558583 C7 D7 五、創作説明（ (請先W讀背面之注意事項再填寫本頁) 本發明為-種濕式轉移印花用轉印圖案紙加工方法， 特別是使用碎素樹脂及壤數12_18之烷基酸衍生物，如 :硬脂酸類、月桂酸類混合溶液，對紙張進行塗佈加工， 使紙張具有水分滲透阻絕性，並使染料能印刷於其上之濕 式轉印用轉印圖案紙加工方法。 先前技術 使用疏水性樹脂作為濕式轉移印花之紙張基本塗佈（ base coating)方法在許多專利文獻中均有提及： 1. 曰本「大日本印刷公司」罾以疏水性松香（R〇sin)樹脂對 30g/m2薄葉紙進行基本塗佈，然後再以含有反應性染 料、變性松香樹脂、甲苯及異丙醇(IPA)等色糊配方進行 圖案印刷而製作成轉印圖案紙。圖案自紙上移轉至布面 所利用原理為松香樹脂之熱熔粘貼性，將染料帶至布 上，後經固著上色，並由水洗去除松香樹脂、增稍劑、 印花助劑及未上色染料等藥劑。其專利文獻包括： JP54117208A 、 JP55022029A 。 經濟部智慧財產局員工消費合作社印製 2. 曰本凸版印刷公司曾以聚酯樹脂或聚醯胺樹脂或乙烯樹 脂或MARINE樹脂或丙烯崩·樹脂或纖維素類等對印刷 用紙或藝術用紙或塗料紙或薄葉紙或聚丙烯(PP)膜或聚 乙烯(PE)臈等進行基本塗佈，然後再以含有分散性染料 或反應性染料、上述樹脂、界面活性劑及異丙醇(IPA) 等為色糊配方進行圖案印刷而製成轉印圖案紙。圖案轉 移原理為利用布疋壓吸驗液後，經熱羅拉加壓、溶融樹 本紙伕尺度適用中國國家榡準（CNS ) AOJt格（210X 297公釐） 558583 C7 D7 五、創作説明（） 脂至布上，後經固著上色，並由水洗去除樹脂、增稠劑、 印花助劑及未上色染料等藥劑。其專利文獻有： JP52077282A 、 JP53134978A 。 3.丹麥坦斯克(DANSK)公司曾以羧甲基纖維(CMC)、海藻 酸納或1乙稀分散液或琴丙烯酸分散液等對玻璃紙 (giassine)進行基本塗佈，然後再以含有水溶性染料或水 可分散型染料、羧曱基纖維素、海藻酸鈉、多元取代澱 粉醚、聚乙二醇酯及親水疏水平衡(HLB)大於15之聚合 體等為色糊配方進行圖案印刷而製成轉印圖案紙。圖案 · 轉移原理為利用布疋壓吸助劑後，經常溫羅拉加壓，將 紙上染料移轉至布上，經固著上色，並由水洗去除上述 增稠劑、印花助劑及未上色染料等藥劑。其專利文獻有·· USP5196030 〇 傳統缺點： 轉印圖案紙使用樹脂類為色糊增稠劑，雖然可以利用 Μ月曰的熱炫黏貼性，提向圖案的離型移轉性（r e丨e a s e 春 經濟部智慧財產局員工消費合作社印製 transfer)，但往往因為樹脂無法完全自布上去除，而導 致轉印後，產品之顏色鮮豔度不足及織物手感不佳等缺點 。另外’使用樹脂為增稠劑，於染料固著過程中，會影響 染料的遷徙（migration)進而影響染料與纖維間的接著力 及染著均勻性，導致轉印產品之色牢度（color fastness) 不佳及顏色色差（color difference)增大等問。 另一方面，使用樹脂類為紙張基本塗佈時，樹脂的成 _ 3 本紙伕尺度適用中國^^準（CNS ) A4jUt格（210X 297公釐)~~ ~ 558583 C7 D7 五、創作説明（） 膜度及皮膜強度會影響轉印後，織物是否會殘留樹脂藥劑 ，一旦織物上殘留有樹脂，亦會影響織物之手感、色牢度 及顏色鮮豔度等。 解決問題之手段： 為了解決轉印物（transfer products)之手感、色牢 度及顏色鮮盤度專問4 ’巴糊中避免使用樹脂類藥劑有其 必要性’除此之外’紙張之基本塗佈（base coating)所 使用樹脂必須加以篩選，樹脂之基本要求是成膜性快速且 完全，皮膜強度要高，如此方能避免樹脂於轉印時，隨著 色料移轉布上’造成轉印物之手感、色牢度及色鮮盤度等 變差。 即，本發明為一種濕式轉移印花用轉印圖案紙加工方 法，使用矽素樹脂及碳數12〜18之烷基酸衍生物，如： 硬脂酸類、月桂酸類混合溶液，對紙張進行塗佈加工，使 紙張具有水分滲透阻絕性，並使染料能印刷於其上之濕式 轉印用轉印圖案紙加工方法。 經濟部智慧財產局員工消費合作社印製 本發明t ’使用先前技術中未曾使用切素樹脂（落 cone)為基本塗佈（base coating)藥劑，矽去 性快速且完全，可以避免因樹蝴性之不== 時，移轉至織物上，造成織物手感變差或色相變暗。 另外，基本塗佈藥劑中亦使用碳數12〜〗8之烷芙妒 衍生物…硬脂酸類、月桂酸類’以提升染料的二： 轉率° 本紙伕尺度適用中辑圉家揉準（CNS ) A4说格（21〇χ297公釐） 558583 C7 D7 五、創作説明（） 上述烷基酸衍生物結構如下： CH3(CH2)n (CH=CH)m COOR 其中m = 0〜12 η = 10 〜16 R=鏈狀多醇類或環狀多醇類 上述烷基酸衍生物以山犁醣單硬脂酸酯（sorbitan monostearate)及甘油單硬脂酸§旨（GiyCero〖monostearate) 等提升染料離型移轉效果佳。 本發明中基本塗佈之塗佈量因紙張的特性而有所不同 ，紙張粗糙度愈小者，塗佈量愈少；反之，塗佈量須較大 ° 般而S ’紙張理想塗佈量=紙張粗糙度+ 〇〜l〇u， 其申最佳紙張理想塗佈量=紙張粗糙度+ 〇〜3u。適當 的塗佈，賦予紙張適度的疏水性及透氣性，使紙張具有良 好的染料離型移轉及染料印刷性。 本發明中紙張經基本塗佈後，必要時再加一層吸墨層 · 經 濟 部 智 慧 財 產 局 g X 消 費 合 社 印 製 (bsorbption Layer)加工，以增加水溶性染料印刷之接 =性。當然吸墨層加工與否，得視所使用紙張特性及基本 玉佈里而疋。吸墨層以增稠劑為主，增稠劑以羧曱基纖維 素（C)羧甲基殿粉（CMS )、礦物系合成糊及聚 丙烯酸酯等為佳。 ，本發明中紙張以石夕素樹脂與絲酸衍生物為主之基本塗 佈液塗佈後，必要時以增稍劑再塗佈-次，然後以水溶性558583 C7 D7 V. Creation instructions (please read the precautions on the back before filling this page) This invention is a kind of processing method of transfer pattern paper for wet transfer printing, especially using crushed resin and soil number 12_18. Alkanoic acid derivatives, such as: stearic acid and lauric acid mixed solutions, apply paper to the paper to make the paper moisture-proof and prevent the dye from printing on wet transfer printing patterns Processing method. The prior art method of using a hydrophobic resin as a base coating method for wet transfer printing has been mentioned in many patent documents: 1. Japan's "Nippon Printing Co." uses hydrophobic rosin ( Rosin) resin is basically coated on 30g / m2 thin leaf paper, and then pattern printing is performed using a color paste formulation containing reactive dyes, denatured rosin resin, toluene, and isopropyl alcohol (IPA) to make transfer pattern paper. The pattern is transferred from paper to cloth by using the principle of hot-melt adhesive of rosin resin. The dye is brought to the cloth, and then fixed and colored. The rosin resin, thinner, and printing aid are removed by washing. And uncolored dyes and other pharmaceuticals. Its patent documents include: JP54117208A, JP55022029A. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 2. The letterpress printing company used polyester resin or polyamide resin or vinyl resin or MARINE resin. Or acrylic, resin or cellulose, etc., to basically coat printing paper, art paper, coated paper, tissue paper, polypropylene (PP) film, polyethylene (PE), etc., and then disperse dye or reaction The dyes, resins, surfactants, and isopropyl alcohol (IPA) are pattern-printed for color paste formulations to make transfer pattern paper. The pattern transfer principle is to use a fabric pressure test solution and press the roller ， The scale of the melted tree paper is applicable to China National Standards (CNS) AOJt grid (210X 297mm) 558583 C7 D7 V. Creation instructions () Grease to the cloth, and then fix and color, and wash the resin to remove Thickeners, printing auxiliaries, uncolored dyes and other pharmaceuticals. Its patent documents are: JP52077282A, JP53134978A. 3. Denmark Dansk (DANSK) company has used carboxymethyl fiber (CMC), sodium alginate or 1 Ethylene dispersion or lysine acrylic dispersion, etc., is used to basically coat cellophane (giassine), and then it contains water-soluble dyes or water-dispersible dyes, carboxymethyl cellulose, sodium alginate, polysubstituted starch ethers Polyethylene glycol esters and polymers with a hydrophilic-hydrophobic balance (HLB) greater than 15 are pattern-printed with color paste formulations to make transfer pattern paper. The pattern and transfer principle is based on the use of fabric pressure-absorbing additives, often Winrolla. Pressurize, transfer the dye on the paper to the cloth, fix and color, and remove the thickener, printing aid and uncolored dyes by washing with water. Its patent documents are: USP5196030 〇 Traditional disadvantages: The transfer pattern paper uses resins as color paste thickeners, although it can take advantage of the hot and sticky adhesiveness of M Yue to improve the releasability of the pattern. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, but the resin cannot be completely removed from the cloth, resulting in shortcomings such as insufficient color vividness and poor fabric feel after the transfer. In addition, the use of resin as a thickener will affect the migration of the dye during dye fixing, and then affect the adhesion between the dye and the fiber, and the uniformity of dyeing, resulting in color fastness of the transfer product. ) Poor and increased color difference (color difference). On the other hand, when the resin is used to basically coat the paper, the resin content is _ 3 The paper size is applicable to China ^^ (CNS) A4jUt grid (210X 297 mm) ~~ ~ 558583 C7 D7 V. Creation instructions () The degree of film and the strength of the film will affect whether the resin agent will remain on the fabric after the transfer. Once the resin remains on the fabric, it will also affect the feel, color fastness, and color vividness of the fabric. Means to solve the problem: In order to solve the hand feel, color fastness, and color freshness of transfer products 4 Special question 4 'It is necessary to avoid the use of resin medicaments in paste.' Besides' the basics of paper The resin used for base coating must be screened. The basic requirements of the resin are fast and complete film formation, and the strength of the film must be high. This can prevent the resin from transferring with the colorant on the cloth during transfer. The hand feeling, color fastness, and color freshness of printed matter deteriorate. That is, the present invention is a method for processing transfer pattern paper for wet transfer printing, using a silicon resin and an alkyl acid derivative having a carbon number of 12 to 18, such as: a mixed solution of stearic acid and lauric acid to coat paper. Fabric processing method for transferring pattern paper for wet transfer to make paper have moisture permeation barrier and enable dyes to be printed thereon. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the present invention t 'Using no cutting resin in the prior art as the base coating agent, silicon is fast and complete, and can be avoided due to tree and butterfly When it is not ==, transfer to the fabric, causing the fabric to feel worse or the hue to be darkened. In addition, alkalene derivatives with carbon numbers of 12 to 8 are also used in the basic coating agent ... stearic acids and lauric acids are used to increase the number of dyes: Turning rate ° This paper's standard is suitable for CNS's standard (CNS) ) A4 lattice (21〇 × 297 mm) 558583 C7 D7 V. Creation instructions () The structure of the above-mentioned alkyl acid derivative is as follows: CH3 (CH2) n (CH = CH) m COOR where m = 0 ~ 12 η = 10 ~ 16 R = chain polyhydric or cyclic polyhydric alcohols. The above-mentioned alkyl acid derivatives are enhanced with dyes such as sorbitan monostearate and glycerol monostearate§ (GiyCero〗 〖monostearate) Good release transfer. The coating amount of the basic coating in the present invention is different due to the characteristics of the paper. The smaller the paper roughness, the smaller the coating amount; otherwise, the coating amount must be larger and the ideal coating amount of the S 'paper. = Paper roughness + 〇 ~ 10u, its ideal optimal paper coating amount = paper roughness + 〇 ~ 3u. Appropriate coating can give paper a moderate degree of hydrophobicity and air permeability, so that the paper has good dye release transfer and dye printability. After the paper is basically coated in the present invention, an additional ink-absorbing layer is added as necessary. The Ministry of Economic Affairs, Intellectual Property, and Industrial Property Bureau g X Consumer Co., Ltd. prints (bsorbption Layer) processing to increase the printability of water-soluble dyes. Of course, whether or not the ink-absorbing layer is processed depends on the characteristics of the paper used and the basic jade cloth. The ink absorbing layer is mainly a thickener, and the thickener is preferably carboxymethyl cellulose (C), carboxymethyl cellulose powder (CMS), mineral-based synthetic paste, and polyacrylate. In the present invention, after the paper is coated with a basic coating liquid mainly composed of syphilin resin and seric acid derivative, it is coated again with a thinner if necessary, and then water-soluble.
558583 經 濟 部 智 慧 財 產 局 員 工 消 費 合 社 印 製 C7 D7 五、創作説明（） 染料、增稠劑及助劑等為色糊配方印刷上述處理之紙張而 製得轉印圖案紙。色糊中增稠劑以綾甲基纖維素（CMC) 、羧甲基殿粉（CMS)、合成糊等對離型性為佳。水溶性 染料可為直接性染料（direct dye)、反應性染料（reactive dye)、士林染料（threnedye)、酸性染料（aciddye)、 金屬複合染料（metal complex dye)及分散性染料等。助 劑包括防止染料分解破壞，如還原防止劑、消泡劑及金屬 子封鎖劑等。 精練、漂白胚布經以增稠劑、酸驗劑及吸濕劑等為主 之壓吸液配方浸潰，以線壓45〜60 kg/cm之壓輥壓吸， 塵吸率控制在60〜70%，再與轉印圖案紙密切墨合經線 壓45〜60 kg/cm之壓輥輾壓，將紙上染料離型移轉至胚 布上，並將紙、布予以分離捲取。轉印後胚布再進行固著 及水洗等工程。固著方式可為飽和蒸處法、高溫蒸處法、 高壓蒸處法、熱熔固色法或冷壓捲置固著法等。 實施例 以下詳細說明本發明之具體實施例。 實施例一： 以50g/m2單面塗佈超乾光紙（Sllper calendering side coating paper)塗佈基本塗佈液，其配方如下·· 30〇g SYL-OFF Q2-7362 2」g SYL-OFF Q2-7367 50-1 〇〇g 烧基酸衍生物 本紙乐尺度適用中國囷家梂準（CNS ) A4况格（210X297公釐） one558583 Printed by the Consumer Affairs Bureau of the Ministry of Economic Affairs and Intellectual Property Co., Ltd. C7 D7 V. Creative Instructions () Dyes, thickeners and auxiliaries are used for color paste formulation to print the above-treated paper to make transfer pattern paper. The thickeners in the color paste are better release properties such as methylcellulose (CMC), carboxymethyl cellulose powder (CMS), and synthetic paste. The water-soluble dye may be a direct dye, a reactive dye, a threedye, an aciddye, a metal complex dye, or a disperse dye. Adjuvants include the prevention of dye degradation, such as reduction inhibitors, defoamers, and metal blocking agents. The scouring and bleaching germs are impregnated with a pressure-absorbing liquid formula mainly consisting of thickener, acid test agent, and hygroscopic agent. The pressure is controlled by a roller with a linear pressure of 45 to 60 kg / cm. The dust absorption rate is controlled at 60. ~ 70%, and then intimately with the transfer pattern paper, press the roller with a pressure of 45 ~ 60 kg / cm to roll, transfer the dye on the paper to the germ, and separate the paper and cloth. After the transfer, the germs are fixed and washed. The fixing method may be a saturated steaming method, a high-temperature steaming method, a high-pressure steaming method, a hot-melt fixing method, or a cold-pressed rolling fixing method. Examples Hereinafter, specific examples of the present invention will be described in detail. Example 1: 50 g / m2 single-side coated ultra-dry glossy paper (Sllper calendering side coating paper) was used to coat the basic coating solution, and its formula was as follows: · 30〇g SYL-OFF Q2-7362 2 ″ g SYL-OFF Q2-7367 50-1 〇〇g Benzoic acid derivatives This paper scale is suitable for China National Standards (CNS) A4 (210X297 mm) one
T_i; -iTrK匀背1£之^意事^^續寫，不頁」 558583 C7 D7 五、創作説明（） ， ^ 600-650g 甲 笨 上述配方SYL-OFF Q2-7362，係指道康寧公司生產之石夕 素樹脂；SYL-OFF Q2-7367係指道康寧公司生產之妙素、 脂架橋劑；該烷基酸衍生物係指碳數12-18之烷基駿衍生 物，其結構式為： CH3(CH2)n(CH=CH)m COOR，m=〇-12，n=l(M6 R=鍵狀多醇類或環狀多醇類 其中可為山犁醣單硬脂酸酯或甘油單硬脂酸酯等。 基本塗佈液塗佈量在2_3 g/m2，然後以反應性染料、海 藻酸鈉、高取代之羧曱基纖維素及助劑等為色糊配方，印 刷上述處理紙而製成轉印圖案紙；其色糊配方為： 60g 反應性染料 如 Remazol Blue R 12g 海藻酸鈉 如 CHT Alginate NVS 43g 羧曱基纖維素 如 Fine gum SA-MT 5g 摔樣酸 l〇g 硫酸納 2g 消泡劑 l〇g 還原防止劑 如 Ludigol 858g 水 經濟部智慧財產局員工消費合作社印製 精練、’示白、絲光棉布以含鹼液為主之壓吸液浸潰，並 經線壓40〜60 kg/cm之壓輥壓吸，壓吸率60〜70%， 再和上述轉印圖案紙密切疊合經壓輥以線壓4〇〜6〇 kg/cm 7 本紙张尺度適用中國國家標準（CNS ) A4见格（21〇>< 297公4 ) " 558583 A7 B7 五、發明説明（） 輾壓而後紙、布分'別捲取。轉印後布依使用藥劑特性，施 以不同固著、加工流程，可為冷壓捲置固著法、常壓飽和 蒸處法、常壓高溫蒸處法及熱固著法等；其鹼液配方為 l〇g 海藻酸鈉 如 Alginate PA-350 0-50g 燒鹼 0-50g 純鹼 0_50g 吸濕劑 0-10g 硫酸鈉 880-980g 水 上述轉印布之染料離型移轉率80%以上，經固著水洗 後上色率80%以上。 實施例二： 精練、漂白之蠶絲、羊毛及聚醯胺等織物亦可使用實 施例一之加工方法進行反應性染料濕或轉移印花加工。 實施例三·· 經濟部智慧財產局員工消費合作社印製 以50g/m2單面塗佈超軋光紙塗佈基本塗佈液，其 配方如下： 200g SM-3000 6.7g SM-3010 50-100g 烷基酸衍生物 20g 合成糊 如PTF(3%) 8 本纸乐尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 558583 C7 D7 五、創作説明（） 673-723g 水T_i; -iTrK ^ Issuance of 1 £ ^^^^ continued, no pages "558583 C7 D7 V. Creation Instructions (), 600-650g Jiaben The above formula SYL-OFF Q2-7362 refers to Dow Corning Shixisu resin; SYL-OFF Q2-7367 refers to the wonderful element and lipid bridging agent produced by Dow Corning; the alkyl acid derivative refers to the alkyl jun derivative with carbon number 12-18, and its structural formula is: CH3 (CH2) n (CH = CH) m COOR, m = 〇-12, n = 1 (M6 R = bonded polyhydric or cyclic polyhydric alcohols, among which can be sorbose monostearate or glycerol Monostearate, etc. The coating amount of the basic coating liquid is 2-3 g / m2, and then the reactive dye, sodium alginate, highly substituted carboxymethyl cellulose, and additives are used as the color paste formula to print the above treatment. Paper is made into transfer pattern paper; its color paste formula is: 60g reactive dyes such as Remazol Blue R 12g sodium alginate such as CHT Alginate NVS 43g carboxyfluorinated cellulose such as Fine gum SA-MT 5g thalamic acid 10 g Sodium sulfate 2g, defoaming agent 10g, reduction preventive agent such as Ludigol 858g, Intellectual Property Bureau, Ministry of Water Economy, Employee Consumption Cooperative, printed and refined, 'whitening, mercerized cotton The pressure-absorbing liquid mainly containing lye is impregnated, and the pressure is absorbed by a pressure roller with a linear pressure of 40 to 60 kg / cm, and the pressure absorption rate is 60 to 70%. With a linear pressure of 40 ～ 60kg / cm 7 This paper is in accordance with the Chinese National Standard (CNS) A4 (21〇) < 297 male 4) " 558583 A7 B7 V. Description of the invention () Do not roll paper or cloth. After transfer, the cloth is subjected to different fixation and processing processes depending on the characteristics of the agent used. It can be cold-rolled fixation method, atmospheric pressure saturated steaming method, atmospheric pressure high-temperature steaming method, and Heat fixing method, etc .; its lye formula is 10g sodium alginate such as Alginate PA-350 0-50g caustic soda 0-50g soda ash 0_50g hygroscopic agent 0-10g sodium sulfate 880-980g water dye transfer cloth The transfer rate is more than 80%, and the coloring rate after fixing water washing is more than 80%. Example 2: Refined and bleached silk, wool, polyamide and other fabrics can also use the processing method of Example 1 for reactive dyes Wet or transfer printing process. Example 3 · Printed on 50g / m2 single-sided coating by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The basic coating solution for calendered paper coating, its formula is as follows: 200g SM-3000 6.7g SM-3010 50-100g alkyl acid derivative 20g synthetic paste such as PTF (3%) 8 This paper scale is applicable to Chinese national standards ( CNS) A4 specifications (210X 297 mm) 558583 C7 D7 V. Creation instructions () 673-723g water
“(請先M讀背面之注意事項再填寫本f ) 上述SM-3000，係指美國通用公司矽素樹脂乳化液， SM-3010係指美國通用公司矽素樹脂架橋劑乳化液，烷基 酸衍生物係指碳數12-18之烷基酸衍生物，其結構式為： CH3(CH2)n(CH=CH)m COOR > m=0-12 ^ π=10-16 R=鍵狀多醇類或環狀多醇類 其中可為山幫醋早硬脂酸醋或甘油翠硬脂酸g旨等。 基本塗佈液塗佈量在2-12g/m2，然後以實施例一之色糊 配方印刷製得轉印圖案紙，再以實施例一之轉印加工方式 進行濕式轉移印花加工，其染料離型移轉率以上， 經固著水洗後，上色率亦在80 %以上。同時本加工法亦 可應用於蠶絲、羊毛及聚酿胺纖維之濕式轉移印花加工。 實施例四： 經濟部智慧財產局員工消費合作社印製 以50g/m2單面塗佈超軋光紙塗佈實施例一或實施例 泰 三之基本塗佈液，然後以酸性染料、豆膠糊（GuarGum) 、澱粉醚及助劑等為色糊配方，印刷上述處理紙而製成轉 印圖案紙；其色糊配方如下： 60g 酸性染料 如 Lanaset Blue 2R 30g 染料溶解劑 如 Glyezin A 50g 豆膠糊（Guar Gum ) 如 Indalca HT-24 0-5g 殿粉驗（starch ether ) 如 Solvitose C-5 9 本紙法尺度適用中國國豕標準（CNS )八4洗^ ( 210 X 297公4 ) 558583 經濟部智慧財產局員工消費合作社印製 A7 __B7 五、發明説明（） 5g 還原防止劑 如Na Cl〇3 2g 消泡劑 l〇g 硫酸鈉 838-843g 水 精練、漂白蠶絲、羊毛或聚醯胺纖維等織物以含酸劑為 主之壓吸液浸潰，並經線壓40〜60g/m之壓輥壓吸，壓 吸率60〜70%，再和上述轉印圖案紙密切疊合經壓輥以 線壓40〜60 kg/m輾壓，而後紙、布分別捲取。轉印布 以常壓飽和蒸處法或高壓蒸處法等固著染料。其酸劑配方 如下： 20-30g 豆膠糊如 Indalca HT-24 15g 檸檬酸（1 : 3) 2g 消泡劑 10g 硫酸鈉 943-953g 水 上述轉印布之染料離型移轉率達80%以上，經固著水 洗後上色率達80%以上。 綜合以上，本發明之濕式轉移印花用轉印圖案紙加工 方法為前所未見，能有效解決轉印物手感、色牢度與顏色 鮮豔度等問題，而具產業利用價值。 為此，爰依法具文提出專利申請，請惠予審查，並祈 及早核准本案專利，是為至每。 10 本纸伕尺度適用中國國家標隼（CNS)A4規格（210X 297公釐）"(Please read the notes on the back before filling in this f) The above SM-3000 refers to the silicone resin emulsion of American General Corporation, and SM-3010 refers to the silicone resin bridging agent emulsion of American General Corporation, alkyl acid Derivatives are alkyl acid derivatives with 12-18 carbon atoms, and its structural formula is: CH3 (CH2) n (CH = CH) m COOR > m = 0-12 ^ π = 10-16 R = bonded Polyols or cyclic polyols can be mountain vinegar early stearic acid vinegar or glyceryl stearic acid g. Etc. The coating amount of the basic coating liquid is 2-12g / m2, and then the first example The color paste formula is printed to obtain the transfer pattern paper, and then the wet transfer printing process is performed by the transfer processing method of Example 1. The dye release rate is higher than that. After the washing with fixing water, the color rate is also 80%. Above. At the same time, this processing method can also be applied to the wet transfer printing processing of silk, wool and polyurethane fibers. Example 4: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and coated with super-calender at 50g / m2 on one side Paper coating the basic coating solution of Example 1 or Example 3, and then using acid dyes, GuarGum, starch ether and additives as Color paste formulation, printing the above treated paper to make transfer pattern paper; the color paste formulation is as follows: 60g acid dyes such as Lanaset Blue 2R 30g dye dissolving agent such as Glyezin A 50g bean paste (Guar Gum) such as Indalca HT-24 0 -5g Starch ether, such as Solvitose C-5 9 This paper method scale is applicable to China National Standard (CNS) 8-4 wash ^ (210 X 297 male 4) 558583 Printed by A7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs __B7 V. Description of the invention (5) 5g reduction preventive agent such as NaCl03 2g defoaming agent 10g sodium sulfate 838-843g water refining, bleaching silk, wool or polyamide fiber, etc. Liquid immersion, and pressure suction by a pressure roller with a linear pressure of 40 ~ 60g / m, pressure absorption rate of 60 ~ 70%, and then closely overlap with the above transfer pattern paper through a pressure roller with a linear pressure of 40 ~ 60 kg / m roller. Press and then take up the paper and cloth separately. The transfer cloth is fixed by dyeing at normal pressure or high pressure. The acid formula is as follows: 20-30g soybean paste such as Indalca HT-24 15g citric acid (1: 3) 2g defoamer, 10g sodium sulfate, 943-953g water The rate is over 80%, and the coloring rate after fixing water washing is over 80%. To sum up, the method of processing the transfer pattern paper for wet transfer printing of the present invention is unprecedented, which can effectively solve the hand feeling of the transfer material, The problems of color fastness and color vividness have industrial use value. To this end, Jiyi has filed a patent application in accordance with the law. Please review it and pray for the early approval of the patent in this case. 10 This paper size is applicable to China National Standard (CNS) A4 (210X 297mm)
(請先閱讀背面之注意事項再填寫本頁)(Please read the notes on the back before filling this page)