 33. The method of claim 32, wherein the hydrocarbon-burning bond is an α, / 3 olefin bond and the grafting monomer is grafted to the oligomer via the α olefin bond. 3 4. The method according to any one of claims 26-28, wherein the weight ratio of graft monomer to oligomer in the reaction mixture is small In i: 2. 35. If you apply for any of the methods in items 26-28 of the scope of patent application, where --------- ^-(Please read the precautions on the back before filling this page), Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the 1T line 575647 A8 B8 C8 _____ D8 VI. Scope of patent application Grafting monomers come into contact with oligomers in the presence of free radical initiators. 35. The method according to item 5, wherein the free radical initiator is selected from the group consisting of dibenzophenydryl peroxide, dichlorobenzylpyrene peroxide 'dicumyl peroxide, second-tertiary -Butyl peroxide, 2,5-dimethyl-2,5-bis (peroxybenzoate) hexyne_3, 丨, 4_bis (tertiary_butylperoxyisopropyl) Benzene lauryl peroxide, tertiary-butyl peracetate, 2,5-dimethyl-2,5-di (secondary-butylperoxy) hexyne_3,2,5- Dimethyl-2,5-di (tertiary-butylperoxy) hexane, tertiary-butyl perbenzoate, tertiary-butyl perphenyl acetate, tertiary-perisobutyrate Butyl ester, per-secondary_octanoic acid tertiary-butyl ester, pervaleric acid tri -Butyl ester, cumene pervalerate, tertiary-butyl hydroperoxide, tertiary-butyl perethyl acetate, azoisobutyronitrile, azoisobutyric acid dimethyl Esters, and mixtures of two or more thereof. 37. The method of claim 35, wherein the weight ratio of the free radical initiator to the graft monomer in the reaction mixture is less than 2: 2. . 38. The method according to any one of claims 26 to 28 of the scope of patent application, comprising contacting the oligomer with the graft monomer in the presence of a solvent. 39. A method of manufacturing a composition comprising combining at least one other resin with a product prepared by a method such as any one of claims 26-28, wherein the resin is selected from the group consisting of Groups: aliphatic hydrocarbon resins, at least partially hydrogenated aliphatic hydrocarbon resins, aliphatic / aromatic hydrocarbon resins, at least partially hydrogenated aliphatic / aromatic hydrocarbon resins, cycloaliphatic hydrocarbon resins, at least partially hydrogenated Cycloaliphatic resin, cycloaliphatic / aromatic hydrocarbon resin, cycloaliphatic / aromatic at least part of the hydrogen This paper size is applicable to China National Standards (CNS) person 4 threats (210x297 mm)------ ---- ^ -------, 玎 ------- 0 (Please read the notes on the back before filling in this page) 575647 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 6. Patented hydrocarbon resins, polyterpene resins, terpene-phenol resins, turpentine esters, rosin acid, graft resins, and mixtures of two or more thereof. 40. A method of manufacturing a composition comprising blending at least one polyolefin into a product prepared by a method such as any one of claims 26-28. 41. The method of claim 40, wherein the polyolefin is selected from the group consisting of polyethylene, ethylene α-olefin (C 3 —c 2) copolymer, polypropylene, propylene α-olefin (C4_C2Q) copolymers, polybutenes, butene alpha olefins (C5-C 2 0) copolymers, alpha -hydrocarbon storage copolymers, including block copolymers of styrene and cochadiene, and A mixture of two or more of them. 4 2. The method according to item 40 of the scope of patent application, wherein the polyolefin is a polymer including ethylene or propylene with a CDBI of 50 to 100% and a polydispersity of less than 4. 43. The method of claim 40, wherein the polyolefin is a polar polymer. 44. The method according to item 43 of the patent application, wherein the polar polymer is selected from the group consisting of polyesters, polyamides, polyureas, polycarbonates, polyacrylonitrile, and polyacrylates. Type, polymethacrylates, ethyl acetate;): copolymers of polyethyl methacrylate, polyvinyl chloride; (: polymers of polybutylene terephthalate, polybutylene terephthalate, poly Acetal, ethylene methyl acrylate, ethylene butyl acrylate and a mixture of two or more thereof. 4 5 · The method according to any one of claims 26 to 28 of the patent application scope, which comprises blending at least one wax or 6. If the method of any one of items 26-28 of the scope of patent application, the paper size of the package is applicable to China National Standards (CNS) A4 standard (210X297 mm) -------- -Meal -------------- Line (Please read the notes on the back before filling this page) 575647 A8 B8 C8 D8 VI. The scope of patent application includes cross-linked resin oligomer with itself or A polymer combined with a resin oligomer. --------- ^-(Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Property Bureau This paper applies the Chinese National Standard (CNS) A4 standard (210X297 mm) -8-