TW520978B - Lures - Google Patents

Abstract

Lures made of acrylic acid-based polymers, preferably molded polyacrylate articles containing water. These lures are comparable in softness, flexibility and molding properties to commonly employed plastic worms (lures) made of vinyl chloride and yet free from the problems of environmental hormones, dioxin, etc. as occurring in the vinyl chloride lures. Namely, favorable fishing and fishery lures which would not remain in nature and thus are non-detrimental to the environment are provided.

Description

1 520978 V. Description of the Invention (!) [Technical Field] The present invention relates to fake fishing lures. [Technical background] According to the knowledge, the fake fish feed used for fishing is mainly based on the gasification of ethylene and plastic traps. Recently, "except for chlorinated ethyl chloride, such as = this published patent" υ Special Kaiping n] Coffee No. 5 "Name: Bio-induction", Special Kaiping n-7 Satoshi "Name: Biodegradable soft 2) JP 11-318277 "Name n & °" 243813 "Name: Environmentally friendly fake bait", 3) JP Kai "Name: Degradable bait", 4) JP Kai Yu 26 rhyme and its Manufacturing method ", 5) Japanese Patent Application No. 10-279762" Name = 2 alcohol-based water-containing condensate composition and its main ingredient, Kaibei 844 for fishing. No. "Name ·· Induced Fu of Biodegradable Resin;) = 平 9_27 助 胄" Name: Manufacturing method and time of fishing ". Faxian_ ", 8) JP 7_213204" Name: Fishing Supplies ", and 9) JP, 2__15" Name: Fake Fish Dance and its manufacturing method "and so on. 2 Alternatives to gasified ethylene-based fake fishing baits are generally not commercially available or not yet widely available. It is known that gasified vinyl plastic insects have flexibility and binding properties, and have good recognition of fish, so they are widely used in fake fishing lures. However, in the current state of use, most of these fake fishing lures have been broken and discarded in nature because they are lost from the needle during use, or lost by being caught by stones or wood in the water. As a result, the discarded fake fish _is in its original form = left in nature: the world t 'may produce a fish that swallowed the plastic worm and died by being accidentally eaten by fish and birds. The body will absorb the solvent (such as Kejia Standard (CNS) A4 specification (G X 297 mm) 312852 Order line 520978 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (2) Plasticizer) 'Inedible due to odor formation. In addition, if the incineration is concentrated, it will cause the problem that harmful substances such as dioxin may be produced and the plastics will become soft, so it is necessary to add plasticizers such as vinegar and so on to generate environmental hormones and other problems. The present invention solves such problems, and provides a fishing and fishing industry that has the same softness and flexibility as the gasified ethylene plastic insects, and solves the problems of environmental hormones and dioxin, and has excellent environmental protection properties that do not remain in nature. Use fake fishing lures. [Invention of the Invention] After various investigations of the present invention, it was found that if the acrylic polymer is thrown, a fake fish _ which can improve the above problems can be obtained, and the present invention has been completed. That is, the present invention is: (1) a fake fish feed made of an acrylic polymer and an acrylic polymer; (2) The fake fishing lure according to the above (1), wherein the acrylic polymer is polyacrylic acid or a salt thereof. (3) The fake fish as described in (1) or (2) above, which is a water-soluble polymer. (4) The fake fishing lure as described in (1) or (2) above, which is a water-insoluble polymer. (5) The pseudo-yudian as described in (4) above, wherein the water-insoluble polymer has a crosslinked structure. (6) The fake fishing lure as described in (4) or (5) above, is composed of polyacrylic anion 'and a salt of a polyvalent cation, or a salt of a polyvalent cation and a salt of a monovalent cation. (7) The fake fishing lure as described in (6) above, wherein the salt of polyacrylic acid anion and polyvalent cation is a polyvalent metal salt of polyacrylic acid. (8) As described in (6) above, the polyacrylic acid anion and multivalent paper scale are applicable to China National Standard (CNS) A4 specifications (2:,: 312852 (Please read the precautions on the back first) (Fill in this page again)

It m ^ ^ I n n —ϋ ϋ i #) Talk 78 A7 B7 V. Description of the invention (3) Cation salt, as much as polyacrylic acid ^ > Saddle salt. (9) As described in any one of (1) to (8) above; the fake fishing lure described in item (1); (10) As in any of (1) to (9) above ~ A 1; It is relative to the total weight of the fake fish, and the moisture content is 5% to 90% by weight. (11) The fake fishing lure as described in item 0 in any of (1) to (10) above, which is printed by the crab consumer department of the Huihui Property Bureau employee consumer cooperative (12) As described in (1) to (n) above The fake fishing bait described in any of the items above, which contains pigment. (13) The false fishing lure as described in any one of (1) to (12) above, which is surface-treated with a polyvalent cation. (14) A method for manufacturing a fake fishing lure, which is characterized in that an aqueous solution of acrylic acid or a salt thereof is charged into a mold for molding and polymerized. (15) The method for manufacturing a fake fish as described in (14) above: polymerization is carried out in the presence of a crosslinking agent. (16) As described in (14) or (15) above, the preparation method of "&"; and "bait" is the content of acrylic acid or its salt in the aqueous solution of 10% by weight and 3% by weight. (1? ) The method for manufacturing a fake fishing lure as described in any one of (W) to (I6) above, wherein the polymerization is static polymerization. (18) The fake fish described in any of (14) to (17) above The manufacturer of _ is treated with polyvalent cations after the polymerization. ⑽The manufacturer of the fake fish series described in any one of (14) to ⑽ above is a polyvalent metal ion or a polyvalent cation. Amine cations. (2 0) — a kind of fake fish feed: It is made of acrylic acid_________________________ The hydrated gel of the compound is applicable to China National Standard (CNS) A4—Specifications (referred to as χ 297 公 楚) ^- -------- — Law

312852 520978 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Description of Invention (4) Composition. [Preferred Aspect of Implementing the Invention] The fake fishing lure of the present invention is an acrylic polymer composed of an acrylic polymer, as long as it can form a water-containing formed body, and: The range which prevents formation of a molded body may be a copolymer with a monomer other than a propylene-based monomer. From the viewpoint of environmental protection and the like, the preferred ones may be polyacrylic acid or pots which are less toxic to living organisms and the like. The salts of acrylic acid only need to be those of acrylic acid anions and cations = OK, such as metal salts that form salts with metal cations, money salts that form salts with cations, or organic amine salts that form salts with organic amines. Examples of the metal salt include polyacrylic acid alkali metal salts such as sodium salt, potassium salt, etc .; polyacrylic acid test metal salts such as magnesium salt, calcium salt, and barium salt; polyacrylic acid salt and the like. Examples of the money salt include ammonium polyacrylate. Examples of the organic amine salt include triethylamine salt, ethylenediamine phosphonium, 1,3-propanediamine salt, -butanediamine salt, N, N-dimethylethylenediamine salt, or dimethylamine propylamine salt, etc. The chain aliphatic amine salt is preferably a polyacrylic acid chain aliphatic amine salt, piperidine which is unsubstituted or substituted with & mono or N, N-di (ci ~ C3) alkyl chain aliphatic amine salt. Salt, 1- (2-aminoethyl) piperidine salt, and other cyclic fatty aliphatic amine salts; most of them are unsubstituted or 6-membered rings substituted with N- [amino (C1 ~ C4) alkyl] Polyacrylic acid cyclic aliphatic amine salt of aliphatic amine salt, 2,3_ diamine. Specific aromatic amine salts such as bitumen salts and pyrimidine salts; preferably 6-membered ring aromatic amine salts that can be substituted by amine groups; polyacrylic acid aromatic amine salts; chitosan salts and other organic polyamines to form salts Polyacrylic acid polyamine salt; polyacrylic acid glycine salt and other polyacrylic acid amino acid salt; polyacrylic acid chitosan amine salt and the like. Although acrylic polymer can be water-soluble polymer, non-water-soluble polymer ------------ install -------- order ----- as (Please read first Note on the back, please fill in this page again.) Use the national standard (CNS) α4 specification < 21〇X 297 mm) of the national paper (312852) to print the paper. 312852 Printed by the Intellectual Property Bureau Employee Consumer Cooperative 520978 ... Α7 V. Description of the invention (Any one of them, but in consideration of durability such as form stability in water, it is preferably a water-insoluble polymer. In addition, an acrylic water-soluble polymer dissolves in a short time from water (Such as 丨 hours to 2 hours), gelation after absorbing water, and gradually dissolve over a long period of time (such as J months to 2 months, longer time is more than half a year) and other forms, but usually because of the expectation of a certain The degree of durability is good, so it is best to gradually dissolve it over a long period of time. Although the polymerization degree of acrylic polymer must be at least to the extent that the polymer can form a hydrogel, the elasticity of the fake fish series is considered. , Durability and other factors, the average molecular weight is usually higher the better, generally more than 1 million, It is preferably more than 3 million. From an economic point of view, the upper limit is about 10 million (non-crosslinked state; determined by the GCP method). Acrylic water-soluble polymers can be, for example, polyacrylic acid, polyacrylic acid anion, and amidine. Salts of shell cations (! Valent metal cations, ^ cation grade cations) (In this description, depending on the situation, also referred to as acrylic acid valent cation salts). Polyacrylic acid anions and valent cation salts can be For example, polyacrylic acid alkali metal salts such as polyacrylic acid sodium and potassium acrylate; polyacrylic acid aliphatic monoamine salts such as polyacrylic acid ammonium salt, polyacrylic acid diethylamine salt; polyacrylic acid amino acid salts such as polyacrylic acid glycine; Acrylic acid, furfurylamine salt, etc. Monovalent cation salts have excellent transparency characteristics. Acrylic water-insoluble polymers include, for example, acrylic polymers with a cross-linked structure or polyacrylic acid anions and polyvalent cations. The polyvalent cation is, for example, a divalent cation or a trivalent cation, and preferably a valent cation. The acrylic polymer having a crosslinked structure may be, for example, crosslinked Polyacrylic acid and its salts. The degree of crosslinking is relatively acrylic water-soluble monomer 312852 -------- ^ --------- (Please read the precautions on the back before filling this page ) 520978

Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, S A7 V. Description of Invention (6) The knife's parental compound, Morse ratio, ranges from 50,000 to 1%, especially from 5,000 to 1 A degree of one-fifth is better, and the range of one-two-hundred and fifty-five hundred and fifty-five is the best. The salts are, for example, metal salts, ammonium salts, or organic amine salts. Examples of the metal salt include cross-linked polyacrylic alkali metal salts such as sodium salt and potassium salt; cross-linked polyacrylic alkaline earth metal salts such as magnesium salt, calcium salt, and barium salt; cross-linked polyacrylic aluminum salt, etc. . The ammonium salt may be, for example, a cross-linked polyacrylic acid salt with a salt of gas; the organic amine salt may be, for example, triethylamine salt 'ethylenediamine salt, 丨, 3-propanediamine salt, 丨, butadiene Ammonium salts, N, N-diamidinoethylenediamine salts, or 3-diamidinopropylamines, preferably aliphatic, unsubstituted or substituted with N-mono or di (C1 ~ C3) alkyl Cyclic aliphatic amine salts such as cyclic aliphatic amines such as crosslinked polyacrylic acid chain aliphatic amine salts, brisidine, 1- (2-aminoethyl) piperidine; preferably with unsubstituted or Crosslinked polyacrylic acid cyclic aliphatic amine salt of N_ [amino (C1 ~ C4) alkyl] substituted 6-membered ring aliphatic amine salt; 2,3_ diamine pyridine, mouth bite and other aromatic amines ; Preferably a polyacrylic acid aromatic amine salt of a 6-membered ring aromatic amine salt which can be substituted by an amine group; a parent-linked polyacrylic acid polyamine salt with salts of other organic polyamines such as chitosan; Cross-linked polyacrylic chitosamine salts and the like. 1 The polyvalent cations in the salts of polyacrylic acid anions and polyvalent cations are preferably (2 to 3) valent cations (divalent cations or trivalent cations), and more preferably divalent cations. Examples of the divalent cation include a divalent metal cation and a divalent amine cation. Examples of the divalent metal cation include an earth metal ion such as magnesium ion, ion barium ion, and the like. Divalent saddle cations such as ethylenediamine cations, 3, propanediamine cations, and M_τ ruler are suitable for home use (CNSM4 specifications (g-equipment -------- order ---- ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Ministry of Economics and Intellectual Property, printed by 520978 V. Description of Invention (7) Ion, N, N < f-ethylenediamine cation, or 3 • dimethylamine Aromatic divalent amines such as propylamine cations, cyclic aliphatic 2½㈣ ions such as H2_aminoethionic ions, aromatic] valent amine cations such as cations, etc. Salts of polyacrylic acid anions and polyvalent cations, for example, Poly (polyacrylic acid), poly (polyacrylic acid), polyacrylic acid (polyacrylic acid), etc. Polyacrylic acid (polyacrylic acid) polyvalent metal salts such as magnesium polyacrylate, calcium polyacrylate, barium polyacrylate and other polyacrylic acid testers are trending today. ; Private ^, metal sol, polyacrylic acid aluminum, polyacrylic acid iron, polyacrylic acid copper, polyacrylic acid, etc. Polyvalent amine salts of polyacrylic acid, such as poly (ethylene diamine), poly (propylene diamine), polypropylene Butanediamine gallate, N, N • dimethylethylenediamine salt of polypropionate And polyacrylic acid aliphatic polyvalent amine salts such as polyacrylic acid 3_dimethylamine propylamine salt; polyacrylic acid piperidine salt, polyacrylic acid 1 (2-aminoethyl) piperidine polyacrylic acid cyclic aliphatic polyvalent amine salt di Polyacrylic acid aromatic polyvalent amine salts such as polyacrylic acid 2,3-pyridine diamine salt and polyacrylic acid pyrimidine salt; polyacrylic acid polyamine salts such as polyacrylic acid chitosan salt, etc. Polyacrylic acid is also included in the above acrylic polymers Partially neutralized. This polyacrylic partially neutralized system can be used for polyacrylic acid test metal salts such as polyacrylic acid, polyacrylic acid sodium or polyacrylic acid unloading, polyacrylic acid alkaline earth metal salts such as polyacrylic acid lock or calcium polyacrylate, Polyacrylic acid or amine salt of polyacrylic acid, etc. 'Acquired by acid or test by partial reconciliation method, or acrylic acid and acrylic acid alkali metal salts such as sodium or potassium acrylate, acrylic acid or acrylic acid Obtained by the method of copolymerization of acrylic water-soluble monomers such as metal salts of aluminum, aluminum acrylate, or amine salts of acrylic acid. In addition, partially neutralized polyacrylic acid with crosslinked structure also belongs to the present invention. -ϋ · ϋ i-ϋ nnm in if ί ϋβ I · m -I- ii---1 1-- i aiT · i -I- nnnin · (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 regulations (210 X 297 meals) 7 312852 520978 Member of Intellectual Property Bureau of the Ministry of Economic Affairs X Consumer Cooperation U printed A7 V. Description of the invention (Crosslinked structure used in Ming Dynasty Acrylic polymers are obtained in the same manner as described above. 帛 The fake fish spinner of the present invention can be used. From the viewpoints of softness, elasticity, specific gravity, and ease of engagement, it is preferably a water-containing formed body, and most preferably: Color body. The moisture content of this hydroformed body is 50 i 90. The whole is better, better, 5%, especially in the range of 60 to 85% by weight. # More is 70 to 85% by weight of chromium. Wife helmet Φ is better to say, those who are inside / 〇 粑 Wai is better. In addition, it contains other additives. It is suspected that other food-promoting bait substances (or preparation inducers) other than pigments, preservatives, and anti-mold agents, etc., have a content of 0 to 20 weight. Second, preferably in the range of 0 to 10 weight 1%. The remainder is acrylic polymer. In addition, when the fake fishing lure is colored, its hue is not particularly limited. For example, hue, black, brown, light blue, blue, red, white, pink, shell, or pumpkin can be used. ^ When manufacturing the fake fishing bait of the present invention, it is only necessary to fill an aqueous solution such as an acrylic water-soluble early body into a fake fishing bait model, and then mix the polymer in a crosslinkable state as required, and then obtain the obtained water-containing polymer. (Water-containing gel) Just take out the second mold. It is also possible to polymerize to obtain an agar-like water-containing polymer (aqueous gel) in a state where the water / valley solution of the acrylic acid-based water-soluble monomer is crosslinked, and then the obtained water-containing polymer may be formed. . Acrylic acid-based water-soluble monomers, when using acrylic acid and the above-mentioned polyvalent cation salts, usually form acrylic water-insoluble polymers after polymerization. The content of the acrylic water-soluble monomer in the aqueous solution is preferably from 丨 0 to 50% by weight, especially from 15 to 40% by weight, and more preferably from ^ to) ^% by weight. For the best. 312852 9 ------- Order · -------- (Please read the notes on the back before filling this page) 520978 A7 " " " '" " " " " '-------—_ —__— B7__ V. Description of the invention (9) In the manufacture of the fake button pull π of the present invention, "" the acrylic water-soluble monomer used at the time is, for example, acrylic acid. And / or its salts. In addition, depending on the situation, if it does not hinder the form (please read the precautions on the back before filling this page), it can also be used to copolymerize with water-soluble monomers of propylene. The monomers are preferably water-soluble monomers. Acrylates include metal salts, ammonium salts, and amine salts thereof. Metal salts of acrylic acid, such as alkali metal salts of acrylic acid such as sodium acrylate and potassium acrylate; Acrylic alkaline earth metal salts such as calcium acrylate; or aluminum acrylate, etc. Ammonium salts of acrylic acid, such as ammonium, triethylamine, ethylenediamine, 1,3-propanediamine, ι, 4-butanediamine Amine salt, Ν, Ν-: methyl ethylene diamine salt or 3-monomethylamine propylamine salt and other acrylic aliphatic amine salts; piperidine salt of polyacrylic acid or 1- (2 -Amino ethyl) piperidine salt and other acrylic cyclic aliphatic amine salts, acrylic acid 2,3 · ^ bite diamine salt or pyrimidine salt and other acrylic acid aromatic amine salts and acrylic acid polyamines and other acrylic polyamines Salts, acrylic acid glycine and other propionic acid amino acid salts, acrylic acid shell sugar amine salts, etc. Among them, the alkali metal salts of acrylic acid are preferred, and sodium acrylate is particularly preferred. Acrylic water-soluble monomers can also use partially neutralized acrylic acid. The partially neutralized acrylic acid is obtained by adding an arbitrary amount of a base to acrylic acid to achieve a desired pH such as ρΗ3 to 8.5. The base referred to is, for example, Sodium hydroxide, potassium hydroxide, amine, etc. In addition, acrylic acid and acrylic acid metal salts such as sodium acrylate or acrylic acid, acrylic acid metal salts such as magnesium acrylate or acrylic dance, or acrylic acid metal salts such as acrylic acid Or acrylic acid amine salt, mixed at any ratio (for example, the weight ratio of acrylic acid and acrylic acid metal salt, or acrylic acid and acrylic acid amine salt ranges from 7: 3 to 1:20) Partially neutralized products of dilute acid. In addition, the size of acrylic paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 312852 520978 A7 B7 Preparation of the invention 5. Partially neutralized product (10), the amine component of the above-mentioned amine salt can be added in any amount, and the same can be paid. These acrylates can be used alone or several kinds of salts (Such as sodium acrylate + magnesium acrylate + chitosamine salt of acrylic acid) are used together. Pigments can also be added to the aqueous solution of acrylic acid water-soluble monomers. By adding pigments, colored fake fishing lures can be obtained. The pigment is not particularly limited, and a water-soluble pigment is preferred. For example, edible blue No. 1, edible red No. 102, or edible yellow No. 4 pigments, Kay aery 1 Yellow 3RL, Kayacryl Red GRL, or Kayacryl Blue GRL (trade name, produced by the company). Basic) dyes, or basics such as Kayaeryl Red CB Liqmd ^ Kayacryl Buie CF Liquid > Kayacryl Yellow CG Liquid ^ Kayacryl Black CN Liquid > Kayacryl Red B Liquid or KayacrylRedPLiquid (trade name 'Nippon Kayaku Co., Ltd.) Dye or direct dye. The pigment may be used by mixing two or more kinds at any ratio. The amount of the pigment to be added is preferably from 0.001 to 50%, and more preferably from 2.00 to 2.0%, relative to the weight of the acrylic water-soluble monomer (converted to i⑽% by weight). In addition, in order to increase fishing results in an aqueous solution of an acrylic water-soluble monomer, a fish-inducing substance may be added. Examples of the fish-inducing substance include amines containing essential amino acids such as chloroine, leucine, isoleucine, threonine 'phenylpropionate, tryptophan' lysine, or methionine. Acid, fish oil or fish meal. In addition, in an aqueous solution of an acrylic water-soluble monomer, such as a mold inhibitor, an inorganic filler, a release agent, an antistatic agent, and ultraviolet absorption can be added in accordance with the purpose within a range that does not harm the purpose of the hair. Agent, flame retardant

10 312852 ------— — I .—— »t (Please read the phonetic notes on the back before filling out this page) Order --- Printed by the Ministry of Economics and Intellectual Property Bureau Employee Consumer Cooperative 520978 V. Description of Invention (U Common additives such as oxidants, fluorescent fluorene, anti-radiation materials, or pigments. The fake fish slanting mold used in the manufacture of the fake bait of the present invention is, for example, a deep cup, a straight line, a beaver tail type, a needle type, a claw , Bead-shaped, throat-shaped fish-like, spear, curled, fish-shaped or spherical, etc. are preferred as the shape of the bait. The mold is usually made by carving the resin into the shape of the desired fake bait. Although this resin can be used arbitrarily, such as Either synthetic resin or natural resin, but preferably acrylic resin, ABS (acrylonitrile, butadiene, and styrene three-component copolymer) resin and other synthetic resins. It can also be a metal mold or Molds made of materials that do not interfere with polymerization can be used. For example, molds made of aluminum or aluminum alloys. There are no particular restrictions on the polymerization of water-soluble acrylic monomers. It is best to perform polymerization by standing. Usually, polymerization is used. Initiator For example, a method of obtaining a gel-like polymer in a static state without stirring an acrylic water-soluble monomer stock solution. The so-called polymerization initiator is not particularly limited as long as it can generate free radicals, such as Water-soluble polymerization initiators such as persulfate or azo-based compounds. Examples of the so-called persulfate include sodium persulfate, potassium persulfate, or ammonium persulfate. The so-called azo-based water-soluble polymerization initiator is, for example, 2,2'-Azo · bis- (2 · methylpropane) 2 hydrochloride, 2,2, _azo_bis_ [2 _ () _ imidazol-2-yl) propane] 2 hydrochloric acid Salt, 2, 2, azo-dimethyl_N · (2-hydroxyethyl) propanamine], 4,4'-azo-bis- (4-cyanovaleric acid), or 2, 2, azo Nitrogen-bis- (isobutyronitrile) and the like. Among these polymerization initiators, from the viewpoint of preventing poor shape reproducibility of a molded body due to polymer shrinkage during polymerization, and false fish stew: a specific gravity control viewpoint means that, for example, an azo compound can be preferably produced. Water-soluble polymerization of other gases 312S52 -------- ήπ --------- (Please read the precautions on the back before filling this page)

II 520978 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (12) Starter. By using a water-soluble polymerization initiator that generates such a gas, Panyu generates nitrogen during polymerization, which can prevent the fake fishing lure from shrinking during polymer polymerization in the forming mold, and improve the shape reproducibility of the molded body. The amount of gas generated can be adjusted for specific gravity. Among the azo-based water-soluble polymerization initiators, 2,2, -azo-bis- (2-methylpropionamidine) 2 hydrochloride is preferred. The polymerization initiator is in an amount of 0.05 to 2.5%, and preferably in an amount of 0.05 to 5% by weight based on the weight of the acrylic water-soluble monomer (equivalent to 100% by weight). This polymerization initiator is added to an aqueous solution of an acrylic aqueous solution monomer. In the polymerization, a chain transfer agent such as a hydrogen sulfate such as sodium bisulfite, a polymerization accelerator such as L-ascorbic acid, or sodium hypophosphite such as a polymerization degree adjusting agent can be used. In addition, a lid is usually placed on the mold during polymerization. The cover is, for example, glass, plastic, wood or metal plate, preferably glass. In addition, tools can also be made. A mold having a pair of left and right monomer injection inlets, and after overlapping the molds, the monomer aqueous solution was injected from the early body injection inlet, and then polymerized. The polymerization temperature is not particularly limited as long as it is above TC. In order to complete the reaction in a short time, the heating conditions are preferably 40 to 70 degrees C. The polymerization time is usually about U 30 hours. In addition, when When the size of the fake fishing lure is relatively small, it is usually difficult to polymerize in the presence of air, so it is usually polymerized in nitrogen. Method 'The cross-linked polymer that is better obtained is an aqueous polymer, especially a method to obtain an aqueous gel, and any one of these methods may be used without particular limitation. Specifically, it is preferable to cross-link the polymer. Perform 12 312852 in the presence of agent ------------- install --- (Please read the precautions on the back before filling this page) ---- Order -------. # 1 520978 Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (13) Polymerization results in cross-linking. Depending on the situation, acrylic water-soluble monomers can also be polymerized according to self-crosslinking conditions, etc. And after polymerization, it can also be cross-linked by radiation irradiation. For example, as long as there are cross-linkable substances, any one can be used, but most of them have unsaturated groups such as double bonds. For example, di- or tri (meth) acrylates (acrylates) of (1) polyols, (2) Di- or tri-maleene-di-acid esters of polyhydric alcohols, (3) Di- or tri-fumarates of polyhydric alcohols, (4) Dipropenamides, (5) Polyepoxy Bis or tris (meth) acrylic acid esters obtained by reacting compounds with (meth) acrylic acid, (hexa) polyisocyanate and (meth) acrylic acid methacrylic acid dimethacrylates obtained by ester reaction, ( 7) Polyallyl allyl compounds, etc. Among them, those having two unsaturated groups are preferred. (1) Di- or tris (meth) acrylates (acrylates) of polyhydric alcohols, such as B Glycol di (meth) acrylate, propylene glycol di (meth) acrylate, trimethylolpropane (meth) acrylate, trimethylolpropane (fluorenyl) acrylate, glycerol di ( (Meth) acrylate, glycerol tri (meth) acrylate, 'polyethylene glycol di (methyl) Acrylates, polypropylene glycol di (meth) acrylates, polyglycerol di (meth) acrylates, polyglycerol tri (meth) acrylates, etc. (di) Di- or tri-maleic acid of polyhydric alcohols The esters are, for example, ethylene glycol dimaleate, propylene glycol dimaleate, 'trimethylolmalonate, and trimethylolmalonate Diesters, Glycerol Dimaleate, Propylene Glycol Di Maleate, Polyethylene Glycol Di Maleate, Poly Glycol Di Maleate Type, polyglycerol dimaleate, polyglycerol trimaleate ------------ ^ -------- ^- ------- ^ (Please read the notes on the back before filling in this page) The standard of wood and paper is applicable to Chinese national standard (CN3) A4 (21 × 297 mm) 13 312852 520978 Intellectual property of the Ministry of Economic Affairs Bureau Consumer Consumption Cooperative Seal-s Α7 Β7 V. Invention Description (14) and so on. (3) Di- or tri-malonic acid esters of polyhydric alcohols, such as ethylene glycol di-malonic acid esters of 'propylene glycol di-malonic acid esters' of trihydroxyfluorenyl propylene dibutylene Diesters, Trimethylol Glycerol Butyrate, Glycerol Diglyceride, Glycerol Triglyceride Dibasic acid esters, polypropylene glycol difumarate, polyglycerol difumarate, polyglycerol trifumarate, and the like. (4) Diacrylamide refers to N, N-methylbis (fluorenyl) acrylamide and the like. In addition, among the dimethacrylates (meth) acrylates obtained by the reaction between (6) polyisocyanates and hydroxy (meth) acrylates, polyisocyanates are fluorene phenylene diisocyanate, hexamethylene diisocyanate, and the like. (VII) Polyallyl allyl compounds such as allylized starch, allyl cellulose, diallyl phthalate, tetraandroxypropoxyethane, pentaerythritol triallyl ether, and trimethylol Propylene triallyl ether, diethylene glycol diallyl ether, or triallyl tris (hexamelate) and the like. The (average) molecular weight of these cross-linking agents is most preferably in the range of 200 to 2000 'and in the range of 200 to 800. In addition, if the softness of the fake bait is taken into consideration, it is best to be water-soluble, especially if it has unsaturated groups such as two double bonds. ) Acrylates are best. The parent linker is added to an aqueous solution of an acrylic water-soluble monomer. The addition can be made from acrylic based on the shape, flexibility, softness, underwater attitude, or the relationship between stretch and recovery of W%. Please read the precautions on the back before filling this page. ) j-fitting ------- ordering ---- as far as possible paper size χ, ^,-; -------- winter leather dagger NS) A4 specification (210 χ 297 mm) 14 312852 520978 A7 B7

V. Description of the invention (ls) The relationship between the weight of water-soluble monomers printed by the Intellectual Property Office of the Ministry of Economic Affairs and the Consumers' Cooperatives shall be appropriately determined. Xin acrylic acrylic water-soluble monomer is relatively, flat basket (converted to 100% by weight), 0.01 to 5,0%, especially Λ] 'It is better to add it, especially from 0.1 to 3.0%, 〇 A range of .2 to 2.0% is more preferred. In particular, in the fake fish series of the present invention obtained according to the above method, the surface needs to be surface-treated with polyvalent cations (preferably treated as described above. Λ surface; μ * (2 to 3) scallop deionization) described above. The processing time is from 1 to 30 hours. Through such considerations, Lu Ru can reduce the solution and bloating in the water by controlling the degree of tolerance in the water. Polyvalent cations can be used as long as they are not compatible with others, such as those that are specifically made of dan, non-sexual, or bloated, such as cymbals; ", and ^ 5 such as metal ions or polyvalent amines. Polyvalent metal ions include, for example, magnesium ions: ion: or barium ions, alkaline earth metal ions, manganese ions, ions, iron ions, nickel ions, copper ions, zinc ions, or ions, ions, etc. Transition metal ions such as ions or aluminum ion polyvalent amine cations, such as triamine cations with two nitrogen atoms. Multi-compensated amine monoamines or two 1 4 butyl π U, such as ethylene di saddle, 1, 3 -Propane-amine, 1, butanediamine, Ν, Ν- difylidene-amine diamine amines _ _ diyinamine propylamine and other fats such as??. It is also an example of polyvalent amines, such as aliphatic polyvalent amines, aromatic dipyridyl amines such as 2,3-pyridine di-waste. Moreover, diamines. In addition, polyamines such as chitosan have nitrogen. Atomic aromatic compounds are also :: Virtually aromatic aromatic cores have two kinds of polyamines, which belong to the so-called polyvalent amines here. Many amine cations and other __: fake fish taken out of the mold, this standard is applicable to Shen Guo National Standard Leather (CNS) A4 size bait dipping 312852 ------------- packing --- ( Please read the notes on the back before filling out this page) Order ---------- ---------- 520978 A7 B7 V. Description of the invention (1ό) == Processing. Contains multiple prices Cationic metal ions or polyvalent amines / valley fluids are obtained by dissolving water-soluble metal salts or polyvalent amines in water. Water, silk, and genus cups “m ♦ Solutions are water-soluble Polyvalent metal salts, two = inorganic acid salts, specifically ... for example, chloride chloride, chlorine, aluminum, barium chloride, zinc chloride'magnesium bromide, evolved calcium, bromide ; Magnesium sulfate, calcium sulfate, ferrous sulfate 'sulfuric acid: valence metal sulfates; polyvalent iron salts such as magnesium stearate, calcium nitrate, aluminum nitrate; polyvalent gold such as magnesium sulfate, calcium carbonate, and aluminum carbonate :: And other substances: v can be used alone or in plural. In addition, polyvalent amines; then 3 is the inorganic acid salt or organic acid salt of the polyvalent amine as described above, and specifically, for example,-acid salt: sulfate, acetate, and the like. These amine salts can be used alone or in combination, or they can also be used for the surface treatment of the amine salts and the above-mentioned water-soluble polyvalent metal salts with amine cations, as compared with the case of treatment with polyvalent metal ions. Fake fish may get transparent. —The concentration of polyvalent cations in aqueous solution is expressed by the concentration of polyvalent cation salts (water-soluble polyvalent metal salts or polyvalent amine salts), preferably in the range of 0 to the solubility concentration [%], especially in the range of A range of 10 to 30% is preferred. The surface treatment time varies depending on the type of fake fishing lure used. For example, in the case of a linear system, it is preferably 3 to 7 hours. In the case of a spherical system, it is preferably 10 to 25 hours. Depending on the time of the surface treatment, the rate of collapse or swelling can be controlled. In the present invention, a fake fishing bait composed of a water-insoluble acrylic polymer-based polyacrylic acid anion, and a salt of a polyvalent cation, or a salt of a polyvalent cation, and a salt of a monovalent cation is a combination of Acrylic acid and multivalent nuclear plume (CNS) A4 profile (Gx 297 M) · L〇 (Please read the precautions on the back before filling out this page) · · ϋ n mu m «ϋ US 1—Order --------- ♦ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 520978 Printed by A7 of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives V. Description of the invention (17) Monomer composed of cation salts, or Acrylic acid is obtained by polymerizing a monomer mixture composed of polyvalent cation salts and monovalent cation salts-奂 ##, and neck (preferably polymerization under cross-linking conditions). In this case, one or more kinds of polyvalent cations can be used, and two or more kinds of fake fish made of water-insoluble water-soluble polymers can be used. Even without surface treatment, they are less soluble and swell in water. With superior durability. In addition, when the combination of @enoic monovalent cation salt is used, if the -valent cation salt is more, because the prepared aqueous polymer dissolves and swells in water faster, it is more soluble than water, Swelling and other conditions are rare, and the less the content is, the better, the amount is 40% or less, and preferably 30% or less, relative to the overall acrylate. Although the fake bait of the present invention obtained by the above method may be uncolored, it may be colored on the surface. The pigment used is the above-mentioned water-soluble pigment. For surface coloring, you can use a brush or pen to apply pigment, or you can dip it in the pigment solution. In the case of immersion, it can be performed simultaneously with the surface treatment of metal ions (for example, immersion in an aqueous solution of metal ions to which a pigment is added). Alternatively, pigmentation may be used. A variety of pigments can be used as long as they do not give adverse effects such as toxicity to fake fish. & Coloring with a pigment, for example, using a brush or pen, applying the pigment to a fake fishing lure. In addition, a water-soluble dye may be colored in advance after it is added to an acrylic water-soluble monomer aqueous solution and then polymerized. The fake fishing lure of the present invention can be used in any place where fishes exist, such as the ocean, river, lake, pond, or swamp. In addition, target fish can be used such as black bass, blue gill fish, rainbow fish, brown fish, catfish, catfish, (CNS) A4 ⑵ 0 X 297 312852 nn · I— I— mmmmme dmame n · 1 niii V r · nnn 11 nnn ^ ^ · nn fi 11 nnn I (please read the precautions on the back before filling this page) 520978 A7 ¾ Consumer Co-operation of the Intellectual Property Bureau of the Ministry of Economic Affairs, Printing by the Society V. Invention Description (18 minutes ", Fish, flat fish, big scorpion fish, flying fish, flounder, magochi, ghost knife", and all kinds of fish collectively called fish eater. The size of the fake bait of the present invention depends on the target fish. The size varies, as long as the size can be made by a fake fishing lure, and any size can be used. [Example] Its ~ person, the present invention will be described in more detail through examples, but the present invention is not limited to this. Examples 1-1 Deoxidize 100 g of a 38 / 〇 acrylic acid aqueous solution in nitrogen, and add a mixed solution of 0. j / 〇L-ascorbic acid aqueous solution 25ml, 0.24ml of a 5% ammonium persulfate aqueous solution, and infuse in ABS resin, engraved into a deep cup, straight , Sea pinch type, needle type, claw, beaded, throated fish-like, spear 'roll # shaped mold' and covered with a glass plate, and then heated to 60 C in a nitrogen atmosphere to carry out the polymerization reaction After the polymerization reaction is completed, each molded article of sodium polyacrylate is taken out from the mold, and the fake fish of the present invention (sodium polyacrylate) is prepared. Example 1-2 38% sodium acrylate aqueous solution 1 〇〇g was deoxygenated in nitrogen, and 0.3% L-ascorbic acid aqueous solution was added. 25%] 5% ammonium persulfate aqueous solution was 0.24ml, and a 0.3% sodium hypohalite aqueous solution was mixed with 〇24mi. ABS resin, engraved into a deep cup, straight line, beaver-tailed, needle-shaped, claw, beaded, throat-shaped fish-like, spear-shaped mold, and covered with a glass plate, then under nitrogen Under the environment, heat to 60 ° C and then proceed to the polymerization reaction. After the polymerization reaction is completed, each of the sodium polyacrylate (please read the precautions on the back before filling this page) --- ^ 9— Chinese paper (CNS) A4 size (210 X 297 public hair y 312852 52097) 8 Printed by A7 B7, member of the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 5. Description of the invention (19) The molded article was taken out of the mold to prepare the fake fishing bait of the present invention. Example 1-3 A 30% sodium acrylate aqueous solution was used. 〇g was deoxidized in nitrogen, and a mixed solution containing 0.3% L-ascorbic acid aqueous solution 0.25ml and 5% ammonium persulfate aqueous solution 0.24ml was poured into an ABS resin, and a deep cup, straight line, Beaver-tailed, needle-shaped, claw, beaded, throated fish, shaped, spear, and curled molds, covered with glass plates, and then heated to 60% under nitrogen. (: Polymerization reaction is performed. After the polymerization reaction is completed, each molded article of sodium polyacrylate is taken out from the mold to prepare the fake fishing lure of the present invention. Example 1-4 100 g of a 30% sodium acrylate aqueous solution was placed in nitrogen Deoxidation was carried out in a mixed solution of 0.3% L-ascorbic acid aqueous solution, 5% ammonium persulfate aqueous solution, 0.24 ml and 0.3% sodium hypophosphite aqueous solution, and 24 ml. Infused with ABS resin and carved in the shape of insect. Into deep cup, straight, beaver tail type, needle type, claw, beaded, throat plate fish, spear, curled mold, cover with a glass plate, and then heat to 6 (rc in a nitrogen atmosphere) The polymerization reaction is performed. After the polymerization reaction is completed, each molded article of sodium polyacrylate is taken out from the mold, and the fake fishing lure (made by sodium polyacrylate) of the present invention is prepared. Test Example 1 (Evaluation test of fake fishing lure) ) For the fake fishing lures prepared in the above embodiment, coloring according to the following method and use it for fishing, evaluate. L coloring method-nn ϋ Iff I nn · · Hi ϋ m I. —I -mi ? -1 ·-111 Is mi one I 9 I ϋ -n n 1 1 · — I 9 (Please read the notes on the back before filling in this page) Use Chinese National Standard (CNS) A4 (210 X 297 male) 19 312852 520978 A7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (20) The edible blue No. 1, edible red No. 102 or edible yellow No. 4 alone or the edible blue No. 1, edible red No. 102 and edible yellow Any appropriate amount of No. 4 was mixed into a 1% aqueous solution of partially neutralized polyacrylic acid [PanakayakuN made by Benhua Pharmaceutical Co., Ltd.]. This solution was applied to the pseudo-yudian of the present invention. 2. Evaluation method of fake bait The fake bait of the present invention (obtained in Examples 1-1 and 1-2) was used to investigate fishing in Kawaguchiko (Yamoto Yamanashi Prefecture) in mid-July (belonging to a summer tourist) And other anglers). The results are shown in Table 1-1. Table 1-1 (Please read the note on the back? Matters before filling out this page) _Installation ---- Order --------- Sample Forming Effect of the fake fish casting of the present invention Bait fishing number mold color CC) number of times result 1 throat fish BD 23 (times) 12 (times) 3 (only) 1 2 shaped ABE 24 6 1 0 3 ABD 25 5 2 1 4 throat fish BE 25 3 1 0 5 Shaped Throat Disk BD 25 10 2 0 6 Shaped Claw CE 25 3 1 1 7 Rosary Red D 26 4 3 0 In Table 1-1, sample numbers 1 to 6 are as shown in Example 1-2 Applicable paper scale] National Standard: CNS) A4 specification (210 χ297) 20 312R52 Printed by the Ministry of Economic Affairs, Intellectual Property and Intellectual Property Bureau, Consumer Cooperative 520978 A7 __________B7____ V. False Idian obtained from the invention description (21): 'Sample No. 7 is a fake fishing lure prepared in Example i. In addition, in the forming mold, A is the pointer type; in the color of the fake bait, B is the watermelon color; c is the light blue; the so-called equipment is the equipment, and in this equipment, the D is the long moving rod, e means short throw. In addition, in Table j, the number of swings refers to the number of throws, and the number of baits refers to the number of times a fish bites a fake bait. Sample 1 shows the result of hanging the fake bait on the needle and throwing it a total of 12 times, of which 3 times the hook was hooked to the fake bait (fishing result). As can be seen from the above Tables 1-1, the fake fishing lures of the present invention are among seven shaped bodies, three of which are harvested by fishing, and the number of times of eating bait is 13 times. Example 2 -1 To 100 g of a 20% aqueous solution of sodium acrylate, 3 g of an edible red 102 aqueous solution of 3% in red color was added, and a polymerization initiator vj〇 {22, · aerosol-methylpropylated vein was added) 2 Hydrochloride; Wako Pure Chemical Industries, Ltd. (stock) t} 0.13g, and KAYARAD PEG400DA {polyethylene glycol diacrylate vinegar: (average) molecular weight 522; a cross-linking agent made of Benhua Pharmaceutical (stock) } 〇22g, after deoxidizing the obtained mixed liquid with nitrogen gas to form bubbles, inject it into ABS resin, engraved into a deep cup, straight line, beaver tail type, needle type, claw, beaded shape, throat according to insect shape Fish-shaped, spear-shaped, curled molds. Covered with a glass plate, and then heated to 60 ° C. under a nitrogen atmosphere to conduct a polymerization reaction for 20 hours. After the polymerization reaction is completed, an aqueous formed product of each cross-linked sodium polyacrylate that is colored red, Take out from the forming mold to obtain the fake fish of the present invention without surface treatment. Feed the fake fish of the present invention without surface treatment: immersed in 5% gasification. Standard (CNS) A4 (210 297 mm) ------------- ^ -------- ^ --------- line (please read the back first (Notes on this page, please fill in this page again) 21 312852 520978 A7 B7 V. Description of the invention (22) The surface treatment was carried out in the aqueous solution for 20 hours, and the fake fish house (cross-linked polyacrylate insecticide) of the present invention was prepared. Example 2-2 In 100 g of a 20% aqueous sodium acrylate solution, 3 g of an edible blue aqueous solution No. 1 was added to 3 g of a blue pigment, 0.103 g of a polymerization initiator V-50 was added, and 0.22 g of KAYARAD was added. PEG400DA, after deoxidizing the obtained mixed solution by forming bubbles with nitrogen, it is poured into ABS resin and carved into a deep cup, a straight line, and a sea in the shape of a bomb. Pinch-tail type 'needle-shaped, claw-shaped, bead-shaped, throat-shaped fish-shaped, spear-shaped, curled mold. Covered with a glass plate, and then' heated to 60 ° C under a nitrogen atmosphere for 20 hours to polymerize After the polymerization reaction is completed, the water-containing shaped articles of each cross-linked sodium polyacrylate that are colored blue are taken out from the forming mold, and then immersed in a 5% gaseous rhenium aqueous solution for 20 hours. A false fish head according to the present invention was prepared: (crosslinked polyacrylate worm). Example 2-3 In 100 g of a 20% sodium acrylate aqueous solution, 3 g of a yellow colored aqueous solution No. 4 was added to 3 g 'Adding 〇3〇g of polymerization initiator v_50, and 0.22g of KAYARAD PEG400DA, the obtained mixture was deoxidized by forming bubbles with nitrogen, then poured into ABS resin, and carved into a deep cup with the shape of insects. , Straight 'beaver tail type, needle type, claw, beaded, throat plate fish, spear, curled mold. Cover with a glass plate, and then heat to 60 ° C for 20 hours in a nitrogen atmosphere. After the polymerization reaction is over, it will be colored yellow Each of the water-containing formed articles of the cross-linked sodium polyacrylate is taken out from the forming mold, and then immersed in 5% chlorine ------ 丨 —— 丨 丨, (Please read the note t on the back before filling (This page) Order --------- The scale of printed wood and paper printed by the staff of the Intellectual Property Bureau of the Ministry of Green Economy applies the Chinese National Standard (CNS) A4 standard (210 X 297 mm) 22 312852 Warp * The Ministry of Economics and Economics Bureau of Jibu's Consumer Property Co., Ltd. 520978 A7 _____B7 _ V. Description of the invention (23) After 20 hours in the magnesium aqueous solution, the fake bait (cross-linked polyacrylate insecticide) of the present invention is prepared. Example 2-4 To 100 g of a 20% aqueous sodium acrylate solution, 3 g of a blue pigmented 0/30 edible blue aqueous solution 1 and 3 g of a yellow pigmented 0.3% edible yellow 4 aqueous solution were added, and further added. .iog 3 polymerization initiator v-50, and 0.222g of KAYARAD PEG400DA, the obtained mixed solution was deoxidized by forming bubbles with nitrogen, and then poured into a deep cup with ABS resin and engraved in the shape of insect. Straight, beaver-tailed, needle-shaped, claw 'beaded, throat-shaped fish-like, spear-shaped, curly-shaped mold. Covered with a glass plate, and then heated to 60 ° C. under a nitrogen atmosphere to perform a polymerization reaction for 20 hours. After the polymerization reaction is completed, 'the water-containing formed articles of each cross-linked polyacrylic steel which are colored green are taken out from the forming mold, and then immersed in a 50/0 aqueous solution of magnesium oxide for 2G hours. The false bait (cross-linked polyacrylate insecticidal preparation) of the present invention was obtained. Example 2-5 To 100 g of a 20% sodium acrylate aqueous solution, 2.03 g of a 0.5% KayaCryl Yellow 3RL aqueous solution of a basic dye made by Nippon Kayaku Co., Ltd. was added, and 103 g of a polymerization initiator ν-5 was further added. 〇, and 〇22g of Kayarad PEG40〇DA, the obtained mixture was deoxidized with nitrogen gas to form a bubble, and then poured into ABS resin and carved into a deep cup, straight line, beaver tail type, needle type with insect shape. , Claws, beaded 'laryngeal fish-like, spear, curled mold. Covered with a glass plate, and then heated to 60 ° C under a nitrogen atmosphere to perform a polymerization reaction for 20 hours. The polymerization progressed well. To be aggregated (CNS) A4 1 grid 0 0 297 male «) --------------------- Order --------- (please first Read the notes on the back and fill out this page) 520978 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (24) After the reaction is completed, the water-forming of each cross-linked sodium polyacrylate that is colored yellow After taking out the object from the forming mold and immersing it in a 5% aqueous solution of magnesium gas for 20 hours, the fake fish head of the present invention was prepared: (crosslinked polyacrylate insects). Example 2-6 To a 100% aqueous solution of sodium acrylate, 100 g, 0.10 g of Kaycel Red CB Liquid, a test dye manufactured by Nippon Kayaku Co., Ltd., was added, and 0103 g of a polymerization initiator V-50 was added. With 0.22 g of KAYARAD PEG400DA, the obtained mixed solution was deoxidized with nitrogen gas to form a bubble, and then poured into an AB S resin, engraved into a deep cup, a straight line, a pinch tail type, and a needle type according to the shape of Jia Claws, beaded 'laryngeal fish-like, spear, curled molds. Covered with a glass breaker, and then heated to 60 ° C under a nitrogen atmosphere to perform a polymerization reaction for 20 hours. After the polymerization is completed, the water-containing shaped articles of each cross-linked sodium polyacrylate that are colored red are taken out from the forming mold and then dipped in a 5% gasified ballast aqueous solution for 20 hours to obtain The fake fishing lure of the present invention (crosslinked polyacrylate insecticidal system). Example 2-7 To a 20% aqueous solution of sodium acrylate, 100 g, a test dye Kayacel Blue CF Liquid, a stock solution of Nihon Kagaku Co., Ltd., 0.1 g, and 0.13 g were added. Agent ν-50 and 〇22g of KAYarad PEG400DA, the obtained mixed solution was deoxidized with nitrogen gas to form bubbles, and then poured into ABS resin and carved into deep cup, straight, beaver tail, needle Shaped, claw, beaded, throat plate fish, spear, curled mold. Cover it with a glass plate, and then add it to --------------- in a nitrogen atmosphere (please read the precautions on the back before filling this page) tr ------ --- This paper & degree applies Chinese national standard (CNS> A4 profile (210 X 297 mm) 24 312852 520978 Printed by Employee Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of invention (25) ° C The polymerization reaction was carried out for 20 hours. After the polymerization reaction was completed, the water-containing formed articles of each cross-linked sodium polypropionate colored blue were taken out from the forming mold, and then immersed in a 5% aqueous solution of magnesium gasification. After 20 hours of incubation, the fake fishing bait (cross-linked polyacrylate insecticidal preparation) of the present invention was prepared.

To 100 g of a 20% sodium acrylate aqueous solution, a Kay acel Yellow CG Liquid stock solution (K〇9 g, 0.103 g of polymerization initiator V_50, 0.22 g of KAYARAD PEG400DA, and The obtained mixed solution was deoxidized by forming bubbles with nitrogen, and then poured into a deep cup, straight line, sea pinch type, needle type, claw, beaded, throat plate fish with ABS resin and engraved with insect shape. Shape, spear, and curled mold. Cover with a glass plate, and then heat to 60 ° C under a nitrogen atmosphere for 20 hours. After the polymerization reaction is completed, each colored yellow The aqueous shaped product of the sodium polypropionate was taken out from the molding / molding tool, and then immersed in a 5% aqueous solution of magnesium gas for 20 hours to prepare the fake fishing lure (crosslinked polyacrylate) of the present invention. Insect control) According to the same method as in the above embodiments 2-1 to 2-8, a fake fishing bait of the present invention (Table 2-1) is prepared as follows. $ Tmnin I l it I lin I · I ϋ tl nnn ϋ 1 ° 4I nni I n 1 nf (Please read the notes on the back before filling this page) Applicable to the national standard (CNS) A4 specifications (210 x 297 mm 25 312852, printed by a member of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by a consumer cooperative) 520978 A7 B7 5. Description of the invention (26) Table 2-1 Example 2 -9 to 2-15 False bait sample dye polymerization initiator metal ion Example 2-9 A 1.5% ammonium persulfate aqueous solution Mg ion Example 2-10 BC Mg ion Example 2-11 AC Ca ion Example 2-12 BC Ca ion Example 243 A 1.5% ammonium persulfate aqueous solution Ca ion Example 2-14 DC Mg ion Example 2-15 D 1.5% persulfate aqueous solution Ca ion In Table 2-1, A Refers to Kayacel Red CB Liquid, B refers to the combined use of Kayacryl Blue CF Liquid, Kayacel Yellow CG Liquid, and KayacelRedCBLiquid, and C refers to 2,2, -azobis_ (2-methylpropane) 2 hydrochloride, D refers to Kay aery 1 Yellow 3 RL. In addition, in Examples 2-14 and 2-15, the coloring of the fake bait is not performed during polymerization, but after the surface treatment of metal ions. Mg refers to magnesium and Ca. Refers to the far bow. Example 2-16 To 78.9 g of 38% sodium acrylate aqueous solution, Japan was added Kaycel Yellow CG Liquid stock solution 0.27g, Kayacel Blue CF Liquid 0.02g and Kayacel Red CB Liquid 0.02g, and 77 3xng polymerization initiator V-50 is dissolved in 71.1g of water. 330mg KAYAJRAD PEG400DA in water. Next, after deoxidizing with nitrogen, it was poured into a spheroidal mold of acrylic resin. With glass plate (please read the notes on the back of S3 first and save this page to fill in this page) F Packing ----------- Ordering ---- This paper size is applicable _ national standard (CNS: A4 specifications ⑵〇χ 297 meals) 26 312852 520978

V. Description of the invention (27) Ministry of Economy-Ministry of Economic and Social Affairs Bureau, Consumer Cooperative, printed and covered the mold, and then heated to 6 (rc) under a nitrogen atmosphere for η hours of polymerization. After the polymerization reaction is over, The cross-linked aqueous sodium polyacrylate shaped product colored into watermelon color was taken out from the forming mold. Then, after being immersed in a 6% ferrous sulfate aqueous solution for a few days, the pseudofish of the present invention was prepared. Insect-resistant polyacrylate). Example 2-17 I Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 10% barium chloride aqueous solution, the rest were treated in the same manner as in Example 2_16 to prepare the fake fishing lure (crosslinked type) of the present invention. Polyacrylate insects). Example 2-18 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 5% zinc gaseous aqueous solution, the rest were treated in the same manner as in Example 24 to obtain a fake fishing lure (crosslinked polymer) of the present invention. Acrylic insects). Example 2-19 Except that the 6% ferrous sulfate aqueous solution in Example 2_1 was changed to a 10% calcium chloride aqueous solution, the rest were treated in the same manner as in Example 2-16, and a fake fishing bait of the present invention was prepared. Insect-resistant polyacrylate). Example 2-20 To 150 g of a 20% aqueous sodium acrylate solution, an aqueous solution in which 154.5 mg of a polymerization initiator V-50 and 750 mg of KAYARAD PEG400DA were dissolved was added. Next, after deoxidizing with nitrogen, it was poured into a fish-shaped worm mold made of acrylic resin. The mold was covered with a glass plate, and then heated to 60 ° C. under a nitrogen atmosphere to perform a polymerization reaction for 17 hours. After the polymerization reaction is completed, the non-colored (white) cross-linked type polyacrylic acid hydrous shaped product is prepared by n nf nnnd · m ϋ HI ϋ fm I «is I—n 1 II—1 nf Order ----- ---- Line (please read the notes on the back before filling this page) The paper size * applies the Chinese National Standard (CNS) A4 (210 X 297 mm) 27 312852 520978 A7 ___ B7 V. Description of the invention (28 ) After being taken out from the forming mold, a fake fishing lure (crosslinked polyacrylic acid insect) of the present invention was prepared without metal ion surface treatment. Example 2-21 (Please read the precautions on the back before filling in this page) In 20% acrylic acid metal salt solution i50g composed of calcium acrylate and sodium acrylate with a molar ratio of 80:20, i54.5mg is dissolved Polymerization initiator V-50, with 1.5 g of KAYARAD PEG400DA in water. Next, after deoxidizing with nitrogen, it was poured into a fish-shaped insect mold made of acrylic resin. The mold was covered with a glass plate, and then heated to 60 ° C under a nitrogen atmosphere to perform a polymerization reaction for 17 hours. After the polymerization reaction is completed, the non-colored (white) cross-linked polyacrylic acid-sodium hydrous formed article is taken out from the forming mold, and the fake fishing bait of the present invention (cross-linked type) without metal ion surface treatment is prepared. Polyacrylate insects). Example 2-22 Printed on a 20% acrylic acid metal salt aqueous solution 150§ composed of calcium acrylate, magnesium acrylate and sodium acrylate with a molar ratio of 40:40:20, printed by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and dissolved in 123.6 mg of polymerization initiator V_50, and 1.2 g of KAYARAD PEG400DA in water. Next, after deoxidation with nitrogen, it was poured into a cute insect mold made of acrylic resin. The mold was covered with a glass plate, and then heated to 60 ° C under a nitrogen atmosphere to perform a polymerization reaction for 16 hours. After the polymerization reaction is completed, the non-colored (white) crosslinked calcium polyacrylic acid sodium sodium hydroformed article is taken out from the forming mold, and then the fake fishing bait (crosslinked type) of the present invention is not subjected to metal ion surface treatment. Polyacrylate insects). Examples 2-2 3 In addition to the 2% 6% ferrous sulfate aqueous solution of Examples 2-16, the wood paper standard with a concentration of 17% was applied to the Shenyang National Standard (CNS) A4 gauge (21〇χ 297 cm) 28 312852 520978 A7 B7 printed by the Consumer Cooperative of the% -Hui Property Bureau of the Ministry of Economic Affairs V. Description of the invention (29) Except for the ethylenediamine dihydrochloride aqueous solution, the rest are treated as in Examples 2-16 to prepare the fake fishing lure of the present invention. (Crosslinked polyacrylate insects). Example 2-24 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 1% butanamine monohydrochloride aqueous solution with a concentration of 3%, the rest were treated as in Example 2-16, and The pseudo-yudian of the present invention was obtained: (crosslinked polyacrylate insecticidal). Examples 2-25 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 5% piperidine dihydrochloride aqueous solution, the rest were treated in the same manner as in Example 2-16 to prepare the present invention. Fake fishing lures (cross-linked polyacrylate insects). Example 2_26 except that the 6% ferrous sulfate aqueous solution of Example 2_1 was changed to a 3% monomethylaminopropylamine dihydrochloride aqueous solution with a concentration of 4%, the rest were treated as in Example 2-16 to obtain the present Invented fake fishing lures (crosslinked polyacrylate insects). Example 2-27 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 1,7% -diaminopropylhydrazone dihydrochloride aqueous solution with a concentration of 7%, the rest were treated as in Example 2-16 ' And the pseudo-yudian ^ cross-linked polyacrylate of the present invention is prepared). Example 2-28 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a diamine pyridine trihydrochloride aqueous solution with a concentration of 7 ° / 〇, the rest were the same as in Example 2_ ----- -------- Installation --------- Order --------- line (please read the notes on the back before filling this page) Each paper size applies Chinese national standards ( CNS) A4 size (210 X 297 mm) 29 312852 520978 Consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 B7 V. Processing of invention description (30) 16 The fake fish feed of the present invention (crosslinking) Type polyacrylic acid worm). Example 2-29 Instead of the 6% ferrous sulfate aqueous solution of Example 2-16, use a concentration of 8. Except for the N, N-dimethylethylenediamine dihydrochloride aqueous solution of 0%, the rest are treated as in Examples 2 to 16 to prepare the pseudo-urdian of the present invention: (crosslinked polyacrylate Insect control). Example 2-30 Instead of Example 2-16, the 6% ferrous sulfate aqueous solution was changed to a concentration of 9. Except for the 1- (2-aminoethyl) piperidine dihydrochloride aqueous solution of 0%, the rest were treated in the same manner as in Examples 2 to 16 to prepare a fake fishing lure (made by a cross-linked polyacrylate) of the present invention. insect). Example 2-31 Except that the 6% ferrous sulfate aqueous solution of Example 2-16 was changed to a 7% pyrimidine dihydrochloride aqueous solution, the rest were treated in the same manner as in Example 2-16 to prepare the present invention. Fake fishing lures (cross-linked polyacrylate insects). Example 2-32 In an aqueous solution of 1.52 g (15 mmol) of 36% hydrochloric acid, 73.5 g of water, and 2.42 g (15 mmol) of chitosan, 77 3rQg of polymerization initiator V-50 and 3 30 mg of KAYARAD were added. After PEG400DA 'and 72.6 g (293 mmol) of a 38% sodium acrylate aqueous solution, an aqueous solution of 43 g (15 mmol) of magnesium vaporization and 4.57 g of water was added. Next, it was poured into a linear Jiaying mold made of gasified ethylene resin and deoxidized with nitrogen. After the lid was directly closed, a polymerization reaction was carried out at 60 ° C for 19 hours in a nitrogen atmosphere. To be gathered -------- ήιτ * ---- (Please read the notes on the back before filling out this page) Each paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 30 312852 520978 A7 B7 printed by the Consumers 'Cooperative of Huizhi Spinal Production Bureau of the Examination Department. V. Description of the invention (31) After the reaction is over, take out the yellowish cross-linked sodium polyacrylate hydroformed product' from the forming mold, then A fake fishing bait of the present invention (crosslinked polyacrylic insect-producing worm) without metal ion surface treatment was prepared. Example 2-33 Mixture of 98% acrylic acid 8 853§ (1204 millimoles), 37.9% sodium acrylate aqueous solution 29.879g (120.4 millimoles), and KAYARAD > PEG400DA251.4mg (0.4816 millimoles) To the solution, 58_7mg (0 2167 亳 mol) of polymerization initiator v-50 and 61.268g of water in water were added "second" to a linear worm mold made of vinyl chloride resin, and deoxidized with nitrogen, and directly After closing the lid, a 16-hour polymerization reaction was carried out at 6 ° C. in a nitrogen atmosphere. After the polymerization reaction was completed, the yellowish cross-linked polyacrylic acid partially neutralized product (sodium) was formed into a water-containing product. It was taken out from the forming mold. Next, this water-containing formed article was immersed in a 20% magnesium sulfate aqueous solution for 1 day to prepare a fake fishing bait (cross-linked polyacrylate insecticidal agent) of the present invention. Test Example 2 (Blister Swelling test) The representative fake fishing lures of the examples shown in Table 2-2 were blistered in accordance with the following method! ± Evaluation. The transparency of the fake fishing lures obtained in the examples was also listed in Table 2-2. The evaluation of blistering property will be the fake fishing lure (about 1 to 3g) obtained in the present invention, In a large amount of water (approximately 100 to 200 g), immerse it overnight (usually 12 hours to 24 hours), measure its weight, divide this measurement value by the weight of the water-formed product before water, and obtain Values are indicated. Applicable paper size is _home standard (Cqing specifications ㈣7 ^) 3 fun ^^ 1 ϋ_ »—ϋ 11 · ϋ 1 ^ 1 m ^^ 1 · ϋ n · 11 n II n I Mmmm§ I nf, . < l_9 mnnn an m I (Please read the notes on the back before filling in this page) 520978 A7

V. Description of the invention (32) Transparency evaluation 23 to 2-31 Transparency evaluation is based on the following criteria. Those who obtained the fake fishing lures showed a sense of transparency: those who were transparent like tofu-like opaque ones were in the middle: those who were opaque are shown in Table 2-2, Examples 2-1 and 2 16 "Through Moon A16, 2-17, n And 33 are treated with the metal and amine salt. The propylene is especially propylene-modulated propylene, which is a polyvalent cation salt such as surface acid magnesium after the 2-20'2_22 & 2_1 C polymerization reaction. Water-based polyvalent cation salt of acrylic water-soluble / Ling (or an aqueous solution containing 1 Wang early body), is not surface treated after polymerization. More I, (Please read the precautions on the back before filling this page ) One pack i-order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

312852 32 520978 A7 B7 Printed by the parent department of the Huibei Industry Bureau employee consumer cooperative. V. Description of the invention (33 Table 2-2 Characteristic samples of fake fishing lures Metal • Amine salt Transparent water swellability Example 2-1 No surface Processing 5% chlorine transparent 35 times Example 246 6% Ferrous sulfate opaque 1 to 2 times Example 247 10% barium chloride transparent (discoloration) 1 times Example 2-20 Metal ion treatment omitted (Mg salt polymerization method) Opaque 1 times Example 2-22 Omit of metal ion treatment (CaMg: Na salt polymerization method) (40:40:20) 2 times after opaque 72 hours Example 2-23 17% ethylenediamine dihydrochloride 1 times transparent Example 2-24 3% 1,4-butanediamine dihydrochloride is twice as transparent Example 2-25 5% Ludian dihydrochloride is twice as opaque Example 2-26 4% 3-dimethylamine propylamine disalt Acid salt translucent 2 times Example 2-27 7% 1,3-propanediamine dihydrochloride 1 times transparent Example 2-28 7% 2,3-Diaminopyridine trihydrochloride 1 times transparent Example 2_29 8% N ^ N-dimethylethylenediamine dihydrochloride is 4 times transparent Example 2-30 9% 1- (2-aminoethyl > quinidine dihydrochloride is 4 times transparent Example 2_31 7% pyrimidine disodium Salt transparent 1 times Example 2-32 Omit of metal ion treatment (Na: Mg: Chitosan salt polymerization method) (85: 10: 5) Transparent 1 times Example 2-33 20% ^ [Acid transparent 2 times wood Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------- i -------- ^ --------- ^ (Please read the note on the back * before filling this page) 312852 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 520978 V. Description of the invention (34) In Table 2_2, after polymerization, the magnesium salt (Example 2 -1, 2-33), metal salts such as sulfur ferrous (Example 2-16) and barium chloride (Example 2-17), and those treated with amine salts of Examples 2-23 to 2-31 The blisters are low in carton, which is a good one. In addition, according to Examples 2-20, 2-22, and 2-32, it is known that the fake fishing bait prepared by polymerizing polyvalent cation salt of acrylic acid, even if the surface is omitted. Treatment, the blistering property is low, which is still good. The so-called "low swellability" means that it has good durability in water and is more likely to become a commercial fake fish. In addition, from Example 2-1, 2-16, 2-17 '2_33, compared with Examples 3 to 2_31 In contrast, if polyvalent metal cations are used for the surface treatment, opaque fake fishing baits other than iron ions are obtained, and if polyvalent amine cations are used, pseudo transparent baits from translucent to transparent can be obtained. From the comparison between Example 2-1 and Example 2_33, it can be seen that even if the same polyvalent metal cation is used, a transparent or opaque one can be obtained. Example 2-34 For acrylic resins, spheroidal molds were carved according to the shape of insects. To 150 g of a 25% sodium acrylate aqueous solution, 3 g of a 03% edible cyan 1 aqueous solution and 0.3% yellow pigment were added. After adding 4.5g of 0.3% edible yellow No. 4 aqueous solution, 15g of polymerization initiator v_50 and KAYARAD PEG400DA 0.33 were added, and the obtained mixture was deoxygenated in nitrogen and then poured. After the mold was covered with a glass plate, a polymerization reaction was performed at 60 ° C for 20 hours in a nitrogen atmosphere. After the polymerization reaction is completed, the green colored parent-linked polyacrylic sodium hydrous formed article is taken out from the forming mold, and a water formed article is obtained. One of them was immersed in a 5% magnesium chloride aqueous solution for 6 hours, and the other was used in accordance with the national standard of this paper.

312852 (Please read the phonetic on the back? Matters before filling out this page) One binding. 520978 A7 B7 V. Description of the invention (35) The same solution was immersed for 20 hours, and two kinds of leave of the present invention were prepared. Fishing lures (cross-linked polyacrylate insects). Test Example 3 (Test of water swelling and long-term collapse in water) Two types of fake fishing lures made of the cross-linked polyacrylate obtained in Example 2-33 were tested for transparency and water immersion. Swellability, residual after 4 months of immersion. • Tests and evaluations of transparency and swellability after immersion in water for 24 days were performed as described in Test Example 2 above. Residual property after 4 months of submergence is based on the residual amount after immersing a hydroformed body (about 3 immersed in about 10 liters of water and left at room temperature for 4 months) divided by the amount before being immersed in water. The value of the weight of the hydroformed body was evaluated. The results are shown in Table 2-3. Observing the residual property after 4 months of immersion, the cross-linked polyacrylate fake fish cast has a shorter surface treatment time (6 Hours) Those who 'almost collapsed and dissolved in 4 months and disappeared. On the other hand, when the surface treatment was performed, the residual amount after immersion for 4 months was about 6 to less than the original time. About 70% 'shows that any person who disappeared due to collapse or dissolution disappeared. Table 2-3 ------------- ^ -------- Order · ---- ---- Line (please read the precautions on the back before filling this page) The Ministry of Economic Affairs, Jibei M Property Bureau staff sells the samples printed by the cooperative, dipping for 6 hours, immersing for 20 hours, the characteristic metal of fake fish casting, and the amine salt is transparent Blistering opaque π times opaque 5 times extant almost no 0.66 times [industrial profitability]

297 mm) 312852 520978 A7 —_ B7 V. Description of the invention (36) The fake fishing lure of the present invention can arbitrarily control the swelling speed or the collapse speed, and has the same flexibility and softness as vinyl chloride plastic insects. Regardless of the fishing season is the summer season, there are many tourists and anglers. In a very lively situation, the fish has good bait (identifiability), and is tasteless, odorless, and can be colored arbitrarily. In addition, since it is produced by polymerizing an acrylic aqueous solution monomer, it does not require large equipment and has good moldability. In addition, the main materials of the fake fishing lure of the present invention are non-toxic acrylic polymers and water, and because they do not contain the solvent used in the conventional plastic insects, even when fish and birds eat them by mistake, they can be greatly reduced. Risk of death, and ② Do not cause the problem of solvent stench. Furthermore, since the fake fishing lure of the present invention does not contain plasticizers such as phthalate esters or chlorine-based organic compounds used by conventional plastic insects, there is no environmental hormone problem, and no harmful substances such as dioxin are generated during combustion. . In addition, the fake bait of the present invention will disappear if it is left in the water for a long time, so it will not remain in the natural world. It is a high-quality fake fish feed for fishing and fishery with superior environmental protection. (Please read the precautions on the back before filling out this page) Packing -------- II ---------. This paper ruler is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 〒 国 ϋ Tsukuba (:) NS) A4 gauge (210 X 297 36 312352

Claims (1)

520978 Patent Application No. 90118398 Amendment to the Scope of Patent Application (August 29, 91) 1. A fake fishing lure made of acrylic polymer. 2. If the provision of item i in the scope of patent application is polyacrylic acid or its salts. ^ 〃 中 propylene_series polymer 3. = Please patent No.! Item 2 or item 2 is a water-soluble polymer. 4. If the scope of the patent application is J or 2nd polymer. , 〃, and bait are water-insoluble 5. ::: Fake Fish Pass of Item 4 of the Patent Scope, wherein the water-insoluble polymer has a crosslinked structure. 6. The false fish feed according to item 5 of the application, wherein the water-insoluble polymer is composed of a salt of polyacrylic acid anion and a polyvalent cation, or a salt of an ion and a salt of a monovalent cation. 7. The fake bait according to item 4 of the patent application, wherein the salt of polyacrylic acid anion and polyvalent cation is a polyvalent metal salt of polyacrylic acid. Printed by the Staff Welfare Committee of the Central Bureau of Standards of the Ministry of Economic Affairs. 8. If the fake fishing bait of item 6 of the patent application is applied, the salt of polyacrylic acid anion and polyvalent cation is the polyvalent aluminum salt of polyacrylic acid. 9 · If the scope of patent application is the first! The fake fishing lure of the item is a hydroformed body. 10. The false fishing lure as stated in the first item of the patent scope refers to 50% to 90% by weight of water relative to the entire weight of the fishing lure. 11. If the fake fishing lure of the first scope of the patent application is a coloring body. 12 · If the scope of patent application is the first! Fake fishing lures of the item, those with pigment on the surface. 13 · If the scope of patent application is the first! The fake bait of this item is implemented with polyvalent cations. The paper size is applicable to the Chinese national standard $ CCNS) A4 size. 1 312852 H3 Surface treatment. Class 14: A method for manufacturing TT bait, which is characterized in that an aqueous solution of acrylic acid or its sleeping matter is charged into a mold for molding and polymerized. t-A method for manufacturing a fake fish bream according to item 14 of US Lee Fan Garden, which is polymerized in the presence of a crosslinking agent. 16. If the method of manufacturing a fake fishing lure according to the scope of the patent application, item 14 or item 15 is based on the content of acrylic acid or its salt in the aqueous solution of 10 to 50% by weight, of which 17. if applied The manufacturing method of the fake fishing lure of the 16th aspect of the patent is a static polymerization. It is based on the method for manufacturing fake fishing lures such as No. 14 in the scope of patent application, and the surface treatment with polyvalent cations after the combination. 19. The method for manufacturing a fake fishing lure according to item 18 of the application, wherein the polyvalent cation is a polyvalent metal ion or a polyvalent amine cation. 20 · —A kind of fake fishing lure, which is composed of an aqueous gel of acrylic polymer. Printed by the Staff Welfare Committee of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is sized to the Chinese National Standard (CNS) A4 (210 x 297 mm) 2 312852