TW562790B - Method of nanoparticulate coating for antifouling product - Google Patents

Method of nanoparticulate coating for antifouling product Download PDF

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Publication number
TW562790B
TW562790B TW91119718A TW91119718A TW562790B TW 562790 B TW562790 B TW 562790B TW 91119718 A TW91119718 A TW 91119718A TW 91119718 A TW91119718 A TW 91119718A TW 562790 B TW562790 B TW 562790B
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Taiwan
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temperature
product
ceramic
oven
fouling
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TW91119718A
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Chinese (zh)
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Wen-Wen Li
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Tien Kuang Entpr Co Ltd
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Abstract

A nanograde antibacterial and antifouling method, comprising: silicon dioxide having a particle size between 8 to 10 nm (nanometer) is used as a coating material. The surface of ceramic product is rinsed by IPA (isopropyl alcohol) and dried. Nanoparticulate silicon dioxide is mixed with IPA in the ratio of 1 to 1 to 3, and then coated over the surface of the ceramic product after being sprayed with diluted IPA by spraying through a spraying gun; afterwards, the product with nanoparticulate coating is placed in the oven and first heated to a temperature of 150 DEG C to 200 DEG C in a temperature increasing rate of 0 to 2 DEG C/min, and then heated at a constant temperature for 20 min to 1 hour, followed by cooling to a temperature below 70 DEG C in a rate of 0 to 1.7 DEG C/min. The cooled product could be removed from the oven after the temperature is down to below that regulated by the standards; the above steps are applied onto ceramic products to improve a nanograde antibacterial and antifouling, and easy to clean effect and thus implementing a clean life in reality.

Description

562790 五、發明說明(1) <發明領域> 本發明係為有關於一種奈米級抗污防 奈米級、技術用於陶冑i' ,以遠到县-、* 進陶瓷製品之抗污防菌 以達到易/月洗之效用,以真實呈 <發明背景〉 印冻乎之生活 -公:的ΐΐΐ衡量尺寸單位,一奈米是1 〇-9次方,即 是相* J的;:之一’比1 0-6次方微米更微小化,所以 疋相當小的早位,舉例夾今, 米。 +例不次人的碩髮其直徑是數萬個奈 承上所述,奈米級技術是極微小的製作#彳&,4_ 圖所示者,以奈米化的製 JI作技術,如苐- 構3經奈米級技術4進行表面;王里、:作成分2與介面結 附著的細緻潔淨表面,以達^ n連水分子都難以 而-般業者以往;= =政府積極推動之技術, 生產之陶竞製品均;支術用於陶竟製品上,使所 穢物殘留在使用面上:、例如菌之效果,$易會使污 備未經抗污防菌處理,易造馬桶、浴缸等衛浴設 到真正的潔淨,而無法帶给t =冑,使衛^間達不 人為使陶€製品達到潔淨:ί費者更向的品質,故本發明 精之精神’利用其專業眼秉持著研究創新、精益求 失,研究出-種更為實c識,並針對上述之缺 用價值之奈米級抗污防菌=乾圍更廣,且符合產業利 破本身技術層面開發,以伟2 一改以往傳統方式’突 以使陶瓷製品具有抗污防菌的效果562790 V. Description of the invention (1) < Field of invention > The present invention relates to a nano-grade anti-fouling and nano-grade technology, which is used in pottery i ', as far as the county-, * resistance to ceramic products In order to achieve the effect of easy / monthly cleaning of bacteria and bacteria, it is based on the reality < Background of the Invention > The Life of the Seal-Public: ΐΐΐ is a unit of measurement. One nanometer is 10-10th power, which is the phase * J ;: One 'is more miniaturized than the 10th to 6th micron, so 疋 is quite small early, for example, this today, m. + The diameter of the case is as large as tens of thousands of nanometers. The nanometer technology is extremely small. # 彳 &, 4_ As shown in the figure, the nanometer JI technology is used. Rugao-structure 3 is surfaced by nano-level technology 4; Wang Li: As a delicate and clean surface attached to the component 2 and the interface junction, it is difficult for even water molecules to be-as usual in the industry; = = Government actively promotes The technology, the production of ceramic products are all used; ceramic surgery is used on ceramic products, so that dirt is left on the use surface: for example, the effect of bacteria, $ easy to make pollution preparation without anti-fouling and anti-bacterial treatment, easy Toilets, bathtubs and other sanitary wares are set to be truly clean, but cannot bring t = 胄, which makes the sanitary wares artificially make the ceramic products clean: the quality of the consumer is more oriented, so the spirit of the essence of the present invention is to 'use Its professional eyes are adhering to research innovation, seeking excellence, and developing a more practical knowledge, and aiming at the above-mentioned non-use value of nano-scale anti-fouling and anti-bacteria = broader dry fence, and in line with the industry's own technology Level development, to change the traditional method of Wei 2 in the past to make ceramic products have antifouling and antibacterial effect

第4頁 562790Page 4 562790

五、發明說明(2) <發明内容> 本發明係將二氧化矽用為奈米材料,其米徑設為8〜 1 0奈米左右’利用水解縮合反應而得’然後再將陶究表 面以異丙醇進行清潔處理後擦乾,再將奈米級二氧化石夕和 異丙醇以適當比例1 : 1〜3稀釋並攪拌均勻,然後再將 稀釋後的異丙醇用噴搶喷在陶瓷產品表面上,待喷塗後產 品,再置入烘箱内以升溫速率每分鐘〇〜2 t加熱至丄5 0 C〜2 0 〇 C,並恆溫2 〇分鐘至1小時,隨後以每分 鐘〇〜1 · 7 t降溫速率降至7 Q t以下,待溫度降至規 範標準以下後’再將產品移出烘箱。 <發明目的〉 本發明 ,使陶瓷製 ,以增進衛 為了使 了解,以下 首先請 發明係用於 (A )將二 為8〜1 〇 (B )將陶 處理後擦乾 (C )將奈 要目的係運用奈米級技術於陶兗製品上 ::具有易清洗之效用,以達到抗污防菌之效果 浴没備之潔淨。 g二ί ί Ϊ貝能對本發明之系統有更進-步之 即配a各圖式及作# 灸關笛-@ 乍评細解說如下: 參閱第一圖所示去 陶瓷製"上 者係為本發明之流程圖,本 翁π二。’其方法步驟如下: 乳化石夕(S i 〇 ) 太半产六,γ 2 )用為奈米材料,其米徑設 不木工右係利用水解縮人;5處而俨· 瓷表面以有機溶劑縮口反應而付, • Μ (異丙醇I P A )進行清潔 9 米級抗污藥劑 氧化矽)和有機溶劑(異丙V. Description of the invention (2) < Summary of the invention > The present invention uses silicon dioxide as a nano material, and the diameter of the rice is set to about 8 to 10 nanometers 'from hydrolytic condensation reaction'. The surface is cleaned with isopropyl alcohol and then wiped dry. Then the nano-grade dioxide and isopropyl alcohol are diluted at an appropriate ratio of 1: 1 to 3 and stirred well, and then the diluted isopropyl alcohol is sprayed with Spray on the surface of the ceramic product. After spraying, the product is placed in an oven and heated at a heating rate of 0 ~ 2 t per minute to 丄 50 C ~ 2 0 ℃, and the temperature is maintained for 20 minutes to 1 hour. The cooling rate is reduced to less than 7 Qt at a rate of 0 ~ 1 · 7 t per minute, and the product is removed from the oven after the temperature has fallen below the specification standard. < Objective of the invention> The present invention is made of ceramics to enhance the health. In order to understand, first, the invention is used in the following (A) will be two to 8 ~ 10 (B) will be dried after the pottery treatment (C) will be Nai The main purpose is to apply nano-grade technology to pottery products: it has the effect of easy cleaning to achieve the effect of anti-fouling and anti-bacterial. g 二 ί ί Ϊ 贝 can make further progress to the system of the present invention-that is, with each figure and work # 关 关 笛-@ 查 评 Detailed explanation is as follows: Refer to the first picture to go to ceramics " the above This is a flowchart of the present invention. The method steps are as follows: Emulsified stone eve (S i 〇) Taiba six, γ 2) is used as a nano material, its diameter is set by woodworking, the right system is used to shrink by hydrolysis; 5 places, and the porcelain surface is organic Solvent shrinkage reaction to pay, • M (isopropanol IPA) for cleaning 9 meters antifouling agent silica (silica oxide) and organic solvents (isopropyl alcohol

562790 五、發明說明(3) 醇)以適當比例1 · …稀釋後“機二3稀;;攪拌均勾; 口本品^ + 有機洛劑,以喷塗設備(嘖搶)在陶瓷產 〜6次; 置入烘箱内以升溫一定程度,該升溫 加熱至1 5 0 °C〜2 0 〇 °C,並恆溫 隨後以每分鐘〇〜1 · 7 C降溫迷率 口口表面上來回噴塗〜 貝馆7 ^ (E )喷塗後產品 速率每分鐘0〜2 2 0分鐘至1小時 降至7 〇 °C以下; (F )待溫度降至規範標準以下後,再將產品移出烘箱, 而完成具有奈米級抗污防菌之陶瓷產品。 ^ 承上所述’本發明人研發奈米級技術抗污防菌形成如 ^大自然中蓮花葉面不沾水,比水分子還細微的奈米介面 〜構的蓮;fb效應’以及動物界鴨子的羽毛呈現奈米化的細 緻結構具有防水作用,因蓮花表面具有奈米詰構及其中所 形成的特性及自然現象,所以污泥和水珠只會在葉面上滾 動’而不會附著在葉面上,將陶瓷製品經奈米級技術進行 表面處理後,則具有上述之效果。 續上所述,本發明奈米級抗污防菌之方法,係運用於 洗手臺、馬桶、浴缸等衛浴設備陶瓷製品上,以馬桶為例 ’如第三圖所示者,該馬桶内左側釉面為經奈米級抗污防 菌處理,右側釉面為一般馬桶釉面,在未沖洗馬桶前,馬 桶内污物在左側釉面呈水珠狀輕附在釉面上,而污物在右 側釉面呈片狀完全附著在釉面上,再如第四圖所示,在同 時以同水量沖洗馬桶後,馬桶内左側釉面上之污物隨著水 滴從釉面滑落,使馬桶内左側釉面不沾污且使全部污物沖562790 V. Description of the invention (3) Alcohol) at the proper ratio of 1 ·… diluted "machine 2 3 dilute; stir evenly hook; mouthpiece ^ + organic lotion, spraying equipment (啧 grab) in ceramic production ~ 6 times; placed in an oven to raise the temperature to a certain degree, the temperature is heated to 150 ° C ~ 200 ° C, and then constant temperature, and then sprayed back and forth on the surface of the mouth at a cooling rate of 0 ~ 1.7C per minute ~ Beckham 7 ^ (E) After spraying, the product rate drops from 0 to 220 minutes per minute to 1 hour below 70 ° C; (F) After the temperature drops below the standard, the product is removed from the oven, and Complete ceramic products with nano-grade anti-fouling and anti-bacteria. ^ Continued from the above, 'The inventors developed nano-technological anti-fouling and anti-bacterial formation, such as the lotus leaf surface in nature does not stick to water, and it is finer than water molecules. Nanometer interface ~ constructed lotus; fb effect 'and the feather structure of the animal world ducks show the fine structure of nanometer has waterproof effect, because the lotus surface has nanometer structure and the characteristics and natural phenomena formed in it, so sludge and Water droplets will only roll on the leaf surface and will not adhere to the leaf surface. After surface treatment with nano-grade technology, the above-mentioned effects are obtained. Continuing from the above description, the nano-grade anti-fouling and anti-bacterial method of the present invention is applied to ceramic products such as bathroom sinks, toilets, bathtubs, etc. Take the toilet as an example. As shown in the third picture, the left side of the toilet is treated with nano-grade anti-fouling and anti-bacterial treatment, and the right side of the toilet is normal toilet glaze. Before the toilet is flushed, the dirt in the toilet is on the left. The glazed surface is lightly attached to the glazed surface, and the dirt is completely attached to the glazed surface in the form of flakes on the right glazed surface. As shown in the fourth figure, after the toilet is flushed with the same amount of water at the same time, the left side of the toilet The dirt on the glazed surface slides off the glazed surface with the water droplets, so that the left glazed surface in the toilet is not stained and all the dirt is washed away.

第6頁 562790 五、發明說明(4) 洗乾淨,而右側釉面(一般馬桶釉面)上之污物則未能沖 洗乾淨,且還有部份污物殘留在釉面上,藉由上述實驗可 知,本發明之奈米級抗污防菌之方法應用在洗手臺、馬桶 、浴缸等衛浴設備之陶瓷製品表面上時,確實能達到不沾 污、易清洗之效果,且因表面不沾水滴,污物會隨著水滴 從表面滑落,並可防止細菌生長,使衛浴空間不會產生異 味,且讓衛浴設備邁向更高潔淨的層級。 綜上所陳,本發明奈米級抗污防菌之方法,實具有產 業利用價值之新穎性與進步性,實符合發明專利之申請要 件,爰依法申請專利之,請速予審查,如蒙 鈞局核准, 實感德便。 【圖式說明】 第一圖係為奈米化流程圖。 第二圖係為本發明之流程圖。 第三圖係為本發明之馬桶沖洗前實施例圖。 第四圖係為本發明之馬桶沖洗後實施例圖。 【圖號說明】 製作原料· · · 1 製作成分· · · 2 介面結構· · · 3 奈米級技術·· 4Page 6 562790 V. Description of the invention (4) Wash clean, but the dirt on the right glazed surface (general toilet glazed surface) has not been washed away, and some dirt remains on the glazed surface. It is known from experiments that when the nano-grade anti-fouling and anti-bacterial method of the present invention is applied on the surface of ceramic products of sanitary equipment such as sinks, toilets, bathtubs, it can indeed achieve the effects of no staining and easy cleaning, and the surface is not Water droplets, dirt will slide off the surface with the water droplets, and can prevent the growth of bacteria, so that the bathroom space will not produce odor, and the bathroom equipment will move to a higher level of cleanliness. To sum up, the nano-grade anti-fouling and anti-bacterial method of the present invention has the novelty and progress of industrial utilization value, and it actually meets the application requirements for invention patents. If you apply for a patent according to law, please review it quickly. Jun Bureau's approval, I really feel virtuous. [Schematic description] The first diagram is a nanometer flow chart. The second figure is a flowchart of the present invention. The third figure is a diagram of the embodiment before toilet flushing according to the present invention. The fourth figure is a diagram of the embodiment after flushing the toilet of the present invention. [Illustration of drawing number] Production materials ...

Claims (1)

901 τΛ 六、申請專利範圍 1 · 一種奈 方法步驟如 (A )將二 為8〜1 0 (B )將陶 處理後擦乾 (C )將奈 醇)以適當 (D )稀釋 產品表面上 (E )喷塗 速率每分鐘 2 0分鐘至 降至7 0 t: (F )待溫 而完成具有 S i〇2 )用為奈米材料,其米徑設 ,係利用水解縮合反應而得; 有機溶劑(異丙醇I P A )進行清潔 米級抗污 比例1 : 後的有機 後產品’ 0 〜2 °C 1小時, 以下; 度降至規 奈米級抗 米級抗污防菌之方法,係用於陶瓷製品上,其 下: 氧化矽( 奈米左右 瓷表面以 藥劑(二氧化石夕)和有機溶劑(異丙 1〜3稀釋並攪拌均勻; 溶劑,以喷塗設備(喷槍)喷在陶瓷 置入烘箱内以升溫一定程度,該升溫 加熱至1 5 0 °C〜2 0 0 °C,並悝溫 隨後以每分鐘0〜1 · 7 °C降溫速率 範標準以下後,再將產品移出烘箱, 污防菌之陶瓷產品。901 τΛ VI. Patent application scope1. A kind of Nai method steps such as (A) will be two to 8 ~ 1 0 (B) After pottery treatment, wipe dry (C) will be Nanol) to appropriately (D) dilute the product surface ( E) The spraying rate is from 20 minutes to 70 t per minute: (F) The temperature is complete and Si02 is used. The nanometer material is used, and its diameter is set by hydrolysis condensation reaction. Organic Solvent (isopropyl alcohol IPA) for cleaning rice-grade anti-fouling ratio 1: organic after product '0 ~ 2 ° C 1 hour, below; the degree is reduced to the standard nano-grade anti-fouling anti-bacterial method It is used on ceramic products, and the following are: silicon oxide (the surface of the ceramics around the nanometer is diluted with medicament (stone dioxide) and organic solvents (isopropyl 1 ~ 3 and stirred evenly); the solvent is sprayed with spray equipment (spray gun) Put the ceramic into the oven to raise the temperature to a certain degree. The temperature is raised to 150 ° C ~ 200 ° C, and the temperature is then lowered below the temperature range of 0 ~ 1 · 7 ° C per minute. The product is removed from the oven, and the ceramic product is anti-bacterial. 第8頁Page 8
TW91119718A 2002-08-29 2002-08-29 Method of nanoparticulate coating for antifouling product TW562790B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100425573C (en) * 2004-02-27 2008-10-15 申佑芝 Mfg. method of nano ceramics

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100425573C (en) * 2004-02-27 2008-10-15 申佑芝 Mfg. method of nano ceramics

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