TW508352B - 4-Haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidines, process for their preparation, compositions comprising them, and their use as pesticides - Google Patents

Abstract

The present invention relates to 4-haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclypyridines of the formula (I) , to processes for their preparation, to compositions comprising them, and to the use of these compounds for controlling animal pests, in particular insects, spider mites, ectoparasites and helminths. In the formula (I), Q is a 5-membered heterocyclic group which is optionally substituted by halogen or organic radicals, Yis halo-C1-C6-alkyl, X is CH or N and m is 0 or 1

Description

508352 ΑΊ _____ Β7 __ 5. Description of the invention (1) The present invention relates to 4-haloalkyl-3 heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidine compounds. Composition and the use of novel and known 4-haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidine compounds for controlling animal pests, especially insects, mites, Use of external parasites and worms. Certain appropriately substituted pyridine or pyrimidine compounds are known to have acaricidal and insecticidal activity. For example, W095 / 07891 describes a pyridine compound having a cycloalkyl group connected at the 4-position through a heteroatom and various substituents at the 3-position. W〇9 3/1 9 0 5 0 reveals 4-monocycloalkylamino- and 4-cycloalkoxypyrimidine compounds, these compounds carry, for example, alkyl, alkoxy or haloalkoxy in the 5-position base. However, the activity of these compounds against pests is not always sufficient. In addition, these compounds often have undue toxicity to mammals and aquatic organisms. DE-A 42 39 727 describes pyridyl-1,2,4-monothiadiazole compounds having fungicidal properties. The compounds disclosed therein carry a thiadiazole ring at the 2, 3 or 4 position of the unsubstituted pyridine. EP — A 0 3 7 1 925 reveals that some printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics of the Nematode (please read the precautions on the back before filling this page) and the fungicidal properties of 1, 3, 4 Diazolyl- and 1,3,4-thiathiazolyl-pyrimidine compounds. In the biologically effective compounds disclosed in this publication, the peak steepness is with an 11-oxadi D seat or a thiadi-π seat ring in the following manner: a) at the 5-position, and optionally thiomethyl Substitution at position 2, or b) at position 2, and optionally substitution of methyl at positions 4 and 6. Known by EP — A 0 1 8 5 2 5 6 It can be used as a pesticide. The paper size is applicable to the Chinese National Standard (CNS) A4 (21〇 × 297 metric t) 508352 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Aryltriazole derivatives of invention description (2). In addition to the particularly desirable phenyltriazole compounds, three haloalkyl-3-pyridyltriazole compounds were also revealed. • 3- (2-chlorophenyl) -1-methyl-5— (4 —Trifluoromethyl—3-pyridyl) —1 fluorene—1,2,4—triazole • 3 -— (2,6-difluorophenyl) —1-methyl—5— (4-trifluoromethyl) -3 -pyridyl)-1 Η-1,2,4 -triazole and • 3-(2-chloro-4 -fluorophenyl)-1 -methyl-5-(4-trifluoromethyl- 3-pyridyl) -1,1,2-, 4-triazole, but their activity is not always satisfactory at low application rates, especially when used to control insects and mites. Some commercially available 4-haloalkyl-3 -heterocyclylpyridines can be found in Maybridge Catalogue 1 996/1 997, Maybridge Chemical Co • Ltd., Trevillett Tintagel, GB: • 3 — (3, 5 — Dichlorophenyl) — 5 — (4-trifluoromethyl—3-pyridyl) —1,2,4 monooxadiazole • 5 — (4-trifluoromethyl—3-pyridyl) —3 — Phenyl-1, 2, 4, monooxadiazole • 3-(4-difluorofluoromethyl-3 —n-pyridyl) — 5-phenylphenyl 1, 2, 4 —oxadiazole • 5 — (2 —Chlorophenyl) —3— (4-trifluoromethyl—3-pyridyl) —1,2,4 monooxadiazole • 5 — (3-chlorophenyl) —3— (4-trifluoromethyl Base 3 —pyridyl) 1,2,4 —oxadiazole 1 (Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 × 297 mm) -5 -508352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 V. Description of the invention (3) • 5 — (4-chlorophenyl) — 3 — (4-trifluoromethyl — 3-pyridyl) — 1, 2 , 4 Dioxadiazole • 5 — (2-fluorophenyl) — 3 — (4 —trifluoromethyl — 3 —pyridyl) —1,2,4 —oxadiazole • 5 — (4 —fluorophenyl) — 3 — (4 —Trifluoromethyl—3-pyridyl) —1′2,4—dioxane, 2-n-sit • 5 — (2,4-dichlorophenyl) —3— (4-trifluoromethyl—3—pyridine) Radical) —1,2,4 —oxadiazole • 5 — (3 ′ 4-monochlorophenyl) — 3 — (4-trifluoromethyl-3 3-pyridyl) —1,2,4,4-oxadiazole • 5 — (3 '5 — monophenyl) — 3 — (4-difluoromethyl—3-pyridyl) —1,2,4 monooxadiazole • 5 — (2,6 —dichloro— 4 -pyridyl) -3-(4-trifluoromethyl -3-n-piridinyl) -1,2,4 -H 2 -dioxane • 5-(3,5-bis-diphenylmethyl) One 3 — (4 —dichloromethyl — 3 —diodine) — 1, 2, 4 — Dioxane • 2 — (2 —chlorophenyl) — 5 — (4—trifluoromethyl—3 —Hydridyl) — 1,3,4 —oxadiazole • 2 — (3-chlorophenyl) — 5 — (4-trifluoromethyl-3 —pyridyl) — 1, 3, 4 — oxadiazole • 2 — (4-monochlorophenyl) —5— (4-trifluoromethyl—3-pyridyl) —1,3,4 monooxadiazole • 2 — (2-trifluoromethoxyphenyl) A 5 — (4 —trifluoromethyl — 3 —pyridyl) — 1, 3, 4 — oxadiazole (Please read the precautions on the back before filling this page)

、 1T The scale of this slave is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -6-508352 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (4) • 2 — (4 — three Fluoromethoxyphenyl) 5 — (4-trifluoromethyl — 3-pyridyl) — 1,3,4 —oxadiazole • 2 — (4-trifluoromethyl — 3-pyridyl) — 5 —Phenyl-1, 3,4 —oxadiazole • 2 — (4-trifluoromethyl — 3-pyridyl) — 4 —methylthiazole carbohydrazine • 2 — (4-trifluoromethyl — 3-pyridyl)-4 -methylthiazolecarboxylic acid ethyl ester • N — (4- monofluorophenyl) carbonyl —N ′-[2- (4-trifluoromethyl—3-pyridyl) —4-methyl -5-thiazolyl] carbonylhydrazine • 2 — (4-trifluoromethyl-3-pyridyl) 4-thiazolylcarbamidine • 4 — (4-monochlorophenyl) — 2 — (4-trifluoro Methyl-3 —pyridyl) thiazole • 4 — (4-monocyanophenyl) — 2 — (4-trifluoromethyl — 3-11 than n-nyl) thiazole • Ν — (4-trifluoromethylphenyl) ) Carbonyl—N ′ — [2 — (4 Trifluoromethyl-3-pyridyl) -4-thiazolyl] carbonylphenone • 2- (2- (4-trifluoromethyl-3-pyridyl) thiazolyl) -5-chloro-3-methylbenzene Benzene [b] thiophene • 2 — (4-chlorophenylmethylthio) — 5 — (4-trifluoromethyl — 3 π-adenyl) — 1 — methyl — 1H — 1, 3, 4 — 3 Mouth seat • 2 — (4-chlorophenylcarbonylmethylthio) — 5 — (4-trifluoromethyl-3-pyridyl) — 1 —methyl — 1H-1, 3, 4 —triazole and • 2 —Ethoxycarbonylmethylthio — 5 — (4 —Trifluoromethyl — 3 —pyridine (please read the precautions on the back before filling out this page)-The size of the booklet is applicable to the national standard (CNS ) A4 specification (210X297 mm) 508352 Λ7 B7 V. Description of the invention (5-based) 1 —methyl-1 1 Η — 1 4 — m mouth sitting °

However, its biological activity against harmful organisms has not been revealed so far. The object of the present invention is to provide compounds which have good insecticidal and acaricidal properties and are low in toxicity to mammals and aquatic organisms. It has been found that the compound of the following formula (I) (which can be arbitrarily formed into a salt form) has a broader 'live 14 ® S' to animal pests than the compounds of the prior art, and has a more favorable toxicity to mammals and aquatic organisms彳 生 学 彳 生 W

Y, N, I (〇) m In formula (I), y is halogen a c Ο) C 6 courtyard; (Please read the notes on the back before filling in this card) • Equipment. Staff Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs X is CH or N; m is 0 or 1; Q is a 5-membered heterocyclic group of which X3

• N a) X 1-W »X 2 = NR a, X ^ CRbR1 or b) X ^ NR3, X ^ CRbR1 ,, x3 = W or this sheet size applies Chinese National Standard (CNS) A4 specification (21 OX 297 mm) 8 508352 ΑΊ Β7 V. Description of the invention (6) C) x 1 = V, X 2 CR a R 1, X 3 = NR 4 d) x 1 = V, X 2 = CR a R 2, X 3 = CR b R 3 or e) x 1 -V, X 2 — CR 4 R 5, X 3 and two CR 6 R 7 or f) x 1 = NR a, X 2 -CR b R 1, X 3 = NR 8. 1 R a and R b together are a bond V is oxygen, sulfur or NR £ I. T W is oxygen or sulfur; R 1 is hydrogen, (C 1 — C 2 〇) fluorenyl, (c 2 — C 2 0) alkenyl, (C 2 -C 2 0) alkynyl> (C 3 -C 8) cycloalkyl (c 4 — -C 8) iresg. Alkenyl, (c 6-C 8) ring The last six types of alkynyl groups mentioned in the following can be: intentionally one or more white selection (please read the notes on the back before filling this page) Substituted by groups: halogen, cyano, nitro, mesogen, —C (= W) R1CI, —C (—N 〇R 1 0) R 1 0,--C (= NNR 1 0 2):, —— C (-W) 0 R 1 0 Ϊ — C (= W) NR 1 〇2, -〇C (-W) R 1 0 5 — 〇C (-W) 〇R 10, -NR 1 0 C (— W) R 1 0, — N [C (=: W) R 1 0] -NR 1 0 C (= W) 〇R 1 0 J-C (-W) NR 1 0 — NR 1 0 2, -C (-W) NR 1 0 — NR 1 0 [C (= W) R 1 0], -NR 1 0 — C (= W) NR 10 2, -NR 1 0 — NR 1 0 C (=: W) R 1 〇, -NR 1 0 — N (C (= W) R 1 0] 2 »-N ((c = W) R 1 0] — NR 1 0 2 '-9- This sheet size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 Λ Β 5RRR- J ^ NNNC Ming II-(oooo ,!) ^ 1 lll issued RRRRRI NN NNN 〇 c

R R N N

R N 〇 1RR, R WN., Ο))) 1 ο ww wloR 1 II II il RN c c c \ My N) y ο ο

R N c

W

R R N 2 〇 s

R N R 2 〇 s 〇 s

R N 2 1 R 〇 R 2 〇 s 〇 R 〇 R s s

R

R 6 S --------: (Please read the precautions on the back before filling out this page) • Equipment. R p R \) y w

R 〇S -S〇2R10, a pw2R heterocyclic group,, a P w3 R 1, aryl group and printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, where the last two groups mentioned can be optionally Substituted by one or more groups selected from: (Ci-C6) alkyl, (C2-c6) alkenyl, (c2-C6) alkynyl, (c3-c8) cycloalkyl, (C4-c8 ) Cycloalkenyl '(c6-c8) cycloalkynyl, (Ci-Ce) haloalkyl, (c2-Ce) haloalkenyl, (C2-c6) haloalkynyl, halogen, -ORiO, -NR102 , One SR10, one SiRi〇3,

—C (= W) Ri〇, — C (= W) 〇R —C (= W) NR102, one S 0 R 1 0 I

S〇2 R nitro, cyano and hydroxy, aryl, which can be optionally substituted by one or more groups selected from the following. This standard is applicable to the national standard (〇 奶) 6 4 specifications (210 ' / 297 mm) -1〇_ t 508352 Λ7 ____ B7 V. Description of the invention (8) (Cl—C6) courtyard, (C2_Ce) alkenyl, (C2 -◦6) alkynyl, (C3-c8) ring Alkyl, (C4-C8) cycloalkenyl and (C6--C8) cycloalkynyl, wherein the above six groups can be optionally substituted by one or more groups selected from the group consisting of: halogen, cyano , Nitro, —C (= W) R 1 〇, (= W) 〇R10,--C (two W) NR102, R 10,-NR 1 0 2, -SR ", -S0Ri〇 and

1 S 〇 2 R group R chlorine 0, N element II halide. C c R W II Γν c-nitrate

R c c

R N N

R c R 〇w R N ΝΛί / w c 〇

Rw c 〇 R 〇 \) / w

Rw II co o IX R N Ν Printed and produced by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

C RIO) N s 2w--o -1 one one; R XV 2 1 3 c Rlow [o R p

R

R (s c I 0, 1 o R 2 N R o I s s

R) 1 w w R p R 〇

R selects the number of groups in the list, or selects 1 or 2 as the meaning, and the ring may be heterocyclic, and 1-based alkyne

C

C

C-C-Cane

6 C

-4ene C

C

Under the C-based alkenyl ring, you can choose more than 1 or 1 as the ground, which can be any group. The basic type of alkyne hexacyclic ring is described above in I 6. The C and its specifications are applicable to China National Standard (CNS) A4 specifications. (210X297 mm) 508352 Λ7 V. The description of the invention (9) is replaced by the group: halonitronitrocyanide R \ Ϊ7 W IIc c R 〇 \) yw

C

R N \) y W R c R 〇 N〇 〇 s

R R \) yw II / (Vc R \) yw II Γνc \ _ / Ν w

R

R N and ο 10RR ο 〇 S) -W, ο II 1 (R c S 〇 1-nitronitrocyano halide

Rw IIc

C

R 〇 \ ly W

C

R N W 1T (Please read the notes on the back before filling out this page) • Install. C 〇

W

R R 〇

R N

Rs

R 2 〇 S I and ο IX R 〇 S R 〇

R N

R S

R 〇 S o (s c

R

R \) yw II ^^ V C

R 〇 N

R Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs

c c 〇N

R N N R N NIJ / w

R

C

R 〇 \) y W c 〇

Rw

Rw II / (\ c o R N I o o Tx IX R R 〇 N) /) ww I a -I ((c c (

c o IX R N R 〇 \) / w 2 1 c

(R R R CNNN w w

o o IX IX

R N

R N

R N

(R c CNN w c RRWR N N-)-) (w o o T * Tx

RR \ Jyw IIc This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -12- 508352 A7 _ B7 V. Description of the invention (1〇) -N (C 2W) R 1 0 _ -NR 1 0 2 -NR 1 0 -NR 1 0 C (C = W) R 1 0], -NR 1 0 —NR 1 0 [(C = W) WR 1 0] 7 -NR 1 0 -NR 1 0 C ( C 2 W) NR 1 〇2) y -NR 1 0 (C = NR 1 0) R 1 0 >-NR 1 0 (C = NR 1 0) NR 1 0 2, -〇NR 1 0 2 y- 〇_NR 1 0 (C-W) R 1 0 -S 〇2 NR 1 0 2 5} — NR 1 0 S 〇2 R 1 0, -S 〇2 〇R 1 0 9 -〇S 〇2 R 1 0 -SC (two = W) R 10:--SC (: two W) 〇R 1 〇, one SC (-: W) NR 1 ° 2 y one -PR 1 〇2 one PW 2 R 1 0 2 , -PW 3 R 10 2, S i R103 or halogen (please read the notes on the back before filling this page) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs R2 and R3 have the definitions in R1 independently of each other ; R2 and R3 together form a 5 to 7-membered ring, which may be partially or completely unsaturated and may be interrupted by one or more atoms selected from nitrogen, oxygen and sulfur Atom 'but two or more oxygen atoms are not directly adjacent to each other, and the ring may be optionally substituted with one or more (but up to 5) R 1 groups; R 4 and R 6 each independently have one of R 1 Definition; R4 and R6 together form a 4 to 7-membered ring, which may be partially or completely unsaturated and may be interrupted by one or more atoms selected from nitrogen, oxygen, and sulfur, but more than two oxygen atoms Are not directly adjacent to each other, and the ring may be optionally substituted with one or more (but up to 5) R 1 groups; R 5 and R 7 are each independently hydrogen, (c χ — C 2 〇) Alkyl, (C2-C2.) Alkyl, (C2-C2Q) alkynyl, (C3-C8) This standard is applicable to China National Standard (CNS) A4 (210X297 mm) -13-508352 Λ7 2. Description of the invention (11) cycloalkyl, (C4-c8) cycloalkenyl, (c6-c8) cycloalkynyl, wherein the last six groups mentioned can optionally be one or more selected from the following Replaced by groups: Halogen, cyano > nitro, hydroxyl, — 1 C (di-W) R i 〇-C ( N 〇R 1 0 1) R 10, -C (NNR 1 0 2) R 1 0 — c (two: W) 〇 R 1 0-C (= W) NR 1 〇2 y a -〇c (:- w) R 1 0, 〇C (= W) 〇R 1 0 y — NR 1 0 c (= W) R 1 0 -N [C (r = W) R.1 0] 2, -NR 1 0 C (= W) 〇R 1 0 -C (W) NR 1 0 — NR 1 0 2 —C (— W) NR 1 0 — NR 1 0 (C (= W) R 1 0] -NR 1 0 — C (= W) NR 1 0 2 -NR 1 0 — NR 1 0 C (= W) R 1 0, -NR 1 0 — N (C (= W) R 1 0) 2 »-N ((C- W) R 1 0] — NR 1 0 2, -NR 1 0 — NR 1 0 ((C = W) R 1 0], -NR 1 0 — NR 1 0 ((C = W) WR 1 0], -NR 1 0 — NR 1. [(C — W) NR 1 〇2], -NR 1 0 (C-NR 1 0) R 10, -NR 1 0 (C 2 NR 1 0) NR 1 0 2 -〇— NR 1 0 2 5- 〇- -NR1 0 (C = W) R 1 〇, -0Ri〇, -NRi〇2, -SRi〇, -S i Rio-Se R 1 0, -PR 1 0 2, -P (= W ) R 1 0 2, 1Γ (Please read the notes on the back before filling out this page)-Installation · This paper size applies Chinese National Standard (cns) A4 specification (21 ox297 mm) 508352 Λ7 ______ B7 V. Description of the invention ( 12) -S〇R1〇,-SO2R10 ^-PW2R102 > — PW3R1 () 2, aryl and heterocyclic group, (Please read the precautions on the back before filling this page) The last two groups mentioned The group may be optionally substituted by one or more groups selected from the group consisting of: (Cl—C6) an alkyl group, (C2—C6) an alkyl group, (C2 — C6) an alkynyl group, and (c3 — c8) a cycloalkyl group. , (C4-c8) cycloalkenyl '(C6-C8) cycloalkynyl, (Ci-c6) haloalkyl, (c2-C6) haloalkenyl, (C2-C6) haloalkynyl, halogen, -OR10 , -NR1〇2, _SRi〇, _SiRi〇3, -c (= W) R10, -C (= W) OR10, -c (-W) NR102, -S. R10, a S02R10, a nitro'cyano group and a mesityl group, which are optionally substituted by one or more (Ci-C6) alkyl, (C2-C6) ene groups (C2-C6) alkynyl, (c3-c8) cycloalkyl, (C4-c8) cycloalkenyl and (C6-C8) cycloalkynyl, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs The above-mentioned six groups may be optionally substituted by one or more groups selected from the group consisting of: halogen, cyano, nitro, —C (= W) R10, —c (diW) —R10, — C (= W) NR102 ,. -〇R10, -NR " 2, -SR ", -S〇r " and -S〇2 R 1 0, halogen, cyano, nitro, -C (= W) R10 , -15- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 Λ7 B7 V. Description of the invention (13) C (: two N 〇R 1 0) R 1 0, C (: two NNR 1 0 2) R10,-C (= W) OR10 C (two = W) NR102, -0C (= W) R10, -〇C (= W) OR10, -NR10C (= W) R10, -N [ C (= W) R10] 2, —NR10C (two W) 〇R10, -〇R10, -NRi〇2, -SR ", -Si Ri〇3, -PRi〇2 -S〇Ri〇,-S〇2Ri〇, -PW2R102 and -PW3R102; pyridyl, which may be optionally substituted with one or more groups selected from: '(Ci-c6) alkyl, (C2 — C6) alkenyl, (c2 — C6) fast radicals' (C3-C 8) cycloalkyl, (C4-C8) cycloalkyl and (c6-c8) cycloalkynyl, among which the above six groups It can be optionally substituted by one or more groups selected from the group consisting of: cyano, nitro, halogen, a C (= W) R10, a C (= W) printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. R10, — C (= W) NR102, —〇R ", one NR " 2, one SR ", one S〇R " and -S 〇2 R 1 0, halogen, cyano, nitro, -C (= W) R1C), —C (two W) 〇R10, —C (—W) NR1%, —0C (—W) Ri0, —OR ", —nri〇2, —SR10, —SOR10 and 1 S〇2R10; -16- (Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 508352 hi ____ B7 V. Description of the invention (14) --C (= W) R 1 0 »-c (= N〇R10) R10 -C (= NNR102) R10, one c (= W) OR10 »one C (= W) NR102 or halogen; R 4 and R 5 together form a 4 to 7-membered ring, which may be partially unsaturated and may be One or more atoms selected from nitrogen, oxygen, and sulfur interrupt the carbon atom, but two or more oxygen atoms are not directly adjacent to each other, and the ring can optionally be one or more (but up to 5) R 1 groups R4 and R5 together form a = 0, or = N — R9 group; R6 and R7 together form a 5 to 7-membered ring, which may be partially unsaturated and may be one or more selected from nitrogen, The oxygen and sulfur atoms interrupt the carbon atom, but two or more oxygen atoms are not directly adjacent to each other, and the ring can be optionally substituted with one or more (but up to 5) R 1 groups; R6 and R7 Jointly formed = 〇, = S or = N — R9 groups; R8 is printed by hydrogen, (Ci—C6) alkyl, (C2—C6) alkenyl, (C2—C6) Alkynyl, (C3-C8) cycloalkyl, (c4-C8) cycloalkenyl, (C3-C8) cycloalkyl- (Cl-C4) alkyl, (C4-C8) cycloalkyl-(Cl- C4) courtyard base, (C3—C8) cycloalkyl— (c2—C4) Alkenyl, (c4--C8) cycloalkenyl- (Cl-〇4) canyl '(Cl-C6) courtyard group-(C3-C8) cycloalkyl group' (C2-C6) alkyl group-(C3-C8 ) Cyclosyl, (C2-C6) alkynyl- (C3-C8) Cycloyl, (Cl-C6) Cycloyl- (C4-C8) Cycloalkenyl, (c2-C6) alkenyl- (c4-- C 8) Cycloalkenyl, the last fourteen types mentioned in the above can be freely selected from one or more -17- (Please read the precautions on the back before filling this page) This I-scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 508352 Λ7 ____ ______ 5. Description of the invention (15) Replaced by the following groups: halogen, cyano, nitro, hydroxyl, thio, amine, formamyl , (Cl ~ c6) alkoxy, (c2-c6) alkenyloxy, (c2-c6) alkynyloxy, (Ci-c6) haloalkoxy, (C2-c6) haloalkoxy '(C2 — C6) haloalkynyloxy, (C3-C8) cyclohexyloxy '(C ^ -Ce) cycloalkenyloxy, (C3-C8) halocyclohexyloxy' (C4-C8) halocycloalkenyloxy , (C3—Cs) ring courtyard— (Cl—C4) courtyard oxygen, (C4—C8) cycloalkenyl— (Cl—C4) courtyard Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) (C 3 — C 8) Huanyuan Jiyi (C2 — C4) Corrective Oxygen, (C4 — ◦8 ) Ring storage base— (Cl—C4) flammable oxy group, (Cl—C6) $ Wood —— (C3—C8) cyclic alkoxy group, (C2—C6) keto group— (C 3 — ◦8) Circumferential group Oxy, (C2-C6) alkynyl- (C3-C8) cycloalkyloxy, (Ci-C6) alkyl- (C4-C8) cycloalkenyloxy, (◦2-C6) alkenyl- (C4 — C8) cycloalkenyloxy, (Ci—C4) oxo- (Cl-C6) oxo, (Cl-C4) oxo- (C2—C6) alkenyl, aminoformamidine, ( Ci-Ce) mono- or dialkylaminoformamidine, (Ci-Ce) mono- or dihaloalkylaminoformamidine, (C 3-C8) mono- or dicycloalkylaminoformamidine, (Ci- Ce) alkoxycarbonyl, (Cs-C8) cycloalkoxycarbonyl, (Ci-Ce) alkanoyloxy, (C 3-C 8) cycloalkanoyloxy, (C i -C 6) haloalkane Oxycarbonyl, (Ci-Cs) haloalkanoyloxy, (Ci-C6) alkanoylamino, (C1-C6) dentamine amine group, (C2-C6) flammable S female group '( C3-C 8) Alkylamine, (C 3 —C 8) cycloalkyl— (C i -C 4) amido, (Cl -C6) sulfur plug, (C2-C6) basic sulfur paper standard applicable to China Standard (CNS) A4 specification (210X297 mm) _-508352 Λ7 B7 V. Description of the invention (16)

C / IV thioalkyne, sulphanyl 6thioCene 1 halide 2 Nly C (C

c C Sulfur 6: alkyne C halo sulfanyl halide

C

2 8 c C alkane C 3 (C > / (radical

C

C

C

C-Cyclohaloane) CycloC-Cylothio

C

C C κίν

C

C C group I alkane 4 ring alkene ring

C

C

C Thiene C / (V-based olefin ring

C-based alkane ring 8) group C sulfur I alkane ring 8 C-3 C / IV I group

C C group _ sulfur

C

C C / 1 \

C

C alkene C I alkyne (Please read the notes on the back before filling out this page) C sulfane ring

C alkane

C

c C 2 2

c c C 6 6 6 I C-based C-olefin,} sulfonyl 2-alkylene ()

6 C

C 1 C C (Γχ, ′ 醯 sulfonylsulfonylene

c C

C group, thiosulfenyl_enesulfonyl C4 ring C > yl I sulfonyl ring, fluorenylsulfonylsulfonylidene alkynyl halide halide} 3 C 醯 c C

C

C

C alkanes)

C -C! 4 (C C, (C 醯 I, sulfofluorene alkylene sulfocycloalkylene) radical 8

C

C

C fluorenylsulfonyl sulfenesulfonylidene halidene alkene ring printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

C

C / IV 8-based C-alkane

C

C I C / TV I group C alkenyl ring group alkane 8 ring C

C

C 醯 sulfinylene alkyl 醯 sulfinylene alkenyl ring C Γν

醯 C sulfo C sulfenyl_enesulfonyl} sulfenyl 4 alkane 1 cyclic 1 C 8 (C

C

c C 4 6

C-based alkenylene c C ring 3 8 C ring sulfinylenesulfinylene sulfonium

C

c C (I 6 group C C alkane C 1) I 2 6 group c C-storage alkyne

C

C 4 olefin ring paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) -19- 508352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7. Description of the invention (17) Glycolic acid, (Cl —C6) nodular mineral acid, (C2-C6) sulfanyl sulfide, (c2-c6) alkynylsulfonium, (Ci — c6) haloalkylsulfonium, (C2 — C6) haloalkenylsulfonium, (C2-C6) haloalkynylsulfonium, (c3-c8) cycloalkylsulfonium, (C4-c8) cycloalkenylsulfonium, (c3-c8) halocycloalkylsulfonium, (C4-c8) Halocycloalkenyl sulfonium, (C3—C8) ring courtyard— (Cl—C4) courtyard based brewing, (C 4—C8) cyclopentyl— (Cl—C4) courtyard extended acid, (C3—C8) ) Cycloalkyl- (C2-c4) alkenylsulfonium, (c4-c8) cycloalkenyl- (Ci-C4) alkenylsulfonium, (Ci-c6) alkyl- (c3-c8) cycloalkyl Sulfonium, (C2-c6) alkenyl- (c3-c8) cycloalkylsulfonic acid '(C2-C6) alkynyl- (C3-C8) cycloalkylsulfonic acid, (Ci-c6) alkyl- ( C4-c8) cycloalkenylsulfonium, (C2-c6) alkenyl- (C4-c8) cycloalkenylsulfonium, (Ci-Ce) alkylalanyl '(C2-C6) amine storage (C2-C6) fast amino, (Ci-c6) haloalkylamino, (C2-c6) haloamino, (c2-c6) haloalkynyl, (c3-c8) cycloalkylamino (C4-C8) cycloalkenylamino, (C3-C8) halocycloalkylamino, (C4-C8) halocycloalkenylamino, (C3-C8) cycloalkyl- (Ci-C4) alkylamino , (C4—c8) cycloalkenyl— (Ci—C4) alkylamino, (c3—c8) cycloalkyl— (C2—C4) enamine, (C4—c8) cycloalkenyl— (Cl—C4) ) Amino group '(Cl—C6), C —— (C3-C8) cycloalkylamino, (c2—c6) alkenyl— (c3—c8) cycloalkylamino, (C2—C6) alkynyl— ( C3— C8) cyclic amine group, (Cl — C6) cyclic group — (C4 — C8) cyclic alkenyl group, (C2 — C6) alkenyl group (please read the precautions on the back before filling this page)

This I-scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297g) 508352 Λ7 ____ B7 _ 5. Description of the invention (彳 8)-(C4-C8) cycloalkenylamine, (Ci-Ce) trioxane Methylsilyl, aryl, aryloxy, arylthio, arylamino, arylaminoformamidine, arylfluorenyl, arylfluorenyloxy, aryloxycarbonyl, aryl- (Ci-C4) alkoxy , Aryl- (C2-C4) alkenyloxy, aryl- (Ci-Cd) alkylthio, aryl- (C2-C4) alkenylthio, aryl- (Ci-C4) Alkylamino, aryl- (C2-C4) enamino, aryl- (Ci-C6) dialkylsilyl, diaryl- (Ci-Ce) alkylsilyl, triarylsilane And 5- or 6-membered heterocyclyls, the last nineteen of which are mentioned may optionally be substituted on their ring portion with one or more substituents selected from the group consisting of halogen, cyano , Nitro, amine, hydroxy, thio, (C i -C 4) alkyl, (C i -C 4) haloalkyl, (C i-C 4) alkoxy, (Ci -C4) Haloalkoxy, (Ci-C4) alkylthio, (Ci-C4) halothio, (Cl-C4) Amine group, (Cl — C4) halogen alkylamino group and (Cl — C4) amino group; aryl group, which can be optionally substituted by one or more groups selected from the following (please first (Please read the notes on the back and fill in this page.) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

C-based fluorenyl methylamino thiol hydroxy nitro cyano halide

C group C oxygen C alkyne, > group

C C / (\ oxane

C

C

C C / V-

C ring, halo}} methyl -8 group 4 C amine C I group halo} oxygen 6ene ring

C group C oxygen C alkane ’halo} oxy alkyne

C / (V methylaminooxene

C

C alkane

C

C oxygen C 0 halo 3 oxygen 6 alkane C ring} oxo alkane C ring one, halo 1 C group 8) c ore C, group |

C / (V

C alkane di} or mono

C This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm) _ ^-508352 hi B7____ V. Description of the invention (19) Oxygen, (Ci-Ce) mono- or dihalo-aminoaminomethane , (Ci-c6) haloalkoxycarbonyl, (Ci-c6) haloalkanoyloxy, ((^ -c6) haloamidoamino, (Ci-C6) haloalkanoamido, (C2-c6)) Alkenylamino, (Ci-c6) alkylthio, (c2-c6) alkenyl '(C 2-C 6) fast thio' (Cl-C6) pentylthio '(C 2 Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the notes on the back before filling out this page) —C6) halothione, (C2—C6) haloalkynethio, (C3-C8) cycloalkylthio, ( C4-c8) cycloalkenylthio, (c3-c8) halocycloalkylthio, (C 3-C 8) halocycloalkenylthio, (C i -C 6) alkylsulfinylfluorene, (C2-c6 ) Alkenylsulfinyl sulfonium, (C2-C6) alkynylsulfinyl sulfinium sulfonium, (Ci-Ce) haloalkylsulfinyl sulfinium sulfonium, (C2-C6) haloalkenyl sulfinium sulfide, (C2-C6) haloquinyl Subminerals' (C3-C8) ring, fluorenylsulfinylpyrene, (C4-c8) cycloalkenylsulfinylpyrene, (c3-c8) halogen ring (C4-C8) halocycloalkenylsulfenyl sulfonium, (Ci-Cs) alkylsulfonium sulfonium, (c2-c6) alkenylsulfonium sulfonium, (C2-c6) alkynylsulfonium sulfonium, (Ci — C6) haloalkylsulfonium, (C2-c6) haloalkenylsulfonium, (c2-c6) haloalkynylsulfonium, (c3-c8) cycloalkylsulfonium, (C4-c8) cycloalkenyl Sulfonium, (c3-c8) halocycloalkylsulfonium, (C4-c8) halocycloalkenylsulfonium, (Ci-c6) alkylamino, (C2-C6) enamino, (C2-c6 ) Alkynylamino, (Ci — C6) aralkylamino, (C 2 -C 6) halenamino, (C 2 -C 6) halynylamino, (Cs — Cs) cycloalkylamino, ( C4—c8) cycloalkenylamino '(C3-c8) halocycloalkenylamino and (C4—C8) halocycloalkenylamino, —C (—W) R 1 1, OR11 or NR11〆R9 is (Cl— C6) Yuanji's (C2—C6) Suspect's (C2—This k-sheet scale is subject to the China National Standard (CNS) A4 specification (210X297mm) _ 22 _ 508352 A1 V. Description of the invention (20)

Ce) alkynyl, (C3—Cs) cycloalkyl, (C4—Cs) cycloalkenyl, (c3—c8) cycloalkyl— (Cl—C4) alkyl, (C4—c8) ring storage—— Cl-C4) Cyclosyl (C3-Cs) ring-Cyclosyl— (C2-C4) alkenyl, (C4-Cs) cycloalkenyl- (Cl-C4) storage base, of which the last nine are mentioned The group can be optionally substituted by one or more groups selected from the group consisting of: halogen, cyano, (Cl-C6) oxy, (C2-Ce) alkenyl, (C2-C6) alkynyloxy And (Cl-c6) haloalkoxy; R1Q is a gas, (Cl-C6) alkynyl '(C2-C6) alkynyl' (C2-C6) alkynyl, (C3-C8) cyclic alkynyl '(C4 — C8) cycloalkenyl, (c3-c8) cycloalkyl— (Ci—C4) alkyl, (C4—Cs) cycloalkenyl— (C1—C4) cycloalkyl, (C3—C8) cycloalkyl — (C2-C4) alkenyl, (C4—C8) cycloalkenyl— (Cl—C4) alkenyl printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs— (Cl—C6) courtyard —— (C3—C8) "Cyclopentyl" (C2-C6) Suijiyi (C3-C8) Cuanji '(C2 ~ C6) Kuaiji-(C3-C8) Cyclodol, (Cl-C6) Chongji-(C4 —C8) Cyclocyclyl '(C2-C6) Cycloyl— (C4—C8) cycloalkenyl, wherein the last fourteen groups mentioned can optionally be one or more groups selected from Replaced by: halogen, cyano, nitro, hydroxy, thio, amine, methyl, (Ci-C6) alkoxy, (C2-c6) alkenyl, (c2-c6) alkynyloxy, (C i -C 6) haloalkoxy, (C 2 — c 6) haloalkoxy-23- (Please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) 508352 Λ7 B7 V. Description of the invention (21)

Base C

C

C group C oxy C alkyne, halo} oxy 6ene C ring

Alkoxy, fluorenyl alkylene oxide 8) ring C halo 1) 3 8 c C C group monoene 3 ring C \) / / 1 \ 8, C group I oxygen 4 ene C ring C halide,} group 00 oxygen C alkane

c C

Radical C1 垸 () 4 -C radical C4

C-based alkane ring

C

C / (V

C 4 oxenyl, 4) C 4 oxen | ene 2 Λ—y C 4 (C

C

C alkane C Γν 8) group C oxygen

, C group _ oxygen 2 alkane ring), C 00 group I C oxygen 1 I alkane C 3 ring C

C / IV alkyl C / (\

C C / (\ I alkenes

C

Alkyl 3 to alkenyl C ring () 8 -C Alkyl alkyne 4 \ 1 / C 6 / IV Alkane ring (Please read the precautions on the back before filling this page) C I 1 'Oxane.CC) ( Alkenes

C-based-oxygen cl_

6 (C

C

C_alkyldioxy or alkane \) y 4 6, c c group 1 1 oxygen 1 1 alkenyl ring 8) yl fluorene C oxymethyl I alkyl 4} amine

c C / (V / IV

A C

C / IV

Or ‘一, _ 3 醯} C 8 C

C-based oxo, alkoxy 醯, alkane 醯} > St. 6 6 methyl c C-based I I amine 1 1 alkane halide,, fluorenyl or methylcarbonyl mono} amineoxy e alkane e alkane ring one ring}

/ IV

c C 3 1 c C / (\ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

C

,, C-based group {oxygen oxygen, fluorenyl alkaneamine ring halide \ j, courtyard 8 6 halogen c C

6 6 c C I I IX IX c C / (V / (V

C carbonyl, aryloxyamine, alkylhalohaloalkylamine}} pinene C alkane I) 3 4 group c C thiocyclic amine 醯

C group, -thio 1 alkynamine: pinane

C / IV

3 \] y G 6 (C

C

8 group | C sulfur 1 I alkane C alkane ring C / (\

C 6 (C ene

C-based sulfan halide-) ^ 2 00 ring c C halide C-thiosulfanyl halide 4 C-/ (\ 4, C-based C-sulfur 'alkyl radical thioalkyne, C-halogen radical,} thio radical 6) Sulphur C cycloolefin I 彡 ring 2 8 halo c C)

C 3 (CI) ring 3 8 \) χ c C 8 (| C 丨 3 | This narrative scale applies the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) -24- 508352 Λ7 B7 V. Description of the invention (22 ) (Please read the notes on the back before filling this page)

The Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed alkyl-1 (C 1-C 4) 1 thiol '(C 4-C 8) ring-based 1 (C 1-~ C 4:〉 alkylthio, (C 3 — C 8) Cycloalkyl — (C 2 — C 4) alkenylthio, (C 4 —C 8) cycloalkenyl — (C 1 — C 4) sulfur storage group> (C 1-C 6) Yuanjiyi (C 3 — 丨 C 8) cycloalkylthio, (C 2-C 6) > Alkenyl— (C 3 — C 8) cycloalkylthio y (C 2-C 6) alkyl— (C 3 — C 8) Cyclothio, (C 1 -C 6) fluorenyl— (C 4 —C 8] > Cyclothio, (C 2 -C 6) alkenyl — (C 4 — C 8) cycloalkenylthio, (C 1 -C 6) alkenylsulfinylsulfonium (C 2 -C 6) alkenylsulfinylsulfonium (C 2 -C 6) pyridinylsulfinylpyrene (C 1-C 6) Haloalkylsulfinium sulfonium (C 2 -C 6) halosulfanylsulfinium sulfonium 9 (C 2 -C 6) halosulfinyl sulfination, (C 3 -C 8) cycloalkylsulfinyl sulfinium sulfonium 9 (C 4 -C 8) cycloalkenylsulfenylsulfonium, (C 3 —C 8) halocyclofluorenylsulfinyl sulfonium (C 4 —C 8) halocycloalkenylsulfinyl sulfinium, (C 3 —C 8) Naphthenic — (C 1 -C 4) Cyclosulfenyl, (C 4 —C 8) cycloalkenyl — (C 1 -C 4) alkylsulfinyl sulfonium, (C 3 -C 8) cycloalkyl- ( C 2 — C 4) Alkenylsulfinyl sulfonium, (C 4-~ C 8) Cyclothione (C 1-C 4) alkenyl i, fluorene, (C i — C 6) 1 C 3-C 8) Cycloalkane: yl: sulfinylsulfonium> (C 2-C 6) alkenyl- (C 3 -C 8) cycloalkylsulfinylfluorene> (C 2 -C 6) alkynyl — (C 3 — C 8) cycloalkylsulfinylsulfonium, (C 1 —C 6) Cycloyl (C 4 —C 8) cycloalkenylsulfinylsulfonium, (C 2 —C 6) alkenyl — ( C 4 — C 8) cycloalkenyl sulfenylsulfonium, (C] L — C 6) alkenylsulfonium sulfonium (C 2 — C 6) alkenylsulfonium sulfonium, (C 2-C 6) alkynylsulfonium sulfonium ( C 1 —C 6) _Sulchisulfonium, (C 2-C 6) halenylsulfonium (G 2 —C 6) halynylsulfonium sulfonium > (C 3 -C 8) Cyclosylsulfonium ('C 4 — — C 丨 8) Cycloalkenyl sulfonium This standard applies to Chinese National Standard (CNS) A4 (210X297 mm) 508352 Λ7 B7 ___ 5. Description of the invention (23), (c3— c8) Halocycloalkylsulfonate醯, (C4-c8) halocycloalkenyl sulfonate, (C3-C8) cyclic alkenyl-(Cl-C4) alkanoic acid '(C4-C8) cycloalkenyl-(Ci-C4) alkylsulfon Rhenium, (C3-C8) cycloalkyl- (c2-C4) alkenylsulfonium, (C4-C8) cycloalkenyl- (Ci-C4) alkenylsulfonium, (Ci-C6) alkane Base one

Cs-C8) cycloalkylsulfonium, (C2-C6) alkenyl (C3-c8) cycloalkylsulfonium, (c2-C6) alkynyl-(C3-c8) cycloalkylsulfonate, (Cl —C6) Yuanyi (C4—C8) cycloalkenyl sulfonium, (c2—c6) alkenyl— (C4—c8) cycloalkenyl sulfonium ′ (Ci—C6) alkylamino, (C2—C6) Refined amine group '(C2-C6) fast amine group, (Cl-C6) haloalkylamine group, (C2-C6) haloamine group' Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (C 2-C 6) Haloalkynyl, (C 3-C 8) cycloalkylamino, (C 4 -c8) cycloalkenylamino, (c3-c8) halocycloalkylamino, (C4 -C8) halocyclodiamine, (C3—C8) ring courtyard— (Cl—C4) courtyard amine group, (C4—C8) ring burning group— (Cl—C4) fct; S female group '(c3—c8) cycloalkyl— (C2— C4) enamino, (C4—c8) cycloalkenyl— (Ci—C4) enamino, (Ci—C6) alkyl— (C3—C8) cycloamino group, (C2—C6) alkyl— (C3-C8) cycloalkylamino, (C2-C6) alkynyl- (C3-C8) cycloalkylamino, (Ci-c6) alkyl- (C4-C8) cycloalkenylamino, (C2 — C 6) alkenyl — (C 4 — C 8 ) Cycloalkenylamino, (C! -C6) trialkylsilyl, aryl, aryloxy, arylthio, arylamino, aryl- (Ci-Cd) alkoxy, aryl- (C2—C4) alkenyl'aryl group— (Cl—C4) sulfanyl group, aryl group— (C2—C4) sulfanyl group ”—26- (Please read the precautions on the back before filling this page ) This narrative scale applies the Chinese National Standard (CNS) AA specification (210X297gt). Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 24) mono (Ci-C4) alkylamino, aryl- (c2-C4) enamino, aryl- (Ci-C6) dialkylsilyl, diaryl- (Ci-Ce) alkyl Silyl, triarylsilyl and 5-or 6-membered heterocyclic groups The last fourteen groups mentioned in them may optionally be one or more groups selected from the group consisting of Replaced by: halogen, cyano, nitro, amine, hydroxyl, thio, (C i-C 4) courtyard, (Cl-C4) _ courtyard, (C3-C8) fe courtyard, (Cl- C4) courtyard oxygen, (Cl —C4) halogen courtyard oxygen, (Cl — C4) Sulfuryl group (Cl — C4) Halosulfanyl group, (Cl ~~ C4) Haloamine group, (Ci-Cd) Haloalkylamine group, Formamyl group and (Ci — Ci) Sulfuryl group Aryl, 5- or 6-membered heterocyclyl, in which the last two groups are optionally substituted with one or more groups selected from the group consisting of: halogen, cyano, nitro, hydroxy, Thio, amine, formamyl, (Ci-C6) oxo, (C2-Ce) alkoxy, (C2-Ce) alkynyloxy, (Ci-c6) haloalkoxy, (c2- c6) haloalkoxy, (C2-C6) halooxy, (C3-C8) cycloalkenyloxy, (c4-Cs) cycloalkenyloxy, (C3-C8) halocycloalkoxy '(C4 -C8) Halocycloalkenyloxy 'aminoformamidine, (Cl -C6) mono- or dialkylaminoformamidine, (C 1 -C 6) oxycarbonyl' (C 1 -C 6) Oxy, (Cl — C6) mono- or dihaloalkylaminomethyl, (Cl — Ce) halooxycarbonyl, (Cl —Ce) haloamidooxy '(Ci — (Read the first (Please fill in this page again)

This scale is applicable to China National Standard (CNS), A4 size (2 丨 0X 297 mm) · 27 _ 508352 Λ7 B7 · · ---------- --------- -, ----------- ----------------------- 5. Description of the invention (25) 〇6) Amine base , (Cl—C6) halofluorenylamino ”(C2—C6) alkenamino, (Ci-C6) alkylthio, (C2-C6) alkenylthio” (C2-C6) alkyne Thio, (Cl-C6) halosulfanyl '(C2-10) halosulfanyl, (C2-C6) haloalkynyl' (C3-C8) cyclohexylthio, (C4-C8) ring Alkenylthio, (C3-C8) halocycloalkylthio, (C 4 --C 8) halocycloalkenylthio, (C i -C 6) alkylsulfinyl M, (C2-C6) Acid expansion, (C2-C6) alkynyl sulfenyl, (Cl-C6) haloyl sulfinyl, (C 2-C6) halo sulfinyl sulfinyl, (C 2-C 6) halynyl sulfinyl Rhenium, (C 3 -C 8) cycloalkylsulfinylsulfonium, (C 4 -C 8) cycloalkenylsulfinylsulfonium, (C 3 -C 8) halocycloalkylsulfinylsulfinium, (C4 -C8) Halocycloalkenylsulfinium sulfonium, (Ci — Co) alkylsulfonium sulfonium, (C2-C6) alkenylsulfonium sulfonium, (C2-C6) alkynylsulfonium sulfonium, C i -C 6) haloalkylsulfonium, (C 2 -C 6) halenylsulfonium, (C 2 -C 6) halalkynylsulfonium, (C 3-C 8) cycloalkylsulfonium , (C 4 -C 8) cycloalkenylsulfonium, (C 3 -C 8) halocycloalkylsulfonium '(C 4 -C 8) halocycloalkenylsulfonium, (C i -C 6) alkane Amine, (C2-C6 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs) Suspected Amine, (C2-C6) Fast Amine '(Cl-C6) Haloalkylamine, (C2-C6) Halene Amino groups, (C 2-C 6) haloalkynyl groups, (C 3-C 8) cycloalkylamino groups, (C 4 -C 8) cycloalkenylamine groups, (C3-C8) halocycloamine groups and (C4-C8) halo ring, and R11 is (Ci-Cio) alkyl, haloalkyl, aryl, which may be optionally substituted by one or more groups selected from the group consisting of: halogen, cyanide Group, nitro group, (Cl — C4) oxy group (Cl — C 4) group, amine group, (Ci — C4) single group amino group and (C1 — 28- (please read the note on the back first) Please fill in this page again for the matters) This paper size applies Chinese National Standard (CNS) A4 specification (210X 297mm) 508352 Λ7 B7 V. Description of invention (26) C 4) Dialkylamino group; NR102, OR10_SR10. The term "halogen" includes fluorine, chlorine, bromine and iodine. The term "(Ci-C4) alkyl" means a straight or branched chain hydrocarbon group having 1, 2, 3 or 4 carbon atoms, for example, methyl, ethyl, propyl, isopropyl, 1 monobutyl, 2-butyl, 2-methylpropyl or tertiary butyl. Similarly, an alkyl group having a larger range of carbon atoms means a straight chain or branched chain-containing saturated hydrocarbon group having a carbon number corresponding to the predetermined range. Thus, the term "(Ci-C6) alkyl" includes the aforementioned alkyl groups and, for example, pentyl, 2-methylbutyl, 1,1-dimethylpropyl or hexyl. The term "(C:-C 1 0) Yuan" refers to the stated Yuan and, for example, nonyl, 1-decyl or 2-decyl, and "(C i -C 2.) Alkyl" "The term refers to the descriptive academic foundation and, for example, the * carbon academic base, the twelve carbon academic base, the pentadecyl or fluorenyl alkyl. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) "(Cl—〇4)) 院 基" means the above-mentioned "(Cl-C4) Yuanji" References to alkyl groups in which one or more hydrogen atoms are replaced by the same number of the same or different halogen atoms (preferably fluorine or chlorine), such as trifluoromethyl '1 monofluoroethyl, 2, 2, 2, —Difluoroethyl, chloromethyl, fluoromethyl, difluoromethyl and 1,1,2,2-tetrafluoroethyl. "(CX-C4) alkoxy" means a hydrocarbon group having the aforementioned "(

Cl-C4) Yuan-based. An alkoxy group containing a wide range of carbon atoms should be understood accordingly. The words "alkenyl" and "alkyne" at the beginning of the wording to indicate the range of carbon atoms are applicable to China National Standard (CNS) A4 specifications (210X297 mm 1.29-" 508352 Λ 7 Β7 V. Invention The description "(27) group" means a straight or branched chain hydrocarbon group containing carbon atoms corresponding to the stated range, which contains at least one multiple bond that can be at any position in this unsaturated group. Therefore, " (C 2 -C 4) alkenyl "is, for example, vinyl, allyl, 2-methyl-2-propenyl or 2-butenyl;" (C2-C6) alkenyl "means the aforementioned group And, for example, pentenyl, 2-methylpentenyl or hexenyl. "(C2-C2Q) alkenyl" is understood to include the aforementioned groups and, for example, 2-decenyl or 2-廿 Carbonyl. "(C 2 -C 4) alkynyl" is, for example, ethynyl, propynyl, 2-methyl-2-propynyl or 2-butynyl. "(C2-c6) "Alkynyl" is understood to include the foregoing groups and, for example, 2-pentynyl or 2-hexynyl, and "(C 2 -C 2 0) alkynyl" is understood to include the foregoing groups to And, for example, 2-octynyl or 2-decynyl. "(C3-Cs) cycloalkyl" means a monocycloalkyl group such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl Or cyclooctyl, and bicycloalkyl, such as probornyl. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling in this I) "(C 3-C 8) Naphthenes "(C 1 -C 4) alkyl" is understood to include, for example, cyclopropylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclohexylethyl and cyclohexylbutyl, and "(Ci —CoCHY— (C 3 -C 8) cycloalkyl ”should be understood to include, for example, i-methylcyclopropyl, 1-methylcyclopentyl, 1-methylcyclohexyl, 3-hexyl ring Butyl and 4-tert-butylcyclohexyl. "(Cx — C4) fluorenyl- (Ci-Coalkoxy" refers to the above-mentioned fluorenyl radical, which is substituted by another radical, for example 1 Ethoxyethoxy. 'This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 508352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ 7 — Β 7. V. Description of the invention (28) "(C 3-C 8) cycloalkoxy" or "(C 3-C 8) cycloalkylthio" shall be understood as the above cycloalkyl group connected through an oxygen or sulfur atom "(C3-C8) cyclo-Cycloyl- (Cl-C6) co-xyloxy" is, for example, cyclopropylmethoxy, cyclobutylmethoxy, cyclopentylmethoxy, cyclohexylmethoxy, cyclo Hexylethoxy or cyclohexylbutoxy. The term "(Cl-C4) cyno- (C3-C8) cyclo-oxy" means "'for example, methylcyclopropoxy, methylcyclobutoxy or butylcyclohexyloxy. ^ (C i -C 6) alkylthio "is an alkylthio group having a definition of" (Cl-c6) alkyl "in its hydrocarbon group portion. Similarly, "(Ci-c6) alkylsulfinyl" is, for example, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, second butyl, or first butyl-1 Mining group "and" (Cl-C6) hospital-based mining group "are, for example, 'methyl, ethyl, propyl, isopropyl, butyl, isobutyl, second butyl, or third butyl -A sulfonyl group. ^ (C i -C 6) alkylamino "refers to a nitrogen atom substituted with one or two alkyl groups, which may be the same or different as previously defined. The term "Ci-Ce" mono- or dialkylaminoformamidine "means an aminoformamidine group having one or two of the aforementioned hydrocarbon groups under the definition of" (Ci-c6) alkyl ", and In the case where it has two hydrocarbon groups, these hydrocarbon groups may be the same or different. Similarly, "(C i-C 6) dihaloalkylaminomethane" means a compound having two (Ci-Ce) haloalkyl groups as defined above or one (Ci-c6) haloalkyl group and one (Ci-Ce) alkyl formamidine groups. (Please read the notes on the back before filling this page)

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -31-508352 Λ7 Β7 V. Description of the invention (2g) "(Ci — Cs) alkyl" is, for example, ethenyl, propionate Group, butyl fluorenyl or 2-methyl butyl fluorenyl. The term "aryl" should be understood as a carbocyclic aromatic group, preferably one having 6 to 14 carbon atoms, especially one having 6 to 12 carbon atoms, for example, phenyl, naphthyl or biphenyl Is preferably phenyl. "Aryl" is therefore a square radical as defined above linked through tenyl, for example, benzyl. The term "heterocyclyl" means a cyclic group that may be fully saturated, partially unsaturated or fully unsaturated and may interrupt the carbon atom by at least one or more of the same or different atoms selected from nitrogen, sulfur, or oxygen, But more than two oxygen atoms are not directly adjacent to each other and there is at least one carbon atom in the ring, for example, thiophene, xanthan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1, 3,4—oxadiazole, 1, 3, 4-thiadiazole, 1, 3, 4-triazole, 1, 2, 4, 4-oxadiazole, 1, 2, 4-thiadiazole, 1 Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the precautions on the back before filling out this page) d, 2,4-triazole, 1,2,3-triazole, 1,2,3,4-tetrazole, Benzo [b] thiophene, benzo [b] furan, indole, benzo [c] thiophene, benzo [c] pyran, isoindole, benzoxazole, benzothiazole, benzimidazole, benzene Benzoxazole, benzoisothiazole, benzopyrazole, benzothiadiazole, benzotriazole, oxoxane, thiocarbamidine, carbazole, pyridine, pyrazine, pentidine, pyridazine, 1, 3 , 5 Triazine, 1,2,4-triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, oxoline, 1,8-naphthyridine, 1, 5-naphthyridine, 1,6-naphthyridine, 1,7-naphthyridine, phthalazine, pyridopyrimidine, purine, pteridine, 4'-quinazine, piperidine, pyrrolidine, oxazoline 'tetrahydrofuran' tetra Hydropyran 'isoxazolidine or thiazolidinyl groups. Therefore, the term "heteroaromatic" refers to the above definition of "Heterocyclic paper size applicable to the Chinese National Standard (CNS) A4 specification (210x297 mm) -32-508352 A7 _____ B7__ 5. Definition of the invention (30) basis" Fully unsaturated aromatic heterocyclic compounds. "Aryl- (Cl-C4) fluorenyl" refers to an aryl group connected through a (Cl-C4) alkoxy group, for example, benzyloxy, phenethyloxy, phenbutyloxy or naphthylmethoxy base. "Arylthio" refers to an aryl group attached through a sulfur atom, for example, phenylthio or 1- or 2-naphthylthio. Similarly, "aryloxy" is, for example, phenoxy or 1- or 2-naphthyloxy. "Aryl- (C i -C 4) alkylthio" refers to an aryl group connected through an alkylthio group, for example, benzylthio, naphthylmethylthio or phenethylthio. The term "Ci-Ce) trialkylsilyl" printed by the Bureau of Consumer Standards of the Bureau of Standards refers to a silicon atom with three identical or different previously defined alkyl groups. Similarly, "aryl- (Cx-Ce) dialkylsilyl" refers to a silicon atom with one aryl group as defined previously and two alkyl groups that are the same or different as previously defined alkyl groups, "one aryl— "(Cl-C6) sulphonium sulphonate" refers to a silicon atom with one alkyl group as defined above and two aryl groups which are the same or different as defined previously, and "triarylsilyl group" refers to a group with three Silicon atom of the same or different aryl group as defined above. In the case where two or more R 1 Q groups are present in one substituent, such as in the case of a C (= W) N R 1 Q 2, these groups may be the same or different from each other. Preferred compounds of formula I are those in which Y is a ci-C 6 alkyl group which is mono- or poly-substituted by chlorine and / or fluorine; -33- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 508352 Staff Consumer Cooperative Cooperative Imprint of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 • Description of the invention (31) m is 0; Q is a 5-section heterocyclic group 0- \ 2 3 Person / of which a) XS-NRaaxs ^ CRbR1 or b) X2 = CRaR2 and X3 = CRbR3 or c) X2 = CR4R5 and X3 = CR6R7; R a and R b are a single bond, R1, R2, R3, R4 and R6 are each independently hydrogen, halogen, C! -C12 alkyl, c3-C8 cycloalkyl, C2-C8 alkenyl, c2-C8 alkynyl, and the last four hydrocarbon groups mentioned can be optionally The same or different substituents selected from the following A 1 groups are mono- or poly-substituted: Ci—Ce—Mine-based ”Cl—C6—Amine-based” Cl—C6—Methoxy, Cl—C 6 alkylthio, C i -C 6 alkylamino, C i -C 6 alkylcarbonylamino, C i -C 6 alkylsulfonamido, phenyl, furyl, pyrrolyl, thienyl, halogen, cyano, phenoxy , Phenylthio and benzene Group, among which the eleven groups mentioned first in the A 1 group can be optionally mono- or polysubstituted by the same or different groups selected from the following B 1 groups: halogen, cyano, C1 -C 3 alkane The oxy group and the phenyl group may be optionally mono- or poly-substituted by one or more halogen atoms, and the three groups mentioned last in the A 1 group may optionally be the same or different and selected from the following B 2 groups Groups are mono- or poly-substituted: halogen 'cyano, nitro, Cl—C3 alkyl and Cl—C3 alkyloxy' or Cl—C 6 alkylcarbonyl, C i — C 6 alkylamino carbonyl, C i One C 6 alkoxycarbonyl paper size ^ > National and National Standard icNS) A4 size (210X297 mm) ~~ _ 34 two (Please read the precautions on the back before filling this page) • Packing · Ordering — thread · 508352 Λ7 B7 V. Description of the invention (32) group, phenyl, pyridyl, furyl, thienyl, pyrrolyl, among which the last eight mentioned groups can optionally be the same or different and selected from the group B 1 The radical 单 is mono- or poly-substituted, or OR10, SR1. Or N (Rl °) 2 t printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. R5 and R7 are each independently hydrogen, halogen, Ci-Cl2 alkyl, c3-C8 cycloalkyl, c2-c8 alkenyl, C2- C8 alkynyl, wherein the last four hydrocarbon groups mentioned are optionally mono- or poly-substituted by the same or different groups selected from the following A 2 groups: Ci-C6 alkylcarbonyl, Ci-C6 alkylaminocarbonyl , C 1 -c 6 alkoxyfluorenyl, C 1 -C 6 alkylthio, C 1 -c 6 alkylamino, C i -C 6 alkylcarbonylamino, phenyl, furyl, pyrrolyl, thienyl, Halogen, cyano, phenoxy, phenylthio, and aniline, among which the first ten groups mentioned in the A 2 group may be singly or more than the same or different groups selected from the B 1 group Substitution, and the last three groups mentioned in the A 2 group may optionally be mono- or poly-substituted by the same or different groups selected from the B 2 group, or Ci-Ce alkylcarbonyl, Ci-Ce alkylamine Carbonyl, C i-C 6 alkoxycarbonyl, phenyl, pyridyl, furyl, thienyl, alkalyl, among which the last eight groups are optionally the same Different from the group B1, the group is mono- or poly-substituted, or OR10, SR10 or N (R10) 2; R1Q is ammonia 'benzyl, Cl—C6 ring group “Cl—C6 ring ring group” C2—C6 alkenyl, C2—C6 alkynyl, phenyl, Ci—C6 alkylcarbonyl, or Ci—c6 alkylsulfonium, where the last eight groups mentioned are optionally the same or different halogen atoms All single or multiple substitutions. -35- (Please read the notes on the back before filling out this page} This leaflet scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Invention Note (33) A more ideal compound of formula I wherein Y is trifluoromethyl; R1, R2, R3, R4 and R6 are each independently hydrogen, Ci—Cu alkyl, C2—C 12 alkenyl, wherein The last two groups mentioned can optionally be mono- or poly-substituted by the same or different groups selected from the group A 3: Ci-Ca alkylcarbonyl, Cx-C4 alkylaminocarbonyl, Ci-C4 oxygen , C 1 -C 4 alkylthio, C 1 -c 4 alkylamino, C 1 -C 4 alkylcarbonylamino, ci -C 4 alkylsulfonamido, phenyl, furyl, pyrrolyl, Thienyl, fluorine, chlorine, bromine, cyano, phenoxy, phenylthio, and aniline, among which the eleven groups mentioned first in the A 3 group can optionally be the same or different and selected from B 1 The groups of the group are mono- or poly-substituted, and the three groups mentioned last in the group A 3 may optionally be the same or different and are selected from the group B 2 The group is mono- or poly-substituted, or OR1Q, SR10 or N (R 1 0) 2; R 5 and R 7 are each independently halogen, C 1 -C! 2 alkyl, c 2-C 12 alkenyl The last two kinds of groups mentioned in the above may optionally be the same or different from the group selected from the following A 4 groups, which may be mono- or poly-substituted: C i -C 4 ethoxy group 'Cl -C4 amine group Cl'-C4 oxo, Cl-C4 oxo, Cl-C4 oxo 'Cl-C4 oxoamino, phenyl, furyl, pyrrolyl, thienyl, fluorine, chlorine, bromine, cyanide Group, phenoxy group, phenylthio group and aniline group, among which the first ten groups mentioned in the A 4 group may optionally be mono- or poly-substituted by the same or different groups selected from the B 1 group, and wherein The last three groups mentioned in the A 4 group can be optionally substituted with the same or different groups selected from the B 2 group, or are (please read the precautions on the back before filling this page). · This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -36 _ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 508352 5. Invention Description (34) 〇R10, SR10 or N (R 1 0) 2; R1Q is a gas 'Cl-C6 radical, C2-C6 storage radical' C2-C6 fast radical, phenyl, Cl-1 (; 4 alkylcarbonyl or Ci-〇4 Alkyl sulfonium, in which the last six groups mentioned are optionally mono- or poly-substituted by the same or different halogen atoms. Particularly desirable compounds of the formula I are wherein R1, R2, R3, R4 and R6 are each independently The ground is hydrogen, Ci — Cio is a radical of C 2-C 10, wherein the last two groups mentioned can optionally be the same or different from the group selected from the following A 5 group. : Ci—Ca alkylcarbonyl, Ci—C4 alkylaminocarbonyl, Ci—Cd alkoxy, C i—C 4 alkylthio, C χ — C 4 alkylamino, C: —C 4 alkyl carbonamino , C 1 -C 4 alkylsulfonamido, phenyl, fluorine, chlorine, bromine, cyano, phenoxy, phenylthio, and aniline, among which the eight groups mentioned first in the A 5 group It may optionally be mono- or poly-substituted by the same or different groups selected from the B 1 group, and the three groups mentioned last in the A 5 group may be optionally the same or different groups selected from the B 2 group Single list Or multiple substitutions; R5 and R7 are each independently halogen, Ci-C " alkyl, Cs-Ci alkenyl, wherein the last two groups mentioned are optionally the same or different and are selected from the following A 6 The groups of the group are mono- or poly-substituted ... C 1 -C 4 alkyl, C! —C4 alkylaminocarbonyl, Ci — C4 alkoxy, Ci—Cq thiothio 'Cl-104 Limyl 'Cl-C4 amine-based amino, phenyl, fluorine, chlorine, bromine, cyano, phenoxy, phenylthio, and aniline, among which the first seven groups mentioned in the Ag group can be freely The ground is the same or different. It is selected from this bismuth scale. Applicable to the Chinese National Standard (CNS) A4 specification (21〇 × 297297t) ~-(Please read the precautions on the back before filling this page) • Equipment-508352 ΑΊ Β7 V. Description of the invention (35) The groups of group B 1 are mono- or poly-substituted, and the last three groups mentioned in group A 6 may optionally be the same or different groups selected from group B 2 Or multiple substitutions. Depending on the nature of the substituents as defined above, the compounds of formula (I) have acidic or basic properties and therefore can form salts. If the compound of formula (I) has, for example, a hydroxyl group, a carboxyl group and other groups having acidic properties, these compounds can react with a base compound to form a salt. Suitable alkali compounds are, for example, hydroxides, carbonates, and bicarbonates of alkaline metals. And alkaline earth metals, especially such compounds as sodium, potassium, magnesium, and calcium, and also ammonia, having (C i Mono-C 4) alkyl primary, secondary and tertiary amines and (C i-C 4) monoalcohols, di- and trialkanolamines. If the compounds of formula (I) carry, for example, amino groups, alkylamino groups and other groups having basic properties, these compounds can react with acid compounds to form salts. Suitable acid compounds are, for example, inorganic acids such as hydrochloric acid, sulfuric acid, and phosphoric acid, organic acids such as acetic acid, oxalic acid, and acid salts such as Na H 4 and K H 4. The salts obtained in this way also have insecticidal, acaricidal and nematicidal properties. The compound of formula (I) printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs may have one or more asymmetric carbon atoms or stereoisomers on the double bond. Therefore, enantiomers or diastereomers may also be present. The present invention includes pure isomers and mixtures thereof. A mixture of diastereomers can be separated into individual isomers by conventional methods, such as selective crystallization using an appropriate solvent or chromatography. The racemic mixture can be isolated into enantiomers by conventional methods. The present invention also provides a method for preparing the compound of formula I: -38- (Please read the notes on the back before filling in this page) This standard is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 508352 Λ7 ____ Description of the invention (36) To prepare a) X1, 2W, X2 = NRa, and Ra, Rb, and R1 are as defined above (the presence of a base ordered an acid derivative of the formula (II) X3 dic R b R 1)

(II) (wherein X and Y are as defined above) with a compound of formula (III)

HO (III) (wherein R 1 is as defined in formula (I)). Suitable activating derivatives are, for example, fluorenyl halides, esters and anhydrides. Suitable bases are amines, such as triethylamine, diisopropylethylamine, pyridine or dimethylpyridine, alkali metal hydroxides, alkali metal alkoxides, such as sodium ethoxide or potassium tert-butoxide, or alkane Base metal compounds, such as butyl cones. Depending on the reaction conditions, the above reaction can be carried out in a single-step procedure or in a two-step procedure through an intermediate of the following formula (IV): Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs / R1 (IV) The compounds can be heated in inert solvents at temperatures up to 180 ° C and cyclized to form 1,2,4 monooxadiazoles. Compounds of formula (IV) can be used by using a dehydrating agent such as dicyclohexyl carbon (please read the precautions on the back before filling this page)

This narrative scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 39 _ 508352 Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Yin Dian Λ7 B7 V. Description of the invention (37) Diamine, 1 ethyl A 3- (3-dimethylaminopropyl) carbodiimide or N, N'-carbonyldiimidazole, which is prepared directly from an acid of formula (II) and amidoxime of formula (III) . Both the acid of formula (I I) and the amidoxime of formula (I I I) are commercially available or can be prepared by methods known in the literature (see, for example,

• Houben-Weyl, Methoden der organischen Chemie, Volume X / 4, pages 209-2 1 2; EP-A 0 580 374; G. F. Holland, J. N • Pereira, J · Med · Chem ·, 1 967 , 10, 149). In the case where W in a) above is sulfur, the compound of formula (I) can be reacted in a manner known in the literature by reacting a compound of formula (VII) with an electrophilic aminating agent such as hydroxylamine-0-sulfonic acid And prepared (see Y. Lin, S. A. Lang, S. R. Petty, J. Org. Chem. 1 980, 45, 3750).

The compound of formula (VII), which is the starting material in this reaction, can be obtained by the following formula (VI II) thiofluorenamine and As before and R12 and R13 are each C i -C 4 alkyl). This paper size applies Chinese National Standard (CNS) A4 specification (21 × 297 mm) -40-(Please read the notes on the back before filling this page)

V. Description of the invention (38 Y S

(VIII) NR120

R13〇, R13CT, R1

N ,, R1 (VII) (IX) To prepare a compound of formula (I) in which b) X1 = NRa, XS ^ CRbR1, χ3 and where Ra, Rb and R1 are as defined above and w is oxygen, order Amidoxime of formula (V) reacts with an activated derivative of an acid of formula (VI) below or the acid of formula (VI) itself.

(V) X or activated O R1 acid derivative

Y N 10, this X

(I) 1Γ (Please read the notes on the back before filling this page)-装-

1T (VI) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs to prepare c), XS ^ CRaR1, X3, N1 ^, and 113, Rb & R1 as defined above and V is sulfur compound of formula (I) A thiolating agent such as Lawesson's reagent can be used in an inert solvent such as toluene, see A · A · EI-Barbary, S. Scheibyl, S. 0. Lawesson, H. Fritz, Acta Chem. Sc and · 1 980, 5 97) are obtained by cyclizing N, N'-diamidyl hydrazine of the following formula (XIII). This slave scale is applicable to China National Standard (CNS) A4 specification UlOX297 mm) -41 508352

Μ

R1 In the case where W in the above b) is oxygen, the compound of the formula (VII) can use an activator such as phosphorus oxychloride or phosphorus pentachloride, so that the acid of the formula (II) and the hydrazine of the following formula (X) (Wherein R1 is as defined above). The policy of employee consumer cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

This reaction can be performed with or without a solvent and with or without an activator. Suitable solvents are hydrocarbons, such as toluene, or ethers, such as 1,2-dimethoxyethane. A suitable activator is, for example, phosphorus oxychloride. The reaction temperature is usually the reflux temperature of the solvent. This paper is again applicable to China National Standard (CNS) A4 (210X297 mm) -42-nmnmmnn-(Please read the precautions on the back before filling this page) Preparation Λ7 ________ _____ V. Description of the invention (40) To prepare d) X1, two V, X2 = CRaR2, X3, two CRbR3, and Ra, Rb, and R3 as defined above and also oxygen compounds of formula (I), can A compound of the following formula (XIV) is reacted with a dehydrating agent.

(XIV) (I) Suitable dehydrating agents are inorganic ammonium chlorides, such as phosphorus oxychloride or thionyl chloride, inorganic acids, such as sulfuric acid or polyphosphoric acid, or a mixture of phosphoric acid and acetic anhydride (see Houben- Weyl, Methoden der organischen Chemie, Volume E8a, pages 935-94 1) o This reaction can be performed with or without solvents. Suitable solvents are inert solvents such as toluene, benzene, dimethoxyethane, dimethylformamide, dimethylacetamide and chlorobenzene. The reaction temperature is preferably between 50 ° C and 150 t :. Compounds of formula (XIV) can be prepared, for example, by oxidizing the corresponding hydroxy compounds of the following formula (XV), where all reagents customary for this purpose in organic chemistry can be used (see Milos Hudlicky, vv Oxidation in Organic Chemistry 〃 , ACS Monograph 186, American

Chemical Society, Washington, DC, 1990) o This paper size applies to Chinese National Standard (CNS) A4 (210 × 297 mm) (Please read the precautions on the back before filling this page)

1T d 508352 Λ7 B7 V. Description of the invention (41)

Y 0 FT

Using a carbonyl derivative of the following formula (XVIII) (wherein Z is halogen, especially chlorine or bromine, fluorenyl or sulfonyloxy, especially methanesulfonyl or tosylsulfonyloxy), the following formula (XVII ) Produced by condensation of thioxanthene.

Ya S

(XVII)

R2 " V (XVIII)

FT

R2 Ι1Γ (Read the precautions on the back before filling this page)

X

V, X 4 T3 5

X Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs to prepare compounds of formula (I) in which e CR6R7 and R4, R5, R6 and R7 are as defined above and V is oxygen. In a solvent of alkane, the compound of formula (XV) and a cyclizing agent such as Burgess reagent (Burges ^ reagent, see G · M. Atkins, E.M. Burgess, J. Am. Chem. Soc. 1 968, 90, 4744). π line This paper size is applicable to Chinese National Standard (CNS) A4 size (210x297mm t) 44-508352 Λ7 B7

(Please read the precautions on the back before filling this page) The compound of formula (XV) can be obtained by formula (II) in an inert solvent (such as dichloromethane) in the presence of an optional base (such as triethylamine). The activated derivative of the acid) is prepared by reacting a β-amino alcohol of the following formula (XV I).

(XVI) A fluorenyl halide or an acid anhydride can be used as an activated derivative of the acid. Many β-amino alcohols of formula (XV I) are commercially available. Others can refer to many preparation methods in the literature, such as the method of reducing α-amino acids (see Β · Μ · Trost, Comprehensive Organic Synthesis, Reduction ', Volume 8, Pergamon Press, Oxford, 1991) o Economy In the case where V in the above-mentioned e) is printed by the Consumer Cooperatives of the Ministry of Standards and Standards, the compound of formula (I) can be obtained by making the thioxamine of formula (XVII) and the compound of formula (XIX) The two substituents Z are as defined above and may be the same or different. They are prepared by reaction (see A · R. Katritzky Comprehensive Heterocyclic Chemistry ”, Volume 6, pages 306-312, Pergamon Press, Oxford). Again applicable to China National Standard (CNS) A4 specifications (2 丨 〇, 〆297 mm) -45- 508352 Λ7 B7 V. Description of invention (43) 11

FT

R6 R7 hr R4 R5

Re (XVII) (XIX) thioxamines of the formula (XVI I) are commercially available or can be prepared by adding hydrogen chloride to the corresponding cyanine in the presence of a base (see A · E. S. Fairfull, J. L. Lowe, D. A. Peak, J. Chem. Soc. 1 952, 742). To prepare a compound of formula (I) where f) X1 = NRa, Xa ^ CRbR1, X3 = NR8 and Ra, Rb, R1 and R8 are as defined above, the hydrazine of formula (XX)

(Please read the precautions on the back before filling out this page) —> ϋ_— ml nm nn · —κι— nn- · i —m ————— · 0¾ Printed amine reaction by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (See Houben-Weyl, Methoden der organischen Chemie, Volume E8d, pages 510-512) o fC qi, ... owe, w HN7, R1 H2N R (XXI) (XXII) This reaction can be used with or without solvents In this case, suitable solvents are alcohols such as ethanol and propanol, or aromatic hydrocarbons such as toluene and xylene. If the reaction is carried out in a solvent, the reaction temperature chosen is better. The standard of this specification is Chinese National Standard (CNS) A4 (210X297 mm)-508352 Λ7 B7. 5. The description of the invention (44) is the reflux temperature of the solvent. . If the reaction is not carried out in a solvent, it can be heated up to 200 ° C if necessary. Once the group Q has been combined by, for example, a condensation, cyclization, or cycloaddition reaction, the groups R 1 to R 9 can be further derivatized, if necessary, using a wide range of techniques and techniques of organic chemical synthesis'. To synthesize a compound of formula (I) in which m is 1, an oxidizing agent such as m-chloroperformic acid can be used to obtain a compound of formula (I) in which m is 0 to obtain the compound. ) Compounds (hereinafter also referred to as "active compounds") have good plant resistance, favorable toxicity to thermophilic animals, and favorable properties to aquatic organisms, so they are suitable for use in agriculture, livestock, forestry, products and The protection of material storage and health care are used to control animal pests, especially insects, arthropods (mites), worms and molluscs, and they are particularly ideal for controlling insects and arthropods. They are active against normally sensitive and resistant species and at all or some individual developmental stages. It should be emphasized here that the control of animal pests can be the result of the toxic and anti-repellent effects of the compounds of the invention. The above-mentioned pests include: (The following Chinese translators have not been translated in Chinese so far.) Those who belong to the order Acarina, for example, Acaroid mites, Sharp edge ticks, Amaranth ticks, Gopher skin mites, Chigger mites, Leaf mites, Bovines Ticks, fanhead ticks, flower ticks, hyalomma ticks, hard ticks, pruritus, itching mites, chigger mites, midges, alfalfa, mites, spider mites, spider mites, hawk mites, and true leaves Mite. Those who belong to the equivalent group, such as Jellyfish, Armadium vulgar and Porcellio -47- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (21〇X297 mm) 508352 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. Ⅴ. Invention Description (45) 80 & 561 *. Those who belong to the biped order, for example; 5131 ^ 111113§111: 1: 111 & 1: 113. Those who belong to the subclass Lipiapoda, for example, Geophilus carpophagus and salamander. Belong to the group, for example, S c u t i g e r e 11 a i m m a c u 1 a t a. Those belonging to the binomid order, for example, western fish. Those belonging to the order Collaptera, for example, Echinococcus. Those belonging to the order Orthoptera, for example, Oriental salamander, American salamander, Madeira salamander, German salamander, domestic salamander, salamander, tropical locust, long-necked locust and desert locust. Those belonging to the Isoptera order, for example, termites. Those who belong to the lice order, for example, grape root nodule aphids, cotton aphids, head lice, blind lice and jaw lice. Those who belong to the order Homophae, for example, feather lice and livestock lice. Those belonging to the order Stelloptera ', for example, greenhouse thrips, tobacco thrips, and various thrips. Those belonging to Heteroptera, for example, shield crickets, intermedius crickets, beet mimicry crickets' bugs, red hunting crickets and wax crickets. Those who belong to the homoptera order, for example, whitefly, Bemisia tabaci, greenhouse whitefly, cotton buds, sweet spot, tussock tumours, Doralis fabae, Doralis pomi, mineral fruit cotton, peach big tail Aphid, Aphis gossypii, Aphis gossypii, Apricot aphid, Chestnut aphid, Leafhopper, Euscelus bilobatus, Black-tailed Leafhopper, Plum Waxwing, Bird Helmet, Rice Gray Planthopper, Rice Brown Planthopper, Red Roundworm , Often for vines, powdery pupae and psyllids. Those who belong to the order Lepidoptera, for example, red bollworm, pineworm, Cheimatobia brumata, apple moth, cherry nest moth, diamondback moth, canopy caterpillar, yellow poisonous moth, poisonous moth, cotton leaf perforating moth, citrus leaf moth, ground tiger, Cut rootworm, brown night (please read the precautions on the back before filling out this page)-Packing. This paper size applies to China National Standard (CNS) A4 (21〇297297 mm) -48- 508352 ______ Β7 V. Description of the invention (46) Moth, Egyptian gold diamond, Spodoptera exigua, Spodoptera exigua, Cabbage Spodoptera, Spodoptera litura, Spodoptera litura, armyworm, Spodoptera litura, Apple moth, cabbage butterfly, pupae, corn borer, Mediterranean Pink maggots, large wax maggots, yellow roll moth, tobacco roll moth, spruce leaf roll moth 'grape fruit moth', green spiny moth ', machine green roll moth, Cuaphalocrocis spp • and hawk moth. Those who belong to Coleoptera's, for example, furniture stealing, stupidity, soybeans, kidney beans, domestic beetle, Acer beetle, potato beetle, horseradish ape, leaf beetle, rapeseed jumping beetle, mexican bean ladybug, Hidden food beetle, Saw ancient thief, weevil, weevil, black grape ear weevil, banana weevil weevil, cabbage pod weevil, first weevil weevil, stupid, spotted stupid, skin stupid, black stupid stupid , Rapeseed flower hair armor 'Spider armor' golden spider armor, wheat spider armor, guava, yellow meal beetle, beetle, gold needle beetle, gill horn beetle, six-purpose beetle, brown New Zealand ribbed wing gill beetle and various weevil . Those who belong to Hymenoptera, for example, Staghorn leaf bee, leaf wasp, ant, kitchen ant and wasp. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, belonging to Diptera, for example, Aedes, Anopheles, Culex, Chimpanzee Drosophila, Housefly, Midge, Redhead Lily, Green Fly, Gold Fly, Anthrax Gastrointestinal fly, Hypobosca spp ·, fly fly, nose fly, skin fly, burdock, pupae, Bibihororanus, Swedish wheat fly, grass fly, beet leaf leaf, Mediterranean fruit fly, olive fruit fly and European giant mosquito . Those belonging to the order Fleas, for example, Oriental rat fleas and bird fleas. Those belonging to the arachnid class, for example, Scorpio maurus and the black widow bulbous spider. Those belonging to the worm class, such as Haematosporia, Trichostrongylus, Austeria spp., Cooperia spp., Xia nematodes, Trichostrongus spp., Knot-49- (Please read the note on the back first Please fill in this page again for this matter} This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 ΑΊ ____ '^ ____ V. Description of the invention (47) Arthropoda, Cyclops, and Xenopus , Genus Ascaris and Heterosoma, and sheet trematodes. (Please read the notes on the back before filling out this page.) Those who belong to the gastropods, for example, Deroceras spp ·, Arion spp ·, Lymnaea spp ·, Galba spp ·, Succinea spp ·, Biomphalaria spp ·, Bulinus spp · and Oncomelania spp · o Belongs to Bivalva, for example, Dreissena spp For example, nematodes that are parasitic on the roots and inhabit the soil, for example, the genus Nematodes (root-knot nematodes such as white peanut root-knot nematodes, peanut root-knot nematodes, and cotton root-knot nematodes), Heterophyllum nematodes And Globodera genus (such as Globodera rostochiensis, Globodera pallida and Cysticercus cyst nematodes) and perforation nematodes (such as Radopholus similis), free root nematodes (such as Pratylenchus neglectus, root rot nematodes and Pratylenchus curvitatus), roots Nematodes (such as citrus root nematodes), Tylenchorhynchus (such as Tylenchorhynchus dubius and Tylenchorhynchus claytoni), Rotylenchus (such as Rotylenchus robustus), Helicotylenchus (such as Helicotylenchus, multicinctus), and Leoninoica ius (Longnoicamus) elongatus), Trichodorus genus (such as Trichodorus primitivus) and Xiphinema genus (such as Xiphinema index). The compounds of the present invention can also be used to control the following nematodes: Stem nematodes (stem parasites such as sweet potato stem nematodes and potato stem nematodes), dried Acanthocephalus (leaf nematodes, such as ritzemabosi nematodes) and Gram nematodes (flower nematodes, such as wheat grain nematodes). This scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -50-508352 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 ____ V. Description of the invention (48) This invention also relates to the formula containing (I) Compositions of compounds and appropriate formulation aids, especially insecticidal and acaricidal compositions. The composition of the present invention usually contains 1 to 95% by weight of the active compound of formula (I). They can be modulated in a variety of ways depending on available biological and / or physical and chemical parameters. The following types of blends are suitable: Wettable powder (WP), emulsifiable concentrate (EC), aqueous solution (SL), emulsion, spray solution, dispersion with oil or water as the substrate, suspended concentrate (SC ), Suspension emulsion (SE), dusting agent (DP), seed coating agent, particulate particles, spray particles, absorbent particles and adsorptive particles, water-dispersible particles (WG), ULV blends, microcapsules, wax Agent or bait. These individual blend types are known in principle and have been described, for example, in Winnacker-Kiichler, Chemische Technologie " [Chemical Technology], Volume 7, C. Hauser Vedag, Munich, 4th edition 1986 ; Van Falkenberg, Pesticides Formulations ", Marcel Dekker, New York, 2nd Edition, 972-73; K. Martens, Spray Drying Handbook ", 3rd Edition, 1979, G, Goodwin Ltd. ,, London. The required formulation aids, that is, carrier substances and surface-acting substances, such as inert materials, surfactants, solvents, and other additives are also known and have been described, for example, in Watkins, Handbook of Insecticide Dust Diluents and Carriers 〃, 2nd ed., Darland Books, Caldwell New Jersey; ·· V. Olphen, C, Introduction of Clay Colloid Chemistry, 2nd ed., J, Wiley & Sons, New York; Marsden 、, Tensor Scale Applicable to China National Standard (cns) a4 specification (210X297 mm) ~. 51-(Please read the precautions on the back before filling this page) 508352 B7 V. Description of the invention (49)

Solvents Guide / 7, 2nd Edition, Interscience, New York 950; McCutcheon, Detergents and Emulsifiers Annual 〃, MC Publ. Corp •, Ridge wood, New Jersey; Sisley and Wood ', Encyclopedia of Surface Active Agents r /, Chem. Publ · Co. Inc., New York 1964; Schonfeldt, Grenzflachenaktive Athylenoxidaddukte 〃 [Surface Active Ethyl Oxide Adduct], Wiss Verlagsgesell ·, Stublikou 1967; Winnacker-Kiichler, Chemische Technologie y / [Chemical Technology], Volume 7, C. Hauser Vedag, Munich, 4th Edition, 1 986. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) d Based on these blends, other pesticidally active substances, fertilizers and / or growth regulators can be produced A combination of agents, for example, in a ready-to-use form or a bottled mixed form. Wettable powders are formulations that are uniformly dispersible in water and contain, in addition to active compounds and diluent or inert substances, wetting agents such as polyoxyethylated alkylphenols, polyoxyethylated aliphatic alcohols, or Alkyl- or alkylphenol sulfonates, and dispersants, such as sodium lignosulfonate or sodium dinaphthyl methane-6,6 / -disulfonate. Emulsifiable concentrates are prepared by dissolving the active compound in an organic solvent, such as butanol, cyclohexanone, dimethylformamide, xylene, or aromatic or hydrocarbons with a higher boiling point, while adding one or more emulsifiers Agent. The following can be used as emulsifiers, for example: · calcium alkaryl sulfonates, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyglycol esters' alkylaryl polyglycol ethers , Aliphatic alcohol polyglycol ether, propylene oxide / ethylene oxide condensation products, alkyl polyethers, fatty acid sorbitan esters, fatty acid polyoxyethylene sorbitan esters or polyoxyethylene sorbitol ester. · The preparation of dust is to apply the active compound and finely divided solid materials such as this iron sheet standard to the Chinese National Standard (CNS) A4 specification (210X297 mm) -52-508352 printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 Β7 V. Description of the invention (50) talc, natural white clay such as kaolin, bentonite and pyrophyllite, or diatomite are ground together. Granules are prepared by spraying the active compound onto an adsorbent particulate inert material, or by using an adhesive (such as polyvinyl alcohol, sodium polyacrylate, or mineral oil) to apply the active compound concentrate to a carrier substance (such as Sand, kaolin or granular inert materials). If it is desired to form a mixture with fertilizers, suitable active compounds can also be granulated in a manner conventionally used to prepare fertilizer granules. In the wettable powder, the concentration of the active compound is usually about 10 to 90% by weight, and the remaining components that bring the total to 100% by weight include conventionally formulated components. In the case of emulsifiable concentrates, the concentration of the active compound may be about 5 to 80% by weight. Dust type blends usually contain 5 to 20% by weight of active compound, while spray solutions contain about 2 to 20% by weight. In the case of granules, the content of the active compound depends in part on whether the active compound is in liquid or solid form, and what kind of granulation aids, additives, etc. are used. In addition, the above-mentioned active compound blends may, if necessary, contain specific customary adhesives, wetting agents, dispersants, emulsifiers, penetrants, solvents, additives, or vehicles. If necessary, commercially available concentrates can be diluted and used, for example, in the case of wettable powders, emulsifiable concentrates, dispersions, and certain particulates, using water for dilution. Dust and particle blends and spray solutions usually do not require further dilution with other inert substances before use. The amount of application required varies with external conditions, such as temperature, humidity, and (please read the notes on the back first

Refill the Hr item. Loading-: Write this page), 11 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) -53- 508352 Λ7 5. Description of the invention (51) Similar. It can be varied within a wide range, for example, the application of an active substance of 〇.〇〇〇〇5 to 10 · 0 kg / h a or more; but preferably 0. 001 to 5kg / ha. The active compounds of the present invention may exist in the form of their commercially available blends, and from these blends with other active substances such as insecticides, attractants, fungicides, acaricides, nematicides, fungicides, growth regulators Agents or herbicides) exist in the form of applications. Pest control agents include, for example, phosphates, carbamates, carboxylates' formazan, tin compounds, substances made from microorganisms, and the like. The preferred mixed components are: 1. Phosphorous compounds: acephate, azamethiphos, azinphos-ethyl printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Azinephos-methyl, bromfosone, bromophos-ethyl, clofenasone, chlormephos, chlorpyrifos, chlorpyrifos ( chlorpyriphosmehyl), demeton, demeton-S-methyl, demeton-S-methylsulfone, dialifos, dalixon, dichloroson, ricketts , Phosphorothioic acid 0,0-1,2,2,2-tetrachloroethyl (SD 208 304), Dimethoate, Disulfoton, EPN, Acizone, Aibaopine ( ethoprophos), etrimfos, famphur, fenamiphos, fenitriothion, fensulfothion, fenthasone, fonofos, fukushima pine , Heptenophos, isazophos, isothioate, isoxathion, marathon, beauty kill Pine (methacrifos), methamidophos, metamatsupine, talaxon -54- (Please read the precautions on the back before filling out this page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 (Mm) 508352 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (52) Song, Su Ling, Nai Lisong, omethoate, oxydemetonmethyl, Parason, Parathionmethyl, phenthoate phorate, phosalone, phosfolan, phosmet, blessingsong, basseton, fenexyl, fenexyl , Bispermum, profenofos, propaphos, proetamphos, prothiofos, pyraclofos, pyridapenthion, kunasson (Quinalphos), sulprofos, temephos, terbufos, tetrachlorvinphos, thiophene, samson pine, triclosan, fern pine; 2.amino Formates: otica (a ldicarb), methylamino carboxylic acid 2-second butyl phenyl ester (BPMC), Jiabaoli, Jiabaofu, Jiabaofan (carboseui), can be added ((: 1061: 11〇 & amp 1:13), Benfujia (^ 611 £ 111 ^ 〇 &]: 1)), Fenca (01;) 1 £ 〇 £ 6] 1. &]: 13), furathiocarb, isoprocarb, total spirit, (methyl) aminocarboxylic acid 5-methyl metacumyl butyl ester, oxamyl, than Gap, propoxur, thiodicarb, thiofanox, 4,6, 9 —triaza-4 4-benzyl-6,10-dimethyl-8 — Oxa-7-oxo-5,1 1-dithia-9-h ethyl dicarbenoate (0 K 1 3 5), N-methyl-N- (morpholinothio) 1-Methylthio (ethyleneamino) ester (UC51717); 3.Carboxylic acid esters: Arlenin, alphametrin, (E) — (1 R) —cis — This scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) —11——11 ~ · (Please read the precautions on the back before filling out this page}-Installation, 11 508352 ΑΊ V. Description of the invention (53) 2,2-Dimethyl-1, 3- (2-Hydoxythiopheneene-3-ylmethyl) cyclopropanecarboxylic acid, 5-benzyl-3, furanyl methyl ester, bioallethnn), Pyramene ((S) cyclopentyl isomer), Pyramene (bioresmethrin), biphenate, (1RS)-trans-3-(4-tributylbutyl)-2,2-dimethylcyclopropanecarboxylic acid (RS)-1-cyano A 1- (6-phenoxy_2-d-to-n-adenyl) methyl ester (NCI 8 5 1 9 3), cycloprothrin, cyhalothrin, cythithrin, Cypress Cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, fenfluthrin, fenpropathrin, fenprothrin Fenvalerate, flucythrinate, flumethrin, fluvalinate (D isomer), Peminin (? 61: 11 ^ 1: 111 *; 111) , Fenanin (0) ^ 11〇1; 111411) ((11) isomer), (1-d-pralethrin, pyrethrin (natural product), resmethrin , Tefluthrin, tetramethrin, tralomethrin; printed by the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 4 · Formazan: amitraz, chlordimeform; 5. Tin compounds: cyhexatin, fenbutatin oxide; 6. Other: This paper is applicable to the standard China National Standard (CNS) A4 specification (21〇 < 297 mm). 56-508352 Λ7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (54) Abaminectin, Bacillus Suning agent (Bacillus thuringiensis), Bensultap, Hypoxe, bromopropylate, Buprofezin, Camphechlor, Pedan, Chlorobenzine, Chloroflurane Through ((: 111〇1111 ^ 21 ^ 〇11), 2- (4-chlorophenyl) -4,5-diphenylthiophene (1131-but-93 0), kefenquan ((: 1 (^ 61 ^ 62 丨 1 ^), 2-naphthyl methyl ester of cyclopropanecarboxylate (1102-04 7 0), cyromazin, N — (3 '5 —dichloro-4 — (1,1 , 2,3,3,3-Hexafluoro-1, 1-propoxy) phenyl) aminoformamidine), 2-Chlorobenzocarbimidate, gram mite, N — (N-(3 , 5—Dichloro-4— (1,1,2,2-tetrafluoro (Oxy) phenylamino) carbonyl) -2,6-difluorobenzamide (XRD473), diflubenzuron, N- (2,3-dihydro-3—methyl-1, 3 -thiazole-2 -yl) -2,4-dimethylaniline, dinobuton, white powder g, fenfan, ethofenprox, (4-ethoxyphenyl) ( Dimethyl) (3- (3-phenoxyphenyl) propyl) silane, (4-ethoxyphenyl) (3- (4-fluoro-3-phenoxyphenyl) propyl) Dimethylsilane, fenoxycarb, 2-fluoro-5- (4- (4-ethoxyphenyl) -4-methyl-1-pentyl) diphenyl ether (MTI 80 0) , Granules and polyhedrons, fenthiocarb, flubenzimine, flucycloxuron, flufenoxuron, gamma-HCH (gamma HCH), black kill Hexythiazox, hydramethylnon (AC 217300), ivermectin, 2-nitromethyl-4,5-dihydro-6H-thiazine (DS 5 2 6 1 8), 2 —Nitromethyl-3,4-dihydrothiazole (SD356 51 (Please read the notes on the back before filling. Install-: Write this page)

、 1T · The scale of the book I scale is applicable to the national standard (CNS) A4 specification (210 × 297mm) -57- 508352 Printed by the Shellfish Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs A7 B7 ........ .-_-_______________________________ -.............. _. V. Description of the Invention (55)) '2 —Nitromethyl-1, 2 —Hipcock House — 3 -Amine Carboxylic acid (WL 1 0 8 4 7 7), propargite, teflubenzuron, get rid of mites, get tetrasul, thiocyclam, difluorowood (Triflumuron) and imidacloprid. The above-mentioned mixed components are known active compounds, and most of them can be found in The Pesticide of Ch · R · Worthing, S · B · Walker

Manual, 7th edition (1 983), British Crop Protection Council. The active compound content in an application form prepared from a commercially available blend may be from 0.00000 to 95% by weight of the active compound, preferably from 0.0001 to 1% by weight. The active compounds are used in a customary manner suitable for the application. The active compounds according to the invention are also suitable for controlling internal and external parasites in the veterinary and livestock industries. The active compounds of the present invention are applied in a known manner in this field, such as by oral form, for example, tablets, capsules, elixirs, or granules, by skin application forms, such as dipping, spraying, pouring , Spot and powder, as well as parenteral administration forms, such as injection. The novel compounds of formula (I) according to the invention are therefore also very suitable for raising livestock (e.g. cattle, sheep, pigs and poultry such as chickens, geese and the like). In a preferred system of the present invention, these novel compounds may be administered to animals orally if suitable in a suitable blend (see above) and if suitable for use with water or food. Since they are excreted in animal manure in an active form, this method can easily prevent the breeding of insects in animal manure. Dosages and blends suitable for various situations (please read the notes on the back before filling this page) -pack.

、 1T This paper size is applicable to Chinese National Standards (CNS) Λ4 specifications (210X297 male f) -58- Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 508352 B7 _ 5. Description of the invention (56) depends on the animal The type and growth stage, and the extent of the aggression 'can be easily determined and determined by conventional methods. For cattle, for example, these novel compounds can be used at doses ranging from 0.1 to 1 mg / kg body weight. In addition to the application methods described above, the active compounds of formula I of the present invention also have excellent systemic effects. Therefore, when the active compounds are applied to the environment around the plant in liquid or solid form (such as the application of granules to the soil, the application in overflow rice fields), the active compounds can penetrate the ground and above the plant Partially (roots, stems, leaves) into the plant. In addition, the active compounds of the present invention are particularly useful in the treatment of fruit and vegetable and productive multiplication crops, such as hoe, fruits and vegetables, cotton, rice, sugar beet and other crops and Seeds of decorative plants, and bulbs, cuttings and tubers of other fruit and vegetable multiplication crops and decorative plants. In this regard, treatment may be performed before sowing or planting (for example, using special seed coating techniques, seed coating or seed box treatment in liquid or solid form), during seeding or planting, or during sowing or planting Treatment after planting (eg seed row treatment). The application amount of the active compound can be varied within a wide range depending on its application form. In general, the application rate is between 1 g and 10 kg of active compound per hectare of soil area. The following examples are provided to illustrate the present invention. A. Example of a blending material a) A dusting agent is prepared by applying 10 parts by weight of the active compound and 90 paper standards to the China National Standard (CNS) A4 specification (210 'to 297 mm) ~ · 59 : ~-I ϋ III-(Read the precautions on the back before filling in this page). Packing. 508352 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Β7 V. Description of the invention (57) parts by weight as inert materials It is prepared by mixing talc and pulverizing it in an impact mill. b) Wettable powder that can be easily dispersed in water. It is made by mixing 25 parts by weight of active compound, 65 parts by weight of high-terrestrial quartz as inert material, 10 parts by weight of potassium lignosulfonate and 1 part by weight. Part by weight of sodium oleate methyl taurate as a wetting agent and dispersant is prepared by grinding in a pin mill. c) A dispersion concentrate that can be easily dispersed in water, which is prepared by mixing 40 parts by weight of an active compound, 7 parts by weight of a sulfosuccinic acid monoester, 2 parts by weight of sodium lignosulfonate, and 51 parts by weight Water, and the mixture was pulverized in a bead mill to a fineness of 5 micrometers or less. d) an emulsifiable concentrate, which can be composed of 15 parts by weight of an active compound, 75 parts by weight of cyclohexane as a solvent, and 10 parts by weight of oxyethylated nonylphenol (1 OEO) as an emulsifier. be made of. e) Granules, which can be prepared from 2 to 15 parts by weight of active compound and inert granular carrier materials such as American activated clay, granular pumice and / or quartz sand. It is more advantageous to use a suspension of a wettable powder of Example b) with a solid content of 30%, and spray this suspension on the surface of the particles of American activated clay, and then dry the components and intimately mix them. In this case, the wettable powder content in the final granules is about 5%, and the inert carrier material is about 95%. (Please read the precautions on the back before filling this page) This narrative scale is applicable _ National Standard (CNS) A4 specification (210X297 mm) -60- 508352 Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Λ7 __ ^ ___B7 V. Description of the invention (58) B · Chemical Examples Example 1 3-Isopropyl-5-(4-trifluoromethyl-3-pyridyl)-1, 2, 4 monooxadiazole (Table 1 Compound No. 8 1) 2 g of 4-trifluoromethylnicotinic acid methyl ester and 1.56 g of isobutyramine oxime were added to 15 m of ethanol, and cooled to 0 ° C. A 10 m 1-2 M sodium ethoxide solution was dropped into the solution. During the two hour period, the mixture was allowed to stand to warm to room temperature, and then continuously stirred at this temperature until TLC analysis showed that the reaction was over. The reaction mixture was concentrated, the residue was carried in a saturated ammonium chloride solution, and extracted with ether. The crude product was purified by chromatography to obtain the desired compound as a yellow oil. 'H-NMR (CDCls »300MHz): d = 1.41 (d, J = 6.9Hz, 6H), 3.22 (m, lH), 7.78 (d, J = 5Hz, 1 H), 9.02 (d, J = 5Hz , LH), 9.34 (s, lH) ppm. Example 2 ^ 3-isopropyl-5-(4-trifluoromethylpyrimidinyl)-1, 2, 4-oxadiazole (Table 1, compound No. 1 8 9) 2 g of 4-3 Fluoromethylpyrimidine 5-carboxylic acid ethyl ester and 1.556 g of isobutyramine oxime were added to 15 ml of 1 ethanol and cooled to 0 ° C. Drop 10m 1-2M sodium ethoxide solution into the solution (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) Α4 size (210X297mmt) · 61 _ 5083 total

Attachment II (A): Patent Application No. 87109414 Chinese I Republic of China 90 丨 V. Description of Invention (59) -----. During the one hour period, the mixture was allowed to warm to room temperature, and then heated at reflux until TLC analysis showed that the reaction was complete. The reaction mixture was concentrated, the residue was carried with a saturated ammonium chloride solution, and extracted with ether. The crude product was purified by chromatography to obtain the desired compound as a yellow oil. 'H- NMR (CDC 13, 300MHz): d = 1.43 (d, J = 7Hz, 6H), 3 · 2 2 (hept., J = 7Hz, 1H), 9.52 (s'1H), 9.58 (s, lH) ppm. Example 3 2 -methyl-5 (4-dichloromethyl-3 -succino) -1,3,4-dioxadiazole (Table 3, compound No. 904) at 3 · 5m 1 4-Omg of 4-trifluoromethylnicotinic hydrazine was heated in triethyl acetate under reflux for 2 hours. The reaction mixture was then concentrated and the residue was carefully mixed with 2 m 1 of phosphorus oxychloride. The mixture was stirred at room temperature for 1 hour, then poured onto ice, and extracted with ethyl acetate. After drying and concentration ', the obtained crude product was purified by chromatography to obtain the desired compound as a yellow oil. 'H-NMR (CDC 13 > 300MHz): d == 2.67 (s, 3H), 7.75 (d, J = 5Hz, lH), 8.99 (d, J = 5Hz, lH), 9.34 (s'lH) ppm. Example 4 62 (Please read the notes on the back first to write this page) The paper size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 male A) 508352 4 A7 B7 V. Description of the invention C 60 4 I (ethoxy Carbonylmethyl) 2-(4-trifluoromethyl-3 -pyridyl) thiazole (Table 4, compound No. 10 4 3) 50 mg of 4-trioxomethyl 1% 3-Thiomonoamidine and 440 mg of ethyl 4-chloroacetate were dissolved in 5 ml of dimethylformamide and heated at Ί 0 ° C for 4 hours. After cooling, the reaction mixture was poured onto ice-water and extracted with ether. The ether phase was dried (using MgSO), filtered, concentrated, and the residue was purified by chromatography. The desired product is obtained in pure form as a colorless oil. 'H-NMR (CDC 1 3 Μ Η ζ d = 1.28 (t, J = 7.5Hz ,; 3.92 (s, 2H), 4.22 (q

H Please read back & notes, 2 H), 7 7. 6 8 (d 8. 8 6 (d 8. 9 7 (s 4 3 (s, 1 H), J = 5 H z, 1 H) J = 5 H z > 1 H) 1 H) ppmo Example 4 Ethyl-2 (4-trifluoromethyl-3 -pyridyl) oxazole (Table 4, Compound No. 1 1 1 7) Mix 2.6 g of 4-trifluoromethylnicotinic acid with 20 ml of thionyl chloride and heat at reflux temperature for 1 hour. After cooling, the excess thionyl chloride was distilled off, and the remaining fluorenyl chloride as a pale yellow oil was carried in 30 m 1 of dichloromethane. Subsequently, the solution was dropped into 2 · 4 g of 2-amino-1 monobutanol and 2. · 75 g of triethylamine in 30 ml of dichloromethane. The standard size of the paper was applicable to China National Standards (CNS) A4 (210X297 mm). -63- 508352 Α7 Β7 V. Description of the Invention (61) Consumption cooperation between employees of the Intellectual Property Office of the Ministry of Economic Affairs and Ti. Printing in an ice-bath-cooled solution. After the added operation is completed 1 Stir continuously at room temperature for about 2 hours. The mixture was poured into a chlorinated solution j and extracted with ethyl acetate. The ethyl acetate phase was dried and concentrated to obtain crude N- (1-hydroxy-2-butyl) -4-trifluoromethylnicotinamide (2 3 g), which was then dissolved in 1 at room temperature. 〇〇m 1 m in dichloromethane and 4.6 g of Piodinan (periodinan (Des S -Martin reagent)). After TLC analysis showed that the reaction had ended, the reaction mixture was concentrated and purified by column chromatography. The obtained 2- (trifluoromethylpyridine-3-aminoamine) butan (1 • 5 g ) Dissolved in 300 mM dimethylformamide, mixed with 2 • 7 2 g of phosphorus oxychloride and heated at 90 ° C. for 15 minutes. Pour the solution on ice > Extract with ether. The ether phase was dried and concentrated and the remaining residue was purified by layer chromatography to give the product as a brown oil. 1] Η--NMR (CDC 1 3, 3 0 0 MW Η Z): d = 1 • 3 (t, J = 7.4 Η z, 丨 3 Η) 2 zero 6 6 (qd, J = 7. 4 Η ζ, J < 1 Η ζ > 2 Η) y 7 • 5 8 (t, J < 1 Η ζ, 1 Η), 7 • 6 5 (d, Bu 5 Η ζ, 1 Η) 丨》 8 ♦ 8 3 (d, J = 5 Η ζ, 1 Η) 丨》 9 • 3 3 (d, J = 5 Η ζ, 1 Η) 1 PP mc > Example 6 4 Ethyl ethyl 2 — (4-trifluoromethyl-3-pyridyl) -4,5-dihydrooxazole (Table 5, Compound No. 1 2 3 1) The size of this paper is applicable to China National Standard (CNS) A4 (210X297 mm) ) -64- (Please read the notes on the back ^ k, write this page) 508352 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (62) 1 g of 4 trifluoromethyl smoke The acid was mixed with 8 ml of thionyl chloride and heated at reflux temperature for 1 hour. After cooling, the excess thionyl chloride was distilled off, and the remaining fluorenyl chloride in the form of a pale yellow oil was carried by 10 m 1 of dichloromethane. This solution was then added dropwise to an ice-bath-cooled solution of 9 3 Omg 2-amino-1-butanol and 1.06 g of triethylamine in 10 m 1 of dichloromethane. After the addition was completed, stirring was continued at room temperature for about 2 hours. The mixture was poured into an ammonium chloride solution and extracted with ethyl acetate. After the ethyl acetate phase was dried and concentrated, crude N- (1 -trimethyl-butyl) -4-trimethylmethylthreonamine (1.03 g) was obtained, which was then reduced at room temperature. It was dissolved in 6 m of tetrahydrofuran, and mixed with 1.09 g of N-[(triethylamine) sulfofluorene] methylcarbamate (Burgis reagent). At 6 0. (The mixture was stirred at 3 for 3 hours. After cooling, the batch was concentrated, the residue was carried with water, and extracted with ethyl acetate. The crude product was purified by chromatography to give the product as a colorless oil. H-.NMR (CDC la > 200MHz): d di 1.03 (t, J = 7.6Hz, 3H), 1.72 (m, 2H), 4.15 (t, J = 7.5Hz, 1H), 4.32 ( m, lH), 4.58 (t, J = 7.5Ηζ, 1Η), 7.6 (d, J = 5Hz, lH), 8.87 (d, J = 5Hz, lH), 9.06 (s, lH) ppm. This paper Standards apply Chinese National Standard (CNS) A4 specifications (21 OX 297 mm) -65 (Please read the precautions on the back before filling out this page) • Equipment · 4 508352 A7 B7 V. Description of the invention (63) Example 7 2 — (3-Thienylmethyl) -5 (4-pyridyl) -1,3,4-oxadiazole (Table trifluoromethyl-3-pyridine No. 9 2 7 Compound 8 8-trifluoromethyl The base pyridine solution was dropped into ice water under reflux. After drying, 6 1 Η-NMR d = 4 · 3 8 1 Η), 7 · 5 Η z, J = Η z, 1 Η) 9 3 6 (s mg of thiophene 3-acetohydrazine added 9 6 0 mg 4 pyridine-3 monocarboxylic acid at 5 m 1 chlorine The resulting solution in phosphorus oxide was heated for 2 hours. The reaction mixture was then neutralized with concentrated aqueous ammonia solution and extracted with ethyl acetate (using Na 2 S 0 4), concentrated and purified by chromatography. The desired product of 2 4m g of slightly brown oil. [CDC 1 3, 2 0 Μ Η ζ): (s, 2 Η), 7.1 (d, J = 5 Η ζ, 23 (s, lH), 7.37 (dd, J = 3Ηζ, 1Η), 7.75 (d, J = 6 1 8 · 98 (d 1 Ι ^ βΗζ 1 1H) ', 1 H) PP m. (Please read the notes on the back first to write this (Page) 0 Binding and Ordering Example: Employees ’Cooperatives of the Intellectual Property Office of the Ministry of Economic Affairs, Consumer Cooperatives, Printing Example 8 5 —Methyl-3— (4-trifluoromethyl-3—pyridyl) —1H—1,2,4,13 Azole (Table 6, compound No. 1303) A mixture of 290 mg of ethyl acetimidate hydrochloride and 100 mg of sodium hydroxide in 2 ml of ethanol was filtered, and Add 50 Omg of 4-trifluoromethyl-3-pyridinecarboxamide 'and then heat the mixture at reflux for 3 hours. Concentrate the reaction mixture' and leave the paper size to the Chinese National Standard (CNS) A4 specifications (210X297 mm)- 66- 508352 Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, anthropomorphic injection _ί-B7. · ,. '— V. Description of the Invention (64) — The substance was suspended in xylene and heated under reflux for 4 hours. This was followed by a general treatment, in which the batch was diluted with ethyl acetate and washed with water. After purification by chromatography, the pure product was obtained as a colorless solid. 1H-NMR (CDC13 ^ 3 0 0MHz): d = 2.58 (s, 3H), 7.64 (d, J = 5Hz, 1H), 8.85 (d, J = 5Hz, 1H), 9.19 (s, 1H) ppm. Example Θ 3- (N-isopropylaminomethylmethyl) -5- (4-trifluoromethyl-3-pyridyl) -1,2,4 monooxadiazole (Table 1 3 3 Compound No. 4) Step 1: 3 -Amino-3-(4-trifluoromethyl-3 -pyridylcarbonyloxyimino) propionic acid third butyl ester 30 g of 4-trifluoromethyl Add 3-pyridinecarboxylic acid to 150 ml of anhydrous THF, and then mix it with 25.3 g of carbonyldiimidazole in small amounts one by one. The mixture was stirred at room temperature for 30 minutes. Then 27.2 g of tert-butoxycarbonylacetamidoxime dissolved in 150 ml of THF was dropped into it. The mixture was stirred overnight, the solvent was evaporated and the residue was carried with ethyl acetate, washed three times with 1 M sulfuric acid and once with a saturated sodium bicarbonate solution. The ethyl acetate phase was concentrated to give 28 g of the product as a pale yellow solid. iH — NMRCCDCh, 300MHz): d = 1.5 (s, 9H), 3.3 (s'2H), 5.55 (br.s, 2H), 7.8 3 (d, J = this paper is in accordance with China National Standard (CNS) A4 Specifications (210X 297mm 1: 67-'(Please read the precautions on the back first! Write this page) Flip-book binding 508352 Λ7 B7 V. Description of the invention (65) 5 Η z, 1 H), 8.97 (d, J = 5Hz'lH) '9.13 (s, lH) ppm. Step 2: 3— (third butoxycarbonylmethyl) -5— (4-trifluoromethyl-3-pyridyl) —1,2,4— Oxadiazole dissolves 2 8 g of 3 -amino-3- (4-difluoromethyl-3 -amidinylcarbonyloxyimino) propionic acid third butyl ester in 380 m 1 of toluene, and Pre-heated at reflux for 17 hours. It was concentrated and the residue was purified by silica gel chromatography to give 14.4 g of the product as a light brown oil. 'H-NMR (CDC 13 ^ 300MHz): d = 1.5 (s, 9H), 3.88 (s, 2H), 7.79 (d, J = 5 Hz, lH), 9.02 (d, J = 5 Hz, lH), 9.33 (s, lH) ppm. Step 3: 3 — (Hydroxycarbonylmethyl)-5-(4-trifluoromethyl-3 -pyridyl)-1,2,4-oxadiazole Employees of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative prints Dissolve 12. 4g of 3- (third-butoxycarbonylmethyl) -5- (4-trifluoromethyl-3-pyridyl) -1,2,4-oxadiazole in 1 1 〇 m 1 methylene chloride and mixed it with 57 m 1 of trifluoroacetic acid. The reaction mixture was stirred at room temperature for 1.5 hours, and then concentrated under reduced pressure. The residue was repeatedly carried with methylene chloride. , And reconcentrated to remove any remaining trifluoroacetic acid. Finally, the mixture was milled with ether to obtain 8.1 g of a white solid product. -68- (Please read the precautions on the back before filling this page ) This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 Wisdom of the Ministry of Economic Affairs / i ^ SM Shoulder Charge Buchan i Zhongyan Guangyi ~ one. One — A7 ί _j two f 57 〇.:- · I…. A Mi, '7 V. Description of the invention U 66) Supplementary step 4: 3- (N-isopropylaminomethylmethyl)-5-(4 trifluoromethyl- 3-pyridine 1), 2, 4 monooxadiazole Dissolve 1 g of the product obtained in the previous step in 10 m 1 THF and mix with 0.59 g of carbonyldiimidazole. The mixture was stirred at room temperature for 10 minutes, 0.22 g of isopropylamine was dropped thereinto, and then the mixture was allowed to react for an additional 1.5 hours at room temperature with stirring. The reaction mixture was then concentrated, and the residue was carried with ethyl acetate and washed three times with 1 M sulfuric acid and once with a saturated sodium bicarbonate solution. The ethyl acetate was dried and concentrated, and the resulting solid residue was recrystallized from tert-butyl methyl ether to obtain 0.46 g of a pure product as a pale yellow solid. 'H-NMRCCDCh, 300MHz) ·· (1 = 1.20 (d, J = 7.6Hz, 6H), 3. 8 2 (s, 2 Η), 4 · 1 2 (m, 1 Η), 6.50 (br. s, lH), 7.81 (d, J = 5 Hz, lH), 9..02 (d, J = 5 Hz, lH), 9.37 (s, lH) ppm. Example 1 0 3 — (N, N — Dimethylaminomethylamidino) -5— (4-trifluoromethyl-3-pyridyl) -1,2,4-oxadiazole (Table 1, Compound No. 50 2) Step 1: 2 —Amino-2-(4-trifluoromethyl-3 -pyridylcarbonyloxyimino) ethyl acetate 17.3g of carbonyldiimidazole is added to 200ml of 1 '4 CNS) A4 specification (210X297 mm) -gg-(Please read the notes on the back to write this page) Assemble and write too much In dioxane, it was mixed in small portions with 20 g of 4-trifluoromethyl-3-pyridinecarboxylic acid. The mixture was stirred at room temperature for 1 hour, and then heated to 4 5 ° C for 2 hours. After cooling to 30 ° C, 14.5 g of ethoxycarbonylformamide oxime was added to it , And the mixture was stirred at 4 5 ° C for 3 hours. The precipitated solid was filtered off with suction, the filtrate was concentrated to 500 m 1 and added with the solid to 250 m 1 of ice water. The solid was filtered off with suction , And dried at 50 ° C under reduced pressure. 28. 7 g of white solid product was obtained, melting point 172-174 ° C. Step 2: 3-ethoxycarbonyl 5-(4 trifluoromethyl-3 —Pyridyl) —1,2,4—oxadiazole Dissolve 20 g of 2-amino-2- (4-trifluoromethyl-3—pyridylcarbonyloxyimino) ethyl acetate in 20%. m 1 of xylene and toluene, and mixed with 5 g of Amberlyst 15 (Amberlyst 15). Using Dean-Stark device at 1 2 5 — 1 3 0 The mixture was boiled for 6 hours at ° C. After the reaction was completed, the mixture was cooled and mixed with a small amount of ether. The mixture was filtered through suction through a glass filter, and the solution was concentrated. 1 5 · 8 g of yellow oil was obtained Product 0 Step 3: 5-(4-trifluoromethyl-3-pyridyl) -1,2,4-dioxadiazole-3-carboxylic acid 15. 8 g of 3-ethoxy Base 5 — (4-trifluoromethyl — 3-pyridyl) — 1, 2, 4 — Dioxadiazole added 1 3m 1 Methanol This paper is in accordance with China National Standard (CNS) A4 specification (210X297 cm) ~ (Please read the precautions on the back before filling out this page.) Pack-a bite 508352 Printed in the Λ7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs v. Invention Description (68), and then under ice cooling at 0 ° C, A solution of 2 · 8 g of lithium hydroxide in 50 m 1 of water was dropped into it. The mixture was stirred at room temperature for 2 hours, 20 ml of ice water was added, and the mixture was extracted with 200 ml of diethyl ether. The aqueous phase was adjusted to p Η = 2 with dilute H C 1 and the precipitated product was filtered off with suction. After drying, 5- (4-trifluoromethyl-3-pyridyl) -1,2,4-dioxadiazol-3-carboxylic acid was obtained as a white solid with a melting point of 15-7-1 59 ° C. Step 4: N, N-Dimethyl-5- (4-trifluoromethyl-3-pyridyl) -1,2,4-oxadiazol-3-carboxylic acid Imidazole was added to 90 mM tetrahydrofuran, and it was successively mixed with 9 g of 5- (4-trifluoromethyl-3-pyridyl) -1,1,2,4-oxadiazol-3-carboxylic acid. mixing. The mixture was stirred at room temperature for 15 minutes, and then heated at 50 ° C for 2 hours. After cooling to room temperature, 2.3 g of dimethylamine was introduced therein over a period of 2 hours in a gentle and gentle flow. After a reaction time of 12 hours, the mixture was concentrated and supported with 2000 ml of diethyl ether. The mixture was washed with an ice-cold semi-concentrated hydrochloric acid solution, washed with a saturated sodium bicarbonate solution and neutralized, dried over magnesium sulfate, and concentrated under reduced pressure. A slightly yellow oil was obtained which solidified into a solid with a melting point of 5 2-5 4 ° C after several days. In a manner similar to the foregoing, the compounds shown in Tables 1 to 6 below can be obtained. The abbreviations used in the table have the following definition of Ph. The base THP: 2-Tetrachloropyranyl (please read the notes on the back _ items before filling. Pack-: write this page),-paper Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) -71-508352

A B V. Description of Invention (69) Table 1

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [° c] 1 N CCI3 0 〇ch3 2 N CCI3 0 〇ch2ch3-3 N CCI3 0 〇COOCH2CH3 4 CH CCI3 0 〇ch3 5 CH CCI3 〇〇c 〇〇ch2ch3 6 N (CF2) 3CHCF2 0 〇ch3 7 N (CF2) 3CHCF2 0 〇c〇〇ch2ch3 8 CH (CF2) 3CHCF2 0 〇ch3 9 CH (CF2) 3CHCF2 〇〇〇〇〇2ch3 10 N (CF2) 3CHCF2 〇s ch2c〇〇c (ch3) 3 11 N (cf2) 3chcf2 0 s ch2c〇nhch3 12 CH (CF2) 3CHCF2 0 s (ch2) 2ch3 13 CH (CF2) 3CHCF2 0 sc〇Ch2ch3 14 N (CF2) 2CHCF2 0 〇ch2ch3 15 N (CF2) 2CHCF2 0 〇COOCH2CH3 16 N (CF2) 2CHCF2 OOOH 17 N (CF2) 2CHCF2 〇0CH3 18 CH (CF2) 2CHCF2 〇ch3 19 CH (CF2) 2CHCF2 〇COOCH2CH3 20 CH (CF2) 2CHCF2 〇〇OH This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) —72-(Please read the precautions on the back before filling this page)

, 1T line 508352

AB 5. Description of the invention (70) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point "c" 21 CH (CF2) 2CHCF2 0 〇NHCH3 22 N cf2cf3 0 〇ch3 23 N CF2CF3 〇〇CH2CH3 24 N CF2CF3 0 〇 (ch2) 2ch3 25 N cf2cf3 0 〇CH (CH3) 2 26 N cf2cf3 0 〇Ring "CsHn 27 N cf2cf3 〇〇ch2c = ch2 28 N cf2cf3 〇〇ch2c ^ ch 29 N cf2cf3 〇〇ch2ch2c = ch 30 N cf2cf3 〇〇ch2c ^ cch2ch3 31 N cf2cf3 〇〇 (CH2) 4C ^ CH 32 N cf2cf3 〇〇CHFCF3 33 N cf2cf3 〇〇c〇〇〇ch2ch3 34 N CF2CF3 0 〇CH2COOC (CH3) 3 35 N cf2CON3 CH3. 36 N cf2cf3 0 〇nh2 37 N cf2cf3 0 〇nhch2ch3 38 CH CF2CF3 0 〇ch3 39 CH cf2cf3 0 〇CH2CH3 40 CH CF2CF3 0 〇 (CH2) 2CH3 41 CH cf2cf3 〇Ch (ch3) 2 42 CH cf2cf3 0 〇 ring CsHn 43 CH CF2CF3 〇〇ch2c = ch2 44 CH cf2cf3 0 〇ch2c〇c (ch3) 3 45 CH cf2cf3 〇〇nh2 46 CH cf2cf3 〇〇NHCOCH3 47 CH cf2cf3 〇〇nhc〇ch2ch3 CNS) A4 Specifications (210X297 mm) -73- (Please read the notes on the back before filling this page), -port 508352 A7 B7 V. Description of the invention (71) Printed by the Consumers Cooperative of the Central Standard Bureau of the Ministry of Economic Affairs X Υ mw R1 · Melting point [. . ] 48 Ν CF2CF3 〇s ch3 49 Ν cf2cf3 0 s CH2CH3 50 Ν cf2cf3 〇s_ (CH2) 2CH3 51 Ν cf2ci 0 〇ch3 52 Ν cf2ci 0 〇ch2ch3 53 Ν cf2ci 〇〇 (ch2) 2chci 54 〇 cf2 ch3) 2 55 Ν cf2ci 〇〇ch2c〇〇c (ch3) 3 56 Ν cf2ci 〇〇ch2conhch3 57 Ν cf2ci 〇OHOH 58 cf2ci 〇〇CH3 59 Ν cf2ci 〇OOCH2CH3 60 Ν cf2ci 0 〇NHCH3 61 CH 〇ch3 62 CH cf2ci 〇〇CH2CH3 63 CH cf2ci 0 〇 (CH2) 2CH3 64 CH cf2ci 0 〇ch (ch3) 2 65 CH cf2ci 0 〇CH2COOC (CH3) 3 66 CH cf2ci 0 〇CH2CONHCH3 67 CH cf2ci 0 〇OH 68 CH cf2ci 0 〇0CH3 69 CH cf2ci 0 〇〇ch2ch3 70 CH cf2ci 〇NHCH3 71 CH cf2ci 〇ring-CeHn 72 CH CF ^ CI 〇〇ch2c = ch2 73 CH CF2Ci 〇〇COOCH2CH3 74 CH cf2ci 0 〇CH2COOC (CH3 ) 3 This k-sheet scale applies to China National Standard (CNS) A4 specification (210X297 mm)-74---------- · Α ------ Order '----- (please first Read the notes on the back and fill in this page) · 508352 A7 B7 V. Description of the invention (72) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry 丨 XY mw ΙηΓ Melting point [° c] 75 CH CF2CI 0 〇ch2c〇nhch3 76 CH CF2CI 0 〇och3 77 CH CF2CI 〇〇NHCH3 78 CH cf3 0 〇ch3 Oil 79 CH cf3 〇〇CH2CH3 oil 80 CH cf3 〇〇 (CH2) 2CH3 oil 61 CH cf3 0 〇ch (ch3) 2 oil 82 CH cf3 〇〇 ring, c3h5 oil 83 CH cf3 〇〇 (CH2) 3CH3 oil 84 CH cf3 0 〇CH (CH3) CH2CH3 oil 85 CH cf3 0 〇ch2ch (ch3) 2 oil 86 CH cf3 〇〇C (CH3) 3 'oil 87 CH cf3 〇ring do-C4H7 88 CH cf3 0 〇 (CH2) 4CH3 oil 89 CH cf3 0 〇ch (ch3) (ch2> 2ch3 90 CH cf3 0 〇 (ch2) 2ch (ch3) 2 91 CH cf3 0 〇ch2c (ch3) 3 92 CH cf3 0 〇-C5H9 oil 93 CH cf3 0 〇 (ch2) 5ch3 94 CH cf3 0 〇c (ch2ch3) 2ch3 95 CH cf3 0 〇Ring 1 -CsH "96 CH cf3 0 〇 (CH2) 6CH3 97 CH cf3 〇〇ch (ch3) (ch2) 4ch3 98 CH cf3 0 〇Ring-C7H13 99 CH cf3 0 〇CH2-Cibubu CsHii 100 CH cf3 0 〇2-Original borneol base 101 CH cf3 0 〇 (CH2) 7CH3 This: The paper size applies to the Chinese national standard (〇 奶) 8 4 specifications (210 297 mm) -75-508352

A

7 B V. Description of the invention (73) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy XY mw R1 Melting point [° c] 102 CH cf3 〇〇ch (ch2ch3) (ch2) 5ch3 103 CH cf3 0 〇 (CH2) 8CH3 104 CH cf3 0 〇 (CH2) 3h ring 105 CH cf3 0 〇 (CH2) 9CH3 106 CH cf3 0 〇1% adamantyl 107 CH cf3 〇 (CH2) 10CH3 108 CH cf3 〇 (CH2) 11CH3 109 CH cf3 〇〇CH (CH3) (CH2) 9CH3 110 CH cf3 0 〇 (CH2) 12CH3 111 CH cf3 〇〇 (CH2) 13CH3 112 CH cf3 0 0 (CH2) 14CH3 113 CH cf3 〇〇 (CH2) 15CH3 114 CH cf3 〇 〇 (CH2) 17CH3 115 CH cf3 〇〇 (CH2) 19CH3 116 CH cf3 〇〇CH〇117 CH cf3 〇〇ch = ch2 Oil 118 CH cf3 0 〇ch2c = c (ch3) 2 119 CH CF3 0 〇ch2ch2c = ch2 120 CH cf3 0 〇ch2c = ch2 121 CH cf3 〇〇C (CH3) = CH2 122 CH cf3 0 〇 (e) -ch2ch = chch2ch3 123 CH cf3 〇〇 (Z) -CH2CH = CHCH2CH3 124 CH cf3 〇〇 (ch2 ) 5c = ch2 125 CH cf3 〇〇C (= CHCH3) CH3 62-64 126 CH cf3 〇〇 牛牛 基 127 CH cf3 〇3-3-menthyl 128 CH cf3 〇〇C ^ CH Paper: paper Dimensions are applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) -76-(Please read the notes on the back • 1 • Items are refilled and filled 丨 · Write this page to order-line 508352 A7 B7 (74) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 丨 XY mw R1 Melting point [° c] 129 CH cf3 0 〇ch2c ^ ch 130 CH cf3 0 〇ch2ch2c ^ ch 131 CH cf3 0 〇ch2ch2c ^ ch 132 CH cf3 〇〇 (ch2) 4c · 133 CH cf3 0 〇chfcf3 oil 134 CH cf3 〇〇c〇ch2ch3 oil 135 CH cf3 0 〇ch2ch2oh oil 136 CH cf3 0 〇CH2CH2OCH3 oil 137 CH cf3 0 〇CH2COOC (CH3) 3 oil 138 CH cf3 〇〇ch2sc6h5 oil-139 CH cf3 〇〇ch2c〇nhch3 109-111 140 CH cf3 〇〇CH2CH (OH) CH2OH 141 CH cf3 0 〇CH2COCH3 142 CH cf3 0 〇COCH3 143 CH cf3 0 〇ch2 CHc6h5 cf3 0 〇COCeHs 145 CH cf3 0 〇CO (4-CI) -C6H4 146 CH cf3 0 〇CF2CH3 147 CH cf3 0 〇ch2cn 148 CH cf3 0 〇CH2CH2CN 149 CH cf3 0 〇ch2ch (-〇-) ch2 150 CH cf3 〇〇CH2 (4-〇CH3) C6H5 151 CH cf3 〇〇CH2 ~ c yclo ~ (4-Oxo) -C6H8 152 CH cf3 〇〇ch2ch (〇h) ch2sc6h5 153 CH cf3 〇〇CH2CH2Si (CH3) 3 154 CH cf3 〇〇ch = cf2 155 CH cf3 〇〇CCI = CHCI This paper standard is applicable China National Standard (CNS) A4 Specification (210X297mm) -77-I ------_ 丨 Installation ------ Order ----- φ. Line (Please read the precautions on the back before (Fill in this page). 508352 A7 B7 V. Description of the invention (75) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy No. XY mw R1 Melting point [〇c] 156 CH cf3 0 〇2-pyridyl 99-101 157 CH cf3 0 〇2-furyl 158 CH cf3 0 〇2-thienyl 106-108 159 CH cf3 0 〇CH2OCCH2CH2〇THP 160 CH cf3 〇〇CH2CH2CI oil 161 CH cf3 〇〇Si (CH3) 3 162 CH cf3 0 〇oc6h5 163 CH cf3 〇〇OH 164 CH cf3 0 〇0CH3 165 CH cf3 〇〇OCH2CH3 166 CH cf3 〇〇〇chf2 167 CH cf3 〇0 och2c6h5 168 CH cf3 〇〇CH2SCH3 48-49 169 CH cf3 〇〇SC6H5 170 CH CF 0 SeC6H5 171 CH cf3 0 〇nh2 116-118 172 CH cf3 0 〇NHCH3 173 CH cf3 0 〇NHCH2CH3 174 CH cf3 0 N (CH2CH3) 2 175 CH cf3 0 〇c〇nhch2c = ch2 105-107 176 CH cf3 0 〇Cl 177 CH cf3 0 〇Br 178 CH cf3 〇〇conh2 206-208 179 CH cf3 〇〇NHCOCH3 129-131 180 CH cf3 〇〇nhc〇ch2ch3 181 CH cf3 〇〇OS02CH3 182 CH cf3 〇〇S〇CH2 (4-B 「)-C6H4 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm)-78-- ----- ~ Install ------ Order ------ line (please read the precautions on the back before filling this page). 508352 A7 B7 • V. Description of Invention (76) Central Standard of the Ministry of Economic Affairs Bureau Consumer Consumption Cooperative Printing Number XY mw R1 Melting point [° c] 183 CH cf3 0 〇n (ch3) c〇〇ch2c6h5 184 CH cf3 0 〇nhnh2 185 CH cf3 0 〇NHN (CH3) 2 186 N cf3 0 〇ch3 187 N cf3 〇〇ch2ch3 oil 188 N cf3 0 〇 (ch2) 2ch3 oil 彳 89 N cf3 0 〇CH (CH3) 2 oil 190 N cf3 〇 (CH2) 3CH3 oil 191 N cf3 0 〇CH2CH (CH3) 2 oil 192 N cf3 0 〇c (ch3) 3-193 N. cf3 〇〇 (CH2) 4CH3 oil 194 N cf3 〇〇CH (CH3) (CH2) 2CH3 195 N cf3 〇〇ch2c (ch3) 3 196 N cf3 0 〇 ring! -C5H9 197 N cf3 0 〇 (ch2) 5ch3 198 N cf3 0 〇1 ring-CsHn 199 N cf3 0 〇ch (ch3) (ch2) 4ch3 200 N cf3 0 0 CH2-ring: · 〇6Ηιι 201 N cf3 0 〇 (ch2) 7ch3 202 N cf3 0 〇 (CH2) 8CH3 203 N cf3 0 〇 (CH2) 9CH3 204 N cf3 0 〇CH (CH3) (CH2) 9CH3 205 N cf3 0 〇 (CH2) 15CH3 206 N cf3 0 〇 ( CH2) 17〇H3 207 N cf3 0 〇 (CH2) 19CH3 208 N cf3 〇〇CH2CH = C (CH3) 2 209 N cf3 〇ch2ch2ch = ch2 This _ paper size applies the Chinese National Standard (CNS) A4 specification (210X297) Li) I 79-I ------ ~ equipment ------ order ----- A___w ^ (Please read the notes on the back before filling this page) '508352 A7 B7 V. Description of the invention ( 77) Printing number XY mw R1 melting point [. 〇] 210 N cf3 0 〇CH2CH = CH2 211 N cf3 0 〇 (Z) -CH2CH = CHCH2CH3 212 N cf3 0 〇 (CH2) 5CH = CH2 213 N cf3 0 〇ch2c ^ ch 214 N cf3 0 〇ch2c = cch2ch3 215 N cf3 〇〇chfcf3 216 N cf3 〇〇COOCH2CH3. 217 N cf3 〇〇ch2ch2 0h 218 N cf3 〇ch2ch2 〇ch3 219 N cf3 0 〇CH2COOC (CH3) 3 220 N. cf3 〇〇〇 2 sc6h5 221 N cf3 ch2conhch3 222 N cf3 〇〇CH2CH (OH) CH2OH 223 N cf3 〇〇CH〇224 N cf3 0 〇COCH3 225 N cf3 0 〇CH2OC? H5 226 N cf3 0 〇COCeHs 227 N cf3 0 〇cf2ch3 228 N cfcn 0 229 N cf3 0 〇ch2ch2cn 230 N cf3 0 〇ch = cf2 231 N cf3 〇〇furyl 232 N cf3 〇2. Ch2c ^ ci 233 N cf3 〇OHOH 234 N cf3 0 〇0CH3 235 N cf3 〇OOCH2CH3 236 N cf3 '0 〇ochf2 This k-sheet scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) —80— 11 i I— i-II-!:-I- -1--. .... I--i · — · In. 、 一 \ I ——i (Please read the notes on the back before filling this page). 508352

A

7 B • V. Description of the invention (78) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy XY mw R1 Melting point [0C] 237 N cf3 0 〇〇ch2c6h5 238 N cf3 0 〇sc6h5 239 N cf3 0 〇nh2 240 N cf3 0 〇nhch3 241 N cf3 0 〇NHCH2CH3 242 N cf3 0 〇N (CH2CH3) 2 243 N cf3 0 〇N (CH2CN) 2 244 N cf3 〇〇N (CH3) 2 245 N cf3 0 〇NHCOCH3 246 N cf3 〇 〇 NHCOCH2CH3-247 N cf3 0 〇OS02CH3 248 N cf3 〇0 NHNH2 249 CH cf3 〇s ch3 250 CH cf3 0 s CH2CH3 251 CH cf3 0 s (CH2) 2CH3 252 CH cf3 0 s CH〇253 CH cf3 0 254 CHFCF cf3 0 s CH2C three CH 255 CH cf3 0 s COOCH2CH3 256 CH cf3 0 s ch2c〇〇c (ch3) 3 257 CH cf3 0 s ch2cn 258 CH cf3 0 s SeC ^ Hs 259 N cf3 〇s ch3 260 N cf3 0 s CH2CH3 261 N cf3 0 s (CH2) 2CH3 262 N cf3 〇s CHFCF3 263 N cf3 0 s ch2ch2〇h This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -81-(Please read the back of the first Note 0—item refilling · loading —. Write this page)

1T line 508352 A7 B7 V. Description of the invention (79) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy No. XY mw R1 Melting point [° c] 264 N cf3 〇s ch2c〇〇c (ch3) 3 265 CH ch2ch2ci 0 〇 ch3 266 CH ch2ch2ci 0 〇CH2CH3 267 CH ch2ch2ci 0 〇 (CH2) 2CH3 268 CH ch2ch2ci 0 〇ch (ch3) 2 269 CH CH2CH2CI 〇〇ch2sc6h5 270 CH ch2ch2ci 〇〇ch2ci2ch2ch2 ch 2 271 CH ch nhch2ch3 273 N ch2ch2ci 〇〇ch2ch3-274 N. ch2ch2ci 〇〇nh2 275 N ch2ci 〇〇ch3 276 CH ch2ci 〇〇ch3 277 CH chf2 0 〇ch3 278 CH chf2 0 〇CH2CH3 279 CH ch2 2 0 chf2 0 〇ch2ch = ch2 281 CH chf2 0 0 C (CH3) = CH2 282 CH chf2 0 〇c〇〇ch2ch3 283 CH chf2 0 〇CH2CONHCH3 284 CH chf2 0 〇CF2CH3 285 CH chf2 〇〇CH〇286 CH chf2 0 nh2 287 CH chf2 〇〇Cl 288 CH chf2 〇〇NHCOCH3 289 CH chf2 〇〇nhnh2 290 N chf2 〇〇ch3 This k-scale applies to China National Standard (CNS) A4 specifications ( 210X297 mm) -82-I ------- install ------ order ----- AW- ^ (Please read the precautions on the back before filling this page). 508352

7 7 AB V. Description of the invention (8〇) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy XY mw R1 Melting point [° c] 291 N chf2 0 〇ch2ch3 292 N chf2 〇〇ch (ch3) (ch2) 4ch3 293 N chf2 〇〇ch2ch = ch2 294 N chf2 0 〇c〇〇ch2ch3 295 N chf2 0 〇nh2 296 CH cf3 1 〇ch3 297 CH cf3 1 〇COOCH2CH3 298 CH cf3 1 〇ch2c〇c (ch3) 3 299 CH cf3 1 〇CHFCF3 300 N cf3 〇ch2nhso2ch3 301 N cf3 〇〇 (CH2) 2NHS02CH3 302 N cf3 0 〇ch2nhs〇2ch2ch3 303 N CF3 0 〇ch2nhs〇2ch2c6h5 304 CH cf3 0 305 (ch2) 4 (ch2) 2s (ch2) 2ch3 306 CH cf3 0 〇 (ch2) 4s (ch2) 4〇ch3 307 CH cf3 0 s (ch2) 2s (ch2) 2cn 308 CH cf3 0 s ch2nhs〇2ch2ch3 309 CH cf3 0 s ch2nhs 〇2ch2c6h5 310 CH cf3 0 s (ch2) 2nhs〇2ch3 311 CH cf3 0 s CH2NHS02CH3 312 CH cf3 0 s ch (ch3) ch2nhc6h5 313 CH cf3 0 s (CH2〉 2S (2-F) -C6H4 314 CH cf (ch2) 6nhch2) 6〇ch3 315 CH cf3 〇s (CH2) 2NH-. (2-F) -C6H4 316 CH cf3 〇s (CH2) 3NHCH2CN 317 CH cf3 0 s (CH 2) 20 (3-CI) -C6H4 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) —83-I ------ AW ~ Packing ------ Order --- --Line (please read the precautions on the back before filling this page). 508352. 5. Description of the invention (8i)

AB Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 雠 [〇C] 318 CH cf3 〇s (CH2) 6NHCH2CF3 319 CH cf3 0 s (CH2) 2〇 (3-CH3) -C6H4 320 CH cf3 0 〇ch2nhc6h5 321 CH cf3 0 〇 (CH2) 4S (2-Br) -C6H4 322 CH cf3 〇〇 (CH2) 6NH (CH2) 2〇CH3 323 CH cf3 0 〇 (ch2) 2nh (ch2) 4〇ch3 324 CH cf3 0 〇 (CH2) 3NH- (4-CM) -C6H4 325 CH cf3 〇〇 (CH2) 2〇 (3-CH3) -C6H4 326 CH cf3 0 〇 (ch2) 4nhch2cf3 327 CH cf3 〇〇 (ch2) 4nhch2cn 328 CH cf3 〇〇 (CH2) 30 (4-〇CH3〉 -C6hU 329 CH cf3 0 〇ch2s〇2: Third-c4h9 oil 330 CH cf3 0 〇CH2S〇2- (4 Dan C6H4 oil 331 CH cf3 0 〇 CH2S〇2 ~ 〇6H5 oil 332 CH cf3 0 〇CH2SOCH3 63 333 CH cf3 0 〇ch2so-c6h5 oil 334 CH cf3 0 〇ch2c5nh (ch2) 2ch3 80-82 335 CH cf3 0 〇 (4-〇CF3) -C6H4 57 -59 336 CH cf3 0 〇CH20CH3 oil 337 CH cf3 0 〇 \ 0 h2c 53-54 338 CH cf3 〇〇i3 h2c s oil 339 CH cf3 0 0 ch2ch2 〇ch2ch3 oil 340 CH cf3 〇〇ch2ch2nc6h5 80-83 (Please (Read the notes on the back before filling out this page)

This: The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -84-508352 A7 B7 V. Description of the invention (82) __R Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Number XY mw R1 Melting point [〇C ] 341 CH cf3 0 〇ch3 Η2Ά 80-81 342 CH cf3 0 〇 / ◦h2 \ 110-111 343 CH cf3 〇〇CH2CH20 (C〇H4-CI) -C6H4. 80-82 344 CH cf3 0 〇CH2- ( 4 «OCH3) -C6H4 54-55 345 CH cf3 0 〇CH2- (3-CI) -C6H4 51 -'52 346 CH cf3 〇〇CH2-ring: oil 347 CH cf3 0 〇CH2- (4-C6H5)- C6H4 oil 348 CH cf3 0 〇D 143-144 349 CH cf3 0 〇CH2CH20 (C〇H2,6-F2) -C6H3 57-58 350 CH cf3 0 〇CH2CH2〇 (C〇H4-N〇2) -C6H4 80 -81 351 CH cf3 0 〇-CH2- (2,6-CI2) -C6H3 91 -92 352 CH cf3 0 〇ch2ch2oso2ch3 oil 353 CH cf3 0 〇ch2ch2〇 (c〇) -third-c4h9 oil 354 CH cf3 0 〇CH2- (3-F) -C6H4 50-51 355 CH cf3 〇〇ch2c〇nch2c = ch 129-131 CNS) A4 specification (210X297 mm) _ 85-I ------ ~ Installation --- --- Order ----- line (please read the notes on the back before filling this page). 508352 A7 B7 V. Description of the invention 83) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy X Υ mw R1 Melting point [〇c] 356 CH cf3 0 〇ch2ch2〇 (c〇) -ring-c3h7 Oil 357 CH cf3 0 〇ch2ch2〇 (c〇) ch3 Oil 358 CH cf3 0 〇CH2- [2l4- (CH3) 2] -C6H3 85-86 359 CH cf3 0 〇CH2CONCH2CH = CH2 / 210-212 360 CH cf3 0 〇ch2c〇n (ch2ch3) 2 oil 361 CH cf3 〇 〇ch2c〇n (ch2) 3ch3 77-79 362 CH cf3 〇〇CH2C〇NCH2h (2-furyl) 139'141 363 CH cf3 〇CH2CONCH (CH3) 2 112-114 364 CH cf3 0 〇ch2c〇nch ( ch3) [(ch2) 4ch3] 73-75 365 CH cf3 0 〇ch2c〇nch2ch2c6h5 120-122 366 CH cf3 0 〇CH2CONCH2CH20CH2CH3 78 367 CH cf3 0 〇CH2CONCH2CF3 176-178 368 CH cf3 0 〇ch2c〇nch ( (ch2) 5ch3] 85-86 369 CH cf3 0 〇 / 2Ctl v FF oil 370 CH cf3 〇〇h2c ^^ oil 371 CH cf3 0 〇CH2CH2- (id ratio alkyl) oil 372 CH cf3 0 〇ch2ch2c6h5 oil paper Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) 86-(Please read the precautions on the back before filling this page)

1T 508352 V. Description of the invention (84) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [〇c] 373 CH cf3 0 〇ch2ci 53-54 374 CH cf3 0 〇 (ch2) 3 〇h 38-39 375 CH cf3 〇〇ch2c〇nch (ch3) [(ch2) 2] ch3 68:69 376 CH cf3 0 〇ch2ch (〇ch3) 2 oil 377 CH cf3 〇〇ch2c〇nch2c (ch3) 3 1 Oil 378 CH cf3 0 〇CH2C〇NC (CH3) 2 (CH2CH3). Oil 379 CH cf3 0 〇CH2C〇NCH2CH2, -C6Hh 82-85 380 CH cf3 〇〇Ch ^ CONCHKCH ^ (1-naphthyl) _ 142 -146 381 CH cf3 〇〇 (CH2) 3CI oil 382 CH cf3 0 〇ch2con- third, c4h9 oil 383 CH cf3 0 〇ch2con (iso-c3h7> 2 70-72 384 CH cf3 0 〇ch2c0n (ch2) 7ch3 79-81 385 CH cf3 0 〇Ch ^ CON-ring; -CeHn 119-121 386 CH cf3 0 〇CH2C〇NCH2CH2- (4-CI) -C6H4 120-121 387 CH cf3 0 〇CH2C〇NCH2- (2 -Thienyl,) 137-139 388 CH cf3. 0 〇〇151-153 389 CH cf3 0 〇ch2c〇nhch (ch3) (ch2ch3) 87-89 390 CH cf3 〇〇 (CH2) 3SCH3 1 Applicable to China National Standard (CNS) A4 specification (210X297 mm)-87-( (Please read the notes on the back before filling in this page): I install ---- order ----- line 508352 A7 B7 V. Description of the invention (85) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs X Υ mw R1 Melting point [.〇] 391 CH cf3 0 0 (ch2) 3s〇ch3 oil 392 CH cf3 0 〇CH2C〇NC (CH3) 2 (CeCH) 111-113 393 CH cf3 0 〇ch2c〇nch (ch3) ch2ch2ch (ch3) 2 72-74 394 CH cf3 0 〇o h3c ch3 oil 395 CH cf3 0 〇CH2CON-ring'-C5H9 110-112 396 CH cf3 0 〇ch2c〇n (ch2) 4ch3 75-77 397 CH cf3 〇〇190-192 398 CH cf3 0 〇CH2CON (3-CF3) C6H4 136-138 399 CH cf3 0 〇ch2c〇n-ring CaHi7 115-117 400 CH cf3 0 〇5H3 0TCH3 ch3 oil 401 CH CF3 0 〇CH2C〇N-, Adamantyl 'oil 402 CH cf3 〇〇ch2c〇n (ch2ch2ch3) 2 1 oil 403 CH cf3 〇〇CH2C〇NCH (CH3) [(4-F) -C6H4] 111-113 404 CH cf3 0 〇ch2c〇nch2ch (ch3) 2 91-93 -------- • Equipment ------ Order ----- ^ (Please read the precautions on the back before filling out this page). W's scale is applicable to China National Standard (CNS) A4 Specification (-88-508352

A

7 B • V. Description of the invention (86) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy XY mw R1 Melting point [〇c] 405 CH cf3 0 〇-VrYp 〇ch3 Oil 406 CH cf3 0 〇ch2conch2ch2〇c6h5 99-101 407 CH cf3 0 〇ch2ch = noch3 oil 408 CH cf3 0 〇CH2C〇NCH2CH2- [3,4- (〇ch3) 2] c6h3 123-125 409 CH cf3 0 〇CH2C〇N- (2-CI) C6H4 138- 140 410 CH cf3 〇〇CH2C0N- (2-SCH3) C6H4 136-138 411 CH cf3 〇〇CH3 222-225 412 CH cf3 0 〇0 N, 〇 '207-209 413 CH cf3 0 〇CH2C〇N- (3 -B 「) C6H4 1-29-131 414 CH cf3 0 〇CH2CON-N- (2J4i6-CI3) C6H2 153-155 415 CH cf3 0 〇CH2CON- (4-I) C6H4 143-145 416 CH cf3 〇〇CH2C 〇N-NC〇CH2 (3-fluorenyl) 185-187 417 CH cf3 0 〇ch2ch2ch〇 Oil 418 CH cf3 0 〇ch2c〇n (ch3) [(ch2) 3ch3] Oil 419 CH cf3 0 〇CH2CON- ( 3l5-CI2-2,4-K2) C6H > 166-167 This k-sheet scale is applicable to China National Standard (CNS) A4 specification (210X297 mm)-training one (Please read the precautions on the back before filling this page)

IIIIII .Aw. 丨 Binding _ Line _ 508352 A7 B7 V. Description of the invention (87) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [〇C] 420 CH cf3 0 〇CH2CON- C6H5 215-217 421 CH cf3 0 〇CH2CON (CH3) (C6Hh) oil 422 CH cf3 0 〇ch2c〇n (ch2ch3) (ch2ch = ch2), oil 423 CH cf3 0 〇CH2C〇N (CH2CH3) [Ch \ OH3 ) 2] Oil 424 CH cf3 0 〇ch2c〇nch (ch3) [(ch3) 2] 108-110 425 CH cf3 0 〇ch2c〇n (ch2ch3) [ch2c (= ch2) (ch3)] Oil 426 CH CF3 〇 〇CH2C〇NCH2 (4-Third-c4h9) c6h4 Oil 427 CH cf3 0 〇ch2c〇nch (ch3) (Third-c4h9) Oil 428 CH cf3 〇〇ch2c〇nch (ch3) [ch2ch (ch3) (CH2CH3 )] Oil 429 CH cf3 0 〇ch2conch2cooch2ch3 103-105 430 CH cf3 0 〇CH2C〇N [(CH2) 2CH3] (CH2-Ring-c3h7) Oil / 431 CH cf3 0 〇ch2c〇nch (ch3) ch2ch2ch (ch3) 2 80-82 432 CH cf3 0 〇ch2c〇nch (ch2ch3) [ch2ch (ch3) 2] Oil 433 CH cf3 0 〇CH2C = 〇- (1-fixed base 丨 丨) Oil 434 CH cf3 〇〇Cl D dagger 180- 182 (Please read the notes on the back before filling out this page) 士-1 ί I! =--1-- ----- This paper size applies to China National Standard (CNS) A4 (210X297 mm) —90-508352 A7 B7 V. Description of the invention (88) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs No. XY mw R1 Melting point [. 〇] 435 CH cf3 〇〇CH2C〇NCH2C (= CH2) (CH3) 86-87 436 CH cf3 0 〇ch2c〇nch [ch (ch3) 2] (c〇ch3) Oil 437 CH cf3 〇〇CH2C〇NCH2h Ring 'c3h7 oil 438 CH cf3 〇〇CH2CON (CH2) 5〇H oil 439 CH cf3 0 〇ch2c〇n (ch3) (ch2c〇2ch3) oil 440 CH cf3 0 〇CH2C〇N (CH3) (CH2CN) oil 441 CH cf3 〇〇ch2c〇nch [ch2ch (ch3> 2) (c〇2 ChW Oil 442 CH cf3 〇〇CH2C〇N- (1-piperidinyl: ·, :) Oil 443 CH cf3 〇〇ch2c〇nch2ch2 〇ch3 97-99 444 CH cf3 〇〇ch2ch2sc6h5 oil 445 CH cf3 0 〇ch2ch2sch3 449 CH cf3 〇〇CH2CON- (3-OH) C6H4 oil 450 CH cf3 〇〇CH2C〇NK2-CH3) C6H4 163-164 451 CH cf3 〇〇CH2C0N- (3-N02) C6H4 176-178 452 CH cf3 〇〇 CH2C〇NK3-〇CF2CHFCI) C6H4 120-121 This k-sheet scale is applicable to China National Standard (CNS) A4 specification (210X297 mm)-91-(Please read the precautions on the back before filling this page) 508352 A7 B7 • Five Description of the invention (89) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw FC 雠 [〇C] 453 CH cf3 0 〇CH2CON- (3-CF3-4-F) C6H3 168-170 454 CH cf3 0 〇CHzCON ^^-C ^ JCeHa 120-122 455 CH cf3 0 〇CH2C〇N- (2-F > 4.CI) C6H3 148-151 456 CH cf3 0 〇CH2C〇N- [2,4- (CH3) 2] C6H3 123-125 457 CH cf3 0 〇CH2C〇N- [2,3- (CH3) 2] C6H3 Wax 458 CH cf3 0 〇Wax 459 CH cf3 0 〇CH2CON- (2-CH3-3-CI) C6H3 160-162 460 CH cf3 0 〇ch2c〇n (ch2ch3) (c6h5) oil 461 CH cf3 〇〇q 0 CH3 124-126 462 CH cf3 0 〇CH2C〇N (2-〇CH3-5-Ph) C6H3 167-169 463 CH cf3 0 〇157-158 464 CH cf3 0 〇CH2C0N- (3-N02-4-CI) C6H3 oil 465 CH cf3 〇〇CH2CON- (2-CI-4-CH3) C6H3 106-108 466 CH cf3 0 〇CH2C〇N -(3-〇CH2CH3) C6H4 Waxy I ------- * 二 衣 ------ 1T ----- (Please read the precautions on the back before filling this page) Standards apply to China National Standard (CNS) A4 specifications (210X 297 mm) _ 92-508352

7 7 AB V. Description of the invention (9〇) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [° c] 467 CH CF3 0 〇〇169-171 468 CH cf3 〇〇CH2C〇N- (4 -CH3) C6H4 139-141 469 CH cf3 0 〇Ch ^ CON- (l-naphthyl) 155-157 470 CH cf3 〇〇CH2C〇N- (3-l) C6H4 135-137 471 CH CF3 0 〇CH2C〇 N- (2 * OCH2CH3) C6H4 138 472 CH cf3 0 〇CH2C〇N- (2-〇CH3) CeH4 130-132 473 CH cf3 0 〇CH2CON- [3,5- (〇CH3) 2] C6H3 130-132 474 CH cf3 0 〇CH2CON- (4-CI) C6H4 139-141 475 CH cf3 0 〇CH2CON- (3-CH3) C6H4 oil 476 CH cf3 0 〇CH2C〇N- (3-〇CH3) C6H4 oil 477 CH cf3 0 〇CH2C〇N- (4-CH2CH3) C6H4 122-123 478 CH cf3 0 〇CH2CON- (4-CF3) C6H4 151-152 479 CH cf3 0 〇CH2CON- (2-CH3-4-CI) C6H3 165- 167 480 CH cf3 0 〇ch2ch2nch2c6h5 oil 481 CH cf3 0 〇CH2CH2NCH: t (3-pyridyl 1) oil 482 CH cf3 0 〇ch2ch = n〇ch2ch3: oil 483 CH cf3 〇ch2ch = noc6h5 China National Standard (CNS) A4 Specification (210X297 mm)-93-

1T ----- 1 line (please read the precautions on the back before filling this page). 508352 A7 B7 V. Description of the Invention (No. 91

X

Y m melting point [° c] 484

CH CF3 0 CH2C0N- (4-N02) C6H, 181-183 485

CH cf3 0 CH2C0N- (2-CH3-4-N02) C6H3 129-131 486

CH cf3 0 CH2C〇N- (2-C bu 3-CF3) C6H2 136 487

CH cf3 〇 CH2CON- (2-CN-4-CI) C6H3 157-159 488

CH cf3 0 CH2C〇NK3,5-CI2) C6H3 167-169 489

CH cf3 0 CH2CON- (3,5-CI2-4- OCF2CHF2) Cifi2 ^ 132-134 Please read the notes on the back first, and then IJ page 490

CH cf3 〇 CH2CON- (2,4,5-013) 06¾ 146 491

CH cf3 〇 CH2C〇N- (3,5-Clr4- 〇CF2CHFCF3) C (H2 124 -126 Order 492

CH cf3 0 CH2CON- (2-CF3-4-CI) C6H3 136 493

CH cf3

Oil line

This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -94- 91-93 123-125 508352 A7 B7 Invention description (92) Number

X

Y m melting point [° C] 496

CH CF3 0 〇

81-83 497

CH CF3 0

Cl \ / N, 113-115 498

CH CF3 〇

C〇〇H 155-157 499

CH CF3 0 4-F-C6H4 104-106 (Please read the precautions on the back before filling this page) 500

CH CF3 0 C〇N (C2H5) 2 oil 501

CH CF3 0 CONCH (GH3) 2 Oil 502

CH CF3 0 C〇N (CH3) 2 5 ^ 54 503

CH CF3 〇

CONHCH2CCH 105-107 504

CH CF3 0 Co-NH-ring i -C3H5 101-103 505

CH cf3 0 〇 CONH2 206-208 506

CH CF3 0 〇 72-74 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 507

CH cf3 〇

95-100 This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm)-95 _ 508352 A7 B7 V. Description of the invention (93) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs No. XY mw R1 Melting point [ ° c] 508 CH cf3 0 08 //. 0 \ 0 108-110 509 CH cf3 0 〇0 140-142 510 CH cf3 0 〇CONHCH3 127-129 511 CH cf3 〇〇c〇nhch2ch = ch2 oil-512 CH cf3 〇〇c〇n (ch2cn) 2 90- 92 513 CH cf3 0 〇4 | C4H9) -C6H4 64-66 514 CH cf3 0 〇4-CF3-C6H4 89-91 515 CH cf3 0 〇4-CH3-3-F-C6H3 104-106 516 CH cf3 0 〇 2, mC6H3 70-72 517 CH cf3 0 〇4- (NHS〇2CH3) -C6H4 204-206 518 CH cf3 〇〇2,6 · -CI-C6H3 139-141 519 CH cf3 0 〇C〇CH2C6H5 83 -85 520 CH cf3 0 〇CONHC3H7 ..................... 521 CH cf3 〇〇3,5- 二 · ΒΜ- (〇ΟΗ3) \ ρ6Η21 132-134 522 CH cf3 〇〇chci2 oil 523 CH cf3 〇CCI3 oil This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) one-T pack-(please first Read the notes on the back and fill in this page) 508352 A7 B7 、 Invention Note (94) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs X 编号 mw R1 Melting point [° c] 524 CH cf3 0 〇CH (〇CH3) 2 , Oil 525 CH cf3 0 〇3-CF3-C6H4 57-59 526 CH cf3 〇〇c〇n (ch2) 5 oil. 527 CH cf3 〇〇c〇n (ch3) ch2c6h5 oil 528 CH cf3 0 0 C〇NHCH2C6H5 96-98 529 CH cf3 0 〇 0 human 0 oil · 530 CH cf3 〇〇C〇NH-r > C6H13 丨 oil 531 CH cf3 0 〇 C〇N (CH2CH3) CH2C6H5 Oil 532 CH cf3 0 〇CONH-c-CeHn 115-117 533 CH cf3 0 〇C〇N (rvC4H9) 2 Oil 534 CH cf3 0 〇0 u Oil 535 CH cf3 0 〇CONHH-C4H9 Oil. 536 CH cf3 〇00 0 ch3 The size of this paper is applicable to the Chinese National Standard (CNS) Α4 size (210 × 297 mm) —97 (Please read the precautions on the back before filling this page) -pack-

, 1T-line · 508352

7 7 AB i. Description of the invention (95) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy XY mw Melting point [° c] 537 CH cf3 0 〇CON (0H2) ^ / 68-70 538 CH cf3 0 〇CON (CH3 ) -n-C6Hi3 oil 539 CH cf3 0 〇c Lor oil 540 CH cf3 0 〇c〇n (ch3) ch2ch3 oil 541 CH cf3 0 〇conhoch3 | oil_ 542 CH cf3 0 〇 > 0 丨 oil 543 CH cf3 0 〇c〇n (ch3) ch2ch2ch3 oil 544 CH cf3 0 〇c〇nhch2ch (och3) 2 oil 545 CH cf3 0 〇CONH4-C4H9 113-115 546 CH cf3 0 〇c〇nhch2 + ci-c6h4 oil 547 CH cf3 0 〇c〇nhch (ch3) c6h5 丨 oil 548 CH cf3 0 〇CONHCH2CH20CH3 92-94 549 CH cf3 0 〇 (r'o 190-192 I ------ install ------ order --- -^ Line (please read the precautions on the back before filling this page). This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) one 98-508352 Μ B7 • Five, invention description (96) Economy Printed by the Consumer Standards Cooperative of the Ministry of Standards, Ministry of Standards, XY mw R1 Melting point [° c] 550 CH cf3 0 〇c〇nhc (ch3) 2cch 90-92 551 CH cf3 0 〇C〇NHCH2-2-furanyl 93-95 552 CH cf3 0 〇c n (ch2) 3 91-93 553 CH cf3 0 〇CONHCH2-C-C3H5 oil 554 CH cf3 0 〇c〇nhc (ch3) 2ch2ch3 oil 555 CH cf3 0 〇c〇nh (ch2) 3c6h5 oil 556 CH cf3 〇〇 CONCH2-3-pyridyl 132-134 557 CH cf3 0 〇CON (CH3) -n-C4H9 oil 558 CH cf3 0 〇CON (CH2CH3) small C3H7 oil 559 CH cf3 0 0 0 person a. Oil 560 CH cf3 0 〇CONHCH2CH2C1 oil 561 CH cf3 0 〇c〇nhch2cn 152-157 562 CH cf3 0 〇CON (CH3) OCH3 丨 oil 563 CH cf3 0 〇CON (CH3) CH2CH = CH2 oil 564 CH cf3 0 〇CONHCH2COOCH3 oil 565 CH cf3 〇〇CON (CH3H-C3H7 oil 566 CH cf3 0 〇c〇n (ch3) ch2ch2cn) The size of this paper is applicable to Chinese national standards ((: milk) 8 4 specifications (210 '乂 297 mm) _99- I- ----- 丨 Install ------ Order ----- (Please read the notes on the back before filling this page), 508352

7 7 AB V. Description of the invention (97) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point 567 CH cf3 0 〇c〇n (ch3) ch2ch (〇ch3) 2 Oil 568 CH cf3 〇〇c〇 n (ch3) ch2ch (-ch2ch2〇-) Oil 569 CH cf3 0 〇c〇nhch2c (= ch2) chh3 Oil 570 CH cf3 0 〇c〇n (ch2ch3) ch2ch = ch2 Oil 571 CH cf3 0 〇CONHCeHs 83-85 — 572 CH cf3 0 〇CON (CH3) CH2CCH oil 573 CH cf3 〇0 c〇n (ch3) ch2cn oil-574 CH cf3 〇〇CON (CH3) CH2CH2N (CH3) 2 oil 575 CH cf3 〇CONCONCH2CH3 114 -116 576 CH cf3 0 〇c〇nhch2cf3 74-76 577 CH cf3 0 〇c〇n (ch2ch2ci) 2 oil 578 CH cf3 0 〇CONH-c-C4H7 sleeve 579 CH cf3 0 〇CON (CH2CH2CH3) CH2- c-C3H5 marriage 580 CH cf3 0 〇CON (CH3) -c-C6H11 'oil 581 CH cf3 0 〇c〇n (ch2ch3) ch2c (= ch2) ch3 sleeve 582 CH cf3 0 〇c〇nh〇ch2ch = ch2 90 -92 583 CH cf3 〇〇c〇nh〇ch2c6h5 126-128 584 CH cf3 〇〇c〇n (ch3) ch2c〇〇ch3 -oil 585 CH cf3 0 〇COONHCH3 230-232 This paper standard applies to Chinese national standards (CNS ) A4 size (210X297mm)-1 〇〇 — I ------- install ------ order ----- line (please read the precautions on the back before filling this page). 508352

A V. Description of the invention (98) Printing number of employees' cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [° c] 586 CH cf3 0 〇 CONHCH2CH3 83-85 587 CH cf3 0 〇c〇nhch (ch3) c 〇ch3 104-106 588 CH cf3 0 〇CONHCH (i-C3H7) COOCH3 sleeve 589 CH cf3 0 〇CON (CH3) CH2CON (CH3) 2 oil 590 CH cf3 0 〇cOn (ch3) + c4h9 oil 591 CH cf3 0 〇C〇NH〇-t-C4H9 103-105 592 CH cf3 0 〇C〇N (CH3) CH (i-C3H7) C〇〇CH3 oil ~ 593 CH cf3 〇〇CH (〇CH2CH3) 2 oil. 594 CH cf3 0 0 0 0 CH, oil 595 CH cf3 0 0. 〆 人 1 0 oil 596 CH cf3 0 〇0 people eight V CH, / A 丨 oil 597 CH cf3 〇0 0 The size of the oil paper is applicable to China National Standard (CNS) A4 (210 X 297 mm)-1 〇 1 I (Please read the precautions on the back before filling this page). Installation Engine Line 508352 V. Description of Invention (99)

AB Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [° c] 598 CH cf3 0 〇Λ ^ Oil 599 CH cf3 0 〇c〇nhch2c〇nhch3 101-103 600 CH cf3 0 〇c〇n ( ch2) 7 'oil 601 CH cf3 0 〇c〇n (ch2) 6 oil 602 CH cf3 0 〇C〇N (CH2CH3) CH2CH2〇CH3 oil 603 CH cf3 0 〇0 oil _604 CH cf3 〇〇0 605 CH cf3 0 〇0 0 person- ^. , V oil 606 CH cf3 0 〇C〇N (CH2CH3) CH2CH2CN oil 607 CH cf3 0 〇Λ, 0 oil 608 CH cf3 0 〇—C〇N (CH2CH3) -n-C4H9 oil (Please read the precautions on the back first (Fill in this page again.) The size of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). I. [〇2-508352 A7 B7. 5. Description of the invention. (100) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Number XY mw R1 Melting point [° c] 609 CH cf3 0 〇 // H 179-181 610 CH cf3 0 〇CONHCH (CH3) CONHCH3 136-138 611 CH cf3 0 〇c〇〇 (ch2) 4 64- 66 612 CH cf3 〇〇c〇nhch2c〇n (ch3) 2 107-109 613 CH cf3 0 〇c〇n (ch2c〇〇ch2ch3) 2 Oil 614 CH cf3 〇00 K · 〇, charge 180-182 615 CH cf3 0 〇Input 221-223 616 CH cf3 0 〇O w-N 234-236 617 CH cf3 0 〇ch, r human xi oil 618 CH cf3 0 〇CO (CH3) CH2 »6-CI-3-_ $ S 油 619 CH cf3 0 〇i 105-107 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -103-(Please read the precautions on the back before filling this page) 508352

7 7 AB V. Description of the invention (101) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY mw R1 Melting point [° c] 620 CH cf3 0 〇c〇nhch (ch3) ch (〇ch3) 2 Oil 621 CH cf3 0 〇CONHCH2CH2SCH3 oil 622 CH cf3 0 〇c〇nhch (ch3) ch2〇ch3 70-72 623 CH cf3 〇〇CONHCH2CH2NHCOCH3 124-126 624 CH cf3 0 〇c〇nh (ch2) 3 〇ch2ch3 oil 625 CH cf3 0 〇 c〇n (ch2ch3) ch2ch2ch3 oil 626 CH cf3 〇〇c〇n (ch2ch3) ch2〇ch3 oil 627 CH cf3 0 〇c〇nhch2ch2sch2ch3 oil. 628 CH cf3 0 〇c〇nhch2ch2 〇ch2ch3 59-61 629 CH cf3 0 〇oil 630 CH cf3 0 〇0 ΛΛ> 174-176 631 CH cf3 0 〇c〇nhch (ch3) ch (〇ch3) 2 oil 632 CH cf3 0 〇CONHCH2CH2SCH3 oil 633 CH cf3 〇〇c〇nhch (ch3) ch2〇ch3 70-72 634 CH cf3 〇〇CONHCH2CH2NHCOCH3 124-126 635 CH cf3 〇〇c〇nh (ch2) 3〇ch2ch3 oil · 636 CH cf3 0 〇C〇N (CH2CH3) CH2CH2CH3 oil This paper is suitable for Chinese countries Standard (CNS) A4 specification (210X297 mm)-104-I ------ install ------- order ----- line (please read the note on the back first) Matters then fill the page). 508 352

A V. Description of the invention (i〇2) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs X Y mw R1 ^ Melting point [° c] 637 CH cf3 0 〇c〇n (ch2ch3) ch2〇ch3 Oil 638 CH cf3 0 〇c〇nhch2ch2sch2ch3 oil 639 CH cf3 0 〇c〇nhch (ch3) ch2c〇Ch2ch3 oil 640 CH cf3 0 〇CONH-4-COOCH3-C6H4 189-191 641 CH cf3 0 〇CONH-4-CONH2-C6H4 265 -267 642 CH cf3 0 〇COHNHCH2CH2Br oil 643 CH cf3 0 〇chnhch2ch = chch2ci oil ~ 644 CH cf3 〇〇CONH-4-CONHCH3-C6H, 219-221 645 CH cf3 〇〇C〇NHCH2CH2CH2Br oil 646 CH cf3 0 〇c〇nhch2ch2ch2〇ch3 oil 647 CH cf3 0 〇CONH-4-CH2CH3-C6H4 97-99 648 CH cf3 0 〇c〇nhch2ch2 〇ch (ch3) 2 oil 649 CH cf3 0 〇CONHCH2GH2CH20CH2CH3 oil 650 CH cf3 0 0 Γ M. Oil 651 CH cf3 〇〇Ao 64-66 (Please read the precautions on the back before filling this page) • Packing _ This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 1; [〇5 508352 A7 B7. V. Description of the invention (103) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy XY mw R1 Melting point [° c] 652 CH cf3 0 〇〇CH ch3 oil 653 CH cf3 0 〇ch3 oil 654 CH cf3 0 〇ch2c〇n (ch3) ch2ch3 oil 655 CH cf3 0 〇CH2CON (CH3) 2 58-60 656 CH cf3 0 〇CH2C〇N (CH2) 4 101-103 657 CH cf3 0 〇1 oil 658 CH cf3 0 〇0 L / 90-92 659 CH cf3 0 〇CH2CONHCH2CH3 104-106 660 CH cf3 0 〇ch2cON (ch3) ch2ch2〇h oil 661 CH cf3 0 〇ch2cON (ch3) ch2ch2ch3 oil 662 CH cf3 〇 CH2CON (CH3) CH2CH f-OCH.CH.O-) Oil 663 CH cf3 0 〇ch2c〇nhch2ch3 104-106 664 CH cf3 〇CH2CON (CH3) CH2CH2OH Oil: Paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) _ 106-(Please read the notes on the back before filling this page) 508352 A7 B7 V. Description of the invention (104) Ministry of Economy Printed by the Consumer Standards of the Central Bureau of Standards XY mw R1 J Melting point [〇c] 665 CH cf3 0 〇ch2c〇n (ch3) ch2ch2ch3 oil 667 CH cf3 0 〇ch2c〇n (ch3) ch2ch (-OCH2CH20-) oil 668 CH cf3 0 〇79-81 669 CH cf3 〇〇ch2c〇nhch2ch2sch3 65-67 670 CH cf3 0 〇CH2CONHCH (CH3) CH2OCH3 86-88 671 CH cf3 〇〇CON (CH3) CH2CH2〇C OoC4H7 oil 672 CH cf3 〇〇CH2CONHCH2CH2Br 87-89 673 CH cf3 0 〇cON (ch3) ch2ch2〇c6h5 oil 674 CH cf3 0 〇c〇n (ch3) ch2ch2〇c00c3h5 oil 675 CH cf3 0 〇CONH-2- CH3-C6H4 104-106 676 CH cf3 〇〇CH2CON (i-C3H7) bucket * F-C6H4 102-104 677 CH cf3 0 〇oil 678 CH cf3 〇〇 human oil 679 CH cf3 0 〇cOn (ch3) ch2ch2 〇c〇nhc6h5 100-102 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm)-107-(Please read the precautions on the back first

508352 A7 B7 V. Description of the invention (i〇5) Number XY m W R1 Melting point. [° c] 680 CH cf3 0 〇C〇N (CH3) CH2CH2〇C〇NHCH2 ch3 oil 681 CH cf3 0 〇c〇n ( ch3) ch2ch2〇s〇2ch3 oil 682 CH CF3 0 〇CH2CONH-C-C4H7 133-135 683 CH cf3 〇〇ch2c〇nhch2cn 158-160 (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Municipal Bureau: Paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 108-508352

A B V. Description of the invention (106) Table 2

Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs XY w R1 Melting point [X] 684 N (CF2) 3CHF2 〇ch3 685 N (CF2) 2CF3 〇ch2ch3 686 N (cf2) 2cf3 〇c〇Ch2ch3 687 N (CF2) 2CF3 Θ OH 688 N (CF2) 2CF3 〇0CH3 689 N cf2cf3 〇ch3 690 N cf2cf3 〇CH2CH3 691 N CF2CF3 s ch3 692 N cf2cf5 s CH2CH3 693 N cf2cf3 s (CH2) 2CH3 CH3 694 CH cf3 cf3 696 CH cf3 〇 (CH2) 2CH3 697 CH cf3 〇ch (ch3) 2 698 CH cf3 〇 (ch2) 3ch3 V 699 CH cf3 〇CH (CH3) CH2CH3 700 CH cf3 〇ch2ch (ch3) 2 701 CH cf3 〇c ( ch3) 3 oil 702 CH cf3 〇 (CH2) 4CH3 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -i09-508352 A7 B7 V. Description of the invention (107) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY w R1 Melting point [° c] 703 CH cf3 〇ch (ch3) (ch2) 2ch3 704 CH cf3 〇 (CH2) 2CH (CH3 ) 2 705 CH cf3 〇ch2c (ch3) 3 706 CH cf3 〇Ring '· 〇5Η9 707 CH cf3 〇Ring-CeH n 708 CH cf3 〇CHO 709 CH cf3 〇ch = ch2 710 CH cf3 〇ch2ch = c (ch3) 2 711 CH cf3 〇ch2ch = ch2 712 CH cf3 〇C (CH3) = CH2 * 713 CH cf3 〇 (CH2) 5C = CH2 714 CH cf3 〇C (= CHCH3) CH3 715 CH cf3 〇ch2c ^ ch 716 CH cf3 〇ch2ch2c ^ ch 717 CH cf3 〇ch2c ^ cch2ch3 718 CH cf3 〇 (ch2) 4och 719 CH cf3 〇CHFCFa 720 CH cf3 COOCH2CH3 721 CH cf3 〇CH2CH20H 722 CH cf3 〇ch2ch2〇ch3 723 CH cf3 〇ch2c〇〇c (ch3) 3 724 CH cf3 〇ch2sc6h5 725 CH cf3 〇CH2CONHCH3 726 CH cf3 〇CH2CH2OH (CH) CH2OH ch3 728 CH cf3 〇C0CH3 729 CH cf3 〇ch2oc6h5 730 CH cf3 〇COCeHs Pack-(Please read the precautions on the back before filling out this page): The size of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ) _ U0 _ 508352

A

7 B V. Description of the invention (108) Printed number XY 1 w R1 melting point [° c] 731 CH cf3 〇cf2ch3 732 CH cf3 〇ch2cn 733 CH cf3 〇CH2CH (-0- ) CH2 734 CH cf3 〇CH2 (4 * OCH3) C6H5 735 CH cf3 〇ch2ch (oh) ch2sc6h5 736 CH cf3 〇ch = cf2 737 CH cf3 〇CCI = CHCI 738 CH cf3 〇 2 pyridyl 739 CH cf3 〇〇 c6h5 740 CH cf3 OH * 741 CH cf3 〇〇ch3 742 CH cf3 0 OCH2CH3 743 CH cf3 〇ochf2 744 CH cf3 〇och2c6h5 745 CH cf3 〇sch3 746 CH cf3 〇SCeHs 747 CH cf3 CHn cf3 NH3 2748 cf3 〇NHCH2CH3 750 CH cf3 〇N (CH2CH3) 2 751 CH cf3 〇N (CH2CN) 2 752 CH cf3 〇n (ch3) 2 753 CH cf3 〇NHCOCH3 754 CH cf3 〇nhc〇ch2ch3 755 CH cf3 〇OS02CH3 756 〇SOCH2 (4-Br) -C6H4 757 CH cf3 〇n (ch3) c〇〇ch2c6h5 758 N cf3 〇ch3 -ί I = —---Calendar-two!-I---I —,-mouth (please (Please read the precautions on the back before filling this page). _The size of the paper is applicable to Chinese national standards (C NS) A4 specification (210X297 mm) -in 508352 A7 B7 V. Description of the invention (109)

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs XY w R1 Melting point [〇C] 759 N cf3 〇CH2CH3 760 N cf3 〇 (ch2) 2ch3 761 N cf3 〇ch (ch3) 2 762 N cf3 〇 (ch2) 3ch3 763 N cf3 〇CH2CH (CH3) 2 764 N cf3 〇C (CH3) 3 765 N cf3 〇ch2c (ch3) 3 766 N cf3 〇--C5H9 767 N cf3 〇Ring'-CsH ”768 N cf3 〇CH2C = C ( CH3) 2 769 N cf3 〇ch2ch2c = ch2 770 N cf3 〇ch2ch = ch2 771 N cf3 〇 (CH2) 5CH = CH2 772 N cf3 〇ch2c = ch 773 N cf3 〇ch2c ^ cch2ch3 774 N cf3 〇CHFCF3 775 N COOCH2CH3 776 N cf3 〇ch2ch2〇h 777 N cf3 〇CH2CH20CH3 778 N cf3 och2c〇〇c (ch3) 3 779 N cf3 〇. Ch2sc6h5 780 N cf3 〇ch2c 〇nhch3 781 N cf3 〇CH2OH (CH2CH) 〇CH〇783 N cf3 〇COCH3 784 N cf3 〇ch2oc6h5 785 N cf3 〇COCeHs 786 N cf3 〇cf2ch3 (Please read the notes on the back before filling this page)

.n mIn I-line 508352 V. Description of the invention (110)

AB Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY w R1 Melting point [° c] 787 N cf3 〇ch2cn 788 N cf3 〇ch2ch2cn 789 N cf3 〇ch = cf2 790 N cf3 〇 Furanyl 791 N cf3 〇OH 792 N cf3 〇〇ch3 793 N cf3 〇OCH2CH3 794 N cf3 OOCHF2 795 N cf3 〇〇ch2c6h5 796 N cf3 〇nh2-797 N cf3 〇NHCH3 798 N cf3 〇nhch2ch3 799 N cf3 〇2 (ch2) (CH2CN) 2 801 N cf3 〇n (ch3) 2 802 N cf3 〇NHCOCH3 803 N cf3 0 NHCOCH2CH3 804 N cf3 〇OS02CH3 805 CH. Cf3 s ch3 806 CH cf3 s CH2CH3 807 CH cf3 s (CH2) 2CH3 s CH〇809 CH cf3 s CHFCF3 810 CH cf3 s ch2c ^ ch 811 CH cf3 s COOCH2CH3 812 CH cf3 s ch2c〇〇c (ch3) 3 813 CH cf3 s ch2cn 814 N cf3 s ch3 (Please read the notes on the back first Please fill in this page again) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) _113 一 508352 _V. Description of the invention (111) Printed by the Consumer Cooperatives of the Central Standards Bureau, Ministry of Economic Affairs, number XY w R1 c] 815 N cf3 s CH2CH3 816 N cf3 s (ch2) 2ch3 817 N cf3 s CHFCF3 818 N cf3 s ch2ch2〇h 819 N cf3 s CH2COOC (CH3) 3 820 N ch2ch2ci 〇ch2ch3 821 N ch2ch2ci 〇n2 823 822 ch3 824 CH chf2 〇CH2CH3 825 CH chf2 〇 (ch2) 2ch3 826 CH chf2 〇ch2c = ch2 827 CH chf2 〇C (CH3) = CH2 828 CH chf2 〇c〇〇ch2ch3 829 CH chf2 〇CH2CHHCH3 830〇 CH chf2 〇CHO 832 CH chf2 〇nh2 833 CH chf2 〇NHCOCH3 834 N chf2 〇ch3 835 N chf2 〇ch2ch3 836 N chf2 〇ch (ch3) (ch2) 4ch3 837 N chf2 〇ch2ch = CH2 CH2 838 NO chf2 〇nh2 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) _114_ 508352

A V. Description of Invention (II2) Table 3

(Please read the notice on the back first, printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. XY m V R1 Melting point [° c] 840 N (CF2) 3CHF2 0 〇ch3 841 N (CF2) 2CF3 0 〇ch2ch3 — 842 N ( CF2) 2CF3 0 〇c〇〇ch2ch3 843 N (CF2) 2CF3 0 〇SH 844 N (CF2) 2CF3 〇0 sch3 845 N (CF2) 2CF3 0 〇sch2c ^ ch 846 N CF2CF3 0 〇ch3 847 N cf2cf3 0 〇ch2ch3 848 N cf3 0 〇ch3 849 N cf3 0 〇ch2ch3 850 N cf3 0 〇 (ch2) 2ch3 851 N cf3 0 〇ch (ch3) 2 852 N cf3 0 〇 (CH2) 3CH3 853 N cf3 0 〇CH2CH (CH3) 2 854 N cf3 0 〇C (CH3) 3 855 N cf3 0 〇ch2c (ch3) 3 856 N cf3 0 〇ring> c5h9 857 N cf3 〇〇 ring, 〇6Hl1 858 N cf3 0 〇ch2ch two c (ch3 ) 2 859 N cf3 〇〇ch2ch2ch = ch2 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) —H5-Packing-: Write this page) Order 1 · Line 508352

A B7 V. Description of the invention (η3) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs X yam V R1 Melting point re] 860 N cf3 0 〇ch2ch = ch2 861 N cf3 0 〇 (ch2) 5ch = ch2 862 N cf3 0 〇ch2c ^ ch 863 N cf3 0 〇ch2c ^ cch2ch3 864 N cf3 〇〇CHFCFa 865 N cf3 0 〇c〇Ch2ch3 866 N cf3 〇〇ch2ch2oh 867 N cf3 〇〇ch2ch2och3 868 N cf3 0 〇CH2CO3OC 869 N cf3 0 〇CH2SPh 870 N cf3 〇〇CH2CONHCH3 871 N cf3 0 〇CH2CH (0H) CH20 872 N cf3 0 〇CH〇873 N cf3 0 〇c〇ch3 874 N cf3 0 〇ch2oc6h5 875 N cf3 0 〇COPh 876 N cf3 0 〇CF2CH3 877 N cf3 0 〇ch2cn 878 N cf3 0 〇ch2ch2cn 879 N cf3 0 〇ch = cf2 880 N cf3 0 〇2-I furanyl 881 N cf3 0 〇OH 882 N cf3 0 〇0CH3 883 N cf3 0 〇OCH2CH3 884 N cf3 0 〇0CHF2 885 N cf3 0 〇〇CH2Ph 886 N cf3 0 〇nh2 887 N cf3 0 〇NHCH3 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 116 _ (Please (Read the notes on the back before filling out this page) Φ.-Item refilling · Loading-508352

AB 5. Description of the invention (in) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economy XY m V R1 Melting point "G" 888 N cf3 0 〇nhch2ch3 889 N cf3 0 〇n (ch2ch3) 2 890 N cf3 0 〇N ( CH2CN) 2 891 N cf3 0 〇N (CH3) 2 892 N cf3 0 〇nhcoch3 893 N cf3 0 〇nhc〇ch2ch3 894 N cf3 〇〇〇s〇2ch3 895 N ch2ch2ci 〇〇ch2ch3 896 N ch2ch2ci 0 897n ch2ci 0 〇ch3 898. N chf2 0 〇ch3 899 N chf2 0 〇CH2CH3 900 N chf2 0 〇CH (CH3) (CH2) 4CH3 901 N chf2 0 〇ch2ch = ch2 902 N chf2 0 〇c〇ch2ch3 903 N chf2 0 〇nh2 904 CH cf3 0 〇ch3 60-61 905 CH cf3 1 〇ch3 906 CH cf3 0 〇CH2CH3 oil 907 CH cf3 1 〇CH2CH3 oil 908 CH cf3 0 〇 (CH2) 2CH3 oil 9P9 CH cf3 1 〇 (ch2) 2ch3 oil 910 CH cf3 0 〇CH (CH3) 2 911 CH cf3 1 〇ch (ch3) 2 912 CH cf3 0 〇 (CH2) 3CH3 913 CH cf3 1 〇 (ch2) 3ch3 914 CH cf3 0 〇CH (CH3) CH2CH3 915 CH cf3 1 〇ch (ch3) ch2ch3 This: Paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 117 -(Please read the notes on the back before filling this page) 508352 V. Description of Invention (II5)

AB Printed and edited by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5¾ XY m V R1 Melting point rc] 916 CH CF3 0 〇ch2ch (ch3) 2 917 CH CF3 1 〇CH2CH (CH3) 2 918 CH CF3 0 〇c (ch3) 3 919 CH CF3 1 0 C (CH3) 3 920 CH CF3 0 〇 (ch2) 4ch3 921 CH CF3 1 〇 (CH2) 4CH3 922 CH CF3 0 〇CH (CH3) (CH2) 2CH3 923 CH CF3 0 〇 (CH2) 2CH (CH3) 2 924 CH CF3 0 〇ch2c (ch3) 3 925 CH CF3 0 〇 ^ 'I0-C5H9-926 CH CF3 0 〇ring do-CsHi 1 927 CH CF3 0 〇CH2: (3-thienyl) oil 928 CH CF3 0 〇CH〇929 CH CF3 0 〇ch = ch2 930 CH CF3 0 〇CH2Ph 61-63 931 CH CF3 0 〇CH2CH = C (CH3) 2 932 CH CF3 0 〇ch2ch = ch2 933 CH CF3 0 〇C ( CH3) = CH2 934 CH CF3 0 〇 (CH2) 5C = CH2 935 CH CF3 0 〇C (= CHCH3) CH3 936 CH CF3 0 〇ch2c ^ ch 937 CH CF3 0 〇ch2ch2och2 938 CH CF3 0 〇ch2c3 939 CH CF3 0 〇 (CH2) 4C ^ CH 940 CH CF3 0 〇CHFCF3 941 CH CF3 0 〇COOCH2CH3 942 CH CF3 0 〇CH2CH20H 943 CH CF3 0 〇CH2CH20CH3 (Please read the precautions on the back before filling this page) Installation ·

、 1T This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) — 508352

AB 5. Description of Invention (II6) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY m V R1 Melting point [° c] 944 CH cf3 0 〇CH2COOC (CH3) 3 945 CH cf3 〇〇CH2SPh 946 CH cf3 0 〇CH2CONHCH3 947 CH cf3 0 〇CH2CH (OH) CH2OH 948 CH cf3 0 〇CH2COCH3 949 CH cf3 〇〇COCH3 950 CH cf3 0 〇CH2〇ph 951 CH cf3 〇〇COPh 952 CH cf3 0 〇CF2CH3 953 CH cf3 〇〇ch2cn Oil ' 954. CH cf3 〇〇CH2CH (-0-) CH2 955 CH cf3 0 〇CH2 (4-〇CH3) Ph 956 CH cf3 0 〇CH2CH (〇H) CH2SPh 957 CH cf3 0 〇ch = cf2 958 CH cf3 〇〇 CCI: CHCI 959 CH cf3 0 0 Ph 120-121 960 CH cf3 0 〇Thienyl 87-89 961 CH cf3 0 〇〇Ph 962 CH cf3 0 〇OH 963 CH cf3 0 〇0CH3 964 CH cf3 0 〇〇CH2CH3 965 CH cf3 0 〇OCHF2 966 CH cf3 0 〇0CH2Ph 967 CH cf3 0 〇sch3 968 CH cf3 〇〇SPh 969 CH cf3 0 〇nh2 190-191 970 CH cf3 〇〇NHCH3 971 CH cf3 〇〇NHCH2CH3 This paper standard applies to Chinese national standards (CNS) A4 specification (210X297 mm)-jig _ ---- ^ ------ ^-install-- (Please read the precautions on the back before filling out this page), 11 508352 A7 B7 V. Description of the invention (in) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System number XY m V R1 Melting point [° c] 972 CH cf3 0 〇n (ch2ch3) 2 973 CH cf3 0 〇n (ch2cn) 2 974 CH cf3 0 〇n (ch3) 2 975 CH cf3 0 〇NHCOCH3 976 CH cf3 0 〇NHCOCH2CH3 977 CH cf3 0 〇OS02CH3 978 CH cf3 0 〇SQCH2 (4: B``) -C6H4 979 CH cf3 〇〇N (CH3) COOCH2Ph 980 CH cf3 〇nch3 ch3 981 CH cf3 0 NCH2CH3 ch3-982 nch2ch3 CH2CH3 983 CH cf3 0 nch2cn ch2ch3 984 CH cf3 0 nch2och3 NHCH3 985 CH cf3 〇nch2〇ch2ch3 CN 986 CH cf3 0 nch2ch = ch2 ch3 987 CH3 CH3 CH2 CH3 0 CH3 cf3 0 990 CH chf2 0 〇ch3 991 CH chf2 0 〇ch2ch3 992 CH chf2 0 〇 (CH2) 2CH3 993 CH chf2 0 〇ch2ch = ch2 994 CH chf2 0 〇C (CH3) = CH2 995 CH chf2 0 〇COOCH2CH3 996 CH 〇CH2CONHCH3 997 CH chf2 〇〇CF2CH3 998 CH chf2 〇〇 C H〇999 CH chf2 〇〇nh2 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm)-120-(Please read the precautions on the back before filling this page) 508352 A7 B7 V. Description of the invention (ns ) >, t ·· Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY m V R1 Melting point [° c] 1000 CH chf2 0 〇NHCOCH3 1001 N CF2CF3 0 s ch3 1002 N CF2CF3 0 s CH2CH3 1003 N cf2cf3 0 s (CH2) 2CH3 1004 N cf3 0 s ch3 1005 N cf3 0 s CH2CH3 1006 N cf3 0 s (CH2) 2CH3 1007 N cf3 〇s CHFCF3 1008 N cf3 0 s CH2CH20H 1009 N cf3 0 s ch2c〇c (ch3) 3 -1010 CH cf3 0 s ch3 1011 CH cf3 〇s ch2ch3 1012 CH cf3 0 s (CH2) 2CH3 1013 CH cf3 0 s CH〇1014 CH cf3 0 s CHFCF3 1015 CH cf3 0 s ch2c = ch 1016 CH cf3 0 s COOCH2CH3 CH cf3 〇s ch2c〇〇c (ch3) 3 1018 CH cf3 0 s ch2cn • Installation-(Please read the precautions on the back before filling out this page), 11 k-sheet scales are applicable to Chinese national standards (CNS> A4 specifications (210X297 mm) _ 121-508352 A7 B7 V. Description of Invention (ll9) Table · 4

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs XY m. V R2 Melting point 1019 N (CF2) 3 chf2 0 s H ch2ch3 1020 N cf2cf2cf3 0 s H CH2CH3 1021 N cf2cf3 0 s H ch2ch3 1022 N CH2CH2CI 0 s H CH2CH3 1023 N ch2ci 0 s H CH2CH3 1024 N cf3 0 s CH2CH3 CH2CH3 1025 N cf3 0 s (ch2) 2ch3 H 1026 N cf3 0 s ch (ch3) 2 H 1027 N cf3 0 s ch2ch (ch3) 2 H 1028 N cf3 0 sc (ch3) 3 H 1029 CH cf3 0 s H ch3 oil 1030 CH cf3 0 s H CH2CH3 oil 1031 CH cf3 0 s H c (ch3) 3 oil 1032 CH cf3 0 s CH2CH3 c〇Ch2ch3 1033 CH cf3 0 s (CH2 ) 2CH3 COOCH2CH3 1034 CH cf3 0 s CH (CH3) 2 c〇〇ch2ch3 1035 CH cf3 0 s ch (ch3) 2 CONHCH2CH3 1036 CH cf3 0 s ch (ch3) 2 CONHCH2CH3 1037 CH cf3 0 s CH (CH3) 2 c 〇n (ch2ch3) 2 1038 CH cf3 0 s ch (ch3) 2 CONH-ring> C3H7 This paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 122-508352 A7 B7 V. Description of the invention ( 12〇) Staff Cooperative Cooperative Printing No. XY m V R2 r " Melting point [° C] 1039 CH cf3 〇s C (CH3) 3 c〇〇ch 2ch3 1040 CH cf3 0 s H CONHCH2CH3 1041 CH cf3 0 s H cOn (ch2ch3) 2 1042 CH cf3 0 s H COOCH2CH3 oil 1043 CH cf3 0 s H CH2C〇CH2CH3 oil 1044 CH cf3 〇s H ch2cho 1045 CH cf3 0 s H CH20CH3 1046 CH cf3 〇s H CH2OCH2Ph 1047 CH cf3 0 s HH 1048 CH cf3 〇s ring,: -C5H9 H. 1049 CH cf3 〇scOn (ch3) 2 ch3 oil 1050 CH cf3 〇s ch3 ch2ch2oh 1051 CH cf3 〇s ch3 ch2ch2och3 1052 CH cf3 〇s ch3 CH2CH2〇CH2Ph 1053 CH cf3 0 s ch3 CH2CH2SP, h 1054 CH cf3 〇s ch3 ch3 oil 1055 CH cf3 0 s ch3 ch2ch2CH 10CH CH5 cf3 cf3 s ch3 CH2CH2CONH2 1058 CH cf3 〇s H (4-CF3〇) C6H4 120-121 1059 CH cf3 0 s ch2c ^ ch H 1060 CH cf3 0 s ch2ch2c = ch H 1061 CH cf3 〇s ch2c ^ cch2ch3 H 1062 CH cf3 〇 s ch2ch = c (ch3) 2 H 1063 CH cf3 〇s ch2ch2ch = ch2 H 1064 CH cf3 〇s ch2ch = ch2 H 1065 CH cf3 〇s C (CH3) = CH2 H 1066 CH cf3 〇s chfcf3 H (Please read first Note on the back, please fill out this page again) This paper size applies Chinese national standards ( CNS) A4 specification (210X297 mm) —123-508352 A.7 B7 V. Description of the invention (1 called the printout number XY m V R " R3 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Melting point 1067 CH cf3 〇s COOCH2CH3 H 1068 CH cf3 0 s ch2ch2〇h H 1069 CH cf3 0 s CH2CH20CH3 H 1070 CH cf3 0 s ch2c〇〇c (ch3) 3 H 1071 CH cf3 〇s CH2COCH3 H 1072 CH cf3 0 s COCH3 H 1073 CH cf3 0 s CH2〇 Ph H 1074 CH cf3 〇s COPh H 1075 CH cf3 0 s CO (4-CI) -C6H4 H 1076 CH cf3 0 s CF2CH3 H. 1077 CH cf3 〇s ch2cn H 1078 CH cf3 0 s CH2CH2CN H 1079 N cf3 0 s HH 1080 N cf3 0 s H CH2CH2CN 1081 N cf3 0 s H ch2c〇2c (ch3) 3 1082 N cf3 0 s H ch2cho 1083 N cf3 0 s H CH2CH2OH 1084 N cf3 0 s H CH2CH2〇CH3 1085 N cf3 0 s ring "C5H9 H 1086 N cf3 0 s ch3 COOCH2CH3 1087 N cf3 0 s ch3 C〇〇H 1088 N cf3 0 s ch3 c〇nh2 1089 N cf3 0 s ch3 c〇nhch2ch3 1090 N cf3 0 s ch3 cOn (ch2ch3) 2 1091 N cf3 0 s ch3 CONHCH3 1092 N cf3 0 s ch3 conhch2cn 1093 N cf3 〇s ch3 CON (CH2CN) 2. 1094 N c f3 0 s ch3 c〇n (ch3) 2 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) _ 124-508352

A

7 B V. Invention Description (I22) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY m V R3 Melting point 1095 N cf3 〇s 〇ch2ch3 1096 N cf3 0 s ch2ch2och OCH2CH3 1097 N cf3 0 s ch2c ^ cch2ch3 1098 N cf3 0 s ch2ch = c (ch3) 2 〇ch2ch3 1099 Bu! cf3 0 s ch2ch2ch = ch2 OCH2CH3 1100 N cf3 〇s ch2ch = ch2 OCH2CH3 1101 N cf3 0 s C (CH3) = CH2 OCH2CH3 1102 N cf3 〇s chfcf3 och2ch3 1103 N cf3 osc 〇 ch2ch3 1 h OCH2CH3-1105 N cf3 0 s CH2CH20CH3 OCH2CH3 1106 N cf3 〇s CH2COOC (CH3) 3 〇ch2ch3 1107 N cf3 0 s ch2coch3 H 1108 N cf3 0 s COCH3 H 1109 N cf3 0 s CH2Oph H H1010 1111 N cf3 0 s CO (4-CI) -C6H4 H 1112 N cf3 0 s CF2CH3 H 1113 N cf3 0 s ch2cn H 1114 N cf3 0 s CH2CH2CN H 1115 CH cf3 0 〇CH2CH3 CH2CH3 1116 CH cf3 0 〇 (CH2) 2CH3 H 1117 CH cf3 0 0 H ch2ch3 Oil 1118 CH cf3 0 〇ch (ch3) 2 c〇〇ch2ch3 1119 CH cf3 0 〇ch (ch3) 2 C〇〇H 1120 CH cf3 〇〇ch (ch3) 2 CONH2 1121 CH cf3 〇〇ch (ch3) 2 ch3 1122 CH cf3 0 〇C (CH3) 3 H This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm)-125-(Please read the precautions on the back before (Fill in this page) 508352

A B7 V. Description of the invention (i23) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy X Ym V R2 R0 Melting point 1123 CH cf3 0 〇H ch3 1124 CH cf3 〇〇H ring 'c5h9 1125 CH cf3 0 〇H ch2ch2ch3 1126 CH cf3 0 〇H Ph 103-10 1127 CH cf3 0 〇H pyridyl 1128 CH cf3 〇〇H furyl 1129 CH cf3 0 〇ring-C5H9 Η 1130 CH cf3 〇〇ch3 COOCH2CH3 1131 CH cf3 0 〇ch3 CO. 〇H 1132 CH cf3 0 0 ch3 CONH2-1133 CH cf3 〇〇ch3 CONHCH2CH3 1134 CH cf3 0 〇ch3 CO (CH2CH3) 2 1135 CH cf3 0 〇ch3 CONHCH3 1136 CH cf3 0 〇ch3 CONHCH2CN 1137 CH cf3 0 〇ch c〇n (ch2cn) 2 1138 CH cf3 0 〇ch3 c〇n (ch3) 2 1139 CH cf3 0 〇ch2c ^ ch H 1140 CH cf3 0 〇ch2ch2c ^ ch H 1141 CH cf3 0 〇ch2c ^ cch2ch3 H 1142 CH cf3 0 〇ch2ch = c (ch3) 2 H 1143 CH cf3 0 〇ch2ch2c = ch H 1144 CH cf3 0 〇ch2ch = ch2 H 1145 CH cf3 0 〇C (CH3) = CH2 H 1146 CH cf3 0 〇CHFCF3 H 1147 CH cf3 0 〇COOCH2CH3 H 1148 CH cf3 0 〇CH2CH20H H 1149 CH cf3 0 〇CH2CH 20CH3 H 1150 CH cf3 0 〇ch2c〇〇c (ch3) 3 H This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 126-(Please read the precautions on the back before filling this page) 蟀Refill the items _ Binding and ordering 508352 A7 B7 V. Description of the invention (I24) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy XY m V R2 Melting point 1151 CH cf3 0 〇ch2c〇ch3 H 1152 CH cf3 0 〇COCH3 H 1153 CH cf3 〇〇CH2〇ph H 1154 CH cf3 0 〇COPh H 1155 CH cf3 0 〇CO (4-CI) -C6H4 H. 1156 CH cf3 0 〇CF2CH3 H 1157 CH cf3 0 〇ch2cn H 1158 CH cf3 0 〇ch2ch2cn H 1159 N cf3 0 〇CH2CH3 CH2CH3 1160 N cf3 0 〇 (CH2) 2CH3 H-1161 N cf3 0 〇CH (CH3) 2 CONH2 1162 N cf3 0 〇CH (CH3) 2 ch3 1163 N cf3 〇〇C (CH3) 3 H 1164 N cf3 0 〇H ch3 1165 N cf3 0 〇H CH2CH3 1166 N cf3 0 〇H CH2CH2CH3 1167 N cf3 0 〇H Ph 1168 N cf3 0 〇H 2-pyridyl 1169 N cf3 0 〇H Furyl 1170 N cf3 0 〇 丨 ring, -C5H9 Η 1171 N cf3 0 〇ch3 C〇〇CH2CH3 1172 N cf3 0 〇ch3 C〇〇H 1173 N cf3 0 〇ch3 CONH2 1174 N cf3 0 〇ch3 C〇NHCH2CH3 1175 N cf3 0 〇ch3 c〇n (ch2ch3) 2 1176 N cf3 0 〇ch3 CONHCH3 1177 N cf3 0 〇ch3 CONHCH2CN 1178 N cf3 〇〇ch3 c〇n (ch2cn) 2 L Paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) _ 127-508352 A7 B7 V. Description of Invention (I25) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Print number XY m V R1 Melting point 1179 N cf3 0 〇ch3 c〇n (ch3) 2 1180 N cf3 0 〇ch2c ^ ch H 1181 N cf3 0 〇ch2ch2c ^ ch H 1182 N cf3 0 〇ch2c ^ cch2ch3 H 1183 N cf3 〇〇CH2CH = C (CH3) 2 H 1184 N cf3 0 〇ch2ch2ch = ch2 H 1185 N cf3 0 〇ch2ch = ch2 H 1186 N cf3 0 0 C (CH3) = CH2 H 1187 N cf3 0 〇chfcf3 H 1188 N cf3 0 〇COOCH2CH3 H 1189 N cf3 0 〇CH2CH2OH H 1190 N cf3 〇0 ch2ch2och3 H 1191 N cf3 0 〇CH2COOC (CH3) 3 H 1192 N cf3 0 〇CH2COCH3 H 1193 N cf3 0 〇COCH3 H 1194 N cf H 1195 N cf3 0 〇COPh H 1196 N cf3 0 〇CO (4-CI) -C6H4 H 1197 N cf3 0 〇cf2ch3 H 1198 N cf3 0 〇ch2cn H 1199 N cf3 0 〇ch2ch2cn H 1200 N cf3 0 〇CH2NHS02CH3 ch3 1201 N cf3 0 〇 (ch2) 2nhs〇2ch3 ch3 1202 N cf3 0 〇CH2NHS02CH2〇2CH2CH2 CH2NHS〇2CH2Ph 1204 CH cf3 0 〇 (ch2) 4nhs〇2cf3 ch3 1205 CH cf3 〇〇 (ch2) 2s (ch2) 2ch3 CH2CH2CH3 1206 CH cf3 0 〇 (ch2) 4s (ch2) 4〇ch3 ch3 National Standard (CNS) A4 Specification (210X297mm) _ 128-508352

A

7 B V. Description of the invention (i26) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy XY m V R2 R3 Melting point [° c] 1207 CH cf3 0 s ch3 (ch2) 2s (ch2) 2cn 1208 CH cf3 0 s CH2NHS02CH2CH3 ch3 1209 CH cf3 0 s CH2NHS〇2CH2Ph CH2CH2CH3 1210 CH cf3 0 s (ch2) 2nhs〇2ch3 cf3 1211 CH cf3 0 s H CH2NHS02CH3 1212 CH cf3 0 s CH (CH3) CH2NHPh cf2 013CH cf2 2-F) -C6H4 ch2ch2ch3 1214 CH cf3 〇s (ch2) 6nhch2) 6〇ch3 cf3 1215 CH cf3 0 s H (CH2) 2NH- (2-F)-c6h4-1216 CH cf3 〇s (CH2) 3NHCH2CN H 1217 CH cf3 0 s (CH2) 20 (3-CI) -C6H4 ch3 1218 CH cf3 0 s cf3 (CH2) 6NHCH2CF3 1219 CH cf3 0 s ch3 (CH2) 20 (3-CH3) -CsH4 1220 CH cf3 0 〇H CH2NHPh 1221 CH cf3 0 〇ch3 (CH2) 4S (2-B``) -C6H4 1222 CH cf3 0 〇 (ch2) 6nh (ch2) 2〇ch3 ch3 1223 CH cf3 0 〇 (ch2) 2nh (ch2) 4〇ch3 H 1224 CH cf3 0 〇cf3 (CH2) 3NH- (4-CN) -C6H4 1225 CH cf3 0 〇 (ch2) 4nhch2cf3 ch3 1226 CH cf3 0 〇C2F5 (CH2) 2〇 (3-CH3) -C6H4 1227 CH cf3 0 〇 (CH2) 4NHCH2CN H 1228 CH cf3 0 〇 (CH2) 30 (4-CI) -C6H4 C 2F5 (Please read the notes on the back before filling out this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 1 129 _ 508352 A7 B7 V. Description of invention (rr Table 5

Consumption cooperation of employees of the Central Bureau of Standards of the Ministry of Economy 丨 No. X Υ V R4 R5 R6 Melting point [° c] 1229 CH cf3 〇HHHH oil 1230 CH cf3 0 HH ch3 H oil 1231 CH cf3 〇HH ch2ch3 H oil 1232 CH cf3 〇HH ch ( ch3) 2 H 1233 CH cf3 〇HH CH2CH (CH3) 2 H 1234 CH cf3 〇HH CH (CH3) CH2CH3 H 1235 CH cf3 〇HH ch2〇h H 1236 CH cf3 〇HH ch (〇h) ch3 H 1237 CH cf3 〇HH ch2sh H 1238 CH cf3 〇HH CH2CH2SCH3 H 1239 CH cf3 〇HH (ch2) 3nh2 H 1240 CH cf3 〇HH (CH2) 4NH2 H 1241 CH cf3 〇HH ch = ch2 H 1242 CH cf3 〇HH (CH2) 2COO 1243 CH cf3 〇HH (CH2) 2COOH H 1244 CH cf3 〇HH (ch2) 2c〇nh2 H 1245 CH cf3 s ch3 ch3 HH 1246 CH cf3 〇HH ch3 ch3 (oil 1247 CH cf3 〇HH ch2c00ch3 H 1248 CH cf3 〇HH CH2COOH H This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 public attack) _ 13〇— --------- ^ ΙΙΓ Install-(Please read the precautions on the back before filling (This page) 508352

A 5. Description of the invention (l28) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XYV R4 R5 R6 R / Melting point [° c] 1249 CH cf3 〇HH CH2C〇NH2 H 1250 CH cf3 〇HH CH2Ph H 1251 CH cf3 〇 HH CH2- (4-〇H) -C6H4 H 1252 CH cf3 〇HH CH2- (3-Π-D heteroaryl) H 1253 CH cf3 〇ch3 ch3 HH oil 1254 CH cf3 〇ch3 HHH oil 1255 CH cf3 〇ch3 HH Ph 1256 CH cf3 〇H (ch2) 4 H 1257 CH cf3 NH H (CH2) 4 H 1258 CH cf3 nch3 H (ch2) 4 H _ 1259 CH cf3 nch2c6h4 H (CH2) 4 H 1260 CH cf3 NCH (CH3) 2 H (CH2) 4 H 1261 CH cf3 〇Ph H Ph H 1262 CH cf3 NH Ph H Ph H 1263 CH cf3 nch3 Ph K Ph H 1264 CH cf3 NCH2CeH4 Ph H Ph H 1265 N cf3 〇HH CH2CH3 H oil 1266 N cf3 〇 HH ch (ch3) 2 H 1267 N cf3 〇HH ch2ch (ch3) 2 H 1268 N cf3 〇HH CH2COOH H 1269 N cf3 〇HH CH2C〇〇CH3 H 1270 N cf3 〇HH CH2CONH2 H 1271 N cf3 〇ch3 ch3 HH 1272 N cf3 〇H (CH H 1273 N cf3 〇HH CH2CH2SCH3 H 1274 CH cf3 SHHHH oil (Please read the precautions on the back before Write Page) This paper scale applicable Chinese National Standard (CNS) A4 size (210X297 mm) _ 131 _ 508 352

A B7 V. Description of Invention (i29) Table 6 R8

C Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs X Υ R8 R1 Melting point [° c] 1275 CH cf3 ch3 SH 209-210 1276 CH cf3 ch3 sch3 1277 CH cf3 ch3 SCH2CH3 1278 CH cf3 ch3 s (ch2) 2ch3 1279 CH cf3 ch3 sch (ch3) 2 1280 CH cf3 ch3 SPh 1281 CH cf3 ch3 s (ch2) 3ch3 1282 CH cf3 ch3 SCH (CH3) CH2CH3 1283 CH cf3 ch3 sch2ch (ch3) 2 1284 CH cf3 ch3 OH 119-120 1285 ch3 0CH3 1286 CH cf3 ch3 OCH2CH3 1287 CH cf3 ch3 oc hf2 1288 CH cf3 ch3 〇CH2Ph 1289 CH cf3 ch3 OCONHPh 1290 CH cf3 ch3 OCONH- (4-F) -C6H4 1291 CH cf3 ch3 〇C. -CI) -C6H3 1292 CH cf3 ch2cn och3 1293 CH cf3 ch2cn OCH2CH3 1294 CH cf3 ch2cn ochf2-Install! (Please read the precautions on the back before filling out this page.)

A4 S N cm 508352

A B7 V. Description of the invention (13〇) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs XY R0 R1 Melting point [° c] 1295 CH cf3 ch2cn 〇CH2Ph 1296 CH cf3 ch2cn OCONHPh 1297 CH cf3 ch2cn 〇C〇NH- ( 4-F) -C6H4 1298 CH cf3 ch2och2ch3 0CH3 1299 ΓΗ cf3 ch2〇ch2ch3 OCH2CH3 1300 CH cf3 ch2〇ch2ch3 OCHF2 1301 CH cf3 ch2〇ch2ch3 〇CH2Ph 1302 CH cf3 CH20 CH2 CH3 CH3 OCON CH2CH3 134-135 1305 CH cf3 H (CH2) 2CH3 1306 CH cf3 H ch (ch3) 2 1307 CH cf3 H ring, -c3h5 1308 CH cf3 H (CH2) 3CH3 1309 CH cf3 H CH (CH3) CH2CH3 1310 CH cf3 H ch2ch (ch3) 2 1311 CH cf3 H ch = ch2 1312 CH cf3 H ch2ch = c (ch3) 2 1313 CH cf3 H ch2ch2ch = ch2 1314 CH cf3 H ch2ch = ch2 1315 CH cf3 HC (CH3) = CH2 1316 CH cf3 H CHFCF3 1317 CH cf3 H COOCH2CH3 1318 CH cf3 H CH2CH20H 1319 CH cf3 H CH2CH2OCH3 1320 CH cf3 H CH2COOC (CH3) 3 1321 CH cf3 ch3 ch2c〇c (ch3) 3 1322 CH cf3 ch2cn CH2COOC (CH3) Note on the back 4 items are refilled and loaded —: copybook ) Under this paper scale applicable Chinese National Standard (CNS) A4 size (210X297 mm) a 508 352 133 _

A V. Description of the invention (1 Called by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, XY Re R1 Melting point [° c] 1323 CH cf3 CH2OCH2CH3 ch2c〇c (ch3) 3 1324 CH cf3 H CH2SPh 1325 CH cf3 H ch2c. nhch3 1326 CH c cf3 H CH2COCH3 1327 CH cf3 H COCH3 1328 CH cf3 H CH2〇ph 1329 CH cf3 H COPh 1330 CH cf3 H CO (3-CI) -C6H4 1331 CH cf3 H CF2CH3 1332 CH cf3 H CH2CN 1333 CH cf3 H ch2ch2cn 1334 CH cf3 H ch2ch (-〇-) ch2 1336 CH cf3 H CH2 (4-OCH3) Ph 1337 N cf3 ch3 SH 1338 N cf3 ch3 sch3 1339 N cf3 ch3 SCH2CH3 1340 N cf3 ch3 SPh 1341 N cf3 ch3 ch3 ) 2 1342 N cf3 ch3 OH 1343 N cf3 ch3 0CH3 1344 N cf3 ch3 〇CH2CH3 1345 N cf3 ch3 〇CH2Ph 1346 N cf3 ch3 OCONHPh 1347 N cf3 ch2cn Oh2CH3CH 3CH 1351 N cf3 ch2och2ch3 0CH3 (Please read the precautions on the back before filling out this page) 508352 A7 B7 V. Description of the invention (l32) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Number XY Re R1 Melting point [ c] 1352 N cf3 CH20CH2CH3 〇CH2Ph 1353 N cf3 ch2〇ch2ch3 OCONHPh 1354 N cf3 H ch3 1355 N cf3 H CH2CH3 1356 N cf3 H (CH2) 2CH3 1357 N cf3 H ch (ch3) 2 1358 N cf3 H (ch2 1359 N cf3 H CH (CH3) CH2CH3 1360 N cf3 H ch2ch (ch3) 2 1361 N cf3 H CH2C = C (CH3) 2 1362 N cf3 H ch2ch = ch2 1363 N cf3 HC (CH3) H = CH2 1364 N cf3 H COOCH2CH3 1365 N cf3 H CH2CH20H 1366 N cf3 H CH2CH20CH3 1367 N cf3 H ch2c00c (ch3) 3 1368 N cf3 H CH2SPh 1369 N cf3 H CH2CONHCH3 1370 N cf3 H CH2COCH3 1371 N cf3 H C0CH3 cf3 H COPh 1374 N cf3 H CH2CN 1375 N cf3 H CH2CH2CN 1376 CH cf3 ch3 CH2CH3 oil. Packing-(Please read the precautions on the back before filling out this page) 4 This paper size applies to China National Standard (CNS) A4 specifications ( 210X297 mm) _ 135-508352 Λ 7 B7 V. Inventory 3) C. Biological Examples Example 1 Prepare petri dishes with filter paper at the bottom and containing about 5 ml of medium. Several filter papers each containing about 30 24 hour-old Heliothis virescens eggs were immersed in an aqueous solution of the test formulation for 5 seconds, and then placed in the petri dish. An aqueous solution of another 200 μl of the test formulation was spread on the medium. The petri dish was sealed and stored in a climate control room at approximately 25 ° C. After 6 days of storage, the effect of the formulation on the eggs and larvae that may have hatched therefrom was determined. At a concentration of 300 p p m (calculated as the active compound content), the formulations of Examples 7 9 and 88 caused a mortality of 90 to 100%. Example 2 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Place the germinated broad bean seeds (Vicia faba) with radicle into a brown glass bottle filled with tap water Then, about 100 bean aphids (Aphis fabae) were implanted. These plants and bean aphids were impregnated with the aqueous solution of the tested formulation. After the solution was dripped, these plants and bean aphids were stored in a climate control room (16 hours of light per day, 25 t, 40-60% relative atmospheric humidity). After 3 and 6 days of storage, the effect of the formulation on the bean aphid was determined. At a concentration of 300 p P m (calculated based on the active compound content), Examples 79, 78, 80, 81, 83, 84, 88, 133, 135, 136, 137, 138, 139, 1117, this: paper Applicable to China National Standard (CNS) A4 specification (210X297 mm) ^ 36 _ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 508352 Λ7 _ Β7 V. Description of Invention 1 (34) 1229, 1230, 1231, 1246 and 1254 The formulation caused 90--100% mortality of the bean aphid. Example 3 The leaves of 12 rice plants with a stem length of 8 cm were immersed in an aqueous solution of the test formulation for 5 seconds. After the solution was dropped, the rice plants thus treated were placed in a petri dish, and about 20 larvae of rice brown planthopper (Nilaparvatalugens) were implanted (L 3 stage). The petri dish was sealed and stored in a climate controlled room (16 hours of light per day, 25 t: 40-60% relative atmospheric humidity). After 6 days of storage, the mortality of rice brown planthopper larvae was determined. At a concentration of 300 p p m (calculated as the active compound content), the formulations of Examples 8, 8, 139, and 9 2 7 caused a mortality of 90 to 100%. Example 4 Germinated broad bean seeds (Vicia faba) with radicle were placed in a brown glass bottle filled with tap water. 4 ml of an aqueous solution of the tested formulation was dropped into the brown glass bottle. About 100 bean aphids (APhis fabae) were subsequently implanted on the broad beans. These plants and bean aphids were then stored in a climate control room (16 hours of light per day, 25 ° C, 40-60% relative atmospheric humidity). After 3 and 6 days of storage 'the root-systemic activity of the formulation on the bean aphid was determined. At a concentration of 30 PP m (calculated based on the content of the active compound), Examples 7 8, 7 9, 80, 8 1, 8 3, 84, 88, 133, 135, 136, 137, 138 copies Applicable to the national standard (CNS) A4 specification (210X297 mm) _ 137-(Please read the precautions on the back before filling this page)

1T 508352 A7 B7 V. Description of the invention < 35), 139,187,1117,1 2 29,1230, 1 2 3 1, 1 2 4 6 and 1 2 5 4 formulations cause beans through root-systemic action 90 to 100% mortality of aphids. (Please read the precautions on the back before filling out this page). 11 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 138

Claims (1)

508352 A8 B8 C8 D8 BI VI. Scope of patent application M Annex I CA): No. 871 0941 Patent Application No. 4 Chinese Application for Patent Scope Amendment April 1991 Amendment 1. One of the following. Formula I-4—Haloalkyl-1 3 -heterocyclylpyridine or 4 monohaloalkyl-5 -heterocyclylpyrimidine compound or its salt form Q where Y is 歯 —C 1 — C6 courtyard; X is C. H or N; m is 〇 or 1; Q is a 5-membered heterocyclic group (please read the precautions on the back before filling this page) Ministry of Economic Affairs Printed by the Intellectual Property Bureau Consumer Cooperatives χ- 'N where a) X 1 b) X 1 c) X 1 d) X 1 W, X2 two NRa, X3 two CRbR1 or NRa, X ^ CRbR1, X: 3 = W Or hX ^ CRaR1, X3 = NR ^ V, X 2 = C. R a R 2, X 3 = CR b R 3 or this paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 508352 A8 B8 ^ C8 _____ D8 6. Scope of patent application e) Xi = V, X2 = CR4.R5, X3 = CR6R7 or " Xΐ two NRa, X2 two CRbRi, X3 two NR8; (Please read the notes on the back before filling in This page) R d and R d together are a bond V is oxygen or sulfur; W is oxygen; R i is hydrogen, C c 1-c 6) alkyl, (c 2-C 6) alkenyl, (C 3 —C 0 cycloalkyl, wherein the last three groups mentioned can be optionally substituted by one or more groups selected from the group consisting of cyano, nitro, hydroxy, —C (= W) R 1 0, -C (two nor 丄 0) R 1 0, -NR 1 0 C (= W) OR10 7 —— C (= W) 〇R 1 0 =, -C (two W) NR 1 0 2, one 〇C (two W) R 1 0,--NR 1 〇C (= (W) R 1 0, -c (= W) NR 1 0-NR 1.2, -C (.W) NRi0- NR10 [C (= W) R10], -〇S 〇2 R i 〇, —〇r 1 0, — n R i 0 2, one SR i 〇, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs—S〇R i 0, — S〇2 R i 〇, phenyl, biphenyl, Piperidinyl, pyrrolyl, morpholinyl, The last nine groups mentioned herein can be optionally substituted by one or more groups selected from: (ci — C 6) alkyl, (C 1 —C 6) haloalkyl, halogen and The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) A8 B8 C8 D8 Patent scope 0R Phenyl, which can be replaced by one or more of the following groups: (Ci — Cs) alkyl (which may optionally be halogen or 10R) and halogen; iso-noisy [I phenyl, pyrazinyl, pyridinyl, sulfanyl, thienyl ---------- Φ_ 丨 (Please read the notes on the back before filling this page) 'It can be substituted by one or more groups selected from the following: halogen, cyano 'Nitro' (Cl — C6) alkenyl '(C2 — C) alkenyl, and phenyl, where the last two groups mentioned can be optionally substituted with halogen; — 〇R 1 0 —NR 1 〇2, -SR 1 〇, -S 〇R 1 (), -S 〇2 R 1 0, -C (---W) R 1 0 ~ C (Ν Ν R 1 0;, 2) R 1 0, —C (two: w) 〇 R 1 to C (W) NR 1 0 2 -NR 1 0 C | (two W) R 1 'NR 1 1] _ -C (two: W) NR 1 〇 2, one C (two W) NR 1 0 — 〇R 1 〇, ~ NR 1 -C (=: W) NR 1 〇2, or -S 〇2 NR R 1 0 2 R 2 and R 3 each Independently has the definition of R 1; each of R4 and R6 each independently has the definition of Ri; R 5, R 7 and R 8 are each independently fluorene or (C 1-C 6) alkyl; this paper size applies Chinese national standards (CNS) Α4 specification (210X297 mm), language. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 508352 A8 B 8 C8 D8 (C alkynyl c application patent scope rule 1. For hydrogen, 〇1 ^ 3, phenylcarbonyl, (Cl — c6) courtyard-S〇2-C 1 2) courtyard '(C 2-C 6 ) j: Hickey, (C 2 — C (C3 — C8) Huan Yuanji '(C3 — C6) Huan Yuanji 1 Ci — C4) Yuan Ji' (C '3 — C6) ^ Yuan Jiyi (C2 — 6) Alkenyl, or (Ci — C6) alkyl — (C3 — C8) ring courtyard, where the last seven rattan groups described can be optionally replaced by the following groups: halogen, cyano, nitro, Hydroxy, (C i -C 6) alkoxy, (C 2 -C 6) alkenyloxy, (C. 2-C 6) alkynyloxy, aminomethylamidino, (Ci — C.6) — Mono- or dialkylaminomethyl fluorenyl, (Cl — c6) alkoxycarbonyl, (Ci — C8) alkoxyl, (Ci — c6) alkylsulfonium (Please read the precautions on the back before filling out this Page) CC 6 alkenylsulfonyl, (ci-C 6 trialkylsilane 〇 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs, phenyl, naphthyl, phenoxy, pyridyl, thienyl, furyl, 〇I —N,, (II ^ 〇Ν > σ '0 and its The ring part of the last eleven groups can be optionally substituted by one or more groups selected from the group consisting of: halogen, (Cl-C 4) halo, (Cl-C4) halo, and (C _1 —C 4) alkoxy; phenyl, naphthyl, oxazolyl, 1, 2, thiazolyl, imidazolyl 4 monothiadiazolyl oxazolyl, iso 3,4 monothiadiazolyl triazolyl, furfuryl, thienyl, benzothiazolyl, transcript paper size applicable to Chinese National Standard (CNS) A4 specification (210 × 297) %) -4- 352 352 A8 B8 C8 D8 6. Scope of patent application The twenty-two groups mentioned at the end may be optionally substituted by one or more groups selected from the following: (Ci-d courtyard, (Ci-C6) v. Courtyard, halogen, via , Nitro, phenylcarbonyl, (Ci-C0-Cyclohydrosulfanyl, (Ci-C6) -halocodyl, cyano (CVC6) -haloalkoxy, phenoxy, (Ci-C6) -Alkoxycarbonyl, (G-CO-alkylamidoamino, aminomethylamido, (CVC6) -mono- or dialkylaminomethylamido, and _s_ (Cl-C6) -alkyl, or In the case of-NR1% groups, two R1. The groups can be combined with the nitrogen atoms (please read the precautions on the back before filling this page) nitrogen atoms: Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The aforementioned groups can be optionally replaced by (Ci-c6) -alkyl. 2 · As in the first patent application, 4 ~ haloalkyl- 3 -heterocyclyl ratio. Steep or 4-dentalyl-5 -heterocyclyl, β-compound, where Υ is halo-C 1 — Ce is radical; X is C Η or N; m is 0 or 1; Q is a 5-membered heterocyclic group This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 A8 B8 C8 D8 6. The scope of patent application where a) X 1: = w, X 2 Ν R a, X 3 = CR b R 1 Or C) X 1: two V, X 2 two CR a R 丄, X 3 two NR b or d) X 1: two V, X 2 two CR 3 R 2, X 3 = CR b R 3 or e) X 1 two two Y, X 2 two c R 4 R 5, X 3 = CR 6 R 7 or f) X 1: two N R a, X 2: = CR b R 1, X 3 two NR 8. R a and R b is a bond in common, V is oxygen or sulfur; W is oxygen; R1 is hydrogen, (Cl — C6) courtyard or (C2 – C6) alkenyl, (Please read the precautions on the back before filling this page) Economy The last two types of groups described by the Ministry of Intellectual Property Bureau employee consumer cooperatives can be optionally substituted by one or more of the following groups: halogen cyano, nitro, hydroxyl, -C ( -W) R -c (two W) 〇R 1 0, one C (= W) NR 1 〇2, one oc (= W) R 1 0, one c (two W) NR1—- NR 1 0 2,-c (— W) NR 1 0-NR 1 0 [C 〇 W) 丨 Ri °) --NR 1 0 〇 5 — SR1 〇, 1 S 〇 2 R 1 〇, piperidinyl, pyrrolyl The last seven groups mentioned here can be one or more randomly selected from the following paper standards. Applicable Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 A8 B8 C8 D8 ___ 6. Scope of patent application (Ci-Ci) alkyl, (Ci-Ce) haloalkyl'halo and -OR10; phenyl, which can be optionally substituted with one or more groups selected from: (C 1 ~ C 6) alkyl (which may optionally be halogen or OR 1 substituted), and halogen; isoxazolyl, pyrazinyl, pyridyl, furyl, thienyl ' or (Please read the note 3 on the back! Please fill in this page] 〇'It can be optionally substituted by one or more groups selected from: _ prime, nitro, (Ci — c6) alkyl and benzene , The last two groups described in the above can be optionally substituted by halogen: NRSR -S 〇R 1 0, -S 0 2 R —C (two w) 〇NRi02 CW) R Intellectual Property Bureau employee consumption Printed by the cooperative-CW) 〇RCW) NR 1 NR 1 0 C (= W) R 1 0, C (two W) NR 1 0 —〇R -NRCW NR or S 0 〇NR 1 R2 is Η, (CVC %) Alkyl group, or (C3-C0 cycloalkyl group, wherein the last two groups can be optionally -S (0) 2- (Ci-C〇 fired basic paper size applicable Chinese national standard 隼 ( CNS> A4 specification (210X297 mm) 508352 A8 B8 C8 __ D8 points, replaced by the scope of patent application; R, 'is Η' C〇2h, -CONH (CVC6) alkyl, -CCMCVCO alkyl,-( : ON [((^-(: 〇alkynyl) 2, _C0nh (C3_C8) ring courtyard, _c0n [(Ci_C6) courtyard]) (C3-C0 cycloalkyl, _c0nh [(Ci- C6) alkoxy- (G-C6) alkyl],-Γ ~ \ —CON 〇CO〇NH [(Cbco alkenyl), -C NH [(C2-C6) alkynyl], V-7 ^ (Ci-C6) alkyl or phenyl, wherein the last two groups are optionally one or more groups selected from Substitute: mesityl, (〇1-(: 6) haloalkoxy, (: 〇211,-(: 〇) ^ [((: 1 < 6) alkyl]), -S- (Please read first (Notes on the back then fill out this page)-. And CH. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, R4, R5 are each hydrogen; R6 '. And Rs are each independently fluorene or (CVC6) alkyl; R is a gas '〇Na' 本 象 基 '(Ci-C6) courtyard-S〇2-' (C1-C12) courtyard, (C2- C6) alkenyl, (C2-C6) alkynyl, or (CkCd cycloalkyl, wherein the last four groups can be optionally substituted with the following groups: halogen 'cyano, (CVC6) alkoxy (CVC6) -mono- or dialkylaminomethylmethyl '(Ci-CeO alkoxycarbonyl, phenyl, phenoxy, thienyl, pyridyl or furanyl, of which the last five groups are The ring moiety can be optionally substituted by halogen or (Ch CeO alkoxy; 0 ^ 0 〇 -.- 〇phenyl, naphthyl, oxazolyl, isoxazolyl, 1,2,4-thiadi Oxazolyl, i, 3, 4-thiadiazolyl, .thiazolyl, imidazolyl, triazolyl, IT.-— This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ~~- 8- 508352 A8 B8 C8 D8 Patent scope Furfuryl, thienyl, benzothiazolyl, furyl, pyridyl,-; CHs Ό: 0 ^ a, 〇 The twenty-two groups mentioned last can be optionally substituted by one or more groups selected from: (Ci-CO-alkyl, (ChCO-alkoxy, halogen, hydroxyl, nitro, Phenylcarbonyl, (Ci-C6) -alkylhydrothio, (ChCO-haloalkyl, cyano (CVC0-haloalkoxy, benzyloxy, (Cl-C6) -j; (Cl-C6) _Instituted amino group, aminomethyl group, (Cl · C6) -Early- or Yiyuan group I female-based methyl group, and-S- (Ci-C6) -Institute group, or In the case of the -NR1 () 2 group, two RU groups can be formed together with the nitrogen atom to which they are attached: —N —N 〇-NN ——N (Please read the notes on the back before filling this page) or -N The printing team of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs can be (Ci-C6) -alkyl To replace. 4 -haloalkyl-3 -heterocyclyl 4-haloalkyl-5 -heterocyclylpyrimidine compounds in the scope of patent application, wherein C i -C6 alkyl is mono- or poly-substituted by chlorine and / or fluorine The aforementioned group 3. If α is determined by β or Υ is m; 0; Q is a 5-membered heterocyclic group 0- \ 2 where X This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ) -9- 508352 A8 B8 C8 ______ D8 6. Scope of patent application b) X2 = CRaR2, x3 = CRbR3 or c) X2 = CR4R5, x3 = cR6r7; (Please read the precautions on the back before filling in this tribute) Rl [ 3Rb is a single bond R1, R2, R3, R4 and R6 are each independently hydrogen, halogen, Ci-C6 alkyl, c3-c8 cycloalkyl, c2-c6 alkenyl, and the last four hydrocarbon groups mentioned therein The group is optionally mono- or poly-substituted by the same or different groups selected from the following A 1 groups: Ci-c6 alkylcarbonyl, Ci—C6 alkylaminocarbonyl, Ci—Ce alkoxy, Cl—C6 alkylthio , Ci-Ce Academy | Lady's, Ci--C6 Academy Mineral-based amino groups, phenyl, halogen, phenoxy 'phenylthio and aniline groups, of which the ten groups mentioned first in the A 1 group Optionally mono- or poly-substituted by the same or different groups selected from the following group B 1: halogen, C i-C 3 alkoxy and phenyl optionally mono- or poly-substituted by one or more halogen atoms And wherein the last three groups mentioned in Group A 1 may optionally be mono- or poly-substituted by the same or different groups selected from the following B 2 groups: halogen, Cl.-C3 alkyl and Ci — Ministry of Economy The Intellectual Property Bureau's Consumer Cooperatives printed the C3 courtyard oxygen 'or (^ — (: ^ alkylcarbonyl, Ci-C6 alkylamino group, Ci--C6 alkoxycarbonyl group, phenyl, pyridyl, furanyl , Thienyl group, oh aryl group, in which the last eight groups are optionally mono- or poly-substituted by the same or different groups selected from the group B 1, or OR ", SR10 or N (R10 ) 2; R5 and R7 are each independently hydrogen, Ci-Cs alkyl, R1Q is hydrogen, benzyl, Ci-Cs alkyl, Ci-C6 cycloalkyl, c2-c6 alkenyl, c2-c6 alkynyl , Phenyl, Ci-Cs alkylcarbonyl 'or C 1-C6 alkyl sulfonium, the last eight groups mentioned therein can be applied to the Chinese National Standard (CNS) A4 regulations on this paper scale Grid (210X297mm) -10- 508352 A8 B8 C8 _ D8 VI. The scope of patent application is optionally single or multiple generations of the same or different halogen atoms. (Please read the notes on the back before filling this page) 4 · For example, in the patent application, item 1 of 4-haloalkyl-3-heterocyclylpyridine or 4-haloalkyl-5-heterocyclylpyrimidine compound, wherein Y is trifluorofluorenyl; R1, R2, R. 3, R4 and R6 are each independently hydrogen, Ci—C6 alkyl ′ C2-c6 alkenyl, wherein the last two groups mentioned are optionally the same or different groups selected from the following A 3 group Mono- or multi-substitution · Cl — C4, several amino groups, Cl—C4, amino-based minerals, Cl—C4, 1-base, Cl—C4, sulfur, Cl—C4, amino ', Cl — 〇4 alkylcarbonyl Amine, Ci-c4 alkylsulfonamido, phenyl, furanyl, pyrrolyl, thienyl, fluorine :, chlorine, bromine, cyano, phenoxy, phenylthio, and aniline, of which group A 3 The eleven groups mentioned in the first can be optionally substituted with the same or different groups selected from the group B1, and the three groups mentioned last in the group A3 The group may optionally be mono- or poly-substituted by the same or different groups selected from the B 2 group, or OR10, SR10 or N (r10) 2; R5 and R7 are each independently Ci—C6 alkyl, Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, R is ammonia 'Cl — C6 academy base, C2 — C6 alkenyl' C2 — C 6 alkynyl, phenyl, Ci — c6 alkylcarbonyl, or (1—C4 alkylsulfonate醯, the last six groups mentioned in the above can be optionally mono- or poly-substituted by the same or different halogen atoms. 5. As in the first patent application, 4-haloalkyl-3-heterocyclylpyridine or 4-haloalkyl-5-heterocyclylpyrimidine compound, wherein R1, R2, R3, R4 and each independently are Hydrogen, Cl — C6 alkane paper standards are applicable to China National Standards (CNS) μ specifications (2 丨 0 > < 297) — -11-508352 A8 B8 C8 D8 ____________ 6. Application for patent scope, C 2-C 6 alkenyl, wherein the last two groups mentioned are optionally mono- or polysubstituted by the same or different groups selected from the group A 5 below: c C 4 alkylcarbonyl, (: C 4 Alkylaminocarbonyl, CC 4 alkoxy Cl — C4 alkylthio, Ci — c4 alkylamino, Ci — C4 alkylcarbonylamino, phenyl, fluorine, chlorine, bromine, phenoxy, phenylthio, and aniline Groups, in which the first seven groups mentioned in the A 5 group can be optionally substituted by the same or different groups selected from the group B 1, and the three groups mentioned last in the A 5 group The group may optionally be mono- or poly-substituted by the same or different groups selected from the B 2 group, and R5 and R7 are each independently a Cl-C6 alkyl group. 6 ·· Preparation as described The method of any one of the compounds of I in the scope of patents 1 to 5, comprising: if A) X 1 = 〇, X 2 = NR a, X 3 = CR b R 1, then the formula (II) Formula of acid activated derivative (Please read the precautions on the back before filling this page) (II) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (where X and Y are defined as those in formula (I)) and react with compounds of the following formula (III): 0% NX H0N R1 (III) (where R1 is defined as The one in the formula (I)) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -12- 508352 A8 B8 C8 ____ D8 VI. The scope of patent application or, if (Please read the note on the back first Please fill in this page again) B) X 1 = S, X2 = NRa, X3 = CRbRi, then make the compound of the following formula (VII) react with the electrophilic aminating agent, Or, if C) Xi = NRa, X ^ CRbR1, x3 = 0, then let the amido oxime of the following formula (V) react with the activated derivative of the acid of the formula (VI) or the acid of the formula (VI) itself , Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs or, if D) X 1-S, X2 CRaRi, X3 = NRb, then in an inert solvent, order N, N '-hydrazine of the following formula (XIII) Reacts with thiolation agents such as Lawesson's reagent (Rewesson, reagent), this paper size applies Chinese National Standard (CNS) A4 specification (21 × 297 mm) 508352 A8 B8 C8 D8 Or, if E) X ^ O, X2 = CRaRi, X3 = NRb, then use an activator such as phosphorus oxychloride or phosphorus pentachloride to make the acid of formula (II) and the hydrazine of formula (X) (where R 1 is defined as in formula (I)). (Please read the precautions on the back before filling out this page.) -1¾. Η 〇 R1 το} IN (X \ R The Intellectual Property Bureau of the Ministry of Economic Affairs ’employee consumer cooperatives printed or ordered the acid hydrazine of formula (XI) and the orthoester of formula (X Ί I) (where R 1 is defined as in formula (I) and R 1 2 For (C! —C4) alkyl) reaction, This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 508352 A8 B8 C8 D8 6. The scope of patent application or, if (please read the precautions on the back before filling this page) F) X2 = CRaR2, X3 = CRbR3 and Ra, Rb and R3 are defined as in formula (I), then the compound of formula (XIV) is made to react with a dehydrating agent (such as inorganic fluorenyl chloride, inorganic acids and anhydrides), Or, if G) X1-S, X2 = CRaR2, X3 = CRbR3, then let thioamidine of the following formula (XVII) and a carbonyl derivative of the following formula (XVIII) (wherein Z is a halogen, especially chlorine or Bromine, fluorenyl or sulfonyloxy, especially methanesulfonyl or tosylsulfonyl), (XVII) (XVIII) (I) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy or, if Η) X 1-S, X2 = CR4R5, X3 = CR6R7, then let the thioxamine of formula (XVII) be Compounds of formula (XIX) (where the dimensions of this paper are applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) -15- 508352 A8 B8 C8 D8, the scope of patent claims for two substituents Z is defined as formula (XVIII) Which can be the same or different reactions, YS 'NH, R: (XIX) hr R7 z R4 Re (l) (xvii) or, if I) X 1-NR aj X 2 = CR b R 1 R b 'R 1 and R 8 are defined as in formula (I), then the hydrazine of formula (XX) is ordered X , Nht ^ NH (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, isr (XX) and compounds of the following formula (XXI) or thiol of the following formula (XXII) Amine reaction R: ΗΝΓ, 'R1 H2N r (XXI) (XXII). 7. A composition having a killing effect on insects and insects, which comprises at least one compound as described in any one of claims 1 to 5. 8 · If the insecticidal composition of item 7 in the scope of the patent application is applied to this paper, the Chinese National Standard (CNS) A4 specification (21 × 297 cm) is applicable to _16_ 508352 A8 B8 C8 D8 ^ It is in the form of a mixture with a carrier and / or a surfactant. 9. If the compound in any one of the items 1 to 5 of the scope of patent application, its ---------% II (Please read the precautions on the back before filling this page) is used as a veterinary medicine. 10 · The composition according to item 7 of the scope of patent application, which is used as a veterinary medicine. 1 1. A method for controlling harmful insects, comprising applying an effective amount of a compound according to any one of claims 1 to 5 to a region to be affected. 12. A method for controlling harmful insects, comprising applying an effective amount of a composition such as item 7 in the patent application scope to a desired area. 13. A method of protecting a useful plant against harmful effects of harmful insects, comprising treating the seed of the useful plant with at least one compound as claimed in any one of claims 1 to 5. 14. The compound according to any one of claims 1 to 5 of the scope of patent application, which is used for controlling harmful insects. 15. The composition according to item 7 of the scope of patent application, which is used for controlling harmful insects. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is sized to the Chinese National Standard (CNS) A4 (210X297 mm) M 7,