TW518352B - Propylene copolymer composition and process for producing thereof - Google Patents

Abstract

The invention provides an olefin (co-)polymer composition. More specifically, the composition comprises 0.01 to 5.0 parts by weight of high molecular weight polyethylene having an intrinsic viscosity [ηE ] of 15 to 1000 dl/g measured in tetralin at 135 degree C; and 100 parts by weight of an olefin (co-)polymer other than the high molecular weight polyethylene. In addition, the said high molecular weight polyethylene exists as dispersed fine particles having a numerical average particle size of 1 to 5000 nm. Thus, the olefin (co)polymer composition, due to its higher melt tension and elevated crystallizing temperature, is suitable for blow molding, foam molding, and extrusion; and can give higher production speed in other forming methods. The present invention relates to the olefin (co-)polymer composition and a method for producing the same, and to a catalyst for olefin (co-)polymer polymerization and a method for producing the same. The olefin (co)polymer composition, for example, can be produced in the presence of a propylene polymerization catalyst comprising a high molecular weight polyethylene particles supported by a titanium series transitional metal compound catalyst along or together with an olefin producing catalyst.

Description

8352 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (ί) [Technical Field] The present invention relates to an olefin (co) polymer composition, a method for preparing the same, a catalyst for olefin (co) polymerization, and Its manufacturing method. In detail, the present invention relates to a polyolefin manufacturing catalyst having at least K titanium-containing compound transition metal compound catalyst component as its main component, carrying polyolefins for formal (co) polymerization purposes and polymers having a high degree of polymerization. Pre-activated catalyst for olefin (co) polymerization of olefins and preparation method thereof, K and K on the pre-activated catalyst for olefins as main components, formal (co) polymerization catalyst for olefins, and melt tension and crystallization using the catalyst Polyolefin composition with high temperature and its preparation method. [Background Technology] According to polyolefins, such as polypropylene, high-density polyethylene, and straight low-density ethylene, they have excellent mechanical properties, chemical resistance, etc. * At the same time, they are extremely advantageous in terms of economic balance and have been widely used. Used in various forming fields. However, due to its low melt tension and low crystallization temperature, the moldability of hollow molding, foam molding, extrusion molding, etc. is not good. Not only that, in other molding methods, the high-speed productivity of the molded body also has its limits. . As a method for increasing the melting tension and crystallization temperature of polypropylene, there has been disclosed a method of reacting an organic peroxide with a bridging agent and polypropylene in a molten state (Japanese Patent Laid-Open No. 5 9-9 3 7 No. 1 and Japanese Unexamined Patent Publication No. 6 152754, etc.), K and the reaction of a low decomposition temperature peroxide with semi-crystalline polypropylene in the absence of oxygen to produce a branch with free end long bonds and no condensation The method of glue polypropylene (Japanese Patent Laid-Open No. 2-2 9 8 5 36) and the like. -4 A paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 mm) (Please read the precautions on the back before filling this page) -------- • Order 1 ---- Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs fl8352 A7 _B7__ V. Invention (1) As another method to improve the melt viscoelasticity such as melt tension, the industry has proposed to mix polymers with different inherent viscosities or different molecular weights. A composition of ethylene or polypropylene, or a method in which the composition K is polymerized in many stages. For example, it has been shown that: 2 to 30 parts by weight of ultra-high molecular weight polypropylene is added to 100 parts by weight of general polypropylene, and the melting point is K at 210 t and the temperature range at M is extruded (Tex. 6) 1-2 8 6 9 4); Extruded tablets composed of two-component polypropylenes with different molecular weights and different molecular weights at 2 K, which are obtained by the multi-stage polymerization method (Trade Fair No. 1 2 7 7 0 Bulletin) .; A method for producing K by melt-kneading or multi-stage polymerization of a polyethylene composition containing polyethylene having a high viscosity average molecular weight of 1 to 10% by weight, and three types of polyethylene having different viscosity average molecular weights, or a multi-stage polymerization method ( Japanese Patent Publication No. 62-6 1Q57); using highly active titanium-vanadium solid catalyst components, M multi-stage polymerization method, the ultra-high molecular weight polyethylene with an ultimate viscosity of 20 dl / gM is polymerized to 0.05 to less than Polymerization method of 1% by weight of polyethylene (Japanese Patent Publication No. 5-7 9 6 8 3); a highly active titanium catalyst component pre-polymerized with K 1-butene or 4-methyl-1 1-pentene, The multi-stage polymerization method using a specially arranged polymerizer, the limiting viscosity is 1 Polymerization method of ultra-high-molecular-weight polyethylene at 5 dl / gM by polymerizing 0.1 to 5% by weight of polyethylene (Japanese Patent Publication No. 7-8890), etc. In addition, by using a prepolymerized catalyst and polymerized propylene in which a supported titanium-containing solid catalyst component and an organoaluminum compound catalyst component are prepolymerized with ethylene and polyolefins, a method for producing polypropylene with high melt tension (specially Kaiping-5- This paper size applies to Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) (Please read the precautions on the back before filling this page)

Printed by F18352 A7 _B7_____ of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Description (4) No. 5-222122), and the use of the same catalyst ingredients, which will be used to independently implement the prepolymerization of Methylene ethylene containing 20%. A method for preparing ethylene-α-olefin copolymer with high melt tension by using ethylene-containing prepolymerization catalyst on dl / gK (Japanese Unexamined Patent Publication No. 4-55410) has also been proposed by the industry. Although the various compositions proposed above and their preparation methods have improved the melting tension to some extent, there are still improvements in the odor retention, crystallization temperature, and thermal stability of the bridging rib agent. Also, in a multi-stage polymerization method in which a manufacturing process of a high molecular weight polyolefin is incorporated into a general olefin (co) polymerization process in a formal polymerization, it is difficult to control a trace amount of the olefin (co) polymerization amount of the high molecular weight polyolefin by using a small amount of K. In addition, in order to generate a polyolefin having a sufficiently large molecular weight, it is necessary to adopt a low polymerization temperature. Therefore, it is necessary to modify the procedure, and in addition, the productivity of the final polyolefin composition will be reduced. In the method of prepolymerizing a polyolefin, it is necessary to separately prepare a polyolefin compound; in the method of prepolymerizing a polyethylene, the dispersion of the prepolymerized polyethylene of the polyolefin composition finally obtained is not uniform. The level of stability of the polyethylene composition is required to be further improved. As mentioned above, according to conventional technology, polyolefins are inadequate in the improvement of melt tension and crystallization temperature. At the same time, they have odor problems or problems with thermal stability to be modified. Moreover, during the manufacture of such polyolefins, , Is required to improve productivity. [Summary of the invention] The purpose of the present invention is to provide a suitable for hollow forming and foam forming. -6- The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210 X 29 * 7 mm) (please first (Read the notes on the back and fill out this page)

fl8352 Printed by A7 B7, Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (4), extrusion molding, or other various molding methods, which can also exert high-speed productivity with high melt tension and high crystallization temperature Polyolefin composition, and its manufacturing method. Yet another object of the present invention is to provide a catalyst for olefin (co) polymerization used in the above-mentioned production, and a method for producing the same. In order to achieve the above-mentioned object, the inventors have made intensive research results. By using the catalyst for polyolefin production, a small amount of polyolefin having a specific intrinsic viscosity for formal (co) polymerization purpose and a specific high Pre-activated catalyst with a small amount of polyolefin with inherent viscosity can obtain a polyolefin composition with high melt tension and high crystallization temperature, and finally complete the present invention. The first invention of the present invention is a & hydrocarbon ( Co-) polymer composition characterized by: This composition contains: (a) An ethylene-olefin copolymer containing 50 weight of ethylene alone polymer or ethylene polymerization unit, measured by naphthalene at least M135 π Intrinsic viscosity [ηΕ] High molecular weight polyethylene 0.001 to 5.0 parts by weight in the range of 15 to 100 dl / g, and (b) olefin (co) polymers other than the above high molecular weight polyethylene 1QQ parts by weight; (c) The above-mentioned high molecular weight polyethylene is one in which microparticles having a number-average particle diameter ranging from 1 to SOOOnin are finely dispersed. In the above-mentioned first invention, the intrinsic viscosity [nE] should be 15 ~ 50. The paper size is applicable to the Chinese National Standard Quarter (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling in this page. )

518352 A7 B7 5. Description of the invention (s) The range of dl / g, particularly preferably the range of 17 ~ 5Qdl / g. In addition, the "existing amount of high molecular weight polyethylene is in the range of 0.02 to 2.0 parts by weight", and particularly preferably 0: 0 5 to 1 · 0. In addition, the plant average number average particle diameter is preferably in the range of 1 to 10000 ηη, particularly preferably in the range of 10 to 500 ηη. Further, in the above-mentioned first invention, the intrinsic viscosity [r? R] measured by naphthalene at K135 ° C of the olefin (co) polymer composition is preferably in the range of 0.2 to 10 dl / g. Of the above ranges, it is more preferable that the * intrinsic viscosity [ηr] is in the range of 0.2 to 8 dl / g ', and the range of 0.7 to 5 dl / g is particularly preferable. In the first invention, the olefin (co) polymer other than the high molecular weight polyethylene K is preferably one or more selected from a propylene homopolymer or a propylene-olefin copolymer containing 50% by weight of a propylene polymerization unit. By. Furthermore, in the above-mentioned first invention, it is preferable that the olefin (co) polymer composition has a frequency of the melt at 23 fl t in the original state without a rubber component or an inorganic filler ω = The storage elasticity coefficient at 10 o'clock is G'U = 10Q), and the storage elasticity coefficient at frequency ω = 1〇_2 is printed by the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page ) When G, (o = 10, z), log (G '(ω = 1〇0))-10g (G, (o > = 10-2)) < In addition, in the first invention of Shangying, the olefin (co) polymer composition preferably has 4 × 10-1 at 190 ° F, 230 t :, and 250 ° C in a state where no electron beam is irradiated. The first normal stress difference N! at a shear rate of (sec_ 1) is a relationship shown by 10 g (Ni)> 10 g (MFR) +5. This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 mm)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention () Also, in the above-mentioned first invention, the olefin (co) polymer composition, preferably, has a value between 19 and 25. Under υ, the first normal stress difference N Γ (190¾) and N / (250 ^) at a shear rate of 4X10-1 (sec-1) are [N i (1 9 0 t)-N i (2 5 0 ° C)] / N! (1 9 0 C) < 0 · 6). Furthermore, in the above-mentioned first invention, the * olefin (co) polymer composition preferably has a melt tension MS (190 tM) at a shear rate of 3 × 10-1 (sec-1) at 190 ° F and 25010 °. In the case of MS and 250 (O), it is a relationship shown by [Msugom-Msusotni / Msugotnu.i. In addition, in the first invention described above, the olefin (co) polymer component preferably has a temperature of 230 ° C. When the strain of the melt is 5Q0%, the elastic modulus of t = lG (sec) under the condition is G (t = lG), and the relaxation elastic modulus of t = 300 (sec) is G (t = 300). [G (t = 10) -G (t = 300)] / GU = 10) < 1. Also in the above-mentioned first invention, the olefin (co) polymer component is preferably one having an elongation viscosity during melt extension that rises in a large deformation region and shows strain hardenability. Furthermore, in the above-mentioned first invention, it is preferable that the high-molecular-weight polyethylene fine particles are added before or during the olefin (co) polymerization. In addition, in the above-mentioned first invention, it is preferable that Yes, olefin (co) polymers are propylene homopolymers or propylene-olefin copolymers containing 50 weight of propylene polymer units, and -9 at 23Q TC of olefin (co) polymer compositions. This paper size applies China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

& 18352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (Ί) Melt tension (MS) and the inherent viscosity [η Τ] measured in naphthalene at 135 1C, with 10 gUS ) > 4.28X l0g [7? T] -1.20. Further, in the above-mentioned first invention, it is preferable that the olefin copolymer is a propylene homopolymer or a propylene-olefin copolymer containing 50 weight of propylene polymerization units, and 230 of the olefin (co) polymer composition is preferred. Between melt tension (MS) at 135 ° C and intrinsic viscosity [nT] measured at 135 ° C in naphthalene, with 4.24 × log [n T] + 0.24 > log (MS) > 4.24x log [n Τ ]

The system is shown by A -1. 0. Further, in the above-mentioned first invention, a 'olefin (co) polymer-based ethylene homopolymer or an ethylene-olefin copolymer containing 50% by weight or more of an ethylene polymerization unit is preferred. In the above-mentioned first invention, it is preferable that at least one stabilizer selected from phenol-based antioxidants and phosphorus-based antioxidants is added to 100 parts by weight of the olefin (co) polymer composition. 2 parts by weight. Furthermore, in the above-mentioned first invention, the olefin (co) polymer other than the high molecular weight polyethylene K is a propylene homopolymer or a propylene-olefin copolymer containing 50% by weight of the propylene polymerization unit K, and contains at least The catalyst component of the transition metal compound containing titanium compounds is from 0.01 to 1Q0G mole per 1 mole of the transition metal atom in the periodic table (1991 edition) Group 1, Group 2, Group 1 and Group 1 The selected metal of group 3 metal group is arsenic metal compound (AL1) and the relative transition metal atom 1 mol is 0 ~ 500 mol -10- This paper size applies to China National Standard (CNS) A4 specification (210X 297 public Li) (Please read the notes on the back before filling out this page)

2 5 3 8 A 5 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 _Invention (&) The combination of the ear's electron donor (El) is a catalyst for polyolefin manufacturing, and it is carried in this Pre-activated polyethylene for catalysts In the presence of a catalyst, '' Formed by formal (co) polymerization of propylene alone or propylene with other olefins having 2 to 12 carbons. In addition, in the first invention of the above, it is preferable that the preactivation catalyst further contains an organic gold compound (AL1) in total with the metal contained in the preactivation catalyst. * Relative to the preactivation catalyst The transition gold atom 1 mol in the medium is Q.Q5 ~ 5QGQ mol. It is an organic metal belonging to the metal selected from Group 1, Group 2, Group 12, and Group 13 of the Periodic Table (1991). The metal compound (AL2), together with the electron donor (E 1) contained in the preliminary activation catalyst, is an electron donor of G to 3000 moles relative to the transition metal atom in the preliminary activation catalyst. In the presence of a formal (co) polymerization catalyst for olefins, it is produced by the formal (co) polymerization of propylene alone or with other olefins having a carbon number of 2 to 12. Moreover, in the above-mentioned first invention, it is preferable that the activated catalyst is prepared and supports the relative transition metal compound catalyst component lg, and the intrinsic viscosity [nA] measured in naphthalene at 135 ° C is 15 to 100 dl / g range of polyethylene 0 · 01 ~ 5QGg. Further, in the above configuration, the supported amount 聚乙烯 of polyethylene relative to the transition metal compound catalyst component lg is in the range of G.05 to 20 (30 g, particularly preferably in the range of 0.1 to 1 (3 00 g). Moreover, in the above-mentioned first invention, it is preferable that the pre-activated catalyst has a fixed viscosity [77B], which is measured in naphthalene, relative to the transition metal compound catalyst component lg, and is smaller than 15 dl / g. Propylene homopolymer or propylene-11- This paper is compliant with China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 18352 A7 B7____ V. Description of the Invention (^) Polypropylene (B) polypropylene (propylene) copolymer of propylene-olefin copolymer with an olefin polymerization unit of more than 50% by weight 0.01 ~ 100 g, And polyethylene with an inherent viscosity [r? A] measured at 135 μM is 0.01 to 5000 g in the range of 15 to 100 dl / g. In the above configuration, the intrinsic viscosity [η B] 'of the prepolymerized polypropylene is preferably in the range of 0.2 to 8 dl / g, and particularly preferably in the range of 0.5 to 8 dl / g. In addition, relative to the transition metal compound catalyst component lg, the pre-polymerized polypropylene carrying amount 'is preferably in the range of G.G1 to 5Qg, and particularly preferably in the range of 0.Q5 to 5Gg. In addition, the content of the prepolymerized polypropylene is preferably in the range of 0. GG1 to 2% by weight ', more preferably in the range of 0.005 to 1.5% by weight, and particularly preferably in the range of 0.001 to 1% by weight. . Furthermore, in the above-mentioned first invention, it is preferable that the high molecular weight polyethylene, a propylene homopolymer other than M or a propylene-olefin copolymer containing 50% by weight of a propylene polymerized military element, is more than propylene or propylene and other The olefin (co) polymerization volume is 1 liter, which is converted into a transition metal atom in the catalyst, and is produced by a catalyst amount of KOO · 01 to 1000 millimoles. In the above-mentioned first invention, it is preferable that the olefin (co) polymer other than the high molecular weight polyethylene K is (a) a propylene homopolymer or a propylene-olefin containing 50% by weight or more of a propylene polymerization unit. Copolymer, containing at least a titanium-containing compound as a transition metal compound catalyst component, relative to the transition metal atom 1 mol is 0.01 to 1 0 0 0 mol due to the periodic table (1991 edition) of the first group, the second group Organometallic compounds (AL1) and relative transition metal atoms of selected metals in the group consisting of metals from Groups 12, 12 and 13 -12- This paper is in accordance with China National Standard (CNS) A4 (210X) 297 mm) (Please read the notes on the back before filling in this page) 丨 'Order-I__ Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ^ 18352 A7 B7 V. The invention will be clear (0 Moore is 0 ~ 5G0 In the presence of a catalyst for polyolefin production composed of a combination of Mohr's electron donor (E1) and a preactivated catalyst for polyethylene carried on the catalyst, propylene alone or propylene and carbon number Formally produced by co-polymerization of 2 to 12 other olefins A mixture of an olefin (co) polymer * and (b) a propylene-olefin copolymer containing 5 G by weight of a propylene homopolymer or a propylene polymerization unit. Second, the olefin (co) polymer composition of the second invention of the present invention The manufacturing method is characterized in that the catalyst component of a transition metal compound containing at least to at least a titanium compound, 0.01 to 1,000 mol relative to 1 mol of the transition metal atom, belongs to Group 1 of the Periodic Table (1991 edition), Organometallic compounds (AL1) of metals selected from the group consisting of metals of Groups 2, 12, and 13 and electron donors (E1) of 0 to 500 mol relative to 1 mol of the transition metal atom The catalyst for polyolefin production composed of the combination, K, and the inherent viscosity of the titanium-containing solid catalyst component lg of 0.0 lg to 5 G GO g supported on the catalyst, measured in 135 Π naphthalene [n] Olefin (co) polymerization in the presence of a pre-activated polyethylene of 15 to 100 dl / g of a polyethylene composed of an ethylene homopolymer or an ethylene-olefin copolymer containing more than 50% by weight of ethylene polymerization units, And made into olefin (co) polymers. In the Ming, it is preferable that the (co) polymerized olefin is propylene alone or an olefin having 2 to 12 carbons, and the olefin (co) polymer is a propylene homopolymer or a propylene-containing polymerization unit containing 50% by weight of K. Copolymers of propylene and olefins with 2 to 12 carbons. -1 3-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X29 * 7). (Please read the precautions on the back before filling (This page)

518352 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7. V. The invention will be clear (; l) In the second invention mentioned above, preferably, in the pre-activated catalyst, further added: (a) Relative to 1 mole of titanium atom in the pre-activated catalyst, the total amount of the organoaluminum compound (AL1) contained in the pre-activated catalyst is 0. G5 to 5000 mol of the organoaluminum compound (AL2), And (b) the titanium atom in the pre-activated catalyst is 1 mole, and the electron donor (E1) contained in the pre-activated catalyst is 0 to 3000 moles of electron donor (E 2) in total. In the second invention described above, it is preferable that the amount of the catalyst is 1 liter relative to the olefin (co) polymerization volume, and is converted into a titanium atom in the catalyst, which is Q.01 to 100Q millimoles. Furthermore, in the above-mentioned second invention, it is preferable that the pre-activated catalyst *, in addition to polyethylene, contains a transition metal compound catalyst component lg * which is relatively supported on the catalyst, and is measured in 135 Ό naphthalene. The intrinsic viscosity [nB] is smaller than 15 (11 / 纟), which is a propylene homopolymer or a polypropylene (B) G.01 to 100 g containing a propylene-olefin copolymer containing 50% by weight or more of a propylene polymerization unit. In addition, In the above-mentioned second invention, it is preferable that the amount of the catalyst is 1 liter relative to the (co) polymerization volume of the olefin, which is converted into a transition metal atom and is 0.01 to 1000 millimolar. In addition, in the above-mentioned second invention, It is preferable to include: (a) the catalyst component of a transition metal compound containing at least a titanium-containing compound, relative to 1 mol of the transition gold atom, is 0.001 to 10 QQ, and the reason belongs to the periodic table (1991 version) Groups 1, 2, 12 and -14. The paper size is applicable to China · National Standard (CNS) Λ4 specification (210X2 ^ 7 mm) (Please read the precautions on the back before filling this page. )

518352 Α7 Β7 V. Description of the Invention (Θ) Central Standard Staff of the Ministry of Economic Affairs, Consumer Consumption, Du Printed 1 Group 3 of the Group of Gold Phosphorus Organometallic Compounds (AL1) of Selected Metals and the Relative Transition Gold Phosphorus Atom In the presence of a catalyst for polyolefin manufacturing composed of a combination of 0 to 500 moles of electron donors (E 1), olefins are (co-) polymerized to produce the compounds measured at 135 ° C naphthalene. The intrinsic viscosity [η] is smaller than 15 dl / g and the relative transition metal compound catalyst component lg is (KGlg ~ IQOg of polyolefin (B). Pre- (co) polymerization process of 0.01 ~ 100g; K and (b) and then The olefin (co) is polymerized to produce a pre-activation of a relative transition metal compound catalyst component lg having a intrinsic viscosity [η] of 15 to 100 dl / g as measured in 135 ° C (0.01 g to 5 0 0 0) ( Co-polymerization process; (c) In the presence of a pre-activated catalyst for olefin (co) polymerization obtained by a method in which polyolefin (B) and polyolefin (A) are supported on a transition metal compound catalyst component Formally (co) polymerize olefins with 2 to 12 carbons. In the two inventions, it is preferred that: U) The composition of the transition metal compound containing at least a titanium compound as a catalyst component and 1 mole of the transition metal atom is Q.Q1 ~ lflQG Moore belongs to the periodic table (1991 version ) The organometallic compound (ALi) and relative transition metal atom 1 mole of the selected gold scorpion selected from the group consisting of gold scorpions of Groups 1, 2, 12 and 13 are 0 to 5 0 0 In the presence of a catalyst for polyolefins composed of a combination of Mohr's electron donors (El), the olefin is (co) polymerized and the -15 measured in naphthalene is -15- This paper is applicable to China Standard (CNS) Λ4 specification (210X 297 mm) Please read the precautions on the back first

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518352 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (θ) Polyolefins with inherent viscosity [η] smaller than 15 dl / g (B) * Generates O.Olg from the relative transition metal compound component lg l0Gg pre (co) polymerization process * and (b) and then * polymerize the olefin (co) to measure the intrinsic viscosity [7?] of 135 ν in naphthalene to 15-100 dl / g polyolefin ( A), K is a pre-activated (co) polymerization process that generates 0 Jig to 5000 g relative to the catalyst component lg of the transition metal compound; and (c) is supported on the transition metal in polyolefin (B) and polyolefin (A) In the presence of a pre-activated catalyst for olefin (co) polymerization obtained by the method of compound catalyst component, olefins are formally (co) polymerized with 2 'to 12 carbons. In addition, in the second invention of the present invention, it is preferred that: (a) the content of the transition metal atom 1 mole relative to the catalyst component of the transition metal compound containing at least a titanium compound is (3.Q1 ~ 1QDQ mole The organometallic compound (AL1) of the metal selected from the group consisting of metals belonging to Groups 1, 2, 12 and 13 of the Periodic Table (1391 edition) and 1 mol relative to the transition metal atom is In the presence of a catalyst for polyolefin composed of a combination of 0 to 5 0 mole electron donors (E 1), the olefin is (co) polymerized and the intrinsic viscosity measured in naphthalene at 135 ° C [ η] is a polyolefin (B) smaller than 15 dl / g, and M is a pre- (co) polymerization process of O.Qlg ~ 10Qg with respect to the transition metal compound component lg, and then, the olefin is (co) polymerized to 135 t Polyolefin (A) with intrinsic viscosity [η] measured in naphthalene is 15 ~ 100 dl / g, based on the relative transition metal compound catalyst component lg-1. 6- This paper applies Chinese national standard (CNS) Λ4 Specifications (210X 297mm) (Please read the notes on the back before filling this page) Install--" Order Φ ----- Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (,) Pre-activation (co) polymerization process of O.Qlg ~ 50GGg; will be used in polyolefins (B) and Polyolefin (A) pre-activated catalyst for olefin (co) polymerization obtained by a method in which a catalyst component of a transition metal compound is supported. (B) 1 mole of the transition metal atom in the pre-activated catalyst, and The total amount of organometallic compounds (AL1) contained in the metal contained in the pre-activated catalyst for olefin (co) polymerization is from 0.05 to 5 0 0 Mor. It belongs to Group 1, Period 2 of the Periodic Table (1991 Edition) Organometallic compounds (AL2) of metals selected from the group of metals of Groups 12, 12 and 13; and ~ (c) 1 mole of the transition metal atom in the pre-activated catalyst relative to the olefin (co) The total amount of the electron donor (E1) contained in the preactivation catalyst for polymerization is 0 to 3QGG Moore's electron donor (E2). In the presence of an olefin (co) polymerization catalyst, the olefin is officially formed. (Co) polymerizer. In the second invention described above, it is preferred that After the combination, at least one stabilizer selected from the group consisting of a phenolic antioxidant and a phosphonium antioxidant is added in an amount of 0. 01 to 2 parts by weight. In addition, in the second invention described above, the olefin obtained in accordance with the above-mentioned production method is relatively The (co) polymer composition is 1QG parts by weight, and the olefin (co) polymer obtained by the conventional method of M can be mixed in the range of K0 ~ 1000 parts by weight, more preferably 0 ~ 500Q parts by weight, particularly preferably. It is added in an amount of 0 to 2000 parts by weight. Secondly, the catalyst for olefin (co) polymerization of the third invention of the present invention, > 17- This paper size applies the Chinese National Standard (CNS) A4 specification (210 乂 297 mm)袈-(Please read the precautions on the back before filling this page) Order Φ—— — — — 18352 A7 B7 V. Description of the invention (6) It is a transition metal compound catalyst component containing at least a titanium compound. · Contains the inherent viscosity [η] of the titanium-containing solid component lg, O.Qlg ~ 5 0 0 g, which is relatively supported on the catalyst, as measured in 135 naphthalene, at 15 dl / g ~ 100 dl / g catalyst for olefin (co) polymerization. Secondly, the method for producing an olefin (co) polymerization catalyst according to the fourth invention of the present invention is based on an organoaluminum compound (AL1) having a molar ratio of 0 to 1 mole per titanium atom and 0 to 1 molar per titanium atom In the presence of a catalyst for polyolefin production composed of a combination of ~ 500 mol of electron donor (E1), the olefin (co) is polymerized to produce an inherent viscosity [r?] Measured in naphthalene at 135 t. 15 (11 / § ~ 100dl / g olefin (co) polymer (A) * and the relative titanium-containing solid catalyst component lg is O.Olg ~ 5fl00g olefin (co) polymer (A), supported on Those who contain titanium solid catalyst components. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) In the third to fourth inventions, the transition metal catalyst components should be suitable. An organometallic compound (AL1) selected from the metal group 1 of the relative transition metal atom 1 Gol to G.01 ~ 1QQQ Mohr belonging to Group 1, Period 2, Group 12, and Group 13 of the Periodic Table (1991 edition) ) And an electron donor (E1) with a mole of 0 to 5Q0 mole relative to the transition metal atom 1 In the third to fourth inventions, the olefin (co) polymer (A) is preferably an ethylene-olefin copolymer containing 50% by weight or more of an ethylene homopolymer or an ethylene polymerization unit. Also, in the third to fourth inventions, it is preferable to use as a catalyst-1 8 _ This paper size applies the Chinese National Standard (CNS) A4 specification (2 丨 0 X 297 mm) 518352 Central Ministry of Economic Affairs Standard Bureau employee consumer cooperative printed A7 B7 V. Description of the invention (, b) Ingredients, which in turn contain organoaluminum compounds (AL1) Q.Q1 ~ Mole relative to 1 mole of titanium atom and 1 mole relative to titanium atom. ~ 5GG Mohr electron donor (E1). In addition, in the third to fourth inventions, it is preferable that the relative transition metal compound component lg is Q.Q1 ~ 100g in 135. The formal (co) polymerization purpose polyolefin (B) whose intrinsic viscosity [η] is smaller than 15 dl / g as measured in naphthalene is further formed in the lower layer of the polyolefin (A) for formal (co) polymerization purpose. Furthermore, in the third to fourth inventions, it is preferable that the transition metal compound is It is a titanium trichloride composition or a titanium-containing solid catalyst component whose main component is titanium tetrachloride. Furthermore, in the third to fourth inventions of the above, it is preferable that the organic metal compound (AL 1) Organoaluminum compounds. In the third to fourth inventions, it is preferable that the electron donor (E1) is an organic compound containing oxygen, nitrogen, phosphorus, or sulfur in the molecule, or in the molecule. Those containing Si-0-C bonded organosilicon compounds. In the third to fourth inventions, it is preferable that the polyolefin (B) is an olefin homopolymer having 2 to 12 carbons or two It is preferable that the copolymer on the M is 0. In the third to fourth inventions, it is preferable to further contain 1 mol relative to the transition metal atom and electrons contained in the catalyst for olefin (co) polymerization. The total amount of the body (E1) is 0 to 3000 moles of the electron donor to the body (E2). -1 9- This paper size applies to Chinese National Standard (CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page) 袈. Order 518352 Α7 Β7 V. Description of the invention () In the third to fourth inventions, the electron donor (E2) is preferably an organic compound containing oxygen, nitrogen, phosphorus, or sulfur in the molecule or an Si-G-C bonded organic silicon compound in the molecule. By. In the third to fourth inventions, it is preferable that the organic compound (AL) further contains 1 mol * of the transition metal atom in the preliminary activation catalyst and a metal contained in the preactivation catalyst. 1) Total * is 0 · 0 5 to 5G00 Mol. Organometallic compounds of metals made from metal groups belonging to Group 1, Group 2, Group 12, and Group 13 of the Periodic Table (1991 edition) (AL2), M and 1 mole of the transition metal atom in the relatively pre-activated catalyst, combined with the electron donor (E1) contained in the pre-activated catalyst, is 0 ~ 3 0 0 0 mole of electron donation体 (Ε2). [The best form of the actual invention] Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). In the description of the present invention, the term "polyolefin" means including Olefin homopolymers having 2 to 12 carbons, olefin random copolymers containing two or more olefin polymerization units, and olefin-based (co) polymers containing olefin block copolymers; "polyethylene" and "ethylene (co)" The term "polymer" means an ethylene fluorene (co) polymer comprising an ethylene homopolymer, an ethylene-olefin random copolymer containing ethylene polymer units of 50 weight X or more, and an ethylene-olefin block copolymer; The term "propylene" refers to a propylene-olefin random copolymer containing propylene homopolymer, a propylene-containing polymerized unit having a weight of 50 weight X or more, and a propylene diene smoke block copolymer. The "polyolefin composition" refers to a mixture of polyolefins having different polymerization units, molecular weights, randomness, and block units. -2 0-This paper size applies to Chinese National Standard (CNS) Λ4 size (210X29 * 7mm) 518352

Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs I Α7 B7 V. Description of the Invention (β) "Pre-activation" refers to the high-molecular-weight activity of the catalyst for the production of polyolefins, and the formal (co) polymerization of olefins Previously, it was activated in advance. In the presence of a catalyst for polyolefin production, olefin was preactivated (co) polymerized and supported on the catalyst. The pre-activated catalyst for olefin (co) polymerization of the present invention refers to the use of a transition metal compound catalyst component, an organometallic compound, and an electron as desired, which have been used so far in the manufacture of polyolefins with at least titanium compounds. A catalyst for polyolefin manufacturing composed of a polymer is supported by a small amount of a polyolefin having a specific intrinsic viscosity for a formal (co) polymerization purpose and a small amount of a polyolefin having a specific high intrinsic viscosity, and an activated catalyst is prepared. In the pre-activated catalyst for olefin (co) polymerization of the present invention, as a transition metal compound catalyst component, a transition metal compound catalyst component can be used, and a κ which contains at least a titanium compound as a proposed transition metal for polyolefin production can be used. The compound catalyst component is any of the conventional catalyst components used as the main component. Among them, a titanium solid catalyst component is more suitable for industrial production. As a titanium-containing solid catalyst component, there have been titanium-containing solid catalyst components whose main component is a titanium trichloride composition (Japanese Patent Publication No. 56-3356, Japanese Patent Publication No. 59-28573, Japanese Patent Publication No. 63-6 6 3 2 3, etc.), a titanium-containing catalyst component containing titanium tetrachloride, titanium KCl, magnesium, halogen, and an electron donor as essential components on a magnesium compound (Japanese Patent Laid-Open No. 62-104810) Bulletin, Japanese Patent Publication No. 62-1 0 4 8 1 Bulletin, Japanese Patent Publication No. 6 2-1 0 4 8 1-21-This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) (Please read the notes on the back before filling out this page) "Order IΦ Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of Invention (d) Report, JP 57-633 1 0, Any of these can be used, such as Japanese Patent Publication No. 57-63 3 1 1, Japanese Patent Publication No. 58-83006, Japanese Patent Publication No. 5 8 2 1 3 8 7 1 2 etc.). As the organogallium compound (AL1) ', a compound having an organic group of a metal selected from the group 1, group 2, and group 13 of the periodic table (1991), for example, an organolithium compound, an organosodium compound , Organomagnesium compounds, organozinc compounds, organoaluminum compounds, etc., used in combination with the aforementioned transition metal compound catalyst components. Particularly useful is the general formula K of AIR1 pR2 qx (3 -p + q) (where R 1 and R 2 represent alkyl, cycloalkyl, aralkyl, etc. hydrocarbon groups and alkoxy groups, which may be the same or Different; X represents a halogen atom; p and q represent an organoaluminum compound represented by (< p + q S3 positive number). Specific examples of the organoaluminum compound include trimethylaluminum, triethylaluminum, tri-n-propylaluminum, tri-n-butylaluminum, triisobutylaluminum, tri-n-hexylaluminum, and triisohexyl Trialkyl aluminum such as aluminum, tri-n-octyl aluminum, diethyl aluminum chloride, di-n-propyl aluminum chloride, diisobutyl aluminum chloride, diethyl aluminum bromide, diethyl aluminum iodide, etc. Dialkylaluminum monohalide, diethylaluminum hydride and other dialkylaluminum hydrides, ethylaluminum sesquichloride and other alkylsilsesquihalides, ethylaluminum dihalide and other alkylaluminums Dihalides ^ 'Other alkoxyalkylaluminums, such as ethoxymonoethylaluminum; more suitable are trialkylaluminum and alkylaluminum monohalides. These organoaluminum compounds may be used singly or in combination of two or more. -22- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

Printed by the staff of the Central Bureau of Standards of the Ministry of Economic Affairs for consumer cooperation 518352 A7 B7 V. Description of the invention () The electron donor (El) is used for the purpose of controlling the speed and / or three-dimensional regularity of polyolefin production, and can be used as necessary. 7 乍 Electronics " ^ Precursor (E1), for example, ethers, alcohols, esters, aldehydes, fatty acids, amidines, nitriles, amines, amidines, urea, and thioureas can be used. , Isocyanates, azo compounds, phosphines, phosphonium phosphites, hydrogen sulfides and thioethers, new alcohols, and other organic compounds with any one of oxygen, nitrogen, sulfur, and phosphorus atoms in the molecule, M and silanol Classes and organic silicon compounds with Si—0—C junctions in the molecule. Examples of the ethers include methyl ether, diethyl ether, n-propyl ether, n-butyl ether, isoamyl ether, n-ether ether, n-hexyl ether, isohexyl ether, n-octyl ether, isooctyl ether, n-dodecyl ether, benzene Ethers, ethylene glycol monoethyl ether, diethylene glycol diethyl ether, tetrahydrofuran, etc .; as alcohols, examples thereof include methanol, ethanol, propanol, butanol, pentanol, hexanol, octanol, 2- — Ethylhexanol, allyl alcohol, benzyl alcohol, ethylene glycol, glycerol and the like; as the phenols, examples thereof include phenol, cresol, xylenol, ethylphenol, naphthol and the like. As the esters, there may be exemplified: methyl methacrylate, methyl formate, methyl acetate, methyl pivalate, ethyl acetate, vinyl acetate, n-propyl acetate, isopropyl acetate, and butyl formate. , Pentyl acetate, n-butyl acetate, octyl acetate, phenyl acetate, acetic acid propionate, butyl benzoate, octyl benzoate, 2-ethylhexyl benzoate, methyl phenylacetate, ethyl phenylacetate Esters, methyl p-methoxybenzoate, ethyl p-methoxybenzoate, propyl p-methoxybenzoate, phenyl p-methoxybenzoate, ethyl naphthalate , Ethyl naphthalate, propyl naphthalate, butyl naphthalate, naphthalene-23- This paper size applies to China National Standard (CNS) A4 (210X 297 mm) (Please read the precautions on the back before filling this page )

518352 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (d) Formic acid-2-ethylhexyl ester, phenyl ethyl acetate and other carboxylic acid esters, 'diethyl succinate, Aliphatic polyvalent carboxylic acid esters such as diethyl methyl malonate, diethyl butyl malonate, dibutyl maleate, diethyl butyl maleate; monomethyl peptidate, Dimethyl phthalate, diethyl titanate, di-n-propyl peptidate, mono-n-butyl phthalate, di-n-butyl peptidate, di-isobutyl peptidate, di-n-heptyl peptate, diphthalate 2-ethylhexyl ester, di-n-octyl peptidate, diethyl isopeptidate, dipropyl isopeptide, dibutyl isopeptate, dipeptidyl 2-ethylhexyl ester, para-peptide Aromatic polyvalent carboxylic acid esters such as diethyl p-peptide, dipropyl p-peptide, dibutyl p-peptide, and diisobutyl naphthalate. Examples of the aldehydes include acetaldehyde, propionaldehyde, benzoaldehyde, and the like; and examples of the carboxylic acids include formic acid, acetic acid, propionic acid, butyric acid, oxalic acid, succinic acid, acrylic acid, maleic acid, and valeric acid. One of the carboxylic acids such as benzoic acid and anhydrous benzoic acid, anhydrous peptidic acid, anhydrous hydrogen peptidic acid, etc .; as the ketones, the examples are acetone, methyl ethyl ketone, methyl methyl butyl ketone, benzoamidine and many more.

Examples of the nitrogen-containing compound include nitriles such as acetonitrile, benzonitrile, and the like; such as methylamine, diethylamine, tributylamine, triethanolamine, — (N, N—diethylamino) ethanol, pyridine, Quinoline, α-piperoline, 2,4,6-trimethylpyridine, 2,2,5,6-tetramethylpyridine, 2,2,5,5-tetramethylpyrrolidine, N, N, N,, N, amines such as tetramethylethylamine, aniline, dimethylaniline, etc .; such as formamidine, hexamethylammonium phosphate, Ν, Ν, Ν,, N,, N "- Pentamethyl-N'-1 / 3-Dimethylaminomethyl-squatamine, trimethylamine octamethylpyroate, etc.-2 4-This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 297) ）) ~ (Please read the precautions on the back before filling this page) 订 -Φ 518352 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Ammoniums of the invention description (is), N, N, N ', N' Urea such as tetramethylurea; Isofluorates such as phenyl isocyanate and phenyl esters for isofluoric acid; such as even H compounds. As phosphorus compounds Examples include: phosphines such as ethylphosphine, triethylphosphine, tri-n-octylphosphine, triphenylphosphine, triphenylphosphine oxide, etc .; such as dimethyl phosphite, di-n-octyl phosphite, phosphorous acid Phosphorous acids such as triethyl ester, tri-n-butyl phosphite, phenyl ester of phosphorous acid, etc. As sulfur-containing compounds, examples thereof include: diethyl sulfide, diphenyl sulfide, methyl, benzene Thioethers such as methyl thioethers; thiols such as ethyl mercaptan, n-propyl mercaptan, thiophenols, etc. As examples of organosilicon compounds, examples include trimethylsilanol, triethyl Silyl alcohols such as trimethylsilyl alcohol, triphenylsilyl alcohol, etc .; such as trimethylmethylsilane, dimethyldimethoxysilane, methylphenyldimethoxysilane, vinyltrimethoxysilane, benzene Trimethoxysilane, trimethylethoxysilane, diisobutyldimethoxy, diisobutyldimethoxysilane, diphenyldiethoxysilane, methyltriethoxysilane, Ethyltriethoxysilane, vinyltriethoxysilane, butyltriethoxysilane, phenyltriethoxysilane, ethyltriethoxysilane Isopropoxysilane, vinyltriethoxysilane, cyclopentylmethyldimethoxysilane, cyclopentyltrimethoxysilane, dicyclopentyldimethoxysilane, cyclohexylmethyldimethyl Organic silicon compounds with Si-0-C bonds in molecules such as oxysilane, cyclohexyltrimethoxysilane, dicyclohexyldimethoxysilane, 2-orthobornylmethyldimethoxysilane, and the like. These electron donors can be used singly or in combination of two or more. -25- This paper size applies to China National Standard (CNS) A4 (210X197 mm) (Please read the precautions on the back before filling this page)

518352 A7 B7 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (> 0 use. The 'olefin (A) in the pre-activated catalyst for olefin (co) polymerization of the present invention has Γδ:-1 0 0 dl / g, preferably in the range of 17 to 50 (in the range of 11 / ^, the inherent viscosity [^] measured in 135 £ 00 Cai Manzhong. Polyolefin (A) 'is a homopolymer of olefins having 2 to 12 carbons Or its copolymer 'preferably a homopolymer of ethylene or propylene, or a polymerization site of ethylene or propylene of 50% by weight or more' is preferably 70% by weight or more, more preferably 90% by weight or more of ethylene-olefin copolymerization Polymer or propylene-olefin copolymer, more preferably a homopolymer of ethylene or an ethylenic polymerization unit of 50% by weight, preferably an ethylene-olefin copolymer at 70% by weight, especially at 90% by weight. When polyolefin If the intrinsic viscosity [η] of (A) is too small, the melt tension and crystallization temperature of the polyolefin composition finally obtained in the formal (co) polymerization become insufficient. In addition, the upper limit of the intrinsic viscosity [η], and There is no special restriction, but it is inherent in the polyolefin composition finally obtained When the degree [η] is too large, the dispersion of the polyolefin in the polyolefin composition via (A) may deteriorate, and as a result, the melt tension may be insufficient. In addition, from the viewpoint of manufacturing efficiency, the upper limit should be limited to 100 dl. In addition, since the inherent viscosity [η] of polyolefin (A) measured in 135 g of naphthalene is necessary to be quantified to 15 dl / g, the efficiency of quantification of the polymer should be appropriate. It is an ethylene homopolymer or an ethylene-olefin copolymer having an ethylene polymerization unit at 50 weight X M. In addition, there is no particular limitation on the density of the polyolefin (A), and it is preferably about 88Q-98Qg / liter. -26 -This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page.) Order #: 518352 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of the invention (7 (1) The supporting amount of the transition metal compound catalyst component lg of the polyolefin (A) is from 0.001 to 500 Gg, preferably from 0.05 to 200 Qg, more preferably from 0.1 to 1 ο 〇Ί〇Τ〇i When the amount of catalyst component T7m of the gold M compound is less than 0. Dig, The effect of increasing the melt tension and crystallization temperature of the polyolefin composition obtained by the formal (co) polymerization of hydrocarbons is not sufficient. Also, when it exceeds 5fl00g * it is not only that the improvement of these effects is not significant. Where the homogeneity of the obtained polyolefin composition is also deteriorated, it is not a favorite. As K polyolefin (A) (co) polymerized polyolefin, including ethylene, propylene, 1-butene, 1- Pentene, 1-hexene, 1-octene, 1-decene, 4-methyl-1, 1-pentene, 3-methyl-1, 1-pentene, etc. Among them, ethylene, propylene, 1-one Butene and 4-methyl-1pentene. On the other hand, the polyolefin (B) is a polyolefin of the same kind as a polyolefin having a formal (co) polymerization purpose whose intrinsic viscosity [η] is smaller than 15 dl / g as measured at 135 μM. Polyolefin (B) is a component that imparts dispersibility to the polyolefin composition finally obtained by polyolefin (A). From its meaning, its inherent viscosity [η] is preferably higher than that of polyolefin (A). The intrinsic viscosity [η] is small and is larger than the intrinsic viscosity of the polyolefin composition finally obtained. On the other hand, the supporting amount of the transition metal compound catalyst component lg of the polyolefin (B) is from 0.001 to 100 g, in other words, the polyolefin composition standard finally obtained by K is preferably 1 weight. % Range. Dangju-27- This paper size is in accordance with Chinese National Standard (CNS) A4 (210X 297mm) (Please read the notes on the back before filling out this page), 11 Φ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (") When the carrying amount of olefin (B) is small, the dispersibility of polyolefin (A) in polyolefin composition becomes insufficient, and when it is too large, polyolefin ( A "The dispersion of H smoke will saturate, and further migration will lead to a decrease in the production efficiency of the olefin (co) polymer preactivation catalyst. The preactivation catalyst for polyolefin (co) polymerization of the present invention is caused by Formal (co) polymerization in the presence of the aforementioned catalyst for the production of polyolefins containing a transition metal compound catalyst component containing at least a titanium compound, an organometallic compound (AL1), and an electron donor (E1) as desired The pre- (co) polymerization process of the intended olefin pre-copolymerization to form polyolefin (B), K and the subsequent pre-activation polymerization process of olefin (co) -polymerization to form the above-mentioned polyolefin (A), in the transition metal The catalyst component of the composite is supported by the pre-activation treatment of polyolefin (B) and polyolefin (A). In this pre-activation treatment, the transition metal compound catalyst component and relative catalyst of the titanium-containing compound are used. 1 mol of transition metal in the composition is Q.01 ~ 100 (3 mol, 亘 is organometallic compound (AL1) of Q5 ~ 500 mol, and 1 mol of transition metal in the relative catalyst component is 0 ~ 500 moles, preferably 0 ~ 1Q Moore's electron donor (E1) combination is used as a catalyst for olefin production. This polyolefin production catalyst is 1 liter of polymerization volume relative to olefin, which is converted into the catalyst component The transition metal atom K0.QQ1 ~ 5GQ0 millimoles, preferably K D.D1 ~ 10QQ millimoles, should be present in the absence of the solvent or in the solvent relative to the catalyst component of the transition metal compound 1 g, up to 1 GG liter ， For -2 8-This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling out this page) -Φ 518352 Staff Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Print A7 .___ B7__V. Description of Invention () To Formal (Total) The targeted olefin Q.01 ~ 5D0g is pre- (co) polymerized to produce the relative transition metal compound catalyst component lg, which is + Qb ~ + 0g in the plant of 0.Q1 ~ 100g, and then " ^ to ¥ hydrocarbons. 〇1 ～ 10000。 (Co) polymerization, relative to the transition metal compound catalyst component lg, to produce o.fli ~ 5000g of polyolefin (A), thereby, polyolefin (B) and (A) ) The coating is supported on the catalyst component of the transition metal compound. In this specification, the term "polymerization volume" means the volume of the liquid phase part in the polymerizer in the case of weak-phase polymerization, and in the case of gas-phase polymerization. Refers to the volume of the gas phase in the polymerizer. The amount of the transition metal compound catalyst component used should be within the above-mentioned range to efficiently and efficiently control the (co) polymerization rate of the polyolefin (A). In addition, if the amount of the organometallic compound (AL1) used is too small, the (co) polymerization reaction rate will be too slow, and even if it is increased, it is difficult to expect that the (co) polymerization reaction rate will increase, or ' Since a large amount of residues of the organometallic compound (AL1) is generated in the polyolefin composition finally obtained, it is not satisfactory. If the amount of the electron donor (E1) used is too large, the (co) polymerization reaction rate will decrease. When the amount of the solvent used is too large, not only a large reaction vessel is required, but also it becomes difficult to control and maintain an effective (co) polymerization reaction rate. Pre-activation treatment, for example, aliphatic hydrocarbons such as butane, pentane, hexane, heptane, octane, isooctane, decane, dodecane, cyclopentane, cyclohexane, methyl ring Cycloaliphatic hydrocarbons such as hexane, aromatic hydrocarbons such as toluene, xylene, ethylbenzene, or the inertness of other gasoline fractions or diesel fuel oil fractions, etc.-29- This paper applies Chinese national standards (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) > Packing-l · Order Φ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (4) Solvent It can be implemented in the weak phase of the olefin itself as a solvent, or it can be implemented in the gas phase without using a solvent. The chemical treatment can be carried out in the presence of hydrogen. In order to generate a high molecular weight polyolefin (A) having an intrinsic viscosity [η] of 15 to 100 dl / g, it is not suitable to use hydrogen. 01〜IQOg 的 进行 进行。 In the pre-activation treatment, the pre- (co) polymerization conditions of the olefin for the formal (co) polymerization purpose, as long as it is a condition that the polyolefin (B) K relative to the transition metal compound catalyst component lg is 0.01 to IQOg. Yes, it is usually carried out at a temperature of -40 to 100 t: and a pressure of 0.1 to 5 MPa for 1 minute to 24 hours. In addition, using pre-activated (co) polymerization conditions of olefins, as long as the catalyst component lg of polyolefin (A) relative to the transition metal compound is lg, 0 · Q 1 to 5 0 QQ g, preferably Q · 0 5 to 2 0 0 Q g, more preferably, the condition of the amount of M 0 · 1 to 1 0 0 g is sufficient, and there is no special limitation. Usually it is -40 ~ 40 ，, preferably -4Q ~ 3QC, preferably at a lower temperature of -40 ~ 20 于, 0.1 ~ 5MPa, preferably 0,2 ~ 5MPa, more preferably 0.3 ~ 5MPa It is carried out under pressure for 1 minute to 24 hours, preferably 5 minutes to 18 hours, more preferably 10 minutes to 12 hours. In addition, after the above pre-activation treatment, K is used for the purpose of suppressing the reduction of the formal (co) polymerization activity by the pre-activation treatment, and the reaction amount of the alkene to the transition metal compound catalyst component lg is (KQ1 to 10Qg) In this case, the amount of organometallic compound (AL1), electron donor (E1), solvent and olefin can be used in conjunction with the preactivation of olefin ( Total) The same standard of aggregation -30- This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) ▼ Packing-(Please read the precautions on the back before filling in this page) l · Order The Consumer Co-operation of the Central Standards Bureau of the Ministry of Economic Affairs has printed 518352 A7 B7. 5. The description of the invention (in) is implemented in the relative transition metal atom 1 mole, which is 0.005 ~ 10 moles, preferably 0.Q1 ~ 5 moles. It is carried out in the presence of an electron donor. The reaction conditions are carried out at a temperature of -40 ~ and a pressure of (3 · 1 ~ 5MPa +) for 1 minute ~ 24 hours. The organometallic compound used in the addition polymerization (AU), electronically The type of the catalyst (E1) and the solvent can be the same as those used in the preactivation (co) polymerization of olefins, and the olefin * is the olefin used for the purpose of formal (co) polymerization. The intrinsic viscosity [η] is in a smaller range than the intrinsic viscosity [η] of the polyolefin (A), and is finally included as part of the polyolefin after formal (co) polymerization. The polyolefin (co) polymerization of the present invention Pre-activated catalyst is used in its original state or together with additional organometallic compounds (AL2) and electron donors (E2) for the purpose of obtaining olefins with a carbon number of 2 to 12 for the intended polyolefin composition. Formal (co) polymerization. The catalyst for formal (co) polymerization of olefins of the present invention is composed of the aforementioned pre-activated catalysts for olefin (co) polymerization, as opposed to the transition metals in the pre-activated catalysts for olefin (co) polymerization. Atom 1 mole, the total amount of organometallic compound (AL1) in the preactivated catalyst for organic and olefin (co) polymerization (AL1 + AL2) is 0.05 ~ 3QGG mole, preferably 0.1 ~ 1 0 0 0 mole Organometallic compounds (AL2), and relative The transition metal atom in the preactivation catalyst for hydrocarbon (co) polymerization is 1 mole, and the total amount of the electron donor (E1) in the preactivation catalyst for olefin (co) polymerization (E1 + Ε2) is 0 ~- 31- This paper size applies to Chinese National Standard (CNS) Α4 size (210 X 297 mm) (Please read the precautions on the back before filling this page)

518352 Α7 Β7 ^, description of the invention (β) 5000 mol, it should be composed of 0 ~ 3GQG electron donor. When the content of the organometallic compound (AL1 + AL2) is too small, the (co) polymerization reaction rate of the formal) polymerization of olefins will be too slow. On the other hand, when the content of the organometallic compounds is too large, it will not increase. The (co) polymerization reaction rate increases as expected and is not efficient '. Moreover, the residue of the organometallic compound in the polyolefin composition finally obtained will increase, which is not satisfactory. * When the content of the electron donor (E1 + E2) is too large, the (co) polymerization reaction rate will be significantly reduced. As catalysts for formal (co) polymerization of olefins, the types of organometallic compounds (AL2) and electron donors (E2) can be used in pre-activated catalysts for olefin (co) polymerization as necessary. The organometallic compound (AL1) and the electron donor (E1) are the same. One type may be used alone or two types may be used in combination. In addition, when pre-activating with olefin (co) polymerization, the user may be the same or different. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs (please read the notes on the back before filling out this page) Φ The catalyst for the formal (co) polymerization of olefins can be used in the pre-activated catalyst for the (co) polymerization of olefins Existing solvents, unreacted olefins, organometallic compounds (AL1), and electron donors (E1), etc. are filtered or decanted to remove the powder and granules obtained, or a suspension obtained by adding a catalyst to the powder and granules Liquid, combined with additional organometallic compound (AL2) and electron donor (E 2) used as desired. It can also be used in the presence of solvents and unreacted diene, by vacuum distillation or inert gas flow, etc. The obtained powder and granules are removed by evaporation, or a suspension obtained by adding a solvent to the powder and granules is formed by combining with an organic gold compound (AL2) and an electron donor (E2) as desired, and -32- The wave scale applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 518352 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Α7 Β7 to complete its manufacturing. In the method for producing a polyolefin composition of the present invention, olefins are formally (co) polymerized in the presence of a catalyst for the (olefinic) polymerization of the olefins of the third invention, which is a catalyst for the formal (co) polymerization of olefins of the third invention. The amount of the pre-activated catalyst for olefin (co) polymerization or the catalyst used for formal (co) polymerization of olefins is 1 liter relative to the polymerization volume, which is converted into the transition gold atom in the pre-activated catalyst for olefin (co) polymerization. (K001 ~ 1000 millimoles, preferably 0.005 ~ 500 millimoles. By making the amount of the catalyst component of the transition metal compound within the above range, the effective and controlled (co) polymerization of olefins can be maintained Speed. The formal (co) polymerization of olefins in the first invention of the present invention can use the conventional olefin (co) polymerization process as the polymerization process * Specifically, it can be used in propane, butane, pentane, hexane, Aliphatic hydrocarbons such as heptane, octane, isooctane, dodecane, cycloaliphatic hydrocarbons such as cyclopentane, cyclohexane, methylcyclohexane, and aromatics such as toluene, xylene, ethylbenzene, etc. In an inert solvent such as a hydrocarbon fraction or a gasoline fraction or a hydrogenated diesel fraction, a slurry polymerization method of (co) polymerization of an olefin is performed, and an overall polymerization method using the olefin itself as a solvent is used to (co) polymerize the olefin Gas phase polymerization The polyolefin produced by (co) polymerization is a liquid solution polymerization, or a polymerization process in which two types of K are combined. Regardless of whether any of the above polymerization processes is used, as the polymerization conditions, 2 is used. 0 ~ 1 2 0 υ, preferably 30 ~ 1 0 0, especially 40 ~ 100 ° C temperature range, 0.1 ~ 5MPa, preferably 0.5 ~ 5MPa polymerization pressure range, in this range -33- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page) Order 518352 Printed by the Central Consumer Bureau of the Ministry of Economic Affairs Consumer Cooperatives Α7 Β7 V. Description of the invention (/ 丨) The method of enclosing K continuous and semi-continuous batches can be polymerized for 5 minutes to 24 hours. By using this range, polyolefins can be efficiently and effectively controlled. In a preferred aspect of the method for preparing an olefinic composition according to the present invention, the polymerization modification is selected so that the intrinsic viscosity [η] of the polyolefin formed by formal (co) polymerization and the finally obtained polyolefin composition is 〇 · 2 ~ 10dl / g, preferably in the range of 0.7 ~ 5dl / g In the obtained polyolefin composition, the polyolefin (A) * derived from the olefin (co) polymerization pre-activation catalyst used in the obtained polyolefin composition * is in the range of G.01 to 5 by weight X. It is also compared with the conventional olefin The polymerization method is the same, and the molecular weight of the (co) polymer obtained by using hydrogen during polymerization can be adjusted. When the intrinsic viscosity [77] of the obtained polyolefin composition does not reach 0.2 dl / g, the final obtained The polyolefin molded product has deteriorated mechanical properties, and when it exceeds 10 dl / g, the moldability deteriorates. On the other hand, the polyolefin (A) derived from a pre-activated catalyst for olefin (co) polymerization Content, if the obtained polyolefin composition does not reach 0.001 weight X, the effect of increasing the melt tension and crystallization temperature of the polyolefin composition is small, and when it exceeds 5 weight X, not only this Where the effect is saturated and the homogeneity of the polyolefin composition is impaired. In the method for producing a polyolefin composition of the present invention, as the olefin used for formal (co) polymerization, an olefin having a carbon number of 1 to 12 can be suitably used. Examples are: ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, 1-decene, 4-methyl-1 1-pentene, 3-methyl-34 -This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X29 * 7mm) (Please read the precautions on the back before filling this page) Φ 518352 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy Α7 Β7 Description of the invention (ρ) -i-pentene, etc. Particularly preferred are ethylene, propylene, 1-butene, 4-methyl-1, 1-pentene and the like. These olefins can be used alone or in combination. The polyolefin obtained by the formal (co) polymerization of these olefins is not only an olefin homopolymer, but also a main monomer. The olefin polymerization unit contains 50 weight: olefin-random copolymer or olefin-block copolymerization on SK The content of the olefin homopolymer and the main monomer is preferably 90% by weight; the above olefin-random copolymer, or the content of the olefin polymerization unit of the main monomer is the olefin one block on the weight K Copolymer. After the formal (co) polymerization of olefins is completed, it is necessary to go through conventional post-treatment processes such as catalyst deactivation process, catalyst residue removal process, drying process, etc. to obtain the desired polymer with high melt tension and high crystallization temperature. Olefin composition. In the method for producing a polyolefin composition of the present invention, a method is adopted in which a high-molecular-weight polyolefin (A) is produced in a pre-activation process and uniformly dispersed in the olefin composition finally obtained. Therefore, the olefin ( The necessary amount of pre-activated catalyst for co-polymerization is comprehensively prepared, and the (co) polymerization of general olefins is carried out in the formal (co) polymerization using the existing process. Therefore, compared with general polyolefin manufacturing, it can maintain the same Productive. The polyolefin composition obtained by using the method for preparing a polyolefin composition using the olefin (co) polymerization preactivation catalyst of the present invention has high melt tension as described above. For example, in the case where the polyolefin produced by formal (co) polymerization is polypropylene, the final melt of the polypropylene composition obtained under 230¾ of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) (%) I— (Please read the precautions on the back before filling this page) Order 518352 A7 B7_____ V. Description of the invention (work) Tension (MS) and intrinsic viscosity measured in naphthalene household at 135 ° C [^] have the following Formula: ----- Divided into "Gate:} One of the systems. The upper limit is not particularly limited. If the melt tension is too high, the formability of the finally obtained polyolefin composition will be deteriorated. Therefore, in Kalou For the purpose of the present invention, 4,24 magic is even better. 5 [Ten 0, 24 > / 〇3 one enters ^ 5 The best is Dou 24, [Magic Ten is Magic> +24 small goods range. 230t: Melt Tension (MS) below is a melt tension tester type-2 (manufactured by Toyo Seiki Seisakusho Co., Ltd.) at 23010. The polyolefin is heated to 230 ° C in the device, and the molten polyolefin is measured from its diameter. 2 · 095πιη nozzle M20ΒΙ® / min speed extruded into the atmosphere of 23Ό, forming For thread stocks, the measured value of the tension of the linear polyolefin when pulling the strands of the obtained thread at a speed of M3.14m / min (unit: CN). Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the back Please fill in this page again after the formalization) After the formal (co) polymerization is completed, you can obtain the polypropylene composition (PP) by post-processing such as the conventional catalyst deactivation process, catalyst residue removal process, and drying process. In the following, for the convenience of explanation, K polypropylene composition (PP) is taken as an example. In the present invention, the phenol-based stabilizer is used for forming the polypropylene composition finally obtained by using MW. The thermal stability, high melt tension, and high crystallization temperature are added. -3 6-This paper size is applicable to China National Standard (CNS) Α4 size (210X 297 mm) 518352 A7 B7 Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed 1. Description of the invention (fir) Addition amount * is a factory that displays the above characteristics and the cost of stabilizers without reducing the inherent properties of the polypropylene composition (PP) of the component (A). ¥¥ ( 100 parts by weight of polypropylene in the factory (?) is 0.001 to 2 parts by weight, preferably 0.005 to 1.5 parts by weight, and particularly preferably in the range of 0.01 to 1 part by weight. As the agent, a phenol-based stabilizer having a known structure used in a polypropylene composition can be used without particular limitation. Specifically, the following compounds can be used. ~ Examples are: 2, 6, 2 and 3 Butyl-p-cresol, 2,6-di-tert-butyl-4 monoethylphenol, 2,6-dicyclohexyl-p-cresol, 2,6-diisopropyl-4 monoethylphenol, 2, 6 —Di-tertiary pentyl cresol, 2,6-di-tertiary octyl-4—n-propanol, 2,6-bicycloethyl-4—n-octyl phenol, 2-isopropyl—4— Methyl-6-Third-Butylphenol, 2-Third-Butyl-4-Ethyl-6-Third-Octylphenol, 2-Isobutyl-4-Ethyl-6-Third Hexylphenol, 2-Cyclic Hexyl-4, n-octyl-6, propofol, acrylic acid 2-third butyl-6 (3-thirdbutyl-5'-methyl-2'hydrobenzyl) 4-methylbenzene Ester, tert-butyl hydrogen, 2,2-methylenebis (4 Methyl-6-Third-Butylphenol), 4,4, monobutylidene (3-methyl-6-Third-Butylphenol), 4,4, monothiodi (3-Methyl-6-Third) Butyl phenol), 2, 2, monothiodi (4-methyl-1, 6-tertiary butylphenol), 4, 4, monomethylene bis (2, 6-tertiary butyl phenol), 2, 2, Monomethylene di [6— (1 -37- This paper size applies to Chinese National Standards (CNS) A4 specifications (210X 297 mm) (Please read the precautions on the back before filling in this page)) Masquerading,, tr Φ 518352 A7 B7 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (%) monomethylcyclohexyl) p-cresol], 2,1-ethylenedi (4, 6-di-tert-butylphenol ), 2,2 'monobutylene di (2-third butyl pair I age), 1, Γ, 3-tris (2-methyl-4, hydroxy-5, tertiary butadiene) Ding Yuan, Triethylene glycol 1,2 [3,3- — (3-Third-butyl-5—methyl-4 4-hydroxyphenyl) propionate], 1,6-hexanediol bis [3-(3 , 5-di-tert-butyl-4 monohydroxybenzene) propionate], 2,2-thiodiethyl Di [3- (3,5-di-third-butyl-4-hydroxyphenyl) propionate], n-octadecyl-3- (3 ', 5 > -di-third-butyl-4'- Hydroxyphenyl) propionate, N, N 'hexamethylene bis (3,5'-di-third butyl-4 4-hydroxy-monophenylpropionamide), 3,5-di-third butyl -4-hydroxybenzyl phosphonate-diethyl ester, 1,3,5-tris (2,6-dimethyl-3-hydroxy-4-tert-butylbenzyl) black urate, 2, 4,1,2 (n-octylsulfur) -6- (4-monohydroxy-3,5-di-tert-butylaniline) -1,3,5-triazine, tetrakis [methylene-3— (3 , 5-Di-tertiary-butyl-4 monohydroxyphenyl) propionate] methane, Di (3,5-di-tertiary-butyl-4 monohydroxybenzyl sulfonate) calcium, Di (3,5 — Di-tert-butyl-4 monohydroxybenzyl sulfonate) Nickel, N, N′-di [3,5-Di-tert-butyl-4 monohydroxyphenyl] propionate] M, 2, 2 '-Methylene bis (4-methyl-6-tert-butylphenol) titanate, 1,3,5-trimethyl-1,2,4,6-tri (3,5 —Di-tert-butyl-4 4-hydroxybenzyl) benzene, 3,9-di [1,2,1-dimethyl-2 — {3-(3-tert-butyl-4 4-hydroxy-5 —methyl Phenyl) -3 8-This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Bureau A7 B7 V. Description of the invention (from) Propyloxy} ethyl] -2,4'8 · 1104-spiro [5,5] Eleventh Hospital, 2,2,12 [4-mono {2- (3,5-di-tertiary-butyldihydroxybenzene_propanyl)) ethoxyphenol] propane, β- (3,5-di-tertiary-butyl 4-hydroxyphenyl ) Alkyl propionate and so on. Among them, 2,6-di-tert-butyl-p-cresol and tetrakis [methylene-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] methyl are particularly preferred. Burning, n-P octadecyl- 3-(3,5 '-2-third butyl-1-hydroxyphenyl) propionate, 2-3-butyl-6-(3, 3-butyl A 5'-methyl-2'-hydroxybenzyl group) a 4-methylphenyl acrylate, a 2,2'-ethylene (4,6-di-tert-butylphenol), etc. A phenolic stabilizer can be used alone or in combination. In the present invention, a phosphorus-based antioxidant is blended as a high-melt tension and high crystallization temperature during molding of a polypropylene composition for the present purpose, heat-oxidative degradation resistance, heat resistance, and one-color prevention properties of a molded product. . The compounding amount is, in terms of the level of performance exhibited by the polypropylene composition of the present invention, and the level of the cost of the antioxidant, relative to the polypropylene composition (PP) of the component (A) of 100 parts by weight, which is (KG01 ~ 2) The weight part is preferably from G.005 to 1.5 parts by weight, particularly preferably 0.01 to 1 part by weight. As a phosphorus-based antioxidant, a conventional phospholipid antioxidant used in a polypropylene composition can be used without special restrictions, specifically The compounds listed below can be used, and these phosphorus-based antioxidants can undoubtedly be used alone or in combination of two kinds of K. -39- The standard of this paper is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297)装) ▼ Loading-(Please read the notes on the back before filling this page) Order printed by the Central Consumers Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives 518352 A7 B7 V. Description of the invention (β) 4 1,2 third butyl phenyl) 4, 4, 4 'phenyl secondary phosphonate, tetra (2, 4 1,2 third pentyl phenyl T 4 4 ν 4' -diphenyl Primary and secondary phosphonates, tetrakis (2,4-dibutyl-5methylphenyl) -4 * 4 ' Primary phenyl secondary secondary phosphonate, tetrakis (2,6-di-tertiarybutyl-4 monomethylphenyl) -4,4 ^ secondary phenyl-secondary phosphonate, tetrakis ( 2,6-di-tert-butyl-1, 4-n-octadecyloxycarbonylethyl-phenyl) -4, 4 ', secondary phenyl, secondary phosphonate, tetrakis [2,6-di Tributyl-1, 4-((2,, 4'-di-tert-butylphenoloxocarbonyl) -phenyl] -4,4'-diphenyl, secondary phosphonate, tetra (2,6- Di-tert-butyl-1, 4-n-hexadecyloxycarbonyl-phenyl) -4,4'-secondary phenyl-secondary phosphonate, di [2,2'-methylene-bis (4 Monomethyl-6-third butylphenyl)]-4,4 'secondary phenyl-secondary phosphonate, di [2,2'-methyl-2 (4,6-2-3 Butylphenyl]] -4,4, primary phenyl, secondary phosphonate, di [2,2, monoethylene bis (4-methyl-6-third butylphenyl) ] One 4,4 'primary phenyl secondary secondary phosphonate, two [2,2' one ethylene one two (4,6-di-tert-butylphenyl)] one 4,4 Secondary phenyl-secondary phosphonates, such as secondary phenyl-secondary phosphonates, such as catechin-2,6-di-third-butyl-4 monomethylphenylphosphite, Theaminyl 2,4,6-tritributylphenyl phosphite, α-naphthylcatechol phosphite, 2,2'-methylenebis (4-methyl-6-third Butylphenyl) 2-naphthylphosphite, 4,4 '-4 0-This paper size applies to China National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the notes on the back before filling (This page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (f) f-Butylene-1 (3-methyl-6-third-butylphenyl-12tridecylphosphite) , 1, 1, 3, 3-tris (2-methyl-4, 112-tridecylsulfonate, 5-tributylphenyl) butane, trilauryl trithiophosphite, 316 Alkyl trithiophosphite, 9,10-dihydro-9 dioxa-1 10-phenanthrene ne 10-oxide, 10-hydroxy-1 9,10-dihydro-9 9-oxa-1 10- Phosphophenanthrene 10-oxide, triphenylphosphite, tris (nonylphenyl) phosphite, tris (2,4-dinonylphenyl) phosphite, tris (mono, dinonylbenzene) Group) phosphite, tris (2,6-di-tert-butyl-4 methylphenyl) phosphite, etc .; such as distearyl-pentaerythritol-diphosphite, diphenyl, pentaerythritol-two Phosphite, bis (nonylphenyl) -pentaerythritol-diphosphite, bis (2,4-bis-third butylphenyl) pentaerythritol-bis-phosphite, bis (2,4-two-three Phenyl) pentaerythritol-diphosphite, bis (2,4-dicumylphenyl) pentaerythritol-diphosphite, bis (2,4-di-tert-butyl-5-methylbenzene Group), pentaerythritol-diphosphite, bis (2,6-di-tertiary-butyl-4 monomethylphenyl) pentaerythritol-di-phosphite, bis (2,6-di-tertiary butyl-4) S-butylphenyl) pentaerythritol diphosphite, di 4, 4, 6-tri-tertiary butyl phenyl) pentaerythritol mono-diphosphite, bis (2, 4 '6-tri-tertiary pentyl phenyl) ) Pentaerythritol-diphosphite, bis (2'6-di-tert-butyl-4, n-octadecyloxycarbonylethyl-phenyl), pentaerythritol-diphosphite, di [2,6-di Tributyl-1 4 -4 1-This paper size is in accordance with Chinese National Standard (CNS) A4 (21〇x 297mm) (Please read the precautions on the back before filling this page). Φ 518352 Α7 Β7 Economy Printed by the Consumers' Cooperatives of the Ministry of Standards and Standards Bureau (Please read the notes on the back before filling this page)

V. Description of the invention (41)-(2, 4, 4, tetraol-diphosphite alkyl chlorocarbonyl-benzene-diphosphite; tetra (2,4 1 »dimethyl-1 2 2 [5 ♦ 5] Decapentyl) -3,9 2,4,8,1 acid ester, tetrakis (2,9-bis (1,1 1-10 tetraoxaspirospirate), 4,6-tris-methyl-1 2-hydroxyethyl ♦ 5] Η--Yunyi phenyl)-3, -2,4,8, phosphate, tetra (2-ylethyl-phenyl) ethyl) -2,4 diphosphite, tetra 'one Di-tert-butyl, 1-dimethyl-tert-tert-butylphenoloxy ester, bis (2,6-diyl) pentaerythritol-tert-1,2-tert-butylphenyl) monohydroxyethyl) One 2,4 one alkane diphosphite, -di (1,1 one dimethyl 〇4-tetraspirospira [5 · 6-two third butyl-4 dimethyl-2-hydroxyethyl [5 ♦ 5] Undecane-tributylphenyl) -3, yl) -2,4,8, diphosphite, tetrakis (2 9-bis (1,1-12 1 0—tetraoxaspiro [ 5,6-di-tertiary-butyl-1,3,9-di (1,, 8,10-tetraoxa [2,6-di-tert-butylphenoloxycarbonyl) -phenyl 2-hydroxy A) 2, -42-carbonyl) monophenyl] pentaerythritol 4-pentaerythritol, pentaerythritol, etc.-3 9 9-bis (1 8 > 1 0-tetraoxatetra (2 4 — Two third groups — 2 monohydroxyethyl) — 5] undecylimethylene (monomethylphenyl) — 3 groups) one 2 9 4 * 8, diphosphites Λ tetra (2 9 one two ( 1 1 1,2 1 0 tetraoxaspiro [5 f 4 9 6 -tri-tert-pentylmethyl- 2 -hydroxyethyl) ♦ 5] undecane-diene 4 -n-octadecylcarbonyl 1 1 Dimethyl-2 — hydroxy [5 * 5] undecaneyl — 4 — (2 f 9 4] — 3 $ 9 one two (1 4 8 $ 1 〇 one four oxygen) This paper size applies Chinese national standards ( CNS) A4 specification (210X297 mm) 518352 A7 B7 V. Description of the invention (W) Heterospiro [5 ♦ 5] Undecane diphosphite, tetrakis (2,6-di-tert-butyl-4, 1-n Hexadecyloxycarbonyl-phenyl) -3,9-di (1,1-dimethyl-2-hydroxyethyl) -2,4,8,10-tetra Oxafluorene [5 * 5] undecane-diphosphite, di [2,2'-methylene-di (4-methyl-6-third-butylphenyl)]-3,9- Bis (1,1, dimethyl-2, hydroxyethyl) -2,4,8,1 0-tetraoxafluorene [5 · 5] undecane-diphosphite, di [2, 2 ' Monomethylene-bis (4,6-di-tert-butylphenyl)]-3,9-di (1,1-methyl-2-hydroxyethyl) -2,4,8,101 Tetraoxafluorene [5 · 5] undecane diphosphite, di [2, 2 'monomethylene dibis (4,6-ditripentylphenyl)] 3, 9 — di (1,1 dimethyl-2 2-hydroxyethyl) -1,2,4,8,10-tetraoxaspiro [5 · 5] undecane-diphosphite, di [2,2'-1 Ethylene di (4-methyl-6-third butylphenyl)] 3,9 di (1,1 dimethyl-2 2-hydroxyethyl) -2,4,8,10 -Tetraoxaspiro [5 · 5] undecane diphosphite, di [2,2 'monoethylene di (4,6-di-tert-butylphenyl) Employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by Fei Cooperative (please read the precautions on the back before filling this page)] 3,9 12 (1,1 dimethyl-2 2-hydroxyethyl) -2, 4, 8, 10-4 Oxaspiro [5 ♦ 5] undecane-diphosphite, di [2,2'-ethyleneethylene-di (4,6-di-tertiarypentylphenyl)]-3,9-two ( 1,1,2-dimethyl- 2-hydroxyethyl)-2,4,8,10-tetraoxaspiro [5 ♦ 5] Undecane diphosphite, etc. [5 ♦ 5 〕 Undecane diphosphite; -43- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 518352 A7 B7 5. Description of the invention (J) Such as 2, 2 'one two ( 4,6-di-tert-butylphenyl) octylphosphite, 2,2'-bis (4,6-di-tert-butylphenyl) nonylphosphite, 2,2'-di ( 4,6-di-tertiary-butylphenyl) lauryl phosphite, 2,2 'di- (4,6-di-tertiary-butylphenyl) tridecyl phosphite, 2, 2, 1, 2 (4,6-di-tert-butylphenyl) myristyl phosphite, 2,1,2 Phenyl) stearyl phosphite, 2,2'-bis (4,6-di-third-butylphenyl) (2,4-di-third-butylphenyl) phosphite, 2,2 '—Bis (4,6-di-tert-butylphenyl) (2,6-di-tert-butyl-4 monomethylphenyl) phosphite, 2,2'-di (4,6-di Tert-butylphenyl) (2,4,6-tri-tert-butylphenyl) phosphite, 2,2 'bis (4,6-tri-tert-butylphenyl) (2,6- Di-Third-Butyl-4 4-n-octadecyloxycarbonylethyl-phenyl) [2,6 — Di-Third-butyl-4 4- (2, 4, 4 '12th) Consumption by Staff of the Central Standards Bureau Printed by the cooperative (please read the notes on the back before filling in this page) Tributylphenoloxycarbonyl) Monophenyl] Phosphite, 2,2 'bis (4,6-Di-tert-butylphenyl) ) (2,6-Di-tertiary-butyl-4,4-n-hexadecyloxycarbonyl-phenyl) phosphite, etc. Phosphate esters; such as 2, 2'-methylene-bis (4-methyl-6-third-butylphenyl) octyl phosphite, 2 Monomethylene-bis (4-methyl-6-tert-butylphenyl) nonyl phosphite, 2,2'-methylene-bis (4-methyl-6-tert-butylbenzene) Based) lauryl phosphite, 2,2'-methylene-bis (4-methyl-6-third-butylphenyl) -4 4-This paper size applies to China National Standard (CNS) A4 specifications ( 210X 297 mm) 518352 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (i) Tridecylphosphite, 2,2'-methylene-bis (4-methyl-1 6-1 Third butylphenyl) myristyl phosphite, 2,2'-methylene-di + Γ4 -methyl-6-third-butylphenyl) stearyl phosphite, 2,2 ' Monomethylene-bis (4-methyl-6-third-butylphenyl) (2,4-bis-third-butylphenyl) phosphite, 2,2'-methylene-bis (4 Monomethyl-6-tert-butylphenyl) (2,6-di-tert-butyl-4 monomethylphenyl) phosphite, 2,2 'monomethylene-di (4-methyl 6-Third-butylphenyl) (2 * 4, 6-Third-butylphenyl) Phosphate, 2,2'-methylene-bis (4-methyl-6-third-butylphenyl) (2,6-di-third-butyl-4-n-octadecyloxycarbonylethyl Monophenyl) phosphite, 2,2'-methylene-bis (4-methyl-6-third-butylphenyl) [2,6-di-third-butyl-1-4- (2 #, 4'-di-tert-butylphenoloxycarbonyl) -phenyl] phosphite, 2,2'-methylene-di (4-methyl-6-third-butylphenyl) (2,6 —Di-tert-butyl-1, 4-n-hexadecyloxy-phenyl) phosphite, etc. 2 »2'-methylene-di (4-methyl-6-tert-butylphenyl) Phosphate. Such as 2,2'-methylene-bis (4,6-di-third-butylphenyl) octylphosphite, 2, -methylene-bis (4,6-di-third-butylphenyl) ) Nonyl phosphite, 2,2 'monomethylene di (4,6-third-butylphenyl) lauryl phosphite, 2,2' monomethylene di (4 * 6- Di-tert-butylphenyl) tridecylphosphite, 2,2'-methylene-di (4,6-di-tert-butylphenyl) nutmeg-45- (Please read the note on the back first Please fill in this page again for the items) ▼ Packing-•} 1τί-- Φ! This paper size applies to China National Standard (CNS) Α4 size (210 X 297 mm) 518352 Printed by A7 B7, Employee Consumer Cooperative of China Standards Bureau, Ministry of Economic Affairs V. Description of the invention (d) Phosphite, 2,2,1-methylene-bis (4,6-di-tert-butylphenyl) stearate, 2,2; -methylene- Bis (4,6-tributylene-benzene ^) (, 4,1,2tributylphenyl) phosphite, 2,2,1-methylenebis (4,6-ditributyl) Phenyl) (2 * 6-di-tert-butyl-4-methylphenyl) phosphite, 2, 2 ' Monomethylene-bis (4,6-di-third-butylphenyl) (2, 4'6-tri-third-butylphenyl) phosphite, 2,2'-methylene-bis (4 , 6-Di-tertiary-butylphenyl) (2,6-Di-tertiary-butyl-1, 4-n-octadecyloxycarbonylethyl-phenyl) phosphite, 2, 2, 1-methylene-1 Bis (4,6-di-tert-butylphenyl) [2,6-di-tert-butyl-1-4- (2,, 4,2-tert-butylphenoloxycarbonyl) -phenyl] phosphorous acid Ester, 2,2,1-methylene-bis (4,6-di-third-butylphenyl) (2,6-di-third-butyl-4-n-hexadecylidene-phenyl) 2,2'-methylene-bis (4'6-di-tert-butylphenyl) phosphite, such as phosphate esters; such as 2,2,1-methylene-di (4,6-2-3rd Amylphenyl) octylphosphite, 2,2,1-methylene-bis (4,6-di-third-pentylphenyl) stearyl phosphite, 2,2'-methylene-1 Bis (4'6-di-third-pentylphenyl) (2,4-di-tert-butylphenyl) phosphinate, 2,2, -methylene-di (4,6-di- Tripentylphenyl) (2,6-di-third-butyl-4-methylphenyl) phosphite, 2,2'-methylene-bis (4,6-di-third-pentylphenyl) ) (2'4,6-tri-tertiary-pentylphenyl) phosphite, 2,2,1-sub-46- This paper scale is applicable to China National Standard (CNS) Λ4 specification (210X 297 mm) ( Please read the precautions on the back before filling in this one hundred ▼. Order Φ 352352 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (^) Phenyl) (2,6-di-tert-butyl-4, n-octadecyloxycarbonylethyl-phenyl) phosphite, 2,2-methylene-bis (4,6-di Tripentylphenyl) [2,6-di-tertiary-butyl 4- (2, 4, 4'-tertiary-butyl phenoloxycarbonyl) -phenyl] phosphite, 2, 2 ' Methyl-bis (4,6-di-tertiary-pentylphenyl) (2,6-di-tertiary-butyl-4-n-hexadecyloxycarbonyl-phenyl) phosphite, etc. A methylene-bis (4,6-di-third-pentylphenyl) phosphite; such as 2 2,1-ethylenedi (4-methyl-6-third-butylphenyl) octylphosphite, 2,2'-ethylene-2 (4-methyl-6-third-butyl) Phenyl) nonylphosphite, 2,2'-Ethylenebis (4-methyl-6-third-butylphenyl) laurylphosphite, 2,2,1-Ethylene-12 (4-monomethyl-6-third butylphenyl) tridecylphosphite, 2,2 'monoethylene dibis (4-monomethyl-6-third butylphenyl) myristyl Phosphite, 2,2'-ethylene-bis (4-methyl-6-third-butylphenyl) stearyl phosphite, 2,2'-ethylene-bis (4-methyl Phenyl-6-tert-butylphenyl) (2'4-tritert-butylphenyl) phosphite, 2,2,1-ethylene terephthalate (4-methyl-6-tert-butyl Phenyl) (2,6-di-third-butyl-4 monomethylphenyl) phosphite, 2,2, diethylene-bis (4-methyl-6-third-butylphenyl) (2,4,6-trit-butylphenylphosphonium) phosphite, 2,2,1-ethylene-6 (4-methyl-6-tert-butyl) (Phenylphenyl) (2, 6 —Di-tert-butyl-1, 4-10—47-) This paper (please read the precautions on the back before filling out this page) Preparation 518352 A7 B7 V. Description of the invention (M) octaalkoxycarbonylethyl-phenyl) phosphite, 2,2'-ethylene-bis (4-methyl-6-third-butylphenyl) ) [2,6-Di-tertiary-butyl-4 4- (2,4'-tertiary-butyl phenoloxyfluorenyl) -phenyl] phosphite, 2,2,1-ethylene-2 (4-methyl-6-tert-butylphenyl) (2,6-di-tert-butyl-4-n-hexadecyloxycarbonyl-phenyl) phosphite, etc. Ethyl-bis (4-methyl-6-tert-butylphenyl) phosphite. Such as 2,2: -Ethylene-bis (4,6-di-tert-butylphenylphosphonium) octylphosphite, 2,2'-Ethylene-bis (4 * 6-di-tert-butyl) Phenyl) nonylphosphite, 2,2 'monoethylenedi (4,6-di-tert-butylphenyl) lauryl phosphite, 2,2' monoethylenedi ( 4,6-di-tert-butylphenyl) tridecylphosphite, 2,2'-ethylene-di ((4,6-di-tert-butylphenyl) myristyl phosphite, 2 , 2'-ethylene-bis (4,6-di-tert-butylphenyl) stearyl phosphite, 2,2'-ethylene-bis (4,6-di-tert-butylbenzene) (), (2,4-di-tert-butylphenyl) phosphite, 2,2'-ethylene-di ((4,6-di-tert-butylphenyl)) (2,6-di-tert-butyl) Butyl-4,4-methylphenyl) phosphite, 2,2'-ethylene-bis (4,6-di-tert-butylphenyl) (2,4,6-tri-tert-butylphenyl) Phenyl) phosphite, 2,2'-ethylene-bis (4,6-di-third-butylphenyl) (2,6-di-third-butyl-4-n-octadecyloxycarbonyl) Ethyl-phenyl) phosphite, 2,2,1-ethylene-bis (4,6-di-tert-butylphenyl) [2,6 _ 4 8-Chinese paper standard (CNS) ) M size (210X 297 mm) (Please read the precautions on the back before filling this page) > Install · l · order 518352 A7 B7 (Please read the precautions on the back before filling this page) Central Bureau of Standards, Ministry of Economic Affairs Printed by the Employee Consumer Cooperatives 5. Description of the invention 2 ') Octylphosphite tripentylphenyl) Hard 4, 6 -disecondary phosphite, 2, phenyl) (2,4 2' Monoethylene-mono-second butyl monoacid Esters, 2,2 ') [2,6-diylphenoloxycarbonyl) bis (4,6-di-4-n-hexadecyloxyethylene-bis (4) such as 2,2'-based phosphites, 2 groups) Nonylphosphite butylphenyl) Laurel 4 1 (2 9% 4 T monophosphate, 2 2 f —yl) 2 6 1 2 3) Phosphite, etc. 2 9 Butylphenyl ) phosphoric acid Monoethylene — bis (4 2 5 2 t monoethylene fatty phosphite 2 9 pentylphenyl) (2 9 4 2 ψ — ethylene — bis (9 6 -triamylbenzene Di (4 6 one two second 4 one n-octadecyloxycarbonyl monoethylene — di (4 third butyl 1 4 1 (2-phenyl) phosphite, third pentylphenyl) ( 2 carbonylcarbonyl-phenyl) phosphorous 9 6 one third pentylbenzene — sulfur — bis (4 6 one> 2 f one m — bis (4 ester 2 > 2 f — thiomonophenyl phosphite, 2 9 2 -49- di-tert-butylphenoloxycarbonylethylene di (4,6 butyl-1 4 n-hexadecyl 2 ^ -ethylene di (

I 6 -di-tertiary pentylphenyl bis (4,6-di-second 2'-ethylene terephthalate (1,2-tertiary pentylphenyl) 4,6-di-tertiary pentyl) phosphorous acid Ester, 2, pentylphenyl) (2,6-ethylethyl-phenyl) phosphorous 6-di-tertiary-pentylphenyl, 4,1,2-tertiary-butane 2,2'-ethyleneidene-1, 2,2 -′- tertiary butyl monoester, etc. 2,2′-mono) phosphite; 2-tert-butylphenyl) octane, 6-tertiary-butylbenzene di (4,6—tertiary , 1 ethylene 1 2 (4 paper scales applicable to Chinese National Standards (CNS) Λ4 specifications (210X 297 mm) 518352 A7 • B7 V. Description of invention (A) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 6 — di-second butylphenyl) tridecylphosphite Λ 2 2 9 monothiodi (4 6 -dibutyl butylphenyl) myristyl m-based phosphite 2 2, —thiodi-2 (4 6 —Di-tert-butylphenyl) stearyl phosphite Λ 2 9 2 9 Monosulfide (4 f 6 -tert-butylphenyl) (2 4 -tert-butylphenyl) Phenyl) Phosphite 2 > 2, Monosulphur di (4 $ 6 Di-tert-butylphenyl) (2 6 Tri-tert-butyl 4- 4-methylphenyl) Phosphite Λ 2 2 monosulfide — bis (4 9 6 bis tertiary butylphenyl) (2 $ 4 6 bis tertiary butylphenyl) phosphite 2, 2 — — ethylene — bis (4 $ 6 — Bis-tert-butylphenyl) (2 9 6-bis-tert-butyl-4-n-octadecyloxycarbonylethyl-phenyl) phosphite Λ 2 9 2 9-sulfur-bis (4 6 a Di-tert-butylphenyl) C 2 5 6 — Di-tert-butyl-4 4- (2 f 4 t bis-tert-butylphenoloxycarbonyl) —phenyl] phosphite 2 3 2, — sulfur — Bis (4 3 6 bis third butyl) 2 > 6 bis second butyl-1 4 —n-deca-pyrene is alkoxycarbonyl monophenyl) phosphite 2 j 2 9 — sulfur — Di (4 6 — Di-tert-butylphenyl) Phosphite 9 such as 2 5 2 f Di (4 > 6 — di-second butylphenyl) fluorophosphite 2 y 2, bis (4- methyl-1 6-second butylphenyl) fluorophosphite Λ 2 2, — di (4-third Butyl-6-methylphenyl) fluorophosphite 2 2 —bis (4 -S —fluorenylphenyl) fluorophosphite 2 2 — —methylene-bis (4 —methyl-1 6 — Dibutylphenyl) fluorophosphite 9 2 t 9 2, —methylene — bis (4 -ethyl-6-third butylphenyl) fluorophosphite 2 2 $ monomethylene-50- (Please read the precautions on the back before filling out this page) # This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 518352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (β) Base 1 2 (4 1 ethyl 1 6 -non Phenyl) fluorophosphite, 2,2'-methylene-bis (4,6diphenyl) fluorophosphite, 2,2'-HI-bis (4-methyl-6-cyclohexyl Phenyl) fluorophosphite, 2,2'-methylene-bis (4-methyl-6- (1,1-methylcyclohexyl) phenyl) fluorophosphate, 2,2'-isopropylidene Bis (4-nonylphenyl) fluorophosphite, 2,2'-butylene di (4,6-dimethylphenyl) fluorophosphite, 2,2'-methylene bis (4,6-di-tertiary-butylphenyl) fluorophosphite, 2,2'-methylene-bis (4,6-di-tertiary-pentyl ~ phenyl) fluorophosphite, 2,2 '' Monoethylene di (4-monomethyl-6-third-butylphenyl) fluorophosphite, 2,2, monoethylene di-2 (4-ethyl-6-third butylbenzene) Group) fluorophosphite, 2 * 2'-ethylene-bis (4-S-butyl 6-Third-butylphenyl) fluorophosphite, 2,2'-ethylene-bis (4,6-di-third-pentylphenyl) fluorophosphite, 2,2'-methylene Bis (4-methyl-4-6-octylphenyl) fluorophosphite, 2,2T-butylene-bis (4-methyl-6- (1'-methylcyclohexyl) phenyl ) Fluorous phosphite, 2,2'-methylene-bis (4,6-dimethylphenyl) fluorophosphite, 2,2'-thio-bis (4-third octylphenyl) Fluorophosphite, 2,2 'monothiodi (4, 6-diisooctylphenyl) fluorophosphite, 2,2' monothiodi (4,6-diisooctylphenyl) Fluorophosphite 2,2'-thiodi (5-third-butylphenyl) fluorophosphite, 2,2'-thio-bis (4-methyl-6-third-butylphenyl) Fluorophosphite, 2, 2 '—Sulfur-5 1- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ▼ Equipment · Printed by Φ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 * B7 V. Invention Ming (4) bis (4-monomethyl-6-α-methylfluorenylphenyl) fluorophosphite, 2,2 'monothiodi (3-methyl-4,6-di-tert-butyl Phenyl) fluorophosphinophosphate, 2,2'-thio-bis (4-third-pentylphenyl) fluorophosphite, etc .; such as di [2,2'-methylene-one Di (4,6-di-tert-butylphenyl)] monoethylene glycol-diphosphite, di [2,2'-methylene-di (4,6-di-tert-butylphenyl) ] -1,4-butanediol-diphosphite, di [2,2'-methylenebis (4,6-di-tert-butylphenyl)]-1,6- ~ hexanediol Bisphosphite, bis [2,2'-methylene-bis (4-methyl-6-third-butylphenyl)] 1-3,9-bis (1,1 dimethyl-2 — Hydroxyethyl) -2,4,8,10-tetraoxafluorene [5 ♦ 5] undecane-diphosphite, di [2,2'-methylene-bis (4,6--2 Third butyl phenyl]] 3,9 bis (1,1 dimethyl-2 2-hydroxyethyl) -2, 4, 8, 10-tetraoxaspiro [5 ♦ 5] eleven Bisphosphite, bis [2,2'-methylenebis (4,6-di-tertiarypentylphenyl)], 3,9, bis (1,1, dimethyl-1, 2-hydroxy Ethyl) 2, 4, 8 * 1 0 —tetraoxaspiro [5 ♦ 5] undecane-diphosphite, di [2,2'-ethylene-diethylene (4-methyl-6— Di-tert-butylphenyl)] -3,9 -di (1,1 -Dimethyl-2 -hydroxyethyl) -2,4,8,10 -Aza [5,5] 11 Alkane-diphosphite, di [2,2'-ethylene-bis (4,6-di-tert-butylphenyl)]-3,9-di (1,1-methyl-2-hydroxy Ethyl-52- This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page) Printed 518352 A7 B7 V. Description of the invention (W))-2-4, 8, 10-tetraoxaspiro [5 ♦ 5] undecane-diphosphite, di [2, 2'-methylene Bis (4,6-di-tert-butyl H)]-N, N '-(2-hydroxyethyl) curoxamine Diphosphites such as diphosphites; such as tris [2,2'-methylenebis (4,6-di-tert-butylphenyl)] monoglycerol-trisphosphites, tris [2,2'-methylene-bis (4,6-di-tert-butylphenyl)]-trimethylolethane-trisphosphite, tris [2,2'-methylene-bis ( 4,6-di-tert-butylphenyl)]-trimethylolpropane-triphosphite, tris [2,2'-di (4,6-di-tert-butylphenyl)]-triethanolamine- Triphosphite, tris [2,2'-bis (4,6-di-tertiarypentylphenyl)]-triethanolamine-trisphosphite, tris [2,2'-methylene-bis (4,6 .  -Di-tert-butylphenyl)]-triethanolamine-triphosphite, tris [2,2'-methylene-di (4,6-di-third-pentylphenyl)]-triethanolamine-trisphosphite Ester, tris [2,2'-ethylenedi (4,6-di-tert-butylphenyl)]-triethanolamine-trisphosphite, tris [2,2,1-ethylene-di (4 , 6-di-tertiary-pentylphenyl)]-triethanolamine-trisphosphite, tris [2 * 2'-methylene-bis (4,6-di-tert-butylphenyl)]-N, N ,, N "-tris (2-hydroxyethyl) black urethane-tris-phosphite and other tri-phosphites; such as tetra [2,2'-methylene-bis (4,6-di-tert-butylbenzene) Based)] tetrabutanol-tetraphosphite, tetra [2,2, monomethylene-di (4,6-di-tert-butylphenyl)]-pentaerythritol-tetraphosphite-53- this paper Standards are applicable to China National Standard (CNS) A4 specifications (210X 297 mm) (Please read the notes on the back before filling out this page). Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. (^) Acid ester, (2,4,2,3,3-butyl-6-methylphenyl) ethyl phosphite, bis (2,4,2,3,3,3-butyl-6-methylphenyl) 2, 1-ethylhexyl Phosphate ester, bis (2,4-tributylbutyl-6-methylphenyl) stearyl phosphite, 2,4,6-tritributylbutyl-2 -ethyl-2-butyl Molybdenum 1, 3-propionate, etc. In the composition of the present invention, antioxidants other than the above-mentioned phosphorus-based antioxidants can be used in combination as long as the purpose of the present invention is not impaired. As such antioxidants, there may be mentioned Examples are conventional phenolic antioxidants or sulfur-based antioxidants used in polypropylene compositions. Examples of sulfur-based antioxidants include dimyristoylthiodipropionate, distearylsulfide Propionate, lauryl stearatethiodipropionate, dilaurylstearylthiodipropionate, pentaerythritol tetrakis (3-laurylthiopropionate, octacosyl, distearyl Thiodibutyrate, etc. These phenol-based and sulfur-based oxidants can be used alone or in combination of two K. The blending amounts of these antioxidants are respectively Relative to 100 parts by weight of the polypropylene composition, it was 0. 001 ~ 1. 5 parts by weight, 亘 is 0. 005 to 1 part by weight, particularly 0 · 0 1 to 0 · 0 5 parts by weight. In the composition of the present invention, various stabilizers other than the above-mentioned stabilizers may be added and used in combination within the scope of the present invention without impairing the purpose of the present invention. As such a stabilizer, it can be practically used to capture the catalyst residue halogen in polypropylene used in the present invention and the finished product. -54- This paper size applies Chinese national standards (CNS) A4 specification (210X 297 mm) (Please read the notes on the back before filling in this page) Packing and ordering 518352 Α7 Β7 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (0) Halogen trapping agent. By using the halogen trapping agent, the thermal stability, odor, hue, corrosion resistance, weather resistance, and the like of the composition of the present invention can be further improved. As the halogen trapping agent, fatty acid metal rhenium, metal alkyl alkanoate metal rhenium, fatty acid metal hydroxy acid rhenium, hydrogenated talc lithium aluminum complex hydroxide 塩, metal oxide, metal hydroxide, metal carbonate rhenium, aliphatic phosphoric acid can be used. Metal fluorene, epoxy compounds, aliphatic amines, aliphatic fluorene amines, hindered amine fluorene compounds, aminotriazine-based compounds, and the like. Specific examples of the halogen trapping agent are shown below. Acetic acid, propionic acid, acetic acid, valeric acid, C (monomethyl butyric acid, hexane acid, sorbic acid, octanoic acid, 2-ethyloctanoic acid, nonanoic acid, hexenoic acid, undecanoic acid, Undecylenic acid, lauric acid, lindruic acid, myristic acid, faseic acid, myristic acid, palmitic acid, palmitic acid, ferracic acid, stearic acid, petrolic acid, oleic acid, trans Oleic acid, rosanoic acid, bakusolic acid, linoleic acid, α-tongic acid, yS-tongic acid, punicic acid, linolenic acid, 7-linolenic acid, octacosatetraenoic acid, 4, 8, 12 , 15-octadecatetraenoic acid, stearynic acid, arachidic acid, saponic acid, amantholic acid, arachidonic acid, shankidic acid, cetyl acid, erucic acid, pasenoic acid, succinic acid, Metal hydrazones of fatty acids such as tetraalkanoic acid, sharkic acid, linoleic acid, wax acid, behenylic acid, octadecanoic acid, melic acid, luinequeic acid, etc .; such as dodecanedioic acid, tetradecanoic acid and Alkanes, such as lactic acid, metal of lactic acid, glycolic acid, lactic acid, hydrogenated acrylic acid, α-oxybutyric acid, propanoic acid, glyceric acid, malic acid, tartaric acid, middle tartaric acid, grapevine The paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the notes on the back before filling this page) Qin, ^ 1 # Printed by the Central Consumers Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 518352 A7 __; _ B7 V. Description of the invention (lat) acid, citric acid, 2-hydroxytetradecanoic acid, 3,1 1-dihydroxymyristic acid, 2-hydroxy-tetradecanoic acid, cerapinolulic acid, 桧Acid, amberglic acid T aleutidic acid, 2-hydroxytetradecanoic acid, 12-hydroxytetradecanoic acid, 18-hydroxytetradecanoic acid, 9, 10-hydroxytetradecanoic acid, M linoleic acid, Metal hydrazones of aliphatic hydroxy acids such as triconjugated bisphosphonium monohydroxyoctadecanoic acid, ricarilic acid, resorrel, cerebrocapric acid; metal hydrazones of alicyclic carboxylic acids such as metal naphthalate; benzoic acid, Metal sulfonium of aromatic carboxylic acids such as tertiary butyl benzoic acid; gold sulfonium of alicyclic hydroxy acids such as metal hydroxycaylic acid; salicylic acid, m-hydroxybenzoic acid, p-hydroxybenzoic acid , 3,5—Di-tert-butyl-4 monohydroxybenzoic acid and other metal fluorene acids; various gold amino acids Thallium hydride; Taluset hydrogen hydride; lithium aluminum complex hydroxides of basic aluminum monolithium-lithium-hydroxy-carbonate-hydrate and basic aluminum monolithium monohydroxy-hydroxide sulfate monohydrate, etc .; gold thorium oxide Metal hydroxides; metal rhenium carbonate; metal phosphate is; such as (one and two mixtures) hexyl phosphoric acid, (one and two mixtures) octyl phosphoric acid, (one and two mixtures) 2-ethylhexyl phosphate, (a , Two mixed) decyl phosphoric acid, (one and two mixed) lauryl phosphoric acid, (one and two mixed) myristyl phosphoric acid, (one and two mixed) palmitic phosphoric acid, (one and two mixed) stearyl phosphate, (One and two mixtures) oleyl phosphoric acid, (one and two mixtures) linoleic acid phosphoric acid, (one and two mixtures) linoleic acid phosphate, (one and two) fluorene dialkyl phosphoric acid, (one and two mixtures) scoop Catechol-based phosphoric acid, (one and two mixed) 廿 tetraalkylphosphoric acid, (one and two mixed) 烷基 hexaalkyl phosphate, -56- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm ) (Please read the precautions on the back before filling out this page) Printed by the Bureau ’s Consumer Cooperatives 518352 A7 B7 V. Description of the Invention (#) (Mixed with 1,2) 廿 Octyl phosphate 塩 and other metal phosphates of aliphatic phosphoric acid; bis (p-tert-butylphenyl) phosphate, Mono (p-to-third butylphenyl) acetic acid, 2,2'-methylene mono, bis (4,6-di-third butylphenyl) phosphonic acid, 2,2 'mono, methylene Bis (4,6-di-third-pentylphenyl) phosphoric acid, 2,2'-ethylene-bis (4,6-di-third-butylphenyl) phosphoric acid, 2,2'-ethylene Metal rhenium of aromatic phosphoric acid such as bis (4,6-di-tertiarypentylphenyl) phosphoric acid, etc .; diacid sulfuric acid; gland; suspicion; cyclic vinegar; organometallic compound; diphenylmethanol; epichlorine Condensate of alcohol and bisphenol A, condensate of 2-methylepichlorohydrin and bisphenol A, triglyceryl black urate, epoxidized soybean oil, epoxidized linseed oil, epoxidized castor oil, etc. Oxygen compounds; hydroxylamines such as octylamine, laurylamine, myristylamine, palmitoylamine, stearylamine, oleylamine, cocoamine, talamine, soyamine, N'N-dicocoamine, N'N-ditalo amine N, N-dimethyl soy amine, N-lauryl-N, N-dimethylamine, N-myristine M-based N, N-dimethylamine, N-palmityl-N, Ν-dimethylamine, Ν—stearyl-N, N—dimethylamine, N—coco—N, N—dimethylamine, N—taro—N, N—dimethylamine, N—soy—N, N, dimethylamine , N-methyl-N, N-di-taroamine, N-methyl-N, N, di-coco amine, N-oleyl-1, 3-diaminopropane, N-taro-1, 3- Diamine propane, hexamethylene diamine and other aliphatic amines; such as N chloride-lauryl-N, N, N-trimethylammonium chloride, N-57- ) A4 specification (2 丨 0 X 297 mm) (Please read the notes on the back before filling out this page) _Installation · Ordering and printing of employee cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (4 ) Palmyl-N, N, N-trimethylammonium, N-stearyl-N, N, N-trimethylammonium, N-fluorenyldialkyl-N, N, N-dimethylammonium, chloride N — coco — N, N, N — trimethylammonium, chlorine 1 ^ 一 1 & 1—〇—N, N, N—Trimethylammonium, N—soy—N, N, N—Dimethylammonium, N, N, N—Triethyl—N—Benzylammonium N—chloride—lauryl—N, N, dimethyl—N—benzyl ammonium, N—stearyl—N, N—dimethyl—N—benzyl ammonium, N—coco—N , N-Dimethyl-N-benzyl ammonium, N, N-Dioleyl-N, N-dimethyl ammonium, N, N-Dicoco-N, N-dimethyl ammonium, N , N — dicoco — N, N — dimethyl dichloride, N, N — di taro — N, N — dimethyl ammonium, nitrogen N, N — di soy — N, N — dimethyl ammonium, chloride N, N-bis (2-hydroxyethyl) -N-lauryl-N-methylammonium, N, N-bis (2-hydroxyethyl) -N-stearyl-N-methylammonium, chloride N, N-di (2-hydroxyethyl) -N-oleyl-N-methylammonium, N * N-di (2-hydroxyethyl) -N-coco-N-methylammonium, chloride N, N-di (polyethylene oxide) -N-lauryl-N-methylammonium, N, N-di (polyethylene oxide) -N-stearyl-N-methylammonium, chloride N , N—di (polyethylene oxide) —N—oil-based—N—methylammonium, N, N—di (polyethylene oxide) —N—coco—N—methylammonium chloride, etc. ; Such as N, N-bis (2-hydroxyethyl) lauryl betaine, N, N-bis (2-hydroxyethyl) tridecyl betaine, N, N-bis (2-hydroxyethyl) ) Myristyl betaine, N, N-di (2-hydroxyethyl-58-) This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X297 mm) (Please read the precautions on the back before filling (This page)-Packing · l · Ordering 518352 Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (钋)) Pentadecyl betaine, N, N-di (2-hydroxyethyl) palm Amino betaine, N, N-bis (2-hydroxyethyl) oleyl betaine, N, N-bis (2-hydroxyethyl) glycine amine betaine, N, N-di (2 1 Hydroxyethyl) glycolamine betaine, N, N-bis (2-hydroxyethyl) cocoaminobetaine, N, N-bis (dihydroxyethyl) taroaminobetaine, and other betaines ; Hexamethylenetetramine; such as triethanolamine, three Alkanolamines such as propanolamine; such as N- (2-hydroxyethyl) laurylamine, N- (2-hydroxyethyl) tridecylamine, N- (2-hydroxyethyl) myristylamine, N- (2-hydroxyethyl) pentadecylamine, N- (2-hydroxyethyl) fluorenedialkylamine, N- (2-hydroxyethyl) fluoroctylamine, N- (2-hydroxyethyl) cocoamine , N-(2-hydroxyethyl) taroamine, N-methyl-N-(2-hydroxyethyl) laurylamine, N-methyl-N-(2-hydroxyethyl) tridecylamine, 1 ^ Monomethyl-1 ^-(2-hydroxyethyl) myristylamine, N-methyl-N- (2-hydroxyethyl) pentadecylamine, N-methyl-N- (2-hydroxyethyl) Palmitoylamine, N-methyl-N- (2-hydroxyethyl) stearylamine, N-methyl-N- (2-hydroxyethyl) oleylamine, N-methyl-N- (2-hydroxyl Ethyl) fluorenedialkylamine, N-methyl-N- (2-hydroxyethyl) cocoamine, N-methyl-N- (2-hydroxyethyl) taroamine, etc. N- (2-hydroxyethyl Based) amines; such as N, N-bis (2-hydroxyethyl) laurylamine, N-N-bis (2-hydroxyethyl) tridecylamine, N, N-bis (2-hydroxyethyl) Ethyl) myristylamine, N, N-bis (2-hydroxyethyl) pentadecylamine, N, N-bis (2-hydroxyethyl) palmamine, N, N-bis (2-hydroxyethyl) Stearylamine, -59- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) • mi »* ιϋ_1 ϋ · — · nn · Installation l · Order 518352 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (A) N, N-Di (2-hydroxyethyl) oleylamine, N, N-Di (2-hydroxy Ethyl) fluorenedialkylamine, N, N-bis (2-hydroxyethyl) cocoamine, N, N-bis (2-hydroxyethyl) taroamine, N, N-di (2-hydroxyethyl) ) Aliphatic amines; these N, N-di (2-hydroxyethyl) aliphatic amines are fatty acids of lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, mangoic acid, erucic acid, etc. Mono- or diester; such as polyethylene oxide lauryl amine ether, polyethylene oxide stearyl amine ether, polyethylene oxide oleyl amine ether, polyethylene oxide coco amine ether , Polyethylene oxide taro-based amino ethers, etc. Ether; such as N, N, N ', N'-tetrakis (2-hydroxyethyl) -1,3-diaminopropane, N, N, N', N'-tetrakis (2-hydroxyethyl) -1,6-diaminohexane, N -lauryl-N, N '»N f -tris (2-hydroxyethyl) -1,3-diaminopropane, N-stearyl-N, N,, N, Tris (2-hydroxyethyl) _1,3-diaminopropane, N — coco-N, N,, N, Tris (2-hydroxyethyl) -1,3-diamine Propane, N — taro — N, N, N, tris (2 via ethyl) — 1, 3 —diaminopropane, N, N — di coco — N 'Ν — 1 (2-hydroxyethyl Group) -1,3-diaminopropane, Ν, Ν-di taro- η,, η, bis (2-hydroxyethyl) -1,3-diaminopropane, Ν-coco-Ν, Ν ,, N, tris (2-hydroxyethyl) -1,6-diaminohexyl, N-taro-N, N ', Ν'-tris (2-hydroxyethyl) -1,6-di Aminohexane, Ν, Ν-dicoco — Ν,, 1 ^ 1, 1,2 (2-hydroxyethyl) 1,6-diaminohexane, Ν, N —ditaro — Ν, N, 1,2 (2-Hydroxyethyl-6 0-This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the precautions on the back before filling out this page). Printed by the Consumers' Cooperative of the Ministry of Standards, the Ministry of Standards and Industry 518352 A7 B7 V. Description of the Invention (β) -Diaminoalkanes such as 1,6-diaminohexane; such as ammonium oleate, ammonium stearate, Erucic acid amine, behenyl behenate, ammonium tartanate, N-stearyl stearate, N-oleyl oleate, N-stearyl oleate, N-oil N-methyl stearate, N-methyl erucyl stearate, N-oleyl palmitate, N_N> -methylene-dilaurate, N-N'-methylene-meat Myristylamine, Ν, Ν, monomethylene-bispalmithenylamine, Ν, Ν '-methylene-bisstearylamine, Ν, Ν'-methylene-1,2-1- Hydroxylamine stearate, Ν, Ν, monomethylene-dioleamide, N, N'-methylene-diamine; | amidoamine, N, N'-methylene- Ammonium erucate, Ν, Ν'-methylene-di montanic acid Hydrazine, Ν, Ν'-methylene-dilaurate, amine, Ν, Ν'-ethylene-1,2-myristate, Ν, Ν, ethylene-1,2-bromide, Ν, Ν, ethylene vinylamine palmitate, N, N 'ethylene vinyl dihydroxystearate, Ν, Ν, ethylene vinyl dioleate, Ν, Ν, "One ethylene one hundred and twenty one mountain" "Acetylamine, Ν, N '-Ethylethylene dierucamide, N, N, Ethyl 1,2, coalamide, N, N' Hexamethylene Distearylamine, Ν, Ν-hexamethylene-dioleic acid amide, Ν, Ν 'hexamethylene-di-isosorbate, Ν, Ν'-distearyl oxalic acid Amidoamine, N, N'-Dioleyloxalate, N, N'-Distearylsuccinate, N, N'-Dioleylsuccinate, N, Stearyl Ammonium adipate, N, N 'monooleyl adipate, N, N' distearyl sebacate, N, N 'monooleyl sebacate-6 1- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) (%) (Please read the notes on the back before filling out this page) > Packing_ l · Order 518352 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. The invention description (s ^) and other fatty acid amides; N, N-bis (2-hydroxyethyl) lauramine, N, N-bis (2-hydroxyethyl) myristylamine, N, N-bis (2-hydroxyethyl) pentadecamide, N, n-bis (2-hydroxyethyl) oleamide, N, N-bis (2-hydroxyethyl) octadecaneamine, N, N-bis (2-hydroxyethyl) cocoamine, N, N-Di (2-hydroxyethyl) tarofluoride and other aliphatic amines; such as polyethylene oxide laurylamine ether, polyethylene oxide stearylamine ether, polyethylene oxide oil Polyoxyalkylene ethers of aliphatic ammonium amines such as amine ethers, polyethylene oxide coco amine ethers, and polyethylene oxide taro amine ethers; 4 monohydroxy-2,2,6,6-tetramethyl Ketoline, 1-allyl-4, hydroxy-2,2,6,6-tetramethylpyridine, 1-monomethyl-4, hydroxy-2,2,6,6-tetramethylpyridine 1, 1 (4-third butyl-2-butenyl)-4-hydroxy-2, 2, 6, 6 — Tetramethylpiperidine, 4-stearylmethyloxy-2,2,6,6 —tetramethylpiperidine, 4-isobutylenemethyloxy-1,2,2,6,6 —pentamethylpiperidine Pyridine, 1-monomethyl-2,2,6,6-tetramethyl-1,4-pyridinylmaleate, bis (2,2,6,6-tetramethyl-1,4-piperidinyl) amber Acid ester, bis (1,2,2,6,6, pentamethyl-4,4-pyridinyl) succinate, bis (2,2,6,6-tetramethyl-1,4-one # pyridyl) Adipic acid ester, bis (2,2,6,6-tetramethyl-1,4-pyridinyl) sebacate, bis (2,2,6,6-tetramethyl-4, piperidinyl) Fumarate, bis (1,2,3,6-tetramethyl-1,6-diethyl-4pyridinyl) sebacate, bis (1-allyl-2 2-62-benzyl) Paper size applies to Chinese National Standard (CNS) Λ4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Hand-filled items · Packing l-Booking-Φ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System 518352 A7 B7 V. Description of the invention (W), 2,6,6-tetramethyl-4 apicyl) fumarate 1,2,1- (1,2-ethanediyl) bis (3,3,5,5-tetramethylpiperidine hydrazone), 2-methyl-2- (2,2,6,6, tetramethyl) -4-piperidinyl) imino-N- (2,2,6,6-tetramethyl-4-piperidinyl) propanamide, 2-methyl- 2-(1,2,2, 6,6-pentamethyl-4 monomorphinyl) imino-N— (1,2,2,6,6-pentamethyl-4 4-piperidinyl) propanamide, 1-propagyl-4 —Hydrofluoroethyloxy—2,2,6,6-tetramethylpyridine, 1—ethylamidine—2,2,6,6—tetramethyl—4—piperidinyl—acetate, Phenyltricarboxylic acid tris (2,2,6,6-tetramethyl-4 piperidinyl) ester, 1 acrylfluorenyl-4 monooxyl 2,2,6,6-tetramethyl Piperidine, bis (1,2,2,6,6-pentamethyl-1,4-pyridinyl) dibutyl fumarate, bis (1,2,2,6,6-pentamethyl-1) Monopiperidinyl) diamidyl-fumarate, bis (1,2,3,6-tetramethyl-2,6-diethyl-4-pyridinyl) diaza: yl-fumarate , Two (1, 2, 2, 6 , 6-pentamethyl-1, 4-pentidyl), 2- (3,5-di-third-butyl-4, 4-hydroxy T-yl) -2-n-butyl fumarate, etc. . For example, di (2,2,6,6-tetramethyl-1,4-tetramethylidene) -1,5-dioxaspiro [5 · 5] undecane-3,3-dicarboxylic acid ester, di ( 1,2,2,6,6-pentamethyl-4 piperidinyl) -1,5-dioxaspiro [5 ♦ 5] undecane-3,3-dicarboxylic acid ester, di (1 1-Ethyl-2,2,6,6-tetramethyl-1, 4-piperidinyl) -63- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) I Binding (please Read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the Invention (M)-1, 5-Dioxaspiro [5 ♦ 5] Undecane-3 , 3-dicarboxylic acid ester, 1,3-di [2,2,1- [di (2,2,6,6-tetramethyl-4 4-piperidinyl) -1,3-dioxane Alkane-5,5-dicarboxylic acid ester]], bis (2,2,6,6, tetramethyl-4, amidinyl), 2— [1, 2 methylethyl [1, 3 — Dioxane-5,5-dicarboxylic acid esters]], 1,2-bis [2,2, bis [2,2,6,6-tetramethyl] 4a # pyridyl) a 2-methyl-1,3-dioxane-5,5-dicarboxylic acid ester]], di [2, 2,6 * 6-tetramethyl one 4 one Piperidinyl)-2-[2-(3, 5-di-tertiary-butyl-4-hydroxyphenyl)] ethyl-2-methyl-1, 3-diazacyclohexane-5, 5 —Dicarboxylic acid ester, bis (2,2,6,6—tetramethyl-1, 4- # pyridyl) —1,5-dioxaspiro [5 • 1 1] decatane 3,3—two Hindered amine compounds such as carboxylic acid esters, such as hexane-1 '* 6 # -1,2- (4-aminoaminomethyloxy-1, 1-n-butyl, 2,2,6,6-tetramethyltonidine ), Toluene-1, 4'-bis (4-aminomethaneoxy-1, n-butyl-1, 2,2,6,6-tetramethylpyridine), dimethyl-bis (2,2,6, 6-tetramethylpiperidine-4-oxy) -silane, phenyl-tris (2,2,6,6-tetramethylpiperidine-4-oxy) -silane, tris (1-propyl-2, 2,6,6-tetramethyl-1 4-pyridyl) monophosphite, tris (1 propyl-2,2,6,6-tetramethyl-1 4-piperidinyl) monophosphate, Phenyl one [di (1 * 2, 2, 6,6 —pentamethyl-4 amidinyl) -64- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) l · Order printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (k)] Monophosphonate, tetrakis (2,2,6,6-tetramethyl-4-pyridinyl) -1 , 2,3,4 monobutanetetracarboxylic acid ester, tetra (1,2,2,6,6, pentamethyl-4 piperidinyl) -1,2,3,4 monobutanetetracarboxylic acid Acid esters, tetrakis (2,2,6,6-tetramethyl-1,4-pyridinyl) -1,2,3,4-butane tetracarbamidine, tetrakis (1,2,2,6,6 —Pentamethyl-4,4-pyridinyl) 1,2,3,4-butane tetracarbamidine and other hindered amine compounds; such as 2-dibutylamino-4,6-di (9-aza -3 -ethyl-8,8,10,10 -tetramethyl-1,5-dioxaspiro [5 • 5] -3-undecylmethoxy) -s -triazine, 2- Dibutylamino-4,6-bis (9-aza-3-ethyl-8,8,9,10,10-pentamethyl-1,5- Dioxaspiro [5 * 5] -3-undecylmethoxy) _s-triazine, tetra (9-aza-3-ethyl-8,8,10,10-tetramethyl-1 , 5-Dioxaspiro [5 • 5] -3-Undecylmethyl) -1,2,3,4-butanetetracarboxylic acid ester, tetra (9-aza-3-ethylethyl 8,8,9,10,10-pentamethyl-1,5-dioxaspiro [5. 5] -3-undecylmethyl) -1,2,3,4, monobutane Tetracarboxylic acid ester, tridecyl-tris (2,2,6,6-tetramethyl-4 piperidinyl) 1,2,3,4-butanetetracarboxylic acid ester, tridecyl-tris ( 1,2,2,6,6,5-pentamethyl-4 piperidinyl) 1,2,3,4-butane tetrakis (tetrahydro) ester, bis (tridecyl) -di (2,2,6 , 6, tetramethyl-1,4-pyridinyl) 1,2,3,4, monobutanetetracarboxylic acid ester, di (tri-65-) This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling out this page)-Loading · Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (β ) Decyl) bis (1,2,2,6,6-pentamethyl-4 4-pyridinyl) -1,2,3,4, monobutanetetracarboxylic acid ester, 2,2,4, 4, tetramethyl- 7-oxa-3, 2 0-diazabisspiro [5 ♦ 1 • 11, 2] difluorene 1 compound acid 21-one, 3, 9 one two [1, 1 One dimethyl one 2 — {tris (2,2,6,6-tetramethyl one 4 one pyridyloxycarboxy) butyl carboxyoxy) ethyl] one 2,4,8 * 10 one tetraoxa Spiro [5 · 5] undecane, 3,9 bis [1,1 dimethyl-1 2 — {tris (1,2,2,6,6-pentamethyl-4 4-piperidinyloxycarboxyl ) ButylcarbonyloxyΓethyl]-2 * 4,8,10—tetraoxafluorene [5 · 5] undecane and other hindered amine compounds; such as poly (2,2,6,6—tetra Methyl-4, pyridinyl acrylate), poly (1,2,2,6,6-pentamethyl-1,4-piperidinyl acrylate), poly (2,2,6,6-tetramethyl) One four-day meal of pyridyl methacrylate), poly (1,2,2,6,6-pentamethyl-1, 4-pyridinyl methacrylate), poly [[di (2,2,6, 6-tetramethyl- 4-piperidinyl) itaconate] [vinylbutenyl ether]], poly [[bis (1,2,2,6,6-pentamethyl-1,4-imidyl) itaconate ] [Vinyl butenyl ether]], poly [[Di (2,2,6,6-tetramethyl-4,4-trityl) itaconate] [vinyl octyl ether]], poly [ [Di (1,2,2,6,6-Pentamethyl-4 pyridyl) itaconate] [Vinyl octyl ether]], Dimethyl succinate 2-(4-monohydroxy A 2,2,6,6-tetramethylpyridine) ethanol condensate and other hindered amine compounds; -66- This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) l ·, ------- ml Pack ------- Order ί (Please read the notes on the back before filling out this page) 518352 A7 B7 V. Description of the invention (P) Methyl [(2,2,6,6-tetramethyl-1,4-pyridinyl) imino]], poly [ethylene [(2,2,6,6-tetramethyl-4,4-pyridinyl) Amine] hexamethylene [(2,2,6,6, tetramethyl-4,4-pyridyl) amino]], poly [[1,3,5-tri Azine-2,4-yl] [(2,2,6,6-tetramethyl-1 4-pyridinyl) imino] hexamethylene [(2,2,6,6-tetramethyl -4-piperidinyl) imino]], poly [[6- (diethylamino) -1,3,5-diazine-2,4-diyl] [(2,2,6,6 —Tetramethyl-1 4-pyridinyl) imino] hexamethylene [[2,2,6,6-tetramethyl-1 4-piperidinyl) imino]], poly [(6- [2-Ethylhexyl) imino] -1,3,5-triazine-2,4-diyl] [(2,2,6,6-tetramethyl-4animidyl) imine Amine]], poly [[6 -— [(1 / 1,3,3-tetramethylbutyl) imino]]-1,3,5-triazine-2,4-diyl] Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the precautions on the back before filling this page) [(2, 2, 6, 6, 4-tetramethyl-4 pyridyl) imine] hexamethylene [ (2,2,6,6-tetramethyl-1,4-pyridinyl) imine]], poly [[6- (cyclohexylimine) -1,2,3,5-triazine-2,4 One two [] [[2,2,6,6-tetramethyl-1,4-pyridinyl) imino] hexamethylene [(2,2,6,6-tetramethyl-1,4-meridinyl) Imino)], poly [[6-morpholino-1,3,5-triazine-2,4-diyl] [(2,2,6,6-tetramethyl-4 4-piperidine ()) Imine] hexamethylene [(2,2,6,6-tetramethyl-4 amidinyl) imine]], poly [[6-67-67- This paper size applies to China Standard (CNS) Λ4 specification (210 × 297 mm) Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (β) (butoxyimino) -1,3,5-triazine One 2,4 one diyl] [2,2,6,6-tetramethyl-1 4-piperidinyl) imino] hexamethylene [(2,2,6,6, one tetramethyl one 4-pyridinyl) imino]], poly [[6- — [(1,1,3,3-tetramethylbutyl] oxy] -1,3,5-triazine-2,4-diyl ] [(2,2,6,6-tetramethyl-4 pyridinyl) imino] hexamethylene [(2,2,6,6-tetramethyl-4 dipiperidinyl) Amine]] and other hindered amine compounds; poly [oxy [6-[(1-pyridinyl) -1,3,5-triazine-2,4-diyloxy-1,2-ethanediyl] [(2,2,6,6-tetramethyl-1,3-oxy-1,4,4,1) -1,2-ethanediyl] [(3,3,5,5-tetramethyl-1,2-oxyl A-1,4-pyridyl) -1,2-ethanediyl]], poly [oxy [6 — [(1. , 1,3,3,4-tetramethylbutyl) imino] 1,2,3,5-diazine, 2,4-diyloxy-1,2, ethanediyl] [(2,2,6 , 6-tetramethyl-1,3-oxy-1,4-pyridyl) -1,2-ethanediyl] [(3,3,5,5-tetramethyl-1,2-oxy-1,4-piperyl) (Pyridyl) -1,2-ethanediyl]], poly [[6- [ethylethylamido) amino] -1,3,5-triazine-2.4-yl] [(2,2,6 , 6-tetramethyl-1, 4-pyridinyl) imine] hexamethylene [(2,2,6,6-tetramethyl-1,4-pyridinyl) imine]], poly [[6 — (2,2,6,6-tetramethyl-1 4-pyridinyl) butylimide] -6-8-This paper size applies to China National Standard (CNS) A4 (210X 29 * 7mm) (%) (Please read the precautions on the reverse side before filling out this page) Clothing · Order 518352 A7 B7 V. Description of the Invention (W) 1,3,5-triazine-1,2,4-diyl] [(2,2 , 6,6, Tetramethyl-4Amidinyl) imino] hexamethylene [(2,2,6 + ^ 6 —tetramethyl-1 4a # pyridinyl) Group]] and other hindered amine compounds; 1,6,1 1-tri [{4,6-di (N-butyl-N-(2,2,6,6-tetramethyl-4 4-piperidine) ) Amine group) -1,3,5 -Tri-exposure 2 -yl} Amine group] Η --- courtyard, 1,6,1 1 -tri [[4,6-di (N-butyl -N- (1,2,2,6,6-pentamethyl-4 4-piperidinyl) amine 'group) -1,3,5-triazine-2 2-yl) amino group] undecyl, 1, 6, 1 1 one three [{4,6-bis (N-octyl-N— (2,2,6,6-tetramethyl-4piperidine, yl) amino) -1,3,5 -tri Azine- 2 -yl} amino] undecyl, 1,6,11-tris [{4,6-bis (N-octyl-N- (1,2,2,6,6-pentamethylmono 4 amidinyl) amino) -1,3,5-triazin-2-yl) amino] undecane, 1,5,8,12-tetrakis [4,6 —bis (N — (2 , 2,6,6-tetramethyl-4 monopiperidinyl) monobutylamino) -1,3,5-triazine-2-yl] -1,5,8,12-tetraazadodeca Alkanes, 1, 5, 8, 1 2 — tetra [4, 6 — di (N — (1,2, 2 6,6—pentamethyl-4, 1st-pyridyl) -butylamino) -1,3,5-dioxan-2-yl] -1,5,8,12-tetraazadodecane, etc. Amine-based compounds; such as 2,4,6-triamine-1,2,3,5-triazine, 2,4 -69- This paper size applies to China National Standard (CNS) A4 (210 X 29? Mm) (Please read the notes on the back before filling in this tile) > Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, printed 518352 A7.  ____B7 V. Description of the invention (β) -diamino-6-methyl-1,3,5-triazine, 2,4-diamino-6-phenyl-1,3,5-triazine, 3 , 9 one two [2-(3,5-diamino-2,4,6-triazaphenyl) ethyl] one 2,4,8,10 -tetraoxafluorene [5 · 5] ten Monoalkyltriazine compounds. In addition, examples of the metal species of the above-mentioned metal rhenium include lithium, sodium, potassium, magnesium, calcium, rhenium, barium, zinc, or aluminum. The metal rhenium undoubtedly includes ortho rhenium and also includes various basic rhenium. . Particularly preferred are fatty acid metal rhenium, alkanoyl lactic acid metal rhenium, aliphatic hydroxy acid metal rhenium, hydrotalusite, lithium aluminum complex nitrogen oxide rhenium, metal oxide, gold rhenium hydroxide, metal carbonate Rhenium, aliphatic metal phosphate, epoxy compounds, aliphatic amines, aliphatic amines, hindered amine compounds, aminotriazine compounds, and mixtures of two or more of these materials. These halogen scavengers can be used alone or in combination of two kinds. The amount of the halogen trapping agent, 100 parts by weight of the polypropylene composition (PP) of the cypress pair A) was 0. 001 ~ 2 parts by weight, preferably 0. 005 ~ 1. 5 parts by weight, preferably 0. 01 ~ 1 parts by weight. Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). In addition to the halogen trapping agent K mentioned above, the composition of the present invention can be used within the scope of the purpose of the present invention, and the general Various additives added to polypropylene, such as light stabilizers, heavy metal deactivators, clearing agents, nucleating agents, slip agents, antistatic agents, anti-fogging agents, anti-seizing agents, no drops, or Free radical generators such as peroxides, flame retardants, flame retardant additives, pigments, organic or inorganic antibacterial agents, talc, mica, clay, silicon-70- This paper applies Chinese national standards ( CNS) A4 specification (210X297 mm) 518352 A7 B7 5. Description of the invention (W) limestone, zeolite, kaolin, bentonite, bead body, diatomite, asbestos, silicon dioxide, sodium dioxide, zinc sulfide, Inorganic fillers such as barium sulfate, magnesium sulfate, calcium silicate, aluminum silicate, glass fiber, potassium titanate, carbon fiber, carbon black, graphite, and metal fiber, etc., mayane series, osmium titanate, boron series, Alumina series, _ alumina strip, etc. Surface treatment agents such as coupling agents and M coupling agents The above-mentioned inorganic fillers for surface treatment, or organic fillers such as wood flour, used paper, synthetic fibers, and natural fibers. The obtained polyolefin composition is compounded with antioxidants, ultraviolet absorbers, antistatic agents, nucleating agents, slip agents, flame retardants, anti-blocking agents, coloring agents, inorganic or organic fillers, etc. as necessary. Various fillers, or further compounded with various synthetic resins, are usually melted and mixed by heating, and then further cut into granules for use in the manufacture of various molded products. Examples and comparative examples are described in further detail. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs (Please read the notes on the back before filling out this page) The terms, definitions, and measurement methods used in the examples and comparative examples are described below. In addition, in the following examples and comparative examples, polypropylene may be saved as PP, and polyethylene may be omitted as PE. ⑴Intrinsic viscosity [η]: The limiting viscosity measured in naphthalene at 1 35 ° C, the value measured by MO stwa 1 d viscometer (manufactured by Mitsui Seki Chemical Co., Ltd.) (unit: d 1 / g) . ⑵Melting tension (MS): M e It T ensi ο η T ester-Type 2 (manufactured by Toyo Seiki Co., Ltd.-7 Pu Tai paper size applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 518352 A7 • _B7 ___ V. Description of the invention (d) The value measured by the company) (unit: CN). (3) Crystallization temperature (Tc): Using a DSC 7 scanning calorimeter (manufactured by Parkin Eluma), the polypropylene composition was heated from room temperature M 3 0 t / min to 2301 at the same temperature. After holding for 1Q minutes, the temperature was reduced to -20 t per minute: After being held at the same temperature for 1 G minutes, the temperature was raised to 2 3 0 Π under the temperature rising condition of 20 ° / minute. After being held at the same temperature for 10 minutes, Κ- 8 0 υ / min is reduced to 150 ° C, and then 150 ° C KK — 5 t: / min is reduced, and the value obtained by measuring the temperature of the maximum peak heat of absorption during crystallization is measured (unit: I ). ⑷ Thermal stability: 2,6-di-tert-butyl one-to-one cresol is 0 to 100 weight of the polyolefin composition.  1 weight and calcium stearate were mixed in an amount of 0.1 part by weight. The mixture was melt-kneaded and granulated with an extrusion granulator K230 ° C with a spiral diameter of 4QIO to prepare a polyolefin composition. As a hot-hole characterization, the obtained pellets and the above-mentioned extrusion granulator of the pellet K are melt-mixed, and the pelletization is repeated two more times, and the melt flow rate (MFR) of the final pellets is obtained (II Bit: g / 10 points) KJISK 7 2 1 0 Condition 14 measurement in Table 1 to calculate the difference between the M FR of the final pellet and the M FR of the first nine pellets obtained (final pellet MFR-initial pellet MFR = AMFR ). Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs (Please read the notes on the back before filling this page) The smaller the AMFR, the better the thermal stability. ⑸1 color preventive property: the same pellets as the nine pellets used for thermal stability measurement, the yellowness (YI) of the pellets obtained initially and the nine pellets finally obtained is measured in accordance with JIS K7 1Q3 to calculate the final pellets Difference from the yellowness of the initially obtained pellets (Δ = final nine pellets YI-first pellets YI). The smaller the difference (ΔΥI), the better the one-color prevention property. _ 7 2-This paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 518352 Consumption cooperation between employees of the Central Bureau of Standards of the Ministry of Economic Affairs Du printed A7 B7_____ 5. Description of the invention (7.) Example 1 ⑴Transition metal Compound catalyst components were prepared in a stainless steel reactor with a stirrer. Decane 0.3 liters' anhydrous magnesium chloride 4 8 g, n-butyl orthotitanate 170 g, and 2-ethyl-1 -hexane were prepared. 195 g of alcohol was mixed, while stirring, K13〇υ was heated for 1 hour to promote its dissolution and form uniform dissolution. This homogeneous solution was warmed, and 18 g of diisobutyl titanate was added under stirring. After 1 hour, silicon tetrachloride 520 gK 2 was added for 5 hours, a solid was precipitated, and K 7 〇C Heat for 1 hour. The solid was separated from the solution and washed with hexane to obtain a solid product. The entire amount of the solid product was dissolved in 1,2-dichloroethane 1. 5 liters of titanium tetrachloride 1.  Mix 5 liters, and then add 36 g of isobutyl peptidic acid. After stirring, let it react at 1 GQ ° C for two hours. After decantation at the same temperature, remove the liquid phase by K decantation. Chloroethane 1. 5 liters and titanium tetrachloride 1. 5 liters, stirred and held at 100 ° C for 2 hours * and washed and dried in K hexane to obtain titanium-containing 2.  8% by weight of a titanium-containing catalyst component (migration metal compound catalyst component).调制 Pre-activation catalyst preparation: A stainless steel reactor with an internal volume of 5 liters and an inclined leaf M was replaced with K Νζ, and then 2.8 liters of n-hexane, triethylaluminum (organic metal compound (AL1) 4) Titanium-bearing catalyst components tuned in millimoles and in the preceding paragraph 9. After adding 〇g (5.26 mmol in terms of titanium atom), 2Qg of propylene was supplied and pre-polymerized at -2 for 10 minutes. In addition, the polymer produced by pre-polymerization under the same conditions will be divided into -73- (Please read the precautions on the back before filling out this page) Qin l · order it This paper wave size applies the Chinese National Standard (CNS) A4 specifications ( 210X297 mm) 518352 A7. _ B7 _ 5. Explanation of the invention (f) Analysis found that Kashiwa's titanium supported catalyst component lg, propylene 2 g became polypropylene (B), and the polypropylene (B) was measured in 135Ό naphthalene The intrinsic viscosity [η B] is 2 · 8 d 1 / g 0 After the reaction time is over, the unreacted propylene is discharged to the outside of the reactor, and the gas phase part K of the reactor is replaced by N2 once. The temperature was maintained at -110, and one side was maintained to maintain the pressure in the reactor. In the method of 59 MPa, ethylene was continuously fed into the reactor for 2 hours to perform pre-activation. In addition, as a result of analysis of the polymer produced by the pre-activation polymerization performed under the same conditions of K, the bun was relatively titanium-containing. Supporting catalyst component lg, polymer exists 24g, and the intrinsic viscosity [πΤζ] of the polymer measured in 1351C of naphthalene is 31. 4dl / g. Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs (Read the precautions on the back before filling this page) Relative to polyethylene containing titanium-supported catalyst component lg produced by pre-activated polymerization of ethylene (A) The amount of polymer (W 2) as the relative pre-activated polymer containing the catalyst component lg and the polyethylene (B) containing the titanium polymer as the catalyst component after pre-polymerization (W 2) The difference in the amount of generation (Wi) can be obtained by the following formula. W 2 = WT 2-W 1 In addition, the inherent viscosity of the polyethylene (A) formed by the pre-activated polymerization of ethylene [η A], the inherent viscosity of the polypropylene (B) produced by the pre-polymerization [ η B] and the intrinsic viscosity of the polymer produced by the pre-activation treatment [η Τ2], M are obtained by the following formula. -74- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 × 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (κ) C71A3- (CTlTz ^ Wt,- iMJ x W〇 / CWT2- W〇r CXC ^ Ιΐ ~ formula, the amount of polyethylene (A) produced by the pre-activation of ethylene is 22 g relative to the titanium-containing catalyst component lg, the inherent viscosity [η A] is 34.  Odl / g 〇 At the end of the reaction time, release unreacted ethylene outside the reaction chamber 'After replacing the gas phase part of the reactor once, diisopropyldimethoxysilane (electron donor ( E1)) After 1 · 6 millimolars, 2flg of propylene was supplied and kept at 1 ° C for 1D minutes, and then subjected to addition polymerization after preactivation treatment. In addition, the analysis results of the polymer produced by addition polymerization under the same conditions of K show that, relative to the titanium-containing catalyst component lg, the polymer is present at 2 6 g, and the polymer is at 1 3 5 ° C naphthalene. The intrinsic viscosity [η Τ3] determined in the experiment is 29. 2dl / g, calculated in the same way as above, the amount of polypropylene produced by K addition polymerization (W3), relative to the titanium-containing catalyst component lg is 2g, the inherent viscosity [n C] is 2. 8dl / g. After the reaction time is over, the unreacted propylene is discharged out of the reactor, and the gas phase part of the reactor is replaced once to form a pre-activated catalyst slurry for formal (co) polymerization. (3) Production of polypropylene composition (formal (co) polymerization of propylene) After replacing the stainless steel polymerizer with a stirrer with a volume of 5Q0 liters, 240 liters of n-hexane and triethylaluminum (organometallic compound) were replaced at 20 ° C. (AC2) 780 millimolar, diisopropyldimethoxysilane (electron donor -75-) This paper size applies the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) l ''. ------- Equipment ------ ^ Order —, ----- (Please read the notes on the back before filling out this page) 518352 Α7 Β7 Printed by the Employees' Cooperatives of the China Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (U) (E2)) 78 millimoles and 1/2 of the pre-activated catalyst slurry obtained above are put into the polymerizer. Then, 5 5 liters of hydrogen was introduced into the polymerizer, and after the temperature was raised to 70, the pressure of the air-cypress part in the polymerizer was maintained at 0 under the conditions of the polymerization temperature.  7 9 MPa, while continuously feeding polypropylene into the polymerizer for 2 hours, the formal polymerization of polypropylene was carried out. After the polymerization time, 1 liter of methanol was introduced into the polymerizer, and the catalyst deactivation reaction was carried out for 15 minutes. After the unreacted gas was discharged, the solvent was separated and the polymer was dried to obtain an inherent viscosity [nT] of 1. · 971 / g polymer 40 · 1 kg. The obtained polymer was equivalent to (a) the polyethylene (A) content derived from pre-activated polymerization of the component (0). 25% by weight of the polypropylene composition, (b) the inherent viscosity of the polypropylene [η P] is 1. 89dl / g. Relative to 100 parts by weight of the obtained polypropylene composition, 2,6-di-tert-butyl-p-cresol was 0.1%.  1 part by weight and calcium stearate 0.  1 part by weight was mixed, and the mixture M was extruded and granulated by an extrusion granulator K23G10 with a screw diameter of 4 flmin to form pellets. Evaluation of various physical properties of the pellets found that their MFR was 3. 5g / 10 minutes, the crystallization temperature is 1 2 2 · 5 ° C, the melt tension (MS) is 4.  9 c N. Detailed physical properties are shown in Table 1. Example 2 and Comparative Example 1 Except that the pre-activated polymerization conditions using ethylene in Example 1 were changed to change the amount of polyethylene (A) produced, other conditions were the same as those of spring application 1 to produce a polypropylene composition, Adjustment S The adjustment of the evaluation samples of Example 2 and Comparative Example 1. -76- (Please read the notes on the back before filling this page) Installation • Please fill in too, 11 Φ This paper size is applicable to Chinese National Standards · (CNS) Λ4 specifications (2 丨 0) < 297 mm) 518352 A7 B7 V. Description of the invention (W) Various physical properties of the polypropylene composition obtained are shown in Table 1. Comparative Example 2 Except 1 In Example 1, instead of using ethylene for preactivation polymerization, 22Qg of propylene was K80g at the start of preactivation polymerization, 8Qg after 30 minutes, and K60g three times after 1 hour. The conditions other than the supply to the reactor were the same as in Example 1 *. A polypropylene composition was produced, and an evaluation sample of Comparative Example 2 was prepared. The physical properties of the obtained polypropylene composition are shown in Table 1. Comparative Example 3 Except that preactivation polymerization of ethylene using a titanium-containing catalyst component was not performed, the same processing conditions as in Example 1 were performed to produce poly / propylene. The polypropylene obtained by K was prepared as an evaluation sample of Comparative Example 3. The physical properties of the obtained polypropylene composition are shown in Table 1. Comparative Example 4 Printed by the Consumer Cooperative Department of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) After replacing the reactor with a stirrer with inclined blades with fi2, a titanium alloy made of trioxane will be used. Inherent viscosity obtained by polymerizing propylene K slurry in n-hexane with a catalyst composed of a titanium-containing catalyst component composed of the composition, diethylaluminum chloride, and ethylene glycol dimethyl ether as the third component [n C] A propylene homopolymer powder 1 (H [g] was placed at 1.67 dl / g and an average particle diameter of 150 win. Then, after the reactor was formed into a vacuum, the operation until the supply to atmospheric pressure was repeated 10 After this time, while stirring, in a N2 atmosphere, the toluene was dissolved at a concentration of 70% by weight at 25 υ 2 bis 2-ethylhexyl peroxydicarbonate (modifying agent) 0. 0 3 5 mol added Mix it. Then, the reactor -77-this paper size applies the Chinese National Standard (CNS) Α4 specification (2 丨 0: < 29 < 7 mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 518352 A7 B7 —One by one ------ ---------------------- ------- --------- V. Description of the invention (%) The temperature rises to 12Dt :, react at the same temperature for 30 minutes. After the reaction time had elapsed, the temperature in the reactor was raised to 135 ° C, and a 30 minute H treatment was performed at the same temperature. After the post-treatment, the reactor was cooled to room temperature, and then the reactor was opened to obtain polypropylene. Based on the obtained polypropylene composition ΐαο parts by weight, 0.1 parts by weight of 2,6-di-tert-butyl-p-cresol and 0.1 parts by weight of calcium stearate were mixed. The granulator was formed into pellets at 23QC granulation, and an evaluation sample of Comparative Example 4 was prepared. The pellets obtained in Examples 1-2 and Comparative Examples 1-4 on K were evaluated for various physical properties. The results are shown in Table 1. Example 3 ⑴Transition metal catalyst catalyst components prepared in a stainless steel reactor with a stirrer, decane 37.5 liters' anhydrous magnesium chloride 7. 14kg and 2-ethyl-butyl alcohol 35.1 liters Mix and perform heating reaction at 14G1C for 4 hours under stirring to form a homogeneous solution. In this uniform solution, 1.67 kg of anhydrous peptidic acid was added, and the mixture was stirred and mixed at 1 30 1C for 1 hour, and the anhydrous peptidic acid was dissolved in the uniform solution. After cooling the obtained homogeneous solution to room temperature (23C), the homogeneous solution K3 was dropped into 200 liters of titanium tetranitride held at -20 Torr for 3 hours. After dripping, K increased to 110 hrs for 4 hours, and 5.03 liters of diisopropyl peptidate was added at 110 hrs, and K was stirred and maintained at 110 hrs for 2 hours for reaction. After the completion of the reaction for 2 hours, the solid was collected by hot filtration, and the solid portion M 275 liters of titanium tetrachloride was resuspended, and the mixture was reacted at 11 G for 2 hours. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) l ----------- (Please read the precautions on the back before filling this page) ---- ^ Order # 518352 A7 B7 V. Description of the invention (9) (Please read the precautions on the back before filling this page) After the reaction is completed, the K solid filtration is used to take the solid part, and the n-hexane fails to pick up the free solution in the washing solution. Titanium, wash thoroughly. Then, the solvent was separated by filtration, and the solid portion was dried under reduced pressure to obtain a titanium-containing supported catalyst component (transition metal compound catalyst component) containing 2.4% by weight of titanium.调制 Modulation of pre-activated catalyst

After replacing the internal volume of 30 liters of stainless steel reactor M Nz with inclined blades, 18 liters of n-hexane, triethylaluminum (organic metal compound (AL1) 60 mmol) and the titanium-containing carrier prepared in the preceding paragraph were replaced. Supported catalyst component was added with 150g (75.16 millimolars equivalent to M titanium atom), and then 210g of propylene was supplied, and K -1C was used for prepolymerization for 20 minutes. In addition, the polymer produced by prepolymerizing K under the same conditions The analysis results show that relative to the titanium-containing catalyst component lg, 1.2 g of polypropylene (B) is produced, and the intrinsic viscosity UB of the polypropylene (B) measured in 1 3 5 t naphthalene is 2 · 7 d 1 / g. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

After the reaction time is over, the unreacted propylene is discharged to the outside of the reactor, the gas phase part K of the reactor is replaced once, and then the temperature in the reactor is maintained at -It: to make the pressure in the reactor While maintaining at 0.53 MPa, ethylene was continuously supplied to the reactor for 3 hours to perform pre-activation polymerization. In addition, the results of analysis of the polymer produced after pre-activation polymerization under the same conditions are shown. Compared to the titanium-containing catalyst component lg, the polymer is 3 3 · 2 g, and the polymer is 1 3 5 ° The intrinsic viscosity [η Τ2] measured in C naphthalene is 29 · 2dl / g 〇 From this result, it can be known that the newly generated poly-79- using the pre-activated polymerization of ethylene-This paper is applicable to China National Standards (CNS) Λ4 specification (210 X 297 mm) 518352 Α7 Β7 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (π) The amount of ethylene (A), relative to the titanium-containing catalyst type catalyst component lg, is 32g , [Η A] is 3G. 2dl / g. After the time has expired * unreacted ethylene is discharged to the outside of the reactor, and the gas phase part of the reactor is replaced once. * Diisopropyldimethoxysilane (electron donor (E1)) is added to the reactor 22 After .5 millimolars, 385 g of propylene was supplied and kept under Ot: for 2Q minutes, and subjected to addition polymerization after preactivation treatment. After the reaction time is over, the unreacted propylene is discharged to the outside of the reactor, and the gas phase part MN2 of the reactor is replaced once to form a pre-activated catalyst slurry for formal (co) polymerization. In addition, when analyzing the polymer produced by addition polymerization under the same conditions, it was found that, relative to the nitrogen-containing catalyst component lg, the polymer was present at 35.4 g, and the inherent properties of the polymer measured in 135 t: naphthalene The viscosity [η T3] was 27 · 6 dl / g. From this result, it can be known that the amount of polypropylene newly formed by addition polymerization is 2.2 g relative to the titanium-containing supported catalyst component lg, and the inherent viscosity [n C] is 2.8 dl / g. ⑶ polypropylene composition Production (formal (co) polymerization of propylene) In a continuous horizontal gas-phase polymerizer (length / diameter = 3.7) with a mixer and a volume of 100 liters replaced by KN2, 25 kg of polypropylene powder was guided. People * used the pre-activated catalyst slurry as a titanium-containing catalyst component K 0.61 g / h, and triethyl aluminum (organic metal compound (AL2)) and diisopropyldimethoxysilane (Electron donor (E2)) 15% by weight of n-hexane was dissolved, and M relative to the titanium atoms in the titanium-containing catalyst component became Morse ratio -8 0-(Please read the precautions on the back before filling (This page) • Item is refilled. The paper size of the book is applicable to the Chinese National Standard (CNS) Α4 specification (210 ×; Z97 mm) 518352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention (π) 30 and 15 are supplied continuously. Under the conditions of the polymerization temperature of 7 G 1C, the ratio of the hydrogen concentration in the polymerizer to the ratio of the hydrogen concentration to the pH of the polymerizer was set to 0 · G 〇6 so that the pressure in the polymerizer was 2.15M Pa. In the method, propylene was separately supplied into a polymerizer, and gas-phase polymerization of propylene was continuously performed for 15 G hours. During the polymerization period, K maintained the polymer retention in the polymerizer to 60% by volume, and the polymer KUkg / h was derived from the polymerizer. The derived polymer was subjected to a contact treatment with N2 containing 5 vol% of water vapor under IQQC for 30 minutes to obtain an intrinsic viscosity [η Τ] of 1.80 dl / g polymer. The polyethylene (A) content was 0.18% by weight, and the intrinsic viscosity [77?] Of polypropylene was 1.75 (11 ^.) Then, under the same conditions as in Example 1, the K extrusion granulator was used to granulate to obtain a polymer. Pellets. As a result of evaluating and measuring various physical properties of the pellets, it was found that the MFR was 6.0 g / 10 minutes, the crystallization temperature was 122.01, and the melt tension (MS) was 2.5 cN. Example 4 Except for changes in the manufacturing conditions of polypropylene The hydrogen concentration ratio relative to the propylene concentration was G. 008 except that the M FR was changed, and other conditions were the same as in Example 3. A polypropylene composition was produced and the evaluation sample of Example 4 was prepared. The physical properties are shown in Table 2. Comparative Example 5 Conditions other than the pre-activated polymerization using ethylene-8 1-This paper · size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm) ϋ -—. 1_ In ml mi ml m ϋϋ I mn I il VJ —Ϋί- ml I n -11- (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 Μ Β7_ 5. The description of the invention (β) is the same as in Example 3 Production of polymer, the evaluation sample of Comparative Example 5 was prepared. The analysis results of the obtained polymer are shown in Table 2. Example 5 调制 The preparation of the transition metal compound catalyst component was performed under the same conditions as in Example 3. A titanium-containing catalyst component was obtained. ⑵Pre-activated catalyst preparation In addition to the pre-activated polymerization conditions using ethylene in the spring of Example 3, the reaction temperature was set to provide 3Gg of propylene in addition to ethylene M The reaction time is 4 5 minutes K, and other conditions are the same as in Example 3 to obtain a pre-activated catalyst slurry. In addition, the analysis results of the catalyst pre-activated under the same conditions found that the relative titanium-containing catalyst Supporting catalyst component lg, polymer exists 23.2g, and the intrinsic viscosity of the polymer measured in naphthalene at 135 ° C [η T2 I is 21.5, dl / g, relative to titanium-supported catalyst component lg * The resulting intrinsic viscosity [^? 八] is 22.5 (11 / ^, 22 g of ethylene-propylene random copolymer (A) having a propylene polymerized unit content of 0.7% by weight (quantitatively at 13 NM R). In addition, polymerization obtained by addition polymerization after preactivation treatment under the same conditions The analysis results showed that the polymer had 25.3g relative to the titanium-containing catalyst component lg * polymer, and the intrinsic viscosity [η Τ3] of the polymer measured in 135C naphthalene was 19.9 dl / g, due to the addition Polymerization, and newly generated relatively titanium-containing catalyst component lg, 2.1g polymer with inherent viscosity [nC] of 2.1dl / gϋ -82- This paper size applies to China National Standard (CNS) Α4 specifications (210χ 297 mm) flm · m · — ϋι_— tmetmaww ϋϋ ϋ— 1 > 1 mi mi am n · —— 111_ tmtu ϋ.ϋ ml · 1 > 111 (Please read the precautions on the back before filling this page) 518352 A7 B7 _ V. Description of the invention (P) ⑶ Production of polypropylene composition (formal (co) polymerization of propylene) Except for ⑶ in Example 3, the preactivation of the above-mentioned preactivation catalyst slurry is used The catalyst slurry was fatigued, and the ratio of the hydrogen concentration to the propylene concentration in the polymerizer was set to 0.012. Except for propylene, the ratio of ethylene M to the concentration of propylene in the polymerizer was maintained at 0 ^ 〇3 and continuously supplied to M. The other conditions were the same as those in Example 3 for a continuous gas phase polymerization of 150 hours, M At a speed of 11.6 kg / n, a polymer having an intrinsic viscosity [η T] of 1.54 dl / g and containing 0.8% by weight of ethylene polymerization units was obtained. The content of the ethylene-propylene random copolymer (A) produced by the preactivation treatment in the polymer is 0 · 12 weight X, and the intrinsic viscosity [η Ρ] of the propylene-ethylene copolymer is 1. 52 dl / g . In the same manner as in (3) of Example 1, granulation was carried out by an extrusion granulator to obtain nine polypropylene compositions. As a result of evaluating and measuring various physical properties of the pellets, it was found that the MFR was 15.4 g / 10 minutes, the crystallization temperature was 121.2 P, and the melt tensile force (MS) was 1.4 cN. Comparison 洌 6 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except that pre-activation treatment using ethylene and propylene is not implemented, other conditions are related to the spring example 5 Similarly, a polymer was produced under the same conditions as in Example 5, and an evaluation sample of Comparative Example 6 was prepared. The measurement results of the physical properties of the obtained polymer are shown in Table 2. Comparative Example 7 In (2) of Example 1, prepolymerization and addition polymerization using propylene were omitted, and only preactivation polymerization using ethylene was performed. Pre--8 3-This paper size applies Chinese National Standards (CNS) Λ4 specifications (210; < 297 mm) 518352 A7 B7 V. Description of the invention (f) Activated catalyst pulp is added with methanol 1 Liters, and a catalyst inactivation reaction was performed at 70C for 1 hour. After the reaction was completed, the polyethylene was filtered and separated from the slurry, and K was used to reduce the drying to obtain an intrinsic viscosity [nA] of 32.5 (11 / g of polyethylene 200 g). In Example 1, omit (2). Using pre-activated polymerization of ethylene and addition polymerization of propylene, 20 kg of polypropylene obtained from the formal polymerization of propylene and 50 g of the polyethylene prepared above were mixed, and then 2,6-di-tert-butyl-p-cresol 20 was added. g and 20g of calcium stearate, 100 liters of Hanschel type mixer, after mixing for 3 minutes, the mixture is granulated with an extruder granulator with a diameter of 40 rim at 23 ° to produce nine capsules The evaluation raw materials of Comparative Example 7 were obtained. The obtained pellets had various physical properties, intrinsic viscosity [η T] of 1. 97 / dl / g, MFR of 3.5g / 10 minutes, crystallization temperature of 116.2 1C, and melt tension. US) is 1 · GCN. Example 6 调制 The composition of the transition metal compound solvent component was obtained under the same conditions as in Example 3, and was obtained by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, which contains a titanium-containing supported catalyst component. (Please read the notes on the back before filling in (This page) 0 之 The preparation of the pre-activated catalyst was performed under the same conditions as in Example 3 to obtain a pre-activated catalyst slurry. (3) Production of polypropylene composition (formal (co) polymerization of propylene) In Example 3, K makes the hydrogen concentration ratio of the relative propylene concentration in the polymerizer (I) to 0.002. Pressure protection -84- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 518352 A7 __ · _B7__ V. Description of the invention (in the manner of 1.77MPa, the propylene is supplied to the polymerizer and implemented Polymerization process (I). The analysis of the polymer obtained by performing the polymerization process under the same conditions as I * M found that the MFR was 1. lg / l0 minutes. The fixed viscosity of the polymer measured at 135 ° C naphthalene [nT ] Is 2.39 dl / g. The intrinsic viscosity [nP] of the polypropylene in the polymerization process (I) is 2.32 dl / g. The polymer obtained above is continuously fed to a 60 ^: polymerizer (1) to The polymerization process (I) was performed while maintaining the hydrogen concentration and ethylene concentration ratio relative to the propylene concentration in the polymerizer at 0. G03 and 0.2, and supplying the pressure in the polymerizer at 1.57 MPa. In K, the degree of retention of the polymer in the polymerizer 60-volume:?: In a way, the polymer is exported from the polymerizer at a rate of K9.4 kg / h. The polymer to be exported is contacted with 5 volumes of hydrogen containing water vapor for 30 minutes at 1QOt: Polymer with intrinsic viscosity [ηΤ] of 2.69 d 1 / g. Printed by the Central Ministry of Economic Affairs. Printed by the Consumer Cooperative of the Bureau (Please read the precautions on the back before filling this page) Generated by pre-activation treatment in the polymer The polyethylene (A) content rate is G. 2 1 weight X, and the intrinsic viscosity [η P] of the propylene-α-olefin block copolymer composition (b) is 2 · 6 3 d 1 / g. Polymerization process ( The polymerization ratio of I) to (Π) is a copolymer in which the reaction ratio of ethylene / propylene is changed in advance, and this is used as a standard sample, and an inspection line is made by infrared absorption spectrum to obtain the polymerization process (I)- 85- The paper scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) 518352 A7 B7_ 5. Description of the invention (0) The ethylene / propylene reaction ratio is' re-measured from the ethylene content in the full polymer The values obtained are shown in Table 3. Alas, according to the same conditions as in Example 1. The polymer pellets were obtained by granulating with an extruder. The evaluation of various physical properties of the pellets showed that the MFR was 0.52 g / 10 minutes, the crystallization temperature was 121 · 9C, and the melt tension (MS) was 5 · 2 CN. Example 7 调制 The composition of the transition metal compound solvent component is the same as that of Example 1 to obtain a titanium-containing catalyst component. ⑵ The preparation of the pre-activated catalyst is the same as Example 1. Conditions to obtain a pre-activated catalyst slurry. (3) Production of polypropylene composition (formal (co) polymerization of propylene) After replacing the stainless steel polymerizer with a mixer with a volume of 5QL by Nz, n-hexane 2 40L, triethyl at 2Gt Aluminium (organometallic compound (AL2)) 780 millimoles, diisopropyldimethoxysilane (electron donor (E2)) 78 millimoles, and the above-obtained preactivities touched the staff of the Central Standards Bureau of the Ministry of Economic Affairs Printed by a consumer cooperative (please read the precautions on the back before filling out this page). 1/2 of the amount of the media prize solution is put into the polymerizer. Then, 100 liters of hydrogen was introduced into the polymerizer, and after the temperature was raised to 7Q ^, the propylene was continuously connected to the soil at a polymerization temperature of 701 under the condition of maintaining the gas phase pressure in the polymerizer at 0.79 MPa. It was supplied to the polymerizer in 9Q minutes, and the polymerization process was performed (ί). After the end of the polymerization process (I), the supply of propylene was stopped, and the temperature in the vessel was cooled to 30 ° C to release hydrogen and unreacted propylene. Finally, the paper will be tired ~ 8 6-This paper size applies the Chinese National Standard (CNS) Λ4 specification (2ι〇χ 297) 518352 Printed by the Employees' Cooperatives of the Bureau of Standards of the Ministry of Economic Affairs A7 Β7 V. Inventions (Bell)-Partially derived, MFR was measured, and it was 7.5 g / 10 minutes. After the temperature in the device was raised to the temperature, 30 liters of hydrogen was introduced into the polymerizer, and a supply ratio of 乙二 妇 一 was 3 5 weight? : Way, iff B "and propylene are connected for 2 hours. The total supply of ethylene is 7.5 kg. After the polymerization time has passed * 1 liter of methanol is introduced into the polymerizer, and the catalyst deactivation reaction spring is applied for 15 minutes. After the unreacted gas is discharged, the solvent is separated and the polymer is dried to obtain the inherent viscosity [η Τ] 40.5 kg of polymer at 1.95 dl / g. The obtained polymer is equivalent to (a) component derived from pre-activated polymerized polyethylene (A) content (K26 weight $ propylene-c (an olefin block polymer composition, (b) component) The intrinsic viscosity [nP] of the propylene-ex-olefin block copolymer composition (b) is 1.89 dl / g. The polymerization ratio between the polymerization process (I) and (E) is a reaction volume ratio of ethylene / propylene produced in advance. The changed copolymer is taken as a standard sample, and an infrared absorption spectrum calibration line is prepared. The ethylene / propylene reaction ratio in the polymerization process (I) is calculated, and then the ethylene content in the whole polymer is measured. The results are shown in Table 3. Then, under the same conditions as in Example 1, granulation was performed by an extrusion granulator to obtain polymer pellets. As a result of evaluating and measuring various physical properties of the pellets, it was shown that MFR was 3.0 g / g 10 minutes, crystallization temperature 121.5 C, melt tension (MS) 2 · 1 CN 〇 Example 8 In Example 7 (3), the formal (co) polymerization of propylene was changed -87- Applicable to this paper size China National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the notes on the back first Please fill in this page again) 518352 A7 B7 V. Description of the Invention (1) The manufacturing conditions of the composition, the first stage is to supply the ethylene concentration relative to the propylene concentration, K to 0.3, and introduce 50 liters of hydrogen into the polymerization In the reactor, the polymerization process was carried out for 90 minutes at a polymerization temperature of 60 ° F., while maintaining the gas phase pressure in the polymerization reactor at 0.79 MPa, and then supplying the propylene border to the polymerization reactor for 90 minutes. (I). After the end of process (I), stop the supply of propylene and ethylene, and cool the temperature in the device to 30t: release hydrogen and unreacted propylene and ethylene. Finally, release a part of the polymerization slurry. When the MFR was measured *, the value was found to be 3.0. After the internal temperature was raised to 60 b, 50 liters of hydrogen was introduced into the polymerizer. The formula was such that the supply ratio of ethylene was 35 weight X, and ethylene and propylene were used for 2 hours. Continuous reading supply. The total supply of ethylene is 8.2fcg. After the polymerization time has elapsed, 1 liter of methanol is introduced into the polymerizer, and the catalyst deactivation reaction M 701 is performed for 15 minutes, and then the unreacted gas is discharged and then carried out. Solvent separation, polymer drying, The polymer with an intrinsic viscosity [η Τ] of 2 · G8dl / g is 40 · 5kg. The polymer obtained by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). The equivalent (a) component is derived from preactivated polymerized polyethylene (A), a propylene-α-olefin block polymer composition having a content of 0. 24% by weight, and (b) a propylene-α-olefin component. The intrinsic viscosity [ηP] of the block copolymer composition (b) was 2.00 dl / g. The polymerization ratio between the polymerization process (I) and (H) is a copolymer prepared by changing the reaction ratio of ethylene / propane in advance, using this as a standard sample, and making an infrared absorption spectrum calibration line to obtain the polymerization process ( H) The ethylene / propylene reaction ratio is calculated from the ethylene content in the full polymer. -88- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297); f > 518352 A7 __B7_ V. Invention The value of the description (%) is shown in Table 3. Then, under the same conditions as in Example 1, the K extruder was granulated to obtain pellets. The results of the evaluation and measurement of various physical properties of the pellets were shown * MFIi system 2.0 g / 10 minutes * Crystallization temperature is 116 · 8υ * Melt tension (MS) is 2.5 c N. Comparative Example 8 A titanium-containing catalyst slurry was obtained under the same conditions as in Comparative Example 5. Use this one The titanium-containing catalyst slurry was fatigued, and a propylene-ex-olefin block copolymer composition was prepared under the same conditions as in (3) of Example 6 to prepare an evaluation sample for Comparative Example 8. The obtained propylene- The physical properties of the α-olefin block polymer composition are shown in Table 3. Comparative Example 9 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Under the same conditions as Comparative Example 3, a titanium-containing catalyst slurry was obtained. Use this The titanium-supported catalyst slurry was fatigued. Using this slurry, the propylene-α-olefin block copolymer composition was prepared under the same conditions as in (3) of Example 7 and the evaluation sample of Comparative Example 9 was prepared. The physical properties of the obtained propylene-α-olefin block polymer composition are shown in Table 3. Comparative Example 10 Under the same conditions as in Comparative Example 3, a titanium-containing catalyst slurry was obtained. Paper size applies Chinese National Standard (CNS) Λ4 specification (210 × 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 V. Description of the invention (). Use this slurry and follow the example 8 ( 3) The same conditions were used to prepare a propylene-ct monoolefin block copolymer composition, and the physical properties of the propylene- (X-olefin block polymer composition) obtained in the evaluation of Comparative Example 10 were shown in Table 3. Example 9 Rhenium transition metal compound solvent The preparation of parts is in accordance with the conditions of Example 1 to obtain a titanium-containing catalyst component. 调制 Preparation of the pre-activated catalyst ~ According to the same conditions as in Example 1, a pre-activated catalyst slurry is obtained. ⑶ Polypropylene Manufacture of composition (formal (co) polymerization of propylene) After replacing a stainless steel polymerizer with a stirrer with a volume of 500 liters in a stainless steel polymerizer, replace 2 with 240 liters of n-hexane, triethylaluminum (organic metal) at 2Qt: Compound (AL2)) 78 0 mol, diisopropylmethoxysilane (electron donor (E2))) 78 mol and 1/2 of the pre-activated catalyst slurry obtained above, put in Inside the aggregator. Then, the hydrogen concentration ratio and the ethylene concentration ratio of the same propylene concentration were supplied as 0.03 and 0.04. After the temperature was raised to 60 ° C, the pressure of the gas phase part in the polymerizer was maintained at 0.79 MPa. It was continuously fed with ethylene for 2 hours in the polymerizer for propylene-α-olefin copolymerization. After the polymerization time elapsed, 1 liter of methanol was introduced into the polymerizer, and the catalyst deactivation reaction was carried out at 60t: 15 minutes, and after the unreacted gas was discharged, the solvent was separated and the polymer was dried to obtain the intrinsic viscosity [η T 〕 为 -90- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 mm) l · -------- φ Pack ------ Order ------ 0 (Please read the precautions on the back before filling out this page) 518352 A7 B7 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (K) 1.91 dl / g polymer 41.0kg. The obtained polymer * is equivalent to (a) component derived from preactivated polymerization of ethylene transport (A) propylene-α-olefin random polymer with a content of 0.24% by weight, and (b) propylene-α of component The intrinsic viscosity [ηP] of the olefin copolymer (b) was 1.83 dl / g. Then, under conditions equivalent to those in Example 1, granulation was performed by an extruder to obtain polymer pellets. As a result of evaluating and measuring various physical properties of the pellets, it was found that the MFR was 3.7 g / 10 minutes, the crystallization temperature was 115.2 υ, and the melt tension (MS) was 1 · 8 c Ν. Example 10 Preparation of 融 Transition metal compound solvent component According to the conditions of Example 3, a titanium-containing catalyst component was obtained.调制 Preparation of pre-activated catalyst The pre-activated catalyst slurry was obtained in the same conditions as in Example 3. (3) Production of polypropylene composition (formal (co) polymerization of propylene) In a continuous horizontal gas phase polymerizer (length / diameter = 3 · 7) with a stirrer with a volume of 11Q liters replaced by NK2, the polymer is polymerized. 25kg of propylene powder was introduced, and the pre-activated catalyst slurry was used as a titanium-containing catalyst component to dissolve triethylaluminum (organic metal compound (AL2)) and diisopropyldimethoxy group at 0.81g / h. 15% by weight of n-hexane of the silane (electron donor (E2))) is dissolved, and K is supplied in a manner of reading Mortar ratio 9 Q and 15 with respect to titanium atoms of the titanium-containing catalyst component. Under the conditions of polymerization temperature of 6Q ° C, K makes the hydrogen concentration in the polymerizer -91- (Please read the precautions on the back before filling this page) I # items are refilled · Packed · Binding The paper size is applicable to China Standard 孳 (CNS) Λ4 specification (210X297 mm) 518352 A7 B7 V. Description of the invention () The ratio of the relative propylene concentration is 0.02. Supply hydrogen and K so that the pressure in the polymerizer is 1.77 MPa. Supply propylene separately. In a polymerizer, helium of propylene was applied for 150 hours. During the polymerization period, the method of maintaining the polymer retention in the polymerizer to 60% by volume, and deriving the polymer at a rate of K12 kg / h from the polymerizer. The derived polymer was contact-treated with {} 2 containing 5 vol% of water vapor at 100 Torr for 30 minutes to obtain a polymer having an intrinsic viscosity [nT] of 1.95 dl / g. The content of polyethylene (A) produced by pre-activation ~ treatment in the polymer was 0.22 weight X * the inherent viscosity of the polypropylene [77P] was 1.89 dl / g 0, and then the same conditions as in Example 1 were adopted. The M extrusion granulator was used for granulation to obtain polymer pellets. Evaluation of various physical properties of the pellets revealed that MFR was 3.2 g / 10 minutes, crystallization temperature was 110.01C, and melt tension (MS) was 1 · 9 C N. Example 1 1 (1) Modulation of transition metal compound melt components Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Under the same conditions as in Example 1 * The titanium-supported catalyst component 〇⑵pre-activated catalyst was prepared under the same conditions as in Example 1 to obtain a pre-activated catalyst slurry. ⑶ Manufacture of polypropylene composition (formal (co) polymerization of propylene) In a stainless steel polymerizer with a mixer of 500 liters and a mixer M -92- The standard of this paper is applicable to China National Standards (CNS) Α4 Specifications (210X 297mm) I ~ 518352 Α7 Β7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () After replacing n2, 240 liters of n-hexane, triethylaluminum (organic gold compound) (AL2)) 780 millimoles, diisopropylmethoxysilane (electron donation I (T2)))) 7 8 millimoles and 1/2 amount of the pre-activated catalyst slurry obtained above Inside the aggregator. Then, the hydrogen concentration of the propylene concentration, the ethylene concentration, and the butene-1 concentration ratio were supplied so that they were 0 · and 0 · 02 5 and 0.038, respectively. After the temperature of the M was raised to 6Q ° C, the temperature was maintained in the polymerizer. At a gas phase pressure of 0.79 MPa, propylene, hydrogen, ethylene, and butene-1 were supplied to a polymerizer for K2 hours, and propylene-α-olefin copolymerization was performed. After the polymerization time has passed, 1 liter of methanol is introduced into the polymerizer, and the catalyst deactivation reaction is applied at 6Q ° C for 15 minutes. After the unreacted gas is exhausted, the solvent is separated and the polymer is dried to obtain the inherent viscosity. [Η T] is a polymer 3 9 · 6 lu of 1 · 6 7 d 1 / g. The obtained compound is equivalent to (a) component derived from pre-activated polymerization polyethylene (A) propylene-α-olefin random copolymer with a content rate of 0.25% by weight, and (b) propylene-10 (- The intrinsic viscosity [η P] of the olefin copolymer (b) was 1.59 dl / g. Then, under the same conditions as in Example 1, a K-extrusion granulator was used to granulate to obtain polymer pellets. As a result of evaluation and measurement of various physical properties, it was found that MFR was 7.6 g / 10 minutes, crystallization temperature was 110.31, and melt tension (MS) was 1 · 3 c Ν 〇 Comparative Example 1 1 According to the conditions of Comparative Example 3, titanium-containing Carrier type catalyst slurry. -93- (Please read the precautions on the back before filling this page) —

、 1T __ This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297mm) 518352 A7 B7_ i. Description of the invention (W) Use this titanium-containing slurry, in accordance with Example 9 (3 ), A propylene-α-olefin copolymer composition was prepared, and an evaluation sample of Comparative Example 11 was prepared. The physical properties' of the obtained propylene-?-Olefin copolymer composition are shown in Table 4. Comparative Example 12 Under the same conditions as in Comparative Example 5, a titanium-containing catalyst slurry was obtained. Using this titanium-containing supporting slurry, the propylene-?-Olefin copolymer composition 'was prepared as an evaluation sample for Comparative Example 12 under the same conditions as in (3) of Example 10. The physical properties of the obtained propylene-?-Olefin copolymer composition are not shown in Table 4. Comparative Example 1 3 According to the same conditions as Comparative Example 3, a titanium-containing catalyst slurry was obtained. Using this titanium-containing supporting slurry, a propylene-α-olefin copolymer composition was prepared under the same conditions as in (1) of Example 11 and an evaluation sample of Comparative Example 11 was prepared. The physical properties of the propylene-α-olefin copolymer composition printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) are shown in Table 4. Example 1 2 Adjustment of ⑴transition gold 靥 compound solvent composition According to the conditions of S Example 1, a titanium-containing catalyst slurry was obtained.调制 Modulation of pre-activated catalyst -94-This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 518352 A7 __; _B7__ 5. Description of the invention (W) In Example 1, the use of C The preliminary polymerization will use the pre-living polymerization of ethylene and the addition polymerization of propylene, according to the conditions of Example 1. In addition, as a result of analysis of a polymer produced by preactivating polymerization under the same conditions of K, it was found that, relative to the titanium-containing catalyst component lg, polyethylene (A) was present at 22.2 g, and the polymer was at 135 C of naphthalene. The fixed viscosity [η A] measured in the test was 32.5 dl / g. In addition, the polymer obtained by performing pre-activation polymerization under the same conditions and then performing addition polymerization, and analysis results show that only M addition polymerization, compared with titanium-containing catalyst component lg, polymer There is 2.Qg * and the fixed concentration [n A] of the polymer measured in 135 10 naphthalene is 2. 3 dl / g. 〇 Manufacture of polypropylene composition (formal (co) polymerization of propylene) Using the adjusted pre-activated catalyst, formal polymerization of propylene was performed under the same conditions as in Example 1 to produce polypropylene. The obtained polypropylene was pelletized under the same conditions as in Example 1, and K was used as a sample for evaluation in Example 12. The physical properties of the polypropylene obtained by Du Yin printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) are shown in Table 5. Comparative Example 1 In Example 1, prepolymerization using propylene and preactivation polymerization using ethylene were omitted, and only addition polymerization with propylene was used, and the preactivation prepared in accordance with the conditions of Example 1 was used. Chemical catalyst, in accordance with Example -95- This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 male f) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 _ V. Description of the invention ) 1, the formal polymerization of propylene to produce polypropylene. The obtained polypropylene was pelletized under the same conditions as in Spring Example 1 to obtain Comparative Example 14-1. Spring Example 1 3 and Comparative Example 15 Except that the prepolymerization using propylene was omitted and the preactivation polymerization condition M using ethylene was changed, the other conditions were processed in the same manner as in Example 1 to produce polyethylene (A). Polypropylene compositions having different contents were treated in the same manner as in Example 1 to prepare the evaluation samples of Example 13 and Comparative Example 15. ~ The physical properties of Example 13 and Comparative Example 15 are shown in Table 5. Example 1 4 Preparation of rhenium transition metal compound solvent component In accordance with the conditions of Example 3, a titanium-containing catalyst slurry was obtained.调制 Preparation of pre-activated catalyst In Example 3, the preliminary polymerization using propylene was omitted, and the pre-active polymerization using ethylene and the addition polymerization using propylene were carried out under the same conditions as in Example 3. In addition, as a result of analysis of the polymer produced by pre-activated polymerization under the same conditions of K, it was found that, relative to the titanium-containing catalyst component lg, polyethylene (A) was present at 32.0 g, and the polymer was 135 Ό in naphthalene The fixed viscosity [nA] measured in the test was 29,8 dl / g. In addition, after the pre-activation polymerization is performed under the same conditions, the polymer obtained by addition polymerization will be implemented. The analysis results show that only M addition polymerization -96- This paper standard applies to China National Standard (CNS) A4 (210 × 297 mm) Ν --------- install ------ • -order Ir ----- (Please read the precautions on the back before filling this page) 518352 A7 B7 _ 5 2. Description of the invention (batch), relative to the titanium-containing catalyst component 12, the polymer is present at 2.2g 'and the fixed concentration of the polymer measured at 1 3 5 ° C naphthalene [π A], is 3 · 4 d 1 / g. 0 (3) Production of polypropylene composition (formal (co) polymerization of propylene) Using the adjusted pre-activated catalyst, formal polymerization of propylene was performed under the same conditions as in Example 3 to produce polypropylene. The obtained polypropylene was pelletized under the same conditions as in Example 3 and used as a sample for evaluation in Example 14. The & properties of the obtained polypropylene are shown in Table 5. Comparative Example 16 In Example 3, the preactivation treatment of (2) was omitted. In the presence of the titanium-containing solid catalyst obtained in (1), the polymerization of propylene was performed under the same conditions as in (3). A propylene (co) polymer composition was produced, and the evaluation samples of Comparative Example 16 were adjusted. Various physical properties of the obtained polypropylene are shown in Table 5. Example 1 5 Preparation of rhenium transition metal compound solvent composition

Printed $ L by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Obtain the titanium-containing catalyst slurry under the same conditions as in Example 1. ⑵The preparation of the pre-activated catalyst was carried out in Example 5. The preliminary polymerization using propylene and the addition polymerization using propylene were omitted, and only the pre-activation polymerization using ethylene-propylene mixed gas was performed according to the conditions of Example 5. Spring Shi. In addition, the ethylene-97 produced by the pre-activation polymerization under the same conditions will be applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). 518352 Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 2. Explanation of the invention (%) The results of a propylene copolymer found that the polymerization unit of propylene was 0.8 weight X (C 1 3 -NMR quantification), relative to the titanium-containing catalyst component lg, ethylene propylene 2 5 g, and the polymer The fixed viscosity [η A] measured in naphthalene at 1 3 5 C was 3Q.Qdl / g. (3) Production of polypropylene composition (formal (co) polymerization of propylene) Using the prepared preactivated catalyst, formal polymerization of propylene was performed under the same conditions as in Example 1 to produce polypropylene. The obtained polypropylene was pelletized under the same conditions as in Example 1, and K was used as a sample for evaluation in Example 15. — The physical properties of the obtained polypropylene are shown in Table 6. Comparative Example 1 In Example 2 (2), in addition to omitting prepolymerization using propylene and addition polymerization using propylene, preactivation polymerization using ethylene will be replaced with K preactivation using ethylene-propylene mixed gas instead. Chemical treatment, supplying 240 g of propylene to the inside and outside of the reactor. Other conditions were the same as in Example 1 of the spring. Polymerization of propylene was performed to produce propylene. Preparation of a propylene (co) polymer composition An evaluation sample of Comparative Example 18 was prepared. The physical properties of the obtained ratio polypropylene are shown in Table 6. Example 1 7 (1) Adjustment of transition metal compound solvent component In accordance with the conditions of Example 3, a titanium-containing catalyst component was obtained.调制 The preparation of the pre-activated catalyst was carried out in Example 3, and the pre-polymerization using propylene was omitted, and the use of propylene-98- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the back first Note: Please fill in the items again. Packing-: write this page) Order 518352 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (Private) The addition polymerization of olefins will only utilize the pre-activity of ethylene The polymerization was carried out under the same conditions as in Example 3. In addition, analysis of the polymer produced by the pre-activation polymerization under the conditions of M Monday found that, relative to the titanium-containing catalyst component lg, 29 g of polyethylene (A) existed, and the polymer was 135 "in naphthalene. The intrinsic viscosity [π A] measured in the process was 35.5 dl / g. (3) Production of polypropylene composition (formal (co) polymerization of propylene) Using the prepared pre-activated catalyst, the conditions were the same as those in Example 5. Formal polymerization of propylene was performed to produce #propylene. The obtained polypropylene was pelletized under the same conditions as in Example 1 and used as samples for evaluation in Example 17. The physical properties of the obtained polypropylene are shown. The results are shown in Table 6. Example 18 In (3) of Baoshi Example 1, except for 100 parts by weight of the obtained polypropylene composition, it replaced the phenolic antioxidant 2 * 6-di-tert-butyl-p-formyl. Phenol is 0.1 parts by weight, and phosphorous-based antioxidant tris (2,4-tributylbutyl) phosphite G.1 parts by weight K is used. Granulator K 230 ^ Granulates to form pellets, evaluates various physical properties on the evaluation of the pellets, results in cyanosis, MFR It is 3.6 g / lG, the crystallization temperature is 1 19.5, and the melt tension (MS) is 2. 1 C N. Example 1 9 In Example 3 (3), except for the obtained polypropylene 100 parts by weight of the composition, in place of the phenolic antioxidant 2,6 —di-tert-butyl-99- This paper size applies to the Chinese National Standard (CNS) Α4 specification (210 X 297 mm) (Please read the back Note: Please fill in this page again) 15 Yiding Φ 518352 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ¾ A7 B7 V. Description of the invention (correction) A pair of cresols, using phospholipid antioxidant 3 (2, 4 1 2 3 Other conditions except for butylphenyl) phosphite K are the same as those in Example 2 and an evaluation sample of Polypropylene Modification Example 19 was produced. The physical properties of the obtained polypropylene are shown in Table 7. Comparative Example 2 0 to 2 3 In Comparative Examples 1 to 4, except for 100 parts by weight of the obtained polypropylene composition, instead of the phenolic antioxidant 2,6-di-tert-butyl-p-cresol, a phosphorus-based compound was used. Except for the antioxidant tris (2 * 4-di-tert-butylphenyl) phosphite M, other conditions ti are the same as those of the comparative examples. The polypropylene composition was manufactured, and the evaluation samples of Comparative Examples 20 to 23 were prepared. The physical properties of the obtained polypropylene are shown in Table 7. Example 2 0 to 2 1 In Examples 3 and 5, except for 100 parts by weight of the obtained polypropylene composition was used in place of the phenol-based antioxidant 2,6-di-tert-butyl-p-cresol, and the phosphorus phosphonium antioxidant tri (2,4-tert-butyl-phenyl) was used. Except for phosphate ester K, the other conditions were the same as those in Examples 3 and 5, a polypropylene composition was produced, and evaluation samples of Examples 21 and 22 were prepared. The physical properties of the obtained polypropylene are shown in Table 8. Comparative Example 2 4 to 2 6 In Comparative Examples 5 and 7 * Except for 100 parts by weight of the obtained polypropylene composition, instead of the phenolic antioxidant 2,6-di-tert-butyl-p-cresol, a phosphorus-based compound was used. Antioxidant tris (2,4,2,3,3-butylphenyl) phosphite K, other conditions are the same as those of the comparative examples. Polypropylene 100- Taizhilang scale is applicable to Chinese National Standard (CNS) Λ4 specifications (210X 297mm) l · ------- • install ------ order ------- m (please read the notes on the back before filling this page) Central Bureau of Standards, Ministry of Economic Affairs Printed by the employee consumer cooperative 518352 A7 B7 V. Description of the invention (Acryl) Composition, preparing the evaluation samples of Comparative Examples 24-26. The physical properties of the obtained polypropylene are shown in Table 8. Actual D 2 In Example 1 (3), except for 1Q0 parts by weight of the obtained polypropylene composition, it replaced phenolic antioxidant 2,6-di-third-butyl-p-cresol by 0.1 parts by weight. Phosphorus-based antioxidant tris (2,4-di-tert-butylphenyl) phosphite 0.G 9 parts by weight and 2,6-di-tertiary-butyl-p-cresol 0. 0 1 parts by weight K Except that, other parts were the same as those of the spring example 1. An extrusion granulator was used to produce a polypropylene i product. As a result of measuring various physical properties of the obtained polypropylene composition, it was found that [nT] was 1.97 dl / g, cMFR was 3.5 g / 10 minutes, the crystallization temperature was 120 · 7C, and the melt tension (MS) was 2.8 CN. Examples 2 In Example 3 (3), except for 100 parts by weight of the obtained polypropylene composition, a phosphorus-based antioxidant tri (3) was used instead of the phenol-based antioxidant 2,6-di-tert-butyl-p-cresol. Except for 2.0 parts by weight of 2,4,3,3-butylphenyl) phosphite and 0.Q2 by weight of dimyristoylthiodipropionate, the rest are the same as in Example 1, and were extruded and granulated. Machine made polypropylene composition. As a result of measuring various physical properties of the obtained polypropylene composition, it was found that the intrinsic viscosity [η T] was 1.97 dl / g. The MFR is 3.5 g / 10 minutes, the crystallization temperature is 119 ° C, and the melt tension (MS) is 2.5 CN. Example 2 4 (1) Modulation of transition metal compound solvent composition -101- The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) m · i ^ n fm ml ϋϋ ml m —HI— ϋϋ · Ϋ_ϋ am—-, 4-- \ >, m ^ e 1 «11 · ϋϋ ml ϋ .—— (Please read the precautions on the back before filling out this page) 518352 Α7 Β7 Staff Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Printed 5. Description of the invention (called) Obtaining titanium-containing catalyst components under the same conditions as in Example 1 ⑵ Pre-Hi line H tuning · Obtaining pre-activated catalysts under the same conditions as in Example 1 Slurry. (3) Production of polypropylene composition (formal (co) polymerization of propylene) After replacing a stainless steel polymerizer K Nz with a stirrer with a volume of 50 Q liters, 240 liters of n-hexane and triethyl aluminum ( Organic gold plaque compound (AL2)) 780 millimoles, diisopropyldimethoxysilane (electron donor (E2)) 78 ^ moles, and 1/2 of the preactivated catalyst slurry obtained above Amount, put into the polymerizer. Then, 95 liters of hydrogen was introduced into the polymerizer. After the temperature was raised to υ, the polymerization temperature was 70 t: and the propylene pressure in the polymerizer was maintained at 0.7 9 MPa, and propylene was continuously supplied for 45 minutes at K Inside the aggregator, Bao Shi polymerization process (I). After the end of the polymerization process (I), the supply of propylene was stopped, the temperature in the vessel was cooled to 301, and hydrogen and unreacted propylene were released. Finally, a part of the pulp fatigue was derived, and the MFR was measured, and it was found to be 6.5 g / 10 minutes. The intrinsic viscosity [τ? Τ1] measured in 135t: naphthalene is 1.78 dl / g. The intrinsic viscosity [η P 1] of the polymer obtained in the polymerization process (I) was 1.5 9 d 1 / g 〇 Then, 45 liters of hydrogen was introduced into the polymerizer, and the temperature in the device was raised to 70 ° C. Under the condition of the polymerization temperature of 7 Gt, and maintaining the gas phase pressure Q.98 MPa in the polymerizer, the propylene continuous ore site M was supplied into the polymerizer for 6Q minutes, and the polymerization process (I) was performed. After the end of the polymerization process (I) -102- (Please read the precautions on the back before filling in this page) _Packing · 1T it This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 518352 A7 B7____ 5. The invention is clear (β), stop the supply of propylene, and cool the temperature in the device to 30t: release the hydrogen and unreacted propylene. Finally, a part of the polymerization slurry was derived, and the analysis results predicted that the MFR was 3.11 lg / 10 minutes, and the inherent viscosity [r] T2] determined by Cai Manzhong was 2.01 dl / g. Intrinsic viscosity of the polymer obtained in the polymerization process (H) [? ? P2] is 2.29 dl / g. Then, 30 liters of hydrogen was introduced into the polymerizer, and after the internal temperature of the reactor was increased to 70, the propylene was continuously supplied under the condition of the polymerization temperature of 70 ° C while maintaining the gas phase pressure in the polymerizer at 0.98MP a. In the polymerizer, carry out the polymerization process (m. After the end of the process (an), stop the supply of propylene, and cool the temperature in the reactor to 30 ° C. * After the polymerization time of hydrogen and unreacted propylene has passed, methanol 1 liter was introduced into the polymerizer, and the catalyst deactivation reaction was performed at 70 π for 15 minutes. After the unreacted gas was discharged, the solvent was separated, and the polymer was dried to obtain an intrinsic viscosity [ηΤ3] of 2.33 dl / g. Polymer 39.1kg. The intrinsic viscosity [η P 3] of the polymer obtained during the polymerization (I) is 3 · 8 6 d 1 / g. The polymer obtained is equivalent to the component (a) derived from pre-activity The polymerized polyethylene (A) content rate Q. 25 weight S: polypropylene polymer composition, (b) component polypropylene polymer composition (b) inherent viscosity [np] is 2.25dl / g. The polymerization process (I), (H) and (I) ratio of the overlapping amount is determined by each stage The magnesium content in the powder was calculated, and its values are shown in Table 10. Then, according to the conditions of Example 1, the K extrusion granulator was used to obtain -103- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) mi —ι_1ϋ til_il ml nn tuai— 1 ^^^ mi am > — I ϋϋ · · ϋι— HKH V. V ιϋ.Γ n tm —! — 1 · Ham (Please read the back first Please pay attention to this page, please fill in this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 518352 A7 B7 V. The polymer pellets of invention (W) were obtained. As a result, evaluation and measurement of various physical properties of the pellets showed that MFR is 1 · 3g / l Q points, crystallization temperature: 122 · 31, melt tension: 9 · 9 c T ^ — Comparative Example 2 7 The same conditions as in Comparative Example 3 were used to obtain a titanium-containing catalyst slurry. Use this one The titanium-containing supporting slurry was fatigued, and a propylene polymer composition was produced under the same conditions as in (3) of Example 24. The properties of the polypropylene obtained in the evaluation sample 0 of Comparative Example 27 were prepared as shown in Table 1 0. Example 2 5 50 parts by weight of the propylene polymer composition of Example 1 and the propylene of Comparative Example 3 were polymerized Composition composition K 50 weight:!; Ratio of mixing, mixing M 2,6-di-tert-butyl-p-cresol Q. 1 part by weight and calcium stearate 0.1 part by weight, the mixture K spiral diameter 4Gmn The extrusion granulator K23G ° C was used to granulate to form pellets. Various properties of the pellets are shown in Table 11. In addition to setting the amount of the pre-activated catalyst containing high molecular weight polyethylene to 0 · Except for 24 weight 35 and Q. 46 weight 55, the rest are the same as in Example 1. The obtained polypropylene composition was analyzed as follows. ⑴ Transmission electron microscope (TEM) The transmission electron microscope (TEM) observation is performed in the following manner. First, set the nine-grained test section M to a hot press at a temperature of 20Q ° C. After preheating for 3 minutes, press molding at 50kg / cm2 for 5 minutes, and then press K at 50 ° C. The cooling press is solidified under the pressure of 50 kg / cm2 for 3 minutes. -104- This paper size is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) H. fi—ϋ 11 = 1¾ mf · mu flu · * » βϋ-ϋ I (Please read the precautions on the back before filling out this page) Order 518352 A7 B7_______ V. Description of the invention (A), make a plate test piece with a thickness of linin. After the test piece was repaired ', in order to impart the contrast when observed by TEM, K was derived from the vapor of Ru04 aqueous solution, and was used as an electric color. The 7K solution was prepared by dissolving 0.6 g of Nalcu (manufactured by Wako i Pharmaceutical Co., Ltd.) and RuCl3 · nH2O (manufactured by Wako Pure Chemical Industries Co., Ltd.) 0.1 g in pure water lOnil. The test piece coexisted with the Ru04 water solution in a closed container, and was left to stand at room temperature for 48 hours to be dyed. Further, in the present invention, the dyeing of K from water-soluble steam is not performed, but in order to obtain the same effect, dyeing by sublimation gas from Ru04 aqueous solution or from Ru04 crystal may be used. & The color sample was sliced with an ultra-thin machine made by a diamond knife K with a cutting angle of 45 ° from Japan Slicing Co., Ltd. to obtain an ultra-thin slice with a thickness of approximately 80 na. The ultra-thin section samples were observed using JEM-100CX type TEM manufactured by Japan Electronics Co., Ltd. and K accelerated lightning pressure lGflkV. The 75,000-times photograph of the above TEM observation is shown in FIG. 1. As can be seen from Fig. 1, in the polymer of this example, a high molecular weight polyethylene having a number average particle diameter of about 70 nm was used as microdispersion * and a high molecular weight polyethylene was observed to have a layered structure. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Figure 2 is a drawing that is easier to add with the photo in Figure 1. The high-molecular-weight polyethylene microspheres and layered structure are added to the figure as an illustration. In contrast, the polypropylene that has been known so far is shown in the TEM photograph of FIG. 3 and FIG. 4 depicting it, and No particles are present. ⑵rheological analysis l.Rheomatrix.Mechanical.Spectrometer (RMS) -105- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 518352 A7 B7 V. Preparation of sample for measurement (M) measurement law. RMS-80G measurement pellets (heat stabilizer: 2,6-di-tert-butyl-p-cresol ΓΒΗΤ): 0.1% by weight, added with lubricant calcium stearate: 0.1% by weight Γ, At 2000 ° C, it was hot pressed into a 25iaffl diameter plate. The plate was measured in RMS-800. 2. Measurement of elongational viscosity M) A thermal stabilizer (BHT: 0.1 parts by weight, lubricant calcium stearate 0.1 weight X) K Hanschel mixer was added to the powder and mixed for 3 minutes. _ (ί i) The above mixture was extruded with a 40-mm diameter extruder, and M 2300 was formed into nine materials. (iii) Melt tension tester (pore diameter as temperature 210 ° C, extrusion speed 5min / inin, and preheating time until extrusion is 5 minutes, manufactured by Toyo Seiki Co., Ltd. Wire stock. The following is a description of the rheological behavior. 1 ♦ Related (Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). For molten materials, use a 25 dia. Mechanical-Spectroffleter RMS-800, manufactured by Rheomatrix, for parallel plates, in the frequency range of 10-2 to 10-2 (rad / sec), strain measurement in the linear range of 230, storage coefficient of densities < 3 ' The results are shown in Figs. 5 to 7. As shown in Figs. 5 to 6 (vertical axis: storage unisex coefficient G ', horizontal axis: frequency ω), the polymer of the present invention (hereinafter abbreviated as "HMS-PP" G ', at low -1.06-This paper size applies Chinese National Standard (CNS) Α4 specification (210 × 297 mm) Printed on the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 • · B7 V. Description of the invention (㈣ ) In the frequency region, there is a second The second flat region has a height that increases with the amount of pretreated PE. This second flat region is also used in copolymers in which rubber particles form islands and are dispersed in the rubber phase, and polymers filled with inorganic fillers. It can be seen that this is due to the long-term mechanism of the dispersed phase. HMS-PP is believed to have this second flat region due to microdispersion of ultra-high molecular weight PE particles of submicron size. Again, Figure 5 "HIMONT LCB-PP" in the above refers to the electronic wire bridging polypropylene manufactured by Haimont's electron beam irradiation method. It should be noted that the electronic wire bridging polypropylene does not have the third flat area. 2 ♦ Regarding Ni as a molten material, MH is equipped with a cone plate with a diameter of 25πηη and a cone angle O.lrad. Mechanical. Spectroffleter RMS-800 manufactured by the company, M 10_2 ~ 10 [sec-1] Shear speed range measurement 190 The first normal stress difference N i at 230 2 5 0 ° C. The measurement is made after the sample is set and the temperature is stable for 30 minutes before it is opened. The time to the constant flow state is determined by prediction. Forecast : K 0 · 0 1 [s-1] 1 5 0 [S], 0 · 0 5, 0 · 1 [s — 1] are given constant flow for 1 Q 0 [S] samples, and the viscosity is determined to be constant The minimum time until the value. Figure 8 (vertical axis: first normal stress difference Nom, horizontal glaze: shear speed T), Figure 9 (vertical axis ·· first normal stress difference, horizontal axis: MFR) It is shown that HMS-PPt N t is higher than conventional PP and increases with the amount of pretreated PE. This -107- Taiji paper scale applies Chinese National Standards (CNS) Λ4 specifications (2 丨 0x297 mm) (Please read the precautions on the back before filling out this page) -Packing-， 11 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System 518352 A7 _B7___ 5. Description of the invention (4) One Ni, which is higher than the conventional PP, has PP made by HI MONT's electron beam irradiation method, but as shown in Figure 9 (vertical axis: first Normal line stress difference I, transverse IT: temperature), conventional PP and electron irradiation method N ·! Will decrease with increasing temperature. In contrast, HMS-PP has low temperature dependence. (3) G (t) The molten material was measured with a mechanical spectrometer RMS · 800 manufactured by Rheomati’ix Corporation with a cone plate having a diameter of 25 m and a cone angle of Q.lrad, and the strain timing was 33Q [s]. As shown in Figs. 10 to 11 (vertical axis: 鑀 and elastic coefficient G (t), horizontal axis: time), the G (t) curve of HMS · PP has approximately the same slope as the conventional PP on the short-time side. Degrees, but on the long-term side, the inclination becomes rampant, showing the morphology of the plateau on the long-term side. In the measurement sequence (hereinafter referred to as 330 [s]), the terminal area cannot be observed. Due to the increase in the amount of pre-processed PP, the starting point of the plateau for a long time is shifted to the short time side. The gradient of the GU) curve of PP by the electron beam irradiation method of HIMONT is better than that of conventional PP and HMS-PP. It does not show a long time plateau. It is the same as conventional PP, and the terminal area is observed. The long plateau of the G (t) curve can also be observed in PP with two molecular weight distributions. 4 · About the elongation viscosity of the strand with a uniform diameter, Meltenrhemometer manufactured by K Toyo Seiki Co., Ltd. was preheated in a 180 t silicone oil bath for 5 minutes, and then a certain strain rate (0. Q 5, 0. 1 0, 0 3 0) Extending, measuring elongation -108- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) Order 518352 A7 B7__ V. Invention Description () Viscosity. The "elongation viscosity" is measured over time with respect to the tension and the strand diameter (the strand diameter is measured by a MCCD camera) ° WT 2 (vertical axis: elongation viscosity, horizontal axis: time), under the conditions of Example 1, The addition amount of the pre-activated catalyst containing high molecular weight polyethylene was changed to 0.46 wt%, and the amount of hydrogen was changed. The rest is the same as in Example 1, and the obtained polypropylene composition was changed in strain rate ( 7) Measure the elongational viscosity. The measurement results are shown in Table 12. [Table 1 2] Sample JJO. MFR (g / l (T points) Strain rate (sec— 1)

HiMS PP-l 0.5 0.0 2 1 Η MSPP-2 0 · 5 0. 0 3 7 HMS PP-3 0.5 0.128 Figure 1 3 (Vertical axis ·· Elongational viscosity, Horizontal axis: Time), which are the conditions of Comparative Example 3 Except that the amount of hydrogen was changed, the others were the same. The obtained polypropylene composition was changed in strain rate (7), and its elongation viscosity was measured. The measurement results are shown in Table 13 below.一一 I-. (Please read the notes on the back before filling this page) Order

Lf Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics [Table 1 3] Sample No. MFRU / 10 points) Strain rate (sec ~ 1) Xi PP-1 0. 5 0.021 Custom PP-2 1 0.020 Custom PP-3 2 0.017 -109- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 518352 A7 B7 ___ V. The invention (M) can be found from the results on M With conventional PP, even if the large deformation caused by elongation is imparted, the elongation viscosity value is concentrated to a certain value (Figure 13). In contrast, Η MS-Γί, after exceeding a certain amount of deformation, the viscosity will rise and the strain will appear. Hardening (Figure 12). This increase in viscosity is advantageous in foam molding or blow molding with large deformation. This strain-hardening property can also be seen in the electron beam irradiation method PP, ionomer, etc. of IZOMT. However, this is a phenomenon in which the polypropylene composition of the precursor is not usually seen. As mentioned above, it is confirmed that the HMS-PP of the present invention has significantly different features from the untreated PP, random PP, and block PP compared with the blank PP without the pre-activated catalyst containing high molecular ethylene. Or special excitement is more significant. It is presumed that this is due to the intermolecular interaction between the highly dispersed high molecular weight ethylene molecules and the polypropylene molecules. In addition, it was confirmed that even if the pre-activated catalyst powder containing high molecular weight ethylene was mixed with PP in the matrix, there would be no upward rheological behavior. FIG. 1 is a 7500-times photograph of the polymer composition of Example 26 of the present invention, as observed by a transmission electron microscope (TEM). FIG. 2 is an explanatory drawing added to make the photo of FIG. 1 easier to explain. Figure 3 is a TEM photograph of a conventionally known polypropylene. FIG. 4 is a drawing for explaining the photo of FIG. 3. Figures 5 to 7 are rheological behaviors of the polymer composition according to Examples 26 of the present invention, showing images of the storage strength coefficient G 'and the frequency ω. Figures 8 to 9 show the rheological behavior of the polymer composition according to Example 26 of the present invention, showing the relationship between the first normal stress difference N and the shear rate. -110- This paper size applies to Chinese National Standard (CNS) Α4 specification (210 χ 297 mm) L --------- installation ------ ^ order ------- (please Read the precautions on the back before filling in this page) 518352 A7 _B7___ V. Description of the invention (/ must be shown in Figure 1 0 ~ 1 1 is the rheological behavior of the polymer composition in Example 26 of the present invention, showing the element and the elastic coefficient G (t) Relationship with time. 11 2 ~ 1 3 are rheological behaviors of the polymer composition of Example 2 6 of the present invention S, showing the relationship between elongation viscosity and time. (Please read the precautions on the back before filling (This page) Printed on paper by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, the Chinese national standard (CNS M4 specification (210 x 297)) [Table 1] Examples Comparative Examples 1 2 1 2 Wood 3 3 4 Pre-polymerization <Polypropylene (B) &gt; Intrinsic viscosity [7? Β] (dl / g) 2.8 2.8 2.8 2.8 2.8 — Ship weight (g / g) 2.0 2.0 2.0 2.0 2.0 A composition ratio & (wt%) 0. 02 0.02 0.02 0.02 0.02 — pre-activated <polyethylene (A) &gt; intrinsic viscosity [7? A] (dl / g) 34.0 34 · 0 34.0 2.8 a fine amount ^ (g / g) 22.0 4.5 0.005 22.0 one one Composition ratio 12 (wt «0. 25 0. 05 0.0001 0. 25 — One addition polymerization <Polypropylene (C)> Intrinsic viscosity [77 C] (dl / g) 2.8 2.8 2.8 2.8 2.8 Production amount &lt; (g / g) 2.0 , 2.0 2.0 2.0 2.0 — Composition ratio (wt «0. 02 0. 02 0.02 0.02 0.02 — Intrinsic viscosity [77 D] (dl / g) 1. 89 1.90 1.89 1.89 1.89 1.67 Composition ratio (cut (wt« 99.7 99.9 100 99 · 100 100 100 Natural viscosity of propylene (co) polymer [77 P] (dl / g) 1. 89 1. 90 1.89 1. 89 1.89 1.67 Natural viscosity of propylene (co) polymer composition [77 T] (dl / g) 1.97 1.92 1.89 1.89 1.89 1.67 Melt tension (MS) (cN) 4.9 2.0 1.0 0.8 0.8 7.2 Crystallization temperature (0〇122.5 121.3 117.0 116.2 116.0 129.4 MFR initial (g / ΙΟ points) 3.5 4.1 4.5 4.5 4.5 9.2 Last (g / l0 points) 3.6 4.3 4.6 4.6 4.6 17.5 △ MFR (g / l0 points) 0.1 0.2 0.1 0.1 0.1 8.3 Remarks *: Relative to the amount of transition metal compound catalyst component is generated (g) 518352 1 2: Composition ratio of acrylic (co) polymer composition (wt%) * 3: Comparative Example 2: Pre-activated monomer using propylene [Table 2] Example Comparative Example 3 4 5 * 3 5 6 7 Wood 4 Prepolymerization <Polypropylene (B)>: Intrinsic viscosity [77 B] (dl / g) 2.7 2.7 2.7 2.7 2.7 — (g / g) 1.2 1.2 1.2 1.2 1.2 — Pirate than wood 2 ( at%) 0.01 0.01 0.01 0.01 0.01 — pre-activated <polyethylene (A)> inherent viscosity [7? A] (dl / g) 30.2 30.2 22.5 1 — 32.5 densities (g / g) 32.0 32.0 22.0 — 1 — Sincerity * 2 (wt3〇0.18 0.17 0.12 — 0.25 addition polymerization <polypropylene (C)> inherent viscosity [77 C] (dl / g) 2.8 2.8 2.2 2.8 2.2 — (g / g) 2.2 2.2 2.1 2.2 2.1 — Fiber ratio * 2 (rt%) 0.01 0.01 0.01 0.01 0.01 Intrinsic viscosity [7? D] (dl / g) during one polymerization 1. 75 1.63 1. 52 1. 75 1.52 1.89 Moth ratio * 2 (wt %) 99.8 99.8 99.9 100 100 99.7 Intrinsic viscosity of propylene (co) polymer [7? P] (dl / g) 1. 75 1.63 1.52 1. 75 1.52 1.89 Intrinsic viscosity of propylene (co) polymer composition [7? T ] (dl / g) 1.80 1.68 1.54 1. 75 1.52 1.97 Melt tension (M) (cN) 2.5 2.4 1.4 0.6 0.3 1.0 Crystallization temperature (° C) 122.0 122.7 121.2 116.1 115.2 116.2 MFR Initial (g &quot; 0 points) 6.0 8.1 15.4 7.2 16.7 3.5 Final (g / 10 points) 6.1 8.0 15.2 7.4 16.5 3.6 △ MFR (g &quot; 0 points) 0.1 -0.1 -〇 · 2 0.2 -0.2 0.1 518352 Remarks * 1: Relative transition metal compound catalyst component lg generation Amount (g) * 2: Composition ratio (wt%) of propylene-α-olefin copolymer composition * 3: Example 5: Pre-activated carcass uses a mixed gas of ethylene and propylene. * 4: Comparative Example 7: Mechanical simple mixing of polyethylene and formal polymerized polypropylene [Table 3] Comparative example of spring example 6 7 8 8 9 10 Prepolymerization <polypropylene (B)> inherent viscosity [7? B] ( dl / g) 2.7 2.8 2.8 2.7 2.8 2.8 Mechanical envy 1 (g / g) 1.2 2.0 2.0 1.2 2.0 2.0 Composition ratio 12 (wtX) 0.01 0.02 0.02 0. 01 0.02 0.02 Pre-activation <polyethylene (A) &gt; inherent Viscosity [7? A] (dl / g) 30.2 34.0 34.0 _ _ Machine weight ^ (g / g) 32.0 22.0 22.0 — — — Dirty ratio 12 ⑽) 0.21 0.26 0.24 One — — Addition polymerization <polypropylene (c) &gt; Intrinsic viscosity [77 c] (dl / g) 2.8 2.8 2.8 2.8 2.8 2.8 Kanji 1 (g / g) 2.2 2.0 2.0 2.2 2.0 2.0 Composition ratio (wttt 0.01 0.02 0.02 0.01 0.02 0. 02 Polymerization process (I) ⑽ ⑽ ) 0 0 2.1 0 0 2.1 Intrinsic viscosity [77 PP] (dl / g) 2.32 1.60 1. 88 2.29 1.71 d. 98 Composition ratio 2 _) 85.7 78.8 82.3 86.1 78.6 81.9 Polymerization process (Π) Ethylene (wtao 57 65 81 56 66 80 Intrinsic viscosity [77 RC] (dl / g) 4.84 3. 22 2.96 5. 29 2.97 2. 70 Composition ratio 12 _ 14.1 20.9 17.4 13.9 21.4 18.1 Intrinsic viscosity of propylene (co) polymer [7? P ] (dl / g) 2. 63 1.87 2. 00 2. 71 1.98 2.11 Propylene (co) polymer composition ethylene (wt ^) 8.2 13.8 14.3 7.8 14.1 14.5 Intrinsic viscosity [77 T] (dl / g) 2. 69 1.95 2. 08 2: 71 1.98 2.11 Melt tension (MS) (cN) 5.2 2.1 2.5 3.3 0.8 1.1 Crystallization temperature (° 〇121.9 121.5 116.8 116.0 115.8 110.3 MFR initial (g / l0 points) 0.52 3.0 2.0 0. 48 2.8 2.1 Final (g / l0 points) 0.51 3.1 1.9 0.48 2.9 2.0 △ MFR (g / l0 points) -0.01 0.1 -0.1 0.00 0.1 -0.1 Remarks * 1: Relative to the amount of transition metal compound catalyst component U produced (g ) 518352 1 2: Composition ratio (wtX) in the (co) polymer composition [Table 4] Examples Comparative Example 9 10 11 11 12 13 Prepolymerization <Polypropylene (B)> Intrinsic viscosity [77 B] (dl / g) 2.8 2.7 2.8 2.8 2 · 7 2.8 Production (g / g) 2.0 1.2 2.0 2.0 1.2 2.0 Sincerity ratio 12 (wt «0.02 0.01 0.02 0. 02 0.01 0. 02 Ethylene (A) &gt; Intrinsic viscosity [7? A] (dl / g) 34.0 30 · 2 34.0 1—First mechanical age 1 (g / g) 22.0 32.0 22.0 — — One composition ratio 12 (wt «0. 24 0.22 0.25--addition polymerization <polypropylene (C)> inherent viscosity [77 C] (dl / g) 2.8 2.8 2.8 2.8 2.8 2.8 mechanical envy 1 (g / g) 2.0. 2.2 2.0 2.0 2.2 2.0 composition ratio ( wtX) 0.02 0.01 0.02 0.02 0.01 0.02 Polymerization process (wtX) 2 · 4.6 2.6 2.4 2.5 4.9 2.4 Butene-1 (wtX) 0 0 3.9 0 0, 3.8 Intrinsic viscosity [7? D] (dl / g) 1.83 1.89 1.59 1.97 1.97 1.69 Composition ratio 12 (wt «99.7 99.8 99 · 100 100 100 Intrinsic viscosity of propylene (co) polymer [77 p] (dl / g) 1.83 1.89 1.59 1. 97 1.97 1. 69 propylene (co) polymer Composition ethylene (wtX) 2.9 4.8 2.7 2.5 4.9 2.4 Γ-ene-1 (wtX) 0 0 3.9 0 0 3.8 Intrinsic viscosity [77 T] (dl / g) 1.91 1.95 1.67 1. 97 1.97 1.69 Melt tension (MS) (cN) 1.8 1.9 1.3 0.7 0.7 0.3 Crystallization temperature (° C) 115.2 110.0 110.3 Can 109.4 4 102.9 104.8 MFR Initial (g / IOO points) 3 · 7 3.2 7.6 3.5 3.1 8.1 Last (g / IOO points) 3.6 3.0 7.6 3.4 2.9 7.9 AMFR (g / IOO points) -0.1 -0.2 0.0 -0.1 -〇 · 2 -0.2 Remarks * 1: Relative amount of transition metal compound catalyst component ig (g) 518352 1 2: Composition ratio (wt%) of propylene (co) polymer composition [Table 5] Examples Comparative Examples 12 13 14 14 15 16 Pre-activation <polyethylene (A) &gt; Intrinsic viscosity [77 A] (dl / g) 32.5 32.5 29 · 8-32.5 One ship period 1 (g / g) 22.2 4.5 32.0 — 0.005 with a composition ratio of 12 ⑽) 0. 25 0.05 0.18 a 0.0001 one addition polymerization <polypropylene (C)> inherent viscosity [77 C] (dl / g) 2.3 2.3 3.4 2.0 2.3 one ship period 1 (g / g) 2.0 2.0 2.2 2.0 2.0 — Composition ratio 12 ⑽) 0.02 0.02 0.02 0. 02 0.02 — Intrinsic viscosity during polymerization [77 D] (dl / g) 1.89 1.89 1. 75 1. 89 1.89 1. 75 Composition ratio 2 ⑽) 99.7 99.9 99.8 100 100 100 Natural viscosity of propylene (co) polymer 1 [77 p] (dl / g) 1.89 1.89 1. 75 1. 89 1.89 1. 75 Natural viscosity of propylene (co) polymer composition 〇 T] (dl / g) 1.97 1.91 1. 80 1. 89 1.89, 1.75 Melt tension (MS) (cN) 3 · 1.6 1.9 0.8 0.9 0.6 Crystallization temperature (° C) 121.5 120.8 121.0 116.1 116.2 116.0 MFR Initial (g / ΙΟ points) 3.5 4.2 6.0 4.5 4.5 7.2 Final (g / IOO points) 3.6 4.3 6.1 4.6 4.6 7.4 △ MFR (g / IOO points) 0.1 0.1 0.1 0.1 0.1 0.2 Remarks * 1: Relative to the amount of lg produced by the catalyst component lg (g) 518352 1 2: Composition ratio (wtX) of propylene (co) polymer composition [Table 6] Examples Comparative Example 1 Wood 3 16 17 17 1 8 Wood 4 19 Pre-activation <Polyethylene (A) &gt; Intrinsic viscosity [77 A] (dl / g) 30. 0 30.0 35.5 3.3 30.0 M11 (g / g) 25.0 6.5 29.0-16.6 0.005 Hatch ratio 12 (wtX) 0.35 0.09 0.18 — 0.23 0.0001 Intrinsic viscosity during polymerization [ 77 D] _) 1.89 1.89 1.68 1.89 1.89 1. 89 Composition ratio 2 (wt%) 99.6 99.9 99.8 100 99.8 100 Intrinsic viscosity of propylene (co) polymer [7? P] (dl / g) 1.89 1.89 1.68 1. 89 1.89 1.89 Propylene (co) polymer composition i Intrinsic viscosity [77 T] (dl / g) 1.99. 1.92 1.81 1.89 1.89 1.89 Melt tension (MS) (cN) 2.7 1.4 1.4 0.8 0.8 0.8 Crystallization temperature (° 〇120.9 119.8 120.0 116.1 116.2 116.2 MFR initial (g / l0 points) 3.3 4.1 5.9 4.5 4.5 4.5 final (g / l0 points) 3.3 4.2 6.0 4.6 4.5 4.6 AMFR (g / l0 points) 0.0 0.1 0.1 0.1 0.0 0.1 Remarks * 1: Relative to 1g of catalyst component of transition metal compound (g) 518352 1 2: Composition ratio (wU) of propylene (co) polymer composition Agriculture 3: Example 1 5: Pre-S-type 彳 b is used in the S body of a mixed gas of ethylene and propylene * 4: Comparative Example 1 8: ® active 彳 b is used in the single-unit 丙 [Table 7] Baoshi Example Comparative Example 18 19 2 0 2 1 Wood 3 22 2 3 Prepolymerization <Polypropylene (B) &gt; Intrinsic viscosity [77 B] (dl / g) 2.8 2.8 2.8 2.8 2.8 _ Thief material (g / g) 2.0 2.0 2.0 2.0 2.0: Younger ratio 12 ( wtX) 0.02 0.02 0. 02 0. 02 0.02 — pre-activated <polyethylene (A) &gt; intrinsic viscosity 0 A] (dl / g) 34.0 34 · 0 34.0 2.8 One Thief 1 (g / g) 22.0 4.5 0.005 22.0 I — 糸 ratio 12 ⑽) 0.25 0.05 0. 0001 0.25 — — addition polymerization <polypropylene (〇 &gt; intrinsic viscosity [77 c] (dl / g) 2.8 2.8 2.8 2.8 2.8 one epoch 1 (g / g) 2.0 _ 2.0 2.0 2.0 2.0 — specific ratio (wtX) 0.02 0.02 0.02 0. 02 0.02 intrinsic viscosity [77 〇] (dl / g) during polymerization 1.89 1.90 1.89 1.89 1.89 1.67 composition ratio 2 (wtX) 99.7 99.9 100 99 · 100 100 Natural viscosity of propylene (co) polymer [7? P] (dl / g) 1.89 1.90 1.89 1.89 1.89 1.67 Natural viscosity of propylene (co) polymer composition [7? T] (dl / g) 1.97 1.92 1.89 1.89 1.89 1.67 Melt Tension KHS) (cN) 2.1 1.2 0.9 0.8 0.8 6.8 Crystallization Temperature (V) 119.5 118.3 116.8 116.1 116.0 129.4 MFR Initial (g / l0 points) 3.6 4.2 4.6 4.5 4.5 9.2 Final (g / l0 points) 3.7 4.3 4.6 4.6 4.6 17.5 △ MFR (g / ΙΟ points) 0.1 0.1 0.0 0.1 0.1 8.3 Π Initial -0.5 -0.4 0.5 -0.6 -0.4 1.0 Last 1.5 1.5 1.4 1.5 1.6 3.5 ΔΥΙ 2.0 1.9 1.9 2.1 2.0 2.5 Remarks * 1 · Relative transition Production amount of gold catalyst compound catalyst component 18 (g) 518352 1 2: Composition ratio (Wt%) of propylene (co) polymer composition * 3: Comparative Example 2 1: Pre-activated carcass [Table 8] Example Comparative Example 2 0 2 1 2 4 2 5 2 6 Wood 3 Prepolymerization <Polypropylene (B)> Inherent Viscosity [77B] (dl / g) ”. 7 2.7 2.7 2.7 Yield M11 (g / g) 1.2 1.2 1.2 1.2 Yield ratio 12 (wt« 0.01 0.01 0.01 0.01 — pre-activated <polyethylene (A)> Intrinsic viscosity [7? A] (dl / g) 30.2 22.5 —-32.5 Machine weight 1: 1 (g / g) 32.0 22.0-One-to-one pulse ratio 12 m) 0.18 0.12 One-0.25 Addition polymerization (polypropylene ( C) &gt; Intrinsic viscosity [7? C] (dl / g) 2.8 2.2 2.8 2.2 Yield 1 (g / g) 2.2 2.1 2.2 2.1 — Composition ratio 12 (wttt 0.01 0.01 0.01 0.01 — Intrinsic viscosity during polymerization [ T7D] (dl / g) 1. 75 1.52 1. 75 1.52 1.89 Green ratio 12 (wtX) 99.8 99.9 100 100 99.7 Propylene (co) polymer 1 Intrinsic viscosity [/ 7 P] (dl / g) 1. 75 1.52 1. 75 1. 52 1.89 Intrinsic viscosity of propylene (co) polymer composition [/? T] (dl / g) 1.80 1.54 1. 75 1.52 1.97 Melt tension ^ milk) (cN) 1.2 1 · 0.6 0.6 1.0 Crystallization Melting temperature (° C) 119.0 118.5 116.1 115.2 116.0 MFR Initial (g / l0 points) 6.0 15.4 7.2 16.7 3.5 Last (g / l0 points) 6.1 15.6 7.3 16.5 3.6 △ MFR (gAO points) 0.1 0.2 0.1 -0.2. 0.1 YI initially -0.8 -0.4 -0.8 -0.3 -0.5 and finally 1. 4 1.5 1.3 1.8 1.5 ΔΥΙ 2.2 L9 2.1 2.1 2.0 Remarks * 1: Relative to the amount of transition metal compound catalyst component lg produced (g) 518352 1 2: Propylene-c (the composition ratio of the olefin copolymer composition (wt%) * 3: Comparative Example 26 6: Mechanical simple mixing of polyethylene and formal polymerized polypropylene 518352 [Table 9] Example 2 2 2 3 Prepolymerization <Polypropylene (B)> Intrinsic viscosity [7? B ] (dl / g) 2.8 2.8 铖 Correction (g / g) 2.0 2.0 糸 Pulse ratio * 2 (wt «0.02 0.02 Pre-activation <polyethylene (A) &gt; Intrinsic viscosity [7? A] (dl / g) 34.0 34.0 The amount of thief ^ (g / g) 22.0 22.0 The thief than snake (wt «0. 25 0.25 addition polymerization <polypropylene (C)> inherent viscosity [77 c] (dl / g) 2.8 2.8 (g / g) 2.0 2.0 Pirate (wt%) 0.02 0.02 Intrinsic viscosity during polymerization [7? D] (dl / g) 1. 89 1.89 Composition ratio * 2 ⑽) 99.7 99 · 7 Inherent in propylene (co) polymer Viscosity [7? P] (dl / g) 1. 89 1.89 Propylene (co) polymer composition 'inherent viscosity [77 T] (dl / g) 1.97 1.97 Melt tension (MS) (cN) 2.8 2.5 Crystallization temperature (0〇120.7 119.8 MFR Initial (g / 10 points) 3.5 3.5 Last (g / 105 ^) 3.6 3.6 △ MFR (g &quot; 0 points) 0.1 0.1 YI first -0.5 -0.6 last 2.5 2.1 ΔΥΙ 3.0 2.7 Remarks * 1 ·· The amount of 1g of the transition metal compound catalyst component (g) * 2: Propylene (total) Composition ratio (wtS :) in polymer composition 518352 [Table 1 〇] Comparative Example 2 4 2 7 Prepolymerization <Polypropylene (B)> Intrinsic viscosity [77 B] (dl / g) 2.8 2.8 Kanji 1 (g / g) 2.0 2.0 Composition ratio 12 (wt%) 0.02 0.02 Pre-activation <polyethylene (A) &gt; Intrinsic viscosity [77 A] (dl / g) 34.0 — throw correction (g / g ) 22.0 — fiber ratio 12 (wt «0.25 one addition polymerization <polypropylene (C) &gt; intrinsic viscosity [77 C] (dl / g) 2.8 2.8 thief ^, (g / g) 2.0 2.0 composition ratio ^ ( wt%) 0.02 0.02 Polymerization process (〇 Intrinsic viscosity [7? Pi] (dl / g) 1.59 1. 77 Composition ratio ^ (wt%) 43.9 40.9 Polymerization process (π) Intrinsic viscosity [77 Ρ2] (dl / g) 2.29 2.21 Composition ratio 12 (wt5〇38.9 37.0 Polymerization process (melon) Intrinsic viscosity [77 P3] (dl / g) 3.86 3. 84 Composition ratio ^ (wt%) 16.9 22.1 Intrinsic viscosity of propylene (co) polymer [77 P ] (dl / g) 2. 25 2. 39 Propylene (co) polymer Intrinsic viscosity of the product 〇 T] (dl / g) 2.33 2. 39 Melt tension (MS) (cN) 9.9 3.4 Crystallization temperature (° C) 122.3 116.3 MFR Initial (g / l0 points) 1.3 1.1 Final (g / l0) Points) 1.4 1.1 △ MFR (g / ΙΟ points) 0.1 0.0 Remarks 1 ι: Relative amount of transition metal compound catalyst component ig (g) * 2: Composition ratio of propylene (co) polymer composition ( wu) 518352

[Table 1 1] Example 2 5 Prepolymerization <Polypropylene (B)> Intrinsic viscosity [;? B] (dl / g) 2.8 繊 比 木 1 (wtX) 0. 02 Preactivation <polyethylene (A ) &gt; Intrinsic viscosity [77 A] (dl / g) 34.0 Composition ratio Wood 1 (nt%) 0.12 Addition polymerization <Polypropylene (C)> Intrinsic viscosity [7? C] (dl / g) 2.8 Young ratio * 1 (wt%) 0.02 Intrinsic viscosity of propylene (co) polymer [7 P] (dl / g) 1. 89 Intrinsic viscosity of propylene (co) polymer composition [77 T] (dl / g) 1.93 Melt tension ( MS) (cN) 2.4 Crystallization temperature (° C) 119.8 MFR Initial (g / 10 points) 4.0 Last (g / 10 points) 4.1 AMFR (g / 10 points) 0.1

Remarks * 1: Relative to the amount of catalyst component produced by the transition metal compound (g)

Claims (1)

518352 VI. Application for Patent Scope f (丨 (Root No. 8 5 11 2 6 2 No. 8 Patent Application Application Amendment of Patent Scope (please read the precautions on the back of 7V and then fill out this page)) 7 ^ —a kind of acrylic 1 total) The polymer composition,-'is characterized by: This composition contains: (a) an ethylene homopolymer or an ethylene-1 olefin copolymer containing 50% by weight of an ethylene polymerization unit, and a naphthalene compound at M 1 3 5 ° C The measured intrinsic viscosity [7? E] is 0.01 to 5.0 parts by weight of high molecular weight polyethylene in the range of 15 to 100 dl / g, and (b) 100 parts by weight of propylene (co) polymer; (c) Also, The above-mentioned high molecular weight polyethylene is a micro-dispersed fine particle having an average particle diameter in the range of 1 to 500 μm. 2. The propylene (co) polymer composition according to item 1 of the patent application scope, wherein the high molecular weight The number average particle diameter of polyethylene is in the range of 10 to 500 nm. 3 · The propylene (co) polymer composition according to item 1 of the patent application scope, wherein the propylene (co) polymer composition The intrinsic viscosity [η] measured by naphthalene at K 1 3 5 ° C is between 0.2 and 1 Within the range of 0 dl / g. 4. The propylene (co) polymer composition according to item 1 of the patent application range, wherein the propylene (co) polymer is composed of a propylene homopolymer or contains 50 units by weight of propylene polymerization units. % K selected from the above propylene-olefin copolymers. * 5. For example, the propylene (co) polymer composition of the first patent application scope, wherein the propylene (co) polymer composition has, in Does not contain rubber ingredients or paper size. Applicable to China National Standard (CNS) A4 size (210 X 297 mm) 0 ^ 8822 ABCD 518352 々, patent application scope (please read the notes on the back and write this page) ) In the original state of the inorganic filler, the storage elastic coefficient at a frequency of ω = 1 0 0 at 230 ° C is (ω = 1 0G) and the storage at a frequency of ω = 1 0-2 When the coefficient is -G 'Γω ^ ΤΟ ~ 2), (G' ㊉ = i 〇.))-! 0 g (G, U = 10- 2)) &lt; 2. 6. The propylene (co) polymer composition according to item 1 of the patent application scope, wherein the propylene (co) polymer composition has a temperature of 190 ° C, 230 ° The first normal stress difference I at a shear rate of 4 X 1 0-1 (sec-1) at 2 5 0 ° C is 1 (^ (1) &gt; log (MFR) +5) 7. The propylene (co) polymer composition according to item 1 of the patent application scope, wherein the propylene (co) polymer composition has 4X10-1 at 190 ° C and 250 ° C The first normal stress difference N i (1 0 0 ° C) and N i (2 5 0 t) at the shear rate of (sec-1) is [N jl (1 9 0 ° C)-N i ( 2 5 0 ° C)] / N i (19 0 ° C) &lt; 0.6. 8. The propylene (co) polymer composition according to item 1 of the scope of patent application, wherein the propylene (co) polymer composition has a temperature of 3X 10 to 1 (1 90 ° C and 2 5 Q ° C). sec — 1) Melting tension MS (190 ° C) and MS (25G ° C) under the shear speed, it is [MS (190 ° C) -MS (25 0 ° C)] / MS (190 ° C) Relations shown in &lt; 3.1. 9. The propylene (co) polymer composition according to item 1 of the scope of the patent application, wherein the propylene (co) polymer composition has a strain of 500% of the melt at 23 ° C and t = 10 When the relaxation elastic coefficient of (sec) is G (t = lG) and the relaxation elastic coefficient of t = 3 0 0 (sec) is G (t = 3 0 0), [G (t = 1 0) -2- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) 518352 A8 B8 C8 D8 VI. Patent application scope-G (t = 3 0 0)] / G (t = 10) &lt; 1 Show related persons. (Please read the notes on the back before writing this page) 10. If the propylene (co) polymer composition of item 丨 of the patent application is applied, I propylene (co) + polymer composition, when jTM is extended The elongation viscosity 'rises in a large deformation region and shows strain hardening. 1 1 · The propylene (co) polymer composition according to item 1 of the scope of patent application, wherein the high molecular weight polyethylene particles are added before propylene (co) polymerization or propylene (co) polymerization. 12. For example, the propylene (co) polymer composition of the scope of application for a patent, wherein the propylene (co) polymer is a propylene homopolymer or a propylene-olefin copolymer having 50% by weight of propylene polymerization units, The propylene (co) polymer composition has a log (MS) between the melt tension (MS) at 23 G ° C and the intrinsic viscosity [η T] measured in naphthalene at 1 35 ° C. ; 4.24 X log [π T] -i · 20 relationship. 13. For example, the propylene (co) polymer composition of the scope of application for patent, wherein the propylene (co) polymer is a propylene homopolymer or a propylene-olefin copolymer containing 50 weight of propylene polymerization units, and the propylene The (co) polymer composition has a melt tension (MS) at 230 and an intrinsic viscosity [η T] measured in naphthalene at 13.5 ° C, which has a ratio of 4 · 2 4 X 1 〇g [ η T] + 0 · 2 4 &gt; 10 g (MS) M · 24 × 10 g [0τ] -1 · 10. It is the propylene (co) polymer composition according to item 1 of the scope of patent application, which is at least 100 parts by weight relative to the propylene (co) polymer composition, and further adds at least the selected amount of stomach S _ antioxidants and phosphorus antioxidants. A stabilizer 0 · 0 0 1 ~ 2 parts by weight. -3-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 518352 398 8 25 ABCD VI. Application for patent scope 15. If the propylene (co) polymer composition of the first patent scope Wherein, the propylene (co) polymer is a propylene homopolymer or a propylene-olefin copolymer containing 50% by weight or more of a propylene polymerization unit, which is propylene alone or propylene in the presence of a preactivation catalyst. Formed by formal (co) polymerization with other olefins having 2 to 12 carbons; the pre-activated catalyst contains: a transition metal compound catalyst component containing at least a titanium compound The organometallic compound (AL1) of metal selected from the metal groups of Group 1, Group 2, Group 12, and Group 13 of the Periodic Table (1991 edition) with ears ranging from 0.01 to 10,000 moles and relative A catalyst for polyolefin production composed of a combination of a transition metal atom of 1 mole to an electron donor (E 1) of 0 to 500 moles, M, and polyethylene supported on the catalyst. 16. The propylene (co) polymer composition according to item 15 of the scope of patent application, which is in the presence of a formal (co) polymerization catalyst for olefins. * Separate propylene alone or other olefins with propylene and 2 to 12 carbons. Formed by formal (co) polymerization; the olefin formal (co) polymerization catalyst is further contained in the preactivated catalyst: an organometallic compound (AL 1) with a metal contained in the preactivated catalyst ) In total, relative to 1 mole of the transition metal atom in the pre-activated catalyst, 0.05 to 5000 moles belong to Group 1, Group 2, Group 12 and Group 1 of the Periodic Table (1991). The organometallic compound (AL2) of the selected metal of the group is a total of 0 to 30 moles of the transition metal atom in the preactivated catalyst and the electron donor (E1) contained in the preactivated catalyst. 00 mol electron donor (E 2). 1 7 · If the propylene (co) polymer composition in item 15 of the scope of patent application -4-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 518352 A8 B8 C8 D8 VI. Application The scope of the patent, in which the pre-activated catalyst contains 1 g of the transition metal compound catalyst component of cypress, which has an intrinsic viscosity [η A] measured in naphthalene at 1 3 5 ° C of 15 to 100 ( 11 ^ range of polyethylene 0.01 ~ 50 (^. 18. For example, the propylene (co) polymer composition of the 15th or 16th in the scope of patent application, wherein the pre-activated catalyst is supported relatively The transition metal compound catalyst component 1 g is 1 3 5 ν. The intrinsic viscosity [π B] is less than 15 dl / g, which is a propylene homopolymer or a propylene-olefin containing 50% by weight of propylene polymerization units. Copolymer of polypropylene (B) 0.01 to 100 g, and polyethylene having an intrinsic viscosity [ΠA] of 15 to 100 dl / g measured in the range of 135 ° CM to 0.01 to 50 fl0 g. 19. If the scope of patent application is 15th Or the propylene (co) polymer composition of item 16, wherein the propylene homopolymer or propylene-containing polymerized unit 5 Propylene-olefin copolymer on weight% M, relative to the (co) polymerization volume of propylene or propylene and other olefins, 1 liter, converted to the transition metal atom in the catalyst, based on the 0.001 to 100G millimolar touch The manufacturer of the medium. 2 · The propylene (co) polymer composition as described in the first item of the patent application scope, wherein the propylene (co) polymer is (a) a propylene homopolymer or a propylene-containing polymerization unit at 50% by weight The above propylene-olefin copolymer is a propylene (co) polymer made by the formal (co) polymerization of propylene alone or propylene with other olefins having 2 to 12 carbons in the presence of a preactivated catalyst; and (B) Propylene homopolymers or propylene-olefin copolymers containing more than 50% by weight of propylene polymerization units; mixtures; This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----- ---------------............. Order! Γ, ... (Please read the notes on the back before writing this page) 518352 A8 B8 C8 D8 6. Scope of patent application (please read the precautions on the back before writing this page) This pre-activated catalyst contains Catalyst component of transition metal compound containing at least a titanium compound, 0.01 to U 1 mole of transition metal atom) 〇0 ^ &quot; ^: The reason belongs to Group 1, Group 2, and 12 of the Periodic Table (1991 edition) And a group consisting of metals of Groups 1 and 3 and a combination of organometallic compounds (AL1) of the selected metal and an electron donor (E 1) of 0 to 50 Q mole relative to 1 mole of the transition metal atom. Catalyst for polyolefin production, M, and polyethylene supported on the catalyst. 2 1. A method for preparing a propylene (co) polymer composition, which is characterized in that: in the presence of a preactivated catalyst, olefin (co) polymerizes * to make a propylene (co) polymer; the prepolymer Activated catalysts, which contain: transition metal compound catalyst components containing at least titanium compounds, 0.01 to 1,000 mol relative to 1 mol of transition metal atoms, belong to Group 1, Group 2, Periodic Table (1991 edition), Group 12 and Group 13 metals are selected from the group consisting of organometallic compounds of metal (AL1) and an electron donor (E 1) of 0 to 500 mol relative to 1 mol of transition metal atom. Catalyst for polyolefin production, K, and the titanium-containing solid catalyst component 1 g supported on the catalyst, with an inherent viscosity of 0.1 g to 500 g, measured at 135 ° C in naphthalene [Η] is 15 to 100 dl / g of polyethylene composed of an ethylene homopolymer or an ethylene-cx-olefin copolymer containing 50 weight of ethylene polymerization units. 22. The method for preparing a propylene (co) polymer according to item 21 of the application, wherein the olefin used in the (co) polymerization is a simple propylene or an olefin having 2 to 12 carbons; the propylene (co) polymerization Propylene homopolymer or propylene containing 50 units of propylene and carbon with 2 to 12 olefins. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 518352 A8 B8 C8 D8 Six Co-polymers of hydrocarbons for patent applications. (Please read the precautions on the reverse side and rewrite this page) 23 · If the propylene (co) polymer manufacturing method in the scope of patent application No. 21, the pre-activated catalyst, and then added: (a) relative The titanium atom in the pre-activated catalyst is 1 mole, and the total amount of the organoaluminum compound (AL1) contained in the pre-activated catalyst is 0 · Q5 ~ 5 00 00 mole of the organoaluminum compound (AL2), and ( b) Relative to the titanium atom i Mol in the preactivated catalyst, the electron donor (E 1) contained in the preactivated catalyst is 0 ~ 3 Q 0 G Mol electron donor (E 2 ). 24. The method for preparing a propylene (co) polymer according to item 21 of the patent application, wherein the amount of the catalyst is 0.01 to 1000 mmol in terms of the titanium atom in the catalyst, relative to the olefin (co) polymerization volume of 1 liter. Ears. 25. The method for preparing a propylene (co) polymer according to item 21 of the application for a patent, wherein the pre-activated catalyst contains, in addition to polyethylene M, a catalyst component of a transition metal compound supported on the catalyst 1 g, the inherent viscosity [π B] measured in 1 3 5 t naphthalene is a propylene homopolymer smaller than 15 dl / g or polypropylene containing propylene-olefin copolymer at 50% by weight of propylene polymerization unit ( B) 0 · 01 to 100g. 2 6. The method for preparing a propylene (co) polymer according to item 25 of the patent application scope, wherein the amount of the catalyst is 1 liter relative to the (co) polymerization volume of the olefin, and is converted into a transition metal atom, which is 〇1 ～ 100. (1 millimolar. 27. The method for preparing a propylene (co) polymer as claimed in item 21 of the scope of patent application, which includes: (a) The paper size applies to China where the transition metal compound containing: at least a titanium compound is in contact with the paper. National Standard (CNS) A4 Specification (210 X 297 mm) 518352 A8 B8 C8 D8 VI. Patent Application Scope (Please &amp;-Read the notes on the back and fill out this page) The media composition and the relative transition metal atom 1 mol is 0 · 01 ~ 10 GO Mor is an organometallic compound of a metal selected from the group consisting of metals belonging to Groups 1, 2, 12, and 13 of the Periodic Table (1991), UL 1) In the presence of a catalyst for the production of polyolefin composed of a combination of an electron donor (E1) with D to 50 G mol relative to the transition metal atom 1 mol, the olefin is (co) polymerized to produce 1 3 Intrinsic viscosity [η] measured in naphthalene at 5 ° C is smaller than 15 dl / g The pre- (co) polymerization process of the transition metal compound catalyst component lg is 0.001 to 100 g of polyolefin (B); M and (b), and then, the olefin is (co) polymerized to generate naphthalene at 135 ° C The pre-activation (co) polymerization process of polyethylene (A) with a natural viscosity [7?] Of 15 to 100 dl / g and a transition metal compound catalyst component lg of O.Olg to 5 0 0 0, measured in Manchuria; (c) In the presence of a pre-activated catalyst for olefin (co) polymerization obtained by polyolefin (B) and polyethylene (A) on K by a method of supporting a catalyst component of a transition metal compound, The olefin having a carbon number of 2 to 12 is (co) polymerized. 28. The method for preparing a propylene (co) polymer as claimed in item 21 of the patent application scope, wherein: (a) In the transition metal compound catalyst component containing at least a titanium compound, the relative transition metal atom 1 mole is 0.01 ~ GGO Mor's organometallic compound (AL 1) and relative transition metal of selected metals from the group consisting of metals belonging to Group 1, Group 2, Group 12 and Group 13 of the Periodic Table (19 91 edition) Atom 1 Molar is 0 ~ 500 Molar Electron Donor (Ei) Group 1 8- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 518352 A8 B8 C8 D8 VI. Patent Application In the presence of a catalyst for polyolefins, the olefin is (co) polymerized, and the intrinsic viscosity [π] measured at the 135 ° C full-scale limit is smaller than 15 dl / g, and M is relatively transitional. The metal compound component lg generates a pre- (co) polymerization process of 0.01 g to 100 g, and then, the olefin is (co) polymerized, and the inherent viscosity [n] determined by Cai Manzhong at 135 ° C is 15-100 dl / g Polyethylene (A), M-b G.Olg ~ 500 g pre-activation (co) polymerization process; olefins (co-) obtained by a method of carrying polyolefin (B) and polyethylene (A) by supporting a catalyst component of a transition metal compound ) Polymerization pre-activation catalyst; (b) 1 mol of transition metal atom in pre-activation catalyst, and organometallic compound of metal contained in pre-activation catalyst for olefin (co) polymerization ( AL1) In total, it is 0.05 to 5 0 0 Mor. The organometallic compound of a metal selected from a group of metals belonging to Group 1, Group 2, Group 12, and Group 13 of the Periodic Table (1991 edition) ( AL2); and (c) 1 mole relative to the transition metal atom in the pre-activated catalyst, and the total amount of the electron donor (E 1) contained in the pre-activated catalyst for olefin (co) polymerization is 0 to 3000 Mohr's electron donor (E2); Formally (co) polymerizes an olefin in the presence of a propylene (co) polymerization catalyst. 2 9. The method for preparing a propylene (co) polymer according to item 21 of the scope of patent application, wherein after the (olefin) polymerization of the olefin, at least one stabilizer selected from the group consisting of a phenolic antioxidant and a phosphorus antioxidant, Add 0 · GG 1 ~ 2 weight. This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) f! (Please read the notes on the back and transcribe this page) II 518352 A8 B8 C8 D8 Patent application scope ugrl species 1 2 No. Encircle λ · β $ A total of 0 to obtain polypropene, a group of compounds, and allyl groups. (Please apply for the polymerization of the group of compounds of phase compounds \ f / ± h (/ fv Alkene obtained 〇 The method and method of mixing 0 Wai Cao Fan M's weight and weight, tr ο ο ο Amount 2 weight ~ ο ο 10M (Please read the notes on the back and write this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)