TW553991B - Polyolefin resin composition, laminate using the same and method for producing the same and applied products thereof - Google Patents

Abstract

The present invention relates to a polyolefin resin composition, a laminate using the composition and applied products using them. The polyolefin resin composition of the present invention comprises a polyolefin resin and a compound having intramolecular unsaturated bondings. It is characterized in that in the polyolefin resin composition, the number of intramolecular unsaturated bondings is more than 0.5 per 103 carbon. While this polyolefin resin composition is used as a resin material for an extruded laminate, the low-temperature moldability and high-speed moldability at the time of forming the extruded laminate are good, and the adhesiveness with the other materials is extremely high. The composition of the present invention is suitable for use in various laminates, for instance, and applied product such as a peeling substrate, operation sheet, packaging material, container, and so on.

Description

553991 A7 _B7_ V. Description of the invention (/) (Please read the precautions on the back before filling this page) The present invention is related to a polyolefin resin composition, a laminated body using the composition, an application product using the same, and this Waiting system. More specifically, the composition of the present invention has an unsaturated bond in the molecule, and a formed body made of an extruded product, an injection molded product, a hollow molded product, or the like using a film, a sheet, or the like using the composition has Excellent adhesion, paintability, printability, etc. In addition, the composition can significantly increase the polarity of the treated surface of the formed body by using surface treatment techniques such as ozone treatment in combination. In particular, the polyolefin strip resin composition of the present invention can exert a significant effect as a resin material for extrusion lamination, and has good low-temperature moldability or high-speed moldability during extrusion lamination, and extremely high adhesion to dissimilar materials. . The present invention relates to the composition, a laminated body of the composition and a dissimilar material, and an application product using such a laminated body as a release substrate, an operation board, a packaging material, a container, and the like. The invention is based on a patent application in Japan (Japanese Patent Application No. 1 G-2 9 4 4 9 9; Japanese Patent Application No. 1-2 7 9 2 0 1; Japanese Patent Application No. 1-2 7 9 2 0 3 Number, No. 10-279205, Tobei No. 1D-279208, No. 10-279214, No. 10-279218, the content of the Japanese application is included in the part of this specification Share Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Strip resin has excellent transparency, heat resistance, air permeability, and chemical resistance. However, the molded articles of these resins lack the problems of poor surface wettability, adhesion, coatability, and printability. One of the uses of the above-mentioned polyolefin strip resin, for example, various films, papers, and paper sizes are applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 5. Description of the invention (>) Metal foil, Laminates formed by extrusion lamination on various substrates such as non-woven fabrics. (Please read the precautions on the back before filling this page.) This extrusion and lamination process is a matter of course and requires high adhesion to various substrates, but these polyolefin resins have low adhesion strength to various substrates. It is impossible to obtain a laminated body with high interlayer strength. Specifically, extruded laminated polyethylene, polypropylene on various plastic films such as polypropylene, polyamide, polyester, ethylene vinyl acetate copolymer alkalizate, etc., aluminum foil, cellophane, paper, non-woven fabric, etc. Polyolefin polymers are used to impart hot plate properties and moisture resistance. These laminated products are mainly used in large quantities as packaging materials. In extrusion lamination, in order to ensure the adhesion strength of the most widely used polyolefin resin and heterogeneous materials, the molding temperature of the resin is extremely high, and surface treatment such as ozone treatment and electric discharge treatment is used during the molding. As a countermeasure. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs , Odor generation, etc. γ Especially in the polyolefin resin, since the propylene strip polymer is a non-polar resin, the adhesion property to the above-mentioned polar substrate is substantially deteriorated. Therefore, when extrusion lamination is performed in a substrate, the general resin temperature is set to a high temperature of 300 ° C or more, and the surface of the molten resin film extruded from the extruder is oxidized to improve the adhesion to the substrate. In the past, in order to improve productivity, higher high-speed moldability was sought, and setting the resin temperature to a higher temperature would not be obtained, which not only deepened the above problems ① and ②, but also reduced the adhesive strength. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 _B7____ 5. Description of the invention (4) In addition, the highly crystalline 4-methyl-1 -pinene strip resin, transparency, ® Excellent heat resistance, gas permeability, and chemical resistance. However, the surface of this resin molded body lacks wettability, and when it is a laminated body, a laminated body with low adhesive strength and high interlayer strength of different materials cannot be obtained. Here, it is shown in Japanese Patent Publication (A) No. Hei 5-1 0 4 6 9 4 _ The production method of the laminated layer of the 4-methyl-1-pentene strip resin with improved interlayer strength is 8 mm thin . In the invention, the 4-methyl-pentene strip resin is treated with ozone, and the substrate to which the substance is adhered is subjected to an oxidation treatment or a thickening coating. However, even if this method is still not sufficient to improve the interlayer strength, the low temperature and high-speed performance required in recent years are especially required. There is a solution to the pollution environment in the case of lower temperature and lower case. For the sake of the law, another example is shown in the following, where the burial number is 4 gas, 72 odor, 7 5, 7 pressure, 57 pressure, and the temperature is low (A low report ° c public 90 open 2 public ο profit 15 specifically in the Japanese sun tree in Strip, ene such as B. Poly / V make the mil coating on the base material to increase the adhesion and increase the lamination pressure on the ML coating. ^^^ 装 ---- 11--tT --------- (Please read the notes on the back before filling out this page} The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs has printed it as a stickman. The slight reduction in temperature can cause the temperature odor or smoke to develop. However, the temperature of the odor caused by the temperature can be reduced, and the thin film can be resolved. The untitled problem is thick and large. Soon there will be changes in retention and residual speed, such as fee Lt, no legal aid, and low yield reduction and strength, and so on. Nisshu Yutiao, olefin polymerization party in the question 11 11 79 good 86 change 18 This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 _B7_ V. Description of the invention (4) Adhesive resin composition for improving adhesive strength. However, until now, it has been printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to improve productivity, seek high-speed moldability, and not pollute the environment. When the system is solving the problem, the problem of separation and filling, and the combination of alkenyl and base are required. Peeling the ethylenic acid is used to separate it, and the bad heat is not necessary. When the polyethylenic shape is peeled, it is resistant to the tree. The low joints of the fat device are filled with high density, the smoke oxygen is filled with stripe, and the density is raised. It is necessary to make the olefin speed and the density and density to be high and high. Shaped olefinic material with a low MW pressure to produce the college entrance examination aggregates into the polymer material Lime tree sticky material _ squeeze out the internal cause, because the high material and the adhesive structure or base polymer M from the enterprise, or Zhongwei mentions the fat material package or application and sign-off sheet U. It is always time and way, and the tree base, and the multi-standard pentene are used on a large scale, such as lamellar strips, etc. Β Medium material is particularly short-term and temperature-increasing. The high-M alkenyl group is used to fill the seam of vinylene film, and it is more effective in filling cohesive polymer environments. In this year, ^ j B is high in fat shadows in the year, and the ring paper is close to the price place U. The tree is resistant to making protective paper, which is peeling, and the low media is in the layer, and the degree is high. I want fat to make sure that I use it as a body when I put it on? I want a strong lifting ring in the joint. The tree is set for the sticky base, so that the stick α mixes the stick and the edge is on the stick. In the lethal method, the base is now peeling off its odor. On the body, the single element is detached and its special shape, the base layer of Shi Zhongqi and Shi Youqi are separated from each other, and the environment is high, and the material is dissociated from the seam. C This layer And the temperature outside the ring is more layered and the layer to be stripped is filled, so that the high and one film have different heights and the use of the base seam or the body as a whole ------------ -Install -------- Order ------ 11 (Please read the note on the back of the phonetic note before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) 553991 Α7 Β7 V. Description of the invention (r) If the adhesiveness is lower, the temperature of the lamination must be further increased, and forming at a low speed, which makes the above problem more serious. (Please read the precautions on the back before filling out this page.) The operation panel 傜 is used on the surface of multi-layered panels such as synthetic leather with uneven patterns or three-dimensional creativity. The operation panel is composed of a structure in which an operation layer is laminated on a substrate. The surface of the operation panel is embossed firmly, and the embossing is extruded, copied, and three-dimensionally created on the synthetic leather. The operation sheet 傺 uses a laminated body that forms a strong embossing and has heat resistance during embossing processing operations. Generally, polypropylene is laminated and embossed on a substrate made of paper or the like to prevent oxidization. Processors such as silicon strip release agents are used as the operating layer. However, the adhesion strength of polypropylene to paper is quite high, and it is pressed against the skin material of the multilayer sheet. When it is embossed, it adheres to the skin material and peels between the substrate and the operating layer. Adhesive strength. Moreover, it is sought to make it in a shorter time. However, when the temperature of the resin is increased, the influence of smoke and the like on the working environment and the surrounding environment is increased, and problems such as deterioration of product odor due to deterioration of gasification at high temperatures arise. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In addition, the packaging is made of a layer of low-density polyethylene and other materials, such as paper, non-woven fabric, and aluminum foil. Materials are used as general packaging materials for industrial, industrial and household products. In addition, a packaging material having a layer made of a low-density polyethylene or the like as a sealing layer is laminated on a substrate made of a barrier material such as an aluminum foil or a polyethylene terephthalate (PET) film as a sealing layer. Dry food packaging, water products This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 ____ 5. Description of the invention (b) Food for food packaging Packaging materials or medical packaging materials such as capsules for medical treatment. In addition, containers made of a laminated body of paper and polyethylene are used as solid, liquid, and gas containers for industrial medicine or industrial materials, and food and medical containers made of a laminated body of paper and polyethylene are used. Used as food containers for dry foods, aquatic foods, or medical containers for pharmaceuticals. The laminated body used for this packaging material or container is generally manufactured by extrusion lamination. However, in recent years, it has been particularly sought to improve the adhesion strength between layers and manufacture it in a shorter time (high-speed molding). However, increasing the temperature of the resin has a problem that the influence of smoke and the like on the working environment and surrounding environment increases. In addition, foods, medical packaging materials, or containers can cause odors to remain in the packaging materials or containers due to the deterioration of gasification at high temperatures, and cause problems such as sticking to food and beverages. In addition, in order to improve the strength between the layers, the use of adhesives or thickening coatings is also considered, but the use of solvents, complex coating operations, and the preparation of thickening agents must be used to treat the thickening agents attached to the stick. I do it because it deteriorates the workability and increases the cost. Especially not suitable as packaging materials or containers for food and beverage. In order to solve the above problems, the present invention provides a compound having a specific structure in a specific amount in a polyolefin strip resin, which can maintain satisfactory adhesion to a heterogeneous substrate, and The resin temperature during the molding of the laminated layer is controlled at a low temperature to minimize the impact on the working environment and surrounding environment. ② It can be further increased by not increasing the resin temperature. -8- This paper applies Chinese National Standards (CNS) A4 specification (210 X 297 mm) ----------------— II ^ > — — — 1 —--- (Please read the precautions on the back before filling in this page ) 553991 Α7 Β7 V. Description of the invention (7) High-speed moldability, ③ A polyolefin resin composition of a molded article having excellent adhesion, coating, and printability can be obtained. (Please read the note on the back? Matters before filling out this page) In other words, the polyene strip resin composition of the present invention is (M) containing (A) a polystyrene resin and (B) a compound having an unsaturated bond in the molecule. Polyolefin strip resin composition. Its sign is that the number of unsaturated bonds in the molecule in the polyolefin resin composition is equivalent to 0.5 or more in 103. When this polyolefin resin composition is used in a laminate, it can be laminated at a low temperature and at a high speed to form an interlayer strength, and it can be widely used in various laminates. In addition, depending on the application, (1) a polyolefin strip resin composition containing (A1) a polyolefin strip resin having a sulfonic number of 3 to 20 and (B1) a compound having an unsaturated bond in the molecule. In addition, the above-mentioned polyene strip resin composition containing 9A) the polyolefin strip resin and (B) a compound having an unsaturated bond in the molecule, further comprises (C) a polyoxyl compound (M2) polyolefin strip resin composition Things are what you want. In addition, the polyene strip resin composition containing (A) a polyene strip resin and (B) a compound having an unsaturated molecule in the molecule and (C) an epoxy compound further contains (D) The (M 3) polyene fluorene resin composition of the functional group-reactive olefin strip resin is desired. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the polyene resin resin composition of Shanghai is especially suitable for various laminates. For example, it is suitable for a variety of applications such as peeling of substrates, operation sheets, packaging materials, and containers. Brief Description of Drawings Figure 1 is a schematic diagram of the structure of a laminated body. -9- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (4) Figure 2 is a side cross-sectional view of an example of the layer composition of a peelable laminate. Fig. 3 (a) is a side cross-sectional view of an example of a layer configuration of a peelable laminated body. (Please read the precautions on the back before filling out this page.) Figure 4 傺 is a side cross-sectional view of an example of the layer configuration of an operation sheet. Fig. 5 is a schematic structural diagram of a manufacturing example of synthetic leather. Fig. 6 is a side cross-sectional view showing an example of the layer configuration of the operation panel. Fig. 7 (a) is a schematic diagram of the manufacturing method of the laminated body. Fig. 8 (a) is a side cross-sectional view of an example of a layer configuration of a packaging material. Fig. 9 (a) is a schematic diagram of the manufacturing method of the laminated body. Fig. 10 is a side cross-sectional view of an example of a layer configuration of a laminated body using a packaging material or a container. Section 11 is a schematic diagram of the manufacturing law of the laminated body. Fig. 12 (a) is a side cross-sectional view showing an example of a layer configuration of a food and medical container. Fig. 13 (a) is a schematic diagram of the manufacturing method of the laminated body. Fig. 14 (a) is a schematic constitutional diagram of the manufacturing method of the laminated body. In order to implement the best form of the invention, in the polyolefin resin composition of the present invention, the component (A) is a polyolefin resin, and more specifically, for example, low-density polyethylene (LDPE) polymerized by high-pressure radicals, Ethylene, vinyl ester copolymers, ethylene, copolymers of α, /?-Unsaturated carboxylic acids or their derivatives, etc. Printed by other consumers of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Consumer Cooperative, other polyene resins such as Ziegler catalysts, Phillips catalysts, aromatic ring metal derivative catalysts, etc. The density of 0.86 to 0.98 / cm3 of ethylene monomers, propylene monomers and other cr-olefins with a sulfur number of 2 to 20 alone or these mutual copolymers. On the low-density polyethylene (LDPE) polymerized by high-pressure free radicals, its paper size -10- applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 _B7_ V. Description of the invention (9) The density is 0.91 to 0.94 g / cm3, preferably 0.912 to 0.935 / cm3, and more preferably 0.912 to 0.930 g / cm3. The melt flow pseudo number is 0.001 to 1000 mg / l Oroin, preferably 0.1 to 100 g / 10 min, and more preferably 1.0 to 50 g / 10 min. The melt tension is preferably 1.5 to 25 g, and more preferably 3 to 20 g. The Mw / M η is 3.0 to 10, and more preferably 4.0 to 8.0. In addition, the terminal vinyl group of the polyethylene is 0.4 or more of 1,000 sulfonic atoms in the polymer chain, preferably 0.4 to 0.8. The ethylene and vinyl ester copolymers of the present invention include, for example, vinyl acrylate, vinyl acetate, vinyl hexanoate, vinyl octanoate, vinyl laurate, vinyl stearate, and trifluorovinyl acetate containing ethylene as a main component. A copolymer of vinyl ester monomers such as esters. Among them, vinyl acetate (EVA) is more preferable. In other words, a copolymer made of 50 to 99.5% by weight of ethylene, 0.5 to 50% by weight of vinyl ester, and 0 to 49.5% by weight of other copolymerizable unsaturated monomers is preferred. In particular, the vinyl ester content is 3 to 20% by weight, preferably 5 to 15% by weight. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- tr ---------- (Please read the precautions on the back before filling out this page) Common purpose methylpropylpropylpropyl ^ 1, ethyl, methyl, methyl π acid esters, esters, allyl allyl hexyl derivatives I propionic acid Butanecycloaliphatic acid, methacrylic acid, or methacrylic acid, such as methacrylic acid, e.g. methacrylic acid, methacrylic acid, methacrylic acid, e.g., methacrylic acid, e. Esters are not isopropyl propyl propyl laurate /?-Ethyl formate, such as formic acid, such as acrylate cyclic acid α example, ester acrylate acrylate, etc. methyl, propylene propyl Formazan, formazan and co-gold propionic acid, esters, succinyl esters, alkenyl butyl esters, propylene propyl n-butyl laurate, alkenyl isoacids, bismuth polyacrylic methacrylate, polypropenyl methacrylate, intellectual property bureau of the Ministry of Economic Affairs Printed by employee consumer cooperatives 553991 Printed by employees' consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7_—15. Description of the invention (i.) Stearyl acrylate, epoxy propylene acrylate, ethoxypropyl methacrylate_

Wait. Among them, alkyl esters such as methyl (meth) acrylate and ethyl ester (EVA) are more preferable. In particular, the content of (meth) acrylate is 3 to 20% by weight, preferably 5 to 15% by weight U. The above-mentioned high-pressure radical polymerization method, the pressure is 500 to 3500 kg / cm 2 G > the polymerization temperature is 100 ~ 400 ° C, using a tubular reactor, autoclave reaction, polymerization in the presence of free radical generators such as organic or inorganic peroxides. In addition, ethylene monopolymers with a density of 0.86 to 0.98 / cm3 are obtained by polymerization at low, medium, and high pressures using Ziegler catalysts, Phillips catalysts, and aromatic ring metal derivative catalysts. Propylene monopolymer or α-olefin mutual copolymer with a sulfonic number of 2 to 20, such as ultra-low density polyethylene with a density of 0.86 g / cin3 to 0.91 g / cm3, and a density of (K91g / cnr3 to 0.94 g / cm3 of linear low-density polyethylene (LLDPE), ethylene stripe polymers such as high-density polyethylene with a density of 0.9949 / cm3 or more, propylene stripe polymers, propylene-ethylene copolymers, etc. Polybutylene resin, 4-methyl-prenene strip resin, etc. Especially for applications requiring peelability, heat resistance, transparency, etc. for peeling bodies, handling M plates, etc., crystalline resins with a carbon number of 3 to 20 Specific examples of the aforementioned α-olefins having a sulfonic number of 2 to 20 are, for example, ethylene, acrylic, butylene, 4-methyl-1-pentene, resin, dihexene, butin, butadiene, 1-dodecene, etc. The U) component of the present invention may be used in combination with a weight% or less (preferably 30 weight% or less) depending on the purpose, for example, polyethylene strip resin, ethoxylate- Acid_12- " " " -------------------- Order --------- (Please read the precautions on the back before filling This page) Paper size_Chinese National Standard (CNS) A4 specification (21G x 297 male f " 553991 A7 B7 V. Description of the invention (i) Vinyl ester copolymer, ethylene-ethyl acrylate copolymer, etc. are polar Based ethylene copolymers, etc. (Please read the note on the back? Matters before filling out this page.) In addition, the component (A) of the present invention has a load of 2.16 g and a melt flow rate (190 ° C for polyethylene). , Polypropylene or 4-methyl-1-pentene strip resin is 230 ° C) ϋ · 0 0 1 ~ 1 000g / 1 Omin is better, more preferably 0 · 1 ~ 100g / lOmin, the best is 1.0 ~ 50g / 10min. If the melt flow rate is too low or too high, the moldability is not good. And when the melt flow rate is too high, the strength of the product is not good. 9 of the present invention b) The component is a compound having an unsaturated bond in the molecule. The number of unsaturated bonds in the molecule must be equal to or more than 0.5 in the 103 sulfonic acid in the entire polyolefin resin composition. If the number of unsaturated bonds in the molecule is less than 0.5, the effect of improving adhesion, coating properties, and printability is small. (B) The compound of the component, for example, a compound having several unsaturated bonds in the molecule, polybutadiene, preferably at least one member selected from 1,2-polybutadiene, polyisobutylene, natural rubber, and ethylene -Compounds, oligomers or polymers of propylene-diene terpolymer, ethylene-allyl (meth) acrylate, ethylene- (meth) acrylate, and the like. Among them, in terms of handleability, workability, etc., 1.2-polybutadiene, especially 1,2-polybutadiene is preferred. These may be used alone or in combination of two or more. The load of the compound (2.2) printed by the Consumer Cooperative Society of the Intellectual Property Bureau of the Ministry of Economic Affairs is 2.16 kg. The melt flow rate is preferably 0.001 to 1000 g / lOmin, more preferably 0.1 to 100 g / l0min, and the best is 1.0 ~ 50g / 10min. If the melt flow rate is too low or too high, the moldability is not good. When the melt flow rate is too high, the strength of the product is not good. -13- The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 ~ ^ ------- B7 V. Description of the invention (^) The number of unsaturated bonds in the molecule is ( B) Among the compounds of the component, 0.5 to 250 値 in 10 sulphur is preferable, 5 to 250 in 103 sulphur is more preferable, and 50 to 250 in 103 sulphur is more preferable. If the number of unsaturated bonds in the molecule is too small, the improvement effect of adhesion, coatability, printability, etc. is small, and if too many, the thermal stability will be deteriorated. The (M) polyolefin resin composition having a component (A) and a component (B) can suitably be combined with a polyethylene resin, a polypropylene resin and the like. In addition, other forms of the polyene strip resin composition of the present invention include a compound having an unsaturated bond in the molecule consisting of a polyolefin strip resin (U1) having a sulfonate number of 3 to 20 and a component (B). The resulting (M 1) polyolefin resin composition. The composition requiring peelability and heat resistance of a peeling body or an operation sheet is preferably a monopolymer or a mutual copolymer of (α1) an α-olefin having a sulfonic number of 3 to 20 or a copolymer thereof. Examples of such suitable examples include polypropylene strip resin, 4-methyl-1 pentene strip resin, 1-butane, 1-hexane, 1-octane, 1-decane, and I-dodecene. Depending on the purpose and application, it may be mixed with appropriate other (A) ingredients. For example, consider the balance between heat resistance, peelability, and adhesion (please read the precautions on the back before filling this page) -------- Order --------- Intellectual Property Bureau, Ministry of Economic Affairs Employee consumer cooperatives printed together to form a common purpose lip Hw S tree alkene acetate pentyl acetate II T alkenyl ethyl methyl, such as 4 cases, with s 0 tree tree bar allyl allyl polymerizable 1) pole A column (TTK In the combination, the time and the time of the use of olefins, copolymers, ethylene, and other materials are very basic, polycoesters, acetic acid, allyl acetate, heat-resistant. / Sexual divorce

Ethylene density is low) / %% S ο 3 is better / -V 8% S This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the employee consumer cooperative 553991 A7 _______B7 V. Description of the invention (θ) 4-methyl-1-pentene fluorene resin, for example, 4-methyl-pentene alone, or this substance and several other sulfonate numbers 2 Copolymer of ~ 16 alpha-olefins. At this time, in the (A) 4-methyl-prene resin composition, depending on the purpose, 49.9% by weight (preferably 30% by weight) non-polar polyolefin resin and ethylene, for example, may be used in combination. -Polyethylene groups, such as vinyl acetate copolymers and ethylene-ethyl acrylate copolymers. In addition, the melt flow rate (261TC) of the 5.0-kg load component (261TC) is preferably 10 ~ 500g / 10min, more preferably 20 ~ 300g / l0fflin, and the most preferable is 5G ~ 30Qg / lQfflin . When the melt flow rate is too low or too high, the moldability is not good. In addition to S, it is composed of (M2) polyolefin resin containing (C) component fluorene compound added to compound of (A) component polyolefin resin and (B) component having a certain amount of unsaturated bonds in the molecule. Good thing. The component (C) of the epoxy compound is preferably a polyvalent epoxy compound containing at least two or more alkoxy groups (ethylene oxide groups) in the molecule and having a molecular weight of 3,000 or less. By containing more than two cyclochloro groups in the molecule, the adhesion strength when the fluorene group in the molecule is 1% can be improved. (C) When the molecular weight of the epoxy compound is 3GG () or less, the adhesive strength can be increased when the composition is formed, and it is preferably 1500 or less. (C) The epoxy compound is exemplified by dipropyl propionate benzoate, dipropylene oxide isobenzoate, dipropylene oxide p-benzoate, dioxopropyl adipate, and trimethylolpropane tricyclic ring. Oxypropyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, butanediol glycidyl ether, hydrogenated bisphenol A dioxopropyl ether, phenol prospinane polyglycidyl ether, Epoxidized vegetable oil, etc. -1 5-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

(Please read the notes on the back before filling this page)

553991

V. Description of the invention (4) Among them, epoxidized vegetable oil is preferred in terms of ease of handling and safety when used in food packaging materials. (Please read the precautions on the back before filling out this page) Here, 璟 oxidized vegetable oil 傺 is used to vaporize unsaturated double bonds of natural vegetable oil, such as epoxidized soybean oil, 璟 oxidized flax Kernel oil, epoxidized olive oil, epoxidized safflower oil, epoxidized corn oil, etc. Such epoxidized vegetable oils are commercially available products such as "0-13GP" (epoxidized soybean oil) and "0-18GA" (epoxidized sub-oil) produced by Asahi Denka Kogyo Co., Ltd. In addition, when the vegetable oil is oxidized, there is no slight byproduct oxidation or the presence of insufficient epoxidized oil, which does not hinder the spirit and essence of the present invention. In addition, in order to further improve the adhesion, a (M3) polyene strip resin composition containing an olefin strip resin having a functional group capable of reacting with an epoxy group in addition to the component (D) is preferable. Examples of the functional group capable of reacting with an epoxy group include a carboxyl group or a derivative thereof, an amine group, a phenol group, a hydroxyl group, a thiol group, and the like. Among these, in terms of the balance between reactivity and stability, acid anhydride groups, carboxyl groups, and metal carboxylic acid hydrochloric acid are preferred. The methods for introducing a functional group that reacts with an epoxy group into an olefin resin mainly include a copolymerization method and a graft method. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It is an olefin copolymer having functional groups reactive with fluorenyl group, which is produced by a copolymerization method, for example, a compound capable of reacting with an epoxy group and a multi-component copolymer of ethylene. Epoxy-reactive compounds used in copolymerization, for example, α, /?-Unsaturated carboxylic acids such as (meth) acrylic acid; (meth) acrylic acid-1 6-This paper applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) 553991 A7 _B7__ V. Description of invention (π) (Please read the notes on the back before filling this page) Unsaturated carboxylic acid metal salts such as sodium; maleic anhydride, itac Unsaturated carboxylic acids such as acid anhydrides and citric anhydride, hydroxyl-containing compounds such as (meth) acrylic hydroxyethyl esters, (meth) acrylic alcohols; unsaturated amine compounds such as allylamine, etc. And other restrictions. Among them, those having an acid anhydride group, a carboxyl group and a carboxylic acid metal salt are preferred. In addition, copolymers of vinyl alcohol esters such as (meth) acrylates, vinyl acetate, vinyl propionate and the like added to these non-planar compounds can also be used. These compounds may be used in a mixture of two or more kinds with a copolymer of ethylene, or a copolymer of two or more kinds of these compounds with ethylene. It is preferable to use an ethylene-maleic anhydride copolymer or an ethylene-maleic anhydride- (meth) acrylate copolymer as the olefin copolymer having a functional group capable of reacting with an epoxy group to be produced by a copolymerization method. The modified olefinic resin introduced with a functional group capable of reacting with a tritium group by graft modification generally melts an unsaturated compound for modification in the presence of a radical generating agent such as a peroxide. Or made in the molten state with polyene. Polyolefins for graft modification such as LDPE, LLDPE, HDPE, PP, ethylene-propylene copolymer, propylene-butene-1 copolymer, EVA, (M) A, ethylene-vinyl acetate- (meth) acrylate Copolymers and the like may be used alone or in combination of two or more. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Alternatively, copolymers containing an acid or a derivative thereof, such as an ethylene- (meth) acrylate-maleic anhydride copolymer, may be additionally graft-modified. There is no particular limitation on the type of the radical generator used in the graft modification, and a general organic peroxide is used. Among them, in terms of reactivity and ease of handling, specific examples include difluorenyl peroxide, 2, 5-dimethyl-17. This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (4) Bases ~ 2, 5-bis (dibutyl peroxide) smelt, i, 3 · bis (dibutyl isopropyl peroxide) Group) Unsaturated compounds for the perchlorination modification of benzene and phenylfluorenyl groups. The unsaturated compounds which are the same as the compounds of ethylene and polyalkylene groups can be used. Tombstones with carboxylic acid groups or carboxylic anhydride groups can be used instead. Unsaturated groups that react with free radicals such as metal salts, amine groups, and leptyl groups. Unsaturated unsaturated compounds such as (meth) propionic acid, etc. = α, point-unsaturated dwarf acid; (meth) propionate sodium, etc. $ α $ saturated money metal salts; maleic anhydride Unsaturated carboxylic acids such as, itaconic anhydride, lemon dianhydride, etc .; (meth) acrylic acid via ethyl esters, (meth) acrylic alcohol, etc .; compounds containing radicals; amine compounds such as allylamine Etc., but not subject to this restriction. Among them, those having an acid anhydride group, a carboxyl group, and a carboxylic acid metal salt are preferred. The amount of the stripe resin having a functional group capable of reacting with an epoxy group, in general, is a resin made of a polyolefin resin and a stripe resin having a functional group capable of reacting with an epoxy group. In terms of ingredients, it is "30% by weight", preferably 2 to 25% by weight, and more preferably 5 to 20% by weight. Adding more than 30% by weight can improve the adhesion, but it has no economic benefits. When the epoxy compound is contained, a synthetic resin such as polystyrene resin is brought into contact with the air during extrusion in an extruder or extruded from a T-mold to vaporize the air. The vaporized polar group generated at this time is (C) The epoxy compound reacts. (C) The epoxy compound is grafted to a polyolefin resin, etc., and the unreacted fluorenyl group remaining in the molecule of the grafted epoxy compound is presumed to further improve the adhesion effect. In addition, by adding the above (D) functional group capable of reacting with epoxy groups-1 8-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------- --- Installation -------- Order --------- (Please read the phonetic on the back? Matters before filling out this page) 553991 A7 B7 V. Invention Description (α) (Please read first Note on the back side, please fill in this page). The reason is to improve the adhesiveness because of the functional group which can react with the ring gas group when extruding in the extruder or extruding from T mold. (C) The epoxy compounds react with each other and the amount of epoxy compounds grafted to the resin component increases. In the (M) polyolefin resin composition of the present invention, the above-mentioned (A) component is preferably contained in an amount of 99.9 to 50% by weight! And the (B) component is blended in an amount of from 0.1 to 5% by weight. The most preferred (A) component is 99.5 to 60% by weight (more preferably 99.0 to 70% by weight), and (B) the component is 0.5 to 40% by weight (more preferably U to 30% by weight) ). If the component (B) is too small and the component (A) is too much, there is no adhesive property; when the component (B) is too large and the component (A) is too small, the heat resistance during kneading and molding will decrease. (A) The (M1) polyolefin resin composition containing (A1) a polyolefin resin having a sulfonic number of 3 to 20 is also the same. (M2) Polyene resin composition (A) contains 99 · 8 ~ 50% by weight and (B) contains 0 · 1 ~ 50% by weight, and (C) contains 0 · 0 1 ~ 5% by weight It is advisable to cooperate. The addition amount of (, C) epoxy compound is from 0.00 to 1 part by weight to 100 parts by weight of (A) polyolefin resin, and preferably from 0.01 to printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 0.9 parts by weight. (C) When the added amount of fluorene compound is less than 0.001 parts by weight, the effect of improving the adhesive strength by the epoxy compound is small, and if it is more than 5 parts by weight, although the adhesive strength can be improved, the laminated body will be affected by adhesion. Unevenness causes cracks and odors. In addition, the polyolefin resin composition of the present invention preferably has a melt flow coefficient of 2.16 k g at a load of 0.001 to 1000 g / lOmin. The better is 0_1 to 100g / 10min, and the best is 1_0 to 50g / 10miii. Melt flow-1 9- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 Printed by A7 B7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs V. When the false number is too low or When it is too high, the formability is not good. Furthermore, if the melt flow coefficient is too high, the strength of the product is not good. The mixing method to obtain the composition can be performed by a general mixing operation, such as a tumble mixing method, a manual mixing method, a Banbury mixing method, or an extrusion granulation method. The polyolefin resin composition may contain an inorganic and / or organic filler in an amount of 100 parts by weight or less to 100 parts by weight of the polyolefin resin composition, and preferably 5 to 50 parts by weight. For the above-mentioned fillers, metal sulfonates such as calcium sulfonate, magnesium sulfonate, hydroxides, metal oxides such as titanium oxide, zinc oxide, inorganic fillers such as silicon dioxide, talc, and organic Agent. In addition, other resins, rubbers, pigments, dyes, antioxidants, ultraviolet absorbers, antistatic agents, smoothing agents, fatty acid metal salts, acid absorbers, and cross-linking can be blended without departing from the spirit of the present invention. Additives, foaming agents, neutralizers, dispersants, weatherability improvers, fillers and other additional ingredients. The polyolefin resin composition of the present invention can be used for various moldings, for example, it can be used for injection molding, hollow molding, extrusion molding, etc., and it can be extruded laminated molten film, film, test tube, tube, etc. Among them, by extrusion lamination, a laminated body having significantly improved adhesion to other layers can be formed. The ozone treatment of the formed body may be performed in a formed state under the molten or heated shape of the formed body, or it may be processed after forming. By applying ozone treatment, the adhesiveness, coatability, and printability can be significantly improved. -2 0-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ----: ------------------ Order ------ --- (Please read the precautions on the back before filling this page) 553991 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7_ V. Description of the invention (β) Polyolefin strip resin composition used in this ozone-treated molded body The (A) polyolefin resin is preferably (A 1) a polyolefin resin of 3 to 2 G, especially a polypropylene resin or a 4-methyl-1 -pentene resin. [Laminated body] The laminated body of the present invention, the first aspect 傺 is a polyolefin resin having a polyolefin resin containing (A1) the carbon number of 3 to 20 and (B) a compound having an unsaturated bond in the molecule. And the unsaturated bond in the molecule of the polyene strip resin composition is a layer formed by 0.5 or more (M 1) polyene strip resin composition in the molecule, and a laminated body with the substrate. . The second form is a polyene strip resin composition containing the above (A) polyene strip resin and (B) the compound having an unsaturated bond in the molecule and (C) an epoxy compound, and the polyene strip resin composition The number of unsaturated bonds in the f molecule in the compound is a laminated body of a layer formed by a layer composed of more than 0.5 (M2) polyene strip resin composition and a base material. The third aspect 傺 is an olefin having a compound containing the above (A) polyene strip resin and (B) an unsaturated bond in the molecule, (C) an epoxy compound, and (D) an epoxy group-containing functional group. Polyolefin strip resin composition of strip resin, and the number of unsaturated bonds in the molecule of the polyolefin strip resin composition is 103 layers with more than 0.5 (M3) polyolefin strip resin composition of the layer and the base Laminated body of wood. The substrate used here includes a film or a sheet (hereinafter referred to as a sheet). In addition, the substrate may be appropriately selected depending on the application, and paper, woven fabric, and non-woven fabric are also suitable. For example, paperboard, high-quality paper, coated paper, kraft-2 1-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ pack- ------- Order --------- (Please read the notes on the back before filling this page) 553991 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^, Thin leaf paper, inorganic fiber mixed paper, synthetic resin mixed paper, etc. Others can also be used as the base material of the laminate, such as polyamide 6, polyamide 6, 6, polyamide 6, 6, 6, polyamine Polyamines such as amines 12 > polyesters such as polyethylene terephthalate, polybutylene terephthalate, polyvinyl naphthalate (hereinafter referred to as PEN), etc .; ethylene vinyl acetate copolymer alkalizates, Thermoplastic resins such as branched low-density polyethylene, linear low-density polyethylene, medium and high-density polyethylene, propylene strip polymers, ethylene- (meth) acrylate copolymers, poly-esters, polyacrylonitrile, etc. Polychlorinated ethylidene, etc. In addition, metal foils such as aluminum, iron, copper, magnesium, tin, alloys based on these, etc. Metal plates; cellophane, etc. Among them, polyester and polyamide are preferred, and PET, PBT, and PEN are more preferred. In addition, depending on the application, steaming of aluminum, alumina, and silicic acid can be applied. Melt treatment, coating treatment of polyethylenyl chloride, etc. In addition, 1-axis or 2-axis extension may be applied. Moreover, printing processing may be applied to all or part of one or both sides. In addition, not only A multilayer body composed of two layers of a base material and a polyolefin resin composition layer may be provided with other layers as long as the effect of the present invention is not impaired. Specific examples of the multilayer body include a PP composition layer / paper. Layer, 4MP1 composition layer / paper layer, PE composition layer / paper layer / PP composition layer / paper layer, 4MP1 composition layer / paper layer / 4MP1 composition layer, PP composition layer / OPP layer, pp composition Layer / paper layer / PP composition layer / OPP layer, PP composition layer / 〇Ρί ^ / PP layer, PP composition layer / PA layer, PP composition layer / PA layer / PP composition layer, PP composition layer / ONY layer, PP composition layer / ONY layer / PP composition layer-22- This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) -----:- -------------— Order · -------- (Please read the phonetic on the back? Matters before filling out this page) 553991 Printed by A7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs B7____ 5. Description of the invention (W), PP composition layer / PEs layer, PP composition layer / PEs layer / PP composition layer, PP composition layer / OPEs layer, PP composition layer / OPEs layer / PP composition layer , PP composition layer / EV0H layer, PP composition layer / EV0H layer / PP composition layer, PP composition layer / paper cloth layer, PP composition layer / A1 foil layer, PP composition layer + HDPE layer / paper Layer / PP composition layer. (Among them, PP: polypropylene; 4MP1: 4-methyl-1-pentene strip resin, 0PP: biaxially stretched polypropylene; PA: polyamidamine; 0NY: biaxially stretched polyamidene; PEs: polyester; OPEs: biaxially stretched polyester; EV0H: ethylene-vinyl acetate copolymer compound; A1 foil. · Aluminum box; HDPE: high-density polyethylene) The method for manufacturing the laminated body of the present invention is On one side, the resin composition of the present invention described above is laminated and adhered by an extrusion lamination method, or the substrate and / or the resin composition film are surface-treated during adhesion, and then adhered through the treated surface. Even if the method is performed at a low temperature and high speed, a laminated body having a reduced adhesive strength can be obtained. For example, a substrate supply operation having ① a supply substrate, and ② a resin containing a polyene strip resin and an unsaturated bond in the molecule can be obtained. A compound, a polyoxyl compound having a functional group capable of reacting with a tritium group depending on the required oxygen compound, and the number of unsaturated bonds in the molecule is more than 0.5 polyenes in sulfonic acid. A method of laminating a resin surface treated with ozone treatment on a molten film formed of a resin composition, and a method of laminating the ③ molten film on an ozone-treated surface on at least one side of a supplied substrate . For example, in the base material supplying operation shown in FIG. 1, a base material 10 made of paper or the like is pulled out from the puncher 16 at a predetermined speed, and is supplied between the clamping stick 18 and the cooling stick 20. At the same time, the resin surface treatment operation is up to -23- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

553991

V. Description of the invention (>-) The resin composition of the polyolefin resin is extruded from the extruder 24 in a molten film state, and is supplied to the cooling 20 side between the clamp 锟 18 and the cooling rod 2G. At this time, the molten film 14 is subjected to an odor treatment. For packing # during extrusion lamination, usually a T-mold device can be used. Then, a lamination operation is performed, in which the substrate 10 and the molten film 14 are laminated by crimping between the pinch roller 18 and the cooling unit 20. At this time, the ozone-treated surface of the molten film 14 is brought into contact with the substrate 10. Then, the obtained laminated body composed of the base material 10 and the polymer resin composition layer 12 is rolled up into a product in a winder 22 as a winding operation. In the present invention, the low-temperature and high-speed forming means that the forming temperature is 3G (TC or less, the forming speed is 200 m / min or more, especially the forming temperature is 200 to 300 ° C. The present invention is in the range of 230 to 270.0, In low-temperature and high-speed molding at a molding speed of 200m / min or more, it can exhibit a significant effect that the adhesive strength will not be reduced. The above surface treatments can be general surface treatments such as corona treatment, ozone treatment, and flame treatment. The better It is ozone treatment. In addition, by laminating and adhering a polyolefin resin composition film to which ozone treatment has been applied and a substrate to which electro-discharge treatment has been applied, the surface treatment is used for lamination and adhesion, and a better effect may be obtained. The molten resin film taken out from the T-mold was blown with odor from the odor supplier on the surface of the adhesive side of the substrate. The ozone treatment amount was 5 to 100 g / hr, preferably 100 to 500 g. / hr. Means of improving interlayer strength 傺 When using conventional knowledge, in the present invention, the unsaturated bond and ozone in the polyolefin resin composition are used to reverse-2 4-This paper size applies Chinese national standards (CNS) A4 Specifications (210 X 297 mm) (Please read the note on the back, and then fill out this page) Order ----- λ. Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7_ V. Description of the invention (—) (Please read the precautions on the back before filling in this page). However, the effect of modification by ozone treatment is great, and the multiplication effect of the polyolefin resin composition of the present invention and ozone treatment can greatly improve the previous Unexplained adhesion strength with other layers. By applying this ozone treatment, the resin temperature during extrusion molding is 200 to 300 ° C, preferably a low temperature of 240 to 28 ° C It can be laminated without reducing the adhesive strength. In addition, the substrate can also be subjected to surface treatments such as thermal treatment, corona treatment, flame treatment, UV treatment, etc., but the application of electro-coated treatment It is demanded that the interlayer adhesion strength between the base material treated with the electric treatment and the resin composition layer applied with the ozone treatment is extremely high. The corona treatment is performed using an electric discharger, preferably 1 ~ 3Q0wmin / m2. , More preferably 10 ~ 100w min / m 2 〇 The present invention uses a high level The laminated body of low strength is laminated at low temperature, and can be manufactured at a high-speed forming surface of 20G ~ 400m / fflin. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Extruding and laminating a layer of polyolefin resin composition on at least one side of the substrate (for example, using two or more polyolefin resin compositions or the substrate side as the polyolefin resin composition), and using other resins on the outside, It is also effective to squeeze and laminate two or more layers on one side of the substrate, and to squeeze and laminate a polyolefin resin composition on both sides of the substrate. In addition, in the present invention, it is not necessary to have a space between the substrate and the polyolefin strip resin composition layer. Adhesives or tackifiers, but these can also be used. The device used for extrusion and lamination can use the device of the usual T-molding method. 2 5-This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of invention 7) Jibei Jiate 4-you annihilation degree by the thick and specific, the outer layer of the layer is optional when the cocoa thing into a group of palm tree pentamyl sticky surface layer pressure adjustment Squeeze the body and layer, build the surface of its smoothness and humidity, borrow the surface, make the body layer when the system is made, and the temperature of the layer of the product is 逑-上 基 4- 由 甲 使 有 4 as the example Only the outer layer and the bottom layer are used to form a base, and the formazan layer is formed into a group of 4-groups and a group of fatty groups is formed into a group of fatty compounds. 1-penta-1x-a

Aliphatic resin I 1X melts into the composition of the material as a group of organiza- tions of the tree structure of the pentene surface 1-epi-lipochemical treatment of oxygen odor, the application of 0 ^ extruded co-methyl I 4 from this and The mulching film is easy to melt and melt, and the method of upper layer, back pressure, and upper extrusion surface, which is the same as that of the 4-basis surface, should be handled by the supply and supply of oxygen and odor. It is necessary to provide a thin film of the selenium resin pentyl I 1X I base layer to the method of lamination and cure the three layers of the Ming San \ \ Press to give the side stick 0, but you must cold give I and, base Lossy forma will be hot 4- intolerant. It is composed of layers that are excellent in diaplasma and transdifferentiation when there is, and has sexual properties. Some of them have a good structure. They are made of alkenyl 1-pentyl. The low-quality products of A are resistant to S and are breathable (please read the note on the back? Matters before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The degree of strength is higher and more viscous, and the layer can be used for reason. The speed of borrowing is based on Wen Qiji's shovel-layer 4 * / product of the structure of the base \ layer of the I into -1 of the base of the group into 4 groups by the borrowing tree is the formation of the pentene layer The high energy resistance and long-term heat resistance of the laminated streak ene body \ High heat resistance% Highly strong adhesion of the interstitial layer of DEK. This paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 Α7 Β7 5. Description of the invention (<) The peeling substrate is used in various labels, adhesive sheets, adhesive fascias, synthetic resin films, and insert-forming films. (Please read the notes on the back before filling this page.) The above polyolefin resin composition of the present invention is suitable for use in the release substrate. The release substrate of the present invention is a layered material having a release material layer formed on the base material through a resin layer, or a resin layer is formed on the base material so that the resin layer is exposed on the surface, and the release material has a layer as a release material layer. Functional layer builders. First, a release substrate having a layer structure in which a release material layer is formed on a base material through a resin layer will be described. For example, the release substrate 10 shown in FIG. 2 is formed by laminating a release material layer 16 on a base material 12 via a resin layer 14. The base material is appropriately selected depending on the application, and is not particularly limited. Generally, synthetic resin, paper, woven fabric, and non-woven fabric can be used. Paper examples include high-quality paper, kraft paper, cellophane, inorganic fiber mixed paper, and synthetic resin mixed paper. The consumer goods cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs can print printed materials using conventional materials, such as silicon dioxide (addition reaction type, condensation reaction type), silicon dioxide, alkylate copolymers, or the like. Mixtures of olefin resins, etc. In addition to the heat-hard type, a radiation-hardenable peelable material can be used, for example, as described in Japanese Patent Laid-Open Publication (A) No. Hei 3-79685. The resin layer is a polyene strip resin composition containing the aforementioned (A) polyene strip resin and (B) a compound having an unsaturated bond in the molecule. The number of unsaturated bonds in the molecule of the polyene strip resin composition is More than 0.5 of 〇 107 -27- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 Α7 --------____ V. Description of the invention (4) H) Polybright bar resin composition, or (M2) a polyene bar resin composition containing (c) an epoxy compound, or (D) an alkenyl resin containing a functional group capable of reacting with a hafnium group (M 3) a layer formed of a polyolefin resin composition. U) Polyolefin resins with a component of (A1) having a carbon number of 3 to 20 are preferred. In the case of the polyolefin resin composition, it was found that the adhesive strength with a base material or a release material layer of a dissimilar material was high, and the adhesive strength was low even when the accumulation temperature was low. In addition, even if the lamination molding speed is increased, a high adhesive strength can be maintained. When the resin layer is composed of a polypropylene strip resin composition, it is a release substrate or a release laminate having high heat resistance. In addition, it is explained that the above-mentioned peeling substrate is a laminated body composed of three layers of a base material, a resin layer, and a peeling material layer, but the present invention is not limited by these, and is within a range that does not impair the effects of the present invention. Other layers can be set. For example, on the side where the resin layer is not formed, any other layer is provided, and on both sides of the base material, a resin layer and a release material layer are formed in five layers, and both surfaces are release substrates formed by the release material layer. , And the resin layer is composed of several layers. In addition, the layer thickness of each layer such as the resin layer, the base layer material, and the release material layer is not particularly limited, and is appropriately set within a range in which the functions of the layers are achieved. The peeling substrate may be a lamination method that can improve the adhesive strength between the layers. In particular, the production method thereof is not particularly limited. As in the above-mentioned lamination method, lamination is performed by extrusion lamination, and a manufacturing method is suitable. -28- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page) -------- Order i -— ^ — ^^ 90 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7_ V. Description of the Invention (W) In other words, the operation is based on the supply of a base material having ① supplied to the base material, ② in the Compounds with unsaturated bonds, and the number of unsaturated bonds in the molecule is 10,3, and the resin film is treated by ozone treatment on a molten film made of a polyolefin resin composition having 0.5% or more in sulfonic acid. The laminating operation of pressing the ozone-treated surface of at least one side of the supplied base layer material on the above-mentioned fused layer, and the operation method of providing a release material layer on the resin layer of the obtained laminated body is preferred. In other words, the base material supply operation forges a base material made of paper or the like between the clamp rod and the cooling bar. Meanwhile, the resin surface treatment operation is to extrude the above polyolefin resin composition as a molten film, and apply ozone treatment to the molten film. Then, the lamination operation bar presses the base material and the molten film between the clamping stick and the cooling stick to be laminated. At this time, the ozone-treated surface of the molten film was brought into contact with the base material to obtain a laminated body composed of the base material and the resin layer. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this page) In addition, a release material layer 16 is formed on the resin layer 14 of the laminate, such as coating with silicon dioxide , And be heated and hardened. Further, the above-mentioned polyolefin resin composition forming the resin layer 14 and the resin forming the release material layer 16 are co-extruded by a co-extrusion lamination method, and simultaneously molded. In addition, a film made of the resin of the release material layer 16 is supplied between the resin layer and the cooling rod, and the release material layer is simultaneously formed by a sandwich lamination method of compression bonding and lamination. In addition, the surface wettability of the resin layer can be controlled by adjusting the lamination temperature during the extrusion lamination operation of the resin layer. Therefore, when forming the release material layer, the surface wettability of the resin layer can be adjusted as needed. -2 9-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 5. Description of the invention (") The peeling substrate is shown in Figure 2 by using the peeling material; ai The peeled body 20 is formed on 6 to form a peeled laminated body 2 4. The peeled body 2 Q fakes the peeled base material 2 made of paper or PE τ film, etc., and the peeled substrate is in the peeled material layer. 1 6 is formed by a peelable adhesive layer 18. The peeled material layer 2 2 can be used for printing and other purposes. The adhesive layer 1 8 can be used as a base material 2 2 to be peeled off. Those with a high adhesive strength and having a low adhesive strength with the release material layer 16 are suitably used for screwing. Next, the function of the base material and the resin layer and the resin layer as a release material layer will be described. The peeling substrate. For example, the peeling substrate 10 shown in FIG. 3 is formed by laminating the resin layer 14 on the base material 12. The base material can be appropriately selected according to its application, and there is no other limitation. The base material is the same. However, the following (A) containing a polyolefin tree The fluorene formed from a polyene strip resin composition having a compound having an unsaturated bond in the (B) molecule can control its adhesion and is found to be non-adhesive. Therefore, the resin layer itself in the peeling substrate in this example has In other words, the layer formed of the polyolefin strip resin composition has high adhesion strength on one side and the base material of a different material, and even if the lamination temperature is lowered, it still has high adhesion strength, and the other side is accelerated. The lamination molding speed can still maintain high adhesive strength and exhibit peelability. In this form, the component U) is a highly crystalline resin such as (A1) polyene resin or 4-methyl-pentene resin. , Its peelability and heat resistance are high -3 0 _ This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the Jiang Yi matters on the back before filling in this package. ------ --- Light "---- I--. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7_ 5. The description of invention (W) is therefore what you want. (Please read the precautions on the back before filling this page ) In addition, the above-mentioned peeling substrate is described as a base material The laminated body formed by the two layers of the resin layer, but the present invention is not limited by these, and other layers can be provided within the range that does not impair the effect of the present invention. For example, on both sides of the base material Each layer is provided with a resin layer to form a three-layer structure, and the two surfaces are a peeling base of the resin layer, etc., and the resin layer is composed of several layers. In addition, the thickness of each layer such as the base material and the resin layer is not particularly limited. The range of functions can be appropriately set. The peeling substrate is prepared by the same method as the above-mentioned peeling substrate. Then, the surface of the resin layer on which the ozone treatment is not applied can be controlled by lowering the temperature of the laminate and controlling the resin layer as much as possible. The surface is oxidized and can exert its non-adhesiveness as a release material layer. The molding temperature is controlled to 230 to 27 (TC), which can exert sufficient mold release property as a release substrate for an adhesive. A specific resin layer which can be laminated at low temperature in the release substrate, one side is It has high adhesion and low adhesion on the other side, so it not only has extremely high adhesion to the substrate, but also has a sufficient function as a release material layer. Therefore, since no silicon dioxide or The coating operation can reduce the number of layers of the stripped substrate and reduce the number of manufacturing operations. The employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the stripped substrate. For example, as shown in FIG. 3, the stripped substrate is formed on the resin layer 14 to be stripped. The peelable laminated body 2 4 is formed by the body 2 Q. The peeled body 2 G has a peeled base material 2 2 made of paper, PET film, or the like, and the peeled base material 2 2 is on the resin layer 14. Peelable, adhesive adhesive layer 18. The peeled substrate 2 2 can be used for printing, etc. depending on its purpose. -31- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) 553991 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, A7 B7 V. Description of the invention (V) The adhesive layer 18 傺 can be appropriately selected to exhibit high adhesive strength with the substrate 2 to be peeled, and low adhesive strength with the resin layer 14. Since there is no need for the peeling substrate, Sealing layer or silicon dioxide, etc., can reduce the number of layers and can be easily manufactured at low cost. [Operation sheet] Binding or wall decoration of shoes, boots, belts, notepads, etc., are widely used in Various woven fabrics are made of multi-layer sheets of skin material made of resin such as polyvinyl chloride or urethane. These cymbals are used to give a three-dimensional idea to the surface by making the surface uneven, especially using For shoes or boots, etc., it is used as the natural leather of synthetic leather. It is given a embossed pseudo-embossed plate or embossed with an embossed pattern on the surface and copied, except for those that must limit the production volume. For small-batch production, embossing can be carried out by using an operation sheet with an embossed surface on the surface. The above-mentioned operation panel of the present invention is conventionally formed by forming an operation layer on a substrate or by forming a substrate on the substrate. Form a surface via an adhesive layer The person who constitutes the surface layer. First, the operation panel for forming the layer of the operation layer on the substrate will be described. The operation sheet, such as the operation panel 14 shown in FIG. 4, has at least a substrate-13 and an operation. Layer 15. The substrate is appropriately selected depending on the application, and is not particularly limited. Generally, paper, woven fabric, and non-woven fabric can be used. Examples of the paper include high-quality paper, kraft paper, cellophane, inorganic fiber mixed paper, and synthetic resin mixed paper. Etc. The operation layer 傺 contains the above-mentioned (A) polyolefin resin and (B) with intramolecular -3 2-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----- ---------------- Order i— ^. (Please read the precautions on the back before filling out this page) 553991 A7 _B7 V. Description of the invention (N) Unsaturated compounds Polyolefin strip resin composition, the number of unsaturated bonds in the molecule of the polyolefin strip resin composition is more than 0.5 (M) polyolefin strip resin composition in 103 carbons, or (C) 璟(M2) polyene strip resin composition of oxygen compound, or another (D) olefin having functional group capable of reacting with epoxy group A layer made of a resin (M 3) polyolefin resin composition. The (A) component of the polyolefin strip resin is preferably a polyolefin strip resin having a (A 1) sulphur number of 3 to 20. Especially polypropylene resin. The (A 1) component is preferably 4-methyl-1-pentenefluorene resin. In addition, it is explained that the above-mentioned operation sheet is a laminated body composed of two layers of a base material and an operation layer, but it is not limited to these. As long as the effect of the present invention is not impaired, other operations may be provided. Floor. For example, if any other layer is provided on the side of the base material on which the operation layer is not formed, the operation layer may be composed of several layers. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------------- 1 ^ i .— ^ — ^^ 9, ( Please read the note on the back? Matters and then fill out this page), the legal layer should be filled with the product. The top and branch trees are made with sterol. The strip is made with strong profit, but the mask is not. It can be used to make objects thick, thick, and sticky. The layer of fat-melting layer should be used to build the upper layer. The upper layer of the layer should be based on the material of the upper layer. The individual layers and 5 high-grade inner high-grade special materials are filled with 0. The air surface material is surrounded by a pressure base that is not odorous and can not be squeezed. There should be a small amount or the method is to apply the inner sulfon to the layer energy. To make use of ① the work on the sub 3 is only based on a 10-layer film to operate the laminate with its C tool and the melt as the basis, each piece is especially made of fat melt, the system can be operated as a tree Available examples of keys are provided for immediate delivery. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7 V. Description of the Invention (^) The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is printed as a board with tightness but tight esters and M sticks. Noodle temperature. The leather sheet is cold-clamped, cold-capped, cold-crusted, and cold-crusted. It is used as a superficial layer of leather and mixed with acid and M. The leather is made of leather, 22 guides, 22U, and 10 leather. The foundation 锟 ttBI12 is made of materials, and the flowers are made tightly during the lamination process. The fabric is tightly closed and the fabric is closed. The surface clamp is the same as that used to make the clamp B10. Μ \ The sum of the 10U1010 pressure guiding machine in the whole example of the silicon layer formed by Duoduo. The shape of the material is adjusted, and the 20 extruded materials are shown to be suitable layers, so that the oxygen pressure can be 锟 18 extruded leather U leather skin 14 is used for the second extrusion and the application of the MC table Figure 1 The plate method is applied, plus 4i ° c and 4 derived from the equivalent. The film side can be made by the layered flower surface, the modal board 5014, and the 11th base. The moisturizing gauge made by the pressure. The plastic H-2 board is covered with leather and is operated from time to time, its operation is wet, squeeze the room T to melt it, the sheet is pressed to the skin 12, and the board is combined with the whole board, so that the pressure 12 is melted and operated 10 times. Finished material, layer-by-layer surface adjustment. First squeeze the cloth for 24 to prepare for operation. Combine the skin and take the product to make the pressure table. It is made of printed material, 21 base sticks, etc. Reinstate it. Lend a rehearsal stick. Since it is from C, this roller is hard to connect from top to bottom, and it is better to make the layer pressed, cold, and ρν shaped, but it is compared with 19 pressure, etc. And after it is finished, it can be cold-rolled into another roll on the back surface, so that 5 from 24 to 22 and grease 24 can be pressed or processed according to the successor's succession. The 14th roll is squeezed 22 to 12 rolls. ---------.—-------- Order i— ^ (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (^) Take out the stick 19 in different ways; This operation plate 14 can be used several times. In this way, multiple layers of synthetic leather can be manufactured continuously. In addition, after a urethane resin or PVC is coated on a flat and wide operation sheet, and the resin sheet is heated and hardened to form a resin film, the resin film can be peeled off from the operation sheet, and it can still be formed on the surface. Synthetic leather made of embossed resin film. In the production of synthetic leather, a method of using embossed pressing plates or sticks on the surface is required. These end of life, or when changing the embossing, large pressing plates or rollers must be exchanged. This requires not only a lot of labor, but also the cost. Will improve. Therefore, the resin must be dried and stabilized after embossing and extrusion, and it takes a long time in manufacturing. However, when using an operation sheet such as the method shown in FIG. 5 above, various embossing processes can be performed by simply replacing the operation sheet, and since the resin is instantly cooled and hardened, it can be easily and in a short time. Made of many layers of synthetic leather at a low price. The thickness of each layer of the multi-layer synthetic leather thus prepared varies depending on its application, and therefore does not need to be treated equally. However, since the thickness of the skin material is embossed, a thickness of at least 40 # m is preferable. In addition, the maximum thickness is 5 () ϋ # ηι in terms of formability. In addition, the thickness of the base cloth is 10 > uni ~ 500 # ιπ. In addition, depending on the application, in addition to the base cloth and the skin material, a protective layer or the like may be provided, and a laminate of three or more layers may be provided. In addition, since the operation layer is made of a polypropylene strip resin composition, it is an operation sheet having high heat resistance. -35- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -i 丨!丨 丨 丨 Order i --- MW, 553991 A7 _____ Β7_V. Description of the Invention (W) When the operation layer of the upper part is a layer made of 4-methyl-1-pentene strip resin composition, It consists of several layers which have the layer which consists only of a 4-methyl-1-pentene strip resin, for example, using the 4-methyl-1-pentene strip resin composition and 4-methyl-1-pentene The olefin strip resin is co-extruded, and the ozone-treated resin surface treatment operation is performed on the molten film formed from the 4-methyl-1-pentene strip resin composition, and pressing is performed on at least one side of the supplied substrate The co-extruded side of the lamination operation with the ozone-treated surface connected to the molten film can be produced by using 0 rolls to give and Ϊ Ϊ 1Ϊ to capture i-ene and-layer ζ film-pentaene. Huaji · Thin Ϊ 1 build 5 rule-manufacturing M Ming base M three, A Yi ip 4- capacity ifl 谞 ，, the method of the layer method J ® # J product operation method T, the layer is connected to the external product Press this pressure 4- to make the predestined things into a group Θ Tree 糸 基 甲 I 4 from the \ layer of the handle is a high-performance T heat-resistant nail-resistant for 4 reasons, especially when In particular, the tree is pentene, and the high plate can be long-lasting and resistant to high-structure materials. It is a layer of heat-resistant material, which is as strong as the word. S3? 4 ^ 9 tree The stripe layer of pentylene 1- on the surface of the layer has a forming layer adhered by the upper material base in the Guanming board said, as a second operation of the 15th layer of the graph of the CO table and as the 16th layer For example, the sticky board and 3 pieces of 1 material should be used. There should be less than 0 pieces of the board, and the 4 pieces of 1 plate should be layered (please read the precautions on the back before filling this page)- ----- ^ 丨 丨 Order i · — ^ — ^ 9. The producers of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs made the special and optional places that can be restricted applicable. It can be used as a base material, and the material containing the base is like a sheet ply. The sticking operation is described later, and then it is polymerized with the resin of the resin, and the polymer is divided into 5 groups. The fat is a number of olefinic polyunsaturated polysaccharides, and the neutralized product is less than the internalized neutrons. The neutralized product is saturated with non-lipid internal slivers. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). ) 553991 A7 B7 I--— ^ ΙΜ_ __ 5. Description of the invention (π) More than (M) polyene strip resin composition, or (M2) polyene fluorene resin composition containing (C) epoxy compound Or a layer formed by (M 3) a polyisocyanate resin composition containing (D) an olefin resin having a functional group capable of reacting with an epoxy group. (A) Polyolefin strip resin with component U 1) Polyolefin strip resin having 3 to 20 carbon atoms is preferred. For the polyene strip resin composition, $ 1, _ stomach S ^ $ has high strength, even if the product has low crystallinity, it still has high adhesive strength, and even if the layer forming speed becomes faster High sticky #strength. The surface layer looks like a mono- or copolymer of α- 纟 Greek hydrocarbons with a carbon number of 3 to 20 (or a composition of these with other polyolefins. Among them, 4-methyl-papene strip resin Or a composition thereof is preferred. Examples of the composition include a mixture of polyethylene strip resin, polypropylene strip resin, 4-methyl-1 -pentene strip resin, and the like. Among them are heat resistance and peeling. In terms of properties or adhesive strength with the adhesive layer, etc., a mixture of polypropylene stripe resin and 4-methyl-1-pentene stripe resin is used in terms of performance and price, etc. 4-methyl-1-pentene stripe resin such as It is 4-methyl-pentene alone, or a copolymer of the same with one or more other α-olefins having 2 to 16 carbon atoms, etc. Furthermore, the 4-methyl-pentene strip resin The melt flow rate of the component with a load of 5.0 kg (2 60 ° C) is preferably 20 to 5 QQ g / 10 mm, and more preferably 50 to 30 Gg / 10 min. If the melt flow rate When it is too low or too high, the formability is not good. The preferred polyolefin for this surface layer, specifically, propylene monopolymer can be used. -37- This paper size applies to China National Standard (CNS) A4 (210 X 2 97 mm) (Please read the phonetic on the back? Matters before filling out this page) --------- 1T ------_—— Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 553991

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (from) (homopolypropylene), block copolymer, random copolymer, or a combination of two or more of these. Block copolymers or random copolymers can be used as ethoxylates, butene-1, pentene-1, hexanox-1, etc., other than propylene. Too good. The propylene content of these copolymers is preferably ~ mole%, more preferably 80 ~ 99mole%. Ethylene is used as a block copolymer of Jiang-Yanyan, and the Ethylene-propylene block in the molecule is dispersed in the homopolypropylene block to exhibit rubber elasticity and function as a rubber ingredient. The content of the rubber component is preferably 10 to 25% by weight of the block copolymer. For the compound of polypropylene, the melt flow image (23G ° C) with a load of 2.16 k g is preferably 10 to 100 g / 1 () min, and more preferably 20 to 80 g / 10 min. When the number of melt flow # is too low or too high, the formability is not good. The surface layer of the present invention may be a separate 4-methyl-pentene resin, but in order to improve the adhesion strength with the adhesive layer, it is preferably formed as a composition layer with polyolefin, especially to maintain the surface layer In terms of heat resistance, peelability, and adhesion strength of the adhesive layer, a 4-methyl-prenene strip resin composition of a polypropylene mixture is preferred. The 4-methyl-1-pentene fluorene resin composition 宜 is preferably blended with 2 to 50% by weight of the aforementioned 4-methyl-pentene fluorene resin component and 98 to 50% by weight of a polyolefin component. Preferably, 傺 is 10 to 20% by weight of a 4-methyl-papene strip resin component and 90 to 80% by weight of a polyolefin component. In terms of peelability or heat resistance, it is better to use 4-methyl-pentene strip resin, but the 4-methyl-1-pentene strip resin is generally expensive, considering economy and maintaining and adhering. Layer of -38- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ----: -----—-------- Order i —.— (Please Read the phonetic on the back? Matters and then fill out this page) 553991 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention (M) Adhesive strength should be within the above range. In addition, in the entire 4-methyl-pentene strip resin composition of the present invention, the melt flow rate (2.30 kg) of a load of 2.16 kg is preferably from 0.1 to 10 GOg / lOmin. The preferred value is 〇 · ι ~ i0Qg / i0min, and the more preferred value is ι · 0 ~ 50g / l (min). If the melt flow rate is too low or too high, the formability is not good. Moreover, the melting point of the 4-methyl-1-pentene strip resin composition is preferably 220 to 250 ° C, and more preferably 230 to 240 ° C. In order to obtain the composition, the mixing method can be carried out by a usual mixing operation, such as a tumble kneader, a manual kneader, a Banbury kneader, or an extrusion granulation method. When the composition is obtained, neutralizers, dispersants, anti-chlorination agents, smoothing materials, weatherability improvers, antistatic agents, pigments, fillers, etc. can be blended within a range that does not hinder the effects of the present invention. Other additional ingredients. In the case of a surface layer made of the 4-methyl-pentene strip resin composition, the heat resistance is extremely high, and once the embossing residual property is excellent, the surface peelability is extremely excellent. The plate is extremely excellent. In addition, it is explained that the above-mentioned operation sheet is a laminated body composed of three layers of a base material, an adhesive layer, and a surface layer, but the present invention is not limited by these, as long as it does not impair the effect of the present invention You can set other layers. For example, an arbitrary layer is provided on the side of the base material on which the adhesive layer is not formed, and the adhesive layer is composed of several layers. The thickness of each layer such as an adhesive layer or a substrate is not particularly limited, and is appropriately set within a range where the functions of each layer can be achieved. -39- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 丨: --------- — -------- Order ---- ^- -(Please read the Zhuyin on the back? Matters before filling out this page) 553991 A7 B7

V. Description of the invention (W-method method The layer-by-layer backlog of the squeezed layer is used to make it sticky. There is no way to make each layer of the limit layer. The board is a piece of film. It should be operated. That is to quickly determine the 3 1X material base, etc. 0 paper should be used to make the diagrams of the law-making party 7th, such as the layer, the product is as an example, the surface of the surface is 32. Each spoonful of AHH 34-shaped nozzle-shaped film sprays grease to the tree to melt and melt. The pressure of the 40 sticking machine is to make the extrusion, so that the self-time degree is the same as that of the stick base. Parallel pressure, squeezing the side 2 to 3 of the cold-shaped interlayer film of the stick tree 32 οϋ The tree stick melts and melts the layer 34 5 I 1 and 6 layer 1 The surface layer is sticky and sticky. 6 1 and Upper S5 3 2 Layer 1 4 Loader Adhesive base for layer picking 13 rolls of coiled material on the top of the convoluted board will be used to make the board base, the sheet will be made later, and then respond. The donor is formed by the layer to accumulate 15 lands The surface material made of layer 13 is the same as the table. When the temperature is 1 degree, the fat tree will form 30. When pressed, it will be ° c (please read the precautions on the back first). Please fill in this page again.) In Mingfa this ° c The film is thin, the layer of accumulated fat, the pressure of the tree connection 5 i 1 is layered to the surface, and the table is used to make it. Leng Yi and Fa Ke also layer by layer, stick to the rule and should be provided in the Ming and the three offerings, the flowers are pressed to make a predetermined surface of the upper layer, so that when necessary, a board need to be printed at regular time. The pressure plate and other squeezed pieces of flowers are used as a stick to make a stick, or for external use. This system is printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to print the silicide oxygen strips in the mold, so that it can be viewed from the perspective. The surface of the table is better. The surface of the base is a T-based base. The base is a S-4 base plate. When the layer is coated, the surface is polymerized and the surface is $ 0 ^ ^. Alkyd resins, pressed trees, and extruded tallows are derived from pentylene and pentylcobene, 1-same, and 1-same-tempered crystallized. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 Α7 Β7 V. Description of the invention (M) (Please read the note on the back first Please fill in this page again) 4 -methyl-pentene strip resin with low segregation viscosity on the surface. As a result, in the obtained surface layer, the proportion of 4-methyl-1 -pentene strip resin on the surface is large, Only a small amount of 4-methyl-1 -pentenefluorene resin is blended, and the high peelability and heat resistance of the 4-methyl-1 -pentene bar resin can be efficiently exhibited in the surface layer. In addition, by adjusting the lamination temperature of the surface layer during the extrusion lamination operation, the wettability of the copy surface can be controlled and the surface peelability can be adjusted. In addition, since 4-methyl-1 -pentene strip resin is used in a small amount, high efficiency can be exhibited, so the cost increase is only slight. [Packaging material] The polyolefin resin composition of the present invention described above can be used as a packaging material made of the laminated body. In other words, the packaging material 傺 of the present invention has at least a layer and a substrate made of the specific polyolefin resin composition described above. Each example will be described below. Packaging material example 1 is conventionally made of a laminate having at least a substrate, a resin layer, and a sealing layer, such as the laminate shown in FIG. 8. The sealing layer 16 is laminated on the substrate 12 through the resin layer 14. Of the composition. The substrate printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is appropriately selected as the substrate of the packaging material according to its use, especially those made of gas barrier materials, such as polyester, polyamide, vinyl, etc. Ethylene glycol (EV 〇 Η), polyethylene glycol, acrylonitrile, ethylidene chloride, polyfluorinated ethylidene, and the like, printed matter, aluminum, metal or metal vapor vaporization Films, etc., or multi-layered structures made of these-41- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 Α7 Β7 V. Description of the invention (#). (Please read the precautions on the back before filling in this page.) Sealing layer: Use conventional materials, such as low-pressure polyethylene with high-pressure radical method, linear low-density polyethylene, etc., especially low-pressure with high-pressure radical method. Polyethylene, Ziegler strips, or aramidene metal derivative strip linear low density polyethylene are preferred. The resin layer 傺 is a polyolefin resin composition containing the above (A) polyolefin resin and (B) a compound having an unsaturated bond in the molecule, and the number of unsaturated bonds in the molecule in the polyolefin resin composition is 1 0 3 carbon has more than 0.5 (M) polyene strip resin composition, and (C) epoxy compound (M 2) polyene strip resin composition, also contains CD) can be used with epoxy (M 3) polyene fluorene resin composition which is a functional group of olefinic resin which reacts with a base. In the case of the polyolefin resin composition, the adhesive strength with a base material or a sealing layer of different materials is high, and the adhesive strength is high even if the lamination temperature is low. In addition, even if the lamination molding speed becomes faster, a high sticking strength can be maintained. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In addition, it is explained that the above-mentioned laminated body is a laminated body composed of three layers of a substrate, a resin layer and a sealing layer, but the present invention is not limited by these, Within the scope of the effect of the present invention, other layers may be provided. For example, other arbitrary layers are provided on the side of the base material on which the resin layer is not formed, and five layers of a resin layer and a sealing layer are provided on both sides of the base material, and the resin layer is composed of several layers. In addition, the substrate may be a multilayer structure such as paper or plastic layer, and a resin layer may be provided on one or both sides thereof, and a sealing layer may also be provided. In addition, the layer thickness of the resin layer, substrate, sealing layer and other layers is not special -42- This paper size is subject to the restrictions of China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention) Appropriately set within the range that can reach the functions of each layer. (Please read the note on the back? Matters before filling out this page) The packaging material can be a lamination method with high adhesive strength between layers, especially the manufacturing method is not particularly limited, but it is laminated by extrusion lamination method The manufacturing method is suitable. For the base material, a sandwich lamination method in which the resin layer and the sealing layer are co-extruded and laminated, and the resin layer is sandwiched therebetween is suitable. For example, the base material shown in FIG. 9 is supplied. The operation is such that the base material 12 made of an aluminum foil, a polyamide film, or the like is extruded from the extruder 40 at a predetermined speed, and is supplied between the nozzle roll 34 and the cooling roll 32. At the same time, a sealing layer 16 made of a low-density polyethylene film or the like is supplied in the same way from the sand extruder 14. In addition, the resin surface treatment operation makes the polyolefin strip resin composition made of the resin layer described above into a molten film state. The extruder 30 is supplied between the base material 12 and the sealing layer 16, and at this time, the molten film is subjected to an odor treatment. The device used for extrusion lamination is usually a T-mold device. Then, a lamination operation is performed to press-contact the base material 12 with the resin layer 14 and the sealing layer 16 between the nozzle stick 34 and the cooling stick 32 to form a laminated body. The obtained laminated body composed of the base material 12, the resin layer 14 and the sealing layer 16 is wound on a winder 42 as a winding operation. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The resin temperature during extrusion molding is generally 280 ~ 35Q ° C, but it can be less than 300 ° C. In addition, the wettability of the surface of the resin layer can be controlled by adjusting the lamination temperature during the extrusion lamination operation of the resin layer. Therefore, when forming the sealing layer, the wettability of the surface of the resin layer can be adjusted as needed. Packaging of various products using this packaging material, pseudo-heat-sealing, etc. -43- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. & Description of Invention The bonding technology may be bag-shaped, etc., and the packaging means is not particularly limited. (Please read the precautions on the back before filling this page) The packaging material is general packaging materials for industrial, industrial, and household products, such as auto parts with tires, packaging for household products, steel wire reeds, air bubbles Packaging materials for tablets, packaging materials such as paper and light materials, liquid synthetic lotions, surfactants, shampoos, moisturizers, liquid fertilizers, imaging liquids, coatings, various drugs, various oils, and various solids and liquids Packaging materials for gas bags. In particular, it is not suitable for packaging lightweight materials such as pharmaceuticals. In addition, it can also be used as food and medical packaging materials, suitable for dry food or aquatic food, such as water, dairy products, fruit juice, wine, coffee, tea, soy sauce, vinegar, tofu, etc. Packaging materials for medical products, medical packaging materials for pharmaceuticals, etc. The present invention can further improve the productivity by increasing the forming speed, and because it can be formed at a low temperature, it can control the influence of smoke on the working environment and its surroundings, and it is almost completely free of odor. The packaging material example 2 is one having at least a resin substrate, a resin layer, and a gas barrier layer. For example, another layer may be provided as shown in (10). This packaging material is particularly suitable for food and medical packaging materials. Examples of food and medical packaging materials printed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs ’consumer cooperatives are assumed to be laminated with a resin base material 16 on one side of the gas barrier layer 10 through a resin layer 12 and gas barrier properties The other side of the layer 10 is laminated with a sealant layer 18 via a resin layer 14. Resin base material 16 is used as the base material of food and medical packaging materials, such as polyamide, polyethylene, polypropylene, poly-p-phenylene-44- This paper applies Chinese national standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (0) Polyesters such as vinyl formate (PET). The resin layers 1 2 and 1 4 ′ are made of the above-mentioned polyolefin resin composition (M), (M 1), (M 2), (M 3). The gas barrier layer 10 is appropriately selected depending on the application, and is not limited. Examples include polyester, polyamine, vinyl ethylene glycol (E V 0 Η), polyethylene glycol, acrylonitrile, and ethylidene chloride. , Polyfluorinated ethylidene, aluminum, metal or metal oxide film and the like. Among them, polyester, polyamide, EV0H, and aluminum foil are preferred. As the sealing layer 18, various conventional ones can be used. The sealing layer 18 is appropriately selected depending on the application of food, medical packaging materials, and the like, and is preferably made of various resins. Examples include low-density polyethylene, high-density polyethylene, linear low-density polyethylene, polypropylene, and other polyolefins, and polyesters such as PET and polyamide. For food and beverage applications, especially low-density polyethylene or linear low-density polyethylene without additives, high-pressure free-radical low-density polyethylene, Ziegler bars, or aromatic metal derivatives Low density polyethylene is preferred. By forming the sealing layer 18, the odor generated by the packaging material can be reduced. In addition, the above-mentioned laminated body for food and medical packaging materials will be described as a laminated body composed of five layers of a resin base material 16 / resin layer 12 / gas barrier layer 10 / resin layer 14 / sealing layer 18; The present invention is not limited to these, and may have at least three layers of a resin-based base material / resin layer / gas barrier layer /. Within the range that does not impair the effect of the invention, it may be other than the above exception.层 结构。 Layer composition. -45- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order ------- -(Please read the precautions on the back before filling this page) 553991 A7 B7_ V. Description of the invention (inclined) (Please read the precautions on the back before filling this page) In addition, the resin base material, resin layer or gas barrier The thickness of each layer such as the sexual layer is not specifically limited, and it is appropriately set within a range that can reach the function of each layer. Food and medical packaging materials need only be a lamination method that can improve the adhesion strength between the layers. In particular, the manufacturing method is not limited. The lamination method by the extrusion lamination method is preferred. The gas barrier layer is The resin layer and the resin-based base material are co-extruded and laminated, and the resin layer is preferably sandwiched between them to form a sandwich. For example, the above-mentioned five-layer laminated body can be produced as follows. As shown in FIG. 11, the gas barrier layer supply operation causes the gas barrier layer 10 formed of aluminum foil or polyamide film or the like to be extruded from the extruder 40 at a predetermined speed, and supplied to the nozzle 34 and the cooling rod. Between 32. At the same time, the resin surface treatment operation co-extruded the extruder 30 from the extruder 30 in a molten film state with the polyolefin strip resin composition forming the above-mentioned resin layer and the resin forming the resin-based base material. At this time, the molten film is subjected to ozone treatment. For the equipment used in the extrusion lamination, a device of the T-molding method can usually be used. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Then, the lamination operation is pseudo-between the nozzle stick 34 and the cooling stick 32, so that the gas barrier layer 10 and the resin layer 12 and the resin base material 16 are crimped, laminated, and laminated. body. Next, the obtained laminated body composed of the gas barrier layer 10, the resin layer 12 and the resin base material 16 is wound on a winder 42 as a winding operation. In addition, the resin surface treatment operation and the lamination operation in this method can have an operation of providing a resin-based base material on the resin layer. In addition, the laminated body is similarly extruded from the extruder 40 at a predetermined speed, and the gas barrier layer of the laminated body is between the nozzle stick 34 and the cooling stick 32 -46- This paper size applies the Chinese national standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7_ V. Description of the invention (^) (Please read the precautions on the back before filling this page) Supply to the cooling 锟 3 2 side. At the same time, the resin surface treatment operation co-extruded the extruder 30 from the extruder 30 in a molten film state with the polyolefin resin composition forming the resin layer and the resin forming the sealing layer. At this time, the molten film is subjected to an odor treatment. Then, a lamination operation is performed by laminating the laminated body and the resin layer between the nozzles 34 and the cooling rods 32 to form a laminated laminated body. Thus, a five-layer packaging material as shown in Fig. 10 was prepared. The resin temperature during extrusion is generally 280 ~ 350 ° C, which can be below 300 ° C. By applying ozone treatment, the resin temperature during extrusion molding is preferably 200 to 310 ° C, preferably 200 to 300 ° C, more preferably 240 to 280 ° C, and the best 2 5 0 ~ 2 0 0 ° C, even at such a low temperature, it will not reduce the adhesive strength, but can be laminated. Therefore, generation of odor can be reduced. Food and medical packaging materials using the laminated body may be food or medical packaging materials using a conventional joining technique such as heat sealing, and there are no other restrictions on the means for forming food and medical packaging materials. For example, the laminated body is cut into a predetermined shape and joined by heat sealing to form the shape of food, medical packaging materials, and bag materials. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The present invention can further improve productivity by increasing the forming speed, and can be formed at a low temperature, which can greatly suppress the influence of the working environment and surroundings due to smoke, or the generation of odor, Packaging materials suitable for food and medical treatment. [Container] The polyolefin strip resin composition of the present invention described above is suitable for use in laminates. -47- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention ( 6) The resulting container. (Please read the precautions on the back before filling out this page.) In other words, the container of the present invention is made of a laminate having at least a substrate and a resin layer. The preferred ones are those having other layers as shown in FIG. 10. Each example will be described below. The laminated body example 1 used in the container shown in FIG. 0 is a resin layer 12 and a surface layer 16 laminated on one side of the substrate 10, and the resin layer 14 and the surface layer 18 are formed in the same manner on the other side. The substrate is appropriately selected depending on its use, and is not limited, but paper, plastic, or aluminum is preferred. Examples of the paper include board paper, high-quality paper, kraft paper, cellophane, inorganic fiber mixed paper, and synthetic resin mixed paper. When a heat-resistant plastic such as polypropylene or high-density polyethylene is used as the base material, a heat-resistant container can be obtained. The resin layer is a polyolefin resin composition containing the above (A) polyolefin resin and (B) a compound having an unsaturated bond in the molecule, and the amount of unsaturated bond in the molecule in the polyolefin resin composition is 1 〇3 The sulfonic acid has more than 0.5 (M) polyene strip resin composition, and (C) a fluorene compound (M2) polyene strip resin composition, and (D) has the ability to react with epoxy groups. (M3) polyene stripe resin composition of a functionalized vinylene resin layer. When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs as the polyolefin resin composition, the adhesive strength with the base material or sealing layer of dissimilar materials is high, and the adhesive strength is high even if the temperature of the laminate is reduced. In addition, high adhesive strength can be maintained even if the lamination molding speed becomes faster. The surface layer shown in this example is appropriately selected depending on the use of the container, etc., and is preferably made of various resins. For example, low-density polyethylene, high-density _ 4 8 _ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 _B7_ V. Description of the invention (47) Polyethylene, linear low-density polymer Polyolefins such as ethylene and polypropylene, polyesters such as PET, and polyamide. (Please read the precautions on the back before filling out this page.) Food and medical containers are especially low density polyethylene or linear low density polyethylene without additives. 'In addition, it is explained that the container made of the above-mentioned laminated body is a container composed of five layers of a surface layer / resin layer / base material / resin layer / surface layer, but it is not limited to these, and may have at least a base material The two layers of the / resin layer may be composed of other layers as long as the effect of the invention is not impaired. Further, the substrate may be formed of a multilayer structure, and for example, a laminate including a paper and a printed P E T film may be used as a substrate. In addition, the layer thickness of each layer such as a resin layer or a substrate is not particularly limited, and it is appropriately set within a range where the functions of each layer can be achieved. The manufacturing method of the laminated body used in the container example 1 may be a laminated method that can improve the adhesive strength between the layers. In particular, the manufacturing method is not particularly limited, and a method of laminating and manufacturing by extrusion lamination is preferable. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. For example, as shown in FIG. 11, the substrate 10 made of paper and the like is drawn from the extruder 40 at a predetermined speed and supplied to the nozzles 34 and the cooling rod 32. The resin in the state of the molten resin film forming the resin layer 12 and the resin in the state of the molten resin film forming the surface layer 16 are co-extruded from the extruder to cool between the nozzle 锟 3 4 and the cooling rod 32.锟 3, and the resin layer is connected to the base material 10 and supplied, to obtain a laminated body in which the resin layer 12 and the surface layer 16 are laminated on the base material 10 (hereinafter, the laminated body composed of the three layers is simply referred to as "inner layer"). Then, for the inner layer, the resin in the state of the molten resin film forming the resin layer 14 and the resin in the state of the molten resin film forming the surface layer 18 are from -49- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7_ V. Description of the invention (W) (Please read the precautions on the back before filling in this page) Extruder 30 squeezes the cooling rod between the nozzle rod 34 and the cooling rod 32 together On the 32 side, the resin layer is connected to the base material 10 of the inner layer, and is obtained. A laminate of the resin layer 14 and the surface layer 18 as shown in FIG. 10 is laminated on the base material 10. The obtained laminated body is wound on a winder 42. The resin temperature during extrusion molding is generally 280 to 350 ° C, and in the present invention, it may be 300 ° C or less. The resin layers 12 and 14 are preferably treated with an odor. Ozone treatment: It can be blown from the ozone supplier 36 to the side of the connection substrate of the molten resin film coming out of the T mold. The ozone treatment conditions are preferably 5 to 100 g / hr. It is 1 G 0 ~ 5 GG g / hr. By applying this ozone treatment, the layer can be appropriately laminated even at a low temperature of 200 to 3 G0 ° C (preferably 240 to 280 ° C) at the time of extrusion molding. A container using this laminated body is not required to use a conventional joining technique such as heat sealing, and the container forming means is not particularly limited. For example, the laminated body is knocked into a predetermined shape and then joined by heat sealing to form a container shape. In addition, the shape of the container is not particularly limited, and may be, for example, a Gabriel container, a Brico container, or a pollution bath container. This container is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The container is suitable for non-dietary products such as liquid synthetic lotions, surfactants, shampoos, moisturizers, liquid fertilizers, imaging fluids, etc. Containers for various solid, liquid, and gas such as paints, various medicines, and various oils. Particularly suitable for containers such as pharmaceuticals. In addition, when using a heat-resistant substrate, it can be used as a retort container that needs to be disinfected by heating. -50- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 --_ B7___ 5. Description of the Invention (Clever) In addition, it is suitable for dry food or aquatic food such as water and dairy products. , Juice, coffee, tea, soy sauce, vinegar, tofu and other containers. It is also suitable for medical containers such as blood bags (containers) and infusion bags (containers). The invention can further improve productivity by increasing the forming speed, and can be formed at a low temperature, so that the influence on the working environment and the surrounding area due to smoke can be controlled, and the generation of odor can be controlled as much as possible. The laminated body used in the container example 2 has at least a base material, a resin layer, and a gas barrier layer. For example, as shown in FIG. 12, other layers may be used. The device is particularly suitable for food and medical containers. The laminated body used for the food and medical containers shown in the figure is formed by laminating a base material 10 via a resin layer 14 on one side of a gas barrier layer 18 and a polyethylene layer via a resin layer 12 on #layer material 10 Layer 16, and the sealing layer 22 is laminated on the other surface of the gas barrier layer 18 via the resin layer 20. The base material 10 is not particularly limited as long as it is used as a substrate for food and medical containers, such as board paper, high quality paper, kraft paper, cellophane, inorganic fiber mixed paper, synthetic resin mixed paper, and the like. The resin layers 12, 14, and 20 are made of a polyolefin resin composition (M), (M1), (M2), or (M3). In the case of the polyolefin strip resin composition, the adhesive strength with a base material of a different material or a gas barrier layer is high, and even if the lamination temperature is low, the adhesive strength is high, and even if the lamination molding speed is fast, it can maintain a high Adhesive strength. The gas barrier layer 18 can be appropriately selected depending on its use, and is not limited. Example-5 1 ~ This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling in this Page) 'Package — Order ---- 1-1 II. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7 V. Invention Description (β) (Please read the precautions on the back before filling this page) Ester, Polyamide, Vinyl Glycol (EVOH), Polyethylene Glycol, Acrylonitrile, Ethylene Chloride, Polyfluorinated Ethylene, Aluminum, Metal or Metal Oxide Film Among the winners, polyester, polyamide, EVOH, and aluminum foil are sought after. As the sealant layer 22, various conventional materials can be used, and they are appropriately selected depending on the use of food and medical containers, and are preferably made of various resins. For example, low-density polyethylene, high-density polyethylene, linear low-density polyethylene, polypropylene such as polypropylene, polyester such as PET, and polyamide. For food and beverage, especially low-density polyethylene or linear low-density polyethylene without additives, high-pressure free-radical low-density polyethylene, Ziegler 糸 or aromatic metal derivatives 糸 linear low Density polyethylene is preferred. The polyethylene layer 16 may be selected from polyethylene suitable for the sealing layer 22. By forming the sealing layer 22 or the polyethylene layer 16, the odor generated from the container can be reduced. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In addition, it is explained that the laminated body used for the above-mentioned food and medical containers is a polyethylene layer 16 / resin layer 12 / base material 16 / resin layer 14 / gas barrier layer 18 / Laminated body composed of 7 layers of resin layer 2G / sealing layer 22, but not limited to these, it has at least 3 layers of paper layer / resin layer / gas barrier layer /, without impairing the invention Within the scope of the effects, other layers may be used in addition to the above examples. In addition, the thickness of each layer such as a paper layer, a resin layer, or a gas barrier layer is not limited, and it is appropriately set within a range that can achieve the functions of each layer. The laminated body of the food and medical container is only required to be a laminated method for improving the adhesive strength between the layers, especially the manufacturing method is not limited, but -52- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of the invention) The method of lamination and manufacturing by extrusion lamination method is suitable. For example, the laminated body having the above-mentioned seven layers is manufactured as follows. (Please read the note on the back? Matters before filling out this page) First, as shown in Figure 13, the base material is extruded from the extruder 40 at a predetermined speed and supplied between the nozzle stick 34 and the cooling cymbal 32, and The resin in the molten film state forming the resin layer 12 and the resin in the molten film state forming the ethylene layer 16 are co-extruded from the extruder 30 on the cooling roller 32 side between the nozzle 锟 34 and the cooling rod 32, and The resin layer 12 is connected to the base material 10 and supplied, and the resin layer 12 and the polyethylene layer 16 are laminated on the base material 10 to obtain a laminated body 24, which is wound on a winder 42. Then, similarly, the gas barrier layer 18 is extruded from the extruder 40 at a predetermined speed, and is supplied between the nozzle 锟 34 and the cooling rod 32 to form a resin in a molten film state with the resin layer 20 and The resin in the molten film state forming the sealant layer 22 is co-extruded from the extruder 30 on the cooling stick 32 side between the nozzle stick 34 and the cooling roll 32, and the resin layer 20 is connected to the gas barrier layer 18 for supply, The resin layer 20 and the sealant layer 22 are laminated on the gas barrier layer 18 to obtain a laminated body 26, which is wound on a winder 42. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Then, as shown in FIG. 4, the laminated body 24 produced by the upper body is extruded by an autonomous press 40, and the laminated body 26 is extruded from the sandwich extruder 44. Press and press the extruder 30 to polymerize Z; the olefin strip resin composition is extruded so that the base material 10 of the laminated body 24 and the gas barrier layer 18 of the laminated body 26 are each composed of the molten polyolefin strip resin. The object is connected, and β 妾 is sandwiched between the nozzle rod 34 and the cooling coil 32 to form a laminated body composed of the layers shown in FIG. 12. The resin temperature during extrusion is generally 280 ~ 35G ° C, but it can be below 300 ° C in the present invention. -5 3-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 553991 Printed by A7 B7_, Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (P) It is advisable to apply ozone treatment on 20. Ozone treatment: Ozone from the ozone supplier 36 is blown on the molten resin layer film extruded from the T mold. The ozone treatment conditions are 5 to 100 Qg / hr, preferably 100 to 500 g / hro. Ozone treatment, even if the resin temperature during extrusion is 2 0 ~ 3 1 0 ° C (preferably 2 0 ~ 3 0 0 ° C, more preferably 2 4 0 ~ 2 8 0 ° C, The best temperature is 250 ~ 280 ° C), the adhesive strength will not decrease, and it can be laminated. Therefore, the generation of odor can be reduced. In addition, for the base material 10 and the gas barrier layer 18, surface treatments such as pre-heat treatment, electric treatment, flame treatment, and UV treatment can be performed. The interlayer adhesion strength between the radon-treated gas barrier layer and the ozone-treated resin layer is extremely high. For the electric treatment, an electric discharger 38 is used, preferably in the range of 1 to 300 W minutes / m 2, and more preferably in the range of 10 to 10 GW minutes / in 2. The food or medical container using the laminate may be any food or medical container using a conventional joining technique such as heat sealing, and there is no particular limitation on the means for forming the food or medical container. For example, the laminated body is formed into a predetermined shape and then joined by heat sealing to form a food or medical container shape. In addition, there are no particular restrictions on the shape of food and medical containers, such as Gabriel-type containers, Brico-type containers, or pollution bath-type containers. The food container is suitable as a container for dry food or aquatic food such as water, dairy products, fruit juice, wine, coffee steak, tea, soy sauce, vinegar, tofu and the like. Moreover, the medical container of the present invention is suitable for a blood bag (Rong-54- this paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm)) ---------- 1- ------ Order i —---- (Please read the precautions on the back before filling this page) 553991 A7 _B7_ V. Description of the Invention (〇) Device, Infusion Bag (Container), etc. (Please read the precautions on the back before filling this page) The present invention can further improve productivity due to the increase in forming speed, and because it is formed at low temperature, it can minimize the impact on the working environment and surrounding areas due to smoke. Impact or odor generation, suitable for food and medical containers. The present invention is described below by way of examples, but the present invention is not limited thereto. In addition, in the evaluation methods of all the examples and comparative examples described below, the evaluation methods of smoke and odor are as follows. [Smoke] a: No smoke at all. b: Slight smoke. c: There is a lot of smoke. [Smell] Three steps were evaluated by participants through functional tests. A: No smell. B: It smells a little. C: It smells very strong. [Example 1] Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Examples 1-1] Polypropylene resin with a melt flow of 20 g / 10min at 230 ° c at 97% by weight, 3_0 weight Si 150 ° C The MFR below is a polypropylene resin composition of 3.0 g / 10 niin of a 1,2-polybutadiene resin. Use the obtained polypropylene resin composition and use a 90 mm extruder-55- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of the invention (from the Ministry of Economy The Intellectual Property Bureau employee consumer cooperative prints the layer of sticky material into the machine layer. The C machine layer extrudes and accumulates into a compacted space. 1. The polymerized compacted space Inη component layer is composed of fat extruded component layer and 90 extruded component layer. The fat of the palm tree is 1 bar, the body of the tree is 90, the body of the tree is 90, the body of the tree is displayed, the layer of the resin is shown, and the layer of the resin is shown. Polyurethane with 1 c Polyene with 1 c Make the table display 2-Make the table display two Make the table display the grease 11, the paint 1 but the paint and 11- 物 和 and 11-polymers and 1 ene, the shape of the case is 10%, the shape of the case is Λ, the shape of the machine is like the application 1-the group of equipment is like the application 1, the group of equipment is like the polyform smoke Fruit Examples Fatty tobacco fruit. Fatty tobacco fruit formation. Hair knot and application. Tree formation α hair knot description 1 tree formation c hair knot 1 layer The evaluation of the olefin layer body 1-The evaluation of the ene layer body 1-% of the evaluation time of the lay-up. 1-Shi mm to make gas 1% by weight of fat I to make 1 gas of heavy nlln to make gas, make 00 to evaluate odor-293 amount of tree to get 00 to make odor-399 described to get 00 to make odor -1 逑 11, J1 is evaluated by heavy olefins, J1 is evaluated by the above group 11, J1 is evaluated by the ascending degree ^ System ο C is used as the ascending degree ^ System% is used as the ascending degree ^ Make wide paper Jin Qiang SM tune 7. Poly makes the wide paper into the strong Ϊ The volume tree makes the paper into the strong fcb only for the [§, of the t for the heavy t []: (Please read the note on the back? Please fill in this page for more details) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7

V. Description of the invention (K table is based on the machine forming layer 0 layer S layer 00 product 11 is 11, the wide paper machine is laminated on the laminated layer showing the layer of the viscous layer. The 1-shaped expression is evaluated when the fruit is knotted. The gas-evaluation odor evaluation and the degree of progress are stronger than the actual examples. The weight is 5 9 9 9 by the example of making 3¾ allyl resin. Said into the above group% of the amount of fat tree heavy ene 05 propylene ο 聚 成 脂 脂 脂 脂 脂 树 烯 二 二 二 二 二 的 的 的 得 脂 脂 脂 脂 脂 树 树 二 二 二 二 丁 丁 的 的 的 得 得 的 的 脂 脂 脂 脂 树 树 树 树 二 二 二 二 丁 二 的 的 的 的 的 得 得 脂 脂 脂 树 树 树 树 树 二 二 二 二 二 二 二 的 的 的 的 脂 脂 脂 脂 脂 树 树 树 树 树 二 Fine Terrestes Dibutyl Polypropylene Polypropylene Obtained Uses The upper wide paper of the machine-laminated extruded piece S 90 for use in preparation The table is made up of things, and the organic fat-shaped tree is formed into a volume of the C olefin layer. The volume S of 00 is made of the viscous interstitial layer. It is evaluated when the expression of the 1-shaped expression is shown, such as the tobacco knot. 〇The evaluation of the gas odor and the degree of progress are strong. The evaluation of the paper sticks to the paper. When the paper is evaluated, the process is separated from the nnu. The interlayer is made of paper that is strong and sticky. (Please read first.) (Notes on the back then fill out this page) The Intellectual Property Bureau staff consumer cooperatives printed the semblance of love. The evaluation of the tree is based on the evaluation of the quasi-physical base, which evaluates the inherent strength of the alkene, and removes the qualitative CQ. It ’s not easy to write down the paper.… △ X The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (Fifth, description of the invention) Table 1 Example Comparative Example 1-1 1-2 1-3 1-1 1-2 1-3 (A) Ingredient name PP PP (A) Ingredient MFE (230 ° C) (g / lOmin) 20 20 (B) Ingredient name 1,2-polybutadiene — 1,2-polybutadiene — (B) Ingredient MFR (g / 10min) 3.0 (150 ° C) — 3.0 (150 ° C) — (B) The number of unsaturated bonds in the molecule (equivalent to 1,000) 250-250 The amount of (B) components 3.0% 1% 1.0% 0 0.05% 0 The number of unsaturated bonds in the composition (equivalent to 1000) Master) 7.5 17.5 2.5 0 0.13 0 Substrate kraft paper Kraft temperature (° c) 270 270 310 Molding speed (m / min) 100 100 100 Air gap (mm) 130 130 130 Film thickness U m) 30 30 30 Ozone treatment YesYes No Adhesive strength © ® △ X X Λ Odor A A A A A C Fume a a a a a c Ozone treatment conditions: 5Gg / m3-4.5m3 / hr -58- (Please read the precautions on the back before filling this page)

This paper size applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) 553991 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 _ V. Description of the invention (〇) From the above results. Compared with Comparative Examples 1-1 lacking the (B) component, all the examples using the (B) component can be sufficiently adhered to the substrate. In addition, as shown in Comparative Example B2, when the blending amount of the component (B) is too small, the effects of the present invention cannot be exhibited. Moreover, as shown in Comparative Examples 1 to 3, when the forming temperature was increased to 31Q ° C, although the adhesive strength was improved, the odor or smoke generation was remarkable. [Example 2] In the following Examples and Comparative Examples, the following resin components were used. LDPE (I): High-pressure free radical method low-density polyethylene having a melt flow rate (190 ° C) of 15 g / 10roiii and a density of 0.918 g / cm3. L D P E (II): High-pressure free radical low-density polyethylene with a melt flow rate (190 ° C) of 8.2 g / 10 min and a density of 0.918 g / cm3. 1,2-polybutadiene resin: The melt flow vulgar number (150 ° C) is .9. 0 g / 10 min, and the number of unsaturated bonds in the molecule is 250 per IP sulphur. [Example 2-1, 2-2] The polymerization of 93.0 wt% of the above LDPE (I), 7.0 wt% of the above 1,2-polybutadiene resin, and oxidized soybean oil (ES0) was adjusted to i50Qppm. Vinyl strip resin composition. The number of intramolecular unsaturated bonds in 103 sulfone in the obtained polyethylene fluorene resin composition was measured by infrared analysis (IR). A layer forming machine having a width of 110 Ginm with a width of 9 Gmin was used, and as shown in FIG. 1, ozone treatment was applied to the obtained resin layer in the state of a molten resin film made of a polyethylene strip resin composition, and the The laminate was laminated on the substrate 1 G under the conditions shown in the following table to obtain a laminate. -59- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------------- Order L (Please read the precautions on the back before (Fill in this page) 553991 A7 B7 V. Description of the invention (Η) Example 2-1 uses PET film, and the example uses polyimide thin film printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 Wide and thin Λ tree compresses amine interlayer amine layer 1, and extruded on top of the machine. % Olefin | h% Polycondensation IISO amount B 90 shows the amount of 7TT of the extrusion layer I is reassembled to make the layer weight mmm so that the product 2Pο Table 4 Product 2 opp90C6-1 ffl with a2 2 7 ο have 2 to get., Pp to get the following example,, 10 to get the example -1; 1) 500, to give 1 1) as the brain product and 2 '1 thing and solid and 2 ί oil Make the solid shape PE as a result, the shape surface PE is made on the bean, such as the LD oil group machine film, such as LD large material with a film tobacco fruit description soybean fat shape c thin tobacco fruit description base to thin hair knot on the tree The volume of the oxygen on the body T is estimated to be 4% when the oxygen content of the olefin layer is estimated. The shape of the PE is 4], and the amount of oxypropene is evaluated to 6]. Made. 2-heavy ring gathers well. Made. 2- The layer of heavy fat makes. 1 gas production, S, 31 gas production, and tree C shows that 51 materials are odorous and 19 fats are obtained from CD, 2 materials are odorous and 19 materials are suspected. 2 materials are based on J2 and trees. Therefore, the basic evaluation of the above example and J2 are from 20% to 逑 mm. The basic value is the degree of travel. Strong f tuned polyester film with 11 [[Ding group of film coating [| 2 tree as film (please read the precautions on the back before filling out this page) The paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 553991 A7 B7 V. Description of the invention] [Comparative Examples 2-1 and 2-2] (Please read the precautions on the back before filling out this page) Only use the above LDPE (I) with 90mm The extruder has a width of 1100 mm, and is laminated on the substrate under the conditions shown in the following table to obtain a laminate. Comparative Example 2-1 used a PE T film, and Comparative Example 2-2 used a polyamide film as the substrate 10. The smoke condition at the time of manufacture was evaluated, and the adhesion strength between layers of the laminated body and ozone measured were measured. The evaluation results are shown in Tables 2-1 and 2-2. [Comparative Examples 2-3, 2-4] A polyethylene strip resin composition composed of 93% by weight of the above LDPE (I) and 7% by weight of a 1,2-polybutadiene resin was adjusted. Using the obtained polyethylene strip resin composition, a laminate molding machine equipped with a 90 mm extruder having a width of 110 miu was laminated on the substrate under the conditions shown in the following table to obtain a laminate. Comparative Examples 2 to 3 used a PE T film, and Comparative Examples 2 to 4 used a polyamide film as the substrate 10. The smoke generation at the time of manufacturing was evaluated, and the adhesion strength and odor of the laminated body obtained by the measurement were evaluated. The evaluation results are shown in Tables 2-1 and 2-2. [Comparative Examples 2-5 and 2-6] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, using only the LDPE (I) with a 1100 mm lamination machine equipped with a 90 mm extruder, the conditions shown in the table below Laminated on a substrate to obtain a laminated body. However, the molten resin was not treated with ozone. Comparative Examples 2 to 5 used a PE T film, and Comparative Examples 2 to 6 used a polyamide film as the substrate 10. To evaluate the smoke status at the time of manufacture and the layer of the laminated body obtained from the measurement, the paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 _B7___ 5. The adhesive strength between the description of the invention (M) ozone. The evaluation results are shown in Tables 2-1 and 2-2. [Evaluation method] [Adhesive strength] The obtained laminated body was cut into a booklet with a width of 15 mm in the direction of flow of the laminated body, and a universal tensile test stack (Orientic) was used to peel off the substrate. The interface between the material and the resin layer (18 Q ° C peeling, peeling speed 3 G 0 in m / min), and observe the adhesive strength. [Adhesive strength 2] After the various laminates were kept at 4 () ° C and humidity 80¾ for 24 hours, they were measured in the same manner as the adhesive strength 1. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 6 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Invention Explanation (Μ) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 2-1 Examples of Comparative Examples 2-1 2-3 2-5 2-1 2-3 2-5 (A) Ingredient name LDPE (I) LDPE (I) LDPE (II) (A) component MFR 15 15 8.2 (B) component name 1,2-polybutadiene — 1,2-polybutadiene one (B) component MFR (g / lOinin) 9.0 (150 ° 〇-9.0 (150 ° C) — (B) The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 250-250 — (B) 7.0% 1.0¾ 7.0% 0 7.00% 0 Composition Number of unsaturated bonds in the molecule (equivalent to 1000 sho) 17.5 2.5 17.5 0 17.5 0 (B) Component name ES0 ESO ESO-ESO (A) Component amount (ppm) 1500 1500 1000 0 0 Base material PET PET PET molding temperature ( ° c) 270 270 320 forming speed (m / min) 150 ISO 150 air gap (M) 120 130 120 film thickness (# m) 30 30 30 ozone treatment with imc chick adhesion strength 1 650 430 630 60 410 230 Adhesive strength 2 620 400 350-150 120 Odor AAAAAC Fumes aaaaac Odor treatment conditions: 50g / m3-4.5ni3 / hr -6 3- (Please read the precautions on the back before filling this page) This Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of the invention (^) Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 2-2 Example Comparative Example 2-2 2 -4 2-6 2-2 2-4 2-6 (A) Ingredient name LDPE (I) LDPE (I) LDPE (II) (A) Ingredient MFR 15 15 8.2 (B) Ingredient name Diene-1,2-polybutadiene- (B) component MFR 9.0 (150 ° 〇- 3.0 (150 ° 〇- (B) The number of unsaturated bonds in the molecule (equivalent to 1000 sulfonate) 250-250- (B) Ingredients 7.0¾ 1.0% 7.0% 0 7.00% 0 The number of bonds and bonds in the composition (equivalent to 1GG0 sulphur) 17.5 2.5 17.5 0 17.5 0 (B) Ingredient name ES0 ESO ESO-ES0-(A ) Composition (ppm) 1500 1500 1000 0 0 Substrate Long film: Long film forming temperature (° c) 270 270 320 Forming speed (m / min) 150 100 150 Air gap (M) 120 120 120 Film Um) 30 30 30 Presence or absence of adhesive strength with ozone treatment 1 650 480 630 60 860 250 Adhesive strength 2 630 420-210 50 Odor AAAAAC Fuming aaaaa C Ozone treatment conditions: 50g / m3-4.5ro3 / hr -64 -(Please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (w) As can be seen from the above description, this implementation The laminated body of the example, regardless of whether the substrate is a PE] · film or a polyamide film, can exhibit high adhesive strength at a high molding speed and a low molding temperature τ. In this regard, the lack of (b) component tb is lower than that of Examples 1 and 2, and its adhesive strength is low. Comparative Examples 3 and 4 that do not contain component (c) have low adhesive strength after the state adjustment. In addition, in Comparative Examples 5 and 6 which lacked the (B) component and were not subjected to an odor treatment, the molding g was high, and although the adhesive strength was improved, there was smoke. [Example 3] In each of the examples and comparative examples below, the following resin components were used. M e P (I) · The melt flow pseudo number (260 ° C) is 100 g; [ffl i 4 -methyl-1-pentene strip resin. M e P (II): 4-methyl-1-pentamidine resin having a melt flow pseudo-number (260 ° C) of 80 g / 10roin. PB (I): The melt flow pseudo-number (150 ° C) is 1, 2_ polybutadiene strip resin with g. Og / lOmin. The number of unsaturated bonds in the molecule is 25.0 / 103 sulfonic acid. P B (II): a polybutadiene strip resin with a melt flow coefficient (150 ° C) of 3.0g / 10min. The number of unsaturated bonds in the molecule is 250/103 sulfonic acid. [Example 3-1] A 4-methyl-papene strip resin composition was prepared from 85% by weight of the MeP (I) and 15% by weight of PB (I). The number of unsaturated bonds in the molecule of 103 in the sulfonic acid in the 4-methyl-pentene strip resin composition obtained by infrared analysis (IR) was measured. Using a laminating machine having a width of liQQinin equipped with a 90 μηι extruder As shown in Figure 1, the -65- made of 4-methyl-pentene strip resin composition is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm). (Please read first Note on the back, please fill out this page) ▼ 装 ----- ^ — Order_ " ^ —. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7 V. Description of Invention (M) (Please read the back first Please note that this page is to be filled in again.) Ozone treatment was applied to the molten resin, and it was laminated on the high-quality paper (16Gg / in2) l () with electric treatment under the conditions shown in Table 3-1. Laminated body. The adhesion strength between layers of the obtained laminated body was performed. The evaluation results are shown in Table 3-1. [Example 3-2] A 4-methyl-1-pentene strip resin composition composed of 97-5 wt% of the aforementioned MeP (I) and 2.5 wt% of PB (I) was prepared. Using the obtained 4-methyl-1-pentene strip resin composition, a lamination molding machine equipped with a 90 mm extruder and a width of 1100 μBin was used. The conditions shown in Table 3-1 were the same as those in Example 3-1. The layers are laminated on top-quality paper to obtain a laminated body. The interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 3-1. [Examples 3 to 3] A 4-methyl-1-pentene strip resin composition was prepared from 85% by weight of the MeP (I) and 15% by weight of the PB (I). The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed on the substrate 4 the obtained 4-methyl-1 -pentene strip resin composition under the conditions shown in Table 3-1 so that the above-mentioned Me P (I) On the cooling roller 3 and 2 sides, a laminating machine equipped with a 90 mm extruder with a width of 110 Gmin was co-extruded and laminated on the high-quality paper to obtain MeP (I) / MeP (I) + PB (I) / substrate Laminated body consisting of 3 layers. The thickness of the layer made of MeP (I) and the layer made of MeP (I) + PB (I) are both 25 # ιη. The resin layer of the laminated body (M e P (I) / M e P (I) + -66- obtained from the measurement) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 _B7_ 5 Description of the invention (K) PB (I) Adhesion strength between the substrate and the substrate. The evaluation results are shown in Table 3-1. [Comparative Example 3-1] (Please read the precautions on the back before filling this page) The MeP (I) was laminated on a high-quality paper in the same manner as in Example 3-1 using a lamination molding machine with a width of 1100 fflm equipped with a 90 mm extruder to obtain a laminated body. The adhesion strength between the layers of the obtained laminated body. The evaluation results are shown in Table 3-1. [Comparative Example 3-2] 99.9% by weight of the aforementioned MeP (I) and 0.1% by weight of the PB (II) of 4-form 1-pentene strip resin composition. Using the obtained 4-methyl-1 -pentene strip resin composition, a lamination molding machine having a width of 1100 mm equipped with a 90 mm extruder was used as shown in Table 3-1. The laminated body was laminated on a quality paper under the conditions shown below to obtain a laminated body. The interlaminar adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 3-1. [Comparative Examples 3-3] Only the above MeP (II) was laminated with a 1100 mm width forming machine equipped with a 9Qmin extruder, and laminated on top-quality paper under the conditions shown in Table 3-1 to obtain a laminated body .But the molten resin was not treated with ozone. The adhesion strength between the layers of the laminated body printed and measured by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs was measured. The evaluation results are shown in Table 3-1. [Evaluation method] [With paper Adhesive strength] Adhesive strength with high-quality paper substrate (for interlayer peeling operations) -67- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7_ (5, description of the invention) The situation is evaluated based on the following three stages. The high-quality paper is firmly integrated with the 4-methyl-1-pentene strip resin composition layer, and the resin is not carefully drawn. Δ: It peels off a little carelessly. X: Peeling easily occurs. ------------------— Order l · —----- (Please read the notes on the back before filling out this page) -68- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 ΓΝ —.ο

V Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (π) Table 3-1 Examples of Comparative Examples 3-1 3-2 3-3 3-1 3-2 3-3 (A) Ingredient Name MeP (I) MeP (I) MeP (II) (A) ingredient MFR 100 100 80 (B) ingredient name 1,2-polybutadiene — 1,2-polybutadiene — (B) ingredient MFR — evening 9.0 (150 ° 〇-3.0 (150 ° 〇 / (ΓΆ 'k) (B) the number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 250-250 — (B) the amount of component 15¾ 2.5¾ 15¾ 0 0.1% 0 Number of unsaturated bonds in the composition (equivalent to 1000 sulfonic acid) 37.5 6.25 37.5 0 0.25 0 Monolayer / co-extrusion single-layer co-extrusion selection S Monolayer substrate quality paper on high-quality paper (° c) 270 270 310 Forming speed (ro / min) 120 120 120 Air gap (mm) 110 110 110 Film thickness Mm) 50 50 50 Electric treatment 7KW 7KW 7KW Ozone treatment has frrr chick adhesion strength © △ XX △ Ozone treatment conditions: 5Gg /in3-4.5ni3/hr -69- (Please read the notes on the back before filling in this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7

5. Description of the invention (W) From the above, it can be seen that the laminated body of this embodiment can exhibit high adhesive strength at a high forming speed and a low forming temperature. In this regard, Comparative Example 1 lacking the (B) component, or Comparative Example 2 with a small number of unsaturated bonds in the molecule, had low adhesive strength. Further, in Comparative Example 3, which lacks the (B) component and is not subjected to an ozone treatment, the adhesion strength is improved by increasing the molding temperature. [Example 4] [Example 4-1] A 97% by weight polybutene resin (I) having a melt flow rate of 30 g / lHmiri at 230 ° C and a 3% by weight MFR at 230 ° C were prepared. g / 10min Polypropylene resin composition of ethylene-propylene-diene terpolymer (EpDM). The number of unsaturated bonds in the molecule of 103 sulfonic acid in the obtained polypropylene strip resin composition was measured by infrared analysis (IR). In addition, using this polypropylene / resin composition, a lamination molding machine having a width of 110 Omni having a 90 nm extruder was laminated on paper under the conditions shown in Table 1 to obtain a laminated body. (Please read the note on the back? Matters before filling out this page) The employee property cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed a layer of 0 and a layer of 1 in the interlayer. condition. An example of how to force the stickiness of the smoke when evaluating the odor of the smoke and the manufacturing system Ϊ PC is controlled by 1% and the amount is adjusted to ° c 1 and the stearylene diene propylene polymer 2 is 1, 1 Zhi | η 4 .1 Example 〇Ιη 施 / 1 og og. 9. The above is a tree with equipment used to form a group of fatty resins. Articles to form an acrylic group of polyester resin. Acrylic resin is used to make a polyextrusion paper. Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 553991 Α7 Β7 V. Description of the invention (w) Laminating presses with a width of 1100 mm. The conditions shown in 4-1 were laminated on paper to obtain a laminated body. The smoke condition at the time of manufacture and the adhesion strength between the layers of the obtained laminated body were evaluated. The evaluation results are shown in Table 4-1. [Example 4-3] A polypropylene strip resin of 90.0% by weight of the above Example 4-1 and 10% by weight of 150 were prepared. A polypropylene fluorene resin composition of 1,2-polybutadiene resin having an MFR of 9.0 g / lflmin. Using the obtained polypropylene strip resin composition, a laminate molding machine having a width of llODmm equipped with a 90-nm extruder was laminated on paper under the conditions shown in Table 4-1 to obtain a laminate. The smoke conditions at the time of manufacture and the interlayer adhesion strength and odor of the obtained laminated body were evaluated. The evaluation results are shown in Table 4-1. [Comparative Example 4-1] Only the polypropylene strip resin (I) of Example 4-1 was used, and a laminating machine having a width of lioomm equipped with a 90 η extruder was used under the conditions shown in Table 4-1 Laminated on paper to obtain a laminated body. The smoke condition at the time of manufacture and the adhesion strength between the layers of the obtained laminated body were evaluated. The evaluation results are shown in Table 4-1. [Comparative Example 4- 2] A polypropylene strip resin (II) having a melt flow rate of 20 g / 10 min at 230 ° C at 99.95% by weight, and a weight of 0.05 ¾ and a MFR of 3.0 g / 10 min were prepared. Polypropylene strip resin composition made of 2-polybutadiene resin. Using the obtained polypropylene strip resin composition, use a 90ηΐπι extrusion-7 1- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---------------- ----- Order --------- (Please read the notes on the back before filling this page) 553991 A7 _B7_ V. Description of the invention (W) (Please read the notes on the back before filling this page ) A laminate forming machine with a press width of 110 Gmin was laminated on paper under the conditions shown in Table 4-1 to obtain a laminate. The smoke conditions at the time of manufacture and the interlayer adhesion strength and odor of the obtained laminated body were evaluated. The evaluation results are shown in Table 4-1. [Comparative Example 4- 3] Only a polypropylene resin (II) having a melt flow rate of 230 ° C of 20 g / 10 min was used, and a lamination molding machine having a width of 110 min with a 9 Gmni extruder was used. The conditions shown in 1 are laminated on paper to make a laminated body. The smoke condition at the time of manufacture and the adhesion strength and odor between the layers of the obtained laminated body were evaluated. The evaluation results are shown in Table 4-1. [Evaluation method] [Adhesive strength with paper] Adhesive strength with paper substrates is evaluated based on the conditions at the time of interlayer peeling using the following three-stage evaluation criteria. The paper and the polypropylene strip resin composition layer are firmly integrated, and the resin is not drawn. △: A little carelessly peels off. X: It is easy to peel off. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs of the Employees' Cooperatives This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Invention Description (^) Printed by the Intellectual Property Bureau of the Ministry of Economics's Consumer Cooperatives 4-1 Project Example Comparative Example 4-1 4-2 4-3 4-1 4-2 4-3 (A) Ingredient name PPU) PP (I) PP (I) PP (I) PP (II) PP (II) (A) Ingredient MFR (230 ° C) (g / 10min) 30 30 30 30 20 20 (B) Ingredient name EPDM 1,2-polybutadiene — 1,2-polybutadiene — (B ) Composition MFR (g / 10min) 3.0 (230 ° C) 9.0 (150 ° 〇— 3.0 (150 ° C) — (B) Number of unsaturated bonds in the molecule (equivalent to 1,000 carbons) 70 250 · — 250 — (B) Composition amount 3.0¾ 10% 1.0¾ 0 0.05¾ 0 The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 2.1 25 2.5 0 0.13 0 substrate kraft paper kraft forming temperature (° c) 270 270 270 270 270 310 Forming speed (m / min) 120 120 120 120 120 120 Air gap (nun) 120 120 120 120 120 120 Film thickness (Am) 40 40 40 40 40 40 Corona treatment 6KW 6KW 6KW 6KW 6KW 6KW 6KW Ozone treatment Yes Yes yes dnt M Abrasion intensity © ® Δ XXA Odor AAAAAC Fume aaaaac Ozone treatment conditions: 50g / m 3 -4 · 5m 3 / hr -73— (Please read the precautions on the back before filling this page) The paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) 553991 ΚΙ_Β7_ V. Description of the invention (P) From the above results, compared with Comparative Example 1 which lacks the (B) component, all the examples using the (B) component can be Fully adhered to the substrate. In addition, when the number of unsaturated bonds in the molecule of Comparative Example 2 was small, the effect of the present invention could not be exerted. Comparative Example 3 By increasing the forming temperature, although the adhesive strength was improved, However, the odor is strong and there is a lot of smoke. Examples of peeling substrates [Example 5] Each resin component in the following example is used in each of the following examples and comparative examples. LDPE (I) ·· Melted Flow Number (19G ° C) is 8.5g / 10roin, density is 0.918g / cm3 high-pressure free radical method low density polyethylene. L D P E (II): A high pressure free radical low density polyethylene with a melt flow rate (190 ° C) of 2Qg / lGmin and a density of 0.918g / cm3. L D P E (III): High-pressure free radical low-density polyethylene with a melt flow rate (19 G ° C) of 8 · 2 g / 10 m i η and a density of 0.918 g / cm3. Mixed PE: A mixture of 40 weight of the above-mentioned LDPE (I) and 60 weight% of a high-density polyethylene having a melt flow rate of 20 g / 10 miη. EPDM: Ethylene-propylene-diene terpolymer with a melt flow pseudo-number (230 ° C) of 3.0 g / 10roiii. The number of unsaturated bonds in the molecule is 70/103 --------- i—φ ^ ----- r——Order i —---- MW (Please read the precautions on the back before filling (This page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ * 1 1 / piece / 8 o S 0 5 0 • 2 3 i 9 is the \ — / number P key. C ο α ο 5 filial piety 5 (1 full (1 countless 僳 internal 僳 two 33 flow split melt. Melt fat melt: tree: \ »/ -f. \ Y ene 1 Π — 二 {Β BP 丁 P 聚Gather a ο 5 2 is a number bond and saturates. 0 Two examples of resinene 1, sulfone 1, and m 3 of sulfone. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991. A7 B7 V. Description of Invention

{物 ΡΕ 成 LD group description on the resin %% of the amount of ethylene on the ethylene 5. Poly 7 7/9 by the production of M. Μ D on the weight of the% group of the resin on the ethylene to determine the \ — / RI / IV analysis of the outer red line with the highest number of -PE ammonium and saturated neutrons with sulfonium, the formation of the machine formed into layers, the fat, m ί m0 00 strip 11 ene is ethyl Kuan Jizhi ’s machine pressure is squeezed out by min 9 to show that there are 4 sets of tools, such as on the table, 12 and paper, and the oxygen and odor at the skin and cattle. There are layers of layered strips of fat that are applied to the tree layer. The c-lipid body tree is melted 1 and the melted layer 5 is the layered body. Determine the measurement and 1 case of the 5 tables. When the smoke is fruiting, the evaluation system will be evaluated. ○ The evaluation will force the chemical system BC 0 to be pre-treated to give the fat tree silicified gas and cover it with the upper resin tree. In the body, Kiyomizu peels another example. Examples I ~ I (Ep. 0 Group LD. Lipids are described in the tree group.% Lipene content. Ethyl alcohol. Polyethylene 5 -r. The amount used is adjusted so that the amount is 2%. There is a device for use. (Please read the precautions on the back before filling out this page.) The employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints a table with layers of 0. The paper of In 0, 00 and 11 on the paper is the Ann layer of the skin layer of the machine-laminated laminate strips of the skin wide cow. The test result and the shape of the 5-shaped epidemic are like fruit. Time evaluation and evaluation system 0Evaluation 2 ίΑ Evaluation progress sticky system 0C hard to pretreat the silicic acid gas to cover the upper layer of the resin tree 0 in-vivo, based on L—shoes, stripped to the extent that this paper is suitable for China National Standard (CNS) A4 Specification (210 X 297 mm) 553991 Α7 B7 V. Description of Invention (74) [Examples 5-3] (Please read the precautions on the back before filling this page) Modulation by 99.0% by weight of the above Polyethylene strip resin composition made of LDPE (I) and 1.0 wt% PB (I). Using the obtained polyethylene strip resin composition, a lamination molding machine equipped with a 90 mm extruder with a width of 110 nm was laminated on kraft paper under the conditions shown in Table 5-1 to obtain a laminated body. The smoke situation and the interlayer adhesion strength of the obtained laminated body were measured. The evaluation results are shown in Table 5-1. In addition, a silicon dichloride resin was coated on the resin layer and cured to obtain a peeling substrate. [Example 5 -4] A polyethylene / resin composition composed of 93% by weight of the above-mentioned mixed PE and 7.0% by weight of the above-mentioned PB (II) was prepared. Using the obtained polyethylene strip resin composition, a 90 mm extruder was used. A laminated forming machine with a width of llQOmni was laminated on kraft paper under the conditions shown in Table 5-1 to obtain a laminated body. The smoke generation during the manufacturing process was evaluated and the adhesion strength between the layers of the obtained laminated body was measured. The evaluation results are shown in the table. 5-1. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. In addition, the resin layer was coated with silicon dioxide resin and hardened to obtain a peeling substrate. [Example 5-5] Prepared by 97.5 weight % Polyethylene LDPE (I), 2.5% by weight of the above polyethylene PB resin resin composition made of PB (I). The obtained polyethylene strip resin composition was placed on the base material layer side, and the above -7 6 copies Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 __________B7___ ^^ Description of the invention (<) LDPE (I) is on the side of the cooling rod 3 2 LDPE (I) / LDPE (I) + PB (I) were produced by co-extrusion and lamination on a kraft paper using a laminating machine with a width of llGflmm with a 90mm extruder under the conditions shown in Table 5 -.1. Laminated body consisting of three layers of base material. Evaluate the smoke generation during manufacturing and measure the adhesive strength between the resin layer (L D P E (I) / L D P E (I) + P B (I)) and the base material. The evaluation results are shown in Table 5-1. In addition, a silicon dioxide resin was applied to the resin layer and cured to prepare a release substrate. [Examples 5 to 6] A polyethylene strip resin composition made of 93% by weight of the above-mentioned mixed PE and 7.0% by weight of the above-mentioned PB (II) was placed on the base material side, and the mixed PE was placed on the cooling pad 32 side. The 90mm extruder is a laminating machine with a width of 110mm, and co-extruded and laminated on kraft paper under the conditions shown in Table 5-1 to obtain a three-layer structure of mixed PE / mixed PE + PB (II) / base material. Laminated body. The smoke condition at the time of manufacture was evaluated and the adhesion strength between the resin layer (hybrid PE / hybrid PE + PB (II)) of the obtained laminate and the base material was measured. The evaluation results are shown in Table 5-1. In addition, the resin layer was coated with a digasified silicone resin and hardened to obtain a peeling substrate. [Comparative Example 5-1] Only the upper LDPEUI was used.) A lamination molding machine with a width of 1100 min equipped with a 9Ginin extruder was laminated on kraft paper under the conditions shown in Table 5-2 to obtain a laminated body. . _ One 7 7-One paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 Public Love 1 丨 ---------------— Order i —.— M9, ( (Please read the precautions on the back before filling this page) 553991 A7 B7 V. Description of the invention (4) Evaluation of the smoke condition during manufacture and the adhesion strength between the layers of the laminated body measured. The evaluation results are shown in Table 5-2. (Please read the precautions on the back before filling this page) [Comparative Examples 5-2] A polyethylene strip resin composition made of 99.95% by weight of the above LDPE (II) and 0.05% by weight of the PB (I) was prepared. Using the obtained polyethylene strip resin composition, a laminate molding machine equipped with a 9flmin extruder and a width of 110min was laminated on the kraft paper under the conditions shown in Table 5-2 to obtain a laminated body. The smoke level and the adhesion strength between the layers of the laminated body were measured. The evaluation results are shown in Table 5-2. [Comparative Examples 5-3] Only the above LDPE (II) was equipped with a 90-minute extruder. A 1100 mm layer forming machine was laminated on kraft paper under the conditions shown in Table 5-2 to obtain a laminated body. Resin is not treated with odor. The smoke condition at the time of manufacture and the adhesion strength between layers of the laminated body obtained are evaluated. The evaluation results are shown in Table 5-2. [Evaluation method] [Adhesive strength with paper] Economy The Ministry of Intellectual Property Bureau ’s consumer cooperatives printed the kraft paper substrate and the kneading strength of the substrate. The following three-stage evaluation criteria were used to evaluate the conditions during the interlayer peeling operation. @: Kraft paper is firmly integrated with the polyethylene resin layer. And the resin is not drawn. △. · It will peel off a little carelessly. X: It is easy to peel off. ~ 7 8-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (〃) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 5-1 Project Example 5-1 5-2 5-3 5-4 5-5 5-6 (A) Ingredient name LDPE (I ) Mixed PE LDPE (I) Mixed PE (A) Ingredient MFR (190 ° C) (g / 10niin) 8.5 20 / 8.5 8. 5 20 / 8.5 (B) Ingredient Name EPDM PB (I) PB (I) PB (II) PB (I) PB (II) (B) Composition MFR (g / 10min) 3.0 (230 ° 〇3.0 (150 ° C) 3.0 (150 ° C) 9.0 (150 ° C) 3. 0 (150 ° C) 9.0 (150 ° C) (B) The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 70 250 250 250 250 250 (B) 2.5% 2.5% 1.0% 7.0% 2.5¾ 7.0% Number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 1.9 6.3 2.6 17.5 6.3 17.5 Monolayer / co-extrusion Single-layer co-extrusion base material Kraft forming temperature (° c) 270 Forming speed (m / min) 350 Air Pitch (mm) 140 Film thickness Um) 20 Corona treatment 7KW Odor treatment has adhesive strength @ △ Fume aaaaaa Ozone treatment conditions: 50g / m3-4.5m3 / hr _79- (Please read the precautions on the back before filling in this (Page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (70 Table 5-2 Printed items of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Comparative Example 5-1 5-2 5-3 (A) Ingredient name LDPE (II) LDPE (II) LDPE (ΠΙ) (A) Ingredient MFR (190 ° C) (g / 10min) 20 20 8. 2 (B) Ingredient name-PB (I) —— (B) MFR (g / 1 Oinin) —— 3.0 (L50 ° C) —— (B) Number of unsaturated bonds in the molecule (equivalent to 1 0 0 0 sulphur) —— 250 —— (B) component amount 0 0.05% 0 number of unsaturated bonds in the molecule (equivalent to 1 0 0 0 sulphur) 0 0.13 0 single layer / co-extrusion single layer single Single-layer base material kraft paper forming temperature (° C) 270 270 270 forming speed (m / mi η) 350 350 350 air gap (mm) 140 140 140 film thickness U «0 20 20 20 electric treatment 7KW 7KW 7KW ozone treatment With or without adhesive strength XXA fume a A c Ozone treatment conditions: 50g / m3 -4.5m3 / hr -80- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 Specifications (210 X 297 mm) 553991 A7 B7 V. Description of the invention (bamboo, the laminated body of this embodiment can exhibit high adhesive strength at high forming speed and low. In this respect, the deficiency is lower than that of Comparative Example 2 in which the compounding amount of the component (B) is small. In addition, the (B) component is absent and ozone is not applied. By increasing the molding temperature, the adhesive strength can be improved. In the examples and comparative examples, each resin component of the diarrhea was used. The melt flow rate of polypropylene (23QX :) is 30g / lQmin, and the melt flow rate of polypropylene (230 ° C) is 2Qg / lQinin, and the melt flow rate of polypropylene (150 ° C) is I, which is 9.0g / 10min. 2-. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. The melting flow rate (150 ° C) is 1, 2_ of 3.0g / 10iniii. The number of unsaturated bonds in the molecule is 250/103 硪. The amount X was charged with PP (I) and 10% by weight of the above-mentioned PB (I) resin composition. The number of unsaturated bonds in the molecule of the obtained polypropylene strip resin group # was determined by an analytical method (I R). The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the comparative example of the component ratio at the forming temperature (B) and the adhesion strength. Comparative Example 3 There will be smoke. [Example 6] The following actual PP ( I): fused PP (II): fused PP (I): fused polybutadiene resin PB (II) ·· fused polybutadiene resin [Example 6-1] Polypropylene reconstituted from 90 A strip is used as the infrared ray component of 103 sulfonic acid, and the laminated body is provided with the conditions shown in FIG. 4 as a molten resin film. (Please read the precautions on the back before filling in this page.) A 90mm extruder with a lamination width of llODmin, shows that the resin layer made of the obtained polypropylene strip resin composition is treated with odor. According to Table 6-1, it was laminated on Kraft paper 12 with corona treatment to obtain 8 1-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (&Amp;) The smoke condition at the time of manufacture was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 6-1. (Please read the precautions on the back before filling in this page.) In addition, apply silicone dioxide to the resin layer and harden it to obtain a peeling substrate. [Example 6-2] A polypropylene strip resin composition made of 99.0% by weight of the above PP (I) and 1.0% by weight of PB (I) was prepared. Using the obtained polypropylene strip resin composition, a laminate molding machine having a width of llGGinin equipped with a 90 mm extruder was laminated on kraft paper under the conditions shown in Table 6-1 to obtain a laminate. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 6-1. In addition, the resin layer was coated with a silicon dioxide resin and hardened to obtain a peeling substrate. [Example 6-3] A polypropylene strip resin composition made of 90% by weight of 3: polypropylene PP (I) and 10% by weight of PB (I) was prepared. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs so that the obtained polypropylene strip resin composition is on the base material side, and the above PP (I) is on the cooling rod 3 2 side. The conditions shown in Table 6-1 are used. The 90mro extruder is a laminating machine with a width of llQQmm. It is coextruded and laminated on kraft paper to obtain a laminated body consisting of three layers of PP (I) / PP (I) + PB (I) / base material. The smoke condition at the time of manufacturing was evaluated, and the adhesive strength between the resin layer (P P (I) / P P (I) + P B (I)) of the obtained laminated body and the base material was measured. -8 2-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 5. Description of the invention (&) Manufactured by Huashuo to give the silicic acid and oxygenated resins on the resins 20 overlays Upper 1 CO CO table. For example, in the case of body fruit, the peeling is evaluated outside the base node and I get 6 I6 * j. In the above example, the bbris is equipped with equipment and the wide body is used to squeeze the body to form a layer. The evaluation system is estimated when the body layer of the display layer of the laminated piece is determined by the C test and the -1 condition 6 results. Evaluation of the 6 cases of strong adhesion to the soil I / V P P

The above-mentioned amount of S is equipped with equipment used to make the material into groups of the group of tallow tree barene ene ethylene polymer polymerization used to make I) squeeze (please read the note on the back? Matters before filling in this (Page) The table is based on the machine 0-shaped body layer 0 layered 0 m, the 00 on the 11 paper is the skin width of the cow's lamination on the laminated layer of the laminated layer. The fixed-measurement and 1-form 6-sentence form is in full swing when the results are estimated. The evaluation case is forced to stick to the case. Compared with the bb printed by the Intellectual Property Bureau Staff Consumer Cooperative, the Ministry of Economic Affairs is only lenient. The machine squeezes m 0 ο 9 with equipment to make paper cows. The layering and accumulating parts of the oxygen and stink are shown in the application. The fat 6-tree surface melts and melts, but the structure of the interlayer layer is layered and the volume is obtained. The test results and 1 case of the 6-segment table smoke are estimated to be fruitful at the end of the evaluation process. 0 The appraisal is forced to adhere to this paper. The standard of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm). 553991 A7 B7 V. Description of the invention (A) [Evaluation method] [Adhesive strength with paper] Adhesive strength with paper base material 傺 The conditions at the time of interlayer peeling operation are evaluated using the following three-stage evaluation criteria. The paper and the polypropylene strip resin composition layer are firmly integrated, and the resin is not drawn. △: A little carelessly peels off. X: It is easy to peel off. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-84- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. &Amp; Description of the Invention Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Table 6-1 Project Example fcb Comparative Example 6-1 6-2 6-3 6-1 6-2 6-3 (A) Ingredient Name PP (I) PP (I) PP (ΙΙ) (A) Ingredient MFR (230 ° C) (g / 10min) 30 30 20 (B) Ingredient name 1,2-polybutadiene — 1,2-polybutadiene MFR (g / 10min) 9.0 (150 ° 〇— 3. 0 (150 ° 〇— (B) The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur)) 250 — 250 one (B) 10.0% 1.0% 10.0% 0 0.05 ¾ 0 Number of unsaturated bonds in the composition (equivalent to 1000 masters) 25 2.5 25 0 0.13 0 Single layer / co-extrusion single layer co-extrusion single-layer base material kraft paper kraft paper Forming temperature (° c) 270 270 310 Forming speed (m / min) 150 150 150 Air spacing (Μ) 120 120 120 Film thickness Um) 20 20 20 Electrolytic treatment 7KW 7KW 7KW Ozone treatment with -fay Μ Intensity © △ © XX Δ Fuming aaaaa C Ozone treatment conditions: 5Gg / m3-4.5m3 / hr -85- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 553991 A7 __ B7 V. Description of the invention (M) (Please read the precautions on the back before filling this page) As can be seen from the above description, the laminated body of this embodiment has high forming speed and low At the molding temperature, high adhesive strength can be exhibited. In this regard, Comparative Example 1 lacking the (B) component or Comparative Example 2 having a small blending amount of the (B) component has low adhesive strength. Moreover, the (B) component is lacking In Comparative Example 3, which was not treated with ozone, by increasing the forming temperature, the adhesive strength was improved and smoke was generated. [Example 7] The following examples are used in the examples and comparative examples. Resin components, LDPE (I): high-pressure free-radical low-density polyethylene with a melt flow rate (191TC) of 8.5 g / 10 min and a density of 0.918 g / cm3. LDPE (II): melt flow image (190 ° C) High-pressure radical polymerization of 20 g / lOmin and density of 0.918 g / cm3 Ene. LDPE (ffl): A high pressure free radical method low density polyethylene having a melt flow image (19Q ° C) of 8.2 g / 10 min and a density of 0.918 g / cm3. EPDM: An ethylene-propylene-diene terpolymer having a melt flow rate (230 ° C) of 3.Gg/10 min. The number of unsaturated bonds in the molecule is 70/103. 1,2-polybutadiene resin: the melt flow pseudo number (15CTC) is 3.Dg / 10 min. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. [Example 7-1] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Polyethylene strip resin composition composed of 98 weight X upper LDPE (I) and 2.0 weight percent of the above EPDM was prepared. The number of unsaturated bonds in the molecule of 103 obtained in the obtained polyethylene strip resin composition was determined by infrared analysis (IR). -8 6-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of invention (α) (Please read the precautions on the back before filling this page) Use 90mm Extruder lamination molding machine with a width of llOOmiR. • Apply ozone treatment to the resin layer in the molten resin film state made of the obtained polypropylene strip resin composition as shown in Figure 4. The conditions shown in 1 were laminated on the kraft paper 12 to which electro-repellent treatment was applied to obtain a peeling substrate. The smoke condition at the time of manufacture was evaluated, and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 7-1. [Example 7-2] A polyethylene fluorene resin composition made of 97.8 weight S: the above-mentioned LDPE (I) and 2.2% by weight of a 1,2-polybutadiene resin was prepared. Using the obtained polyethylene strip resin composition, a laminate molding machine equipped with a 90 mm extruder and having a width of 110 Gmin was laminated on kraft paper under the conditions shown in Table 7-1 to obtain a laminate. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 7-1. [Example 7-3] A polyethylene strip resin composition made of 99.3% by weight of the above LDPE (I) and 0.7% by weight of the above-mentioned 1,2-polybutadiene resin was prepared. The polyethylene strip resin composition obtained by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs was printed and used. A laminate molding machine with a width of llGGmin equipped with a 90 mm extruder was laminated on the kraft paper under the conditions shown in Table 7-1. On the other hand, a laminated body was prepared. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 7-1. -8 7-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (M) [Example 7-4] (Please read the precautions on the back before filling (This page) A polyethylene strip resin composition made of 97_0% by weight of the above LDPE (I) and 3 · ®% by weight of the above 1,2-polybutadiene resin was prepared. The obtained polyethylene strip resin composition was placed on the base material layer side, and the LDPE (I) was placed on the cooling rod 32 side. Using the conditions shown in Table 7-1, a laminate having a width of 110 mm was used. The forming machine was co-extruded and laminated on kraft paper to obtain a laminated body composed of three layers of LDPE (I) / LDPE (I) + 1,2-polybutadiene resin / base material. Evaluate smoke generation during manufacturing and measure the adhesion strength between the resin layer (L D P E (I) / L D P E (I) + 1,2-polybutadiene resin) and the base material. The evaluation results are shown in Table 7-1. [Comparative Example 7-1] Only the above LDPE (II) was laminated on a kraft paper under the conditions shown in Table 7-1 using a lamination molding machine having a width of 1100 mm equipped with a 9Gmm extruder, to obtain a laminated body. The smoke condition at the time of manufacture was evaluated, and the adhesion strength between the layers of the laminated body obtained was measured. The evaluation results are shown in Table 7-1. [Comparative Example 7-2] Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, a polyethylene strip resin composition made of 99.95% by weight of the above LDPE (II) and 0.05% by weight of the above 1,2-polybutadiene resin . Using the obtained polyethylene strip resin composition, a lamination molding machine equipped with a 90 mm extruder with a width of 110 mm was laminated on the kraft paper under the conditions shown in Table 7-1 to obtain a laminate. body. Evaluation of smoke generation during manufacturing and measurement of the interlayer of the laminated body -8 8-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7

V. Description of the invention (W table if the evaluation and evaluation ο --- degree? Strong 7 5 cases are more sticky b only f shows that there are equipment on the machine to use a wide machine to squeeze paper cows at 0 The indication of the stratified accumulation of oxygen and stink is not shown in Figure 1. The 7-tree surface is melted with molten rid, but the machine is in shape. Shape. The layered layered layered layered layered layer is successfully obtained. 1 Estimation and evaluation system at the end of the smoke-like fruit. ○ Evaluation of iM 6U. Evaluation of the forced progress of the French side. Evaluation of the time of the strength of the sticky paper and the tree. One peeling. The ground-level solid layer evaluation is based on the layered material from the quasi-cheng base group C to evaluate the stripping of the Zhili strong evaluation tree. Juqing Xiaoyi's basic description and the silk can not be controlled. The paper is pulled a little bit with a paper ... and there is: and, © not < 1 > < Kuan Zhi (Please read the precautions on the back before filling this page) Ministry of Economic Affairs Printed by the Intellectual Property Bureau Staff Consumer Cooperatives This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297) (B) 553991 A7 project example printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs bb Comparative Example 7-1 7-2 7-3 7-4 7-1 7-2 7-3 ⑷Component name LDPE (I) LDPE ( II) LDPE (III) (A) component MFR (190 ° C) (g / 10min) 8.5 20 8.2 名 component name EPDM 1,2-polybutadiene-1, 2-polybutadiene-1 (B) component MFR (g / lOmin) 3.0 (230 ¾ 3.0 (150 ° 〇-3.0 (150 ° 〇- (B) the number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 70 250 — 250 one (B) component amount 2.0% 2.2¾ 0.7¾ 3.0% 0 0.05¾ 0 The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 2 5.5 2.3 8 0 0.13 0 Single / co-extruded single-layer co-extruded single-layer base material kraft paper Kraft paper forming temperature (° c) 250 250 320 forming speed (m / min) 300 300 350 air gap (leg) 130 130 140 film thickness Um) 20 20 20 corona treatment 7KW 7KW 7KW ozone treatment with or without adhesive strength ® @ A ® XX △ Fuming aaaaaa C Odor treatment conditions: 50g / m 3 -4.5m 3 / hr -90- (Please read the precautions on the back before filling this page) This paper size applies to Chinese national standards (CN S) A4 specification (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 ---------V. Description of the invention Compared with Comparative Example 1 lacking the (B) component, all the examples using the (B) component can be sufficiently adhered to the substrate. When the number of unsaturated bonds in the molecule of Comparative Example 2 is small, the effects of the present invention cannot be exhibited. In Comparative Example 3, by increasing the molding temperature, although the adhesion strength can be changed somewhat, the odor is strong and the smoke is much. § Examples of operating sheet [Example 8] Each of the following examples and comparative examples uses the following resin components. PP: Polypropylene with a melt flow image (230 ° C) of 35 g / lflinin. 8 (1): 1,2-polybutadiene resin with a melt flow rate (150 ° 0) of 9.08 / 1101 ^ 11. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. P B (II): 1,2-polybutadiene resin with a melt flow coefficient (150 ° C) of 9.0 g / 10iBin. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. [Example 8-1] A polypropylene strip resin composition made of 92% by weight of PP and 8.8% by weight of PB (I) was prepared. The number of unsaturated bonds in the molecule of 103 sulfone in the obtained polypropylene strip resin composition was determined by infrared analysis (IR). Using a laminated molding machine having a width of llDOmm with a 90 mm extruder, ozone treatment was applied to the resin layer in the molten resin film state formed from the obtained polypropylene strip resin composition as shown in FIG. The conditions shown in Table 8-1 were laminated on a high-quality paper (130g / m2) 12 to which an electric treatment was applied to obtain a laminated body. To evaluate the smoke status at the time of manufacture and to measure the interlayer of the laminated body-9 1- The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) I ---------- · Install -----.--- Order ---- r ---- (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 553991 A7 _B7_ V. Invention Explain the adhesive strength of (M). The evaluation results are shown in Table 8-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation panel. The obtained operation sheet was embossed to a sufficient degree, and remained embossed and had sufficient heat resistance. [Example 8-2] A polypropylene strip resin composition made of 99.0 weight SS of the above-mentioned PP and 1.0 weight% of PB (I) was prepared. Using the obtained polyethylene strip resin composition, a lamination molding machine having a width of 1100 mm equipped with a 90 mm extruder was laminated on kraft paper under the conditions shown in Table 8-1 in the same manner as in Example 8-1. Get laminated. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 8-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation sheet. The obtained operation sheet was embossed to a sufficient degree, and remained embossed and had sufficient heat resistance. [Example 8-3] A polypropylene fluorene resin composition composed of 90% by weight of the PP and 10% by weight of the PB (I) was prepared. The obtained polypropylene strip resin composition was on the side of the base layer 13 and the above-mentioned PP was on the side of the cooling rod 32. Using the conditions shown in Table 8-1, a laminated molding machine having a 90 mm extruder with a width of 110 mm was used. Laminated layers were co-extruded to produce a laminated body consisting of three layers of PP / PP + PBU) / base material. -9 2-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) --------- ίιφ > ^ ---- 1 (Please read the notes on the back before filling (This page) Order --------- M9Ι 553991 A7 _B7 _; _ V. Description of the invention () Evaluation of smoke generation during manufacturing and determination of resin layer (PP / PP + PB (I))) and base layer Adhesive strength between materials. The evaluation results are shown in Table 8-1. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the residual layer d. The extruded part II, the system of the II.mm strips are 00 on the top, the bottom 1, the body of the paper, the 11th of the 90 paper flowers, the 00th of the upper layer. For the mass pressure range of 11 paper products, the thickness of the leather is 1 layer. The job is wide. 1¾ Use the 8-layer mechanism added to the shown el to make the table. The hemming place is prefabricated to the machine layer for 5S, and the pressure of the extruded part is determined by pressure. The hematocrit measures 1.0 objects, and the mm stink is measured on the extruded part and 8-ο machine. And 190 pre-to-mm strip condition table group shape 8- shows the application part 90 shape like M material fat layered condition table is not filled with indicator fruit-ha into the tree layered smoke such as with 1 fat in. The result of the preparation of the set of knots is 8-tree body, with a ratio of 1% to 1% of the production of fatty alkenes to make the surface melt-SB) The laminate is charged at 8 when the II tree is 2mm, and the estimated time is by melting. The jj I productiveness makes the table. 51 reviews on I00 (I, but it should be used as a hot 1PP 11-paper C1PP machine with a system of 1.9ene. In. Operation resistance -1, Evaluate strong -299 propyl is a quality evaluation -3, shape, board And ^ 18 on the machine. Commenting on J8 by Jusuo Kuan and evaluating strong J8. After layering, the film can be made to make the body stick. B is used to carry B. The layer is made to be pressed. Br is only layered b. ® Adjusted to make the machine layer sticky U only accumulates: ^ The system of tb that is condensed in the layer 4 (please read the precautions on the back before filling this page) The paper size applies to the Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 553991 A7 B7 V. Description of the invention (9. The stratified layer is obtained. The test results are shown and the condition of the 0-shaped table cigarettes is estimated to be C. Estimation of the degree of sticking to the appraisal force is strong. The appraisal of the appraisal paper with the method of sticking to the sticky formula is consistent with the state of the tree. The evaluation of the ground is based on the solid layer appraisal. Pseudobase group C is estimated to be able to evaluate the peeling strength of the tree. The sticky segment C is the grade of C-shaped core stripping material. Very paper with: Yes :: and, ® No △ X condition fat (please read the precautions on the back before filling this page) ^ 1 ϋ i ^ i mtme I Hal One: 口 、 I ϋ— I n ϋ i ^ i I. Printed by the Intellectual Property Bureau of the Ministry of Economy ’s Consumer Cooperatives This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of Invention (”) Printed by the Intellectual Property Bureau of the Ministry of Economy ’s Consumer Cooperatives Tabulation 8-1 Item Example Comparative Example 8-1 8-2 8-3 8-1 8-2 8-3 (A) Ingredient name PP PP PP PP PP PP (A) Ingredient MFR 35 35 35 35 35 35 (B) Ingredient name 1,2-polybutadiene — 1,2-polybutadiene one (B) component MFR 9.0 (150 ° C) — 3.0 (150 ° C) One (B) component is not intramolecular Number of saturated bonds' (equivalent to 1,000 carbons) 250 — 250 One (B) component amount 8.0% 1.0% 8.0% 0 0.05% 0 Number of unsaturated bonds in the molecule (equivalent to 1,0005 corpses) 20 2.5 20 0 0.13 0 Single-layer / co-extruded single-layer single-layer single-layer co-extruded single-layer single-layer single-layer substrate High-quality paper-to-quality paper forming temperature (° c) 270 270 270 270 270 270 310 Forming speed (m / min) 120 120 120 120 120 120 air Air gap (nun) 110 110 110 110 110 110 Film thickness U m) 40 40 40 40 40 40 Corona treatment 7KW 7KW 7KW 7KW 7KW 7KW Ozone treatment Yes Yes Yes 4jrr Μ Adhesive strength ® △ © XXA a C Ozone treatment conditions: 50g / m3-4.5m3 / hr -95- (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives 553991 A7 B7_ 5. Description of the Invention (94) From the above, it can be seen that the laminated body of this embodiment can exhibit high adhesive strength at a high forming speed and a low forming temperature. In this regard, Comparative Example 1 lacking the (B) component or Comparative Example 2 having a small amount of the (B) component has a low adhesive strength. Further, in Comparative Example 3, which lacks the (B) component and is not treated with ozone, by increasing the molding temperature, the adhesive strength can be improved and smoke may occur. [Example 9] In the following Examples and Comparative Examples, the following resin components β were used

MeP (I): 4-methyl-1 -pentene bar resin with a melt flow rate (260 ° C) of 100 g / lOmin.

MeP (II): 4-methyl-1 -pentene bar resin with a melt flow coefficient (260 ° C) of 80g / 10min. PB (I): 1,2-polybutadiene resin with a melt flow rate (150 ° C) of 9.0 g / 10min. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. PB (II): 1,2-polybutadiene resin with a melt flow coefficient (150 ° C) of 3.0g / 10min. The number of unsaturated bonds in the molecule is 2 5 G / 1 G 3 carbon. [Example 9-1] A 4-methyl-1-pentene strip resin made of 90% by weight of MeP (I) and 10% by weight of PB (I) was prepared. The number of unsaturated bonds in the molecule of 103 in the obtained 4-methyl-1 -pentene stripe resin composition was measured by infrared analysis (I R). Using a laminated molding machine having a width of llGGinin with an extruder, a resin layer in the state of a molten resin film made of the obtained 4-methyl-1 -pentene strip resin composition as shown in FIG. 4 was used. Apply odor treatment to -96- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------------ Order-- ------- (Please read the precautions on the back before filling out this page) 553991 A7 B7_ V. Description of the invention (吣) The conditions shown in Table 9-1 make it laminated on the top-quality paper treated with electricity. (160 g / m 2) above 10 to obtain a laminated body. (Please read the precautions on the back before filling out this page.) Measure the adhesion strength between the layers of the laminate. The evaluation results are shown in Table 9-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation sheet. The obtained operation panel was embossed to an extent that it was sufficiently embossed, and had sufficient heat resistance. [Example 9-2] A 4-methyl-1-pentenefluorene resin composition composed of 98% by weight of the aforementioned MeP (I) and 2.0% by weight of PB (I) was prepared. Using the obtained 4-methyl-1 -pentene strip resin composition, a lamination molding machine having a width of llQGmm equipped with a 9Qmro extruder was used. The conditions shown in Table 9-1 were the same as in Example 9-1. Laminate on top quality paper to make a laminated body. # V. Perform smoke evaluation during manufacturing and measure the interlayer adhesion strength of the resulting laminate. The evaluation results are shown in Table 9-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation sheet. The operation panel printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs has been embossed to the extent that it is fully embossed and has sufficient heat resistance. [Example 9-3] A 4-methyl-1 -pentenefluorene resin composition was prepared from 90 weight SS of the MeP (I) and 10 weight% of the PB (I). -97- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 _B7_ V. Description of the Invention (A) The resulting 4-methyl- The pentene strip resin composition is on the substrate 13 side and the MeP (I) is cooled on the 32 side. Using the conditions shown in Table 9-1, a laminated molding machine equipped with a 90inro extruder with a width of llGGmni is used. The laminate was extruded and laminated on top-quality paper to obtain a laminated body composed of three layers of MeP (I) / MeP (I) + PB (I) / base material. The thickness of the layer made of MeP (I) and the layer made of MeP (I) + PB (I) are both 20 μm. Evaluate the smoke generation during manufacturing and measure the adhesive strength between the resin layer (M e P (I) / M e P (I) + P B (I)) and the substrate. The evaluation results are shown in Table 9-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation sheet. The obtained operation panel was embossed to the extent that it was fully embossed, and had sufficient heat resistance. [Comparative Example 9-1] Only the upper MeP (I) was laminated on a high-quality paper in the same conditions as in Example 9-1 using a lamination molding machine equipped with a 9Gmni extruder and a width of 110 inin under the conditions shown in Table 1. A laminated body was obtained. The interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 9-1. [Comparative Example 9-2] A 4-methyl-1 -pentenefluorene resin composition made of 99.95% by weight of the MeP (I) and 0.05% by weight of the PB (II) was prepared. Using the obtained 4-methyl-1 -pentene strip resin composition, a lamination molding machine having a width of llGOmro equipped with a 90 mm extruder was used to laminate on top-quality paper under the conditions shown in Table 9-1 to obtain a laminate. body. -98- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -----! --- * Order ---- ----- avmw—-553991 A7 B7_ 5. Description of the invention (97) The interlayer adhesion strength of the obtained laminated body is measured. The evaluation results are shown in Table 9-1. (Please read the phonetic notes on the back before filling in this page.) [Comparative Examples 9-3] Use only the above-mentioned MeP (I) with a laminating machine with a 90mm extruder and a width of 1100mm as shown in Table 1. In the same manner as in Example 9-1, a laminated body was prepared by laminating on a high-quality paper. However, no ozone treatment was applied to the molten resin. The interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 9-1. [Evaluation method] [Adhesive strength with paper] The adhesive strength with paper substrates is evaluated based on the conditions at the time of peeling between layers, using the following three-stage evaluation criteria. ®: The paper and the polypropylene strip resin composition layer are firmly integrated, and the resin is not drawn. A: It will peel off a little carelessly. X: It is easy to peel off. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs of the Employees' Cooperatives. The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 Invention Description (9ί Table 9-1. system

Project Example Comparative Example 9-1 9-2 9-3 9-1 9-2 9-3 230 ° C) (g / lOmin) 100 100 100 80 (B) Ingredient name 1,2-polybutadiene-1,2-polybutadiene- (B) Ingredient MFR (g / 10min) 9.0 (150 ° 〇— 3.0 (150 ° 〇 The number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) in one (B) component Number of Saturated Bonds (equivalent to 1000 sulphur) 25 5 25 0 0.13 0 Single layer / coextruded single layer single layer 270 310 Forming speed (m / fflin) 120 120 120 120 120 120 Air gap (M) 110 110 110 110 110 110 Film thickness Um) 50 50 50 50 50 50 Electric treatment 7KW 7KW 7KW 7KW 7KW 7KW 7KW Yes Yes Yes m Adhesive strength © △ © XXA

I

I Order 暦-

I

I Odor treatment conditions: 50g / m3-4.5ro3 / hr Packing • 100 · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7_ V. Description of the invention (99) (please first (Read the notes on the back and fill in this page again.) From the top, it can be seen that the laminated body of this embodiment can exhibit high adhesive strength at a high forming speed and a low forming temperature. In this regard, Comparative Example 1 lacking the (B) component or Comparative Example 2 having a small amount of the (B) component has a low adhesive strength. Further, in Comparative Example 3, which lacks the (B) component and is not treated with ozone, by increasing the molding temperature, the adhesive strength can be improved and smoke may occur. [Example 1] In each of the following examples and comparative examples, the following resin components were used. PP (I): Polypropylene with a melt flow rate (230 ° C) of 40g / 10min. P P (II): Polypropylene with a melt flow pseudo number (230 ° C) of 20 g / 1 0 in i η. L D Ρ Ε: Low density polyethylene with a melt flow vulgar number (190 ° C) of 7 g / 10 m i η. PB ·· 1,2-polybutadiene resin with a melt flow pseudo number (150 ° C) of 9.0 g / 10min. The number of unsaturated bonds in the molecule is 250 per 103 sulfonic acids. 4-Methyl-Pentene Strip Resin: The pseudo-number of the melt flow measured at a load of 250 g k g and 2 60 ° C is 10 Q g / 10 m i η. [Example 1 0-1] Printed and prepared by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of 75% by weight of the above-mentioned PP (I), 10% by weight! Supper PPB, and 15% by weight of the above LDPE polyolefin resin composition . The number of unsaturated bonds in the molecule of 103 sulfone in the obtained polyene strip resin composition was determined by infrared analysis (I R). In addition, a 4-methyl-1 -pentenefluorene resin composition made of 80% by weight of the above-mentioned PP (I) and 20% by weight of a 4-methyl-1 -pentene strip resin was prepared. Use a 9Qmin extruder and 65 «extruder with a width of -10 llQOmin -10 1- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (w ) (Please read the precautions on the back before filling in this page) Co-extrusion laminated molding machine, as shown in Figure 7, the co-extruded polyolefin tobacco rod resin composition and 4-methyl-1 -pentene bar A resin composition was subjected to ozone treatment on an adhesive layer in the state of a molten resin film of a polyolefin resin composition, and was applied to a paperboard (16Gg / m2) 13 subjected to an electric treatment. Lamination was performed under the conditions shown in G-1 to obtain a laminated body. The adhesive strength between the substrate and the adhesive layer of the obtained laminated body was measured, and a peelability test on the surface layer was performed. The evaluation results are shown in Table 1 Q-1. Then, a predetermined embossing is applied to the operation layer of the laminated body to obtain an operation sheet. The obtained operation sheet was embossed to an extent that it was sufficiently embossed and had sufficient heat resistance. [Example 1 0-2] A polyolefin resin composition composed of 84% by weight of the aforementioned PP (I), 1.0% by weight of PB, and 15% by weight of L D PE was prepared. An operating sheet was obtained in the same manner as in Example 1 except that the obtained polyolefin resin composition was used as an adhesive layer. The obtained operation sheet was embossed to an extent that it was sufficiently embossed and had sufficient heat resistance. [Comparative Example 10-1] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A polyolefin resin composition composed of 85% by weight of the aforementioned PP (I) and 15% by weight of the LDPE was prepared. In addition, a 4-methyl-pentene stripe resin composition made of 80% by weight of the PP (I) and 20% by weight of the 4-methyl-1-pentene stripe resin was prepared. Same as in Example 1 0-1, the obtained polyolefin resin composition-1 0 2-This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Consumption by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative 553991 A7 B7_ V. Description of the invention I) As an adhesive layer, a 4-methyl-pentene strip resin composition was used as a surface layer, which was laminated on a board to obtain a laminated body. [Comparative Example 1 0-2] A polyolefin resin composition composed of 84.95% by weight of PP (I), 0.05% by weight of the PB, and 15% by weight of the LDPE was prepared. In addition, a 4-methyl-pentenefluorene resin composition composed of 80% by weight of the PP (I) and 20% by weight of the 4-methyl-1-pentene strip resin was prepared. In the same manner as in Example 10-1, a polyene strip resin composition was used as an adhesive layer, and a 4-methyl-1-pentene strip resin composition was used as a surface layer, which was laminated on a board to obtain a laminated body. [Comparative Example 10-3] A polyolefin resin composition composed of 85% by weight of the aforementioned PP (I) and 15% by weight of LDPE was prepared. In addition, a 4-methyl-1-pentene strip resin composition made of 80% by weight of the PP (I) and 20% by weight of the 4-methyl-1-pentene fluorene resin was prepared. Same as in Example 10-1, a polyene strip resin composition was used as the adhesive layer, and a 4-methyl-1-pentene strip resin composition was used as the surface layer. The lamination temperature was 30 ° C. On the board, a laminated body was prepared. [Comparative Examples 1 to 4] A polyolefin resin composition composed of 80% by weight of the PP (II) and 20% by weight of the LDPE was prepared. The polyolefin resin composition was laminated on a board to obtain a laminate. [Evaluation method] [Adhesive strength with paper] -103- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page) • 丨 丨丨 h ---- Order · --------. 553991 A7 _B7_ V. Description of the invention) The adhesion strength with the paper base material is caused by the condition of the interlayer peeling operation, and the following three stages of evaluation criteria are used. Be evaluated. ®: The paper and the polypropylene strip resin composition layer are firmly integrated, and the resin is not drawn. A: It will peel off a little carelessly. X: It is easy to peel off. [Peelability test of the surface layer] A urethane slurry having a thickness of 100 # m was coated on the surface layer, and heat-treated at 130 ° C for 1 minute, and then cooled to normal temperature. Peel strength of urethane film (g / 3Qmin width). (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -104- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991

7 7 AB V. Description of invention (w) Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, a comparative example of the project 10-1 10-2. 10-1 10-2 10-3 10-4 Table composition surface 4-- Methyl-1-pentene strip resin 20¾ 20% — Layer polypropylene 80% 80% — (A) Ingredient name PP PP PP Viscosity μ) Ingredient MFR (230 ° C) (g / 10min) 40 40 20 (B) Ingredient name 1,2-pinebutadiene-1,2-polybutadiene-_ (B) Ingredient MFR (g / 10min) 9.0 (150 ° 〇-9.0 (150 ° 〇-BI component) Num_ ramm loam) 250 one 250 — one layer (B) 10.0 ¾ 1.0 ¾ 0 0.05% 0 0 in the bowl of the puzzle 25 2.6 0 0.13 0 0 forming temperature of substrate paperboard paper (° c) 270 270 305 305 Forming speed (ffl / fflin) 150 150 150 150 Air gap (mm) 110 110 110 110 Film thickness Um) One ~ ~ ~ One 40 Surface layer (# m) 15 15 15 — Adhesive layer (# ffl) 25 25 25 One Electrolytic treatment 7KW 7KW 7KW 7Ktf Ozone treatment with fyn? M Anr m Adhesive strength @ XX Δ A 7 7 7 7 12 70 Ozone treatment conditions: 5Gg / m3-4.5in3 / hr ----- ------ install ----- ： --- IT --------- (Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) 553991 A7 ___B7_ 5. Description of the invention From Table 10, it can be seen that the operating sheet of this embodiment can exhibit high adhesive strength at a high forming speed and a low forming temperature, and even if only a small amount of 4-methyl- The 1-pentene strip resin can still be easily peeled from the polyurethane film. In this regard, Comparative Example 1 lacking the (B) component in the adhesive layer, or Comparative Example 2 having a small blending amount of the (B) component, had low adhesive strength. In addition, in Comparative Example 3, which lacks the (B) component and is not treated with ozone, by increasing the forming temperature, although its adhesive strength can be improved to some extent, there will be smoke. In addition, in Comparative Example 4, by increasing the molding temperature, although the molding temperature can be improved to some extent, there is smoke, and the lack of the 4-methyl-1-pentene strip resin component makes the urethane coating Peel strength is improved. § Examples of needles for packaging materials [Example 11] In each of the following examples and comparative examples, the following resin components were used. LDPE (I): High-pressure free radical low-density polyethylene with a melt flow pseudo-number (19G ° C) of 20g / 10min and a density of 0.918g / cin3. LDPE (II): High-pressure free radical method low-density polyethylene with a melt flow rate (19G ° C) of 8.2g / 10min and a density of 0.918g / cm3. 1,2-polybutadiene resin. · The melt flow coefficient (150 ° C.) is 3.0 g / 10 m i η. The number of unsaturated bonds in the molecule is 250/103. [Example 1 1-1 and 1 1-2] A polyethylene strip resin composition made of 95.0 wt% of the above-mentioned LDPE (I) and 5.0 wt% of a poly1,2-polybutadiene resin was prepared. -1 0 6- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (please read the note on the back before filling in this page) —BBi i ^ i · ϋ · ϋ h I ϋ n ϋ 1 1 a— I _ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 _B7 V. Description of the invention) The infrared ray method (IR) was used to determine the carbon dioxide in the polyethylene strip resin composition. Number of unsaturated bonds in the molecule. Using a laminated molding machine having a width of llGGinni equipped with a 9Gmni extruder, ozone treatment was applied to the resin layer in a molten resin film state formed from the obtained polyethylene strip resin composition as shown in FIG. 9, and the following The conditions shown in the table were laminated on the substrate 12 to obtain a laminated body. In Example 1, an aluminum foil was used, and in Example 2, a polyimide film treated with electrofluoride was used as the base material 12. The smoke condition at the time of manufacture was evaluated, and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 1b1, 11-2. In addition, a high-pressure radical method low-density polyethylene was laminated on the resin layer as a sealant to obtain a packaging material. The obtained packaging material is non-breathable and suitable for packaging. In addition, it is odorless and can be applied to food packaging materials or medical packaging materials. [Example 1 1-3, 1 1-4] A polyethylene strip resin composition made of 99.0% by weight of the above LDPE (I) and 5.0% by weight of 1,2-polybutadiene resin was prepared. Using the obtained polyethylene fluorene resin composition, a laminate molding machine having a width of llGGinin equipped with a 90 mm extruder was used to laminate on the substrate under the conditions shown in the following table to obtain a laminate. In Example 3, an aluminum foil was used, and in Example 4, a polyimide film treated with an electrofluoride was used as the base material 12. The smoke condition at the time of manufacture was evaluated, and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Tables 1-1 and 1 1-2. -107- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Printed on the Intellectual Property of the Ministry of Economic Affairs, the Consumer Cooperative of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 553991 A7 B7_ V. Description of the Invention (1) In addition, high-pressure free radical low-density polyethylene was laminated on the resin layer as a sealant to obtain packaging materials. The obtained packaging material is non-breathable and suitable for packaging. In addition, it is odorless and can be applied to food packaging materials or medical packaging materials. [Example 1 1-5, 1 1-6] A polyethylene fluorene resin composition made of 95.0% by weight of the above LDPE (I) and 5.0% by weight of the above 1,2-polybutadiene resin was prepared. The obtained polyethylene fluorene resin composition was placed on the base material layer side, the LDPE (I) was placed on the cooling roll 32 side, and the conditions shown in the following table were used to form a laminate having a width of llGGmin equipped with a 9Ginin extruder. The laminate was co-extruded by a machine to obtain a laminated body composed of three layers of LDPE (I) / LDPE (I) + 1,2-polybutadiene resin / base material. In Example 5, an aluminum foil was used, and in Example 6, a polyimide film treated with electrofluoride was used as the base material 12. The smoke condition at the time of manufacturing was evaluated, and the adhesive strength between the resin layer (L D P E (I) / LDPE (I.) + 1,2-polybutadiene resin) and the substrate was measured. The evaluation results are shown in Table 1 and Tables 1 and 1 1-2. In addition, a high-pressure radical method low-density polyethylene was laminated on the resin layer as a sealant to obtain a packaging material. The obtained packaging material is non-breathable and suitable for packaging. In addition, it is odorless and can be applied to food packaging materials or medical packaging materials. [Comparative Example 11-1, 1 1 _ 2] Only the LDPE (II) was laminated on a base material using a lamination molding machine having a width of 1100 mm equipped with a 9ϋηι extruder under the conditions shown in the following table,- 1 08- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau 553991 A7 B7_ V. Description of Invention (, .7) A multilayer body was made. Comparative Examples 1 to 1 used aluminum foil, and Comparative Examples 1 to 2 used a polyamide film as the base material 12. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Tables 11-1 and 11-2. [tb Comparative Examples 11-3 and 11-4] A polyethylene fluorene resin composition made of 99.95 wt% of the above LDPE (II) and 0.05 wt% of the above-mentioned 1,2-polybutadiene resin was prepared. Using the obtained polyethylene strip resin composition, a laminated molding machine having a width of 1100 mm equipped with a 90-millimeter extruder was laminated on the substrate under the conditions shown in the following table to obtain a laminated body. Comparative Examples 1 to 3 used aluminum foil, and Comparative Examples 1 to 4 used a polyamide film as the substrate 12. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Tables 11-1 and 11-2. [Comparative Examples 11-5, 11-6] Only the upper L · DPE (II) was used with a lamination molding machine having a width of 110 mm with a 9 G mm extruder, and the conditions shown in the following table Laminated on a substrate to obtain a laminated body. However, the molten resin was not subjected to ozone treatment. Comparative Examples 1 to 5 used aluminum foil, and Comparative Examples 1 to 6 used a polyamide film as the substrate 12. The smoke generation at the time of manufacturing was evaluated and the interlayer adhesion strength of the obtained laminated body was measured. The evaluation results are shown in Table 1 and Tables 1 and 1 1-2. [Evaluation method] -1 0 9- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ί------------------- ^- --------- (Please read the precautions on the back before filling in this page) 553991 A7 _B7_ V. Description of the invention (,. 〇 [Adhesive strength] Cut the obtained laminated body wide toward the direction of flow of the laminated body A 15mm booklet, using a universal tensile tester (manufactured by Orientec), peeled off the interface between the substrate and the resin layer (90 ° peeling, peeling speed: 30 Omm / min), and observed the adhesive strength (Please read the note 3 on the back before filling out this page.) Packing ----- &1; 1 $, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ο This paper size applies the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) 553991 A7 _B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (7) Table 11-1 Project Example Comparative Example 11-1 11-3 11-5 11-1 11-3 11-5 (A) Ingredient name LDPE (I) LDPE (I) LDPE (I) LDPE (II 1 (A) Ingredient MFR (190 ° C) (g / lOmin) 20 20 20 8.2 1 — (B) Ingredient name 1,2 -Polybutadiene-1,2 Butadiene — J, '; (B) component MFR (g / 10min) 3.0 (150 ° 〇-3.0 (150 ° C) —: • J (B) the number of unsaturated bonds in the molecule (equivalent to 1000 sulfonate ) 250 one 250 one; * > (B) component content 5.0% 1.0¾ 5.0% 0 0.05% 0 number of unsaturated bonds in the molecule (equivalent to 1000 carbons) 12.5 2.6 12.5 0 0.13 0 single layer / coextrusion Single-layer single-layer co-extrusion single-layer substrate aluminum foil aluminum foil forming temperature (° c) 280 280 280 280 280 320 forming speed (m / min) 200 200 200 200 200 200 air gap (M) 120 120 120 120 120 120 Film thickness (# m) 30 30 30 30 30 30 Odor treatment Yes Yes Yes 4irr m Adhesive strength 390 250 380 40 40 200 Odor AAAAAC Fumes 3. aaa C Ozone treatment conditions: 50g / m3-4.5m3 / hr -ill- Crack—I—Order: —'----- ΜΨ. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 V. Description of the invention (u Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau 11-2 Project Example bb Comparative Example j 11-2 11-4 11-6 11-2 11-4 11-6 1 (A) Name LDPE (I) LDPE (I) LDPE (I) LDPE (II (A) Ingredient MFR (190 ° C) (g / lOmin) 20 20 20 8.2 i (B) Ingredient Name 1,2-Polybutadiene— 1,2-polybutadiene-J (B) component MFR (g / 10min) 3.0 (150 ° 〇-3.0 (150 ° C) — &•; • (B) the number of unsaturated bonds in the molecule (equivalent) At 1000 sulphur) 250 one 250 one (B) 5.0% 1.0% 5.0¾ 0 0.05% 0 Number of unsaturated bonds in the composition (equivalent to 1000 carbons) 12.5 2.6 12.5 0 0.13 0 single layer / coextrusion Single-layer single-layer co-extrusion single-layer single-layer single-layer substrate Nylon film Nylon film Forming temperature (° c) 280 280 280 280 280 320 Forming speed (ffl / min) 200 200 200 200 200 200 Air gap (M ) 120 120 120 120 120 120 Film thickness Um) 30 30 30 30 30 30 Electro-radiation treatment 7KW 7KW 7KW 7KW 7KW 7RW Ozone treatment Yes Yes Yes Fnr Chick adhesion strength 870 500 850 50 50 200 Odor AAAAAC Smoke aaaaac IIII Ozone treatment conditions: 50g / m3-4.5m3 / hr • 112 · The size of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 5 53991 A7 " ------- B7 _ 5. Description of the invention (",) (Please read the precautions on the back before filling this page). In the laminated body of this embodiment, the base material is an aluminum foil or a polyamide film, which can exhibit high sticky strength at a high forming speed and a low forming temperature. In this regard, Comparative Examples 1 and 2 lacking the (B) component or the number of unsaturated bonds in the molecule are smaller than Comparative Examples 3 and 4 and have low adhesive strength. In addition, in Comparative Examples 5 and 6 that lacked the (B) component and were not treated with ozone, by increasing the forming temperature, although the adhesive strength could be improved, smoke generation and ozone were produced. [Example 1 2] In each of the examples and comparative examples below, the following resin components were used. LDPE (I): A high-pressure free radical method low-density polyethylene having a melt flow rate (191TC) of 20 g / 10 min and a density of 0.918 g / cm3. PB: 1,2-polybutadiene resin with a melt flow rate (150 ° C) of 3.0 g / 10min. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. [Example 1 2-1] A polyolefin resin composition composed of 95% by weight of LDPE and 5.0% by weight of the PB was prepared. The number of unsaturated bonds in the molecule of 103 obtained in the obtained polyolefin resin composition was determined by infrared analysis (IR). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, using a laminate molding machine with a width of llQGfflia and a 90mm extruder and 65ιη «ι extruder. Co-extruded with the upper LDPE, and applied ozone treatment to the resin layer in the state of a molten resin film made of a polyolefin strip resin composition, and made it into a PET film 10 with aluminum vaporized. The conditions shown in Fig. 1 were laminated on the surface 1 of the steam-melted surface, which was treated with electricity. PET / Polyene-113 was produced by aluminum evaporation. This paper size is in accordance with China National Standard (CNS) A4 (210 X 297). (Mm) 553991 A7 _B7_ V. Description of the invention (Heart) 糸 Packaging material composed of resin composition layer / LDPE layer. (Please read the precautions on the back before filling out this page.) Measure the adhesion strength between the gas barrier layer and the resin layer of the obtained packaging material, and evaluate the odor. [Example 1 2-2] A polyolefin strip resin composition composed of 99.5% by weight of the above LDPE and 5.0% by weight of PB was prepared. A packaging material for food and medical was obtained in the same manner as in Examples 1 to 2 except that the obtained polyolefin resin composition was used as the resin layer. [Example 1 2-3] The same procedure as in Example 1 2-1 was carried out except that a chlorinated vinyl-coated biaxially stretched polypropylene (K-coated OPP) was used instead of the aluminum-evaporated PET film. Food and medical packaging materials. [Comparative Example 1 2-1] A food and medical packaging material was obtained in the same manner as in Example 1 2-1 except that LDPE was used instead of the prepared polyolefin resin composition. [Comparative Example 1 2-2] A polyolefin resin composition composed of 99.9% by weight of the above LDPE and 1% by weight of the PB was prepared. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives for the production of materials and materials for the purpose of grouping. RW tree stripe polymerization. This material is used to make the packaging of the same phase. S The above-mentioned method is used to make the layering and squeezing in the same phase when the temperature is not exempliated and the temperature is formed. The material is packaged for treatment. The paper dimensions are applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 553991 A7 _B7 V. Description of the invention ("々" [Evaluation method] [Adhesive strength with gas barrier layer] Cut the obtained laminated body in the direction of the flow of the laminated body into a short 15 mm wide booklet, use universal Tensile testing machine (manufactured by Orion Dick) to peel off the interface between the substrate and the resin layer (peeling at 90 °, peeling speed is 3QGrnm / min), and observe the adhesive strength. (Please read the note on the back? (Fill in this page again) -Packing ------- Order ----------- · Printed on paper by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economy Standards for Chinese papers (CNS) A4 (210 X 297) Mm) 553991 A7 B 7 V. Description of the Invention (μ) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 12-1 Example Comparative Project 12-1 12-2 12-3 12-1 12-2 12-3 Level 1 LD LD LD LD LD LD Layer 2 LD + PB LD + PB LD + PB LD LD + PB LD Layer 3 A1 vaporized PET K Coated OPP A1 vaporized PET LD MFR (g / 10min) 20 20 20 20 20 20 Look at PB (g / 10min) 3 3 3 — 3 II in uni mm Addition of PB (wt%) 5 0.5 5 0 0.1 0 The amount of unsaturated groups in the composition (10/10 carbon) 12.5 1.25 12.5 0 0.25 0 Layer thickness (#ffl) First layer 10 10 10 10 10 10 Second layer 10 10 10 10 10 10 Formation temperature (° c) 270 270 270 270 270 300 Formation speed (ni / niin) 200 200 200 200 200 200 Electrolytic treatment 7KW 7KW 7KW 7KW 7KW 7KW 7KW Ozone treatment Yes Yes Yes Yes 315 160 330 50 55 210 Odor AAAAAC Ozone treatment conditions: 50g / m3-6 in3 / hr -116- This paper scale applies to Chinese national standards ( CNS) A4 size (210 x 297 mm) (Please read the precautions on the back before filling this page)

* T · · ϋ —Hi Mmmmf I βΜββ MmmKm mmtB emem ϋ emmmm It I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7-^ ------------ B7 -1 It can be seen that the food and medical packaging materials of this example are made of a laminated body that can exhibit high adhesive sound intensity at a high forming speed and a low forming temperature, and do not have odor, and can be used as food, For medical packaging materials. In contrast, Comparative Example 12-1, in which the (B) component is absent in the resin layer, or Comparative Example 12-2, which has a small number of unsaturated bonds in the molecule, has low adhesive strength. In addition, in Comparative Example 12-3, which lacks the (B) component, by increasing the molding temperature, although the adhesive strength can be improved to some extent, there is smoke and odorous chlorine is generated. § Examples of Containers [Example 1 3] In each of the examples and comparative examples, each resin component of the yoke was used. LDPE (I): a high-pressure radical method low-density polyethylene having a melt flow rate (19CTC) of 20 g / 10 niin and a density of 0.918 g / cm3.

LdPE (II): High-pressure free radical low-density polyethylene with a melt flow pseudo-number (190 ° C) of 8.2 g / 10 inin and a density of 0.918 g / cm3. PB (I): a 1,2-polybutadiene resin having a melt flow rate (150 ° C) of 3.0 g / l () fflin. The number of unsaturated bonds in the molecule is 250 per 103 sulfonic acids. P B (II): 1,2-polybutadiene resin with a melt flow image (150 ° C) of LOg / lOiniii. The number of unsaturated bonds in the molecule is 250 per 103 sulfonic acids. [Example 1 3-1] A polyolefin resin composition composed of 95 wt. S! Loading LDPE (I) and 5.0 · wt. Loading PB (I) was prepared. -117- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------ 丨 丨 丨 丨 丨 -------- Order ------- 1 (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 _B7 V. Description of the invention () Infrared analysis method (I β) is used to determine the obtained polyolefin resin composition The number of unsaturated bonds in the molecule of sulphur 103. A lamination molding machine having a width of llGGmin having a 9 (3ηιη) extruder and a 65mni extruder was used to coextrude the obtained polyolefin resin composition with the above-mentioned LDPE (I) as shown in Fig. 11 And apply ozone treatment to the resin layer in the state of a molten resin film made of the polyolefin strip resin composition, so that it is laminated on the paperboard to which electrolysis is applied under the conditions shown in the inner layer in Table 13-1 ( Laminated body (inner layer) was prepared at 260 g / m2) 10. In addition, the obtained polyolefin resin composition was co-extruded with the above LDPE (I) using the obtained polyolefin resin composition in the same manner as the upper substrate for the inner layer substrate. And apply ozone treatment to the resin layer in the state of the molten resin film made of the polystyrene resin composition, and laminate under the conditions shown in Table 1 3-2 and the outer layer, as shown in FIG. 10 to obtain a laminated body (Inner layer (surface layer / resin layer / base material) + outer layer (resin layer / surface)), that is, LDPE (I) / LDPE (I) + PB / substrate / LDPE (I) + PB / LDPE (I) A laminated body composed of 5 layers. The adhesion strength between the base material 10 and the resin layers 12 and 14 of the obtained laminated body was measured, and the development of the laminated body was evaluated. In addition, this laminated body was used to manufacture food and medical containers. The odor generated from the containers was evaluated. [Example 1 3-2] 99% by weight of the LDPE (I) and 1.0% by weight were prepared. Polyolefin strip resin composition made of PB. Except that the obtained polyolefin strip resin composition was used as the resin layer, a laminated body food and medical container was prepared in the same manner as in Example 1-3. -1 1 8 -This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -.------- Order -------- 1 · (Please read the note on the back? Matters before (Fill in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7 V. Description of the invention (π) [Examples 1 3-3] Modulated by 95 · 0% by weight LDPE (I), 5.0% by weight的 Polyolefin strip resin composition made of PB (II). Except that the obtained polyolefin strip resin composition was used as a resin layer, a laminate and a food and medical container were prepared in the same manner as in Example 13-1. [Comparative Example 1 3-1] An inner layer was obtained in the same manner as in Example 1 3-1 using only the above-mentioned LDPE (I). In addition, only the same was used. The above-mentioned LDPE (I) is laminated on an outer layer to obtain a laminated body composed of LDPE (I) / LDPE (I) / base material / LDPE (I) / LDPE (I). [Comparative Example 1 3-2] A polyolefin resin composition composed of 99.95% by weight of the above LDPE (I) and 0.05% by weight of the PB was prepared. Using this polyolefin resin composition, in the same manner as in Examples 1 to 3, a laminated body composed of an inner layer and an outer layer was obtained. [Comparative Example 1 3-3] Using only the above-mentioned LDPE (I), a lamination molding machine equipped with a 91ηιπ extruder with a width of 1 1 0 Q min was laminated on the conditions shown in Table 1 3-1 to obtain A laminated body (inner layer), and similarly, LDPE (II) was used for the base material of the inner layer to obtain a laminated body composed of three layers: LDPE (II) / base material / LDPE (II). [Evaluation method] [Adhesive strength with paper] Adhesive strength with paper substrate is the same as when performing interlayer peeling operation -1 1 9- This paper size applies to China National Standard (CNS) A4 (210 X 297) Li) (Please read the notes on the back before filling in this page)

553991 A7 B7 V. Description of the invention (The tree and the body are evaluated to form a solid group based on the material. It is estimated that the tree will be peeled off from the tree. Segmental. That is, the detached C-shaped heart is peeled off. The love story is easy to understand, and the paper pull is very easy to use., ^ ··: ， ® No △ X Kuanzhi (Please read the precautions on the back before filling this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of the invention (^) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Table 13-1 Comparative Example Item 13-1 13-2 13-3 13-1 13-2 13-3 (A) Ingredient name LDPE (I) LDPE (I) LDPE (II) (A) Ingredient MFR (190 ° C) (g / 10min) 20 20 8.2 (B) Ingredient name 1,2-polybutadiene1,2-polybutadiene1,2, _ polybutadiene-internal ingredient MFR (g / 10min) 3.0 (150 ° 〇9.0 (150 ° C) — 3.0 (150 ° 〇 One (B) number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 250 250-250 One (B) component amount 5.0¾ 1.0¾ 5.0% 0 0.05¾ 0 molecules in the layer composition Number of unsaturated bonds (equivalent to 1D00 sulphur) 12.5 2.6 12.5 0 0.13 0 Forming temperature (° c) 250 250 250 320 Forming speed (m / fflin) 300 300 Air gap (mm) 160 160 Film thickness (Am ) One — 40 (B) -containing layer 15 One 15 — Stone (B) -containing layer 25 15/25 25 —— Corona treatment 7KW 7KW 7KW Ozone treatment has fyrr m Adhesive Strength ® ® XXA Fuming Si aaaa C Odor treatment conditions: 50g / m3-4.5m3 / hi? -121- ---------- install · ------- order --------- AVMWi ( · Please read the notes on the back before filling this page.) This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 553991 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A7 B7. ^) Table 13-2 Example tb Comparative example item 13-1 13-2 13-3 13-1 13-2 13-3 (A) Component name LDPE (I) LDPE (I) LDPE (II) (A) Ingredient MFR (190 ° C) (g / 10min) 20 20 8.2 (B) Ingredient name 1,2-polybutadiene 1,2-polybutadiene — 1,2-polybutadiene (B) MFR (g / 10min) 3.0 (150 ° 〇9.0 (150 ° C) — 3.0 (150 ° C) Number of unsaturated bonds in the molecule of one (B) component (equivalent to 1000 carbons) 250 250 — 250 One (B) component amount 5.0% 1.0¾ 5.0¾ 0 0.05% 0 Layer composition Number of unsaturated bonds in the molecule (equivalent to 1000 sulphur) 12.5 2.6 12.5 0 0.13 0 Forming temperature (° C) 260 260 320 Forming speed (ffl / min) 300 300 300 Air gap (nm〇160 160 160 Film thickness (# m) — — — — — — 20 — (B) component layer 10 — 10 — Stone (B) component layer 7KW 10/10 10 — Electrical processing 7KW 7KW 7KW 7KW Ozone treatment with or without adhesive strength @ ® XXA Fuming aaaaa C Odor AAAAAC Ozone treatment conditions: 50g / m 3 -4.5m 3 / hr -122- ---------- installation -------- order ---- ----- Ανν— (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 _B7_ V. Description of the Invention (^) From Table 1 3-1 and 1 3-2 it can be seen that the food and medical container of this embodiment Speed, at a lower molding temperature can exhibit high adhesive strength of the laminate formed by, with and without odor, can be used as food, medical container persons. From the above, it is understood that the laminated body of this embodiment can exhibit high adhesive strength at a high forming speed and a low forming temperature. In this regard, Comparative Example 1 lacking the (B) component or Comparative Example 2 having a small amount of the (B) component has a low adhesive strength. Further, in Comparative Example 3, which lacks the (B) component and is not treated with ozone, by increasing the molding temperature, the adhesive strength can be improved and smoke may be generated. [Example 1 4] In each of the following examples and comparative examples, the following resin components σ LDPE were used: The melt flow rate (190 ° C) was 2Qg / 10inin, and the density was 0.918g / cm3. Low density polyethylene. PB: 1,2-polybutadiene resin with a melt flow rate (150 ° C) of 3.0 g / 10min. The number of unsaturated bonds in the molecule is 250/103 sulfonic acids. [Example 1 4-1] A polyolefin resin composition composed of 95% by weight of the above LDPE and 5.0% by weight of the PB was prepared. The number of unsaturated bonds in the molecule at 1035 was measured in the obtained polyolefin resin composition by infrared analysis (I R). Using a lamination molding machine with a width of 110 Ginin equipped with a 9 Ginin extruder and a 65 mm extruder, coextrusion of the obtained polyolefin resin composition with the above-mentioned LDPE (I) as shown in FIG. 13, And the composition is made of polyolefin resin-1 2 3-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) ----- --- Order ----- $ Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 553991 A7 B7_ V. Description of the invention (, a) The resin layer in the state of the molten resin film formed by the object is treated with ozone to make it The conditions shown in the inner layer of Table 14-1 were laminated on the paperboard (260g / m2) lG to which electro-repellent treatment was applied to obtain a laminated body 24 as shown in FIG. Then, the obtained polyolefin resin composition and the above PDPE are co-extruded in the same manner, and the resin layer in a molten resin film state made of the polyolefin resin composition is subjected to ozone treatment, and The biaxially stretched Nylon film 18 having been subjected to the corona treatment was laminated on the conditions shown in Table 14-1 to obtain a laminated body 26 as shown in FIG. Then, as shown in FIG. 14, the laminated body 24 obtained as described above is extruded from the extruder 40, the upper laminated body 26 is extruded from the sandwich extruder 44, and the upper part is extruded from the extruder 30.逑 The polyethylene strip resin composition is extruded, and the paper layer 10 of the laminated body 24 and the gas barrier layer 18 of the laminated body 26 are connected to each other. The molten polyolefin strip resin composition is applied to the nozzle rod 34 and the cooling rod. 3 2 was crimped and sandwiched and laminated to obtain a laminated body composed of 7 layers. The adhesion strength between each layer of the obtained laminated body was measured. In addition, this laminated body is used to manufacture food and medical containers. Furthermore, the odor generated from the container was evaluated. [Example 1 4-2] A polyolefin resin composition composed of 99.5% by weight of the above LDPE and 5.0% by weight of PB was prepared. Except that the obtained polyolefin resin composition was used as a resin layer, a laminated body, a food container, and a medical container were produced in the same manner as in Example 4-1. [Example 1 4-3] Except using biaxially stretched EV0H instead of biaxially stretched Nylon film, and -124- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)- ------year! Order! .—— $ (Please read the precautions on the back before filling this page) 553991 A7 _B7 V. Description of the invention (W) The above-mentioned Example 14-1 was prepared in the same manner as the laminated body, food and medical containers. [Example 1 4-4] (Please read the precautions on the back before filling in this page.) Except using aluminum foil instead of biaxially stretched Nylon film, and using laminated body 24 and laminated body 26 together LDPE was prepared at 320 ° C, except that it was a laminate, a food, and a medical container in the same manner as in Example 14-1. [Comparative Example 1 4- 1] In the same manner as in Example 14-1, L D PE was used instead of the polyolefin resin composition prepared as described above to obtain a laminate, a food, and a medical container. [Comparative Example 1 4- 2] Prepared from 99.9% by weight 1 ^ ?, 0.1% by weight above? 8 of the polyolefin resin composition. Using this polyolefin resin composition, a laminate and a container were obtained in the same manner as in Example 4-1. [Comparative Example 1 4-3] LDPE was used instead of the polyolefin resin composition prepared as described above, which was the same as Example 1 4-1 except that the molding temperature during extrusion lamination was 3 1 0 ° C. Laminates, food and medical containers. [Evaluation method] [Adhesive strength with paper] The adhesive strength of printed and paper-based substrates printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs is evaluated based on the following three-stage evaluation criteria based on the conditions of interlayer peeling operations. © ·· The paper and the polypropylene strip resin composition layer are firmly integrated, and the resin is not drawn. △: A little carelessly peels off. -125- This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 _B7 V. Description of the invention (《Κ) X: It is easy to peel off. [Adhesive strength with gas-barrier layer] The obtained laminated body was cut into a booklet with a width of 15 «in the direction of the flowing direction of the laminated body. Using a universal tensile testing machine (made by Orion Dick), the substrate and the substrate were peeled off. The interface of the resin layer (90 ° peeling, peeling speed: 30 Qnim / min), and the adhesive strength was observed. ----------- Install --------- Order --------- AW (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employee Cooperative Cooperative -12 6- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 553991 A7 B7 5. Invention Description 0,) Printed by the Employee Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Example Comparative Example Item 14-1 14-2 14-3 14-4 14-1 14-2 14-3 LD LD 2nd Same as LD + PB LD LD + PB LD No .: ^. 糸 tt Paper No. 4 Chip LD + PB LD + PB LD + PB LD, 2 LD LD + PB LD 5th ONY ONy EVOH A1 ONy ONy ONy 6IB LD + PB LD + PB LD + PB LD + PB LD LD + PB LI) Layer 7 LD LD LD Depleted MFR (^ / IQmin.) 20 2 () PB MFR (g / LOmin.) 3 — 3 One Ρί3 Depleted amount (wt7c) 5 0.5 5 5 0 0.1 0 (Pcs / 103 carbon) 12.5 1.25 12.5 12.5 0 0.25 0 Layer thickness 1st layer 10 10 (/./m) 2nd layer 10 10 4th layer 20 20 6th layer 20 20 7th layer 20 20 Forming temperature (T :) 270 270 310 Forming speed (m / min) 200 2 () () Electron treatment 7KW 7KVV Ozone treatment n Yes-No. 2 adoption strength / paper dust of the adoption strength ◎ △ ◎ XX Δ No. shed / paper waste ◎ △ ◎ ◎ XX Δ Wfmmmm 710 430 680 300 50 55 230 6th obstacle layer 830 520 730 310 60 60 310 Odor and gas Λ AAAA Λ C * 1: 50g / m3-6m ^ r * 2: Laminate 24 and Laminate 26 The temperature of the post is 32 (TC -127- (Please read the note 5 on the back before filling in this page) ▼ Install ----- ^ --- Order ---------. Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 553991 A7 B7 V. Description of the invention (4 in it. The stubborn container is used for medical high-viscosity, medical products, The food can be prepared for the food, and the temperature can be normal, and the application of gas can be a bad smell, and I don't know / > The high level of this expression on the high-level application of the strong accumulation of the 0-dimensional layer of the high-level application of this hair, it can be seen that the temperature above the formation of two cases of less oxygen than the smell of bb It is not very good and the composition is equal to} parts (B is deficient) owing to B / V, or 1 and Example 0, the lower strength of the strong composition is sticky. By borrowing. In the case of Form 3, the smoke is more reasonable than some, and the inner component contains more fatty tree energy bars, which can be added as a fungus to form a group of fatty tree energy bars. The oxygen group of stink fat can be borrowed and polymerized by olefins, but special envoys can be used. The physique forms a kind of layered alienation product, which holds the bond, its peace is especially easy to be saturated, and it is incompatible with strong interlayers. High sexuality is covered by the surface of the body, the shape of the surface, the shape of the brush, and the shape of the body. The HE. T duality treatment of qi and odor is high, it can be lifted, and it can be transformed into time and shape. The layered person is squeezing into a high speed and high temperature (please read the precautions on the back before filling out this page). The Intellectual Property Bureau of the Ministry of Economic Affairs, the employee consumer cooperative, prints low-yield cigarettes, thinking that it will be issued due to cocoa. The degree of control is strong and the shape can be sticky. The shape of the shape can be maintained and the temperature can be lowered. The reason is that the film is used for exercise / the body is peeled. Each side is responsible for the use of the environment and the environment, food and gas, resistors, containers, packaging materials, medical packaging, medical PP, and food. Gas, etc., resistor materials, container materials for medical treatment, treatment, board medicine products. The paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -------- Order -------- · 553991 A7 _B7 V. Explanation of the invention (W) Symbol Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives 10 Stripped substrate 11 Multi-layer synthetic leather 12 Base material 13 Substrate 14 Resin layer 15 Operating layer 16 Release material layer 18 Adhesive layer 2 0 Peeled material 2 2 Peeled substrate 2 4 Peelable laminated body 2 6 Laminated body 28 T-die 3 0 Extruder 3 2 Cooling 锟 34 Roller 3 6 Ozone Supply 38 Electric Discharger 40 Extruder 4 2 Winder 4 4 Sand Extruder -12 9--Loading ---- (Please read the precautions on the back before filling this page) Order ———— — $ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

Members are kindly requested to clarify whether the original substantive content will be changed after the amendment of this case No. 88 1 1 6629 "Patent of Polyene Resin Composition, Its Laminated Body, and Its Manufacturing Method and Application Product Support Sheet" (December 10, 1990) (Amendment) Six applications for patent scope: 1. A polyene-based resin composition comprising 99.9 to 50% by weight of (A) polyene-based resin and 0.1 to 50% by weight of 2 (B) in the molecule. Saturated bond compounds, characterized in that the number of unsaturated bonds in the molecule in the polyolefin resin composition is 0.5 or more per 103 carbons, and (B) the unsaturated molecules in the compound having unsaturated bonds in the molecule The number of bonds is 0.5 to 250 per 103 carbons. 2. The polyolefin resin composition according to item 1 of the scope of patent application, wherein (A) the polyolefin resin is (A1) a polyolefin resin having 3 to 20 carbon atoms. 3. The polyolefin resin composition according to item 1 of the scope of patent application, wherein (B) the compound having an unsaturated bond in the molecule is at least one member selected from the group consisting of polybutadiene, ethylene-propylene-diene copolymer, Polyisoprene. 4. The polyolefin resin composition according to item 1 of the patent application scope, wherein (B) the compound having an unsaturated bond in the molecule is 1,2-polybutadiene. 5. The polyolefin resin composition according to item 1 of the patent application scope, further comprising (C) an epoxy compound. 6. The polyolefin resin composition according to item 5 of the patent application, wherein (C) the epoxy compound is one having two or more epoxy groups in the molecule and having a molecular weight of 3,000 or less. 7. The polyolefin resin composition according to item 5 of the scope of patent application, in which 553991 six 'patent scope of application contains (D) an olefin resin having a functional group capable of reacting with epoxy groups. 8. The polyolefin resin composition according to item 5 of the application, wherein (C) the epoxy compound is an epoxidized vegetable oil. 9 · The polyolefin resin composition according to item 丨 of the patent application scope, which is a resin composition for extrusion lamination molding. 1 ·· A laminated body characterized in that a layer formed of a polyolefin resin composition is provided on at least one side of a substrate, wherein the polyolefin resin composition contains 99.9 to 50% by weight of 2 (A1) carbon Polyolefin resins of 3 to 20 and 0.1 to 50% by weight of ⑶ 丨) compounds with unsaturated bonds in the molecule, and the number of unsaturated bonds in the molecule is 0.5 or more per 103 carbons, and In the compound having an unsaturated bond in the molecule (B), the number of the unsaturated bond in the molecule is 0-5 to 250 per 103 carbons. 11. A laminated body characterized in that a layer formed of a polyolefin resin composition is provided on at least one side of a substrate, wherein the polyolefin resin composition contains (A) a polyolefin resin and (B) molecules Compounds with unsaturated bonds and (C) epoxy compounds, in which the number of unsaturated bonds in the molecule is 0.5 or more per 103 carbons. 12. The laminated body according to item 11 of the scope of patent application, wherein the polyolefin resin composition further contains (D) an olefin resin having a functional group capable of reacting with epoxy groups. 13. —A method for manufacturing a laminated body, which is characterized in that a laminated body made of a polyolefin resin composition is adhered to a base material by extrusion lamination method 553991 6. At least one side of the scope of patent application, wherein The polyolefin resin composition contains (A1) a polyolefin resin having 3 to 20 carbon atoms and (B) a compound having an unsaturated bond in the molecule, and the number of unsaturated bonds in the molecule is 103 carbons per molecule More than 0.5 pieces. 14. A method for producing a laminated body, characterized in that a laminated layer made of a polyolefin resin composition is adhered to at least one side of a substrate by an extrusion laminated method, wherein the polyolefin resin composition contains Among the (A) polyene resin, (B) the compound having an unsaturated bond in the molecule, and (C) the epoxy compound, the number of the unsaturated bond in the molecule is 0.5 or more per 103 carbons. 15. The method for manufacturing a laminated body according to item 14 of the scope of patent application, wherein the polyolefin resin composition further contains (D) an olefin resin having a functional group capable of reacting with an epoxy group. 16. The method for manufacturing a laminated body according to item 13 of the scope of patent application, wherein when the polyolefin resin composition is extruded and laminated by the extrusion lamination method on at least one side of the substrate, the substrate and / or The surface of the film made of the polyolefin resin composition is treated and then adhered through the surface-treated surface. 17. The method for producing a laminated body according to item 16 of the scope of patent application, wherein the ozone-treated polyolefin resin composition and the substrate subjected to corona discharge treatment are laminated through the surface-treated surface. Sticky. 18. For the manufacturing method of laminated body according to item 13 of the scope of patent application, of which, 553991 VI. Range of patent application The forming temperature of extrusion laminated layer is 200 ~ 30CTC. 19. A release substrate, which is a release substrate having a resin layer formed on a base material layer, or a release substrate having a release material layer formed on the base material through the resin layer, wherein the above-mentioned resin layer is (A) A layer formed by a polystrip resin composition and (b) a polyolefin resin composition having a compound having an unsaturated bond in the molecule, and the number of unsaturated bonds in the molecule in the polyolefin resin composition It is 0.5 or more per 103 carbons. 20. The peeling substrate according to item 19 of the application, wherein the polyolefin resin composition further contains (C) an epoxy compound. 21. —An operation panel, which is an operation panel having an operation layer formed on a substrate, characterized in that the operation layer is a compound containing an (A) polyene-based resin and (B) a compound having an unsaturated bond in the molecule. A layer formed by a polyolefin resin composition, and the number of unsaturated bonds in the molecule of the polyolefin resin composition is 0.5 or more per 103 carbons. 22. The operation panel according to claim 21, wherein the polyolefin resin composition further contains (C) an epoxy compound. 23. An operation panel, which is an operation panel with a surface layer formed on the substrate through an adhesive layer, and is characterized in that the adhesive layer system has (A) a polyene-based resin and (B) an unsaturated molecule. A layer formed by a polyene resin composition of a bonded compound, and the number of unsaturated bonds in the molecule of the polyene resin composition is 0.5 or more per 103 carbons; the surface layer is composed of carbons Monomers or copolymers of 3 to 20 olefins or this 553991 VI. Patent application scope and other polyene composition. 24. The operation panel according to item 23 of the scope of patent application, wherein the polyolefin resin composition of the adhesive layer further contains (C) an epoxy compound. 25. A packaging material, which is a packaging material made of a laminate having at least a substrate and a resin layer, characterized in that the resin layer has a (A) polymer-containing resin and (B) an unsaturated molecule. A layer formed by a polyene resin composition of a bonded compound, and the number of unsaturated bonds in the molecule of the polyene resin composition is 0.5 or more per 103 carbons. 26. The packaging material according to item 25 of the patent application scope, further comprising (C) an epoxy compound in the polyolefin resin composition. 27. For the packaging material under the scope of patent application No. 25, there is another sealing layer. 28. The packaging material under the scope of application for a patent No. 25, which further has a gas barrier layer. 29. The packaging material according to item 25 of the patent application, wherein the substrate is made of a gas barrier material. 30. A seed cultivator, which is a container having at least a laminate having a resin layer formed on a substrate, characterized in that the resin layer has a polymer resin containing (A) and A layer formed by a polyolefin resin composition of a saturated bond compound, and the number of unsaturated bonds in the molecule of the polyolefin resin composition is 0.5 or more per 103 carbons. 553991 VI. Scope of patent application 31. The container in the scope of patent application No. 30, wherein the polyolefin resin composition further contains (C) an epoxy compound. 32. The container according to the scope of patent application No. 30, further comprising a gas barrier layer. 33. The container according to the scope of application for patent No. 32, wherein a resin layer / paper layer / resin layer / polyethylene layer is laminated on one side of the gas barrier layer, and the other side of the same gas barrier layer is passed through The resin laminate has a sealing layer.