TW515784B - Chelating agent and detergent comprising the same - Google Patents

Chelating agent and detergent comprising the same Download PDF

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TW515784B
TW515784B TW85114085A TW85114085A TW515784B TW 515784 B TW515784 B TW 515784B TW 85114085 A TW85114085 A TW 85114085A TW 85114085 A TW85114085 A TW 85114085A TW 515784 B TW515784 B TW 515784B
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acid
aqueous solution
compound
group
formula
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TW85114085A
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Chinese (zh)
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Hiroshi Yamamoto
Yasuyuki Takayanagi
Kiyobumi Takahashi
Teturo Nakahama
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Mitsubishi Rayon Co
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Abstract

Disclosed is a biodegradable chelating agent which comprises a compound of the following formula [1] and at least one compound selected from the group consisting of aspartic acid, maleic acid, acrylic acid, malic acid, glycine, glycolic acid, iminodiacetic acid, nitrilotriacetic acid, Α-alanine, β-alanine, iminodipropionic acid, fumaric acid, a synthetic starting amino acid and a synthetic intermediate amino acid and a salt thereof in an amount of 8% by weight or less based on the compound of the formula [1]: wherein R1 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1-10 carbon atoms, R2 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1-8 carbon atoms, R1 and R2 may form a ring together, the substituent which can be present in R1 and R2 is at least one member selected from the group consisting of -OH, -CO2M and -SO3M where M represents hydrogen or an alkali metal; X represents where R3 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1-8 carbon atoms, the substituent is at least one member selected from the group consisting of -OH, -CO2M and -SO3M, R4 represents at least one member selected from the group consisting of hydrogen, -CO2M and -SO3M, A1 and A2 each represent at least one member selected from the group consisting of hydrogen, CO2M and SO3M, A5 represents an alkylene group of 1-8 carbon atoms which may be of straight chain or branched chain or may form-a ring, the alkylene group may contain in the chain an ether bond -O-, an ester bond -COO- or an amide bond -CONH-, M represents hydrogen or an alkali metal, and n represents an integer of 1-8; and Y represents at least one member selected from the group consisting of hydrogen, CO2M and SO3M.

Description

515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（i ) 本發明之背景 (1 )發明之領域 本發明係關於一種在生物降解能力有優異表現之胺基 羧酸螯合劑及螯合劑之用途。尤其，本發明係關於以固體 ，水溶液或泥漿形式，在操作性能有優異表現之生物可降 解之螯合劑，及關於一種包含生物可降解之螯合劑之具有 優異清淨力與高生物降解能力之清潔劑組成物。 (2)相關技藝之描述 一般，以固體形式使用之螯合劑係以在袋或斗倉中之 粉末或片狀粉粒之形式儲存。固體螯合劑因硬化性質（視 累積條件與時間及保存條件與時間而定）而逐漸地變至堅 硬塊。因此，在使用之前該物質必需壓碎而這是非常不便 於操作處理的。 以水溶液或泥漿之形式所使用之螯合劑不必要壓碎， 但具有嚴重之問題：例如：因在水溶液中之分解作用與變 色作用而導致純度降低。 一般，胺基羧酸螯合劑廣泛地使用做爲照相漂白劑， 清潔劑組成物，清潔劑組份，重金屬多價螯合劑，過氧化 物之安定劑與類似物之成份。 清潔劑組成物廣泛地使用於廚房用具之家用清潔，衣 服之家用清潔，營業目的之餐具之清潔，工廠之清潔，營 業目的之衣服清潔與類似用途。而且，其結合適當添加劑 做爲漂白劑，去鍋垢劑，金屬多價螯合劑，及類似物使用 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 一 4 一 0 Hal· ϋ··— mmKtMKm tMMmMt 111 11 1§1 mmmKmet ϋ_ϋ tmm/ββ 1 1 na^i · β 、3 (請先閲讀背面之注意事項再填寫本頁) 叫 經濟部中央標準局員工消費合作社印製 515784 A7 _____B7_ 五、發明説明（2 ) 0 迄今做爲清潔劑組份使用之三聚磷酸鈉具有高性能之 螯合能力。然而，其包含磷且當其釋放至環境中時，造成 河流與湖泊被磷，氮等物質污染而致藻類急速繁殖，因此 ，目前不再使用。 目前做爲清潔劑組份使用之沸石具有下述缺點：因其 爲無機物質，其具有低螯合性能且不具有生物降解能力。 而且，沸石不溶於水且具有限制：其不可使用於液體清潔 劑，特別是澄清液體清潔劑。而且，沸石具有許多問題， 使得其黏附至下水道管路之內壁或在河流底端沈澱而造成 淤泥之形成。因此，試圖降低所使用之沸石量及製備替代 沸石之物質，該替代物希望具有充份之螯合力與清淨力， 但此類替代物到目前尙未獲得。 曾使用做爲清潔劑組份之胺基羧酸，伸乙基二胺四醋 酸（EDTA)在寬廣pH範圍中具有優異之螯合力，但 在生物降解能力是差的，且難以藉由平常之廢水處理（採 用活性淤泥）而退化。而且，氮三乙酸（NTA)具有某 些生物降解能力，因曾記載NTA具有致畸態性且氮三乙 醋-鐵錯化合物具有致癌性，從環境健康之觀點氮三乙酸 是不佳的。在其他傳統胺基羧酸之中，在螯合性能優異但 在生物降解能力低之胺基羧酸具有下述困難：當其釋放至 環境中時，其在環境中累積爲有害之重金屬。關於上述有 機胺基酸曾研究種種化合物，但目前尙未揭發在螯合性能 與生物降解能力具有優異表現之化合物。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 5 - (請先閱讀背面之注意事項再填寫本頁〕 •訂- 經濟部中央標準局員工消費合作社印製 515784 A7 _ B7 五、發明説明（3 ) 本發明之簡述 本發明之目的係提供一種在儲放期間不會硬化成爲塊 狀物之生物可降解之粉末螯合劑或提供一種在儲放期間不 會進行分解或變色之以水溶液或泥漿形式之生物可降解之 螯合劑，及另外提供一種包含該螯合劑之清潔劑組成物。 由於發明者所引導之徹底研究企圖解決上述問題，發 現甚至以固體形式之某些螯合劑在特殊條件之下亦可易於 操作而不會變硬，一些螯合劑甚至以水溶液或泥漿之形式 在特殊條件之下亦可安定地操作且容易地超過一段長時間 而不會進行分解或變色，另外藉由結合這些生物可降解之 螯合劑與表面活化劑及類似物可獲得高清淨力。因此，實 現本發明之目的。 換言之，本發明之螯合劑爲一種包含下式〔1〕之化 合物與至少一種選自天冬胺酸，順-丁烯二酸，丙烯酸， 蘋果酸，甘胺酸，羥基乙酸，亞胺二醋酸，氮三乙酸，α 一丙胺酸，—丙胺酸，亞胺二丙酸，反一 丁烯二酸之化 合物，一種做爲式〔1〕化合物合成起始物質之胺基酸（ 在下文被稱爲>合成之起始胺基酸"），一種在式〔1〕 之化合物之合成反應所產生之中間物胺基酸（在下文被稱 爲％合成之中間物胺基酸及相當於2 5重量％ (係以 式〔1〕之化合物爲基礎）或更少之其鹽，或相當於8重 量％ (係以式〔1〕之化合物爲基礎）或更少之其鹽，以 水溶液或泥漿之形式之螯合劑： 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _^衣 I I n' n ^ I 4 (請先閲讀背面之注意事項再填寫本頁) 叫 一 6 一 515784 A7 B7 五、發明説明（4 ) R 2 R 1 X - N - CH-Y 〔1〕 其中R1代表氫或1 - i 〇碳原子之未經取代或經取代之 烴基’而R2代表氫或1 - 8碳原子之未經取代或經取代 之烴基，R1與R2可一起形成環，可以R1與R2存在 之取代基爲至少一種選自一 0H，一 C02M與 一 S03M之鏈節，其中Μ代表氫或鹼金屬；X代表 R 3 R 4 - C Η - 或515784 Printed by A7 B7, Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (i) Background of the invention (1) Field of the invention The invention relates to an amino carboxylic acid chelating agent with excellent performance in biodegradability and The use of chelating agents. In particular, the present invention relates to a biodegradable chelating agent having excellent performance in the form of a solid, an aqueous solution or a mud, and a cleaning product having excellent detergency and high biodegradability including a biodegradable chelating agent.剂 组合 物。 Composition. (2) Description of related skills Generally, the chelating agent used in solid form is stored in the form of powder or flakes in a bag or a silo. The solid chelating agent gradually changes to a hard mass due to the hardening properties (depending on the accumulation conditions and time and storage conditions and time). Therefore, the substance must be crushed before use, which is very inconvenient to handle. The chelating agent used in the form of an aqueous solution or slurry does not need to be crushed, but has serious problems: for example, the purity is reduced due to decomposition and discoloration in the aqueous solution. In general, amino carboxylic acid chelating agents are widely used as components of photographic bleaches, detergent compositions, detergent components, heavy metal sequestering agents, peroxide stabilizers and the like. The detergent composition is widely used for household cleaning of kitchen utensils, household cleaning of clothes, cleaning of tableware for business purposes, cleaning of factories, cleaning of clothes for business purposes and the like. Moreover, it is combined with appropriate additives as bleaching agent, descaling agent, metal sequestering agent, and the like. The paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm)-4-0 Hal · ϋ ·· — mmKtMKm tMMmMt 111 11 1§1 mmmKmet ϋ_ϋ tmm / ββ 1 1 na ^ i A7 _____B7_ V. Description of the invention (2) 0 Sodium tripolyphosphate used as a cleaning agent component has high-performance chelating ability. However, it contains phosphorus and when it is released into the environment, it causes rivers and lakes to be contaminated by phosphorus, nitrogen, and other substances, causing algae to multiply rapidly. Therefore, it is no longer used. The zeolite currently used as a detergent component has the following disadvantages: because it is an inorganic substance, it has low chelating properties and does not have biodegradability. Moreover, zeolites are insoluble in water and have a limitation: they cannot be used in liquid cleaners, especially clear liquid cleaners. Furthermore, zeolite has many problems that cause it to adhere to the inner walls of sewer pipes or settle at the bottom of rivers and cause the formation of sludge. Therefore, attempts have been made to reduce the amount of zeolite used and to prepare a substitute for zeolite. The substitute is expected to have sufficient chelating power and detergency, but such a substitute has not been obtained so far. Aminocarboxylic acid, which has been used as a cleaning agent component, ethylenediaminetetraacetic acid (EDTA) has excellent chelating power in a wide pH range, but it is poor in biodegradability and it is difficult to use ordinary Wastewater treatment (using activated sludge) and degradation. In addition, nitrogen triacetic acid (NTA) has certain biodegradability. Because it has been documented that NTA is teratogenic and nitrogen triethyl acetate-iron compound is carcinogenic, nitrogen triacetic acid is not good from the viewpoint of environmental health. Among other conventional amine carboxylic acids, amine carboxylic acids that have excellent chelating properties but low biodegradability have the following difficulties: when they are released into the environment, they accumulate as harmful heavy metals in the environment. Various compounds have been studied about the above-mentioned organic amino acids, but currently no compounds have been disclosed that have excellent performance in chelating properties and biodegradability. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 5-(Please read the precautions on the back before filling out this page] • Order-Printed by the Central Consumers Bureau of the Ministry of Economy Staff Consumer Cooperative 515784 A7 _ B7 V. Description of the invention (3) Brief description of the present invention The object of the present invention is to provide a biodegradable powder chelator that does not harden into a block during storage or to provide a biodegradable powder chelator that does not decompose during storage or Discolored biodegradable chelating agent in the form of an aqueous solution or mud, and additionally provide a detergent composition containing the chelating agent. As a result of thorough research led by the inventors in an attempt to solve the above problems, it was found that some even in solid form Chelating agents can also be easily handled without hardening under special conditions. Some chelating agents can operate stably even in the form of aqueous solutions or slurries under special conditions and easily exceed a long period of time without decomposition or Discoloration, and high-definition net power can be obtained by combining these biodegradable chelating agents with surfactants and the like. Therefore, In other words, the chelating agent of the present invention comprises a compound of the following formula [1] and at least one member selected from the group consisting of aspartic acid, maleic acid, acrylic acid, malic acid, glycine, and a hydroxyl group. Acetic acid, imine diacetic acid, nitrotriacetic acid, α-alanine,-alanine, imine dipropionic acid, trans-butenedioic acid, an amine group as a starting material for the synthesis of compounds of formula [1] Acid (hereinafter referred to as > synthetic starting amino acid "), an intermediate amino acid (hereinafter referred to as% synthesis intermediate) produced in the synthesis reaction of a compound of formula [1] Amino acid and its salt equivalent to 25% by weight (based on the compound of the formula [1]) or less, or 8% by weight (based on the compound of the formula [1]) or less Its salt, chelating agent in the form of aqueous solution or mud: This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _ ^ 衣 II n 'n ^ I 4 (Please read the precautions on the back first Fill out this page again) Call 1 6 1 515784 A7 B7 V. Description of the invention (4 ) R 2 R 1 X-N-CH-Y [1] where R1 represents hydrogen or an unsubstituted or substituted hydrocarbyl group of 1-i 0 carbon atom 'and R2 represents hydrogen or an unsubstituted carbon atom of 1-8 carbon atom Or a substituted hydrocarbon group, R1 and R2 may form a ring together, and the substituents that may exist in R1 and R2 are at least one selected from the group consisting of -0H, -C02M and -S03M, where M represents hydrogen or an alkali metal; X represents R 3 R 4-C Η-or

Ai — CH — ΝΗ — Α5 — A 2 一（ C Η 2) n 經濟部中夬標準局員工消費合作社印製 其中R 3代表氫或1 - 8碳原子之未經取代或經取代之烴 基，取代基爲至少一種選自一 0Η，—（：02“與 一 S03M之鏈節，R4代表至少一種選自氫，一 C02M 與一 S03M之鏈節，A1與A2各自代表至少一種選自 氫，C02M與S03M之鏈節，A5代表可爲直鏈或支 鏈或可形成環之1 一 8碳原子之烯烴基’烯烴基可在鏈中 一 7 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 515784 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（5 ) 包含醚鍵一 0 —，酯鍵一 C00 -或醯胺鍵一 CONH -，Μ代表氫或鹼金屬，而η代表1 — 8之整數；Y代表至 少一種選自氫，C02M與303^1之鏈節。 而且，本發明之螯合劑爲一種包含上述式〔1〕之化 合物與至少一種選自下述化合物之以水溶液或泥漿形式存 在之螯合劑：天冬胺酸，順-丁烯二酸，丙烯酸，蘋果酸 ，甘胺酸，羥基乙酸，亞胺二醋酸，氮三乙酸，α -丙胺 酸，Θ -丙胺酸，亞胺二丙酸，反一丁烯二酸，一種合成 起始之胺基酸，一種合成之中間產物胺基酸與相當於2 5 重量％ (係以式〔1〕之化合物爲基礎）或更少之其鹽類 〇 此外，本發明關於具有優異清淨力且包含所述生物可 降解之螯合劑之清潔劑組成物。 本發明之較佳體系 至於式〔1〕之單胺化合物 其中X爲 R 3 R 4 — C Η — (其中R 3與R 4如上所定義），例如可以下述爲材料所 製成：天冬胺酸一 Ν -單醋酸（ASMA)，天冬胺酸一 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） ,· (請先閱讀背面之注意事項再填寫本頁)Ai — CH — ΝΗ — Α5 — A 2 I (C Η 2) n Printed by the Consumer Cooperatives of the China Standards Bureau of the Ministry of Economic Affairs where R 3 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 8 carbon atoms, substituted The radical is at least one selected from the group consisting of a 0Η,-(: 02 "and a S03M, R4 represents at least one selected from hydrogen, a C02M and a S03M, A1 and A2 each represent at least one selected from hydrogen, C02M With the S03M link, A5 represents an alkene group of 1 to 8 carbon atoms that can be straight or branched or can form a ring. The olefin group can be in the chain 7-(Please read the precautions on the back before filling this page ) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 515784 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 Β7 V. Description of the invention (5) Contains an ether bond — 0 — and an ester bond — C00- Or amine bond-CONH-, M represents hydrogen or an alkali metal, and η represents an integer of 1 to 8; Y represents at least one kind of chain selected from hydrogen, C02M and 303 ^ 1. Moreover, the chelating agent of the present invention is a kind of The compound comprising the above formula [1] and at least one compound selected from the group consisting of Chelating agents in the form of aqueous solutions or slurries: aspartic acid, maleic acid, acrylic acid, malic acid, glycine, glycolic acid, iminodiacetic acid, azatriacetic acid, α-alanine, Θ-alanine, imine dipropionic acid, trans-butenedioic acid, a synthetic starting amino acid, a synthetic intermediate product amino acid and equivalent to 25% by weight (based on the formula [1] Compound-based) or less of its salts. In addition, the present invention relates to a detergent composition having excellent detergency and containing the biodegradable chelating agent. A preferred system of the present invention is as shown in the formula [1]. Amine compounds in which X is R 3 R 4 — C Η — (where R 3 and R 4 are as defined above), for example, can be made of the following materials: aspartic acid mono-N-monoacetic acid (ASMA), asparagus Amino acid paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm), (Please read the precautions on the back before filling this page)

I 1 ϋ I » I I I -8 - 515784 A7 _B7___ 五、發明説明（6 ) N，N -二醋酸（ASDA)，天冬胺酸一 N -單丙酸（ ASMP)，亞胺二琥珀酸（IDA) ，N -（2 -硫代 甲基）天冬胺酸（SMAS) ，N —（2 —硫代乙基）天 冬胺酸（SEAS)，穀胺酸一 N，N -二醋酸（ GLDA) ，N — (2 —硫代甲基）穀胺酸（SMGL) ，N — (2 —硫代乙基）榖胺酸（SEGL) ，N —甲基 亞胺二醋酸（MIDA)，“一丙胺酸一1^，1^一二醋酸 (a ~ A L D A )，沒一丙胺酸一N，N—二醋酸（点一 ALDA)，絲胺酸一 N，N —二醋酸（SEDA)，異 絲胺酸一 N，N —二醋酸（ISDA)，苯基丙胺酸一 N ，N—二醋酸（PHDA)，鄰一胺基苯甲酸一N，N — 二醋酸（ANDA)，磺胺酸一 N，N —二醋酸（ SLDA) ，牛磺酸一 N，N -二醋酸（TUDA)與硫 代甲基一 N，N —二醋酸（SMDA)與其鹼金屬鹽類或 錢鹽類。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 這些化合物具有不對稱碳，因此係以光學異構體存在 。從生物可降解能力之觀點，較佳爲（S ) -天冬胺酸-單醋酸，（S)-天冬胺酸一N，N-二醋酸，（S)-天冬胺酸一單丙酸，（S，S) -亞胺二琥珀酸，（S， R)—亞胺二琥珀酸，（S)—2-硫代甲基天冬胺酸， (S)—2—硫代乙基天冬胺酸，（S)—穀胺酸一N， N-二醋酸，（S)-2—硫代甲基穀胺酸，（S)—2 —硫代乙基穀胺酸，（S)—α-丙胺酸一N，N-二醋 酸，（S) -絲胺酸一 N，N -二醋酸，及（S) -苯基 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -9 一 515784 A7 —__B7_ 五、發明説明（7 ) 丙胺酸一 N，N -二醋酸與其鹼金屬鹽或銨鹽。 至於提到以式〔1〕所代表之二胺化合物，其中X爲 A1 - CH-NH-A5 - A 2 -（ C Η 2) n (其中A1 ，A2與A5如上所定義），可以下述之物質 製成：例如，伸乙基二胺二琥珀酸（EDDS) ，1，3 一丙烷二胺二琥珀酸（13PDDS)，伸乙基二胺二穀 胺酸（EDDG) ，1，3 -丙烷二胺二榖胺酸（ 13EDDG) ，2 -羥基一 1，3 -丙烷二胺二琥珀酸 (PDDS - 0H)與2 -羥基—1，3 -丙烷二胺二榖 胺酸（PDDG — 0H)與其鹼金屬鹽或銨鹽。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 這些化合物具有不對稱碳，因此係以光學異構體存在 。從生物可降解能力之觀點，較佳爲（S，S) —伸乙基 二胺二琥珀酸，（S，S) — 1，3 —丙烷二胺二琥珀酸 ，（S，S) —伸乙基二胺二穀胺酸，（S，S) — 1， 3 -丙烷二胺二穀胺酸，（S，S) — 2 —羥基一 1，3 —丙烷二胺二琥珀酸與（S，S) -2 -羥基一 1，3 — 丙烷二胺二榖胺酸及其鹼金屬鹽或銨鹽。 單胺化合物通常係藉由下述之方法而獲得：起始胺基 酸或磺酸與氫氰酸與甲醛水溶液進行加成反應，在鹼性條 件之下水解而獲得加成產物，或胺基酸或磺酸與丙烯睛或 本紙張尺度適用中國國家標準（CNS ) A4規格（210乂297公釐） -10 - 515784 A7 __B7 五、發明説明（8 ) 類似物進行加成反應並在鹼性條件之下水解而獲得加成物 。因此，所希望之單胺螯合劑通常除了包含起始胺基酸或 磺酸之外還包含雜質之側反應產物。 例如，在牛磺酸一 N，N —二醋酸鹽之合成作用中， 係藉由將氫氰酸與甲醛水溶液添加至牛磺酸中，然後水解 所得之加成反應產物，所形成之產物除了未反應之牛磺酸 之外還包括副產物，例如羥基乙酸，甘胺酸，亞胺二醋酸 ，氮三乙酸，反一丁烯二酸，—丙胺酸與亞胺二丙酸。 除了這些雜質之外，視反應條件而定有時偵測到例如蘋果 酸與丙烯酸鹽之雜質。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 二胺化合物通常藉由添加二分子順-丁烯二酸至一分 子烯烴基二胺中而產生。在此例中，所得之所希望之二胺 螯合劑通常包含雜質，未反應之順-丁烯二酸，僅具有一 分子所添加之順-丁烯二酸之反應中間產物胺基酸與其側 反應產物。例如，在伸乙基二胺二琥珀酸鹽之合成中，係 藉由添加二分子順一丁烯二酸至一分子伸乙基二胺中，除 了未反應之順一 丁烯二酸之外，還可看到例如伸乙基二胺 單琥珀酸之副產物。 而且，關於二胺化合物之製備，存在根據下述之方法 :二分子起始胺基酸，例如天冬胺酸或穀胺酸，使用二鹵 素乙烷，環氧氯丙烷或類似物連結。在此例中，所得之所 希望之二胺基聚羧酸螯合劑通常包含雜質，起始胺基酸， 具有一分子所添加之起始胺基酸之反應中間產物胺基酸與 其側反應產物。例如，在（S，S) -伸乙基二胺二琥拍 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -11 - 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（9 ) 酸之合成中，係藉由將二分子（S ) -天冬胺酸加至一分 子二氯乙烷中，然後，將加成反應產物添加無機酸而進行 沈澱作用，看到除了未反應之（S) -天冬胺酸之外亦看 到之外亦看到副產物，例如（S ) - N — 2 —氯乙基天冬 胺酸，（S) - N — 2 —羥基乙基天冬胺酸，（S，S) —N — 2 —羥乙基伸乙基二胺二琥珀酸與反—丁烯二酸。 在本發明中，製備之螯合劑使得上述雜質鹽之含量爲 2 5重量％或更少，較佳爲8重量％或更少，係以鹽之形 式之式〔1〕之化合物重量爲基礎。當滿足此類條件時， 特別是當雜質鹽之含量爲8重量％或更少時，所得之螯合 劑之硬化甚至在普通儲放階段是徹底被抑制的。雜質鹽之 總量更佳爲3重量％，係以式〔1〕之化合物重量爲基礎 ，而甚至在嚴重之儲放條件之下，最佳3重量％或更少， 可徹底地抑制硬化成爲塊狀物。當滿足這些條件時，經抑 制硬化成爲塊狀物之粉末僅可藉由濃縮式〔1〕之化合物 之合成作用之反應混合物（在下文中僅僅被稱爲a反應混 合物而獲得，從那時以後，將濃縮之反應混合物進行 噴霧乾燥與類似程序，但在其他例子中，藉由進行下列純 化作用可降低雜質鹽之含量。 至於關於螯合劑之純化作用音指包含下述之方法·· 將反應混合物一經添加例如硫酸之無機酸便發生沈澱 作用而分離出高純度之結晶螯合劑，然後於鹼中再次溶解 該結晶物。另外，當純化固體原螯合劑時，同樣有效以醇 類（例如甲醇）洗滌螯合劑而移除高溶解度之低分子雜質 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 -12 - 經濟部中央標準局員工消費合作社印製 515784 A7 ______JB7_ 五、發明説明（10 ) 〇 在本發明中，當雜質爲以酸之形式時，螯合劑同樣以 如同所提到之以鹽形式之雜質之相同方法製備，換句話說 ，這些雜質酸之含量爲2 5重量％或更少，較佳爲8重量 %或更少，係以式〔1〕之化合物爲基礎。當滿足此類條 件時，特別是當雜質酸之含量爲8重量％或更少時，甚至 在一般儲存狀態亦徹底地抑制所得螯合劑之硬化。雜質酸 之總量更佳爲3重量％或更少，係以式〔1〕之化合物爲 基礎，另外甚至在嚴重之儲放條件之下較佳0.5重量％ 或更少徹底地抑制硬化。 若雜質酸（鹽）之總量不能允許符合上述條件時（將 藉由上述反應所獲得之螯合劑僅添加酸而進行沈澱作用） ，原始結晶物可藉由大量水洗滌，藉由原始結晶物之重覆 再結晶作用，或藉由其他方法而純化。 藉由這些方法在雜質含量中之螯合劑經純化至2 5重 量％或更低，即使在儲存或輸送期間，螯合劑以結晶或薄 片之形式沈澱，螯合劑可易於回復至粉末或薄片之形式。 因此，該螯合劑可存放超過一段長時間且是安定且易於處 理的。 在本發明中，螯合劑調整至包含2 5重量％或更低之 雜質鹽，較佳1 0重量％或更低，更佳爲5重量％或更低 ，係以式〔1〕之化合物爲基礎，螯合劑亦可以水溶液或 泥漿之形式使用。當藉由上述滿足上述條件之反應而獲得 螯合劑時，實際上可使用反應混合物，但若雜質之含量超 本紙張尺度適用中國國家標準（CNS〉A4規格（210X 297公釐） 一 13 - (請先閲讀背面之注意事項再填寫本頁) 裝-I 1 ϋ I »III -8-515784 A7 _B7___ V. Description of the invention (6) N, N-diacetic acid (ASDA), aspartic acid-N-monopropionic acid (ASMP), imine disuccinic acid (IDA ), N- (2-thiomethyl) aspartic acid (SMAS), N- (2-thioethyl) aspartic acid (SEAS), glutamate-N, N-diacetic acid (GLDA ), N — (2-thiomethyl) glutamic acid (SMGL), N — (2-thioethyl) glutamic acid (SEGL), N — methylimine diacetic acid (MIDA), “— Alanine- 1 ^, 1 ^ -diacetic acid (a ~ ALDA), alanine-N, N-diacetic acid (point one ALDA), serine-N, N-diacetic acid (SEDA), isose Amino acid N, N-diacetic acid (ISDA), phenylalanine mono-N, N-diacetic acid (PHDA), o-aminoaminobenzoic acid N, N-diacetic acid (ANDA), sulfanilic acid N, N-diacetic acid (SLDA), taurine-N, N-diacetic acid (TUDA) and thiomethyl-N, N-diacetic acid (SMDA) and its alkali metal salts or money salts. Central Standard of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperative (please read the precautions on the back before filling in this ) These compounds have asymmetric carbon, so they exist as optical isomers. From the viewpoint of biodegradability, (S) -aspartic acid-monoacetic acid, (S) -aspartic acid-N , N-diacetic acid, (S) -aspartic acid-monopropionic acid, (S, S) -imine disuccinic acid, (S, R) -imine disuccinic acid, (S) -2-sulfur Methyl aspartic acid, (S) -2-thioethyl aspartic acid, (S) -glutamine mono-N, N-diacetic acid, (S) -2-thiomethyl glutamine Acid, (S) -2-thiothioethylglutamic acid, (S) -α-alanine mono-N, N-diacetic acid, (S) -serine mono-N, N-diacetic acid, and (S) ) -Phenyl This paper is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) -9 515784 A7 —__ B7_ V. Description of the invention (7) Alanine mono-N, N-diacetic acid and its alkali metal or ammonium salt As for the diamine compound represented by the formula [1], where X is A1-CH-NH-A5-A 2-(C Η 2) n (where A1, A2 and A5 are as defined above), the following The substance is made of, for example, ethylenediamine disuccinic acid (EDDS), 1,3 propane Amine disuccinic acid (13PDDS), ethylene diamine diglutamic acid (EDDG), 1,3-propanediamine diamidine acid (13EDDG), 2-hydroxy-1,3-propanediamine disuccinic acid (PDDS-0H) and 2-hydroxy-1,3-propanediamine diamidine acid (PDDG-0H) and its alkali metal or ammonium salts. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) These compounds have asymmetric carbons and therefore exist as optical isomers. From the viewpoint of biodegradability, (S, S) -ethylenediamine disuccinic acid, (S, S) -1,3-propanediamine disuccinic acid, (S, S) -ethylene Ethyldiamine diglutamic acid, (S, S) — 1, 3-propanediamine diglutamic acid, (S, S) — 2-hydroxy-1,3-propanediamine disuccinic acid and (S, S) , S) -2-Hydroxy-1,3-propanediamine diamidine and its alkali metal or ammonium salt. Monoamine compounds are usually obtained by the addition of an initial amino acid or sulfonic acid with hydrocyanic acid and an aqueous formaldehyde solution, and hydrolysis under alkaline conditions to obtain an addition product, or an amine group The acid or sulfonic acid is compatible with the Chinese standard (CNS) A4 specification (210 乂 297 mm) -10-515784 A7 __B7 with the standard of this paper. It is hydrolyzed under the conditions to obtain an adduct. Therefore, the desired monoamine chelator generally contains side reaction products of impurities in addition to the starting amino acid or sulfonic acid. For example, in the synthesis of taurine-N, N-diacetate, the addition reaction product is obtained by adding hydrocyanic acid and an aqueous formaldehyde solution to taurine, and then hydrolyzing it. In addition to unreacted taurine, by-products such as glycolic acid, glycine, iminodiacetic acid, azatriacetic acid, fumaric acid, alanine and imine dipropionic acid are included. In addition to these impurities, impurities such as malic acid and acrylate are sometimes detected depending on the reaction conditions. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page). Diamine compounds are usually produced by adding two molecules of maleic acid to one-molecular olefin-based diamine. In this example, the desired desired diamine chelator usually contains impurities, unreacted maleic acid, and only one molecule of the maleic acid, the intermediate product of the maleated maleic acid, and its side reaction product. For example, in the synthesis of ethylenediamine disuccinate, by adding two molecules of maleic acid to one molecule of ethylenediamine, in addition to unreacted maleic acid, By-products such as ethylenediamine monosuccinic acid can be seen. Furthermore, regarding the preparation of diamine compounds, there are methods according to the following: two molecules of starting amino acids, such as aspartic acid or glutamic acid, are linked using dihalogenethane, epichlorohydrin or the like. In this example, the desired desired diamine polycarboxylic acid chelating agent usually contains impurities, a starting amino acid, a reaction intermediate product having a molecule of the starting amino acid added, and a side reaction product. . For example, the paper size of (S, S) -Ethylene Diamine Disuccinate is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) -11-515784 printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (9) In the synthesis of acid, a molecule of (S) -aspartic acid is added to one molecule of dichloroethane, and then the addition reaction product is added with an inorganic acid to perform precipitation. See that in addition to the unreacted (S) -aspartic acid, also see by-products, such as (S) -N-2-chloroethylaspartic acid, (S) -N — 2-Hydroxyethylaspartic acid, (S, S) —N — 2-Hydroxyethylendiamine disuccinic acid and trans-butenedioic acid. In the present invention, the chelating agent is prepared so that the content of the aforementioned impurity salt is 25% by weight or less, preferably 8% by weight or less, based on the weight of the compound of the formula [1] in the form of a salt. When such conditions are satisfied, especially when the content of the impurity salt is 8% by weight or less, the hardening of the obtained chelating agent is completely suppressed even in the ordinary storage stage. The total amount of the impurity salt is more preferably 3% by weight, based on the weight of the compound of the formula [1], and even under severe storage conditions, the optimal 3% by weight or less can completely inhibit the hardening into Lumps. When these conditions are met, powders that have been inhibited from hardening into lumps can only be obtained by concentrating the reaction mixture of the compound of formula [1] (hereinafter referred to simply as a reaction mixture), and from then on, The concentrated reaction mixture is subjected to spray drying and similar procedures, but in other examples, the content of impurity salts can be reduced by performing the following purification. As for the purification action of the chelating agent, the method includes the following method: Once a mineral acid such as sulfuric acid is added, precipitation occurs to isolate a high-purity crystalline chelating agent, and then the crystal is dissolved again in an alkali. In addition, when purifying a solid prochelant, it is also effective to use alcohols (such as methanol) Wash the chelating agent to remove low-molecular-weight low-molecular-weight impurities. The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page.) Printed by the Consumer Cooperatives of the Ministry of Central Standards Bureau 515784 A7 ______JB7_ V. Description of Invention (10) 〇 In the present invention, When the impurities are in the form of an acid, the chelating agent is also prepared in the same way as the mentioned impurities in the form of a salt, in other words, the content of these impurities is 25% by weight or less, preferably 8% by weight % Or less based on the compound of the formula [1]. When such conditions are satisfied, especially when the content of the impurity acid is 8% by weight or less, the obtained chelate is completely inhibited even in a general storage state. The hardening of the mixture. The total amount of impurity acids is more preferably 3% by weight or less, based on the compound of formula [1], and further preferably 0.5% by weight or less thoroughly even under severe storage conditions. Inhibition of hardening. If the total amount of impurity acids (salts) does not allow the above conditions to be met (the chelating agent obtained by the above reaction will only be added with acid for precipitation), the original crystals can be washed with a large amount of water and Repeated recrystallization of the original crystals, or purification by other methods. The chelating agents in the impurity content by these methods are purified to 25% by weight or less, even during storage or transportation, The chelant can be easily returned to the powder or flaky form as a crystal or flake. Therefore, the chelant can be stored for a long period of time and is stable and easy to handle. In the present invention, the chelant is adjusted to contain 2 5 Impurity salt by weight or less, preferably 10% by weight or less, more preferably 5% by weight or less, based on the compound of formula [1], the chelating agent may also be used in the form of an aqueous solution or a slurry When a chelating agent is obtained by the above reaction that satisfies the above conditions, the reaction mixture can be used in practice, but if the content of impurities exceeds the paper standard, the Chinese national standard (CNS> A4 specification (210X 297 mm)) 13- (Please read the notes on the back before filling out this page)

、tT 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（11 ) 過上述範圍時，則需額外之操作進行純化作用。 藉由上述方法經純化至2 5重量％或更低（依據雜質 之含量）之螯合劑可以包含至少10重量％水之水溶液或 泥漿之形式使用，但從防腐與操作能力之觀點，希望使用 在螯合劑之鹽濃度爲5 _80重量％，較佳20 - 50重 量％之水溶液或泥漿。 做爲操作（例如儲放，輸送或混合）所使用之桶，槽 車，儲存槽，攪拌機與類似物之材質可爲任何合金，玻璃 襯料，合成樹脂襯料與類似物，最佳爲不銹鋼。 就化合物濃度爲5 — 4 0重量％而論，本發明之螯合 劑之操作溫度較佳爲0 — 7 5°C，至於化合物濃度爲4 0 一 5 0重量％時，較佳之操作溫度爲5 - 7 5°C，而化合 物濃度爲5 0 — 8 0重量％時，較佳之操作溫度爲1 ◦一 7 5 〇C。 通常，在這些條件之下儲放約3年是可能的，品質未 降低之螯合劑水溶液或泥漿可容易地取出並依照需要使用 〇 在此方法所獲得之螯合劑與表面活化劑及其他添加劑 之添加而構成具有優異之清淨力。 一般這些螯合劑係以鹼金屬鹽（例如鈉鹽與鉀鹽）之 形式使用，但可以藉由溶解在鹼性水溶液中添加酸而沈澱 所分離出來之酸形式結晶物所獲得之部份中和之水溶液形 式使用，以鹼性水溶液之反應混合物之形式使用，以藉由 濃縮上述水溶液所獲得之固體鹽之形式使用，或以任何其 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 扣衣-----Ί (請先閲讀背面之注意事項再填寫本頁) ί.— ϋϋ ! Hal «ml ϋϋ n ^ mi in·— m« ml In —-flu In ml n···- ϋϋ ϋ·ϋ ·, TT 515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (11) When the above range is exceeded, additional operations are required for purification. The chelating agent purified to 25% by weight or less (depending on the content of impurities) by the above method may be used in the form of an aqueous solution or slurry containing at least 10% by weight of water, but from the viewpoint of antiseptic and handling ability, it is desirable to use it in The salt concentration of the chelating agent is 5 to 80% by weight, preferably 20 to 50% by weight of an aqueous solution or mud. The barrel, tanker, storage tank, mixer and the like used for operation (such as storage, transportation or mixing) can be made of any alloy, glass lining, synthetic resin lining and the like, preferably stainless steel . As far as the compound concentration is 5 to 40% by weight, the operating temperature of the chelating agent of the present invention is preferably 0 to 75 ° C. As for the compound concentration of 40 to 50% by weight, the preferred operating temperature is 5 -7 5 ° C, and when the compound concentration is 50-80% by weight, the preferred operating temperature is 1 ◦ 750 ° C. Generally, it is possible to store for about 3 years under these conditions. Chelating agent aqueous solution or slurry without degrading quality can be easily taken out and used as needed. The chelating agent, surfactant and other additives obtained by this method It is added to have excellent detergency. Generally, these chelating agents are used in the form of alkali metal salts (such as sodium salt and potassium salt), but can be partially neutralized by dissolving the acid form crystals separated by adding an acid in an alkaline aqueous solution to precipitate Use in the form of an aqueous solution, in the form of a reaction mixture of an alkaline aqueous solution, in the form of a solid salt obtained by concentrating the above-mentioned aqueous solution, or in accordance with the Chinese National Standard (CNS) A4 specification (210X297) Li) Button-up clothes ----- Ί (Please read the precautions on the back before filling this page) ί.— ϋϋ! Hal «ml ϋϋ n ^ mi in · — m« ml In —-flu In ml n ·· ·-Ϋϋ ϋ · ϋ ·

IT -14 - 經濟部中央摞準局員工消費合作社印製 515784 A7 ______B7_ 五、發明説明（12 ) 他之形式使用。若需要的話，在使用時這些螯合劑可調整 至適當之p Η。換句話說，本發明之螯合劑可以經抑制硬 化避免成爲成爲塊狀物之粉末或薄片及水溶液或泥漿之任 一形式使用。 接下來，將解釋說明本發明之清潔劑組成物。 本發明之清潔劑組成物包含本發明之螯合劑，尤其是 (S ) -天冬胺酸一 Ν，Ν -二醋酸，Ν —甲基亞胺二醋 酸且/或牛磺酸一 Ν，Ν -二醋酸，若需要的話，亦包含 非離子表面活化劑，陰離子表面活化劑，矽酸鹽，漂白劑 且/或脂肪酸鹽。 在本發明中可使用之非離子表面活化劑包括，例如經 乙氧化之壬基酚，經乙氧化之辛基酚，經乙氧化之山梨糖 醇酐脂肪酸酯與其氧化丙烯加成物，這些非離子表面活化 劑並不特別地限制。然而，藉由每一分子由下式〔2〕所 代表之醇或酚平均5 - 12，較佳6 — 8環氧乙烷及平均 0 — 12，較佳2 — 5環氧丙烷之隨意或嵌段加成作用所 獲得之化合物具有特別高之清淨力，例如，經乙氧化之一 級脂肪族醇，經乙氧化之二級脂肪族醇及其環氧丙烷加成 物。這非離子表面活化劑可各自單獨使用或以二或更多之 混合物使用。 R — Ο Η 〔 2〕 (R : 8 - 24碳原子之烷基，鏈烯基或烷苯基）。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 一 -15 - (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 515784 A7 _ B7五、發明説明（I3 ) 在本發明中可使用之陰離子表面活化劑，例如平均具 有8 - 1 6碳原子之烷基之直鏈烷基苯磺酸鹽，平均1 〇 —2 0碳原子之α -烯烴磺酸鹽，由下式〔3〕代表之脂 肪族之較低碳數之烷基磺酸鹽或脂肪族之磺酸作用產物， 平均1 0 - 2 0碳原子之烷基硫酸鹽，平均具有1 〇 -2 0碳原子之直鏈或支鏈烷基或鍵烯基及另外所添加之平 均具有〇·5-8莫耳環氧乙烷之烷基醚硫酸鹽或鍵烯基 醚硫酸鹽，及平均1 0 - 2 2碳原子之飽和或不飽和脂肪 酸鹽。 (請先閱讀背面之注意事項再填寫本頁)IT -14-Printed by the Consumers' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs 515784 A7 ______B7_ V. Description of Invention (12) Use in other forms. If necessary, these chelating agents can be adjusted to an appropriate p 时 during use. In other words, the chelating agent of the present invention can be used in any form of powder or flakes and an aqueous solution or mud which is prevented from becoming hardened by being hardened. Next, the detergent composition of the present invention will be explained. The detergent composition of the present invention contains the chelating agent of the present invention, especially (S) -aspartic acid-N, N-diacetic acid, N-methylimine diacetic acid and / or taurine-N, N -Diacetic acid, if required, also contains non-ionic surfactants, anionic surfactants, silicates, bleaches and / or fatty acid salts. Non-ionic surfactants that can be used in the present invention include, for example, ethoxylated nonylphenol, ethoxylated octylphenol, ethoxylated sorbitan fatty acid ester and its propylene oxide adduct, these The nonionic surfactant is not particularly limited. However, with each molecule of alcohol or phenol represented by the following formula [2], an average of 5 to 12, preferably 6 to 8 ethylene oxide and an average of 0 to 12, preferably 2 to 5 propylene oxide can be used. The compounds obtained by block addition have particularly high detergency, for example, ethoxylated primary aliphatic alcohols, ethoxylated secondary aliphatic alcohols, and propylene oxide adducts thereof. These nonionic surfactants may be used each alone or in a mixture of two or more. R — Ο Η [2] (R: alkyl, alkenyl or alkylphenyl of 8 to 24 carbon atoms). The size of this paper applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -15-(Please read the notes on the back before filling this page) Binding and binding 515784 A7 _ B7 V. Description of the invention (I3) Anionic surfactants that can be used in the invention, for example, linear alkylbenzene sulfonates of alkyl groups having an average of 8 to 16 carbon atoms, α-olefin sulfonates of average 10 to 20 carbon atoms, from the following An aliphatic alkyl sulfonate with a lower carbon number or an aliphatic sulfonic acid reaction product represented by the formula [3], an average alkyl sulfate having 10 to 20 carbon atoms, having an average of 10-20 carbons Atomic straight or branched chain alkyl or bond alkenyl and other added alkyl ether sulfates or bond alkenyl ether sulfates with an average of 0.5-8 moles of ethylene oxide, and an average of 10-2 A saturated or unsaturated fatty acid salt of 2 carbon atoms. (Please read the notes on the back before filling this page)

R — CH — COOY 3 S 0 3 Ζ 裝-----！--訂--- 經濟部中央標準局員工消費合作社印製 (R:8-20碳原子之烷基或鍵烯基，Υ:1—3碳原 子之烷基或平衡離子，而Ζ:平衡離子）。 在本發明中可使用之矽酸鹽係由下式〔4〕所代表之 矽酸鹽或由下式〔5〕所代表之鋁矽酸鹽，且其可各自單 獨使用或以適當比例之二或多之混合物使用。在清潔劑組 成物中，矽酸鹽之量爲0 · 5 — 80重量％，較佳5 — 4 0重量％。 〇 2Cx + i) · y Η 2 〇 4 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -16 - 515784 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（Η ) (L代表鹼金屬，Μ，代表鈉或氫，X代表1·9一4之 數值，而y代表0 - 20之數值）。 Naz〔（A102)z(Si02)y〕· χ Η 20 〔5〕 (ζ代表6或更大之數值，y代表滿足ζ與y之比例爲 1·0-0·5之數值，而χ代表5—276之數值）。 在本發明中可使用之漂白劑包括，例如過碳酸鈉與過 硼酸鈉。在清潔劑組成物中，這些漂白劑之量爲〇.5- 6 0重量％，較佳1 一 40重量％，更佳2 - 2 5重量％ 〇 在本發明中所使用之脂肪酸鹽包括，例如鹼金屬鹽， 鹼土金屬鹽，銨鹽或未經取代或經取代之銨鹽，較佳爲鹼 金屬鹽或鹼土金屬鹽，更佳爲平均1 〇 - 2 4碳原子飽和 或不飽和脂肪酸之鹼金屬鹽。這些脂肪酸鹽亦可以二或多 種之混合物使用。 在本發明中所使用之脂肪酸鹽之實例爲鹼金屬鹽，鹼 土金屬鹽，銨鹽或未經取代或經取代之銨鹽，較佳爲鹼金 屬鹽，鹼土金屬鹽，銨鹽或未經取代或經取代之胺鹽，較 佳爲月桂酸，肉豆蔻酸，硬脂酸與類似物之鹼金屬鹽。 本發明之清潔劑組成物可另外包含不同之添加劑，例 如安定劑，鹼鹽，酵素，香料，表面活化劑（除了非離子 與陰離子型式），附著物抑制劑，泡沫劑與抗泡沬劑。 另外較高性質之清潔劑組成物可藉由使用多數螯合劑 (請先閲讀背面之注意事項再填寫本頁) II ϋϋ a^li m 1*1— in^|心 ml ---------------- # 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 17 - 515784 Α7 Β7 經濟部中央標準局員工消費合作社印製 五、發明説明（15 ) 結合而獲得。 在一些實例中，視所採用之P Η而定，螯合力量不能 充份地顯現螯合劑之用途，但優秀之清潔劑組成物具有不 受其所使用之環境中pH之變化而影響其清淨力，此優秀 之清潔劑組成物可藉由使用多數螯合劑之混合物而獲得。 在對p Η具有優異適應性之本發明之清潔劑組成物中 所使用之螯合劑爲（S) —天冬胺酸一 Ν，Ν —二醋酸， 牛磺酸一 Ν，Ν —二醋酸與Ν —甲基亞胺二醋酸。其每一 種之特徵於下解釋。 在對Ρ Η具有優異適應性之本發明之清潔劑組成物中 可使用（S) -天冬胺酸_Ν，Ν —二醋酸。尤其，其在 中性Ρ Η區域中授與優異之性能，因此是較佳的。在上述 三種Ν，Ν -二醋酸型式之螯合劑中，對於鈣或類似物之 螯合劑安定性常數是特別重要的。因此，同樣結合羧酸表 面活化劑（例如月桂酸鈉），（S ) —天冬胺酸一 Ν，Ν 一二醋酸與目的金屬堅固地結合成螯合劑，因此是較佳的 〇 曾記載關於氮三乙酸之鈣之螯合劑安定性常數爲 6 . 4而（S) -天冬胺酸一 Ν，Ν -二醋酸之鈣之螯合 劑安定性常數爲5 · 8。然而，事實上關於實際組份性能 ，（S)—天冬胺酸一Ν，Ν-二醋酸是優於氮三乙酸。 由於（S ) —天冬胺酸一 Ν，Ν —二醋酸爲具有四羧基之 單胺螯合劑，其可藉由在最大之五配位基配位排列捕集目 的之金屬（例如鈣）。因此，當與具有三羧基之氮三乙酸 (請先閱讀背面之注意事項#|填寫本頁) 裝· 訂 '參 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ29?公釐） 一 18 - 515784 A7 B7__ 五、發明説明（) (藉由在最大之五配位基配位排列捕集目的之金屬（例如 鈣））做比較時，（S)—天冬胺酸一N，N—二醋酸之 螯合力大於氮三乙酸之螯合力並在中性區域中展示顯著之 優異性能。 與磺酸表面活化劑（例如十二烷基苯磺酸鈉）結合， (S) —天冬胺酸一 N，N —二醋酸在pH7 - 8具有高 於氮三乙酸之C a + +捕集力且等於伸乙基二胺四醋酸之 C a + +捕集力。 當使用月桂酸鈉（爲一種羧酸表面活化劑）取代十二 烷基苯磺酸鹽（爲一種磺酸表面活化劑）時，在PH 1 2 (S) —天冬胺酸一 N，N —二醋酸保留約50%之 C a + +捕集力。具有如上相同之表面活化劑取代時，（S )一天冬胺酸一 N，N —二醋酸之C a + +捕集力係劣於保 留約9 0 % C a + +捕集力之伸乙基二胺四醋酸，但下述事 實是令人驚訝的：在存有羧酸表面活化劑之情況下，大部 份已知單胺螯合劑完全失去C a + +捕集力。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 在生物降解能力試驗中，例如關於化學藥品之試驗之 OE CD指導方針中所描述之3 0 2A經改良之S CAS 試驗，（S) -天冬胺酸一 N，N -二醋酸完全地分解爲 無機物質。在某些時間週期中藉由活化淤泥完全分解包含 (S)—天冬胺酸一 N，N—二醋酸之家用廢水。 在對P Η具有優異適應性之本發明之清潔劑組成物中 可使用牛磺酸一 Ν，Ν —二醋酸，且因其在微弱鹼pH區 域中授給優異性能，因此其是最佳的。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -19 - 515784 Α7 Β7 五、發明説明（17 ) 曾記載牛磺酸- N，N -二醋酸對於鈣之螯合物安定 性常數爲4 · 2之值。然而，在實際組份性能方面，事實 上牛磺酸一 N，N -二醋酸優於氮三乙酸。當從螯合性能 之觀點來看牛磺酸一 N，N -二醋酸之分子結構時，其包 含直接參與目的之金屬之捕集力之亞胺二醋酸部份及參與 適應目的金屬捕集力之p Η之磺酸部份。意即認爲牛磺酸 一 Ν，Ν —二醋酸之磺酸基不會直接參與目的之金屬之捕 集，但安排之化學環境使得分子在較中性側藉由例如對中 性側等電點之移動作用而易於顯現其螯合力。 結合磺酸表面活化劑，牛磺酸- Ν，Ν -二醋酸在 ρ Η 8具有等於伸乙基二胺四醋酸之C a + +捕集力，且在 PH8 · 5或更高則優於伸乙基二胺四醋酸。在相同條件 之下，下述事實令人驚訝：當與氮三乙酸（典型之相同N ，N—二醋酸螯合劑）比較時，僅當pH達到1 〇時， C a + +捕集力超過伸乙基二胺四醋酸。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在生物降解能力試驗中，例如上述之3 0 2 A經改良 之S CAS試驗，在短時間內牛磺酸一 Ν，N —二醋酸完 全分解爲無機物質。在短時間內藉由活化淤泥與包含牛磺 酸一 Ν，N -二醋酸之廢水浸化而完全地分解。 在對p Η具有優異之適應性之本發明之清潔劑組成物 中可使用甲基亞胺二醋酸且是最佳的，因此其在鹼性ρ Η 區域中授給優異之性能。 曾記載甲基亞胺二醋酸關於鈣之螯合物安定性常數爲 3 · 7。然而，在實際之組份性能方面，事實上甲基亞胺 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） -20 - 515784 A7 B7 五、發明説明（i8 ) 二醋酸超過氮三乙酸。當從螯合性能之觀點來看甲基亞胺 二醋酸之結構時，認爲因藉由甲基之導入及因其小分子量 ，增加每重量C a 〃捕集力而使胺基轉化成爲三級結構胺 基，使得對於鈣之螯合物安定性常數較簡單之亞胺二醋酸 增加。 與磺酸表面活化劑結合，在pH至少爲1 〇，甲基亞 胺二醋酸在C a —捕集力遠大於伸乙基二胺四醋酸，此外 其顯現令人驚訝之性能：在相同條件之下，超過被視爲具 有優異性能之氮三乙酸之性能。 在生物降解能力試驗中（例如在關於化學藥品試驗之 OE CD指導方針中所描述之3 0 1 C改良之Μ I T I試 驗（1))，於短時間內甲基亞胺一 Ν，Ν —二醋酸完全 分解爲無機物質。甲基亞胺二醋酸易受居住於環境之水中 (例如河流，湖泊）之微生物所分解，一般污水不需要進 行活化淤泥處理或類似方法處理。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) (S) -天冬胺酸一 Ν -單一醋酸與（S) —天冬胺 酸- Ν -單丙酸爲適合甲基亞胺二醋酸之生物可降解之組 份，但雖然在Ρ Η爲1 0或更高之下其顯現優異之組份性 能，其每重量C a + +捕集力劣於甲基亞胺二醋酸，因此其 必須大量使用。在生物降解能力試驗中（例如上述之 301C改良之MITI試驗），在短時間內（S) —天 冬胺酸一 N —單醋酸與（S ) -天冬胺酸一 N -單丙酸完 全轉化成爲無機物質。其易受居住於環境之水中（例如河 流，湖泊）之微生物分解，一般污水不需要進行活化淤泥 本紙張尺度適用中國國家標準（CNS〉A4規格（210X297公釐） -21 - 515784 A7 __B7 五、發明説明（19 ) 處理或類似方法處理。 在上述，（S)-天冬胺酸一N，N-二醋酸，牛磺 酸一 N，N —二醋酸與甲基亞胺二醋酸係以其如同生物可 降解之組份之特徵解釋。同時包含至少二種做爲組份成份 之清潔劑組成物在寬廣之P Η條件中展現優異之性能。意 即，藉由適當包含這些組份成份，在從中性區域至鹼性區 域之寬廣，Ρ Η條件中可獲得之性能等於或高於迄今較佳 被使用做爲優異組份之伸乙基二胺四醋酸之性能。而且， 在特殊ρ Η與特殊表面活化劑之條件之下，藉由增加特殊 生物可降解之組份成份之含量亦可能特別顯示出優異之性 在例如紙漿與衣服之用途中，添加做爲漂白目的之過 氧化氫或有機過氧化物，且組份具有避免這些過氧化物受 重金屬，例如鐵之催化而分解之能力。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在食品加工工業之領域中，在啤酒瓶，餐具與機器設 備之洗滌中，僅包含做爲主要成份之組份成份且不包含表 面活化劑之清潔劑組成物有時用於移除碳酸鈣，草酸鈣與 類似物。 本發明之清潔劑組成物可包含，如緩衝劑，安定劑與 再黏附抑制劑，一般輔助添加劑，矽酸之鹽類，結晶鋁矽 酸，薄片狀之矽酸與類似物，胺基酸（例如甘胺酸，-丙胺酸，牛磺酸，天冬胺酸與榖胺酸）之鹽類，聚合物（ 例如聚丙烯酸，聚順-丁烯二酸，聚烏頭酸，聚縮醛羧酸 ，聚乙烯吡咯酮，羧甲基纖維素與聚乙二醇）之鹽類，有 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -22 - 經濟部中央標準局員工消費合作社印製 515784 A7 _____B7 五、發明説明（2〇 ) 機酸（例如檸檬酸，蘋果酸，反一 丁烯二酸二鈉，琥珀酸 ，葡萄糖酸與酒石酸）之鹽類，酵素（例如蛋白酶，脂肪 酶與纖維素酶，及對-甲苯磺酸與硫代磺酸之鹽類。 可另外添加膠凝抑制劑，例如矽酸鈣，過氧化物安定 劑’例如矽酸鎂，抗氧化劑，例如第三丁基羥基甲苯，螢 光塗料，香料與其他物質。這些物質並未限制但可視用途 而添加。 本發明並不排除使用結合上述組份，三聚磷酸，焦磷 酸與類似物之鹽類，二伸乙基三胺五醋酸，伸乙基二胺四 醋酸，氮三乙酸與類似物之鹽類，及其他物質（如組份） 。然而，從安全之觀點及環境負荷之減小，希望避免使用 這些傳統之組份。 接下去，根據本發明清潔劑組成物之成份之使用條件 與比例將詳細地說明。 在廣泛使用條件之下，爲了獲得等於或高於優異組份 之伸乙基二胺四醋酸之性質，希望同時使用在（S) -天 冬胺酸一 N，N—二醋酸，牛磺酸一 N，N -二醋酸與甲 基亞胺二醋酸三種組份之中至少二種生物可降解之組份。 較佳使用5 — 9 7重量％ (依據酸），較佳40 - 9 5重 量％(8)—天冬胺酸一1^，1^一二醋酸，0 — 9 7重量 % (依據酸），較佳40 - 90重量％牛磺酸一 N，N -二醋酸，與〇 - 97重量％ (依據酸），較佳30-70 重量％甲基亞胺二醋酸。希望組份之總量爲6 - 8 1 0重 量％(依據以表面活化劑成份爲基礎之酸），較佳爲20 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 裝-----7 (請先閱讀背面之注意事項再填寫本頁) J--訂-- -23 - 515784 A7 ____B7 五、發明説明（21 ) 一240重量％，更佳爲80—120重量％。 就採用此類生物可降解組份之組成物比例之情況而言 ，每重量（依據酸）組份性能等於或高於在pH6 - 1 3 範圍中伸乙基二胺四醋酸或氮三乙酸與表面活化劑（在分 散能力有優異表現之磺酸型式）結合之組份性能且等於或 高於在P Η 7 — 1 2範圍中伸乙基二胺四醋酸或氮三乙酸 與表面活化劑（在分散能力有表現不佳之羧酸型式）結合 之組份性能。在此之組份性能不僅包括C a + +捕集力，亦 包括例銹皮或重金屬之分散能力，p Η緩衝能力，污物再 黏附之抑制作用，液體清潔劑沈澱之抑制作用與固體清潔 劑之形狀保持，根據本發明之組份亦超過氮三乙酸之這些 性質，且所獲得之性質不輸於伸乙基二胺四醋酸與三聚磷 酸之性質。 當事先已知某些用途之條件時，例如Ρ Η與所使用之 表面活化劑，較方便製備具有適合這些用途條件之生物可 降解之組份組成物比例之清潔劑組成物。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在很多例子中，在約6.5—8.5之pH中結合表 面活化劑（例如十二烷基苯磺酸鹽，月桂醇硫酸鹽酯與聚 乙二醇）使用關於家用廚房與衣服之中性清潔劑。在這些 用途中，適合使用20 — 9 7重量％ (依據酸），較佳 50 - 95重量％ 2(S) -天冬胺酸一 N，N -二醋酸 ，50-90重量％ (依據酸），較佳50 — 80重量％ 之牛磺酸一 N，N —二醋酸，及0 - 2 0重量％ (依據酸 )，較佳10 — 15重量％之甲基亞胺二醋酸，係以組份 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 24 - 經濟部中央標準局員工消費合作社印製 515784 A7 B7 五、發明説明（22 ) 組成物爲基礎。 做爲衣服，餐具，機器設備，瓶子及其他之清潔用之 工業清潔劑係在從中性至強鹼條件之廣寬P Η範圍中使用 。尤其在ΡΗ9—13之鹼條件之下之用途中’適合使用 0 - 90重量％ (依據酸），較佳20 - 50重量％之（ S) -天冬胺酸一 Ν，Ν -二醋酸，5 - 90重量％ (依 據酸），較佳50 — 80重量％之牛磺酸一 Ν，Ν -二醋 酸，20 - 97重量％ (依據酸），較佳60 - 90重量 %之甲基亞胺二醋酸，係以組份組成物爲基礎。 然而，實際上在ΡΗ9 - 1 3之鹼條件之下工業清潔 劑之用途，當使用在分散能力拙劣之表面活化劑（例如月 桂酸鹽）時，適合使用20_95重量％(依據酸），較 佳5 0 — 9 0重量％之（S) —天冬胺酸一 Ν，Ν -二醋 酸，5 — 90重量％ (依據酸），較佳50 - 80重量％ 之牛磺酸一 Ν，Ν —二醋酸，及〇 — 2 0重量％ (依據酸 )，較佳10—15重量％之甲基亞胺二醋酸，係以組份 組成物爲基礎。 而且，在任何用途中，在本發明之清潔劑組成物中生 物可降解之組份成份之甲基亞胺二醋酸之全部或部份可以 (S) -天冬胺酸一 Ν -單醋酸與（S) -天冬胺酸一 Ν 一單丙酸之一或二者取代。當使用（S) -天冬胺酸一 Ν 一單醋酸時，適合使用80一350重量％(依據酸）， 較佳1 5 0 - 3 2 0重量％，係以甲基亞胺二醋酸爲基礎 。當使用（S) —天冬胺酸一 Ν —單丙酸時，適合使用 本紙張尺度適用中國國家標準（CNS ) Α4規格（21GX 297公釐)" 一 25 - ϋ—· ϋϋ ϋ-· n··— am· 11 Hal ϋ· —^i_i —ϋ V ml ml ·11 (請先閱讀背面之注意事項再填寫本頁) 4 515784 A7 B7 五、發明説明（23 ) 120-560重量％ (依據酸），較佳240 - 420 重量％，係以甲基亞胺二醋酸爲基礎。 本發明之清潔劑組成物亦可以預定之比例藉由混合螯 合劑與表面活化劑及其他組成成份而製備如液體清潔劑或 高濃度之粉末清潔劑，且此清潔劑組成物可在使用時以水 稀釋至所要之濃度。可替代的是這些成份可以預定之比例 添加至稀釋水中。 本發明將藉由下述實例做更詳細地說明，無論如何這 些實例不被解釋爲本發明之限制。 例1 包含1 0 0 0克（S ) -天冬胺酸一 N -單醋酸之三 鈉鹽（S — ASMA - 3Na)與25 · 0克雜質鹽（包 含18 · 3克天冬胺酸二鈉，4 · 0克反一 丁烯二酸二鈉 ’ 2 · 2克甘胺酸之單鈉鹽與〇 · 5克順一 丁烯二酸二鈉 )之乾燥粉末之硬化強度係藉由在2 0 0〔克/公分2 〕 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 之負載之下，儲放2個月之時間後，根據 J 1 s A 1 108之下述方法（關於測量混凝土之壓 縮強度之方法）所測量之壓縮強度表示，因此，評價粉末 之硬化性質。 <關於壓縮強度之測量方法> (1)將試驗樣品（500克）放在20公分X20 公分之聚乙烯袋中並放置於2 〇 — 3 0°C之溫度與4 0 — 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇><297公釐） - 26 _ 515784 A7 __B7 _ 五、發明説明（24 ) 7 0%相對濕度之室中。將粉末舖平至2 0公分X 2 0公 分之區域，將空氣從袋中壓出來，然後密封該袋。將此袋 另外放在牛皮紙袋中並密封此牛皮紙袋。 (2) 將（1)之牛皮紙袋水平放在平坦之板上並將 一板放置在牛皮紙袋上。將4個各自重2 0公斤之重物放 在上端之板上以對試驗樣品提供2 0 0〔克/公分2 〕之 負載。 (3) 保持20 — 30 °C之溫度及40 - 70%之相 對濕度，在提供負載起始2個月時間之後將試驗樣品拿出 。從樣品剪去數個試驗片（4公分長X 4公分寬X 2公分 高）。 (4 )藉由壓縮測試器（電腦控制之通用精密測試器 :Simadzu自動繪圖儀AG S — 1 0 〇 B ;最大負載： 100公斤；負載速度：2〔公分/分鐘〕）負載試驗片 ，最大負載（爲測試器顯示當試驗片破碎時之值）除以試 驗片之斷面積，所得值做爲壓縮強度。 由於測量之結果，試驗片具有1 · 2〔克/公分2 〕 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 之壓縮強度，且其在如此之狀態可被分解而不需任何特殊 之研磨之處理。 例2 除了使用1 000克（S) -天冬胺酸一 N —單丙酸 之三鈉鹽（S — ASMP — 3Na)與20 · 0克雜質鹽 (包含8 · 2克反—丁烯二酸二鈉，6 · 2克天冬胺酸二 本紙張尺度適用中國國家標準（CNS ) A4規格（210、乂29?公釐） -27 - 515784 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（25 ) 鈉，4 · 3克亞胺二醋酸二鈉，1 · 1克順一丁烯二酸二 鈉與0·2克氮三乙酸三鈉）之外，以如例1之相同方法 進行實驗。結果示於表1中。 例3 除了使用1 000克（S) —天冬胺酸一 N，N —單 醋酸之四鈉鹽（S — ASDA — 4Na)與15 · 0克雜 質鹽（包含5 · 5克天冬胺酸二鈉，3 · 1克反一 丁烯二 酸二鈉，3 · 1克Θ -丙胺酸之鈉鹽，2 · 4克亞胺二丙 酸二鈉，0 . 7克順—丁烯二酸二鈉與〇 · 2克丙烯酸鈉 )之外’以如例1之相同方法進行實驗。結果示於表1中 0 例4 除了使用1 000克（S) — c«—丙胺酸一 N，N — 二醋酸之三鈉鹽（S— ALDA — 3Na)與22 · 5克 雜質鹽（包含1 · 5克α -丙胺酸之單鈉鹽，3 · 6克甘 胺酸之單鈉鹽，4 · 8克亞胺二醋酸二鈉與3 · 7克氮三 乙酸三鈉）之外，以如例1之相同方法進行實驗。結果示 於表1中。 例5 除了雜質鹽之含量變爲5·0%且應用至試驗樣品之 負載爲100〔克/公分2 〕之外，使用相同之組成物， 度朗巾酬家^ ( CNS ) Α4規格（210X297公釐) 一 28 -R — CH — COOY 3 S 0 3 ZE equipment -----! --Order --- Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (R: 8-20 carbon atom alkyl or bond alkenyl, Υ: 1-3 carbon atom alkyl or counter ion, and Z: balanced ion). The silicate that can be used in the present invention is a silicate represented by the following formula [4] or an aluminosilicate represented by the following formula [5], and they can be used individually or in appropriate proportions of two Or more mixtures. In the detergent composition, the amount of silicate is from 0.5 to 80% by weight, preferably from 5 to 40% by weight. 〇2Cx + i) · y Η 2 〇4 This paper size applies to Chinese National Standards (CNS) A4 specifications (210X297 mm) -16-515784 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ) (L represents an alkali metal, M, represents sodium or hydrogen, X represents a value of 1.9-4, and y represents a value of 0-20). Naz [(A102) z (Si02) y] · χ Η 20 [5] (ζ represents a value of 6 or more, y represents a value satisfying a ratio of ζ to y of 1 · 0-0 · 5, and χ represents 5-276). Bleaching agents that can be used in the present invention include, for example, sodium percarbonate and sodium perborate. In the detergent composition, the amount of these bleaching agents is 0.5 to 60% by weight, preferably 1 to 40% by weight, and more preferably 2 to 25% by weight. The fatty acid salts used in the present invention include, For example, alkali metal salts, alkaline earth metal salts, ammonium salts or unsubstituted or substituted ammonium salts, preferably alkali metal salts or alkaline earth metal salts, and more preferably, saturated or unsaturated fatty acids having an average of 10 to 24 carbon atoms. Alkali metal salt. These fatty acid salts can also be used as a mixture of two or more kinds. Examples of fatty acid salts used in the present invention are alkali metal salts, alkaline earth metal salts, ammonium salts or unsubstituted or substituted ammonium salts, preferably alkali metal salts, alkaline earth metal salts, ammonium salts or unsubstituted Or a substituted amine salt, preferably an alkali metal salt of lauric acid, myristic acid, stearic acid and the like. The detergent composition of the present invention may further include various additives, such as stabilizers, alkali salts, enzymes, perfumes, surfactants (except non-ionic and anionic types), attachment inhibitors, foaming agents, and antifoaming agents. In addition, higher-quality detergent compositions can be used by most chelating agents (please read the precautions on the back before filling this page) II ϋϋ a ^ li m 1 * 1— in ^ | 心 ml ------ ---------- # This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm)-17-515784 Α7 Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ) Combined. In some examples, depending on the P 采用 used, the chelating power may not fully manifest the use of a chelating agent, but an excellent detergent composition is not affected by the change of pH in the environment in which it is used to affect its cleanliness This excellent detergent composition can be obtained by using a mixture of most chelating agents. The chelating agent used in the detergent composition of the present invention having excellent adaptability to pΗ is (S) -aspartic acid-N, N-diacetic acid, taurine-N, N-diacetic acid and N-methylimine diacetic acid. The characteristics of each of them are explained below. (S) -Aspartic acid_N, N-diacetic acid can be used in the detergent composition of the present invention having excellent adaptability to PΗ. In particular, it imparts excellent performance in the neutral PZ region and is therefore preferred. Among the above three types of chelating agents of the N, N-diacetic acid type, the stability constants of chelating agents for calcium or the like are particularly important. Therefore, the same combination of carboxylic acid surfactant (such as sodium laurate), (S) -aspartic acid-N, N-diacetic acid and the target metal are firmly combined to form a chelating agent, so it is better. The stability constant of the chelating agent of calcium azatriacetate is 6.4 and the stability constant of the chelating agent of (S) -aspartic acid-N, N-diacetic acid calcium is 5.8. However, in fact, regarding actual component performance, (S) -aspartic acid mono-N, N-diacetic acid is superior to nitrogen triacetic acid. Since (S) -aspartic acid mono-N, N-diacetic acid is a monoamine chelating agent having a tetracarboxyl group, it can capture the target metal (for example, calcium) by arranging coordination at the largest five ligands. Therefore, when combined with nitrogen triacetic acid with tricarboxyl group (please read the precautions on the back # | Fill this page first) Binding and binding 'Refer to the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 × 29? Mm)-18 -515784 A7 B7__ V. Description of the invention () (by comparing the metal (for example, calcium) for the purpose of capture with the largest five ligand coordination arrangement), (S) —aspartic acid-N, N— The chelating power of diacetic acid is greater than the chelating power of azatriacetic acid and exhibits remarkable excellent performance in the neutral region. In combination with a sulfonic acid surfactant (such as sodium dodecylbenzenesulfonate), (S) -aspartic acid mono-N, N-diacetic acid has a higher C a + + capture rate than nitrogen triacetic acid at pH 7-8 The concentration is equal to the C a + + trapping force of ethylenediaminetetraacetic acid. When sodium laurate (as a carboxylic acid surfactant) is used in place of dodecylbenzenesulfonate (as a sulfonic acid surfactant), at pH 1 2 (S) —aspartic acid mono-N, N -Diacetic acid retains about 50% of the C a + trapping force. With the same surfactant substitution as above, the (C) + trapping power of (S) aspartate mono-N, N-diacetic acid is inferior to the elongation retention of about 90% C a + + trapping power. Diamine tetraacetic acid, but the fact that it is surprising is that in the presence of carboxylic acid surfactants, most known monoamine chelating agents completely lose their C a + + trapping power. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) In the biodegradability test, for example, 3 0 2A described in the OE CD guidelines for testing of chemicals In the S CAS test, (S) -aspartic acid mono-N, N-diacetic acid was completely decomposed into inorganic substances. In certain time periods, domestic wastewater containing (S) -aspartic acid-N, N-diacetic acid is completely decomposed by activated sludge. Taurine-N, N-diacetic acid can be used in the detergent composition of the present invention having excellent adaptability to PΗ, and it is the best because it imparts excellent properties in a weak alkaline pH region. . This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -19-515784 A7 B7 V. Description of the invention (17) It has been recorded that taurine-N, N-diacetic acid is stable to calcium chelate The constant is a value of 4 · 2. However, in terms of actual component performance, taurine-N, N-diacetic acid is actually superior to nitrogen triacetic acid. When the molecular structure of taurine-N, N-diacetic acid is viewed from the viewpoint of chelating performance, it contains an iminodiacetic acid moiety that directly participates in the trapping force of the metal and the metal trapping force that participates in the adaptation of the purpose Of p Η of the sulfonic acid portion. It means that the sulfonic group of taurine-N, N-diacetic acid will not directly participate in the capture of the target metal, but the chemical environment is arranged so that the molecule is electrically charged on the more neutral side by, for example, isolating the neutral side. The movement of the dots makes it easy to show its chelating force. In combination with a sulfonic acid surfactant, taurine-N, N-diacetic acid has a C a + + trapping force equal to ethylene diamine tetraacetic acid at ρ Η 8 and is superior to PH 8 · 5 or higher Ethylenediamine tetraacetic acid. Under the same conditions, the following fact is surprising: when compared with nitrogen triacetic acid (typically the same N, N-diacetic acid chelating agent), only when the pH reaches 10, the C a + + trapping force exceeds Ethylenediamine tetraacetic acid. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) In the biodegradability test, such as the above-mentioned 3 2 A modified S CAS test, in a short time Acid mono-N, N-diacetic acid is completely decomposed into inorganic substances. It was completely decomposed in a short time by infiltration of activated sludge with wastewater containing taurine mono-N, N-diacetic acid. Methylimine diacetic acid can be used in the detergent composition of the present invention having excellent adaptability to pΗ, and it is the best, so it imparts excellent performance in the alkaline pρ region. It has been reported that the stability constant of calcium chelate of methylimine diacetate is 3.7. However, in terms of the actual component performance, in fact, the size of the methylimine paper is in accordance with the Chinese National Standard (CNS) A4 (210X 297 mm) -20-515784 A7 B7 V. Description of the invention (i8) Diacetic acid exceeds Nitrotriacetic acid. When the structure of methylimine diacetic acid is viewed from the viewpoint of chelating performance, it is thought that the amine group is converted into three groups due to the increase in Ca a trapping force per weight due to the introduction of methyl groups and its small molecular weight. The secondary structure of the amine group increases the stability constant for the chelate of calcium compared to the simpler imine diacetate. In combination with a sulfonic acid surfactant, at a pH of at least 10, the trapping power of methylimine diacetic acid at Ca is much greater than that of ethylenediamine tetraacetic acid. In addition, it exhibits surprising performance: under the same conditions Below, it exceeds the performance of nitrotriacetic acid, which is considered to have excellent performance. In biodegradability tests (such as the 3 0 1 C modified M ITI test (1) described in the OE CD guidelines on chemical testing), methylimine-N, N-di Acetic acid is completely decomposed into inorganic substances. Methyliminodiacetic acid is easily decomposed by microorganisms living in environmental water (such as rivers, lakes). Generally, sewage does not need to be treated with activated sludge or similar methods. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) (S) -Aspartic acid-N -Single acetic acid and (S) -Aspartic acid-Ν -monopropene Acid is a biodegradable component suitable for methylimine diacetic acid, but although it exhibits excellent component performance at a pH of 10 or higher, its C a + + trapping force per weight is inferior to Methylimine diacetic acid, so it must be used in large quantities. In the biodegradability test (such as the 301C modified MITI test), within a short period of time (S) —aspartic acid-N—monoacetic acid and (S) -aspartic acid-N-monopropionic acid are completely Conversion into inorganic substances. It is susceptible to microbial decomposition living in environmental water (such as rivers, lakes), and ordinary sewage does not need to be activated sludge. The paper size is applicable to Chinese national standards (CNS> A4 specification (210X297 mm) -21-515784 A7 __B7 V. Description of the invention (19) Treatment or similar methods. In the above, (S) -aspartic acid-N, N-diacetic acid, taurine-N, N-diacetic acid and methylimine diacetic acid are based on As the characteristics of the biodegradable components are explained. A detergent composition containing at least two kinds of components as components shows excellent performance under a wide range of conditions. That is, by including these components appropriately, In a wide range from the neutral region to the basic region, the performance obtainable under the conditions of P is equal to or higher than the performance of ethylenediaminetetraacetic acid, which has been hitherto preferably used as an excellent component. Moreover, in special ρ Η Under the conditions of special surfactants, by increasing the content of special biodegradable components, it may also show excellent properties. In applications such as pulp and clothing, it is added for bleaching purposes. Hydrogen peroxide or organic peroxide, and the components have the ability to prevent the decomposition of these peroxides by the catalysis of heavy metals, such as iron. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling in (This page) In the field of food processing industry, in the washing of beer bottles, tableware and machinery, detergent compositions that contain only the main component and do not contain a surfactant are sometimes used to remove Calcium carbonate, calcium oxalate and the like. The detergent composition of the present invention may contain, for example, buffering agents, stabilizers and re-adhesion inhibitors, general auxiliary additives, salts of silicic acid, crystalline aluminosilicic acid, flake silicon Acids and analogs, salts of amino acids (such as glycine, -alanine, taurine, aspartic acid and lysine), polymers (such as polyacrylic acid, polymaleic acid, Polyaconitic acid, polyacetal carboxylic acid, polyvinylpyrrolidone, carboxymethylcellulose and polyethylene glycol) salts, this paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -22 -Warp Printed by the Consumers' Cooperative of the Ministry of Standards, the Ministry of Standards and Technology 515784 A7 _____B7 V. Description of the invention (20) Organic acids (such as citric acid, malic acid, disodium fumarate, succinic acid, gluconic acid and tartaric acid) Enzymes (such as proteases, lipases and cellulases, and salts of p-toluenesulfonic acid and thiosulfonic acid. Gelation inhibitors, such as calcium silicate, and peroxide stabilizers, such as silicic acid Magnesium, antioxidants, such as tert-butyl hydroxytoluene, fluorescent coatings, perfumes and other substances. These substances are not limited but can be added depending on the application. The present invention does not exclude the use of a combination of the above components, tripolyphosphate, pyrophosphate Salts with analogs, diethylene triamine pentaacetic acid, ethylene diamine tetraacetic acid, nitrogen triacetic acid and analog salts, and other substances (such as components). However, from a safety standpoint and a reduction in environmental impact, it is desirable to avoid the use of these traditional components. Next, the use conditions and ratios of the ingredients of the detergent composition according to the present invention will be explained in detail. Under widely used conditions, in order to obtain the properties of ethylenediaminetetraacetic acid equal to or higher than the excellent component, it is desirable to use it simultaneously with (S) -aspartic acid-N, N-diacetic acid, and taurine. At least two of the three components of mono-N, N-diacetic acid and methylimine diacetic acid are biodegradable components. 5-97% by weight (based on acid), preferably 40-95% by weight (8)-aspartic acid-1 ^, 1 ^-diacetic acid, 0-97% by weight (based on acid) Preferably, 40-90% by weight of taurine-N, N-diacetic acid, and 0-97% by weight (depending on the acid), preferably 30-70% by weight of methylimine diacetic acid. It is hoped that the total amount of the component is 6-8 10% by weight (based on the acid based on the surfactant component), preferably 20 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Equipment ----- 7 (Please read the precautions on the back before filling this page) J--Order-- -23-515784 A7 ____B7 V. Description of the invention (21) 240% by weight, more preferably 80-120 weight%. In the case where the composition ratio of such a biodegradable component is used, the performance per component (based on the acid) is equal to or higher than that in the pH range of 6-1 3 Surfactant (sulfonic acid type with excellent performance in dispersing ability) combined with component performance equal to or higher than P Η 7 — 1 2 in the range of ethylenediaminetetraacetic acid or nitrotriacetic acid with surfactant ( In the dispersing ability, there is a poorly performing carboxylic acid type) combination of component properties. The component performance here includes not only the Ca + + trapping force, but also the ability to disperse rust or heavy metals, p Η buffering ability, inhibition of dirt re-adhesion, inhibition of liquid detergent precipitation and solid cleaning The shape of the agent is maintained, the components according to the invention also exceed these properties of nitrotriacetic acid, and the properties obtained are not inferior to those of ethylenediaminetetraacetic acid and tripolyphosphoric acid. When the conditions of certain uses are known in advance, such as P Η and the surfactant used, it is more convenient to prepare a detergent composition having a ratio of biodegradable component composition suitable for these use conditions. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) In many cases, a surfactant (such as dodecylbenzenesulfonate) is incorporated at a pH of about 6.5-8.5 , Lauryl Sulfate and Polyethylene Glycol) Use neutral detergents for household kitchens and clothes. In these applications, 20-97% by weight (based on acid), preferably 50-95% by weight 2 (S) -aspartic acid mono-N, N-diacetic acid, 50-90% by weight (based on acid ), Preferably 50-80% by weight of taurine-N, N-diacetic acid, and 0-20% by weight (based on the acid), preferably 10-15% by weight of methylimine diacetic acid, based on Composition This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm). 24-Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 515784 A7 B7 V. Description of the invention (22) Composition-based. Used as clothes, tableware, machinery and equipment, bottles and other industrial cleaners for cleaning in a wide range of P Η from neutral to strong alkaline conditions. Especially in the use under the basic conditions of PZ 9-13 'suitable to use 0-90% by weight (based on acid), preferably 20-50% by weight of (S) -aspartic acid mono-N, N-diacetic acid, 5-90% by weight (based on acid), preferably 50-80% by weight of taurine-N, N -diacetic acid, 20-97% by weight (based on acid), preferably 60-90% by weight of methylidene Amine diacetic acid is based on component composition. However, in fact, the use of industrial cleaners under alkaline conditions of pH 9-13, when using a surfactant with poor dispersing ability (such as laurate), it is suitable to use 20-95% by weight (based on acid), preferably 50 to 90% by weight of (S) -aspartic acid mono-N, N-diacetic acid, 5-90% by weight (depending on the acid), preferably 50-80% by weight of taurine-N, N- Diacetic acid, and 0-20% by weight (based on acid), preferably 10-15% by weight of methylimine diacetic acid, are based on the component composition. Moreover, in any use, all or part of the methylimine diacetic acid, which is a biodegradable component ingredient in the detergent composition of the present invention, may be (S) -aspartic acid-N-monoacetic acid and (S)-One or both of aspartic acid-N-monopropionic acid is substituted. When (S) -aspartic acid-N-monoacetic acid is used, 80-350% by weight (based on the acid) is suitable, preferably 150-320% by weight, based on methylimine diacetic acid as basis. When using (S) —aspartic acid—N—monopropionic acid, it is suitable to use this paper. Standards of China (CNS) A4 specification (21GX 297 mm) " One 25-ϋ— · ϋϋ ϋ- · n ·· — am · 11 Hal ϋ · — ^ i_i —ϋ V ml ml · 11 (Please read the precautions on the back before filling this page) 4 515784 A7 B7 V. Description of the invention (23) 120-560% by weight ( Based on acid), preferably 240-420% by weight, based on methylimine diacetic acid. The detergent composition of the present invention can also be prepared in a predetermined ratio by mixing a chelating agent with a surfactant and other components, such as a liquid cleaner or a high-concentration powder cleaner, and the detergent composition can be used in Water is diluted to the desired concentration. Alternatively, these ingredients may be added to the diluted water in a predetermined ratio. The present invention will be explained in more detail by the following examples, which are not to be construed as limiting the present invention in any way. Example 1 contains 100 g (S) -aspartic acid-N-monoacetic acid trisodium salt (S — ASMA-3Na) and 25 · 0 g of impurity salt (including 18 · 3 g of aspartic acid di Sodium, 4.0 g of disodium maleate butyrate (2. 2 g of monosodium salt of glycine and 0.5 g of disodium maleate) were obtained by drying at 2 0 0 [g / cm2] Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page), and store it for 2 months, according to J 1 s A The compressive strength measured by the following method of 1 108 (method for measuring the compressive strength of concrete) is expressed, so the hardening properties of the powder are evaluated. < Measurement method for compressive strength > (1) Put a test sample (500 g) in a polyethylene bag of 20 cm x 20 cm and place it at a temperature of 20-30 ° C and 40-the paper size Applicable to China National Standard (CNS) A4 specification (21〇 < 297 mm)-26 _ 515784 A7 __B7 _ V. Description of the invention (24) 70% relative humidity in the room. The powder was spread out to an area of 20 cm x 20 cm, air was pushed out of the bag, and the bag was sealed. Place this bag separately in a kraft paper bag and seal the kraft paper bag. (2) Place the kraft paper bag of (1) horizontally on a flat board and place one board on the kraft paper bag. Four weights each weighing 20 kg were placed on the upper plate to provide a load of 200 [g / cm2] to the test sample. (3) Maintain a temperature of 20-30 ° C and a relative humidity of 40-70%. Take out the test sample after 2 months from the start of providing the load. Several test pieces (4 cm long X 4 cm wide X 2 cm high) were cut from the sample. (4) Compression tester (computer-controlled universal precision tester: Simadzu automatic plotter AG S — 10 〇B; maximum load: 100 kg; load speed: 2 [cm / min]) load test piece, maximum The load (the value shown by the tester when the test piece is broken) is divided by the cross-sectional area of the test piece, and the resulting value is used as the compressive strength. As a result of the measurement, the test piece has a compression strength of 1. 2 [g / cm 2] printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page), and it is in this state Can be decomposed without any special grinding treatment. Example 2 Except the use of 1 000 g (S) -aspartic acid-N-monopropionic acid trisodium salt (S — ASMP — 3Na) and 20.0 g of impurity salt (including 8.2 g of trans-butene di Disodium acid, 6.2 grams of aspartic acid Two paper sizes are applicable to Chinese National Standard (CNS) A4 specifications (210, 乂 29? Mm) -27-515784 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention Except (25) sodium, 4.3 g of disodium imine diacetate, 1.1 g of disodium maleate and 0.2 g of trisodium nitrotriacetate), as in Example 1 Experiment in the same way. The results are shown in Table 1. Example 3 Except using 1,000 g (S) -aspartic acid-N, N-tetrasodium salt of monoacetic acid (S-ASDA-4Na) and 15.0 g of impurity salt (including 5.5 g of aspartic acid) Disodium, 3.1 grams of disodium maleate, 3.1 grams of sodium Θ-alanine, 2.4 grams of disodium imine dipropionate, 0.7 grams of maleic acid Experiments were performed in the same manner as in Example 1 except disodium and 0.2 g of sodium acrylate). The results are shown in Table 1. 0 Example 4 In addition to 1 000 g (S) — c «— alanine mono-N, N — diacetic acid trisodium salt (S — ALDA — 3Na) and 22.5 g impurity salts (including 1 · 5 g of monosodium salt of α-alanine, 3.6 g of monosodium salt of glycine, 4.8 g of disodium imine diacetate and 3.7 g of trisodium nitrotriacetate), and Experiments were performed in the same manner as in Example 1. The results are shown in Table 1. Example 5 Except that the content of the impurity salt becomes 5.0% and the load applied to the test sample is 100 [g / cm2], the same composition is used. Dulang towels (CNS) A4 size (210X297 Mm) a 28-

{請先閲讀背面之注意事項再填寫本頁)(Please read the notes on the back before filling this page)

515784 A7 ___T._— 、_ 五、發明説明（26 ) 以如例1之相同方法進行實驗。結果示於表1中。 例6 除了雜質鹽之含量變爲6 · 〇%且應用至試驗樣品之 負載爲100〔克/公分2 〕之外，使用相同之組成物， 以如例2之相同方法進行實驗。結果示於表1中。 例7 除了雜質鹽之含量變爲8 · 〇%且應用至試驗樣品之 負載爲100〔克/公分2 〕之外，使用相同之組成物， 以如例3之相同方法進行實驗。結果示於表1中。 例8 除了雜質鹽之含量變爲7 · 0%且應用至試驗樣品之 負載爲100〔克/公分2 〕之外，使用相同之組成物， 以如例4之相同方法進行實驗。結果示於表1中。 例9 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了雜質鹽之含量變爲0·3%且應用至試驗樣品之 負載爲300〔克/公分2 〕之外，使用相同之組成物， 以如例1之相同方法進行實驗。結果示於表1中。 例1 0 除了雜質鹽之含量變爲0·2%且應用至試驗樣品之 負載爲300〔克/公分2 〕之外，使用相同之組成物， 本紙張尺度適用中國國家標準（CNS ) A4規格（210'乂297公釐） -29 - 515784 A7 B7 五、發明説明（27 ) 以如例2之相同方法進行實驗。結果示於表1中。 例1 1 除了雜質鹽之含量變爲0·4%且應用至試驗樣品之 負載爲300〔克/公分2 〕之外，使用相同之組成物， 以如例3之相同方法進行實驗。結果示於表1中。 例1 2 除了雜質鹽之含量變爲0 · 3%且應用至試驗樣品之 負載爲300〔克/公分2 〕之外，使用相同之組成物， 以如例4之相同方法進行實驗。結果示於表1中。 例1 3 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了使用1 0 0 0克（S) -天冬胺酸一 N -單醋酸 (S — ASMA)與30 · 0克雜質酸（包含20 · 1克 天冬胺酸，6 · 0克反一丁烯二酸二鈉，3 · 2克甘胺酸 與〇 · 7克順一丁烯二酸）之外，以如例1之相同方法進 行實驗。結果示於表1中。 例1 4 除了使用1 000克（S) -天冬胺酸一 N -單丙酸 (S—ASMP)與15 · 0克雜質酸（包含6 · 6克反 一丁烯二酸，4 · 7克天冬胺酸，3 · 1克亞胺二醋酸， 〇 · 8克順一丁烯二酸二鈉與0 . 1克氮三乙酸）之外， 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -30 - 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（28 ) 以如例1之相同方法進行實驗。結果示於表1中。 例1 5 除了使用1 000克（S) -天冬胺酸一 N，N —二 醋酸（S — ASDA)與20 · 0克雜質酸（包含8 · 5 克天冬胺酸，5 · 3克反一丁烯二酸二鈉，3 · 3克点一 丙胺酸，2 · 3克亞胺二丙酸，0 · 5克順一丁烯二酸二 鈉與0·1克丙烯酸）之外，以如例1之相同方法進行實 驗。結果示於表1中。 例1 6 除了使用1 000克（α) —α —丙胺酸一N，N — 二醋酸（S - ALDA)與24 · 5克雜質酸（包含 11 · 0克α -丙胺酸，4 · 6克甘胺酸，5 · 2克亞胺 二醋酸與3·7克氮三乙酸）之外，以如例1之相同方法 進行實驗。結果示於表1中。 例1 7 除了雜質酸變爲4·0%且應用至試驗樣品之負載爲 100〔克/公分2 〕之外，使用相同組成物，以如例 1 3之相同方法進行實驗。結果示於表1中。 例1 8 除了雜質酸變爲8·0%且應用至試驗樣品之負載改 本紙張尺度適用中國國家標準（CMS ) Α4規格（210X 297公釐） 一 31 - (請先閲讀背面之注意事項再填寫本頁) r 515784 A7 B7 五、發明説明（29 ) 爲1 0 0〔克/公分2 〕之外’使用相同組成物’以如例 1 4之相同方法進行實驗。結果示於表1中。 例1 9 除了雜質酸變爲7.0%且應用至試驗樣品之負載改 爲100〔克/公分2 〕之外’使用相同組成物，以如例 1 5之相同方法進行實驗。結果示於表1中。 例2 0 除了雜質酸變爲6·0%且應用至試驗樣品之負載改 爲100〔克/公分2 〕之外’使用相同組成物，以如例 1 6之相同方法進行實驗。結果示於表1中。 例2 1 除了雜質酸變爲0·2%且應用至試驗樣品之負載改 爲300〔克/公分2 〕之外，使用相同組成物，以如例 1 3之相同方法進行實驗。結果示於表1中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 例2 2 除了雜質酸之含量變爲0·3%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例1 4之相同方法進行實驗。結果示於表1中。 例2 3 I紙張尺度適用中國國家標準（CNS ) ϋ規格（2丨0X297公釐) ~ 515784 A7 _____B7___ 五、發明説明（3〇 ) 除了雜質酸之含量變爲0.5%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例1 5之相同方法進行實驗。結果示於表1中。 例2 4 除了雜質酸之含量變爲0.4%且應用至試驗樣品之 負載改爲300 〔克/公分2 〕之外，使用相同組成物， 以如例1 6之相同方法進行實驗。結果示於表1中。 例2 5 除了使用1 0 0 0克牛磺酸一 N，N —二醋酸之三鈉 鹽（TUDA — 3Na)與25 · 0克雜質鹽（包含 6 · 0克牛磺酸之單鈉鹽，5 · 0克甘胺酸之單鈉鹽， 7·0克亞胺二醋酸二鈉與7·0克氮三乙酸三鈉）之外 ，以如例1之相同方法進行實驗。結果示於表1中。 例2 6 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了使用1 0 0 0克N —甲基亞胺二醋酸二鈉（ MIDA— 2Na)與20 · 0克雜質鹽（包含8 · 0克 甘胺酸之單鈉鹽，7 · 0克亞胺二醋酸二鈉與5 · 0克氮 三乙酸三鈉）之外，以如例1之相同方法進行實驗。結果 示於表1中。 例2 7 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（31 ) 除了使用1 000克鄰一胺基苯甲酸一 N，N —二醋 酸之三鈉鹽（ANTDA - 3Na)與15 · 〇克雜質鹽 (包含4 · 0克鄰一胺基苯甲酸單鈉，3 · 〇克甘胺酸之 單鈉鹽，5 · 0克亞胺二醋酸二鈉與3 · 0克氮三乙酸三 鈉）之外，以如例1之相同方法進行實驗。結果示於表1 中〇 例2 8 除了雜質鹽之含量變爲5·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例2 5之相同方法進行實驗。結果示於表1中。 例2 9 除了雜質鹽之含量變爲6·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例2 6之相同方法進行實驗。結果示於表1中。 例3 0 除了雜質鹽之含量變爲8·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例2 7之相同方法進行實驗。結果示於表1中。 例3 1 除了雜質鹽之含量變爲〇 . 3 %且應用至試驗樣品之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 袈_ 訂 經濟部中央標準局員工消費合作社印製 515784 A7 ______B7 五、發明説明（32 ) 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例2 5之相同方法進行實驗。結果示於表1中。 例3 2 除了雜質鹽之含量變爲0.2%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例2 6之相同方法進行實驗。結果示於表1中。 例3 3 除了雜質鹽之含量變爲0.4%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例2 7之相同方法進行實驗。結果示於表1中。 例3 4 除了使用1 0 0 0克牛磺酸一 N，N -二醋酸鹽（ TUDA)與25 . 0克雜質酸（包含6 · 0克牛磺酸， 5 · 0克甘胺酸，7 · 0克亞胺二醋酸與7 · 0克氮三乙 酸）之外，以如例1之相同方法進行實驗。結果示於表1 中〇 例3 5 除了使用1 0 0 0克N —甲基亞胺二醋酸（Μ I DA )與20 · 0克雜質酸（包含8 · 0克甘胺酸，7 · 0克 亞胺二醋酸與5·0克氮三乙酸）之外，以如例1之相同 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁)515784 A7 ___ T ._—, _ V. Description of the Invention (26) The experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 6 An experiment was carried out in the same manner as in Example 2 except that the content of the impurity salt was changed to 6.0% and the load applied to the test sample was 100 [g / cm2]. The results are shown in Table 1. Example 7 An experiment was performed in the same manner as in Example 3 except that the content of the impurity salt was changed to 8.0% and the load applied to the test sample was 100 [g / cm2], using the same composition. The results are shown in Table 1. Example 8 An experiment was performed in the same manner as in Example 4 except that the content of the impurity salt was changed to 7.0% and the load applied to the test sample was 100 [g / cm2], using the same composition. The results are shown in Table 1. Example 9 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) except that the content of impurity salts becomes 0.3% and the load applied to the test sample is 300 [g / cm 2 Except for this, experiments were performed in the same manner as in Example 1 using the same composition. The results are shown in Table 1. Example 1 0 Except that the content of the impurity salt becomes 0.2% and the load applied to the test sample is 300 [g / cm2], the same composition is used. The paper size applies to the Chinese National Standard (CNS) A4. (210 '乂 297 mm) -29-515784 A7 B7 V. Description of the invention (27) The experiment was performed in the same manner as in Example 2. The results are shown in Table 1. Example 11 1 An experiment was carried out in the same manner as in Example 3 except that the content of the impurity salt was changed to 0.4% and the load applied to the test sample was 300 [g / cm 2]. The results are shown in Table 1. Example 1 2 An experiment was performed in the same manner as in Example 4 except that the content of the impurity salt became 0.3% and the load applied to the test sample was 300 [g / cm2], using the same composition. The results are shown in Table 1. Example 1 3 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Except using 100 g (S) -Aspartic acid-N-monoacetic acid (S — ASMA ) With 30.0 grams of impurity acid (contains 20.1 grams of aspartic acid, 6.0 grams of disodium malonic acid, 3.2 grams of glycine and 0.7 grams of maleic acid) Except that, experiments were performed in the same manner as in Example 1. The results are shown in Table 1. Example 1 4 In addition to using 1,000 g (S) -aspartic acid-N-monopropionic acid (S-ASMP) and 15.0 g of impurity acids (including 6.6 g of trans-butenedioic acid, 4 · 7 In addition to grams of aspartic acid, 3.1 grams of imine diacetic acid, 0.8 grams of disodium maleate and 0.1 grams of nitrogen triacetic acid), this paper size applies the Chinese National Standard (CNS) A4 specifications (210X297mm) -30-515784 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (28) The experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 1 5 In addition to using 1,000 g (S) -aspartic acid mono-N, N-diacetic acid (S-ASDA) and 20.0 g of impurity acid (including 8.5 g aspartic acid, 5.3 g Disodium transbutyrate, 3.3 g of a point alanine, 2.3 g of imine dipropionate, 0.5 g of disodium maleate and 0.1 g of acrylic acid), and Experiments were performed in the same manner as in Example 1. The results are shown in Table 1. Example 1 6 In addition to using 1 000 g (α) -α-alanine mono-N, N-diacetic acid (S-ALDA) and 24.5 g of impurity acids (including 11.0 g of α-alanine, 4 6 g Experiments were performed in the same manner as in Example 1 except for glycine, 5.2 g of imine diacetic acid and 3.7 g of nitrogen triacetic acid). The results are shown in Table 1. Example 17 An experiment was carried out in the same manner as in Example 13 except that the impurity acid was changed to 4.0% and the load applied to the test sample was 100 [g / cm2]. The results are shown in Table 1. Example 1 8 Except that the impurity acid becomes 8 · 0% and the load applied to the test sample is modified, the paper size is applicable to the Chinese National Standard (CMS) A4 specification (210X 297 mm)-31-(Please read the precautions on the back before (Fill in this page) r 515784 A7 B7 V. Description of the invention (29) is 100 [g / cm2] except for 'use the same composition' in the same way as in Example 14 for experiments. The results are shown in Table 1. Example 19 An experiment was performed in the same manner as in Example 15 except that the impurity acid was changed to 7.0% and the load applied to the test sample was changed to 100 [g / cm2] 'using the same composition. The results are shown in Table 1. Example 2 0 An experiment was performed in the same manner as in Example 16 except that the impurity acid was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm2] 'using the same composition. The results are shown in Table 1. Example 2 1 An experiment was performed in the same manner as in Example 13 except that the impurity acid was changed to 0.2% and the load applied to the test sample was changed to 300 [g / cm 2]. The results are shown in Table 1. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Example 2 2 Except that the content of impurity acids becomes 0.3% and the load applied to the test sample is changed to 300 [g / Except for 2 cm], experiments were performed in the same manner as in Example 14 using the same composition. The results are shown in Table 1. Example 2 3 I paper size applies Chinese National Standard (CNS) ϋ Specifications (2 丨 0X297 mm) ~ 515784 A7 _____B7___ V. Description of the invention (3〇) Except for the impurity acid content of 0.5% and applied to the load of the test sample The experiment was carried out in the same manner as in Example 15 except that it was changed to 300 [g / cm 2], using the same composition. The results are shown in Table 1. Example 2 4 An experiment was performed in the same manner as in Example 16 except that the content of the impurity acid was changed to 0.4% and the load applied to the test sample was changed to 300 [g / cm 2]. The results are shown in Table 1. Example 2 5 In addition to using 1000 g of taurine mono-N, N-diacetic acid trisodium salt (TUDA-3Na) and 25.0 g of impurity salts (including 6.0 g of monosodium salt of taurine, Except 5.0 g of monosodium salt of glycine, 7.0 g of disodium imine diacetate and 7.0 g of trisodium azatriacetate), the experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 2 6 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except using 1 0 0 g of N-methylimine diacetic acid disodium (MIDA-2Na) and 20 · Except for 0 g of impurity salts (including 8.0 g of monosodium salt of glycine, 7.0 g of disodium imine diacetate and 5.0 g of trisodium nitrotriacetate), use the same method as in Example 1. conduct experiment. The results are shown in Table 1. Example 2 7 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 515784 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (31) In addition to using 1 000 g of o-aminobenzene Mono-N, N-trisodium diacetate (ANTDA-3Na) and 15.0 grams of impurity salts (including 4.0 grams of mono-o-aminobenzoic acid monosodium and 3.0 grams of monosodium salt of glycine Except 5.0 g of disodium imine diacetate and 3.0 g of trisodium nitrotriacetate), the experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 2 8 The same composition was used as in Example 2 except that the content of the impurity salt was changed to 5.0% and the load applied to the test sample was changed to 100 [g / cm2]. Experiment in the same way. The results are shown in Table 1. Example 2 9 An experiment was performed in the same manner as in Example 26 using the same composition except that the content of the impurity salt was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 1. Example 3 0 The experiment was carried out in the same manner as in Example 27 except that the content of the impurity salt was changed to 8.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 1. Example 3 1 Except that the content of impurity salt becomes 0.3% and the paper size applied to the test sample is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page ) __ Order Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 515784 A7 ______B7 V. Description of the invention (32) The load is changed to 300 [g / cm2] except that the same composition is used. conduct experiment. The results are shown in Table 1. Example 3 2 An experiment was performed in the same manner as in Example 26 using the same composition except that the content of the impurity salt was changed to 0.2% and the load applied to the test sample was changed to 300 [g / cm2]. The results are shown in Table 1. Example 3 3 An experiment was performed in the same manner as in Example 27 except that the content of the impurity salt was changed to 0.4% and the load applied to the test sample was changed to 300 [g / cm 2]. The results are shown in Table 1. Example 3 4 Except using 1000 g of taurine mono-N, N-diacetate (TUDA) and 25.0 g of impurity acid (including 6.0 g of taurine, 5.0 g of glycine, 7 Except for 0 g of imine diacetic acid and 7.0 g of nitrogen triacetic acid), the experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 3 5 In addition to 1 000 g of N-methylimine diacetic acid (M I DA) and 20.0 g of impurity acids (including 8 0 g of glycine, 7 0 Gimine diacetic acid and 5.0 g nitrogen triacetic acid), the same paper size as in Example 1 applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling (This page)

515784 A7 B7 五、發明説明（33 ) 方法進行實驗。結果示於表1中。 例3 6 除了使用1 0 〇 〇克鄰-胺基苯甲酸一 N，N —二醋 酸（ANTDA)與15 . 〇克雜質酸（包含4 · 0克鄰 一胺基苯甲酸，3 · 〇克甘胺酸，5 . 0克亞胺二醋酸與 3 · 0克氮三乙酸）之外，以如例1之相同方法進行實驗 。結果示於表1中。 例3 7 除了雜質酸之含量變爲4·〇%且應用至試驗樣品之 負載B夂爲1 0 〇〔克/公分2 〕之外，使用相同組成物， 以如例3 4之相同方法進行實驗。結果示於表1中。 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 之， 品物 樣成 。 驗組中 試同1 至相表 用用於 應使示 且，果 %外結 ο 之 。 • ·-^,驗 8 2 實 爲分行 變公進 量 \ 法 含克方 之 t 同 酸 ο 相 質 ο 之 雜 1 5 了 爲 3 8 除改例 3 載如 例負以 之， 品物 樣成。 驗組中 試同 1 至相表 用用於 應使示 且，果 % 外結 ο 之 。 • J 驗 7 2 實 爲分行 變公進 量 \ 法 含克方 之 C 同 酸 ο 相 質 ο 之 雜 1 6 了爲 3 9 除改例 3 載如 例 負以 本紙張尺度適用中國國家標準（CNS ) A4規格（210'〆297公釐） 515784 A7 _______ B7____ 五、發明説明（34 ) 例4 0 除了雜質酸之含釐變爲〇 · 2 %且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物， 以如例3 4之相同方法進行實驗。結果示於表1中。 例4 1 除了雜質酸之含量變爲〇·3%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例3 5之相同方法進行實驗。結果示於表1中。 例4 2 除了雜質酸之含量變爲〇·5%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例3 6之相同方法進行實驗。結果示於表1中。 例4 3 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了使用1 0 〇 〇克鄰一胺基苯甲酸一 N，N —二醋 酸之鐵鹽（ANTDA - Fe)與15 _ 0克雜質Fe鹽 (包含4 · 0克鄰一胺基苯甲酸鹽，3 · 0克甘胺酸之鹽 ，5 · 0克亞胺二醋酸鹽與3 · 0克氮三乙酸鹽）之外， 以如例1之相同方法進行實驗。結果示於表1中。 例4 4 除了雜質鹽之含量變爲5.0%且應用至試驗樣品之 i紙張尺度適用中國國家標準（CNS ) A4規格(210 X 297公釐） 一 37 - 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（35 ) 負載改爲100〔克/公分2 〕之外’使用相同組成物，. 以如例4 3之相同方法進行實驗。結果示於表1中。 例4 5 除了雜質鹽之含量變爲0 · 3 %且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物’ 以如例4 3之相同方法進行實驗。結果示於表1中。 比較例1 除了雜質鹽之含量變爲1 0 %且應用至試驗樣品之負 載改爲1〇〇〔克/公分2 〕之外’使用相同組成物’以 如例1之相同方法進行實驗。結果示於表2中。 比較例2 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外’使用相同組成物，以 如例2之相同方法進行實驗。結果示於表2中。 比較例3 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同組成物，以 如例3之相同方法進行實驗。結果示於表2中。 比較例4 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） . "~— -38 - (請先閲讀背面之注意事項#'填寫本頁)515784 A7 B7 V. Description of the invention (33) The method is used for experiments. The results are shown in Table 1. Example 3 6 Except using 1000 g of o-aminobenzoic acid mono-N, N-diacetic acid (ANTDA) and 15.0 g of impurity acid (including 4.0 g of o-aminobenzoic acid, 3.0 g Except glycine, 5.0 g of imine diacetic acid and 3.0 g of nitrogen triacetic acid), experiments were performed in the same manner as in Example 1. The results are shown in Table 1. Example 3 7 The same method was used as in Example 34, except that the content of the impurity acid was changed to 4.0% and the load B applied to the test sample was 100 [g / cm2], using the same composition. experiment. The results are shown in Table 1. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. In the test group, try the same to 1 to the phase table for the application. • ·-^, Experiment 8 2 It is the branch to change the amount of quotation. The method contains t of the square formula, the same acid ο phase quality ο miscellaneous 1 5 is 3 8 except for the modification 3, which is given as an example. . In the test group, try the same 1 to the phase table for the application, and the results% will be solved. • J Examination 7 2 is actually a branch variable quotient \ method containing grams of C acid and phase ο phase ο miscellaneous 1 6 is 3 9 except for modification 3 The example given in this paper applies the Chinese national standard on this paper scale ( CNS) A4 specification (210'〆297 mm) 515784 A7 _______ B7____ V. Description of the invention (34) Example 4 0 In addition to the impurity acid content changed to 0.2% and the load applied to the test sample was changed to 300 [g / Cm 2] except that the same composition was used, and experiments were performed in the same manner as in Example 34. The results are shown in Table 1. Example 4 1 An experiment was carried out in the same manner as in Example 35 except that the content of the impurity acid was changed to 0.3% and the load applied to the test sample was changed to 300 [g / cm 2]. The results are shown in Table 1. Example 4 2 An experiment was performed in the same manner as in Example 36 using the same composition except that the content of the impurity acid was changed to 0.5% and the load applied to the test sample was changed to 300 [g / cm2]. The results are shown in Table 1. Example 4 3 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). ANTDA-Fe) and 15 — 0 grams of impurities Fe salts (containing 4.0 grams of o-monoaminobenzoate, 3.0 grams of glycine salts, 5.0 grams of imine diacetate and 3.0 grams G nitrogen triacetate), the experiment was performed in the same manner as in Example 1. The results are shown in Table 1. Example 4 4 Except that the content of impurity salts becomes 5.0% and the paper size applied to the test samples is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm)-37-515784 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System A7 B7 V. Description of the invention (35) The load was changed to 100 [g / cm2] except for 'using the same composition. The experiment was performed in the same manner as in Example 43. The results are shown in Table 1. Example 4 5 An experiment was performed in the same manner as in Example 4 3 except that the content of the impurity salt was changed to 0.3% and the load applied to the test sample was changed to 300 [g / cm2] using the same composition. The results are shown in Table 1. Comparative Example 1 An experiment was performed in the same manner as in Example 1 using the same composition except that the content of the impurity salt became 10% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. Comparative Example 2 An experiment was carried out in the same manner as in Example 2 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm2] 'using the same composition. The results are shown in Table 2. Comparative Example 3 An experiment was carried out in the same manner as in Example 3, except that the content of the impurity salt became 20% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. Comparative Example 4 This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm). &Quot; ~ — -38-(Please read the note on the back first # 'Fill this page)

515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（36 ) 除了雜質鹽之含量變爲1 8 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物’ 以如例4之相同方法進行實驗。結果示於表2中。 比較例5 除了雜質酸之含量變爲3 0 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外’使用相同之組成物’ 以如例1 3之相同方法進行實驗。結果示於表2中。 比較例6 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同組成物，以 如例1 4之相同方法進行實驗。結果示於表2中。 比較例7 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物， 以如例1 5之相同方法進行實驗。結果示於表2中。 比較例8 除了雜質鹽之含量變爲2 3 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同組成物，以 如例1 6之相同方法進行實驗。結果示於表2中。 本紙張尺度適用中國國家標準（CNS )八4規格（21〇χ 297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝_ 訂 515784 A7 ______B7_ 五、發明説明（37 ) 比較例9 除了雜質鹽之含量變爲丄〇%且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同組成物，以 (請先閱讀背面之注意事項再填寫本頁) 如例2 5之相同方法進行實驗。結果示於表2中。 比較例1 0 除了雜質鹽之含量變爲1 5%且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物， 以如例2 6之相同方法進行實驗。結果示於表2中。 比較例1 1 除了雜質鹽之含量變爲2 0 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物， 以如例2 7之相同方法進行實驗。結果示於表2中。 比較例1 2 經濟部中央標準局員工消費合作社印製 除了雜質酸之含量變爲3 0%且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物， 以如例3 4之相同方法進行實驗。結果示於表2中。 比較例1 3 除了雜質鹽之含量變爲2 0 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外，使用相同之組成物’ 以如例3 5之相同方法進行實驗。結果示於表2中。 本紙張尺度適用中國國家標準（CNS ) Α4規格（21〇X 297公釐） 515784 A7 B7 五、發明説明（38 ) 比較例1 4 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載改爲100〔克/公分2 〕之外’使用相同之組成物’ 以如例3 6之相同方法進行實驗。結果示於表2中。 比較例1 5 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載改爲100 〔克/公分2 〕之外’使用相同之組成物’ 以如例4 3之相同方法進行實驗。結果示於表2中。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 515784 B7 五、發明説明（39 ) 表1 經濟部中央標準局員工消費合作社印製 例 式[I]之化合 物 雜質之含量 [wt. % ] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 1 S-ASMA-3Na 2. 4 200 1. 2 2 S-ASMP-3Na 2. 0 200 1. 0 3 S-ASDA-4Na 1.5 200 0. 9 4 S-ALDA-3Na 2.2 200 1. 1 5 S-ASMA-3Na 5. 0 100 1. 2 6 S-ASMP-3Na 6. 0 100 1.2 7 S-ASDA-4Na 8. 0 100 1. 3 8 S-ALDA-3Na 7. 0 100 1.0 9 S-ASMA-3Na 0.3 300 0. 8 10 S-ASMP-3Na 0. 2 300 1.0 11 S-ASDA-4Na 0. 4 300 0. 8 12 S-ALDA_3Na 0. 3 300 0. 9 13 S-ASMA 2. 9 200 1. 1 14 S-ASMP 1. 5 200 0. 6 15 S-ASDA 2.0 200 0.9 16 S-ALDA 2. 4 200 0. 8 17 S-ASMA 4. 0 100 0. 9 18 S-ASMP 8. 0 100 1. 2 19 S-ASDA 7. 0 100 1.1 20 S-ALDA 6.0 100 1. 0 21 S-ASMA 0. 2 300 0. 8 22 S-ASMP 0.3 300 0.9 23 S-ASDA 0. 5 300 1. 0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 丨 小 一 42 - 515784 A7 B7 五、發明説明（4〇 表1(續） 經濟部中央標準局員工消費合作社印製 例 式[I]之化合 物 雜質之含量 [wt. % ] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 24 S-ALDA 0· 4 300 0. 9 25 TUDA-3Na 2. 4 200 1. 1 26 MIDA-2Na 2. 0 200 1. 2 27 ANTDA-3Na 1.5 200 1. 0 28 TUDA-3Na 5.0 100 1. 3 29 MIDA-2Na 6. 0 100 1. 2 30 ANTDA-3Na 8. 0 100 1.2 31 TUDA-3Na 0. 3 300 1. 0 32 MIDA-2Na 0. 2 300 0. 8 33 ANTDA-3Na 0. 4 300 0. 9 34 TUDA 2. 9 200 1.2 35 MIDA 1.5 200 0.8 36 ANTDA 2. 0 200 0.9 37 TUDA 4. 0 100 1.0 38 MIDA 8. 0 100 1.1 39 ANTDA 7. 0 100 1. 2 40 TUDA 0. 2 300 0. 9 41 MIDA 0.3 300 1. 0 42 ANTDA 0.5 300 1.1 43 ANTDA-Fe 1. 5 200 0. 9 44 ANTDA-Fe 5. 0 100 1. 0 45 ANTDA-Fe 0. 3 300 0.8 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 一 43 - 515784 A7 B7 五、發明説明（41 ) 表2 經濟部中央標準局員工消費合作社印製 比 較 例 式[I]之化合 物 雜質之含量 [wt.%] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 1 S-ASMA-3Na 10 100 2.6 2 S-ASMP-3Na 15 100 3. 0 3 S-ASDA-4Na 20 100 3. 2 4 S-ALDA-3Na 18 100 2. 8 5 S-ASMA 30 100 2.8 6 S-ASMP 20 100 2. 5 7 S-ASDA 15 100 2. 3 8 S-ALDA 23 100 2. 6 9 TUDA-3Na 10 100 2.5 10 MIDA-2Na 15 100 2. 6 11 ANTDA-3Na 20 100 2. 5 12 TUDA 30 100 3. 3 13 MIDA 20 100 2. 7 14 ANTDA 15 100 2.5 15 ANTDA-Fe 15 100 2.5 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -44 - 515784 A7 ___B7_ 五、發明説明（42 ) 從這些實例看出：當雜質酸或其鹽係以大於8%量（ 以式〔1〕之化合物爲基礎）存在時，增加所儲放粉末之 硬化，同時，增加壓縮強度。當雜質酸或其鹽係以幾乎8 %量存在時，未看見增加此類儲放粉末之硬化性質與壓縮 強度。 例4 6 除了使用1 0 0 0克伸乙基二胺二琥珀酸四鈉（ EDDS - 4Na)與25 · 0克雜質鹽（包含8 · 0克 順一丁烯二酸二鈉，9 · 0克反一丁烯二酸二鈉，5 · 〇 克伸乙基二胺單琥珀酸二鈉與3·0克蘋果酸二鈉）之外 ，以如例1之相同方法進行實驗。結果示於表3中。 例4 7 除了使用1 000克（S，S) —伸乙基二胺二琥拍 酸四鈉（SS-EDDS-4Na)與20 · 0克雜質鹽 (包含5 · 0克（S) —天冬胺酸二鈉，5 · 0克（S) 一 N (2 —羥乙基）一天冬胺酸二鈉，5 · 0 (S，s) —N —（2 —羥乙基）一伸乙基二胺二琥珀酸四鈉與 5·0克反一丁烯二酸二鈉）之外，以如例1之相同方法 進行實驗。結果示於表3中。 例4 8 除了使用1 000克1 ，3 —丙烷二胺二琥珀酸四|內 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X Μ?公釐） 請 ku 閲 讀 背 之 注 意 事 ¥ 寫 t 經濟部中央標準局員工消費合作社印製 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（43 ) (PDDS - 4Na)與15 · 0克雜質鹽（包含5 · 0 克順一 丁烯二酸二鈉’ 4 · 0克反一丁烯二酸一鈉’ 3 · 0克1，3 -丙烷二胺單琥拍酸二納與3 · 0克蘋果 酸二鈉）之外，以如例1之相同方法進行實驗。結果示於 表3中。 例4 9 除了使用1 〇〇〇克（S，S) —丙烷二胺二琥珀酸 四鈉（SS — PDDS — 4Na)與20 · 0克雜質鹽（ 包含5 · 0克（S) —天冬胺酸二鈉，5 · 0克（S) — 3 -羥丙基天冬胺酸二鈉，5 . 0 (S，S) - 3 —羥丙 基一 1 ，3 -丙烷二胺二琥珀酸四鈉與5 · 0克反一丁烯 二酸二鈉）之外，以如例1之相同方法進行實驗。結果示 於表3中。 例5 0 除了使用1000克（S，S) — 2羥基一 1，3 — 丙烷二胺二琥珀酸四鈉（SS — PDDS - OH - 4Na )與25 · 0克雜質鹽（包含5 · 〇克（s) -天冬胺酸 二鈉，5 · 0 克（S) — N —（1，2 -二羥丙基）—天 冬胺酸二鈉與5 · 0克反一 丁烯二酸二鈉）之外，以如例 1之相同方法進行實驗。結果示於表3中。 例5 1 本紙張尺度適用中國國家標準（CNS ) Μ規格（210'〆297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝·515784 Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (36) Except that the content of impurity salts becomes 18% and the load applied to the test sample is changed to 100 [g / cm2], use The same composition was tested in the same manner as in Example 4. The results are shown in Table 2. Comparative Example 5 An experiment was performed in the same manner as in Example 13 except that the content of the impurity acid was changed to 30% and the load applied to the test sample was changed to 100 [g / cm2] using the same composition. The results are shown in Table 2. Comparative Example 6 An experiment was carried out in the same manner as in Example 14 except that the content of the impurity salt was changed to 20% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. Comparative Example 7 An experiment was performed in the same manner as in Example 15 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 2. Comparative Example 8 An experiment was performed in the same manner as in Example 16 except that the content of the impurity salt was changed to 23% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. The size of this paper applies to China National Standard (CNS) 8.4 (21〇χ 297 mm) (please read the precautions on the back before filling out this page). Binding 515784 A7 ______B7_ V. Description of Invention (37) Comparative Example 9 Except that the content of the impurity salt becomes 〇 ％ and the load applied to the test sample is changed to 100 [g / cm 2], the same composition is used to (please read the precautions on the back before filling this page) as an example Experiments were performed in the same way as 25. The results are shown in Table 2. Comparative Example 10 An experiment was performed in the same manner as in Example 26 using the same composition except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. Comparative Example 11 An experiment was performed in the same manner as in Example 27 except that the content of the impurity salt was changed to 20% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 2. Comparative Example 1 2 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs except that the content of the impurity acid has been changed to 30% and the load applied to the test sample has been changed to 100 [g / cm2], using the same composition as Experiments were performed in the same manner as in Example 34. The results are shown in Table 2. Comparative Example 13 An experiment was performed in the same manner as in Example 3 5 using the same composition 'except that the content of the impurity salt became 20% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 2. This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 515784 A7 B7 V. Description of the invention (38) Comparative Example 1 4 In addition to the impurity salt content becoming 15% and applied to the test sample The load was changed to 100 [g / cm2], and the experiment was performed in the same manner as in Example 36 using the same composition. The results are shown in Table 2. Comparative Example 15 An experiment was performed in the same manner as in Example 43 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm2] using the same composition. The results are shown in Table 2. (Please read the precautions on the back before filling out this page) The paper size printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 515784 B7 V. Description of the invention (39) Table 1 Contents of impurities in compounds of formula [I] printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs [wt.%] Load [kg] Compressive strength after storage for 2 months [kg / cm 2] 1 S- ASMA-3Na 2. 4 200 1. 2 2 S-ASMP-3Na 2. 0 200 1. 0 3 S-ASDA-4Na 1.5 200 0.9. 4 S-ALDA-3Na 2.2 200 1. 1 5 S-ASMA- 3Na 5. 0 100 1. 2 6 S-ASMP-3Na 6. 0 100 1.2 7 S-ASDA-4Na 8. 0 100 1. 3 8 S-ALDA-3Na 7. 0 100 1.0 9 S-ASMA-3Na 0.3 300 0. 8 10 S-ASMP-3Na 0. 2 300 1.0 11 S-ASDA-4Na 0. 4 300 0. 8 12 S-ALDA_3Na 0. 3 300 0. 9 13 S-ASMA 2. 9 200 1. 1 14 S-ASMP 1. 5 200 0. 6 15 S-ASDA 2.0 200 0.9 16 S-ALDA 2. 4 200 0. 8 17 S-ASMA 4. 0 100 0. 9 18 S-ASMP 8. 0 100 1. 2 19 S-ASDA 7. 0 100 1.1 20 S-ALDA 6.0 100 1. 0 21 S-ASMA 0. 2 300 0. 8 22 S-ASMP 0.3 300 0.9 23 S-ASDA 0. 5 300 1. 0 paper Zhang scale is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) Binding and ordering 丨 Primary One 42-515784 A7 B7 V. Description of the invention (4〇Table 1 (Continued) Content of impurity [wt.%] Of compound of formula [I] printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs [wt.] Load [kg] Compressive strength after storage for 2 months [kg / cm2] 24 S -ALDA 0 · 4 300 0. 9 25 TUDA-3Na 2. 4 200 1. 1 26 MIDA-2Na 2. 0 200 1. 2 27 ANTDA-3Na 1.5 200 1. 0 28 TUDA-3Na 5.0 100 1. 3 29 MIDA-2Na 6. 0 100 1. 2 30 ANTDA-3Na 8. 0 100 1.2 31 TUDA-3Na 0. 3 300 1. 0 32 MIDA-2Na 0. 2 300 0. 8 33 ANTDA-3Na 0. 4 300 0 . 9 34 TUDA 2. 9 200 1.2 35 MIDA 1.5 200 0.8 36 ANTDA 2. 0 200 0.9 37 TUDA 4. 0 100 1.0 38 MIDA 8. 0 100 1.1 39 ANTDA 7. 0 100 1. 2 40 TUDA 0. 2 300 0. 9 41 MIDA 0.3 300 1. 0 42 ANTDA 0.5 300 1.1 43 ANTDA-Fe 1. 5 200 0. 9 44 ANTDA-Fe 5. 0 100 1. 0 45 ANTDA-Fe 0. 3 300 0.8 This paper size applies China National Standard (CNS) A4 Specification (210X 297mm) ( Read the precautions on the back before filling this page.) 43-515784 A7 B7 V. Description of the invention (41) Table 2 The content of impurities in the compound [I] printed by Comparative Example [I] printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs [wt. %] Load [kg] Compressive strength after 2 months storage [kg / cm2] 1 S-ASMA-3Na 10 100 2.6 2 S-ASMP-3Na 15 100 3. 0 3 S-ASDA-4Na 20 100 3. 2 4 S-ALDA-3Na 18 100 2. 8 5 S-ASMA 30 100 2.8 6 S-ASMP 20 100 2. 5 7 S-ASDA 15 100 2. 3 8 S-ALDA 23 100 2. 6 9 TUDA -3Na 10 100 2.5 10 MIDA-2Na 15 100 2. 6 11 ANTDA-3Na 20 100 2. 5 12 TUDA 30 100 3. 3 13 MIDA 20 100 2. 7 14 ANTDA 15 100 2.5 15 ANTDA-Fe 15 100 2.5 The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) -44-515784 A7 ___B7_ V. Description of the invention (42) From these examples: When the impurity acid or its salt is present in an amount of more than 8% (based on the compound of formula [1]), the hardening of the stored powder is increased, and at the same time, the compressive strength is increased. When the impurity acid or its salt is present in an amount of almost 8%, no increase in the hardening properties and compressive strength of such stored powders is seen. Example 4 6 In addition to 1000 grams of tetrasodium diethylene diamine disuccinate (EDDS-4Na) and 25.0 grams of impurity salts (including 8.0 grams of disodium maleate, 9 grams of reaction Experiments were performed in the same manner as in Example 1 except for disodium monobutyrate, 5.0 g of disodium ethylenediamine monosuccinate and 3.0 g of disodium malate). The results are shown in Table 3. Example 4 7 In addition to using 1,000 g (S, S) -tetrasodium diethylene diamine disuccinate (SS-EDDS-4Na) and 20 · 0 g of impurity salt (including 5.0 · (g)-day Disodium aspartate, 5.0 g (S) -N (2-hydroxyethyl) disodium aspartate, 5.0 · (S, s) —N — (2-hydroxyethyl) monoethyl ether Experiments were performed in the same manner as in Example 1 except that tetrasodium diamine disuccinate and 5.0 g of disodium maleate were used. The results are shown in Table 3. Example 4 8 In addition to using 1,000 g of 1,3-propanediamine disuccinic acid tetra | Inner paper size applies Chinese National Standard (CNS) A4 specification (21 × Μ? Mm) Please read the note of ku ¥ Write t Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (43) (PDDS-4Na) and 15 · 0 g impurity salt (including 5.0 · 0 g Disodium maleate '4. 0 g Monosodium maleate' 3 .0 g 1,3-propanediamine monosuccinate and 3.0 g disodium malate) The experiment was performed in the same manner as in Example 1. The results are shown in Table 3. Example 4 9 Except using 1000 g (S, S) -propanediamine disuccinic acid tetrasodium (SS — PDDS — 4Na) and 20.0 g impurity salts (including 5.0 g (S) — Asparagus Disodium Amino Acid, 5.0 g (S) — Disodium Sodium 3-Hydroxypropyl Aspartate, 5.0 (S, S)-3 -Hydroxypropyl-1,3-propanediamine disuccinic acid Experiments were performed in the same manner as in Example 1 except for tetrasodium and 5.0 g of disodium fumarate. The results are shown in Table 3. Example 5 0 In addition to using 1000 grams of (S, S) — 2hydroxy-1,3 — propanediamine disuccinate tetrasodium (SS — PDDS-OH-4Na) and 25.0 grams of impurity salts (including 5.0 grams) (S)-Disodium aspartate, 5.0 g (S) — N — (1,2-Dihydroxypropyl)-disodium aspartate and 5.0 g Except sodium), experiments were performed in the same manner as in Example 1. The results are shown in Table 3. Example 5 1 This paper size applies Chinese National Standard (CNS) M specifications (210'〆297 mm) (Please read the precautions on the back before filling this page)

經濟部中央標準局員工消費合作社印製 五、發明説明（44 ) 除了雜質鹽之含量變爲5 · 0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例4 6之相同方法進行實驗。結果示於表3中。 例5 2 除了雜質鹽之含量變爲6.0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例4 7之相同方法進行實驗。結果示於表3中。 例5 3 除了雜質鹽之含量變爲8 · 0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例4 8之相同方法進行實驗。結果示於表3中。 例5 4 除了雜質鹽之含量變爲6·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外’使用相同組成物， 以如例4 9之相同方法進行實驗。結果示於表3中。 例5 5 除了雜質鹽之含量變爲8·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例5 0之相同方法進行實驗。結果示於表3中。 本纸張尺度適用中國國家標準（CNS ) A4規格（21〇Χ297公釐） (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (44) The same composition is used except that the content of the impurity salt becomes 5.0% and the load applied to the test sample is changed to 100 [g / cm 2] Experiments were performed in the same manner as in Example 46. The results are shown in Table 3. Example 5 2 An experiment was performed in the same manner as in Example 4 7 except that the content of the impurity salt was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 3. Example 5 3 An experiment was carried out in the same manner as in Example 4 8 except that the content of the impurity salt was changed to 8. 0% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 3. Example 5 4 An experiment was performed in the same manner as in Example 4 9 except that the content of the impurity salt was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm2] using the same composition. The results are shown in Table 3. Example 5 5 An experiment was carried out in the same manner as in Example 50 except that the content of the impurity salt was changed to 8.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 3. This paper size applies to China National Standard (CNS) A4 specification (21〇 × 297 mm) (Please read the precautions on the back before filling this page)

515784 A7 _B7 __ 五、發明説明（45 ) 例5 6 除了雜質鹽之含量變爲0 · 3 %且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物’ 以如例4 6之相同方法進行實驗。結果示於表3中。 例5 7 除了雜質鹽之含量變爲0·2%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物’ 以如例4 7之相同方法進行實驗。結果示於表3中。 例5 8 除了雜質鹽之含量變爲0.4%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例4 8之相同方法進行實驗。結果示於表3中。 例5 9 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 除了雜質鹽之含量變爲0·2%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外，使用相同組成物， 以如例4 9之相同方法進行實驗。結果示於表3中。 例6 0 除了雜質鹽之含量變爲〇·4%且應用至試驗樣品之 負載改爲3 0 0〔克/公分2 〕之外，使用相同組成物， 以如例5 0之相同方法進行實驗。結果示於表3中。 紙張尺度適用中國國家標準（CNS (21〇><297公釐） " 515784 A7 ____ B7 五、發明説明（46 ) 例6 1 除了使用1 0 0 0克伸乙基二胺二琥珀酸（EDDS )與25 · 0克雜質酸（包含8 · 〇克順一丁烯二酸， 9 · 0克反一丁烯二酸，5 · 0克伸乙基二胺單琥珀酸與 3·0克蘋果酸）之外，以如例1之相同方法進行實驗。 結果示於表3中。 例6 2 除了使用1 0 00克（S，S) —伸乙基二胺二琥珀 酸（SS — EDDS)與20 · 0克雜質酸（包含5 · 0 克（S) —天冬胺酸，5 · 0克（S) — N (2 —羥乙基 )一天冬胺酸，5.0(3，3)-1^一（2-羥乙基） —伸乙基二胺琥珀酸與5 · 0反一丁烯二酸）之外，以如 例1之相同方法進行實驗。結果示於表3中。 例6 3 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了使用1 0 0 0克1 ，3 -丙烷二胺二琥珀酸（ PDDS)與15 · 0克雜質酸（包含5 · 0克順一丁烯 二酸，4 · 0克反—丁烯二酸，3 · 〇克1，3 —丙烷二 胺單琥珀酸與3·0克蘋果酸）之外，以如例1之相同方 法進行實驗。結果示於表3中。 例6 4 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 515784 A7 _B7 ___ 五、發明説明（47 ) 除了使用10 00克（s , S) -丙烷二胺二琥珀酸 (SS — PDDS)與20 · 0克雜質酸（包含5 · 0克 (S) —天冬胺酸，5 · 〇克（s) 一 3 一經丙基天冬胺 酸，5 · 0 (S，S) - 3 -羥丙基一 1 ’ 3 —丙焼一 一 胺二琥珀酸與5 . 0反一丁烯二酸）之外’以如例1之相 同方法進行實驗。結果示於表3中。 例6 5 除了使用1000克（s , s) 一2羥基一 1，3 一 丙烷二胺二琥珀酸（SS — PDDS — OH)與25 · 0 克雜質酸（包含15 · 〇克（s) 一天冬胺酸’ 5 · 0克 (S) — N -（1，2 -二羥丙基）一天冬胺酸與5 · 〇 克反-丁烯二酸）之外，以如例1之相同方法進行實驗。 結果示於表3中。 例6 6 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 除了雜質酸之含量變爲5·〇%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外’使用相同組成物’ 以如例61之相同方法進行實驗。結果示於表3中。 例6 7 除了雜質酸之含量變爲6 · 0 %且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例6 2之相同方法進行實驗。結果示於表3中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -50 - 經濟部中央標準局員工消費合作社印製 515784 A7 —_______B7__ 五、發明説明（48 ) 例6 8 除了雜質酸之含量變爲8.0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例6 3之相同方法進行實驗。結果示於表3中。 例6 9 除了雜質酸之含量變爲6 · 0 %且應用至試驗樣品之 負載改爲100 〔克/公分2 〕之外，使用相同組成物， 以如例6 4之相同方法進行實驗。結果示於表3中。 例7 0 除了雜質酸之含量變爲8·0%且應用至試驗樣品之 負載改爲100〔克/公分2 〕之外，使用相同組成物， 以如例6 5之相同方法進行實驗。結果示於表3中。 例7 1 除了雜質酸之含量變爲0 · 3 %且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物， 以如例6 1之相同方法進行實驗。結果示於表3中。 例7 2 除了雜質酸之含量變爲0·2%且應用至試驗樣品之 負載改爲300〔克/公分2 〕之外’使用相同組成物， 本紙張尺度適用中國國家標準（CNS) A4規格（210X 297公釐) 一 一 -51 - (請先閲讀背面之注意事項再填寫本頁) 裝· 钉 515784 A7 _B7 _五、發明説明（49 ) 以如例6 2之相同方法進行實驗。結果示於表3中 含 之 酸 質 雜 了 3 除 7 例 之 品 kfrvK 榡 驗 試 至 用 應 且 % 4 ο 爲 變 物 成。 組中 同 3 相表 用於 使示 , 果 外結 之。 3 驗 2 實 分行 公進 .\ 法 克方 C 同 ο 相 ο 之 3 3 爲 6 改例 載如 負以 ο 爲 變 量 含 之 酸 質 雜 了 4 除 7 例 之 品 樣 驗 試 至 用 應 且 % 物 成。 組中 同 3 相表 用於 使示 ， 果 外結 之。 驗 2 實 分行 公進 \ 法 克方 ί 同 相 之 3 4 爲 6 改例 載如 ΤΙΡΓ 負以 ο ο 含 之 酸 質 t三 了 5 除 7 例 之 品 樣 驗 試 至 用 應 且 % 4 ο 爲 變 物 成。 組中 同 3 相表 用於 使示 ’ 果 外結 之。 3 驗 2 實 分行 公進 \ 法 克方 C 同 ο 相 ο 之 3 5 爲 6 改例 載如 負以 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 銨 鐵 酸 珀 琥二 胺二 基 乙 伸 克 ο ο ο IX 用 使 了 6 除 7 例 與 9 xly ， 4 鹽 Η 酸 Ν 二 I 烯 0 J? F I 1 順 S 克 D ο D . Ε 8 含 包 ， C 鹽 鹽酸 銨二 質烯 雜丁 克 I ο 反 .克 之 ) ο 鹽中 酸 3 果表 蘋於 克示 ο 果 .結 3 ο 與驗 鹽實 酸行 珀進 琥法 單方 胺同 二相 基之 乙 1 伸例 克如 ο 以 • t 5 外 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 515784 A7 B7 五、發明説明（) 例7 7 除了使用1 0 0 0克伸乙基二胺二琥珀酸銅二鈉（ EDDS - Cu — 2Na)與25 · 0克雜質鈉鹽（包含 8 · 0克順一 丁烯二酸鹽，9 · 0克反一 丁烯二酸鹽， 5.0克伸乙基二胺單琥珀酸鹽與3·0克蘋果酸鹽）之 外，以如例1之相同方法進行實驗。結果示於表3中。 例7 8 除了使用1 0 0 0克伸乙基二胺二琥珀酸鎳二鈉（ EDDS — Ni - 2Na)與25 · 0克雜質銨鹽（包含 8 · 0克順一 丁烯二酸鹽，9 · 0克反一 丁烯二酸鹽， 5 . 0克伸乙基二胺單琥珀酸鹽與3 . 0克蘋果酸鹽）之 外，以如例1之相同方法進行實驗。結果示於表3中。 例7 9 經濟部中央標準局員工消費合作社印製 .(請先閱讀背面之注意事項再填寫本頁) 除了使用1 000克（S，S) —伸乙基二胺二琥珀 酸鐵銨（SS — EDDS - Fe—NH4 )與 25 · 0 克 雜質銨鹽（包含5 · 0克（S) -天冬酸鹽，5 · 0克（ S) - N — (2 —羥乙基）一天冬胺酸鹽，5 . 0克（S ，S) —N - (2 —羥乙基）一伸乙基二胺二琥珀酸鹽與 5 . 0克反一 丁烯二酸鹽）之外，以如例1之相同方法進 行實驗。結果示於表3中。 例8 0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 五 、發明説明（51 ) 除了使用1000克（s，S) —伸乙基 酸銅二鈉（SS - EDDS — Cu — 2Na)與 · 〇 克雜質鈉鹽（包含5 · 0克（S) -天冬酸鹽’ 5 · 0克 (S) 一 N — (2 —羥乙基）一天冬胺酸鹽，5 · 〇克（ 琥珀 乙基）一伸乙基二胺二琥珀酸與 5.〇克反一丁烯二酸鹽）之外，以如例1之相同方法進 行實驗。結果示於表3中。 S , 例8 (請先閱讀背面之注意事項再填寫本頁) 裝_ 基二胺二琥珀515784 A7 _B7 __ V. Description of the invention (45) Example 5 6 'Use the same composition' except that the content of the impurity salt becomes 0.3% and the load applied to the test sample is changed to 300 [g / cm 2] Experiments were performed in the same manner as in Example 46. The results are shown in Table 3. Example 5 7 An experiment was performed in the same manner as in Example 4 7 except that the content of the impurity salt was changed to 0.2% and the load applied to the test sample was changed to 300 [g / cm2] using the same composition. The results are shown in Table 3. Example 5 8 An experiment was carried out in the same manner as in Example 4 8 except that the content of the impurity salt was changed to 0.4% and the load applied to the test sample was changed to 300 [g / cm 2]. The results are shown in Table 3. Example 5 9 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) except that the content of impurity salts becomes 0.2% and the load applied to the test sample is changed to 300 [g / Other than 2 cm], experiments were performed in the same manner as in Example 49 using the same composition. The results are shown in Table 3. Example 6 0 The experiment was performed in the same manner as in Example 50 except that the content of the impurity salt was changed to 0.4% and the load applied to the test sample was changed to 300 [g / cm 2]. . The results are shown in Table 3. The paper size applies the Chinese national standard (CNS (21〇 > < 297mm) " 515784 A7 ____ B7 V. Description of the invention (46) Example 6 1 In addition to using 1000 grams of ethylenediamine disuccinic acid ( EDDS) with 25.0 grams of impurity acids (including 8.0 grams of maleic acid, 9.0 grams of trans maleic acid, 5.0 grams of ethylenediamine monosuccinic acid and 3.0 grams of malic acid ), The experiment was carried out in the same manner as in Example 1. The results are shown in Table 3. Example 6 2 Except using 1000 g (S, S) -ethylenediamine disuccinic acid (SS-EDDS) and 20.0 grams of impurity acid (contains 5.0 grams (S) —aspartic acid, 5.0 grams (S) — N (2-hydroxyethyl) aspartic acid, 5.0 (3,3) -1 ^ ((2-hydroxyethyl) -ethylenediamine succinic acid and 5.0 trans-butenedioic acid) were tested in the same manner as in Example 1. The results are shown in Table 3. Example 6 3 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except the use of 1 000 g of 1,3-propanediamine disuccinic acid (PDDS) and 15.0 g of impurities Acid (contains 5.0 g of Sunichi Experiments were carried out in the same manner as in Example 1 except for butenedioic acid, 4.0 g of trans-butenedioic acid, 3.0 g of 1,3-propanediamine monosuccinic acid and 3.0 g of malic acid). The results are shown in Table 3. Example 6 4 This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 515784 A7 _B7 ___ V. Description of the invention (47) In addition to using 100 g (s, S) -Propanediamine disuccinic acid (SS — PDDS) and 20.0 grams of impurity acids (including 5.0 grams (S) —aspartic acid, 5.0 grams (s) — 3 , 5.0 (S, S)-3 -hydroxypropyl-1'3-propane-monoamine disuccinic acid and 5.0 trans-butenedioic acid) were performed in the same manner as in Example 1 The results are shown in Table 3. Example 6 5 Except using 1000 g (s, s) -2hydroxy-1,3-propanediamine disuccinic acid (SS — PDDS — OH) and 25.0 g of impurity acid ( Contains 15.0 g (s) of aspartic acid '5.0 g (S) — N-(1,2-dihydroxypropyl) aspartic acid and 5.0 g of trans-butenedioic acid) In addition, experiments were performed in the same manner as in Example 1. Results It is shown in Table 3. Example 6 6 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) except that the content of the impurity acid becomes 5.0% and the load applied to the test sample is changed. The experiment was performed in the same manner as in Example 61 except that the same composition was used except 100 [g / cm 2]. The results are shown in Table 3. Example 6 7 An experiment was performed in the same manner as in Example 62 except that the content of the impurity acid was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 3. This paper size applies to China National Standard (CNS) A4 (210X297 mm) -50-Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 515784 A7 —_______ B7__ 5. Description of the invention (48) Example 6 8 In addition to the change in the content of impurities The test was performed in the same manner as in Example 63 except that the load applied to the test sample was changed to 100 [g / cm2] except that it was 8.0%. The results are shown in Table 3. Example 6 9 An experiment was performed in the same manner as in Example 64 except that the content of the impurity acid was changed to 6.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 3. Example 7 0 An experiment was carried out in the same manner as in Example 65 except that the content of the impurity acid was changed to 8.0% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 3. Example 7 1 An experiment was performed in the same manner as in Example 61 except that the content of the impurity acid was changed to 0.3% and the load applied to the test sample was changed to 300 [g / cm2] 'using the same composition. The results are shown in Table 3. Example 7 2 Except that the content of the impurity acid has changed to 0.2% and the load applied to the test sample has been changed to 300 [g / cm2] 'The same composition is used, and the Chinese paper standard (CNS) A4 specification applies to this paper size (210X 297mm) 1-1-51-(Please read the precautions on the back before filling in this page.) Fixing and nailing 515784 A7 _B7 _V. Description of the invention (49) The experiment was performed in the same way as in Example 62.2. The results are shown in Table 3. The acid content was mixed with 3 except 7 cases of the product kfrvK. The test was successful and% 4 ο was a variant. The same three-phase table in the group is used to show the results. 3 Examination 2 Actual branch advancement. \ Faqfang C Same as ο Phase ο 3 3 is 6 The modified example contains negative acidity with ο as a variable. 4 samples except 7 cases have been tested and applied. % Resulting. The same three-phase table in the group is used to show the results. Examination 2 Real Branch Promotion \ Fak Fang 3 Same phase 3 4 is 6 The modification example is shown as ΤΙΡΓ minus ο ο containing acid t 3 5 except 7 cases of sample test to the application and% 4 ο is Into something. The same 3-phase table in the group is used to show the results. 3 Examination 2 Real branch advancement \ Faker side C Same ο Phase ο 3 5 is 6 The amendment is contained as negative (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Persuccinate diammonium ferric ammonium ferric acid ο ο ο IX used 6 divided by 7 cases with 9 xly, 4 oxalic acid N diIene 0 J? FI 1 cis S gram D ο D. Ε 8 contains package , C salt, ammonium dihydrochlorinate dibutene I (ο trans. G)) ο acid in salt 3 fruit table ping Yu Keshi ο fruit. Knot 3 ο with the test salt of the acid and the two-phase group B 1 Extending the example such as ο t 5 The paper size is applicable to the Chinese National Standard (CNS) A4 (210X 297 mm) 515784 A7 B7 V. Description of the invention () Example 7 7 In addition to using 1 0 0 0 gram Copper Disodium Diamine Disuccinate (EDDS-Cu — 2Na) and 25.0 grams of impurity sodium salt (contains 8.0 grams of maleic acid salt, 9.0 grams of trans maleic acid salt, 5.0 Experiments were carried out in the same manner as in Example 1 except for gram ethylenediamine monosuccinate and 3.0 grams malate. The results are shown in Table 3. Example 7 8 Except using 1000 g of disodium nickel diethylene diamine disuccinate (EDDS — Ni-2Na) and 25 · 0 g of impurity ammonium salt (including 8 · 0 g of maleic acid salt, 9 · Experiments were carried out in the same manner as in Example 1 except that 0 g of trans-malonic acid salt, 5.0 g of ethylenediamine monosuccinate and 3.0 g of malate were used. The results are shown in Table 3. Example 7 9 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. (Please read the precautions on the back before filling this page.) In addition to using 1 000 g (S, S)-ethylenediamine disuccinate (SS — EDDS-Fe—NH4) and 25.0 g of impurity ammonium salt (containing 5.0 g (S) -aspartate, 5.0 g (S)-N — (2-hydroxyethyl) aspartamine Acid salt, except 5.0 g of (S, S) -N- (2-hydroxyethyl) monoethylenediamine disuccinate and 5.0 g of trans-butenedioate, as in the example Experiments were performed in the same manner as in 1. The results are shown in Table 3. Example 8 0 This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) 5. Description of the invention (51) In addition to the use of 1000 g (s, S)-copper sodium ethyl acetate (SS-EDDS-Cu — 2Na) and · 0 g of impurity sodium salt (containing 5.0 g (S) -aspartate '5.0 g (S) -N-(2-hydroxyethyl) aspartate, 5 · Experiments were carried out in the same manner as in Example 1 except that (succinethyl) monoethylenediamine disuccinic acid and 5.0 g of transbutylene succinate were used. The results are shown in Table 3. S, Example 8 (Please read the precautions on the back before filling this page)

除了使用1000克（S ’ S 酸鎳二鈉（SS - EDDS — Ni - 2Na)與 20 · 〇 克雜質鈉鹽（包含5 · 0克（S) -天冬胺酸鹽’ 5 · 0 克（S) — N —（2 —羥乙基）一天冬胺酸鹽’ 5 · 〇克 (S，S) — N —（2 —羥乙基）一伸乙基二胺一琥珀酸 鹽與5 · 0克反一 丁烯二酸鹽）之外’以如例1之相同方 法進行實驗。結果示於表3中。 例8 2 除了使用1000克（S，S) - 1 ’ 3 -丙院二胺 二琥珀酸鐵銨（SS — PDDS — Fe—NH4 )與 2〇 · 0克雜質銨鹽（包含5 · 〇克（s) 一天冬酸鹽， 5 · 0克（S) - 3 -羥丙基天冬胺酸鹽，5 · 0克（S ，S) — 3 -羥丙基—1 ，3 -丙烷二胺二琥珀酸鹽與 5 · 0克反—丁烯二酸鹽）之外，以如例1之相同方法進 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 、·?τ 經濟部中央標準局員工消費合作社印製 一 54 _ 515784 A7 , ____ B7__ 五、發明説明（52 ) 行實驗。結果示於表3中。 例8 3 除了使用1000克（S，S) — 1 ，3 —丙烷二胺 二琥珀酸銅二鈉（SS - PDDS — Cu - 2Na)與 20 · 0克雜質鹽（包含5 · 〇克（S) -天冬酸鹽，In addition to the use of 1000 grams (S'S nickel disodium acid (SS-EDDS-Ni-2Na) and 20 · gram impurities sodium salt (including 5.0 · (S) -aspartate '5 · 0 grams ( S) — N — (2-hydroxyethyl) aspartate '5.0 g (S, S) — N — (2-hydroxyethyl) monoethylenediamine monosuccinate with 5.0 The test was carried out in the same manner as in Example 1 except for the grams of trans-butenedioate). The results are shown in Table 3. Example 8 2 except that 1000 g of (S, S) -1'3-propanediamine Ferric ammonium disuccinate (SS — PDDS — Fe-NH4) and 2.00 g of impurity ammonium salt (containing 5.0 g (s) aspartate, 5.0 g (S)-3 -hydroxypropyl Aspartate, 5.0 g (S, S) — 3-hydroxypropyl-1,3-propanediamine disuccinate and 5.0 g trans-butenedioate) The same method as in Example 1 is adopted in this paper. The standard of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm), and is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. (52) Perform the experiment. The results are shown in Table 3. Example 8 3 In addition to using 1000 grams of (S, S) — 1, 3 —propanediamine disuccinate copper disodium (SS-PDDS — Cu-2Na) and 20.0 grams of impurity salts (including 5.0 grams ( S)-aspartate,

5 · 0克（S) - 3〜羥丙基天冬胺酸鹽，5 · 0克（S ，S) — 3 -羥丙基〜1，3 -丙烷二胺二琥珀酸鹽與 5 · 0克反一 丁烯二酸鹽）之外，以如例1之相同方法進 行實驗。結果示於表3中。 例8 4 除了使用1000克（S，S) — 1，3 —丙烷二胺 二琥珀酸鎳二鈉（SS — PDDS-N i - 2Na )與 20 · 0克雜質鹽（包含5 · 〇克（s) -天冬胺酸鹽，5.0 g (S)-3 ~ hydroxypropyl aspartate, 5.0 g (S, S)-3-hydroxypropyl ~ 1,3-propanediamine disuccinate with 5.0 G. Trans-malonic acid salt). The results are shown in Table 3. Example 8 4 Except using 1000 g (S, S) — 1,3-propanediamine nickel disodium disuccinate (SS — PDDS-N i-2Na) and 20.0 g impurity salts (including 5.0 g ( s)-aspartate,

5 · 0克（S) - 羥丙基天冬胺酸鹽，5 . 0克（S ，S) - 3 —羥丙基〜i , 3 -丙烷二胺二琥珀酸鹽與 5·0克反一丁烯二酸鹽）之外，以如例1之相同方法進 行賓驗。結果示於表3中。 比較例1 6 除了雜質鹽之含量變爲1〇%且應用至試驗樣品之負 載更改爲1 0 0〔克/公分2 〕之外，使用相同之組成物 ，以如例4 6之相同方法進行實驗。結果示於表4中。 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇父297公釐） 請 先 閱 讀 背 面 之 注 意5.0 g (S)-hydroxypropyl aspartate, 5.0 g (S, S)-3-hydroxypropyl ~ i, 3-propanediamine disuccinate and 5.0 g of trans Except monobutyrate), the test was performed in the same manner as in Example 1. The results are shown in Table 3. Comparative Example 16 Except that the content of the impurity salt was changed to 10% and the load applied to the test sample was changed to 100 [g / cm 2], the same composition was used, and the same method as in Example 4 6 experiment. The results are shown in Table 4. This paper size is in accordance with Chinese National Standard (CNS) A4 specification (21 mm parent 297 mm) Please read the note on the back first

經濟部中央標準局員工消費合作社印製 -55 515784 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（53 ) 比較例1 7 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載更改爲1〇〇〔克/公分2 〕之外，使用相同之組成物 ’以如例4 7之相同方法進行實驗。結果示於表4中。 比較例1 8 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載更改爲1 〇 〇〔克/公分2 〕之外，使用相同之組成物 ’以如例4 8之相同方法進行實驗。結果示於表4中。 比較例1 9 除了雜質鹽之含量變爲3 0 %且應用至試驗樣品之負 載更改爲1〇〇〔克/公分2 〕之外，使用相同之組成物 ’以如例4 9之相同方法進行實驗。結果示於表4中。 比較例2 〇 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 ’以如例5 0之相同方法進行實驗。結果示於表4中。 比較例2 1 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 本紙張尺度適用中國國家標準（CNS ) A4規格（210父297公釐） (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-55 515784 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (53) Comparative Example 1 7 Except for the impurity salt content becoming 15% and applied to the test The load of the sample was changed to 100 [g / cm2], and experiments were performed in the same manner as in Example 47 using the same composition. The results are shown in Table 4. Comparative Example 18 The same method was used as in Example 4 8 except that the content of the impurity salt was changed to 20% and the load applied to the test sample was changed to 1000 [g / cm 2]. experiment. The results are shown in Table 4. Comparative Example 19 Except that the content of the impurity salt was changed to 30% and the load applied to the test sample was changed to 100 [g / cm 2], the same composition was used in the same manner as in Example 4 9 experiment. The results are shown in Table 4. Comparative Example 2 The experiment was performed in the same manner as in Example 50 except that the content of the impurity salt was changed to 20% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 4. Comparative Example 2 1 Except that the content of the impurity salt has been changed to 15% and the load applied to the test sample has been changed to 100 [g / cm 2], the same composition has been used. The Chinese paper standard (CNS) A4 specification applies to this paper. (210 father 297 mm) (Please read the notes on the back before filling this page)

-56 - 515784 A7 _______B7_ 五、發明説明（54 ) ，以如例61之相同方法進行實驗。結果示於表4中。 比較例2 2 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載更改爲1 0 0〔克/公分2 〕之外，使用相同之組成物 ，以如例6 2之相同方法進行實驗。結果示於表4中。 比較例2 3 除了雜質鹽之含量變爲1 0%且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 ，以如例6 3之相同方法進行實驗。結果示於表4中。 比較例2 4 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 ，以如例6 4之相同方法進行實驗。結果示於表4中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 比較例2 5 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外’使用相同之組成物 ，以如例6 5之相同方法進行實驗。結果示於表4中。 比較例2 6 除了雜質鹽之含量變爲3 0%且應用至試驗樣品之負 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -57 - 515784 A7 B7 五、發明説明（55 ) 載更改爲1 0 0〔克/公分2 〕之外，使用相同之組成物. ，以如例7 9之相同方法進行實驗。結果示於表4中。 比較例2 7 除了雜質鹽之含量變爲2 0%且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 ，以如例8 0之相同方法進行實驗。結果示於表4中。 比較例2 8 除了雜質鹽之含量變爲1 5 %且應用至試驗樣品之負 載更改爲100〔克/公分2 〕之外，使用相同之組成物 ，以如例8 1之相同方法進行實驗。結果示於表4中。 (讀先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210'乂297公釐） -58 - 515784 A7 B7 五、發明説明（56 ) 表3 經濟部中央標準局員工消費合作社印製 例 式[I]之化合 物 雜質之含量 [wt. %] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 46 EDDS-4Na 2.4 200 1. 1 47 SS-EDDS-4Na 2. 0 200 1. 2 48 PDDS-4Na 1. 5 200 1.0 49 SS-PDDS-4Na 2.0 200 1. 3 50 PDDS-OH-4Na 2. 4 200 1.2 51 EDDS-4Na 5.0 100 1. 2 52 SS-EDDS-4Na 6.0 100 1. 0 53 PDDS-4Na 8. 0 100 0. 8 54 SS-PDDS-4Na 6.0 100 0. 9 55 PDDS-OH-4Na 8. 0 100 1.2 56 EDDS-4Na 0. 3 300 0. 8 57 SS-EDDS-4Na 0. 2 300 0. 9 58 PDDS-4Na 0. 4 300 1.0 59 SS-PDDS-4Na 0. 2 300 1.1 60 PDDS-0H-4Na 0· 4 300 1.2 61 EDDS 2. 4 200 0. 9 62 SS-EDDS 2.0 200 1. 0 63 PDDS 1.5 200 1.1 64 SS-PDDS 2. 0 200 0. 9 65 PDDS-OH 2.4 200 1.0 66 EDDS 5. 0 100 0. 8 67 SS-EDDS 6. 0 100 1. 1 68 PDDS 8. 0 100 1.2 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -59 - 515784 A7 B7 五、發明説明（57 ) 表3(續） 經濟部中央標準局員工消費合作社印製 例 式[I]之化合 物 雜質之含量 [wt.%] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 69 SS-PDDS 6. 0 100 1· 0 70 PDDS-OH 8. 0 100 0. 8 71 EDDS 0. 3 300 1.2 72 SS-EDDS 0· 2 300 1.3 73 PDDS 0· 4 300 1.1 74 SS-PDDS 0· 2 300 1_ 2 75 PDDS-OH 0. 4 300 1. 0 76 EDDS-Fe-NH4 2· 4 200 1.1 77 EDDS-Cu-2Na 2. 4 200 1.2 78 EDDS-Ni-2Na 2. 0 200 1. 0 79 SS-EDDS-Fe-NH4 S 2· 0 200 0. 9 80 S-EDDS-Cu-2Na S 2· 0 200 1.0 81 S-EDDS-Ni-2Na S 2. 0 200 1. 2 82 S-PDDS-Fe-2NH4 S 2. 0 200 1. 1 83 S-PDDS-Cu-2Na S 2. 0 200 1.3 84 S-PDDS-Ni-2Na 2. 0 200 1.0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 一 60 - 515784 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（58 ) 表4 比 較 例 式[I]之化合 物 雜質之含量 [wt.%] 負載 [公斤] 在儲放2個月 後之壓縮強度 [公斤/公分2] 16 EDDS-4Na 10 100 2. 8 17 SS-EDDS-4Na 15 100 2. 9 18 PDDS-4Na 20 100 3. 0 19 SS-PDDS-4Na 30 100 2. 9 20 SS-PDDS-0H-4Na 20 100 2. 7 21 EDDS 15 100 2. 8 22 SS-EDDS 15 100 2. 5 23 PDDS 10 100 2. 7 24 SS-PDDS 15 100 2. 8 25 SS-PDDS-OH 20 100 2. 5 26 SS-EDDS-Fe-NH4 30 100 2, 7 27 SS-EDDS-Cu-2Na 20 100 2. 8 28 SS-EDDS-Ni 15 100 2· 5 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -61 - 515784 A7 B7 五、發明説明（59 ) 例8 5 在不銹鋼容器中（表面安裝有熱電之加熱器），將包 含1 000克（S) -天冬胺酸一 N —單醋酸之三鈉鹽（ ASMA — 3Na)與250克雜質鹽（包含183克天 冬胺酸二鈉，4 0克反一丁烯二酸二鈉，2 2克甘胺酸之 單鈉鹽與5克順-丁烯二酸二鈉）之乾燥粉末溶解於 1 5 0 0克水中而製備淡黃色之透明水溶液。將此水溶液 保持在50°C60天，然後，藉由HPLC分析成份，且 同時觀察溶液之外觀。結果示於表5中。 例8 6 除了使用1 000克（S)—天冬胺酸—N，N —二 醋酸之四鈉鹽（ASDA — 4Na )與2 0 0克雜質鹽（ 包含8 2克反一丁烯二酸二鈉，6 2克天冬胺酸二鈉， 4 3克亞胺二醋酸二鈉，1 1克順一丁烯二酸二鈉與2克 氮三乙酸三鈉）之外，以如例8 5之相同方法進行實驗。 結果示於表5中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 例8 7 除了使用1 000克（S) -天冬胺酸一N —單丙酸 之三鈉鹽（ASMP — 3Na )與1 5 0克雜質鹽（包含 5 5克天冬胺酸二鈉，3 1克反一 丁烯二酸二鈉，3 1克 石一丙胺酸之單鈉鹽，2 4克亞胺二丙酸二鈉，7克順一 丁烯二酸二鈉與2克丙烯酸鈉）之外，以如例8 5之相同 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 62 - 515784 A7 __B7 五、發明説明（60 ) 方法進行實驗。結果示於表5中。 例8 8 除了使用1 〇〇〇克（S) — α —丙胺酸一 N，N — 二醋酸之三鈉鹽（S - ALDA — 3Na )與200克雜 質鹽（包含1 0 〇克α -丙胺酸之單鈉鹽，4 0克甘胺酸 之單鈉鹽，3 0克亞胺二醋酸二鈉與3 0克氮三乙酸三鈉 )之外，以如例8 5之相同方法進行實驗。結果示於表5 中〇 例8 9 除了雜質鹽之含量爲2 · 5%，在水溶液中式〔1〕 之化合物之含量爲4 9 · 4%，且將溶液保持在7 5 °C之 外，使用相同之式〔1〕化合物，以如例8 5之相同方法 進行實驗。結果示於表5中。 例9 0 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了雜質鹽之含量爲2 · 0%，在水溶液中式〔1〕 之化合物之含量爲4 9 · 5%，且將溶液保持在7 5 °C之 外，使用相同之式〔1〕化合物，以如例8 6之相同方法 進行實驗。結果示於表5中。 例9 1 除了雜質鹽之含量爲1 · 〇% ’在水溶液中式〔1〕 本ϋ尺度適用中國國家標準（CNS ) A4規格（210X297公釐) ' 一 -63 - 515784 A7 ____B7 五、發明説明（w ) 之化合物之含量爲4 9 · 8%，且將水溶液保持在7 5 °C 之外，使用相同之式〔1〕化合物，以如例8 7之相同方 法進行實驗。結果示於表5中》 例9 2 除了雜質鹽之含量爲1 · 2%，在水溶液中式〔1〕 之化合物之含量爲4 9 · 5%，且將水溶液保持在7 5 °C 之外，使用相同之式〔1〕化合物，以如例8 8之相同方 法進行實驗。結果示於表5中。 例9 3 除了雜質鹽之含量爲1 0 · 0%，在水溶液中式〔1 〕之化合物之含量爲6 5 · 4%，且將水溶液保持在6 5 °C之外，使用相同之式〔1〕化合物，以如例8 5之相同 方法進行實驗。結果示於表5中。 例9 4 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 除了雜質鹽之含量爲1 0 · 0%，在水溶液中式〔1 〕之化合物之含量爲6 5 · 4%，且將溶液保持在6 5 °C 之外，使用相同之式〔1〕化合物，以如例8 6之相同方 法進行實驗。結果示於表5中。 例9 5 除了雜質鹽之含量爲1 〇 · 0%，在水溶液中式〔1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） "—' - -64 - 515784 A7 __B7_ 五、發明説明（62 ) 〕之化合物之含量爲6 5 · 4%，且將溶液保持在6 5 °C 之外，使用相同之式〔1〕化合物，以如例8 7之相同方 法進行實驗。結果示於表5中。 例9 6 除了雜質鹽之含量爲1 〇 · 〇%，在水溶液中式〔1 〕之化合物之含量爲6 5 · 4%，且將水溶液保持在6 5 °C之外，使用相同之式〔1〕化合物，以如例8 8之相同 方法進行實驗。結果示於表5中。 例9 7 除了雜質鹽之含量爲2 · 5%，在水溶液中式〔1〕 之化合物之含量爲7 8 · 4%，且將溶液保持在7 0°C之 外，使用相同之式〔1〕化合物，以如例8 5之相同方法 進行實驗。結果示於表5中。 例9 8 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁)-56-515784 A7 _______B7_ V. Description of the Invention (54) The experiment was performed in the same way as in Example 61. The results are shown in Table 4. Comparative Example 2 2 The same method was used as in Example 6 2 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm 2]. experiment. The results are shown in Table 4. Comparative Example 2 3 An experiment was performed in the same manner as in Example 63 using the same composition except that the content of the impurity salt became 10% and the load applied to the test sample was changed to 100 [g / cm2]. The results are shown in Table 4. Comparative Example 24 The experiment was carried out in the same manner as in Example 64 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm2], using the same composition. The results are shown in Table 4. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Comparative Example 2 5 Except that the content of impurity salts becomes 20% and the load applied to the test sample is changed to 100 [g / The test was performed in the same manner as in Example 65 using the same composition except for "cm 2". The results are shown in Table 4. Comparative Example 2 In addition to the content of impurity salts becoming 30% and the negative paper size applied to the test samples, the Chinese National Standard (CNS) A4 specification (210X297 mm) -57-515784 A7 B7 V. Description of the invention (55 ) The load was changed to 100 [g / cm2], and the same composition was used. The experiment was performed in the same manner as in Example 79. The results are shown in Table 4. Comparative Example 27 Except that the content of the impurity salt became 20% and the load applied to the test sample was changed to 100 [g / cm2], the experiment was performed in the same manner as in Example 80 using the same composition. The results are shown in Table 4. Comparative Example 2 8 An experiment was performed in the same manner as in Example 81 except that the content of the impurity salt was changed to 15% and the load applied to the test sample was changed to 100 [g / cm 2]. The results are shown in Table 4. (Read the precautions on the back before you fill in this page.) The paper printed by the Central Consumers Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, is a paper size that applies the Chinese National Standard (CNS) A4 (210 '乂 297 mm) -58-515784 A7 B7 5 Description of the invention (56) Table 3 Contents of impurities in compounds of formula [I] printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs [wt.%] Load [kg] Compressive strength after 2 months of storage [kg / Cm2] 46 EDDS-4Na 2.4 200 1. 1 47 SS-EDDS-4Na 2. 0 200 1. 2 48 PDDS-4Na 1. 5 200 1.0 49 SS-PDDS-4Na 2.0 200 1. 3 50 PDDS-OH- 4Na 2. 4 200 1.2 51 EDDS-4Na 5.0 100 1. 2 52 SS-EDDS-4Na 6.0 100 1. 0 53 PDDS-4Na 8. 0 100 0.8 8 54 SS-PDDS-4Na 6.0 100 0.9 5 PDDS -OH-4Na 8. 0 100 1.2 56 EDDS-4Na 0. 3 300 0. 8 57 SS-EDDS-4Na 0. 2 300 0. 9 58 PDDS-4Na 0. 4 300 1.0 59 SS-PDDS-4Na 0. 2 300 1.1 60 PDDS-0H-4Na 0 · 4 300 1.2 61 EDDS 2. 4 200 0. 9 62 SS-EDDS 2.0 200 1. 0 63 PDDS 1.5 200 1.1 64 SS-PDDS 2. 0 200 0. 9 65 PDDS -OH 2.4 200 1.0 66 EDDS 5. 0 100 0. 8 67 SS-EDDS 6. 0 100 1. 1 68 PDDS 8. 0 100 1.2 (Please read the notes on the back before filling in this page) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -59-515784 A7 B7 V. Description of the invention (57) Table 3 (Continued) The content of impurities [wt.%] Of the compound [I] printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs [load] Load [kg] Compressive strength after storage for 2 months [kg / cm 2] 69 SS -PDDS 6. 0 100 1 · 0 70 PDDS-OH 8. 0 100 0. 8 71 EDDS 0. 3 300 1.2 72 SS-EDDS 0 · 2 300 1.3 73 PDDS 0 · 4 300 1.1 74 SS-PDDS 0 · 2 300 1_ 2 75 PDDS-OH 0.4 4 300 1. 0 76 EDDS-Fe-NH4 2 4 200 1.1 77 EDDS-Cu-2Na 2. 4 200 1.2 78 EDDS-Ni-2Na 2. 0 200 1. 0 79 SS-EDDS-Fe-NH4 S 2.0 0 200 0. 9 80 S-EDDS-Cu-2Na S 2.0 0 200 1.0 81 S-EDDS-Ni-2Na S 2. 0 200 1. 2 82 S-PDDS- Fe-2NH4 S 2. 0 200 1. 1 83 S-PDDS-Cu-2Na S 2. 0 200 1.3 84 S-PDDS-Ni-2Na 2. 0 200 1.0 This paper size applies to China National Standard (CNS) A4 specifications (210X 297mm) (Please read the precautions on the back before filling out this page) 60-515784 A7 B7 Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Bureau of Standards 5. Explanation of the invention (58) Table 4 Contents of impurities in the compound of formula [I] [wt.%] Load [kg] Compressive strength [kg / cm] after 2 months of storage 2] 16 EDDS-4Na 10 100 2. 8 17 SS-EDDS-4Na 15 100 2. 9 18 PDDS-4Na 20 100 3. 0 19 SS-PDDS-4Na 30 100 2. 9 20 SS-PDDS-0H-4Na 20 100 2. 7 21 EDDS 15 100 2. 8 22 SS-EDDS 15 100 2. 5 23 PDDS 10 100 2. 7 24 SS-PDDS 15 100 2. 8 25 SS-PDDS-OH 20 100 2. 5 26 SS -EDDS-Fe-NH4 30 100 2, 7 27 SS-EDDS-Cu-2Na 20 100 2. 8 28 SS-EDDS-Ni 15 100 2 · 5 (Please read the precautions on the back before filling this page) This paper The dimensions are applicable to the Chinese National Standard (CNS) A4 (210X 297 mm) -61-515784 A7 B7 V. Description of the invention (59) Example 8 5 In a stainless steel container (surface-mounted thermoelectric heater), it will contain 1,000 Grams (S)-Aspartic acid mono-N-trisodium salt of monoacetic acid (ASMA-3Na) and 250 grams of impurity salts (including 183 grams of disodium aspartate, 40 grams of disodium butenedioate 22 g of monosodium salt of glycine and 5 g of cis-butene di Disodium) dried powder was dissolved in 1,500 g of water to prepare a pale yellow transparent aqueous solution of. This aqueous solution was kept at 50 ° C for 60 days, and then the components were analyzed by HPLC, and at the same time the appearance of the solution was observed. The results are shown in Table 5. Example 8 6 In addition to using 1,000 g (S) -aspartic acid-N, N-tetrasodium salt of diacetic acid (ASDA-4Na) and 200 g of impurity salt (including 82 g of trans-butenedioic acid) Disodium, 62 grams of disodium aspartate, 43 grams of disodium imine diacetate, 11 grams of disodium maleate and 2 grams of trisodium nitrotriacetate), as in Example 8 5 Experiment in the same way. The results are shown in Table 5. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Example 8 7 Except the use of 1,000 g (S) -aspartic acid-N-trisodium trisodium salt ( ASMP — 3Na) and 150 g of impurity salt (including 55 g of disodium aspartate, 31 g of disodium maleate, 31 g of monosodium salt of mono-alanine, 24 g In addition to disodium imide dipropionate, 7 g disodium maleate and 2 g sodium acrylate), the same paper size as in Example 8 5 applies the Chinese National Standard (CNS) A4 specification (210X297 mm) A 62-515784 A7 __B7 V. Description of the invention (60) The method is used for experiments. The results are shown in Table 5. Example 8 8 Except using 1000 g (S) -α-alanine mono-N, N-diacetic acid trisodium salt (S-ALDA-3Na) and 200 g of impurity salt (including 100 g of α-propylamine The experiment was carried out in the same manner as in Example 8 except that the monosodium salt of acid, the monosodium salt of glycine, 40 grams of disodium imine diacetate, and 30 grams of trisodium azatriacetate were used. The results are shown in Table 5. Example 8 9 The content of the compound of formula [1] in the aqueous solution was 4 9 · 4% except that the content of the impurity salt was 2.5%, and the solution was kept at 7 5 ° C. Using the same compound of the formula [1], an experiment was performed in the same manner as in Example 85. The results are shown in Table 5. Example 9 0 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except for the content of impurity salt is 2.0%, the content of the compound of formula [1] in the aqueous solution is 4 9 · 5%, and keep the solution outside 75 ° C, using the same compound of formula [1], the experiment was performed in the same manner as in Example 86. The results are shown in Table 5. Example 9 1 In addition to the content of impurities, the salt content is 1.0%. 'Formula [1] in aqueous solution. The Chinese standard (CNS) A4 specification (210X297 mm) applies to this standard.' -63-515784 A7 ____B7 V. Description of the invention ( w) The content of the compound is 4 9 · 8%, and the aqueous solution is kept outside 7 5 ° C, and the same formula [1] is used to carry out the experiment in the same manner as in Example 8 7. The results are shown in Table 5. "Example 9 2 Except for the content of impurity salts of 1.2%, the content of the compound of formula [1] in the aqueous solution was 49.5%, and the aqueous solution was maintained at 7 5 ° C. Using the same compound of formula [1], the experiment was carried out in the same manner as in Example 88. The results are shown in Table 5. Example 9 3 The same formula [1] was used except that the content of the impurity salt was 10 · 0%, the content of the compound of formula [1] in the aqueous solution was 65 · 4%, and the aqueous solution was kept at 65 ° C. The compound was tested in the same manner as in Example 85. The results are shown in Table 5. Example 9 4 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except for the content of impurity salt is 10 · 0%, the content of the compound of formula [1] in the aqueous solution is 6 The experiment was carried out in the same manner as in Example 86 using 5 · 4% and keeping the solution outside 65 ° C, using the same compound of formula [1]. The results are shown in Table 5. Example 9 5 In addition to the content of impurity salt is 1.0%, in the aqueous solution, [1 paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) " — '--64-515784 A7 __B7_ V. Description of the invention (62)] The content of the compound is 65. 4%, and the solution is kept outside 65 ° C. Using the same compound of the formula [1], the experiment is performed in the same manner as in Example 87. The results are shown in Table 5. Example 9 6 The content of the compound of formula [1] in the aqueous solution is 65. 4%, except that the content of the impurity salt is 10.0%, and the same formula is used except that the aqueous solution is maintained at 65 ° C. The compound was tested in the same manner as in Example 88. The results are shown in Table 5. Example 9 7 The same formula [1] was used except that the content of the impurity salt was 2.5%, the content of the compound of formula [1] in the aqueous solution was 78.8%, and the solution was kept at 70 ° C. The compounds were tested in the same manner as in Example 85. The results are shown in Table 5. Example 9 8 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page)

除了雜質鹽之含量爲2 . 0%，在水溶液中式〔1〕 之化合物之含量爲7 8 · 7%，且將水溶液保持在7 0°C 之外，使用相同之式〔1〕化合物，以如例8 6之相同方 法進行實驗。結果示於表5中。 例9 9 除了雜質鹽之含量爲1 · 0%，在水溶液中式〔1〕 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~ " -65 - 515784 A7 ______B7 五、發明説明（63 ) 之化合物之含量爲7 9 · 4%，且將水溶液保持在7 0°C 之外，使用相同之式〔1〕化合物，以如例8 7之相同方 法進fr實驗。結果τκ於表5中。 (請先閱讀背面之注意事項再填寫本頁) 例1 0 0 在不銹鋼容器中（表面安裝有熱電之加熱器），將包 含1 0 0 0克牛磺酸一 N，N -二醋酸之三鈉鹽（ TUDA — 3Na )與2 5 0克雜質鹽（包含5 0牛磺酸 之單鈉鹽，5 0克羥基乙酸二鈉，5 0克甘胺酸之單鈉鹽 ，5 0克亞胺二醋酸二鈉與5 0克氮三乙酸三鈉）之乾燥 粉末溶解於1 5 0 0克水中而製備具有淡黃色之透明水溶 液。將此水溶液保持在5 0°C 6 0天，然後，藉由 Η P L C分析成份，且同時觀察溶液之外觀。結果示於表 5中。 例1 0 1 經濟部中央標準局員工消費合作社印製 除了使用1 0 0 0克Ν —甲基亞胺二醋酸二鈉（ MIDA — 2Na)與200克雜質鹽（包含50克羥基 乙酸二鈉，5 0克甘胺酸之單鈉鹽，5 0克亞胺二醋酸二 鈉與5 0克氮三乙酸三鈉）之外，以如例1 〇 〇之相同方 法進行實驗。結果示於表5中。 例1 0 2 除了使用1 0 0 0克鄰一胺基苯甲酸一 ν，N —二醋 本紙張尺度適用中國國家標隼（CNS ) A4規格（210X297公釐） 515784 A7 B7 五、發明説明（64 ) 酸之三鈉鹽（ANTDA - 3N a )與1 5 0克雜質鹽（ 包含3 0克鄰一胺基苯甲酸單鈉’ 6 0克羥基乙酸二鈉’ 3 0克甘胺酸之單鈉鹽，3 0克亞胺二醋酸二鈉與3 0克 氮三乙酸三鈉）之外’以如例1 〇 0之相同方法進行實驗 。結果示於表5中。 例1 0 3 除了雜質鹽之含量爲2 · 5% ’在水溶液中式〔1〕 之化合物之含量爲4 9 · 4% ’且將溶液保持在7 5 °C之 外，使用相同之式〔1〕化合物，以如例1 0 〇之相同方 法進行實驗。結果示於表5中。 例1 0 4 除了雜質鹽之含量爲2 · 0% ’在水溶液中式〔1〕 之化合物之含量爲4 9 · 5%，且將溶液保持在7 5 °C之 外，使用相同之式〔1〕化合物，以如例1 〇 1之相同方 法進行實驗。結果示於表5中。 經濟部中央標準局舅工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 例1 0 5Except that the content of the impurity salt is 2.0%, the content of the compound of the formula [1] in the aqueous solution is 78.7%, and the aqueous solution is kept at 70 ° C, the compound of the same formula [1] is used to Experiments were performed in the same manner as in Example 86. The results are shown in Table 5. Example 9 9 In addition to the content of impurity salt is 1.0%, the formula in the aqueous solution is [1] This paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm) ~ " -65-515784 A7 ______B7 5. Description of the invention The content of the compound of (63) was 79.4%, and the aqueous solution was kept outside 70 ° C. Using the same compound of the formula [1], fr experiments were performed in the same manner as in Example 87. The results τκ are shown in Table 5. (Please read the precautions on the back before filling out this page) Example 1 0 0 In a stainless steel container (surface-mounted thermoelectric heater), 100 g of taurine-N, N-diacetic acid will be included Sodium salt (TUDA — 3Na) and 250 g of impurity salt (including monosodium salt of 50 taurine, 50 g of disodium glycolate, 50 g of monosodium salt of glycine, 50 g of imine A dry powder of disodium diacetate and 50 g of trisodium nitrotriacetate) was dissolved in 1500 g of water to prepare a pale yellow transparent aqueous solution. This aqueous solution was kept at 50 ° C for 60 days, and then the components were analyzed by Η PL C while the appearance of the solution was observed at the same time. The results are shown in Table 5. Example 1 1 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. In addition to using 100 g of N-methylimine diacetic acid disodium (MIDA-2Na) and 200 g of impurity salts (including 50 g of disodium glycolate, Except 50 g of monosodium salt of glycine, 50 g of disodium imine diacetate and 50 g of trisodium azatriacetate), the experiment was performed in the same manner as in Example 1000. The results are shown in Table 5. Example 1 In addition to using 1000 g of o-aminoaminobenzoic acid mono-v, N-diacetate, the paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 515784 A7 B7 V. Description of the invention ( 64) Trisodium salt of acid (ANTDA-3N a) and 150 g of impurity salt (containing 30 g of o-monoaminobenzoic acid monosodium '60 g of disodium glycolate' 30 g of glycine Sodium salt, 30 g of disodium imine diacetate and 30 g of trisodium azatriacetate) were tested in the same manner as in Example 1000. The results are shown in Table 5. Example 1 0 3 The same formula [1] was used except that the content of the impurity salt was 2.5% 'the content of the compound of formula [1] in the aqueous solution was 4 9 · 4%' and the solution was kept at 7 5 ° C The compound was tested in the same manner as in Example 100. The results are shown in Table 5. Example 1 0 4 The same formula [1] was used except that the content of the impurity salt was 2.0%. The content of the compound of formula [1] in the aqueous solution was 49.5%, and the solution was kept at 7 5 ° C. The compound was tested in the same manner as in Example 101. The results are shown in Table 5. Printed by the Central Consumers ’Bureau of the Ministry of Economic Affairs, Consumer Goods Cooperative (please read the notes on the back before filling this page) Example 1 0 5

除了雜質鹽之含量爲1 · 〇%，在水溶液中式〔1〕 之化合物之含量爲4 9 · 8%，且將水溶液保持在7 5 °C 之外，使用相同之式〔1〕化合物，以如例1 0 2之相同 方法進行實驗。結果示於表5中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 515784 A7 B7 五、發明説明（65 ) 例1 0 6 除了雜質鹽之含量爲1 0 · 〇%，在水溶液中式〔/ 〕之化合物之含量爲6 5 · 4%，且將水溶液保持在6 5 。(：之外，使用相同之式〔1〕化合物，以如例χ 〇 〇之相 同方法進行實驗。結果示於表5中。 例1 0 7 除了雜質鹽之含量爲1 0 · 〇%，在水溶液中式〔i 〕之化合物之含量爲6 5 · 4 %，且將水溶液保持在6 5 。(：之外，使用相同之式〔1〕化合物，以如例1 〇 1之相 同方法進彳了實驗。結果不於表5中。 例1 0 8 除了雜質鹽之含量爲1 〇 · 〇%，在水溶液中式〔工 〕之化合物之含量爲7 8 · 4%，且將水溶液保持在7 〇 °C之外’使用相同之式〔1〕化合物，以如例1 〇 2之相 同方法進行實驗。結果示於表5中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁} 例1 0 9 除了雜質鹽之含量爲2 · 〇%，在水溶液中式〔1〕 之化合物之含量爲7 8 · 7%，且將水溶液保持在6 〇°C 之外’使用相同之式〔1〕化合物，以如例i 〇 1之相同 方法進行實驗。結果示於表5中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -68 - 515784 A7 B7 五、發明説明（66 ) 例1 1 0 除了使用1 000克鄰一胺基苯甲酸一 N，N —二醋 酸之鐵鹽（ANTDA — F e)與20克雜質F e鹽（包 含4克鄰一胺基苯甲酸鹽，8克羥基乙酸鹽，4克甘胺酸 鹽，4克亞胺二醋酸鹽與4克氮三乙酸鹽），在水溶液中 式〔1〕之化合物之含量爲49 · 5%，且將水溶液保持 在4 0°C之外，以如例1 0 〇之相同方法進行實驗。結果 示於表5中。 例1 1 1 除了使用1 0 0 0克鄰一胺基苯甲酸一 N，N —二醋 酸之鐵鹽（ANTDA — F e )與1 0克雜質F e鹽（包 含2克鄰一胺基苯甲酸鹽，4克羥基乙酸鹽，2克甘胺酸 鹽，2克亞胺二醋酸鹽與2克氮三乙酸鹽），在水溶液中 式〔1〕之化合物之含量爲39 . 8%，且將水溶液保持 在4 0°C之外，以如例1 0 0之相同方法進行實驗。結果 示於表5中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 比較例2 9 除了雜質鹽之含量爲3 5 · 0%，在水溶液中式〔1 〕之化合物之含量爲3 5 · 1%，且將水溶液保持在5 0 °C之外，使用相同之式〔1〕化合物，以如例8 5之相同 方法進行實驗。結果示於表6中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 515784 A7 B7 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 五、發明説明（67 ) 比較例3 0 除了雜質鹽之含量爲3 〕之化合物之含量爲3 5 · 。(：之外，使用相同之式〔1 方法進行實驗。結果示於表 比較例3 1 除了雜質鹽之含量爲3 〕之化合物之含量爲3 5 · °C之外，使用相同之式〔1 方法進行實驗。結果示於表 比較例3 2 除了雜質鹽之含量爲3 〕之化合物之含量爲3 5 · °C之外，使用相同之式〔1 方法進行實驗。結果示於表 比較例3 3 除了雜質鹽之含量爲5 〕之化合物之含量爲3 3 · °C之外，使用相同之式〔1 方法進行實驗。結果示於表 5.0%，在水溶液中式〔1 1%，且將水溶液保持在5 0 〕化合物，以如例8 6之相同 6中。 5.0%，在水溶液中式〔1 1%，且將水溶液保持在50 〕化合物，以如例8 7之相同 6中。 5.0%，在水溶液中式〔1 1%，且將水溶液保持在50 〕化合物，以如例8 8之相同 6中。 0.0%，在水溶液中式〔1 3%，且將水溶液保持在5 0 〕化合物，以如例8 5之相同 6中0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 515784 A7 B7 五、發明説明（68 ) 比較例3 4 除了雜質鹽之含量爲3 5 · 〇%，在水溶液中式〔1 〕之化合物之含量爲35·1%，且將水溶液保持在75 °C之外，使用相同之式〔1〕化合物，以如例8 5之相同 方法進行實驗。結果示於表6中。 比較例3 5 除了雜質鹽之含量爲2 8 · 0%，在水溶液中式〔1 〕之化合物之含量爲51·4%，且將水溶液保持在60 °C之外’使用相同之式〔1〕化合物，以如例8 5之相同 方法進行實驗。結果示於表6中。 比較例3 6 除了雜質鹽之含量爲3 5 · 0%，在水溶液中式〔1 〕之化合物之含量爲35·1%，且將水溶液保持在50 °C之外’使用相同之式〔1〕化合物，以如例8 6之相同 方法進行實驗。結果示於表6中。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 比較例3 7 除了雜質鹽之含量爲3 5 · 0%，在水溶液中式〔1 〕之化合物之含量爲3 5 · 1%，且將水溶液保持在5 0 °C之外，使用相同之式〔1〕化合物，以如例1 〇 〇之相 同方法進行實驗。結果示於表6中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 35.〇%，在水溶液中式〔1 •1%，且將水溶液保持在50 1〕化合物，以如例1 〇 2之相 於表6中。 515784 A7 _______ B7 五、發明説明（69 ) 比較例3 8 除了雜質鹽之含量爲35·〇%，在水溶液中式〔工 〕之化合物之含量爲3 5 · 1%，且將水溶液保持在5〇 。(：之外，使用相同之式〔1〕化合物，以如例i 〇 J之相 同方法進行實驗。結果示於袠6中。 比較例3 9 除了雜質鹽之含量爲 〕之化合物之含重爲3 5 t之外，使用相同之式〔 同方法進行實驗。結果示 比較例4 0 除了雜質鹽之含量爲5 〇 · 0%，在水溶液中式〔工 〕之化合物之含量爲3 3 · 3%，且將水溶液保持在5 〇 °C之外，使用相同之式〔1〕化合物以如例1 〇 〇之相同 方法進行實驗。結果示於表6中。 比較例4 1 除了雜質鹽之含量爲3 5 · 0%，在水溶液中式〔1 〕之化合物之含量爲3 5 · 1%，且將水溶液保持在7 5 °C之外’使用相同之式〔1〕化合物以如例χ 〇 1之相同 方法進行實驗。結果示於表6中。 本^張尺度適用中國國家標準（CMS ) Α4規格（210X^97公釐） 裝---- (請先閲讀背面之注意事項再填寫本頁) -----訂 經濟部中央標準局員工消費合作社印製 -72 - 515784 A7 B7 五、發明説明（7〇 ) 比較例4 2 1 ο 司 C 4 相 式在之 中持 ο 液保 1 溶液 1 水溶例 在水如 ， 將以 % 且物 ο , 合 。 • % 化中 8 8 ] 6 2 · 1 表 爲 3 t 於 量 4 式.示 含爲之果 之量同結 鹽含相。 質之用驗 雜物使實 了合，行 除化外進 之之法 3 OC 方 (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 73 -Except that the content of the impurity salt is 1.0%, the content of the compound of the formula [1] in the aqueous solution is 49. 8%, and the aqueous solution is kept at 7 5 ° C, the compound of the same formula [1] is used to Experiments were performed in the same manner as in Example 102. The results are shown in Table 5. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 515784 A7 B7 V. Description of the invention (65) Example 1 0 In addition to the impurity salt content is 10 · 0%, in the aqueous solution of the formula [/] The content of the compound was 65. 4%, and the aqueous solution was kept at 65. (: Except that, using the same compound of the formula [1], the experiment was performed in the same manner as in Example χ 〇〇. The results are shown in Table 5. Example 1 7 The content of the salt except for impurities was 10 · 〇%. The content of the compound of the formula [i] in the aqueous solution was 65. 4%, and the aqueous solution was kept at 65. (except that the same compound of the formula [1] was used in the same manner as in Example 101 except that The results are not shown in Table 5. Example 108 Except for the impurity salt content of 10.0%, the content of the compound of formula [engineering] in the aqueous solution was 78.8%, and the aqueous solution was maintained at 70 ° Except C ', the compound of the same formula [1] was used, and the experiment was performed in the same manner as in Example 102. The results are shown in Table 5. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the precautions on the back first Refill this page} Example 1 0 9 Except for the content of impurity salts of 2.0%, the content of the compound of formula [1] in the aqueous solution is 7 8 · 7%, and the aqueous solution is kept at 60 ° C. The compound of the same formula [1] was tested in the same manner as in Example 〇1. Results Shown in Table 5. This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -68-515784 A7 B7 V. Description of the invention (66) Example 1 1 0 In addition to using 1 000 g of o-aminoamine benzene Formic acid mono-N, N-diacetic acid iron salt (ANTDA-Fe) and 20 grams of impurity Fe salt (including 4 grams of o-monoaminobenzoate, 8 grams of glycolate, 4 grams of glycine, 4 g of imine diacetate and 4 g of nitrogen triacetate), the content of the compound of formula [1] in the aqueous solution is 49.5%, and the aqueous solution is kept outside 40 ° C, as in Example 10. The experiment was carried out in the same manner. The results are shown in Table 5. Example 1 1 1 except that 1000 g of o-aminoaminobenzoic acid mono-N, N-diacetic acid iron salt (ANTDA-F e) and 10 g were used. Impurity Fe salt (containing 2 g of o-monoaminobenzoate, 4 g of glycolate, 2 g of glycine, 2 g of imine diacetate and 2 g of nitrogen triacetate), in an aqueous solution of formula [ 1] The content of the compound was 39.8%, and the aqueous solution was kept outside 40 ° C, and the experiment was performed in the same manner as in Example 100. The results are shown in Table 5. Central Ministry of Economic Affairs Printed by the Consumer Bureau of Standards Bureau (please read the precautions on the back before filling out this page) Comparative Example 2 9 Except for the content of impurity salt is 3 5 · 0%, the content of the compound of formula [1] in the aqueous solution is 3 5 · 1%, keeping the aqueous solution outside 50 ° C, using the same compound of formula [1], the experiment was performed in the same way as in Example 85. The results are shown in Table 6. The paper dimensions are applicable to Chinese national standards ( CNS) A4 specification (210X 297 mm) 515784 A7 B7 (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (67) Comparative Example 3 0 In addition to impurity salts The content of the compound of 3] is 3 5 ·. (: Except that, the experiment was performed using the same formula [1. The results are shown in Table Comparative Example 3 1 except that the content of the impurity salt is 3] The content of the compound was 3 5 · ° C, and the same formula [1 The method was used to perform the experiment. The results are shown in Table Comparative Example 3 2 The experiment was performed using the same formula [1] except that the content of the impurity salt content was 3] and the compound content was 3 5 · ° C. The results are shown in Table Comparative Example 3 3 The test was performed using the same method [1] except that the content of the compound with an impurity salt content of 5] was 3 3 ° C. The results are shown in Table 5.0%, in the aqueous solution, the formula [1 1%, and Keep the compound in 50] as in Example 8 6 in the same 6. 5.0%, in the aqueous solution of the formula [11% and keep the aqueous solution in 50] compound as in Example 8 7 in the same 6. 5.0%, A compound of formula [1 1% and keeping the aqueous solution at 50] in an aqueous solution is the same as in Example 8 8 0.0%, a compound of formula [1 3% and maintaining an aqueous solution at 50] in the aqueous solution, such as Example 8 5 of the same 6 of 0 This paper size applies to China National Standard (CNS) A4 regulations (210X297 mm) 515784 A7 B7 V. Description of the invention (68) Comparative example 3 4 In addition to the content of impurity salt is 35.0%, the content of the compound of formula [1] in the aqueous solution is 35.1%, and the aqueous solution is The experiment was carried out in the same manner as in Example 8 and 5 using the same compound of the formula [1] except at 75 ° C. The results are shown in Table 6. Comparative Example 3 5 The content of the salt except for impurities was 2 8 · 0% The content of the compound of the formula [1] in the aqueous solution was 51.4%, and the aqueous solution was kept outside 60 ° C. Using the same compound of the formula [1], the experiment was performed in the same manner as in Example 85. The results are shown. The results are shown in Table 6. Comparative Example 3 6 The content of the compound of formula [1] in the aqueous solution was 35.1%, except that the content of the impurity salt was 35.0%, and the aqueous solution was kept at 50 ° C. The same is used. The compound of formula [1] was tested in the same manner as in Example 86. The results are shown in Table 6. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Comparative Example The content of 3 7 except impurities is 3 5 · 0%. In the aqueous solution, the formula [1 The content of the compound was 35. 1%, and the aqueous solution was kept outside 50 ° C. The experiment was performed in the same manner as in Example 100 using the same compound of the formula [1]. The results are shown in Table 6. The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 35.0%. In the aqueous solution, the compound [1 • 1%, and the aqueous solution is maintained at 50 1] compounds, as in Example 1 〇2 The phases are shown in Table 6. 515784 A7 _______ B7 V. Description of the Invention (69) Comparative Example 3 8 In addition to the content of impurity salts is 35.0%, the content of the compound of formula [engineering] in the aqueous solution is 35.1%, and the aqueous solution is maintained at 50%. . (: Except that, using the same compound of the formula [1], the experiment was performed in the same manner as in Example i 0J. The results are shown in 袠 6. Comparative Example 3 9 The content of the compound except for the content of impurity salts is] Except for 3 5 t, experiments were performed using the same formula [same method. The results are shown in Comparative Example 40 except that the content of the impurity salt was 50.0%, and the content of the compound of the formula [engineering] in the aqueous solution was 3 3 · 3% The experiment was performed in the same manner as in Example 1000 using the same compound of formula [1] using the same formula [1] while maintaining the aqueous solution at 50 ° C. The results are shown in Table 6. Comparative Example 4 1 3 5 · 0%, the content of the compound of formula [1] in the aqueous solution is 3 5 · 1%, and the aqueous solution is kept outside 7 5 ° C 'using the same compound of the formula [1] as in the example χ 〇1 Experiments were carried out in the same way. The results are shown in Table 6. The dimensions of this sheet are applicable to the Chinese National Standard (CMS) A4 specification (210X ^ 97 mm). ---- (Please read the precautions on the back before filling this page) ----- Order printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-72-515784 A7 B7 5 Description of the invention (70) Comparative example 4 2 1 ο The company C 4 phase is held ο Liquid protection 1 Solution 1 Water-soluble examples in water, such as% and ο, combined. •% 化 中 8 8] 6 2 · 1 The table shows the formula of 3 t in the amount 4. The amount of the fruit shown is the same as that of the salt. The quality is verified by the sundries, and the method of addition to the chemical is 3 OC (please First read the notes on the back and then fill out this page) The paper size printed by the Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 (210X297 mm)-73-

515784 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（Ή ) 表5 例 式[I]之化合物 雜質之含 量 wt. 9Γ 保持 溫度 °C 保持60天前後之變化# wt. % 外觀 36.4 淡黃色透明水溶液 85 S-ASMA-3Na 25.0 50 35.4 淡黃色透明水溶液 37.0 淡黃色透明水溶液 86 S-ASDA-4Na 20.0 50 1 36.4 淡黃色透明水溶液 37.8 淡黃色透明水溶液 87 S-ASMP-3Na 15.0 50 1 37.8 淡黃色透明水溶液 37.0 淡黃色透明水溶液 88 S-ALDA-3Na 20.0 50 36.5 淡黃色透明水溶液 49.4 無色透明水溶液 89 S-ASMA-3Na 2.5 75 1 49.4 無色透明水溶液 49.5 無色透明水溶液 90 S-ASDA-4Na 2.0 75 1 49.5 無色透明水溶液 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -74 - 515784515784 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (Ή) Table 5 Contents of impurities in the compound of the formula [I] wt. 9Γ Keeping temperature ° C Keeping the change before and after 60 days # wt.% Appearance 36.4 light yellow transparent aqueous solution 85 S-ASMA-3Na 25.0 50 35.4 light yellow transparent aqueous solution 37.0 light yellow transparent aqueous solution 86 S-ASDA-4Na 20.0 50 1 36.4 light yellow transparent aqueous solution 37.8 light yellow transparent aqueous solution 87 S-ASMP-3Na 15.0 50 1 37.8 light yellow transparent aqueous solution 37.0 light yellow transparent aqueous solution 88 S-ALDA-3Na 20.0 50 36.5 light yellow transparent aqueous solution 49.4 colorless transparent aqueous solution 89 S-ASMA-3Na 2.5 75 1 49.4 colorless transparent aqueous solution 49.5 colorless transparent aqueous solution 90 S-ASDA- 4Na 2.0 75 1 49.5 Colorless and transparent aqueous solution (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -74-515784

7 7 A B 五、發明説明（72 ) 表5(續) 經濟部中央標準局員工消費合作社印製 49.8 無色透明水溶液 91 S-ASMP-3Na 1.0 75 1 49.8 無色透明水溶液 49.8 無色透明水溶液 92 S-ALDA-3Na 1.0 75 49.8 無色透明水溶液 65.4 淡黃色泥漿 93 S-ASMA-3Na 10.0 65 i 63.7 淡黃色泥漿 65.4 淡黃色泥漿 94 S-ASDA-4Na 10.0 65 1 64.5 I 淡黃色泥漿 65.4 淡黃色泥漿 95 S-ASMP-3Na 10.0 65 65.4 淡黃色泥漿 65.4 淡黃色泥漿 96 S-ALDA-3Na 10.0 65 64.7 I 淡黃色泥漿 78.4 白色泥漿 97 S-ASMA-3Na 2.5 70 76.8 I 白色泥漿 78.7 白色泥漿 98 S-ASDA-4Na 2.0 70 78· 5 白色泥漿 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -75 - 5157847 7 AB V. Description of the invention (72) Table 5 (continued) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 49.8 Colorless transparent aqueous solution 91 S-ASMP-3Na 1.0 75 1 49.8 Colorless transparent aqueous solution 49.8 Colorless transparent aqueous solution 92 S-ALDA -3Na 1.0 75 49.8 colorless transparent aqueous solution 65.4 light yellow mud 93 S-ASMA-3Na 10.0 65 i 63.7 light yellow mud 65.4 light yellow mud 94 S-ASDA-4Na 10.0 65 1 64.5 I light yellow mud 65.4 light yellow mud 95 S- ASMP-3Na 10.0 65 65.4 light yellow mud 65.4 light yellow mud 96 S-ALDA-3Na 10.0 65 64.7 I light yellow mud 78.4 white mud 97 S-ASMA-3Na 2.5 70 76.8 I white mud 78.7 white mud 98 S-ASDA-4Na 2.0 70 78 · 5 White mud This paper is sized for Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -75-515784

A B 五、發明説明（73 ) 表5(續) 經濟部中央標準局員工消費合作社印製 79.4 白色泥漿 99 S-ASMP-3Na 1.0 70 79.4 白色泥漿 36.4 淡黃色透明水溶液 100 TUDA-3Na 25.0 50 1 34.7 淡黃色透明水溶液 37.0 淡黃色透明水溶液 101 MIDA-2Na 20.0 50 1 36.6 淡黃色透明水溶液 37· 8 淡黃色透明水溶液 102 ANTDA-3Na 15.0 50 1 37.8 淡黃色透明水溶液 49.4 無色透明水溶液 103 TUDA-3Na 2.5 75 i 49.4 無色透明水溶液 49.5 無色透明水溶液 104 MIDA-2Na 2.0 75 1 49.5 無色透明水溶液 49.8 無色透明水溶液 105 ANTDA-3Na 1.0 75 49.8 無色透明水溶液 65.4 淡黃色泥漿 106 TUDA-3Na 10.0 65 63.7 淡黃色泥漿 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） —--------裝---- (請先閱讀背面之注意事項再填寫本頁) --riyjϋϋ α mmj I m ί mi —^ϋ nn m i --- -76 - 515784 經濟部中央標準局員工消費合作社印製 五、發明説明（μ ) 表5(續) 107 MIDA-2Na 10.0 65 65.4 1 64.5 淡黃色泥漿 淡黃色泥漿 78.4 白色泥漿 108 TUDA-3Na 2.5 70 76.9 白色泥漿 78.7 白色泥漿 109 MIDA-2Na 2.0 70 1 78.5 白色泥漿 49.5 帶紅色之棕色水溶液 110 ANTDA-Fe 2.0 40 1 49.3 帶紅色之棕色水溶液 39.8 帶紅色之棕色水溶液 111 ANTDA-Fe 1.0 40 39.8 帶紅色之棕色水溶液 (雜質之重量） (雜質之含量）=--XIOOtwt.%] (式[I]之化合物之重量） wt. %:在水溶液中式[I]之化合物之含量 上列:在給定溫度保持60天之前(正好在水溶液製備之後) 下列:在保持60天之後 本紙張尺度適用中國國家標準（CN? ) A4規格（210 X 297公釐） 一 77 - (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 515784 A7 __B7 五、發明説明（75 ) 表6 經濟部中央標準局員工消費合作社印製 比 保持 在給定溫度保持60天前 較 式[I]之化合物 雜質之含 溫度 後之變化# 例 量 wt. 9Γ °C wt. % 外觀 35.1 淡黃色透明水溶液 29 S-ASMA-3Na 35.0 50 1 31.1 棕色水溶液 35.1 淡黃色透明水溶液 30 S-ASDA-4Na 35.0 50 i 31.8 棕色水溶液 33.3 淡黃色透明水溶液 31 S-ASMP-3Na 35.0 50 33.2 棕色水溶液 35.1 淡黃色透明水溶液 32 S-ALDA-3Na 35.0 50 31.8 棕色水溶液 33.3 淡黃色透明水溶液 33 S-ASMA-3Na 50.0 50 1 30.5 棕色泥漿 35.1 淡黃色透明水溶液 34 S-ASMA-4Na 35.0 75 1 30.6 棕色水溶液 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~ 78 - 515784 A7 B7 五、發明説明（76 ) 表6(續） 經濟部中央標準局員工消費合作社印製 51.4 淡黃色透明泥漿 35 S_ASMA-3Na 28.0 60 1 47.3 I 棕色泥漿 51.4 淡黃色透明泥漿 36 S-ASDA-4Na 28.0 60 48.3 棕色泥漿 35.1 淡黃色透明水溶液 37 TUDA-3N 35.0 50 30.4 棕色水溶液 35.1 淡黃色透明水溶液 38 MIDA-2Na 35.0 50 29.9 棕色水溶液 35.1 淡黃色透明水溶液 39 ANTDA-3Na 35.0 50 31.8 棕色水溶液 33.3 淡黃色透明泥漿 40 TUDA-3Na 50.0 5 1 29.5 1 、 棕色泥漿 35.1 淡黃色透明水溶液 41 MIDA-2Na 35.0 75. 29.6 淡黃色透明水溶液 43.8 帶紅色之棕色水溶液 42 ANTDA-Fe 28.0 40 i 40.6 帶黑色之棕色水溶液 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) 裝. 、1Τ -79 - 515784 A7 ____B7 五、發明説明（77 ) 表6 (續） (雜質之重量） (雜質之含量）=------X lOOtwt. %] (式[I]之化合物之重量） ** wt·%:在水溶液中式〔I〕之化合物之含量 上列：在給定溫度保持6 0天之前（正好在水溶液製 備之後） ‘ 下列：在給定溫度保持6 0天之後 例1 1 2 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 在不銹鋼容器中（表面安裝有熱電之加熱器），將包 含1 0 0 0克伸乙基二胺一 N，N > —二琥珀酸四鈉（ EDDS - 4Na)與2 50克雜質鹽（包含1 00克順 一丁烯二酸二鈉，1 〇 〇克反一丁烯二酸二鈉與5 0克伸 乙基二胺單琥珀酸二鈉）之乾燥粉末溶解於1 5 0 〇克水 中而製備具有淡黃色之透明水溶液。將此水溶液保持在 50充60天，然後，藉由11?1^(：分析成份，且同時觀 察溶液之外觀。結果示於表7中。 例1 1 3 除了使用含1000克（S，S) —伸乙基二胺一 n ，一二琥珀酸四鈉（SS — EDDS — 4Na)與 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一" -80 - 經濟部中央標準局員工消費合作社印製 515784 A7 B7 五、發明説明（78 ) 2 0 0克雜質鹽（包含40克（S) —天冬胺酸二鈉， 40克（S) — N —（2-氯乙基）一天冬胺酸二鈉， 40克（S) — N — (2 -羥乙基）一天冬胺酸二鈉， 40克（S，S) _N -（2 —羥乙基）一伸乙基二胺一 N，N > —二琥珀酸四鈉及4 0克反一 丁烯二酸二鈉）之 外，如例1 1 2之相同方法進行實驗。結果示於表7中。 例1 1 4 除了使用包含1 000克1 ，3 —丙烷二胺一 N， N — —二琥珀酸四鈉（PDDS — 4Na)與250克雜 質鹽（包含100克順一丁烯二酸二鈉，100克反一丁 烯二酸二鈉及5 0克伸乙基二胺單琥珀酸二鈉）之乾燥粉 末之外，以如例1 1 2之相同方法進行實驗。結果示於表 7中。 例1 1 5 除了使用含1000克（S，S) — 1，3 —丙烷二 胺一 N，N — 二琥珀酸四鈉（SS — PDDS — 4Na) 與200克雜質鹽（包含40克（S) —天冬胺酸二鈉， 40克（S) — N — (2 -氯丙基）一天冬胺酸二鈉， 40克（S) - 2 -羥丙基天冬胺酸二鈉，40克（s， S) — N- (2 -羥丙基）一 1，3 —丙烷二胺一 N， N / —二琥珀酸四鈉與4 0克反一 丁烯二酸二鈉）之外， 如例1 1 2之相同方法進行實驗。結果示於表7中。 本紙張尺度適用中國國家標準（CNS )八4規格（210X297公釐) ' ' ' ~ 81 - (請先閱讀背面之注意事項再填寫本頁) 、11 515784 A7 _B7 _ 五、發明説明（79 ) 例1 1 6 除了使用1000克（s，S) -2 —羥基一 1 , 3 一丙烷二胺一 N，N —二琥珀酸四鈉（SS — PDDS — OH — 4Na)與15 0克雜質鹽（包含50克（S)— 天冬胺酸二鈉，50克（S) — N —（1 ，2 —二羥基丙 基）一天冬胺酸二鈉及5 0克反一 丁烯二酸二鈉）之外， 以如例1 1 2之相同方法進行實驗。結果示於表7中。 例1 1 7 除了雜質鹽之含量爲1 · 0%，在水溶液中式〔i〕 之化合物之含量爲4 9 · 8%，且將水溶液保持在7 5 °C 之外，使用相同之式〔1〕化合物以如例1 1 2之相同方 法進行實驗。結果示於表7中。 例1 1 8 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 除了雜質鹽之含量爲1 0 · 0%，在泥漿溶液中式〔 1〕之化合物之含量爲6 5 · 4%，且將溶液保持在6 5 °C之外，使用相同之式〔1〕化合物，以如例1 1 3之相 同方法進行實驗。結果示於表7中。 例1 1 9 除了雜質鹽之含量爲1 0 · 0%，在泥漿溶液中式〔 1〕之化合物之含量爲6 5 . 4%，且將溶液保持在6 5 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) 一 82 - 515784 A7 ____ B7 五、發明説明（80 ) °C之外，使用相同之式〔1〕化合物，以如例1 1 4之相 同方法進行實驗。結果示於表7中。 例1 2 0 除了雜質鹽之含量爲2 · 5%，在泥漿溶液中式〔1 〕之化合物之含量爲78 · 4%，且將溶液保持在70 °C 之外，使用相同之式〔1〕化合物，以如例1 1 5之相同 方法進行實驗。結果示於表7中。 例1 2 1 除了雜質鹽之含量爲2 . 0%，在泥漿溶液中式〔1 〕之化合物之含量爲78 · 7%，且將溶液保持在70 °C 之外，使用相同之式〔1〕化合物，以如例1 1 6之相同 方法進行實驗。結果示於表7中。 (請先閲讀背面之注意事項再填寫本頁) 2 2 1 例 經濟部中央標準局員工消費合作社印製 式 4 中在 液持 溶保 水液 在溶 ， 將 %且 ο ， • % ο 1 1 · 爲 4 量 7 含爲 之量 鹽含 質之 雜物 了 合 除化 之 同 相 之 2 is 1 例 如 以 物。 合中 化 7 3表 1 於 C 示 式果 之結 同 。 相驗 用實 使行 ， 進 外法 之方 3 2 1 例 式 4 中在 液持 溶保 漿液 泥溶 在將 ’aTj% ， ο % • IX ο · 1 4 爲 7 量爲 含量 之含 鹽之 質物 雜合 了化 除之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 83 - 經濟部中央標準局員工消費合作社印製 515784 A7 __B7_ 五、發明説明（81 ) °C之外，使用相同之式〔1〕化合物，以如例1 1 4之相 同方法進行實驗。結果示於表7中。 例1 2 4 在不銹鋼容器中（表面安裝有熱電之加熱器），將包 含1 0 0 0克伸乙基二胺一 N，N / —二琥珀酸銅二鈉（ EDDS - C-2Na)與250克雜質鹽（包含100 克順一 丁烯二酸二鈉，1 0 0克反一丁烯二酸二鈉及5 0 克伸乙基二胺單琥珀酸二鈉）之乾燥粉末溶解於1 5 0 0 克水中而製備具有淡黃色之透明水溶液。將此水溶液保持 在5 0°C6 0天，然後，藉由HPLC分析成份，且同時 觀察溶液之外觀。結果示於表7中。 例1 2 5 除了使用1000克（S，S) —伸乙基二胺一 N， N / - 二琥珀酸鐵銨（S S — EDDS - F e— NH4) 與200克雜質鹽（包含40克（S) -天冬胺酸二銨， 40克（S) — N -（2 —氯乙基）一天冬胺酸二銨， 40克（S) - N— (2 —羥乙基）一天冬胺酸二銨， 4 0克（S，S) — N —（2 —經乙基）一伸乙基二胺一 N，—二琥珀酸四鈉及40克反一 丁烯二酸二銨）之 外，以如例1 1 2之相同方法進行實驗。結果示於表7中 〇 本紙張尺度適用中國國家標準（CNS ) M規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· •氬 -84 - 515784 A7 _B7_ 五、發明説明（82 ) 例1 2 6 除了使用包含1 000克1 ，3 -丙烷二胺一 N， -二琥珀酸銅二鈉（PDDS - Cu — 2Na)與 2 5 0克雜質鹽（包含1 〇 〇克順一丁烯二酸二鈉’ 1 0 0克反一丁烯二酸二鈉及5 0克伸乙基二胺單號拍酸 二鈉）之乾燥粉末之外，以如例1 1 2之相同方法進行實 驗。結果示於表7中。 例1 2 7 除了使用含1000克（S，S) —1 ，3 —丙烷二 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 胺一 N，一二琥珀酸鎳二鈉（SS - PDDS — N i 一 2Na)與200克雜質鹽（包含40克（S) —天冬 胺酸二鈉，40克（S) —N -（2 -氯丙基）一天冬胺 酸二鈉，40克（S) — 2 -羥丙基天冬胺酸二鈉，40 克（S，S) - N— (2—羥丙基）一 1，3 —丙烷二胺 一 N，N > —二琥珀酸四鈉與4 0克反一 丁烯二酸二鈉） 之外，以如例1 1 2之相同方法進行實驗。結果示於表7 中〇 例1 2 8 除了使用1000克（S，S) -2 —羥基—1 ，3 一丙烷二胺一 N，N —二琥珀酸銅二鈉（S S — PDDS 一 Cu — 2Na)與1 50克雜質鹽（包含50克（S) —天冬胺酸二鈉，50克（S) - N -（1，2 -二羥基 本紙張尺度適用中國國家標準（CNS ) A4規格（210'〆297公釐) -85 - 515784 A7 B7 五、發明説明（83 ) 丙基）一天冬胺酸二鈉及5 〇克反一 丁烯二酸二鈉）之外 ，以如例112之相同方法進行實驗。結果示於表7中。 比較例4 3 除了雜質鹽之含量爲3 0 · 〇%，在水溶液中式〔工 〕之化合物之含量爲35 · 7%，且將水溶液保持在5〇 。(：之外，使用相同之式〔1〕化合物，以如例1 1 2之相 同方法進行實驗。結果不於表8中。 比較例4 4 除了雜質鹽之含量爲30·〇%，在水溶液中式〔1 〕之化合物之含量爲35 · 7%，且將水溶液保持在50 °C之外，使用相同之式〔1〕化合物，以如例1 1 3之相 同方法進行實驗。結果示於表8中。 比較例4 5 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 除了雜質鹽之含量爲50·〇%，在水溶液中式〔1 〕之化合物之含量爲3 3 · 3%，且將水溶液保持在5 0 °C之外，使用相同之式〔1〕化合物，以如例1 1 4之相 同方法進行實驗。結果示於表8中。 比較例4 6 除了雜質鹽之含量爲40 · 0%，在水溶液中式〔1 〕之化合物之含量爲41 · 6%，且將水溶液保持在75 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 一 86 一 515784 A7 __B7 五、發明説明（84 ) 。(：之外，使用相同之式〔1〕化合物，以如例1 1 5之相 同方法進行實驗。結果示於表8中。 比較例4 7 除了雜質鹽之含量爲30·0%，在水溶液中式〔1 〕之化合物之含量爲4 3 · 5%，且將水溶液保持在7 5 °C之外，使用相同之式〔1〕化合物，以如例1 1 6之相 同方法進行實驗。結果示於表8中。 比較例4 8 除了雜質鹽之含量爲30·0%，在水溶液中式〔1 〕之化合物之含量爲35·7%，且將水溶液保持在50 °C之外，使用相同之式〔1〕化合物以如例1 2 4中之相 同方法進行實驗。結果示於表8中。 比較例4 9 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 除了雜質鹽之含量爲30·0%，在水溶液中式〔1 〕之化合物之含量爲3 5 · 7%，且將水溶液保持在5 0 °C之外，使用相同之式〔1〕化合物，以如例1 2 5之相 同方法進行實驗。結果示於表8中。 比較例5 0 除了雜質鹽之含量爲30 · 0%，在水溶液中式〔1 〕之化合物之含量爲3 5 · 7%，且將水溶液保持在5 0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 87 - 515784 A7 —__ — B7 _ 五、發明説明（85 ) °C之外，使用相同之式〔1〕化合物，以如例i 2 6之相 同方法進行實驗。結果示於表8中。 (請先閱讀背面之注意事項再填寫本頁) 比較例5 1 除了雜質鹽之含量爲3 〇 · 〇%，在水溶液中式〔工 〕之化合物之含量爲43 · 5%，且將水溶液保持在75 °C之外，使用相同之式〔1〕化合物，以如例1 2 7之相 同方法進行實驗。結果示於表8中。 比較例5 2 除了雜質鹽之含量爲30·〇%，在水溶液中式〔1 〕之化合物之含量爲43 . 5%，且將水溶液保持在75 °C之外，使用相同之式〔1〕化合物，以如例1 2 8之相 同方法進行實驗。結果示於表8中。 從這些實例中下 述變成明顯的：當雜質係以大量存在於關於式〔1〕化合 物之水溶液或泥漿中時，由於在儲放期間式〔1〕化合物 進行分解，純度與著色退化。 經濟部中央標準局員工消費合作社印製 根據本發明曾相當困難地以固體形式處理之式〔1〕 之化合物藉由降低共存之雜質鹽之含量及沈澱適當之水量 或保持水溶液或泥漿之適當溫度，可以以水溶液或泥漿之 形式安定化儲存或處理一段長時間而不會有因成份之分解 所致之純度或著色退化。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -88 - 515784AB 5. Description of the invention (73) Table 5 (continued) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 79.4 White mud 99 S-ASMP-3Na 1.0 70 79.4 White mud 36.4 Light yellow transparent aqueous solution 100 TUDA-3Na 25.0 50 1 34.7 Light yellow transparent aqueous solution 37.0 Light yellow transparent aqueous solution 101 MIDA-2Na 20.0 50 1 36.6 Light yellow transparent aqueous solution 37 · 8 Light yellow transparent aqueous solution 102 ANTDA-3Na 15.0 50 1 37.8 Light yellow transparent aqueous solution 49.4 Colorless transparent aqueous solution 103 TUDA-3Na 2.5 75 i 49.4 Colorless and transparent aqueous solution 49.5 Colorless and transparent aqueous solution 104 MIDA-2Na 2.0 75 1 49.5 Colorless and transparent aqueous solution 49.8 Colorless and transparent aqueous solution 105 ANTDA-3Na 1.0 75 49.8 Colorless and transparent aqueous solution 65.4 Pale yellow mud 106 TUDA-3Na 10.0 65 63.7 Pale yellow mud The dimensions are applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) —-------- installation— (Please read the precautions on the back before filling this page) --riyjϋϋ α mmj I m ί mi — ^ ϋ nn mi --- -76-515784 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Description of the invention (μ) Table 5 (continued) 107 MIDA-2Na 10.0 65 65.4 1 64.5 light yellow mud light yellow mud 78.4 white mud 108 TUDA-3Na 2.5 70 76.9 white mud 78.7 white mud 109 MIDA-2Na 2.0 70 1 78.5 white Mud 49.5 Reddish brown aqueous solution 110 ANTDA-Fe 2.0 40 1 49.3 Reddish brown aqueous solution 39.8 Reddish brown aqueous solution 111 ANTDA-Fe 1.0 40 39.8 Reddish brown aqueous solution (weight of impurities) (content of impurities) =- -XIOOtwt.%] (Weight of the compound of the formula [I]) wt.%: The content of the compound of the formula [I] in the aqueous solution is listed above: before being held at a given temperature for 60 days (just after the preparation of the aqueous solution) the following: After keeping it for 60 days, the paper size applies the Chinese National Standard (CN?) A4 specification (210 X 297 mm). 77-(Please read the precautions on the back before filling this page.) Binding and binding 515784 A7 __B7 V. Description of invention (75) Table 6 The content of impurities in the compound of formula [I] compared with the compound of formula [I] printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs at a given temperature for 60 days After the change # Example amount wt. 9Γ ° C wt.% Appearance 35.1 light yellow transparent aqueous solution 29 S-ASMA-3Na 35.0 50 1 31.1 brown aqueous solution 35.1 light yellow transparent aqueous solution 30 S-ASDA-4Na 35.0 50 i 31.8 brown aqueous solution 33.3 light yellow transparent aqueous solution 31 S-ASMP-3Na 35.0 50 33.2 brown aqueous solution 35.1 light yellow transparent aqueous solution 32 S-ALDA-3Na 35.0 50 31.8 brown aqueous solution 33.3 light yellow transparent aqueous solution 33 S-ASMA-3Na 50.0 50 1 30.5 brown mud 35.1 Light yellow transparent aqueous solution 34 S-ASMA-4Na 35.0 75 1 30.6 Brown aqueous solution (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) ~ 78-515784 A7 B7 V. Description of invention (76) Table 6 (continued) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 51.4 Light yellow transparent mud 35 S_ASMA-3Na 28.0 60 1 47.3 I Brown mud 51.4 Light yellow transparent mud 36 S-ASDA- 4Na 28.0 60 48.3 Brown mud 35.1 Light yellow transparent water solution 37 TUDA-3N 35.0 50 30.4 Brown water solution 35.1 light yellow transparent aqueous solution 38 MIDA-2Na 35.0 50 29.9 brown aqueous solution 35.1 light yellow transparent aqueous solution 39 ANTDA-3Na 35.0 50 31.8 brown aqueous solution 33.3 light yellow transparent slurry 40 TUDA-3Na 50.0 5 1 29.5 1 、 brown mud 35.1 light yellow transparent aqueous solution 41 MIDA-2Na 35.0 75. 29.6 Light yellow transparent aqueous solution 43.8 Brown aqueous solution with red color 42 ANTDA-Fe 28.0 40 i 40.6 Brown aqueous solution with black color This paper applies Chinese national standard (CNS) A4 specification (210X297 mm) (Please Read the precautions on the back before filling in this page.) Packing, 1T -79-515784 A7 ____B7 V. Description of the invention (77) Table 6 (continued) (weight of impurities) (content of impurities) = ------ X lOOtwt.%] (Weight of compound of formula [I]) ** wt ·%: listed in the content of compound of formula [I] in aqueous solution: before holding at a given temperature for 60 days (just after the preparation of the aqueous solution) 'The following: Example 1 after holding at a given temperature for 60 days Example 1 2 2 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) A stainless steel container (with a thermoelectric heater installed on the surface) will contain 1000 grams of ethylenediamine-N, N >-tetrasodium disuccinate (EDDS-4Na) and 2 50 grams of impurity salts (including 1 00 g of disodium maleate, 100 g of disodium maleate and 50 g of disodium ethylenediamine monosuccinate) were dissolved in 1 500 g of water to prepare a dry powder. Light yellow transparent aqueous solution. This aqueous solution was kept at 50 for 60 days, and then the composition was analyzed by 11? 1 ^ (: and the appearance of the solution was observed at the same time. The results are shown in Table 7. Example 1 1 3 In addition to using 1000 g (S, S ) —Ethylenediamine-n, tetrasodium disuccinate (SS — EDDS — 4Na) and this paper size are applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm)-" -80-Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Standards Bureau 515784 A7 B7 V. Description of the invention (78) 200 grams of impurity salt (including 40 grams (S)-disodium aspartate, 40 grams (S)-N-(2-chloro Ethyl) disodium aspartate, 40 g (S) — N — (2-hydroxyethyl) disodium aspartate, 40 g (S, S) —N-(2-hydroxyethyl) monoethene The experiment was carried out in the same manner as in Example 1 12 except for tetramethylene diamine-N, N >-tetrasodium disuccinate and 40 g of disodium fumarate. The results are shown in Table 7. Examples 1 1 4 In addition to using 1,000 grams of 1,3-propanediamine-N, N-tetrasodium disuccinate (PDDS-4Na) and 250 grams of impurity salts (including 100 grams of disodium maleate, 100 Gram The experiment was performed in the same manner as in Example 1 12 except for the dry powder of disodium monobutyrate and 50 g of disodium ethylenediamine monosuccinate). The results are shown in Table 7. Example 1 1 5 In addition to using 1000 grams (S, S) — 1,3-propanediamine-N, N — tetrasodium disuccinate (SS — PDDS — 4Na) and 200 grams of impurity salts (including 40 grams (S) — Asparagus Disodium amino acid, 40 g (S) — N — (2-chloropropyl) disodium aspartate, 40 g (S)-2-hydroxypropyl aspartate, 40 g (s, S) —N- (2-hydroxypropyl) -1,3-propanediamine-N, N / —tetrasodium disuccinate and 40 g of disodium succinate) as in Example 1 Experiments were performed in the same way as in 12. The results are shown in Table 7. This paper size is in accordance with China National Standard (CNS) 8-4 specifications (210X297 mm) '' '~ 81-(Please read the precautions on the back before filling out this Page), 11 515784 A7 _B7 _ V. Description of the invention (79) Example 1 1 6 In addition to using 1000 g (s, S) -2 -hydroxy-1,3-propanediamine-N, N-tetrasodium disuccinate (SS — PDDS — OH — 4Na) and 150 grams Quality salt (containing 50 g (S) -disodium aspartate, 50 g (S) -N- (1,2-dihydroxypropyl) disodium aspartate and 50 g of trans-butene di Except for disodium acid), the experiment was performed in the same manner as in Example 11.2. The results are shown in Table 7. Example 1 1 7 Except that the content of the impurity salt is 1.0%, the content of the compound of formula [i] in the aqueous solution is 4 9 · 8%, and the aqueous solution is kept at 7 5 ° C, the same formula [1] is used The compound was tested in the same manner as in Example 11.2. The results are shown in Table 7. Example 1 1 8 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Except for the content of impurity salt is 10 · 0%, the content of the compound of formula [1] in the mud solution The experiment was carried out in the same manner as in Example 1 13 using the same compound of the formula [1] while keeping the solution at 65. 4% and maintaining the temperature outside 65 ° C. The results are shown in Table 7. Example 1 1 In addition to the content of impurity salts being 10 · 0%, the content of the compound of formula [1] in the mud solution is 65.4%, and the solution is kept at 65. This paper size applies to Chinese national standards (CNS ) A4 specification (210X297 mm)-82-515784 A7 ____ B7 V. Explanation of invention (80) ° C, using the same compound of formula [1], the experiment was carried out in the same manner as in Example 11 14. The results are shown in Table 7. Example 1 2 0 The same formula [1] was used except that the content of the impurity salt was 2.5%, the content of the compound of formula [1] in the mud solution was 78.4%, and the solution was kept at 70 ° C. The compounds were tested in the same manner as in Example 115. The results are shown in Table 7. Example 1 2 1 The same formula [1] was used except that the content of the impurity salt was 2.0%, the content of the compound of formula [1] in the mud solution was 78.7%, and the solution was kept at 70 ° C. The compounds were tested in the same manner as in Example 116. The results are shown in Table 7. (Please read the precautions on the back before filling out this page) 2 2 1 Example Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs in the printed formula 4 For the amount of 4 the amount of 7 is the amount of salt and the quality of the impurities is the same phase 2 is 1 for example. The results in Table 1 are the same as those shown in C. The test is carried out by practical methods. In the foreign method 3 2 1 Example 4 In the liquid holding solution, the slurry is dissolved in 'aTj%, ο% • IX ο · 1 4 is 7 The quality of the paper is based on the Chinese paper standard (CNS) A4 (210X297 mm). 83-Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 515784 A7 __B7_ V. Description of the invention (81) ° C In addition, using the same compound of the formula [1], an experiment was carried out in the same manner as in Example 114. The results are shown in Table 7. Example 1 2 4 In a stainless steel container (surface mounted with a thermoelectric heater), it will contain 1 000 g of ethylenediamine-N, N / -disodium disuccinate (EDDS-C-2Na) and 250 A dry powder of 100 g of impurity salt (containing 100 g of disodium maleate, 100 g of disodium maleate and 50 g of disodium ethylenediamine monosuccinate) was dissolved in 1 500 A pale yellow transparent aqueous solution was prepared in water. This aqueous solution was kept at 50 ° C for 60 days. Then, the components were analyzed by HPLC, and at the same time the appearance of the solution was observed. The results are shown in Table 7. Example 1 2 5 In addition to using 1000 g (S, S) -ethylenediamine-N, N /-ferric ammonium disuccinate (SS — EDDS-F e — NH4) and 200 g of impurity salt (including 40 g ( S)-Diammonium aspartate, 40 g (S)-N-(2-chloroethyl) diammonium aspartate, 40 g (S)-N-(2-hydroxyethyl) aspartate Diammonium acid, other than 40 g (S, S) — N — (2 —Ethyl) -ethylidene diamine—N, —Tetrasodium disuccinate and 40 g of diammonium dibutyrate Experiments were performed in the same manner as in Example 11.2. The results are shown in Table 7. This paper size is in accordance with Chinese National Standard (CNS) M specification (210X297 mm) (Please read the precautions on the back before filling out this page). Installation · • Argon-84-515784 A7 _B7_ V. Invention Explanation (82) Example 1 2 6 In addition to using 1,000 grams of 1,3-propanediamine mono-N,-copper disuccinate disodium (PDDS-Cu — 2Na) and 250 grams of impurity salts (including 100%) Grams of disodium maleic acid disodium '100 grams of disodium maleic acid and 50 grams of sodium diethylenediamine monosodium phthalate) dry powder, the same as in Example 1 12 Methods for experiments. The results are shown in Table 7. Example 1 2 7 In addition to using 1000 grams (S, S) — 1, 3 — propane di printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) Amine N, One Two Disodium nickel succinate (SS-PDDS — Ni-2Na) and 200 g of impurity salt (including 40 g (S)-disodium aspartate, 40 g (S) —N-(2-chloropropyl) Disodium aspartate, 40 g (S) — 2-Hydroxypropylaspartate, 40 g (S, S)-N — (2-Hydroxypropyl) -1,3-propanediamine Except for -N, N >-tetrasodium disuccinate and 40 g of disodium succinate), experiments were carried out in the same manner as in Example 1 12. The results are shown in Table 7. Example 1 2 8 In addition to using 1000 g (S, S) -2 -hydroxy-1,3 -propanediamine -N, N -disodium copper disuccinate (SS-PDDS -Cu- 2Na) and 150 grams of impurity salts (including 50 grams (S) — disodium aspartate, 50 grams (S)-N-(1,2-dihydroxy) This paper is in accordance with China National Standard (CNS) A4 specifications (210'〆297 mm) -85-515784 A7 B7 V. Description of the invention (83) Propyl) Disodium aspartate and 50 g of disodium butenedioate), for example 112 Experiment in the same way. The results are shown in Table 7. Comparative Example 4 3 In addition to the content of the impurity salt being 30.0%, the content of the compound of the formula [engineering] in the aqueous solution was 35.7%, and the aqueous solution was kept at 50%. (: Except, using the same compound of the formula [1], the experiment was performed in the same manner as in Example 1 12. The results are not shown in Table 8. Comparative Example 4 4 Except for the impurity salt content of 30.0%, in an aqueous solution The content of the compound of the formula [1] was 35.7%, and the aqueous solution was kept outside 50 ° C. Using the same compound of the formula [1], the experiment was performed in the same manner as in Example 1 13. The results are shown in the table. 8. Comparative Example 4 5 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Except for the content of impurity salt of 50%, the compound of formula [1] in aqueous solution. The content was 3 3 · 3%, and the aqueous solution was kept outside 50 ° C. The experiment was performed in the same manner as in Example 1 14 using the same compound of formula [1]. The results are shown in Table 8. Comparative Examples 4 6 Except for the impurity salt content of 40 · 0%, the content of the compound of formula [1] in the aqueous solution is 41 · 6%, and the aqueous solution is maintained at 75. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 Mm) 86 86515 784 A7 __B7 V. Description of the invention (84 ). (: Except using the same compound of the formula [1], the experiment was performed in the same manner as in Example 1 15. The results are shown in Table 8. Comparative Example 4 7 Except for the impurity salt content of 30.0%, The content of the compound of the formula [1] in the aqueous solution was 43.5%, and the aqueous solution was kept outside 7 5 ° C. The experiment was performed in the same manner as in Example 1 16 using the same compound of the formula [1]. The results are shown in Table 8. Comparative Example 4 8 Except that the content of the impurity salt was 30 · 0%, the content of the compound of formula [1] in the aqueous solution was 35.7%, and the aqueous solution was kept at 50 ° C and used. The compound of the same formula [1] was tested in the same manner as in Example 1 2 4. The results are shown in Table 8. Comparative Example 4 9 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back first) (Fill in this page), except that the content of impurity salt is 30 · 0%, the content of the compound of formula [1] in the aqueous solution is 3 5 · 7%, and the aqueous solution is kept at 50 ° C, the same formula [1 The compound was tested in the same manner as in Example 1 2. The results are shown in Table 8. Comparative Examples The content of the compound of formula [1] in the aqueous solution is 35.0.7%, and the content of the compound in formula [1] in the aqueous solution is 30. 0%, and the aqueous solution is maintained at 50. This paper size applies the Chinese National Standard (CNS) A4 specification ( 210X297 mm) 87-515784 A7 —__ — B7 _ 5. Except for (85) ° C, using the same compound of formula [1], the experiment was performed in the same manner as in Example i 2 6. The results are shown in Table 8. (Please read the precautions on the reverse side before filling out this page) Comparative Example 5 1 Except for the content of impurity salt is 3 〇 ％, the content of the compound of formula [engineering] in the aqueous solution is 43.5%, and the aqueous solution is kept at Experiments were performed in the same manner as in Example 1 2 7 except that the compound of the formula [1] was used at 75 ° C. The results are shown in Table 8. Comparative Example 5 2 A compound of the same formula [1] was used except that the content of the impurity salt was 30.0%, the content of the compound of the formula [1] in the aqueous solution was 43.5%, and the aqueous solution was kept at 75 ° C. Experiments were performed in the same manner as in Example 1 28. The results are shown in Table 8. It becomes apparent from these examples that when impurities are present in a large amount in an aqueous solution or a slurry of the compound of the formula [1], since the compound of the formula [1] is decomposed during storage, purity and coloring are degraded. The Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed the compound of formula [1] which had been treated in a solid form according to the present invention with considerable difficulty by reducing the content of coexisting impurity salts and the appropriate amount of water in Shendian or maintaining the proper temperature of the aqueous solution or slurry It can be stably stored or processed in the form of aqueous solution or mud for a long time without degradation of purity or coloring caused by the decomposition of the ingredients. This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -88-515784

A B 經濟部中央標準局員工消費合作社印製 五、發明説明（86 ) 表7 例 式[I]之化合物 雜質之含 量 wt· 保持 溫度 °C 在給定溫度保持60天 前與後之變化# wt. % 外觀 36.4 淡黃色透明之水溶液 112 EDDS-4Na 25.0 50 36.4 淡黃色透明之水溶液 37.0 淡黃色透明之水溶液 113 SS-EDDS-4Na 20.0 50 1 35.6 淡黃色透明之水溶液 36.4 淡黃色透明之水溶液 114 PDDS-4Na 25.0 50 36.4 淡黃色透明之水溶液 45.4 無色透明水溶液 115 SS-PDDS-4Na 20.0 75 1 44.3 無色透明水溶液 46.5 無色透明水溶液 116 SS-0PDDS-4Na 15.0 75 44.7 無色透明水溶液 49.8 無色透明水溶液 117 EDDS-4Na 1.0 75 49.8 無色透明水溶液 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 一 89 - 515784Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (86) Table 7 Contents of impurities in the compound of formula [I] wt. Keeping temperature ° C Change before and after keeping at a given temperature for 60 days # wt % Appearance 36.4 light yellow transparent aqueous solution 112 EDDS-4Na 25.0 50 36.4 light yellow transparent aqueous solution 37.0 light yellow transparent aqueous solution 113 SS-EDDS-4Na 20.0 50 1 35.6 light yellow transparent aqueous solution 36.4 light yellow transparent aqueous solution 114 PDDS -4Na 25.0 50 36.4 light yellow transparent aqueous solution 45.4 colorless transparent aqueous solution 115 SS-PDDS-4Na 20.0 75 1 44.3 colorless transparent aqueous solution 46.5 colorless transparent aqueous solution 116 SS-0PDDS-4Na 15.0 75 44.7 colorless transparent aqueous solution 49.8 colorless transparent aqueous solution 117 EDDS- 4Na 1.0 75 49.8 Colorless transparent aqueous solution The paper size is applicable to Chinese National Standard (CNS) A4 (210X 297 mm) (Please read the precautions on the back before filling this page)-89-515784

AA

7 B 五、發明説明（87 ) 表7(續) 經濟部中央標準局員工消費合作社印製 65.4 淡黃色泥漿 118 SS-EDDS-4Na 10.0 65 65.4 淡黃色泥漿 65.4 淡黃色泥漿 119 PDDS-4Na 10.0 65 i 65.4 淡黃色泥漿 78.4 白色泥漿 120 SS-PDDS-4Na 2.5 70 78.4 白色泥漿 78.7 白色泥漿 121 SS-0PDDS-4Na 2.0 70 78.7 白色泥漿 74.1 白色泥漿 122 EDDS-4Na 10.0 40 I 74.1 白色泥漿 74.1 白色泥漿 123 PDDS-4Na 10.0 40 1 74.1 白色泥漿 36.4 深藍色透明水溶液 124 EDDS-Cu-2Na 25.0 50 36.3 深藍色透明水溶液 37.0 帶紅色之棕色水溶液 125 SS-EDDS-Fe-NH4 20.0 50 36.5 帶紅色之棕色水溶液 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -90 - 515784 A7 __B7五、發明説明（88 ) 表7(續） 36.4 深藍色透明水溶液 126 PDDS-Cu-2Na 25.0 50 36.4 深藍色透明水溶液 45.4 藍色透明水溶液 127 SS-PDDS-Ni-2Na 20.0 75 44.0 藍色透明水溶液 49· 4 深藍色透明水溶液 128 SS-PDDS-OH-Cu- 15.0 75 2Na 47.9 深藍色透明水溶液 抑衣----- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 (雜質之重量） (雜質之含量)=-X100[wt.%] (式[I]之化合物之重量） wt. %:在水溶液中式[I ]之化合物之含量 上列:在給定溫度保持60天之前(正好在水溶液製備之後) 下列:在給定溫度保持60天之後 π— —II、一^J1 I I I ---1 - I I— I-- ----- 二 --1h - 1 L 1117 B V. Description of the invention (87) Table 7 (continued) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 65.4 Light yellow mud 118 SS-EDDS-4Na 10.0 65 65.4 Light yellow mud 65.4 Light yellow mud 119 PDDS-4Na 10.0 65 i 65.4 Light Yellow Mud 78.4 White Mud 120 SS-PDDS-4Na 2.5 70 78.4 White Mud 78.7 White Mud 121 SS-0PDDS-4Na 2.0 70 78.7 White Mud 74.1 White Mud 122 EDDS-4Na 10.0 40 I 74.1 White Mud 74.1 White Mud 123 PDDS-4Na 10.0 40 1 74.1 White mud 36.4 Dark blue transparent aqueous solution 124 EDDS-Cu-2Na 25.0 50 36.3 Dark blue transparent aqueous solution 37.0 Reddish brown aqueous solution 125 SS-EDDS-Fe-NH4 20.0 50 36.5 Reddish brown aqueous solution Paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the notes on the back before filling out this page) -90-515784 A7 __B7 V. Description of the invention (88) Table 7 (continued) 36.4 Dark blue Color transparent aqueous solution 126 PDDS-Cu-2Na 25.0 50 36.4 Dark blue transparent aqueous solution 45.4 Blue transparent aqueous solution 1 27 SS-PDDS-Ni-2Na 20.0 75 44.0 Blue transparent aqueous solution 49 · 4 Dark blue transparent aqueous solution 128 SS-PDDS-OH-Cu- 15.0 75 2Na 47.9 Dark blue transparent aqueous solution ----- (Please read first Note on the back, please fill in this page again.) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (Weight of impurities) (Content of impurities) =-X100 [wt.%] (Weight of compound of formula [I]) wt.% : The content of the compound of formula [I] in the aqueous solution is listed above: before the given temperature is kept for 60 days (just after the aqueous solution is prepared) the following: after the given temperature is kept for 60 days π-II, ^ J1 III- -1-II— I-- ----- II--1h-1 L 111

Jm 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -91 - 515784 A7 ___B7 五、發明説明（89 ) 表8 經濟部中央標準局員工消費合作社印製 比 較 例 式[I]之化合物 雜質之含 量wt· 保持 溫度 °c 在給定溫度保持60天 前後之變化# wt. % 外觀 35.7 淡黃色透明水溶液 43 EDDS-4Na 30.0 50 35.7 淡黃色透明水溶液 35.7 淡黃色透明水溶液 44 SS-EDDS-4Na 30.0 50 1 34.4 淡黃色透明水溶液 33.3 淡黃色透明水溶液 45 PDDS-4Na 50.0 50 33.3 淡黃色透明水溶液 41.6 無色透明水溶液 46 SS-PDDS_4Na 40.0 75 40.7 無色透明水溶液 43.5 無色透明水溶液 47 SS-PDDS-OH- 30.0 75 4Na 41.8 無色透明水溶液 35.7 深藍色透明水溶液 48 EDDS-Cu-2Na 30.0 50 31.4 深藍色透明水溶液 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 一 92 - 515784Jm This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) -91-515784 A7 ___B7 V. Description of Invention (89) Table 8 Comparative Example [I] printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Content of compound impurities wt. Holding temperature ° c Change before and after holding at a given temperature for 60 days # wt.% Appearance 35.7 light yellow transparent aqueous solution 43 EDDS-4Na 30.0 50 35.7 light yellow transparent aqueous solution 35.7 light yellow transparent aqueous solution 44 SS-EDDS -4Na 30.0 50 1 34.4 light yellow transparent aqueous solution 33.3 light yellow transparent aqueous solution 45 PDDS-4Na 50.0 50 33.3 light yellow transparent aqueous solution 41.6 colorless transparent aqueous solution 46 SS-PDDS_4Na 40.0 75 40.7 colorless transparent aqueous solution 43.5 colorless transparent aqueous solution 47 SS-PDDS-OH -30.0 75 4Na 41.8 colorless transparent aqueous solution 35.7 dark blue transparent aqueous solution 48 EDDS-Cu-2Na 30.0 50 31.4 dark blue transparent aqueous solution This paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the note on the back first Matters refill this page ) A 92-515784

7 B 五、發明説明（9〇 ) 表8(續) 經濟部中央標準局員工消費合作社印製 35.7 帶紅色之棕色水溶液 49 SS - EDDS-Fe - 顺4 30.0 50 29.9 帶黑色之棕色水溶液 35.7 深藍色透明水溶液 50 PDDS-Cu-2Na 30.0 50 1 32.2 深藍色透明水溶液 43.5 藍色透明水溶液 51 SS-PDDS-Ni_2Na 30.0 75 38.4 藍色透明水溶液 43.5 深藍色透明水溶液 52 SS-PDDS-OH-Cu- 2Na 30.0 75 1 38.7 深藍色透明水溶液 (雜質之重量） (雜質之含量)=-X100[wt.%] (式[I]之化合物之重量） wt. %:在水溶液中式[I ]之化合物之含量 上列·.在給定溫度保持60天之前(正好在水溶液製備之後) 下列:在給定溫度保持60天之後 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· • ΙΓ· I ...Γ -93 - 515784 A7 B7 五、發明説明（91 ) 〔清潔劑組成物〕 清淨力之測量方法 1 )人造土之製備 使用主要由高嶺石，蛭石或在2 0 0°C乾燥3 0小時 結晶物質之類似物所組成之泥土做爲無機土。 將3 · 5克凝膠溶解於950cc約40°C之水中， 然後藉由乳化作用分散機將0 · 2 5克碳黑分散於水中。 然後，添加14 · 9克無機土並乳化之，而且，添加 3 1 · 3 5克有機土至其中並乳化及分散而製備安定之土 浴。將1 0公分X20公分之乾淨布（棉布#6 0，由日 本石油化學協會（Japan Oil Chemical Society)命名） 浸於土浴中，從那時以後，藉由以橡膠製成之雙橡膠滾筒 壓擠而移除水，將所附著之土暈均勻化，接著以布之兩邊 各擦拭2 5次。將布切成5公分X 5公分並使用4 2±2 %反射率之布做爲經土壤弄髒之布。所得之經人造土壤弄 髒之布之土壤組成物示於表9中。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -94 - 515784 A7 B7 五、發明説明（92 表9 經濟部中央標準局員工消費合作社印製 土壤成份 組成（w t % ) 有機土 油酸 28.3 三油精 15. 6 油酸膽甾酯 12.2 液態石蠟 2. 5 鯊烯 2. 5 膽甾醇 1.6 油質土之合計 62. 7 明膠 7. 0 4πχ. iM 丄 眺機土 29. 8 碳黑（由日本石油化學協會（J- 0.5 apan Oil Chemical Society) 命名） 2 )清潔之方法 將人造經土壤弄髒之布及經編織之布導至由美國特斯 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 一 95 - (請先閱讀背面之注意事項再填寫本頁) 裝· 訂' 515784 A7 B7 五、發明説明（93 ) 定（Testing)有限公司所製造之Terg-O-Tome ter中，該 設備具有設定洗滌液比例至3 0分鐘，以1 2 0 r pm， 在2 5°C進行清潔1 0分鐘。 使用9 0 0亮升量0 . 0 8 3%清潔劑濃度之清潔溶 液，並以900毫升水進行沖洗3分鐘。使用3° DH之 水。 3 )評價 藉由式〔5〕獲得清淨力。 (經清潔之布之K / S — 經土壤弄髒之布之K/S) 清淨力=-X 1 〇 〇 (%) (經土壤弄髒之布之κ/s- 經土壤弄髒之布之K/S) (5 ) K/S = (i-r/i〇〇)/(2R/100) 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) R爲藉由反射計所測量之反射率（％)之象徵。依據 1 0次經人工土壤弄髒之布之試驗所得之結果之平均值評 價清淨力。 例1 2 9 使用在下文中表1〇-21所示之清潔劑組成物之成 本紙張尺度適财關家標準（CNS ) A4規格（2H)X297公釐) 一 一 96 - 515784 A7 __B7__ 五、發明説明（94 ) 份製備6 0 %固體含量之清潔劑泥漿，該組成物排除非離 子之表面活化劑，部份矽酸鹽，部份碳酸鈉，酵素與香料 。使用在2 7 0 °C熱空氣溫度之逆流噴霧乾燥塔乾燥清潔 劑泥漿，以致水含量達到5 %，因此獲得經噴霧乾燥之產 物。 將此經噴霧乾燥之產物，非離子表面活化劑與水引進 至連續式之捏製機中而獲得密度大且均勻之經捏製之產物 。在捏製機之出口處裝備具有5mmp (直徑）80洞之 多孔薄板（1 0毫米厚）並將經捏製之產物製成大約5 mmpx1〇mm之圓柱狀之圓片。 將該圓片與以圓片之2倍量（重量）1 5 °C之冷卻空 氣一起導入至壓碎機中。壓碎機在橫斷4階段具有1 5公 分長之截斷器、，壓縮機以3 0 0 0 r p m旋轉，且篩包含 3 6 0°具有2 0 0mm?)孔徑且開度2 0%之衝孔金屬 〇 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 通過篩之顆粒與牛磺酸- N，N -二醋酸衍生物粉末 ，6 · 5重量％變成粉狀之碳酸鈉與2重量％之矽酸鹽粉 末混合，並添加酵素與香料而獲得具有在下文中表1 0 -2 1所示之組成物之清潔劑組成物。評價清潔劑組成物之 清淨力。 在表1 0 — 2 1中縮寫之意義與細節如下所述’ Ε Ο p意指環氧乙烷之平均添加莫耳數而P 〇 P意指環氧 丙烷之平均添加莫耳數。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -97 - 經濟部中央標準局員工消費合作社印製 515784 A7 B7 五、發明説明（95 ) (1 )陰離子表面活化劑： a_SF : α —硫代脂肪酸（C14—Ci6)甲基脂之 鈉鹽。 AOS : α —烯烴磺酸鈉（C14-Ci8)。 LAS :烷基苯磺酸鈉（烷基：Ci。一 C14)。 (2 )非離子表面活化劑： AE: C12醇羥乙基鹽（E0p = 15)。 NFE:壬基酚羥乙基鹽（E0p = 15)。 AOE · PO : C12 — Ci3 醇類之 E0 · P0 加合物 (Ε0ρ = 15 5 Ρ0ρ = 5)。 FEEiCnUO (OCH2OCH2) ! 5 O C Η 2 (3 )組份： TUDA :牛磺酸—N，N -二醋酸之鈉鹽 矽酸鹽：A型式沸石 (4 )酵素··蛋白酶，澱粉酶，纖維素酶，脂肪酶 (5 )其他添加劑： 螢光劑 香料 PAa :聚丙烯酸鈉 PEG400 :聚乙二醇 #400 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 98 - (請先閱讀背面之注意事項再填寫本頁) 1'、 —ai^ ϋ· ΜΜΜΒΜΛ^^Λ/ι «ϋ-ϋ men IB··— ϋ·ϋ —BIH— ^ϋ« Βϋ·^ nail _ 515784 A7 B7 五、發明説明（96 表10 經濟部中央標準局員工消費合作社印製7 B V. Description of the invention (90) Table 8 (continued) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 35.7 Reddish brown aqueous solution 49 SS-EDDS-Fe-Shun 4 30.0 50 29.9 Blackdish brown aqueous solution 35.7 Dark blue Color transparent aqueous solution 50 PDDS-Cu-2Na 30.0 50 1 32.2 Dark blue transparent aqueous solution 43.5 Blue transparent aqueous solution 51 SS-PDDS-Ni_2Na 30.0 75 38.4 Blue transparent aqueous solution 43.5 Dark blue transparent aqueous solution 52 SS-PDDS-OH-Cu- 2Na 30.0 75 1 38.7 Dark blue transparent aqueous solution (weight of impurities) (content of impurities) = -X100 [wt.%] (Weight of compound of formula [I]) wt.%: Content of compound of formula [I] in aqueous solution The above list: Before the given temperature is kept for 60 days (just after the aqueous solution is prepared) The following: After the given temperature is kept for 60 days, this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read first Note on the back, please fill in this page again) Installation · • ΙΓ · I ... Γ -93-515784 A7 B7 V. Description of the invention (91) [Cleaning agent composition] Method for measuring detergency 1) Preparation and use of artificial soil Mainly by high Ridges, vermiculites or clays which are dried at 200 ° C for 30 hours are considered as inorganic soil. 3.5 grams of the gel was dissolved in 950cc of water at about 40 ° C, and then 0.25 grams of carbon black was dispersed in the water by an emulsifying disperser. Then, 14.9 g of inorganic soil was added and emulsified, and 3 1 .35 g of organic soil was added thereto and emulsified and dispersed to prepare a stable soil bath. A clean cloth (cotton cloth # 60, named after the Japan Oil Chemical Society) of 10 cm x 20 cm was immersed in a soil bath, and after that, pressed by a double rubber roller made of rubber Squeeze to remove the water, homogenize the attached soil halo, and then wipe each side with the cloth 25 times. Cut the cloth into 5 cm x 5 cm and use a 4 2 ± 2% reflectance cloth as the soiled cloth. The soil composition of the obtained soiled cloth was shown in Table 9. (Please read the notes on the back before filling this page) The paper size printed by the Employees' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -94-515784 A7 B7 V. Description of the invention (92 Table 9 Composition of printed soil components by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (wt%) Organic soil oleic acid 28.3 triolein 15. 6 Cholesteryl oleate 12.2 Liquid paraffin 2.5 Squalene 2.5 Cholesterol 1.6 Total of oily soils 62.7 Gelatin 7. 0 4πχ. IM 丄 machine soil 29.8 carbon black (named by the Japan Petroleum Chemical Society (J-0.5 apan Oil Chemical Society)) 2) cleaning method Soil-stained cloth and warp-woven cloth are guided by the American Standard Paper (Applicable to Chinese National Standard (CNS) A4 size (210X 297 mm)) 95-(Please read the precautions on the back before filling this page) Assembling and ordering '515784 A7 B7 V. Description of the invention (93) In the Terg-O-Tome ter manufactured by Testing Co., Ltd., the equipment has a setting of the washing liquid ratio to 30 minutes, with 1 2 0 r pm, Clean at 25 ° C 10 minutes. Use a cleaning solution with a brightness of 0.08 3% detergent concentration and rinse with 900 ml of water for 3 minutes. Use 3 ° DH of water. 3) Evaluation The cleansing power was obtained by the formula [5]. (K / S of the cleaned cloth — K / S of the soiled cloth) Detergency = -X 1 〇〇 (%) (κ / s of the soiled cloth / s- Soiled cloth K / S) (5) K / S = (ir / i〇〇) / (2R / 100) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the notes on the back before filling this page) R is Symbol of reflectance (%) measured by reflectometer. Detergency was evaluated based on the average of the results obtained from 10 tests on cloths soiled with artificial soil. Example 1 2 9 The cost of using the cleaning agent composition shown in Tables 10-21 below. Paper Standards (CNS) A4 Specification (2H) X297 mm) 96-515784 A7 __B7__ V. Invention Note (94) parts prepare a detergent slurry of 60% solids content. This composition excludes non-ionic surfactants, some silicates, some sodium carbonate, enzymes and fragrances. A countercurrent spray-drying tower was used to dry the detergent slurry at a hot air temperature of 270 ° C so that the water content reached 5%, so a spray-dried product was obtained. The spray-dried product, nonionic surfactant and water were introduced into a continuous kneader to obtain a dense and uniform kneaded product. At the exit of the kneader, a porous sheet (10 mm thick) with 5 holes (diameter) of 80 holes was equipped, and the kneaded product was made into a cylindrical disk of about 5 mmpx and 10 mm. The disc was introduced into a crusher together with cooling air at 15 ° C, which is twice the amount (weight) of the disc. The crusher has a 15 cm long cut-off in the 4th stage of the cross, the compressor rotates at 3 0 0 0 rpm, and the screen contains 3 6 0 ° with a diameter of 2 0 mm? Porous metal printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The sieved particles and taurine-N, N-diacetic acid derivative powder, 6.5 wt% Powdered sodium carbonate was mixed with 2% by weight of silicate powder, and enzymes and fragrances were added to obtain a detergent composition having a composition shown in Tables 10 to 21 below. The detergency of the detergent composition was evaluated. The meanings and details of the abbreviations in Tables 10 to 21 are as follows: Ε Ο p means the average added mole number of ethylene oxide and P o P means the average added mole number of propylene oxide. This paper size applies to China National Standard (CNS) A4 (210X 297 mm) -97-Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 515784 A7 B7 V. Description of the invention (95) (1) Anionic surfactant: a_SF : Sodium salt of α-thio fatty acid (C14-Ci6) methyl ester. AOS: Sodium α-olefin sulfonate (C14-Ci8). LAS: Sodium alkylbenzenesulfonate (alkyl: Ci.-C14). (2) Non-ionic surfactant: AE: C12 alcohol hydroxyethyl salt (E0p = 15). NFE: Nonylphenol hydroxyethyl salt (E0p = 15). AOE · PO: C12 — E0 · P0 adduct of Ci3 alcohols (Ε0ρ = 15 5 Ρ0ρ = 5). FEEiCnUO (OCH2OCH2)! 5 OC Η 2 (3) Component: TUDA: Taurine-N, N-diacetic acid sodium silicate: Type A zeolite (4) Enzyme · Protease, amylase, cellulose Enzymes, lipases (5) Other additives: Fluorescent fragrance PAa: Sodium polyacrylate PEG400: Polyethylene glycol # 400 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 98-(please first Read the notes on the back and fill in this page) 1 ', —ai ^ · ΜΜΜΒΜΛ ^^ Λ / ι «ϋ-ϋ men IB ·· — ϋ · ϋ —BIH— ^ ϋ« Βϋ · ^ nail _ 515784 A7 B7 V. Description of the invention (96 Table 10 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

樣品編號Sample serial number

組成物（wt.%) 陰離子： a -SF AOS LAS 非離子：Composition (wt.%) Anion: a -SF AOS LAS Non-ion:

AEAE

NFE A0E · P0 FEE 組份：NFE A0E · P0 FEE Components:

ASDA 碳酸鉀_ 碳酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（¾) 本纸張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -99 一 515784 A7 __B7 五、發明説明（97 ) 表11 經濟部中央標準局員工消費合作社印製 樣品編號 9 10 11 12 13 14 15 16 組成物（wt.%) 陰離子： a -SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 非離子： AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE 組份： ASDA 15 25 5 10 10 10 10 10 碳酸鉀 8 8 8 8 8 8 8 8 碳酸鈉 22 22 27 22 22 22 22 22 酵素： 蛋白酶 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0· 1 0. 1 0· 1 — 0.5 一 - 0. 1 纖維素酶 0.1 0.1 0. 1 一 一 0.5 一 0. 1 脂肪酶 0.3 0.3 0.3 - 一 - 0.5 0.3 其他添加劑： 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 硫酸納 0.2 0.2 0.2 0.2 0.2 平衡 0.2 0.2 0.2 清淨力（％) 88 86 90 88 88 88 87 88 (請先閲讀背面之注意事項再填寫本頁) 裝· 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -100 - 515784 A7 B7 五、發明説明（98 ) 表12 經濟部中央標準局員工消費合作社印製 樣品編號 17 18 19 20 21 22 23 24 組成物（wt.%) 陰離子： a -SF 20 20 20 20 20 20 20 20 AOS 3 3 5 一 3 3 3 3 LAS 2 2 一 5 2 2 2 2 非離子： AE 5 5 5 5 5 - 一 - NFE 3 3 3 3 - 5 - 一 Α0Ε · P0 2 2 2 2 一 一 5 一 FEE 5 組份： TUDA 5 10 10 10 10 10 10 10 碳酸鉀 8 8 8 8 8 8 8 8 碳酸鈉 22 22 22 22 22 22 22 22 酵素： 蛋白酶 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0.1 0.1 0.1 0.1 0. 1 0. 1 0· 1 0· 1 纖維素酶 0.1 0.1 0.1 0. 1 0· 1 0.1 0· 1 0.1 脂肪酶 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 其他添加劑： 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 硫酸鈉 平衡 清淨力（％) 84 87 87 85 84 85 86 85 (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -101 - 515784 經濟部中央標準局員工消費合作社印製 五、發明説明（99 ) 樣品編號 組成物（wt.%) 陰離子： a -SF AOS LAS 非離子： AE NFE A0E · P0 FEE 組份： TUDA 碳酸鉀 碳酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（％) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）ASDA Potassium Carbonate _ Sodium Carbonate Enzyme: Protease Amylase Cellulase Lipase Other Additives: Sodium Sulfite Spice Fluorescent Agent PAa PEG 400 Detergent Sodium Sulfate (¾) This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -99 515784 A7 __B7 V. Description of invention (97) Table 11 Sample number 9 10 11 12 13 14 15 16 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Composition (wt.%) Anion: a- SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 Non-ionic: AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE component: ASDA 15 25 5 10 10 10 10 10 Potassium carbonate 8 8 8 8 8 8 8 8 Sodium carbonate 22 22 27 22 22 22 22 22 Enzyme: Protease 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0 · 1 0. 1 0 · 1 — 0.5 1-0. 1 Cellulase 0.1 0.1 0. 1-1 0.5-0. 1 Lipase 0.3 0.3 0.3-1-0.5 0.3 Other additives: sodium sulfite 1 1 1 1 1 1 1 1 1 0.2 0.2 0.2 0.2 0.2 0.2 0 .2 0.2 Fluorescent agent 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 Sodium sulfate 0.2 0.2 0.2 0.2 0.2 Balance 0.2 0.2 0.2 Detergency (%) 88 86 90 88 88 88 87 88 ( Please read the notes on the back before filling in this page.) Paper size: Applicable to China National Standard (CNS) A4 size (210X297 mm) -100-515784 A7 B7 V. Description of the invention (98) Table 12 Central Standard of the Ministry of Economic Affairs Sample number printed by the Consumer Cooperative of the Bureau 17 18 19 20 21 22 23 24 Composition (wt.%) Anion: a -SF 20 20 20 20 20 20 20 20 AOS 3 3 5 1 3 3 3 3 LAS 2 2 5 2 2 2 2 Non-ionic: AE 5 5 5 5 5-One-NFE 3 3 3 3-5-One Α0Ε · P0 2 2 2 2 One One 5 One FEE 5 Components: TUDA 5 10 10 10 10 10 10 10 10 Potassium carbonate 8 8 8 8 8 8 8 8 Sodium carbonate 22 22 22 22 22 22 22 22 22 Enzymes: Protease 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0.1 0.1 0.1 0.1 0. 1 0. 1 0 · 1 0 · 1 Fiber 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Lipase 0.3 0.3 0.3 0. 3 0.3 0.3 0.3 0.3 Other additives: sodium sulfite 1 1 1 1 1 1 1 1 1 perfume 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 fluorescer 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 sodium sulfate equilibrium detergency (%) 84 87 87 85 84 85 86 85 (Please read the precautions on the back before filling out this page) The size of the paper used for binding and binding applies to the Chinese National Standard (CNS) A4 specifications (210X297 mm) -101-515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (99) Sample number composition (wt.%) Anion: a -SF AOS LAS Non-ion: AE NFE A0E · P0 FEE Component: TUDA Potassium Carbonate Sodium Carbonate Enzyme: Protease Amylase Cellulase Lipase Other Additives: Sodium Sulfite Spice Fluorescent Agent PAa PEG 400 Sodium Detergency (%) This paper size is applicable to Chinese National Standard (CNS) A4 specifications ( 210X297 mm)

-102 - 515784 經濟部中央標準局員工消費合作社印製 五、發明説明（100) 樣品編號 組成物（wt.%) 陰離子： a -SF AOS LAS 非離子： AE NFE A0E · P0 FEE 組份： 矽酸鹽 ASDA 碳酸鉀 碳酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（％)-102-515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (100) Sample number composition (wt.%) Anion: a -SF AOS LAS Non-ion: AE NFE A0E · P0 FEE Component: Silicon ASDA potassium carbonate sodium carbonate enzyme: protease amylase cellulase lipase other additives: sodium sulfite perfume fluorescer PAa PEG 400 sodium detergency (%)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -103 - 515784 經濟部中央標準局員工消費合作社印製 五、發明説明（101) 樣品編號 組成物（wt.%) 陰離子： a-SF AOS LAS 非離子： AE NFE A0E · P0 FEE 組份： 矽酸鹽 ASDA 碳酸鉀 碳酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（％) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) -103-515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (101) Sample number composition (wt.%) a-SF AOS LAS Non-ionic: AE NFE A0E · P0 FEE Ingredients: Silicate ASDA Potassium Carbonate Sodium Carbonate Enzyme: Protease Amylase Cellulase Lipase Other Additives: Sodium Sulfite Spice Fluorescent Agent PAa PEG 400 Sodium Detergency (%) This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm)

-104 - 515784 A7 B7 五、發明説明（1〇2) 表16 經濟部中央標準局員工消費合作社印製-104-515784 A7 B7 V. Description of the Invention (102) Table 16 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

樣品編號 組成物（wt.%) 陰離子： a-S¥Sample number Composition (wt.%) Anion: a-S ¥

AOSAOS

LAS 非離子：LAS non-ionic:

AEAE

NFENFE

A0E · P0 FEE 組份： 矽酸鹽A0E · P0 FEE Composition: Silicate

TUDA 碳酸鉀 碳酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（％) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 105 - 515784 A7 B7 五、發明説明（103) 表17 經濟部中央標準局員工消費合作社印製 樣品編號 57 58 59 60 61 62 63 64 組成物（wt.%) 陰離子： a -SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 非離子： AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE - 組份： 矽酸鹽 一 - 15 15 15 15 15 15 TUDA 15 25 5 10 10 10 10 10 碳酸鉀 8 8 8 8 8 8 8 8 碳酸鈉 22 22 27 22 22 22 22 22 酵素： 蛋白酶 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0· 1 0· 1 0· 1 一 0.5 一 — 0· 1 纖維素酶 0· 1 0· 1 0· 1 - — 0.5 一 0· 1 脂肪酶 0.3 0.3 0.3 — 一 一 0.5 0.3 其他添加劑： 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0· 3 0.3 PEG 400 硫酸鈉 0.2 0.2 0.2 0.2 0.2 平衡 0.2 0.2 0.2 清淨力（％) 90 87 88 87 88 87 89 86 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁) I裝--- I i m m· mi ·ϋ mi ϋϋ mu Bui Bui ϋ·^— ϋ·^— ϋ_Ι_— ϋ_ι -106 - 515784 經濟部中央標準局員工消費合作社印製 五、發明説明（104) 樣品編號 組成物（wt.%) 陰離子： a -SF AOS LAS 非離子： AE NFE A0E · P0 FEE 組份： 矽酸鹽 ASDA 碳酸鉀 碳酸鈉 漂白劑： 過碳酸鈉 高硼酸鈉 酵素： 蛋白酶 澱粉酶 纖維素酶 脂肪酶 其他添加劑： 亞硫酸鈉 香料 螢光劑 PAa PEG 400 硫酸鈉 清淨力（％) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）TUDA Potassium Carbonate Sodium Carbonate Enzyme: Protease Amylase Cellulase Lipase Other Additives: Sodium Sulfite Flavor Fluorescent Agent PAa PEG 400 Detergent Sodium Sulfate (%) This paper size applies to China National Standard (CNS) A4 (210X297 mm) 105-515784 A7 B7 V. Description of the invention (103) Table 17 Sample No. 57 58 59 60 61 62 63 64 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Composition (wt.%) Anion: a -SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 Non-ionic: AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE-Composition: Silicate Mono-15 15 15 15 15 15 TUDA 15 25 5 10 10 10 10 10 Potassium Carbonate 8 8 8 8 8 8 8 8 Sodium Carbonate 22 22 27 22 22 22 22 22 Enzymes: Protease 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0 · 1 0 · 1 0 · 1 1 0.5 1 — 0 · 1 Cellulase 0 · 1 0 · 1 0 · 1-— 0.5—0 · 1 Lipase 0.3 0.3 0.3 — one by one 0.5 0.3 Other additives: sodium sulfite 1 1 1 1 1 1 1 1 perfume 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 fluorescer 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0 0.3 0.3 PEG 400 sodium sulfate 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Detergency (%) 90 87 88 87 88 87 89 86 This paper size applies to the Chinese National Standard (CNS) Α4 size (210 X 297 mm) (Please read the precautions on the back before filling this page) I Pack- -I imm · mi · ϋ mi ϋϋ mu Bui Bui ϋ · ^ — ϋ · ^ — ϋ_Ι_— ϋ_ι -106-515784 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (104) Sample number composition (wt .%) Anion: a -SF AOS LAS Non-ion: AE NFE A0E · P0 FEE Component: Silicate ASDA Potassium Carbonate Sodium Carbonate Bleaching Agent: Sodium Percarbonate Sodium Borate Enzyme: Protease Amylase Cellulase Lipase Other Additives: Sodium sulfite fragrance fluorescer PAa PEG 400 Detergency of sodium sulfate (%) This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm)

-107 - 515784 A7 B7 五、發明説明（1〇5) 表19 樣品編號 73 74 75 76 77 78 79 80 組成物（Wt.%) 陰離子： a-SF AOS LAS 非離子： AE NFE A0E · P0 FEE 組份： 20 20 20 20 20 20 20 20 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 矽酸鹽 _ — 15 15 15 15 15 15 ASDA 碳酸鉀 15 8 25 8 5 8 10 8 10 8 10 8 10 8 10 8 碳酸鈉 漂白劑： 22 22 27 22 22 22 22 22 過碳酸鈉 10 10 10 10 10 10 10 10 高硼酸鈉 酵素： 10 10 10 10 10 10 10 10 蛋白酶 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0. 1 0· 1 0. 1 一 0.5 一 - 0· 1 纖維素酶 0· 1 0. 1 0.1 - 一 0.5 一 0· 1 脂肪酶 其他添加劑： 0.3 0.3 0.3 一 一 一 0.5 0.3 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0,3 PEG 400 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 硫酸鈉 平衡 清淨力（％) 90 88 87 86 87 88 88 87 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 108 - 515784 A7 B7 五、發明説明（106) 表20 經濟部中央標準局員工消費合作社印製 樣品編號 81 82 83 84 85 86 87 88 組成物（wt.%) 陰離子： a -SF AOS LAS 非離子： 20 3 2 20 3 2 20 5 20 5 20 3 2 20 3 2 20 3 2 20 3 2 AE NFE A0E · P0 FEE 5 3 2 5 3 2 5 3 2 5 3 2 5 5 5 5 組份： 矽酸鹽 15 15 15 15 15 15 15 15 TUDA 碳酸鉀 5 8 10 8 10 8 10 8 10 8 10 8 10 8 10 8 碳酸鈉 漂白劑： 22 22 22 22 22 22 22 22 過碳酸鈉 10 10 10 10 10 10 10 10 高硼酸鈉 酵素： 10 10 10 10 10 10 10 10 蛋白酶 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0· 1 0· 1 0. 1 0· 1 0· 1 0.1 0. 1 0· 1 纖維素酶 0. 1 0.1 0.1 0.1 0.1 0· 1 0.1 0.1 脂肪酶 其他添加劑： 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 硫酸鈉 平衡 清淨力（％) 84 85 87 87 88 84 88 85 裝----* (請先閲讀背面之注意事項再填寫本頁) i#. 了項再填办 ......- !| 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -109 - 515784 A7 B7 五、發明説明（1〇7) 表21 經濟部中央標準局員工消費合作社印製 樣品編號 89 90 91 92 93 94 95 96 組成物（wt.%) 陰離子： a -SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 非離子： AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE 一 組份： 矽酸鹽 — 一 15 15 15 15 15 15 TUDA 15 25 5 10 10 10 10 10 碳酸鉀 8 8 8 8 8 8 8 8 碳酸鈉 漂白劑： 22 22 27 22 22 22 22 22 過碳酸鈉 10 10 10 10 10 10 10 10 高硼酸鈉 10 10 10 10 10 10 10 10 酵素： 蛋白酶類 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 澱粉酶 0. 1 0· 1 0.1 一 0.5 一 — 0· 1 纖維素酶 0· 1 0.1 0. 1 - - 0.5 - 0.1 脂肪酶 0.3 0.3 0.3 一 一 - 0.5 0.3 其他添加劑： 亞硫酸鈉 1 1 1 1 1 1 1 1 香料 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 螢光劑 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 硫酸鈉 0.2 0.2 0.2 0.2 0.2 平衡 0.2 0.2 0.2 清淨力（％) 89 88 88 89 87 87 86 90 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 裝-- (請先閲讀背面之注意事項再填寫本頁) -I 、v5 d -110 - 515784 經濟部中央標準局員工消費合作社印製 A7 _B7___五、發明説明（108) 例 1 3 0 - 1 5 3 (1 )表2 2顯示包含一些（S) -天冬胺酸一 N， N —二醋酸（ASDA)，牛磺酸一 N，N -二醋酸（ TUDA)，甲基亞胺二醋酸（MIDA) ，（S) —天 冬胺酸一 N —單醋酸（ASMA)與（S) -天冬胺酸一 N 一單丙酸（A SMP)之組份之本發明之清潔劑組成物 之實例。 表2 2另外顯示各自使用伸乙基二胺四醋酸（ EDTA)，氮三乙酸（NTA) ，ASDA，TUDA ，Μ I DA，ASMA與ASMP做爲組份之比較例之組 成物。 (2 )表2 3顯示在上述實例與比較例中’依據酸在 各自之pH，每重量組份之C a + +捕集力。在存有100 p pm十二烷基苯磺酸鈉做爲指示劑之情況下，使用1重 量％醋酸鈣水溶液進行滴定而測定C a + +捕集力。 (3 )在具有上述實例與比較例之組成物或沸石與三 聚磷酸鈉（S T P P )之組份上進行清淨力試驗。將經人 工弄髒之棉布，25 °C 1000毫升自來水（硬度： 5° DH) ，1 · 2克清潔劑組成物放在清潔裝置中（T-ei*g-0-Tome ter)，接著以4 8 %氫氧化鈉水溶液調整至 預定之P Η。然後，以每分鐘2 0 0旋轉數進行清潔 1 0分鐘。而且，在排乾之後，新添加2 5 °C 1 000毫 升之自來水（硬度：3° DH)並在200rpm進行漂 洗5分鐘。結果示於表24中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） — -111 - (請先閱讀背面之注意事 ，項再填. 裝----‘--、Ti--- :寫本頁) d 515784 A7 B7 五、發明説明（109) 藉由下列公式獲得清淨力。 在清潔後布之反射係數- 清潔前布之反射係數 清淨力=----X 1 0 0 (%) 未弄髒布之反射係數- 清潔前布之反射係數 所使用之清潔劑組成物具有下列組成物。至於表面活 化劑係選擇十二烷基苯擴酸鈉（S D S )或月桂酸鈉（ S L A )。 (請先閱讀背面之注意事_ S 項再填· 批衣 · 、TJ :寫本頁) 經濟部中央標準局員工消費合作社印製 表面活化劑 2 5 w t % 組份 25wt%(依據酸） 矽酸鈉 5wt% 碳酸鈉 3wt% 羧基甲基纖維素 1 w t % 硫酸鈉 41 w t % 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -112 - 515784-107-515784 A7 B7 V. Description of the invention (105) Table 19 Sample No. 73 74 75 76 77 78 79 80 80 Composition (Wt.%) Anion: a-SF AOS LAS Non-ion: AE NFE A0E · P0 FEE Composition: 20 20 20 20 20 20 20 20 20 (Please read the notes on the back before filling out this page) Silicate printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 15 — 15 15 15 15 15 ASDA Potassium Carbonate 15 8 25 8 5 8 10 8 10 8 10 8 10 8 10 8 Sodium carbonate bleach: 22 22 27 22 22 22 22 22 Sodium percarbonate 10 10 10 10 10 10 10 10 Sodium perborate enzyme: 10 10 10 10 10 10 10 10 Protease 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0.1 1 0 · 1 0. 1 One 0.5 One-0 · 1 Cellulase 0 · 1 0. 1 0.1-One 0.5 One 0 · 1 Lipase Other additives: 0.3 0.3 0.3 one by one 0.5 0.3 sodium sulfite 1 1 1 1 1 1 1 1 1 perfume 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 fluorescer 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Equilibrium detergency of sodium sulfate (%) 90 88 87 86 87 88 88 87 Paper rule Applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 108-515784 A7 B7 V. Description of invention (106) Table 20 Printed sample number 81 82 83 84 85 86 87 88 (Wt.%) Anion: a -SF AOS LAS Non-ion: 20 3 2 20 3 2 20 5 20 5 20 3 2 20 3 2 20 3 2 20 3 2 AE NFE A0E · P0 FEE 5 3 2 5 3 2 5 3 2 5 3 2 5 5 5 5 Ingredients: Silicate 15 15 15 15 15 15 15 15 15 TUDA Potassium carbonate 5 8 10 8 10 8 10 8 10 8 10 8 10 8 10 8 Sodium carbonate bleach: 22 22 22 22 22 22 22 22 Sodium percarbonate 10 10 10 10 10 10 10 10 Sodium perborate enzyme: 10 10 10 10 10 10 10 10 Protease 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0 · 1 0 · 1 0. 1 0 · 1 0 · 1 0.1 0. 1 0 · 1 Cellulase 0.1 1 0.1 0.1 0.1 0.1 0 · 1 0.1 0.1 Other lipase additives: 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Sodium sulfite 1 1 1 1 1 1 1 1 1 Fragrance 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Fluorescent 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 0.2 0.2 0.2 0.2 0 .2 0.2 0.2 0.2 Equilibrium detergency of sodium sulfate (%) 84 85 87 87 88 84 88 85 Pack ---- * (Please read the precautions on the back before filling this page) i #. ....-! | This paper size applies to China National Standard (CNS) A4 (210X297 mm) -109-515784 A7 B7 V. Description of Invention (107) Table 21 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Sample No. 89 90 91 92 93 94 95 96 Composition (wt.%) Anion: a -SF 20 20 20 20 20 20 20 20 AOS 3 3 3 3 3 3 3 3 LAS 2 2 2 2 2 2 2 2 non Ions: AE 5 5 5 5 5 5 5 5 NFE 3 3 3 3 3 3 3 3 A0E · P0 2 2 2 2 2 2 2 2 FEE One component: Silicate-1 15 15 15 15 15 15 TUDA 15 25 5 10 10 10 10 10 Potassium carbonate 8 8 8 8 8 8 8 8 Sodium carbonate bleach: 22 22 27 22 22 22 22 22 Sodium percarbonate 10 10 10 10 10 10 10 10 Sodium perborate 10 10 10 10 10 10 10 10 Enzymes: Proteases 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amylase 0.1 1 0 · 1 0.1 One 0.5 One — 0 · 1 Cellulase 0 · 1 0.1 0. 1--0.5-0. 1 Lipase 0.3 0.3 0.3 one-to-0.5 0.3 Other additives: sodium sulfite 1 1 1 1 1 1 1 1 1 perfume 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 fluorescer 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 PAa 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 PEG 400 Sodium sulfate 0.2 0.2 0.2 0.2 0.2 Balance 0.2 0.2 0.2 Detergency (%) 89 88 88 89 87 87 86 90 90 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) Pack-(Please Please read the notes on the back before filling this page) -I, v5 d -110-515784 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 _B7___ V. Description of Invention (108) Example 1 3 0-1 5 3 (1 ) Table 22 shows that some (S) -aspartic acid mono-N, N-diacetic acid (ASDA), taurine mono-N, N-diacetic acid (TUDA), methylimine diacetic acid (MIDA), An example of the detergent composition of the present invention is a component of (S) -aspartic acid-N-monoacetic acid (ASMA) and (S) -aspartic acid-N-monopropionic acid (A SMP). Table 22 also shows the composition of a comparative example in which ethylenediaminetetraacetic acid (EDTA), azatriacetic acid (NTA), ASDA, TUDA, MIDA, ASMA and ASMP are used as components. (2) Table 23 shows the C a + + trapping force per weight component in the above examples and comparative examples according to the respective pHs of the acids. In the case where 100 p pm of sodium dodecylbenzenesulfonate was used as an indicator, a 1% by weight aqueous solution of calcium acetate was used for titration to measure the Ca + + trapping force. (3) The detergency test is performed on the composition having the above-mentioned examples and comparative examples or the components of zeolite and sodium tripolyphosphate (STPP). Put artificially soiled cotton cloth, 1000 ml of tap water (hardness: 5 ° DH) at 25 ° C, and 1.2 g of the detergent composition in a cleaning device (T-ei * g-0-Tome ter), followed by The 48% sodium hydroxide aqueous solution was adjusted to a predetermined PΗ. Then, cleaning was performed at 200 revolutions per minute for 10 minutes. Furthermore, after draining, freshly add tap water (hardness: 3 ° DH) at 25 ° C and 1,000 ml, and rinse at 200 rpm for 5 minutes. The results are shown in Table 24. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) — -111 — (Please read the notes on the back, and then fill in the items. Packing ----'--, Ti ---: Written Page) d 515784 A7 B7 V. Description of the invention (109) The detergency is obtained by the following formula. The reflection coefficient of the cloth after cleaning-The reflection coefficient of the cloth before cleaning = ---- X 1 0 0 (%) The reflection coefficient of the unstained cloth-The detergent composition used for the reflection coefficient of the cloth before cleaning has The following composition. As for the surfactant, sodium laurylbenzene sulfamate (S D S) or sodium laurate (S L A) is selected. (Please read the notes on the back _ item S, then fill in. Approval, TJ: Write this page.) Surfactant printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 25 wt% Component 25 wt% (based on acid) Silicon Sodium 5wt% Sodium carbonate 3wt% Carboxymethyl cellulose 1 wt% Sodium sulphate 41 wt% This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) -112-515784

五、發明説明（no) 表22 經濟部中央標準局員工消費合作社印製 組份之組成物 例 ASDA TUDA ： ：MIDA ： ASMA ： ：ASMP 例1 30 60 20 20 0 0 例131 60 10 30 0 0 例1 32 50 25 25 0 0 例1 33 50 10 40 0 0 例134 50 40 20 0 0 例1 35 40 30 30 0 0 例1 36 40 40 10 0 0 例1 37 40 10 40 0 0 例1 38 30 35 35 0 0 例1 39 30 60 10 0 0 例140 20 10 60 0 0 例141 20 10 40 10 0 例1 42 90 10 0 0 0 例143 50 50 0 0 0 例144 20 80 0 0 0 例145 80 20 0 0 0 例146 20 10 40 10 0 例1 47 90 10 0 0 0 例1 48 95 0 5 0 0 例149 80 5 15 0 0 例1 50 80 15 5 0 0 例151 10 0 0 80 10 例1 52 20 0 0 80 0 例153 45 0 ： 0 50 5 (請先閲讀背面之注意事項再填寫本頁)V. Explanation of the invention (no) Table 22 Composition examples of printed components of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs: ASDA TUDA :: MIDA: ASMA :: ASMP Example 1 30 60 20 20 0 0 Example 131 60 10 30 0 0 Example 1 32 50 25 25 0 0 Example 1 33 50 10 40 0 0 Example 134 50 40 20 0 0 Example 1 35 40 30 30 0 0 Example 1 36 40 40 10 0 0 Example 1 37 40 10 40 0 0 Example 1 38 30 35 35 0 0 Example 1 39 30 60 10 0 0 Example 140 20 10 60 0 0 Example 141 20 10 40 10 0 Example 1 42 90 10 0 0 0 Example 143 50 50 0 0 0 Example 144 20 80 0 0 0 Example 145 80 20 0 0 0 Example 146 20 10 40 10 0 Example 1 47 90 10 0 0 0 Example 1 48 95 0 5 0 0 Example 149 80 5 15 0 0 Example 1 50 80 15 5 0 0 Example 151 10 0 0 80 10 Example 1 52 20 0 0 80 0 Example 153 45 0 ： 0 50 5 (Please read the precautions on the back before filling this page)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -113 - 515784 A7 B7 五、發明説明（ill) 表23 經濟部中央標準局員工消費合作社印製 組份之組 Ca++捕集力[CaC〇3毫克/依據酸之酸份（克） 成物 pH 7. 0 8.0 8.5 9. 0 10. 0 11. 0 12. 0 13. 0 例130 214 271 316 340 460 536 621 624 例131 206 208 276 305 474 569 659 668 例132 188 255 307 336 477 558 633 637 例133 176 209 248 284 499 606 691 708 例134 199 304 374 403 519 592 665 671 例135 162 239 299 332 495 579 646 650 例136 169 268 332 353 416 464 519 518 例137 144 175 213 248 460 561 634 648 例138 137 223 290 328 512 601 658 663 例139 157 300 390 415 475 520 562 565 例140 86 145 203 254 559 687 747 761 例141 81 152 210 262 482 640 697 708 例142 294 335 361 370 400 456 564 569 例143 208 333 407 423 440 477 538 541 例144 71 331 441 464 471 493 517 518 例145 273 335 372 383 410 461 558 566 例146 83 114 153 195 408 530 580 598 例147 305 337 355 345 402 469 587 593 例148 301 320 335 345 402 469 587 593 例149 261 288 313 331 432 469 587 593 例150 269 319 352 366 417 477 577 579 例151 51 80 120 187 263 555 578 587 例152 79 110 151 216 282 563 598 616 例153 154 180 210 254 313 517 578 582 裝---- (請先閱讀背面之注意事項再填寫本頁) ^ J - 二二- - ill d 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -114 - 515784 A7 B7 五、發明説明（m) 表24 經濟部中央標準局員工消費合作社印製 組份之組成物 表面活化劑 pH 清淨力[%] 例130 SDS 8 56. 6 例131 SDS 11 59. 5 例132 SDS 9 58.0 例133 SDS 12 60. 1 例134 SLA 12 51. 3 例135 SDS 8 55. 4 例136 SDS 8 61. 1 例137 SDS 10 58. 2 例138 SLA 10 51. 1 例139 SDS 9 56.6 例140 SDS 11 61. 3 例1 4 1 SDS 10 60. 0 例142 SLA 9 50. 2 例143 SDS 8 57.7 例144 SDS 9 58. 9 例145 SDS 7 58.1 例146 SDS 12 60. 0 例147 SLA 11 53. 2 例148 SLA 12 51.6 例149 SLA 13 54. 8 例150 SDS 9 57. 4 例151 SDS 12 60.1 例152 SDS 12 60. 2 例153 SDS 12 60. 3 沸石 SDS 12 48. 1 STPP SDS 12 60. 5 (請先閲讀背面之注意事 ΙΦ ’項再填- 裝---- :寫本頁) 1T———V.--β — 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -115 - 經濟部中央標準局員工消費合作社印製 515784 A7 B7 五、發明説明（ll3) 如從表2 3與2 4中所見，本發明之清潔劑組成物顯 出在廣潤之pH範圍中，C a + +捕集力與清淨力遠優於包 含下述各自獨自做爲單一組份之組成物：天冬胺酸- N， N —二醋酸，牛磺酸一 N，N —二醋酸，甲基亞胺二醋酸 ，天冬胺酸一 N -單醋酸，天冬胺酸—N -單丙酸，氮三 乙酸或沸石，而且其顯出等於或高於三聚磷酸鈉或伸乙基 二胺四醋酸之優異清淨力。本發明之清潔劑組成物包含適 合於傳統組份之無害生物可降解之組份，例如三聚磷酸鈉 ，伸乙基二胺四乙醋與氮三乙酸（其具有被燐，氮等物質 污染而致藻類急速繁殖，非生物可降解作用與毒性之問題 例1 5 4 製備示於表2 5，26與2 7之清潔劑組成物並評價 清淨力。 成份之縮寫示於下列。 S — ASDA: (S) —天冬胺酸一 N，N —二醋酸 之四鈉鹽 S - GLDA: (S) —穀胺酸—N，N —二醋酸之 四鈉鹽 TUDA :牛磺酸一 N，N—二醋酸 S L A :月桂酸鈉 SMA:肉豆蔻酸鈉 C M C :羥基甲基纖維素 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 裝-I I (請先閲讀背面之注意事項再填寫本頁) IT—I-p.I-1 515784 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（1H) 表25 樣品編號 1 2 3 4 5 6 7 8 9 10 組成物(wt·%) S-ASDA 25 25 25 25 25 0 0 0 0 0 S-GLDA 0 0 0 0 0 25 25 25 25 25 TUDA 0 0 0 0 0 0 0 0 0 0 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 矽酸鈉 5 5 5 5 5 5 5 5 5 5 碳酸鉀 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 硫酸鈉 41 41 41 41 41 41 41 41 41 41 清淨力(％) 90 88 88 86 85 85 84 85 84 87 (請先閱讀背面之注意事項再填寫本頁) ΒΗΙΙΜΜ♦J. (I 、-口 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 一 117 - 515784 A7 B7 五、發明説明（115) 表26 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁)This paper size applies to China National Standard (CNS) A4 (210X 297 mm) -113-515784 A7 B7 V. Description of Invention (ill) Table 23 Group Ca ++ capture of printed components by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Force [CaC〇3 mg / acid based acid (g) Product pH 7. 0 8.0 8.5 9. 0 10. 0 11. 0 12. 0 13. 0 Case 130 214 271 316 340 460 536 621 624 Case 131 206 208 276 305 474 569 659 668 cases 132 188 255 307 336 477 558 633 637 cases 133 176 209 248 284 499 606 691 708 cases 134 199 304 374 403 519 592 665 671 cases 135 162 239 299 332 495 579 646 650 cases 136 169 268 332 353 416 464 519 518 cases 137 144 175 213 248 460 561 634 648 cases 138 137 223 290 328 512 601 658 663 cases 139 157 300 390 415 475 520 562 565 cases 140 86 145 203 254 559 687 747 761 141 cases 141 81 152 210 262 482 640 697 708 cases 142 294 335 361 370 400 456 564 569 cases 143 208 333 407 423 440 477 538 541 cases 144 71 331 441 464 471 493 517 518 cases 145 273 335 372 383 410 461 558 566 cases 146 83 114 153 195 408 530 580 598 cases 147 305 337 355 3 45 402 469 587 593 cases 148 301 320 335 345 402 469 587 593 cases 149 261 288 313 331 432 469 587 593 cases 150 269 319 352 366 417 477 577 579 cases 151 51 80 120 187 263 555 578 587 cases 152 79 110 151 216 282 563 598 616 Example 153 154 180 210 254 313 517 578 582 Pack ---- (Please read the precautions on the back before filling this page) ^ J-22--ill d This paper size applies Chinese national standards ( CNS) A4 specification (210X 297 mm) -114-515784 A7 B7 V. Description of invention (m) Table 24. Composition of surfactant surfactants, detergency, pH detergency [%] of the components printed by employees' cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs 130 SDS 8 56.6 cases 131 SDS 11 59.5 cases 132 SDS 9 58.0 cases 133 SDS 12 60.1 cases 134 SLA 12 51. 3 cases 135 SDS 8 55.4 cases 136 SDS 8 61.1 cases 137 SDS 10 58.2 cases 138 SLA 10 51.1 cases 139 SDS 9 56.6 cases 140 SDS 11 61.3 cases 1 4 1 SDS 10 60. 0 cases 142 SLA 9 50. 2 cases 143 SDS 8 57.7 cases 144 SDS 9 58. 9 Example 145 SDS 7 58.1 Example 146 SDS 12 60.0 Example 147 SLA 11 53.2 Example 148 SLA 12 51.6 Example 149 SLA 13 54.8 Example 150 SDS 9 57. 4 Example 1 51 SDS 12 60.1 Example 152 SDS 12 60. 2 Example 153 SDS 12 60. 3 Zeolite SDS 12 48. 1 STPP SDS 12 60. 5 (Please read the notes on the back ⅠΦ 'Fill in-Fill ----: (Write this page) 1T ——— V .-- β — This paper size is applicable to China National Standard (CNS) A4 (210X 297 mm) -115-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 515784 A7 B7 V. DESCRIPTION OF THE INVENTION (ll3) As can be seen from Tables 2 3 and 24, the detergent composition of the present invention shows that in the wide pH range, the C a + + trapping power and detergency are much better than those including the following As a single component composition alone: aspartic acid-N, N-diacetic acid, taurine-N, N-diacetic acid, methylimine diacetic acid, aspartic acid-N-monoacetic acid, Aspartic acid-N-monopropionic acid, nitrogen triacetic acid or zeolite, and it shows excellent detergency which is equal to or higher than that of sodium tripolyphosphate or ethylenediaminetetraacetic acid. The detergent composition of the present invention contains harmless biodegradable components suitable for traditional components, such as sodium tripolyphosphate, ethylene diamine tetraethyl vinegar, and nitrogen triacetic acid (which has been contaminated by substances such as thallium, nitrogen, etc. The problems caused by the rapid propagation of algae, non-biodegradability and toxicity Example 1 5 4 The detergent compositions shown in Tables 2, 5, 26 and 27 were prepared and evaluated for detergency. The abbreviations of the ingredients are shown below. S — ASDA : (S) —aspartic acid mono-N, N —tetrasodium salt of diacetic acid S-GLDA: (S) —glutamic acid —N, N —tetrasodium salt of diacetic acid TUDA: taurine mono-N, N-diacetic acid SLA: Sodium laurate SMA: Sodium myristate CMC: Hydroxymethyl cellulose This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) Pack-II (Please read the precautions on the back first Refill this page) IT—Ip.I-1 515784 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1H) Table 25 Sample No. 1 2 3 4 5 6 7 8 9 10 Composition (wt %) S-ASDA 25 25 25 25 25 0 0 0 0 0 S-GLDA 0 0 0 0 0 25 25 25 25 25 TUDA 0 0 0 0 0 0 0 0 0 0 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 Sodium silicate 5 5 5 5 5 5 5 5 5 5 Potassium carbonate 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 1 Sodium sulfate 41 41 41 41 41 41 41 41 41 41 41 Detergency (%) 90 88 88 86 85 85 84 85 84 87 (Please read the precautions on the back before (Fill in this page) ΒΗΙΙΜΜ ♦ J. (I,-the size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm)) 117-515784 A7 B7 V. Description of the invention (115) Table 26 The size of the paper is applicable China National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page)

樣品編號 11 12 13 14 15 16 17 18 19 20 組成物(wt·%) S-ASDA 0 0 0 0 0 15 15 15 15 15 S-GLDA 0 0 0 0 0 10 10 10 10 10 TUDA 25 25 25 25 25 0 0 0 0 0 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 矽酸鈉 5 5 5 5 5 5 5 5 5 5 碳酸鉀 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 硫酸鈉 41 41 41 41 41 41 41 41 41 41 清淨力(%) 85 88 85 87 88 88 85 86 85 86 經濟部中央標準局員工消費合作社印製 ~ 118 - 515784 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（lie) 表27 樣品編號 21 22 23 24 25 26 27 28 29 30 組成物(wt.%) S-ASDA 15 15 15 15 15 10 10 10 10 10 S-GLDA 0 0 0 0 0 10 5 10 5 10 TUDA 10 10 10 10 10 5 10 5 10 5 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 矽酸鈉 5 5 5 5 5 5 5 5 5 5 碳酸鉀 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 硫酸納 41 41 41 41 41 41 41 41 41 41 清淨力(%) 88 87 87 86 85 84 87 88 88 86 裝-------訂-- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -119 一 經濟部中央標準局員工消費合作社印製 515784 A7 __B7 , 五、發明説明（I!7) 生物降解能力試驗： 在本發明中所使用之亞胺二醋酸衍生物之生物降解能 力係藉由經修訂之s C A S方法測試，所述之方法爲一種 使用描述於〇 E C D化學產物試驗指導方針中之活化污泥 之生物降解能力試驗之方法。 (試驗方法） (1 )在試驗槽中放入1 5 0毫升經活化之污泥混合 溶液並藉由氣動泵曝露至空氣中。 (2 )持續曝露至空氣中2 3小時，然後使污泥沈澱 4 5分鐘，接著移除1 0 0毫升浮在表層之液體。 (3 )靜置9 5毫升廢水並在試驗槽中放入試驗物質 未經稀釋之溶液，1 0 0毫升靜置之廢水放入槽中以控制 樣品，再次將槽中之內容物曝露至空氣中。 (4 )每天重覆上述程序並取樣浮在表層之液體，藉 由HP LC (高成形液體色譜法）方法與TO C (溶解之 有機碳）方法追踪試驗物質之滯留速率。 (結果）· 並聯試驗（S) -天冬胺酸一 N，N —二醋酸之四鈉 鹽，外消旋天冬胺酸一N，N—二醋酸四鈉鹽，（S)— 穀胺酸一 N，N -二醋酸之四鈉鹽，外消旋穀胺酸一 N， N —二醋酸四鈉鹽，牛磺酸一 N，N -二醋酸之三鈉鹽與 伸乙基二胺四乙酸四鈉。在每一試驗方法中所獲得之滯留 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) ' 一 120 - (請先閲讀背面之注意事項再填寫本頁) 裝---- T · 515784Sample No. 11 12 13 14 15 16 17 18 19 20 Composition (wt.%) S-ASDA 0 0 0 0 0 15 15 15 15 15 15 S-GLDA 0 0 0 0 0 10 10 10 10 10 TUDA 25 25 25 25 25 0 0 0 0 0 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 Sodium silicate 5 5 5 5 5 5 5 5 5 5 Potassium carbonate 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 1 Sodium sulfate 41 41 41 41 41 41 41 41 41 41 41 Detergency (%) 85 88 85 87 88 88 85 86 85 86 System ~ 118-515784 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (lie) Table 27 Sample No. 21 22 23 24 25 26 27 28 29 30 Composition (wt.%) S-ASDA 15 15 15 15 15 10 10 10 10 10 S-GLDA 0 0 0 0 0 10 5 10 5 10 TUDA 10 10 10 10 10 5 10 5 10 5 SLA 25 0 20 15 10 25 0 20 15 10 SMA 0 25 5 10 15 0 25 5 10 15 Sodium silicate 5 5 5 5 5 5 5 5 5 5 Potassium carbonate 3 3 3 3 3 3 3 3 3 3 CMC 1 1 1 1 1 1 1 1 1 1 Sodium sulfate 41 41 41 41 41 41 41 41 41 41 41 Detergency (%) 88 87 87 86 85 84 87 88 88 86 installed ------- order-(Please read the note on the back first Please fill in this page again for this matter) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297mm) -119 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 515784 A7 __B7, V. Description of Invention (I! 7) Biological Degradability test: The biodegradability of the iminodiacetic acid derivative used in the present invention was tested by a modified s CAS method, which was described using a method described in the OECD Chemical Product Test Guidelines Test method for biodegradability of activated sludge. (Test method) (1) Put 150 ml of activated sludge mixed solution in a test tank and expose it to the air by a pneumatic pump. (2) Continue to be exposed to the air for 23 hours, and then allow the sludge to settle for 45 minutes, and then remove 100 ml of the liquid floating on the surface. (3) Leave 95 ml of waste water and put an undiluted solution of the test substance in the test tank, and put 100 ml of waste water into the tank to control the sample, and then expose the contents of the tank to the air again in. (4) Repeat the above procedure every day and sample the liquid floating on the surface, and track the retention rate of the test substance by HP LC (High Forming Liquid Chromatography) method and TO C (Dissolved Organic Carbon) method. (Results) · Parallel test (S)-Aspartic acid mono-N, N-tetrasodium salt of diacetic acid, racemic aspartic acid mono-N, N-tetrasodium salt of diacetic acid, (S) -glutamine Tetrasodium salt of acid N, N-diacetic acid, Tetrasodium salt of racemic glutamic acid N, N -tetrasodium salt of diacetic acid, trisodium salt of taurine N, N -diacetic acid and ethylenediamine Tetrasodium tetraacetate. The paper size obtained in each test method is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) '-120-(Please read the precautions on the back before filling out this page) Packing-T 515784

AA

7 B 五、發明説明（us) 速率示於表2 8中。 表28 經濟部中央標準局員工消費合作社印製 化合物 藉由HPLC之 滯留速率 (%) 藉由TOC之 滯留速率 (%) (S)-天冬胺酸-N, N -—‘醋 酸之四鈉鹽 0 0 外消旋天冬胺酸-N, N-二 醋酸四鈉鹽 65 50 (S)-穀胺酸-N, N-二醋酸 之四鈉鹽 0 0 外消旋穀胺酸-N, N-二醋 酸四鈉鹽 60 50 牛磺酸-N, N-二醋酸之三 鈉鹽 0 0 伸乙基二胺四乙酸四鈉 100 100 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 裝-- (請先閲讀背面之注意事項再填寫本頁) -121 - 申請曰期 沾钜 11 月1 R 案 號 85114085 類 別 h /[^o j7^1 (以上各欄由本局填註） 口. -本Η Α4 C4 發明 為g專利説明書5!5784 中 文 發明 名稱 英 文 螯合劑及包含此螯合劑之清潔劑7 B V. Description of the invention (us) The rates are shown in Table 2-8. Table 28 Retention rate of compounds printed by employees 'cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (%) Retention rate by TOC (%) (S) -Aspartic acid-N, N ---' Tetrasodium acetate Salt 0 0 Racemic aspartic acid-N, N-diacetic acid tetrasodium salt 65 50 (S) -Glutamic acid-N, N-tetrasodium salt of diacetic acid 0 0 Racemic glutamic acid-N Tetrasodium salt of N-diacetic acid 60 50 Tasodium-N, Trisodium salt of N-diacetic acid 0 0 Tetrasodium diamine tetraacetic acid 100 100 This paper is applicable to Chinese National Standard (CNS) A4 specifications ( 210X297 mm) Packing-(Please read the notes on the back before filling out this page) -121-Application date: November 1 R Case No. 85114085 Class h / [^ o j7 ^ 1 (The above columns are provided by the Bureau Remarks) Mouth. -Ben A4 C4 invention is g patent specification 5! 5784 Chinese name of the invention English chelating agent and cleaning agent containing this chelating agent

Chelating agent and detergent comprising the same (1)(2)(3) 名 姓 山本浩 高柳恭之 高橋清文 國 籍 (1)日本 (2)日本 (3) 日本 裝 發明 人 (1)日本國撗浜市保土女谷區岩井町二四: 儿口 7 >岩井町二〇四號 住、居所 (2)日本國千葉縣松戶市五番西二丁目三〇一二二 (3)日本國東京都新宿區新宿六丁目二七一二五 訂 姓 名 (名稱） (1)三薆麗陽股份有限公司 三薆夫会 線 經濟部智^叫4::?:9工消骨合作社印製 國 籍 住、居所 (事務所） 代表人 姓 名 (1)日本 (1)日本國東京都港區港南一丁目六番四一號 (1)田口栄一 本纸張尺度適用中國國家標準（CNS ) A4規格（21 OX 297公釐） 515784Chelating agent and detergent comprising the same (1) (2) (3) First name surname Yamamoto Koyanagi Kyoyuki Takahashi Nationality (1) Japan (2) Japan (3) Japanese inventor (1) Hoto, Japan No. 24, Iwai-cho, Onani-ku: Children's mouth 7 > No. 24, Iwai-cho Residence, domicile (2) No. 30, 22, Goji Nishi-chome, Matsudo, Chiba Prefecture, Japan (3) Shinjuku, Tokyo, Japan Shinjuku, Rokuchome, 27,125 Names (Names) (1) Mikasa Liyang Co., Ltd. Mikado Line, Ministry of Economic Affairs, Chi ^ called 4 ::?: 9 Gongxiao Bone Cooperative Co., Ltd. Printed National Residence, Residence (Office) Name of Representative (1) Japan (1) Konanichichome, Liupansi No. 41, Minato-ku, Tokyo, Japan (1) Taguchi 栄 Paper size applies Chinese National Standard (CNS) A4 specifications (21 OX 297 Mm) 515784

申請曰期 85 年 11 月 16日 案 號 85114085 類 別 (以上各欄由本局填註） $ g專利説明書 中 文 發明 名稱 英 文 姓 名 國 籍 (4)中濱哲朗 (4)日本 發明 播 人 住、居所 姓 名 (名稱） (4)日本國福島縣1、打含市常磐上湯長谷町五反田 七_ 經濟部智慧叫4岣^工>/]費合作社印製 申請人 國 籍 住、居所 (事務所） 代表人 姓 名 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Application date: November 16, 1985 Case No. 85114085 Class (the above columns are filled by this Office) $ g Patent specification Chinese invention name English name Nationality (4) Nakahama Tetsuro (4) Japanese invention broadcaster's residence and residence name ( (Name) (4) Fukushima Prefecture, Japan 1, Takanami, Hitomi-cho, Hase-cho, Gotanda-cho, Hitachi-shi _ Ministry of Economic Affairs Wisdom Call 4 岣 ^ 工 > // Fei Cooperative Co., Ltd. Prints the applicant ’s nationality, residence (office) Representative Name This paper size applies to China National Standard (CNS) A4 specification (210X297 mm)

Claims (1)

515784 A8 B8 C8 D8 六、申請專利範圍 附件1(a):515784 A8 B8 C8 D8 VI. Scope of patent application Annex 1 (a): 第85114085號專利申請案Patent Application No. 85114085 中文申請專利範圍修正本 民國89年3月修正 1 · 一種爲粉末形式之螯合劑，包含下述式〔1〕之 化合物與至少選自下述一種化合物：天冬胺酸，順丁烯二 酸，丙烯酸，蘋果酸，甘胺酸，羥基乙酸，亞胺二醋酸， 氮三乙酸 一丙胺酸，Θ -丙胺酸，亞胺二丙酸，反一 丁烯二酸；及一種合成之起始胺基酸，一種合成之中間產 物胺基酸及相當於8重量％ (係以式〔1〕之化合物爲基 礎）或更少之其鹽類： R 2 R 1I I X — N — CH — Y 〔1〕 -------------------丨訂--------- (請先閱讀嘴面之注音S事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 其中R1代表氫或1 - 1 0碳原子之未經取代或經取代之 烴基，R2代表氫或1 - 8碳原子之未經取代或經取代之 烴基，但須R1與R2可一起形成環，可以R1與R2存 在之取代基爲至少一種選自一 OH，一 C02M與 一 S03M之鏈節，其中Μ代表氫或鹼金屬；X代表 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 一 1 - 515784 經濟部智慧財產局員工消費合作社印製 A8 B8 C8 D8 六、申請專利範圍 R 3 I R 4 - C Η - 或 A1 - CH-NH-A5 - I A 2 -（ C Η 2) η 其中R3代表氫或1 - 8碳原子之未經取代或經取代之烴 基，取代基爲至少一種選自一 0H，— C02M與 一 S03M之鏈節，R4代表至少一種選自氫，一 C02M 與一 S03M 之鏈節，A1與A2各自代表至少一種選自 氫，C02M與S03M之鏈節，A5代表可爲直鏈或支 鏈或可形成環之1 - 8碳原子之烯烴基，烯烴基可在鏈中 包含醚鍵_〇 —，酯鍵一 C00 -或醯胺鍵一 CONH — ，Μ代表氫或鹼金屬，而η代表1 一 8之整數；Y代表至 少一種選自氫，C02M與S03M之鏈節。 2 · —種水溶液或泥漿形式之螯合劑，其包含下述式 〔1〕之化合物與至少選自下述之化合物：天冬胺酸’順 丁烯二酸，丙烯酸，蘋果酸，甘胺酸，羥基乙酸’亞胺二 醋酸，氮三乙酸，α -丙胺酸，Θ -丙胺酸，亞胺二丙酸 ，反-丁烯二酸；一種合成之起始胺基酸，一種合成之中 間產物胺基酸及總量相當於2 5重量％ (係以式〔1〕之 化合物爲基礎）或更少之其鹽： 未紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） —-----------------訂--------- (請先閱讀臂面之注意事項再填寫本頁) - 2 - 經濟部智慧財產局員工消費合作社印製 515784 A8 B8 C8 D8 六、申請專利範圍 R 2 R 1 I I X — N — CH - Y 〔 其中R1代表氫或1 - 1 〇碳原子之未經取代或經取代之 煙基’ R 2代表氫或1 一 8碳原子之未經取代或經取代之 烴基，但須R1與R2可一起形成環，可以與尺2存 在之取代基爲至少一種選自一 〇H，_ C02M與 一 S〇3 Μ之鏈節，其中μ代表氫或鹼金屬；X代表 R 3 I R 4 — C Η — 或 Ai — CH - ΝΗ — Α5 一 I A 2 - ( C Η 2) η 其中R 3代表氫或1 - 8碳原子之未經取代或經取代之烴 基，取代基爲至少一種選自一 0H，一 C02M與 一 S03M之鏈節，R4代表至少一種選自氫，一 C02M 與一 S03M 之鏈節，A1與A2各自代表至少一種選自 氫，C02M 與S03M 之鏈節，A5代表可爲直鏈或支 鏈或可形成環之1 - 8碳原子之烯烴基，烯烴基可在鏈中 ^紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) 一 3 - -------------裝-------^丨訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 515784 A8 B8 C8 D8 六、申請專利範圍 包含醚鍵_0-，酯鍵—COO -或醯胺鍵一 CONH — ，MR表氫或鹼金屬，而η代表1 一 8之整數；γ代表至 少一種選自氫，C02M 與S03M 之鏈節。 3 ·如申請專利範圍第1項或第2項之螯合劑，其中 在式〔1〕中之X爲 R 3 I R 4 — C Η - 其中R3與R4如上所定義。 4 ·如申請專利範圍第1項或第2項之螯合劑，其中 在式〔1〕中之X爲 A1 - CH-NH-A5 - I A 2 一 ( C Η 2) n 其中A1 ，A2與A5如上所定義。 5 ·如申請專利範圍第3項之螯合劑，其中式〔1〕 之化合物係選自天冬胺酸一 N -單乙酸，天冬胺酸一 N， N -二醋酸，天冬胺酸一 N -單丙酸，亞胺二琥珀酸，N 一（2 —硫代甲基）天冬胺酸，N —（2 —硫代乙基）天 冬胺酸，榖胺酸一 N，N —二醋酸，N —（2 -硫代甲基 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) ------------------^—訂--------- (請先閱讀-t面之注咅？事項再填寫本頁) 一 4 一 515784 A8 B8 C8 D8 六、申請專利範圍 (請先閱讀嘴面之注意事項再填寫本頁) )穀胺酸，N —（2 —硫代乙基）穀胺酸，N —甲基亞胺 二醋酸，α -丙胺酸—N，N-二醋酸，々一丙胺酸一 N ，Ν —二醋酸，絲胺酸一 Ν，Ν -二醋酸，異絲胺酸一 Ν ，Ν -二醋酸，苯基丙胺酸一 Ν，Ν -二醋酸，鄰一胺基 苯甲酸一 Ν，Ν —二醋酸，磺胺酸一 Ν，Ν —二醋酸，牛 磺酸一 Ν，Ν —二醋酸，硫代甲基一 Ν，Ν —二醋酸與其 鹼金屬鹽及銨鹽。 6·如申請專利範圍第3項之螯合劑，其中式〔1〕 之化合物係選自（S) -天冬胺酸一單乙酸，（S) -天 冬胺酸一Ν，Ν-二醋酸，（S)-天冬胺酸一單丙酸， (S，S) -亞胺二琥珀酸，（S，R) -亞胺二琥珀酸 ，（S)—2—硫代甲基天冬胺酸，（S)—2—硫代乙 基天冬胺酸，（S)-穀胺酸一Ν，Ν-二醋酸，（S) 一2—硫代甲基穀胺酸，（S)—2—硫代乙基穀胺酸， (S) - α —丙胺酸一 Ν，Ν —二醋酸，（S)—絲胺酸 —Ν，Ν —二醋酸，（S) -苯基丙胺酸—Ν，Ν -二醋 酸與其鹼金屬鹽及銨鹽。 經濟部智慧財產局員工消費合作社印製 7 ·如申請專利範圍第4項之螯合劑，其中式〔1〕 之化合物係選自伸乙基二胺二琥珀酸，1 ，3 —丙烷二胺 二琥珀酸，伸乙基二胺二戊二酸，1 ，3 —丙烷二胺二戊 二酸，2 -羥基一 1，3 -丙烷二胺二琥珀酸，2 -羥基 一 1 ，3 -丙烷二胺二戊二酸與其鹼金屬鹽。 8 ·如申請專利範圍第4項之螯合劑，其中式〔i〕 之化合物係選自（s，S) -伸乙基二胺二琥珀酸，（S 本紙張尺度it用中國國家標準（CNS)A4規格（210 X 297公釐） " ' -5 - 515784 A8 B8 C8 D8 六、申請專利範圍 ’ S) — 1 ，3 一丙烷二胺二琥珀酸，（s，S) —伸乙 基一胺二戊二酸，（s，S) — 1 ，3 -丙烷二胺二戊二 酸’ （S，s) 一 2 -羥基一 1，3 -丙烷二胺二琥珀酸 ’ （S ’ S) — 2 -羥基一 1，3 -丙烷二胺二戊二酸及 其鹼金屬鹽。 9 · 一種清潔劑組成物，其組成如下： (a) 〇 · 5 — 80重量％選自（s)—天冬胺酸一 N ’ N -二醋酸，牛磺酸一 n，N -二醋酸及其混合物之 螯合劑， (b) 〇 · 2 - 60重量％非離子表面活化劑， (c) 〇 · 2 - 60重量％陰離子表面活化劑， (d) 〇 · 5 - 80重量％矽酸鹽，及 (e) 〇 · 5-60重量％漂白劑。 1 0 ·如申請專利範圍第9項之清潔劑組成物，其另 外包含脂肪酸鹽。 1 1 · 一種清潔劑組成物，其組成如下： (a) 〇 · 5 — 8 0重量％之同時包含至少一選自下 述三群組之各自至少二群組的成份， 群組A: (S)_天冬胺酸—N，N -二醋酸， 群組B :牛磺酸—N，N -二醋酸，及 群組C:甲基亞胺二醋酸，（S) -天冬胺酸一 N — 單乙酸與（S) —天冬胺酸一 N —單丙酸， (b) 〇 . 2 - 60重量％非離子表面活化劑，及 (c) 0 · 2 - 60重量％陰離子表面活化劑。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀嘴面之注意事項再填寫本頁) '-------訂.--------. 經濟部智慧財產局員工消費合作社印製 -6 -Amendments to the scope of patent application in Chinese Amendment of the Republic of China in March 89. 1 · A chelating agent in powder form, containing a compound of the following formula [1] and at least one compound selected from the group consisting of aspartic acid, maleic acid , Acrylic acid, malic acid, glycine, glycolic acid, imine diacetic acid, nitrotriacetic acid monoalanine, Θ-alanine, imine dipropionic acid, trans-butenedioic acid; and a synthetic starting amine Acid, a synthetic intermediate amino acid and its salts equivalent to 8% by weight (based on the compound of formula [1]) or less: R 2 R 1I IX — N — CH — Y [1 〕 ------------------- 丨 Order --------- (Please read the phonetic note S before filling out this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives where R1 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 10 carbon atoms, and R2 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 8 carbon atoms, provided that R1 and R2 may form a ring together, and the substituents that may exist in R1 and R2 are at least one kind selected from the group consisting of mono-OH, mono-C02M and mono-S03M, where M represents hydrogen or Metal; X represents the paper size applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1-515784 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 VI. Patent application scope R 3 IR 4 -C Η-or A1-CH-NH-A5-IA 2-(C Η 2) η where R3 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 8 carbon atoms, and the substituent is at least one member selected from the group consisting of 0H, — a link of C02M and S03M, R4 represents at least one link selected from hydrogen, a C02M and S03M link, A1 and A2 each represent at least one link selected from hydrogen, a link of C02M and S03M, and A5 represents Straight chain or branched chain or an alkene group having 1 to 8 carbon atoms. The alkene group may include an ether bond — 0—, an ester bond — C00 — or a amine bond — CONH — in the chain, and M represents hydrogen or a base. Metal, and η represents an integer of 1 to 8; Y represents at least one kind of link selected from hydrogen, C02M and S03M. 2. A chelating agent in the form of an aqueous solution or mud, comprising a compound of the following formula [1] and at least one compound selected from the group consisting of aspartic acid 'maleic acid, acrylic acid, malic acid, and glycine , Glycolic acid 'imine diacetic acid, nitrogen triacetic acid, α-alanine, Θ-alanine, imine dipropionic acid, trans-butenedioic acid; a synthetic starting amino acid, a synthetic intermediate product Amino acid and its total equivalent to 25% by weight (based on the compound of formula [1]) or less of its salt: Chinese paper standard (CNS) A4 (210 X 297 mm) --------------------- Order --------- (Please read the precautions of the arm surface before filling out this page)-2-Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the employee consumer cooperative 515784 A8 B8 C8 D8 VI. Patent application scope R 2 R 1 IIX — N — CH-Y [where R1 represents hydrogen or an unsubstituted or substituted nicotyl group of 1 to 10 carbon atoms' R 2 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 8 carbon atoms, provided that R1 and R2 can form a ring together, and can be substituted with a ruler 2 Is at least one selected from the group consisting of 10H, _CO2M and S03M, where μ represents hydrogen or an alkali metal; X represents R 3 IR 4 — C Η — or Ai — CH-ΝΗ — Α5-IA 2 -(C Η 2) η wherein R 3 represents hydrogen or an unsubstituted or substituted hydrocarbon group of 1 to 8 carbon atoms, and the substituent is at least one member selected from the group consisting of 0H, C02M and S03M, and R4 represents at least One is selected from the group consisting of hydrogen, a C02M and an S03M, A1 and A2 each represent at least one selected from the group consisting of hydrogen, C02M and S03M, and A5 represents a 1-8 carbon which may be straight or branched or may form a ring Atomic olefin group, olefin group can be in the chain ^ Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm)-3-------------- install --- ---- ^ 丨 Order --------- (Please read the precautions on the back before filling out this page) Printed by the Employee Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 515784 A8 B8 C8 D8 Ether bond — 0—, ester bond —COO — or amido bond — CONH —, MR represents hydrogen or alkali metal, and η represents an integer of 1 to 8; γ represents at least one selected from hydrogen, C02M and S03M link. 3. The chelating agent according to item 1 or item 2 of the scope of patent application, wherein X in the formula [1] is R 3 I R 4 — C Η-wherein R 3 and R 4 are as defined above. 4 · If the chelating agent of item 1 or item 2 of the patent application scope, wherein X in the formula [1] is A1-CH-NH-A5-IA 2-(C Η 2) n where A1, A2 and A5 As defined above. 5. The chelating agent according to item 3 of the application, wherein the compound of the formula [1] is selected from aspartic acid mono-N-monoacetic acid, aspartic acid mono-N, N-diacetic acid, and aspartic acid mono- N-monopropionic acid, imine disuccinic acid, N- (2-thiomethyl) aspartic acid, N- (2-thioethyl) aspartic acid, sulfamic acid-N, N- Diacetic acid, N — (2-thiomethyl) This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) ------------------ ^ — Order --------- (Please read the note on the -t side first? Matters and then fill out this page) One 4 One 515784 A8 B8 C8 D8 VI. Application for patent scope (Please read the notes on the mouth side first, then Fill in this page)) Glutamic acid, N- (2-thioethyl) glutamic acid, N-methylimine diacetic acid, α-alanine-N, N-diacetic acid, pyrene-alanine-N , N-diacetic acid, serine-N, N-diacetic acid, isosenic acid-N, N-diacetic acid, phenylalanine-N, N-diacetic acid, o-aminobenzoic acid-N, N—diacetic acid, sulfanilic acid-N, N—diacetic acid, taurine-N, - diacetate, thiomethyl a Ν, Ν - diacetate their alkali metal and ammonium salts. 6. The chelating agent according to item 3 of the scope of patent application, wherein the compound of formula [1] is selected from (S) -aspartic acid-monoacetic acid, (S) -aspartic acid-N, N-diacetic acid , (S) -aspartic acid-monopropionic acid, (S, S) -imine disuccinic acid, (S, R) -imine disuccinic acid, (S) -2-thiomethylaspartic acid Amino acid, (S) -2-thioethyl aspartic acid, (S) -glutamine mono-N, N-diacetic acid, (S) 2-thiomethyl glutamic acid, (S) —2—thioethylglutamate, (S) -α-alanine mono-N, N-diacetic acid, (S) -serine-N, N-diacetic acid, (S) -phenylalanine —N, N -diacetic acid and its alkali metal and ammonium salts. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs7. For example, the chelating agent in item 4 of the scope of patent application, wherein the compound of formula [1] is selected from the group consisting of ethylenediamine disuccinic acid, and 1,3-propanediaminediamine Succinic acid, ethylenediamine diglutaric acid, 1,3-propanediamine diglutaric acid, 2-hydroxy-1,3-propanediamine disuccinic acid, 2-hydroxy-1,3-propanedi Amine diglutaric acid and its alkali metal salts. 8. The chelating agent according to item 4 of the scope of the patent application, wherein the compound of the formula [i] is selected from (s, S) -diethylenediamine disuccinic acid, (S This paper uses the Chinese National Standard (CNS) ) A4 specification (210 X 297 mm) " '-5-515784 A8 B8 C8 D8 6. Application scope of patents' S) — 1, 3 propanediamine disuccinic acid, (s, S) — ethylene Monoamine diglutaric acid, (s, S) — 1,3-propanediamine diglutaric acid '(S, s) 2-hydroxy-1,3-propanediamine disuccinic acid' (S 'S ) — 2-Hydroxy-1,3-propanediamine diglutaric acid and its alkali metal salt. 9. A detergent composition having the following composition: (a) 0.5-80% by weight selected from (s) -aspartic acid-N'N-diacetic acid, taurine-n, N-diacetic acid Chelating agents and mixtures thereof, (b) 0.2-60% by weight non-ionic surfactant, (c) 0.2-60% by weight anionic surfactant, (d) 0.5-80% by weight silicic acid Salt, and (e) 0.5-60% by weight bleach. 10 · The detergent composition according to item 9 of the patent application scope, further comprising a fatty acid salt. 1 1 · A detergent composition, the composition of which is as follows: (a) 0.5-80% by weight and simultaneously contains at least one component selected from each of at least two groups of the following three groups, group A: ( S) _Aspartic acid—N, N-diacetic acid, group B: taurine—N, N-diacetic acid, and group C: methylimine diacetic acid, (S) -aspartic acid -N—monoacetic acid and (S) —aspartic acid—N—monopropionic acid, (b) 0.2-60% by weight non-ionic surfactant, and (c) 0 · 2-60% by weight anionic surface Activator. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on your mouth before filling this page) '------- Order .------- -. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-6-
TW85114085A 1996-02-02 1996-11-16 Chelating agent and detergent comprising the same TW515784B (en)

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JP3907596 1996-02-02
JP3907796 1996-02-02
JP3907696 1996-02-02
JP11950296 1996-04-18

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