518453 A7 B7 五、發明説明（丨） (請先閱讀背面之注意事項再填寫本頁) 本發明係有關一種爲使電子照片之靜電潛像顯像的顯像 用調色劑（以下稱調色劑組成物），即適用於在高速下進行 被印刷體之閃光固定的雷射印表機或LED印表機之靜電 潛像顯像用調色劑組成物。 電子照相法係由使利用光導電性物質的感光體上賦予一 樣的靜電荷之帶電工程，照射光以形成靜電潛像之曝光工 程，在潛像部份使調色劑附著靜電之潛像工程，在調色劑 像載體上複印之複印工程，使該調色劑像以壓力、熱、閃 光等固定於調色劑像載體之固定工程，除去殘留於感光體 上之未複印調色劑的淸潔工程及除去感光體上之靜電荷且 回復至初期狀態的除電工程所成，反覆操作此等之工程以 得畫像。 經濟部智慧財產局員工消費合作社印製 電子照片印表機之固定方法之一的壓力固定方式，雖有 可即時移動，不需使用加熱器做爲熱源而可節省電力，且 固定部不會有發火的危險等優點，惟有使畫像之固定性惡 化，畫像之光澤不佳的低級品等缺點，故一般藉由加熱固 定方式較有利。該加熱固定方式有藉由熱輥固定予以接觸 加熱固定方式，與藉由閃光固定及通過電熱加熱器之加熱 氣氛中藉由烤箱固定之非接觸加熱固定方式，係爲已知。 本發明係有關非接觸加熱固定方式之典型例的藉由閃光 以固定者，閃光固定方式有在調色劑之可視像上以微秒以 下之短時間照射氙氣燈或鹵素燈等發光光譜，藉由該輻射 熱以使調色劑軟化熔融，固定於調色劑載體的方法（日 -3 - 本紙張尺度適用中國國家標準（CpS ) A4規格（210X297公釐) ' 518453 A7 B7 五、發明説明（2：) 本特開平7- 1 0 7 80 5號公報），具有下述之優點。 (請先閱讀背面之注意事項再填寫本頁) (1 )由於爲非接觸固定，不會使顯像時之畫像解析度惡 化。 (2) 不需電源投入後之等待時間，可儘速開始。 (3) 因系統中斷，在固定器內即使記錄紙等阻塞時仍不 會有發火情形。 (4) 不需視調色劑載體種類（記錄紙之材質、摺紙、厚紙 等）而定皆可呈現良好的固定性。 (5) 由於僅使黑色部份的調色劑加熱，故記錄紙等之熱 收縮小，可爲用紙搬送優異的高速印字。 然而，閃光固定方式由於爲非接觸加熱固定方式，其周 圍之能源逸散比例高，且由於爲間歇性能源照射，與熱輥 固定比較，熱效率不佳，即爲消耗電力大的固定方式。另 外，閃光固定方式係在極短的時間內藉由激烈的高能源之 閃光照射，調色劑組成物之表面溫度在瞬間可達數百度之 高溫，且因部份調色劑組成物之添加劑分解、氣化、而放 出惡臭或產生有害的氣體等分解生成物的問題產生。 經濟部智慧財產局員工消費合作社印製 閃光固定方式之印表機，一般採用爲了除去閃光固定時 之分解生成物，在閃光固定部中吸引此等之分解生成物， 且通過活性碳等之過濾器吸附捕捉有害氣體的方法。然 而，由於使用過濾器及過濾器之交換壽命短等，仍是提高 使用成本之問題產生。 本發明係爲解決上述之問題點所發明者，在採用閃光 -4 - 本紙張尺度適用中國國家標準（CpS ) A4規格（210X297公釐） 518453 A7 B7 五、發明説明（>3 ) (請先閱讀背面之注意事項再填寫本頁) 固定方式之印表機中，壓抑分解生成物之產生而不使用過 濾器，或爲解決因過濾器之交換壽命短等提高使用成本的 問題，提供的靜電潛像顯像用調色劑組成物。 本發明係提供一種調色劑組成物之固定方法，其特徵爲 在使至少由粘著樹脂，著色劑及荷電控制劑所成的調色劑 組成物予以閃光固定時，使用選自4級銨鹽化合物、三 苯基甲烷系化合物、或在100 °C〜250 °C之溫度下且在 0.02MPa以下之真空度中予以真空力口熱處理的苯胺黑系化 合物之荷電控制劑。 另外，本發明係有關一種使用閃光固定之靜電潛像顯像 用調色劑組成物，其特徵爲在至少由粘著樹脂、著色劑及 荷電控制劑所成的調色劑組成物中，藉由在3 3 (TC下加熱 90秒，產生苯的產生濃度爲60 μ g/g以下。 圖式之簡單說明 第1圖係表示本發明之畫像形成裝置之簡略縱截面圖。 第2圖係表示本發明之固定裝置的簡略截面圖。 -rf.. 第3圖係表示藉由第2圖之實施狀態的畫像固定裝 置，在放射能源之記錄介質上的分佈圖。 經濟部智慧財產局員工消費合作社印製 第4圖係表示本發明之固定裝置的一實施狀態之簡略 截面圖。 第5圖係表示本發明之畫像固定裝置的一實施例之簡 略縱截面圖。 第6圖係表示自記錄介質側所見本發明之實施例圖。 爲實施本發明之最佳形態 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 B7 五、發明説明（夺） 本發明之調色劑組成物係藉由在3 3 0 °C下加熱處理9 0 秒，產生濃度爲60//g/g以下，較佳者爲40//g/g以下。 若苯之產生濃度大於60//g/g時，必須有脫煙過濾器之強 化等措施。 此處，決定過濾器之必要性，決定壽命的分解生成物， 惟就法規而言會有做爲分解生成物之苯的產生問題。特定 該苯之產生量的方法係採取移動，印表機，且採取自此所 產生的排氣氣體，並予以定量的方法，惟有試樣問題，影 響調色劑以外之要因等的問題，做爲調色劑之較佳特性無 法得到。本發明人等繼續檢討有關實用上再現性的條件， 發現藉由在3 3 0°C下加熱90秒產生的苯量可成爲判斷調色 劑好壞的標準，且發現使用該產生量爲60 # g/g以下之調 色劑時，過濾器之壽命會大幅地增長。 此處，變化與閃光能源相關之閃光電壓，通常所使用的 185 0V之電壓會有苯產生，惟降低至175 0V時，苯之產生 量可大幅地減少。推定閃光固定時之調色劑於瞬間更升至 高溫，惟使用知道分解溫度之指標物質，間接地推定其電 壓條件時，可知對應於3 3 (TC壓花之時間的分解條件。換 言之，在3 3 0 t下使指標物質充份分解的90秒條件下評估 調色劑之苯產生量時，發現其評估結果與實際自印表機產 生的苯量之間具良好的關係。 苯之產生量的測定條件係毫無疑問地爲測定在3 3 0 °C下 90秒間所產生的苯量方法，惟例如使1 〇mg試樣裝入內容 量爲2 0 m 1的玻璃器中，氮氣淸除後予以密閉，在 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂_ 經濟部智慧財產局員工消費合作社印製 518453 A7 B7 五、發明説明（t ) (請先閲讀背面之注意事項再填寫本頁) 3 3 0 °C電爐中加熱90秒。使0.5ml玻璃容器內之氣相注入 氣相質譜儀中，以調查苯之產生量。此處所使用的氣相質 譜儀之測定條件只要爲可使苯之再現性佳，定量的方法即 可，例如可使用下述之條件予以測定。 氣相質譜議條件： ：SPB-1 S 0.32mm X 60mm 載體氣體 ••He 柱溫度 :5 0 〇C 2 8 0 〇C (1 〇 t： / 分） 檢測器 ：FID 注入量 :0.5ml 爲達成該產生量的方法係考慮種種的因素，惟本發明人 等經過再三深入硏究有關苯之產生原因的結果，發現該苯 之產生量通常係一般使用的苯胺黑系荷電控制劑受到閃光 固定的光能源分解而產生苯。因此，使用下述之方法較佳。 (1) 除去苯胺黑系荷電控制劑中之苯產生物質 經濟部智慧財產局員工消費合作社印製 檢討苯胺黑系荷電控制劑之苯方產生機構結果，發現因 主成份分解而產生苯，同時藉由荷電控制劑所含之雜質而 產生苯。因此，除去雜質的方法例如有藉由真空加熱處理 來除去雜質的方法，及以醇類等之有機溶劑來洗滌的方 法，惟就工程之容易而言以真空加熱處理的方法較佳。 (2) 使用不產生苯的荷電控制劑 該物以使用4級銨鹽化合物、三苯基甲烷系荷電控制 劑等較佳。 -7 - 惟使用4級銨鹽化合物時，不易賦予調色劑良好的帶 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 ___B7_ 五、發明説明（6 ) (請先閱讀背面之注意事項再填寫本頁) 電性，而且使用三苯基系荷電控制劑時，在高溫下固定時， 荷電控制劑會分解而致使印字周邊受到污染，故以除去苯 胺黑系荷電控制劑之苯產生物質更佳。 此處，荷電控制劑使用4級銨鹽化合物時，較佳者有4 級銨鹽化合物之陰離子爲鉬或鎢原子之無機陰離子。無機 陰離子之具體例例如有鉬酸、鎢酸、磷鉬酸、矽鉬酸、磷 鎢酸、矽鎢酸、磷鎢、鉬酸、矽鎢、鉬酸、磷鎢、鉬酸、 鉻、鉬酸等。 該4級銨鹽化合物之具體例如保土谷化學公司製TP-302 ， 415 等。 4級銨鹽化合物之添加量對1 00重量份調色劑組成物而 言以0 · 1〜5重量份較佳。若小於0.1重量份時無法使調 色劑具充份的帶電性，而若大於5重量份時由於荷電控 制劑與其他的調色劑成份相比極爲高價，致使成本提高。 另外，荷電控制劑使用三苯基甲烷系荷電控制劑時，三 苯基甲烷系荷電控制劑例如使用C.I. Solvent Blue6 6、124、 C.I.PigmentBlue61，56，19，18 等，以使用 C.I.Slovent 經濟部智慧財產局員工消費合作社印製518453 A7 B7 V. Description of the invention (丨) (Please read the precautions on the back before filling out this page) The present invention relates to a developing toner (hereinafter referred to as toning) for developing electrostatic latent images of electronic photos. Agent composition), that is, a toner composition for electrostatic latent image development of a laser printer or an LED printer which is used for flash fixing of a printed body at a high speed. The electrophotographic method consists of a charging process that imparts the same electrostatic charge to a photoreceptor using a photoconductive substance, an exposure process that irradiates light to form an electrostatic latent image, and a latent image process in which toner is attached to the electrostatic part in the latent image part. , A copying process of making a copy on a toner image carrier to fix the toner image to the toner image carrier by pressure, heat, flash, etc., to remove the uncopied toner remaining on the photoreceptor The cleaning process and the static elimination process to remove the electrostatic charge on the photoreceptor and return to the initial state are repeated operations to obtain a portrait. The pressure fixing method, which is one of the fixing methods for the printing of electronic photo printers by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, although it can be moved instantly, it can save electricity without using a heater as a heat source, and the fixed section will not have The advantages of danger of fire, etc., have the disadvantages of lowering the fixation of the portrait and low-grade products with poor gloss, so it is generally advantageous to fix it by heating. The heating and fixing methods include contact heating and fixing methods using a heat roller, and non-contact heating and fixing methods using an oven in a heating atmosphere by flash fixing and electric heating. The present invention relates to a typical example of a non-contact heating fixing method, which is fixed by a flash. The flash fixing method illuminates a light emission spectrum such as a xenon lamp or a halogen lamp on a visible image of a toner for a short time of less than microseconds. Method for softening and melting the toner by the radiant heat and fixing it to the toner carrier (Japan-3-This paper size applies the Chinese National Standard (CpS) A4 specification (210X297mm) '518453 A7 B7 V. Description of the invention (2 :) Japanese Unexamined Patent Publication No. 7-1 0 7 80 5) has the following advantages. (Please read the precautions on the back before filling in this page) (1) Since it is non-contact fixing, it will not deteriorate the image resolution during development. (2) There is no need for waiting time after the power is turned on, and it can be started as soon as possible. (3) Due to the system interruption, there is no fire even if the recording paper is blocked in the holder. (4) It does not need to depend on the type of toner carrier (material of recording paper, origami, thick paper, etc.), it can show good fixability. (5) Since only the black portion of the toner is heated, the thermal contraction of the recording paper and the like is small, and high-speed printing can be performed for paper conveyance. However, since the flash fixing method is a non-contact heating fixing method, its surrounding energy dissipation ratio is high, and because it is intermittent energy irradiation, compared with the heat roller fixing, the thermal efficiency is not good, which is a fixing method with large power consumption. In addition, the flash fixing method is irradiated with intense high-energy flashes in a very short time. The surface temperature of the toner composition can reach a high temperature of hundreds of degrees in an instant, and due to the additives of some toner compositions Decomposition, gasification, and problems of decomposition products such as foul odor or harmful gas generation. The printers of the flashlight fixing method printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs generally use the flashlight fixing section to remove the decomposition products during the flashlight fixing, and filter them through activated carbon. A method for adsorbing and trapping harmful gas. However, the use of the filter and the short exchange life of the filter still raises the problem of increasing the use cost. The present invention was invented by the inventor to solve the above-mentioned problems. When using Flash-4, this paper size applies the Chinese National Standard (CpS) A4 specification (210X297 mm) 518453 A7 B7. 5. Description of the invention (> 3) (Please (Please read the precautions on the back before filling this page.) In fixed printers, suppress the generation of decomposition products without using a filter, or provide solutions to increase the cost of use due to the short exchange life of the filter. A toner composition for developing an electrostatic latent image. The invention provides a method for fixing a toner composition, which is characterized in that when a toner composition made of at least an adhesive resin, a colorant, and a charge control agent is flash-fixed, a grade 4 ammonium is used. A charge control agent for a salt compound, a triphenylmethane-based compound, or an aniline black-based compound that is subjected to vacuum heat treatment at a temperature of 100 ° C to 250 ° C and a vacuum of 0.02 MPa or less. In addition, the present invention relates to a toner composition for electrostatic latent image development using flash fixing, which is characterized in that a toner composition made of at least an adhesive resin, a colorant, and a charge control agent is used. By heating at 3 3 ° C for 90 seconds, the production concentration of benzene is 60 μ g / g or less. Brief Description of the Drawings FIG. 1 is a schematic longitudinal sectional view showing the image forming apparatus of the present invention. FIG. 2 is a -Rf .. Fig. 3 shows the distribution of the image fixing device in the state of implementation in Fig. 2 on the recording medium of radioactive energy. Employees, Bureau of Intellectual Property, Ministry of Economic Affairs Fig. 4 printed by a consumer cooperative is a schematic cross-sectional view showing an implementation state of the fixing device of the present invention. Fig. 5 is a schematic vertical cross-sectional view showing an embodiment of the image fixing device of the present invention. The embodiment of the present invention as seen on the recording medium side. For the best form of implementing the present invention, the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 A7 B7 5. Description of the invention (captured) Ming's toner composition is produced by heat treatment at 330 ° C for 90 seconds to produce a concentration of 60 // g / g or less, preferably 40 // g / g or less. If it is greater than 60 // g / g, measures such as strengthening of the de-smoke filter must be provided. Here, the necessity of the filter is determined, and the decomposition product of the life is determined. The problem of benzene generation. The method of specifying the amount of benzene is to move, print the printer, and use the exhaust gas generated from it to quantify it. The only problem is the sample, which affects factors other than toner. It is impossible to obtain the best characteristics of the toner as the other problems. The present inventors continued to review the conditions for practical reproducibility, and found that the amount of benzene generated by heating at 330 ° C for 90 seconds can be judged. The standard of toner quality is good, and it is found that the life of the filter will greatly increase when using the toner whose production amount is 60 # g / g or less. Here, the flash voltage related to the flash energy is usually changed. The used voltage of 185 0V will generate benzene, but when it is reduced to 175 0V, The amount of production can be greatly reduced. It is estimated that the toner when the flash is fixed will rise to a high temperature in an instant, but using an index substance that knows the decomposition temperature and indirectly estimating its voltage condition, it can be seen that it corresponds to 3 3 (TC embossed Decomposition conditions of time. In other words, when the benzene production amount of the toner was evaluated under the condition of 90 seconds that the index substance was fully decomposed at 3 3 0 t, it was found that the evaluation result was between the actual benzene production amount from the printer There is a good relationship. The measurement conditions of the amount of benzene produced are undoubtedly the method for measuring the amount of benzene produced at 90 ° C for 90 seconds, but for example, the content of a 10 mg sample is 20 The glassware of m 1 is sealed after being purged with nitrogen, and the Chinese paper standard (CNS) A4 (210X297 mm) is applied to this paper size (please read the precautions on the back before filling this page) Order_Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau 518453 A7 B7 V. Description of Invention (t) (Please read the precautions on the back before filling this page) 3 3 0 ° C in an electric furnace for 90 seconds. The gas phase in a 0.5 ml glass container was injected into a gas mass spectrometer to investigate the amount of benzene produced. As long as the measurement conditions of the gas mass spectrometer used herein are quantitative as long as the reproducibility of benzene is good, a quantitative method is acceptable. For example, the following conditions can be used for measurement. Gas phase mass spectrometry conditions:: SPB-1 S 0.32mm X 60mm carrier gas •• He Column temperature: 50 〇C 2 8 0 〇C (1 〇t: / min) Detector: FID injection volume: 0.5ml is The method for achieving this amount of production takes various factors into consideration. However, the inventors have repeatedly studied the causes of the occurrence of benzene. They found that the amount of benzene produced is usually a commonly used aniline black charge control agent that is fixed by flashing light. The decomposition of light energy produces benzene. Therefore, it is preferable to use the following method. (1) Remove the benzene-generating substance in the aniline black-based charge control agent Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed and reviewed the results of the benzene production mechanism of the aniline-black charge control agent, and found that benzene was generated due to the decomposition of the main component, and Benzene is generated from impurities contained in the charge control agent. Therefore, the method for removing impurities includes, for example, a method for removing impurities by vacuum heating treatment, and a method for washing with an organic solvent such as alcohol, but a method of vacuum heating treatment is preferable in terms of ease of engineering. (2) Use of a charge control agent that does not generate benzene This substance is preferably a fourth-order ammonium salt compound, a triphenylmethane-based charge control agent, or the like. -7-However, when using a grade 4 ammonium salt compound, it is not easy to give the toner a good tape. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 A7 ___B7_ 5. Description of the invention (6) (please first Read the precautions on the back and fill in this page again.) When using triphenyl-based charge control agents, when fixed at high temperature, the charge-controlling agents will decompose and contaminate the surroundings of the printing. Therefore, aniline black-based charge control is removed. The benzene generating substance of the agent is more preferable. Here, when a fourth-order ammonium salt compound is used as the charge control agent, an inorganic anion in which the anion of the fourth-order ammonium salt compound is a molybdenum or tungsten atom is preferred. Specific examples of the inorganic anion include molybdic acid, tungstic acid, phosphomolybdic acid, silicomolybdic acid, phosphotungstic acid, silicotungstic acid, phosphotungstic acid, molybdic acid, silicotungstic acid, molybdic acid, phosphorous tungsten, molybdic acid, chromium, and molybdenum Acid etc. Specific examples of the fourth-order ammonium salt compound include TP-302, 415, etc. manufactured by Hodogaya Chemical Co., Ltd. The addition amount of the fourth-order ammonium salt compound is preferably from 0.1 to 5 parts by weight based on 100 parts by weight of the toner composition. If it is less than 0.1 parts by weight, the toner cannot be sufficiently charged, and if it is more than 5 parts by weight, the charge control agent is extremely expensive compared with other toner components, resulting in an increase in cost. In addition, when a triphenylmethane-based charge control agent is used as the charge control agent, for example, CI Solvent Blue6 6, 124, CIPigmentBlue 61, 56, 19, 18, etc. are used for the triphenylmethane-based charge control agent to use the wisdom of CISlovent Printed by the Property Agency Staff Consumer Cooperative
Blue 124較佳。該三苯基甲烷系荷電控制劑之具體例如黑 其史頓（譯音）公司製之"Copy blue”PR，”Brilliant Blue Base ”SM，BASF，日本公司製之"BASF Alkali Blue” N B D 6 1 5 6 D LD 等。 三苯基甲烷系荷電控制劑之添加量對1 00重量份調色劑 組成物而言以0.1〜5重量份較佳。若小於〇 · 1重量份時 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 B7 五、發明説明（7 ) (請先閲讀背面之注意事項再填寫本頁) 無法賦予調色劑具充份的帶電性，而若大於5重量份時 由於荷電控制劑與其他的調色劑成分相比極其高價，致使 成本提高。 此外，使苯胺黑系荷電控制劑真空加熱處理的方法中， 以在100°C〜250°C之溫度下且在〇.〇2MPa以下之真空度下 真空加熱處理較佳，以在100°C〜25 0X：下且在0.00 5 MPa 以下之真空度下真空加熱處理較佳，更佳者在130 °C〜220 °C之溫度且在0.003MPa以下之真空度下真空加熱處理更佳。 以該處理來控制閃光固定時苯之產生的構想無法實現。 原因係爲荷電控制劑（如苯胺黑系化合物）本身熱分解而產 生苯時，以真空加熱處理等無法除去苯之產生來源。本發 明著重於苯之產生源不是荷電控制劑本身而有最初的構想。 若加熱溫度小於1 00 °C時，無法壓抑分解生成物之生成， 而無法延長過濾器之壽命，而若大於250 °C時荷電控制劑 本身開始分解，失去做爲荷電控制劑之帶電賦予功能。若 真空度大於0.02MPa時，爲達成效果必須在長時間下予以 真空加熱處理，欠缺實用性。而且，苯胺黑系荷電控制劑 之含量對全部調色劑組成物而言以0 · 1〜5重量份較佳， 更佳者爲0.5〜2重量％。 經濟部智慧財產局員工消費合作社印製 就加熱時間而言，較佳爲1小時至24小時之間。若低 於1小時，則無法充分呈現抑制因加熱所產生之分解生成 物之效果。另外，最適當之加熱時間係隨其加熱裝置、應 予加熱之荷電控制劑量而異，惟就經濟性等方面而言，超 過24小時爲不佳者。 另外，以有機溶劑來洗淨處理苯胺黑系荷電控制劑的方 法中，有機溶劑例如有甲醇、乙醇、丙醇、異丙醇、丁 醇等之醇類、丙酮、甲基乙酮、甲基異丁酮、己酮等 -9 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~ 518453 A7 B7 五、發明説明（》） 之酮類，甲苯、二甲苯等芳香族，惟以醇類洗淨處理較佳。 (請先閱讀背面之注意事項再填寫本頁) 洗淨處理之具體方法，有在常溫下對苯胺黑系荷電控制 劑而言來回操作以數倍量之有機溶劑予以洗淨的方法。 本發明之調色劑組成物係至少由粘著樹脂，著色劑及荷 電控制劑所成，於下述中說明此等之組成物。 本發明調色劑組成物所含的粘著樹脂可使用公知的粘著 樹脂，例如聚苯乙烯均聚物、苯乙烯-異丁烯共聚物、苯 乙烯-丁二烯共聚物、丙烯±、-丁二烯-苯乙烯共聚物、苯乙 烯-丙烯共聚物、苯乙烯-甲基丙烯酸酯共聚物、苯乙烯-甲 基丙烯酸正丁酯共聚物、苯乙烯·甲基丙烯酸甘油酯共聚 物等之苯乙烯共聚物，聚甲基丙烯酸甲酯、聚甲基丙烯酸 乙酯、聚甲基丙烯酸正丁酯、聚甲基丙烯酸甘油酯等之丙 烯系均聚物或共聚物，聚對苯甲酸乙烯酯、富馬酸/醚化 二苯系聚酯、多元醇及/或多元羧酸所交聯的聚酯等之聚 酯系樹脂、環氧系樹脂等。其中，爲降低因閃光固定時之 熱分解所產生的臭氣，以聚酯樹脂爲宜。 經濟部智慧財產局員工消費合作社印製Blue 124 is better. Specific examples of the triphenylmethane-based charge control agent include "Copy blue" PR, "Brilliant Blue Base" SM, BASF, "BASF Alkali Blue" NBD 6 manufactured by Japan Corporation 1 5 6 D LD, etc. The addition amount of the triphenylmethane-based charge control agent is preferably 0.1 to 5 parts by weight based on 100 parts by weight of the toner composition. If it is less than 0.1 parts by weight, the size of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 A7 B7 V. Description of the invention (7) (Please read the precautions on the back before filling this page) Cannot grant The toner has sufficient chargeability, and if it is more than 5 parts by weight, the charge control agent is extremely expensive compared to other toner components, resulting in increased cost. In addition, in the method for vacuum-heating the aniline black-based charge control agent, the vacuum-heating treatment is preferably performed at a temperature of 100 ° C to 250 ° C and a vacuum degree of not more than 0.02 MPa, and at 100 ° C ~ 25 0X: Vacuum heat treatment is preferably performed under a vacuum degree of 0.00 5 MPa or less, and more preferably, vacuum heat treatment is performed at a temperature of 130 ° C to 220 ° C and a vacuum degree of 0.003 MPa or less. The idea of using this process to control the generation of benzene when the flash is fixed cannot be realized. The reason is that when benzene is generated by thermal decomposition of a charge control agent (such as nigrosine compounds), the source of benzene cannot be removed by vacuum heating treatment. The present invention focuses on the origin of benzene, not the charge control agent itself, but the original concept. If the heating temperature is less than 100 ° C, the generation of decomposition products cannot be suppressed, and the life of the filter cannot be extended. If it is higher than 250 ° C, the charge control agent itself begins to decompose, and it loses the function of providing charge as a charge control agent . If the degree of vacuum is greater than 0.02 MPa, in order to achieve the effect, vacuum heating treatment must be performed for a long time, which is not practical. The content of the nigrosine-based charge control agent is preferably from 0.1 to 5 parts by weight, and more preferably from 0.5 to 2% by weight, based on the entire toner composition. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In terms of heating time, preferably between 1 hour and 24 hours. If it is less than 1 hour, the effect of suppressing decomposition products due to heating cannot be sufficiently exhibited. In addition, the most appropriate heating time varies with its heating device and the charge control dose to be heated, but in terms of economics and other aspects, it is not good for more than 24 hours. In addition, in the method for cleaning and treating the nigrosine-based charge control agent with an organic solvent, the organic solvents include, for example, alcohols such as methanol, ethanol, propanol, isopropanol, and butanol, acetone, methyl ethyl ketone, and methyl alcohol. Isobutyl ketone, hexanone, etc.-9-This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) ~ 518453 A7 B7 V. Description of the invention (") Ketones, toluene, xylene and other aromatics, However, it is better to wash with alcohol. (Please read the precautions on the back before filling this page.) The specific method of cleaning treatment is to clean the nigrosine-based charge control agent at room temperature with several times the amount of organic solvent. The toner composition of the present invention is composed of at least an adhesive resin, a colorant, and a charge control agent. These compositions are described below. The adhesive resin contained in the toner composition of the present invention may be a known adhesive resin such as a polystyrene homopolymer, a styrene-isobutylene copolymer, a styrene-butadiene copolymer, propylene ±, butadiene Diene-styrene copolymer, styrene-propylene copolymer, styrene-methacrylate copolymer, styrene-n-butyl methacrylate copolymer, styrene-glyceryl methacrylate copolymer, etc. Ethylene copolymers, propylene homopolymers or copolymers of polymethyl methacrylate, polyethyl methacrylate, poly-n-butyl methacrylate, polyglyceryl methacrylate, etc., polyethylene terephthalate, Polyester resins, epoxy resins, and the like, such as fumaric acid / etherified diphenyl-based polyesters, polyesters cross-linked with polyols and / or polycarboxylic acids, and the like. Among them, polyester resin is preferred to reduce the odor generated by thermal decomposition during flash fixing. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
沒有特別的限制，惟以由聚酯樹脂之酸成份中80莫耳 %以上爲由苯甲酸系二羧酸所成的酸成份，與醇類成份中 莫耳％以上爲由雙酚A氧化亞烷基加成物所成的醇成 份而得的聚酯樹脂較佳。另外，考慮固定性時，軟化點爲 8 〇〜1 3 0 °C，玻璃轉移點（τ g )爲5 5〜7 (TC，藉由流動測 試之熔融粘度爲1 0 0 0 0厘泊時之到達溫度爲9 0〜1 3 5 °C -10- 參紙張尺度適用中關家標準（) A4規格（21GX297公着） 518453 A7 _ B7 五、發明説明（？） 較佳。聚酯樹脂之分子量分佈，數平均分子量爲2500〜 45 00，重量平均分子量爲7000〜1 3 0000。 (請先閲讀背面之注意事項再填寫本頁) 本發明之調色劑組成物所含的著色劑可使用公知的著色 劑，例如有爐黑、乙炔炭黑、槽法炭黑等炭黑外，可使用 強磁性體微粒子、例如磁鐵礦微粒子粉末。另外，黑色著 色劑可混合強磁性體微粒子與炭黑使用。此等之著色劑中 炭黑對粘著樹脂中之分散，就調色劑之荷電安定性而言極 爲重要，視其所需可倂用分散劑。而且，炭黑之含量對100 重量份調色劑組成物而言以1〜1 0重量份較佳。 若小於1重量份時，粘接樹脂之隱蔽力不足而無法得 到充份的畫像濃度。另外，若大於1 〇重量％時就增大所 形成的畫像之隱蔽力，提高畫像濃度而言較佳，惟就反面 而言，調色劑粒子中所形成的炭黑的鏈結構而使調色劑粒 子過度導電，損害其絕緣性，減少調色劑之帶電性，結果 降低畫像濃度而使得白色部份受到污染或調色劑飛散情形 增力口。 經濟部智慧財產局員工消費合作社印製 本發明之調色劑組成物中的流動性提高劑，視其所需可 添加平均粒徑爲〇.〇〇 5〜1.0//m之無機微粒子，有機微粒 子。無機微粒子可使用二氧化矽、氧化鈦、氧化鋁等之微 粒子。尤其是就確實可得高流動性而言以經疏水化 處 理的二氧化矽微粒子較佳。而且，有機微粒子可使用 聚 氟化次乙烯基粒子、聚甲基丙烯酸甲酯、氟樹脂、矽樹脂 等之樹脂微粒子。 本發明之調色劑組成物的平均粒徑爲4〜2 0 // m較佳， -11- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） / · 518453 經濟部智慧財產局員工消費合作社印製 A7 —___B7_五、發明説明（I。） 更佳者爲6〜12//m。若調色劑之平均粒徑小於4 /zm時， 不易藉由習知的混練粉碎法來製造，.故會顯著降低製品 收率，而若大於20 # m時會有細線再現性不佳的問題。 本發明所使用的調色劑組成物可以習知的方法製得。換 言之，使粘接樹脂、著色劑、荷電控制劑及視其所需的 分 散補助劑等之調色劑組成物以例如超級混練機予以預備混 合後，以2軸押出機均勻地分散、熔融、混練且以噴射 微粉機予以微粉碎後，藉由風力分級機分級以製得所企求 的調色劑組成物。 本發明之調色劑組成物與載體混合，可做爲二成份系顯 像劑。而且，調色劑組成物含有磁性物時，亦可直接做爲 一成份系顯像劑予以靜電潛像之顯像。載體係由鐵、錳、 鈷、鎳、鉻等金屬或二氧化鉻、三二氧化鐵、四三氧化鐵 等金屬氧化物或鐵酸鹽等磁性材料所成，鐵酸鹽係爲以一 般式MFe204(M爲Mn、Co、Mg、Zn或Cιι)所示者。而且， 使載體以金屬材料構成時，爲防止載體表面氧化，故形成 氧化物被膜較佳。此外，磁鐵礦微粒子除使鐵酸鹽微粒子 造粒的磁鐵礦、鐵酸鹽載體外，亦可使用在樹脂中分散有 磁鐵礦微粒子或鐵酸鹽微粒子與荷電控制劑（即樹脂型載 體）。另外，在載體表面上被覆以改善帶電特性等之目的 之與調色劑組成物中所含的樹脂相同之樹脂或不同之樹 載體之粒徑一般使用20〜200//m者，惟以使用20〜60 // m之小粒徑載體時可得良好的印字濃度係爲所企求。 -12- (請先閱讀背面之注意事項再填寫本頁) . 訂 #f 本紙張尺度適用中國國家標準（cys ) A4規格（2!0X297公釐） 518453 A7 ____ B7_ 五、發明説明（U ) 載體之粒徑的測定方法係使用雷射繞射或粒度分佈測定 機SALD-2000J(島津製作所製）予以測定。 二成份系顯像劑係混合調色劑組成物與上述之載體而製 得。調色劑組成物之配合比對調色劑組成物與載體之總量 而言通常爲5〜3 0重量％，惟此係視載體之種類與所使用 的調色劑的帶電特性及顯像方式而大有不同。爲增加與小 粒徑載體相同的載體之比表面積，一般而言可增大調色劑 之配合比。顯像劑中調色劑濃度過低時，畫像濃度變薄， 或載體會附著於感光體上，即易產生載體過多的情形。另 外，若調色劑濃度過高時，因畫像背景之白色部份受到污 染或調色劑飛散情形，致使印表機內外之污染顯著，正確 的調色劑配合比係由實際上印表機之印字予以評估來決 定。 本發明之靜電潛像顯像用調色劑組成物係使用藉由閃光 使記錄介質上之調色劑像固定的畫像固定裝置。較佳者係 使用特徵爲部份限制賦予來自閃光光源所產生的記錄介質 上之調色劑像的放射能源之限制體，設置於上述光源與記 錄介質之間的畫像固定裝置。另外，使用特徵做爲在部份 閃光光源之外壁上設置部份限制放射能源之限制體的畫像 固定裝置較佳。 而且，在本發明之畫像固定裝置中，上述限制物係爲具 使來自上述光源之放射能源反射，散亂或曲折的性質者較 佳。 另外，在本發明之畫像固定裝置中，上述限制體如果 -13- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 518453 A7 __B7_ 五、發明説明（11) (請先閱讀背面之注意事項再填寫本頁) 上述限制體沒有將放射能源限制時，需至少部份強制限制 賦予記錄介質上之高放射能源的放射能源，並至少部份稍 微限制賦予記錄介質上之低放射能源的放射能源較佳。 此外，在本發明之畫像固定裝置中，係以具備可藉由上 述光源以賦予調色劑像放射能源前，使上述記錄介質預 熱之預熱手段者較佳。 於本發明中「限制放射能源」係指在閃光光源之放射能 源產生部位與記錄介質之搬送途中之間放置限制物、吸 收、反射、散亂或曲折放射能源，若沒有限制物存在時記 錄介質或其上之調色劑像中特定部位（大多爲能源密度最 高的部位）所賦予的放射能源的一部份，予以減低之意。 惟此處限制物所遮蔽的放射能源，較佳者係藉由反射、散 亂或曲折賦予於記錄介質之其他部位。藉此可使賦予於記 錄介質或其上之調色劑的放射能源之搬送方向分佈均勻 化。而且，限制物亦可以爲在光源表面或其附近所具有者。 經濟部智慧財產局員工消費合作社印製 於本發明中記錄介質只要是可使調色劑像固定者即可。 大多數以使用紙、塑膠薄膜、布帛、金屬板等片狀物較佳。 紙或塑膠薄膜由於過度加熱而變形，且有變質的可能性， 故適用做爲可降低最大能源密度之本發明適用對象。 本發明之調色劑組成物所使用的典型畫像形成方法，及 電子照片印表機（畫像形成裝置）之槪略係如第1圖所說 -1 4- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 B7 _ 五、發明説明（13 ) 明。電子照片印表機係使調色劑像在感光鼓1上形成。 首先，在感光鼓1上使用帶電器2以使其產生相同地帶 電。然後，使用具備有LED陣列或雷射束之曝光裝置3 ’ 視欲形成的畫像而定選擇曝光空間。感光鼓1上所形成 的潛像，係藉由顯像劑使用顯像裝置4予以顯像，且在感 光鼓1上形成調色劑像。使該顯像的調色劑像藉由複印 帶度電器5複印於記錄介質6上。使記錄介質6以一定 速度搬送，且藉由固定器7予以熔融、固定。 沒有複印於記錄介質之調色劑像，對調色劑而言使負的 偏壓藉由淸潔刷8予以淸除，回復至原來的狀態。 使用第2、3圖來說明限制物。第2圖係爲詳細說明 固定器7者。固定器係藉由閃光光源9使記錄介質6上 之調色劑像1 〇藉由光熱變換作用固定，照射放射能源。 該閃光光源可使用氙氣燈，氖氣燈，氬氣燈及氪氣燈等。 由於有效地使用來自閃光光源之放射能源，在閃光光源背 部配置反射板Π。除此以外，爲構成固定裝置係具有玻璃 板1 2、罩子1 3。來自閃光光源9所照射的放射能源，係 合倂來自背面之反射板1 1所反射的成份，透過玻璃板1 2， 且使記錄介質6上已形成的調色劑像1 0照射。經照射的 放射能源可選擇性地吸收於調色劑像1 〇上，使調色劑發 熱，熔融，且固定於記錄介質6上。記錄介質上之放射 能源分佈如第3圖所示，通常在閃光光源9正下方所照 射的部份最高，如不進行本發明的放射能源限制時，可知 會產生高斯分佈之形狀。 -1 5- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁)There is no particular limitation, but more than 80 mol% of the acid component of the polyester resin is an acid component made of benzoic acid-based dicarboxylic acid, and more than mol% of the alcohol component is oxidized by bisphenol A. Polyester resins obtained from an alcohol component of an alkyl adduct are preferred. In addition, when considering the fixability, the softening point is 8 0 to 130 ° C, and the glass transition point (τ g) is 5 5 to 7 (TC, and the melt viscosity by flow test is 1 0 0 0 0 centipoise. The reaching temperature is 9 0 ~ 1 3 5 ° C -10- Refer to the paper standard for Zhongguanjia standard () A4 specification (21GX297) 518453 A7 _ B7 5. The invention description (?) Is better. Polyester resin Molecular weight distribution, the number average molecular weight is 2500 ~ 45 00, and the weight average molecular weight is 7000 ~ 1 3 0000. (Please read the precautions on the back before filling this page) The toner contained in the toner composition of the present invention can be used Known coloring agents include carbon blacks such as furnace black, acetylene black, and channel black, and ferromagnetic particles, such as magnetite particles, can be used. In addition, black colorants can be mixed with ferromagnetic particles and carbon. Black is used. The dispersion of carbon black in the adhesive resin in these colorants is extremely important in terms of the charge stability of the toner, and a dispersant can be used as needed. In addition, the content of carbon black is 100 The toner composition is preferably 1 to 10 parts by weight. If it is less than 1 part by weight, the hiding power of the adhesive resin is insufficient to obtain a sufficient image density. In addition, if it is more than 10% by weight, the hiding power of the formed image is increased, and it is preferable to increase the density of the image. However, on the other hand, the carbon black chain structure formed in the toner particles makes the toner particles excessively conductive, damages their insulation, reduces the chargeability of the toner, and reduces the density of the image to make the white portion. Contaminated or toner scatters to increase the mouth. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the fluidity improver in the toner composition of the present invention, and the average particle size can be added as needed. 〇5 ~ 1.0 // m of inorganic fine particles, organic fine particles. For inorganic fine particles, fine particles of silicon dioxide, titanium oxide, alumina, etc. can be used. In particular, in terms of high fluidity, hydrophobization-treated dioxide is used. Silicon fine particles are preferred. In addition, as the organic fine particles, resin fine particles such as polyfluorinated vinylidene particles, polymethyl methacrylate, fluororesin, and silicone resin can be used. The average particle size of the composition is 4 ~ 2 0 // m is better, -11- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) / · 518453 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 —___ B7_ V. Description of the invention (I.) The more preferable is 6 ~ 12 // m. If the average particle diameter of the toner is less than 4 / zm, it is not easy to manufacture by the conventional kneading and pulverizing method. Therefore, the yield of the product will be significantly reduced, and if it is larger than 20 #m, there will be a problem of poor reproducibility of fine lines. The toner composition used in the present invention can be prepared by a conventional method. In other words, the adhesive resin, The toner composition such as the colorant, the charge control agent, and the necessary dispersing auxiliary agent is preliminarily mixed with, for example, a super kneader, and then uniformly dispersed, melted, and kneaded with a 2-axis extruder, and then sprayed with a micronizer. After being pulverized, it is classified by a wind classifier to obtain a desired toner composition. The toner composition of the present invention is mixed with a carrier and can be used as a two-component developer. Moreover, when the toner composition contains a magnetic substance, it can also be used as a one-component developer to develop an electrostatic latent image. The carrier is made of metal such as iron, manganese, cobalt, nickel, chromium, or metal oxides such as chromium dioxide, iron dioxide, and iron tetraoxide, or magnetic materials such as ferrite. The ferrite is based on the general formula MFe204 (M is Mn, Co, Mg, Zn or Cm). When the carrier is made of a metal material, it is preferable to form an oxide film in order to prevent oxidation of the surface of the carrier. In addition, in addition to magnetite and ferrite carriers that granulate ferrite particles, magnetite particles can also be used in which magnetite particles or ferrite particles and a charge control agent (that is, resin type) are dispersed in a resin. Carrier). In addition, the particle diameter of the resin that is the same as the resin contained in the toner composition or a different tree carrier that is coated on the surface of the carrier for the purpose of improving the charging characteristics is generally 20 ~ 200 // m. A good printing density can be obtained when a carrier with a small particle size of 20 ~ 60 // m is desired. -12- (Please read the notes on the back before filling in this page). Order #f This paper size is applicable to Chinese national standard (cys) A4 specification (2! 0X297 mm) 518453 A7 ____ B7_ 5. Description of the invention (U) The particle diameter of the carrier is measured by a laser diffraction or particle size distribution measuring machine SALD-2000J (manufactured by Shimadzu Corporation). The two-component developer is obtained by mixing a toner composition with the aforementioned carrier. The blending ratio of the toner composition is usually 5 to 30% by weight based on the total amount of the toner composition and the carrier, but it depends on the type of the carrier and the charging characteristics and development of the toner used. Ways are very different. In order to increase the specific surface area of the same carrier as the small-particle-size carrier, in general, the mixing ratio of the toner can be increased. When the toner concentration in the developer is too low, the density of the image becomes thin, or the carrier adheres to the photoreceptor, that is, the situation of excessive carrier tends to occur. In addition, if the toner concentration is too high, the white part of the background of the image is contaminated or the toner scatters, which causes significant contamination inside and outside the printer. The correct toner mixing ratio is actually the printer. The print is evaluated to determine. The toner composition for developing an electrostatic latent image of the present invention uses an image fixing device that fixes a toner image on a recording medium by flashing. The preferred one is an image fixing device that is provided between the light source and the recording medium, and is a restriction body that is characterized by partially restricting the radiation energy given to the toner image on the recording medium generated by the flash light source. In addition, it is preferable to use a feature as an image fixing device for setting a part of a restricting body for restricting radiation energy on the outer wall of a part of the flash light source. Furthermore, in the image fixing device of the present invention, it is preferable that the restricted object is a material that reflects, disperses or twists the radiation energy from the light source. In addition, in the portrait fixing device of the present invention, if the above-mentioned restricting body is -13- this paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) Order printed by the Intellectual Property Bureau's Consumer Cooperatives of the Ministry of Economic Affairs 518453 A7 __B7_ V. Description of the invention (11) (Please read the precautions on the back before filling this page) When the above restrictions do not restrict radiation energy, at least some mandatory restrictions The radioactive energy imparted to the high-radiation energy on the recording medium is at least partially limited, and the radioactive energy imparted to the low-radiation energy on the recording medium is at least partially restricted. In addition, in the image fixing device of the present invention, it is preferable to provide a preheating means for preheating the recording medium before the toner can be radiated with energy by the light source. In the present invention, "restricted radioactive energy" refers to placing a restricted object, absorbing, reflecting, scattered, or tortuous radioactive energy between the radioactive energy generating part of the flash light source and the transportation of the recording medium. If no restricted object exists, the recording medium Or a part of the radiant energy given by a specific part of the toner image (mostly the part with the highest energy density) is reduced. However, the radiant energy covered by the restricted object is preferably given to other parts of the recording medium by reflection, scattering, or zigzag. This makes it possible to make the distribution direction of the radiation energy imparted to the recording medium or the toner on the recording medium uniform. Furthermore, the restriction may be provided on or near the surface of the light source. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs The recording medium in the present invention may be any one that can fix the toner image. Most of them are preferably made of paper, plastic film, cloth, metal plate and the like. The paper or plastic film is deformed due to excessive heating, and there is a possibility of deterioration, so it is suitable as the applicable object of the present invention that can reduce the maximum energy density. The typical image forming method used in the toner composition of the present invention, and the outline of the electronic photo printer (image forming device) are as shown in Fig. 1-1 4- This paper size applies to the Chinese National Standard (CNS ) A4 specifications (210X297 mm) 518453 A7 B7 _ 5. Description of the invention (13). An electrophotographic printer forms a toner image on the photosensitive drum 1. First, a charger 2 is used on the photosensitive drum 1 so that it is uniformly charged. Then, using an exposure device 3 'equipped with an LED array or a laser beam, the exposure space is selected depending on the image to be formed. The latent image formed on the photosensitive drum 1 is developed using a developing device 4 by a developer, and a toner image is formed on the photosensitive drum 1. The developed toner image is copied onto the recording medium 6 by a copying belt electric device 5. The recording medium 6 is conveyed at a constant speed, and is melted and fixed by the holder 7. The toner image which is not copied on the recording medium is erased by the cleaning brush 8 with the negative bias voltage for the toner, and returns to the original state. Restrictions are described with reference to FIGS. 2 and 3. Fig. 2 is a detailed description of the holder 7. The holder fixes the toner image 10 on the recording medium 6 by the flash light source 9 by the light-to-heat conversion effect, and irradiates the radiation energy. The flash light source may be a xenon lamp, a neon lamp, an argon lamp, a krypton lamp, or the like. Since the radiation energy from the flash light source is effectively used, a reflecting plate Π is arranged on the back of the flash light source. In addition, a glass plate 1 2 and a cover 1 3 are provided to constitute the fixture. The radiation energy radiated from the flash light source 9 is based on the components reflected from the reflection plate 11 on the back side, passes through the glass plate 12, and irradiates the toner image 10 formed on the recording medium 6. The irradiated radiation energy can be selectively absorbed on the toner image 10 to cause the toner to heat, melt, and be fixed on the recording medium 6. As shown in Fig. 3, the radiation energy distribution on the recording medium is usually the highest at the portion directly under the flash light source 9. If the radiation energy limitation of the present invention is not carried out, a Gaussian distribution shape will be generated. -1 5- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)
、1T #Ί 經濟部智慧財產局員工消費合作社印製 518453 A7 __B7 五、發明説明（W ) 此處，使限制物1 4放置於閃光光源9與記錄介質6之 間，且配置於閃光光源9與記錄介質6之最短距離的位 置上。如此使限制物1 4配置於使記錄介質6上照射放射 能源最高部位之光線路徑，部份降低來自閃光光源9所 照射的放射能源。藉由該效果可降低原本在閃光光源9正 下方所產生的高放射能源波峰，如第3圖所示可使放射 能源之分佈均勻化。 而且，使該限制物14不吸收光，總之係爲具擴散或反 應性質，使原本集中於閃光光源9正下之放射能源，移 至周圍部份爲所企求。另外，由於不吸收光，限制物1 4 很少會因吸收放射能源而發熱，具有安定的效果。具該效 果之材質可考慮做爲反射材之金屬製網、格柵或鉻蒸熔膜 等。若爲網、格柵時，就耐熱耐候性而言以不銹鋼較佳。 擴散材可考慮耐熱性光學擴散板等。光學擴散板可考慮使 玻璃表面磨粗的玻璃。此外，曲折材則可考慮圓柱透鏡。 另外，鉻蒸熔膜或光學擴散板做爲限制物1 4時，可使限 制物1 4與玻璃板1 2 —體化。 而且，對記錄介質6之搬送方向而言，變化放射能源 之限制率，可得較均勻的放射能源分佈。總之，較接近閃 光光源9，其放射能源愈高部份，在限制物1 4上具較 強 的限制性質。具體而言，爲金屬製網、格柵時，可提 高 中央部份之網的密度，降低周圍部份之網的密度。爲 鉻 蒸熔時，可增加中央部份之金屬蒸熔量，且減少周圍 部份。 -16- 本紙張尺度適用中國國家標準（CpS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁)、 1T # Ί Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 518453 A7 __B7 V. Description of the Invention (W) Here, the restricting object 14 is placed between the flash light source 9 and the recording medium 6 and is arranged on the flash light source 9 At the shortest distance from the recording medium 6. In this way, the restricting object 14 is arranged on the light path where the recording medium 6 irradiates the highest radiation energy portion, and the radiation energy from the flash light source 9 is partially reduced. This effect can reduce the high radiation energy peaks that are originally generated directly under the flash light source 9, and as shown in Fig. 3, the radiation energy distribution can be made uniform. In addition, the restriction 14 does not absorb light. In short, it has a diffusive or reactive property, so that the radiation energy that was originally concentrated under the flash light source 9 is moved to the surrounding part. In addition, since it does not absorb light, the restriction 1 4 rarely generates heat due to absorption of radioactive energy, and has a stable effect. Materials with this effect can be considered as metal mesh, grid or chrome vapor-deposited film as reflective material. In the case of nets and grilles, stainless steel is preferred in terms of heat and weather resistance. As the diffusion material, a heat-resistant optical diffusion plate or the like can be considered. The optical diffusion plate may be a glass having a roughened glass surface. In addition, cylindrical lenses can be considered for zigzag materials. In addition, when a chromium vapor-deposited film or an optical diffusion plate is used as the restriction member 14, the restriction member 14 and the glass plate 12 can be integrated. In addition, as for the conveyance direction of the recording medium 6, changing the restriction rate of the radiation energy can obtain a more uniform radiation energy distribution. In short, the closer to the flash light source 9 is, the higher the portion of its radiated energy is, the stronger the restricting property is on the restriction 14. Specifically, in the case of metal nets and grilles, the density of the nets in the central portion can be increased and the density of the nets in the surrounding portions can be reduced. In the case of chromium evaporation, the amount of metal in the center can be increased and the surrounding portion can be reduced. -16- This paper size applies to Chinese National Standard (CpS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)
、1T 經濟部智慧財產局員工消費合作社印製 518453 A7 B7 五、發明説明（^) (請先閱讀背面之注意事項再填寫本頁) 第3圖係表示有限制物1 4時或沒有限制物1 4時記錄 介質6上之放射能源分佈例。若爲有限制物1 4時，可得 較均勻的放射能源分佈。 玻璃板1 2係爲防止自記錄介質所產生的紙粉或調色劑、 或自調色劑所產生的氣體等污染閃光光源9與反射板 11，以置於閃光光源9與記錄介質6之間較佳。而且， 藉由使限制體1 4設於玻璃板12之閃光光源9側，可防 止因限制體1 4之調色劑像1 0等所引起的污染，係爲所企 求。 於下述中具體地說明本發明之實施例，惟本發明不受此 等所限制。 實施例 參考例1 (詳細的固定裝置） 經濟部智慧財產局員工消費合作社印製 使用第1圖說明本發明之靜電潛像顯像用調色劑組成 物固定時所使用的含固定裝置，固定方法之電子照片印表 機（畫像形成裝置）之槪略。電子照片印表機係在感光鼓1 上形成調色劑像。首先，在感光鼓1上使用帶電器2使 其具有相同的帶電。然後，使用具備有LED陣列或雷射 束之曝光裝置3，視欲形成的畫像而定選擇空間予以曝光。 在感光鼓1上所形成的潛像上，由調色劑而使用顯像器4 予以顯像，且在感光鼓1上形成調色劑像。使該經顯像 的調色劑像藉由複印帶電器5複印於記錄介質6上。使 記錄介質6以一定速度搬送，藉由如上述之實施形態的 固定器7予以熔融、固定。 使用第1圖說明本發明之固定裝置’固定方法的實施 -17- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 經濟部智慧財產局員工消費合作社印製 A7 __B7 一 五、發明説明（) 例。本實施例係在固定器內部前段藉由產生具有接近2〜ί // m之能源波峰波長的遠紅外線爲主成份之放射熱能源之 鹵素燈1 5，及閃光光源9使記錄介質上之調色劑像固定。 鹵素燈1 5係連續點燈。使記錄介質6及調色劑像1 0預 先加熱。藉由該預先加熱來除去記錄介質爲紙時所含有的 水份，且使記錄介質6全體預熱。由於不僅是調色劑像 且記錄介質6可有效地吸收遠紅外線，然後再藉由調色 劑像有效地吸收閃光光源9所賦予的放射能源，來控制 調色劑像與記錄介質產生溫度差，而可更爲堅固地固定。 換言之，即使閃光光源9之放射能源較低，仍可得良好 的固定性能，而達到輔助的效果。另外，在固定器內部之 後段裝設有爲吸收固定時自調色劑所產生的臭氣或氣體之 排氣口 1 6。 閃光光源9係使氙氣燈。本實施例之氙氣燈的外形大 小係爲直徑約15mm，發光部之長度約爲42 5 mm、定格印 可電壓1 8 5 0V，定格能源爲343 J。閃光光源9產生的能 源以200 J以上較佳。本氙氣燈伴隨著上述介質6之搬送 (約225 mm/ sec)，以6_6Hz周期點燈。總之，在記錄介質 6上以約3 4 m m的間隔使氙氣燈點燈。 在閃光光源9與記錄介質6之搬送途徑之間設有限制 物14。限制物14係使用使厚度0.1mm不銹鋼板（寬14mm， 長44 1mm)藉由蝕刻加工的格柵狀物。第5圖係表示自記 錄介質側所見到的本固定器。本限制物1 4係由與寬0.1 mm 之1 1條與閃光光源9之長方向（與記錄介質_搬送方向 -1 8- 各紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項存填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 518453 A7 B7 V. Description of the invention (^) (Please read the precautions on the back before filling out this page) Figure 3 shows when there is a restricted object 14 or no restricted object Example of radiation energy distribution on recording medium 6 at 14:00. If there are restrictions 1 to 4, a more uniform radiation energy distribution can be obtained. The glass plate 12 is to prevent paper powder or toner generated from the recording medium or gas generated from the toner from contaminating the flash light source 9 and the reflective plate 11 to be placed between the flash light source 9 and the recording medium 6. Better. Furthermore, by providing the restricting body 14 on the flash light source 9 side of the glass plate 12, pollution caused by the toner image 10 of the restricting body 14 and the like can be prevented, which is desirable. Examples of the present invention will be specifically described below, but the present invention is not limited thereto. Examples Reference Example 1 (Detailed Fixing Device) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, using the first figure to explain the fixing device used in fixing the toner composition for electrostatic latent image development of the present invention. Method of electronic photo printer (image forming device) method. The electronic photo printer forms a toner image on the photosensitive drum 1. First, a charging device 2 is used on the photosensitive drum 1 so as to have the same charging. Then, an exposure device 3 provided with an LED array or a laser beam is used to select a space for exposure depending on the image to be formed. The latent image formed on the photoconductor drum 1 is developed by a toner using a developer 4, and a toner image is formed on the photoconductor drum 1. The developed toner image is copied on a recording medium 6 by a copying charger 5. The recording medium 6 is transported at a constant speed, and is fused and fixed by the holder 7 according to the embodiment described above. Use Figure 1 to illustrate the implementation of the fixing method of the fixing device of the present invention. -17- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __B7 One Five , Invention description () example. In this embodiment, in the front section of the holder, the recording medium is adjusted by generating a halogen lamp 15 and a flash light source 9 which emit radiant heat energy with far-infrared rays having an energy peak wavelength close to 2 ~ ί // m as the main component. The toner image is fixed. Halogen lamps 1 to 5 are continuously lit. The recording medium 6 and the toner image 10 are heated in advance. This pre-heating removes the moisture contained when the recording medium is paper, and preheats the entire recording medium 6 as a whole. Since not only the toner image but the recording medium 6 can effectively absorb far infrared rays, the toner image can effectively absorb the radiation energy provided by the flash light source 9 to control the temperature difference between the toner image and the recording medium. , But can be more firmly fixed. In other words, even if the radiation energy of the flash light source 9 is low, a good fixing performance can still be obtained, and an auxiliary effect can be achieved. In addition, an exhaust port 16 is provided at the rear of the holder to absorb the odor or gas generated from the toner during the fixing. The flash light source 9 is a xenon lamp. The external shape of the xenon lamp in this embodiment is about 15 mm in diameter, the length of the light-emitting part is about 42 5 mm, the stoppage voltage is 1850V, and the stoppage energy is 343 J. The energy generated by the flash light source 9 is preferably 200 J or more. This xenon lamp is lit at a frequency of 6-6 Hz with the transport of the medium 6 (approximately 225 mm / sec). In short, the xenon lamps are lit on the recording medium 6 at intervals of about 34 mm. A restriction 14 is provided between the flash light source 9 and the transport path of the recording medium 6. The restrictor 14 is a grid-like object obtained by etching a stainless steel plate having a thickness of 0.1 mm (14 mm in width and 44 1 mm in length). Fig. 5 shows the holder as seen from the recording medium side. This restriction 14 is made up of 11 strips with a width of 0.1 mm and the long direction of the flash light source 9 (and the recording medium_conveying direction-1 8- each paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back and save this page)
518453 A7 B7 五、發明説明（ί7 經濟部智慧財產局員工消費合作社印製 垂直的方向）平行的線圈，及與此等相互連結的數條斜的 線圈所成。1 1條與閃光光源9之長方向平行的線圈係配 置成相當於閃光光源9正下方的部份密度高，周圍部份 密度低。數條斜的線圈係兼具使平行的線圈相互連接，且 限制量大的狀態。 使具有此等不銹鋼製編織的構造之限制物1 4放置於玻 璃板12之上部，閃光光源9下，使兩端挾在，固定於玻 璃板1 2與外殻1 7之間。 使用具該構成之實施例的畫像形成裝置 之調色劑的實驗。 參考例2(標準載體之製造） 聚酯樹脂（塔弗頓’’（譯音）TTR-2， 花王（股）公司製 磁性物（ΕΡΤ-100，戶田工業公司製） 荷電控制劑（”伯頓龍（譯音）"S-34: 歐里遠頓化學公司製） 蠘（LUVAX-1151:日本精蠘公司製） 充份混合上述成份後，以2軸押出機（PCM-30，池貝公 司製）予以熔融、混練後。使該混練物冷卻後以粗粉碎機 (UG-210KGS:朋來鐵工所製）粗粉碎成2mmp帕且使該物 在中粉碎機（"飛因密音"（譯音）FM-3 00N:日本Uni-mutlti工業製）中粉碎後，使用微粉碎機（”洗巴雷塔"（譯 音）”DS-5UR:日本Unimulti工業製）進行分級以製得重 量平均粒徑50/zm之樹脂載體。 -19- 進行使用下述 24 74 重量％ 重量％ 重量％ 重量％ (請先閱讀背面之注意事項再填寫本頁) 、tr 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 B7____ 五、發明説明（P ) 參考例3 使歐里遠頓（譯音）化學公司製”伯頓龍"（譯音）N-01在190 t：、〇 . 〇 〇 1 Μ P a真空加熱下處理6小時以製造荷電控制 劑A。 參考例4 使歐里遠頓化學公司製"伯頓龍"N-01在160°C、〇.〇〇2MPa 之真空加熱下處理1 2小時以製造荷電控制劑B。 參考例5 使歐里遠頓化學公司製"伯頓龍"N-01在90°C、O.OOIMPa 之真空加熱下處理6小時以製造荷電控制劑C。 參考例6 使歐里遠頓化學公司製"伯頓龍"N_01在160°C、〇.〇〇2MPa 之真空加熱下處理6小時以製造荷電控制劑D。 參考例7 使l〇g歐里遠頓化學公司製’’伯頓龍’’N-01在100g甲醇 (試藥特級拿卡賴迪史庫（譯音）（股）公司製）3次更換甲醇 且重覆洗淨以製造荷電控制劑E ° 實施例1 使用下述之成份來製造調色劑。 〔調色劑組成〕 聚酯樹脂Γ塔弗頓"TTR-2、花王（股）公司製）60重量％ 聚酯樹脂（"塔弗頓"TTR-5、花王（股）公司製） 1 6重量％ 磁性物（EPT- 1 000、戶田工業公司製） 20重量％ 炭黑（卡波頓（譯音）公司製；”里卡魯" 2重量％ -20- 本紙張尺度適用中國國家標準（C^S ) A4規格（210X297公釐） I I n I ϋ I I I I I (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 518453 A7 B7 五、發明説明（i?) (譯音3 3 0R) 參考例3之荷電控制劑A 2重量％ (請先閱讀背面之注意事項再填寫本頁) 充分混合上述成份後，以2軸押出機（PCM-30 ;池貝公 司製）予以熔融、混練後，以噴射混練粉碎機（PJM-100 ; 曰本Unimu It i工業公司製）予以微粉碎後，以風力分級機 (A-12 ;阿魯比尼（譯音）公司製）分級，製得重量平均粒徑 爲8 V m之調色劑。另外，爲提高調色劑之流動性，對調 色劑而言添加1.2重量％疏水性二氧化矽微粒子（黑其中頓 (譯音）日本公司製；HVK-2150)，以超級混練機（SMV-20 ; 卡瓦塔（譯音）公司製）混合、調整成調色劑且製得正帶電性 調色劑。 該調色劑之330 °C，加熱處理90秒時之苯產生量爲9//g / g。 經濟部智慧財產局員工消費合作社印製 然後，配合1 〇重量％該調色劑及90重量％參考例2所 製造的樹脂載體以調整顯像劑，且在參考例1所示之LED 印表機上進行畫像顯像，且評估畫像品質。該印表機使用 活性炭量爲3 00 g之過濾器。初期及印字90萬字後皆可得 良好的畫像。而且，測定初期，印字9 0萬字後之過濾器 通過後排氣中之苯量，與周圍大氣水準之1 p p b間沒有很 大的差別，在大氣變動水準（〇.3ppb)以下。 苯量之測量係以個體捕集法（〇&1*1)(^1^134()0)採取11^過濾 器通過部份之氣體，且在熱脫離裝置（TDU)中裝置捕集管， 藉由熱脫離〜GC-FID法，GC/ MS法予以分析。 實施例2 -2 1- 本紙張尺度適用中國國家標準（C^S ) A4規格（210X297公釐） 518453 A7 B7 五、發明説明（>。） 除使用於實施例1之調色劑組成中取代荷電控制劑A 做爲荷電控制劑B外，相同地製作調色劑。該調色劑在 3 3 0 °C、加熱處理90秒時苯之產生量爲14 // g/g。使用該調 色劑同樣地製作顯像劑。使用該顯像劑與實施例1相同 地，在參考例1所示之LED印表機進行畫像顯像，且評 估畫像品質。初期及印字90萬字後皆可得良好的畫像。 而且，測定初期，印字90萬字後過濾器通過後排氣中苯 之產生量，與周遭大氣水平之lppb間沒有很大的差別， 在大氣變動水平（〇.3ppb)以下。 比較例1 除使用未處理的苯胺黑系荷電控制劑之"伯頓龍（譯音）N-〇·1"來取代實施例1之參考例3的荷電控制劑Α外，相 同地製作調色劑。該調色劑在3 3 0 °C下加熱處理9 0秒時苯 之產生量爲100//g/g。使用該調色劑與實施例1相同地 製作顯像劑。使用該顯像劑與實施例1相同地在參考例1 所示之LED印表機上進行畫像顯像，且評估畫像品質。 印字的結果可得良好的畫像。然而，測定排氣中之苯量時， 爲9ppb比大氣水平（lppb)較高，可知必須使用過濾器。 因此，使用活性炭量爲 3 0 0 g之過濾器來進行印字，初期 與周遭大氣水平之lppb間沒有很大的差異，惟於印字60 萬字後，過濾器通過後排氣中之苯量爲2ppb，對大氣之變 動水平而言爲優勢，必須交換過濾器。 比較例2 除使用未處理的苯胺黑系荷電控制劑之"伯頓龍”Nq 3 -22- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） . / I---：-I^----#! (請先閱讀背面之注意事項再填寫本頁) 、11 tf—· 經濟部智慧財產局員工消費合作社印製 518453 A7 __—_B7_ 五、發明説明（Μ ) (請先閲讀背面之注意事項再填寫本頁) 來取代實施例1之參考例3的荷電控制劑A外，其餘 地相同製作調色劑。該調色劑在3 3 (TC下加熱處理9 0秒時 苯之產生量爲1 5 0 // g/g。使用該調色劑與實施例1相同 地製作顯像劑。使用該顯像劑與實施例1相同地，在參 考例1所示之LED印表機上進行畫像顯像，評估畫像品 質。印字結果可得良好的畫像。然而，於測定排氣中苯之 產生量時，爲l〇.5ppb較大氣水平（lppb)爲高，可知必須 使用過濾器。因此，使用活性炭量爲3 00g之過濾器來進 行印字時，初期與周遭大氣水平之1 P P b間沒有很大差異， 惟於印字60萬字後過濾器通過後之排氣中苯量爲2ppb， 對大氣變動水平而言爲優勢，必須更換過濾器。 比較例3 經濟部智慧財產局員工消費合作社印製 除使用荷電控制劑C來取代實施例1之調色劑組成中 的荷電控制劑A外，同樣地製作調色劑。該調色劑在3 3 〇 °C下加熱處理90秒時苯之產生量爲74 // g/g。使用該調色 劑製作相同的顯像劑。使用該顯像劑與實施例1相同地 在參考例1所示的LED印表機上進行畫像顯像，且評估 畫像品質。初期及印字70萬字後可得良好的畫像。惟於 印字70萬字後過濾器通過後排氣中之苯量爲2ppb，對大 氣變動水平（0.3 ppb)而言有差別，必須更換過濾器。 實施例3 除使用荷電控制劑D取代實施例1之調色劑組成中的 荷電控制劑A外，同樣地製作調色劑。該調色劑在3 3 〇 下加熱處理9 0秒時苯之產生量爲3 2 g g/g。使用該調色劑 -23- 本紙張尺度適用中國國家標準（CpS ) A4規格（210X297公螯） 518453 A7 _ B7 五、發明説明（W ) (請先閲讀背面之注意事項再填寫本頁) 同樣地製作顯像劑。使用該顯像劑與實施例1相同地在 參考例1所示之LED印表機上進行畫像顯像，且評估畫 像品質。初期及印字90萬字後皆可得良好的畫像。而且， 測定初期，印字90萬字後過濾器通過後排氣中之苯產生 量，與周遭大氣水平之lppb間沒有很大差異，在大氣變 動水平（〇.3ppb)以下。 實施例4 除使用荷電控制劑E取代實施例1之調色劑組成中的 荷電控制劑A外，同樣地製作調色劑。該調色劑在3 3 〇 下加熱處理90秒時苯之產生量爲36/zg/g。使用該調色劑 同樣地製作顯像劑。使用該顯像劑與實施例1相同地在 參考例1所示之LED印表機上進行晝像顯像，且評估畫 像品質。初期及印字90萬字後皆可得良好的畫像。而且， 測定初期，印字90萬字後過濾器通過後排氣中之苯產生 量，與周遭大氣水平之lppb間沒有很大差異，在大氣變 動水平（〇.3ppb)以下。 實施例5 使用下述之成份來製造調色劑。 經濟部智慧財產局員工消費合作社印製 〔調色劑組成〕 聚酯樹脂（”塔弗頓"TTR-2，花王（股）公司製）60重量％ 聚酯樹脂（"塔弗頓’’TTR-5，花王（股）公司製） 16重量％ 磁性物（EPT- 1 000，戶田工業公司製） 20重量％ 炭黑（卡伯頓公司製；”里卡普" 3 3 0R) 2重量％ 三苯基甲烷系荷電控制劑 2重量％ -24- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 B7 五、發明説明（>3) ("CopybUe"PR，黑其史頓公司製） 使上述成份混合後，以2軸押出機（PCM-30 ;池貝公司 製）予以熔融，混練後，以噴射混練機（PJM-100 ;日本 Uni multi工業公司製）予以微粉碎後，以風力分級機（A—! 2 ; 阿魯比公司製）予以分級，可得重量平均粒徑爲8^m之調 色劑。而且，爲提高調色劑之流動性，對調色劑而言添加 1·2重量％疏水性二氧化矽微粉子（黑其史頓日本公司製； HVK-2150)，且以超級混合機（SMV-20;卡瓦塔公司製）予 以混合以調整調色劑，製得正帶電性調色劑。 該調色劑在33 0°C下加熱處理90秒時苯之產生量爲2//g/g。 然後，配合10重量％該調色劑及90重量％參考例2所 製造的樹脂載體來調整顯像劑，且在參考例1所示之LED 印表機上進行畫像顯像並評估畫像品質。該印表機可在不 使用過濾器下印字。印字結果可得良好的畫像。而且，測 定排氣中之苯量與周遭大氣水平之lppb間沒有很大差異， 在大氣變動水平（〇.3ppb)以下。 苯量之測定係以個體捕集法（(：&1^(^1^?4()0)探取1[過濾 器通過部份之氣體，且在熱脫離裝置（TDU)裝置捕集管， 且藉由熱脫離〜GC-FID法，GC/MS法予以分析。 實施例6 除使用"Brilliant Blue Base”SM(黑其史頓公司製）來取代 實施例5之三苯基甲烷系荷電控制劑之”Copyblue"外，同 樣地製作調色劑。該調色劑在3 3 0 °C下加熱處理90秒時 苯之產生量爲4 # g/g。使用該調色劑與實施例5相同地 -25- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） J^----— (請先聞讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 518453 A7 B7 五、發明説明（β ) 製作顯像劑。使用該顯像與實施例5相同地以參考例1 所示之LED印表機進行畫像顯像且伴估畫像品質。印字 結果可得良好的畫像。而且，測定排氣中之苯量，與周遭 大氣水平之1 P P b間沒有很大的差別，在大氣變動水平 (0.3ppb)以下。 實施例7 使用下述之成份來製作調色劑。 〔調色劑之組成〕 6 0重量％ 16重量％ 2 0重量％ 2重量 2重量％ (請先閲讀背面之注意事項再填寫本頁) 聚酯樹脂（"塔弗頓"TTR-2，花王（股）公司製） 聚酯樹脂（”塔弗頓"TTR-5，花王（股）公司製） 磁性物（EPT- 1 000，戶田工業公司製） 炭黑（卡伯頓公司製；"里卡普"3 3 0R) 4級銨鹽化合物之荷電控制劑 (TP-3 02，保土谷化學公司製） 經濟部智慧財產局員工消費合作社印製 使上述成份充份混合後，以2軸押出機（PCM-30 ;池貝 公司製）予以熔融，混練後，以噴射混練機（PJM-100 ;曰 本Unimulti工業公司製）予以微粉碎後，以風力分級機（A-1 2 ;阿魯比公司製）予以分級，製得重量平均粒徑爲8 // m 之調色劑。另外，爲提高調色劑之流動性，對調色劑而言 添加1.2重量％疏水性二氧化矽微粉子（黑其史頓日本公司 製；HVK-2150)，再以超級混合機（SMV-20;卡瓦塔公司 製）予以混合以而調整調色劑，製得正帶電性調色劑。該 調色劑在330°C下加熱處理90秒時之苯產生量爲4/zg/g。 然後，配合10重量％該調色劑及90重量％參考例2所製 -26- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 518453 A7 _B7_ 五、發明説明（攻） (請先閱讀背面之注意事項再填寫本頁) 造的樹脂載體以調整顯像劑，在參考例1所示之LED印 表機上進行畫像顯像並評估畫像品質。該印表機在不使 用過濾器下印字。印字結果可得良好的畫像。而且，測 定排氣中之苯量與周遭大氣水平之Ippb間沒有很大差異， 在大氣變動水平（〇.3ppb)以下。 苯量之測定係以個體捕集法（Carbotrap400)探取^排 氣，且在熱脫離裝置（TDU)中裝置捕集管，且藉由熱脫離 〜GC-FID法，GC/MS法予以分析。 實施例8 除使用TP-415(保土谷化學公司製）來取代實施例7之4 級銨鹽化合物的荷電控制劑”ΤΡ_3 02 ”外，同樣地製作調色 劑。該調色劑在3 3 0 °C下加熱處理90秒時苯之產生量爲2 A g/g。使用該調色劑同樣地製作顯像劑。使用該顯像劑與 實施例7 相同地在參考例1所示之LED印表機進行畫像 顯像，且進行畫像品質評估。印字結果可得良好的畫像。 而且，測定排氣中之苯量與周遭大氣水平之1 ppb間沒有 很大的差異，在大氣變動水平（0.3ppb)以下。 產業上之利用可能性 經濟部智慧財產局員工消費合作社印製 如上所述，藉由使用本發明之調色劑可增長過濾器之交 換壽命，或可不需使用過濾器，故可降低印表機之流動 成本。 -27- 本紙張尺度適用中國國家標準（CNS ) A4規格（2l〇X297公釐） 518453 A7 B7 五、發明説明（: 符號之說明 I 2 6 8 9 源 光 光 置置電質(Γ4像 鼓器裝裝帶介器刷燈劑板板 體燈口 光電光像印錄定潔氣色射璃子制素氣殼 感帶曝顯複記固淸氙調反玻箱限鹵排外 器 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）518453 A7 B7 V. Description of the invention (ί7 Printed in the vertical direction by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs) Parallel coils and several oblique coils connected to each other. 11 The coil system parallel to the long direction of the flash light source 9 is arranged so that the density of the portion directly below the flash light source 9 is high and the density of the surrounding portion is low. The plurality of oblique coil systems have a state in which parallel coils are connected to each other with a large amount of restriction. A restrictor 14 having such a stainless steel braided structure is placed on the upper portion of the glass plate 12 under the flash light source 9 with both ends resting on it and fixed between the glass plate 12 and the case 17. An experiment using a toner of the image forming apparatus of the embodiment having this configuration. Reference Example 2 (Manufacture of Standard Carrier) Polyester Resin (Taverton TTR-2, Kao Corporation, Magnetic Product (EPT-100, Toda Industry Co., Ltd.) Charge Control Agent ("Bo Dunlong " S-34: manufactured by Orion Farton Chemical Co., Ltd.) (LUVAX-1151: manufactured by Nippon Seikan Co., Ltd.) After the above ingredients are fully mixed, they are extruded on a 2-axis machine (PCM-30, Ikegai Corporation After being melted and kneaded, the kneaded product was cooled and coarsely pulverized into a 2 mmp pa by a coarse pulverizer (UG-210KGS: made by Penglai Iron Works), and the material was pulverized in a pulverizer " (Transliteration) FM-3 00N: Japan Uni-mutlti Industrial) after pulverization, use a micro-pulverizer ("Zibaretta" DS-5UR: Japan Unimulti Industrial) to classify to produce Get a resin carrier with a weight average particle size of 50 / zm. -19- Perform the following 24 74% by weight% by weight% by weight (please read the precautions on the back before filling out this page), tr This paper size applies to China Standard (CNS) A4 specification (210X297 mm) 518453 A7 B7____ 5. Description of the invention (P ) Reference Example 3 The "Burton Dragon" N-01 manufactured by Oriton Chemical Co., Ltd. was processed under vacuum heating at 190 t: 0.001 MPa for 6 hours to produce a charge control. Agent A. Reference Example 4 The "Burton Dragon" N-01 manufactured by Orient Farton Chemical Co., Ltd. was treated under vacuum heating at 160 ° C and 0.002 MPa for 12 hours to produce a charge control agent B. Reference Example 5 The "Burton Dragon" N-01 manufactured by Orion Farton Chemical Co., Ltd. was processed under vacuum heating at 90 ° C and 0.0000 MPa for 6 hours to manufacture a charge control agent C. Reference Example 6 The Orion Farton Chemical company " Borton Dragon " N_01 was processed under vacuum heating at 160 ° C and 0.002 MPa for 6 hours to produce a charge control agent D. Reference Example 7 10 g of Orion Farton Chemical Co., Ltd. was used. 'Burton Dragon' N-01 was replaced with methanol three times in 100 g of methanol (test reagent premium Nacalaisdoku (produced by the transliteration) Co., Ltd.) 3 times and washed repeatedly to produce a charge control agent E ° Example 1 Toner is produced using the following components: [Toner composition] Polyester resin ΓTaverton " TTR-2, manufactured by Kao Corporation) 60% by weight Polyester resin (" Taverton " TTR-5, manufactured by Kao Corporation) 16% by weight Magnetic material (EPT-1 000, manufactured by Toda Industry Co., Ltd.) 20% by weight carbon black (Carboton ( Transliteration) made by the company; "Rikaru" 2% by weight -20- This paper size applies to the Chinese national standard (C ^ S) A4 specification (210X297 mm) II n I ϋ IIIII (Please read the precautions on the back before Fill in this page) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives 518453 A7 B7 V. Description of the invention (i?) (Transliteration 3 3 0R) Reference charge 3 A 2% by weight (Please read the note on the back first Please fill in this page for further details.) After mixing the above ingredients thoroughly, melt and knead with a 2-axis extruder (PCM-30; manufactured by Ikegai Corporation), and then use a jet kneader (PJM-100; manufactured by Yumoto Unimu It i Industrial Co., Ltd.). ) After being pulverized, it is classified with a wind classifier (A-12; manufactured by Arubini) to obtain a toner having a weight average particle diameter of 8 V m. In addition, in order to improve the fluidity of the toner, 1.2% by weight of hydrophobic silica fine particles (Heizhong Dun (manufactured by Japan); HVK-2150) are added to the toner, and a super kneading machine (SMV- 20; manufactured by Kawata Co., Ltd.), mixed, adjusted to toner, and produced a positively charged toner. The toner had a temperature of 330 ° C and a benzene generation amount of 9 // g / g during 90 seconds of heat treatment. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and then mixed with 10% by weight of the toner and 90% by weight of the resin carrier manufactured in Reference Example 2 to adjust the developer, and the LED printed sheet shown in Reference Example 1 Perform image development on board and evaluate image quality. The printer uses a filter with an activated carbon content of 300 g. Good images can be obtained at the beginning and after printing 900,000 words. In addition, at the beginning of the measurement, the amount of benzene in the exhaust after passing the filter with 900,000 characters was not significantly different from the ambient air level of 1 p p b, and was below the atmospheric fluctuation level (0.3 ppb). The measurement of benzene content is based on the individual trapping method (〇 & 1 * 1) (^ 1 ^ 134 () 0), which takes 11 ^ filter to pass part of the gas, and captures it in the thermal desorption unit (TDU). The tube was analyzed by thermal desorption ~ GC-FID method and GC / MS method. Example 2 -2 1- This paper size applies the Chinese National Standard (C ^ S) A4 specification (210X297 mm) 518453 A7 B7 V. Description of the invention (>) Except for the toner composition used in Example 1 Instead of the charge control agent A as the charge control agent B, a toner was produced in the same manner. The amount of benzene produced by this toner at 3 30 ° C and heat treatment for 90 seconds is 14 // g / g. A developer was prepared in the same manner using this toner. Using this developer, the image was developed in the LED printer shown in Reference Example 1 in the same manner as in Example 1, and the image quality was evaluated. Good images can be obtained at the beginning and after printing 900,000 words. Moreover, at the beginning of the measurement, the amount of benzene produced in the exhaust after the filter passed 900,000 characters was not significantly different from the ambient air level of 1 ppb, and was below the atmospheric fluctuation level (0.3 ppb). Comparative Example 1 A tint was produced in the same manner except that the untreated nigrosine-based charge control agent "Burton Dragon N-〇 · 1" was used instead of the charge control agent A of Reference Example 3 of Example 1. Agent. This toner was heat-treated at 330 ° C for 90 seconds and the amount of benzene produced was 100 // g / g. Using this toner, a developer was produced in the same manner as in Example 1. Using this developer, image development was performed on the LED printer shown in Reference Example 1 in the same manner as in Example 1, and the image quality was evaluated. The result of printing is good portrait. However, when the amount of benzene in the exhaust gas was measured, it was 9 ppb higher than the atmospheric level (lppb), and it was found that a filter was necessary. Therefore, using a filter with an activated carbon content of 300 g for printing, there is no great difference between the initial and ambient air levels of lppb, but after printing 600,000 words, the amount of benzene in the exhaust gas after the filter passes is 2ppb is an advantage for the level of change in the atmosphere, and the filter must be exchanged. Comparative Example 2 Except the use of untreated aniline black charge control agent " Burton Dragon " Nq 3 -22- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm). / I ---: -I ^ ---- #! (Please read the notes on the back before filling out this page), 11 tf— · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 518453 A7 __—_ B7_ V. Description of Invention (Μ) ( Please read the precautions on the back before filling in this page). Instead of the charge control agent A of Reference Example 3 of Example 1, the rest is made the same. This toner is heat treated at 3 3 (TC at 9 0 The amount of benzene produced in 1 second was 150 / g / g. Using this toner, a developer was prepared in the same manner as in Example 1. Using this developer, the same as in Example 1 was shown in Reference Example 1. The image was developed on an LED printer to evaluate the quality of the image. The printing result can obtain a good image. However, when measuring the amount of benzene in the exhaust gas, the larger gas level (lppb) is 10.5ppb, which is high. It is known that a filter must be used. Therefore, when using a filter with an activated carbon content of 300 g for printing, the initial and surrounding conditions There is not much difference between 1 PP b at the gas level, but the amount of benzene in the exhaust gas after the filter passes 600,000 characters is 2 ppb, which is an advantage for atmospheric fluctuation levels, and the filter must be replaced. Comparative Example 3 Economy Printed by the Consumer Cooperative of the Ministry of Intellectual Property Bureau except that the charge control agent C was used instead of the charge control agent A in the toner composition of Example 1. The toner was produced in the same manner. The toner was at 3 3 ° C. The amount of benzene produced was 74 // g / g at 90 seconds under heat treatment. The same developer was produced using this toner. The same developer was used as in Example 1 and the LED print shown in Reference Example 1 was used. The image is displayed on the monitor and the image quality is evaluated. Good images can be obtained at the initial stage and after printing 700,000 characters. However, after the 700,000 characters are printed, the amount of benzene in the exhaust gas after passing the filter is 2ppb, which changes the level of the atmosphere. (0.3 ppb) is different, and the filter must be replaced. Example 3 A toner was produced in the same manner except that the charge control agent D was used instead of the charge control agent A in the toner composition of Example 1. The amount of benzene produced when the agent was heat-treated at 3 3 0 for 90 seconds was 3 2 gg / g. Use this toner-23- This paper size is applicable to Chinese national standard (CpS) A4 specification (210X297 male chelate) 518453 A7 _ B7 V. Description of invention (W) (Please read the notes on the back before filling (This page) A developer was prepared in the same manner. Using this developer, image development was performed on the LED printer shown in Reference Example 1 in the same manner as in Example 1, and the image quality was evaluated. Initially and after printing 900,000 words Good images can be obtained. In addition, at the beginning of the measurement, the amount of benzene in the exhaust gas after the filter passed 900,000 characters passed was not significantly different from the ambient air level of lppb, and the atmospheric fluctuation level (0.3ppb) the following. Example 4 A toner was produced in the same manner except that the charge control agent E was used instead of the charge control agent A in the toner composition of Example 1. The amount of benzene produced when the toner was heat-treated at 330 for 90 seconds was 36 / zg / g. Using this toner, a developer was produced in the same manner. Using this developer, daytime image development was performed on the LED printer shown in Reference Example 1 in the same manner as in Example 1, and the image quality was evaluated. Good images can be obtained at the beginning and after printing 900,000 words. In addition, at the beginning of the measurement, the amount of benzene in the exhaust after the filter passed 900,000 characters was not significantly different from the ambient air level of 1 ppb, and was below the atmospheric change level (0.3 ppb). Example 5 A toner was produced using the following components. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Toner composition] Polyester resin ("Taverton" & TTR-2, manufactured by Kao Corporation) 60% by weight polyester resin (" Taverton ' 'TTR-5, manufactured by Kao Corporation) 16% by weight magnetic material (EPT-1 000, manufactured by Toda Kogyo Corporation) 20% by weight carbon black (Caboton Corporation; "Rikap " 3 3 0R ) 2% by weight Triphenylmethane-based charge control agent 2% by weight -24- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 A7 B7 V. Description of the invention (> 3) (" CopybUe " PR, manufactured by Heiki Ston Co., Ltd.) After mixing the above ingredients, it is melted with a 2-axis extruder (PCM-30; manufactured by Ikegai Corporation), and after kneading, it is jet-kneaded (PJM-100; Japan Uni multi Industries) After being finely pulverized, the particles were classified with a wind classifier (A—! 2; manufactured by Arubi) to obtain a toner having a weight average particle diameter of 8 ^ m. Further, in order to improve the fluidity of the toner, 1.2% by weight of hydrophobic silica fine powder (manufactured by Hekiston Japan Co., Ltd .; HVK-2150) was added to the toner, and a super mixer ( SMV-20; manufactured by Cavata Corporation) were mixed to adjust the toner to obtain a positively charged toner. The amount of benzene generated when the toner was heat-treated at 33 ° C for 90 seconds was 2 // g / g. Then, 10% by weight of the toner and 90% by weight of the resin carrier produced in Reference Example 2 were used to adjust the developer, and image development was performed on the LED printer shown in Reference Example 1 to evaluate the image quality. The printer can print without a filter. Good results can be obtained by printing. In addition, there was no significant difference between the measured benzene content in the exhaust gas and the ambient air level of lppb, and it was below the atmospheric fluctuation level (0.3 ppb). The measurement of benzene content is based on the individual capture method ((: & 1 ^ (^ 1 ^? 4 () 0) to detect 1 [the gas that passes through the filter and is captured in a thermal release unit (TDU) unit Tube, and analyzed by thermal desorption ~ GC-FID method, GC / MS method. Example 6 Instead of using " Brilliant Blue Base "SM (manufactured by Heiki Steel Co., Ltd.) instead of triphenylmethane of Example 5 In addition to the "Copyblue" of the charge control agent, a toner was produced in the same manner. The toner produced 4 # g / g of the toner when heat-treated at 330 ° C for 90 seconds. Using this toner and Example 5 is the same -25- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) J ^ ----— (Please read the precautions on the back before filling this page) Order the wisdom of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Property Bureau 518453 A7 B7 V. Description of the invention (β) Developed developer. Using this developer, the same image as in Example 5 was used for the image development with the LED printer shown in Reference Example 1 and estimated. Image quality. Good results can be obtained by printing. Also, the amount of benzene in the exhaust gas is not significantly different from the ambient air level of 1 PP b. The difference is below the atmospheric fluctuation level (0.3 ppb). Example 7 Toner was produced using the following ingredients. [Toner Composition] 60% by weight 16% by weight 20% by weight 2% by weight 2% by weight ( Please read the notes on the back before filling this page) Polyester resin (" Taverton " TTR-2, manufactured by Kao Corporation) Polyester resin ("Taverton " TTR-5, Kao ( Co., Ltd.) Magnetic material (EPT-1 000, manufactured by Toda Kogyo Co., Ltd.) Carbon black (Caboton Co., Ltd .; " Ricap " 3 3 0R) Charge control agent (TP, Grade 4 ammonium salt compound) -3 02, manufactured by Hodogaya Chemical Co., Ltd.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs to fully mix the above ingredients, melted by a 2-axis extruder (PCM-30; manufactured by Ikegai Corporation), and then sprayed The kneading machine (PJM-100; manufactured by Unimoto Industrial Co., Ltd.) was finely pulverized, and then classified by a wind classifier (A-1 2; manufactured by Arubi) to obtain a weight average particle size of 8 // m. Toner. In order to improve the fluidity of the toner, 1.2% by weight of toner is added to the toner. Water-based silicon dioxide micropowder (Hirki Ston Japan Co., Ltd .; HVK-2150), and then mixed with a super mixer (SMV-20; Kavta Co., Ltd.) to adjust the toner to obtain positive charge Toner. The amount of benzene generated when the toner was heat-treated at 330 ° C for 90 seconds was 4 / zg / g. Then, 10% by weight of the toner and 90% by weight of Reference Example 2 were prepared. -This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) 518453 A7 _B7_ V. Description of invention (tapping) (Please read the precautions on the back before filling this page) Resin carrier made to adjust the developer The image was developed on the LED printer shown in Reference Example 1 and the image quality was evaluated. The printer prints without a filter. Good results can be obtained by printing. In addition, there is no significant difference between the measured amount of benzene in the exhaust gas and the ambient air level Ippb, and it is below the atmospheric fluctuation level (0.3 ppb). The measurement of benzene content is based on the individual trapping method (Carbotrap400) to detect the exhaust gas, and the trap tube is installed in the thermal desorption unit (TDU), and it is analyzed by thermal desorption ~ GC-FID method, GC / MS method . Example 8 A toner was produced in the same manner except that TP-415 (manufactured by Hodogaya Chemical Co., Ltd.) was used instead of the charge control agent "TP_3 02" of the fourth-stage ammonium salt compound of Example 7. The amount of benzene produced by the toner under heat treatment at 330 ° C for 90 seconds was 2 A g / g. A developer was produced in the same manner using this toner. Using this developer, image development was performed on the LED printer shown in Reference Example 1 in the same manner as in Example 7, and image quality evaluation was performed. Good results can be obtained by printing. The amount of benzene in the exhaust gas is not significantly different from the ambient air level of 1 ppb, and it is below the atmospheric fluctuation level (0.3 ppb). Industrial utilization possibilities Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs as described above. By using the toner of the present invention, the exchange life of the filter can be increased, or the filter can be eliminated, so the printer can be reduced. Liquidity costs. -27- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) 518453 A7 B7 V. Description of the invention (: Explanation of symbols I 2 6 8 9 Source light and optical power (Γ4 drum device) Installed with a mediator brush lamp board plate body light port photoelectric photo imprinting Dingjie gaseous color glass lacquer element gas shell sensor strip exposure display re-fixed solid Xenon inversion glass box halogen-limiting exclusion device (please read the note on the back first) Please fill in this page for further information.) The paper printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 specification (210X 297 mm).