TW574279B - Surface treatment apparatus and surface treatment method - Google Patents

Description

574279 i No. 9] m good j V. Description of the invention ^^ _ a ^ .χ [Technical field to which the invention belongs 1 The present invention relates to surface treatments and difficult-to-access vehicle components and surface treatment methods, especially methods. Surface treatment device and surface treatment for earth material [Background Technology] Most vehicle components use hard-to-adhere bases composed of silicone, polyurethane resin, fluorocarbon resin, polyethylene resin, etc. = material . However, it is difficult to connect or water-repellent because of this, so it is generally difficult to: "::, often has a surface treatment of hydrophobic outer line coating. Special ;; when the component is followed by stamping, purple three-dimensional processing or foaming, it will Difficult adhesive materials are mixed and not smooth, and it is difficult to regenerate the surface structure of the substrate with other members. Therefore, in order to improve the surface characteristics of the materials mentioned above, the dipping device or 4 = difficult adhesive substrate is used. Or apply Shishiya coupling agent or titanium coupling on its surface; Category: Primer coating, in order to obtain the prescribed modification effect, a large number of primers and husbands are often required. However, there are also problems in the manufacturing process. The Mori is also relatively long, so this is the system. As an alternative to primer coating or coupling surface modification methods, the method currently being studied is corona discharge treatment, plasma treatment, surface-imparting induction substrate: wire : Shooting method, branch method, sand blasting method, solvent treatment and acid mixing solution treatment / = light connection method. Treatment of various surface changes 91124440-91081NKTCJP-F017TW.ptc Page 4 2003. 07. 02 · 〇〇 4 574279

For example, in Japanese Patent Application Laid-Open No. 5-689 34, a method of exposing ancient ΐ = high-pressure mercury lamp to illuminate the surface of hydrophobic plastic with ::, 使, and 使 to make the wettability and adhesion of the k-guard layer. US _ ^ Bu 50986 1 8 ^ ^ ^ ® t > A method for selectively weaving and adhering to the surface of a UV-adhesive R coating with a wavelength of 185rm and 2 54nm. In addition, said = flat; ^ # ^ _ consumption & wet-bleaching plastic surface \ gas, corona treatment with high repeated pulses. In Japanese Patent Application Laid-Open No. 8 1 09228, the gazette also revealed that the dyeing properties can be improved.

After the surface is subjected to ozone treatment, surface treatment, plasma treatment, corona treatment, high-pressure irradiation, etc. === After the surface activation treatment, etc. === 8. However, the aforementioned surface modification method not only does not improve the surface characteristics: There are various problems as follows: pollution of the operating environment, potential dangers of environmental problems, environmental problems, and other operational problems such as washing and waste water treatment. Economic issues such as high prices.

It can be removed. As for the simple and cheap surface modification method, although the surface of the difficult-to-adhesive substrate is flame treated, the modification of the surface characteristics represented by the wet finger = contact angle is not. Sufficient, and the effect is maintained for a long time. Furthermore, as disclosed in Japanese Patent Application Laid-Open No. 9-1248 1 0 = No, when the surface of a difficult-to-adhesive substrate is flame-treated, there is still a problem that the valley is liable to thermal deformation. -Therefore, 'the inventors of the present invention, as disclosed in DE 0010 0 1 9926Al, have also proposed a method for modifying the surface of a solid substrate, which method includes two

574279 V. Description of the invention (3) Step: First, use a gas burner to at least once oxidize flame treatment on the surface of a solid substrate of a metal or glass product to modify the surface; and then perform at least one oxidized flame treatment on the surface to make the surface Improved. By adopting such a solid substrate surface modification method, the surface of the solid substrate can be surely subjected to modification treatment 'to obtain the effect of firmly adhering to printing inks or ultraviolet curable coatings. However, the disclosed method for the modification of the surface of a solid substrate is based on the use of a tetramethoxylite yakaya (Buddhist point 12 2 ° C) -type yoshinoyan yakiya compound as a silane compound. When a large amount of an alkoxysilane compound is mixed with air or the like, a phenomenon of partial incomplete combustion tends to occur. In addition, an additional oxidizing flame treatment step is included before the oxidizing flame treatment of Shixi, so although an excellent modification effect can be obtained on the surface of the solid substrate, it is found that the bean time becomes longer. Therefore, the present inventors have conducted careful research and found that: using flip == $ and applying a flame generated by a fuel gas containing a silane compound at the same time, the vehicle components can be extremely quickly and efficiently. Large-scale inaccessible substrates are surface-treated to complete the present invention. The present invention provides a surface treatment for the difficult-to-adhesion-based efficiency of vehicle components, so that the foamed layer or the lining = i and the decorative layer can be firmly adhered to the surface treatment. And surface treatment methods.

【content】

574279 Amendment: _Case No. 911244 such as _ V. Description of the invention (4) ^ The generating unit and the substrate processing unit are set to have the surface treatment charge derived from the compound containing Shi Xixuan; and the fuel derived from the fuel The flame of the gas jet: The substrate processing unit has a substrate for making the substrate difficult to adhere to:: == before and after, making the substrate difficult to adhere to: designated: flat: "turning table for condensing and moving &Amp; The water-thousand axis is essentially flat: When the surface treatment device of Mao Qiming is installed, it is advisable to turn over the worktable system fixture to fix the difficult-to-adhere substrate. There is a solid fixture to use this fixing The whole [= turn processing, when set, it should be adjusted for the angle. The angle adjustment base to the angle with respect to the vertical direction [Material Department: When processing equipment, the fire culture generating unit * as a table constitutes the frame At the same time, the above-mentioned reversing system and the aforementioned flames are released: t: 2, when the device is installed: should be controlled [6] and 'constitute the surface of the present invention] :: machine. According to the memory shape correlation [7], the birth of the present invention: ^ It is a control device which is characterized by using the package :: method; mounting properties, surface treatment of the material = middle surface treatment surface, and the production section, so that 91124440-91081NKTCJP.F017TW derived from the fuel gas containing silane compounds. ptc p. 7 2003.07. 02. 007 574279

_ Case No. 9112444η V. Description of the invention (5) The steps of flame ejection; ★ The steps of ejecting the flame under the condition that the former material is processed to make the above-mentioned difficult-to-adhere base material hall; The shaft is centered on the surface of a difficult-to-adhesive substrate after surface rotation of the turning table. In the implementation of the surface treatment method of the present invention, it is difficult to adhere a certain material to a polyolefin resin, a polyurethane resin, and a base material cool misty night S 4 At least one kind of resin, such as silicone resin or poly-surface resin, is composed of at least one kind of resin. Brief Description of the Drawings Fig. 1 is a diagram for explaining the device according to the present invention. Fig. 2 is a diagram for explaining the method of the present invention. Fig. 3 is a table for explaining the present invention. Fig. 0 Surface treatment according to the first embodiment. Surface treatment of a surface treatment device. Fig. 4 is a perspective view of a front instrument panel. Figure 5 is a perspective view of the door. Figure 6 is a perspective view of the seat. Figure 7 is a perspective view of the operation box. Fig. 8 is an oblique view of the interior material mounted on the door & morning door. Figure 9 is a perspective view of the bumper. Fig. 10 is an oblique view of a vehicle ornament.

FIG. 11 is a diagram for explaining a method of forming a powdery shell of a decorative member

574279 -__ Case No. 91124440__year $ day Amendment ___ 5. Description of the invention (6) (one). Fig. 12 is a diagram (No. 2) for explaining a method for forming a powdery shell of a decorative member. Fig. 13 is a diagram for explaining a method of manufacturing a three-dimensional decorative member by using the surface treatment apparatus according to the present invention. ^ Figures 14 and 14 are diagrams illustrating three-dimensional decorative pieces. Fig. 15 and Fig. 15 are diagrams for explaining a method of layering a decorative member when manufacturing a three-dimensional decorative member. [Surface [Section No. 10, Fuel 12; Treatment Transfer for Application] The following describes the best embodiment of the surface treatment device and method of the present invention in detail with reference to the drawings. 1st Embodiment] The first state is shown in Fig. 1 and Fig. 2. The surface treatment device includes a surface including a flame generating portion and a substrate processing portion, and the flame generating portion is provided for supplying stone-containing firewood. The dance of the compound ": 9 and the substrate treatment part for spraying the flame 8 originating from the combustion gas has a difficult-to-adhesive property, and a hard-to-adhesive material is made before and after the injection is made = simultaneously The turning table 18 for surface movement is featured. ， 7 " The shaft 20 is the center. The flame generating part contains the storage tank 9 and control containing the compound as shown in Figure 2. The flame generating part should be used to store the compound. Tibetan machete k W points, containing

2003. 07. 02. 〇〇9 574279 jj 9 ?? 24440 V. Description of the invention (7) The injection of the fuel gas flame 8 is to make the position of the injection device 12 as a congratulatory part and Contains used parts. Drive device 1 suitable for δ movement (1) The drive of the storage tank (1) is shown in Figure 3, the fire and the μ are used to store the silane compound 34 "!" The upper part is equipped with heating means 36 'gas and other combustion-supporting gas The second storage tank (Fu: gang _ ^ and the storage of compressed air under the first storage tank 32 are prepared from A to Erbu). In this example, it should be a force opening formed by the plus plate of the exchanger, or a thermal conductor, or connected to the means 36 at normal temperature and pressure, so that the liquid E compound 34 is difficult to adhere to. The surface treatment period 36 of the material is to heat the stone Xihua in the first storage tank 32 and use the energy-saving energetic material 4 that is heated by a heating hand to heat to a predetermined temperature and make it lice, and assist the combustion gas. (Air, etc.) σ 'Formation of combustion gas. The content of silane compounds in the combustion gas should be controlled indirectly by the content of Shi Xixuan compounds. To: Therefore, a pressure gauge (or liquid level gauge) 38 is set up to monitor the silicon betin tank. 32 pressure (or the amount of silane compound). In addition, although the feature of the present invention is that a part of the silane octahedron is used, the boiling point of the silane compound used as the combustion gas is preferably in the range of 10 to 100 ° C. Under pressure) The reason is that the boiling point of the related silane compound is not. It is volatile and sometimes difficult to handle. On the other hand, if the phase u0, when the boiling point of the compound exceeds 1001, the silanization with air-assisted 3, lactate, or combustion-supporting 91124440-91081NKTCJP-F017TW.ptc page 10 2000.07. 02.010 574279 Month_M No. 91124⑽ V. Description of the invention (8) The mixing property of the agent will be significantly reduced, and it will be easy to make, so that the surface of the substrate that is difficult to adhere to will be changed. The incomplete combustion will keep the modification effect. It is difficult to keep it for a long time, so it is more suitable to be within the range of the boiling t of the related silane compound, which is 2. ~ 6 (rc Fanyuan point and is controlled in the structure: limit Γ:;: == ::: The money-receiving compound itself is adjusted by using a low-boiling dioxin ... mixed compound. Although the alkoxysilanization type with a relatively low coin point is not particularly limited, for example, an alkenylsilane compound or an alkoxysilane compound can be used. In the capture, the -based ... composite-average point is low; low change :: after: Ϊ: combined, can be mixed with air, etc. 'is a more suitable money compound., Shixi burned compound' The following compounds can be selected: used alone or in combination of two or more compounds: tetramethyl stone Hyun, tetraethylsilane, 1,2-dichlorotetramethylsilane, 12 ~ diphenyltetra, 1,2-digastetraethyl crushed, dibenzyltetraethylsilene compound. ,, 2-Digas tetramethyl money ". Second comparison: physical: its surface modification effect is particularly good I, it is a more suitable silanized population. Because of the aforementioned compounds, the oxybenzyl compound is attributable. For its cool structure, 91124440-91081NKTCJP-F017T ^ .ptc Page 11 2000, 07.02.011 574279

Modification Although Y is mostly the one with a higher boiling point, if it has a boiling point in the range of 10 to 100 ° C, i can exhibit a better surface modification effect for difficult-to-adhesive substrates, which is a more suitable silane compound. When measured by a mass spectrometer, the average molecular weight of the silane compound should preferably be within a controlled range. The reason is that if the average silane compound is less than 50 ′, the volatility is high and the operation is difficult. On the other hand, if the average molecular weight of the t f compound exceeds 1 000, it is difficult to mix with air and the like by heating the gas. Therefore, when measured by a mass spectrometer, the average molecular weight of the silane compound is preferably controlled in the range of 60 to 50 0, and more preferably in the range of 70 to 200. ^ The density of the Shixiyan compound in the liquid state should preferably be within the range of 0.3 to 0.9 g / cm3 ^. The reason is: if the density of the related silane compound is less than 0. "/ cm3, the operation is difficult and it is more difficult to store it in an aerosol can. On the other hand, if the density of the related silane compound exceeds 0.9 g / cm3, it is difficult, and at the same time, when stored in an aerosol can, it will be in a state away from the 7G king such as air. Therefore, the density of the silane compound should be controlled within the range of 0.4 ~ 0.82 / (: 1113). It is more suitable to control within the range of 0.5 ~ 〇7 § / (: 1113 (2) Conveying section% delivery section as shown in Figure 3, generally has a tubular structure, the conveying section has the first storage tank 32 Ishibaki compound 34 and a combustion-supporting gas (air) from a second storage tank (not shown) are mixed together to form a combustion chamber 42 ′: a valve and a flow rate are provided for controlling the flow rate Word ten, or for controlling the combustion gas pressure gauge 4 8 is appropriate

2003. 07. 02.012 574279 V. Description of the invention (ίο) After the combination, for the mission: the body is evenly mixed with the pump or the baffle plate for extending the residence time according to the specified ratio. "Supreme" again ~ (3) The fuel gas of the injection unit is burned, and the spray for spraying the surface of the sexual substrate sent by the conveying unit 44 is "injection to the treatment object is difficult to follow the gas Although the type of device is not "歹 ·: flammable milk state). Also related to Rensi, species, pre-mixed gas burners, ^ type In addition, gas burners: two :: I :: gas burners, pulverized coal gas burners, and so on. The direction toward the front end ~, = j is particularly limited, and it can be shaped as shown in Fig. 3, with the injection ports arranged laterally. ] Kaiba. Structure can also be approximately rectangular. In addition, the configuration of the spraying section, that is, _ when considering the shape of the substrate that is difficult to be adhered to the object to be treated: 3 and :: 'Should be the second and difficult to access / surface modification of the substrate = Properties :: fixed weight, etc., (4) drive unit 丨 1 is appropriate for the difficult to adhere to the substrate should be equipped with a drive that includes a drive device ^ = J fire know generating unit automatically installed as an outfit The shape 'down' can move freely in three dimensions. After the flame H robot arm, regardless of the shape of the substrate being difficult to access ^, Tian You can perform the surface treatment of the substrate and the shape of the substrate can be 9l08lNKTCJP-F0l7T \ V.ptd page 13 574279 V. Description of the invention (11) The automatic arm wants to appropriately control the length and position of the arm, the position that it should be directed to and the distance between difficult-to-adhere substrates are often controlled, and this positional relationship can often be maintained at the surface of the uniform sentence. That is, as shown in FIG. 2, the automatic arm is provided under the seat a bucket eighteen 16 and is provided with wheels 16a and guide rails. Its management mouth ’The seat mouth = The coordinating movement between Shulunxian and Guijin = 糸, and the position of the charge moves quickly and smoothly in the horizontal direction. Shape and: Γ Γ :! The raw part can move freely in three dimensions corresponding to the shape of the difficult-to-bond base material, and change its position. -(5) The flame generating part of the ignition device is equipped with a fire device and flame detection means for injecting fuel gas. If it is set, it can spray the flame or detect the flame ejection of the flame generating part. The substrate processing unit must be the same as the cattle and 吝 L. The reason is: It can reduce the consumption of fuel gas, as in "secondary ignition and flameout, so in addition, when the flame generation part = the amount of carbon oxides. Minutes, it is necessary to rely on the flame ^ fire ^ = or injection The flame is not charged, and then the safety device detects the state of the fire 2 and measures the state to make it fire again according to the conditions. &Quot; Flame spray of the Ministry of Health, or as shown in Figure 1, install the device in the spray. The general ignition gas is used to make the auxiliary ignition device. The cough-fire fire used for the oxidized flame treatment of Shi Xi; 8 places ^ / combustion state, and at the same time, the injection device 12 that implements the flame 8 is preferably 91081NKTCJP.F017TW. ptd page 14 574279

Who 耔 Et 令 甘 谉 沁 # \ Caimen, such as the auxiliary ignition device i ^ a from the time of the application of silicon oxide flame treatment ^ a from the time before the cooking time "二 乂 V u will close the injection device f near the auxiliary ignition device M ° ρ σ Point, therefore, 'with the auxiliary ignition device 12a, the ignition program can be interspersed and extended,

(6) Control device 1 can be used, P

As the control device of the flame generating unit, a position control system including an automatic arm and a shape memory (storage) device of the object to be processed are preferable. The reason is that, with such a control device, it is possible to correctly recognize the existence of difficult-to-treat substrates of the object to be treated, and then regardless of the shape and size of the difficult-to-adhesive substrates, the flame-generating part can be uniform and rapid. Surface treatment. Therefore, once the position and shape of the substrate to be treated is difficult to adhere to, the surface treatment can be performed quickly based on the identified information. In addition, the control device of the flame generating portion is preferably a control device that also serves as a substrate processing portion. That is, it is preferable that the control device of the flame generating section is synchronized with the operation of the substrate processing section, and the flame processing is performed while controlling the position of the automatic arm of the flame generating section. 2 · Substrate processing unit (1) The surface modification device of the first embodiment of the turning table is as shown in Figs. 1 and 2. It is preferable that the substrate processing unit contains a rotation or The semi-rotating turning table 18 is used to perform surface modification of a difficult-to-adhere substrate. That is, each of the two or more difficult-to-adhesive substrates is held in a fixed state by using both sides or one side of the turning table, respectively.

91081NKTCJP.F017TW.ptd Page 15 574279 V. Description of the invention (13) The surface modification shall be carried out on either side or in order on either side. The reason is: use this kind of reversing process.-A difficult-to-adhesive substrate is subjected to a surface treatment. 3 =: = = = A large-sized, difficult-to-adhesive substrate such as a cleverly-adhesive substrate is a fixed preparation. Surface treatment of soap truck components. j ”柽 The i8 (m and I shown in the figure is implemented quickly and efficiently. The turning table is mainly composed of a substrate placing part angle adjustment member (not shown) and a turning table of 28 and structure. Significant Tigu ;; Li You Department. Using this type of binding device and angle adjustment for efficiency. It is expected that by controlling the installation, it is possible to quickly implement the fixation of difficult-to-adhere substrates. * Table :: Quality; Second turn ;; Work ί; In order to make up the difficult-to-adhesive substrate (A) at a fixed ^ ^ turn: as the platform 1 8 Μ, < from the surface of the surface to the surface treatment, when the car platform 18 is in a vertical position, the Turning table 18: It has the function of the wall part as a part of the frame body 17; With this function, the turning table can be released to the right part of the right saki π field protection and flame preparation. The fire of the fire prevention part is effectively prevented. (2) Fixing fixture; The rotary table should be provided with fixing fixtures 26, 27 as shown in Fig. 2. The fixtures 26, 27 'hold the difficult-to-adhesive substrate at a predetermined position, and the surface modification is performed in this state. The reason m has =

574279 V. Description of the invention (14) __ The turning table of the fixed fixture, when it is difficult to connect the table and rotate it, the positions are exactly the same, and the surface modification is correctly performed for the difficult connection = work = degree. The shape of the fixing jig is not provided: Material 2: The figure shown should be composed of claw-like parts 2, which can be easily fixed, and two locking pieces 27, which can also be fixed by cattle. And frame 3. The frame The flame generating portion and the substrate processing portion should be substantially contained in the frame 17 as shown in Figs. 2 and 2. The reason is that # 图 锦 不 ， Because of the internal storage of the flame generating part and the frame, you can get the safety treatment of the substrate and the substrate processing part, which can provide a safe insert. For%; brother. Therefore, it is possible to operate the flames and heat of the flame generating section with ease. ", While taking into account the fire but 疋 'as shown in Figure 2, the fire and the name of the device and other equipment should be set in the frame ^ 17 \ ^; fuel tank 9 and a fixed platform nil1 control Π outer wall connection = Side, if it is arranged in the frame, etc., the reason is: the fuel tank is configured so that the silly U ten random dice can be easily supplemented. At the same time, the outer wall of the fuel tank, which is the flame, is completely separated. , P χ 口 ΡDepends on the environment.] Wu Wang knife away can provide operations with excellent security such as: 于 = should be equipped with a mobile phone in its lower position, such as a car to make it moveable ... Hands slave, for example, when using fork surface modification to be placed in the housing, i will be difficult to adhere to the substrate forming machine: two can easily reach the vicinity of the machine or the difficult to adhere to the substrate coating $ 17 pages 91081NKTCJP-F017TW.ptd 574279

5. Description of the invention (15) Near the device, for example, it is possible to arbitrarily and conveniently constitute the entire processing system from the difficult to adhere to the decoration. & 4. Object (1) Hard-to-adhesive substrate The type of hard-to-adhesive substrate used in the first embodiment is not particularly limited, and at least one resin can be selected from the following resin groups ... Ethyl amino resin, fluorocarbon resin, silicone resin, polyester resin, polyethylene resin, polypropylene resin, modified polypropylene resin, polymethylpentene resin, ether resin, polycarbonate resin, polymer Ether_resin, polyacrylate resin, polyether ether ketone resin, polyimide resin, polyimide resin, polystyrene resin, polyimide resin, polyphenylene sulfide resin, ethylene-tetrafluoroethylene Copolymer, polyfluorinated vinyl resin, tetrafluoroethylene-perfluoroether copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, polytetrafluoroethylene resin, polyvinylidene fluoride resin, polytrifluoroethylene resin , Ethylene-trifluoroethylene copolymer, poly, rubber, polyurethane rubber, fluoro rubber, stone rubber, = H-associated rubber, ethylene_propylene-dilute hydrocarbon rubber, styrene vinyl heat Plastic elastomer urethane-based thermoplastic elastomer. Dan r Ze :::: ', especially the contact angle A, the polyethylene with a small wet index, the polyester resin, the auricular resin, etc ... Resin, polycarbonate resin, polytetrafluoroethylene effect. (2) Filling material W T is difficult to adhere to the substrate and is a metal material, inorganic filler or

V. Description of the invention (16) Dimensional fillers. This kind of metal material or two or more kinds are used together: aluminum, y bucket and one of the following metals: gold, copper, iron, silver, zinc, tin ^, stainless steel, nickel, chromium, crane, material Select one or more groups: nettle. The inorganic filler is preferably made of the following materials: zinc oxide, oxide, tin oxide :::: used: titanium dioxide, oxide, zeolite, gold, silver, copper, zinc, nickel, talc, calcium carbonate, lime,:. The fiber is declared as the following fiber; 2 m glass, ceramic *, polyamide fiber, metal fiber H fiber = fiber, poly i fiber is relatively difficult to connect, raw materials; ^ = or fiber, the overall addition amount α range. In addition, it is controlled to 1 ~ 3 0% by weight. (3) Morphology = If the shape of the substrate is three-dimensional: it should be cylindrical, columnar, spherical, block, inner tube, etc .: Do not restrict A \ Membrane, fiber, dimensional, fabric, bundle, etc. As shown in Fig. 4, the household weight-convex 4 meter = 1, the door 102 shown in Fig. 5, the operation box 104 shown in Fig. 6 of the seat, and the car box shown in Fig. 8 ΐ ?: Bucket 105, bumper 106 shown in Fig. 9 and accessories of vehicle type 107 are acceptable. _No, even if the adhesive substrate has a flat structure such as a plate shape, a sheet shape, a rectangular shape, a disk shape, or a rope shape. = State 1 for this

9l081NKTCJP.F017TW.ptd Page 19 574279

574279 V. Description of the invention (18) _ Large size (eg, width up to lm or more) up to eight inches of decorative members of any size (eg, · width is 1 Ocm or more, as shown in Figure 14, substrate The surface of 58 is laminated and installed; between the surface-hardened decorative member 94 after the surface treatment, it should be <days ^ 'in the hard-to-adhesive substrate 5 8 and layer 56. The reason is multiple: mining = improvement The layer is used as the intermediate high-adhesion adhesive substrate and the decorative member: 'It can provide a significant three-dimensional feeling after the significant lifting or buffer layer, and adopts a foamed layer processing device. /, A table with moderate cushioning can be used The type of urethane = sintering coupler, polyester tree if it is an undercoat layer or then changed to 'if it is a foamed layer or a buffer layer is not particularly limited. Resin, epoxy resin, acrylate resin, Fat, etc. The thickness of the intermediate layer is determined by its function, and in the case of a good layer, it should be within the range of 0 ·; [in the range of ~ 100em layer ', it should be within the range of 0.1 · 10mm. [Second Embodiment] Such as As shown in Figs. 2 (a) to (d), the second embodiment uses a portion including a heat generating part and a base material. The surface treatment equipment with a turning table and a surface treatment method a \ Surface treatment method is a two-surface method characterized by the following steps: ⑴ ～ ⑶. Force (1) The flame generating unit uses A step of ejecting a fuel gas flame (hereinafter referred to as a first step). Person (2) In a substrate processing section, a state in which a difficult-to-adhesive substrate is fixed to a reversing process is to spray a flame to perform a surface treatment (hereinafter Called to

91081NKTCJP-F017TW.ptd page 21 5. Description of the invention (19) Step 2). After (yo) # 2, the horizontal axis of 疋 is used as the center to make the turning jade platform rotate # to take out the step). (f) Step of producing raw materials (hereinafter referred to as step 3 1 · silicon of step 1): two substances and two steps 'the fuel gas can be the same as that of the first embodiment' and the compound and the combustion-supporting gas. When the total amount of Yao carcass is 100 mole%, the silanization system is… if the relevant mouth is: and it is in the range of 1 x 1 0 ′ to 10 mole%. The reason is not A ^ a 、 The addition amount of silane compound is less than 1 x 10-10 mole%, shell, j ΐ;: ΓΓ The addition effect of difficult-to-adhesive substrates is due to the addition of other compounds and the compound When 10 mol%, the silane is incomplete. This σ will reduce the production, which will cause the silane compound to burn six compounds. Once the total amount of combustion gas is 100 mol%, the silane 1 χ 10 -8 i 2 mouth 1 should be set in the range of 1 χ 10_9 ~ 5 mole%, most preferably in the range of lx 10 ~ 14 ear%. Combustion support: Valley ί Control the flame temperature, generally in the combustion gas Additives :, or hydrogen, two, f kinds of combustion-supporting gases have two I gas or natural gas and other smoke gases! 1 oxygen, air-type combustion-supporting gases. In addition, when burning Gas; Pressure ;;: When used behind the tank, this type of combustion-supporting gas should be propane-fired 2: 100 mol. 1)% 'This type is best controlled at 80 ~ 99.9 mol (mole) Within the range of 574279 1 &gt; ιι ·· ι 5. Description of the invention (20). The reason is that when the content of such a combustion-supporting gas is less than 80 mol%, the miscibility of the stone yaki compound and air will decrease, resulting in incomplete combustion of the stone yaki product. On the other hand, if the content of such a combustion-supporting gas exceeds 99.9 mol%, the effect on a difficult-to-adhesive substrate may not be exhibited in some cases. Therefore, when the total amount of combustion gas is 100 moles, the gas content chamber is in the range of 85 to 99 mole%, and most preferably in the range of 90 to 99 mole%. ^ In order to fully mix the silane compound in the combustion gas, it is advisable. f namely: It is suitable to premix the carbamate compounds with carrier gas, and then inject them into the gas-supporting gas such as air stream. The reason is that these two officials are using a relatively large molecular weight and moving: difficult gas is easy to burn, can be uniform and sufficient ==== chemical, quality. As for this kind of more suitable carrier gas, it is better to use it as a core gas. Hydrocarbons such as pit milk or natural gas. When the second step is performed, the silicon oxide flame treatment is made in the range of 5000 ~ 150 (KC. The reason is that if the fire temperature is controlled, the flame should be controlled. When the temperature exceeds 1 5001, the king burns. Another adhesive substrate may be thermally deformed or: the limitation of the two-side modification object may be used as a substrate for difficult-to-adhesive substrates. The flame temperature on page 23 91081NKTCJP.F0J7TW.ptd 574279 V. Description of the invention (21) It should be set within the range of 550 ~ 1200 ° C, and most preferably within the range of 600 ~ 900 ° C. In addition, the flame temperature The temperature measured at the end of the flame before the flame can be appropriately adjusted according to the type of combustion gas used or the flow rate of the combustion gas, or the type or quantity of silicon compounds added to the combustion gas. Flame treatment time for silicon oxide flame treatment ( The spraying time should be controlled within the range of 0.1 seconds to 100 seconds. The reason is that if the flame treatment time is less than 0.1 seconds, the modification after the use of the Shibata compound is not uniformly displayed. Effect.On the other hand, when the flame is processed When the time exceeds 丨 00 seconds, the difficult-to-adhesive substrate that is the object of surface modification may be thermally deformed or hardened, which will overly restrict the types of substrates that may be difficult-to-adhesive substrates. Because, 2. =; time It should be set in the range of .3 seconds to 3. seconds, and most preferably 0.5 to 3. When the third step is performed, in order to remove the substrate after the surface treatment, it should be located in the vertical direction. The turning table rotates about 90 ° with the center as the center, as shown in Figure 2 (c0 & + ^, horizontal axis state. Force_U), temporarily returns to the horizontal state, and then the turning operation is in the horizontal state. The reason for the horizontal axis specified by the table center is that the turning table 18 is located on the water surface 1 8 b and can be easily installed for the next time to be processed. ^^ %% ^ In this case, even if the size of the substrate is large or Miscellaneous substrate. Also the platform is in a horizontal state, which can be easily disassembled from the other side.

574279 V. Description of the invention (22) _______ rotates about 90 for the center. As shown in Figure 2 (d), go back again. The reason is that after the configuration, the square-straight center worktable 18 can be removed at the fixing fixture 26 of the worktable 18 to turn the material A over. That is, even if the vehicle components are large and difficult to adhere to the substrate, the vertical direction of the work ^ a variety of shapes, the main steps, as described later, can be laminated decorative elements, or brush designated text or Marks, etc. In addition to Gu Yi's seal, as shown in Fig. 2 (d), dismantled and treated by the 矣 品 老儿 q # uj / c 必 、、、 工 丁

It is difficult for the reverse surface 18b of the turning table 18 to make the substrate A difficult to adhere to the substrate B.理由 理 #. Under the conditions of 4 e-human substrate to be treated, and at the same time, the surface of another difficult to adhere to the substrate: difficult to connect 4. Other After the third step, it should be installed + &amp; Α The decorative component used in the decoration step must have :: and =, Γ chooses any size 'so it should be Ruchuan: = 图 = 良, and a is a decoration formed by powdered shells member. Figure Π (a) is a heating installation step in which a metal w having a forming surface 85 is adjusted with a gas or a lightning source. The shape of the forming surface 85 of the forming mold 84 of the metal mold 82, which is a heated metal mold 82, is preferably determined by the shape of the resin molded article of the garment. Figure 11 (b) shows the heated empty shell mold 82 and the flow container 574279. 5. Description of the invention (23) A reserve tank 8 8 in the form of powder resin 9 2 is formed on the forming surface 8 5 of the forming mold 8 4 toward The step of connecting one body under the state that the opening of the spare tank 88 faces upward. Fig. 11 (c) is a step of rotating the hollow metal mold 82 and the spare tank 88 to form a resin film 94 of a predetermined thickness on the molding surface 85 of the hollow metal mold 82 2 and the forming mold 8 4. That is, it is preferable to reverse the empty shell mold 82 and the backup tank 88 up and down. The reason is that the powder resin 9 2 in the spare tank 8 8 falls on the molding surface 85 of the molding die 84 by its own weight, so the resin contacting the molding surface 85 and the laminated resin film 9 4 are based on the molding die 8 4 The heat is in a molten state and adheres to the molding surface 85 as a surface layer. Fig. 12 (a) is a step of disassembling the spare tank 8 8 from the hollow shell mold 8_2 by forming a resin film 9 4 m of a predetermined thickness on the forming mold 8 4. Fig. 12 (b) is a step of cooling the whole of the shell metal mold 82 or a part of the forming mold 84 by using water-cooling or air-cooling cooling means 9 8 to harden the tree shrew film 94. Fig. 12 (c) shows a step of peeling the resin film 94 from the forming die 84. ， 丨 丨 tree, pancreas, and decorative elements) laminated to the difficult-to-access Λ material Λ .: 2: Second, the decorative member is laminated to the difficult-to-adhere surface D and there is an intermediate layer 56. For example, a primer coating is provided. The formation condition, and at the same time, the lamination dress II can be paid for excellent processing conditions. ^ ^ However, to make the steps easier and faster, as shown in Figure 15 'should be

574279 V. Description of the invention (24) After the material 57 which is the raw material of the intermediate layer 56 is formed on the difficult-to-adhesive substrate 58, the decorative member 94 is laminated thereon. In this state, the decoration is performed by heating or irradiating ultraviolet rays. The subsequent fixing of the member 94 and the formation of the intermediate layer 56 are performed simultaneously. [Examples] [Examples 1] 1. Manufacturing of surface treatment device A hard-to-adhesive substrate subjected to three-dimensional processing was prepared. In other words, a polypropylene-based vehicle front instrument panel substrate (50 cm in length, 200 cm in width, and cm) was prepared. …, Be prepared! The surface treatment device shown in Fig. 1 adjusts the turning process to a horizontal state, and uses the fixed fixture and brake H 'on the turning table to fix the base of the instrument panel in the front of the car. The surface treatment device of material A is actuated, and the front instrument panel of the vehicle is subjected to a dream oxidation flame treatment. That is, a flame derived from a rich compound gas containing M η rT Γ-based silane) is applied to the substrate at a unit area (j ° Cm2: V ^ -M, t, ^ 〇), and then a foamed ammonia is coated. Cool 7

Rn0r, a methamphetamine and a decorative component. With heating for 5 minutes, it will be used as an intermediate: bribery, while adhering the decorative member, and forming 2. Evaluation of difficult-to-adhesive substrates

91081NKTCJP.F017TlV.ptd Page 27 574279 V. Description of the invention (25) Use standard solution, measure gold production-front instrument panel base for vehicles; use the same method for the stage after oxidation flame treatment, and measure force and instrument panel Base material_index Ⅱ Before car flame treatment before car auxiliary 3 Evaluation of surface treatment device For vehicle front instrument 矣 Siyi 4 and after the decorative components, the meaning of t =: = f foam "formic acid "The purpose layer inspection standard" is used to measure the peeling strength of the component and evaluate it with a chessboard. The following benchmarks

(I There is no peeling at all; the number of peeling is 1 to 2; the number of peeling is 3 to 10; the number of peeling is 11 or more ◎: in a checkerboard test of 100

〇ΔX 100 checkerboard square test 100 checkerboard square test 100 checkerboard square test [Examples 2 to 7] In Examples 2 to 7, as shown in Table 1, the board Difficulty of the substrate The type of substrate and the processing time of the silicon oxide flame of the front instrument: Xiao Example j Eight-purpose: Evaluation of the instrument panel substrate and the surface treatment device of the second instrument panel substrate. Before entering the vehicle for vehicles [Comparative Examples 1 to 2] In Comparative Example 1, the surface was completely made of compressed air containing no silane compound, and the body in Comparative Example 2 was used instead of the stone in Example 1. Combustion of the fuel gas of compound m

574279 V. Description of the invention (26) Example 彳 1 In the same way, the evaluation of the front instrument panel substrate and the surface treatment device for vehicles is performed separately. Table 1

Substrate Silicon Oxide Flame Treatment Wetness Index (dyn / cm) Checkerboard Check (sec / 100 cm2) Before Treatment After Treatment After Treatment Before Example 1 PP 0.5 34 68 X ◎ Example 2 PP 1 34 69 X 〇 Example 3 PE 1 32 66 X ◎ Example 4 PE 1 1 32 68 X ◎ Example 5 PET 0.5 38 68 X ◎ Example 6 PET 1 38 70 X ◎ Example 7 Fluorocarbon Shed 1 31 65 X ◎ Compare Example 1 PP 0 34 36 XX Comparative Example 2 PP flame treatment 0.5 34 36 XX 91081NKTCJP-F017TW.ptd page 29 574279 V. Description of the invention (27) Industrially available as described above, followed by surface treatment of the substrate, that is, It is possible to treat the bonding strength of the three-dimensional processing on the substrate which is not difficult to adhere and in addition, if the flame of the difficult-to-adhere gas processed by the body is processed. If the surface treatment of this hair is difficult to connect, the original can still be maintained. If the application of this invention is based on the implementation of the special decorative member, the surface of the invention can be applied to the surface of the substrate, which is difficult to be exposed. Qiantian # π® pitting device, through the flame layer of the fuel gas of the compound through the middle layer, can obtain a strong bonding strength between. : Surface treatment method, by applying a special primer treatment to the prefabricated facade with a fuel derived from a stone-containing compound, the firm treatment device and surface treatment method are obtained between the base material and the decorative member 'Effect even after 2 months after surface treatment. 574279 Brief description of the drawings [Simplified description of the drawings] The device diagram is used to explain the surface treatment method related to the first embodiment of the present invention. The Γ diagram is used to explain the surface treatment using the surface treatment apparatus of the present invention. ^ Θ system The figure for explaining the flame generating part of the surface treatment apparatus of this invention is a perspective view of a front instrument panel. Figure 5 is a perspective view of the door. Figure 6 is a perspective view of the seat. Figure 7 is a perspective view of the operation box. $ = Picture is a perspective view of the interior materials installed on the door. Figure 9 is a perspective view of a bumper. Fig. 10 is an oblique view of a vehicle ornament. Figure η is a diagram for explaining a method for forming a powdered shell of a decorative member (picture of a shell molding method) (Figure 12 is for explaining that a powder of a decorative member is empty, and the stop is 3 :) The related surface treatment device is a diagram of a method for making a three-dimensional decorative piece. Figures 14 and 14 are used to explain the three-dimensional decorative pieces. Figures of the methods and Figures 15 and 15 are used to illustrate the production of three-dimensional decorative pieces. Close

574279 Brief description of drawings [Description of drawing numbers] 7 Conveying pipe 8 Flame 9 Fuel tank 10 Surface treatment device 11 Fixed platform 12 Injection device 12a Auxiliary ignition device 13 Driving device

16 seat 16a wheels 16b guide rail 17 frame 17a moving means 18 flip table 18a substrate placement section 18b substrate placement section 20 horizontal axis

22 Rotating jig 26 Fixing jig (claw) 27 Fixing jig (locking member) 28 Control device 32 First tank 34 Silane compound

91081NKTCJP-F017TW.ptd Page 32 574279 Brief description of the drawing 3 6 Heating means 38 Pressure gauge C or level meter) 42 Mixing chamber 44 Conveyor 48 Pressure gauge 56 Intermediate layer 5 7 Material 58 Difficult adhesive substrate 82 Empty Shell mold 84 Forming mold 85 Forming surface 86 Heating device 88 Spare tank 92 Powder resin 94 Resin film (decorative member) 101 Front instrument panel 102 Door 103 Seat 104 Operating box 105 Interior material 106 Bumper 107 Decoration

91081NKTCJP-F017TW.ptd Page 33

Claims (1)

574279- 1 A surface treatment device comprising a flame treatment portion and a surface treatment device for a difficult-to-adhesive substrate for substrate treatment j, wherein the raw portion has a fuel derived from a compound containing a stone-burning material. The gas fire can and the flame originating from the fuel gas spray are sprayed on the surface; the liter management unit is provided with a turning table for fixing the difficult-to-adhesive substrate and moving at the same time as the surface rotation.疋 "The water thousand axis is the center of the rotation 2 · As in the scope of the patent application 1g, this platform is essentially flat ::; = processing device, in which the above-mentioned turning fixtures are fixed to fix =; \ 于 基 其:. The surface is provided with ^^ 3 === Item Λ table, processing device,. Angle adjustment member for the angle 4 · If the heterogeneous part and the base material processing part of the first scope of the patent application are substantive, processing The device 'where the aforementioned flame transfer workbench constitutes the first part of the frame: it is contained inside the frame' and the above-mentioned view t 5 · such as 晴 91081NKTCJP-F017TW.ptd of Shenqing Patent Scope, page 34, 574279 VI. The scope of the patent application declares that the surface of the red perimeter j of the patent is treated and stored) The shape of the substrate that is difficult to adhere to, according to the record: Issuance of a memory message: 'Long memory message' used to move the position of the aforementioned fire trend generating part It is characterized by adopting a method including a flame generating portion and a base method that includes a processing device for surface-treating a difficult-to-adhesive substrate = the aforementioned flame generating portion, so that the step derived from the silane-containing flame is ejected; Pyrotechnic K, W The step of spraying the aforementioned flame under the state of F drinking room; and the step of taking the surface treated difficult-to-adhesive substrate after the reversing table is rotated as the center of the horizontal axis. The surface treatment method according to item 7 of the patent, wherein the aforementioned difficult material is composed of at least one resin of polyolefin resin, polyurethane resin, fluorocarbon resin, silicone resin or polyester resin as the main raw material. 9l081NKTCJP-F017TW.ptd Page 35