TW574437B - Electrodeposition device and electrodeposition system for coating structures which have already been made conductive - Google Patents

Description

(i) (i) 574437 发明, description of the invention (the description of the invention should state: the technical field to which the invention belongs, the prior art, the internal technology. The invention belongs to an electrolytic device and belongs to an electrically conductive layer on a substrate. -Electrolytic system for electrolysis.-Use of electrolysis device and electrolysis system to fabricate conductors covering all surfaces. Body structure and conductor layer "For example, using this device can produce antenna coils, printed circuit boards, chip card modules or Similar items. This is the way to date to form conductor structures of this type using corrosion treatment. For this purpose, a metal circular cylinder, which is continuously connected like the same cathode, is at least partially immersed in an electrolyte The electrolyte tank is made to rotate. There is an anode device in the electrolyte tank. Depending on the electrolyte used, a metal layer is decomposed on the slowly rotating cathode. Outside of the electrolyte, this metal layer is formed into a thin sheet. Add on a so-called non-conductive thin plate of the substrate. This method can only produce a metal layer on one side of the carrier substrate. The minimum thickness of the metal that can be obtained is limited. Generally made of copper, the metal falls off the cathode and is added to a sheet made of plastic. Considering the possibility of crack formation caused by subsequent further processing, the minimum limit is _ sheet thickness is about 17 μηι. After a thin sheet-like metal layer has been added on the thin plate, this metal layer has a thickness ranging from 17 μπ ^ 75 μπι, and an etching resist is added to the metal layer, which is then made using lithography technology. Exposure. The subsequent etching steps will be used to cover all the surfaces. These are not required to be etched away from the pattern area with the conductor path. After removing the etch resist that is stored on the metallization of the pattern, The required conductor structure is completed. The method of explanation-6- (2) 574437 method, see introduction, uses the principle of corrosion. The first disadvantage is that because of the use of the principle of corrosion, the required chemical guest is-枓 A consumes a lot and is wasted on the use of a large amount of raw materials (metal layers). ㊉ can only obtain a low amount of growth. The disadvantage of this step is that the anode cleaning of the cylindrical cathode must be performed regularly i * ίΐ [ΙΪ 1 xh ife Μ, iri-, »〇. __ 进 / π 口 π 内 内 少 Γ to go from right to bottom, tpv makes q must be regularly performed L. Although nitric acid can be used to perform the cleaning of the anode, it must be The electrolyte phase of the electrolyte phase is completely eliminated. During this cleaning period, the electrolytic device 2 is not used for production. Instead, it is a known method for searching the state for cleaning purposes. However, this type of tritium, Vermiculite-type &lt; device, in the gland edge mode, because it is necessary-within a short time-to add a very high current, there is a very high Consumption. Therefore, from the perspective of purchase and maintenance costs, installing this type of pulse is expensive. Therefore, the present invention provides an electrolysis device and an electrolysis system according to this purpose. Compared with the prior art, a faster, simpler, and simpler manufacturing process: a substrate with a lower electrical conductive layer can be obtained. This purpose can be achieved by applying for the patent scope (characteristics of electrolysis device reading patent scope item 13 (electrolytic system)) + + ¾. This kind of configuration with excellent polymerization can be obtained from each appendix in the scope of patent application. M ^ is shown in the general term. With the electrolytic device of the above invention, it is possible to carry out an electrically conductive layer on a substrate that already has a conductive structure. # The conductive structure preferably includes the The surface of the substrate is solid and fixed to even a gentleman.—Earth alley plate <conductive particles. The conductive particles added to the surface of the substrate become "non-covered," which means that there is no substance embedded around it. For example It can be said that the conductive particles can be added to the substrate by means of blowing, continuous shooting, rolling and brushing. The surface of the conductive particles and the substrate is sufficiently obtained by (3) 574437: and / or The comparative characteristics of the substrate in the form of an alloy make the surface ultrasonic waves or the addition of conductive electrical particles to ensure the conductivity in actual definition. Therefore, the purpose of one grain can be seen by electrolysis to achieve the safety , Each In the case, at least "and the previous surface, the particles are first applied to the substrate body by means of thermal and / or static and / or magnetic force. The conductive particles graphite or conductive polymer particles of iron, nickel, gold, silver, "Aluminum and copper composition" During the addition to the substrate, the particles are preferably powdered. The composition is preferably composed of a non-conductive material, and the surface of the substrate is sticky. For example, 'by softening the surface or adding a sticky substance, Viscosity becomes active. Softening of the surface can be achieved by heat radiation and the use of solvents, so for this purpose, the surface is treated with a solvent before the particles are prepared in advance. Instead or in addition, The substrate body can also be treated with solvent before. In the case of dissolution-free operation, conductive particles are added to the substrate covering the entire surface of the required conductor structure. The pre-treated electrical particles of the substrate continue to adhere to the substrate, and only here There is a bonding device or an electrolytic system to thicken the conductive micro-electrode by electrolysis. This shows that since the actual need is only a planning aspect, the electrolysis according to the invention It is possible to use the supply to bring the distribution. In the $, the thin plate described, that is, for example, a conductor structure is dominated. The electrolysis device for an electrically conductive layer on the substrate has an anode and at least one contact. Electrolytic cell contact of the switch-on unit-The switch-on unit has multiple electrically conductive areas, and each of the multiple contact and switch-on units becomes the connection between the cathode and anode. The device contains -8- (4) (4) 574437 Proprietary cathode connection element (metal cylinder). According to the electrolytic device of the invention, it has a contact that can connect the cathode and the anode. A private solution device can be defined as a self-regenerating device. This means that this electrolytic device no longer requires an anode roller for connection to the cathode. &Lt; Any downtime in cleaning. As a result, it is possible to obtain a sufficiently high production capacity, so that the unit cost of manufacturing the conductor structure is also reduced. Since only a part of the conductive particles deposited on the electrically conductive area connected to the cathode is used to thicken the substrate by electrolysis, the electrically conductive area is contaminated during the whole process. Since each electrically conductive area becomes an anode connection at least once after it has been called a cathode connection, the contact-switching unit is self-cleaning. At this time, the electrically conducting area for electrolysis is used as an auxiliary cathode. Therefore, since each electrically conducting area of a contacting / connecting device can be connected as a cathode or as an anode, Anode cleaning, this distribution method is so far known only. Depending on its location, the conductive area can be a cathode or anode connection. In particular, different electrical conduction regions can be made as cathode and anode connections at the same time. Since at least one electrically conductive region is always connected to both the cathode and the anode, the electrolysis device can be operated continuously. Conductor structure, for example, to see the fact that the antenna coil or chip module in the preface can be completed and thickened by electrolysis using an electrolytic device, low-cost production is also possible, so separate the separate conductor structures No further processing steps are required. Therefore, the step according to the invention is an additional or semi-additive processing step for manufacturing a conductive structure. (5) 574437 Again, the quality of the metal structure of the electrically conductive layer can be controlled, and f is a very uniform thickness. Furthermore, it is possible to manufacture a double-sided metallization using an electrolytic device according to the invention. For this purpose, it is necessary to add conductive particles to both sides of the substrate in a structured manner before processing by the electrolytic device. In addition to the advantages of forming a double-sided metal layer at the same time, self-regeneration of electricity through contact is also possible. It is also possible for these contacts, together with the conductor structure combined on the opposite major face of the substrate, to have a thickness of approximately uniform layer. The advantage of this step is that it is also possible to manufacture layer thicknesses of varying degrees by changing the current strength of the electrolytic device and / or the rate at which the substrate passes through the electrolytic device in a single operation of an electrolytic device. In each case, it is sufficient to make an electrically conductive region a cathode and anode connection. However, it is also conceivable to simultaneously form a cathode connection for adjacent electrically conductive regions. In this case, it is possible to accelerate the thickness of the substrate by electrolysis. In a similar manner, it is also possible to connect a plurality of electrically conductive regions, but it is not necessary to arrange to be directly adjacent to each other, and at the same time to form an anode connection. The electrically conductive region 'of the contact-switching unit arranged adjacent to the electrically conductive region to be connected like an anode is preferably connected like a cathode. The electrically conductive areas are connected like anodes, forming a complementary anode. _ In principle, the contact-on unit can be of any desired shape, in particular it should match the substrate on which the electrolysis is performed. This reason is that the substrate is thickened by electrolysis, not only a flat substrate but also a three-dimensional substrate. -10-

574437 Furthermore, an improved invention contact-on unit can be connected to a pulse processor. The contact-connection unit is preferably a cylindrical design. The electrically conducting area then extends from one basic face to the other basic face to extend the side face of the cylindrical contact, contact, and connection unit. Chevrolet ’s preference is that ‘if the electrically conductive areas are spaced apart from each other and run in a wave, sawtooth, or ramp shape. The electrically conducting area may also be linear. The wave shape, zigzag shape, or slope shape has the advantages of achieving a consistent high level of reliability for this area of the substrate to be electrolyzed and ensuring the uniform growth of the conductive layer. -If the side of the electrically conductive area is a significant wave, zigzag, or slope, the area of the electrically conductive area that is connected to the cathode is the most suitable if the anode device is shielded by a shielding device advantageous. This area should be shielded because it is not located in the immediate vicinity of the substrate and no current is required to be transmitted. In the area where the cathode is connected, the shielding device can be designed as a wing-shaped side, so that it can avoid direct decomposition on the area where the cathode is connected. Φ It is preferable to provide a holder for pressing the substrate on at least one contact-on unit, and the holder may be a non-conductive roller. The holder can also be designed as a further contact-on unit. The substrate to be electrolyzed can be pressed by the holder onto the electrically conductive area of the contact-connected contact-connected sheet, which is like a cathode. ‘In / alternative configuration, the contact-on arrangement may have sliders that wish to make contact with the area of the substrate on which electrolysis is performed. Special ~ Kao, Keli -11-574437

⑺ Three-dimensional space is achieved with child slides, for example, cut down and difficult to access the substrate area. The slider can be removed or replaced from the object being electrolyzed by pneumatic or hydraulic means. Then a slider, depending on where it is located, determines whether it is a cathode or anode connection. In another configuration, the contact-on unit has a plug that can move about a substrate and can perform different activities as required. Depending on its position, the plug can be connected to a cathode or anode. The contacting / closing unit described here is particularly suitable for thickening printed circuit boards by electrolysis. According to the conductor structure to be electrolyzed, the plug "extends" from the substrate, so as to make a cathode connection at the position of the conductor structure. The plug is retracted into the base, which can be used as the anode connection. This led to the cleaning of the plug which had previously been connected to the cathode. The fact that the report was reported as a two-layer structure and that the first layer was the anode connection, and the fact that the second house was the cathode connection made this possible. Depending on where it is currently located, it can be detected as a connection to the anode or cathode. / The bolts that form an electrically conductive area can be retracted and extended by, for example, pneumatic, hydraulic or electric hoisting techniques. According to the invention, at least An unpacking system with more than one electrolysis device as described on Taijin, which contains a substrate feeding to at least-cutting cup + ~, an electrolysis device to feed into the packaging and feeding device, and a receiving device Let ’s say ~ the substrate is received again. In particular, the substrate can be transported to at least one electrolytic cell in a ring-like manner. In this way, because the electrolytic device is effective and full of time = * — name 1τ machine time, so Get low fees .- and reliable manufacturing electrolytic cell is preferably arranged to collect an electrolytic solution prepared tenon access Fan Yi Shi the collection container placed in the electrolyte solution ^, (iv) the electrolytic solution may overflow, so -12-574437

电解液 The electrolyte in the electrolyte tank appears to be self-replenishing. For this purpose, the collection container is equipped with an electrolyte tank of an electrolysis device through an overflow. In a similar method, the collection container has a pump and a filter that draw the treated electrolyte back into the electrolyte tank. In a selected installation, the electrolysis system according to the invention has at least two electrolysis systems connected in series, and electrolysis using the same electrolyte or different electrolytes

The electrolytic system according to the invention can therefore be a modular structure. The operation and production volume are determined by the number of modules. The advantage of the electrolytic device according to the invention is that it can operate at different current strengths within the same electrolyte, and in particular the anode device and auxiliary anode device can be operated with different current strengths. The invention will be described in more detail with reference to the following drawings, in which: FIG. 1 shows a schematic cross-section of a specific embodiment of an electrolysis device according to the invention, and FIG. 2 shows an electrolysis device The operation and structure of the contact-switching unit used in FIG. 3 shows a cross-sectional view of a specific example of a first example of an electrolytic device according to the invention, which is shown in FIG. 4. The electrolytic system of the electrolytic device illustrated in Fig. 3, Figs. 5 and 6 show various arrangements of a contact-connection unit for electrolysis of a ring-shaped substrate, and Fig. 7 shows a second embodiment of an electrolytic device Perspective-13- 574437 (9) mwm Figure 8 shows a cross-sectional view through one of the electrolytic devices shown in Figure 7, Figures 9 and 10 show in each figure a specific embodiment showing the second example The configuration of the electric conduction area, FIG. 11 shows a specific example of a third example of an electrolysis device in which the electric conduction area is designed in a thin plate shape, and FIG. 12 shows a contact as shown in FIG. 2- Arrangement of the shielding device on the cathode connection area of the switching unitFig. 1 shows a specific embodiment of a first example of an electrolytic device 10 according to the invention. By way of example only, five contact-on units 16 are arranged in the electrolyte bath 14 in order, and the bath 26 is filled with electrolyte. The cross section of the contact-on unit 16 is circular. The explanation is again purely illustrative, and an electrode 28 of an anode device 30 is shown between or close to one of the contact-on units 16. The anode 28 of the anode device 30 can be arranged in any manner in principle. On each contact-connection unit 16, there is arranged a non-conductive material and a holder 18 for pressing the substrate onto the contact-connection unit is shown. In each cleaning situation, the substrate for electrolysis (not shown in the drawing) will be rotated between a roller 1S and a contact-on unit 16 to rotate the substrate. The substrate may be ring-shaped and placed in the electrolyte tank 14 The upper part is introduced, while the other one is sent out. The structure of the contact _.on unit 16 can be seen more clearly from FIG. 2. The pattern of the side surfaces of the electrically conductive region 20 spaced apart from each other can be more clearly seen from the entire periphery of the circular-shaped contact-connection unit. When the electrolytic device is in operation, the contact and connection unit is not driven by a motor. -14- 574437 (ίο) It is inferred from the substrate itself—A, &amp; ^, and 10,000. … The electrical conduction area 20 indicated by 20k in FIG. 2 will be in contact with Linghong Zheba, Nonghe device 22 to form a cathode connection, in order to clean the connection hall and pull wtf a m · »·, contact -Switch on the early stage, and at the same time, contact the electrically conductive area 20 (this area is represented by 20a) with 臬 —, ”彳】 Wan Shisuo ,,, and the two anode devices 24, then become the anode. Connection. When the contact * on unit 16 rotates 360 degrees, each conductive region 20 to y has a polar and secondary connection like an anode. The cathode device 22 and the anode device 24 can be designed, for example, in a wheel shape or The form of a roller is placed on the contact-connection unit 16. In the specific embodiment illustrated by Wang Jinxian, the cathode device 22 and the anode device 24 are arranged opposite to each other. The anode device 24 can be arranged in principle at any of the two requirements. The position, which may be different from what is shown in the drawing, is formed immediately after the cathode &amp; the same as the auxiliary anode #. Therefore, "just after the cathode should be understood to mean that there is an angle close to Bias offset, corresponding to the selected position of cathode 22 Set approximately 9〇 degrees. In fact, the contact-switching unit 16 has a plurality of electrically conductive regions 20, and different conductive regions are simultaneously connected to the anode and the cathode, so that the electrolytic device according to the invention can be continuously operated. The anode connection of the anode device 24 can automatically clean and remove conductive particles decomposed on the electrically conductive area 20k forming the cathode connection. This step enables continuous operation of the electrolysis unit without interruption or unnecessary shutdown. Fig. 12 shows a modified-contact-on unit shown in Fig. 2. Among them, it is shown by way of example first, and the display is a metalized anode device M and a substrate 12. In fact, it is arranged along the inner periphery of the cylindrical contact-connection unit 16. The cathode device 22 and the anode electrode 15-574437, and 30 have nothing to do with the present invention, and they have an architectural configuration. Figure 2 shows the difference between the most obvious difference in the pole connection area 20k. Figures 2 and 5 are arranged on the pole connection area 20k. The masking device 25 is intended to prevent the decomposition of the metal on the area where the flow is not needed. . These areas are indicated by 21 'and the contact point between the area 2Gk and the substrate. If the electric conduction area 20 has 3 cylinders of movement from the 3rd, the 3rd, the 3rd, the 3rd, the 3rd, the 3rd, and the 3rd, the waveform or the surface of the tine or the slope of the pole, 活动, # 咛 咛 know that using this kind of shielding device is very advantageous to illustrate it The shielding device 25 has a wing-like example as shown in FIG. 12. (1) The metalized substrate 12 and the shielding device 25 are indicated by arrows (indicated by the previously formed ridge 13a on the substrate and the electrolytic formation). 13b). Fig. 3 again shows the arrangement of the electrolyte tank 14 and the contact-on unit 6 and the anode devices 22 and 24. The cathode device and the anode device 24 are both arranged outside the electrolytic solution tank 14 by way of example. Rotating Fructus Juice The different conductive areas 20 become the connection between the anode and the cathode. A non-guide roller 18 is arranged above the contact-on unit 16. Electrolysis is performed through a clear slot formed between the roller 18 and the contact-connection unit 16, and the roller 18 is provided with a pressure for pressing a pre-formed substrate against an electrically conductive region of the cathode. In principle, the electrolysis device may include only one contact-on unit 16 and, by arranging a plurality of contact-on units in an electrolytic cell, electrolysis can be performed on a substrate provided with conductive particles to increase the life of the electrically conductive layer. Fig. 4 shows an electrolytic system according to the invention using the electrolytic device illustrated in Figs. Arrange the electrolytic device 10 in a collection container 46

It indicates that the special side of the negative power transmission device is 0. The cathode 22 is shaped behind the head, and the substrate for the electricity is visible. 〇 The cooking rate is set. -16-

574437 is inserted into the overflow 48 of the electrolyte tank 14 and transfers the overflowed electrolyte to the collection tanks 46. The collection container 46 has a pump 50 that pumps the treated electrolyte back into the electrolytic bath liquid 14 and has a filter. The electrolytic system other than that shown in Fig. 4 is particularly suitable for processing a substrate in a ring form. A substrate having conductive particles has been formed, and is wound around the feeding device 42 in a drum shape. The substrate is guided by the feeding device 42 into the electrolytic device 10 in the direction shown by the arrow, and the substrate passes between the respective contact-connecting unit 16 and the roller 18, and is removed again on the left-hand side of the electrolytic device 10 . The substrate which has been thickened by electrolysis is passed on a T-shaped mop 52 to remove the attached electrolyte. The substrate, which is still in the shape of an endless belt, enters a rinsing device 56 through a guide wheel 54. The substrate is turned by two guide wheels 58 and enters and passes through another T-shaped mop 60, and the other guide wheel 62 and the spray rinsing device 64 enter a purifier 68. After the substrate passes through another τ-shaped mop 72 and is guided through a dryer 74 for drying, finally the substrate is wound back to a receiving device 44 in the shape of a drum. Substrates that have been thickened by electrolysis can now be separated for further steps. It should be emphasized again that the conductor structure at this time has become its final form, that is, it is no longer necessary to perform any further etching steps or further structure processing on it. Fig. 5 shows an exemplary embodiment in which a further contact-on unit 16 has been used instead of the roller 18 for generating pressure. In this case, the two respective contact-on units 16 are arranged opposite to each other so that the substrate can pass between the two again. In order to simplify the design, the electrolytic solution tank and the anode device 30 have been omitted in FIG. 5. Fig. 6 is also the same, in which the contact-on units 16 -17- (13) (13) 574437 are arranged next to each other by way of example. Therefore, the base plate 12 is passed through the zigzag shape between the contact and connection units 16 and the required force can be ensured by the offset arrangement in each case. First, even if these metallized substrates do not have a pass_contact, = 2 is shown in the contact_connection unit 16 of FIGS. 5 and 6, and the two sides of the substrate are given I: 日 :: 化 can also be manufactured. If the substrate does have a through-contact, and if the conductive structure with the above-mentioned form has been provided before the treatment of the invention and the invention 4 &amp; electrical conduction plus: electrolysis device, only _ one side of the substrate will be used It is sufficient to connect on a contact-on-early 7L-16. Nonetheless, because the through and contact are automatically thickened, it has good electrical conductivity and can be used for materials. -And on the far side of the contact-connecting unit 16 a unit of ancient soldiers &amp; metal with a conductor structure is formed, so it can be ensured that the metallization of the two sides is tens of tons. This is a conductive structure with a layer thickness of approximately a fixed value; A metal unit is then formed by -contacting and bonding the conductor. Fig. 7 shows a specific embodiment of a further example of the contact-switching unit 16 according to the invention. Now force,, ~ contact-turn on the early element to become a thin plate-like shape. It consists of points that are adjacent to each other but separated by wind, and a plurality of κ κ Μ ° bolts 36 that can be placed downward in the bottom plate 34 can be removed from the bottom plate 34 to a defined position. The control mechanism not shown is to perform electrolysis of the substrate. It can be seen from Fig. 8 that all of the six sores 36 have been removed from the base plate 34 to the main sores.

^ &lt; position. The bottom plate 34 includes two layers 38, 4C. The first layer 38 is connected like an anode, and the second layer 40 is connected like a cathode. Of course, layers 38 and 40 are electrically insulated from each other. Ebolt -18- 574437 (14)

The position of 36 can be individually determined whether it is a cathode or anode connection. This can be seen more clearly from Figs. 9 and 10, which show a bolt 36 outside the restricted position of its bottom plate 34 (Fig. 9) and a bolt 36 within the restricted position of its bottom plate 34 (Fig. 10). The bolt 36 has an insulator 82 having a greater length than the thickness of the second layer 40. A conductive region 80 conforming to the diameter of the bolt 36 is brought into contact with a contact surface on which it can be moved. As shown in Fig. 9, if the plug 36 is in its restricted position, it becomes a cathode connection. In contrast, if all the bolts 36 enter the bottom plate 34, they are connected to the anode. The contact-switching unit 16 shown in Figs. 7 to 10 is particularly suitable for thickening a printed circuit board having a required conductor-frame structure by electrolytic plating. Because the pick 16 is arranged at a regular interval with each other, by moving the bolt% to its limit position as shown in FIG. 9, it is possible in principle to remanufacture any required conductor structure 1. The bolt is retracted regularly to it The restricted position shown in FIG. 10 can ensure that the electrically conductive area 80 connected to the U plate for electrolysis is in a normal position for cleaning the anode. FIG. 11 shows another specific embodiment of the contact-connection unit 16. The contact-on unit 16 is made into the form of a conveyor belt, and a plurality of sheets 90 are mounted along the conveyor belt. The sheet 90 is connected to the conveyor belt through an articulated connector 96, and the sheet is away from the articulated connector. There is only one electrically conductive region 94 at the end, in other words, there is-an insulator% separating the two. When the conveyor belt is rotated, the result is that the teleconducting and conducting areas 94 alternately form cathodes and anodes. The connection sheet 90 and the substrate 12 indicated by the symbol K are in contact with each other for electrolysis. connection. Until a slice reaches the transport belt "a predetermined position, this situation forms the connection of the anode (Α) • 19- 574437

And a clean way. In principle, the design of the contact-making unit is unlimited regardless of its shape. In particular, as long as the contact-on unit can cooperate with the substrate on which electrolysis is performed, it is feasible even in the area undercut. The illustrated electrolytic device can also be operated in a known pulse mode. And the device can use all known commercially available electrolytes. It will become clearer from the description of the electrolytic device according to the invention that the electrolytic device can be accompanied by a certain quality and high productivity, and the manufacturing cost is low. The part of the conductor structure required for the manufacture of the required conductors, based on the need to perform electrolysis-one of its advantages-. A further advantage is that, since all relevant devices used for control purposes can be arranged outside the electrolyte tank, the illustrated electrolytic device is simple to manufacture and easy to maintain. In particular, for an electrolytic system of a plurality of contact-on units shown in Fig. 4, it is possible to arrange the contact-on units in series. Then the workload depends only on the number of modules and the application thickness required for the conductive layer. In this case, it is possible to manufacture a substrate with a uniform quality that has not been seen so far, and combining the lowest possible price in both the regular processing and the circular processing. Description of Symbols of the Drawings 10 Electrolytic device-12 Substrates 13a, b Conductive layer 14 Electrolyte tank 16 Contact-on unit -20- 574437 (16) 18 20, 20a, 20k, 21 22 24 25 26 30 32 34 36 38 38 40 42 44 46 48 50 52, 60, 72 54, 58, 70 56 64 68 74 80 Roller electrical conduction area cathode device anode device shield device well / tank anode device slider bottom plate-bolt-first layer (anode) second Layer (cathode) Feeding device Receiving device Collecting container Overflow pump / filter T-shaped mop guide roller rinsing device-spray rinsing · device copper passivator drying hair dryer conductive area

-21-574437

(17) 82 insulator 90 sheet 92 insulator 94 conductive area 96 articulation

-twenty two-

Claims (1)

* -------------— Amendment of Supplementary Benefit Application Θ Replacement (October 1992) Pick up and apply for patent scope 1. A kind of electrolysis-electrically conductive layer on the substrate (12) An electrolysis device (10) comprising an electrolyte device (30) in which an anode device (30) is arranged and at least a contact-connection unit (16) (1 sentence, each contact-connection unit (16) has multiple Each of the electrically conductive areas (20), in each case at least one of the electrically conductive areas becomes the connection between the cathode and the anode. 2. If an electrolytic device according to item 1 of the patent application scope is characterized by a plurality of electrically conductive areas The area (20) can be connected to the cathode or anode at the same time. 3. If the electrolysis device of the first or second item of the patent application scope is characterized by each electrically conductive area (20) of the contact-connection unit (16) ) Can be connected like a cathode or anode. 4. The electrolytic device according to item 1 of the scope of patent application is characterized by connecting the contacts arranged in the vicinity of the electrically conductive area (20) as an anode-like contact and connection unit (16 ) 'S electrically conductive area (20) is connected as a cathode and forms a supplementary anode. 5. If applied The electrolytic device according to item 1 of the utility model is characterized in that the contact-connection unit (16) has a cylindrical design. 6. If the electrolytic device in the application item 5 of the patent application is characterized by the electric conduction area (20) in a circle The side surface of the cylindrical contact-connection unit (16) extends from the opposite to one of the other basic surfaces. 7 · If the electrolytic device of the scope of patent application No. 6 is characterized by an electric conduction area (20) It is separated from each other and moves in the shape of a wave, a tooth or a slope. O: \ 81 \ 81279-921 (X) 2.DOO 8 Apply for the annual profit range title page: Device, which is characterized as a slave anode device that becomes a cathode (30) 8) If the area of the electrically conductive area (20) of the electrolytic connection (7) in the scope of the patent application is covered by the area 0 9 · If the electrolytic device of the scope (i) of the patent application is covered, it is characterized by a ) Press down on at least one contact and turn on the holder of the unit (I.) 10. If the electrolytic device of the scope of patent application item 9 is characterized in that the holder is a further &lt; contact-on-unit (16) or A non-conducting roller (18). 1L electrolysis as described in the first patent application scope It is characterized in that the contact-connecting unit (16) has a sliding sheet intended to make contact with the area of the substrate (12) where electrolysis is performed. 12. If an electrolytic device according to item} of the patent application, it is characterized by contact- The connection sheet 7C (16) has a movable bolt (36) on a base plate (34) that can perform different activities as required, and the bolt can be a cathode or anode connection depending on its position. &Lt; 13 · For example, the electrolytic device of the scope of application for patent No. 12 is characterized in that the bottom plate (34) is a two-layer structure, and the first layer (38) is connected to the anode and the second layer (40) is connected to the cathode. 14. An electrolysis system having at least one electrolysis device (10) as claimed in any one of claims 1 to 10, comprising: feeding a substrate (12) for electrolysis to at least one electrolysis device (1〇 ) A feeding device (42) and a receiving device for receiving the electrolyzed substrate (丨 2). 15. The electrolytic system according to item 14 of the scope of patent application, characterized in that the substrate (12) is fed to the at least one electrolytic device (10) in a ring form. 16. The electrolytic system according to item 14 or 15 of the scope of patent application, characterized in that the -2- O: \ 81 \ 81279-921002.DOO 9 574437 electrolytic device (10) is arranged in a collector (46), There is an electrolytic solution tank (14) with an electrolytic solution, and the filtered electric tank overflows, so that the electrolytic solution appears in the electrolytic solution (14). 17. According to the scope of the patent application, 14 electrolytic systems are connected in series using the same electrolyte or different electrical devices (10). Application for patent application page 1 The solution placed in the collection container can be self-replenished by the electrolyte and has a self-replenishing feature which is characterized by at least two electrolytic operations for the solution operation 0: \ 81 \ 81279-921002.DOQ 9