TW518234B - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
TW518234B
TW518234B TW88105768A TW88105768A TW518234B TW 518234 B TW518234 B TW 518234B TW 88105768 A TW88105768 A TW 88105768A TW 88105768 A TW88105768 A TW 88105768A TW 518234 B TW518234 B TW 518234B
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Taiwan
Prior art keywords
cosmetic composition
weight
zeolite
composition
product
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TW88105768A
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Chinese (zh)
Inventor
Kenzo Koike
Masaki Shimizu
Junichi Fukasawa
Hiroshi Ota
Tsutomu Fujimura
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Kao Corp
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Priority claimed from JP10101079A external-priority patent/JPH11292730A/en
Priority claimed from JP10107698A external-priority patent/JP3544120B2/en
Priority claimed from JP10107898A external-priority patent/JPH11292729A/en
Priority claimed from JP10107798A external-priority patent/JPH11292735A/en
Priority claimed from JP10118716A external-priority patent/JPH11310797A/en
Application filed by Kao Corp filed Critical Kao Corp
Application granted granted Critical
Publication of TW518234B publication Critical patent/TW518234B/en

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Abstract

A non-aqueous cosmetic composition contains (A) activated zeolite, (B) a polyhydric alcohol having a molecular weight not higher than 1,000, and (C) a high molecular compound soluble in the ingredient (B). When shaken upon use, the cosmetic composition permits ready and even dispersion of the zeolite, exhibits good spreadability and compatibility on the skin and can be readily applied over a wide area. Moreover, the cosmetic composition also has excellent massaging effect.

Description

518234 五、發明說明α) 發明背景 a) 發明領域 本發明有關一種可對皮膚展現良好塗佈性及相容性及優 異按摩效果之化粧品組合物。 b) 相關技藝描述 有助於按摩之習知化粧品組合物包含添加有沸石以利用 其水合熱而賦與增溫感者、及添加有多種粉末以利用其磨 洗效果者。其中,利用水合後放出熱之沸石(活化沸石)之 化粧品組合物已知包含揭示於USP 3, 2 5 0, 6 8 0、曰本特開 a召6 1 - 2 0 4 1 1 1及日本特開平6 - 1 0 0 4 1 1者。其據描述可促進 血液循環及使用時由於沸石水合熱而提供良好舒適感。 此種粉狀物質長期保持沈澱狀,經過結塊而變得難以再 分散。因此,含有該等粉狀物質之化粧品組合物通常藉使 用增稠劑轉化成凝膠系統,因此粉狀物質維持均勻分散。 然而,此種膠凝系統損及其對皮膚之塗佈性及相容性, 因此難以以身體製劑塗佈於廣面積上。 發明概述 因此本發明之目的為提供一種化粧品組合物,其對皮膚 展現良好塗佈性及相容性且易於塗佈至廣面積之身體表 面。 本發明者發現含有與水接觸後可釋出熱之沸石(活化沸 石)、特定多元醇及高分子化合物之非水性化粧品組合物 當使用搖晃時可使沸石均勻分散,且此非水性化粧品組合 物對皮膚展現良好塗佈性及相容性,可易於塗佈至廣面積518234 V. Description of the invention α) Background of the invention a) Field of the invention The present invention relates to a cosmetic composition which can exhibit good applicability and compatibility to the skin and excellent massage effect. b) Description of related techniques. Conventional cosmetic compositions that are helpful for massage include those who have added zeolite to use the heat of hydration to impart a warming sensation, and those who have added various powders to take advantage of their abrasive effect. Among them, a cosmetic composition using zeolite (activated zeolite) that emits heat after hydration is known to contain disclosed in USP 3, 2 5 0, 6 8 0, Japanese Patent Publication No. 6 1-2 0 4 1 1 1 and Japan JP 6-1 0 0 4 1 1 It is described to promote blood circulation and provide good comfort due to the heat of zeolite hydration during use. This powdery substance remains precipitated for a long time, and becomes difficult to redisperse after agglomeration. Therefore, cosmetic compositions containing these powdery substances are usually converted into a gel system by using a thickener, so that the powdery substances remain uniformly dispersed. However, such a gelling system impairs its applicability and compatibility to the skin, and therefore it is difficult to apply the body preparation over a wide area. SUMMARY OF THE INVENTION It is therefore an object of the present invention to provide a cosmetic composition which exhibits good applicability and compatibility to the skin and is easy to apply to a wide area of the body surface. The present inventors have found that a non-aqueous cosmetic composition containing a zeolite (activated zeolite), a specific polyol, and a polymer compound that can release heat after contact with water can uniformly disperse the zeolite when shaking, and the non-aqueous cosmetic composition Shows good applicability and compatibility to the skin, and can be easily applied to a wide area

第6頁 518234 五、發明說明(2) 亦具有優異按摩效果 水性化粧品組合物中 清潔劑。 此外,亦 可獲得亦 發現添加界面活性劑至非 具優異放熱性及安定性之 本發明一目的中,提供一種非水性化粧品組合物,包括 (A)活化沸石、(B)分子量不大於1,000之多元醇,及(C)可 溶於成分(B)之高分子化合物。 本發明另一目的中,亦提供一種實質上非水性清潔劑組 (B)分子量不大於1,000之多元 高分子化合物,及(F )界面活性 合物 醇, 劑。 本 增溫 如當 得舒 於分 於廣 產品 另 清潔 劑、 劑、 皂。 洗皂 發明 ,包括(A )活化沸石, (C)可溶於成分(B)之 發明之化 感且由於 化粧品組 適溫熱感 散彿石’ 面積之身 ,如乳液 一方面, 劑或清洗 洗碗機清 抗黴劑、 尤其適合 粧品組合物 粉末之磨洗 合物塗佈至 。使用搖晃 對皮膚呈現 體表面上。 、乳霜、牙 含有界面活 劑,包含衣 潔劑、洗車 沐浴組合物 作為沐浴組 與水接 效果而 以洗澡 時,此 良好塗 因此可 膏或軟 性劑之 物清潔 清潔劑 、洗髮 合物、 詳細說明及較佳具體例 觸時,由於水合熱而提供 呈現優異之按摩效果。例 水浸溼之皮膚上時,可獲 化粧品組合物可均勻且易 佈性及相容性且易於塗佈 使用作為按摩目的之化粧 膏。 清潔劑組合物可使用作為 劑、清洗劑、洗碗清潔 、工具清潔劑、家用清潔 精、洗臉組合物及手洗 洗髮精、洗臉組合物及手Page 6 518234 V. Description of the invention (2) It also has excellent massage effect Cleaner in water-based cosmetic composition. In addition, it is also possible to obtain a non-aqueous cosmetic composition, including (A) activated zeolite, (B) molecular weight of not more than 1, in a purpose of the present invention where it is also found that adding a surfactant is not excellent in heat release and stability. 5,000 polyols, and (C) polymer compounds soluble in component (B). In another object of the present invention, there is also provided a substantially non-aqueous detergent group (B) a multivalent polymer compound having a molecular weight of not more than 1,000, and (F) an interfacial active compound alcohol. This warming Rudang Deshu is divided into Yuguang products and other cleaning agents, agents, soaps. Soap-washing invention, including (A) activated zeolite, (C) soluble in ingredient (B) of the invention, and due to the cosmetics group ’s temperature and heat-sensing properties, such as lotions, agents or cleaning Dishwasher anti-mildew agent, especially suitable for applying the abrasive composition of powder to the cosmetic composition. Use shaking to show the skin on the body surface. , Cream, teeth contain surfactants, including laundry detergent, car wash bath composition as a bathing group with the effect of water to take a bath, this is a good coating so it can be a cream or softener cleaning cleaners, shampoos When detailed explanation and preferred specific examples are touched, it provides excellent massage effect due to hydration heat. Example When the skin is wet with water, a cosmetic composition can be obtained which is uniform, easy to spread and compatible, and easy to apply. A cosmetic cream used for massage purposes. The detergent composition can be used as a detergent, a cleaning agent, a dishwasher cleaner, a tool cleaner, a household cleaner, a face wash composition and a hand wash, a shampoo, a face wash composition and a hand

518234518234

五、發明說明(3) 使用作為本發明成分(A)之活化(或放熱)沸石並备 限制。由供應性及成本考量,較好包含以下 …主、一 沸石3 A、沸石4 A及沸石5 A : 式表不之 及X、y及z代表平均 離子交換處理及中和 Μχ0 · Al2〇3 · ySi02 · zH2〇 其中M代表驗金屬及/或驗土金屬, 值◦再者,亦可使用進行特殊處理如 處理之彿石。 由水合率及使用感觀之,該等沸石較好粒徑為〇1至2⑽ 微米,尤其自1至1 〇 〇微米。 該等沸石可藉本技藝本身已知之方法進行製造、純化、 研磨、鍛燒及分類而獲得。如歐洲專利號1 8 79 1 2〔日本特 開昭61。-2 04 1 1 1號〕所述,所需活性之沸石可藉由在約3〇寸〇 至6 0 0 C下鍛燒原料沸石並使其脫水,再使其置於 * 氣中而得。 、 木工 活=沸石吸收某些量之氣體,因此與水反應時釋放出氣 體’猎由釋放之氣體,#内充填有組合物之容器將引致膨 脹。、為避免此潛在問題,本發明中較好使活化濟石在與其 他成分混合前在加熱或減壓下進行脫氣體處理。至於脫氣 =件,較好在7Gt或更高溫及㈣0托耳或更錢下(尤 /、f 90至150 c及60托耳或更低壓)下進行脫氣處理1至24 =體料^已充分進行可藉測量沸石《氣體吸附相 二疋一氣拉吸附性可藉述於例如日本特公平8 - 5 7 7 0所过 方法測量。或者,可藉添加為沸石兩倍量之水至沸石本身 518234 五、發明說明(4) 或含沸石之化粧品於密封容器中,接著測量釋放出之氣體 量之方法測量。 由避免氣體釋出及容器變形之觀點來看,氣體吸附為2 毫升/克或更低,又進一步為1毫升/克或更低,顯著為0.5 毫升/克或更低。 再者,可藉混合沸石及乙醇而移除氣體。當例如沸石為 沸石4 A時,可吸附在沸石上之乙醇量理論上約為沸石之3 0 重量%。因此,較好混合3 0重量份或更多之乙醇及1 0 0重量 份之沸石,以沸石/乙醇比例自1 0 0 / 5 0至1 0 0 / 5 0 0 (重量比) 尤佳。 為了有效移除氣體成份,沸石可在乙醇存在下加熱、解 壓或加壓。就熱處理而言,30 °C或更高溫,尤其是50至90 °C較佳。處理時間並無特別限制,實務上為1小時至3天。 較好使用純度9 5 %或更高,尤其9 8%或更高之乙醇。 由組合物之放熱性質及塗佈性觀點觀之,本發明化粧品 組合物中沸石使用比例較好為1至6 0重量%,尤其自5至4 0 重量%,典型上自10至30重量%。 使用作為本發明成分(B )之多元醇為分子量不大於1,0 0 0 者。分子量大於1,000之許多多元醇具高熔點且不適宜作 為主要成分。但不排除以小比例使用。 分子量不大於1,0 0 0之多元醇並無特別限制,只要是普 遍用於化粧品者即可。例如烷二醇如乙二醇、丙二醇、丁 二醇、戊二醇、異戊二浠二醇及己二醇;二烧二醇如二乙 二醇、二丙二醇、二乙二醇單甲醚、二乙二醇單乙醚;脂V. Description of the invention (3) The activated (or exothermic) zeolite used as the component (A) of the present invention is limited. In terms of availability and cost considerations, it is preferable to include the following: main, monozeolite 3 A, zeolite 4 A, and zeolite 5 A: where the formula is not as good as X, y, and z represent the average ion exchange treatment and neutralization Μχ0 · Al2〇3 · YSi02 · zH2〇 Where M stands for metal and / or soil metal, value ◦ Furthermore, it is also possible to use a special treatment such as Buddha stone. From the hydration rate and the sense of use, the preferred particle size of these zeolites is from 0.01 to 2 μm, especially from 1 to 1000 μm. These zeolites can be obtained by methods known in the art per se for manufacturing, purification, grinding, calcination and classification. Such as European Patent No. 1 8 79 1 2 [Japanese Patent Laid-Open No. 61. -2 04 1 1 1], the desired zeolite can be obtained by calcining the raw zeolite at about 30 inches to 600 ° C. and dehydrating it, and then placing it in * gas. . Woodworking activity = zeolite absorbs a certain amount of gas, so it releases gas when reacting with water. The gas released is caused by the reaction. # The container filled with the composition will cause expansion. In order to avoid this potential problem, in the present invention, it is preferred that the activated zeolite be subjected to degassing treatment under heating or reduced pressure before being mixed with other ingredients. As for degassing = pieces, it is better to perform degassing treatment at 7 Gt or higher and ㈣0 Torr or less (especially, f 90 to 150 c and 60 Torr or lower pressure) 1 to 24 = bulk ^ The zeolite can be measured by measuring the gas-adsorbed phase and the gas-adsorbed property by, for example, the method described in Japanese Patent Publication No. 8-5770. Alternatively, it can be measured by adding twice the amount of water as zeolite to the zeolite itself. 518234 V. Description of the Invention (4) or cosmetics containing zeolite in a sealed container, followed by measuring the amount of released gas. From the standpoint of avoiding gas release and container deformation, the gas adsorption is 2 ml / g or less, further 1 ml / g or less, and significantly 0.5 ml / g or less. Furthermore, the gas can be removed by mixing zeolite and ethanol. When, for example, the zeolite is zeolite 4 A, the amount of ethanol that can be adsorbed on the zeolite is theoretically about 30% by weight of the zeolite. Therefore, it is preferable to mix 30 parts by weight or more of ethanol and 100 parts by weight of zeolite, and the ratio of zeolite / ethanol from 100/50 to 100/500 (weight ratio) is particularly preferable. To effectively remove gaseous components, zeolites can be heated, decompressed or pressurized in the presence of ethanol. In terms of heat treatment, 30 ° C or higher, especially 50 to 90 ° C is preferred. The processing time is not particularly limited, but it is practically 1 hour to 3 days. Ethanol having a purity of 95.5% or more, especially 98% or more is preferably used. From the viewpoint of exothermic properties and coating properties of the composition, the use ratio of zeolite in the cosmetic composition of the present invention is preferably from 1 to 60% by weight, especially from 5 to 40% by weight, and typically from 10 to 30% by weight . The polyol used as the component (B) of the present invention is one having a molecular weight of not more than 1,000. Many polyols having a molecular weight greater than 1,000 have a high melting point and are not suitable as a main component. It does not exclude the use in small proportions. The polyol having a molecular weight of not more than 1,000 is not particularly limited as long as it is generally used in cosmetics. For example, alkanediols such as ethylene glycol, propylene glycol, butanediol, pentanediol, isoprene glycol, and hexanediol; dialkylene glycols such as diethylene glycol, dipropylene glycol, and diethylene glycol monomethyl ether , Diethylene glycol monoethyl ether; lipid

第9頁 518234 五、發明說明(5)Page 9 518234 V. Description of the invention (5)

族三醇如丙三醇;聚丙三醇;聚乙二醇;聚丙二醇;環氧 乙烷-環氧丙烷共聚物、環氧乙烷-環氧丙烷共聚物之丁基 單醚;及環氧烷包含(V5醚類如聚環氧乙烷、聚環氧丙烷 及聚(環氧乙烷-環氧丙烷)之甘油加成物。 I 其中’由使用感及保屋觀點來看,以聚乙二醇(分子 . 量:200至600)、丁二醇、異戊二烯二醇及丙三醇尤佳。 該等多元醇可單獨或組合使用。此種多元醇較佳量為佔 組合物總量之1至95 wt%,較好自5至9〇 ,尤其自1 〇至 7 0 wt %,因為具良好塗佈性、良好使用感及良好觸感之 故。 高分子化合物(C)可溶於多元醇(B)。”可溶” 一詞意指溶 解度至少為溶劑之〇 · 〇 1 w t %。π高分子"一詞意指分子量 2,0 0 0或更高。此成分使其可改良粉末如沸石於非水性介 質中之再分散性。此種高分子化合物實例包含天然物質如· 纖維素衍生物;及合成聚合物如(曱基)丙烯酸及其衍生物. 之共聚物。至於市售產品有例如"Carbopol ETD- 2 0 2 0 "、Triols such as glycerol; polyglycerol; polyethylene glycol; polypropylene glycol; ethylene oxide-propylene oxide copolymer, butyl monoether of ethylene oxide-propylene oxide copolymer; and epoxy Alkane contains glycerol adducts of (V5 ethers such as polyethylene oxide, polypropylene oxide, and poly (ethylene oxide-propylene oxide). I Among them, from the perspective of feeling of use and housing, Ethylene glycol (molecule. Amount: 200 to 600), butanediol, isoprenediol, and glycerol are particularly preferred. These polyols can be used alone or in combination. The preferred amount of such polyols is the combination 1 to 95 wt% of the total amount, preferably from 5 to 90%, especially from 10 to 70% by weight, because of good coating properties, good use feeling, and good touch. Polymer compounds (C ) Soluble in polyol (B). The term "soluble" means that the solubility is at least 0.001 wt% of the solvent. The term "π polymer" means a molecular weight of 2,00 or higher. This Ingredients make it possible to improve the redispersibility of powders such as zeolites in non-aqueous media. Examples of such polymer compounds include natural substances such as cellulose derivatives; and synthetic polymers . The product (Yue-yl) acrylic acid copolymers and derivatives thereof As the commercially available products are, for example " Carbopol ETD- 2 0 2 0 ",

Carbopol ETD-13821’、"Carbopol ETD-1342 "、"Pemulen TR-Γ’ 及"Pemuien TR-2n (商品名;B.F. Goodrich 公司產 品)。 其中’特佳為丙稀酸-曱基丙烯酸g旨共聚物,如 一 nCarbopol ETD- 2 0 2 01,、"Pemuien TR-11,及"Pemuien TR-2n ,其具下式所示結構:Carbopol ETD-13821 ’, " Carbopol ETD-1342 ", " Pemulen TR-Γ ', and " Pemuien TR-2n (trade name; product of B.F. Goodrich). Among them, ‘excellent’ is a copolymer of acrylic acid and fluorinated acrylic acid, such as nCarbopol ETD- 2 0 2 01, " Pemuien TR-11, and " Pemuien TR-2n, which have the structure shown in the following formula:

第10頁 518234 五、發明說明(6)Page 10 518234 V. Description of the invention (6)

Η——C——ΗΗ——C——Η

其中R代表含1 聚物中對應單元 0. 1至20. 0莫耳% 至於成分(C ): 此種高分子化合 w t %,較好自0 . 1 粧品組合物良好 再者,不溶於 綸粉末可使用不 本發明化粧品 此額外成分,可 鹽實例包含鹼金 佳。該等固體鹽 0 . 1至1 . 5毫米。 該等固體鹽可 量之0.1至30 wt 收敛效果。 0至3 0個碳原子之烷基,X及y代表個別共 之莫耳%,X自80· 0至99. 9莫耳%,及y自 〇 可單獨或組合使用此種高分子化合物。 物較佳量為佔組合物總量之自0. 0 1至5 至3 wt%,尤其自0.1至2 wt%,可赋與化 之沸石再分散性。 多元醇之高分子化合物如纖維素粉末及耐 損及本發明效果之量。 組合物可進一步添加固體鹽(D )。藉實施 得到擦洗效果及皮膚收斂效果。此種固體 屬鹽及鹼土金屬鹽,以氣化鈉及氯化鉀特. 類顆粒大小較好自0 , 0 1至3毫米,尤其自_ 單獨或組合使用。鹽較佳量為佔組合物總 %,尤其1至1 5 w t %,以賦與良好擦洗感及 518234 五、發明說明(8) 性)或非離子性,且可單獨或組合使用。陰離子界面活性 劑特定貫例包含C H 2 0脂肋'酸鹽、烧鱗硫酸醋、烧基硫酸 酯、烷基苯磺酸酯、α -烯烴磺酸酯、單烷基磷酸酯及二 院基構酸醋;陽離子性界面活性劑包含"S a n i s ο 1 Μ及 π Q u a r t a m i ηπ (商標,花王公司產品);兩性界面活性劑包 '含n Anhi tol"系列(商標,花王公司產品)及胺基酸-鹼界面 活性劑;非離子性界面活性劑包含高級醇、烷糖苷、聚氧 乙烯院醚、糖醇一脂肋Γ酸酯、單甘油S旨及二甘油S旨。 該等界面活性劑中,特佳為可溶劑多元醇且低含水量 者,因為其易調配及具優異放熱性及使用感之故。 成分(F )之界面活性劑添加比例較好佔總組合物之1至5 0 wt%,更好自2至30 wt%,尤其自5至20 wt%,因為所得清 潔劑組合物具優異清潔性及使用感之故。 本發明化粧品組合物或清潔劑組合物中亦可再併入螫合 劑或抗氧化劑。此可進一步改良安定性。特定實例包含乙 二胺四乙酸(EDTA)、羥二乙烷膦酸及二丁基羥基甲苯。 此種螯合劑或抗氧化劑之添加比例較好佔總組合物之 0. 0 0 0 1至2 wt%,尤其自0· 01至1 wt%,因為在貯存期間可 充分維持放熱性之故。 除了上述成分以外,若需要可添加化粧品組合物慣用之 進一步成分至不損及本發明效果之程度。其為例如油性成 分、潤滑劑、保溼劑、保存劑、殺菌劑、消炎劑、收斂 劑、止血劑、鎮痛劑、維他命及其衍生物、黏度改質劑、 消泡劑、清爽劑、冷卻劑、金屬銹抑制劑、前述以外之動Wherein R represents the corresponding unit in the polymer containing 0.1 to 20.0 mol%. As for the component (C): this polymer compound wt%, preferably from 0.1. The cosmetic composition is good, and it is insoluble in nylon. The powder may use this additional ingredient other than the cosmetic of the present invention, and examples of salt may include alkali gold. The solid salts are from 0.1 to 1.5 mm. These solid salts can have an astringent effect of 0.1 to 30 wt. Alkyl groups of 0 to 30 carbon atoms, X and y represent individual mole percentages in total, X is from 88.0 to 99.9 mole%, and y from 〇 Such polymer compounds may be used alone or in combination. The preferred amount of the zeolite is from 0.01 to 5 to 3 wt%, especially from 0.1 to 2 wt% of the total composition, which can impart redispersibility to the zeolite. Polymer compounds of polyhydric alcohols such as cellulose powder and damage resistance and the amount of the effect of the present invention. The composition may further add a solid salt (D). By doing this, the scrub effect and skin astringency effect can be obtained. Such solid salts and alkaline earth metal salts are characterized by sodium gaseous and potassium chloride. The particle size is preferably from 0, 0 1 to 3 mm, especially from _ used alone or in combination. The preferred amount of salt is% of the total composition, especially from 1 to 15 wt%, to impart a good scrubbing feel and 518234. (5. Description of the invention (8)) or nonionic, and can be used alone or in combination. Specific examples of anionic surfactants include CH 2 0 fatty rib 'acid salt, burned scale sulfuric acid vinegar, burned sulfuric acid ester, alkylbenzene sulfonate, α-olefin sulfonate, monoalkyl phosphate and dimeryl Acid acid vinegar; cationic surfactants include " S anis ο 1 Μ and π Q uartami ηπ (trademark, Kao Corporation products); amphoteric surfactant package 'containing n Anhi tol " series (trademark, Kao Corporation products) and Amino acid-base surfactants; non-ionic surfactants include higher alcohols, alkanosides, polyoxyethylene ethers, sugar alcohol monolipids, monoglycerides, and diglycerides. Among these surfactants, particularly preferred are those having a solvent-soluble polyol and low water content, because they are easy to formulate and have excellent exothermicity and usability. The addition ratio of the surfactant (F) is preferably 1 to 50 wt% of the total composition, more preferably 2 to 30 wt%, especially 5 to 20 wt%, because the obtained detergent composition has excellent cleaning performance. Sex and use. The cosmetic composition or the detergent composition of the present invention may be further incorporated with a coupler or an antioxidant. This can further improve stability. Specific examples include ethylene diamine tetraacetic acid (EDTA), hydroxydiethanephosphonic acid, and dibutylhydroxytoluene. The addition ratio of such a chelating agent or antioxidant preferably accounts for 0.01 to 2 wt% of the total composition, especially from 0.01 to 1 wt%, because the exothermic property can be sufficiently maintained during storage. In addition to the above-mentioned ingredients, if necessary, further ingredients conventionally used in cosmetic compositions may be added to such an extent that the effects of the present invention are not impaired. It is, for example, oily ingredients, lubricants, humectants, preservatives, bactericides, anti-inflammatory agents, astringents, hemostatic agents, analgesics, vitamins and their derivatives, viscosity modifiers, defoamers, refreshers, cooling agents Agents, metal rust inhibitors, and other actions

第13頁 518234 五、發明說明(9) 物或植物萃取物 本發明化粧品 法使上述成分混 〃實質上非水性'f 水。此化粧品組 時可產生足夠之 實用上,本發 時,較好升至高 有關上市型式 靜置之兩層分離 粉末成分再分散 布魯克菲爾德型 mPa · s,尤其自 粧品組合物可充 可藉觀察透明 狀態,亦即化粧 容器維持頭朝下 兩層分離狀態 影響活化沸石及 面層係由陶磁或 磁或鐵氟龍製得 之不銹鋼球。攪 毫米,因為可確 當本發明化粧Page 13 518234 V. Description of the invention (9) Extract or plant extract The cosmetic method of the present invention mixes the above ingredients with substantially non-aqueous water. This cosmetic group can produce enough practicality. In the present hair, it is better to rise to a high level. The two-layer separation powder component on the market type is left to re-disperse the Brookfield type mPa · s, especially the self-makeup composition can be filled and can be observed and transparent. The state, that is, the makeup container maintains two separate layers with its head down, affects the activated zeolite and the surface layer is a stainless steel ball made of ceramic or magnetic or Teflon. Stir millimeters, because it is sure

、著色劑及香料。 組合物或清潔劑組合物之調配可藉尋常方 合在一起且實質上為非水性者。本文中 並未排除化粧品組合物中含有較少量之 合物可含有些許水,只要其與外來水接觸 水合熱即可。 明化粧品組合物溫度在與等量2 5 °C水混合 如4 0 °C左右。 ,較好為其中粉末沈澱於液體介質而保持 型。使用時,搖晃或攪:動化粧品組合物使 。分散成均勻混合物時,黏度(在2 5 °C以 黏度計測量者)較好不高於5,0 0 0 5 0 0至2,0 0 0 mP a · s。在此範圍内,此化 分擴展於皮膚上並可以廣面積施用。 容器底部未殘留沈澱物而確信完全再分散 品組合物在容器中藉搖晃或攪動而混合且 以觀察底部狀態。 之例中,可於產品容器中置入攪拌球。由 無機鹽之觀點來看,攪拌球較好為至少表 鐵氟龍(TEFLON)(商標)所製得。除了由陶 之球以外,亦可使用以陶磁或鐵氟龍包覆 拌球較佳直徑為1至5 0毫米,尤其自5至2 5 使充分攪拌之故。 品組合物或清潔劑組合物貯存於容器中, Colorants and spices. The formulation of the composition or detergent composition can be combined together in an ordinary manner and is substantially non-aqueous. It is not excluded herein that a relatively small amount of the composition in the cosmetic composition may contain a little water, as long as it comes into contact with external water, the heat of hydration. Ming cosmetic composition temperature is mixed with an equal amount of 25 ° C water, such as about 40 ° C. It is preferably a type in which the powder is precipitated in a liquid medium and maintained. During use, shake or stir: shake the cosmetic composition. When dispersed into a homogeneous mixture, the viscosity (measured by the viscosity meter at 25 ° C) is preferably not higher than 5, 0 0 5 0 0 to 2, 0 0 0 mP a · s. Within this range, this ingredient spreads on the skin and can be applied over a wide area. The bottom of the container was free of sediments and it was believed that the completely redispersible product composition was mixed in the container by shaking or stirring and the bottom condition was observed. In an example, a stirring ball may be placed in a product container. From the viewpoint of an inorganic salt, the stirring ball is preferably made of at least Teflon (trademark). In addition to ceramic balls, ceramic balls or Teflon-coated balls can also be used. The preferred diameter is 1 to 50 mm, especially from 5 to 2 5 for sufficient stirring. Product composition or cleaner composition in a container

第14頁 518234 五:發明說明一Page 14 518234 5: Invention Description 1

時’較好使用層壓之樹脂容器以維持活化沸石及多元醇之 放熱性質,亦且保護組合物免受光影響及進一步提供作為 市售產品之令人滿意外觀。尤其較好使用包括兩種或多種 選自高密度聚乙烯(HDPE)樹脂、乙烯-乙烯基醇(EVOH)樹 脂、聚丙烯(ΡΡ )樹脂、聚對酞酸乙二酯(PET )樹脂、鐵氟 龍樹脂、耐綸樹脂、金屬鋁、玻璃及陶磁所成組群之材料 之層壓樹脂容器。其中較好為由HDPE樹脂、EVOH樹脂及PP 樹脂所製得之層壓樹脂容器,以其内又包含金屬鋁層之容 器尤佳。 本發明依據實例進一步說明。但須謹記本發明不限於該 專實例。 實例1 (調配程序) 1 ·沸石脫氣 2 〇重量份沸石[水含量:5 %最多,,,Z e ο 1 u m A 4粉末π (商 品名),TOSOH公司產品]在配置有玻璃夾套之2公斤攪動均 質混合機中在5 0 r pm攪拌下於1 5 0 °C油浴中加熱並脫氣2小 時,同時藉抽真空泵維持内壓在6 〇托耳或以下。 2. n Pemulen” 相製備It is preferable to use a laminated resin container to maintain the exothermic properties of the activated zeolite and polyol, and to protect the composition from light and further provide a satisfactory appearance as a commercially available product. It is particularly preferable to use two or more kinds selected from high-density polyethylene (HDPE) resin, ethylene-vinyl alcohol (EVOH) resin, polypropylene (PP) resin, polyethylene terephthalate (PET) resin, iron Laminated resin containers made of fluorine resin, nylon resin, metal aluminum, glass and ceramics. Among them, a laminated resin container made of HDPE resin, EVOH resin, and PP resin is preferable, and a container containing a metal aluminum layer therein is particularly preferable. The present invention is further explained based on examples. It must be kept in mind, however, that the invention is not limited to this specific example. Example 1 (preparation procedure) 1 • Zeolite degassing 2 0 parts by weight of zeolite [water content: 5% max., Z e ο 1 um A 4 powder π (trade name), product of TOSOH company] is equipped with a glass jacket Heat and degas in an oil bath at 150 ° C for 2 hours while stirring at 50 r pm in a 2 kg agitating homogeneous mixer, while maintaining the internal pressure at 60 Torr or lower by means of a vacuum pump. 2. n Pemulen ”phase preparation

聚乙一醇400(50.5重量份)與5重量份丙三醇及η重量份 L 3 — 1丁二醇混合,接著在室溫與由0· 5重量份”pemuien TR- 1Π及3重量份矽氧油所構成之懸浮液混合。所得混合物 在分散液粉碎機中在1,5 〇 〇 rpm攪拌丨〇分鐘。所得溶液加 熱至80°C,溶液在該溫度在1〇〇 rpm攪拌3〇分鐘。Polyethylene glycol 400 (50.5 parts by weight) was mixed with 5 parts by weight of glycerol and η parts by weight of L-1-butanediol, and then at room temperature with 0.5 parts by weight of "pemuien TR-1" and 3 parts by weight of silicon. The suspension composed of oxygen oil was mixed. The resulting mixture was stirred at 1,500 rpm for 10 minutes in a dispersion grinder. The resulting solution was heated to 80 ° C, and the solution was stirred at 100 rpm at this temperature for 30 minutes. .

第15頁 ^234 五、發明說明(π) —'一~— 一~ -一~- 3 、、e .^合及冷卻 於步驟1脫氣之沸石中,、入 牛 制 減壓。於_勒祕所人 添加γ私2衣備之液相同時維持 起。;攪=均貝此合機中在50至100 rpm攪拌混合在— 現人物=均貝扣合機中攪拌(7,0 0 0 rpm)10分鐘,且所得 0物冷卻至4 0 °C。 ^ ·添力σ劑 於步驟3製備之漿料中旦 , 均顆东 寸甲 以總ϊ 1 〇重莖伤添加氣化鈉(平 劑。=小· 0 ♦ 5笔米)及少量香料、安定劑及界面活性 配。传此合物再攪拌混合。接著冷卻至室溫而完成調 (使周用配士之化粧品組合物在25 °c黏度為丨,0 0 0 mPa · s。 v 1之用時評估) mPa吏用s)市售身體凝膠(洗除型,黏度:8 0,0 0 0至1 0 0,0 0 0 易、作為對照组’由1 0位測試者就有關塗佈至身體難 咸,廿#丨生及相谷性評估本發明產品及市售產品之使用 Α ·亚依下列標準評定: β 測!^中6位或以上感覺良好。 C :丨 測5式者中3至5位感覺良好。 丄υ位測試者+ 9 a斗、 、 再者,夂' 口有中2位或以下感覺良好。 溫产㈣儿σ樣品於燒杯中與等量水(2 5 t:)混合且隨後記錄 /又、交化。所. 田 運之攻大溫度亦示於表1。Page 15 ^ 234 V. Description of the invention (π) — '一 ~ — 一 ~-一 ~-3, e. ^ Combination and cooling In the zeolite degassed in step 1, the pressure is reduced to beef. The liquid phase of γ Private 2 was added to the _ Le Seisuo people while maintaining. ; Stirring = homogeneous in this machine at 50 to 100 rpm. Stir and mix in — present figure = homogeneous buttoning machine in agitation (7, 0 0 rpm) for 10 minutes, and the resulting product is cooled to 40 ° C. ^ In the slurry prepared by Step 3 in the slurry prepared in Step 3, add one sodium carbamate (leveling agent. = Small · 0 ♦ 5 strokes of rice) and a small amount of spices, with a total stem diameter of 10 cm, to a total stem injury. Stabilizer and interface active compound. The mixture was stirred and mixed. Then cool to room temperature to complete the adjustment (make the cosmetic composition for weekly use at 25 ° c viscosity 丨, 0 0 0 mPa · s. V 1 when used) mPa official use s) commercially available body gel (Wash-off type, viscosity: 8 0,0 0 to 1 0 0,0 0 0, as a control group, from 10 testers, it is difficult to apply salt to the body, 廿 # 丨 生 和 相 谷 性Evaluate the use of the product of the present invention and commercially available products. A. Asia is evaluated according to the following criteria: β test! ^ 6 or more feel good. C: 丨 test 5 to 3 out of 5 feel good. 丄 υ testers + 9 a bucket,, and again, 夂 'mouth has a middle 2 or below feels good. A sample of warm production ㈣ σ is mixed with an equal amount of water (2 5 t :) in a beaker and then recorded / recrossed. Therefore, Tian Yun's attack temperature is also shown in Table 1.

第16頁 518234Page 16 518234

五、發明說明(12) 表1 本發明產品1 市售產品A 市售產品BΊ 黏度(mPa . s,25°C) 1,000 100,000 --——~~._ 80,000 塗佈難易 A B ' 二--—~~~- B 塗佈性 A B —-—_ B 相容性 A B —-~~~~~~~. B 所達最高溫度 38〇C 26〇C 25〇C~~^ 由上述結果明顯看出本發明產品1提供良好使用感。 實例2 、 類似於實例1之方式調配化粧品組合物,但添加〇 · 8重量 份”?6111111611 TR-2n 替代0· 5 重量份f’Pemulen TR-1”。 ^ 比較產品1 類似於實例1之方式調配化粧品組合物但未添加 丨,Pemulen T R - 1,f 。 比較產品2 類似於實例1之方式調配組合物,但添加不溶於多元醇 溶劑之聚苯乙烯磺酸鈉(聚合度:50)替代,,Pemillen TR-Γ 丨。 評估比較產品1及2及本發明產品1及2之再分散性。 表2 添加有高分子化合物 靜置ί週後產品再分散i η 本發明產品1 “Pemulen TR-Γ(可溶於多元醇) 搖晃約10分鐘後易再分散 本發明產品2 “Pemulen TR-2”(可溶於多元醇) 搖晃約10分鐘後易^^^ 一' 比較產品1 未添加 甚至搖晃多如30分鐘仍未再今考今 _比較產品2 聚苯乙烯磺酸鈉(不溶於多元醇) 甚至搖晃多如30分鐘仍未再分勒V. Description of the invention (12) Table 1 Product of the present invention 1 Commercial product A Commercial product BΊ Viscosity (mPa.s, 25 ° C) 1,000 100,000 ------ ~~ ._ 80,000 Coating difficulty AB 'II- — ~~~-B Coating AB —-—_ B Compatibility AB —- ~~~~~~~. The highest temperature reached by B is 38 ° C 26 ° C 25 ° C ~~ ^ Obvious from the above results It can be seen that the product 1 of the present invention provides a good feeling of use. Example 2 A cosmetic composition was formulated in a manner similar to that of Example 1, except that 0.81 part by weight "? 6111111611 TR-2n was added instead of 0.5 part by weight f'Pemulen TR-1". ^ Comparative Product 1 A cosmetic composition was formulated in a manner similar to Example 1 but without the addition of Pemulen T R-1, f. Comparative product 2 The composition was formulated in a manner similar to Example 1, except that sodium polystyrene sulfonate (polymerization degree: 50) which was insoluble in a polyol solvent was added instead. Pemillen TR-Γ 丨. The redispersibility of Comparative Products 1 and 2 and Inventive Products 1 and 2 was evaluated. Table 2 The product was re-dispersed after the polymer compound was allowed to stand for a week i η Product 1 of the present invention "Pemulen TR-Γ (soluble in polyhydric alcohol) After shaking for about 10 minutes, it was easy to redisperse Product 2 of the present invention" Pemulen TR-2 "(Soluble in polyhydric alcohol) Easy to shake after about 10 minutes ^^^ 1'Comparative product 1 Not added or even shaken as much as 30 minutes has not been tested again today_Comparative product 2 Sodium polystyrene sulfonate (insoluble in polyhydric alcohol Alcohol) Even shaken for as much as 30 minutes and still not separated

518234 五、發明說明(13) 由上述結果看出各含有可溶於多元醇之對應高分子化合 物之本發明產品具優異再分散性。 實例3 藉一般方法調配表3所示配方之按摩助劑。使用時,評 估皮膚收斂效果及使用感。結果示列於表3。 (評估方法) 藉10位年齡自22至38歲之日本女性,每曰一次在其上臂 塗佈各按摩助劑,同時在沐浴後身體仍溼時予以按摩,該 等程序進行6周未中斷,以感官評估其皮膚收斂感並依據 下述標準評定。有關使用感,以感官評估滑順感並依據下 列標準評定。 (評定標準) (1 )皮膚收斂效果 A ·· 1 0位中8位或以上受試者有收斂感 B : 1 0位中6位至7位受試者有收斂感 C : 1 0位中3位至5位受試者有收斂感 D : 1 0位中2位或更少受試者有收斂感 (2 )使用感(滑順感)518234 V. Description of the invention (13) From the above results, it can be seen that the products of the present invention each containing a corresponding polymer compound soluble in a polyhydric alcohol have excellent redispersibility. Example 3 Blend a massage aid with the formula shown in Table 3 by a general method. When using, evaluate skin astringency effect and feeling of use. The results are shown in Table 3. (Assessment method) Ten Japanese women aged 22 to 38 apply massage aids to their upper arms each time and massage them while their bodies are still wet after bathing. These procedures are not interrupted for 6 weeks. Sensory evaluation of skin astringency and evaluation according to the following criteria. Regarding the feeling of use, the slippery feeling is evaluated sensory and evaluated according to the following criteria. (Evaluation Criteria) (1) Skin convergence effect A ·· 10 subjects among 8 or more subjects have a sense of convergence B: 6 to 10 subjects among 10 subjects have a sense of convergence C: 10 subjects 3 to 5 subjects have a sense of convergence D: 2 out of 10 subjects have a sense of convergence (2) feeling of use (smoothness)

A B C D 1 0位中8位或以上受試者感覺滑順 1 0位中6位至7位受試者感覺滑順 1 0位中3位至5位受試者感覺滑順 1 0位中2位或更少受試者感覺滑順ABCD 10 8 or more subjects feel smooth 10 out of 10 6 to 7 subjects feel smooth 10 out of 3 3 to 5 subjects feel smooth 10 out of 2 Or fewer subjects feel smooth

第18頁 518234 五、發明說明(14) 表3 成分(Wt.〇/〇) ------ 勹 比較產品 丙三8享 J ------- c __4 3 .聚乙二醇400 J ---~~~-__> 36 _5 5 39 59 丁二醇 15 -—______ __J 7 _15 20 -----— 丙婦酸··甲基丙烯酸院酯共聚物(“pemujen TR-1”,B.F. Goodrich 公司產品) :& 7Z ίΎΓ\<^Γ\Ύ^[八二立 口、* 1 ---—-一 — 1 1 /即 〈 ί 公口j 彦1 口口) Τ»τ Ήττ /Τ/^Ιλι^υλ o tn 1 Λά QfL /A / _ 25 ---- __25 /却廉个取物(丄chirnaru商樂月又份有pg /入:^车〇、 3 ---—-——口口 j 求奶(干泮貝祖穴小· ΙΛ)愛木) 10 10 10 乙醇 ~^— 么囱古f -- π 1 5 --——.— 100 . 5 5 rf> Is .ΙΑ- A/ v./ vff 100 100 皮贗收斂效果 A B c F〇 r^r / ' rft —P \ 使用感(滑順感) B B cPage 18 518234 V. Description of the invention (14) Table 3 Ingredients (Wt. 〇 / 〇) ------ 勹 Comparison product C3 8 Enjoy J ------- c __ 4 3. Polyethylene glycol 400 J --- ~~~ -__ > 36 _5 5 39 59 Butanediol 15 -_______ __J 7 _15 20 ------ Propionic acid ·· methacrylic acid ester copolymer ("pemujen TR- 1 ”, product of BF Goodrich): & 7Z ίΎΓ \ < ^ Γ \ Ύ ^ [八 二 立 口, * 1 ---—- 一 — 1 1 / that is, 〈公 口 j 彦 1 口 口) Τ »τ Ήττ / Τ / ^ Ιλι ^ υλ o tn 1 Λά QfL / A / _ 25 ---- __25 / However, it is a pick-up item (丄 chirnaru Shangleyue also has pg / into: ^ Cars 0, 3 ------—— Koukou j begging for milk (dried beizu point small · ΙΛ) love wood) 10 10 10 ethanol ~ ^ — Mo Henggu f-π 1 5 --——.— 100. 5 5 rf > Is .ΙΑ- A / v. / Vff 100 100 Skin convergence effect AB c F〇r ^ r / 'rft —P \ Usability (smoothness) BB c

*依實例1類似方法脫氣後使用。 實例4 調配表4所列配方之清潔劑組合物。 (調配程序) 1 ·類似於實例1之方式使沸石[含水量:5 %最多,* Use after degassing similar to Example 1. Example 4 A detergent composition was formulated with the formulations listed in Table 4. (Mixing procedure) 1 · Make zeolite similar to Example 1 [water content: 5% max.

Zeoliim A4粉末(商品名),TOSOH公司產品]脫氣。 2·在室溫下混合多元醇(聚乙二醇4〇〇,丙三醇、匕^丁 =醇)、可溶於多元醇之高分子化合物("pemulen TR-1” 等)及界面活性劑’接著在分散液粉碎機中在丨,5 〇 〇 rpm攪Zeoliim A4 powder (trade name), product of TOSOH] degassing. 2. Mix polyols (polyethylene glycol 400, glycerol, butane = alcohol), polyol-soluble polymer compounds (" pemulen TR-1 ", etc.) and interfaces at room temperature. The active agent was then stirred at 500 rpm in a dispersion mill.

第19頁 518234 五、發明說明(15) 拌1 0分鐘。所得溶液加熱至80 °C,溶液在1 00 rpm於該溫 度加熱擾拌3 0分鐘。 3. 於步驟1中脫氣之沸石中,添加步驟2製得之液相同時 維持減壓。在擾動均質混合機中在5 0至1 0 0 p p m擾拌混合 在一起,再於均質混合機中攪拌(7,0 0 0 r pm) 1 0分鐘,且 所得混合物冷卻至4 0 °C。 4. 於步驟3製備之漿料中,添加香料、氯化鈉及螫合劑 或安定劑,接著再攪拌。再冷卻至室溫,因此完成調配, 製得清潔劑組合物。Page 19 518234 V. Description of the invention (15) Mix for 10 minutes. The resulting solution was heated to 80 ° C, and the solution was heated and stirred at 100 rpm at this temperature for 30 minutes. 3. To the degassed zeolite in step 1, add the liquid phase obtained in step 2 while maintaining the reduced pressure. Stir and mix together at 50 to 100 p p m in a disturbance homomixer, stir (7, 0 0 0 r pm) for 10 minutes in the homomixer, and cool the resulting mixture to 40 ° C. 4. In the slurry prepared in step 3, add perfume, sodium chloride, and a coupler or stabilizer, followed by stirring. After cooling to room temperature, the preparation was completed to prepare a detergent composition.

第20頁 518234 五、發明說明(16) 表4 成分(Wt.%) 2 ^發明產品 比車父產品 5 6 7 4 (彿石) “Zeolum A-4”(T〇S0H 公司產品) 23 23 23 23 (多元醇) 聚乙二醇400 其餘 其餘 其餘 其餘 丙二醇 5 5 5 5 1,3-丁二醇 15 15 15 15 (可溶於多元醇之高分子化合物) 丙稀酸-曱基丙烯酸共聚物(“卩6111111611丁11- 0.5 - 0.5 - 1”,B. F_ Goodrich 公司產品) 丙烯酸-曱基丙烯酸共聚物(叩61111^11丁1^ - 0.8 - - 2”,B. F. Goodrich 公司產品) (界面活性劑) 月桂酸 - 1.5 1.5 - 山梨糖醇酐椰子脂肪酸酯 3 2.5 2.5 3 聚乙二醇單月桂酸酯(E012) 2 - - 2 月桂醯胺丙基甜菜鹼 0.50 1.00 1.00 0.50 磷酸月桂酯 0.5 3 3 0.5 聚乳乙婦(¾月桂基硫酸納 0.50 1.00 1.00 0.50 (固體鹽) 氯化納 5 5 5 5 (螫合劑或抗氧化劑) 乙二胺四乙酸二鈉 0.4 0.4 0.4 0.4 羥基乙烷二膦酸 0.2 0.2 0.2 0.2 二丁基羥基曱苯 0.5 0.5 0.5 0.5 香料 適量 適量 適量 適量 518234 五、發明說明(17) 測試(分散性評估) - 實例4所得之清潔劑組合物置於玻璃瓶中並在室溫靜置1 ^ ' 週。所有溶液為沈澱有粉末之兩層分離狀態。其上下搖晃· * 以評估其再分散性。本發明產品5至7之清潔劑組合物易再 分散,而比較產品4中,粉末結塊且無法再分散。Page 20 518234 V. Description of the invention (16) Table 4 Composition (Wt.%) 2 ^ Invented product is more than car parent product 5 6 7 4 (Buddha) "Zeolum A-4" (T0S0H company product) 23 23 23 23 (Polyol) Polyethylene glycol 400 Remaining Remaining remaining propylene glycol 5 5 5 5 1,3-butanediol 15 15 15 15 (Polyol-soluble polymer compound) Acrylic acid-fluorenyl acrylic acid copolymerization ("卩 61111116111111-0.5-0.5-1", product of B. F_ Goodrich) Acrylic acid-fluorene-based acrylic copolymer (叩 61111 ^ 11but1 ^-0.8--2 ", product of BF Goodrich) ( Surfactant) Lauric acid-1.5 1.5-Sorbitol anhydride coconut fatty acid ester 3 2.5 2.5 3 Polyethylene glycol monolaurate (E012) 2--2 Laurylamine propyl betaine 0.50 1.00 1.00 0.50 Laurel phosphate Esters 0.5 3 3 0.5 Polylactone (¾ Sodium Lauryl Sulfate 0.50 1.00 1.00 0.50 (Solid Salt) Sodium Chloride 5 5 5 5 (Couplings or Antioxidants) Disodium Ethylene Diamine Tetraacetate 0.4 0.4 0.4 0.4 Hydroxyethyl Alkane diphosphonic acid 0.2 0.2 0.2 0.2 0.5 0.5 0.5 0.5 Fragrance right amount right amount right amount 518234 V. Description of the invention (17) Test (dispersion evaluation)-The detergent composition obtained in Example 4 was placed in a glass bottle and left at room temperature for 1 ^ 'week. All solutions were The two layers of powder precipitated and separated. It was shaken up and down to evaluate its redispersibility. The detergent compositions of the products 5 to 7 of the present invention were easily redispersed, while in the comparative product 4, the powder was agglomerated and could not be redispersed.

第22頁Page 22

Claims (1)

案號8810;Case number 8810; 月 518234 曰 六、申請專利範圍 1 . 一種非水性化粧品組合物,包括(A ) 1〜6 0重量%活化 彿石,(B)l〜95重量%分子量不大於1,000之多元醇,及 (C)0.01〜5重量%可溶於該成分(B)且選自(曱基)丙烯酸及 其衍生物之高分子化合物。 m請委員α7'·τ、 W質内容 2 .根據申請專利範圍第1項之非水性化粧品組合物,其 中該組合物以均勻混合物時在2 5 °C之黏度不大於5,0 0 0 m P a · s ° 3 .根據申請專利範圍第1或2項之非水性化粧品組合物, 進一步包括(D)固體鹽。 4.根據申請專利範圍第1或2項之非水性化粧品組合物, 進一步包括(E )海藻萃取物。 5 .根據申請專利範圍第1或2項之非水性化粧品組合物, 為按摩助劑。 6 . —種實質上非水性化粧品組合物,包括(A ) 1〜6 0重量 %活化沸石、(B)l〜95重量%分子量不大於1,000之多元 醇、(C)0.01〜5重量%可溶於成分(B)且選自(甲基)丙烯酸 及其衍生物之高分子化合物,及(F ) 1〜5 0重量%界面活性 劑。May 518234, the scope of patent application 1. A non-aqueous cosmetic composition comprising (A) 1 to 60% by weight activated fossil, (B) 1 to 95% by weight of a polyol having a molecular weight of not more than 1,000, and (C) 0.01 to 5% by weight of a polymer compound soluble in the component (B) and selected from (fluorenyl) acrylic acid and its derivatives. Please invite members α7 '· τ, W. Content 2. The non-aqueous cosmetic composition according to item 1 of the scope of patent application, wherein the viscosity of the composition at 25 ° C is not greater than 5, 0 0 0 m P a · s ° 3. The non-aqueous cosmetic composition according to item 1 or 2 of the patent application scope, further comprising (D) a solid salt. 4. The non-aqueous cosmetic composition according to item 1 or 2 of the patent application scope, further comprising (E) algae extract. 5. The non-aqueous cosmetic composition according to item 1 or 2 of the scope of patent application, which is a massage aid. 6. A substantially non-aqueous cosmetic composition comprising (A) 1 to 60% by weight of activated zeolite, (B) 1 to 95% by weight of a polyol having a molecular weight of not more than 1,000, and (C) 0.01 to 5% by weight % Polymer compound soluble in component (B) and selected from (meth) acrylic acid and its derivatives, and (F) 1 to 50% by weight surfactant. O:\57\57966.ptc 第24頁O: \ 57 \ 57966.ptc Page 24
TW88105768A 1998-04-13 1999-04-12 Cosmetic composition TW518234B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP10101079A JPH11292730A (en) 1998-04-13 1998-04-13 Cosmetic
JP10107698A JP3544120B2 (en) 1998-04-13 1998-04-13 Cosmetics
JP10107898A JPH11292729A (en) 1998-04-13 1998-04-13 Production of cosmetic
JP10107798A JPH11292735A (en) 1998-04-13 1998-04-13 Cosmetic
JP10118716A JPH11310797A (en) 1998-04-28 1998-04-28 Detergent composition

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