TW526252B - Solid compositions, their preparation process and their use - Google Patents

Abstract

Solid-state fluorescent composition comprising at least one host chromophore selected from the group consisting of a benzo[4,5]imidazo[2,1-a]isoindo-11-ones and an effective amount of at least one guest chromophore, and if desired a polymer C, wherein the emission spectrum of the host chromophore overlaps with the absorption spectrum of the guest chromophore, and wherein (a1) the host chromophore is covalently linked to a polymer backbone A (""host polymer""), and/or (a2) the guest chromophore is covalently linked to a polymer backbone B (""guest polymer"").

Description

2 5 2 6 2 5 Λ7 Η: A description of the invention printed by a Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (/ 'The present invention relates to a solid composition comprising at least one selected from the group consisting of benzo [4,5] imidazo [2,1-a] Host chromophore of isoindole-1 1-one and an effective amount of at least one guest chromophore 'and, if necessary, polymer C, wherein the emission spectrum of the host chromophore is the same as the guest chromophore The absorption spectra of the chromophores overlap, and (al) the host chromophore is covalently bonded to the polymer backbone A Γ host polymer "), and / or U2) the guest chromophore is covalently bonded to the polymer Main chain B ("guest polymer") Furthermore, the present invention relates to a method for preparing the composition of the present invention and its use as a fluorescent material. EP-AG 4 5 6 6 0 9 discloses an alternative Method for preparing 1,2,3,4-tetrachlorobenzo [4,5] imidazo [2,1-a] isoindole-11-one and its derivatives in the presence of a solvent. They are showing solid-state fluorescence And pigments for improving outdoor durability. 95% 1,2,3,4-benzo [4,5] imidazo [2, bua] isoindolin-11-one and the name% yin are also mentioned in general The combination of Danslin blue produces a green fluorescent pigment. Therefore, the system is a pigment compound, and the new color produced is only the sum of the two simple and large component colors, not the new color produced by the energy transfer method. FW Harris et al. Describe the compound 1,2,3,4-tetraphenyl-benzo [4,5] pyrazolo [2, Bu in ACS Symp. Ser. 132, 39 (19 8 0). a] Isoindazim 1 1-one is used as a mold material, such as the investigation part of phenylated polyoxazolopyrrolidone for their potential use in related research on the application of the aerospace universe. This paper size applies Chinese national standards (CNS) Λ4 specifications (210X 297 public power) Please read the 5 notes first

I 526252 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 _,, _ ^ _ 137____ V. Description of Invention (ス) However, its fluorescent behavior is not mentioned. Historically, observations of energy transfer and sensitized athermal light images were performed by Cario and Frank in the early 1923, and experiments were performed using mercury and plutonium in the vapor phase, Z. PHYZIK 17, 202 (1923). J. Perrin and CR Choucroun performed qualitative observations of energy transfer to solution several years later, HEBD. SEANCES ACAD · SCI., 189, 1 2 1 3 (19 2 9). Although some research was held in those years, it is still Th. Fster The praised work, which describes in the most detail, the phenomena, mechanisms and parameters of energy transfer in quantitative terms is specific to sensitized fluorescence such as Z. PHY ZIK CHEM., 1,275 (1954). Moreover, Frster brought the field of sensitized fluorescence to a broader discussion forum, and later ignited a wider interest, which led to the concept being used in a wider range of applications. For example, in the area of electrofluorescence, Tang et al. Have demonstrated the effectiveness of sensitized fluorescence to create extremely bright electroluminescent devices (J. APPL. PHYS · 65 (9), 3 6 1 0 (1 9 8 9) ) 〇 In the field of biodiagnosis, sensitized fluorescence is also well established as a detection target for specific biomolecules, such as the presence of nucleic acids or antigens, and highly sensitive tools, such as Verner et al., ANAL. BI0CHEM · 198, 3 0 8 (1991) Brinkley et al. Disclose the use of sensitized fluorescence to detect biomolecules, such as DNA and RNA, and polymeric materials that can also be used in flow cytometry and analytical microscopy (W0 9 3/2 3 4 9 2 ). In Brink ley, etc. This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297g t) (Please read the notes on the back first

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V. Description of the invention (3) The patent application (W0 9 3/2 3 4 9 2) of the person reveals the effectiveness of the fluorescent polymer beads in biological diagnosis. However, * the composition which includes the host chromophore and the guest chromophore is not disclosed, as disclosed above, and the validity of the composition outside the special biological application field is not provided. Therefore, an object of the present invention is to provide a solid-state fluorescent composition having a chromophore as a host using benzo [4, 5] imido- [2,1--a] isoindole-11-one as a matrix. It does not show the above-mentioned disadvantages, it is better to provide a composition where i) impart strong solid-state fluorescence, preferably where the emission wavelengths are in the visible region of the electromagnetic spectrum, ii) a high proportion of host and guest molecules can be combined as The polymer part also retains solid fluorescent properties (that is, quenching at a negligible concentration). iii) These substances can be excited in both UV and visible wavelengths, iv) can achieve very good light stability, v) can achieve a wide range of emission wavelengths (color (please read the Precautions

This page) Order-Printed packages and C-bases by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. The combination of color and energy is one of the key words and the transfer of the minor owner. The ketone needs to be covered, the 1-fruit sub-kettle, which is -1, such as the single ingredient, the indole and the group are ind. It becomes m-based 5-fluorene and also al color ·, disintegration, state 1-hair soluble main preparation [2, system will not only produce seeds 1 [ke'an and firefly Yi i thermal release capacity P high Dissolving and draining hair] ^ 少) »Successful product, 5 to the total output is equal to this [4 cocoa} the factor} i) ii} benzene effect iii X f VVV i Including the paper size Applicable to China National Standard (CNS) Λ4 specification (210X297) while 526252 Λ7 137 V. Description of the invention (4 &); solid composition, in which the emission spectrum of the host chromophore and the absorption spectrum of the guest chromophore overlap, and where ( a 1) The host chromophore is covalently bonded to the polymer backbone A ("host polymer"), and / or (a2) the guest chromophore is covalently bonded to the polymer backbone B ("guest polymerization In addition, a method for preparing the composition of the present invention and its use as a fluorescent material have also been found. The first specific embodiment of the present invention relates to a solid-state composition comprising at least one host chromophore selected from the group consisting of benzo [4,5] oxazolo [2, bua] isoindole-U-one And an effective amount of at least one guest chromophore, and polymer C if necessary. Wherein the emission spectrum of the host chromophore overlaps with the absorption spectrum of the guest chromophore, and where U1) the host chromophore is covalently bonded to the polymer backbone A ("host polymer"), and / or U2) The guest hair chromophore is covalently bonded to the polymer host B ("guest polymer"). This means a solid composition or host hairpin containing a covalent bond to the polymer backbone A (referred to as "host polymer"). A chromophore or a guest chromophore that includes a covalent bond to the polymer backbone B (hereinafter referred to as "guest polymer") or a host chromophore and a covalent bond that includes a covalent bond to the polymer backbone A The guest chromophore bound to the polymer backbone B (the latter is often referred to as a blend or mixture of two polymers). -6- This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297 males) (Please read the precautions on the back first v Loading-Arm this page) Order Printed by the Central Consumers Bureau of the Ministry of Economic Affairs Consumer Cooperatives 526252 A7 B7 V. The invention description printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (s) In the context of the present invention, the significance of the overlap of the absorption spectrum of the guest chromophore and the honey emission spectrum of the host chromophore ' People are clear. However, to help others understand that 'overlap' means 'spectral overlap' defined by the following integrals: S = J:, F (V) / A (v) dv where / F (V), is normalized, so / F ( v :) dv is equal to the fluorescence quantum yield of the subject, and where V is the wave number, the fluorescence spectrum of the subject measured by K quantum, and the spectral distribution of the Moire extinction coefficient of the guest. The overlap with the actual fluorescence enhancement spectrum is usually more than 10, preferably more than 100, more preferably more than 500. Because the amount of "overlap" has no maximum value (ie, the larger, the better), the upper limit is not limited. In a preferred embodiment, the solid composition of the present invention is characterized by uniform distribution of (al) guest hair coloring bases, preferably dissolution and uniform distribution, in a matrix formed by the host polymer, or U2) host hair color The bases are uniformly distributed, preferably dissolved and uniformly distributed, in the matrix formed by the guest polymer, or (b) the host polymer and the guest polymer are blended, preferably uniformly. In the context of the present invention, the term "uniformly" means that the molecules are uniformly or uniformly distributed or dispersed throughout the mixture or polymer matrix, and, preferably, ideally, are substantially at equal distances from each other. According to observations today, a more uniform or even distribution is better fluorescent properties. In addition, all paper sizes are in accordance with Chinese National Standards (CNS) Λ4 specifications (210X 297 cm) (Please read the precautions on the back page 9 π first page) • 燊 · 、 \ >

^ 26252 Λ7, one _ϋζ _____ 5. Invention description (6) or a uniform distribution is better, usually because the chance of gathering is reduced. In the context of the present invention, the term "dissolved" means that the molecule M is free and completely isolated in a given environment or matrix, preferably, without any interaction between molecules of the same species, that is, it is completely bounded by the matrix Way surrounded by molecules. Generally the matrix may be a liquid organic solvent or a solid substance such as a polymer or another fluorescent substance (host), which has a different chemical structure. Limits on the concentration of molecules in the dissolved state generally depend strongly on the associative nature of the molecules and the matrix medium, and / or those cohesive forces that exist between the guest molecules in question. Rather, it is not possible to define the full range of the preferred concentration, and therefore usually must be handled on a special basis, for example by some simple experiments. In a further preferred embodiment, the solid composition is composed of at least one host chromophore and an effective amount of at least one guest chromophore, wherein the emission wavelength range of the host is at least partially heavier than the absorption wavelength range of the guest ( Please read the notes on the back first

(M page)

Dissolve the base color hair, and the main chain of the chain will come together to the bond bond commensal base, and its master \ 1 / > 1 stack of U-Quan Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative prints the solution base hair color body And bpc subject matter or together; together to its knot at the bond cloth price point common ground sentence color is issued and the dissolution of the subject matter is not the same as the bond valence common basis or color; The cloth base color is uniformly distributed and the main cloth is divided into 5, uniform [4, homogeneous and benzene, and mixed with coating and self-selection base poly color and other hair. The body ketone, the main part of the T, and its hydrazone and oxazoline indigo paper size are applicable to the Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) 526252 /, ^ _I_ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 (7) In the viewpoint of the present invention, "host chromophore" means a fluorescent molecule or a fluorescent moiety, preferably selected from or derived from solid fluorescent organic compounds such as dyes, pigments, and their derivatives. Group, K absorbs energy when exposed to the appropriate radiation wavelength in the UV and / or white light region. This energy is sequentially transferred, preferably almost quantitatively, in resonance mode, to the chromophore of the object. In the present invention, the "fluorescent molecule serving as the host chromophore" is also referred to as the host molecule or host monomer. The "fluorescent part which serves as the color base of the subject" is also referred to as the subject part. The main chromophore that is covalently bound to the polymer main chain is the main part while the main chromophore that is dissolved is a free, non-polymeric main molecule. Fluorescent molecules, which serve as the host chromophore used to prepare the composition U2) according to the present invention, are preferably sufficiently dissolved in the preparation medium so that they can help themselves participate in the formation of the composition. Less soluble host chromophores can also be used, however this may require special equipment to continuously dissolve the host compound in the reaction medium. Solubility can be imparted by the choice of core structure, substituents, functional groups and / or the length of the intervals of these functional groups. The structures containing the fluorescent moiety used to prepare the composition according to the invention (either the host polymer alone or blended with the guest polymer) are preferably fully dissolved in the reaction medium, so that they quickly help themselves to be Polymerize; or covalently bind to the polymer backbone or receptor surface via a chemical reaction. The reaction medium may be a comonomer or a suitable solvent. A less soluble host structure can be used, however this may require special equipment to continuously dissolve the host compound in the reaction medium. Solubility can be imparted by the choice of core structure, substituents, functional groups and / or the length of the intervals of these functional groups. -9- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297g t) (Please read the precautions on the back first

Dingquan 526252 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics B7 V. Description of the Invention (δ) In the view of the present invention, the color base of the object indicates that it has at least partial overlap with the emission area of an individual subject in the system Fluorescent molecules or parts of fluorescent light. Among them, these guest chromophores receive energy from the host chromophore, and in turn emit the visible radiant transfer energy, at the same wavelength as the emission wavelength of the same guest chromophore that is molecularly dissolved in the solvent. It further requires that the concentration of the guest chromophores in the composition must be such that they will not combine with each other to form a localized guest domain, but in fact is completely isolated in the polymer body when they are dissolved molecularly. In the present invention, "fluorescent molecules acting as guest chromophores" are also referred to as guest molecules or guest monomers. The "fluorescent part as the color base of the object" is also called the object part. The guest chromophore that is covalently bound to the polymer main chain is the guest part dispersed at the same time. The guest chromophore is the guest molecule or guest monomer. Fluorescent molecules, which are used to prepare the guest chromophores of the composition U1) according to the present invention, are preferably sufficiently dissolved in the preparation medium, so that they can help themselves to participate in the formation of the composition. Less soluble guest compounds may also be used, however this may require special equipment to constantly dissolve the host compound in the reaction medium. Solubility can be imparted by the choice of the length of the core structure, substituents, functional groups, and / or the spacing of these functions. The fluorescent moieties used as guest chromophores for the preparation of the composition according to the invention (either the guest polymer alone or blended with the host polymer) are preferably fully dissolved in the reaction medium so that they quickly help themselves Be polymerized; or covalently bonded to the polymer backbone or receptor surface via a chemical reaction. The reaction medium may be a comonomer or a suitable solvent. Can use less soluble -10- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 2W) while taking advantage of this paper size (Please read the precautions on the back first

(This page) ^ 1 526252 Λ7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () Object structure, however, this may require special equipment to continuously dissolve monomers in the reaction medium. Solubility can be imparted by the choice of core structure, substituents, functional groups and / or the length of the intervals of these functional groups. The fluorescent host / guest composition of the present invention emits solid-state fluorescence with very enhanced emission intensity when compared with the emission intensity of the same composition lacking the host chromophore or the same composition of the solid fluorescence lacking the guest chromophore. 0 The term "enhancement factor", as used herein, is defined as an increase or decrease factor. The peak emission intensity of the solid composition of the present invention is compared with a comparable host chromophore in the absence of a guest chromophore. The comparison is really considered as long as the wavelength of the excitation radiation is the same. Naturally, however, the emission wavelength of the host / guest material occurs at longer wavelengths (lower energy) as compared to the same material without the guest chromophore. The enhancement factors for the present invention are preferably all positive and particularly preferably at least 1.3, more preferably at least about 2 and most preferably at least 20. The maximum fluorescence emission of the fluorescent polymer of the present invention may be in the range of about 400 to about 8 GQ nanometers, preferably about 4 2 0 to about 7 8 0 nanometers, more preferably about 4 2 0 to about 750 Nano. A specific embodiment (a 1) of the present invention relates to a host chromophore and an effective amount comprising at least one member selected from the group consisting of benzo [4, 5] imidazo [2, I-a] isoindole-11-fluorene At least one guest chromophore, and if desired, a solid composition of polymer C, in which the emission spectrum of the host chromophore overlaps with the absorption spectrum of the guest chromophore, and where the host chromophore is covalently bonded to the polymer Main chain A ("host polymer"). -1 1-(Please read the notes on the back first

π This page) Spring paper size is applicable to Chinese National Standards (CNS) Λ4 specifications (210X297g t) printed in 6252 Μ Β7 printed by the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (ID) For use in the composition (a 1) The fluorescent part as the main chromophore is covalently linked to the polymer main chain directly or via a bridging group. The bridging group may contain 1 to 60 atoms, preferably 1 to 3 Q atoms, and preferably 1 to 20 atoms, selected from the group consisting of C, 0, S, and N. The bridging group is particularly preferably a hydrocarbon residue, which may be interrupted by one or more heteroatoms selected from the group consisting of 0, S, N or the group C (O) and / or by one selected from the group consisting of 0, S, Heteroatom termination of N or radical C (0), and it preferably contains a total of 1 to 4 G atoms, more preferably 2 to 30 atoms and particularly preferably 3 to 20 atoms. The fluorescent moiety which is covalently bonded to the polymer main chain directly or by a bridging group as a host chromophore can be represented by K formula II -X 1-(R 1) r- (X 2) s-R3 -Host (II) where Xi and] (2 each independently represent a direct bond, or Xi and Xz each independently represent -S-, -NRz _,-, -〇-c (0)-, -0-C (0 00- , -s〇2 -0-S〇2 -0-S〇2-0-9 -NR2 -C (0)-; -C (0) -NR2 -NRz -C (0) -0 "; 0- C (0) -NRz ^ ^ R2 -C (〇)-NR2 -NRz -S〇2-, -S02-, -NRz _S〇z S〇2 -NR2 -or -NR2 -S〇2 -NR2 'Ri Each independently represents a divalent bridging group. Host represents a monovalent benzo [4, 5] oxo [2, ha] isoindole-1 benzone derivative, and Rz are each independently H, Ci _Ci 2 alkyl, C5 _ Or C6 cycloalkyl, C5 -12- This paper size applies to the Chinese National Standard (CNS) Λ4 size (210x297 cm) (Please read the precautions on the back first, 100-pack ', 1T 526252 Λ7 B7 V. Invention Note (11)-or C6 cycloalkylmethyl or -ethyl, phenyl, benzyl or 1-phenyl-2-ethyl, R3 is each independently a direct hydrazone, Ci-Ci 8 alkylene, c5- Or c6 alkylene, c6 -Cl 0 arylene or C7 -Ci 2 aralkylene. RTABLE The number of 0 or 1 and S represents the number of 0 or 1, but the condition is that S is 0, if r is 0, and X represents the number of 0 or 1, and y represents the number of 0 or 1, but the condition is that y is 0 if X is 0. Throughout the alkyl group, R2 preferably has 1 to 6 and more preferably 1 to 4 C atoms. Some examples are methyl, ethyl, n-propyl or isopropyl, butane Group, pentyl, hexyl and octyl. In this context cycloalkyl R2 is preferably cyclohexyl, in this context cycloalkylmethyl, preferably cyclohexylmethyl. In a preferred embodiment R2 represents 1 or (1-C4 alkyl. The divalent bridging group is preferably a hydrocarbon residue, which preferably contains 1 to 3Q, more preferably 2 to 20, most preferably 3 to 20 and particularly preferably 3 to 18 C atoms, which are unsubstituted or substituted one or more times with Ci-C4 alkyl, Ci-C4 alkoxy, or = 0. The hydrocarbon residue may also be selected from the group consisting of-〇-, and-NR2- The heteroatom is interrupted one or more times, whereby Rz is preferably fluorene or Ci-C4 alkyl. The divalent bridging group may be Ci-c2 0-, preferably C2-Ci 2 alkylene, which may be straight Chain or branch. Some examples are methylene, ethylene, 1,2- or 1,3-propane 1,1,2,1,3- or 1,4-butynyl, pentyl, hexyl, octyl, decyl, dodecyl, tetradecyl, hexadecane -13- This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297 male # :) (Please read the precautions on the back first

Order printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 5. Description of the invention (p) Phenyl and octadecyl. The divalent bridging group may have 2 to 12, preferably 2 to 6, and more preferably 2 to 4 oxyalkylene units, and 2 to 4 in the alkylene moiety, preferably 2 or 3 C Atomic polyoxyalkylene. Particularly preferred are polyoxyethylene and polyoxypropylene groups having 2 to 6 oxyalkylene units. The bivalent bridging group may be Cs -C i 2, preferably C5 -C8-and most preferably C5-or (6 alkylene, such as cyclopentyl, cyclohexyl, cyclooctyl or cyclodeca Dialkylene. The divalent bridging group may be C5 -Ci 2-, preferably C5 -Cs-and more preferably C5-or C6 cycloalkyl-Ci -Ci 2 -alkylene and most preferably C5 -Or%-cycloalkyl-C4-alkylene. Some examples are -cyclopentyl-CnH2n- and -cyclohexyl-CnH2n-, where n is a number from 1 to 4. Particularly preferred is -cyclohexyl- The CHz divalent bridging group may be c5 -Ci 2-, preferably c5 -c8-and more preferably C5-or C6 cyclofluorene- (Ci -Ci 2 alkylene) 2-and most preferably -C4-alkylene )2 . Some examples are cyclopentane- (CnHz n-) 2 and cyclohexane- (Cn

Hz n-) 2, where n is the number from 1 to 4. Especially preferred is -CH2 -cyclohexyl ~ C Η 2-. The divalent bridging group may be a c6 -Ci 4 arylene group and preferably a 0 arylene group, such as a naphthyl group or more preferably a phenylene group. The divalent bridging group may be a c7-C2 0 aralkylene group and a preferred C7-C i 2 aralkylene group. More preferred is arylene-CnH2?-, Arylene represents naphthyl and preferred phenylene, and η represents a number of 1 to 4. Examples are benzylidene and -14- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210x 297 gt) (please read the precautions on the back first d • Installation-explain this page) Order the Central Bureau of Standards of the Ministry of Economic Affairs Printed by employee consumer cooperatives 5% 252 A7 B7 V. Description of the invention (I3 phenylethylene). The divalent coupling group may be aromatic hydrocarbon (CnH2 η-) 2-, of which the aromatic hydrocarbon is preferably naphthalene It is more preferably benzene and η is a number of 1 to 4. Examples are xylylene and benzene (CH2 CHz) 2-. R3 preferably contains 2 to 12 and more preferably 1 to 6 C atoms. Particularly preferred examples are methylene, ethylene, 1,2- or 1,3-propenyl and 1,2-,: I, 3- and 1,4-butynyl. R3 epiaryl The alkylene group is preferably a phenylene group and the alkylene group is a benzyl group. In a preferred embodiment, the bridging group may be selected from the formula (Ila) -C (0)-0 R, 0-C (0)-(R (,)) (Ila) wherein R ′ is C2 to Cz, preferably C2 to Ci2, and more preferably C2 to C6 alkylene, benzyl, benzyl, or more preferably 2 to 6, and more The oligomeric alkylene group of R 2 and 4 oxyethylene and / or oxypropylene units and R "represents a direct bond, Ci Ci 2 alkylene, phenylene, or benzyl. Monovalent benzo [4,5] oxazolo [2, I-a] isoindino-11-one derivatives can be general formula (III) or ( Ilia) said

This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297mm #) (Please read the note on the back 9 β page first) • Packing. Order 526252 Λ7 B7 V. Description of the invention (from) Carbon adjacent to the benzene ring Atoms can be fused with benzene rings, heteroaromatic rings, or both, and functional groups can be attached to these rings instead of to the benzene ring of the nuclear polycyclic structure. These aromatic rings are unsubstituted or F, C1 Or Br, I, -CN, -N02, Ci to Ci8 alkyl, C3 to Ci2 cycloalkyl 'C6 to Ci8 aryl, C5 to Ci7 heteroaryl, C 3 to Ci 2 cycloalkylalkyl, C 6 to Ci 8 aralkyl, C s to Ci 7 heteroaralkyl, Ci to Ci 8 alkoxy, C3 to ci 2 cycloalkyloxy Group, Cs to Ci 8 aryloxy, c 5 to Ci 7 heteroaryloxy, C3 to "2 cycloalkylalkoxy, Ce to Ci 8 aralkyloxy, (^ to" 7 hetero Aralkyloxy, (: 1 to (: 18 alkylthio, C3 to ci Z cycloalkylthio, C 6 to C i 8 arylthio, C 5 to C JI 7 heteroarylthio, c3 to Ci 2 cycloalkylalkylthio, C6 to Ci 8 aralkylthio, cs to Ci 7 heteroarylthio, ci to Ci 8 alkyl-so- or -so2, C3 to Ci 2 cycloalkyl - SO-or-S02, C6 to Ci 8 aryl-so- or-S〇2, Cs to Cl 7 heteroaryl-SO-or-S02, C3 to Cji 2 cycloalkylalkyl-SO- or -S〇2, C6 to "8aralkyl-SO- or so2, C5 to Ci7heteroaralkyl-SO- or -S〇2, a secondary amine group having 2 to 30 carbon atoms, and having Alkoxyalkyl radicals of 2 to 20 carbon atoms. Cycloaliphatic and aromatic residues (substituents) can also be substituted 'for example by halogens like F, C1 or Br; or -CN, -N02, (^ To CiS alkyl, c3 to Ci 2 cycloalkyl, C 6 to ci 8 cycloalkyl, C3 to Ci 2 cycloalkylalkyl, C 6 to ci 8 aralkyl, C 5 to C: 7 Heteroaralkyl, Ci to Ci 8 alkoxy, C3 to Ci 2 cycloalkyloxy, C6 to Ci 8 aryloxy. Substituent alkyl can be straight or branched and can be halogenated Like ^^ or. Replaced. -1 6-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 public incineration) (Please read the precautions on the back-installation-this page) Set the central standard of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 526252 ΑΊ Β7 5. Description of the Invention (α) Examples of substituents are F, Cl, Br, methyl • ethyl, propyl Butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxy, methylthio, ethylthio, methyl- or ethyl-SO-, methyl- or ethyl- SOz-, phenyl, benzyl, tolyl, xylyl, methylbenzyl, dimethylbenzyl, chlorophenyl, dichlorophenyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, Dimethoxybenzyl. Preferably, the 1 or 2 rings are fused with adjacent carbon atoms to form a bicyclic fluorene or tricyclic ring system. They can be selected from the group consisting of benzene, furan, thiophene, pyrrole, pyridine, and blind. In a preferred embodiment, the monovalent benzo [4,5] oxazolo [2, I-a] isoindole-11-one derivative is equivalent to formula (I 11 b) or (111 c) '(please Read the notes on the back first

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Ordered by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs where R ο 1 »R〇2, Ro 3, R〇4, and 5 each independently represent 乂, C1, C i to C 1 8 alkyl, ci to C i 8 alkoxy, phenyl, benzyl, Ci to Ci! 2 alkylphenyl or Ci to Ci 2 alkyl benzyl. 5 in formula IIIc preferably represents hydrazone, R01, Ro2 'R03 and R04 are particularly preferably fluorene, phenyl, benzyl, Ci to Ci2 alkylphenyl, or Cl to (^ 2 alkylbenzyl and R0 are particularly preferably Η. Some preferred embodiments corresponding to the fluorescent part of Formula II as the main chromophore are -17- This paper size applies to Chinese national standards (CNS ) Λ4 specification (210X 297) while I 5 2 6 2 5 Λ7 V. Description of the invention (4

C (0) 0-CH2CH O-C (O)

c (O) 0-CH2CH2-0-C (O)-C6H5? 6H5 9

C (〇) -〇-CH2CH2-〇-C (〇)-(Please read this note first) and -C (O) -o-ch2ch -o

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. The fluorescent part as the main chromophore is bonded to the structural unit of the main chain via functional group 圑. Examples of functional groups are -OH, -SH, -NHR2, -CH = 0, carboxylic acid, carboxylic acid ester, ammonium carboxylate, -S03 amidine, epoxide, vinyl or isocyanate, of which amidine or Ci to C4 alkyl. The polymers may be selected from natural or synthetic polymers. Examples of natural polymers are polysaccharides like cellulose, starch or polyurethane, which may be partially etherified with Ci-C4 alkyl or esterified with Ci-C8 fluorenyl. With functional groups -1 8-This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 526252 Λ7 B7 _ V. Synthetic polymer of invention description (17) can be prepared according to known methods. Some examples of synthetic polymers are copolymers of polyvinyl alcohol and vinyl alcohol with unsubstituted or substituted olefins as comonomers; polymethacrylic acid * polyacrylic acid and polymaleic acid and methyl Copolymers of acrylic acid, acrylic acid and / or maleic acid with unsubstituted or substituted olefins as comonomers, polyhydroxyalkyl acrylates, polyhydroxyalkyl methacrylates and polymaleic acid Copolymers of hydroxyalkyl acrylates and hydroxyalkyl esters of methacrylic acid, acrylic acid and / or maleic acid with unsubstituted or substituted olefins as comonomers; polypropylene 醯Amines and polymethacrylamides and acrylamides, methacrylamides or copolymers of both with unsubstituted or substituted olefins as comonomers; polyaminoalkyl acrylates, -methyl Acrylates and -maleates and polyurethane alkyl acrylates, -methacrylates and -maleates or two or three of them are unsubstituted as comonomers Or copolymers of substituted olefins; polyhydroxyalkanes -Or a copolymer of polyaminoalkyl vinyl alcohol and hydroxyalkyl vinyl ether or amino alkyl vinyl ether or both with an unsubstituted or substituted olefin as a comonomer; from butadiene, iso Hydroxylated polybutadiene and butadiene, isoprene or chloroprene or two or three of these monomers with unsubstituted or comonomers Copolymers of substituted olefins; hydroxy- or amine-polystyrene, chloromethylstyrene and polystyrene sulfonic acid and hydroxystyrene- or amine-styrene, chloromethylstyrene and polystyrene sulfonate Acid or copolymer of two or K of these monomers with unsubstituted or substituted olefins as comonomers; polyglycidyl ether and hydroxyalkylated or -19- This paper size applies to Chinese national standards (CNS) Λ4 size (210X 297 male) (Please read the notes on the back first--installation--items κ)

Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 1T 526252 Λ7 B7 V. Description of the Invention (丨 3) Polyglycidyl ethers of amine alkylation; and polyesters obtained from monomers containing hydroxyl groups, polyamines and polyamines Carbamate. Other suitable vinyl polymers are polyvinylpyrrolidone, polyvinylimidazole and polyvinylpyridine and vinylpyrrolidone, vinylimidazole, vinylpyridine or two or three of them as copolymerized monomers A copolymer of an unsubstituted or substituted olefin. Suitable olefin comonomers are, for example, ethylene, propylene, butene, pentene, octene, vinyl chloride, vinylidene chloride, styrene and acrylonitrile. The polymers may also consist of crosslinked polymers, such as those derived from olefins * optionally non-functionalized olefin monomers, and diene monomers such as butadiene, divinylbenzene or glycol diacrylate or Polymerization product of diol dimethacrylate. The polymer may also be composed of a thermosetting resin such as an epoxy resin, a melamine-formaldehyde resin, and a phenolic resin. The host moiety bonded to the polymer may be derived from a monofunctional or polyfunctional host molecule. Preferably such molecules are mono- to trifunctional * particularly preferably mono- or difunctional. The weight-average molecular weight of the non-crosslinked polymer used in the present invention may be 103 to 2 X 106, preferably, 104 to 106, more preferably, 2 X 1G4 to 106, and most preferably 4 X 104 to 5 X 105 grams of Mohr-1, as determined by K gel permeation chromatography, using polystyrene standards as calibration. 0 Polymers can range from monovalent covalently bonded monovalent to trivalent residues of the main chromophore. The monomer unit is composed of other monomer units which can be selected as required. -20- This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297) (Please read the notes on the back first

1.1T printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the invention (θ) The weight ratio of the main hair color base structural unit (k) to the non-fluorescent structure unit (η) depends on the actual application Therefore, there is no better definition of a better ratio, except for a wide range of 100: 0 to 1 · 9 9 9. In some applications where both color intensity and fluorescence are required, the preferred ratio of chromophore-based structural units to non-fluorescent structural units is 20:80 to 100: 0, preferably 50:50 to 1 0 0: 0 and more preferably 8 0: 2 0 to 1 0 0: 0. In environments where fluorescence is required but color intensity is not required, the preferred ratio of chromophore-based structural units to non-fluorescent structural units is 20:80 to 1:99, more preferably 10:90 to 1: 999 and better 5: 95 to 1: 9 9 9. These polymers may consist of repeating structural units of formula (IV) -A-

I

Host (| V) may be composed of repeating cross-linked structural unit of formula (IVa), alone or in combination with structural unit of formula (IV) (please read the precautions on the back side first n ^ this page) A—

a), (IV Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Co-existence, Time Division, 5 Divisions, 5 Units, Units [4] Fluoride 2 Valence Price A A Valence Ternary II Gongweiwei or A in the base A is csist valence. This A AHO borrows azozomidone bridge from ketone via 1- or T to D5, which is different, a Definitions 1-2, so the paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 cm) 526252 Λ7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention (W) Polymer May additionally include the structural unit of formula (IVb), " A 4-(IVb) where A4 · table is the same or different divalent residue OA that cannot be copolymerized with A and A2, and A 2 and A 4 can be derived from optional Including olefins, poly-stomach_% di- or tri-hydrocarbons, polyhydric alcohols such as diols and triols, polyamines such as diamines and triamines, polyisocyanates such as di- or tri-isocyanates, polybasic acid Monomers of acids such as di- and tricarboxylic acids, and polyepoxides such as di- and triepoxides. Chromophore structural units ( The weight ratio of IV) and (IVa) to non-fluorescent structured units (IV b) depends on the actual application, so there is no better ratio for better definition, except for a wide range of 100: 0 to 1: 9 Other than 9 9. In some applications where both color intensity and fluorescence are required, the preferred ratio of chromophore-based structural units to non-fluorescent structural units is 20:80 to 100: 0, preferably 50:50. 1 0 0: 0 and more preferably 8 0: 2 0 to 1 0: 0. In an environment where fluorescence is required but color intensity is not required, the chromophore-based structural unit is better than the non-fluorescent structural unit. The ratio is 20:80 to 1: 9 9 9, more preferably 10:90 to 1: 9 9 9 and more preferably 5: 95 to 1: 9 9 9. In a preferred embodiment, these according to the invention The polymer contains repeating structural units of formula (V) and optional repeating structural units of formula (VI) if necessary. -22- (Please read the precautions on the back first

(This page) The paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X2W publicly available) 526252 Λ7 B7

5. Description of the invention (W

-S Χ2) / ^ \) / 4 一 € R — CIX 5 a 6 RICIR

8 110 RICIR 7 -9 RICIR \ — / (Please read the precautions below and print out one thousand hits by the Consumers Cooperatives of the K-Staff Bureau of the Ministry of Economic Affairs. Xi and Xz each independently indicates that Xi and Xz are independent tables. Does not directly affect _s_, _NR2 -.- 〇 (〇) -〇- · -〇-c (〇)--〇-c (〇) -〇- «-so2 -〇-, -o-so2-> -〇-s〇2 -〇- * -NR2 'C (〇) -nr2 -nr2 -〇 (〇) -〇- * 〇-c (〇) -n ^--NR2 -C (0) NR2-, n-s〇2… -s〇2 -m ..._.-, -Η o2 -nr2 _ or -NR2 -so2 -NR2-, Ri represents a divalent bridging group 'Ho st means selected from the group consisting of benzo [4 , 5] imidazo [2, bua] isoindole d ketone as the monovalent fluorescent moiety of the main chromophore 'represents Η, Ci-Ci 2 基 group' Cs or k-ring alkyl group 'Cs-or Cs ring Alkylmethyl or -ethyl, phenyl 'benzyl or phenyl-2 * " ethyl' represents a direct bond, -Ci 8 alkylene group 'C5 " or Ce-cycloalkylene group, C6 -Ci 0 arylene or "-ci 2 aralkylene's each independently represents the number of 0 or 1 but provided that if s is 0, R 2 R 3 Γ and r are 0 4 and Rs each independently represent Η, Ci -C6 alkyl, c6 Aryl, or C7 -Ci 2 -23 aryl group present burn paper apply China National Standard Scale (CNS) Λ4 Specification (2ΙΟΧ297 well #)

Μ page) Dingquan ⑽ 252 Λ7 B7 5. The invention description printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (% means Η or basic -C (0) 0-Ri i) Page) R7 represents fluorene, Ci-C6 alkyl, C6-C! 〇aryl or C7-Ci 2 aralkyl, RS represents fluorene, F, Cl, CN, Ci-C6 alkyl or C6. Aryl, R 9 represents H, C i-Q alkyl or -C (0) 0-R ^ i,

Ri 〇 represents H, C i alkyl, -C i 〇 aryl, C 7 -C i 2 aralkyl, oxazolyl, pyrrolidinyl, F, Cl, CN or group -Xi-(Ri) r- (Xz) sH, and

Ri ^ means only 1 (, ^, (: 1-(: 18alkyl, (: 1-(; 18hydroxyalkyl, cyclohexyl, cyclopentyl, cyclohexylmethyl, phenyl, {^-" Alkylbenzyl, benzyl or Ci-C4 alkylbenzyl. For X ** 2, Ri, R2, R3 and Host, the meaning and preferred embodiments are the same as previously described here. 1U and Rs are taken as Alkyl means preferably Ci-C4 alkyl, such as methyl'ethyl, n-, iso-propyl and n-, iso- or tertiary-butyl; as aryl is preferably naphthyl or phenyl; and As the aralkyl group, a benzyl group is preferred. R4 is fluorene, and R5 is fluorene or methyl. It preferably represents fluorene, -C (0) 0H or-(:( 0) 0-(^ to " The group 0 R7 as the alkyl group preferably represents a C 1 -C 4 alkyl group such as methyl, ethyl, n- or iso-propyl and n-, iso- or tertiary-butyl; and for aryl, naphthalene is preferred Or phenyl group; and benzyl as the aralkyl group is preferred. R7 is preferably Η 〇-24- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 297 g t) 526252 Λ7 _ll_______ 5. Description of the invention ( 23) r8 as alkyl preferably represents ci-c4 alkyl, such as methyl'ethyl N- or iso-propyl and n-, iso- or tertiary-butyl; and naphthyl or phenyl is preferred for aryl; and benzyl is preferred as aralkyl. Particularly preferred is hydrazone, Cl , CN, phenyl or Ci to C4 alkyl. R9 as alkyl preferably represents Ci-C4 alkyl, such as methyl, ethyl, n-, iso-propyl and n-, iso- or tertiary-butyl In the group 4 (0) 0-1 i, Rii preferably represents ^ 1 or Ci-Ciz alkyl, more preferably an alkyl group, such as methyl, ethyl, propyl, butyl, pentyl, hexyl, Heptyl, octyl, nonyl, decyl, undecyl, dodecyl, dodecyl, hexadecyl and octadecyl. Particularly preferred R9 is fluorene, (: (0) 01 ^ -(:( 0) -0-(^-C4 alkyl. I 0 as alkyl preferably represents Ci-C4 alkyl, such as methyl, ethyl, n- or iso-propyl and n-, iso- or Third-butyl; and preferably aryl and naphthyl as an aryl group; and benzyl as an aralkyl group. Ri0 preferably represents Η 'Ci -C4 alkyl group' phenyl 'Bt tower 'F'Cl'CN or radical -Xi-Ui) r- (X2) sH.

Ri i can be, for example, 1 ^, 1 (, ^, (: 1-(: 6alkyl, (: 1-(: 6-hydroxyalkyl, cyclohexyl, cyclopentyl, cyclohexylmethyl'phenyl'toluene) Benzyl or methylbenzyl. The weight ratio of chromophore structural unit (V) to non-fluorescent chromophore structural unit VI depends on practical applications, so the preferred ratio is not well defined, except for a wide range. 1 ϋ 0: 0 to 1: 9 9 9. In some applications where both color intensity and luminescence are required, the chromophore-based structural unit is suitable for non-fluorescent junctions. CNS) Λ4 specification (210 × 297 public carboxylic acid) (Please read the notes on the back first) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs The preferred ratio of the structural unit is 20:80 to 100: 0, more preferably 50:50 to 100: 0 and more preferably 80: 2Q to 1Q0: 0. In an environment where light intensity is not required, the preferred ratio of the chromophore-based structural unit to the non-fluorescent structural unit is 20:80 to 1: 99.9, preferably 1. 0 ·· 9 0 to 1: 9 9 9, better 5: 9 5 to 1: 9 9 9, best 2 0: 8 0 to 10 0: 0, particularly preferably 5 0: 5 0 to 10 0: 0 And Hejia 80: 20 to 100: 0. A polymer having a structural element of formula (V) and optional (VI) can be cross-linked with a combination of polyfunctional monomers, such as using such monomers 0.1 to 80% by weight, preferably 0.1 to 60% by weight, relative to 100 grams of polymer. Depending on the type of polymer, at least trifunctional carboxylic acid, isofluoroester can be used Alcohols, amines, vinyls or epoxides. In addition, residues containing at least two olefinic (olefinic) unsaturated groups can be used. The ethylenic unsaturated crosslinking agent can be selected from the group consisting of two Vinyl benzyl alcohol, bis-methyl butene difluorenimide monoalkenyl such as bis- (dimethyl-butene difluorenimide)-methylene or-ethylene, polyol Type (preferably diols to tetraols) or polyamines, respectively, preferably diamines to tetraamines, acrylic or methacrylic acid esters or -amidoamines. Preferred ethylenically unsaturated crosslinking The agent is selected from the group consisting of containing especially good 2 12, and particularly good 2 to 8 C-atomic aliphatic, cycloaliphatic and cycloaliphatic-aliphatic diols to tetraols and diamines to tetraamines acrylic or methacrylic esters. Some examples of diols are alkanediols like ethylene glycol, 1,2- or 1,3-propanediol, 1,2-, 1,3- and 1,4-butanediol, pentanediol, hexanediol , Octanediol, decanediol, dodecanediol, cyclohexanediol, bis (hydroxymethylcyclohexane-26- (Please read the precautions on the back first Ϊ. 装 — ^ This page) 泉- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297) while it is U6252 Μ__ Printed by the Consumers Cooperative of the Central Standards Bureau, Ministry of Economic Affairs, B7 Invention Description (/), derived from the better c2 -c6 alkanediol The polyoxyalkanediol has a unit selected from the group consisting of preferably 2 to 100 diol units 'more preferably 2 to 50 monohydric alcohol units' and most preferably 2 to 20 alkanediol units. For example, polyethylene glycol, polypropylene glycol, polybutadiene, and polyethylene / polypropylene glycol 'further, 1,1,1-dimeryl methyl ethyl or propylene, isoprene, and diisoprene alcohol. Some examples of dopamine are ethylenediamine, 1,3- and 1,3-propanediamine 'I, 2-' 丨, 3 " and butanediamine, 1,6-hexanediamine, diethyl Triethyleneamine, triethylenetetramine, cyclohexanediamine, (aminemethyl) cyclohexylamine, isophoramdiamine and bis (aminemethyl) cyclohexane. In a preferred embodiment of the present invention, the polymers include the structural element H R12 II 12 —c—c— (VII) of formula (V 11), where ha is H or methyl, and Xi, χζ , R1, R3, Host, i *, and s have the same meanings as the foregoing, including preferred embodiments, and optional structural elements of Formula VI as required. The radical -Xi-(Ri) r- (X2) s-R3 is preferably represented in the structural element of formula V * VI1 as -C (0) -0-, -C (0) -0-C2 -c6 焼 if radical -〇-c (〇)-, -C (0) -0- (C2-C6 alkylidene-〇) uC (〇), having a number of u from 2 to i〇, -0-C (0)- C6 H5, CH2-O-C (〇) -C6 Hs _ or _〇 ~ c (〇) -C i to Ci 2 alkylene. Structural elements with formula (V) or (VII), and optional formulas as required. -27- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 public carboxylic acid) 526252 Λ7 ___ B7 _V. Description of the invention (Permitted), (VI) The polymer of the structural element may additionally include the same or different structural elements of the formula (VIII).

H R 12 —c-c— H (VUI), wherein R12, Xi, X2, Ri, r, and s have the aforementioned definitions, including preferred embodiments. These structural elements are especially present when the group Hot is introduced to the polymer via a reaction between a side functional group on the polymer and a functional group on the respective host and guest molecule. Polymers having structural elements of formula (V) or (VII), and optional structural elements of formula (VI) as required * It is preferable to include the same or different structural elements of formula (IX) as preferred units of formula (VI) (Please read the notes on the back first.

, 1T

H R 12

-c—c—— IIHR (IX), printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economics where Ri 2 represents hydrazone or methyl, and Ri 3 represents H, cx -C4 alkyl, Ci -C4 alkoxy,- CN, C1, phenyl, pyrrolidinyl, pyridyl, imidazolyl, C (0) OR14 or -Ciin-NRi 5 I 6, Ri 4 represents fluorene or Ci -Ci 8-and preferably Ci -Ci 2 Alkyl, and 5 and Ri 6 each independently represent HSCi -Ci 2-, and preferably "-C6 alkyl. It has a structural element of formula (V) or (VII), and optionally, formula -28- Paper size applies to Chinese National Standard (CNS) / \ 4 specifications (210X 297) 丨% 526252 Λ7 V. Description of the invention (^ 7) Polymers with the same or different structural elements of formula (vi) or formula (ix), Structural elements of formula (X) or (XI) may be additionally included as preferred units of the crosslinking agent,

HICIH

2 R1—C—— I HICIH C • 7 R1 ☆ c (

HICIH 121 RICI \) / where Ri 2 represents fluorene or methyl, X3 represents -〇-, -ΝΗ-or-N (Ci -C4 " * alkyl)-'and Rl 7 represents C2 -Ci 2-and more Ci-C6 alkylene, cyclohexylene, cyclohexane dimethylene, phenylene, or χ3 and Ri 7 represent C2-C6 alkylene- (c2-C6 alkylene-0) 2 To 2 0 "2 (Please read the precautions on the back page first-this page),-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs» 12119 Wugou RICIR alkane 118 HICIR C zygote_Ju Li Zhi Tong Tong As mentioned in the previous example, the comparison of the basic product and the basic product

X is not or is in phase with inclusion step

(XI in other

Rx 2 represents fluorene or methyl, Ri 8 represents Η and R! 9 represents -C (0) 0R2 0 '-S〇3 R2 0' H4 -COOR2 0 '-c6 H4 -S〇3 R2 O ~ c6 H4- R2; -29- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297g t) 526252 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 ____ B7_______ 5. Description of the invention (4) or -C (0) -X4 -C2 -C6 alkylene-R2 2 'X4 represents -0- or -NH-, Ri 8 and 1 ^ 9 each independently represent -C (0) 0R2 〇 or -C (0) -X4 -c2 -C6 alkylene-Rz 2, Rz 0 represents an alkali metal, preferably Li, Na or K, R 2 i represents an ammonium group or an ammonium methyl group, and Rz 2 represents an ammonium group. The ammonium group or ammonium in the ammonium methyl group may be derived from a primary, secondary or tertiary amine group; a quaternary ammonium group is preferred. The ammonium group or ammonium in the ammonium methyl group may correspond to the formula (XIII)-+ nr23r24r25 (XIII), wherein R2 3, R24 and R2 5 each independently represent-, preferably (^ -Ci 2-and more preferably Ci- C6 alkyl, CS-or C6 cycloalkyl, phenyl, benzyl, 1-phenyl-2-ethyl, or R2 3 and IU-starting from tetramethylene, pentamethylene or -CH2 CH2- 0-CH2 CH2 R2 6 has the definition as previously described. Suitable relative anions can be derived from inorganic or organic acids, such as, for example, osmic acid, sulfonic acid, and halo acids. Preferred relative anions are chlorides and bromides. Polymerization products and comparisons Preferably, the aforementioned polymerization product may additionally contain structural elements having acid groups such as -C (0) 0H or -S03 Η, especially when it involves glue polymerization-3 0 ~ This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (2ΐ 〇χ297 公 楚) ~~ (Please read the precautions on the back i buy this first) When installing, ν " 526252 Λ7 _ V. Description of the invention (1) The structural element with an acid group can be equivalent to the formula (XIV) H R12 -cc- (XIV), II white 27 latch 26 of which

Ri 2 represents η or methyl,

Rz 7 represents Η and β2 S represents -C (0) 0H, -S〇3 H, -C6 H4 -COOH, -C6 Η4 -S03 Η, or Rz 6 and R2 7 represent -C (0) OH. Polymers having amine or acid groups are preferably soluble in water or they can be prepared by emulsion polymerization in which monomers are dispersed and / or dissolved. In another preferred embodiment, the polymers according to the invention can be cross-linked with difunctional host and / or guest molecules. These polymers may contain repeating structural elements of formula (XV), alone or in combination with structural elements of formula (V),

V I12 I —C one C—— one c——C- H Η (χν) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back page)

Ri, R3, Ri2, X1, X2, r, s, and a Host-have the meanings given above, including the preferred embodiments. These polymers may additionally contain non-fluorescent structural units derived from single and / or polyethylenically unsaturated monomers. -3 1-This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 public dredging) 526252 Λ7 Β7 V. Description of the invention (π) Structural unit (XV) and (V) selected as required for non-fluorescent emission The weight ratio of the color-based structural unit depends on the actual practical application, so the better ratio is not well defined, except for a wide range of 1 0 0 ·· 0 to 1: 9 9 9. In some applications where both color intensity and fluorescence are required, the preferred ratio of chromophore-based structural units to non-fluorescent structural units is 20 ·· 80 to 100 ·· 0, preferably 50: 50 0 to 1 0 0: 0 and better 8 0: 2 0 to 1 0 0: 0. In an environment where fluorescence is required but color intensity is not required, the preferred ratio of the chromophore-based structural unit to the non-fluorescent structural unit is 20:80 to 1:99, and preferably 10:90 to 1: 9 9 9, more preferably 5: 9 5 to 1: 9 9 9 〇 The above-mentioned crosslinked polymer having one or two structural elements of formula (XV) may include formula (V), (VI), (IX ), (X), (XI), (XII), UIII) and (XIV) structural elements, alone or in combination with at least two of these structural elements, or may contain preferred residues of formula (VI), U ) And (IX), and further (X), (XI), (XII), (XIII) and (XIV) structural elements, alone or in combination with at least two of these structural elements. Equivalent divalent residue equivalent (xvi) of a better host chromophore (please read the precautions on the back first)

"This page" is printed by the Consumer Cooperatives of the Central Standards Bureau of Quanquan Ministry of Economic Affairs. \ // Will be able to be, and the above, and the cyclist will form two knots or polycyclic aromatic nucleus. In addition, the original carbon is close to the adjacent radicals. Central ring energy and its benzene official standards. Home country | China use one suitable one button β S Ν one miscellaneous ¥ 526252 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 ^ _____ V. Description of the invention (>> 丨) These aromatic rings are unsubstituted or F, Cl or Br, I, -CN, -N〇2, C ^ to C! 8 alkyl, C3 to C i 2 cycloalkyl, C6 to C 1 8 aryl, cs to Ci 7 heteroaryl, C3 to C 1 2 cycloalkylalkyl, C6 to C: 8 aralkyl, C 5 to C i 7 heteroaryl Alkyl, Ci to Ci! 8 alkoxy, C3 to ci 2 cycloalkyloxy, C6 to Ci 8 aryloxy, C 5 to ci 7 heteroaryloxy, C3 to Ci 2 cycloalkylalkane Oxy, C6 to ci 8, aralkoxy, C5 to C i 7 heteroaralkyloxy, C i to C i 8 alkylthio, C3 to ci 2 cycloalkylthio, Cs to C i 8 aromatic Thio, CS to C 1 7 heteroarylthio, C3 to Ci 2 cycloalkylalkylthio, Ce to ci 8aralkylthio * C5 to Ci 7 heteroaralkylthio, ci to Ci 8 alkyl-so- or -so2, c3 to Ci 2 cycloalkyl-SO- or -S02, C6 to Ci 8 aryl-so -Or -S0Z, C5 to Ci7 heteroaryl-SO- or -S02, C3 to Ci2 cycloalkylalkyl-SO- or -S02, C6 to. 8 aralkyl-SO- or S02, c5 to C i 7 heteroaralkyl-SO- or -S02, secondary amine groups having 2 to 30 carbon atoms, and those having 2 to 20 carbon atoms Alkoxyalkyl substitution, cycloaliphatic and aromatic residues (substituents) can also be substituted, for example by halogens like F, C1 or Br; or -CN, -N02, Ci to Ci 8 alkyl, C3 To (^ 2 cycloalkyl, C6 to Ci 8 aryl, C3 to Ci 2 cycloalkylalkyl, "to ci 8 aralkyl, C 5 to Ci 7 heteroaralkyl, ci to Ci 8 alkoxy, c3 to Ci 2 cycloalkyloxy, C6 to ci 8 aryloxy, and A6 and A7 represent direct fluorene or divalent organic groups. Examples of substituents are F, Cl, Br, methyl, ethyl Propyl, butyl, butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxy, methyl-33- ^ Paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297) H one one (please read the note on the back page first)

1T 526252 Λ7 B7 V. Description of the invention (β) Thio, ethylthio, methyl- or ethyl-so-, methyl- or ethyl-so2-, phenyl, benzyl, tricresyl, di Tolyl, tolyl, dimethylbenzyl, chlorophenyl, dichlorophenyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl. Preferably, the 1 or 2 rings are fused with adjacent carbon atoms to form a bicyclic fluorene or tricyclic fluorene. They can be selected from benzene, furan, pheno, pyrrole, pyridine, and pyrimidine. In a preferred embodiment, As and A7 are equivalent to formula (XVII)

Xi-(Ri) r- (X2) 3 -E3-(XVII) where

Xi, X2, R3, r and s have the aforementioned definitions, including the preferred specific embodiments. In the preferred embodiment, the divalent host residues are equivalent to the formulae (XVIII) and (XVllla) (please read the note on the back page of Ami first)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs, among which R01, R02, R03, R04, and R05 each independently represent 'c 1, C 1 to C 8 alkyl, C i To C i 8 alkoxy, phenyl, benzyl 'C 1 to C 1 2 alkylphenyl or C i to C 2 alkyl benzyl. R05 preferably represents Η, and corresponds to a divalent residue of formula XVI with A7. -3 4-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 public carboxylic acid) 526252 Λ7 B7 V. Description of the invention (33) In the preferred embodiment, these groups A6 and 87 are optional And β ′ is C2 to c2 0, preferably C2 to Ci 2, and more preferably c2 to c6 acryl'phenylene, benzyl, or having preferably 2 to 6 and more preferably 2 to 4 'Oxylidene and / or oxypropylene units of oligooxyalkylene group, R "represents Cl to ^ 2 alkylene, phenylene or benzyl, and u represents 0 or 1. Some correspond to the formula ( XVI) The preferred example of the host chromophore residue is C (0) -0CH2CH2-0- (0) CC (CH3) -ch- (Please read the precautions on the back page first)

(〇) o-ch2ch2o-c (o) -c (ch3) -CH-

, TT Quan Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

I I c (〇) -〇-CH2CH2-〇-C (〇) -c (ch3 Bu CH-

: i〇IIC (0) o-ch2ch2-oc (0) -c (CH3) -ch- -35 This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297g t) 526252 Λ7 B7 V. Description of the invention (Arsenic) C (0) 0CH2CH20C (0) -C (CH3) -CH- 〒Lu 5 〇 | | NC (〇) ~ 0 ~ CH2CH2 ~ ° ~ C (O) -C (CH3) -CH-

C6H5 I C6H5

In another preferred embodiment of the present invention, the polymer according to the present invention may include or may consist of a functional host structure. The host structure may include two or three covalently connected to the host core structure via a bridging group. A ring functional group. Therefore, the polymers having repeating structural units of the formulae (IV), (IV.a) and (IVb) may be additionally included, or the units of the formula (IVa) may be represented by the formula (IVc), (IVd) or both Instead of repeating crosslinking units,

Host— * A- (IVc), (Please read the precautions on the back first v Pack 丨 —Miscellaneous page) Order-Printed by Quanzhou · Ministry of Economics Central Standards Bureau Staff Consumer Cooperative

Host-A- (IVd), where A8 represents a trivalent or tetravalent organic residue, copolymerizable with groups A to A4, and Ho st is a monovalent fluorescent moiety, as previously defined. -36-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 Gongchu) 526252 Λ7 Β7 V. Description of the invention The bivalent and trivalent residues of the color base of the better subject are also equivalent to the formula (XIX ) And (XlXa)

(XIX), (Please read the back notice first

(XlXa),

(This page) where the carbon atom adjacent to the benzene ring can be fused with a benzene ring, a heteroaromatic ring, or both, and these aromatic rings are unsubstituted or substituted with F, C1 or Br, I, -CN, -NO2 ' C i to Ci 8 alkyl, C3 to C 1 2 cycloalkyl, C 6 to Ci 8 aryl 'to C: 7 heteroaryl, C3 to Ci 2 cycloalkylalkyl, C6 to Ci 8 Aromatic radical 'C5 to Cl 7 Heteroaromatic radical, Ci to (^ 8 radicals, C3 to C 2 cycloalkyloxy, C 6 to C 1 8 aryloxy, C 5 to C i 7 Heteroaryloxy, C3 to ci 2 cycloalkylalkoxy, C6 to C i 8, aralkoxy 'to (^ 7 heteroarylalkyloxy, Cl to Cl 8 sulfuryl, C3 to C 1 2 cycloalkylthio, C 6 to Ci 8 arylthio, CS to Ci 7 heteroarylthio, C3 to ci 2 cycloalkylalkylthio, to ci 8 aralkylthio 'C5 to "7 Heteroaralkylthio, Ci to (^ 8alkyl-SO- or -S02, c3 to Ci2cycloalkyl-S0_ or -s〇2, (^ to Ci 8aryl-SO- -37- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 citizenship). Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. Printed 526252. B7___ 5. Description of the invention (#) or-S〇2, C5 to Ci 7 Base- SO-or-S〇2, C3 to {^ 2 cycloalkylalkyl-SO- or-S〇2, c6 to 0; 18 aralkyl-SO-or S〇2, C5 to Ci 7 hetero Aralkyl-SO- or -S02, secondary amine groups having 2 to 30 carbon atoms, and alkoxyalkyl substituted, cycloaliphatic and aromatic residues having 2 to 20 carbon atoms ( Substituents) can also be substituted, for example by halogens such as F'C1 or Br; or -CN, -N02, 〇1 to (: 18 alkyl, 〇3 to "2-cycloalkyl, C 6 to C 1 8 aryl, C 3 to C 1 2 cyclofluorenylalkyl 'Ce to ci 8 aralkyl, C 5 to ci 7 heteroaralkyl, ci to C i 8 alkoxy, c3 to C i 2 cycloalkane An alkoxy group, c6 to Ci 8 aryloxy group, and A8 represent a trivalent or tetravalent organic group. Examples of the substituent are F, Cl, Br, methyl, ethyl, propyl, butyl, hexyl, methoxy Methyl, ethoxy, propoxy, butoxy, hexyloxy, methylthio, ethylthio, methyl- or ethyl-so-, methyl- or ethyl-so2-, phenyl, benzyl Methyl, tolyl, xylyl, methylbenzyl, dimethylbenzyl, chlorophenyl, dichlorophenyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl. Good 1 Rings condense with adjacent carbon atoms to form bicyclic fluorene. They can be selected from benzene, furan, thiophene, pyrrole, pyridine, and pyrimidine. In a preferred embodiment, A8 is equivalent to formula (XX) or (XXa), -R3i- (X4) a-R32- (X5) b (XX), / R3l-X7-R3 ~ X6. -3 8-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 gong) (Please read the note on the back page first) Printed by the Staff Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Staff Consumption of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative printed Λ7B7 __V. Description of the invention Q7) (a) R3 i is a direct bond, ^ to Cl £ alkylene 'phenylene or benzyl; X4 is N, 0, S, C (0) 0 or C (0) N; R32 represents C2 to Cl2 alkyltriyl, phenyltriyl or benzyltriyl, when a is 1 and b is 2, or CZ to "2alkyltetrayl, phenyltetrayl or benzyl Four bases, when a is 1 and b is 3; X5 represents 〇, S, NH, C (0) 0, C (0) NH, 〇C (0) —CH-CH2 OC (O) —c (CH3 ) A CH- — HNC (O) CH-CH * HNC (O) ~ C (CH3) ~ CH-—1, 1, 丨, 丨, · or (b) R3 2 is chemical 鐽, a is 0 and b Is 2 or 3, X5 has the above definition and Rs i represents C2 to Ci 2 alkyltriyl, phenyltriyl or benzyltriyl, when b is 2, or C2 to Ci 2 alkyltetrayl, phenyltetrayl or Tetrayl, when b is 3; (c) R3: is directly fluorene, (^ to Cl2 alkylene, phenylene or benzyl; Xg6 is N or C (0) N; R3 3 is C2 to C i 2 alkylene; X7 is 0, S, C (0) 0, C (0) NH, and OC (O) —CH-CH2 — OC (O) —C (CH3) —CH2 — HNC (O) —CH-CH, ~ HNC (0) -C (CHJ — CH, — III 2 I * »» -CH-CH.-I. -39- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2IOX297) t) ~ " " (Please read the note on the back page first)-equipment, \ 呑 526252 R .. 〇

Λ7 —____ 5. Description of the invention (? 犮)

Rb i and R3 3 contain preferably 2 to 8 and more preferably 2 to 4 C-atoms in the meaning of an alkylene group. R3 2 in the meaning of trialkyl contains preferably 2 to 8, more preferably 2 to 6, and more preferably 2 to 4 C-atoms. In another preferred embodiment, the bivalent or trivalent fluorescent moiety serving as the main chromophore is equivalent to the formulae (XXI) and (XXla)

r〇5 (XXI), '\ (XXla), where i, Ro2, Ro3, Ro5, and 5 each independently represent Η, C1, C1 to Ci8 alkyl, and Ci to C i 8 alkoxy, phenyl, benzyl, C 1 to C 2 alkylphenyl or C i to C 2 alkylbenzyl, and A8 correspond to formula XXVI or XXVla. R0 5 preferably represents H. In a preferred embodiment, the group A8 may be selected from the following groups

(Please read the precautions on the back of V first. • Installation-explain this page)

, 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs • C—N ~ II 〇 [CHj-CH-CH2] — c —〇—CH; II 〇

Γ3 -c — I

N cn〇_ _ CN ο I -CH--CHr? H2 -o- CHr CH, 〇- -c- II 〇-o — CH- -CH- I CH0 -CH, -40 This paper size applies to Chinese national standards (CNS) Λ4 specification (210X 297 male Zhao) 526252 Λ7 B7 V. Description of the invention ("-C —〇-CH" II 2 〇η I CH-CH2〇- C — CH-CH2 -C —〇-CH- II 2 〇II 〇

• CH-Cl I CH.O-C- 2 II 〇 ch3 I ii I 31 • C —C — CH ^ -C-I CH, -CH, CH,

nil -c — CH-CHU -C —〇—CH, — C-Cl ·. II 2 I 〇 CH.O-C ——CH ——CH, II I I 〇1 1 CH o

CH 2 H -c H3-\ C —-- CH2 IC— 〇nc \ 3 I \ IH oC— c H2-c cn o l0 ~ H3 _ H2 c— c— c (Please read the precautions on the back first-c -II 〇-ο — CH; π II ch2〇-c—ch-ch2 〇I II I • c. I iO- _ II 〇c I 〇I cn o H cl ON c H c

Η I c CM I 〇 2 H cI c H-, c- c 2 H c H cI c H c- Some preferred examples are residues derived from the following groups (Ph stands for phenyl):

Ph

: Ί >

Ph

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

Ph

Ph C (0) och2ch (ch2ch2o-) 2

sc6h4 (c〇2_): -41 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 cm) 526252 ΑΊ Β7 V. Description of invention (jealousy)

Ph

C (0) 0CH2C (CH3) (ch2

Ph

C6H4 (C〇2-):

(Please read the note on the back first V

Ph

J ^ J ^ C (0) 0CH2C (CH2CH20-);

Ph

(C6H4 (NH-) 2 Pack--for this page)

Ph

CH2C6H4 (C〇2-) 2

Ph Ph Ph

〇c6h4 (c〇2-) 2 Ph, v '

Ph

c6h4 (o_):

Ph Ph Ph

c6h4 (nhch2ch2〇-) Ph Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs _ 4 2-This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 gong) 526252 Μ Β7 V. Description of invention (similar)

Ph

-c (〇) -ch-ch2) 2

i I J ^ Jj-C (0) 0CH2-C (CH3)-(CH2〇-C (〇) -CH-CH2) 2

Ph

Please read the item i on the back, printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. These polymers used in the present invention can be random, block, graft or emulsion polymers (lattice). The preparation of polymers and their fixation are known in the art. One method is to polymerize monomers having a side chain host molecule, and the other is to use a polymer having a side chain functional group and react them with a host molecule also having a functional group. The preparation of polymers according to the invention can be carried out according to methods known in the polymer chemistry, such as stepwise growth, anionic, cationic and free radical polymerization. Polymerization methods are solution, bulk, latex, photo- and interfacial polymerization. -43- This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 cm) 526252 Λ7 B7 ___ V. Description of the invention (ip) The reaction temperature range can be 0 to 250 ° C. The use of properly and well-established catalysts and photoinitiators is not described in detail here. Azobisisobutyronitrile is known as an effective free radical catalyst for the thermal polymerization of olefinically unsaturated compounds. Polymerization can be performed by mixing these monomers, catalysts and optionally solvents and heating, irradiation, or both by heating and irradiation. The polymers can be isolated by precipitation into non-solvents or by removing those solvents. . If further purification is required, it can be carried out by repeated precipitation and drying. These monomers are partly novel and partly known or they can be prepared by known or similar methods. These bulk monomers can be prepared according to the method described in EP 0 4 5 6 609. Functional host chromophores are known or can be synthesized by similar methods K known or their synthesis using selectively protected functional intermediates. Among them, the peptidic anhydride reacts with 1,2-diaminobenzene, whereby the anhydride * diaminobenzene or both contain a selectively protected functional group. More details are revealed in the examples. The functional groups may be selected from the group including alkyl groups bonded to halogens such as C1 and Br; -N3, epoxide, -OH, -SH, -CN, -NHRi〇0, = C = NRi 〇〇, = CO,-CH-0,-NCO,-CH = CH2, -C (CH3) = CH 2 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs,-C (0) 0 H >-S 0 3 H 5- S 0 2 Cl '-S 0 2 Br, -C (0) ~ C1 »-C (0) -Br, ~ 〇C (〇) -〇Ri 〇1, -〇C (0) -NIli 〇2 〇 3, -C (0)-0 R 1 〇4 '-S 0 z -ORi 〇4, -C (0)-NR 1 〇2 Ri 〇3 and -SO2 -NRi 〇2 Ri 〇3, where

Ri00 means H, CA-Ci8 alkyl, phenyl, or benzyl, -44- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297) 526252 Λ7 B7 V. Description of the invention (⑬)

Ri 〇 i represents Ci-Ca 8 alkyl, phenyl, or benzyl,

Ri 〇 2 and Ri 〇 3 each independently represent fluorene, Ci-Ci 8 alkyl, phenyl, or benzyl, and

Ri04 represents Ci-Ci8 alkyl, phenyl, or benzyl. R 1 ο 〇, Rio 1 * R 1 〇 2 * R 1 〇 3, and Ri 〇 4 as the alkyl group preferably contain 1 to 12, more preferably 1 to 8 and most preferably 1 to 4 carbon atoms. More preferred functional groups are selected from the group consisting of alkyl groups bonded to C1 and Br; epoxides, -OH, -SH, -NHR 100, -CH = CH2, -C (C H3) = CH2, -NCO , -C (0) 0H, -C (0) -C1, -C (0) -Br, -C (0) -OR i 〇4, -C (0) -NR! 〇2 Ri 〇3, where R i 〇〇 represents H or C! -C i 2 alkyl,

Ri 〇2 and 1 ^ 〇3 each independently represents 1 ^ or (: 1 -C4 alkyl group, and Rj104 is represented by Cl-R8 group. Used to prepare the composition U 1) a particularly preferred second crosslinked polymer The functional host compound is equivalent to formula (XXII) Please read the notice on the back before printing on the page printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

A-7

(XXI This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 public incineration) 526252 Μ B7 V. Description of the invention (secret) where A6 is Ce% and a? Is a direct bond or c 1 to c6 alkylene group, Phenylene or articulate group 'and A "3 represent -c〇OH, -C (0) -C1, -C (0) -Br, -C (0) -〇Rl 0 4 ,, C (〇) -NR! 〇2 Ri 〇3, _C (0) 0-C2 to ㈧ 2 courtyards — OH, c (〇) 〇-c2 to Ci 2 alkylene-〇-c (o) -ch = ch2 'Or -c (〇) (Nc2 to (^ 2 alkylene-0-c (0) -c (ch3) = CH2. As examples of difunctional host compounds, the following compounds can be mentioned: (I) (please first (Read the note on the back page)

: ΝχΜ c) -ο Order_

It can be synthesized from the equivalent of ammonium chloride, such as by reacting in a solvent such as anhydrous pyridine and adding one, preferably a large excess, of hydroxyethylmethyl. The acrylate is preferably dissolved in the same solvent. The final treatment can be carried out by slowly pouring the complete reaction mixture on ice that can contain acid like HC 1 -46- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 gong) 526252 Λ7 B7 Instructions (required), and precipitation occurs, which can be filtered and dried, for example by a vacuum pump. This crude precipitate can preferably be further purified, and the remaining hydroxyethyl methacrylate is removed by reprecipitation such as from chloroform into a large excess of hexane. The equivalent fluorenyl chloride can preferably be synthesized, preferably by reaction of an equivalent dibasic acid compound with thionyl chloride, preferably in a solvent like dry benzene. The reaction mixture can be heated to complete the reaction, for example to reflux temperature. It is preferred to remove the solvent and excess thionyl chloride using a nitrogen stream. Equivalent diacid compounds can be synthesized, for example starting from biphenyl-3,4,3-tricarboxylic acids, which can be carried out according to the method described by Zh · Org. Khini, 2 (7), 1288 (19 66) Obtained, by reaction with 3,4-diaminobenzoic acid, preferably in a solvent such as acetic anhydride. The obtained benzo [4,5bimizolo [2, bua] isoindazole-1 1-one dicarboxylic acid can be filtered and washed, for example, with water and methanol as usual, and can be further passed Purification is preferably performed by column chromatography using chloroform as the dissolution solvent. (II) (Please read the precautions on the back v IF page first)-Equipment-Line Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

It can be obtained from the equivalent tetraphenyl-benzo [4,5] imidazo [2, Ι-a] isoindene-11-one carboxylic acid chloride (available in a similar manner as the dibasic acid chloride described above). Obtained from the reaction with dipropenylamine, preferably dissolved in the same solvent, -47- This paper size applies Chinese National Standard (CNS) A4 specifications (210 father 297 public 5 526252 Λ7 B7 V. Description of the invention (from ) Initial synthesis. The final treatment can be carried out by pouring the complete reaction mixture onto ice water, washing with water to obtain the crude product and drying it. It can be further purified by column chromatography using chloroform as the solvent for the lysate. As Examples of trifunctional host compounds, the following compounds can be manufactured:

The preparation of this compound can be started from the equivalent trifunctional tetraphenyl-benzo [4,5] imidazo [2, Ι-a] isoindole-11-one, a 0H-derivative, and allyl chloride. , Preferably in a solvent such as dichloromethane. Final treatment can be carried out by injecting the reaction mixture into a large excess of water and then filtering K to produce a precipitate. If desired the crude product can be washed further, for example with water and methanol * and then dried, e.g. in the atmosphere under reduced pressure. The equivalent trifunctional OH-derivatives are preferably obtained by isopentaerythritol (in large excess) and tetraphenyl-benzo [4,5] oxazolo [2, Ι-a] isoindole-11- The reaction of a ketone-carboxylic acid chloride (obtainable by reacting a comparable carboxylic acid with thionyl chloride) is preferred in a solvent like anhydrous pyridine. The final treatment can be performed as usual and as described above. Monofunctional benzoU, 5] imidazo [2, bua] isoindio-110-ones are known or novel. The functional group may be selected from the group including halogens such as C1 and Br; -N3, epoxide, -OH '-SH' -CN '-NHR 1 〇〇, = C = NR 〇〇, -48- This paper size applies to China National Standard (CNS) A4 Specification (2 丨 0X297 Gongjun) (Please read the notes on the back first and then the page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 V. Description of Invention (叼) = CO ， -CH-0 ,-NCO, -CH = CHz, _C (CH3) = CHZ, -C (0) OH, -S03 H, -S02 Cl, -S02 Br, -C (0) -C1, -C (0) -Br , -ΟΠΟ) ,! 〇i, -0C (0)-NRi 〇2 Ri 〇3, -C (0) -0 Ri 〇4 »~ S〇2 -ORi 〇4, -C (0) -NRi 〇2 Ri 〇3 and -S〇z -NRi 〇2 Ri 〇3, wherein R100 represents H, alkyl, phenyl, or benzyl,

Rio 1 represents CjL-Cl 8, or phenyl, or benzyl,

Ri 02 and 103 each independently represent fluorene, Ci-Ci 8 alkyl, phenyl, or benzyl, and

Rl 0 4 represents Cl -Cjl 8 alkyl, phenyl, or carboyl.

Rio 〇 * R 1 ο 1 5 R 1 〇 2 f R 1 〇 3 ′ and R104 as the alkyl group preferably contain 1 to 12, more preferably 1 to 8 and most preferably 1 to 4 carbon atoms. More preferred functional groups are selected from the group consisting of alkyl groups bonded to halogens such as c 1 and Br; epoxides, -0H, -SH, -NHRlo, -CH = CH2, -C (C H3) = CHz,- NCO, -C (0) 0H, -C (0) -C1, -C (0) -Br, -C (0)-ORi 〇4 »-C (0) * ~ NRi 〇2 Ri 〇3 * where

Ri〇〇 means H or Ci-Cl2 alkyl,

RiO2 and RiO3 each independently represent H or C1-C4 alkyl, and RiO4 represents Ci-Rg alkyl. The best compound is equivalent to formula (XXIII) -49- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297 cm) (Please read the precautions on the back before

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Θ〇

(XXIII), 526252 Λ7 B7 V. Description of the invention (4 C6H5 cSh5 Τχ > Α ^ Α " C6Hs where a9 is a direct fluorene or Ci to c6 alkylene group, phenylene group or benzyl group, and A%

Represents -COOH, -C (0) -Cl, -C (0) -Br, -C (0) -ORi 〇4, -C (〇) -NRi 〇2 Ri 〇3 ^ _C (0) 0-C2 To Ci 2 alkylene-OH, C (0) 0-C2 to C χ 2 alkylene-0-C (0)-CH = CH2, or -C (0) 0-C2 to Ci 2 alkylene -0-C (0) -C (CH3) = CH2. An example of a monofunctional host compound used to prepare a composition (al) polymer is (Ph stands for phenyl): (Please read the precautions on the back and then the page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, where R3 4 is Cl, OH, ORi 〇4 and 〇4 represent Ci-Cs radicals, NRi〇2Rio3 and Rio2 and Ri〇3 each independently represent H, Ci-C4 alkyl Or C2 to (: 4-hydroxyalkyl, -C (0) 0-C2 to Ci 2 alkylene-0-C (0) -CH = CH2, -C (0) 0-C2 to fluorene 2 alkylene -0-C (0) -50- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) 526252 Λ7 B7 V. Description of the invention (吣 -c (ch3) = ch2, -C (0) 0NH-C2 to (:! 2 alkylene-oc (o)-CH = CH2, or -C (0) NH-C2 to Ci 2 alkylene-〇-C (0) -C (CH3) = CHz ;

Where R3 5 is a direct bond, methylene, ethylene, 2,2-propenyl, 0, S, NH, N (Ci to C4 alkyl), C (0) or C (0) NH, and R3 4 has the aforementioned definition;

Ph

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where R3 s has the former definition and R3 6 represents Η, C2 to C4 hydroxyalkyl, glycidyl or OR3 6 represents glycidyl or NHC2 to C4 hydroxyalkyl; and 51 -This paper size is in accordance with Chinese National Standard (CNS) A4 (210X 297), 526252 Λ7 B7 V. Description of the invention (θ

Ph

Ph

1 4-NH-C (0) -C (CH3) = ch2

NX > 0-C (0) -ch = ch2

Ph

0-C (0) -C (CH3) = CH2

Ph

Ph BU CH, -CH = CH,

(Please read the Caution page on the back first) The method for preparing such materials and compounds containing the polymer according to the ingredient (al) can be performed in an inert solvent. Inert means that the choice of solvent is determined by the reactivity of the components used, so the solvent is chosen so that no unwanted side reactions occur. Suitable inert solvents are, for example, protic polar and aprotic solvents, which can be used alone or in a mixture of at least two solvents. Examples are: water, alcohols (methanol, ethanol, propanol, butanol), ethylene glycol glycerol monomethyl mono or monoethyl ether, ethers (dibutyl ether, tetrahydrofuran, dioxane, ethylene glycol Dimethyl ether, ethylene glycol diethyl ether, diethylene glycol diethyl ether, triethylene glycol dimethyl ether), halogenated hydrocarbons (dichloromethane, chloroform, 1,2-dichloroethane, 1, 1, 2) Trichloroethane, 1,1,2,2-tetrachloroethane), carboxylic acid esters and lactones (ethyl acetate, methyl propionate, ethyl benzoate, 2-methoxyethyl acetate ， G- 丁 -5 2-This paper size is applicable to Chinese National Standard (CNS) A4 (210X297). Order printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 ------ B7 V. Description of the invention (0) @ vinegar 'd-valerolactone, pivalolactone), carboxylic acid amide and lactam; N, N-dimethylformamide, N, N-diethylformamide, N, N-dimethylacetamidamine'tetramethylammonium, hexamethylene phosphate triammonium phosphate, g-butyrolactam, buprolactam 'N-methylpyrrolidone, N-acetamidine N-methylpyrrolidone, N-methylcaprolactam; sublimines (dimethylidene I), Class (dimethylboron, diethylpyrene, trimethylene maple 'tetramethylene); tertiary amines (N-methylhexahydropyridine, N-methyl?), Aliphatic and aromatic hydrocarbons such as Petroleum ether, pentane, hexane, cyclohexane, methylcyclohexane, benzene or substituted benzene (chlorobenzene, o-dichlorobenzene, 1,2, 4-trichlorobenzene, nitrobenzene, toluene, dioxane Toluene) and nitriles (acetonitrile * propionitrile, benzonitrile, phenylacetonitrile), ketones (acetone, methyl isobutyl ketone). Suitable guest chromophores are those fluorescent molecules whose absorption wavelength covers the emission wavelength of the respective host. The guest molecules are preferably selected from those having a wavelength in the range of 380 to 8 G 0 nanometers and emitting fluorescence at a wavelength in the range of 400 to 7 8 Q nanometers. It is generally preferred that these guest molecules have a fluorescence quantum yield of from 0.1 to 1.Q, preferably from 0.3 to 1.0, more preferably from 0.5 to 1. G, and optimally from 0.7 to 1.0. . The fluorescent part printed as an object chromophore by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is selected from the group consisting of quinacridone's, diketopyrrolopyrrole, fluorescein, rhodamine, and coumarin Class, oxo, stilbene, benzyl, oxazole, cyanine pigments, peptide cyanine dyes, lanoline and styryl dyes. The guest molecules may be unsubstituted or substituted by F, Cl, Br, I, -CN, -N02, Ci to Ci 8 alkyl, C3 to Ci 2 cycloalkyl, C6 to Ci 8 aryl, C 5 to Ci 7 heteroaryl, C 3 to Ci 2 cycloalkynyl, cs to Ci 8 aralkyl, Cs to Ci 7 heteroaryl, h to Ci 8 -5 3-paper size Applicable to Chinese National Standards ^^^ By specifications 丨 210, / 297々 ^) ^ 26252 5. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy and Labor Λ7B7 __Invention Note (P) Alkoxy, C3 to Ci 2 ring Alkyloxy, c6 to Ci 8aryloxy 'to Ci 7 heteroaryloxy, C3 to Ci 2 cycloalkylalkoxy, cS to Ci 8, aralkyloxy, Cs to Cl 7 heteroaralkyloxy, Ci to (^ 8 alkylthio, C3 to Ci 2 cycloalkylthio, C 6 to Ci 8 arylthio, C 5 to ci 7 heteroarylthio, C3 to C i 2 cycloalkylalkylthio, Cs to ci 8 arylalkylthio, c5 to ci 7 heteroarylthio, C i to ci 8 alkyl-so- or -so2, C3 to Ci 2 cycloalkyl- SO-or-S〇2, c6 to Ci 8 aryl-s0- or -S02, c5 to Ci 7 heteroaryl-SO- or -S02, C3 to Ci2 cycloalkylalkyl-SO -Or -S02, C6 to "8aralkyl-SO- or S02, C5 "7heteroaralkyl-SO- or -SO2, a secondary amine group having 2 to 30 carbon atoms, and an alkoxyalkyl substitution having 2 to 20 carbon atoms. Cycloaliphatic and aromatic residues (Substituent) can also be substituted, for example by halogen like?, (: 1,81 ^, 1, or -〇 {^,-{{〇2, Ci to (: 18 alkyl, (^ to C 1 2 cycloalkyl, C6 to ci 8 aryl, C3 to Ci 2 cycloalkylalkyl, C 6 to Ci 8 aralkyl, C 5 to ci 7 heteroaralkyl, CX to ci 8 alkoxy , C3 to ci 2 cycloalkyloxy, Cs to Ci 8 aryloxy. Substituent alkyl can be straight or branched and can be substituted with halogen like F or C1. Examples of substituents are F, Cl, Br , Methyl, ethyl, propyl, butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxy'methylthio, ethylthio, methyl- or ethyl- SO-, methyl- or ethyl-Soz-, phenyl, benzyl, tolyl, xylyl, methylbenzyl, dimethylbenzyl, chlorophenyl, dichlorophenyl, methoxyphenyl , Dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl. -54- This paper size applies to China National Standard (CNS) Λ4 specification (2 10X297 (go to the public) Please read me back 1¾ Winter items

t 526252 \ Ί B7 V. Description of the Invention (iT3) The number of substituents is arbitrary and essentially depends on the possibility of synthesis and the optical properties and absorption of the fluorescent light required. Preferably, those guest molecules M are represented by the following formula:

NRn

8 ο R

(Please read the caution page on the back first)

And rhodamine residues, including those with the group = N + Roi iR〇12, where -55- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 gong) 526252 Λ7 B7 V. Description of the invention (W)

Ro 6, Ro 7 and Ro 8 are each independently fluorene or a substituent, or one of them is Ro and the other R7, Ro6, and 8 are each independently fluor or y or a substituent, or R 〇8 is Η and the other R07 and Ro6 are each independently Η or a substituent, B is Η or a substituent, R〇ii represents Ci to C2 alkyl, or is unsubstituted or passed through h to Ci 8-substituted phenyl or benzyl, 9 and i 0 each independently represents Η, Ci to C2 alkyl, or phenyl or benzyl which is unsubstituted or substituted with Ci to Ci 8 alkyl . i 2 is Η or C i to C 1 8 alkyl, please read the precautions first printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Commerce. These aromatic rings are unsubstituted or F f C 1 or Β r, I, -CN, -N02, Ci to C 1 8 alkyl, C3 to C i 2 ring radical, C 6 to C 1 8 aryl 9 C 5 to C i 7 heteroaryl, C 3 to C i Z cycloalkylalkane; m!, C 6 to c 1 8 arylalkyl, C 5 to C 1 7 heteroaralkyl, -C 1 mc 1 β alkoxy »C3 to Ci 2 cycloalkyloxy Radicals, C 6 to C! 8 aryloxy, 1 Cs to Ci 7 heteroaryloxy, C3 to ci 2 cycloalkyl radical, c6 to C 1 8 $ aryloxy 1 c 5 to C i 7 Heteroarylalkyloxy »Cl to C 1 8 alkylthio, c3 to ci 2 cycloalkylthio jc 6 to C i 8 arylthio, c5 to C 1 7 heteroarylthio * C3 to C i 2 Cycloalkylsulfanyl 9 Ce to Ci; 3 arylalkylthio, c5 to Ci7 heteroarylthio, ci to C1 8 alkyl-1 SO- or -S 0 2 C3 to IC! 2 Cycloalkyl-SO- or -S〇2 > Ce to C i 丨 3aryl-so- or -S〇2, C 5 to C i 1 f heteroaryl-so- or -S0 2, C3 to C 1 2 ring courtyard; courtyard -SO- or -S〇2, C 6 to C i 8 aralkyl-: 30- or S 0 2 9 -56- This paper size applies to China Standard (CNS) Λ4 specification (210X 297) 526252 Λ7 B7 V. Description of the invention (rf C5 to C i 7 heteroaralkyl-SO- or -S02), secondary amine with 2 to 3Q carbon atoms Radicals, and alkoxyalkyl radicals having 2 to 20 carbon atoms. Cycloaliphatic and aromatic residues can also be substituted, for example by F, C 1, B r, I, -CN, -N02 , (: 1 to (: 18 alkyl, 匸 3 to (: 12 cycloalkyl, Q to C: 8 aryl, C3 to Ci 2 cycloalkylalkyl,% to Ci 8 aralkyl, C 5 to Ci 7 heteroaralkyl, ci to Ci 8 alkoxy, c3 to Ci 2 cycloalkyloxy, C6 to Ci 8 aryloxy. The alkyl group may be substituted with a halogen such as F, C1 or Beta * More preferred substituents are F, Cl, Br, methyl, ethyl, propyl'butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxy, methylthio, Ethylthio, methyl- or ethyl-SO-, methyl- or ethyl-S02-, phenyl, benzyl, tolyl, xylyl, methylbenzyl, dimethylbenzyl, Phenyl, dichlorophenyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl group. R〇ii preferably represents h to ^ 8 alkyl, which may be straight or branched, or unsubstituted or phenyl or benzyl substituted with C 1 to C 2 alkyl, and Preferably, each independently represents fluorene, Ci to Ci 8 alkyl, or phenyl or benzyl which is unsubstituted or substituted with Ci to Ci 2 alkyl. Examples are methyl, ethyl, and propyl, butan , Pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, cetyl, ten Heptadecyl, octadecyl, undecyl, eicosyl, phenyl, benzyl, tolyl, ethylphenyl, propylbenzene-5 7-This paper size applies to China National Standard (CNS) A4 (210X297) Please read the matter on the back. Pi Order pi printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the invention) Butyl, pentyl, pentyl, hexyl, heptyl Isomers of phenyl, methylbenzyl, ethylbenzyl, propylbenzyl, butylbenzyl, pentylbenzyl, hexylbenzyl, heptylbenzyl, and octylbenzyl. R0 i 2 preferably represents C i to C i 2 alkyl, more preferably C 1 to R 8, and most preferred C i to C 4 alkyl. Suitable salts may be derived from inorganic or organic acids such as HC1, HBr, H2 S04, carboxylic acids such as acetic acid, chloro- or fluoroacetic acid, propionic acid, benzoic acid, chloro- or fluorobenzoic acid, and sulfonic acids such as methylsulfonic acid. , Chloro- or fluoromethylsulfonic acid, phenylsulfonic acid, tolylsulfonic acid, and chloro- or fluorobenzenesulfonic acid. A better object molecule is represented by the following formula: (Please read the precautions on the back ^ this page)

Printed by the Employees' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -58- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public description) 526252 Λ7 B7

CN C〇2CH2-CH (CH3) 2

ch (ch3) 2 CH (CH3) '3 ^ 2 (Please read the notes on the back ^ this page first) CHfCHJ. 〇CcHc OC.H. nu / nH ^

ch (ch3) 2 0c6h5 oc6h5 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Pigment precursors with removable alkoxycarbonyl groups, such as those described in EP-A-Q 654 711 are also preferred guest molecules. They have high solubility in a polar solvent as hereinbefore described, enabling the component (al) to be easily prepared and even molecularly dissolved pigments as guest molecules are easily regenerated by simple heat treatment after the component (al) is prepared. The guest molecules used as component U1) can be selected from the following, but not limited to them: diphenyldibutyldiketylpyrrolo [3,4-c] pyrrole, di- (m-methyl) Phenyl Ν, ίΓ-dibutyldiketopyrrolopyro [3,4-c] pyrrole * -59- This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 cm) 526252 A7 B7 V. Invention Instructions (Prostituted diphenyl N, N, -dibenzyl diketopyrrolo [3,4-c] pyrrole, please read the precautions before you fill out this page before di- (p-phenyl) benzene N, N, -dibutyldiketylpyrrolo [3,4-c] pyrrole, di- (p-methyl) phenyl N, N, -dibutyldifluorenylpyrrolo [3,4 -c] pyrrole, diphenyl N, N, -diethyldiketopyrrolo [3,4-c] pyrrole, di- (p, tertiaer-butyl) phenyl N, N, -di Methyldiketylpyrrolo [3,4-c] pyrrole, N, N'-bis (1-heptyloctyl) station-3, 4: 9,10-bis (dicarboxyamidoimine), N, N'-bis (businylnonyl) charge-3,4: 9,1 0_bis (dicarboxyamidoimine), ^ '-bis (bunonyldecyl) flower-3,4: 9,1 ( ) -Bis (dicarboximimine), ^, Di (budecylundecyl) north-3,4: 9,10-bis (dicarboxyamidoimine), N, N'-bis (budecyltridecyl) and -3 , 4: 9, iq-bis (dicarboxyamidoimine), In addition, ^ -bis (1-hexadecylheptadecanyl) 5 £ -3,4: 9,10-bis (dicarboxyamido) Amine), «," '-bis (buheptyloctyl) north-3,4: 9,10-bis (dicarboxyamidoimine), N, N, bis (buoctadecadecanadecanyl) And -3,4: 9, 10-bis (dicarboximide), the Ministry of Standards and Technology of the People's Republic of China, only the consumer cooperatives printed in N, N, -di (i-2,5 -di-tertiary Ding Phenyl) ®_3,4: 9,1Q-bis (dicarboxyamidoimine), N, N'dimethylquinacridone, N, M'diethylquinacridine, Ν, Ν'di Benzylquinacridone, Ν, Ν 'bis (o-chlorobenzyl) quinacridone, 60-This paper size applies to China National Standard (CNS) Λ4 specification (210X297 mm) 526252 A7 B7 V. Invention Description (q) H, N'bis (isopropyl) quinacridone, N, N'bis (n-butyl) quinacridone, luciferin, 2 ', 7'_dichlorofluorescein,

Lumogen queue compounds (BASF), rhodamine 6G, rhodamine 6G perchlorate, rhodamine 6G tetrachloroborate, rhodamine 19 perchlorate, rhodamine 110, rose red B, Rhodamine 116, Rhodamine 1 2 3. The solid composition (al) according to the present invention comprises a host chromophore and an effective amount of a guest chromophore. The weight between these host hair color bases and guest hair color bases is preferably 50:50 to 9 9 9 9: 1, more preferably 60:40 to 9 9 9: 1 and the best 7 0: 30 to 9 9 9: 1. The Central Bureau of Standards of the Ministry of Industry and Technology of the People's Republic of China only works on cooperative cooperatives. Another aspect of the present invention is to use the composition U1) linear (thermoplastic) polymer to prepare a semi-permeable network. By blending a polymer containing a host and a guest molecule with a polyfunctional comonomer or a multifunctional prepolymer, so that neither the host polymer nor the guest molecule participates in the polymerization reaction, but are entangled and dispersed in it, respectively, and Obtain a high fluorescent semi-permeable network. Alternatively, the guest molecules can be expanded by cross-linking the system in a solvent containing the guest molecules, and allowing him -61- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 526252 A7 B7

V. Description of the invention (We diffuse into the network and disperse in the cross-linking network. Preferred cross-linking systems include, but are not limited to, alcohol-isocyanate, amine-isocyanate, polyethenyl monomer, and more Prepolymers based on vinyl, prepolymers containing polypropenyl groups, amine-epoxy resins and acid-epoxy resins. Another aspect of the invention is the use of polymers of composition ui) to prepare permeate networks. The system preferably uses a host containing a side chain or an end group functional group that can participate in a cross-linking reaction with a polyvinyl or polyfunctional comonomer or prepolymer. K provides a high fluorescent cross-linking system. . These guest molecules are dispersed in the crosslinking reaction medium. Alternatively, if the cross-links swell in a solvent containing guest molecules, the guest molecules can diffuse into the network. Preferred crosslinking systems include, but are not limited to, alcohol-isocyanate, amine-isocyanate, polyvinyl monomer, polyvinyl-containing prepolymer, polypropylene-containing prepolymer, amine- Epoxy and acid-epoxy. The fluorescent molecule used as the main chromophore of the composition U2) of the present invention is benzo [4,5] imidazo [2,1-a] isoindio-11-11-one, preferably with the general formula ( I) means,

Member of the Central Bureau of Standards of the People's Republic of China has eliminated the cooperative cooperative seal (please read the notes on the back before filling out this page) ⑴, where the carbon atoms adjacent to the benzene rings 1 and 2 can be associated with benzene rings, heteroaromatic rings, aliphatic rings, Or -6 2-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 526252 A7 B7 5. Description of the invention (W) βι is also both, the blend ring part or heteroalicyclic ring is fused, And where the benzene ring 1 or 2: £ are all unsubstituted or substituted with an organic group. The group forming the fused ring is preferably selected from the formula: -N-CH = N-, -CH = C, -CH = CH-O- 5-, -CHz

"Η: = CH-CH = CH-, -CH

= CH-N = CH- »-CH = CH-CH = N H-NR3 7 _, -CH = N-CHz-, _CH Two CH members of the Central Bureau of Economic Affairs, τ Consumer Cooperative Co., Ltd. print water (CHz ) s-^-(CHz) 4-^ -CHz -CHz NRi -CHz --CHz -CH2 -NR3 7-J -CH2 -CHz -〇-c02 -ch2 -o-, -CHz -ch2 -s-ch2 -, _CH2 -CHz CHz S CH2 -0 -CH2 -CH2 -CH2 -0- J -CH2 -S CHz and CH2 -CH2- -S divalent residues; where h 7 is H or an organic substituent, and The divalent residue is unsubstituted or substituted with an organic group. R3 7 as an organic substituent may be a straight or branched Ci to C20 alkyl, C5 to C7 cycloalkyl, benzyl or R3 8 -C (0)-, where R3 8 is Ci to C 2 . Alkyl, which is unsubstituted or substituted with F, C 1 or Ci to Ci 2 alkoxy, or to C7 cycloalkyl, phenyl or benzyl, which is unsubstituted or substituted with F, C 1, C i to C 1 2 alkyl or C! To C i 2 alkoxy. Preferred examples of Ri are fluorene, methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, methylbenzyl, dimethylbenzyl, ethenyl, propionyl, butylfluorenyl, benzyl- C (0)-, phenyl-C (0)-, toluenyl-C (0)-, mono-, di- or tri-chloroethenyl and mono-, di- or tri-trifluoroacetamidine Group, mono- and dichlorophenyl-C (0)-. Organic substituents can be selected from the group consisting of halogen, -CN, No2, ^ to -63. This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the precautions on the back before filling in this Page) 丨 ._

, 1T Xian 526252 Judging by the Ministry of Confusion, printed by the Bureau of Jujube. T-Consumer Cooperatives printed A7 B7 V. Description of the invention (θ) C! Ci 8 via alkyl, Ci to Ci 8 dentyl, C3 to C! 2 ring alkyl, to Cl 8 aryl 'to (^ 1 7 heteroaryl' C3 to ^ 2 cycloalkyl alkyl, C6 to Ci 8 aralkyl, CS to Ci 7 heteroaralkyl, Ci to Ci 8 alkoxy, C3 to Ci 2 cycloalkoxy 'C6 to (^ 8 aryloxy, C5 to Ci 7 Heteroaryloxy, C3 to Ci 2 cycloalkylalkoxy, C6 to Ci 8 aralkyloxy, C 5 to C 1 7 heteroarylalkyloxy 'Ci to Ci 8 alkylthio , C3 to Ci 2 cycloalkylthio * c6 to Ci 8 arylthio, c5 to Cr 7 heteroarylthio, C3 to Cl 2 cycloalkylalkylthio, C6 to C 1 8 aralkylthio , C 5 to C i 7 heteroaralkylthio 'C i to Ci 8 alkyl, -SO-or-S02, C3 to Cl 2 cycloalkyl, -SO-or-S02, c6 to Ci 8aryl-so- or -so2, C5 to Ci7heteroaryl-so- or -S02, C3 to (^ 2 cycloalkylalkyl-SO- or -S02, C6 to. 8 aralkyl -SO- or S02, Ci to Ci 8 alkyl-CO-, C3 to Ci 8 cycloalkyl-C 0-, C 6 to Ci 8 aromatic -C 0 _, c 5 to ci 7heteroaryl-CO- > C3 to Ci 2 cycloalkyl alkynyl-CO-, C6 to Ci 8 aralkyl-co-, C5 to ci 7 heteroaryl -Co-, -NR3 9 IU O, alkoxyalkyl having 2 to 20 carbon atoms, polyoxyalkylene-0R4 2, -X- (R4 1) k -C (0 NR3 9 R4 〇 , -X- (lUiU-cm-OlUz,]-(^ 4 1) k ~ S〇2 -0R4 z 9 ~ X ~ (R4 i) k ~ S〇2 -NR3 9 R4 〇, -NH-C ( 0) -R4 2 and -0-C (0) -R4 2, where R3 9 and R4 0 each independently represent, for example, H, C i to c2 0 alkyl, ring-64- This paper standard applies Chinese National Standard (CNS ) Λ4 size (210X 297mm) '(Please read the precautions on the back before filling this page)

526252 A7 B7 ____ ----------- --_______________ ** One or five, description of the invention (β) amyl, cyclohexyl, phenyl, benzyl, Cl to Cl2 fluorenyl, ci to C j 2 alkane Benzyl, or R3 9 and "0 together represent either tetramethylene, pentamethylene, or the group _CH2 _CH2 KH2 -CH2 or -CH2 -CH2 -NR3 -CHz -CHz R3 is H or CA. Alkyl, R41 is (^ to ^ 2 alkylene, phenylene or benzyl, R4 2 represents C20 alkyl, cyclopentyl, cyclohexyl, benzyl, benzyl, ci to ci 2 alkylphenyl or ci to C! 2 benzyl, X is a direct bond, -0- or s, k is 0 or 1 and salts of these acids. Preferred salts are alkali metal salts and alkaline earth metals, such as from Li, Na, κ , Mg, Ca, Sr, Ba 0 Cycloaliphatic and aromatic residues (substituents of organic groups) can also be substituted by the Consumer Cooperatives of the Ministry of Standards and Technology of the Ministry of Standards. , -CN, -N02, Ci to "8 alkyl, C3 to C! 2 cycloalkyl, C6 to Ci 8 aryl, C3 to C! 2 cycloalkyl alkyl, Cs to Ci 8 aralkyl , C5 to Ci 7 heteroaralkyl, Ci to C: 8 alkoxy, C3 to Ci 2 cycloalkyloxy, Cs to C 1 8aryloxy. In the context of the present invention, the organic substituent substituent alkyl may be straight or branched and contains preferably 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 Up to 6 C-atoms and especially good 1 to 4 C-atoms. Some examples are A-65- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297 male f) 526252 A7 B7扃 Working Consumer Cooperatives Co., Ltd. Yin Ling V. Description of the invention (You; 1 1 I group> Ethyl, n-propyl or isopropyl $ n-one, iso- or third butyl t and 1 1 1 pentyl $ hexyl , Heptyl, octyl% stilbyl f decyl 9 undecyl 5 und 1 1 alkyl f 13 tridecyl $ 14 tetradecyl $ 15 pentadecyl 9 deca alkyl S 17 please 1 1 Read | Isomers of alkyl and octadecyl groups 0 4: back I side I In the context of the present invention the organic substituent halogen may be F y C1 Note 1 I means 1 I 9 Br or I and preferably F Or C 1 c Item 1 I 1 In the context of the present invention, an alkenyl group having a 4m m group substituent may be linear or branched 1% \ ti l.'J in this chain and contains preferably 2 to 12 C-atoms 9 more preferably 2 To 8 C-atomic% top 1 1 good 2 to 6 C-atoms and particularly good 2 to 4 C-atoms 0 some examples are ethylene 1 1 I alkenyl 9 propenyl 9 methyl vinyl 9 but- 1-ene- 4-yl 9 but-2--ene- 4_ 1 1 group $ but-3-fu-4-yl, 3-methyl-propyl + alkenyl 3-yl and pentenyl 1 hexenyl , Heptenyl% octenyl 9 nonenyl, decenyl undecenyl 9 1 I dodecenyl, tridecenyl, tetradecenyl pentaenyl $ decaenyl 1 1 1 17 Isomers of alkenyl and octadecenyl group 0 1 1 In the context of the present invention, the organic group substituent alkynyl may be straight or branched (chain and contains preferably 2 to 12 C-atoms) &gt; more preferably 2 to 8 C-atoms &gt; up to 1 1 best 2 to 6 C-atoms and particularly preferred 2 to 4 C-atoms 0 * Some examples are ethynyl 9 alkynyl 9 crotonyl 9 methyl ethynyl 9 but-butyne-4 -yl &gt; but-2-yn 1 1 1 -4 -yl:, butane 3-alkyn-4-yl 5, 3 -methyl-prop-1--1-yn-3-yl $ and propynyl 1 1 hexynyl, heptynyl, octyl Alkynyl 9 nonynyl, decynyl y undecynyl 1 1 dodecynyl 9 tridecynyl &gt; tetradecynyl, pentaynyl decaV- alkynyl 1 1 t heptynyl and Isomers of octadecynyl group 01 I In the context of the present invention, the organic substituent hydroxymethyl may be straight chain or 1 1 I-66 1 — 1 1 This paper is applicable to Chinese National Standard (CNS) Λ4 Specifications (210X297 male f) 526252 A7 B7 V. Description of the invention (κ) branched chain and contains preferably 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 to 6 C-atoms and Particularly preferred are 1 to 4 C-atoms. Some examples are hydroxymethyl, hydroxyethyl, n- or iso-hydroxypropyl, n-iso- or tertiary-hydroxybutyl, and hydroxypentyl, hydroxyhexyl, hydroxyheptyl, hydroxyoctyl, hydroxynon Hexyl, hydroxydecyl, hydroxyundecyl, hydroxydodecyl, hydroxytridecyl, hydroxytetradecyl, hydroxypentadecyl, hydroxyhexadecyl, hydroxyhexadecyl and hydroxy Isomers of octadecyl. In the context of the present invention, the organic substituent haloalkyl may be straight or branched and contains preferably 1 to 12 C-atoms, more preferably 1 to 8 0-atoms, most preferably 1 to 6 C-atoms. And particularly good 1 to 4 C-atoms. The halogen may be F, Cl, Br or I, and preferably F and C1. Some examples are chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chloroethyl, n- or iso-chloropropyl, n-, iso- or Third-chlorobutyl, perfluoroethyl and perfluorobutyl. Printed by the Central Bureau of Standards, S <_T. Consumer Cooperatives. In the context of the present invention, the organic substituent cycloalkyl contains preferably 4 to 8 and more preferably 5 to 7 ring carbon atoms. Examples are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl and cyclododecyl. Preferred groups are cyclopentyl and cyclohexyl. In the context of the present invention, the organic substituent aryl may be Czeki or better phenyl. In the context of the present invention, the organic substituent heteroaryl contains preferably 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or 2 heteroatoms selected from the group consisting of 0, S and N. Some examples are pyrimidinyl, pyrimidinyl, furanyl, pyran-67- This paper size is applicable to the Chinese Standard (CNS) Λ4 specification (210X 297 male f) 526252 Λ7 ___ B7 V. Description of the invention (recognition) And thiophenyl. In the context of the present invention, the organic group substituent cycloalkyl-alkyl is preferably cycloalkyl-methyl or -ethyl, and cycloalkyl preferably represents cyclopentyl or cyclohexyl. In the context of the present invention, the organic substituent aralkyl is preferably arylmethyl or -ethyl, and aryl preferably represents phenyl or naphthyl. Some examples are benzyl, phenethyl and naphthylmethyl. In the context of the present invention, the organic substituent heteroaralkyl is preferably heteroarylmethyl or -ethyl, and heteroaryl preferably contains 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or Two heteroatoms selected from the group consisting of 0, S and N. Some examples are pyridylmethyl or monoethyl, pyrimidinyl, furylmethyl, pyrrolylmethyl and thiophenylmethyl. In the context of the present invention, the organic substituent alkoxy may be straight or branched and preferably contains 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 to 6 C- Atoms and particularly preferred 1 to 4 C-atoms. Some examples are methoxy, ethoxy, n- or iso-propoxy, n-iso- or tertiary-butoxy, and pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy Base, decyloxy, ^ -oxyl, twelve-oxyl, tridecyloxy, tetradecyloxy Printed base by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, pentadecyloxy, hexadecane Isomers of oxy, heptadecyloxy and octadecyloxy. In the context of the present invention, the organic substituent cycloalkyloxy preferably contains 4 to 8 and more preferably 5 to 7 ring carbon atoms. Examples are cyclopropoxy, cyclobutoxy, cyclopentyloxy, cyclohexyloxy, cycloheptyloxy, cyclooctyloxy and cyclododecyloxy. Preferred radicals are cyclopentyloxy and cyclohexyloxy. -68- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 cm) '' &quot; &quot; 526252 Λ7 B7 V. Description of the invention U;? In or better 5 or 6 S and N furan Some examples are cyclic or cyclohexyl in aryl. Some examples are heteroaromatic and preferred. Furanyl is branched and most preferably 1 methylthio, thio, organic substituents in the context of the present invention. The aryloxy group may be a naphthyloxyphenoxy group. In the context of this invention ring atoms and preferably 1 to (Please read the notes on the back first

-Mai P (this page), r Γ Heteroatom printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Some real oxy, pyrrolyloxy alkyl-methoxy or -ethyl in the context of the present invention. The organic substituent heteroaryloxy in the context of the present invention preferably contains 3, more preferably 1 or 2 selected from Including 0, examples are pyridyloxy, pyrimidinyloxy, and thiophenoxy. The organic group substituent cycloalkyl-alkoxy group is more oxy group, and the cycloalkyl group preferably represents a cyclopentyl organic group substituent arane and the aryl group preferably represents a phenoxy group, a phenylethoxy group, and a naphthylmethoxy group. In the context of a radical, the organic substituent is heteroaryl and the heteroaryl group preferably comprises 2 selected from the group consisting of 0, oxy or -ethoxy is benzylmethyl. The present invention is methyl 1 to 3. Some examples are methoxy. Included to 6, ethylthio or monoethyl, more preferably 1 or pyridylmethoxy or monoethoxy, in the context of pyrrolylmethyl containing 1 to 12 oxygen and thiophenylmethoxy organic substituents Alkylsulfur C-atoms, more preferably 1 to C-atoms and particularly preferably 1 to 4 C-atoms, n- or iso-propylthio, n-, and pentylthio, hexylthioundecanethio The group, dodecyl, heptylthio, octylthioalkylthio, and tridecylthiooxy are preferably aryl or naphthyl. The 10 alkyloxy group is preferably a heterocyclic pyrimidinyloxy group having 5 or 6 ring atoms S and N. The radical may be straight-chain or 8 C-atoms,. Some examples are iso- or tertiary-butane, nonylthio, decyl, tetradecanesulfur 69- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public #) Employees of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative printed 526252 Λ7 V. Description of the invention (β) isomers of pentadecylthio, hexadecylthio, heptadecylthio and octadecylthio. The organic group substituent cycloalkyl in the context of the present invention preferably contains 4 to 8 and more preferably 5 to 7 ring carbon atoms. Examples are cyclopropylthio, cyclobutylthio * cyclopentylthio, cyclohexylthio, cycloheptylthio, cyclooctylthio and cyclododecylthio. Preferred groups are cyclopentylthio and cyclohexylthio. In the context of the present invention, the organic substituent arylthio may be naphthylthio or preferably phenylthio. In the context of the present invention, the organic substituent heteroarylthio preferably contains 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or 2 heteroatoms selected from the group consisting of 0, 3 and 1 ^. Some examples are pyridylthio, pyrimidinylthio, furylthio, pyrrolylthio, and thiophenylthio. In the context of the present invention, the organic substituent cycloalkyl-alkylthio is preferably cycloalkyl-methylthio or -ethylthio, and cycloalkyl preferably represents cyclopentyl or cyclohexyl. In the context of the present invention, the organic group substituent aralkylthio is preferably arylmethylthio or -ethylthio, and aryl preferably represents phenyl or naphthyl. Some examples are benzylthio, phenylethylthio and naphthylmethylthio. In the context of the present invention, the organic substituent heteroarylalkyl is preferably arylmethylthio or monoethylthio, and heteroaryl preferably contains 5 or 6 ring atoms and more preferably 1 to 3, more preferably 1 or 2 selected from heteroatoms including 0'S and N. Some examples are pyridylmethylthio or -ethylthio, pyrimidinylthio, furylmethylthio, pyridylmethylthio, and thiophenylmethylthio. -70- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210 × 297) (please read the notes on the back before this page) Order 526252 Λ7 B7 V. Description of the invention (present) In the context of the present invention The organic substituent -so-or-S〇2-may be straight or branched and preferably contains 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 to 6 C-atoms and particularly preferred 1 to 4 C-atoms. Some examples are methyl-so- or -so2-, ethyl-SO- or -S02-, n- or iso-propyl-SO or-S〇2-, n-, iso- or tertiary-butyl -so- or S〇2-, and pentyl-SO- or -S〇2 hexyl-SO- or-S〇2 heptyl-SO- or-S〇2-, octyl-so-or-S〇 2 Nonyl-SO- or -S〇2 * 'decyl-SO- or -S〇z-, undecyl-so-or-S〇2 dodecyl-so-or -S〇2- Tridecyl-so-or-S〇2-, tetradecyl-so-or-S〇2-, pentadecyl -so- or -so2-, cetyl-so- or -so2 -, Heptadecyl-SO- or -S02- and octadecyl-SO- or -S02- isomers. In the context of the present invention, the organic radical is f-substituted cycloalkyl-SO- or -so2-preferably containing 4 to 8 and more preferably 5 to 7 ring carbon atoms. Examples are cyclopropyl-so- or -so2-, cyclobutyl-so- or -so2-, cyclopentyl-so or -so2-, cyclohexyl-SO- or -S〇2-cycloheptyl-SO -Or -S02-, cyclooctyl -SO-or -S02-and cyclododecyl -SO- or -so2-. Preferred groups are cyclopentyl-SO- or -S02- and cyclohexyl-so- or -S02-. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. In the context of the present invention, the organic substituent aryl-SO- or -s02- may be naphthyl-SO- or -S02- or preferably benzene-SO. -Or -S02- group. In the context of the present invention, the organic substituent heteroaryl -SO or -S02-preferably contains 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or 2 selected from the group consisting of 0, S and N Heteroatoms. Some examples are pyridinyl-SO- or -S 02-, pyrimidinyl-so- or -S 02-, furanyl-SO- or -S 02-, pyrrole-71- This paper is for China National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 A7 B7 V. Description of the invention (7C) -SO-or-S〇2-and thiophenyl-SO- so2-. In the context of the present invention, the organic substituent cycloalkyl-alkyl-S0- or -so2-is preferably a cycloalkyl-methyl-SO- or -so2-or -ethyl-so- or -S02- , And cycloalkyl preferably represent cyclopentyl or cyclohexyl. In the context of the present invention, the organic substituent aralkyl-so- or -so2-is preferably arylmethyl-SO-or -so2-or -ethyl-so-or-so2-, and aryl is preferred Represents phenyl-SO- or -S02- or naphthyl-SO __- S02-. Some examples are benzyl-so- or -so2-, phenyl-so- or -S02-and naphthylmethyl -S 0-¾ -S 0 z-0 in the context of the present invention. -So- or -S 〇2-is preferably heteroarylmethyl-so- or -so2-or -ethyl-so- or -so2-, and heteroaryl preferably contains 5 or 6 ring atoms and Preferably 1 to 3, more preferably 1 or 2 are selected from heteroatoms including 0, S and N. Some examples are pyrimidinylmethyl-so- or so2- or -ethyl-so- or -so2, pyrimidinyl-so- or -S02-, furylmethyl-S0- or -S〇2- , Pyrrolylmethyl-S0 or -S02- and thiophenylmethyl-so- or -so2-. In the context of the present invention, the organic substituent alkyl-C0- may be straight or branched and preferably contains 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 to 6 C-atoms and particularly preferred 1 to 4 C-atoms. Some examples are methyl-CO-, ethyl-co-, n- or iso-propyl CO-, n-, iso- or tertiary-but_co-, and pentyl_co_, hexyl_co_, heptyl _Co_, octyl-C0-, nonyl_C0_, decyl-C0-, undecyl_C0_, dodecyl-C0-, tridecyl-C0-, tetradecyl-C0 -; Pentadecyl-co-, hexadecane-72- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public #_) (Please read the precautions on the back page first)

, 1T 526252 Λ7 B7 V. Description of the invention (々 丨) Isomers of -C0-, heptadecyl-C0- and octadecyl-C0-. In the context of the present invention, the organic substituent cycloalkyl-C0- preferably contains 4 to 8 and more preferably 5 to 7 ring carbon atoms. Examples are cyclopropyl-C 0-, cyclobutyl- C0-, cyclopentyl-C0-, cyclohexyl-C0-, cycloheptyl-C0-, cyclooctyl-C0- and cyclododecyl- C0-. Preferred groups are cyclopentyl-C0- and cyclohexyl-C0-. In the context of the present invention, the organic substituent aryl-C0- may be naphthyl-C0- or preferably phenyl-C0-. In the context of the present invention, the organic substituent heteroaryl preferably contains 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or 2 heteroatoms selected from the group consisting of 0, S and N. Some examples are pyridyl, pyrimidinyl, furyl, pyrrolyl and thiophenyl. In the context of the present invention, the organic substituent cycloalkyl-alkyl-C0- is preferably cycloalkyl-methyl-C0- or -ethyl-C0-, and cycloalkyl preferably represents cyclopentyl or Cyclohexyl. In the context of the present invention, the organic group substituent aralkyl-C0- is preferably arylmethyl-C0- or -ethyl-C0-, and aryl preferably represents phenyl-C0- or naphthalene central standard Bureau employee consumer cooperative printed base-C0-. Some examples are benzyl-C0-, phenethyl-C0- and naphthylmethyl-C0-. In the context of the present invention, the organic substituent heteroarylalkyl-C0- is preferably heteroarylmethyl-C0 -Or -ethyl-C0-, and heteroaryl preferably contain 5 or 6 ring atoms and preferably 1 to 3, more preferably 1 or 2 heteroatoms selected from the group consisting of 0, S and N. Some examples are pyridylmethyl-C0- or -ethyl-C0-, pyrimidine-73- _________; __ This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 gong) 526252 Λ7 B7 V. Description of the invention ( 7 B) pyridyl-C0-, furylmethyl-C0-; atrylmethyl-C0- and thiophenylmethyl-C0-. In the context of the present invention, the organic substituent alkoxyalkyl may be straight or branched and preferably a total of 2 to 12 C-atoms, more preferably 2 to 8 C-atoms, most preferably 2 to 6 C -atom. An alkoxy group may contain 1 to 4 C-atoms. . Some examples are methoxyethyl, methoxyethyl, methoxypropyl, methoxybutyl'methoxypentyl, methoxyhexyl, ethoxymethyl, ethoxyethyl, ethoxypropyl, ethyl Oxybutyl, ethoxypentyl, ethoxyhexyl, propoxymethyl and butoxymethyl. In the context of the present invention, the organic substituent polyoxyalkylene-O-Rs preferably contains 2 to 12 and more preferably 2 to 6 oxyalkylene units, of which the alkylene group is preferably an ethylene group, 1 , 2- or 1,3-propenyl or 1,2-, 1,3- or 1,4-butynyl. R6 is preferably fluorene or Ci to C4 alkyl. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. In the context of the present invention, R3 9 and R4 may be straight or branched in the sense of an alkyl group and contain preferably 1 to 12 C-atoms, more preferably 1 Up to 8 C-atoms, most preferably 1 to 6 C-atoms and particularly preferably 1 to 4 C-atoms. Some examples are methyl, ethyl, n-propyl or isopropyl, n-, iso- or tert-butyl, and pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl , Dodecyl, tridecyl, tetradecyl, pentadecyl, cetyl, heptadecyl and octadecyl isomers. In the context of the present invention, the meanings of R3 9 and O in the alkylphenyl group are preferably C 1 to C 8 alkylphenyl, and C 1 to C4 alkylphenyl. Some examples are methylbenzyl, ethylphenyl, n- or iso-propylphenyl, n-, iso- or tertiary--74- This paper size applies to Chinese national standard (〇 ~ 5) / \ 4 specifications (210 乂 297) 犮 526252 Λ7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (? 3) Butyl, hexyl, octyl, dodecyl, and di Tolyl. In the context of the present invention, the meanings of 9 and R4 0 in alkylbenzyl are preferably C 1 to C8 alkylbenzyl, and c i to C4 alkylbenzyl. Some examples are methylbenzyl, ethylbenzyl, n- or iso-propylbenzyl, n-, iso- or tert-butylbenzyl, hexylbenzyl, octylbenzyl, dodecylbenzyl, and Dimethyl section base. In the context of the present invention, R3 9 and R4 0 are preferably each independently η, Ci to C4 alkyl, cyclohexyl, phenyl, benzyl, (1 to (4 alkylbenzyl), or 9 and R4. —Indicates or tetramethylene, pentamethylene, or —CH2 ~ C Η 2-0-C Η 2 -C Η 2-0 In the context of the present invention R4 i is more important in the meaning of alkylene Preferred are fluorene to C6 alkylene, and Ci to C4 alkylene, such as methylene, ethylene, propylene or butyl. The most preferred R4 is methylene, ethylene, phenylene or Benzyl. In the context of the present invention R 4 2 may be a straight or branched chain in the sense of an alkyl group and contains preferably 1 to 12 C-atoms, more preferably 1 to 8 C-atoms, most preferably 1 to 6 C-atoms and particularly preferred 1 to 4 C atoms. Some examples are methyl, ethyl, n-propyl or isopropyl, n-, iso- or tert-butyl, and pentyl, hexyl , Heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, cetyl, heptadecyl and octadecyl Isomers of alkyl. R4 2 is preferably fluorene, Ci to Ci 2 alkyl'cyclopentyl, cyclohexyl Phenyl, benzyl. -75- ^ Zhang scales are applicable to China National Standards (CNS) Λ4 specifications (210X 297 Gong Jun) (Please read the precautions on the back page π)-Installation · Line 526252 Λ7 ______ Β7 — I. _____ —- — 5. Description of the invention (made)

Examples of substituents are F, Cl, Br, methyl, ethyl, propyl, butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxymethylthio, ethylthio , Methyl_ or ethyl-so-, methyl- or ethyl_s02 phenyl, benzyl, tolyl, xylyl, methylbenzyl, dimethylbenzyl, chlorophenyl, dichlorobenzene Methyl, methoxyphenyl, dimethoxyphenyl, methoxyphenyl-methoxybenzyl, CH3 -C0_, C6 C0-, ch3 _co ~ o-, C6 H5 C ο 0… CH3-S〇2 -0 —, C6 h "s〇2 -〇-, -nh2, -nhch3, -NHC2 Hs, -NHC8 Hi 7, -N (CH3) 2 '_C °° H' C〇CH3» -C0-0C2 Hs »SO3 Η »-S〇2 -0CH3» S〇2 0Cz… C0-NH2, -C0-NCH3, -CO-NHC2 Hs, -C0-NHC8 Hi 7, -C〇- NH (CH3, -SOz-NH2, _s 〇2 &quot; * NHCH3, -s〇2 -NHC2 H5, -S〇2 -NHCs H! 7, -s〇2 -N (CH3) 2 'Hz N-S〇2-, methoxymethyl, methyl Oxyethyl, ethoxyethyl,-(OCH2 CH2) 2 ~ 〇Η »-CN and -NO2 ° The number of substituents is arbitrary and essentially depends on the possibility of synthesis, the required optical properties and fluorescence Light absorption, depending on required solubility Ministry of Economic Affairs Bureau of Standards printed in a consumer cooperative employees preferred embodiment of the present invention, the compound of formula (I) equivalent to the formula X X I V,

R

(XXIV), -76- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210 × 297) while printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. β4 4, fU S and R4 S are each independently fluorene, C i to C 1 8 alkyl, ci to ci 8 alkoxy, ci to C i 8 alkylthio, aryl, aralkyl, ci to C i 2 alkyl-aryl or Ci to Ci 2 alkyl-aralkyl, and ring 2 is unsubstituted or substituted as described above, including these preferred substituents, preferably at least one R4 3, R4 4 R4 5 and R4 6 are one of the substituents defined. More preferably R4 4 and R4 5 are one of the substituents defined. Most preferably R4 3, R4 4, R4 S and R4 6 are substituents. In the context of the present invention R4 3, IU 4, R4 5 and R4 S may be straight or branched in the sense of alkyl and contain preferably 1 to 12 C-atoms, more preferably 1 to 8 C- Atoms, preferably 1 to 6 C-atoms and particularly preferably 1 to 4 C-atoms. Some examples are methyl, ethyl, n-propyl or isopropyl, n-, iso- or tert-butyl, and pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl , Dodecyl, tridecyl, tetradecyl, pentadecyl, cetyl, heptadecyl and octadecyl isomers. In the context of the present invention R4 3, R4 4, R4 5 and IU β may be straight or branched in the sense of alkoxy and preferably contain 1 to 12 C-atoms, more preferably 1 to 8 c -Atoms, preferably 1 to 6 C-atoms and particularly preferably 1 to 4 C-atoms. Some examples are methoxy, ethoxy, n- or iso-propoxy, n-, iso- or tert-butoxy, and pentyloxy, hexyloxy, heptyloxy, octyloxy , Nonyloxy, decoxy, fluorene--alkoxy, dodecyloxy-77- This paper size applies to China National Standard (CNS) A4 specification (210X 297 cm) (Please read the precautions on the back before reading) (This page)

Order 526252 Λ7 B7 V. Description of the invention (Exo) Tridecyloxy, tetradecyloxy, pentadecyloxy, hexadecyloxy, heptadecyloxy and octadecyloxy Thing. In the context of the present invention R4 3, R4 4, R4 5 and R4 6 may be straight or branched in the sense of alkylthio and preferably contain 1 to 12 C-atoms, more preferably 1 to 8 C -Atoms, preferably 1 to 6 C-atoms and particularly preferably 1 to 4 C-atoms. Some examples are methylthio, ethylthio, n- or iso-propylthio, n-, iso- or tertiary-butylthio, and pentylthio, hexylthio, heptylthio, octylthio, Nonylthio, decylthio, undecylthio, dodecylthio, tridecylthio, tetradecylthio, pentadecylthio, cetylthio, heptadecylthio and Stearyl isomers. In the context of the present invention R4 3, IU 4, R4 5 and R4 6 may be naphthyl or preferably phenyl in the meaning of aryl. In the context of the present invention, R4 3, R4 4, R4 5 and R4 6 may be aromatic radicals, preferably arylmethyl or -ethyl. And aryl preferably represents phenyl or naphthyl. Some examples are phenyl, phenethyl and naphthylmethyl. In the context of the present invention, IΪ4 3, β4 4, 5 and IU 6 in the meaning of alkyl-aralkyl may preferably be alkylbenzyl, more preferably Ci to C6 alkylbenzyl, and most preferably Cl to c4 Alkyl benzyl. Some examples are tolyl, ethylbenzyl, n- or iso-propylbenzyl, n-, iso- or fluorene butylbenzyl, hexylbenzyl, octylbenzyl, dodecylbenzyl, and dimethyl BenQ. In the context of the present invention, the meaning of R43, R44, β45 and R46 in alkylbenzyl may be alkyl-benzyl, more preferably Ci to (: 8 alkylbenzyl, and most preferably C i to C4 alkylbenzyl. ~ Some examples are methyl benzyl_ 7 8-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 Gongjun) 'Please read the notes on the back

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the invention (&lt; 7), ethylbenzyl, n- or iso-propylbenzyl, n-, iso- or tertiary, butyl, hexyl Benzyl'octylbenzyl'dodecylbenzyl, and dimethylbenzyl. In a particularly preferred embodiment of the present invention, ring 2 is also substituted, particularly at the 7-position, at the 8-position, or both by organic substituents. In a particularly preferred embodiment of the present invention, the compound of formula I is equivalent to the compound of formula xxv,

I 2

R 47 (XXV), where R 4 3 R 4, R 4 5 and R 4 S are phenyl or C i to c alkyl phenyl. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. R 4 7 is fluorene or organic substituent, and R 4 8 is Η or an organic substituent, or ring 2 is substituted with 1 or 2 groups selected from -CH = CH-CH = CH-. Ring 2 is preferably mono-substituted, meaning that at least one of R 4 7 and R 4 8 is an organic substituent. R4 3, R4 4, R45 and R4 6 are particularly preferably phenyl. Throughout the present invention, the definition of R4 7 and R4 8 in organic substituents is preferably selected from the group consisting of -CN, No2, (^ to (^ 8 alkyl, to cl8). ) Λ4 specification (210X 297g t) 526252 Λ7 Β7 ____ V. Description of the invention (#) Alkenyl, C2 to C i 8 alkynyl, C: to C i 8 controlled alkyl group 'C 1 to C 1 8 haloalkyl , C 3 to C i 2 cycloalkyl, C 6 to C 1 8 aryl 'C 3 to ci 2 cycloalkyl-alkyl, Cs to C i 8 arylalkyl' C 1 to C 1 8 alkyloxy , C3 to Ci 2 cycloalkoxy, C6 to ci 8 aryloxy '' C3 to Ci 2 cycloalkylalkoxy, C 6 to Ci 8 arylalkyloxy 'C 1 to C 1 8 alkane Thio, C3 to Ci 2 cycloalkylthio, C6 to C 1 S arylthio 'C3 to c A 2 cycloalkyl-alkylthio, C6 to C is aralkylthio, ci to Ci 8 alkyl -CO-, C3 to (^ 8 cycloalkyl_C0- 'C6 to Ci 8 aryl-C 0-, C 3 to Ci 2 cycloalkylalkyl-c 0-, c 6 to c 1 8 Aromatic group -C0_, -HR3 9 R4 0, oxyalkylene group having 2 to 20 carbon atoms' polyoxyalkylene-0R4 2, _P (IU 1 _C (0) -NR3 9 β4., _X-( R4 i) kC (0) -OR4 2, small (R4 1) kS〇2 -〇β4 2 '-χ -(R4 i) k-S02 -NR3 9 IU 〇, -NH-C (0) -R4 2 and -〇-C (〇) -R4 2, of which the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs printed R3 9 and R4o is each independently, for example, fluorene, c1 to c2ofluorenyl'cyclopentyl, cyclohexyl, phenyl, benzyl, ei to Clz alkylbenzyl to Ci2 alkylbenzyl, or R3 9 together with "〇 Table or tetramethylene, pentamethylene, or -CH2 -CH2 -0-CH2 -CH2-or -CH2 -HR3 -CH2 -CH2-, R3 is H $ Ci to Ce alkyl group R4 1 is ( ^ To Cl 2 alkylidene, benzyl or benzyl 'R4 2 represents H, Ci to C20 alkyl' cyclopentyl 'cyclohexyl' benzyl, benzyl, ci to Ci 2 alkylphenyl or ci To Ci 2 alkylbenzyl, -80- This paper size applies Chinese National Standards (CNS) Λ4 specifications (210X297 prostitutes) 526252 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ___ Β7 V. Description of the invention (7f) X is Directly, or s, k is 0 or 1 and the salts of these acids. The foregoing preferred definitions are also valid for the definitions of R4 7, R4 8, X and R3 9 to IU 2. R4 7 and R4 8 in the definition of the organic substituent are preferably selected from the group consisting of -CN, No2, C1 to C1 8 alkyl, C to C! 8 hydroxyalkyl, C5 to C 7 cycloalkyl, C s to Ci aryl, C 7 to Ci aralkyl, C ^ to Ci 8 alkoxy, c3 to Ci 2 cycloalkoxy, C6 to Ci. Aryloxy, C5 to C7 cycloalkyl-alkoxy, C7 to Cii aralkyloxy, Ci to Ci 8 alkylthio, C5 to C7 cycloalkylthio, C6 to Ci 0 arylthio, c5 to c7 cycloalkyl-alkylthio, c7 to C ii aralkylthio, -C i to ci 8 alkyl-C 0 _, C 5 to C 7 cycloalkyl-C 0 -, C s to Ci 0 aryl-CO-, C5 to C7 cycloalkyl-alkyl-CO-, c7 to Cjl aralkyl-CO-, -NR3 9 R4 〇, having 2 to 12 carbons Atomic Oxygen and Oxygen 'Polyoxyalkylene-0 "2,-$-(" 1) ^ (:( 0) 41 {3 9 ^ 4〇,-乂-U4 1) k_C (0) -0R4 2 , -X_ ("1) kS〇2 -0IU 2 '-X- (R4 1) kS〇2 -NR3 9 R4 〇, -NH-C (O) -R4 2 and -〇-C (0) ~ R4 z, wherein R3 9 and R4 are each independently, for example, H, C 1 to alkynyl, cyclopentyl, cyclohexyl, phenyl, benzyl 'c 1 to C s phenyl or C 1 to C 6 , Or R3 9 and 5U—indicates or tetramethylene, 5-8 1-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X297), (Please read the precautions on the back side of this page first β page ) • Equipped · 、 -mouth line 526252 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 Description of the invention (and) methylene, or the group -CH2_CH2 -O-CHz -CH2-, R4 1 is Ci to C4 alkylene, phenylene or benzyl, R4 2 represents fluorene, C: to C i 2 alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, Cl to C6 phenyl or Cl to fluorenyl, X is a direct bond, -0- or s' k is 0 or 1 and this Isoacid salts. In a particularly preferred embodiment of the present invention, R4 7 and R4 8 are selected from the group consisting of -N0 2, Ci to Ci 8 alkyl, which are straight or branched, ci to ci 8 alkane An oxy group, which is a straight or branched chain, -C (0) 0H, or -C (0) -0 ~ Ci to c 1 8 alkynyl. The compound moiety of formula I is known or can be easily obtained from Unsubstituted or substituted o-phenylenediamine and unsubstituted or substituted peptidic anhydride are prepared, for example, as described in EP-A-0 4 5 6 6 0 9. Composition U2) used in the present invention is regarded as The fluorescent part of the guest chromophore (or "guest polymer") is derived from a guest molecule as described above, which is covalently linked (directly or via a bridging group) to the polymer backbone. The bridging group can be independently selected from the disclosure The bridging group of the above-mentioned main chromophore polymer includes Example Preferably the solubility object monomeric structure is induced in K quickly they can help themselves the solution polymerization or the polymerization may be generally rapid dissolution in the comonomer mixture. Effective solvents for use in solution polymerization are known to the artisan and have been mentioned above. 1 8 2-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297g t) (Please read the precautions on the back before this page)

1T-line

Br, I, -CN NOz ring 526252 Λ7 ____B7 V. Description of the invention (57) A better guest molecule is selected from the group consisting of monovalent residues including quinacridinium, diketopyrroylpyrrole, rhodamine, and northern class. These optimally selected guest molecules may be unsubstituted or F, C1 Ci to Ci8 alkyl, C3 to alkyl, C6 to Cχ 8 aryl, C5 to Ci 7 heteroaryl, C3 to C: 2 cycloalkylalkyl, Cs to C1 8aralkyl, Cs to C: 7 heteroaralkyl, ci to Ci8 alkoxy, c3 to Ci2 cycloalkyloxy C6 to Ci 8 aryloxy, C 5 to Ci 7 heteroaryloxy, C3 to Ci 2 cycloalkylalkoxy, Cs to ci 8 arylalkoxy, C5 to Ci 7 heteroaryl Alkyloxy, Ci to Ci 8 alkylthio, C3 to Ci 2 cycloalkylthio, Cs to Ci 8 arylthio, Cs to Ci 7 heteroarylthio, c3 to Ci 2 ring Alkyl alkylthio, C6 to Ci 8 aralkylthio, C 5 to C 1 7 heteroarylthio, Ci to Ci 8 alkyl-SO- or -SOz, c3 to Ci 2 cycloalkyl -SO- or -S02, c6 to Ci 8aryl-SO- or -S02, c5 to Ci 7 heteroaryl-so- or -S02, c3 to Ci 2 cycloalkylalkyl- so- or -S02, C6 to Ci 8 aralkyl-SO- or S〇2, c5 to ci 7 heteroaralkyl-SO- or -S02, secondary amine group having 2 to 30 carbon atoms , And alkoxyalkyl substituted with 2 to 2G carbon atoms. Cycloaliphatic and aromatic residues (substituents) can also be substituted, for example by halogens such as F, C1 or Br, or -CN, -N02, Ci to Ci8 alkyl, C3 to ci2 ring Alkyl, C6 to Ci 8 aryl, C3 to C 1 2 cycloalkylalkyl, C s to ci 8 aralkyl, C s to C i 7 heteroaralkyl, ci to C i 8 alkoxy , C3 to C 1 2 cycloalkyloxy, C6 to C 1 8 aryloxy. -83- This paper size applies to Chinese National Standard (CNS) Λ4 specification (21〇X 297 cm) Please read the note at the back first

Page Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the Invention (β) The substituent alkyl group may be straight or branched and may be substituted by halogens such as F or Cl. Examples of substituents are F, Cl, Br, methyl, ethyl, propyl, butyl, hexyl, methoxy, ethoxy, propoxy, butoxy, hexyloxy, methylthio, ethylthio Methyl, methyl- or ethyl-SO-, methyl- or ethyl-S02-, phenyl, dry, tolyl, xylyl, formamyl, dimethyl benzyl, chlorophenyl, digas Benzoyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl. The number of substituents is arbitrary and depends essentially on the possibility of synthesis and the required optical properties of fluorescence and absorption. The better unit price fluorescent part is used as the object hair color base, which is selected from the unit price residues with the following formula (please read the notes on the back first)

, TT Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

B

And This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297g t) 526252 Λ7 B7 V. Description of invention (β) 巳

(Please read the precautions on the back before 'The salt printed by Rhodamine residues of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, including salts with base = N + R〇i iRo, where Ro 6 is a R7 and R08 are independently fluorene or a substituent, or one of R07 is fluorene and the other R07, Ro6, and R8 are each independently fluorene or a substituent, or R8 Η and other R07 and RoS are each independently Η or a substituent, B is Η or a substituent, β〇1 1 represents C i to C 2 0 alkyl, or is unsubstituted or substituted by C i To Ci 8 alkyl substituted phenyl or benzyl, β〇9 and R〇10 each independently represent η, ci to C 2 alkyl, or benzene which is unsubstituted or substituted with Ci to Ci 8 alkyl Or benzyl. Β〇 β2 is Η or Ci to CX 8 alkyl, whereby these rings are unsubstituted or substituted by F, C1 or Br, I, -CN, -N02'C i to ci 8 alkyl, C3 to Ci 2 cycloalkyl, C6 to Ci 8 aryl 'to Ci 7 heteroaryl, C3 to Ci 2 cycloalkylalkyl, C6 to Ci 8 aralkyl, C 5 to C i 7 heteroaralkyl, C i to C i 8 alkoxy, C3 -8 5 ~

、 1T -age-This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297) while 526252 Λ7 B7 5. Description of the invention (tear) to C 1 2 cycloalkyloxy, CS to C 1 8 aromatic oxygen , C 5 to ci 7 heteroaryloxy, C 3 to ci 2 cycloalkylalkoxy, C 6 to C i 8, aralkyloxy 'C 5 to ci 7 heteroaralkyloxy, C 1 To C1 8 alkylthio, c3 to C 1 2 cycloalkylthio, C 6 to Ci 8 arylthio, C 5 to ci 7 heteroarylthio 'C3 to Ci 2 cycloalkylalkylthio, C6 to Ci 8 aralkylthio, c5 to Ci 7 heteroarylthio, Ci to Ci 8 alkyl-so- or -s02, c3 to Cl 2 cycloalkyl-SO- or -S02, C6 to (^ 3aryl or -S〇2, C5 to Ci7 heteroaryl-so- or -so2, c3 to cA2 cycloalkylalkyl-SO- or -S02, C6 to (^ 8aralkyl-so- Or s〇2,

Cs to C 1 7 heteroaralkyl-SO- or -S02, a secondary amine group having 2 to 30 carbon atoms, and an alkoxyalkyl group having 2 to 20 carbon atoms. Cycloaliphatic and aromatic residues can also be substituted, for example by F, C 1, B r, I, -CN, -N 0 2, C 1 to C! 8 alkyl, C 3 to C 2 cycloalkane Group, C6 to Ci 8 aryl, C3 to C ^ 2 cycloalkylalkyl,% to Ci 8 aralkyl, C5 to ci 7 heteroaralkyl, Ci to Ci 8 alkoxy, c3 to ci 2 cycloalkyloxy, c6 to C i 8 aryloxy. The substituent alkyl may be straight or branched and may be substituted with a halogen such as F, C1 or Br. The Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs printed better substituents as F, Cl, Br, methyl, ethyl, propyl, butyl, hexyl, methoxy, ethoxy, propoxy, butoxy , Hexyloxy, methylthio, ethylthio, methyl- or ethyl-so-, methyl- or ethyl-s02-, phenyl, benzyl, tolyl, xylyl, methylbenzyl The group 'dimethylcarbyl' chlorophenyl, dichlorophenyl, methoxyphenyl, dimethoxyphenyl, methoxybenzyl, dimethoxybenzyl. -86- This paper size applies Chinese National Standard (CNS) Λ4 specification (21〇X 297 public) 526252 Λ7 ___ B7 V. Description of invention (political) R〇ii means better Ci to (^ 8 alkyl, which can be Straight or branched ′ ′ or unsubstituted or phenyl or benzyl substituted with C i to C 1 2 alkyl, and R 9 and R 0 i 0 preferably each independently represent Η, C i to C! 8 Alkyl, or phenyl or benzyl unsubstituted or substituted with Ci to Ci 2 alkyl Examples are methyl, ethyl, and propyl, butyl, pentyl, hexyl, heptyl, octyl , Nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, cetyl, heptadecyl, octadecyl, nineteen Alkyl, eicosyl, phenyl, benzyl, tolyl, ethylphenyl, propylphenyl, butylphenyl, pentylphenyl, hexylphenyl, heptylyl, octylphenyl, methylbenzyl, Isomers of ethylbenzyl, propylbenzyl, butylbenzyl, pentylbenzyl, hexylbenzyl, heptylbenzyl, and octylbenzyl.

Ro i 2 preferably represents C i to C i 2 alkyl, more preferably c i to R 8 alkyl and most preferably C i to C 4 alkyl. Suitable salts can be derived from inorganic or organic acids, such as HC 1, ΗBr, Hz S04, carboxylic acids such as acetic acid, chloro- or fluoroacetic acid, propionic acid, and benzoic acid. Printed by the Consumer Cooperatives of the Central Standards Bureau, Ministry of Economic Affairs. Mono- or fluorobenzoic acid, sulfonic acids such as methanesulfonic acid, chloromono- or fluoromethylsulfonic acid 'phenylsulfonic acid, tolylsulfonic acid, and chloromono- or fluorobenzenesulfonic acid. More preferably, the fluorescent part of the hair color base of the object is a residue of the following formula: _ 8 7-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 Gongchu) 526252 Λ7 B7 5. Description of the invention (advise) C = 0 〇

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs These object parts are bound to the structural unit of the main chain via functional groups. Examples of functional groups are -0H, -SH, -NH2, -NflR2, -CH = 0, carboxylic acid _ 8 8-This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 526252 Λ7 B7 V. DESCRIPTION OF THE INVENTION (sy), -S03Η, epoxide, vinyl or isocyanate, wherein R2 is preferably Η or CJL to C4 alkyl. The polymers may be selected from the same natural polymers or synthetic polymers as disclosed in composition U1). Examples are given above. The guest chromophore bonded to the polymer can be derived from a monofunctional or multifunctional guest molecule. Preferably such molecules are mono- to trifunctional, and even more preferably mono- or difunctional. The polymer may be composed of monovalent and divalent residue-containing monomer units having a covalently-bonded guest chromophore, and optionally from other comonomer units, if desired. These polymers having a covalently-coupled guest chromophore can be homopolymers or copolymers. The monomer unit containing the guest (designated as m) is preferably M 0 · 0 0 1 to 0 · 5, more preferably 0 · 0 1 to 0 · 3, and most preferably 0 · 0 0 1 to 0 · 〇5. The scope exists. Non-fluorescent monomer units (designated as η) are in the range of 0 to 0.999, whereby m and η are typically selected so that m + n = 1. These polymers can be composed of repeating structural units of formula (XXVI) printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy

Guest (XXVI), or may be composed of repeated cross-linking units of formula (XXVI a), used alone or in combination with structural units of formula (XXVla) A.-Guest — A,-

I I (XXVIa), of which -89- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public trend) 526252 \ Ί ____________ Β7_ V. Description of the invention (network)

Ai and A3 are trivalent organic residues,

Guest is a monovalent or divalent fluorescent moiety that serves as the color base of the guest. As previously defined, it is also covalently coupled directly or via a bridging group, whereby A i and A 2 can be copolymerized when used in combination. The polymer may additionally include structural units of the formula (XX VII) -A4-(XXVII) where A4 represents the same or different divalent residues copolymerizable with Ai and / or A3, and A4 may be derived from the optional Includes olefins, polyolefins like mono-, di- or triolefins, polyols like diols and triols, polyamines like diamines and triamines, polyisocyanates like di- or triisocyanates, polycarboxylic acids Acids like di- and tri-carboxylic acids, and polyepoxides like di- and tri-epoxide monomers. The structural element of formula (XXVI) may be present in an amount of κ 0 · 0 1 to 50% by weight, preferably 0.1 to 30% by weight, more preferably 0.1 to 5% by weight, and most preferably 0.1 to 3% by weight . The elements of the printed cooperative (XXVI a) structure of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs may be M 0. 01 to 50 wt.%, Preferably 0. 1 to 30 wt.%, More preferably 0. 1 to 5 wt. The polymer is preferably present in an amount of from 0.1 to 3% by weight. In a preferred embodiment, the polymers according to the present invention include a repeating structural unit of formula (XXVIII), and optionally a repeating structural unit of formula (XXIX) -90- ^-526252 A7 ΒΊ 5. Description of the invention One c one c— (XXVIII), R6 Xr (Ri) r- (x2) sR3-Guest (XXIX), ^ (please read it first)

8 110 RICIR 7-9 RICIR π page) and X2 are independent of each other and x2 are independent of each other. Directly, $ Λ Ω, 0-(; (0, -0-c (0)-0 -NR2- c (0)-j -c (0) &gt; -NR2 -C (0) NRz NRz -soz -〇-, Printed by the Consumer Cooperatives of the Central Standards Bureau, Ministry of Economic Affairs -0-, -S-, -NR2- , -C (〇) -0-, -S〇2 -0- ^ -〇-S〇2-J -〇-S〇2 0 nf * (0)--NR2 _, -NR2 -C (0) -〇-, 0--, -NRz _ S〇2-, -s〇2 〇2 _NR2-or -NR2, S〇2 _NR2-'

Ri represents a divalent bridged group ’

Guest represents a monovalent fluorescent guest chromophore, R2 represents an alkyl group, C5 or Cs cycloalkyl 5 or 6-cycloalkylmethyl or _ethyl, phenyl, benzyl or phenylethyl R3 represents a direct bond , 8 alkylene group, Cs- or C6 -cycloalkyl group, C6. Arylene or C7 -Ci 2 aralkylene, -91- This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 526252 Λ7 B7 V. Description of the invention (Products 1 »and 3 are independently indicated 〇 or 1, but the condition is that if S is 0, r is 0, R4 and 1 ^ each independently represents Η, h-C6 alkyl, C6 〇 alkyl or C7-Ci 2 aralkyl, R6 Represents H or a group-(:( 0) 0-1 i, R7 represents Cl 'Cl alkyl' _Ci 〇aryl or C7 -Cl 2 aralkyl, R8 represents Η, F, Cl, CN, Ci -C6 Alkyl or C6_Ci ο aryl, R9 represents Η, Ci -Cs alkyl or -C (0) 0 ·! ^ !,

R10 represents H, Cl -Ce alkynyl '-Cl o aryl, C7 -Cl 2 aralkyl, imidazolyl, pyrrolidone, F, Cl, CN or group -Xi-(Ri) r-( X2) s-H 'and

Ri! Represents H, K, Na, C1-Cl8 alkyl, Cl-Cl8 hydroxyalkyl, cyclohexyl, cyclopentyl, cyclohexylmethyl, phenyl, Ci-C4 alkylphenyl, benzyl or "- "Alkylbenzyl. For X1, X2, R1, R2, R3, r, s, and Guest, the meanings and preferred embodiments are valid for the structural elements of formulas XXVI11 and XXIX, as described above. R4 and R5 as alkyl preferably represent C i -C4 alkyl, such as methyl, ethyl, n- or iso-propyl and n-, iso- or third-butyl; as aryl, naphthalene is preferred Or phenyl, and as the aralkyl group are preferably benzyl. Particularly preferred is fluorene, and RS is fluorene or methyl. Brother 6 is better to indicate Η '-C (0) 0H or -C (O) to 〇-Ci -C4's burning base -92 This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 cm) Please first Read the note_ f Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Μ B7 V. Description of the invention (Xi /) R 7 as an alkyl group preferably represents a C 1 -C 4 alkyl group, such as methyl, ethyl, n -Or iso-propyl and n-, iso- or tertiary-butyl; naphthyl or benzyl is preferred as the aryl group and benzyl is preferred as the aralkyl group. R7 is particularly good. R8 as the alkyl group preferably represents a Ci-C4 alkyl group such as methyl, ethyl, n- or iso-propyl and n-, iso- or third-butyl; and for aryl, naphthyl or benzene is preferred And as the aralkyl group, benzyl is preferred. Particularly preferred R8 is fluorene, C1, CN, phenyl or C ^ to C4 alkyl. R9 as alkyl preferably represents Ci-C4 alkyl, such as methyl, ethyl, n- or iso-propyl and n-, iso- or tertiary-butyl. In the group -C (0) 0-hi, Rii preferably represents only or an alkyl group, more preferably Ci-C6 alkyl, such as methyl, ethyl, propyl'butyl'pentyl'hexyl'heptyl, Octyl, nonyl, decyl, undecyl, dodecyl, tetradecyl, cetyl and octadecyl. Particularly preferred R9 is fluorene, C (0) 0H or -c (0) -O-Ci -C4 alkyl C 4 alkyl, such as methyl

Ri 〇 as the alkyl group is better means C printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economics, please read the notes on the back first ethyl, n- or iso-propyl and n-, iso- or third-butyl; and as Aryl is preferably phenyl and naphthyl; and as aralkyl is preferably benzyl. R10 preferably represents fluorene, Ci-C4 alkyl, phenyl, pyrrolidinyl, F, Cl 'CN or the group -X!-(Ri) r- (X2) s-H.

Ri 1 may be, for example, 1 ^, &amp;, ^, (: 1-(: 6-alkyl, (^-(: 6-alkyl, cyclohexyl, cyclopentyl, cyclohexylmethyl, phenyl, tolyl) , Benzyl or methylbenzyl. -93- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 cm) 526252 \ Ί ~ ____ Β7 5. Description of the invention (^ 二) Structural element of formula (XXVIII) It may be present in an amount of 0.00 to 5G% by weight, preferably 0.1 to 30% by weight, more preferably 0.1 to 5% by weight, and most preferably 0.1 to 3% by weight, relative to the total polymer The structural element of formula (XXIX) may be present in an amount of 0 to 99.99% by weight, preferably 10 to 99. 9% by weight, and more preferably 50 to 99. 9% by weight, relative to the polymer's Total weight: Polymers with structural elements of the formula (XX VIII) and optional (XXIX) can be cross-linked with polyfunctional monomers, for example, with Q · D1 to 80% by weight, preferably 0.1 to 1 60% by weight of monomer, relative to 100 grams of polymer. Depending on the type of polymer, at least trifunctional acetic acid, isocyanates, alcohols, amines, vinyls or Oxides. In addition, residues containing at least two olefinic (olefinic) unsaturations can be used. The ethylenically unsaturated cross-linking agent can be selected from the group consisting of divinylbenzyl, bis-methyl maleene Imine-olefin groups such as bis- (dimethylin-aleinimidyle) -methylene or -ethylene, polyols (preferably diols to tetraols) or polyamines Respectively, preferred diamines to tetraamines are acrylic- or methacrylic acid esters or -amidoamines. The preferred ethylenically unsaturated cross-linking agent printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs is selected from the group consisting of Especially preferred are 2 to 12, and especially preferred are 2 to 8 C-atomic aliphatic, cycloaliphatic and cycloaliphatic-aliphatic diols to tetraols and diamines to tetraamines acrylic or methacrylic acid Some examples of such glycols are alkanediols such as ethylene glycol, 1,2- or 1,3-propanediol, 1,2-, 1,3- and 1,4-butanediol, pentanediol , Hexanediol, octanediol, decanediol, dodecanediol, cyclohexanediol, bis (hydroxymethylcyclohexyl-94-) This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297飨) 526252 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (household) Burning, obtained from the polyoxygen compound of the diols of the better C2 compound, which is selected from the better 2 to 1Q0 Alcohol units 'are more preferably 2 to 50 calcined diol units, and most preferably 2 to 2 Q alkanediol units. Like for example polyethylene glycol' polypropylene glycol, polybutylene glycol and polyethylene / polypropylene glycol, further 1 , 1,1 ~ trihydroxymethylethane or monopropane, isoprene tetraol and diisoprene tetraol. Some examples of polyamines are ethylenediamine, 1,3- and 1,3-propanediamine '1,2-' 1,3- and ι, 4-butanediamine, 1,6-hexanediamine, di Ethylenetriamine, triethylenetetramine, cyclohexanediamine, (aminemethyl) cyclohexylamine, isophoronediamine and bis (aminemethyl) cyclohexane. In a preferred embodiment of the present invention, the polymers include a structural element V of the formula (XXX) ——C—C — HX ^ \-(X2) S ^ 3-Guest (XXX), wherein Ri2 is Η or methyl, and χ, χ2, Ri, R3, Guest, 1 &gt; and s have the same meanings as the foregoing, including preferred embodiments; and structural elements of optional formula (XXXIX) if necessary. -X!-(Ri) r- (X2:) s-R3-is better represented in structural elements of formula (xxxx) -c (o) -o-, -c (o) -o-cz alkylene Radical-〇- c (0)-

, -C (0) -0- (C2 -c6 alkylene-〇) uc (〇) 'has a number of u of 2 to 10, -0-C (0) -C6 Hs -〇-c (0b H5 —or -〇-C (0)-C: to C ^ 2 alkylene group. -95- This paper size applies to China National Standard (CNS) Λ4 specification (210X 297). (Please read the note on the back first Matters on this page) Order 丨 fox. 526252 Λ7 B7 12 V. Description of the invention) Polymers with structural elements of formula (XXVIII) or (XXX) and optional structural elements of formula (XXIX) may optionally include formula ( XXX) the same or different structural elements

H R-C-c-(XXXI), where RiZ, Xi, X2, r and s have the aforementioned definitions, including preferred embodiments. These structural elements are especially present when the groups Host and Guesy are introduced to the polymer via a reaction between the side functional groups on the polymer and the functional groups on the respective host and guest molecules. Polymers having structural elements of formula (XXVIII) or (XXX), and optionally having structural elements of formula (XXIX), preferably contain structural elements with the same or different formula (XXXII) as the better formula (XXIX) Unit i-lli--I -11 — ^ n-i ϋ— 1 --- taxi.n! Ml--I II one V US., -Port (please read the precautions on the back P page first)

Η 丨 C—H 12-1 3 RMICIR1

XI X (X printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

Ri 2 represents fluorene or methyl, and

Ri 3 represents fluorene, Ci -C4 alkyl, Ci -C4 alkoxy, -CN, Cl, phenyl, pyrrolidinyl, pyridinyl, imidazolyl, C (0) 0 R i 4 or -C ( 0) H 5 Ri 6,

Ri 4 said? 1 or (: 1 -Ci 8-and preferably "-Ci 2 alkyl, and Ri 5 and Ri 6 each independently represent Η or Ci -Ci 2-, and preferably (^ -9 6-this paper size Applicable to Chinese National Standard (CNS) Λ4 specification (210X297 Gongchu) 526252 Λ7 — B7 V. Description of the invention (Boundary) ~~ -C 6 alkyl group. It has structural elements of formula (XXVIII) or (XXX), and it may be as necessary _Selection of the same or different structural element formula with the meaning 丨 meaning 丨 or the polymer with the formula ^ ": ^, may additionally include the structural element of the formula (XXXIII) or (XXXIV) as the preferred unit of the crosslinking agent ,

ICIH I HICIH

X! X (X

121 RI ο.- I HIC3IH C -R1 3 -X c (

HICIH 121 RICI

XIV X X Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

Ri 2 represents fluorene or methyl, X3 represents -0-, -ΝΗ-or-N (Ci -C4 -syndyl)-, and R17 represents C2 -Ci 2-and preferably Ci -Ce alkylene, Cyclohexylene 'cyclohexane dimethylene, phenylene, or X3 represents -0- and 7 represents C2 -C6 alkynyl-(C2 -Cs alkylene-0) 2 to 2 0 -C2- C6 alkylene. The polymerization product and preferably the aforementioned polymerization product may further contain the same or the same ionic structural element, such as the formula (XXXV) -97- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297) Chu 526252 Λ7 B7 V. Invention Description (

HR 12 -cc— II R18 R19 (XXXV), where Ri 2 represents H or methyl, Ri 8 represents H and Ri 9 represents-C (0) 0R2 〇, -S〇3 Η 4 ~ C 0 0 R ζ 〇, ~ C 6 Η 4 ~ S 0 3 R ζ 〇 ~ C 6 Η 4-R 2 ι or -C (0) -X4 -C2 -C6 Abrasion group -Rz 2, X4 means -0- or- NH-, Ri 8 and Ri 9 each independently represent _C (0) 0R2 〇 or -C (0) -X4-C2 -Ce intensive group 2 * R2 〇 represents an alkali metal, preferably Li, Na or K, R21 represents an ammonium group or an ammonium methyl group, and Rz 2 represents an ammonium group. The ammonium group or ammonium in the ammonium methyl group may be derived from a primary, secondary or tertiary amine group; a quaternary ammonium group is preferred. Ammonium or ammonium in ammonium methyl can be equivalent to the formula (XXXVI) -NR23R24R25 (XXXVI), please read the note on the back first

Pi i

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of IT and Economy

Wherein Rz 3, R2 4 and Rz 5 are each independently fluorene, C i -C 8-, preferably Cl -Cl 2-and more preferably Ci -Cs alkyl, C 5-or Cs cycloalkyl, phenyl, benzyl Phenyl, phenyl-2-ethyl, or R2 3 and R4 together as tetramethylene, pentamethylene or-CH2 CH2 -0-CH CH2-; Rz has the definition as previously described -98- The Zhang scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 Gongchu) 526252 Λ7 B7 V. Description of the invention (? 7) Appropriate relative anions can be derived from inorganic or organic acids, such as for example osmic acid, sulfonic acid and halogen acid . Preferred relative anions are chloride and bromide. The polymerization product and preferably the aforementioned polymerization product may additionally contain a structural element having an acid group like, for example, -C (0) OH or -S03 当, especially when it relates to an emulsion polymerization product. Structural elements with acid groups can be equivalent to the formula (XXXVII) (Please read the precautions on the back first

2 I 6 1-2 RICIR _27 H-CIR (XXXVII), "this page"

Ri2 represents fluorene or methyl, 'R2 7 represents Η and R2 6 represents _C (0) 0H, -S03 H, -C6 H4 -COOH, -C6 H4 -S03 H, or 6 and Rz 7 represent ~ C (0 ) 0H. Polymers having amine or acid groups are preferably soluble in water or they can be prepared by emulsion polymerization in which monomers are dispersed and / or dissolved. In another preferred embodiment, the polymers according to the present invention can be crosslinked with difunctional guest molecules. These polymers may contain repeating structural elements of formula (XXXVIII), alone or in combination with structural elements of formula (XXX), V ^ 3〇 ί- ΐ —C —C— -c—c — 11 I ′

H Xr (R1) r- (X2) s * R3-Guest-R3- (x2)-H (XXXVIII), where

Ri, ruler 3, Ri2 »Xi» Xz, r, s and a Guest-with the above-99-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public carboxylic acid) 526252 Λ7 B7_____ V. Description of the invention (F) the meaning given, including the preferred embodiment. The structural element of formula (XXXVIII) may be 0.01 to 5 G% by weight of the κ polymer, preferably 0.1 to 3 (3% by weight, more preferably 0.1 to 5% by weight, and most preferably 0. It is present in an amount of 1 to 3% by weight. The above-mentioned crosslinked polymer having one or both of the structural elements of the formula (XXXVIII) may include the formula (XXVI), (XXVII), (XXXI), (XXXIII), (XXXIV) (XXXV), (XXXVI) and (XXXVII) structural elements, alone or in any combination of at least two of these structural elements, or may contain residues of the preferred formulae (XXIX), (XXX) and (XXXII) Structural elements, and further (XXXXIII), (XXXXIV), (XXXXV), (XXXXVI), and (XXXXVII), alone or in any combination of at least two of these structural elements. Structures of some formula (XXX VIII) The best example of the unit is (please read the precautions on the back page first)

、 -IT Η 印 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -CH0

• c / ^ ch2

〇

H line -1 0 0-This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 297 public capital) 526252 kl B7 V. Description of the invention (lamp) Η -c -CH-

Please read the note below for details t Printed by the Consumer Cooperatives of the Central Standards Bureau, Ministry of Economic Affairs These polymers according to the invention can be random, block, graft or emulsion polymers (lattice). The preparation of the polymers and their fixation in the art are known and can be performed as described for the polymers of the composition (al). These monomers are partly novel and partly known or they can be prepared by known or similar methods. Functional guest chromophores are known or can be synthesized by similar methods using known or their synthesis using selectively protected functional intermediates. The guest chromophore can be obtained from a chromophore precursor containing a H Η-group by reaction with a haloalkane which additionally contains a functional group such as a carboxyl group or a vinyl group. Polyfunctional guest compounds can be prepared in a manner which is incompatible with the method described in document EP-A 0 337 951. -101- This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 cm) 526252 Λ7 B7 V. Description of the invention (furnace) The solid composition (a2) according to the present invention contains a main color base and an effective amount Object hair color base. The weight between the host hair color base and the guest hair color base is preferably 5 Q: 50 to 9 9 9 9 · 1 'is more preferably 6 0: 4 0 to 9 9 9: 1 and the best 7 o: 30 to 9 9 9: 1. Another aspect of the present invention is the preparation of a semi-permeable network using the composition U2) straight (thermoplastic) polymer. By blending a guest-containing polymer with a host molecule of a multifunctional comonomer or a multifunctional prepolymer, the guest polymer or host molecule does not participate in the polymerization reaction, but is entangled and dispersed in it, respectively, to obtain High fluorescent semi-permeable network. Alternatively, the host molecules can be dispersed in the cross-linking network 'by expanding the cross-linking system in a solvent containing the host molecules and allowing them to diffuse into the network. Preferred crosslinking systems include, but are not limited to, alcohol-isocyanate, amine-isofluoroester, polyvinyl monomer, polyvinyl-containing prepolymer, polypropylene-containing prepolymer, amine- Epoxy and acid-epoxy. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Another aspect of the present invention is the preparation of an internally permeable network using a polymer of the composition U 2). The system preferably uses a guest polymer comprising a side chain- or end-group functional group that can participate in a cross-linking reaction with a polyvinyl or polyfunctional comonomer or prepolymer to provide a high fluorescent cross-linking circuit. These host molecules are dispersed in the crosslinking reaction medium. Alternatively, if the cross-linked compound swells in a solvent containing a host molecule, the host molecule may diffuse into the network. Preferred crosslinking systems include, but are not limited to, alcohol-isocyanate, amine-isofluoroester, polyvinyl monomer, polyvinyl-containing prepolymer, polypropylene-containing prepolymer, amine- Epoxy and acid-epoxy. -102- This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297) 526252 Λ7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (Η) Further preferred embodiments of the invention Related is a mixture of a host compound of the present invention and a guest polymer of the present invention. According to the present invention, the host polymer and the guest polymer (hereinafter abbreviated as `` 'ister product b') are preferably the same as those described earlier in the compositions (al) and (a2), respectively. These polymers are incorporated herein For reference, including host and guest chromophores, and preferred embodiments of such polymer backbones. Composition (b) is, for example, a blend of linear (thermoplastic) polymers. Generally preferred Individual polymers are compatible, K is determined to be effective, preferably completely * the occurrence of energy transfer between host and guest components. Composition (b) is, for example, a host chromophore containing a covalent knot Repeating structural unit, and thermosetting resin containing dissolved and uniformly distributed guest chromophores, or guest chromophores with covalent knots, and repeating structural units containing dissolved and uniformly distributed host chromophores. Preferred thermosetting The resin is composed of ethylenic unsaturated monomers, which have been described in the polymers (a 1) and (a 2) of the above components. M is incorporated herein for reference, including preferred embodiments. Another aspect of the invention is the use Preparation of the (b) semipermeable network of the polymer. By blending the polymer containing the host and the equivalent polymer containing the guest with a polyfunctional comonomer or a polyfunctional prepolymer, the host polymer Neither the guest molecules nor the polymer molecules participate in the polymerization reaction, but they are entangled in the resulting meltable network, which can produce a high fluorescent semi-permeable network. Preferred crosslinking systems include, but are not limited to, alcohol-isocyanate, amine-isocyanate, Polyvinyl monomer, prepolymer containing polyvinyl, prepolymer containing polypropylene -103- (Please read the precautions on the back first

This page) Threading This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 hours) ^ 6252 Λ7 ^ _____ 5. Description of the invention (fO ^) ’Amine-epoxy resin and acid · epoxy resin. Another aspect of the present invention is the preparation of a semi-permeable network using the polymer of composition (b), in which a host polymer or a guest polymer can participate in a network formation reaction. The host polymer or guest polymer is caused to participate in the crosslinking reaction by blending the polymer containing the host and the polymer containing the equivalent guest together with the polyfunctional comonomer or polyfunctional prepolymer. Polymers that choose not to participate in network-forming reactions are entangled in the cross-linking pathway. In this case, a highly fluorescent semi-permeable network is produced. Preferred crosslinking systems include, but are not limited to, alcohol-isocyanate, amine-isofluoroester, polyvinyl monomer, polyvinyl-containing prepolymer, polypropylene-containing prepolymer, amine- Epoxy and acid-epoxy. Another aspect of the present invention is the preparation of an internal permeation network using the polymer of composition (b). This system preferably uses a host polymer and a guest polymer body containing a side chain one or end group functional group that can participate in a cross-linking reaction with a polyfunctional comonomer or prepolymer. The final material is a high fluorescent cross-linking outline. Preferred crosslinking systems include, but are not limited to, alcohol-isofluoroesters, amine-isofluoroesters, polyvinyl monomers, prepolymers containing polyvinyl groups, prepolymers containing polypropylene groups , Amine-epoxy and acid-epoxy. The solid composition (b) according to the present invention contains a host chromophore and a guest chromophore. The weight between these host hair color bases and object hair color bases is preferably 50:50 to 9 9 9 9: 1, more preferably 60:40 to 9 9 9: 1 and the best 7 0: 3 0 to 9 9 9: 1. Another specific spring embodiment of the present invention relates to a solid composition for preparing the hair. -104-The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 g t)

1.1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 ___ B7. Μ _ _______________________ _. The host polymer and the guest chromophore are blended, or the guest polymer and the guest chromophore are blended, or the host polymer and the guest polymer are preferably blended in the presence of a solvent and the solvent is removed after blending. Another embodiment of the present invention The embodiment relates to a method for preparing a solid composition of the present invention, which is characterized by polymerizing a host chromophore monomer or a prepolymer thereof in the presence of a dissolved guest chromophore, or combining them in the presence of a dissolved host chromophore. The guest chromophore or its prepolymer can optionally be combined with non-fluorescent monomers as required. Another preferred embodiment of the present invention relates to a method for preparing a solid composition (al) according to the present invention, U2) and (b), characterized by (1) uniformly mixing the host component and the guest component, whereby at least one component is a polymer (host polymer and / or guest polymer); or (2) is dissolved Aggregated host Chromophore monomer or its prepolymer, or polymerized guest chromophore monomer or its prepolymer in the presence of a dissolved host chromophore, optionally together with a non-fluorescent monomer as needed; or Ministry of Economic Affairs The Central Standards Bureau ’s Consumer Co-operative Printing Act first orders the raw material and the basic carbonyl main oxygen, but as the case may be, it is possible to unpack and dissolve it from Yan Yi ’s place. The product is then used for polymerization or whitening: s is in a mixed place. The homogeneous carbonyl carboxide is removed from the alkanes to remove the body in a wet manner. The division of the cube-type main fusion composite is illegally mixed, so that the paper size can always be applied to the Chinese National Standard (CNS) Λ4 specification (210X 297 gong) 526252 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation ___ Β7_ V. Description of the invention (1fen) In the context of the present invention, materials can be mixed by dissolving these ingredients in a common solvent and then evaporating the solvent; precipitation from a good solvent into a poor solvent ( Vigorous stirring can be used); freeze-drying; and Shen Dian during polymerization of polymerizable monomers or oligomers, preferably by stirring under sufficient energy. Appropriate inert solvents have been previously described. In In the precipitation method, the difference in the relative solubility of these components is used. Once dissolved in a normal good solvent, the host and guest components are added to a large excess of the poorly stirred poor solvent. The final material is high in fluorescence and shows the host / guest. All the characteristic properties of the material. In the freeze-drying method, the steady state of the ingredients and solvents is produced by a frozen solution, where the ingredients are uniformly distributed. This state is maintained once the solvent is removed by lyophilization. The final material is highly fluorescent and shows all the characteristic properties of the host / guest material. If one component is crosslinked, it is possible to introduce equivalent components by expanding the crosslinked material in a good solvent containing the relative material dissolved therein. After the opposite substance has penetrated into the gel, the solvent is removed to complete the high-fluorescence host / guest material. A further method of mixing the ingredients is by melting-mixing the ingredients at a temperature below the individual decomposition temperature K, and at a pressure selectable as needed. This method can be performed in a thermoplastic molding apparatus such as injection, extrusion or compression molding. Another possibility is the presence or absence of a solvent in the color base of the object or subject -106- This paper size applies the Chinese National Standard (CNS) Λ4 specification (3Ι0χ297) 犮 (Please read the precautions on the back before this page) —Packing, wood, νδ-# ^ 1 526252 Λ7 B7 5. Description of the invention () Dissolve a host or guest chromophore or its prepolymer (like oligomer) in the presence and image formation in known methods Overall polymer precipitation, solution or emulsion polymerization mixture. Fine particles can be obtained using emulsion polymerization. This method is suitable for producing crosslinked polymers. When molecularly dissolved pigments are intended as guest chromophores, they can be generated from pigment precursors containing protective groups, which are subsequently removed after the composition U2) is prepared and dried. The amount of pigment produced should be controlled to avoid the formation of nano-sized pigment particles. The upper limit is preferably 2.5% by weight and more preferably 2% by weight with respect to the composition (a2). In the context of the present invention, where the pigment is carefully considered from a pigment precursor, it is necessary to remove the protective group covalently bonded to the pigment. These protecting groups may additionally have the function of dissolving insoluble pigments. Removal of the protecting group can be achieved by chemical methods like acids, bases, catalysts present in the composition; by light irradiation or heating precipitation, or a combination of these methods. A preferred method is heating, whereby acids, bases and or catalysts can help reduce the decomposition temperature of the pigment precursors. The actual temperature used must be below the decomposition temperature of the individual host chromophores and polymers used in the composition. The temperature must also be at the melting temperature M of the host chromophore and the polymer to avoid migration and aggregation of pigments that have been carefully considered. The temperature must also be above the decomposition temperature M of the pigment precursor. The temperature range of the heat treatment of the precipitate may be, for example, 5 Q to 25 G ° C, preferably 70 to 2 2 0 ° C, more preferably 80 to 2 0 0 ° C, and most preferably 100 to 18 0 ° C. When the crosslinked polymer is heated, higher temperatures can be used. -107- This paper size is applicable to China National Standards (CNS) Λ4 specification (210X 297mm) (Please read the precautions on the back before

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the Invention (l #) When using a polymer matrix containing a side chain body, the selected decomposition temperature of the pigment precursor can also be viewed as the softening of the polymer or Depending on the glass transition temperature. This is to avoid the migration of carefully considered pigment molecules, which in turn can lead to the generation of unwanted nano-sized pigment particles. It is also generally found that the heating temperature may be about or slightly above the softening or glass transition temperature. In addition, the use of short and optionally repeated heating cycles and times can be a useful way to avoid any unwanted attacks. Short and remaining heating times can be achieved, for example, using microwaves or thermal spokes. These methods can also be used for polymers with low glass transition temperatures, such as polyolefins or rubbers. The composition produced by the decomposition of the pigment precursor method provides a normally insoluble pigment material contained in a molecularly dissolved state. In addition, the composition according to the present invention does not generally exhibit the typical color typical of pigments in compositions of polymers and purely aggregated pigments, or in compositions containing a host chromophore optionally with a polymer matrix. Typical mixed colors. If the pigment precursor is completely decomposed and the molecules remain dissolved, the color of the composition can be used for detection. Compound 1,2,3,4-tetraphenyl-benzo [4,5] imidazo [2, bu &amp;] isoindazim-1 1-one and its derivatives printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs It is a preferred group of host compounds used in the present invention and has an absorption maximum at about 370 nm, which is located in the UV region. However, their excitation wavelength is around 350 nm, in the UV region, and to 450 nm, in the visible region of the electromagnetic spectrum. As a result, host / object type materials using such compounds, as host, can be used in a wide range of applications and quickly help them when stimulated by both UV and white light radiation sources. -108- This paper is scaled to China National Standard (CNS) Λ4 specification (210X 297 Gong 526252 Λ7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention) 1 II 〇 Therefore $ is used for example in road signs and traffic signs for night and white painting 1 1 1 can provide effective colorants in use 9 When they show bright fluorescent light, and ^, 1 I can also be excited by UV radiation of halogen lamps of cars% 1 I for intense bright colors. Other rjtg willing to use as pigment 9 colorant 5 read back 1 1 1 material for scintillator material for solar current collector &gt; for light emission 1 I% 1 I shot Materials for electroluminescent devices Materials for photoimages and use of printing inks 1 1 Ink usage 9 and 9 The choice of guest fiXL compounds can provide a lot of flexibility to the emission wavelengths required for all systems &gt; Energy pages with color adjustment in them 1 I Power and ease of color application through the wavelength core system. Borrowed by 1 1 I. Fluorescent image produced by known photoresist technology (high uneven structure) is also possible. 1 1 capable 0 Composition of the present invention Materials can also be used in paints 5 paints or printing inks 0 1 order 1 1 The compositions according to the invention (al) 9 (a 2) and (b) can be used in various forms &gt; depending on the end use 〇1 1 I The composition according to the present invention may be ground or may be produced in the form of particles 1 1 0 The further giant of the present invention is in the form of particles, especially the composition of finely divided particles 〇 1 I average diameter or particle size can be 50 nanometers to 1000 microns 9 preferably 0.5 1 1 I to 500 microns' • better 0 • 5 to 200 microns, • optimal 0 • 1 to 100 microns j and 1 1 I are particularly preferably 5 to 50 microns. The particles may be round or irregular &gt; depending on the method of manufacturing 1 1 9 and the particles may be compacted or porous. The size of the particles 1 | To meet the needs of their final my application. 0 1 I The composition according to the present invention can be blended with other polymers. The present invention further advances the 1 1 I step—a blend comprising (1) a non-fluorescent polymer and a matrix. Wu He 1 1 10 9- 1 1 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 male Zhao) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 ____ 5. Description of the invention (ΐβ) (2) Composition according to the invention (al), (a2) or (b). The amount of the component (2) may be, for example, 0.1 to 99.9% by weight, more preferably 1.0 to 50% by weight, relative to the total composition. The amount used basically depends on the polymer with side chain host and guest chromophores present in the composition and also on the compatibility with the polymer substrate. These non-fluorescent polymer substrates can be selected from thermoplastic, thermoset and structural crosslinked polymers. The blend of the thermoplastic and thermosetting plastics of the present invention is a polymer alloy or blend. These polymers can be homopolymers, copolymers, block polymers, graft polymers or random polymers. These polymers may be opaque or translucent, but are preferably transparent. The polymers may be selected from, for example, thermoplastic polymers such as polyesters, polyamides, polyimides, polyimides-polyimides, polyimides, polyurethanes, polyimides Urea, polyolefins; substituted olefins such as vinyl ethers, vinyl esters, vinyl alcohol, vinyl chloride, dichloroethylene acetonitrile, acrylic acid, methacrylic acid, acrylic acid, methacrylic esters and fluorene Amines, Styrene, Chlorostyrene, Methyl Styryl, Ethylene Sulfonic Acids and Their Esters and Amines, Vinyl Carbazole, Vinyl Pyridine, Vinyl Pyrrolidone: Polymaleic Acid And esters and amines derived therefrom; polyethers, polyfluorenes, polyfluorenes, polyphenylsulfides, and polyacetals; cellulose and its esters and ethers, and starch or A polymer of starch derivatives. Examples of thermosetting resins and structural crosslinked resins are, for example, polyepoxides, unsaturated polyesters, light crosslinked resins, such as those obtained from acrylic acid and / or methacrylate, and / or from polyols and / Or Polyamine amine, honey-1 1 0-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 public incineration) (Please read the precautions on the back before this page), \ d 526252 Λ7 B7 V. Description of the invention (pf Printed amine / methylisoprene and natural rubber method 埶 i polymer by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy Polycomposite precursors, such as polymers of electrification agents, aldehyde resins, and phenol / formaldehyde resins; copolymers derived from butadiene, olefin and / or chloroprene, and olefins, which can be Polymers of natural rubber; and silicates that can be obtained, for example, by known solids / coagulants. Solid plastic compositions are, for example, by known mixing methods such as blended solutions and solvent removal, injection molding and extrusion Availability and structure The cross-linked composition can be obtained by a known method such as press molding, and thus the composition of the present invention is preferably low-molecular-weight and dissolved in a compound. In a further aspect, the composition of the polymer-structured cross-linked invention is distributed in The composition of the present invention can be used as a thermoplastic and thermosetting filler by the physical and particle-forming solvents invented by the composition. The further purpose is to include U) a polymer substrate and (2) ) Polymer particles (a 1) according to (&amp; 2) or (1)), or a combination thereof, wherein. The amount may be from 50 to 50% by weight. Known polymerized polymers are mechanically uniformly divided into molding agents such as from 0.1 to 90% by weight, preferably from 0.1 to 70% by weight of the total composition. Include those as described above. This mixing method is easily prepared as described above, whereby the particles are dispersed beforehand. The composition may contain further ingredients to improve certain characteristics such as quality, and / or processability, dispersant for cloth, lubricant, plasticizer, antistatic, antioxidant, light stabilizer, filler and additive 111 -This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 cm) (Please read the precautions on the back-&lt; ·· ν page) 526252 Λ7 s______ 5. Description of the invention ((IP) Fillers such as glass balls and glass fibers, silicates (such as mica, clay, calcium silicate), metal and semiconductor gold oxides, metal carbonates, metal salts, metal and semiconductor gold oxides, carbon black, as Powder, or carbon fibers, whiskers, metal and semiconductor metal carbides, metal and semiconductor metal nitrides, dyes, pigments, and others. A further object of the present invention is a shaped article obtained from (1) a composition according to the present invention (Al), (a2) or (b), or (2) —a polymer matrix comprising (a 1), (a 2), or (b) of (2-1) polymer matrix according to the present invention Composition, or (2-2) containing this The particles of the composition (a 1), (a 2) or (b) are distributed uniformly in the polymer substrate alone or together with a composition of the present invention. In another aspect, according to the present invention, The polymer and particles of the composition can be used as a coating on a carrier material, using the above composition. Another object of the present invention is a composition comprising (1) a carrier material and (2) a coating on at least one surface, The coating is printed by (i) the composition (a 1), (a 2) or (b) of the present invention, printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs, and (ii) as a polymer, including uniformly distributed Among them, the composition (al), U2) or (b), or (iii) of the present invention is a mixture comprising a polymer as a substrate and a uniformly distributed composition (al), (a2) or ( b), or alone or in admixture with particles of the composition (a 1), (a 2) or (b) of the present invention. Appropriate carrier materials can be selected from organic or inorganic materials like glass, ceramic-112- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297) while 526252 Λ7 B7 V. Description of the invention (u \), mineral, Plastic, paper, wood, semiconductor, metal, metal oxide and semiconductor gold oxide, and metal or semiconductor metal nitride or a carbide. The thickness of the coating depends on the application and can be 0.1 to 1QG0 microns, It is preferably 0.5 to 500 micrometers, and particularly preferably 1 to 100 micrometers. Those coatings can be protected by applying a coating which is preferably transparent. The coatings are general light-crosslinking coatings which are known and mainly used for this purpose and are known in the art. The preferred coating is clear. Moreover, the materials belonging to the composition of the present invention, which are surface-modified, can also be protected by a K coating. Such coated materials can be obtained by known methods like brush coating, casting or spin coating, either directly or together with solutions or dispersions of polymeric components. It is also possible to use a polymerizable composition comprising a polymer-forming monomer, especially a crosslinkable olefinically unsaturated monomer. Polymerization can be induced by kappa heat or by light radiation. Those coating compositions are novel and a further object of the present invention. Therefore, another object of the present invention is a solvent and a solvent containing a composition selected as required, including (1) the composition (al), (a2) or (b) of the present invention and a non-fluorescent polymer selected as required. (2) Receptor polymer, which contains particles of the composition (a 丨), U2) or (b) of the present invention uniformly distributed, alone or in combination with the composition (aU, (a2) or (b) of the present invention) Particle blending. These compositions may include solvents, such as those previously mentioned, # -113- This paper size applies Chinese National Standards (CNS) Λ4 specifications (210X 297) while please read the note on the back first Item "This page) Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 V. Description of the Invention (IP) Surfactants and dispersants that can be selected as required. The viscosity range depends on Depending on the required application of the coating, the required viscosity can be achieved by selecting the amount of solvent as the polymer and fluorescent material of the binder. To further achieve the required viscosity, thickener additives can be used. Once again appropriate Solvents have been mentioned. The preparation of this composition can be achieved by simple mixing of the ingredients using appropriate mixing equipment. Dispersions are usually stable, depending on the viscosity. If the particles will aggregate, they can be re-stirred by stirring Distribution. The polymerizable composition can be used in a highly advantageous embodiment for preparing a coating. 'At least one of the support material's surface is coated and subsequently polymerized by kappa or radiation. Photopolymerizable mixtures can also be obtained by known photoresist Agent technology is used to generate fluorescent images. A further preferred embodiment of the present invention is a polymerizable composition, including (1) and particles of the composition of the present invention Ul), U2) or (b), and A polymerizable monomer or prepolymer of (a 1), U2) or (b) composition of the present invention in which the composition can be selectively dissolved is required; (2) the polymerizable monomer or prepolymer and the dissolution The composition of the present invention (al), (a2) or (b); (3a) a polymerizable host chromophore as defined herein, comprising at least one polymerizable group or at least two functional groups, or Prepolymer; optional with main body as needed Non-fluorescent monomers or prepolymers whose color base can be copolymerized; and guest hair color bases or pigment precursors dissolved in it; -114- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297) ) (Please read the notes on the back first to write this page)-526252 Λ7 _ V. Description of the invention () (3b) Polymerizable guest chromophore, which contains at least one polymerizable group or at least two functional groups, or Polymers; non-fluorescent monomers or prepolymers that can be copolymerized with guest chromophores as needed; and host chromophores as defined herein, dissolved therein. The composition can be used to produce the composition (a 1), (a 2) or (b) of the present invention as described above. The preferred composition contains a solvent when the coating or image is produced. The specific embodiments described later are also applicable to this composition, including the preferred embodiments. In a preferred embodiment, the composition is based on a polymerizable monomer and / or a prepolymer selected from ethylenic unsaturated groups, preferably selected from -CH = CH, and -C (CH3) = CH2, It can be thermally or photo-polymerized. Photopolymerizable monomers and prepolymers are known in the art and are described, for example, in EP-A-0 654 711. Preferred photopolymerizable monomers and prepolymers are those methacrylic or methacrylic acids and alcohols, polyol ', and esters or amines of amines and polyamines as the mains. Photopolymerizable compositions are particularly suitable for producing coatings and images. A further preferred embodiment of the present invention printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economics relates to a composition comprising (1) a carrier material and (2) a polymerized photoresist material on at least one surface of the carrier A high-convex image comprising (2-1) particles of a composition of the present invention uniformly distributed; or components (al), (a2) or (b) of the present invention dissolved and uniformly distributed therein; or Both; or (2-2) Photoresist consisting of the following polymers (cl) Photopolymerizable host chromophore as defined herein, containing at least one light -115- This paper standard applies to China Standard (CNS) Λ4 specification (210X 297 Gongchu) '~~~ 526252 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 __B7 V. Description of the invention (丨 屮) Polymerizable group or at least two functional photoreactive groups Or its prepolymer; non-fluorescent monomers or prepolymers that can be polymerized with the host chromophore as needed; and guest chromophores or pigment prepolymers dissolved in it; (C 2) —light Polymerizable guest chromophore containing at least one photopolymer Or at least two functional photoreactive groups or their prepolymers; non-fluorescent monomers or prepolymers that are polymerizable with the guest chromophore as needed; and a host chromophore as defined herein , Dissolved in it. A further preferred embodiment of the present invention relates to a method for preparing a fluorescent high-convex image on a carrier, which comprises irradiating under a photomask or writing by a laser. The photopolymerizable composition is developed with the irradiated composition and finally the non-irradiated portion is removed. The removal of the non-irradiated portion is preferably performed by using a solvent treatment. A further preferred embodiment of the present invention relates to a method for generating fluorescent radiation, which requires electrons or radiation by UV or visible light, or both to excite the fluorescent composition (al) (a2) and (B). Another preferred embodiment of the present invention relates to the use of the fluorescent compositions (a 1) (a 2) and (b) according to the present invention as fluorescent materials. If compared with a composition of comparable prior art, the composition does show the following advantages: i) it imparts strong solid-state fluorescence, preferably where the emission wavelengths are in the visible region of the electromagnetic spectrum * ii) a high proportion of the main body and The guest molecule as a part of the polymer also retains the solid fluorescent properties (that is, the negligible concentration quenching) ° -1 1 6- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X2 ^ 7 Gong Jun)

(Please read the precautions on the back of the V installation first-▼ this page) '1T — Preparation · 526252 Λ7 B7 V. Description of the invention (Uf) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs iii) These components can be used Excitation in both UV and visible light wavelengths, iv) very good light stability can be achieved, v) a wide range of emission wavelengths can be achieved by selecting guest molecules. (Color adjustment), vi) can achieve high thermal stability, vii) can produce dissolved and insoluble fluorescent compositions, viii) basically excludes the migration of fluorescent host and guest molecules and ix) these substances are easy to prepare, but also That is, a one-pot reaction is possible. The present invention will now be described via examples. A) Preparation of host chromophore and / or host monomer / polymer intermediate. Rich Example A1: 1.2.3.3. 4-tetraphenyl-7- (carboxylic acid) -benzo [4,5bimizo [2, la] isoindole-1buconone (A1, containing equivalent 8-isomers included) 10 g (0 · (3 2 2 mol) 3,4-diaminobenzoic acid magnetic stirrer in a reaction vessel should be heated to reflux temperature dark yellow color. Then the Inverse temperature (1 G 5 ° C) indwelling 7 2 alcohols to wash. The yellow product was then left in the aspirator M tube Example A: 1,2,3,4-tetraindolinone) tetraphenylpeptide anhydride And 3.35 g (0.022 mol) added to a condenser, flushed with light nitrogen, and 100 ml of acetic acid. The gray reversed. After a few hours the reaction started to occur and the mixture should be slightly below the reflux temperature. Filter fresh The yellow precipitate and M water and forma were finally dried in a vacuum oven overnight (6 ° C). The yield was 81%. Phenyl-benzo [4, 5] -imidazo [2, Ι-a] iso -7-carboxylic acid chloride (A2, including 8-isomers-117) This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 cm) Please read the notes on the back binding 5262 52 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (inclusive). 5 grams (0.08 mol) of compound a 丨 and 3 Q ml of anhydrous benzene were added to the #condensation. "Light nitrogen flush and inside the reaction vessel of a magnetic stirrer. Keep at room temperature." Add excess thionyl chloride to the reaction mixture and let it stir for 30 minutes. The reaction mixture is a yellow suspension The solution was then heated to reflux temperature for about 2 hours to produce a clear gold color solution. The solvent and excess thionyl chloride were removed using a stream of nitrogen to produce a yellow fluorenyl chloride derivative. The yield was 94%. Polymerizable main derivative Example of the production of β-LJ_ 1,2,3,4-tetraphenyl-benzo [4,5] imidazo [2, bua] isoindole B_1_1-keto-7-carboxyethyl Methacrylate (B1, including the 8-isomer). 4 g of A2, dissolved in 30 ml of anhydrous pyridine, was slowly added to a solution containing 5 g (large excess) at room temperature over about 30 minutes. The hydroxyethyl methacrylate was in a stirred solution in 10 ml of anhydrous pyridine. The reaction mixture was left at room temperature and further stirred 2 The complete reaction mixture was then slowly added to, stirred at 13:00, containing 100 g of ice and 1 (30 ml of HC1 in a beaker. A yellow precipitate was obtained and allowed to settle before filtration (sintered glass G3), by The crude product was produced by a vacuum pump. The crude precipitate was further purified to remove residual hydroxyethyl methacrylate, and reprecipitated from chloroform into a large excess of hexane (yield 86%). Preparation of mysterious compounds 〇-118- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X297 cm) (Please read the precautions on the back page first) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 526252 Λ7 B7 Description of the Invention (γ) Tube axillary case f &gt; 1: Carboxylethylmethacrylate derivative of transdanmin-B (Cl). 3.5 grams (0.QQ73 mole) of Rhodamine-B was added to about 30 ml of anhydrous dichloromethane (A 1 d r i c h special grade) in a reaction vessel equipped with a condenser, light nitrogen flushing, and a magnetic stirrer. While maintaining at room temperature, 1.54 g (0.0095 mol, 1.3 excess) of N, N'-carbonyldiimidazole was added to the vigorously mixed rhodamine solution over a period of about 10 minutes. This reaction was further left at room temperature and stirred for 4 hours to produce the desired acid imidazole. Three equivalents of 2-hydroxyethyl methacrylate (2.8 g, 0.02 mole) were then added to the reaction mixture and allowed to stir at room temperature for a further 72 hours. The solvent was removed from the crude reaction mixture, and the product was purified by column chromatography. 90 C H C 13/10 M e 0 Η was used as a dissolution solvent. Hei 02: The preparation of a polyfunctional difluorenylpyrrolo-pyrrole compound similar to C 2 can be achieved by 'EP-A 337 951 or preferably as described in Example 12 of EP-A 787 731.

-119- This paper size applies to China National Standard (CNS) Α4 size (210X 297 Gongao) (Please read the notes on the back before filling this page) Order 526252 Printed bags for the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ_ _B7 V. DESCRIPTION OF THE INVENTION (i) D) As borrow of fluorescent polymers. Example D-1: Free radical polymerization of a monomer containing a chromophore group A polymer containing a chromophore group was prepared. 2.04 g of the main monomer B1, 1.7 g of methyl methacrylate, 〇.172 g of recrystallized AIBN and 12 ml of chloroform were added to a clean 5 (3 ml reaction flask. The reaction mixture MN 2 gas was bubbled about 30 The oxygen was removed in minutes. The reaction mixture was placed in a water bath controlled at 60 ° C and ended when the viscosity of the reaction solution increased significantly (8 hours). The polymer was separately prepared by using chloroform and methanol (or hexane). As a combination of solvent and non-solvent, a series of ▲ strings are reprecipitated and separated. Yield 53%, Mw2.5xl05. Example P2: Preparation of guest chromophore-containing group via free radical polymerization of monomer containing chromophore of guest. Polymer: A monomer feed mixture containing 0.06 grams of guest monomer C1, 9.14 grams of methyl methacrylate and 0.88 grams of hydroxyethyl methacrylate was added to a clean reaction flask and 0.04 grams Recrystallize 2, 2'-azobisisobutyronitrile (ΑΙΒΝ) together with 30 ml of chloroform as a polymerization solvent. After 60 hours and 10 hours, a copolymer with Mw ~ 2.6 · 105 was obtained. The yield was 47%. In the following, all fluorescent polymer-like Light fluorescence and excitation spectra were recorded using a Hitachi F-4500 fluorescence spectrophotometer in a standard reflectance mode (with the aid of a commercial solid sampler with a transparent quartz window). Polymer samples were cast on glass slides and The solvent was removed before the measurement. The scanning rate was 240 nm / min. When Example F-1: Preparation of Fengshen / Shenzhen Polymer Alloy -120- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification ( 210X 297 mm) (Please read the notes on the back before filling out this page) Order ΙΟΛΙ 526252 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Λ7 ____ ΙΠ 5. Description of the invention (丨 &gt; f) The guest polymer versus the host molecule The weight ratio is 50: 50. After complete mixing, the solution is knife-coated with the aid of a bar coater to form a uniform polymer film with a thickness of 2 microns. 0 Absorption and fluorescence characteristics of the host / guest system and its individual The ingredient list is in the following Table 3: Table 3: Host-guest polymer AbsMax ExMax EmMax PI ratio (% by weight) (% by weight) (nano) (Nano) (nano) 50 # 0 365 365 501 1 0 100 560 560 580-50 50 365 365 580 8.9 (# 50: 50% by weight [1,2,3, 4-tetraphenyl-7 (or 8]-(2, -methyl-2 -propyl) -benzo [4,5] imidazo [2, 1 -a] isoindiodo-1 1-. Ketone / ΡΜΜ A)物 膜]. (PI; maximum peak height intensity, Abs Ma X; absorption maximum, E x M a x; real excitation maximum, E mM a X; experimental emission maximum). Example R-4: λ |, a molecular solution of a latent molecular host in a polymer of a guest molecule having a covalent bond. The polymer of Example D 1 and the potential guest molecules were mixed. 0.1 g of the host polymer and 0.01 0 g of the precursor N, N'-double-SS — _ PiJ — 4 D Oxycarbonyl-1,4-diketo-3, 6-diphenyl-pyrrolo-[-3, 4-• c] pyrrole (,, Bo c--123- (Please read the precautions on the back first Page) This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 cm) 526252 Λ7 B7 V. Description of the invention () DPP "* Prepared in a method similar to EP-Α 6 5 4 7 1 1) The two components were dissolved in chloroform so that the solid to solvent ratio was 5 weight / vol%. A part of the solution was blade-coated on a glass sheet with the aid of a bar coater to form a film having a thickness of about 2 microns. This film was then heated on a 1 2 Q ° C hot plate for 1 minute, once the dissolved third-Boc group was removed by heat, resulting in insoluble pigment 1,4-diamidino-3,6- A molecular solution of diphenyl-pyrrolo [-3, 4-c] [ft]. Energy transfer is observed by a spectroscope. Changes in fluorescence emission are observed. Absorption of the host object before and after heating The details of the radiation and fluorescence characteristics are listed in Table 4 below: (Please read the precautions on the back page first) • Installation, \ ST &gt; Table 4 ·: Abs Max Em Max PI ratio (weight%) (weight) ％) (nano) (nano) (enhancement ratio) Before heating 99.9 0.1 365 501-After heating 99.94 # 0.06 # 365 508 1.3 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (# due to potential guest molecules of t-Boc The increase and loss of the weight percentage of the subject and object due to the loss of the base) (PI; maximum peak height intensity, AbsMax; absorption maximum, EmMax; experimental emission maximum).-124- This paper size applies to Chinese national standards ( CNS) Λ4 specification (210X 297 males)

Claims (1)

CH (CH3) 2 CH (CH3) 2 526252 々, patent application scope ,, Γ --6 · 5 Gate 5 The weight ratio of the host hair color base to the guest hair color base is 9999: 1 and if For the desired compound G, the fine emission spectrum of the towel body overlaps with the absorption spectrum of the guest chromophore, and (al) the host color is difficult to co-polymerize with the polymer chain (,, host polymer &quot;), And / or ii) the guest chromophore is covalently bonded to the polymer backbone B (,, the guest polymer ')', where the polymer backbones A and B interact with the heteromethacrylate. 2. The solid fluorescent composition according to item i of the patent application, wherein (al) the color base of the guest is uniformly distributed in the matrix formed by the host polymer, or The matrix formed by the guest complex, or (b) the host polymer and the guest polymer are blended. 3. The solid fluorescent composition according to item 2 of the scope of the patent application, wherein (al) the guest chromophore is dissolved and uniformly distributed in a matrix formed by the host polymer. 4. The solid-state fluorescent composition according to item 2 of the scope of the patent application, wherein (a2) the host chromophore is dissolved and uniformly distributed in the matrix formed by the guest polymer. 5. The solid fluorescent composition according to item 2 of the scope of the patent application, wherein (b) the host polymer and the guest polymer are uniformly blended. — (Please read the notes on the back before filling out this page) * 11 · — 526252 098859 ABCD VI. Patent Application Scope I 6 · —A method for preparing solid fluorescent composition according to item i of the patent application scope, its characteristics The host polymer and the guest chromophore, or the guest polymer and the host chromophore, or the host polymer and the guest polymer are blended. 7. The method according to claim 6 of the patent scope, wherein the mixing is performed after the solvent is present and the solvent is removed after blending. 8. A method for preparing a solid fluorescent composition according to item i or 2 of the scope of the patent application, characterized by polymerizing the main chromophore monomer or its prepolymer in the presence of a dissolved guest chromophore, or The guest chromophore or its prepolymer is polymerized in the presence of the dissolved host chromophore, optionally together with a non-fluorescent monomer. 9. The solid fluorescent composition according to item 1 or 2 of the patent application, in the form of particles. 10. A fluorescent composition comprising (1) a carrier substance and (2) a coating on at least one surface (i) a composition according to item 1 of the scope of the patent application, and (ii) a substance as a substrate A polymer comprising a solid fluorescent composition according to item 9 of the scope of patent application in the form of particles uniformly distributed therein, or (iii) a mixture containing a polymer as a substrate and a uniform distribution according to the application The composition of item 1 of the patent scope is blended alone or with the solid fluorescent composition according to item 9 of the patent scope in the form of particles. 11.A polymerizable fluorescent composition comprising (1) a polymerizable monomer or prepolymer and particles in the form of particles according to the size of the paper applied for the application of Chinese National Standard (CNS) A4 (210 X 297 mm). ............ Order ... ..... (Please read the notes on the back before filling in this page) A8B8C8D8 526252 VI. Application of solid-state fluorescent composition in the scope of patent application / scope of benefit 9, and if necessary, according to the scope of patent application in scope 1 The composition is dissolved therein; (2) the polymerizable monomer or prepolymer is dissolved therein; and (3a) the polymerizable chromophore includes at least one polymerizable group Or at least one Lupinyl or its prepolymer; a non-fluorescent monomer or prepolymer that is copolymerizable with the host chromophore as needed; and a guest chromophore or pigment precursor is dissolved therein; (3b) A polymerizable guest chromophore comprising at least one polymerizable group or at least two functional groups, or a prepolymer thereof; a non-fluorescent monomer or prepolymer that is copolymerizable with the guest chromophore as needed; and As defined in The main chromophore 'is dissolved therein. 12. A fluorescent composition comprising (1) a carrier substance and (2) a high relief image of a polymerizable photoresist material on at least one surface of the carrier, which includes (2-1) a uniform distribution A solid fluorescent composition according to item 9 of the scope of patent application in particle form; or a composition according to item 1 of the scope of patent application dissolved or uniformly distributed therein; or both; or (2-2) of light The resist is composed of a polymer (cl) of a photopolymerizable host chromophore including at least one photopolymerizable group or at least two functional photoreactive groups or a prepolymer thereof; Color group copolymerizable non-fluorescent monomers or prepolymers; dissolved in guest chromophores or pigment precursors; (c2) —a photopolymerizable guest chromophore that contains at least one photopolymerizable 4 scale applicable China National Standard (CNS) A4 Specification (210 X 297 Male '------------------------ Fee ............... .... 1T ---------------- (Please read the precautions on the back before copying this page) 526252 False C8 D8 VI. Patent application scope / sex-based or at least two Functional photoinduced reaction Bases or their prepolymers; non-fluorescent monomers or prepolymers that can be copolymerized with guest chromophores as needed; and host chromophores defined here, dissolved in it. 13. According to the scope of the patent application Item 1 or 2 of the solid fluorescent composition 'It is used as a fluorescent substance. (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) Date of application? 7, &gt;. (Ό Case No. 27 / ό / 7 ^ 2: Category —- *-4-1 ~-— Zuo〃 / (The above columns are noted by the Pacific Bureau) A4 C4 526252 The Ministry of Economic Affairs Zhicicai is a printed collection of the capital-industrial and consumer cooperatives. Patent specification Invention I. A new name Chinese solid composition, its preparation method and its application English Solid Compositions, Their Preparation Process and Their Use Anglade. David Lin 4. Out of the wild 2. Otani Junji L. Abu Ikubar 3. Kunimoto Katsuhiko 6. Sammy Hossain Erding _ Invention of Nationality 1. UK 2.3.4. Japan 5 .Bangladesh 6. Swiss creation A Residence, residence 1. Japan 2665-202, Takamatsu, Takamatsu, Hyogo Prefecture, Japan 2. Japan 6 57-11201, Shinoharadai, Nada-ku, Kobe, Hyogo Prefecture 3. Japan 569-1 1 4-9-3, Akutagawa, Takahata, Osaka Prefecture 4. Japan 669-11 1-7-Nanadai, Nanaishi, Nishinomiya, Hyogo Prefecture 3 5. 1732 Arcosir, Ladie 202 6. Switzerland 1784 Kortpin, La Grandefin Name (Name) Cibaat Chemicals Holding Company Nationality Switzerland 3. Applicant's residence, residence (office) ） Name of Representative No. 141, Kleiber Street, Basel City, Switzerland 4057 1. Ernst. Athel 2. Hans-Petter. Wittling-Bu _ This paper size applies the Chinese National Standard (CNS ) A4 size (210X297 mm) Binding line 526252 89.9.2 5 and hb.-;-· __Kl ·, especially _B7_ V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The host polymer of Example D 1 and the guest polymer of D 2 were dissolved in a general solvent (chloroform), so that the solid-to-solvent ratio was 5 weight / volume%. The weight ratio of host polymer to guest molecule is 50:50. After complete mixing, the solution was applied by a rib coater to form a polymer film with a thickness of about 2 micrometers. The absorption and fluorescence characteristics of the host / guest system and their individual components are listed in Table 1 below: Table 1 • Host polymer guest polymer AbsMax ExMax EfflMax PI ratio (wt%) (wt%) (nano) (nano) (nano) (enhancement factor) 100 0 365 365 501 1 0 100 560 560 580- 50 50 365 365 580 2.5 (PI; maximum peak height intensity, Ab sM ax; absorption maximum, ExMax ;: experimental excitation maximum, ΕηΜ ax; S test emission maximum). Example E-2_: Preparation of a molecular dispersion of a small molecular guest molecule in a polymer and a covalently linked host molecule 0 The host polymer of Example D 1 and a common solvent (95CH2 Clz / 5CH3 OH) ) And Rhodamine 19 perchlorate (laser grade) so that the solid to solvent ratio is 5 weight / vol%. The weight ratio of the host polymer to the guest molecule is 99.8 »: 0.2c &gt; After being completely mixed, the solution is passed through the rod -121- ------------ ^ --— Order — (Please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 526252 89. 9.25;,.. .. * f &gt; ί- ----------------- gy --------- V. Description of the invention () —— —— —————— The rib of the coating machine is applied in the solvent. After removal, a polymer film with a thickness of 2 micron order was formed. The absorption / fluorescence characteristics of the host / guest system and their individual components are listed in Table 2 below: Table 2: Host-AbMax ExMax EaiMax PI ratio mm%) (nanometer) (nanometer) (fenmi) ( Strong and rare) 100 0 365 365 501-0 0.2 «560 560 580-99.8 0.2 365 365 580 2.7 [#The matrix is a non-fluorescent polymer polymethylmethacrylate (PMMA) 〇 (PI ;; the maximum peak High Intensity, AbsMax; Absorption Max, ExMax; Experimental Excitation Max, EfflMax; Spring Examination Emission) 0 Blocking Example R d: Small in polymer with guest molecules of covalent lotus root ------------- ^ --- I ^ · IIII (Please read the notes on the back before filling this page) The molecular decomposition of the molecular body printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The guest polymer and host molecules of Example D 2 were mixed. The host molecule was prepared according to Spring Example A1, except that the diamine used was third butyl-1,2-diaminobenzene (ie, 1,2,3,4-tetraphenyl-bu (or 8 -(2'-methyl-2-propyl) benzo [4,5] -imidazole [2, bua] isofluorene-11-one). The guest polymer is dissolved in a common solvent ( 95CH2 Clz / Mlh 01U fO The main molecules are mixed, and the ratio of solid to solvent is 5% by weight / vol%.