TW561207B - Carbon fiber with high thermal conductivity - Google Patents

Carbon fiber with high thermal conductivity Download PDF

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TW561207B
TW561207B TW91112487A TW91112487A TW561207B TW 561207 B TW561207 B TW 561207B TW 91112487 A TW91112487 A TW 91112487A TW 91112487 A TW91112487 A TW 91112487A TW 561207 B TW561207 B TW 561207B
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thermal conductivity
carbon fiber
high thermal
scope
carbon
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TW91112487A
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Chinese (zh)
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Yu-Huei Juang
Ming-Fa Shiu
Yung-Kuen Lin
Tze-Hau Ke
Wen-Shiung Guo
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Chung Shan Inst Of Science
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Abstract

A carbon fiber with a high thermal conductivity mainly is formed by coating a PAN (poly acrylic nitrile) based carbon fiber with a bituminous derivative or a polymer material, followed by carbonization and graphitization; the produced carbon fiber displays excellent structural strength and thermal conductivity, and can be used in the formation of a composite device with a high thermal conductivity.

Description

561207 __皇號91112487 私生4月修正__ 五、發明說明(1) '~~~ '~" 《發明概述》 本發明係關於一種「具高導熱性之碳纖維」,尤指一 種以聚丙烯(poly acrylic nitriie,PAN)瀝青延生物或 高分子聚合物原材,再經碳化與石墨化處理所製成之碳纖 維結構’不僅可供高導熱性之複材元件成型使用,更可以 發,高強度與高導熱性之特性,且可透過一般製程技術加 以λ把,而旎有效簡化高導熱性複材元件之生產程序,以 及降低生產之成本,使達顯著之實用性。 《發明背景》 按,一般電子產品大多安裝有各 件:ϋ為:保電子零件之使用品質與壽命 之穩疋性衫響外,電路設計及零件配铲 八v件配置上,#需考慮散埶性的n 1,、s ^ 透過安裝散熱風扇等散熱裝置提==通常 方式,以達導熱、散熱之目的。^零件導熱性能561207 __ 皇 号 91112487 illegitimate April revision __ V. Description of the invention (1) '~~~' ~ " Summary of Invention The present invention relates to a "carbon fiber with high thermal conductivity", especially a kind of carbon fiber with high thermal conductivity. Carbon fiber structure made of polypropylene (poly acrylic nitriie, PAN) bitumen or high molecular polymer raw material, and then carbonized and graphitized is not only used for the molding of composite materials with high thermal conductivity, but also can be developed. The characteristics of high strength and high thermal conductivity can be added to λ through general process technology, which effectively simplifies the production process of high thermal conductivity composite components and reduces the cost of production, which makes it significantly practical. "Background of the Invention" According to the general electronic products are mostly installed with various pieces: 件 is: to ensure the stability of the quality and life of electronic parts, in addition to the circuit design and parts configuration of the shovel with eight v parts, The flexible n 1, and s ^ are provided by installing a cooling device such as a cooling fan, etc. to achieve the purpose of heat conduction and heat dissipation. ^ Part thermal conductivity

由於複&材料本身具有導熱 導熱或散熱元件之製作,惟隨 :吊被應用於各Since the compound material itself is made of thermally conductive or thermally conductive components, the

散熱性之需求遂不斷提升,因此如何::之小型化’對 導熱性能加以提升,以符合市場、十對現有複材元件 有鑑於此,本發明者即憑恃著個人確有其急迫性 維之研究及融會貫通之構思,而發明ί長期對於各種碳 維被覆瀝青延生物或高分子聚合物=一種以PAN基碳| 化處理所製成之碳纖維結構,不僅可3:;經碳化與石 供兩導熱性之複材The demand for heat dissipation has continued to increase, so how to: "miniaturize" to improve the thermal conductivity to meet the market, ten pairs of existing composite materials in view of this, the inventor simply has his urgency to maintain it Research and integrate the idea, and invented a long-term for various carbon-dimensional coated asphalt-extended biological or high-molecular polymers = a carbon fiber structure made of PAN-based carbonization treatment, not only can be 3: Thermally conductive composite

561207 — 案號 91112487 五、發明說明(2)561207 — Case number 91112487 V. Description of the invention (2)

修正 件成型使用,以發揮複材與高導熱性之特性,且可透過一 般製程技術加以實施,而能有效簡化高導熱性複材元件之 生產程序,同時降低生產之成本,使達極佳產業利用性與 實用價值。 《發明目的》 緣此,本發明之 碳纖維,其係利用被 纖維上被覆一層瀝青 用碳化及石墨化處理 碳纖維得具良好之高 之複材元件成型使用 本發明之次要目 維,其事先運用被覆 碳纖維,以供製成複 材元件之製法,係可 本之目的。Correction parts are molded to make use of the characteristics of composite materials and high thermal conductivity, and can be implemented through general process technology, which can effectively simplify the production process of high thermal conductivity composite components, and reduce the cost of production, making it an excellent industry Exploitability and practical value. "Objective of the Invention" For this reason, the carbon fiber of the present invention is formed by using a layer of bitumen to cover a layer of pitch with carbonized and graphitized carbon fibers to obtain a composite material with a high height. The secondary visual dimension of the present invention is used in advance. The method of coating carbon fiber for making composite materials is the purpose of the original.

主要目的係在提供一種具高導熱性之 覆(coating)之製程技術,於PAN基罐 延生物或高分子聚合物原材後,再利 以製成所需之碳纖維複合素材,使該 導熱性’俾可提供各種需要高導熱性 〇 的,在提供一種具高導熱性之碳纖 及喊化、石墨化之技術形成高導熱性 材=t之製法,相較習用高導熱性複 有效簡化生產程序,並達降低生產成 《發明之詳細說明》 為使審查委員對本發明能 較佳實施例,並配合圖示、圖 其所達成的功效詳細說明如后 《具體實施例說明》 進一步的瞭解,以下茲舉一 % 號’將本發明之構成内容及The main purpose is to provide a coating technology with high thermal conductivity. After PAN-based canning of biological or polymer raw materials, it can be used to make the required carbon fiber composite materials to make the thermal conductivity. '俾 can provide a variety of methods that require high thermal conductivity 0, in providing a carbon fiber with high thermal conductivity and the technology of forming high thermal conductivity = graphitization technology, compared with the conventional high thermal conductivity, simplify the production process effectively In order to make the reviewing committee better understand the present invention, and cooperate with the diagrams and figures to achieve a detailed description of the effect, please refer to the "Specific Embodiment Description" for further understanding. I give you a% '

第6頁 561207 - 91112487_p年為月 <日 修正__ 五、發明說明(3) 請參閱第一〜三圖所示,係為本發明碳纖維之構造剖 面示意圖,其主要係以PAN基碳纖維(1〇)被覆(c〇ating). 末狀之瀝青延生物或高分子聚合物原材(2〇)或其他可附著 之瀝青中間相或介相材料(mesophase)後,再經碳化與石 墨化處理,使發揮高導熱性之特性所構成,並藉此使該組 成之導熱性碳纖維(A)具有良好之導熱性,而可運用於各 種需要高導熱性之複材元件成型使用。 另需特別說明的是’利用本發明之導熱性碳纖維(A) 製作複材元件時,僅需將準備好之P AN基碳纖維(1 〇 )事先 被覆(coating) —瀝青延生物或高分子聚合物原材(2〇), 再經碳化與石墨化處理後,即可實施於一般製程技術;其 中該一般製程技術係包含利用本發明之導熱性碳纖維(A) 直接與樹脂等補強材一體成型之技術,而不需特殊或專門 之技術,其製作之技術門檻較低。 又,本發明利用PAN基碳纖維(1〇)採被覆 青延生物或高分子聚合物原材,再經碳化與石墨化處理之 作法’係可在不影響P A N基碳纖維(1 〇 )原有之物性下,故 於製作上非常快速簡便,且可有效降低生產製作成本,加 上高導熱之物性,使對生產高導熱性係數之複材元件,有 其加乘之效果,比如實施於散熱片等需要高導熱性之元件 時’即可同時獲取複材及高導熱性之特性,不僅可簡化高 導熱性複材元件之生產程序,亦能降低生產成本,而具有 顯著之實用功效。 為使審查委員了解本案之實用性,茲舉以下實施例來Page 6 561207-91112487 _ year is the month < the day is modified __ V. Description of the invention (3) Please refer to the first to third figures, which are schematic diagrams of the structure of the carbon fiber of the present invention, which is mainly based on PAN-based carbon fiber ( 1〇) Coating (coating). After the final asphalt or biopolymer raw material (20) or other attachable asphalt mesophase or mesophase material, carbonization and graphitization It is processed to make use of the characteristics of high thermal conductivity, and thereby the thermally conductive carbon fiber (A) of this composition has good thermal conductivity, and can be used for molding various composite materials that require high thermal conductivity. In addition, it should be specifically stated that when using the thermally conductive carbon fiber (A) of the present invention to make composite materials, it is only necessary to coat the prepared P AN-based carbon fiber (10) in advance—asphalt-based biopolymer or polymer polymerization. After the raw material (20) is carbonized and graphitized, it can be implemented in general process technology. The general process technology includes the use of the thermally conductive carbon fiber (A) of the present invention to be integrally formed with a reinforcing material such as resin. Technology without special or specialized technology, the technical threshold for its production is low. In addition, the method of using the PAN-based carbon fiber (10) to cover the raw material of green or biological polymer, and then subjecting it to carbonization and graphitization treatment can not affect the original of the PAN-based carbon fiber (10). Under the physical properties, it is very fast and easy to manufacture, and can effectively reduce the cost of production. In addition, the high thermal conductivity of the physical properties makes it possible to have a multiplier effect on the production of composite materials with high thermal conductivity coefficients, such as implementation on heat sink When components with high thermal conductivity are needed, the characteristics of composite materials and high thermal conductivity can be obtained at the same time, which not only simplifies the production process of high thermal conductivity composite components, but also reduces production costs, and has significant practical effects. In order for the reviewing committee to understand the practicability of the case, the following examples are provided.

第7頁 561207 案號 91112487 五、發明說明(4)說明:Page 7 561207 Case number 91112487 V. Description of invention (4) Description:

實施例1 ·· 以丁-30 0 PAN基碳纖維經過分紗處理後,再以粉 技術,、將瀝青或瀝青介相材料均勾附著於碳纖維之曰 將该纖維放入烤粕中加熱至1〇〇〜3〇〇 I,2一5小時, 步升溫至200 0-3 〇0(TC,2〜1〇小時石墨化,而得到表再進一 墨化之高強度碳纖維。瀝青介相材料(mes〇phase)所得 熱性較佳,若使用瀝青本身則需在經過一原位產生介相 (mesophase)的過程,以達到高導熱之效果。產生之導熱 碳纖維拉伸強度lOOksi以上,導熱性在2〇_2〇〇w/“,依石 墨層厚度,一般在卜20 之間不同而有差異。其中粉末塗 層與熱處理設計成一連續生產之形式。 實施例2 : 以T-70 0 PAN基碳纖維代替T- 300碳纖維,則導熱纖維 拉伸強度150ksi以上,導熱性在2 0- 20 0W/m\。 實施例3 : 以醯聚亞胺(ρ ο 1 y i m i d e )溶於有機溶劑中,含浸於T -3 0 0ΡΑΝ基碳纖維表面。將已含浸之纖維放入烤箱中加熱至Example 1 ······································································································································································ 丁 · 〇〇〜300〇I, 2 to 5 hours, stepwise temperature rise to 200-3000 (TC, 2 to 10 hours of graphitization, and then the surface is further inking high-strength carbon fiber. Asphalt mesophase material ( mesophase) has better thermal properties. If bitumen itself is used, it needs to undergo a mesophase process in situ to achieve high thermal conductivity. The thermal conductivity of the generated carbon fiber is above 100ksi and the thermal conductivity is 2 〇_2〇〇w / ", depending on the thickness of the graphite layer, generally different between Bu 20. The powder coating and heat treatment are designed in a continuous production form. Example 2: T-70 0 PAN-based carbon fiber Instead of T-300 carbon fiber, the thermal conductive fiber has a tensile strength of 150 ksi or more and a thermal conductivity of 20-200 W / m \. Example 3: Polyimide (ρ ο 1 yimide) is dissolved in an organic solvent and impregnated in T-3 0 0ΡΑΝ based carbon fiber surface. Put the impregnated fiber into the oven Medium heat to

第8頁 561207 _ 案號 91112487五、發明說明(5) 产年4月,Page 8 561207 _ Case No. 91112487 V. Description of the invention (5) Year of birth,

修正 100-300 °C,2-10 小時,再進一步升溫至 2000-3000 °C,2-1 0小時石墨化,而得到導熱碳纖維。纖維拉伸強度1 〇 〇 ks i 以上,導熱性50 -5 0 0W/m\。 實施例4 : 以液晶聚合物(L C P ),如聚醯亞胺或聚醴類高分子, 含浸於PAN基碳纖維上,石墨化過程同上。 綜上所述 纖維被覆 墨化處理 元件成型 一般製程 之生產程 用性及成 使用,誠 准予專利 需陳 用之技術 之功能作 在本發明 ,本發 遞青延 所製成 使用, 技術加 序,以 本效益 符合發 ,至為 明者, 原理, 用仍未 之範圍 明具高導 生物或高 之碳纖維 以發揮複 以實施, 及降低生 ,且其構 明專利申 感禱。 以上所述 若依本發 超出說明 内,合予 熱性之碳纖維,係提供一種以碳 分子聚合物原材,再經碳化與石 結構,不僅可供高導熱性之複材 材與高導熱性之特性,且可透過 而月b有效簡化高導熱性複材元件 產之成本,俾使整體極具產業實 成結構又未曾見於諸書刊或公開 請要件,楚、請釣局明鑑,早日 1疋本發明之具體實施例及所運 :j:想所作之改變,其所產生 ;明式所涵蓋之精神時’均應 561207 修正 案號 91112487 圖式簡單說明 《圖面之簡單說明》 第一圖係為本發明碳纖維之構造剖面示意圖。 第二圖係為本發明碳纖維之被覆製程示意圖。 第三圖係為本發明碳纖維之碳化與石墨化製程示意圖 《圖號說明》 (A) · · · (10)——· (20) · · · 導熱性碳纖維 PAN基碳纖維 瀝青延生物或高分子聚合物原材Correct 100-300 ° C for 2-10 hours, then further increase the temperature to 2000-3000 ° C, graphitize for 2-10 hours, and obtain thermally conductive carbon fibers. The fiber has a tensile strength of 100 ks i or more, and a thermal conductivity of 50-500 W / m \. Embodiment 4: A liquid crystal polymer (L C P), such as polyimide or polyfluorene polymer, is impregnated on a PAN-based carbon fiber, and the graphitization process is the same as above. In summary, the general production process of the fiber-covered inking treatment element forming process is useful and useful. The patented technology that is required to be used is hereby used in the present invention. Based on this benefit, the principle is clear. The principle is to use a range of high-conductivity organisms or high-carbon fibers to implement the implementation and reduce health, and it is also a patent application. If the above-mentioned carbon fibers are combined with thermal properties in accordance with the present description, a carbon molecular polymer raw material is provided, which is then carbonized and stone structured. It can not only be used for composite materials with high thermal conductivity and high thermal conductivity. Characteristics, and can effectively simplify the production cost of high thermal conductivity composite components through month b, so that the overall industry has a solid structure and has not been seen in books or publications, please read the book of the fishing bureau, as soon as possible. Specific embodiments and operations of the invention: j: the changes you want to make, the results; the spirit covered by the explicit form 'should be 561207, amendment number 91112487, a simple illustration of the "simple description of the drawing", the first diagram is It is a schematic structural sectional view of the carbon fiber of the present invention. The second figure is a schematic diagram of the coating process of the carbon fiber of the present invention. The third picture is a schematic diagram of the carbonization and graphitization process of the carbon fiber of the present invention. "Illustration of drawing number" (A) · · · (10)-· (20) · · · Thermally conductive carbon fiber PAN-based carbon fiber pitch biodegradation or polymer Polymer raw material

第10頁Page 10

Claims (1)

561207 —案號 91112487 年 修正 六、申請專利範圍 1、一種具高導熱性之碳纖維,其主要係以聚丙埽 (PAN)基碳纖維被覆(c〇ating) 一瀝青、瀝青延生物或高分 :,合物原材後,再經碳化與石墨化處理所構成;藉此 : 之碳纖維具有極佳之高導熱性,其導熱性在2 0〜5 0 0 九/米K。 2 纖維, 3 纖維, 4 纖維, 類高分 、依據申請專利範圍第1 其中,該被覆原材係為渥 、依據申請專利範圍第1 其中被覆層石墨化後之厚 、依據申請專利範圍第工 其中高分子聚合物為聚酿 項所述之具高導熱性之碳 青介相粉末。 項所述之具高導熱性之碳 度在1〜20 //m之間。 項所述之具高導熱性之碳 亞胺或具液晶特性之聚酯561207 — Amendment No. 91112487 6. Application for Patent Scope 1. A kind of carbon fiber with high thermal conductivity, which is mainly coated with polypropylene (PAN) -based carbon fiber. Asphalt, bituminous biomass or high score :, After the raw material is formed, it is further formed by carbonization and graphitization treatment; thereby: The carbon fiber has excellent high thermal conductivity, and its thermal conductivity is 20 ~ 50 0 9 / meter K. 2 fibers, 3 fibers, 4 fibers, high scores, according to the first scope of the patent application. Among them, the covering raw material is Wool, according to the first scope of the patent application. The thickness of the coating layer after graphitization, according to the first scope of the patent application. The high-molecular polymer is a carbon green mesophase powder with high thermal conductivity as described in the polymerization item. The carbon degree with high thermal conductivity mentioned in item is between 1 ~ 20 // m. High thermal conductivity carbon imine or polyester with liquid crystal characteristics
TW91112487A 2002-06-06 2002-06-06 Carbon fiber with high thermal conductivity TW561207B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8906339B2 (en) 2009-12-30 2014-12-09 Industrial Technology Research Institute High modulus graphitized carbon fiber and method for fabricating the same
TWI503459B (en) * 2012-05-10 2015-10-11

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8906339B2 (en) 2009-12-30 2014-12-09 Industrial Technology Research Institute High modulus graphitized carbon fiber and method for fabricating the same
TWI503459B (en) * 2012-05-10 2015-10-11

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