TW513470B - Reactive dye composition - Google Patents

Abstract

A reactive dye composition comprising (a) at least a black or navy reactive dye with good color fastness to laundering-oxidative bleach response; and (b) at least a red, orange, yellow or other shade of reactive azo dye. The dye composition of the present invention is suitable for use in dyeing fiber materials. It has good property in build-up, wash fastness, wash-off, and levelness, especially performing excellently in the properties of good color fastness to laundering-oxidative bleach response.

Description

513470 A7 B7 Printed by the Consumer Affairs Cooperatives of the Intellectual Property Agency of the Ministry of Economic Affairs

[Technical Field of the Invention] V The present invention relates to a reactive dye composition, particularly a black or marine blue reactive dye composition suitable for dyeing fibrous substances, and has excellent fastness to oxidation / π white fading (c 〇i〇ur fastness t〇 jiaimia iaim (jering_ oxidative bleach response) 〇 [Invention technology background] As far as the objective W, with regard to the dyeing of leather, fabrics and other objects, it has not been possible to obtain a high concentration of black dyes from a single reactive dye . To obtain high-concentration black dyes, the dyes used are high-concentration black dye compositions derived from color mixing. White is the same; Chendu black dye composition is usually a reactive black or sea-blue dye. The main body, especially the reactive black with the following formula: The dye No. is the king of the market, and it is mixed with other reactive dyes of red, dial or yellow, and mixed to obtain a dark reactive black dye composition. ------------------ ^ --------- Awl (Please read the notes on the back before filling this page)

S〇2C2H4〇S〇3l · /, τ Yuki Bulletin Special Publication No. 58-160362, Japan, Gazette No. 63-17817G, Japan Patent Gazette No. Heibu No. ^, Japan Maze Pure special time 2__73 Please No., Japanese Patent Publication 513470

Explanation of the invention (3) Printed by Kaizu No. 2-202956, Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Japanese Patent Publication No. 8-1040822, Japanese Patent Publication No. 8-253697, and US patents are still V. 5,445,654 and US Pat. No. 5,6u, 82i have made efforts in this regard. However, due to the needs of energy saving and environmental protection, the washing machine technology has improved, the cleaning power has been greatly improved, and the development of H detergent has been greatly used. (Bleaching agent) high-efficiency cleaning agent to improve the cleanliness of the laundry, so that after a lot of water washing, the dyeing will greatly fade, especially the reactive black No. 5 dye as the main reactive dye composition Therefore, it is an objective of the industry to provide a reactive black or marine blue dye composition that is resistant to oxidation, bleaching, fading and repeated washing. The reactive black or No. 5 dye composition composed of reactive black dye No. 5 as the main body and a plurality of reactive azo dyes is used. The main reason why discoloration occurs during the multiple cleaning processes is mainly It is because the composition of the dye has poor fastness to oxidation and bleaching, and it is discolored by the bleaching agent added during the washing process. Especially when the dye composition has different fastness to oxidation and bleaching, the phenomenon of fading is not limited to the fading of the color, and even the hue of the laundry is changed. Currently, black or marine blue dyes on the market generally have this disadvantage, and the most important reason is that the reactive black No. 5 dye used in the dye main body has a very poor fastness to oxidation and bleaching. Therefore, if the red, Reactive dyes of other colors such as dial or yellow, with 4 paper sizes. Applicable to China National Standard (CNS) A4 (210 X 297 public love) ^ -------- ^ ----- ---- (Please read the precautions on the back before filling this page) Chuan 470 V. Description of the invention (彡: Wrong fastness to oxidation and bleaching naked color, there will be washing after washing for many times = phase quilt The change happened, so that the dyes that were originally black or sea blue would be perceived as other colors or hue. In order to solve the problem that the hue of dyes was changed, it has been proposed that as long as the oxidation resistance #color fastness is selected, and reactive black No. 5 Dye-like dyed yarn, two orange or yellow color reactive dyes, such black or ^ blue dye composition dyed dyes can overcome the hue of dyes changed. However , The dye has been washed In the process, the added color of bleach caused the dye to fade greatly, and the problem of faint fading became unsolved in this solution. [Summary of the invention] The object of the present invention is to provide a reactive dye composition It can be used for dyeing, printing and continuous dyeing of fibers to provide more excellent dyeing effect. Another object of the present invention is to provide a reactive dye composition with excellent dyeing effect. Fastness, detergency, and leveling property The printing of consumer cooperatives by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs has excellent characteristics, especially in terms of fastness to oxidation and bleaching. The reactive dye composition of the invention is It is a reactive dye composition with excellent fastness to bleaching and fading resistance, which mainly includes ... »at least one black or sea blue reactive dye selected from excellent fastness to bleaching and fading resistance, and (b) at least A paper selected from other colors such as red, orange, or yellow. The paper is translated to Chinese National Standard (cNS) A4 specifications (210 X 297 public love).

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (4) \ Reactive azo dyes are mixed to obtain dark reactive black 2 sea blue dye composition. That is, the reactive dye composition of the present invention is a black or marine blue dye composition with excellent wood dyeing properties, and a reactive black No. 5 dye with a matching component (C) of the following formula y) may be added for market demand. . , C2H4S〇2__Q_n = n ^ J ^ n = n_q_s〇2c Fine_ (I) The reactive dye composition of the present invention is in addition to black or per-color wood with good dyeing properties. More specifically, this The reactive dye composition of the invention is also a dye having excellent fastness to fading due to oxidation bleaching. In order to improve the characteristics of the dye composition, the present invention specifically uses an oxidation-resistant bleaching base color with excellent fastness. Reactive dyes are used to enhance the oxidation-bleaching resistance of the entire group of reactive dye compositions. This solution can not only effectively overcome The problem is that the hue of the dye is changed during the washing process, and the problem that the dye is faded by the added bleaching agent during the washing process can make the dye fade. [Specific description of the invention] The present invention <reactive dye composition roughly includes two main components: component ⑷ and ⑻, that is, component ⑷ is at least one selected from the group consisting of oxidation-resistant bleaching, excellent color hardness & black Marine blue reactive dye; and component (b) is composed of at least one reactive azo dye selected from other colors such as red, orange or yellow. 6 This paper size applies to China National Standard (CNS) A4 (210 X 297 ^ 7 ----------- I -------- ^ --------- & lt (Please read the notes on the back before filling this page) A7

V. Description of the invention (5)

The IH (II) n B printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is independent, and each represents a member selected from the group consisting of: ring, radical, radical, C1 ~ C4 radical, oxenyl, amine or its derivative Aromatic ring derivatives of substituents. The compound of the formula (King) has a similar color masterbatch with the reactive black poly number, and also uses the amino group, and the 4-hydroxy-3,6-disulfonic acid naphthalene as the reactive dye composition of the invention, except that Component (a) and component (b 4) In addition, a reactive black No. 5 dye with the following formula 组成 can be added as needed. Μ ho3soc2h4so2

S02C2H40S03H The component (a) black or sea-blue reactive dye used in the present invention is not subject to any particular restrictions; as long as the dyeing characteristics, coloring rate, and affinity are similar to the formula (1: reactive black No. 5 dye, and can be The black or sea-blue reactive dye ⑷, which exhibits excellent resistance to oxidation and bleaching, and has a high degree of hardness.-枓, can be used as a hair dye, and many black or sea-blue reactive dyes are used as the present invention. The constituents are those who have JH as follows: ^

A—N = N

&quot; so3H This paper size applies to China's "(CNS) A4 specification (210 X 297 ^ 7 1 ^ 1 t -----, --- ^ --------- {Please read the back Note: Please fill in this page again) 513470 V. Description of the invention (6) Resin composed of bisazo masterbatch derivative ^ Masterbatch of masterbatch] 5 virtual M: 疋 this kind of bisazo masterbatch, , Reconstruction and Reactive Black No. 5 Masterbatch _ This adjustment, for example, the aromatic ring of azo needs to have-and = two can achieve excellent fastness with oxidation resistance bleaching fun color = = so-material Based on the above, formula (π) can be listed as follows: Υ

Alas,

S03H

n = n OH NH2

N = N (IV)

Ri

Y r2 so3h c, please read the notes on the back before filling this page).

ϋ ml fen n ^ y i mmmi i ϋ n D = D 0. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where y and y ’are independent and represent —s〇2X, __ 一 w,

This paper size applies to China National Standard (CNS) A4 specifications (21〇Ί ^^

Cl 513470 A7 B7 V. Description of the invention (W stands for

N—or + ^ ~ ^, X represents a 0H Rs Cl F -CH = CH2 —C2H40S03H or a C2H4C1, T represents a NHCN, fluorine or chlorine atom, P represents a hydrogen atom, halogen atom, C1 ~ C4 alkyl or C 1 to C4 alkoxy, R5 is a chlorine atom or C ^ Czl · alkoxy; Ri, R2, R3, and R4 are independent of each other and represent a hydrogen atom, a halogen atom, a music group, (^ ~ 〇4 alkyl, Ci ~ C4 alkoxy or sulfonic group. More specific examples are: ho3soc2h4so2 丨 Η ΝΗ2

N = N-

SO2C2H4OSO3H (Please read the precautions on the back before filling this page)

H〇3S / ^^ \ ^ \ s〇3H HO3SOC2H4SO2

N = N_ H3CO H〇3S / ^ / \ ^^ s〇3H

SO2C2H4OSO3H Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy HO3SOC2H4SO2

N = N-

-SO2C2H4OSO3H (ΙΠ-3) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 513470 A7 B7 V. Description of the invention (s)

S02C2H40S03H

S02C2H40S03H

S02C2H4C1 0. (-Please read the precautions on the back before filling out this page) -pack- 、 11 Printed by the Employee Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

S02C2H40S03H III-7 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention (Clever) HO3SOC2H4SO2 ·

Λ〉 h brain -N

03H ψΐ ㈣ 丫 ~ ^ Ν = Ν · ^ S〇3H Ο

SO2C2H4OSO3H ΙΙΙ-8 Ε

SO2C2H4OSO3H (Please read the notes on the back before filling out this page) F Cl (ΙΙΙ-9)

Ο

SO2C2H4OSO3H III -10 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

ΙΙΙ-11 11 This paper size applies to the Chinese National Standard (CNS) A4 (210X 297 mm) 513470 A7 B7 V. Description of the invention (p

so3H HO3SOC2H4SO2

HN

= N

N = N S03H

—S03H 0 Please read the notes on the back before filling in this page)

-N

Cl IIM3)

Cl

-N

S03H

F III-14 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs H5C2-

(III-15) 12 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention (I 丨)

V N

so2ch = ch2

so2c2h4c1 C Please read the notes on the back before filling this page)

F

, 1T h3c〇n /

A

F

S02C2H4〇S03H Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs III-18 13 This paper size applies to China National Standard (CNS) Α4 specification (210X 297 mm) 513470 Α7 Β7 V. Description of the invention (μ)

-〇

S02C2H40S03H (ΙΙΙ-19

(-Please read the notes on the back before filling out this page) (IV-1)

(IV-2 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

SO2C2H4OSO3H (IV-3) 14 This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 513470 A7 B7 V. Description of the invention (G)

(IV-4) c

(IV-5)

(IV-6) (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

15 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 513470

5. Description of the invention () Bucket) If only the above-mentioned black or sea-blue reactive dye of the composition ⑷ is used, the formula ⑴Reactive Black No. 5 dye can only get blue: 枓 ::: 丨':: method to obtain a black or aqua blue dye composition with good deepness and = w * black or aqua blue dye composition with good deepness needs to be matched with /, dagger,., Work color, orange or yellow and other colors Department of reactive dyes. The component (b) red, color-shifting, or yellow-based reactive dyes used in the present invention are basically the same without any particular limitation, as long as the characteristics, coloring rate, and affinity can be matched with the black or Haijiao: Sex dyes and the formula 能够 Reactive black can be matched with deep black or sea blue dye composition red: 2: two yellow and other reactive dyes, we are all Can be used. … Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-Paper Among many reactive dyes of other colors such as red, orange, or yellow, the more feasible red, orange, or ρ color system that combines the constituents of the present invention Reactive dyes can be listed as the following examples:

513470 A7 B7 V. Description of the invention (/ 5)

Y

N = N

HO

so2x (VII)

(VIII Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

-N = N- Vz = | ^ As〇3H R2 Rs (IX) 17, (Please read the precautions on the back before filling this page)

This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 No. 99109339 2001/6/11 amendment page amendment:

so3h

Y

(XI) where D stands for

S03Hsax, Z stands for ~ CH3, rtt first read the phonetic on the back? (Please fill in this page for more details) Install -C—C2H5

Cl

S02X or

Cl Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy A represents 0H, -Shun2 or -CH3, R6 represents -c0H, ~ -LH3, Q represents a C02H or S03H, R? And R8 Each independently,-eight groups selected from a hydrogen atom, a C4 alkyl group, an amine group or a derivative thereof, η is an integer of 0 to 3, wherein X, γ, γ, Ri, and T are defined as above . More specific examples are:

297 mm) ----- Order --------- line · 513470 A7 B7 V. Description of the invention (I?

(v-1) H03SOC2H4S02 ·

) H Aj LJl / H03s / NH— N

S02C2H40S03H (Please read the precautions on the back before filling this page) (ν-2)

NHCOCH3 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

NHCOCH3 19 This paper size applies to Chinese National Standard (CNS) A4 specification (2IOX297 mm) 513470 A7 B7 V. Description of invention (stained)

(V-5)

(V-7) (Please read the notes on the back before filling this page)

, Line 1T «'· Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

20 This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 513470 A7 B7 V. Description of invention (/?) Ho3s

so2ch = ch2 ho3s

ho3s

(Please read the notes on the back before filling out this page) (VI-3 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs HO3SOC2H4SO2

SO3H 21 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention HO3SOC2H4SO2

N two N

N H3C

SO3H (VII-2 HO3SOC2H4SO2

PCH3 Η 丨 Ν = Ν ·

Ν

S03H h3co h3c (VII-3) HO3SOC2H4SO2

N = N.

N H3C

S03H (VII-4 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy HO3SOC2H4SO2-

H3CO

N = N] ’i OCH3 Η

S03H ho2c (VII-5) 22 (Please read the precautions on the back before filling this page)

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention (&gt; 丨 H03SOC2H4S02

Ν = Ν · H02C (VII-6)

SO3H HO3SOC2H4SO2

SO3H

SO3H

SO2C2H4OSO3H (Please read the notes on the back before filling out this page) Printed by the Employee Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs VII-8)

23 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 513470 A7 B7 V. Description of the invention (y

HQ HO3SOC2H4SO2-

Ν = Ν ·

so3h (&quot; Please read the notes on the back before filling this page) (VIII-3 HO3SOC2H4SO2

N = N.

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

S03H (VIII-4 24 This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 513470 A7 B7 V. Description of the invention (θ H03S0C2H4S〇2-

N two N- ho3s (VIII-5 HO3SOC2H4SO2-

N = N— () —NH2

S03H (VIII-6)

HQ HO3SOC2H4SO2-

N = N.

Co2h printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (VIII-7 25 0 Please read the precautions on the back before filling this page)

This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention (&gt; +) HO3SOC2H4SO2-

H3Q

N_N ~ NH2

SO3H (IX-1) H03SOC2H4S02

N = N

nh2 so3h (Please read the notes on the back before filling this page) IX-2) HO3SOC2H4SO2

N = N

NH2 S03H IX-3)

5〇sH HO3SOC2H4SO2- -N = N ·

-NH2 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

X 26 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 3 H Γ 513470 A7 B7 V. Description of the invention (4)

so2ch = ch2 (X-1)

S02C2H40S03H 0 Please read the notes on the back before filling out this page) (X-2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

(X-4) 27 This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 513470 A7 B7

5. Description of the invention (A

S〇3H

N = N

H〇3S / ^^^^ \ s〇3H

SO2C2H4OSO3H (XI-1) H03SOC2H4S02

-N two N,

S03H

(Please read the notes on the back before filling this page)

H03S

S03H (XI-2) Order Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

28 This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297mm) 513470 Α7 Β7 V. Description of the invention (&gt; 1)

NHCN ho3soc2h4so

(XI-4) The dye composition of the present invention can be formulated by various methods, for example, by making individual dye mixtures formulated separately and having different formulations, either the individual dyes in the formula can be mixed together, or they can be separated first. Mix one and mix with another bubble. This method of mixing takes place in a suitable mixer, for example, in a stirrer, in a compact mill, such as a ball and sand mill, but it is equally possible. The individual dyes of different formulas are mixed by agitating them into a dye liquid. The initiator is to control the reaction conditions in the preparation method of each dye, so that an ideal mixture can be produced in the prepared peers, and it can also be used in the process of dyeing or printing However, the individual dyeing rates can be mixed with each other, or with other dyes. The dyes of the present invention may be powder, granular, granular, or aqueous liquids, and may contain general dye auxiliary agents such as retarders, leveling agents, co-solvents, surfactants, buffers, dispersants, and the like. In this type I, the dyes all contain anionic groups like phosphonium acid groups, which is convenient to be expressed in the form of Λ free bismuth in this specification, but in the present invention, the dye form _ ==: rr⑽ exists, especially: = especially sulfonium salts, Potassium or ammonium. The ratio of various dyes can be 210X297 mm) "Please read the precautions on the back before filling out this page."

V. Description of the invention (J In a fairly wide range, it is not easy to change points. The minimum relative weight of a component is 3% and the maximum relative weight percentage is 90%. The above dyes can be widely used for containing Hydroxyl or amine-based textile dyeing, you | 4, deaf, magic fiber such as cotton, hemp, rayon and rayon, cellulose fiber, L universal U million or fork fabrics, the dyeing method used is The methods used in the dyeing of general anisotropic dyes, such as dip dyeing and printing, are suitable for continuous dyeing. Taking cellulose dye as an example, before, during or after dyeing, the acid binding agent will be treated. Caustic soda, sodium carbonate, sodium phosphate, or sodium bicarbonate, and the dyeing and finishing aids required for the addition part are added together. The dye of the present invention is a reactive dye with industrial price and can be used for various dyes. Good dyeing properties, and the dyeing properties have excellent characteristics in terms of deepness, washing fastness, detergency and leveling, especially in the fastness to oxidation and fading. Here, the so-called dye has excellent fastness to bleaching and fading, and is used to dye unmercerized knitted cotton (unmercerized cotton) with a dye weight of 3% owf (〇n the weight of Hber). Dyeing and dyeing the dyed matter in accordance with British Standard BS 1 006; UK-T0 colour fastness to domestic laundering-oxidative bleach response. Macbeth and Color-Eye 3 100 do computer color measurement, and use the color formula (CIE Lab and CMC (2: 1) color change; △ E) as the judgment standard 'When the gray scale becomes faded (gray scaie for 30 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) C Please read the precautions on the back before filling this page)

513470 A7 B7 V. Description of the invention (&gt; 1) Assessing change of c〇i〇ur rating) Grade 3-4 or above, or z \ E <3, and those with the same hue fading (on-t〇ne fading), then judge The dye is qualified, and it is believed that the dye has excellent fastness to bleaching and oxidation. For the convenience of further explanation, the following examples will be enumerated for more specific description. [Preferred Embodiments of the Invention] The following examples are specific illustrations of the present invention, but will not limit the scope of the present invention. The compounds are expressed in the form of a free acid, but the actual form may be a metal salt. It is more likely to be an alkali metal salt, especially a sodium salt. The parts or percentages used in the examples are based on weight unless otherwise specified, and the temperature unit is Celsius. c. Throughout Example 1, take 86 parts of the formula (III-1) dye and 14 parts of the formula (VIII-2) dye, and mix them with each other to obtain a uniform dye composition. Then, use the following dyeing method to perform a dyeing test and do oxidation resistance Fastness test for bleaching and fading. 1. Dyeing test: a. Take 2 parts of the above dye composition and dissolve completely in 100 parts of distilled water to prepare a dye solution. · B. Rinse the spherical glass bottle for staining with distilled water, pour 12 parts of the dye solution into the cup, and then add 6.4 parts of thenardite. 31 This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) (Please read the precautions on the back before filling this page)

Printed by 1T Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs 513470

Description of the invention U "d uniform g Finally, the dyeing bath was added to a total of 80 parts with distilled water. Then 8 parts of non-mersified knitted cotton cloth was added to the spherical glass bottle for dyeing. The above-mentioned spherical glass bottle for dyeing was locked tightly Then shake up and down to make the dye solution even. Put this glass ball bottle into a 60 ° C thermostatic glycerin dyeing proofing machine to start the dyeing. After 20 minutes, add 5 parts of 32 g / 1 pure test and keep 90 After that, take out the cloth, rinse it with cold water, put it in a large steel basin, and wash it with boiling water for 10 minutes. Then put the cloth into a large steel basin containing 20 g / 1 lotion, and rinse it with boiling water. After 10 minutes, remove the cloth and rinse it with cold water, then dehydrate and dry.

f Please read the precautions on the back first, and then fill in this one. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 2. Anti-oxidation, bleaching and fading firm skin. To the test content: BS 1006; UK-T0 colour fastness to domestic. laundering-oxidative bleach response, 1998) a. Take the cloth that has been dried in the dyeing test, and place it at 65% relative humidity and 20 ° C. 〇, After 4 hours in a closed constant temperature and humidity box, take 10 × 5 cm 2 as a sample cloth to carry out the fastness test of oxidation and bleaching. b. Take 10 grams of ECE soap containing no phosphorus, 12 grams of sodium perborate, and 1.8 grams of TAED (Tetra acetyl ethylenediamine)-dissolve in 1,000 ml of distilled water to make a test solution. C. Take the test solution in a cloth: solution, bath ratio of 1: 100 and place it in a 550 ml round steel cylinder. 32 This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -Order-

、 Explanation of the invention (today, after the lid is locked on the box, the steel bottle is put into the textile for washing fastness (please read the precautions on the back before filling this page) = medium k 30 degrees to 60 degrees The heating rate is 2 degrees / minute, and the test is performed for 30 minutes at 4 test temperatures and 60 degrees. E. After the test, the cloth is taken out and washed, and then dehydrated and dried. F. The result judgment criteria: The dyed matter is Macbeth, Co. 〇r_Eye31〇〇 do computer color measurement, and use the color formula (c〇l〇ur f0rmular) CIE Lab and CMC (2 ·· i) color difference colour (colour change; △ £) as the determination standard, when the gray scale becomes faded (Gray scale f0r assessing change 〇fc〇1_) 3_ 4 or more or △ e &lt; 3, and the same color tone fades (〇n_t〇ne 仏), then it is judged that the foot dye is qualified, and the dye is considered to be excellent The fastness to bleaching and fading resistance of oxidation. Example 2 to Example 24 Printed in accordance with the following table (I-1) by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs; examples, tables (1-2); the contents of comparative examples, repeated ”Describe [Classification_3 一 's dyeing test procedure, and will test the fastness of bleaching by oxidative bleaching] The results are summarized in the following Table (II-1); Examples, Tables (Π-2); Comparative Examples: 33 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 513470 A7 B7 V. Description of the invention () Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (1-1) Group composition (a) Group composition (b) Group composition (c) Compound proportion Compound proportion Compound proportion Compound proportion Example 2 (111-1) 25% ( Vl) 16% Yiyi (1) 59% Example 3 (111-1) 27% (Vl) 13% (VM) 6 ° / 〇 (1) 54% Example 4 (111-1) 27% (V- 3) 18% fine surface (1) 55% Example 5 (111-1) 27% (V-3) 23 ° / (1) 50% Example 6 (111-1) 86% (V- 3) 7% (VIII-2) 7% Example 7 (111-1) 78% (VI-1) 8% (Xl) 14 ° / ° E. Example 8 (111-1) 74% (VI- 1) 13% (XM) 13% Example 9 (111-1) 74% (VIII-2) 20% (IX-2) 6% Application Example 10 (111-1) 62% (VIII-2) 25% (IX-2) 13%-Example 11 (111-1) 24% (VIII-2) 16% (IX-2) 11 ° / 〇 (1) 49% Example 12 (111-2) 27% (Vl) 15% Scale (1) 58% Example 13 (111-2) 29% (Vl) 12% (VI-1) 6% (1) 53% Example 14 (111-2) 29% (V-3) 18% (1) 53% implementation 15 (111-2) 28% (V-3) 23%-(1) 49% Example 16 (111-2) 88% (V-3) 6% (νΐΙΙ-2) 6%-Example 17 (111-2) 79% (VI-1) 13% (Xl) 8% Example 18 (111-2) 75% (VI-1) 12% (ΧΙ-1) 13 ° / 〇Miscellaneous Example 19 (111-2) 87% (VIII-2) 13% __ Zouyi 34 (Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) 513470 A7 B7 V. Description of the invention (θ) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 20 (111-2) 75% (VIII-2) 19% (IX-2) 6% Example 21 (111 -2) 64% (VIII-2) 24% (IX-2) 12% Example 22 (111-2) 25% (VIII-2) 15% (IX-2) 11% (1) 49% Implementation Example 23 (IV-1) 28% (Vl) 15 ° / 〇 Sun (1) 57% Example 24 (IV-1) 30% (Vl) 12% (VI-1) 6% (1) 52% Example 25 (IV-1) 30% (V-3) 17 ° / 〇 (1) 53% Example 26 (IV-1) 29% (V-3) 22%-(1) 49% Example 27 (IV-1) 88% (V-3) 6% (VIII-2) 6% Example 28 (IV-1) 80% (VI-1) 12% (Xl) 8 ° / Example 29 (IV -1) 76% (VI-1) 12% (XI-1) 12% Miscellaneous Example 30 (IV-1) 65 ° / 〇 (VIII-2) 23% (IX-2) 12% 31 (IV-l) 26 ° / 〇 (VIII-2) 15% (IX-2) ll ° / 〇 (1) 48% ------------ install ---- X please Read the notes on the back before filling this page) Order --- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 513470 A7 B7 V. Description of invention (section) Intellectual Property Bureau employee, Ministry of Economic Affairs Printed by Consumer Cooperatives

Table (Π-1) Grade GIE Lab (ΔΕ) CMC (2: 1) (ΔΕ) On-Tone fading Example 1 5 0.05 0.21 Y Example 2 3-4 2.89 2.49 Y Example 3 3-4 2.84 2.47 Y Example 4 3-4 2.85 2.32 Y Example 5 3-4 2.79 2.42 Y Example 6 4-5 0.63 0.46 Y Example 7 4-5 0.60 0.44 Y Example 8 4-5 0.79 0.58 Y Example 9 4- 5 0.45 0.39 Y example 10 5 0.35 0.52 Y example 11 3-4 2.62 2.32 Y example 12 3-4 2.79 2.24 Y example 13 3-4 2.61 2.31 Y example 14 3-4 2.68 2.28 Y example 15 3-4 2.58 2.23 Y Example 16 4-5 0.51 0.39 Y Example 17 4-5 0.75 0.60 Y Example 18 5 0.31 0.31 Y 36 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) ----------- install -------- order --------- line 0, please read the precautions on the back before filling in this page) 513470 A7 _ B7 5 Description of invention (Qi) Printing of clothing by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

Example 19 4-5 0.50 0.38 Y Example 20 4-5 0.40 0.32 Y Example 21 4-5 0.65 0.53 Y Example 22 3-4 2.75 2.14 Y Example 23 3-4 2.65 2.13 Y Example 24 3- 4 2.28 2.09 Y example 2 5 3-4 2.55 2.26 Y example 26 3-4 2.39 2.11 Y example 27 4-5 1.27 0.96 Y example 28 5 0.17 0.29 Y example 29 5 0.14 0.30 Y example 30 4 -5 0.70 0.56 Y Example 31 3-4 2.27 2.06 Y ----------- Installation -------- Order --------- (Please read the Note: Please fill in this page again.) This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 513470 A7 B7. 5. Description of the invention (fighting). b) Component (c) Compound proportion Compound proportion Compound proportion Compound proportion Compound proportion Comparative Example 1 (Vl) 18% (VM) 9% (1) 73% Comparative Example 2 (V-3) 25% Lai (1) 75% Comparative Example 3 (V-3) 19% (V-4) 21 ° / 〇 (VII-1) 3% (1) 57% Comparative Example 4 (V-4) 22% (VII-1) 3% (1) 75% Comparative Example 5 (V-4) 18% (VII-1) 3% (VIII-2) 17% (IX-2) 11% (1) 51% Comparative Example 6 (VIII-2) 210 / 〇 (IX-2) 14% Pain · (1) 65%

Please read the notes on the back first, and then slump.

Table (Π-2) Grade GIE Lab (ΔΕ) CMC (2: 1) (ΔΕ) On-Tone fading Comparative Example 1 3 3.61 2.78 N Comparative Example 2 3 4.88 3.31 N Comparative Example 3 3 3.16 2.95 N Comparative Example 4 2 -3 4.33 3.21 N Comparative Example 5 3 3.19 2.80 N Comparative Example 6 3 4.94 3.15 N Order --------- This paper size applies to China National Standard (CNS) A4 (21〇X 297 mm) A7 ------- B7__ V. Invention rewards) -------- [Effects of the invention] The present invention "Dye composition ⑼ is a universal W reaction 1 raw dye composition 'can be widely applied to Based on a wide range of textile wood colors such as basic or amino groups, the dyeing method used is the same method used when dyeing with reactive dyes, such as dip dyeing, printing or continuous dyeing. The dye composition described in the present invention is a reactive wood with industrial value. It can obtain various dyeing materials with good dyeing properties, and the dyeing materials have excellent characteristics in terms of deepness, fastness to washing, detergency and leveling. , Especially in the fastness of bleaching resistance to oxidation and bleaching has a very excellent performance. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 9 3 Applicable State Country-State China Moderately I-shaped Paper 7 129 X 10 (2 grid A4

Claims (1)

513470 ^ rgginQ ^ gg ^ 〇nn〇 / A〇 /? T 6. Apply for a patent-into one ------ / A 3 amend 丨 1 · a reactive dye with excellent oxidation resistance bleaching # color fastness A composition comprising: ⑷, at least 3% to 90% by weight-selected from oxidation bleaching resistance fading fastness k good &lt; black or sea blue reactive dyes, the black or sea blue reactive dyes Selected from the formula (111) Y, where γ and Y ’are independent and represent —s〇2X, —_— w -m-ζ ^ Or -NH— ^ \ NH &lt; x ^ --------- ^ 1 (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Consumption Cooperative Print 4 R5 Ci ' F-·, Modi here, a CH = CH2, or-= (Division, t represents -NHCN, fluorine or hafnium, p atom, halo atom C4 alkyl or Cl ~ C4 alkyl, R5 is chlorine :: where w stands for Or Ci ~ C4 alkoxy; Rl, R2, R3, and R4 are independent of each other, and represent hydrogen atom, _ prime atom, respectively. This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm> Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 513470 6. Scope of Patent Application: Hydroxyl, Ci ~ C4 alkyl, Ci ~ C4 alkoxy or sulfonate 'or Formula (IV) dye Y, π) 3% by weight Reactive azo dyes up to yu / 0 ~ L yellow color system 'this, red, &amp; color, or' color color L reactive azo dye system is selected from formula (v), formula (VI), formula (νπ ) Formula (νΠ: (ίχ), Formula (X) or Formula (XI) dye, -ΝΗ-ZO where D stands for Os〇2X or 41. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -SO3H, S〇2X -------- ^ --------- Line- (Please read the notes on the back before filling out this page) 513470 Α8 Β8 C8 D8 VI. Patent application for picking Z representative -C—ch3 —C—c2h5, or the definitions of X and T are as described above; Υ 、 (S03H) n HN—C—A where Y is defined as described above or —CH3; (VI) η is an integer from 0 to 3, A represents a 0H, a NH2 (Please read the precautions on the back before (Fill in this page) R2 -N = N v == y ^ so2x where X, Y, Rl, and R2 are defined as described above. R6 stands for —CO2H or a CH3 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. R2 -N = N_ (VIII 42 papers Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm), A Q 513470 〇f) f) 9 / n〇 / 〇i Six, the scope of patent application A8 B8 C8 D8 where Y, R !, R2 And the definition of A is as described above, "Q stands for -co2h or -SO3H; so3h where Y, Rl, and R2 are defined as described above, and R7 and Rg are each independently a hydrogen atom, an alkyl group, an amine group, or a group of a derivative thereof; page) so3h where Y and Y ′ are defined as described above; so3h Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The definitions of Y, Y ’, η, and Ri are as described above. 2. The composition according to item 1 of the scope of patent application, wherein the black or sea-blue reactive dye of the component (a) is selected from the formula (II). 3. If the composition of the scope of application for the first item of the patent, where the component (a) is black or 43 paper size applicable to China National Standard (CNS) A4 specifications (210 X 297 public love) A8 B8 C8 D8 513470 No. No. 88109339. 2002/02/2 ^ · # ^ 奚 6. The scope of patent application The sea-blue reactive dye is selected from the formula (IV). 4. If the composition of the scope of the patent application item 2, the formula (III) is A compound of the following formula (III-1). SO2C2H4OSO3H 5. The composition according to item 2 of the scope of patent application, wherein the formula (III) is a compound of the following formula (III-2). (Please read the notes on the back before filling this page) (ΙΠ-2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. If the composition of the scope of patent application No. 3, wherein the formula (IV) is a compound of the following formula (IV-1). IV-1 44 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 513470 Α8 B8 C8 D8 夂, patent application scope 7. If the composition of the first scope of patent application, the formula (v ) Is a compound of the following formula (V-1). 8. The composition according to item 1 of the scope of patent application, wherein the formula (V) is a compound of the following formula (V-3). (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs S〇2CH = CH2 9. The composition according to item 1 of the scope of patent application, wherein the formula (VI) is a compound of the formula (VI-1). 10. The composition according to item 1 of the scope of patent application, wherein the formula (vm) is a compound of the following formula (VIII-2). 45 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 513470% RR1 9ΠΠ9 / η〇 / 91 A8 B8 C8 D8 VI. Patent application scope HO3SOC2H4SO2 ^^-N = N. Nh2 S03H (VIII-2) 11. The composition according to item i in the scope of patent application, wherein the formula (IX) is a compound of the following formula (IX-2). N = N ~ nh2 S03H (Please read the cautions on the reverse side before filling out this page) 12. If you apply for a compound in the scope of the patent. The composition of item, where formula (X) is the following formula (χ-1 Consumption by Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by a cooperative S02CH-CH2 (Xl 1 3. As for the composition of the scope of patent application item 1, where the formula (χι) is the following formula 46 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) • nnnnn «Ϋ n V nnna— nnn I. :) ΐ34 / υ Article 88〗 g # 9009/09/71 Α8 Β8 C8 D8 6. Application scope of patents --- (XI-1) compounds. H03S0C2H4S02 so3h (xi_i) 14 · A kind of bleaching bleach with excellent oxidation resistance, which includes ... "Reactive dye composition (a) 3% to 90% by weight, excellent black or sea blue fastness to fading Color reaction ':: selected oxidative bleaching blue reactive dyes are selected from the formula (III) dye coat, black or sea γ,. (Please read the notes on the back before filling out this page) In the printed format of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, γ and Υ ’are independent and represent —s〇2x, • NHi SQzX or 47 Paper Ruler (CNS) Standard A_4_'ii (210 X 297 Public Love) 513470 6. Scope of Patent Application / = ^ where W stands for H. R5 , X represents —ΟΗ—CH = CH2, or —C2H4〇s〇3H, τ represents ~ Jian ⑶, represents a hydrogen atom, a halogen atom, p — Liaoyuanyu, P is a chlorine atom or Ci ~ C4 alkoxy group; Bur'han 5M, K2, I13, and R4 are each independent, and respectively represent a hydrogen atom, a halogen atom, a C4C4 alkyl group, a C4C4 alkoxy group, or a sulfonic acid group, and the formula (IV) Dye C Please read the notes on the back before filling this page} Y Y 'where γ, Y', Ri, and R2 are defined as described above; and --------- line · printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (b) the weight percentage is 3% to At least 90% of the reactive azo dyes selected from the red, orange or yellow color system, the reactive azo dyes of the red, lamp or yellow color system are selected from the formula (V), formula (VI), formula (VII), formula (VIII), formula (IX), formula (x) or formula (XI) dyes, 48 This paper size is applicable to China National Standard (CNS) A4 regulations (2) 0X 297 public love) 513470 Α8 Β8 C8 D8 VI. Patent application scope ho3s where D stands for h Z generation of brother, brother clothing c-ch3 -c-c2h5 X and T are defined as above; D-N = Ν NH-Z (V) so2x, or ^ N ^^ n == n -y (Please read the precautions on the back before filling in this page), (S03H) n HN-CA (where Y is the meaning of VI as described above, n is an integer from 0 to 3, and A stands for —〇H or — CH3; -nh2 Y R2 HO -Ν = so2x Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (VII) where X, Υ, Rl, and R2 are defined as described above, R6 represents a C02H, or a CH3; 49 This paper standard applies to Chinese National Standards (CNS) A4 specification (210 X 297 mm) 513470 gf ^ 9ΠΠ9 / Π9 / 91 A8 B8 C8 D8 Patent application scope • N = N- QY r2 (VIII) where Y, Rl, R2 and A are defined as described above, Q Represents one Co2H or -SO3H Y -N two N S03H (Please read the precautions on the back before filling this page) Ri Rs ix) where Υ, Rl, R2 are as defined above, and R7 and R8 are each independently hydrogen atom, Ci ~ C4 alkyl, amine or The group of its derivative; mmmt ϋΒ n · nn 11 UK 1, · 1 fBi a— tmm9 In so3h line · The definition of Y and Y ’in the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is as described above; Y (XI 50 This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) 513470 A8 B8 C8 D8 Printed by Employee Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs.) 6. Application scope of patents: Y, Y, and R4 As defined previously; and Reactive black No. 5 dye of S02C2H40S03H. 15. The composition according to item 14 of the application, wherein the black or sea-blue reactive dye of the component (a) is selected from the formula (II). 16. The composition according to item 14 of the scope of patent application, wherein the black or sea-blue reactive dye of the component (a) is selected from the formula (IV). 17 · If the composition of the scope of the patent application item 14, wherein the Z substituent of the formula (V) is _c ~ c2H5 0 18 · If the composition of the scope of the patent application item 14, the formula (in) Ri, r2, R3, and R4 are each independent, and each represents a hydrogen atom, a prime atom, a meridian group, (^ ~. An alkyl group, a CPC4 alkoxy group, or a sulfonic acid group. 19. Composition as described in item 4 of the scope of patent application The weight percentage of formula (in) is 10 to 95%, the weight percentage of formula (V-3) is 3 to 40%, and the weight percentage of formula (VIII-2) is 3 to 40%. 20 · For example, the composition of item 4 of the scope of patent application, wherein the weight percentage of formula (Hu) is 10 to 95%, the weight percentage of formula (VI-D) is 3 to 40%, and the weight percentage of formula (X-1) is 3 ~ 40% ° 51 This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back before filling this page) 1 ^, ϋ n 1 n · 1 nn I nn 1 nn ϋ nnnn I &gt; 13470 Α8 Β8 C8 '^ 2009/00 / ^ rirn_ D8 VI. Patent application scope 2 ^ Reactive dye composition according to item 4 of the patent application scope, where formula (I II-1) weight percentage of 10 to 95%, formula (VI-1) weight percentage of 3 to 40%, and formula (XI-1) weight percentage of 3 to 40%. The composition of 4 items, wherein the weight percentage of formula (III-1) is 10 to 95% and the weight percentage of formula (VIII-2) is 3 to 40%. 23. If the composition of item 4 of the scope of patent application, Wherein, the weight percentage of formula (III-1) is 10 to 95%, the weight percentage of formula (VIII-2) is 3 to 40%, and the weight percentage of formula (IX-2) is 3 to 40%. 24_If you apply The composition of item 5 of the patent, wherein the weight percentage of formula (III-2) is 10 to 95%, the weight percentage of formula (V-3) is 3 to 40%, and the weight percentage of formula (VIII-2) is 3 ~ 40%. 25. The composition according to item 5 of the patent application scope, wherein the weight percentage of formula (III-2) is 10 ~ 95%, the weight percentage of formula (VI-1) is 3 ~ 40% and formula The weight percentage of (X-1) is 3 to 40%. 26. The composition of item 5 in the scope of patent application, wherein the weight percentage of formula (ιπ_2) is 10 to 95%, and the weight percentage of formula (VI-1) 3 ~ 40% and weight of formula (χΙ-1) The percentage of the amount is 3 to 40%. 27. The composition of item 5 of the patent application range, wherein the weight percentage of the formula (IΠ-2) is 10 to 95% and the weight percentage of the formula (VIII-2) is 3 to 40. %. 28. The composition according to item 5 of the scope of patent application, wherein the weight percentage of the formula (III-1-2) is 10 to 95%, the weight percentage of the formula (VIII-2) is 3 to 40%, and the formula (Ιχ-2) The weight percentage is 3 to 40%. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) Order --------- Line · Intellectual Property Bureau Staff, Ministry of Economic Affairs Printed by the Consumer Cooperative 513470 C8 — ^ 88100 ^^ 9 9Ππο ^ 9 / 9ΐ __D8________ VI. Application for a patent scope 29_ For the composition of item 6 of the patent scope, where the weight percentage of the formula (with-丨) is 10 ~ 95 %, The weight percentage of the formula (V_3) is 3 to 40%, and the weight percentage of the formula (VIII-2) is 3 to 40%. 30. The composition according to item 6 of the scope of patent application, wherein the weight-to-blade ratio of formula (IV-1) is 10 to 95%, the weight percentage of formula (VI-1) is 3 to 40%, and formula (X) ) The weight percentage is 3 ~ 40% 〇3 1 · If the composition of item 6 of the patent scope is declared, wherein the weight percentage of formula (ιν_ 1) is 10 ~ 95% and the weight percentage of formula (VI-1) It is 3 to 40% and the weight percentage of formula (XI-1) is 3 to 40%. 32. The composition according to item 6 of the scope of patent application, wherein the weight percentage of formula (m) is 10 to 95%, the weight percentage of formula (νΠΙ_2) is 3 to 40%, and the weight percentage of formula (Ιχ-2) It is 3 ~ 40%. 3 3 · The composition of item 14 in the scope of patent application, wherein the weight percentage of formula (I) is 10 to 95%, the weight percentage of formula (m) is 10 to 95%, and employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer cooperatives print agriculture. (Please read the notes on the back before filling out this page) (V_1) The weight percentage is 3 ~ 40% 〇3 4 · The composition of the material in item 14 of the scope of patent application, where the formula ( I) weight percentage of 10 to 95%, formula (m-ι) weight percentage of 10 to 95%, formula (V-1) weight percentage of 3 to 40% and formula (VM) weight percentage 3 ~ 40% 〇3 5 · The composition of item 1 $ in the patent scope of Shenyan, wherein the weight percentage of formula (I) is 10 ~ 95%, and the weight percentage of formula (m-ι) is 10 ~ 95 The weight percentage of% and formula (V-3) is 3 to 40%. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 513470 Hyundai Tak I / 91 ABCD VI. Scope of patent application (please read the precautions on the back before filling this page) 36. If you apply for a patent The composition of the range item 14, wherein the weight percentage of formula (I) is 10 to 95%, the weight percentage of formula (III-1) is 10 to 95%, and the weight percentage of formula (VIII-2) is 3 to 40. % And the weight percentage of formula (IX-2) is 3 to 40%. 37. The composition of item 14 in the scope of the patent application, wherein the weight percentage of formula (I) is 10 to 95%, the weight percentage of formula (Π1-2) is 10 to 95%, and formula (V-1 ) The weight percentage is 3 to 40%. 38. The composition of item 14 in the scope of patent application, wherein the weight percentage of formula (I) is 10 to 95%, and the weight percentage of formula (in-2) is 10 to 95%, weight percentage of formula (V ") is 3 ~ 40%, and weight percentage of formula (VI-1) is 3 ~ 40 ° / 〇〇39. If the composition of the scope of application for item 15 of the patent, where formula The weight percentage of (I) is 10 to 95%, the weight percentage of formula (III-2) is 10 to 95%, and the weight percentage of formula (V_3) is 3 to 40%. 40. The composition according to item 14 of the scope of patent application, wherein the weight percentage of formula (I) is 10 ~ 95%, the weight percentage of formula (ΠΙ-2) is 10 ~ 95%, and the employee of the Intellectual Property Bureau of the Ministry of Economic Affairs consumes The weight percentage printed by the cooperative (VIII-2) is 3 to 40% and the weight percentage of formula (IX-2) is 3 to 40%. 41. The composition according to item 14 of the scope of patent application, wherein the weight percentage of formula (I) is 10 to 95%, the weight percentage of formula (with -1) is 10 to 95%, and the weight of formula (乂 _1) The percentage is 3 ~ 40%. 42. If the composition of the scope of application for item No. 14, wherein the weight percentage of formula (I), the paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 513470 A8 B8 C8 9009 ^ 9/91 __________ 夂, the scope of patent application is 10 ~ 95%, the weight percentage of formula (IV-1) is 10 ~ 95%, the weight percentage of formula (vl) is 3 ~ 40% and the weight percentage of formula (VI-1) 3 ~ 4 ％% 〇43. If the composition of the scope of application for item No. 14, wherein the weight percentage of formula (I) is 10 ~ 95%, the weight percentage of formula (〖vl) is 10 ~ 95% and formula ( ν-3) The weight percentage is 3 ~ 40% ◦ 44. If the composition of the scope of application for item 14 of the patent, wherein the weight percentage of formula (I) is 10 ~ 95%, the weight percentage of formula (IV-1) is 10 to 95%, the weight percentage of formula (VIII-2) is 3 to 40%, and the weight percentage of formula (IX-2) is 3 to 40%. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is in accordance with China National Standard (CNS) A4 (210 X 297 mm)