TW508216B

TW508216B - Herbicide/safener combinations

Info

Publication number: TW508216B
Application number: TW88120184A
Authority: TW
Inventors: Frank Ziemer; Lothar Willms; Hermann Bieringer; Erwin Hacker
Original assignee: Hoechst Schering Agrevo Gmbh
Priority date: 1998-11-21
Filing date: 1999-11-18
Publication date: 2002-11-01

Abstract

There are described herbicidal compositions which comprise at least one herbicidally active compound of the formula (I) and at least one crop-plant-protecting compound as safener. In this formula (I), V is an optionally substituted radical selected from the group consisting of isoxazol-4-yl, pyrazol-4-yl, cyclohexane-1,3-dion-2-yl and 3-oxopropionitril-2-yl and R9 is nitro, amino, halogen or a carbon-containing radical. The group of the safeners contains, for example, 2,4-D, cyometrinil, dicamba, dymron, fenclorim, flurazole, fluxofenim, lactidichlor, MCPA, mecoprop, MG-191, oxabetrinil, methyl diphenylmethoxyacetate, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea, 1,8-naphthalaic anhydride, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea, 1-[4-(N-4,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea, 1-[4-(N-naphthoylsulfamoyl)phenyl]-3,3-dimethylurea, (4-chlorophenoxy)acetic acid, 4-(2,4-dichlorophenoxy)butyric acid, 4-(4-chloro-o-tolyloxy)butyric acid, 4-(4-chlorophenoxy)butyric acid, in each case their acids and esters, N-acylsulfonamides, N-acylsulfamoylbenzamides, in each case, if appropriate, also in salt form and in each case optionally substituted 1-phenylpyrazoline, 1-phenylpyrazole, 1-phenyltriazole, 5-phenylisoxazoline and 5-phenylmethylisoxazoline-3-carboxylic esters and 2-(8-quinolinyloxy)acetic acid derivatives.

Description

經濟部智慧財產局員工消費合作社印製 508216 A7 - _B7 五、發明說明（1 ) 本發明係關於莊稼保護產物的工藝範圍，特別是於有用的莊稼植物中顯著地合適用來與有害植物競爭之除草劑 /解毒劑組合物（除草劑/安全劑組合物）。最近某些抑制對一羥苯丙酮酸二氧化鎗（Η P P D 0 )的具除草性化物質具有非常好的使用性質，同時可對廣泛的單子葉及雙子葉雜草系列以非常低的比例施加（參見，例如，Μ·Ρ. Pdsbylla等人，Brighton莊稼保護會議-雜草 ( 1 9 9 3 )，731 - 738) ° US P 5627131、EP 551650 及 EP 298680揭示特定的除草劑與安全劑之混合物，特別是幼苗出土前的的安全劑。從不同的公告中進一步熟知爲對-羥苯丙酮酸二氧化鑰抑制劑的苯甲醯環己二酮系列之除草劑乃基於如苯甲醯惡唑彼等系列之相同機構作用，於此文中對照，J. Pesticide Sci. 21，473-478 (1996)，雜草科學45，601 - 609 (1997)，殺蟲劑科學 50，83-84 (1997)及殺蟲劑展望，29 — 32 (19 9 6年十二月）。再者，從殺蟲劑科學50， 83 — 84 (199 7)中熟知化學式（A)的苯甲醯惡唑可，於某些條件下，經歷再排列以獲得化學式（B )的苯甲醯一3—氧丙腈。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -4 · — It — — —^1 — — — — — — ·1111111 tllllllla^ <請先閲讀背面之注意事項寫本頁) 508216 A7 B7 五、發明說明（2 )Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7-_B7 V. Description of the Invention (1) The present invention relates to the technological scope of crop protection products, especially in useful crop plants that are significantly suitable for competition with harmful plants Herbicide / antidote composition (herbicide / safener composition). Recently, some herbicidal substances that inhibit p-hydroxyphenylpyruvate dioxide gun (ΗPDD 0) have very good use properties, and can be applied to a wide range of monocotyledonous and dicotyledonous weeds at very low proportions. (See, for example, MP. Pdsbylla et al., Brighton Crop Protection Conference-Weeds (199 3), 731-738) ° US P 5627131, EP 551650 and EP 298680 disclose specific herbicides and safeners Mixtures, especially safeners before the emergence of seedlings. Herbicides of the benzamidine cyclohexanedione series that are further known as p-hydroxyphenylpyruvate dioxidant inhibitors from different announcements are based on the same mechanism of action as the benzamidine oxazole series Control, J. Pesticide Sci. 21, 473-478 (1996), Weed Science 45, 601-609 (1997), Pesticide Science 50, 83-84 (1997) and Pesticide Outlook, 29-32 ( 19 9 December 6). Furthermore, the benzamidine oxazole of chemical formula (A) is well known from Insecticide Science 50, 83-84 (199 7). Under certain conditions, it undergoes rearrangement to obtain the benzamidine of chemical formula (B). One 3-oxypropionitrile. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -4 · — It — — — ^ 1 — — — — — 1111111 tllllllla ^ < Please read the notes on the back first to write this Page) 508216 A7 B7 V. Description of the invention (2)

但是，許多具有高效活性的物質無法完全的（即不具足夠的選擇性）與某些重要的莊稼植物相容諸如玉蜀黍、米或穀類，所以嚴格地限制其使用。於某些有用的莊稼植物中，因它們僅可以此低比例使用所以並不保証具對雜草之廣泛的除草劑活性的需求，或非全部。特別地，大量上述提及的除草劑無法完全選擇地對玉蜀黍、米、穀類或某些其它莊稼中的有害植物使用。爲了克服這些缺點已熟知利用具除草性活性物質與所謂的安全劑或解毒劑組合。安全劑爲，對於本發明之目的，一種可補償，或減低，除草劑對有用植物的毒害植物性賢而沒有實質上減少除草劑對有害植物的作用之化合物或化合物之混合物。要發現用於特別類別之除草劑的安全劑爲一困難的工作因爲事實上安全劑減低除草劑的有害作用之機構並不熟知。與特別的除草劑組合之化合物的事實作用爲安全劑因此無疑地允許此化合物將亦顯示與其它類別的除草劑作用的安全劑。因此，當使用安全劑來保護有用的植物不受除草劑影響時，已暴露出許多安全劑仍然存在某些缺點。這些包括：本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -5 - (請先閱讀背面之注意事 h -------訂---------線L 本頁) 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（3 ) • 安全劑減低除草劑對有害植物的作用， • 保護有用植物的性質不足， • 與提供的除草劑組合中，可應用安全劑/除草劑的有 .用植物系列不夠廣泛， • 提供的安全劑不可能總是結合與足夠大量的除草劑。本發明之目標爲發現與上述提及的除草劑組合而可合適的增加這些除草劑對重要莊稼植物的選擇性之化合物。驚人地，現在已發現一種化合物族群，其可與特定作爲Η P P D 0抑制劑的除草劑一起增加這些除草劑對重要莊稼植物的選擇性。本發明因此係關於一種具除草性活性的組合物’其包含的混合物有 A · —種或多種化學式（I )之化合物的具除草性活性量請先閱讀背面之注意However, many highly active substances cannot be completely (ie, not sufficiently selective) compatible with certain important crop plants such as maize, rice, or cereals, so their use is strictly limited. In some useful crop plants, because they can only be used in this low proportion, there is no guarantee that the weeds will have extensive herbicide activity, or not all. In particular, a large number of the herbicides mentioned above cannot be fully selectively applied to harmful plants in maize, rice, cereals or some other crops. In order to overcome these disadvantages it is well known to use herbicidally active substances in combination with so-called safeners or antidotes. A safener is, for the purposes of the present invention, a compound or mixture of compounds that can compensate, or reduce, the phytotoxicity of a herbicide to a useful plant without substantially reducing the effect of the herbicide on a harmful plant. Finding safeners for particular classes of herbicides is a difficult task because the fact that safeners reduce the harmful effects of herbicides is not well known. The fact that the compound in combination with a particular herbicide acts as a safener therefore undoubtedly allows this compound to also show a safener that works with other classes of herbicides. Therefore, when using safeners to protect useful plants from herbicides, it has been exposed that many safeners still have certain disadvantages. These include: This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -5-(Please read the note on the back h ------- Order -------- -Line L on this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 B7 V. Description of the invention (3) • Safeners reduce the effect of herbicides on harmful plants, • Insufficient protection of useful plants, and Among the herbicide combinations, safeners / herbicides can be applied. The range of plants used is not extensive, and the safeners provided cannot always be combined with a sufficient amount of herbicide. The object of the present invention is to find compounds which, in combination with the herbicides mentioned above, can suitably increase the selectivity of these herbicides to important crop plants. Surprisingly, a family of compounds has now been discovered that can increase the selectivity of these herbicides for important crop plants, together with herbicides specifically as pupae P P D 0 inhibitors. The present invention therefore relates to a composition having herbicidal activity 'which contains a mixture of A ·-one or more compounds of formula (I) with herbicidal activity. Please read the note on the back

Η 頁 I I 訂 ▲ 〇Η Page I I Order ▲ 〇

\—/ ίν 經濟部智慧財產局員工消費合作社印製 V Γν 自選爲 V 其團基的 4 V /(\ 至\ — / Ίν Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V Γν 4 V / (\ to

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -6 -This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -6-

(V3 508216 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（4 ) 其中的符號及標誌具有下列意義： R 爲氫、（ Cl — C4) —院氧基幾基、（Cl — C4) 一鹵院氧基擬基、（Cl 一 C4) —院基磺醯基、（Cl· 一 C4) 一院基亞擴基、（Cl— C4) 一院硫基、 COOH、氰基，較佳地氫、（Ci—Ca) —烷氧基振基， R1爲氫、（Ci — Cd) —烷基、（C2 - C4) 一烯烴基、（C2— C4) - 炔基、（C3 - C8) - 環烷基、（ c3— C8) -環烯烴基、（Ci— C4) 一烷基一（ c3— c8) —環烷基、（c3 - C7) -鹵環烷基、（ Cl — C4)—院硫基—（C3 - C8) -環院基、（ Cl— C8)—鹵院基或（C2 - C8) —鹵燒煙基’較佳地（C3 - C7) —環烷基、（Ci—Cd) —烷基一 (c3— c7) -環烷基； R2爲氫、（CX — C4) —烷基、（Ci— C4) 一烷氧基、(C 1 C 4 )—鹵院基、鹵素、（Cl 一 C4)—鹵烷氧基、氰基、硝基、較佳地氫； R3爲氫、（Ci — Cd)—烷基、（c2 - C4) 一烯烴基、（C2 - C4) 一快基、（Cl 一 C4)—齒院基、（ Ci— C4) 一烷氧基一（Ci— C4) —烷基、（Ci 一 C4) 一烷基羰基、（Ci—CO -烷基磺醯基' (Cl 一 C4)—鹵院基礦酸基、（Cl— C4) 一院基一經取代或未經取代的芳香基磺醯基、（c i 一 C 4 ) -烷基-經取代或未經取代的芳香基羰基-（C i - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） -ϋ i_i n Mmmt ma§ 1^dJ an ϋ 1 ϋ 1 ·_1 ϋ I - (請先閱讀背面之注意事項再¾寫本頁) 508216 A7(V3 508216 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (4) The symbols and signs have the following meanings: R is hydrogen, (Cl — C4) — oxoyl, (Cl — C4) monohalo-oxymethylene radical, (Cl-C4) —honosulfonyl, (Cl · -C4) one-base sub-anionization, (Cl—C4) one-base sulfur, COOH, cyano, Preferably, hydrogen, (Ci-Ca) -alkoxy group, R1 is hydrogen, (Ci-Cd) -alkyl group, (C2-C4) -alkene group, (C2-C4) -alkynyl group, (C3 -C8)-cycloalkyl, (c3-C8)-cycloalkene, (Ci-C4)-alkyl-(c3-c8)-cycloalkyl, (c3-C7)-halocycloalkyl, (Cl — C4) —Sulfuryl— (C3-C8) —Cyclocycline, (Cl—C8) —Haloxine or (C2—C8) —Haloxanyl 'preferably (C3-C7) —Cycloalkane Group, (Ci-Cd) -alkyl- (c3-c7) -cycloalkyl; R2 is hydrogen, (CX-C4) -alkyl, (Ci-C4) -alkoxy, (C 1 C 4) —Halogeno, halogen, (Cl—C4) —haloalkoxy, cyano, nitro, preferably hydrogen; R3 is hydrogen, (C i — Cd) —alkyl, (c2-C4)-alkene, (C2-C4)-fast group, (Cl-C4)-dental compound, (Ci-C4)-alkoxy-(Ci-C4 ) —Alkyl, (Ci-C4) -Alkylcarbonyl, (Ci-CO-Alkylsulfonyl '(Cl-C4) -halophenyl mineral acid group, (Cl- C4) Unsubstituted aromatic sulfonyl, (ci-C 4) -alkyl- substituted or unsubstituted aromatic carbonyl- (C i-This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 public love) -ϋ i_i n Mmmt ma§ 1 ^ dJ an ϋ 1 ϋ 1 · _1 ϋ I-(Please read the notes on the back before writing this page) 508216 A7

c4) 一垸基或（Ci—Cd) -烷基一經取代或未經取代的芳香基一（Ci—C4) 一烷基，較佳地氫、（五、發明說明（5 ) C1 一 C4) 一院基、（C1 一 C4) 一烷基一經取代的芳香基磺醯基、（Cl 一 C4) 一烷基一芳香基擬基甲基、苄基； R 爲氣、（Cl 一 C4) 一院基、（C2— C4) —嫌烴基、（c2 — C4) —炔基、（Ci— c4) 一鹵烷基、苯基或；基，較佳地（Cl 一 C4) 一院基； R5 爲（Cl— C4) 一院基、（Cl —C4) —院氧基、（ Cl— C4) 一烷氧基—（Cl 一 C4) 一烷基、（Cl —C4) —二烷氧基—（Ci—C4) 一烷基、（Cl 一 C 4 ) -烷硫基、鹵素、經取代或未經取代的芳香基、四氫吡喃一 4 —基、四氫吡喃一3 —基、四氫硫基吡喃一 3 —基、1 一甲基硫環丙基、2 —乙基硫丙基或二個R5基團一起爲（C2 - C4) 一伸烷基，較佳地 (C 1 — C 4 )—院基、（Cl— C4) 一院氧基或一·個 R 5基團爲C 2 -烯烴基； (請先閱讀背面之注意事項再 I. I 本頁) 訂---------線經濟部智慧財產局員工消費合作社印製c4) monomethyl or (Ci-Cd) -alkyl-substituted or unsubstituted aromatic- (Ci-C4) -alkyl, preferably hydrogen, (v. description of the invention (5) C1-C4) A radical, (C1-C4)-alkyl-substituted aromatic sulfosulfanyl, (Cl-C4)-alkyl-arylsulfonylmethyl, benzyl; R is gas, (Cl-C4)- Academic base, (C2—C4) —hydrocarbyl, (c2—C4) —alkynyl, (Ci—c4) monohaloalkyl, phenyl or alkynyl, preferably (Cl—C4) —radical; R5 It is (Cl—C4) —a radical, (Cl—C4) —a radical, (Cl—C4) —alkoxy— (Cl—C4) —alkyl, (Cl—C4) —dialkoxy— (Ci-C4) -alkyl, (Cl-C4) -alkylthio, halogen, substituted or unsubstituted aromatic group, tetrahydropyran 4-yl, tetrahydropyran 3-yl, Tetrahydrothiopyran- 3-yl, 1-methylthiocyclopropyl, 2-ethylthiopropyl or two R5 groups together are (C2-C4) unialkylene, preferably (C 1 — C 4) —yuan, (Cl—C4) one oxygen or one R 5 group is C 2 -olefin (Please read the notes on the back before I. I on this page) Order --------- Line Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

C /(V 基羥爲 6 RC / (V-based hydroxyl 6 R

C C χίν * 基氧烷C C χίν * alkane

8 C 鹵 C Γν 、基氧醯甲基氧烷8 C halide C Γν, alkoxymethylmethoxane

CC

基基氧硫醯烷磺鹵基 I 院} I 4 COxo, sulfoxane, sulfanyl, sulfohalo, I, I}

或基广、磺C1基亞{烷基、一院基4) -經C4 4)地 I Ρ二 C佳1 I 較 C ， Γν IX C 基爲 7 R (C 準標家國國中用適度尺張紙本Or base, sulfo C1, alkylene, alkyl group, 4)-via C4, 4), I, P, C, 1, I is better than C, Γν IX, C is 7 R (C quasi-standard, moderate, moderate Sheet of paper

CC

芳 C 基氧羰基烷基硫 C 烷、 -基 >氧 4 C芳 - f 1基 C 硫Aryl C oxycarbonyl alkyl thio C alkane, -yl > oxygen 4 C aryl-f 1 yl C sulfur

C 基烷 4 C C (C alkane 4 C C (

基-氧4) 烷C 硫苯醯·’ 磺基基烷鹵釐公 97 2 X 10 2 /IV 格規 8 508216 A7 B7_ 五、發明說明（6 ) (請先閱讀背面之注意事項再本頁) C3 - C8)—環院基、（Cl_C4)—院基—（C3 一 c8)—環烷基或（c3 - c8) -鹵環烷基，較佳地（c3 - C7) —環烷基； R8爲氰基、（Cl— C4) —院氧基鑛基、（Cl— C4) —烷基羰基、（Ci— C4)—烷基磺醯基、（Ci — C4) 一院基亞礦基、（Cl—C4)—院硫基、（Cl 一 C4) 一烷基胺基羰基或（Ci—Ci) 一二烷基胺基羰基，較佳地氰基； I 爲從0至6之整數，較佳地0至3，其中，若1>2 ，基團R5可彼此相同或不同，及 R9爲相同或不同的硝基、胺基、（Ci-Ca) —烷基、 (C2— C4) —燃煙基、（C2 - C4)—快基、鹵素、（Cl 一 C4 )—鹵垸基、（C2— C4)—鹵嫌煙基、（C2— C4)—鹵快基、（Cl— C4)—鹵院氧基、(C 1 — C 4 )—鹵院硫基、（Cl_C4)—院氧基鑛基、（Cl 一 C4)—院基磺酿基、（Cl— C4) 一烷基亞磺基、（Ci-C 4) 一烷硫基、芳香基磺醯基、芳香基亞磺基、芳硫基、（Ci 一 C4) 一烷氧基、經濟部智慧財產局員工消費合作社印製 (C 1 — C 4 )—院氧基—（Cl— C4) 一院氧基、（ C 1 — C 4 )—院硫基_ (Cl 一 C4)—院氧基、（ C 1 - C 4 )—烷基羰基、（Ci — Cd -烷基胺基磺酿基、（Cl—C4) — 一《院基胺基礦酿基、（Cl 一 c4) 一烷基胺甲醯基、（CX—C4)—二烷基胺甲醯基、（Cl 一 C4) 一院氧基—（Cl— C4)—院基 -9- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508216 A7 B7 五、發明說明（7 ) 、苯氧基、氰基、芳香基、烷基胺基或二烷基胺基，較佳地（Ci—Ci) 一烷基、鹵素、硝基、（Ci — c4) 一鹵烷基、（Ci— C4) 一鹵烷氧基、（Ci—· c4) 一烷基磺醯基、（Ci—Cd) -烷基磺醯氧基、（Ci — Cd) -烷基磺醯基胺基、（Ci — Cd) — 烷氧基羰基； q 爲〇、1、2、3或4，較佳地0、1、2或3 ; 及 B .· —種或多種安全劑有效解毒劑量，其選自： a )化學式（I I )至（I V )之化合物， (請先閱讀背面之注意事項再本頁)Radical-oxygen 4) Alkane C thiophenylhydrazone · 'sulfoalkane halide 97 2 X 10 2 / IV Gage 8 508216 A7 B7_ V. Description of the invention (6) (Please read the precautions on the back before this page ) C3-C8) —Cyclosyl, (Cl_C4) —Cyclos— (C3—c8) —Cycloalkyl or (c3-c8) —Halocycloalkyl, preferably (c3-C7) —Cycloalkyl ; R8 is cyano, (Cl—C4) —Hydroxyl group, (Cl—C4) —Alkylcarbonyl group, (Ci—C4) —Alkylsulfonyl group, (Ci—C4) (Cl—C4) —Culthio, (Cl—C4) —alkylaminocarbonyl, or (Ci—Ci) —dialkylaminocarbonyl, preferably cyano; I is from 0 to 6 An integer, preferably 0 to 3, wherein if 1 > 2, the groups R5 may be the same or different from each other, and R9 is the same or different nitro, amine, (Ci-Ca) -alkyl, (C2- C4) —flammable base, (C2-C4) —fast radical, halogen, (Cl—C4) —halofluorenyl, (C2—C4) —halo smokey radical, (C2—C4) —halo fast radical, (Cl — C4) —Haloxyloxy, (C 1 — C 4) —Haloxyl sulfur, (Cl_C4) —Holoxyl, (Cl—C4) — Sulchi sulfo group, (Cl—C4) monoalkylsulfinyl group, (Ci-C 4) monoalkylthio group, aromatic sulfonyl group, aromatic sulfinyl group, arylthio group, (Ci-C4) Monoalkoxy, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (C 1 — C 4) —Institute Oxygen— (Cl— C4) One Institue Oxygen, (C 1 — C 4) —Institute Thio_ ( Cl—C4) —sinoxy group, (C1-C4) —alkylcarbonyl group, (Ci—Cd—alkylaminosulfonyl group, (Cl—C4) —a “sinylamino group, (Cl-c4) Monoalkylaminomethane, (CX-C4) -dialkylamine formamyl, (Cl-C4) Single-oxyl- (Cl-C4) -Yinji-9- This paper The standard is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 508216 A7 B7 V. Description of the invention (7), phenoxy, cyano, aromatic, alkylamino or dialkylamine, compared with (Ci—Ci) monoalkyl, halogen, nitro, (Ci — c4) monohaloalkyl, (Ci—C4) monohaloalkoxy, (Ci— · c4) monoalkylsulfonyl, (Ci-Cd) -alkylsulfonyloxy, (Ci-Cd) -alkylsulfonylamino, (Ci-Cd) Alkoxycarbonyl; q is 0, 1, 2, 3 or 4, preferably 0, 1, 2 or 3; and B... One or more safe detoxifying doses selected from: a) the chemical formula ( II) to (IV) compounds, (Please read the precautions on the back before this page)

(Ri7)n'~O.J Λ R18(Ri7) n '~ O.J Λ R18

(R19), (I") η. A， R23 (iv) 經濟部智慧財產局員工消費合作社印製 (Π) 其中符號及標誌具有下列意義： η’爲一從0至5的自然數，較佳地0至3; Τ 爲未經取代或由一個或二個（Ci— C4) 一烷基基團或由〔（Ci—Cs) —烷氧基〕羰基取代的 C 2 ) -二烷烴基鏈； W 爲一未經取代或經取代的二價雜環基團，其選自具有 1至3個N或0型式的雜環原子之部分未飽合或芳香族五圓環的雜環之基群，其中之環包含至少一個N原子及不多於一個的0原子，較佳的基團選自（W1 ) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -10- 508216 A7 B7 五、發明說明（8 ) 至（W 4 )(R19), (I ") η. A, R23 (iv) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (Π) where symbols and signs have the following meanings: η 'is a natural number from 0 to 5, Preferably 0 to 3; T is unsubstituted or C 2) -dialkane substituted by one or two (Ci-C4) -alkyl groups or [(Ci-Cs) -alkoxy] carbonyl groups Chain; W is an unsubstituted or substituted divalent heterocyclic group selected from partially unsaturated or aromatic five-ring heterocycles having 1 to 3 heterocyclic atoms of the N or 0 type Groups, in which the ring contains at least one N atom and no more than one 0 atom. The preferred group is selected from (W1). The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)- 10- 508216 A7 B7 V. Description of the invention (8) to (W 4)

(W1) (W2)(W1) (W2)

m Rm R

R 經濟部智慧財產局員工消 f 合作社印製R Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs

RR

R 爲0或1，「，R19 爲相同或不同的鹵素、（Ci 一 C4) 一烷基、（Cl 一 C4) 一院氧基、硝基或（Cl— C4) 一鹵院基； ^ R 2 0 爲相同或不同的〇R24、SR24或NR24 R25或飽合或未飽合的3 -至7 -圓環的雜環，其具有至少一個N原子及上至3個雜原子，較佳地選自〇及S，其於（I I )或（I I I )處經由n原子連結至羰基同時爲未經取代或由選自（Ci 一 C4) 一烷基、（Ci— C4) 一烷氧基的基團或視需要經取代的苯基而取代，較佳地爲化學式〇r24、NHR25或N ( C Η 3 ) 2基團，特別是化學式〇R 2 4 ; 4 爲氫或未經取代或經取代的脂肪族烴基團，較佳地具有總C原子爲1至1 8個； 5 爲氫、（Ci — Cs) - 烷基、（Ci — c6) 一院氧基或經取代或未經取代的苯基； 6 爲氫、（Cl — C8) —垸基、（Cl — c8) — 鹵烷基、（Cl — c4) —烷氧基一（Ci — c4)—烷 (請先閱讀背面之注意事項再¾寫本頁) 太訂----------線‘ -11 508216 A7 B7 五、發明說明（9 ) 基、（Cl 一 c6) -羥烷基、（c3— c12) - 環烷基或三_ (Ci — Cd) -烷基矽基； P 2 7 〇 2 8 ϋ 2 9 R ，R R 爲相同或不同的氫、（Ci—Cs· )一院基、（Ci—Cd — 鹵烷基、（c3— c12) -環烷基或經取代或未經取代的苯基； R 爲（Ci— C4) 一院基、（Ci—C4)—齒院基、（c2 - C4) 一烯烴基、（c2 — c4) 一鹵烯烴基、（C3— c7) 一環烷基，較佳地二氯甲基； R22，R23爲相同或不同的氫、（Ci — CO —烷基、 (C2 - C4) 一烯烴基、（C2 - C4) 一炔基、（R is 0 or 1, ", R19 is the same or different halogen, (Ci-C4)-alkyl, (Cl-C4)-oxygen, nitro or (Cl-C4)-halogen; 2 0 is the same or different OR24, SR24 or NR24 R25 or a saturated or unsaturated 3-to 7-ring heterocyclic ring having at least one N atom and up to 3 heteroatoms, preferably Is selected from 0 and S, which is connected to the carbonyl group through the n atom at (II) or (III) and is unsubstituted or selected from (Ci-C4) -alkyl, (Ci-C4) -alkoxy The group is optionally substituted with a substituted phenyl group, preferably a group of chemical formula 〇r24, NHR25, or N (CΗ3) 2, especially a formula of 〇2 2; 4 is hydrogen or unsubstituted or Substituted aliphatic hydrocarbon groups, preferably having 1 to 18 total C atoms; 5 is hydrogen, (Ci — Cs)-alkyl, (Ci — c6) monooxyl or substituted or unsubstituted 6 is hydrogen, (Cl — C8) —fluorenyl, (Cl — c8) —haloalkyl, (Cl — c4) —alkoxy- (Ci — c4) —alkane (please read the (Notes ¾ write this page) too ordered --- ------- line '-11 508216 A7 B7 V. Description of the invention (9) group, (Cl-c6) -hydroxyalkyl, (c3-c12) -cycloalkyl or tri- (Ci — Cd) -Alkylsilyl; P 2 7 〇 2 8 ϋ 2 9 R, RR is the same or different hydrogen, (Ci—Cs ·) one group, (Ci—Cd — haloalkyl, (c3 — c12)- Cycloalkyl or substituted or unsubstituted phenyl; R is (Ci—C4) —academic group, (Ci—C4) —academic group, (c2-C4) —olefin group, (c2—c4) — Halo alkenyl, (C3-c7) monocycloalkyl, preferably dichloromethyl; R22, R23 are the same or different hydrogens, (Ci — CO —alkyl, (C2-C4) monoalkenyl, (C2 -C4) an alkynyl, (

Cl 一 C4) —鹵院基、（C2— C4) —鹵嫌烴基、（ Cl 一 C4) 一烷基胺甲醯基—（Cl — C4) 一烷基、 (C2 — C4)—烯烴基胺甲醯基一（Cl — c4)—烷基、（Ci— C4)—烷氧基—（Ci—CO -烷基、二茂院基（Cl — C4) 一院基、噻哇基、咲喃基、咲喃基院基、噻吩基、_ η定基、經取代或未經取代的苯基、或R 2 2及R 2 3 —起形成一種經取代或未經取代的雜環，較佳地一種惡唑烷、噻唑烷、哌啶、嗎福啉、六氫嘧啶或苯肼惡嗪環； b ) —種或多種化合物基團，其組成爲： 1 ，8 —萘二甲酸酐，二苯基甲氧基醋酸甲酯，氰基甲氧基亞胺基（苯基）乙腈（cyometrinil)， 1，3 —二茂烷一 2 -基甲氧基亞胺基（苯基）乙腈本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） · 12 - (請先閱讀背面之注意事項再 i. 本頁)Cl-C4) —haloalkyl, (C2-C4) —halohydrocarbyl, (Cl-C4) -alkylaminomethyl— (Cl—C4) -alkyl, (C2—C4) —alkenylamine Formamyl- (Cl-c4) -alkyl, (Ci-C4) -alkoxy- (Ci-CO-alkyl, di-methylene radical (Cl-C4) one-radical, thiayl, sulfanyl Group, sulfanyl group, thienyl group, _η phenyl group, substituted or unsubstituted phenyl group, or R 2 2 and R 2 3 together form a substituted or unsubstituted heterocyclic ring, preferably An oxazolidine, thiazolidine, piperidine, morpholine, hexahydropyrimidine or phenylhydrazine ring; b)-one or more compound groups, the composition of which is: 1, 8-naphthalenedicarboxylic anhydride, dibenzene Methyl methoxymethyl acetate, cyanomethoxyimino (phenyl) acetonitrile (cyometrinil), 1,3-dichloromethylene-2-ylmethoxyimino (phenyl) acetonitrile Paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm) · 12-(Please read the precautions on the back before i. This page)

-------訂---------線L 經濟部智慧財產局員工消費合作社印製經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（1〇) (oxabetrinil)， 4，一氯一 2，2，2 —三氟乙醯苯〇—丄，3 —二茂院一2 —基甲基月亏（fluxofenim)， 4 ’ Θ- 一氯一 2 - 本基囉陡（fenci〇rim)， 2 —氯一 4 一三氟甲基_1，3—噻唑一 5 —羧酸苄酯（flurazole)， 2 —二氯甲基一2 —甲基一1 ，3 —二茂烷（MG — 19 1)， N —（4 一甲基苯基）一 Ν’ —（1—甲基一 1_苯基乙基）尿素（dymron)， 1—〔4 一（N — 2 —甲氧基苯甲醯氨磺醯基）苯基〕一 3 —甲基尿素， 1—〔4 一（N — 2 —甲氧基苯甲醯氨磺醯基）苯基〕一3，3 —二甲基尿素， 1 一〔4 一（N — 4，5 —二甲基苯甲醯氨磺醯基）苯基〕一3—甲基尿素， 1 一〔4 一（N —奈甲醯基氨磺醯基）苯基〕一 3， 3 —二甲基尿素， (2，4 一二氯苯氧基）醋酸（2，4 — D)， (4一氯苯氧基）醋酸， (R，S) — 2 —（4 —氯一對一甲苯氧基）丙酸（ mecoprop)， 4 — (2，4 一二氯苯氧基）丁酸（2，4 一 DB) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -13 - -imt ·1 ϋ I 1 I I J β I a··· aam I · 言矣k (請先閱讀背面之注意事項再¾寫本頁) :裝太 508216 A7 B7 五、發明說明（11 ) (4一氯一對一甲苯氧基）醋酸（MCPA)， 4 一（4 一氯一對一甲苯氧基）丁酸， 4— (4 一氯苯氧基）丁酸， 3，6 —二氯一 2 —甲氧基安息香酸（麥草畏）， 3，6 —二氯一 2 —甲氧基安息香酸1一（乙氧基羰基）乙酯（lactidichlor) 及其鹽類及酯類，較佳地（Cl— C8); c )化學式（V)之N -醯基磺胺類及其鹽類 (請先閱讀背面之注意事項再本頁) R30 V 〇 <31 R33 0 〇ο - (V) 經濟部智慧財產局員工消費合作社印製 (R32)n 其中 R 3 0爲氫、烴基團、烴氧基團、烴硫基團或較佳地經由碳原子鍵結的雜環基團，4個最後提及的基團中的每一個爲未經取代或由一種或多種選自鹵素、氰基、硝基、胺基、羥基、羧基、甲醯基、羧醯胺、磺胺及化學式Za — Ra基團之相同或不同的基團取代，每個烴部分較佳地具有1至2 0個碳原子及含碳的基團R3()含較佳地具有1至3 0個碳原子的取代物； R 3 1 爲氨或（Ci— C4) 一院基，較佳地氨，或 R3Q及R31 —起與化學式一 C0 — N —基團爲3 一至8-環的飽合或未飽合環的殘餘物；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -14- 508216 A7 ____ B7 五、發明說明（12 ) R 3 2爲相同或不同的鹵素、氰基、硝基、胺基、經基、羧基、甲醯基、CONH2、S〇2NH2或化學式忑6 一 R b之基團； R 3 3爲氫或（Cr— C4)_烷基，較佳地H; R 3 4爲相同或不同的鹵素、氰基、硝基、胺基、經基、羧基、CHO、C0NH2、S〇2NH2或化學式zc 一 R °之基團； R 爲煙基團或雑環基團，最後提及的二個基團中每個爲未經取代或由一種或多種相同或不同選自鹵素、氰基、硝基、胺基、羥基、單及二一〔（Ci—Ce) -院基〕胺基、或烷基團之基團取代，其中多數，較佳地 2或3，非毗連的CH2基團於每個實例中由一個氧原子置換；經濟部智慧財產局員工消費合作社印製 R b , R c爲相同或不同及爲烴類基團或雜環基團，最後提及的二個基團中每個爲未經取代或由一種或多種相冋或不同選自鹵素、氨基、硝基、胺基、經基、單及二一〔（Cl 一 C4) 一院基〕胺基、或烷基團之基團取代，其中多數，較佳地2或3，非毗連的CH2基團於每個實例中由一個氧原子置換；------- Order --------- line L Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by 508216 A7 B7 V. Description of Invention (1) (oxabetrinil), 4, monochloro-2, 2, 2, 2-trifluoroacetophenone 0-fluorene, 3-dioxo-one 2-fluxylimide (fluxofenim), 4 'Θ- monochloro-2- Fenciolim, 2-chloro-4, trifluoromethyl_1,3-thiazole-5, carboxylic acid benzyl ester (flurazole), 2-dichloromethyl-1, 2-methyl-1 , 3 -dioxane (MG-19 1), N-(4-methylphenyl) -N '-(1-methyl-1 -phenylethyl) urea (dymron), 1-[4- (N 2 -methoxybenzylsulfamoyl) phenyl] phenyl 3-methylurea, 1- [4-((N-2-methoxybenzylsulfamoyl) phenyl) phenyl] One 3,3-Dimethylurea, 1 One [4-One (N-4,5-Dimethylbenzylsulfamoyl) phenyl] One 3-methylurea, 1 One [4-One (N —Nylidenesulfamoyl) phenyl] -3,3-dimethylurea, (2,4-dichloro (Oxy) acetic acid (2,4 — D), (4-monochlorophenoxy) acetic acid, (R, S) — 2 — (4-chloroone-toluyloxy) propionic acid (mecoprop), 4 — ( 2,4 dichlorophenoxy) butyric acid (2,4 one DB) The paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -13--imt · 1 ϋ I 1 IIJ β I a ··· aam I · Yan 矣 k (Please read the precautions on the back before writing this page): Packing 508216 A7 B7 V. Description of the invention (11) (4-chloro-toluene-1) acetic acid (MCPA), 4- (4-chloro-l-tolyloxy) butanoic acid, 4- (4-chloro-chlorophenoxy) butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba) ), 3,6-dichloro-2-dimethoxybenzoic acid 1- (ethoxycarbonyl) ethyl (lactidichlor) and its salts and esters, preferably (Cl-C8); c) chemical formula ( (V) N-fluorenyl sulfonamides and their salts (please read the precautions on the back first and then this page) R30 V 〇 < 31 R33 0 〇ο-(V) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs ( R32) n where R 3 0 is hydrogen, a hydrocarbon group, a hydrocarbon Group, hydrocarbon sulfur group or heterocyclic group preferably bonded via a carbon atom, each of the 4 last-mentioned groups is unsubstituted or is selected from one or more selected from halogen, cyano, Nitro, amine, hydroxyl, carboxyl, methylamidino, carboxamidine, sulfamine, and the same or different groups of the chemical formula Za — Ra are substituted, each hydrocarbon moiety preferably has 1 to 20 carbon atoms And the carbon-containing group R3 () contains a substituent preferably having 1 to 30 carbon atoms; R 3 1 is ammonia or (Ci—C4) a radical, preferably ammonia, or R3Q and R31 — Residues of saturated or unsaturated rings with a C0 — N — group of 3 to 8-rings with the chemical formula one; This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -14- 508216 A7 ____ B7 V. Description of the invention (12) R 3 2 is the same or different halogen, cyano, nitro, amine, mesityl, carboxyl, formamyl, CONH2, S2NH2 or chemical formula 忑 6 -R b group; R 3 3 is hydrogen or (Cr—C4) _alkyl, preferably H; R 3 4 is the same or different halogen, cyano, nitro, amine, meridian, carboxyl, CH O, CONH2, S02NH2 or a group of the formula zc-R °; R is a nicotine group or a fluorene ring group, each of the two last mentioned groups is unsubstituted or one or more of the same or Different substituents selected from the group consisting of halogen, cyano, nitro, amine, hydroxy, mono- and di-[(Ci-Ce) -amino] amino, or alkyl groups, most of which are preferably 3. The non-adjacent CH2 group is replaced by an oxygen atom in each instance; R b is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and R c is the same or different and is a hydrocarbon group or a heterocyclic group. Each of the last two groups mentioned is unsubstituted or is selected from one or more phases or is differently selected from halogen, amino, nitro, amine, meridian, mono and two [(Cl-C4)- [Chenyl] amino group, or alkyl group substitution, most of which, preferably 2 or 3, non-adjacent CH2 group is replaced by an oxygen atom in each instance;

Za爲二價基團，其化學式爲〇、S、CO、CS、C〇一〇、C〇一S 、〇一 C〇、S — C〇、S〇、S〇2 、NR*、 C〇一 NR*、NR*— C〇、S〇2 — N R *或N R * — S 0 2，於每個二價基團右側提供的鍵處鍵結至基團Ra，及於最後提及的5個基團中之基團 -15- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）經濟部智慧財產局員工消費合作社印製 508216 A7 _____B7 五、發明說明（13 ) R *於每個實例中各別地爲Η、（ C i 一 C 4 ) 一烷基或鹵一（C1 — C4) 一院基； z b > z c彼此各別地爲直接鍵結或二價基團，其化學式· 爲〇、s、c〇、cs、c〇一o、c〇一s、〇一 C〇、S — C〇、S〇、S〇2、NR*、 S〇2 — NR*，N R *- S 〇 2 > C〇一NR* 或 NR*—C〇，其中，於不對稱性的二價基團中，於右側的原子連結至基團Rb或及於最後提及的5個基團中的基團 .R *於每個實例中各別地爲Η、（ C : 一 C 4 ) 一烷基或鹵一（Cl— C4) 一焼基； η 從0至4的整數，較佳地爲0、1或2，特別地爲0 或1，及 t 從0至5的整數，較佳地爲0、1、2或3，特別地爲0、1或2 ; d)化學式（V I )的酿基氨磺醯基苯酿胺，視需要亦爲鹽形式，Za is a divalent group, and its chemical formula is 〇, S, CO, CS, CO 〇〇, CO 〇 S, 〇 CO, S — CO, S〇, S〇2, NR *, CO. -NR *, NR * —C〇, S〇2—NR * or NR * —S 0 2 are bonded to the group Ra at the bond provided to the right of each divalent group, and 5 at the last mentioned Groups in each group -15- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 508216 A7 _____B7 V. Description of the invention (13) * In each example, it is fluorene, (C i -C 4) -alkyl or halo (C1-C4) -one radical; zb > zc are each directly bonded or divalent radical Group, whose chemical formula is 0, s, c0, cs, c0o, c0s, 〇C0, S — C0, S0, S02, NR *, S〇2 — NR *, NR *-S 〇2 > C〇-NR * or NR * -C〇, in the asymmetric divalent group, the atom on the right side is connected to the group Rb or mentioned at the end In each of the 5 groups. R * is Η, (C: -C 4) an alkyl or halo (Cl—C4) -fluorenyl group; an integer from 0 to 4, preferably 0, 1 or 2, especially 0 or 1, and an integer from 0 to 5 , Preferably 0, 1, 2 or 3, especially 0, 1 or 2; d) sulfamoylsulfenylbenzylamine of formula (VI), if necessary, also in the form of a salt,

其中 X 3爲C Η或N ; R 3 5 爲氫、雜環基或烴類基團，最後提及的二個基團視需要爲由一種或多種選自鹵素、氰基、硝基、胺基、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公f "Where X 3 is C Η or N; R 3 5 is hydrogen, heterocyclyl or hydrocarbon group, and the last two groups mentioned are optionally selected from one or more kinds selected from halogen, cyano, nitro, amine Base and paper sizes are applicable to China National Standard (CNS) A4 specifications (210 X 297 male f "

508216 經濟部智慧財產局員工消費合作社印製 A7 B7__ 五、發明說明（14) 羥基、羧基、CH〇、C〇NH2、S〇2NH2及 Zd—Rd相同或不同的基團取代； R 3 6 爲氫、羥基、（Ci—Ce) - 烷基、（C2 - C6)· 一烯烴基、（C2 - C6) —炔基、（Ci— C6) —院氧基、（C2 — C6) -烯烴氧基、最後提及的五個基團視需要爲由一種或多種選自鹵素、羥基、（Ci一 c4) 一烷基、（Ci—Cd) — 烷氧基及（Ci— C4 )-烷硫基的相同或不同之基團取代，或 R35及R36與它們附加的氮原子一起爲3 一至8 一圓環的飽合或未飽合的環； R 3 7 爲相同或不同的鹵素、氰基、硝基、胺基、羥基、羧基、CHO、CONH2、3〇21^112或26 — 1^ 9 R 3 8 爲氨、（Cl 一 C4) 一院基、（C2—C4) -嫌煙基或（C2— C4) -快基； R 39爲相同或不同的鹵素、氰基、硝基、胺基、羥基、羧基、磷醯基、CHO、CONH2、S〇2NH2或 Z f - r' f ；508216 Printed by A7 B7__ in the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (14) Substituent for the same or different groups of hydroxyl, carboxyl, CH0, CO〇NH2, S〇2NH2 and Zd-Rd; R 3 6 is Hydrogen, hydroxyl, (Ci-Ce)-alkyl, (C2-C6)-alkene, (C2-C6)-alkynyl, (Ci-C6)-courtyard oxygen, (C2-C6)-olefin oxygen And the last five groups are optionally selected from one or more selected from halogen, hydroxyl, (Ci-c4) -alkyl, (Ci-Cd) -alkoxy and (Ci-C4) -alkylthio The same or different radical substitution of the radical, or R35 and R36 together with the nitrogen atom attached to them are a 3 to 8 ring saturated or unsaturated ring; R 3 7 is the same or different halogen, cyano , Nitro, amine, hydroxyl, carboxyl, CHO, CONH2, 3,021 ^ 112, or 26 — 1 ^ 9 R 3 8 is ammonia, (Cl-C4)-courtyard, (C2-C4)-smoky or (C2—C4)-fast group; R 39 is the same or different halogen, cyano, nitro, amine, hydroxyl, carboxyl, phosphonium, CHO, CONH2, So2NH2 or Z f-r 'f;

Rd爲（〇2—C2Q)—烷基團，其碳鏈由氧原子中斷一次或多次，或爲雜環基或烴類基團，最後提及的二個基團視需要爲由一種或多種選自鹵素、氰基、硝基、胺基、羥基、單及二一〔（Ci-Ca) —烷基〕胺基之相同或不同的基團取代；Rd is (〇2-C2Q) -alkyl group, whose carbon chain is interrupted one or more times by an oxygen atom, or is a heterocyclyl or hydrocarbon group. The last two mentioned groups are optionally composed of one or A plurality of the same or different groups selected from the group consisting of halogen, cyano, nitro, amine, hydroxy, mono and di [(Ci-Ca) -alkyl] amino;

Re，Rf 爲相同或不同及爲（C2 — C2。）一烷基團’ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -17- (請先閱讀背面之注意事項再^本頁)Re, Rf are the same or different and are (C2-C2.) An alkyl group 'This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -17- (Please read the precautions on the back first (^^ this page again)

508216 A7 ___B7 五、發明說明（15 ) 其碳鍵由氧原子中斷一次或多次，或爲雜環基或烴類基團，僉後提及的一個基團視需要爲由一種或多種選自鹵素、氰基、硝基、胺基、羥基、磷醯基、（（：1 一 c4)—鹵院氧基、單及二—〔（Cl-C4) 一烷基〕胺基之相同或不同的基團取代； zd爲選自〇、s、c〇、cs、c(〇）〇、c(〇） S 、 S〇、S〇2、NR*、C (〇）NR 氺或 S〇2 N R *的二價單位；，Zf 爲相同或不同及爲直接鍵結或選自0、S、 C〇、CS、C (〇）〇、c (〇）S、 S〇、S〇2 、NR* 、S〇2NR*或C(〇）NR*的二價單位 (請先閱讀背面之注意事項再本頁) R *爲氫508216 A7 ___B7 V. Description of the invention (15) The carbon bond is interrupted one or more times by an oxygen atom, or is a heterocyclic group or a hydrocarbon group. One of the groups mentioned later is optionally selected from one or more selected from Halogen, cyano, nitro, amine, hydroxy, phosphino, ((: 1-c4) -haloalkyloxy, mono and di-[(Cl-C4) -alkyl] amino groups are the same or different Group substitution; zd is selected from the group consisting of 0, s, co, cs, c (〇) 〇, c (〇) S, S〇, S〇2, NR *, C (〇) NR 氺 or S〇2 NR * divalent unit; Zf is the same or different and is directly bonded or selected from 0, S, C0, CS, C (〇) 〇, c (〇) S, S〇, S〇2, NR *, S〇2NR * or C (〇) NR * bivalent unit (Please read the precautions on the back before this page) R * is hydrogen

CC

C 院基或（Cl — C4)—鹵院基 s 0 爲從0至4的整數，及於X爲CH的事件中，爲從0至5的整數及 N的事件中，爲從〇至4的整數；化學式（V I I )之化合物，於X爲經濟部智慧財產局員工消費合作社印製C Yuanji or (Cl — C4) —Haoyuan s 0 is an integer from 0 to 4, and in the event where X is CH, it is an integer from 0 to 5 and in the event of N, it is from 0 to 4 A compound of formula (VII), printed at X for the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

|E)m" R42 (VII) 其中符號及標誌具有下列意義：. R 4 0 爲 H、（Ci— C4) 一烷基、由（Cl— C4) —烷基—X4或（Ci — C4) 一鹵垸基一 X4取代的 -18- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508216 A7 B7 五、發明說明（16)| E) m " R42 (VII) where the symbols and signs have the following meanings:. R 4 0 is H, (Ci—C4) -alkyl, (Cl—C4) —alkyl—X4, or (Ci — C4) Monohalofluorene-X4 Substituted -18- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 508216 A7 B7 V. Description of the invention (16)

Cl 一 C4) —院基、（Cl 一 C4) 一鹵院基、N〇2Cl-C4) — Yuan, (Cl—C4) —Halogen, No. 2

C NC N

C〇〇一 R 4 3C〇〇一 R 4 3

NR 4 4 S〇2NR245—C〇NR2 4 6 R 4 1 爲 Η、鹵素、（Ci— C4) 一烷基、CF3、（ Ci— C4) 一烷氧基或（Ci — Ca) -鹵烷氧基；NR 4 4 S〇2NR245—C〇NR2 4 6 R 4 1 is pyrene, halogen, (Ci—C4) monoalkyl, CF3, (Ci—C4) monoalkoxy or (Ci — Ca) -haloalkoxy base;

R 爲Η、鹵素或（Ci-Cd) -院基；R is thorium, halogen or (Ci-Cd)-courtyard;

QQ

Q E，G爲相同或不同的 S 、C R 2 4 7 C〇、NR48或化學式（VI I I)之基團 ^C=CH-0-CR29.(CO)-A (VIII) 其附帶條件爲 a) 至少基團Q1、Q2、E、G中的一個爲羰基，事實上這些基團中的一個爲化學式（VI I I)的基團及化學式（VI I I)的基團毗連至羰基團，及 b) 二個毗連基團Q1、Q2、E及G不可同時地爲氧；QE, G are the same or different S, CR 2 4 7 Co, NR48 or a group of formula (VI II) ^ C = CH-0-CR29. (CO) -A (VIII) with the condition a) At least one of the groups Q1, Q2, E, G is a carbonyl group. In fact, one of these groups is a group of the formula (VI II) and a group of the formula (VI II) is adjacent to the carbonyl group, and b) The two adjacent groups Q1, Q2, E and G cannot be oxygen at the same time;

Rg爲相同或不同的Η或（CRg is the same or different Η or (C

C 烷基或二個基團 (請先閱讀背面之注意事項再 I · I I 本頁) --線- 4 9 經濟部智慧財產局員工消費合作社印製C alkyl or two groups (please read the notes on the back before I · I I on this page)-line-4 9 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

基一（C R9 —起爲（C2 - C6)—伸院基； Α 爲 Y3 — Rh 或 NR2 X 4爲〇或s (〇）X ; Y 3爲〇或S ;Base one (C R9-starting with (C2-C6)-Shenyuan base; Α is Y3-Rh or NR2 X 4 is 0 or s (〇) X; Y 3 is 0 or S;

Rh 爲H、（Cl— C8) —院基、（Cl — C 8)—鹵院基、（Cl 一 C4)—院氧基一（Cl— C8) - 院基、（ Cs - C6) -烯烴氧基一（Ci—C8) -烷基、或苯 c8) —烷基，其中苯基環視需要由鹵素本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公爱） -19- 508216 A7 B7 五、發明說明（17) (請先閱讀背面之注意事項再本頁) 、（Ci—C4) —烷基、CF3、甲氧基或甲基一 S ( Ο ) X ； (c3 — c6)烯烴基、（c3— c6) — 鹵烯烴基、苯基_ (c3— c6)—烯烴基、（c3 —. C6) -炔基、苯基—（C3— C6) -快基、惡丁環英基、糠基、四氫糠基取代； R 4 3 爲 Η 或（Ci—Cd) —烷基； R 4 4 爲相同或不同的Η、（Ci— C4) 一烷基、（Rh is H, (Cl—C8) —yuan, (Cl—C 8) —halogen, (Cl—C4) —oxyl— (Cl—C8) —yuan, (Cs—C6) —olefin Oxy- (Ci-C8) -alkyl, or benzene c8) -alkyl, in which the phenyl ring is made of halogen as needed. This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 public love) -19- 508216 A7 B7 V. Description of the invention (17) (Please read the precautions on the back before this page), (Ci-C4) -alkyl, CF3, methoxy or methyl-S (Ο) X; (c3-c6 ) Alkenyl, (c3—c6) —haloalkenyl, phenyl— (c3—c6) —olefin, (c3—. C6) —alkynyl, phenyl— (C3—C6) —fastyl, oxetane Cycloinyl, furfuryl, and tetrahydrofurfuryl are substituted; R 4 3 is fluorene or (Ci-Cd) -alkyl; R 4 4 is the same or different fluorene, (Ci- C4) -alkyl, (

Ci — Ca) -烷基羰基或二個基團R44 —起爲（c4 .一 C 5 ) -伸烷基； R 4 5，R 4 6 於每個實例中各別地爲相同或不同的Η、( Ci—Cd)—烷基，或二個基團R45及/或R46 — 起爲（C4 — C5) —伸院基，其中一個CH2基團可由〇或3置換或一個或二個C H2基團可由NR 1置換 > R 爲Η或（Ci— Ce) -院基； R 4 7 爲相同或不同的Η、（Ci —Cs) —院基或二個基團R47—起爲（C2— C6)—伸烷基；經濟部智慧財產局員工消費合作社印製 R 4 8 爲Η、（ C i — C 8 ) -烷基、經取代或未經取代的苯基、或爲於苯基環爲未經取代或經取代的苄基； R 4 9 爲相同或不同的Η、（Ci — C8) —烷基、苯基、苯基—（Ci 一 C8) -院基，其中苯基環可由F、 Cl、Br、N〇2、CN、〇CH3、 ( C 1 - C 4 ) —院基或CH 3S〇2 —、（Cl 一 C4) —烷氧基—（. C i 一 C 8 )—烷基、（C 3 - C 6 ) -烯烴基、（C 3 -20- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508216 A7 B7 五、發明說明（18) —C6) -炔基、（C3 — C6) -環院基取代或一個基團R49 —起爲（C4 一 c5) —伸烷基，其中一個 C H2基團可由〇或s置換或一個或二個c H2基團可· 由N R k置換；Ci—Ca) —alkylcarbonyl or two groups R44—from (c4.—C5) —alkylene; R 4 5 and R 4 6 are each the same or different in each example. , (Ci-Cd) -alkyl, or two groups R45 and / or R46 — starting from (C4 — C5) — Shenyuan, where one CH2 group can be replaced by 0 or 3 or one or two C H2 Groups can be replaced by NR 1 > R is Η or (Ci-Ce)-Yuan; R 4 7 is the same or different Η, (Ci -Cs)-Yuan or two groups R47-starting with (C2 — C6) —Dialkyl; printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, R 4 8 is Η, (C i — C 8) -alkyl, substituted or unsubstituted phenyl, or phenyl The ring is unsubstituted or substituted benzyl; R 4 9 is the same or different fluorene, (Ci — C8) —alkyl, phenyl, phenyl — (Ci — C8) — courtyard, where the phenyl ring Can be selected from F, Cl, Br, No2, CN, 0CH3, (C 1-C 4) — courtyard or CH 3S〇2 —, (Cl-C4) — alkoxy — (. C i-C 8 ) —Alkyl, (C 3-C 6) -Olefin, (C 3 -20- This paper is applicable to China Standard (CNS) A4 (210 X 297 mm) 508216 A7 B7 V. Description of the invention (18) -C6)-alkynyl, (C3-C6)-cycloalkyl substituted or a group R49-starting with (C4 A c5) —alkylene, in which one C H2 group may be replaced by 0 or s or one or two c H2 groups may be replaced by NR k;

Rk爲H或（Cx— C4) —烷基； m ”爲〇或1及 X 爲0、1或2 ; 包含立體異構物及農業上常用的鹽類，與除混合物外，其中 a )於化學式（I )之化合物中，V = V1或V4及安全劑具有化學式（I V)或選自1，8 —苯二甲酸酐；二苯基甲氧基醋酸甲酯；2 —二氯甲基一 2 —甲基一 1，3 -二茂烷；氰基甲氧基亞胺基（苯基）乙腈； 4，6 -二氯一 2 -苯基喃卩定；1，3_二茂垸一 2 —基甲氧基亞胺基（苯基）乙腈；4’ 一氯一 2，2 ，2 —三氟乙醯苯〇_1，3 —二茂院一 2 —基甲基肟；（5 —氯一 8_喹啉氧基）醋酸1 一甲基己酯及苄基一 2 —氯一 4_三氟甲基—1，3 —噻唑一5 — 羧酸鹽；或 b)於化學式（I )之化合物中，V = V3其中R6 = 〇H ，及安全劑一具有化學式（I I)其中W = W1、W2、W3 或W4其中m’ =1，或一具有化學式（I I I)及T爲（Ci 一或C2) - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -21 - (請先閱讀背面之注意事項再 I i I 本頁) •線· 經濟部智慧財產局員工消費合作社印製 508216 經濟部智慧財產局員工消費合作社印製 A7 B7____ 五、發明說明（19 ) 一 ί兀煙基鍵’其爲未經取代或由一個或二個（C 1 一 C4) -烷基團取代，或一具有化學式（IV)，或一爲由1，8 —奈二甲酸酐、氰基甲氧基一亞胺基 —(本基）—乙腈、oxabetrinile、fluxofenim 及 flurazole 組成的化合物基團。具除草性活性的量爲，本發明之目的，能夠相反地影響植物生長的一種或多種除草劑的量。解毒地有效量爲，本發明之目的，能夠至少部分地抗衡除草劑或除草劑混合物於有用植物上的毒害植物影響之一種或多種安全劑的量。除非有其它各別地定義，否則遵循的定義通常地應用至化學式（I)至（VI I I)的基團及於隨後的化學式中〇於每個實例中的烷基、烷氧基、鹵烷基、鹵烷氧基、烷基胺基及烷硫基基團及相符合的未飽合及/或經取代的基團其碳鏈可爲直鏈或分枝的。烷基團，此組成亦意指爲諸如烷氧基、1鹵烷基及其類似物，較佳地具有1至4個碳原子及爲，例如，甲基、乙基、正一或異一丙基或正一、異-、第三或2 - 丁基。烯烴基及炔基團意指爲可與烷基團相符的未飽合基團；烯烴基爲，例如，烯丙基、1 一甲基丙—2 —儲—1—基、2 -甲基丙一 2 —嫌一 1 一基、丁一 2 —嫌一 1 一基、丁一 3 —嫌一1 一基、1 一甲基丁一 3 —烯一 1-基及1 —甲基丁一 2 -烯—1 一基。炔基爲本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐) - 22- (請先閱讀背面之注意事項再If寫本頁)Rk is H or (Cx—C4) —alkyl; m ”is 0 or 1 and X is 0, 1 or 2; contains stereoisomers and salts commonly used in agriculture, and in addition to mixtures, a) in In the compound of the formula (I), V = V1 or V4 and the safener has the formula (IV) or is selected from 1,8-phthalic anhydride; methyl diphenylmethoxyacetate; 2-dichloromethyl-1 2-methyl-l, 3-diocenane; cyanomethoxyimino (phenyl) acetonitrile; 4,6-dichloro- 2-phenylsulfanilidine; 2-methylmethoxyimino (phenyl) acetonitrile; 4 'monochloro-2,2,2-trifluoroacetamidobenzene 0_1,3-dimethylene oxime 2-ylmethyloxime; (5 —Chloro-8-quinolinyloxy) acetic acid 1-methylhexyl ester and benzyl 2- 2-chloro-4—trifluoromethyl-1,3-thiazole-5—carboxylate; or b) in the chemical formula ( In the compounds of I), V = V3 where R6 = 0H, and the safener has a chemical formula (II) where W = W1, W2, W3 or W4 where m '= 1, or a compound of formula (III) and T is (Ci I or C2)-This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) -21-(Please read the notes on the back before I i I this page) • Line · Printed by the Employee Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 Printed by the Employee Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7____ V. Description of the invention (19) A fluorenyl bond is unsubstituted or substituted by one or two (C 1 -C 4) -alkyl groups, or one has the chemical formula (IV), or one is represented by 1 , 8-naphthalenedicarboxylic anhydride, cyanomethoxy-imino- (benzyl) -acetonitrile, oxabetrinile, fluxofenim, and flurazole. The amount of herbicidal activity is, for the purpose of the present invention, able to The amount of one or more herbicides that adversely affect plant growth. A detoxically effective amount is one or more safeners that at least partially counteract the toxic plant effects of herbicides or herbicide mixtures on useful plants Unless there are other individual definitions, the following definitions are generally applied to the groups of formulae (I) to (VI II) and to the subsequent formulae: alkyl, alkane in each example Carbon, haloalkyl, haloalkoxy, alkylamino and alkylthio groups and corresponding unsaturated and / or substituted groups may have a straight or branched carbon chain. Alkyl Group, this composition also means such as alkoxy, 1 haloalkyl and the like, preferably having 1 to 4 carbon atoms and is, for example, methyl, ethyl, n- or iso-propyl Or n-, iso-, tertiary, or 2-butyl. Alkenyl and alkynyl groups mean unsaturated groups compatible with alkyl groups; alkenyl groups are, for example, allyl, 1-methyl Glycyl-2 —Chrysyl — 1-yl, 2-Methylpropanyl-2 — Suspect 1- 1 radical, Ding 2- 2 — Suspect 1 — 1 radical, Ding 3- 3 — Suspect 1- 1 radical, 1-methyl butane A 3-ene-1-yl group and a 1-methylbut-2-ene-1-yl group. The alkynyl group is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)-22- (Please read the precautions on the back before writing this page if)

508216 A7 B7 五、發明說明（2〇) ，例如，炔丙基、丁 — 2 —炔一 1—基、丁一 3 —炔一 1 一基、1—甲基丁一 3 —炔—1—基。'（Ci—Cd) -烷基〃爲具有1至4個碳原子的烷基之縮寫；相同類似地· 應用至其它基團的一般定義，其中可能的碳原子數目範圍指爲同類。環院基，較佳地，爲具有3至8，較佳地3至7，特別佳地3至6，個碳原子的環狀烷基團，例如環丙基、環丁基、環戊基及環己基。環烯烴基及環炔基指爲相符的未飽合化合物。鹵素爲氟、氯、溴或碘。鹵烷基、鹵烯烴基及鹵炔基爲部分或完全由鹵素，較佳地由氟、氯及/或溴，特別地由氟或氯取代的烷基、烯烴基或炔基，例如C F 3、 CHF2、CH2F、CF3CF2、CH2FCHC1、 CCls、CHC12、CH2CH2CI。鹵烷氧基，例如，爲〇CF3、〇CHF2、〇CH2F 、CF3CF2〇、〇ch2cf3及〇ch2ch2ci。此亦類似地應用至其它鹵素取代的基團。烴基團可爲芳香族或脂肪族烴基團，其中脂肪族烴基團通常爲直鏈或分枝的飽合或未飽合的烴基團，較佳地具有1至1 8，特別佳地1至1 2，個碳原子，例如烷基、烯烴基或炔基。脂肪族烴基團較佳地爲具有上至1 2個碳原子的烷基、烯烴基或炔基；相同類似地應用至於烴氧基團中的脂肪烴基團。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再本頁) 經濟部智慧財產局員工消費合作社印製 -23- 508216 A7 _______ B7 五、發明說明（21) 芳香基通常爲具有較佳的6 - 2 0個碳原子，較佳地 6至1 4個碳原子，特別佳地6至1 0個碳原子的單、雙一或多環狀芳香族系統，例如苯基、萘基、四氫萘基、茚基、茚滿基、戊搭烯基及莽基，特別佳爲苯基。雜環、雜環基團或雜環基爲飽合、未飽合及/或芳香族的單、雙-或多環系統及包括一個或多個，較佳地1至 4 ’個雜原子，較佳地選自N、S及〇。較佳物爲具有3至7環原子的飽合雜環及一個或二個雜原子選自N、0及S，其硫族不毗連。特別佳地爲具有 3至7個環原子的單環及雜原子選自N、〇及S，及亦可爲嗎福林、二茂烷、哌嗪、咪唑啉及惡唑烷。非常特別佳的飽合雜環爲環氧丙烷、吡咯烷酮，嗎福林及四氫呋喃。亦較佳的爲部分未飽合具有5至7個環原子的雜環及一個或二個雜原子選自N、〇及S。特別佳地爲部分.未飽合具有5至6個環原子的雜環及一個雜原子選自N、〇及 S。非常特別佳地爲部分未飽合的雜環有吡唑啉、咪唑啉及異惡哩啉。相當佳的爲雜芳香基，例如具有5至6個環原子，其含一個至四個選自N、0、S，且硫族不毗連，的雜原子之單或雙環芳香族雜環。特別佳地爲具有5至6個含選自 N、0及S雜原子的環原子之單環芳香族雜環，及亦爲嘧啶、吡嗪、噠嗪、惡唑、噻唑、噻二唑、惡二唑、吡唑、三唑及異惡唑。非常特別佳地爲吡唑、噻唑、三唑及呋喃本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -24 - (請先閱讀背面之注意事項再 i I 本頁) — — — — — — — ^ 1111111! 經濟部智慧財產局員工消費合作社印製 508216 A7 ____B7___五、發明說明（22 ) 經取代的基團，諸如經取代的烴基團，例如經取代的烷基、烯烴基、炔基、芳香基諸如苯基及芳香基烷基諸如苄基，或經取代的雜環基，爲衍生自未經取代的骨架之經取代的基團，取代物爲，較佳地，一種或多種，較佳地1 、2或3，於C 1及F的實例中亦上至最大可能的數目，取代物選自鹵素、烷氧基、鹵烷氧基、烷硫基、羥基、胺基、硝基、羧基、氰基、疊氮基、烷氧基羰基、烷基羰基、甲醯基、胺甲醯基、單及二烷基胺基羰基，經取代的胺基諸如醯基胺基、單及二烷基胺基及烷基sulfynyl、鹵烷基 sulfynyl、烷基磺醯基、鹵烷基磺醯基及，於環狀基團的實例中，亦爲烷基及鹵烷基及未飽合的符合上述提及飽合的含烴取代物之脂肪族取代物，較佳地爲烯基、炔基、烯烴氧基及炔氧基。於具有碳原子的基團實例中，那些具有1 至4個碳原子，特別地1或2個碳原子，爲較佳的。通常，較佳的取代物爲選自鹵素的那些，例如氟或氯、（C i - 請先閱讀背面之注意事項508216 A7 B7 V. Description of the invention (20), for example, propargyl, but-2-yn- 1-yl, but-3-3-acetyl-1, 1-methylbut-1-3-acetyl-1 base. '(Ci-Cd) -alkyl〃 is an abbreviation for an alkyl group having 1 to 4 carbon atoms; the same applies similarly to the general definition of other groups, where the range of possible carbon atoms refers to homogeneous. Cyclocyclyl, preferably a cyclic alkyl group having 3 to 8, preferably 3 to 7, particularly preferably 3 to 6, carbon atoms, such as cyclopropyl, cyclobutyl, cyclopentyl And cyclohexyl. Cycloalkynyl and cycloalkynyl refer to corresponding unsaturated compounds. Halogen is fluorine, chlorine, bromine or iodine. Haloalkyl, haloalkynyl and haloalkynyl are alkyl, alkenyl or alkynyl groups partially or completely substituted with halogen, preferably fluorine, chlorine and / or bromine, especially fluorine or chlorine, such as CF 3 , CHF2, CH2F, CF3CF2, CH2FCHC1, CCls, CHC12, CH2CH2CI. Haloalkoxy groups are, for example, 0CF3, 0CHF2, 0CH2F, CF3CF2O, 0ch2cf3, and 0ch2ch2ci. This also applies analogously to other halogen-substituted groups. The hydrocarbon group may be an aromatic or aliphatic hydrocarbon group, wherein the aliphatic hydrocarbon group is usually a linear or branched saturated or unsaturated hydrocarbon group, preferably having 1 to 18, particularly preferably 1 to 1 2, carbon atoms, such as alkyl, alkenyl or alkynyl. The aliphatic hydrocarbon group is preferably an alkyl group, an olefin group or an alkynyl group having up to 12 carbon atoms; the same applies similarly to the aliphatic hydrocarbon group in the alkoxy group. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before printing this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-23- 508216 A7 _______ B7 V. Description of the invention (21) The aromatic group is usually a mono-, bi- or polycyclic ring having preferably 6 to 20 carbon atoms, preferably 6 to 14 carbon atoms, particularly preferably 6 to 10 carbon atoms. Aromatic systems such as phenyl, naphthyl, tetrahydronaphthyl, indenyl, indanyl, pentenenyl, and manganyl, particularly preferably phenyl. A heterocyclic ring, heterocyclic group or heterocyclic group is a saturated, unsaturated and / or aromatic mono-, bi- or polycyclic ring system and includes one or more, preferably 1 to 4 'heteroatoms, It is preferably selected from N, S and 0. Preferred are saturated heterocyclic rings having 3 to 7 ring atoms and one or two heteroatoms selected from N, 0 and S, and the chalcogens are not contiguous. Particularly preferred are monocyclic and heteroatoms having 3 to 7 ring atoms selected from N, 0 and S, and may also be morpholin, dioctane, piperazine, imidazoline and oxazolidine. Very particularly good saturated heterocycles are propylene oxide, pyrrolidone, morpholin and tetrahydrofuran. It is also preferred that the partially unsaturated heterocyclic ring having 5 to 7 ring atoms and one or two heteroatoms are selected from N, 0 and S. Particularly preferred is a moiety. Unsaturated heterocycles having 5 to 6 ring atoms and one heteroatom are selected from N, O and S. Very particularly preferably partially unsaturated heterocycles are pyrazoline, imidazoline and isoxazoline. Quite preferred are heteroaromatic groups, such as mono- or bicyclic aromatic heterocycles having 5 to 6 ring atoms containing one to four heteroatoms selected from N, 0, and S, and not having a chalcogen. Particularly preferred are monocyclic aromatic heterocycles having 5 to 6 ring atoms containing heteroatoms selected from N, 0 and S, and also pyrimidine, pyrazine, pyridazine, oxazole, thiazole, thiadiazole, Oxadiazole, pyrazole, triazole and isoxazole. Very particularly good for pyrazole, thiazole, triazole and furan. The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -24-(Please read the precautions on the back before i I page) — — — — — — — ^ 1111111! Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 ____B7___ V. Description of the invention (22) Substituted groups, such as substituted hydrocarbon groups, such as substituted alkyl , Alkynyl, alkynyl, aryl such as phenyl and arylalkyl such as benzyl, or substituted heterocyclyl are substituted groups derived from an unsubstituted skeleton, and the substitution is, preferably Groundly, one or more, preferably 1, 2, or 3, are also up to the largest possible number in the examples of C 1 and F, and the substituents are selected from halogen, alkoxy, haloalkoxy, alkylthio, Hydroxyl, amino, nitro, carboxyl, cyano, azide, alkoxycarbonyl, alkylcarbonyl, formamyl, carbamoyl, mono and dialkylaminocarbonyl, substituted amine groups such as Fluorenylamino, mono and dialkylamino and alkylsulfynyl, haloalkylsulfynyl, Alkylsulfonyl, haloalkylsulfonyl and, in the examples of cyclic groups, also alkyl and haloalkyl and unsaturated aliphatic hydrocarbons in accordance with the saturated hydrocarbon-containing substituents mentioned above Substituents are preferably alkenyl, alkynyl, alkoxyl and alkynyloxy. Among the examples of the group having carbon atoms, those having 1 to 4 carbon atoms, particularly 1 or 2 carbon atoms, are preferred. Generally, the preferred substitutes are those selected from halogens, such as fluorine or chlorine, (C i-Please read the note on the back first

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C 烷基，較佳地甲基或乙基、（Ci—Cd) —鹵烷經濟部智慧財產局員工消費合作社印製基，較佳地三氟甲基、（C i 一 C 4 ) 一烷氧基，較佳地甲氧基或乙氧基、（Ci—Cd) -鹵烷氧基、硝基及氰基。於此文中特別佳地爲甲基、甲氧基及氯取代物。單或二經取代的胺基爲化學地穩定基團，其選自N -取代的經取代胺基團，例如，一個或二個選自烷基、烷氧基、醯基及芳香基的相同或不同基團；較佳地單烷基胺基、二烷基胺基、醯基胺基、芳香基胺基、N -烷基一 N -芳香基胺基及N -雜環。於本文中較佳的爲具1至4個碳本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -25 508216 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（23) 原子的烷基團。較佳地，芳香基爲苯基。較佳地，經取代的芳香基爲經取代的苯基。下列提供的進一步定義應用至醯基，較佳地爲（Ci 一 C4) 一院醇基。此亦類似地應用至經取代的羥基胺基或肼基。較佳地，視需要經取代的苯基爲未經取代或單或多取代的，較佳地上至三取代的苯基，於鹵素的實例中諸如 C 1及F亦上至五取代，由相同或不同的選自鹵素、（Ci 一 c4)—烷基、（Ci—CO —烷氧基、（Ci— c4) 一鹵烷基、（Ci—C 4) 一鹵烷氧基及硝基，例如鄰一、間一及對一甲苯基、二甲基苯基、2 —、3 —及4 一氯苯基、2 —、3 -及4 —三氟一及—三氯苯基、2，4一、 3，5 -、2，5 —及2，3 —二氯苯基、鄰―、間一及對一甲氧基苯基基團。醯基團爲具有較佳地上至6個碳原子的有機酸基團，例如羧酸基團及由此衍生的酸基團，諸如硫羧酸，視需要爲N -經取代的亞胺基羧酸、或碳酸單酯基團，視需要n -經取代的胺基甲酸、磺酸、亞磺酸、膦酸、亞膦酸。醯基爲’例如，甲釀基、院基鑛基諸如（Cl 一 C4 一院基） -羰基、苯基羰基，其爲可爲經取代的苯基環，例如如上述指定苯基、或烷氧基羰基、苯氧基羰基、苄氧基羰基、烷基磺醯基、烷基sulfynyl或N -烷基一 1 —亞胺基烷基〇全部顯示相同拓樸連結原子，及其混合物的立體異構物，亦落在化學式（I)至（VI I I)中。此化合物包 (請先閱讀背面之注意事項丨—— 再本頁) •線」本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 26 508216 A7 ____B7______五、發明說明（24) 含一個或多個不對稱碳原子或其它沒於一般化學式中明確指定的雙鍵。可能的由其特定的空間形式定義之立體異構物，諸如鏡像物、非對映異構物、Z -及E -異構物，可利用習慣的方法或其它利用立體選擇性反應與使用立體化學純起始物質組合製備而獲得立體異構物混合物形式。根據本發明合適的具除草性活性物質爲化學式（I ) 的那些化合物，其本身，不使用，或不理想的使用，於穀類莊稼、米及/或玉蜀黍因爲它們太傷害莊稼植物。已知化學式（I )之除草劑，例如，從E P -A 0 137 963、EP-A 〇 3 5 2 543、C alkyl, preferably methyl or ethyl, (Ci-Cd) -halane, printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs, preferably trifluoromethyl, (C i -C 4) -alkane Oxy, preferably methoxy or ethoxy, (Ci-Cd) -haloalkoxy, nitro and cyano. Particularly preferred herein are methyl, methoxy and chloro substituents. Mono- or di-substituted amine groups are chemically stable groups selected from N-substituted substituted amine groups, for example, one or two of the same group selected from alkyl, alkoxy, fluorenyl, and aromatic groups Or different groups; preferably monoalkylamino, dialkylamino, fluorenylamino, arylamino, N-alkyl-N-arylamino and N-heterocyclic. In this article, it is better to have 1 to 4 carbon paper sizes and apply Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -25 508216 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Inventions Illustrate the alkyl group of (23) atom. Preferably, the aromatic group is phenyl. Preferably, the substituted aromatic group is a substituted phenyl group. The further definitions provided below apply to fluorenyl, preferably (Ci-C4) -alcohol. This also applies similarly to substituted hydroxylamino or hydrazine. Preferably, optionally substituted phenyl is unsubstituted or mono- or poly-substituted, preferably up to tri-substituted phenyl, in the case of halogen such as C 1 and F are also substituted up to penta, from the same Or differently selected from halogen, (Ci-c4) -alkyl, (Ci-CO-alkoxy, (Ci-c4) -haloalkyl, (Ci-C4) -haloalkoxy and nitro, For example, o-, m- and p-tolyl, dimethylphenyl, 2-, 3-, and 4-monochlorophenyl, 2-, 3-, and 4-trifluoro- and -trichlorophenyl, 2, 4 1, 3, 5-, 2, 5 — and 2, 3- dichlorophenyl, o-, m- and p-methoxyphenyl groups. The fluorene group has preferably up to 6 carbons. Atomic organic acid groups, such as carboxylic acid groups and acid groups derived therefrom, such as thiocarboxylic acids, if desired, are N-substituted iminocarboxylic acids, or carbonate monoester groups, as necessary n -Substituted amino formic acid, sulfonic acid, sulfinic acid, phosphonic acid, phosphinic acid. The fluorenyl group is, for example, a methyl group, a base group such as (Cl-C4-a group)-a carbonyl group, a phenyl Carbonyl, which may be substituted phenyl ring For example, as specified above, a phenyl group, or an alkoxycarbonyl group, a phenoxycarbonyl group, a benzyloxycarbonyl group, an alkylsulfonyl group, an alkylsulfynyl group, or an N-alkyl-1-iminoalkyl group is shown. The stereoisomers of Pu-linked atoms, and their mixtures, also fall into the chemical formulae (I) to (VI II). This compound package (please read the precautions on the back first --- then this page) Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 26 508216 A7 ____B7______ V. Description of the invention (24) Contains one or more asymmetric carbon atoms or other double bonds not explicitly specified in the general chemical formula .Possible stereoisomers defined by their specific spatial forms, such as mirror images, diastereomers, Z- and E-isomers, can be reacted and used by customary methods or other methods using stereoselectivity Stereochemically pure starting materials are prepared in combination to obtain stereoisomer mixtures. Suitable herbicidally active substances according to the present invention are those compounds of formula (I), which are themselves not used, or are undesirably used in Cereal crops, rice and / or maize because they are too harmful to crop plants. Herbicides of the chemical formula (I) are known, for example, from EP-A 0 137 963, EP-A 〇 3 5 2 543,

E P A 0 4 1 8 175、EP — a 〇 496E P A 0 4 1 8 175, EP — a 〇 496

631及AU — A 6 7 2 058。已知化學式（ii) 之化合物，例如，從EP — A— 0 3 3 3 1 3 1 ( Z A — 8 9 / 1 9 6 0 EP-A-0 2 6 9 8 0 6 ( (請先閱讀背面之注意事項再本頁) £ 經濟部智慧財產局員工消費合作社印製 US - A4，891，057)、Ep〜A—〇 346 620 (AU-A-89/34951)、EP — A— 〇 174 562 ' EP-A-0 3 4 6 6 2 〇 ( W 0 - A -91/08 202)、WO - A — 9i/〇7874 或 WO — A95/07897 (ZA 94/7i2〇)及在弓丨的方法或類似的製備。已從 EP — Α — 0 0 8 6 7 5 〇 , p D Λ ι Κ 一 Α — 0 94349 (US-A-4，9〇2,34〇)、 EP - A-0 191 736(US〜a4，"i， 966)及EP — A-0 4 9 2 υ 6及在其中引用的線- 508216 Α7 Β7 五、發明說明（25) 文獻中知到化學式（I I I )之化合物或可利用描述在其中的方法或類似的製備。再者，某些化合物描述於E P -A— 〇 5 8 2 198中。已從大量的專利申請中知曉化. 學式（IV)之化合物，例如US—A — 4，021， 224 及 US — A — 4，021，229。再者，從基團 (b)之化合物已從CN — A — 87/102 789、 EP — A - 365 484中及從 '殺蟲劑手冊〃，英國莊稼保護會議及皇家社會化學，第1 1版，Farnham 1 9 9 7中知曉。基團（c )的化合物描述於WO — A -9 7/ 450 1 6，基團（d)中的那些則於德國專申請 197 42 95 1.3中及基團（e)的那些則於 W 0 - A 98/1 3 36 1中。引用的公告包括製備方法及起始物質的詳細訊息。這些公告以參考之方式倂於本文。較佳的除草劑/安全劑組合物爲含化學式（I I )及 /或（I I I )之那些安全劑，其中的符號及標誌具有下列意義：經濟部智慧財產局員工消費合作社印製 R 2 4 爲氫、（Cl— Cl8) —院基、（C3 - Cl2) 一環院基、（C2— Ce) -嫌烴基及（C2 - Ci8) -炔基，其中含碳基團可由一個或更佳地上至三個’ 基團R 5 ^取代； R 5 0 爲相同或不同的鹵素、羥基、（Ci—Cs) —烷氧基、（Cl—C8) -院硫基、（C2 - C8) -嫌煙硫基、（C2— C8) -快硫基、（C2 - C8) -嫌煙本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） Γ?8^ " 508216 A7 B7 五、發明說明（26 ) 氧基、（c2 — c8) —炔氧基、（c3 - C7) —環烷基、（C3— C7) -環院氧基、氰基、單及二—（631 and AU — A 6 7 2 058. Known compounds of formula (ii), for example, from EP — A — 0 3 3 3 1 3 1 (ZA — 8 9/1 9 6 0 EP-A-0 2 6 9 8 0 6 ((Please read the back first Note on this page) £ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy US-A4,891,057), Ep ~ A-〇346 620 (AU-A-89 / 34951), EP — A-〇174 562 'EP-A-0 3 4 6 6 2 〇 (W 0-A -91/08 202), WO-A — 9i / 〇7874 or WO — A95 / 07897 (ZA 94 / 7i2〇) and in the bow 丨Method or similar preparation. It has been prepared from EP — Α — 0 0 8 6 7 5 〇, p D Λ κ Α — 0 94349 (US-A-4, 920, 34 〇), EP-A- 0 191 736 (US ~ a4, " i, 966) and EP — A-0 4 9 2 υ 6 and the lines cited therein-508216 Α7 Β7 5. Description of the invention (25) The chemical formula (III) is known in the literature The compounds may be prepared by the methods described therein or similar preparations. Furthermore, certain compounds are described in EP-A- 05 8 2 198. Chemical formulas have been known from a large number of patent applications. Compounds, such as US-A-4,021,224 and US-A-4,021,229. Furthermore, the radical The compound of (b) has been obtained from CN — A — 87/102 789, EP — A-365 484 and from the 'Insecticides Handbook 〃, British Crop Protection Conference and Royal Social Chemistry, 11th Edition, Farnham 1 9 9 Known in 7. The compounds of group (c) are described in WO — A -9 7/450 1 6 and those in group (d) are those in German application 197 42 95 1.3 and group (e). Then in W 0-A 98/1 3 36 1. The quoted announcements include detailed information on the preparation methods and starting materials. These announcements are incorporated herein by reference. The preferred herbicide / safener composition contains For those safe agents of the chemical formula (II) and / or (III), the symbols and signs have the following meanings: R 2 4 printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is hydrogen, (Cl-Cl8)-courtyard, ( C3-Cl2) monocyclic radical, (C2-Ce) -hydrocarbyl and (C2-Ci8) -alkynyl, in which the carbon-containing group may be substituted by one or more preferably up to three 'groups R 5 ^; R 5 0 is the same or different halogen, hydroxyl, (Ci-Cs) -alkoxy, (Cl-C8)-sulfanyl, (C2-C8)-fuming sulfanyl, C2— C8) -Fast sulfur-based, (C2-C8) -The paper size of susceptible cigarettes applies the Chinese National Standard (CNS) A4 (210 X 297 mm) Γ? 8 ^ " 508216 A7 B7 V. Description of the invention (26 ) Oxy, (c2-c8) -alkynyloxy, (c3-C7) -cycloalkyl, (C3-C7) -cycloalkyloxy, cyano, mono and di- (

Cl 一 C4)—院基胺基、竣基、（Cl—C8)—院氧· 基羰基、（C2 - c8) —烯烴氧基羰基、（Ci — C8 )一烷硫基羰基、（C2— c8) -炔氧基羰基、（ Ci—Cs) -烷基羰基、（c2 - c8)—烯烴基羰基、（C 2 — c8) -炔基羰基、1 一（羥亞胺基）一（ C 1 — C 6 )—院基、1—〔（Cl — C4) 一院基亞胺基〕—（Cl—C4) 一院基、1 一〔（Cl—C4) 一烷氧基亞胺基〕—（Ci—Ce)—烷基、（Ci — C8 )一院基鑛基胺基、（C2 - C8) —燦煙基幾基胺基、（C2 — c8) -炔基羰基胺基、胺基羰基、（Ci —C8)—烷基胺基羰基、二一（Ci—Ce)—烷基胺基羰基、（c2-c6) -烯烴基胺基羰基、（C2 —c6)—炔基胺基羰基、（Cl—c8) -烷氧基羰基胺基、（C i 一 C 8 ) —烷基胺基羰基胺基、爲未經取代或由R51取代的（Ci— c6) -烷基羰氧基，或爲（c/一 c6) —烯烴基羰氧基、（c2 - c6) -炔基羰氧基、（Ci-Cs) -烷基磺醯基、苯基、苯基 —(Cl 一 C6)—院氧基、苯基一（Cl— C6)—院氧基羰基、苯氧基、苯氧基一（Ci— C6) —烷氧基、苯氧基一（Ci—Cs) -烷氧基羰基、苯基羰氧基、苯基羰基胺基、苯基一（Ci—Ce) -烷基羰基胺基，最後提及之9個基團可爲未經取代或由單或多取本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -29 (請先閱讀背面之注意事項丨--- 再本頁) --線· 經濟部智慧財產局員工消費合作社印製 A7Cl-C4) —Chenylamino group, cynyl, (Cl—C8) —Chenoxy · carbonyl group, (C2-c8) —Alkenyloxycarbonyl group, (Ci—C8) -Alkylthiocarbonyl group, (C2— c8) -alkynyloxycarbonyl, (Ci-Cs) -alkylcarbonyl, (c2-c8) -alkenylcarbonyl, (C 2-c8) -alkynylcarbonyl, 1- (hydroxyimino)-(C 1 — C 6) —Yuanji, 1 — [(Cl — C4) One Yield Imine] — (Cl—C4) One Yield, 1 One [(Cl—C4) Alkoxyimine] — (Ci—Ce) —alkyl, (Ci—C8) monoamine-based mineral amine, (C2-C8) —cannynylamino, (C2—c8) —alkynylcarbonylamino, amine Carbonyl, (Ci-C8) -alkylaminocarbonyl, di (Ci-Ce) -alkylaminocarbonyl, (c2-c6) -alkenylaminocarbonyl, (C2-c6) -alkynylamine Carbonyl, (Cl-c8) -alkoxycarbonylamino, (C i -C 8) -alkylaminocarbonylamino, (Ci-c6) -alkylcarbonyl which is unsubstituted or substituted by R51 Oxygen, or (c / a-c6) -alkenylcarbonyloxy, (c2-c6) -alkynylcarbonyloxy, (Ci-Cs) -alkylsulfonyl, Group, phenyl— (Cl—C6) —hodooxy, phenyl— (Cl—C6) —hodooxycarbonyl, phenoxy, phenoxy— (Ci—C6) —alkoxy, phenoxy Mono (Ci-Cs) -alkoxycarbonyl, phenylcarbonyloxy, phenylcarbonylamino, phenyl- (Ci-Ce) -alkylcarbonylamino, the last nine mentioned groups may be unsubstituted Substitute or take single or multiple dimensions of this paper are applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -29 (Please read the precautions on the back 丨 --- then this page) --Line · Economy Printed A7 by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau

五、發明說明（27 ) 經濟部智慧財產局員工消費合作社印製代，較佳地上至三個R52基團取代、SiR, 3、 OS iR 3、R、s i— (Cl— c8) 一烷氧基、 C〇一〇一 NR’2 、〇一 N=CR,2 、N=CR,2 、〇一NR’2、NR，2、 CH (〇R，） 2、〇一（CH2) q—CH (〇R，） 2 、 cR，，，（〇R，）2 、〇_(CH2)wCR”，（〇11，，）2或由1^，，〇一 CHR”’ CHC〇R” 一（Ci—Ce) —烷氧基， R 5 1 爲相同或不同的鹵素、硝基、（Cl — c4) 一院氧基及爲未經取代或由一個或多個，較佳地上至三個 R 5 2基團取代之苯基； R52 爲相同或不同的鹵素、（Ci — C4) 一烷基、( Cl — C4) 一烷氧基、（Cl —C4)—鹵烷基、（ Cl — C4) 一鹵院氧基或硝基； R’爲相同或不同的氫、（Ci — Cd) —烷基、爲未經取代或由一個或多個，較佳地上至三個R52基團取代的苯基，或二個R’基團一起形成（C2— C6)-二烷烴基鏈； R”爲相同或不同的（Ci-C4) 一烷基或二個R”基團一起形成（C2 — C6) - 一院烴基鏈； R 爲氫或（Ci 一 C4)—院基； w 爲 0、1、2、3、4、5或6。特別佳地爲根據本發明之除草劑/安全劑組合物包含化學式（I I)及/或（I I I)之安全劑’其中的符號及標誌具有下列意義： (請先閱讀背面之注意事項再 •襄___ 编本頁) ·. 線· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -30- 508216 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（28) R 2 4 爲氫、（Ci—Cs) - 烷基或（C3 - C7) — 環烷基，上述含碳基團爲未經取代或由單或多鹵素取代或由單或二R5()基團取代，較佳地爲單取代， R 5 0 爲相同或不同的羥基、（Ci— C4) 一烷氧基、羧基、（Ci_C4) 一烷氧基羰基、（C2 — C6) — 烯烴氧基羰基、（C2 — C6) -炔氧基羰基、1 一（羥基亞胺基）—（Ci— C4)—烷基、1_〔（Ci —C4)—垸基亞胺基〕一（Ci 一 C4) 一院基及1 —〔（Cl 一 C4) 一院氧基亞胺基〕—（Cl 一 C4) —烷基；S i R，3、〇一N=CR’2、N=CR’2、 NR ’2及〇NR ’3，其中R’爲相同或不同的氫、（ Cl 一 C4)—院基或，成對的，（C4— C5) -二院烴基鏈， R27，R28，R29 爲相同或不同的氫、（Ci—Cs )—院基、（Cl —C6) —鹵院基、（C3 — C7) — 環烷基或爲未經取代或由一個或多個選自鹵素、氰基、硝基、胺基、單及二—〔（Cl 一 C4) 一院基〕一胺基、（Ci— C4) 一烷基、（Ci—Cd) -鹵烷基、(C 1 — C 4 )—院氧基、（Cl— C4) 一鹵院氧基、(C 1 - C 4 ) 一烷硫基及（C i 一 C 4 ) 一烷基磺醯基基團取代的苯基； R 2 6 爲氣、（Cl— C8) - 院基、（Cl 一 Cs) -鹵院基、（Cl — C4 一院氧基）一（Cl — C4) 一院基、（Cl— C6)—經院基、（C3 — C7)—環院基本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -31 - I丨訂·！！！線L (請先閱讀背面之注意事項再與寫本頁) 太 508216 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（29) 或三一（Ci 一 C4) 一院基砂基， R17，R19爲相同或不同的鹵素、甲基、乙基、甲氧基、乙氧基、（〇1或（：2) —鹵烷基，較佳地爲氫、鹵素或（Ci—Cs) —鹵烷基。非常特別佳地，化學式（I I )之安全劑的符號及標誌於具有下列意義：V. Description of the invention (27) Printed on behalf of consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, preferably up to three R52 groups substituted, SiR, 3, OS iR 3, R, si— (Cl—c8) monoalkoxy Group, C〇〇〇一 NR'2, 〇N = CR, 2, N = CR, 2, 〇NR'2, NR, 2, CH (〇R,) 2, 〇一 (CH2) q— CH (〇R,) 2, cR ,,, (〇R,) 2, 〇_ (CH2) wCR ”, (〇11 ,,) 2 or CHR" 'CHC〇R "a (Ci—Ce) —alkoxy, R 5 1 is the same or different halogen, nitro, (Cl — c4) monooxy and is unsubstituted or consists of one or more, preferably up to three R 5 2 group substituted phenyl; R52 is the same or different halogen, (Ci — C4) -alkyl, (Cl — C4) -alkoxy, (Cl —C4) —haloalkyl, (Cl — C4) monohalooxy or nitro; R 'is the same or different hydrogen, (Ci — Cd) —alkyl, unsubstituted or substituted by one or more, preferably up to three R52 groups Phenyl, or two R 'groups together to form a (C2-C6) -dialkane chain; R "is The same or different (Ci-C4) one alkyl group or two R "groups together form (C2-C6)-a courtyard hydrocarbyl chain; R is hydrogen or (Ci-C4)-courtyard; w is 0, 1 , 2, 3, 4, 5 or 6. Particularly preferably, the herbicide / safener composition according to the present invention contains a safener of formula (II) and / or (III). The symbols and signs therein have the following meanings: (Please read the precautions on the back before making this page.) · Thread · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -30- 508216 Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by Consumer Cooperative A7 B7 V. Description of the invention (28) R 2 4 is hydrogen, (Ci-Cs)-alkyl or (C3-C7)-cycloalkyl, the above carbon-containing groups are unsubstituted or mono Or polyhalogen substituted or mono- or di-R5 () groups, preferably mono-substituted, R 5 0 is the same or different hydroxy, (Ci—C4) monoalkoxy, carboxyl, (Ci_C4) monoalkane Oxycarbonyl, (C2-C6) -olefinoxycarbonyl, (C2-C6) -alkynyloxycarbonyl, 1- (hydroxyimino)-(Ci-C4) -alkyl, 1_ [ (Ci —C4) —fluorenimine] — (Ci—C4) —one and 1 — [(Cl—C4) —oxyimine] — (Cl—C4) —alkyl; S i R, 3, 〇-N = CR'2, N = CR'2, NR'2, and 〇NR'3, where R 'is the same or different hydrogen, (Cl-C4) -based or, paired , (C4—C5) —Secondary hydrocarbyl chain, R27, R28, and R29 are the same or different hydrogens, (Ci—Cs) —Hospital, (Cl —C6) —Halogen base, (C3 — C7) — Ring Alkyl is either unsubstituted or consists of one or more selected from the group consisting of halogen, cyano, nitro, amine, mono and di-[(Cl-C4) -amino] -amino, (Ci-C4)- Alkyl, (Ci-Cd) -haloalkyl, (C 1-C 4) -honooxy, (Cl- C4) monohalooxy, (C 1 -C 4) monoalkylthio, and (C i -C 4) a phenyl group substituted by an alkylsulfonyl group; R 2 6 is a gas, (Cl—C8)-courtyard, (Cl-Cs)-halogen radical, (Cl — C4-oxygen Basic) One (Cl — C4) One hospital base, (Cl — C6) — Economic hospital base, (C3 — C7) — Central hospital basic paper standards are applicable to Chinese National Standard (CNS) A4 regulations Grid (210 X 297 mm) -31-I 丨 Order! !! !! Line L (Please read the precautions on the back before writing this page) Ms. 508216 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (29) or Trinity (Ci-C4) R17 and R19 are the same or different halogen, methyl, ethyl, methoxy, ethoxy, (〇1 or (: 2) -haloalkyl, preferably hydrogen, halogen or (Ci-Cs ) —Haloalkyl. Very particularly preferably, the symbols and signs of the safener of formula (II) have the following meanings:

R 爲鹵素、硝基或（Ci-C4) 一鹵烷基； η 爲 0、1、2 或 3 ; R 1 8 爲化學式OR24之基團R is halogen, nitro or (Ci-C4) monohaloalkyl; η is 0, 1, 2 or 3; R 1 8 is a group of formula OR24

R 2 4 爲氫、（Cl—Cs)—院基或（C3— C7) — 環烷基，其中上述含碳基團爲未經取代或由相同或不同的鹵素基團單或多取代，較佳地上至三取代，或二取代，較佳地單取代的，由相同或不同選自羥基、（ Cl —C4)—院氧基、（Cl —C4) 一垸氧鑛基、（ C2 - c6) -烯烴氧基羰基、（C2 - c6) —炔氧基羰基、1—(羥亞胺基）—（Ci—CO -烷基、1 —〔（ Cl 一 C4)—院基亞胺基〕一（Cl 一 C4) 一烷基、1 一〔（Ci—Cd)—烷氧基亞胺基〕—（ Ci—Cd) —烷基的基團及化學式s i R’3、〇一 N=CR，2、N=CR’2、NR，2及〇一NR’2的基團，其中於上述提及的化學式中R’基團爲相同或不同的氫、（Cl—C4) 一院基或’成對的，爲（C4 或C 5 )—二烷烴基；請先閱讀背 Sr 之注意事項本R 2 4 is hydrogen, (Cl—Cs) —sinyl or (C3—C7) —cycloalkyl, in which the above carbon-containing group is unsubstituted or mono- or poly-substituted with the same or different halogen groups. It is preferably up to tri-substituted, or di-substituted, preferably mono-substituted, which is the same or different and is selected from the group consisting of hydroxyl, (Cl-C4) -co-oxy, (Cl-C4) monooxo-based, (C2-c6 ) -Olefinoxycarbonyl group, (C2-c6) -alkynyloxycarbonyl group, 1- (hydroxyimino group)-(Ci-CO-alkyl group, 1-[(Cl-C4) -institutional imino group] Mono (Cl-C4) -alkyl, 1-[(Ci-Cd) -alkoxyimino]-(Ci-Cd) -alkyl group and chemical formula si R'3, 〇N = CR , 2, N = CR'2, NR, 2 and 0-NR'2, in which the R 'group in the above-mentioned chemical formula is the same or different hydrogen, (Cl-C4) a radical or 'The pair is (C4 or C 5) -dialkane group; please read the note about Sr first

RR

R 2 8R 2 8

R 爲相同或不同的氫R is the same or different hydrogen

CC

C -32- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）爲齒素或（Cl 一 C 4 ) 一齒院基；、1、2或3，其中（R 1 9 ) η，爲，較佳地 508216 Α7 __________ Β7 五、發明說明（30) )—烷基、（Ci — C6) —鹵院基、（C3 - C7) -環烷基或未經取代或由一個或多個選自鹵素、（Ci-C4) —院基、（Cl— C4) 一院氧基、硝基、（Cl. 一 C4) 一鹵烷基及（CX—C4) -鹵烷氧基基團取代的苯基，及 R 爲氣、（Cl— C8) — 院基、（Cl 一〇8)- 鹵院基、（C1—C4) 一院氧基一（Cl—C4) 一院基、（Cl 一 C6) -經院基、（C3 - C7) -環院基或三一（Cl— C4) 一院基砂基。非常特別佳地，亦爲化學式（I I I )之安全劑，其符號及標誌具有下列意義：C -32- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm). It is tooth element or (Cl-C 4) one tooth base;, 1, 2 or 3, where (R 1 9 ) η is, preferably, 508216 A7 __________ B7 V. Description of the invention (30)) -alkyl, (Ci-C6) -haloalkyl, (C3-C7) -cycloalkyl or unsubstituted or a Or more selected from the group consisting of halogen, (Ci-C4) —sinyl, (Cl—C4) —sinoxy, nitro, (Cl.—C4) —haloalkyl, and (CX—C4) —haloalkoxy Phenyl substituted by a group, and R is a gas, (Cl—C8) —a radical, (Cl—108) —a halogen radical, (C1—C4) —a radical oxygen— (Cl—C4) —a radical (Cl-C6)-Jingyuan Foundation, (C3-C7)-Huanyuan Foundation or Trinity (Cl-C4) -Sanyuan Foundation Sand Foundation. Very particularly preferably, it is also a safe agent of the chemical formula (I I I). Its symbols and signs have the following meanings:

R η ’ 爲 0、1 -C 1 ； R 2 0 爲化學式OR24之基團； T 爲CH2或CH (C〇〇一（Ci— C3) —烷基）及請先閱讀背之注項頁R η ′ is 0, 1 -C 1; R 2 0 is a group of chemical formula OR24; T is CH2 or CH (C〇〇 (Ci—C3) —alkyl) and please read the notes on the back

R 2 4 爲氫R 2 4 is hydrogen

C C8)—院基、（Cl 一 C8) 經濟部智慧財產局員工消費合作社印製鹵院基或（Cl— C4) 一院氧基一（Cl 一 C4) 一院基，較佳地爲（Cl — C8) -院基。特別佳地，化學式（有下列意義： W 爲（W 1 ); 之安全劑的符號及標誌具C C8) —Institute base, (Cl—C8) The Intellectual Property Bureau of the Ministry of Economy ’s Intellectual Property Bureau employee printed cooperatives printed halogen institute bases or (Cl—C4) —Institutional oxygen— (Cl—C4) —institution bases, preferably ( Cl — C8)-Yuan Ji. Particularly preferably, the chemical formula (has the following meanings: W is (W 1);

R ηR η

爲鹵素或（CFor halogen or (C

C 鹵院基；爲0、1、2或3，其中（R17) 爲較佳地2 ’ 4 -33- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508216 A7 ________Β7 五、發明說明（31 ) 一 C 1 2 ; R 1 8 爲化學式〇R 2 4基團； R 2 4 爲氫 (C ! 一 C 8 ) - 烷基、 ( C 1 — C 4 ) 一鹵院基、 ( C 1 — C ^ 〖）-羥烷基、 ( C 3 — C 7 ) 一環烷基 ' ( C 1 一 C 4 ) —院氧基一（ C 1 -C 4 ) 一院基或二 -( C 1 一 C 2 ) -烷基矽基，較佳地（ C 1 - -C 4 ) — 烷基 9 R 2 7 爲氫、 (Cl- C 8 )— 烷基、 ( C 1 一 C 4 ) — 鹵院基或 ( C3 — C7)—環烷基，較佳地爲氫或 ( (請先閱讀背面之注意事項再 R i I 本頁) c i _ C 4 ) 一烷基，及訂---------線. R 2 6 爲氫、（Cl — Cs) —院基、（Cl 一 C4) 一鹵院基、（Cl— C4) —經基院基、（C3—C7) — 環烷基、（Ci — c4) —烷氧基一（C2 — C4) -烷基或三—（Ci — Cz) -烷基矽基，較佳地爲氫或（ c i — C 4 ) 一烷基。亦特別佳地，包含化學式（I I )之安全劑的除草劑組合物其符號及標誌具有下列意義：經濟部智慧財產局員工消費合作社印製 W 爲（W 2 ); -l·.. R 1 7 爲鹵素或（Ci—C2) —鹵烷基； η 爲0、1、2或3，其中（R17) η，爲較佳地2 ’ 4 -C 1 2 ； R 1 8 爲化學式OR24基團； R 2 4 爲氫、（Cl — C8) - 院基、（Cl 一 C4) 一鹵烷基、（Ci— C4) 一羥烷基、（c3 - C7) -環本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公β -34- ' 508216 A7 B7 五、發明說明（32) 院基、（Cl 一 C4 —院氧基）—（Cl— C4)—院基或三一（Ci—C2) -烷基一矽基，較佳地爲（Ci 一 C 4 )—烷基，及 R 2 7 爲氯、（Cl— C8) —院基、（Cl— C4) — 鹵烷基、（C 3 - C 7 ) -環烷基或苯基，較佳地爲氫或（Ci— C4) —烷基。亦特別佳地，化學式（I I )之安全劑的符號及標誌具有下列意義： W 爲（W 3 ); R 1 7 爲鹵素或（Ci— C2) —鹵院基； η’爲0、1、2或3，其中（尺17)^較佳地爲2，4 -C 1 2 ； R 1 8 爲化學式OR24基團； R 2 4 爲氯、（Cl — C8) —院基、（Cl— C4) — 鹵烷基、（Ci— C4) —羥基烷基、（C3 — C7) -環院基、（Cl — C4) —院氧基—（Cl 一 C4) — 烷基或三一（Ci—Cs) -烷基矽基，較佳地爲（ C 1 — C 4 )—院基’及 R 2 8 爲（Cl— C8)—院基或（Cl— C4)—鹵院基，較佳地爲C 1 一鹵院基。亦特別佳地，化學式（I I )之安全劑的符號及標誌具有下列意義： W 爲（W 4 ); R 1 7 爲鹵素、硝基、（C^— C4) —烷基、（Ci — 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再 I · I 本頁 -------訂---------線- 經濟部智慧財產局員工消費合作社印製 -35- 508216 A7 _____B7 _ ' '~--- 五、發明說明（33 ) c2)_鹵烷基，較佳地爲CF3、或（Γ 、、匕 1 — C 4 ) 一院氧基； η ’ 爲〇、1、2 或 3 ; m ’爲〇或1 ; R 1 8 爲化學式OR24基團； R24 爲氫、（Cl 一 C4)—院基、殘基〜 v C 1 — C4) —院基、（Cl 一 C4) 一院氧基幾碁_(Ci — c4)—院基，較佳地（Ci— c〇一烷氧基—c〇 —CH2 —、（Cl— C4) 一院氧基一 ( ch3)(h)——ho—co—ch〜^h〇一c〇 -C ( C Η 3 ) (Η) —，及 R 2 9 爲氫、（Ci — C4) 一院基、（C! 、 1 〜C 4 ) 一鹵院基、（C 3 - C 7 )—環院基或未經取代或由一個或多個選自鹵素、（Cl — C4) —院基、f V C 1 ~ C 4 )一鹵垸基、硝基、氰基及（Cl 一 C4)〜院氧基基團取代的苯基。接下來的化合物基團特別地合適使用於具除草;彳生、活，性物質的化學式（I )之安全劑： a )二氯苯基吡唑啉- 3 -羧酸型式的化合物（即化學式 (II)，其中 W=(W1)及（R17)n，=2，4 一 C 1 2 )，較佳地化合物諸如1 一（ 2，4 一二氯苯基）一 5 —（乙氧基羰基）一5 —甲基一 2 —吡唑啉一 3 —羧酸乙酯（II 一 1)，及相關的化合物如描述於W0 — A 9 1/07874中的那些；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -36: " (請先閱讀背面之注意事項再 I I I 丨 I I I 訂·！1!! . 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（34) b)二氯苯基吡唑羧酸衍生物（即化學式（I I)，其中 W=(W2)&(R17)n，=2，4 — Cl2)，較佳地化合物諸如1 一（2，4 —二氯苯基）一 5 -甲基—吡唑—3 —羧酸乙酯（I I— 2) 、1— (2， 4 —二氯苯基）一 5 -異丙基吡唑一 3 -羧酸乙酯（ II— 3) 、1— (2，4 一二氯苯基）一 5 -（1 ，1 一二甲基乙基）吡唑一3 —羧酸乙酯（I 1一4 )、1 一（2，4 一二氯苯基）一 5 -苯基吡唑一 3 -羧酸乙酯（I 1 一 5)及相關的化合物如描述於 EP - A - 〇 3 3 3 131 及 ΕΡ-Α-0 2 6 9 8 0 6中的那些。 c )三唑羧基的型式之化合物（即化學式（I I )，其中 W= (W3)及（R17) n，=2，4 — Cl2)，較佳地化合物諸如fenchlorazol，即1 一（2，4 一二氯苯基）一 5 —三氯甲基一（1H) — 1，2，4 一三唑一 3 -羧酸乙酯（I I 一 6 )，及相關的化合物（參見 EP — A - 0174 562 及 EP-A - 0 3 4 6 6 2 0 )； d) 5-苄基一或5-苯基一2-異惡唑啉一3-羧酸型式或5，5_二苯基一 2 -異惡唑啉一 3 -羧酸型式之化合物（其中W = ( W 4 ))，較佳地化合物諸如 5 -（2，4 —二氯苄基）—2 -異惡唑啉—3 -羧酸乙酯（I 1一7)或5 -苯基一 2 —異惡唑啉一 3 一羧酸乙酯（ I I 一 8 )及相關的化合物如描述於本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再本頁) 經濟部智慧財產局員工消費合作社印製 -37· 508216 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（35) W〇一 A— 9 1/08202中的那些，或5 ，5 — 二苯基一 2 —異惡唑啉—羧酸乙酯（I I 一 9 )或5 ，5 -二苯基一 2 —異惡唑啉一羧酸正一丙酯（I I —10)或5 — (4 -氟/苯基）一 5 -苯基—2 -異惡唑啉一 3 —羧酸乙酯（II 一 11)，如描述於 W〇一A — 9 5/07 89 7中的那些。 e ) 8 -喹啉氧基醋酸型式的化合物，例如化學式（ I I I)的那些其中（R19)n，=5 — Cl 、R20 = 〇R 2 4及T = C Η 2，較佳地化合物有 (5 —氯一 8 —喹啉氧基）醋酸1—甲酯（I I I 一 1 )， (5 —氯一8 —喹啉氧基）醋酸1，3 —二甲基—丁 —1 一基酯（III 一 2) ’ (5 —氯一 8 -喹啉氧基）醋酸4 一烯丙氧基丁酯（ I I I — 3 )， (5 -氯一 8 -喹啉氧基）醋酸1 一烯丙氧基丙一 2 —基酯（I I I 一 4 )， (5 —氯—8 -卩奎啉氧基）醋酸乙酯（1 1 1 一 5) (5 —氯一 8 —喹啉氧基）醋酸甲酯（1 1 1 一 6) ， (5 -氯—8 —喹啉氧基）醋酸烯丙酯（1 1 1 一7 )， (5 —氯—8 —喹啉氧基）醋酸2 -（2 -亞丙院亞 (請先閱讀背面之注意事項 — --- 再本頁) 訂---------線 Γ · 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -38 - 508216 A7 B7 五、發明說明（36 ) 胺氧基）一1一乙酯（111—8)， (5 —氯一 8 —喹啉氧基）醋酸2 -氧—丙一 1 一基酯（I I I 一 9)及相關的化合物如描述於EP — A -〇 8 6 0 750、EP — A — 〇 094 349 及 EP 一 A — 〇 191 736 或 EP — A - 〇 4 9 2 3 6 6 中的那些。 f) (5—氯一8-喹啉氧基）丙二酸型式的化合物，即化學式（I I I)，其中（R19)n，=5 — C1、 r20=〇r24、T = (C〇〇一烷基）一，較佳地化合物（5 -氯一 8 -喹啉氧基）丙二酸二乙酯、（5-氯一8-喹啉氧基）丙二酸二烯丙酯、（5 -氯一 8 —喹啉氧基）丙二酸甲乙酯及相關的化合物如描述於ΕΡ—Α—0 582 198中的那些。 g )二氯乙醯胺型式的化合物，即化學式（I V )，較佳地： N，N -二烯丙基—2，2 -二氯乙醯胺（dichlormid ，從 US — A 4，137，070)， 4 —二^乙醯基一3，4 —二氫一3 —甲基一2H — 1，4 —苯肼惡嗪（benoxacor，從 EP 0 1 4 9 9 7 4 )，C Halogen base; 0, 1, 2 or 3, of which (R17) is preferably 2 '4 -33- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 508216 A7 ________ Β7 V. Description of the invention (31)-C 1 2; R 1 8 is a group of chemical formula 〇 2 2; R 2 4 is hydrogen (C!-C 8) -alkyl, (C 1-C 4) (C 1-C ^ 〖)-hydroxyalkyl, (C 3-C 7) monocycloalkyl '(C 1-C 4)-oxo one (C 1-C 4) one oxo or two -(C 1 -C 2) -alkylsilyl, preferably (C 1--C 4) -alkyl 9 R 2 7 is hydrogen, (Cl- C 8) -alkyl, (C 1-C 4) — halogenated or (C3 — C7) —cycloalkyl, preferably hydrogen or ((please read the notes on the back before R i I page) ci _ C 4) an alkyl group, and order --------- line. R 2 6 is hydrogen, (Cl — Cs) — courtyard, (Cl — C4) — halogen courtyard, (Cl — C4) — via courtyard, (C3 — C7) —cycloalkyl, (Ci — c4) —alkoxy- (C2 — C4) -alkyl or tri- (Ci — Cz) -alkane Silicon based, preferably hydrogen or a (c i - C 4) an alkyl group. It is also particularly preferable that the symbol and mark of the herbicide composition containing the safener of the chemical formula (II) have the following meanings: W printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is (W 2); -l · .. R 1 7 is halogen or (Ci-C2) -haloalkyl; η is 0, 1, 2 or 3, wherein (R17) η is preferably 2 '4 -C 1 2; R 1 8 is a group of chemical formula OR24 ; R 2 4 is hydrogen, (Cl — C8)-courtyard, (Cl-C4) monohaloalkyl, (Ci-C4)-hydroxyalkyl, (c3-C7)-ring paper standard applicable to Chinese national standards (CNS) A4 specifications (210 X 297 male β -34- '508216 A7 B7 V. Description of the invention (32) courtyard, (Cl-C4-courtyard oxygen)-(Cl-C4)-courtyard or Trinity ( Ci—C2) —alkyl—silyl, preferably (Ci—C 4) —alkyl, and R 2 7 is chlorine, (Cl—C8) — courtyard, (Cl — C4) — haloalkyl (C 3 -C 7) -cycloalkyl or phenyl, preferably hydrogen or (Ci-C4) -alkyl. Also particularly preferably, the symbols and signs of the safener of formula (II) have the following meanings : W is (W 3); R 1 7 is halogen or (Ci— C2) —Huangyuanji; η ′ is 0, 1, 2 or 3, wherein (footer 17) ^ is preferably 2,4-C 1 2; R 1 8 is a group of chemical formula OR24; R 2 4 is chlorine, ( Cl — C8) — courtyard, (Cl — C4) — haloalkyl, (Ci — C4) — hydroxyalkyl, (C3 — C7) — cyclic courtyard, (Cl — C4) — courtyard — —Cl -C4)-alkyl or tri- (Ci-Cs) -alkylsilyl, preferably (C 1-C 4) -yuan 'and R 2 8 is (Cl- C8) -yuan or Cl— C4) —halogenated radical, preferably C 1 -halogenated radical. Also particularly preferably, the symbols and signs of the safener of chemical formula (II) have the following meanings: W is (W 4); R 1 7 Halogen, nitro, (C ^ —C4) —alkyl, (Ci — This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before I · I This page ------- Order --------- Line-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-35- 508216 A7 _____B7 _ '' ~ --- V. Description of the invention (33 ) c2) _haloalkyl, preferably CF3, or (Γ,, d 1-C 4) a group of oxygen; η 'is 1, 2 or 3; m ′ is 0 or 1; R 1 8 is a group of the formula OR24; R24 is hydrogen, (Cl-C4) —a radical, a residue ~ v C 1 — C4) —a radical, (Cl A C4) a compound of oxygen — (Ci — c4) — a radical, preferably (Ci — c〇-alkoxy — c 0 — CH2 —, (Cl — C4) a compound of oxygen — (ch3 ) (h) —— ho-co-ch ~ ^ h〇-c〇-C (C Η 3) (Η) —, and R 2 9 is hydrogen, (Ci — C4) Yiyuanji, (C !, 1 ~ C 4) a halogen compound, (C 3-C 7) -ring compound or unsubstituted or one or more selected from halogen, (Cl-C4)-compound, f VC 1 ~ C 4 ) A halofluorenyl group, a nitro group, a cyano group, and (Cl-C4) ~ phenyl group substituted with an oxy group. The following compound groups are particularly suitable for use as safeners of the formula (I) with herbicidal, bioactive, and sexual substances: a) Compounds of the formula dichlorophenylpyrazoline 3-carboxylic acid (ie chemical formula (II), wherein W = (W1) and (R17) n, = 2,4—C 1 2), preferably a compound such as 1— (2,4—dichlorophenyl) —5— (ethoxy (Carbonyl) -methyl 5-methyl-2-pyrazoline-3-carboxylic acid ethyl ester (II-1), and related compounds such as those described in WO-A 9 1/07874; this paper size applies to China Standard (CNS) A4 specification (210 X 297 mm) -36: " (Please read the precautions on the back before ordering III 丨 III! 1 !!. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 508216 A7 B7 V. Description of the invention (34) b) Dichlorophenylpyrazole carboxylic acid derivative (that is, chemical formula (II), where W = (W2) & (R17) n, = 2, 4 — Cl2), preferably Compounds such as 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylic acid ethyl ester (II-2), 1- (2,4-dichlorophenyl) -5- Isopropylpyrazole 3 -carboxy Ethyl ester (II-3), 1- (2,4-dichlorophenyl) -5- (1,1-dimethylethyl) pyrazole-3-carboxylic acid ethyl ester (I1-4), 1- (2,4-dichlorophenyl)-5-phenylpyrazole- 3-carboxylic acid ethyl ester (I 1 -5) and related compounds as described in EP-A-〇3 3 3 131 and EP -Those of A-0 2 6 9 8 0 6. c) a compound of the form of a triazole carboxyl group (that is, chemical formula (II), wherein W = (W3) and (R17) n, = 2, 4—Cl2), preferably a compound such as fenchlorazol, namely 1- (2,4 (Dichlorophenyl) -5-trichloromethyl- (1H) -1,2,4-triazole- 3-carboxylic acid ethyl ester (II-6), and related compounds (see EP — A-0174 562 and EP-A-0 3 4 6 6 2 0); d) 5-benzyl- or 5-phenyl- 2-isooxazoline- 3-carboxylic acid type or 5,5-diphenyl- 2 -Isoxazoline-3 -carboxylic acid type compounds (where W = (W 4)), preferably compounds such as 5-(2,4-dichlorobenzyl) -2-isoxazoline-3- Ethyl carboxylate (I 1-7) or 5-phenyl-1 2-isoxazoline-3 Ethyl carboxylate (II-8) and related compounds as described in this paper apply Chinese National Standard (CNS ) A4 size (210 X 297 mm) (Please read the precautions on the back before printing this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-37 · 508216 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Invention Description (35) W〇一 A— 9 1/08202, or 5,5-diphenyl-2-isoxazoline-carboxylic acid ethyl ester (II-9) or 5,5-diphenyl-2-isoxazoline-carboxylic acid N-propyl acid ester (II-10) or 5- (4-fluoro / phenyl) -5-phenyl-2-isoxazoline-3 ethyl carboxylate (II-11) as described in W 〇 A — 9 5/07 89 7. e) 8-quinolinoxyacetic acid type compounds, such as those of formula (III) wherein (R19) n, = 5-Cl, R20 = 0R2 4 and T = C Η 2, preferably the compounds are ( 5-chloro-8-quinolinyloxy) acetic acid methyl ester (III-1), (5-chloro-8-quinolinyloxy) acetic acid 1,3-dimethyl-butane-1yl ester ( III-2) '(5-chloro-8-quinolinoxy) acetate 4 monoallyloxybutyl (III-3), (5-chloro-8-quinolinoxy) acetate 1 monoallyloxy Propyl 2-yl ester (III-4), ethyl (5-chloro-8-quinolinolyloxy) acetate (1 1 1-5) (5-chloro-8-quinolinyloxy) methyl acetate Esters (1 1 1-6), (5-chloro-8-quinolinoxy) allyl acetate (1 1 1-7), (5-chloro-8-quinolinoxy) acetate 2-(2 -Asian Academy of Fine Arts (Please read the precautions on the back --- --- on this page) Order ---------- Line Γ · This paper size applies to China National Standard (CNS) A4 (210 X 297) (Mm) -38-508216 A7 B7 V. Description of the invention (36) Aminooxy) 1-ethyl ester (111-8), (5-chloro-8 Quinolinyloxy) acetic acid 2-oxo-propanyl 1-yl ester (III-9) and related compounds are described in EP-A-0086 0 750, EP-A-〇094 349 and EP-A- 〇191 736 or EP — A-〇 4 9 2 3 6 6. f) (5-chloro-8-quinolinyloxy) malonic acid type compound, namely chemical formula (III), where (R19) n, = 5-C1, r20 = 〇r24, T = (C〇〇一Alkyl) mono, preferably compound (5-chloro-8-quinolinoxy) diethyl malonate, (5-chloro-8-quinolinoxy) diallyl malonate, (5 -Chloro-8-quinolinyloxy) malonate and related compounds such as those described in EP-A-0 582 198. g) a compound of the dichloroacetamide type, namely chemical formula (IV), preferably: N, N-diallyl-2,2-dichloroacetamide (dichlormid, from US-A 4,137, 070), 4-di ^ ethylfluorenyl-3,4-dihydro-1,3-methyl-1 2H-1,4-phenylhydrazine (benoxacor, from EP 0 1 4 9 9 7 4),

Nl，N2 —二烯丙基一 N2 —二氯乙醯基甘氨酸醯胺（DKA— 24，從 HU 2 1 4 3 8 2 1 )， 4 —二氯乙醯基—1 — oxa — 4 — a z a —螺〔4 ，5〕癸烷（AD — 67)，本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） · 39 - (請先閱讀背面之注意事項再 m. I I ! I I I 訂-— — — — — — — . 頁) 經濟部智慧財產局員工消費合作社印製 508216 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（37) 2，2 —二氯一 N —（1，3 —二茂院一 2 —基甲基 )—N— (2 -丙烯基）乙醯胺（PPG — 1292)， 3_二氯乙醯基一 2，2，5 —三甲基惡唑烷， 3 —二氯乙醯基一 2，2 —二甲基—5 -苯基惡唑烷， 3_二氯乙醯基一 2，2 —二甲基一 5 —（2 —噻吩基）惡唑烷， 3 —二氯乙醯基一5 —（2 —咲喃基）一 2，2 —二甲基惡 11 坐院（furilazole，MON 1 3 9 0 0 )， 1 一二氯乙醯基一六氫一 3，3，8 a —三甲基卩比咯並〔1，2 — a〕嘧定一 6 ( 2H) —酮（dicyclonon， BAS 1 4 5 1 3 8 )，基團B ( b )之化合物，較佳地爲 1 ，8 _萘二甲酸酐，二苯基甲氧基醋酸甲酯，氰基甲氧基亞胺基（苯基）乙腈（cyometrinil)， 1，3 —二茂烷一 2 —基甲氧基亞胺基（苯基）乙腈 (oxabetrinil )， 4,一氯一 2，2，2 —三氟乙醯苯〇一 1 ，3 —二茂院一 2 _ 基甲基！亏（fluxofenim)， 4，6 —二氯一 2_ 苯基嚼陡（fenclorim)， 2 -氯—4 —三氟甲基一 1，3 —噻唑一 5 —羧酸苄鹽（flurazole )， 2 —二氯甲基一 2 —甲基一 1 ’ 3 —二茂烷（MG — 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -40 - -11 訂 ------ (請先閱讀背面之注意事項再d寫本頁) I 襄寫太 508216 A7 _B7_ 五、發明說明（38 ) 19 1)， N — (4 -甲基苯基）一Ν’一（1—甲基—1—苯基乙基）尿素（dymrone)， 1 一〔4 一（N — 2 —甲氧基苯甲醯氨磺醯基）苯基〕一 3 —甲基尿素， 1 一〔4 一（N — 2 —甲氧基苯甲醯氨磺醯基）苯基〕一3，3 —二甲基尿素， 1_〔4 — (N — 4，5 —二甲基苯甲醯氨磺醯基）苯基〕一 3 —甲基尿素， 1—〔4 一（N —萘甲醯基氨磺醯基）苯基〕一 3， 3 —二甲基尿素， (2，4 —二氯苯氧基）醋酸（2，4 — D)， (4 一氯苯氧基）醋酸， (R，S) — 2 —（4 一氯—對一甲苯氧基）丙酸（ mecoprop)， 4_ (2，4 —二氯苯氧基）丁酸（2，4 — DB) (4一氯一對—甲苯氧基）醋酸（MCPA)， 4— (4 一氯一對一甲苯氧基）丁酸， 4— (4 一氯苯氧基）丁酸， 3，6 —二氯一 2 —甲氧基安息香酸（麥草畏）， 3，6 —二氯一2 —甲氧基安息香酸1 一（乙氧基羰基）乙酯（lactidichlor)，及其鹽類及酯類，較佳地爲（Ci—Cs)。本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） :41 - (請先閱讀背面之注意事項再 -1. 本頁： •線· 經濟部智慧財產局員工消費合作社印製 508216 A7 ______B7五、發明說明（39 ) 再者較佳的安全劑爲化學式（V)之化合物或其鹽類，其中 R3。爲氬、（Ci— C6) —烷基、（C3— C6) -環烷基、呋喃基或噻吩基，其中最後提及的4個基團中每個爲未經取代或由一個或多個選自鹵素、（Ci-C4) 一烷氧基、鹵—（Cl— c6) —烷氧基及（Cl - C4) -烷硫基取代物取代及，於環狀基團的實例中，亦爲（Cl — C4) 一院基及（Cl 一 C4) 一鹵院基 (請先閱讀背面之注意事項再 --- 麵本頁)Nl, N2 —diallyl-N2 —dichloroethenylglycine amide (DKA-24, from HU 2 1 4 3 8 2 1), 4 —dichloroethenyl — 1 — oxa — 4 — aza —Spiro [4,5] decane (AD — 67), this paper size applies Chinese National Standard (CNS) A4 (210 x 297 mm) · 39-(Please read the precautions on the back before m. II! Order III — — — — — — — —. Page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 Printed by the Employee Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (37) 2, 2-Dichloroa N — (1,3 —Dimethylamine — 2-methyl —) —N — (2-propenyl) acetamidamine (PPG — 1292), 3-dichloroethenyl — 2,2,5 —tri Methyloxazolidine, 3-dichloroacetamidino-2,2-dimethyl-5 -phenyloxazolidine, 3-dichloroacetamidino-1,2,2-dimethyl-5- (2 —Thienyl) oxazolidine, 3-dichloroethenyl-5— (2-pyranyl) —2,2-dimethyloxa 11 (furilazole, MON 1 3 9 0 0), 1 1 Dichloroethenyl-hexahydro-3, 3, 8 a —Trimethylpyrene [1,2, a] pyridin-6 (2H) —one (dicyclonon, BAS 1 4 5 1 3 8), a compound of group B (b), preferably 1 , 8-naphthalenedicarboxylic acid anhydride, diphenylmethoxymethyl acetate, cyanomethoxyimino (phenyl) acetonitrile (cyometrinil), 1,3-dichloromethylene-2-ylmethoxy Amino (phenyl) acetonitrile (oxabetrinil), 4, monochloro-2, 2, 2, 2-trifluoroacetamidobenzene 1-1, 3-dimethylene 2-methyl group! Fluxofenim, 4,6-dichloro-2-2-phenyl fenclorim, 2-chloro-4-trifluoromethyl-1,3-thiazole-5, carboxylic acid benzyl salt (flurazole), 2 — Dichloromethyl-1, 2-methyl-1, 1-, 3-dioxane (MG — This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -40--11 order ----- -(Please read the notes on the back before writing this page) I write Matthew 508216 A7 _B7_ V. Description of the Invention (38) 19 1), N — (4-methylphenyl) —N ′ — (1— Methyl-1-phenylethyl) urea (dymrone), 1- [4-((N-2—methoxybenzylsulfamoyl) phenyl] -3-methylurea, 1— [4 Mono (N-2 -methoxybenzylsulfamoylsulfonyl) phenyl] -3,3-dimethylurea, 1_ [4-(N-4,5 -dimethylbenzylsulfoniumsulfonyl) Phenyl] phenyl 3-methylurea, 1- [4-mono (N-naphthylmethylsulfamoyl) phenyl] phenyl 3,3-dimethylurea, (2,4-dichlorobenzene (Oxy) acetic acid (2,4 — D), (4 monochlorophenoxy) acetic acid, (R, S) — 2- (4-chloro-p-tolyloxy) propanoic acid (mecoprop), 4- (2,4-dichlorophenoxy) butyric acid (2,4—DB) (4-chloro-p-tolyloxy) ) Acetic acid (MCPA), 4- (4-chloro-toluene-tolyloxy) butanoic acid, 4- (4-chloro-chlorophenoxy) butyric acid, 3,6-dichloro- 2-methoxybenzoic acid ( Dicamba), 3,6-dichloro-2-methoxybenzoic acid 1- (ethoxycarbonyl) ethyl (lactidichlor), and its salts and esters, preferably (Ci-Cs). This paper size applies to China National Standard (CNS) A4 (210 X 297 mm): 41-(Please read the precautions on the back before -1. This page: • Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 ______B7 V. Description of the invention (39) Furthermore, the preferred safener is a compound of the formula (V) or a salt thereof, in which R3 is argon, (Ci-C6) -alkyl, (C3-C6)- Cycloalkyl, furyl or thienyl, where each of the last four groups mentioned is unsubstituted or consists of one or more selected from halogen, (Ci-C4) -alkoxy, halo- (Cl — C6) —alkoxy and (Cl-C4) -alkylthio substituents and, in the case of cyclic groups, also (Cl — C4) a radical and (Cl-C4) a halogen radical (Please read the precautions on the back first --- this page)

R R 3 3 ，素氫鹵爲爲鹵R R 3 3, the halogen is halogen

CC

C C X/V I 鹵基烷C C X / V I haloalkane

CC

c C 基、 ( 鑛基、基氧基氧烷氧烷 _ 烷 Ic C group, (mineral group, alkoxy group, alkoxy group, alkoxy group_alkane I

CC

C 或C or

CC

C 烷C alkane

C 1C， 1彳基 C 、羰 {基基、醯烷基磺 I 烷基} C /IV 素鹵爲地佳較C 1C, 1 fluorenyl C, carbonyl {yl, sulfanylsulfonyl I alkyl} C / IV halogen is better than

C 基甲氟三如諸基烷鹵 ---- 訂 ----I! 線- C /(\C-based methyl fluoride is trialkyl halide ---- order ---- I! Line-C / (\

C C I 1 C I 鹵 Λ 基氧烷氧烷基C C I 1 C I halo Λ-oxyloxyalkoxyalkyl

CC

C C 或基羰基氧烷C C or carbonylcarbonyloxane

C 烷經濟部智慧財產局員工消費合作社印製C-Lane Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

R R 3 3 3 4 ,, 素基氫鹵 _ 爲爲磺基 C Γ\R R 3 3 3 4, the prime hydrogen halide is sulfo C Γ \

C C ✓(V I 鹵基烷C C ✓ (V I haloalkane

4 6 c C 基 - 苯鹵、、基基烷烷環4 6 c C-Benzyl halide, alkyl alkane ring

CC

C /IV C I IX C /1\ 基 VJ Π y f 11 uC / IV C I IX C / 1 \ base VJ Π y f 11 u

CC

C C Γν 基硫烷 4 1 基、氧基烷氧 I 烷} C /ί\ 氰C C Γν-based sulfane 4 1 group, oxyalkoxy I-alkane} C / ί \ cyanide

C 基烷 C Γν 基醯磺基烷C-based alkane C Γν-based sulfonane

C 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -42 - j^216 A7 、^ -----B7 五、發明說明（4〇 ) )一烷氧基羰基或（Ci—co -烷基羰基，較佳地爲鹵素、（CX — C4)〜烷基、（Cl—C4) 一鹵烷基諸如三氟甲基、鹵（Ci—Cd) —烷氧基、（Cl . — C4) 一烷氧基或（Ci—Cd) —烷硫基， n .爲0，1或2及 t 爲1或2。再者較佳的爲化學式（V I )之安全劑，其中 x 3 爲 C Η ; R 3 5 爲氫、（Ci—Ce) —烷基、（c3 — c6) 一環烷基、（C2 - c6) -烯烴基、（C5_C6) -環燒烴基、苯基或具有上至Η個選自氮、氧及硫的雜原子之3 -至6 —圓環雜環基，最後提及的六個基團視需要爲由一個或多個相同或不同選自鹵素、（Ci一 c6)—烷氧基、（Ci— c6) 一鹵烷氧基、（Ci — c 2 )—烷基 sulfynyl、（Ci— c2)-烷基磺醯基、 (C3 - C6) -環烷基、—烷氧基羰基、（C i 一（：4)一烷基羰基及苯基的取代物取代及於環狀基團的實例中，亦爲（Ci — Ca) —烷基及（ C 1 — C 4 ) 一鹵院基； R 3 6 爲氫、（Cl— Ce)—烷基、（c2— Ce) -嫌烴基、（C2 - C6) -炔基、最後提及的三個基團視需要爲由一個或多個相同或不同選自鹵素、羥基、 (Cl—C4) —院基、（Cl 一 C4) —垸氧基及（ c i 一 C 4 ) 一烷硫基的取代物取代；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） _ _ (請先閱讀背面之注意事 aMmm ammt ί ϋ ΛΜ9 mmmmm ·ϋ ^ m. · n 1_ 1 tmme §_1 I ι 言矣k 本頁) 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（41 ) R 3 7 爲相同或不同的鹵素、（Cl 一 C4) 一鹵烷基、 (Ci — Ca)—鹵院氧基、硝基、（Ci 一 C4)—院基、（Cl 一 C4) —院氧基、（Cl— C4) —院基磺. 醯基、（Cl 一 C4) —院氧基鑛基或（Cl — C4) — 烷基羰基； R 3 8 爲氫； R 3 9 爲相同或不同的鹵素、硝基、（Ci — Cd) —烷基、（Cl 一 C4) 一鹵院基、（Cl— C4) —鹵院氧基、（C3 - C6) —環院基、苯基、（Cl 一 C4) — 院氧基、氰基、（Cl — C4) 一院硫基、（Cl 一 C4 )一院基亞磺基、（Cl 一 C4) 一院基磺醯基、（C This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -42-j ^ 216 A7, ^ ----- B7 5. Description of the invention (4〇)) Alkoxycarbonyl or (Ci-co-alkylcarbonyl, preferably halogen, (CX-C4) ~ alkyl, (Cl-C4) monohaloalkyl such as trifluoromethyl, halogen (Ci-Cd) -alkoxy, (Cl. — C4) an alkoxy group or (Ci—Cd) —alkylthio group, n. Is 0, 1 or 2 and t is 1 or 2. Still more preferably, it is a safety agent of formula (VI), Where x 3 is C Η; R 3 5 is hydrogen, (Ci-Ce) -alkyl, (c3- c6) monocycloalkyl, (C2-c6)-alkene, (C5_C6)-cycloalkane, phenyl Or 3- to 6-ring heterocyclic groups having up to 杂 heteroatoms selected from nitrogen, oxygen, and sulfur, the last six groups mentioned are optionally selected from halogen by one or more of the same or different (Ci-c6) -alkoxy, (Ci-c6) monohaloalkoxy, (Ci-c 2) -alkylsulfynyl, (Ci-c2) -alkylsulfonyl, (C3-C6) -Cycloalkyl, -alkoxycarbonyl, (C i-(: 4) -alkylcarbonyl and phenyl substituents In the examples of cyclic groups, they are also (Ci — Ca) —alkyl and (C 1 — C 4) monohalo; R 3 6 is hydrogen, (Cl — Ce) —alkyl, (c2 — Ce) —hydrocarbyl, (C2-C6) —alkynyl, the last three mentioned groups are optionally selected from one or more of the same or different from halogen, hydroxyl, (Cl—C4) — (Cl-C4) —Methoxy and (ci-C 4) -Alkylthio Substituted Substitute; This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) _ _ (Please read first Note on the back aMmm ammt ί ΛΜ9 mmmmm R 3 7 is the same or different halogen, (Cl-C4) monohaloalkyl, (Ci — Ca) —haloalkyloxy, nitro, (Ci—C4) —hospital, (Cl—C4) —hospital Oxy, (Cl—C4) —Hydroxylsulfonium, fluorenyl, (Cl—C4) —Hydroxyl or (Cl — C4) —alkylcarbonyl; R 3 8 is hydrogen; R 3 9 is the same or Different halogen, nitro, Ci — Cd) — alkyl, (Cl — C4) monohalo, (Cl — C4) — halooxy, (C3-C6) — cycloalkyl, phenyl, (Cl — C4) — halo Group, cyano group, (Cl — C4) one group thio group, (Cl one C4) one group sulfinyl group, (Cl one C4) one group sulfofluorenyl group, (

Cl — C4) 一院氧羯基或（Cl — C4) 一院基鑛基； s 爲0、1或2及 0 爲1或2。接下來的副基團在化學式（V I I )之安全劑中爲特別佳： —R48及R49爲H、（Ci— C8) -烷基、苯基、苯基—（Cl— C8) - 院基、（Cl 一 C4)—院氧基一 (Ci—Cs) —烷基、（C3 - c6) —烯烴基或（ c3 - c6) -炔基之化合物，對苯基環而言其可由F 、Cl、Br、N〇2、CN、〇CH3、 ( C 1 — C 4 )一烷基或CH3— S〇2取代； -R g爲Η之化合物； — Α爲Υ—Rh之化合物；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -44 - (請先閱讀背面之注意事項再 I · I I 本頁) --線· 經濟部智慧財產局員工消費合作社印製 508216 A7 __ B7 五、發明說明（42) 一 E爲氧之化合物；一 Q1爲CR247之化合物； —R 4 7爲氫之化合物； —m”=l及E爲氧或硫之化合物； —m ” = 〇之化合物；一於每個實例中R4〇、R41、R42、R43及R44爲氫、E 爲氧、QiCR/^A 爲 Y — Rh 及m” =1，特別地R47爲Η、Rb爲CH3及Y爲氧的那些化合物， —Q1爲CR247及m”等於0，特別地R44及R47爲氫及A爲Y — Rh，其中Rh較佳地爲甲基及Y較佳地爲氧的那些化合物。較佳的化學式（I )之除草劑基團則提供於表1至4 。於這些表中，使用的縮寫指示如下： c — Pr =環丙基 Bz =苯甲醯基 Et =乙基 Me =甲基 P h =苯基 (請先閱讀背面之注意事項再 1 - I I 本頁) 訂： --線. 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508216 經濟部智慧財產局員工消費合作社印製 A7 B7 、發明說明（43) 表 1 ( V = V 1 ): 卜(R9)q 請先閱讀背實施例案號 R R1 (R9)q 之 1-1 Η c-Pr 2-S〇2Me-4-CF3 i; 1-2 Η c-Pr 2-S〇2Me-4-Cl 飞ί 1-3 Η c-Pr 2-Cl-4-S〇2Me ί；碣‘ 1-4 Η c-Pr 2-N〇2-4-S〇2Me ): 1-5 Η c-Pr 2,4-Cl2-3-Me 1-6 Η c-Pr 2,4-Cl2 1-7 Η c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 1-8 Η c-Pr 2,4-Br2 1-9 Η c-Pr 2,4-Br2-3-〇CH2SMe 1-10 Η c-Pr 2-CFs-4-S〇2Me 1-11 Η c-Pr 2-S〇2Me-4-Br 1-12 Η c-Pr 2-Cl-3-OEt-4-S〇2Et 1-13 Η c-Pr 3,4-Cl2-S〇2Me 1-14 Η c-Pr 2-SMe-4-CF3 1-15 Η c-Pr 2-SMe-4-Br 1-16 Η c-Pr 3,4-Cl2-2-SMe 1-17 . Η c-Pr 4-SFs 1-18 COOEt c-Pr 2-S〇2Me-4-CF3 1-19 COOEt c-Pr 2-S〇2Me-4-Cl 1-20 COOEt c-Pr 2-N〇2-4-S〇2Me 1-21 COOEt c-Pr 2,4-Cl2-3-Me 1-22 COOEt c-Pr 2,4-Br2 1-23 COOEt c-Pr 2,4-Br2-3-〇CH2SMe - I I I I I 訂本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -46- 508216 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（44) 1-24 COOMe c-Pr 2-S〇2Me-4-CF3 1-25 COOMe c-Pr 2-S〇2Me-4-Cl 1-26 COOMe c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 1-27 Η 1 -Me-c-Pr 2-S〇2Me-4-CF3 ，、 i t 1-28 Η 1 -Me-c-Pr 2-S〇2Me-4-Cl B1 1-29 Η 1 -Me-c-Pr 2-Cl-4-S〇2Me ~f [ 1-30 Η 1 -Me-c-Pr 2-N〇2-4-S〇2Me 之： 1-31 Η 1 -Me-c-Pr 2,4-Cl2-3-Me 1 r 1-32 Η 1 -Me-c-Pr 2,4-Cl2 1-33 Η 1 -Me-c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 1-34 COOEt 1 -Me-c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 本 r. 1-35 COOEt 1 -Me-c-Pr 2-S〇2Me-4-CFs 1-36 COOEt 1 -Me-c-Pr 2-S〇2Me-4-Cl 1-37 COOEt 1 -Me-c-Pr 2-Cl-4-S〇2Me 1-38 COOEt 1 -Me-c-Pr 2-N〇2-4-S〇2Me 1-39 SChMe c-Pr 2-S〇2Me-4-CF3 1-40 SChMe c-Pr 2-S〇2Me-4-Cl 1-41 SOMe c-Pr 2-S〇2Me-4-CF3 1-42 SOMe c-Pr 2-S〇2Me-4-Cl 1-43 SChMe c-Pr 2-N〇2-4-S〇2Me ( 1-44 SOMe c-Pr 2-N〇2-4-S〇2Me 1-45 、 SChMe c-Pr 2-Cl-4-S〇2Me 1-46 SOMe c-Pr 2-Cl-4-S〇2Me 1-47 COOMe c-Pr 2-SOMe-4-CFs 1-48 COOEt c-Pr 2-SOMe-4-CFs 1-49 H c-Pr 2-SOMe-4-CFs 1-50 S〇2Me 1 -Me-c-Pr 2-S〇2Me-4-CF3 1-51 SOMe 1 -Me-c-Pr 2-S〇2Me-4-CF3 1-52 SChMe 1 -Me-c-Pr 2-S〇2Me-4-Cl 1-53 SOMe 1 -Me-c-Pr 2-S〇2Me-4-ClCl — C4) an oxygen-based compound or (Cl — C4) a mineral-based compound; s is 0, 1 or 2 and 0 is 1 or 2. The following secondary groups are particularly preferred among the safeners of formula (VII): —R48 and R49 are H, (Ci—C8) —alkyl, phenyl, phenyl— (Cl—C8) — (Cl-C4) —Coxy— (Ci-Cs) —alkyl, (C3-c6) —olefin or (c3—c6) —alkynyl compounds. For the phenyl ring, it can be F, Cl , Br, No2, CN, 0CH3, (C1-C4) -alkyl or CH3-S02 substitution; -R g is a compound of Η;-Α is a compound of Υ-Rh; Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -44-(Please read the notes on the back before I · II on this page) --Line · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 508216 A7 __ B7 V. Explanation of the invention (42) -E is a compound of oxygen; -Q1 is a compound of CR247; -R 4 7 is a compound of hydrogen; -m "= 1 and E is an oxygen or sulfur compound; -m" = 〇； In each example, R4〇, R41, R42, R43 and R44 are hydrogen, E is oxygen, QiCR / ^ A is Y — Rh and m ”= 1, in particular R47 is Η, Rb is CH3 And those in which Y is oxygen "—Q1 is CR247 and m" is equal to 0, especially those compounds where R44 and R47 are hydrogen and A is Y-Rh, where Rh is preferably methyl and Y is preferably oxygen. Preferred herbicide groups of formula (I) are provided in Tables 1 to 4. In these tables, the abbreviations used are indicated as follows: c — Pr = cyclopropyl Bz = benzamyl Et = ethyl Me = methyl P h = phenyl (please read the precautions on the back first and then 1-II) (Page) Order: --Line. Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 508216 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 Description of the invention (43) Table 1 (V = V 1): Bu (R9) q Please read the case number 1-1 of R R1 (R9) q in the back first 实施 c-Pr 2-S〇2Me-4- CF3 i; 1-2 Η c-Pr 2-S〇2Me-4-Cl Fly 1-3 Η c-Pr 2-Cl-4-S〇2Me ；; 碣 '1-4 Η c-Pr 2- N〇2-4-S〇2Me): 1-5 Η c-Pr 2,4-Cl2-3-Me 1-6 Η c-Pr 2,4-Cl2 1-7 Η c-Pr 2-Cl- 3-C〇2Me-4-S〇2Me 1-8 Η c-Pr 2, 4-Br2 1-9 Η c-Pr 2, 4-Br2-3-〇CH2SMe 1-10 Η c-Pr 2-CFs -4-S〇2Me 1-11 Η c-Pr 2-S〇2Me-4-Br 1-12 Η c-Pr 2-Cl-3-OEt-4-S〇2Et 1-13 Η c-Pr 3 , 4-Cl2-S〇2Me 1-14 Η c-Pr 2-SMe-4-CF3 1-15 Η c-Pr 2-SMe-4-Br 1-16 Η c-Pr 3,4-Cl2-2 -SMe 1-17. Η c-Pr 4-SF s 1-18 COOEt c-Pr 2-S〇2Me-4-CF3 1-19 COOEt c-Pr 2-S〇2Me-4-Cl 1-20 COOEt c-Pr 2-N〇2-4-S〇 2Me 1-21 COOEt c-Pr 2,4-Cl2-3-Me 1-22 COOEt c-Pr 2,4-Br2 1-23 COOEt c-Pr 2,4-Br2-3-〇CH2SMe-IIIII Paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -46- 508216 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (44) 1-24 COOMe c-Pr 2- S〇2Me-4-CF3 1-25 COOMe c-Pr 2-S〇2Me-4-Cl 1-26 COOMe c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 1-27 Η 1 -Me-c-Pr 2-S〇2Me-4-CF3, it 1-28 Η 1 -Me-c-Pr 2-S〇2Me-4-Cl B1 1-29 Η 1 -Me-c-Pr 2-Cl-4-S〇2Me ~ f [1-30 Η 1 -Me-c-Pr 2-N〇2-4-S〇2Me of: 1-31 Η 1 -Me-c-Pr 2,4 -Cl2-3-Me 1 r 1-32 Η 1 -Me-c-Pr 2,4-Cl2 1-33 Η 1 -Me-c-Pr 2-Cl-3-C〇2Me-4-S〇2Me 1-34 COOEt 1 -Me-c-Pr 2-Cl-3-C〇2Me-4-S〇2Me Ben r. 1-35 COOEt 1 -Me-c-Pr 2-S〇2Me-4-CFs 1 -36 COOEt 1 -Me-c-Pr 2-S〇2Me-4-Cl 1-37 COOEt 1 -Me-c-Pr 2-Cl-4-S〇2Me 1-38 COOEt 1 -Me-c-Pr 2 -N〇2-4-S〇2Me 1-39 SChMe c-Pr 2-S〇2Me-4-CF3 1-40 SChMe c-Pr 2-S〇2Me-4-Cl 1-41 SOMe c-Pr 2 -S〇2Me-4-CF3 1-42 SOMe c-Pr 2-S〇2Me-4-Cl 1-43 SChMe c-Pr 2-N〇2-4-S〇2Me (1-44 SOMe c-Pr 2-N〇2-4-S〇2Me 1-45, SChMe c-Pr 2-Cl-4-S〇2Me 1-46 SOMe c-Pr 2-Cl-4-S〇2Me 1-47 COOMe c- Pr 2-SOMe-4-CFs 1-48 COOEt c-Pr 2-SOMe-4-CFs 1-49 H c-Pr 2-SOMe-4-CFs 1-50 S〇2Me 1 -Me-c-Pr 2 -S〇2Me-4-CF3 1-51 SOMe 1 -Me-c-Pr 2-S〇2Me-4-CF3 1-52 SChMe 1 -Me-c-Pr 2-S〇2Me-4-Cl 1- 53 SOMe 1 -Me-c-Pr 2-S〇2Me-4-Cl

II

I 訂I order

II

A 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -47- 508216 A7 B7 五、發明說明（45 表 2(V = V2): OMnnc οA The paper size applies to the Chinese National Standard (CNS) A4 (210 x 297 mm) -47- 508216 A7 B7 V. Description of the invention (45 Table 2 (V = V2): OMnnc ο

——R4 經濟部智慧財產局員工消費合作社印製實施例案號 R2 R3 R4 (R9)q 2-1 Η Η Et 2-Cl-3-OEt-4-S〇2Et 2-2 Η Η Et 2-S〇2Me-4-CF3 2-3 Η Η Et 2-S〇2Me-4-Cl 2-4 Η Η Et 2-S〇2Me-4-Br 2-5 Η Η Et 2-CF3-4-S〇2Me 2-6 Η Η Et 2-Cl-4-S〇2Me 2-7 Η Η Et 3,4-Cl2-2-S〇2Me 2-8 Η Η Et 2-Cl-3-C〇〇Me-4-S〇2Me 2-9 Η Η Et 2,4-Cl2 2-10 Η Η Et 2-N〇2-4-S〇2Me 2-11 Η Η Et 2,4-Br2-3-〇CH2SMe 2-12 Η Η Et 2,4-Br2 2-13 Η Η Me 2-S〇2Me-4-CF3 2-14 Η Η Me 2-S〇2Me-4-Cl 2-15 Η Η Me 2,4-Br2-3-〇CH2SMe 2-16 Η Η Me 2,4-Cl2 2-17 Η Η Me 2-S〇2Me-4-Cl 2-18 Me CH2-CO-(4-Me-Ph) Me 2,4-Cl2-Cl-3-Me 2-19 Me CH2-CO-(4-Me-Ph) Me 2-S〇2Me-4-CF3 2-20 Me CH2-C〇-(4-Me-Ph) Me 2-S〇2Me-4-Cl 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）——R4 Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economics. Case No. R2 R3 R4 (R9) q 2-1 Η Η Et 2-Cl-3-OEt-4-S〇2Et 2-2 Η t Et 2 -S〇2Me-4-CF3 2-3 Η Η Et 2-S〇2Me-4-Cl 2-4 Η Η Et 2-S〇2Me-4-Br 2-5 Η Η Et 2-CF3-4- S〇2Me 2-6 Η Η Et 2-Cl-4-S〇2Me 2-7 Η Η Et 3,4-Cl2-2-S〇2Me 2-8 Η Η Et 2-Cl-3-C〇〇 Me-4-S〇2Me 2-9 Η Η Et 2,4-Cl2 2-10 Η Η Et 2-N〇2-4-S〇2Me 2-11 Η Η Et 2,4-Br2-3-〇 CH2SMe 2-12 Η Η Et 2,4-Br2 2-13 Η Η Me 2-S〇2Me-4-CF3 2-14 Η Η Me 2-S〇2Me-4-Cl 2-15 Η Η Me 2, 4-Br2-3-〇CH2SMe 2-16 Η Η Me 2,4-Cl2 2-17 Η Η Me 2-S〇2Me-4-Cl 2-18 Me CH2-CO- (4-Me-Ph) Me 2,4-Cl2-Cl-3-Me 2-19 Me CH2-CO- (4-Me-Ph) Me 2-S〇2Me-4-CF3 2-20 Me CH2-C〇- (4-Me- Ph) Me 2-S〇2Me-4-Cl This paper is sized for China National Standard (CNS) A4 (210 X 297 mm)

(請先閱讀背面之注A -48- 508216 五、發明說明（46 ) 經濟部智慧財產局員工消費合作社印製 A7 B7 2-21 Me CH2-C〇-(4-Me-Ph) Me 2,4-Br2-3-〇CH2SMe 2-22 Me CH2-C〇-(4-Me-Ph) Me 24-C12 2-23 Me CH2-C〇-(4-Me-Ph) Me 2,4-Br2 2-24 Me CH2-CO-(4-Me-Ph) Me 2-S〇2Me-4-Cl 2-25 Me CH2-C〇-(4-Me-Ph) Me 2-Cl-3-CO〇Me-4-S〇2Me 2-26 Me CH2-C〇-(4-Me-Ph) Me ' 2-N〇2-4-S〇2Me 2-27 Me S〇2-(4-Me-Ph) Me 2,4-Cl2 2-28 Me S〇2-(4-Me-Ph) Me 2,4-Br2 2-29 Me S〇2-(4-Me-Ph) Me 2,4-Cl2-3-Me 2-30 Me S〇2-(4-Me-Ph) Me 2-S〇2Me-4-CF3 2-31 Me S〇2-(4-Me-Ph) Me 2-S〇2Me-4-Cl 2-32 Me S〇2-(4-Me-Ph) Me 2,4-Br2.3-OCH2SMe 2-33 Me S〇2-(4-Me-Ph) Me 2-N〇2-4-S〇2Me 2-34 Me CH2-C〇-Ph Me 2,4-Cl2 2-35 Me CH2-CO-Ph Me 2,4-Cl2-3-Me 2-36 Me CH2-C〇-Ph Me 2-S〇2Me-4-CF3 2-37 Me CH2-C〇-Ph Me 2-S〇2Me-4-Cl 2-38 Me CH2-C〇-Ph Me 2,4-Br2-3-〇CH2SMe 2-39 Me CH2-C〇_Ph Me 2-Cl-3-COOMe-4-S〇2Me 2-40 Me CH2-C〇-Ph Me 2,4-Br2 2-41 Me CH2-C〇-Ph Me 2-N〇2-4-S〇2Me 2-42 H Bz Me 2,4-Cl2 2-43 H Bz Me 2,4-Cl2-3-Me 2-44 H Bz Me 2-S〇2Me-4-CF3 2-45 H Bz Me 2-S〇2Me-4-Cl 2-46 H Bz Me 2,4-Br2 2-47 H Bz Me 2-N〇2-4-S〇2Me 2-48 H Bz Me 2-Cl-3-C〇〇Me-4-S〇2Me 2-49 H Bz Me 2,4-Br2-3-〇CH2SMe 請先閱讀背面之注事項 I i 訂本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 49· 508216 A7 B7 五、發明說明（47) 表 3(V = V3): (R5)(Please read the note A-48-508216 on the back first. V. Invention Description (46) Printed by A7 B7 2-21 Me CH2-C〇- (4-Me-Ph) Me 2, printed by Employee Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 4-Br2-3-〇CH2SMe 2-22 Me CH2-C〇- (4-Me-Ph) Me 24-C12 2-23 Me CH2-C〇- (4-Me-Ph) Me 2,4-Br2 2-24 Me CH2-CO- (4-Me-Ph) Me 2-S〇2Me-4-Cl 2-25 Me CH2-C〇- (4-Me-Ph) Me 2-Cl-3-CO〇 Me-4-S〇2Me 2-26 Me CH2-C〇- (4-Me-Ph) Me '2-N〇2-4-S〇2Me 2-27 Me S〇2- (4-Me-Ph ) Me 2,4-Cl2 2-28 Me S〇2- (4-Me-Ph) Me 2,4-Br2 2-29 Me S〇2- (4-Me-Ph) Me 2,4-Cl2- 3-Me 2-30 Me S〇2- (4-Me-Ph) Me 2-S〇2Me-4-CF3 2-31 Me S〇2- (4-Me-Ph) Me 2-S〇2Me- 4-Cl 2-32 Me S〇2- (4-Me-Ph) Me 2,4-Br2.3-OCH2SMe 2-33 Me S〇2- (4-Me-Ph) Me 2-N〇2- 4-S〇2Me 2-34 Me CH2-C〇-Ph Me 2,4-Cl2 2-35 Me CH2-CO-Ph Me 2,4-Cl2-3-Me 2-36 Me CH2-C〇-Ph Me 2-S〇2Me-4-CF3 2-37 Me CH2-C〇-Ph Me 2-S〇2Me-4-Cl 2-38 Me CH2-C〇-Ph Me 2,4-Br2-3-〇 CH2SMe 2-39 Me CH2-C〇_Ph Me 2-Cl-3-COOMe-4-S〇2Me 2-40 Me CH2-C〇-Ph Me 2,4-Br2 2-41 Me CH2-C〇- Ph Me 2-N〇2-4-S 2Me 2-42 H Bz Me 2,4-Cl2 2-43 H Bz Me 2,4-Cl2-3-Me 2-44 H Bz Me 2-S〇2Me-4-CF3 2-45 H Bz Me 2- S〇2Me-4-Cl 2-46 H Bz Me 2,4-Br2 2-47 H Bz Me 2-N〇2-4-S〇2Me 2-48 H Bz Me 2-Cl-3-C〇〇 Me-4-S〇2Me 2-49 H Bz Me 2,4-Br2-3-〇CH2SMe Please read the notes on the back I i The size of the paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 49) 508216 A7 B7 V. Description of the invention (47) Table 3 (V = V3): (R5)

σ 經濟部智慧財產局員工消費合作社印製實施例案號 (R5)丨 R6 (R9), 3-1 OH 2-Cl-4-S〇2Me 3-2. • OH 2-N〇2-4-S〇2Me 3-3 雞 OH 2,4-Cl2 3-4 OH 2,4-Br2 3-5 • OH 2,4-Cl2-3-Me 3-6 • OH 2,4-Br2-3-〇CH2SMe 3-7 OH 2-S〇2Me-4-Cl 3-8 晒 OH 2-S〇2Me-4-CF3 3-9 霉 OH 2-S〇2Me-4-Br 3-10 • OH 2-Cl-3-COOMe-4-S〇2Me 3-11 • OH 2-NO2-4-OCF2H 3-12 4,4-(Me)2 OH 2-NO2.4-OCF2H 3-13 4,4-(Me)2 OH 2-Cl-4-S〇2Me 3-14 4,4-(Me)2 OH 2-N〇2-4-S〇2Me 3-15 4,4-(Me)2 OH 2,4-Cl2 3-16 4,4-(Me)2 OH 2-Cl-3-C〇〇Me-4-S〇2Me 3-17 4,4-(Me)2 OH 2,4-Br2-3-OCH2SMe 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 50-σ Print out the case number (R5) 丨 R6 (R9), 3-1 OH 2-Cl-4-S〇2Me 3-2. • OH 2-N〇2-4 -S〇2Me 3-3 Chicken OH 2,4-Cl2 3-4 OH 2,4-Br2 3-5 • OH 2,4-Cl2-3-Me 3-6 • OH 2,4-Br2-3- 〇CH2SMe 3-7 OH 2-S〇2Me-4-Cl 3-8 Sun OH 2-S〇2Me-4-CF3 3-9 Mold OH 2-S〇2Me-4-Br 3-10 • OH 2- Cl-3-COOMe-4-S〇2Me 3-11 • OH 2-NO2-4-OCF2H 3-12 4,4- (Me) 2 OH 2-NO2.4-OCF2H 3-13 4,4- ( Me) 2 OH 2-Cl-4-S〇2Me 3-14 4,4- (Me) 2 OH 2-N〇2-4-S〇2Me 3-15 4,4- (Me) 2 OH 2, 4-Cl2 3-16 4,4- (Me) 2 OH 2-Cl-3-C〇〇Me-4-S〇2Me 3-17 4,4- (Me) 2 OH 2,4-Br2-3 -OCH2SMe This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 50-

508216 A7B7 五、發明說明（48) 經濟部智慧財產局員工消費合作社印製 3-18 4,4-(Me)2 OH 2-S〇2Me-4-Cl 3-19 4,4-(Me)2 OH 2-S〇2Me-4-CFs 3-20 4,4_(Me)2 OH 2,4-Cl2-3-Me 3-21 4,4-(Me)2 OH 2,4-Br2 3-22 4-CH2-CH2-6 SPh 2-Cl-4-S〇2Me 3-23 4-CH2-CH2-6 SPh 2,4-Cl2-3-Me 3-24 4-CH2-CH2-6 SPh 2,4-Br2-3-OCH2SMe 3-25 4-CH2-CH2-6 SPh 2-N〇2-4-S〇2Me 3-26 4-CH2-CH2-6 SPh 2,4-Cl2 3-27 4-CH2-CH2-6 SPh 2-S〇2Me-4-Cl 3-28 4-CH2-CH2-6 SPh 2,4-Br2 3-29 4-CH2-CH2-6 SPh 2-Cl-3-C〇〇Me-4-S〇2Me 3-30 4-CH2-CH2-6 SPh 2-S〇2Me-4-CF3 3-31 5,5-(Me)2 OH 2-NO2.4.OCF2H 3-32 5,5-(Me)2 OH 2-Cl-4-S〇2Me 3-33 5,5-(Me)2 OH 2-N〇2-4-S〇2Me 3-34 5,5-(Me)2 OH 2-Cl-3-C〇〇Me-4-S〇2Me 3-35 5,5-(Me)2 OH 2,4-Cl2-3-Me 3-36 5,5-(Me)2 OH 2,4-Cl2 3-37 5,5-(Me)2 OH 2,4-Br2 3-38 5,5-(Me)2 OH 2,4-Br2-3-〇CH2SMe 3-39 5,5-(Me)2 OH 2-S〇2Me-4-Cl 3-40 5,5-(Me)2 OH 2-S〇2Me-4-CF3 i I I I II I 訂11111! -*5^ · (請先閱讀背面之注意事項再IFk本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） -51 - 508216 A7 B7五、發明說明（49 ) 表 4 : (V = V4): ο R7508216 A7B7 V. Description of the invention (48) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy 3-18 4,4- (Me) 2 OH 2-S〇2Me-4-Cl 3-19 4,4- (Me) 2 OH 2-S〇2Me-4-CFs 3-20 4,4_ (Me) 2 OH 2,4-Cl2-3-Me 3-21 4,4- (Me) 2 OH 2,4-Br2 3- 22 4-CH2-CH2-6 SPh 2-Cl-4-S〇2Me 3-23 4-CH2-CH2-6 SPh 2,4-Cl2-3-Me 3-24 4-CH2-CH2-6 SPh 2 , 4-Br2-3-OCH2SMe 3-25 4-CH2-CH2-6 SPh 2-N〇2-4-S〇2Me 3-26 4-CH2-CH2-6 SPh 2,4-Cl2 3-27 4 -CH2-CH2-6 SPh 2-S〇2Me-4-Cl 3-28 4-CH2-CH2-6 SPh 2,4-Br2 3-29 4-CH2-CH2-6 SPh 2-Cl-3-C 〇〇Me-4-S〇2Me 3-30 4-CH2-CH2-6 SPh 2-S〇2Me-4-CF3 3-31 5,5- (Me) 2 OH 2-NO2.4.OCF2H 3- 32 5,5- (Me) 2 OH 2-Cl-4-S〇2Me 3-33 5,5- (Me) 2 OH 2-N〇2-4-S〇2Me 3-34 5,5- ( Me) 2 OH 2-Cl-3-C〇〇Me-4-S〇2Me 3-35 5,5- (Me) 2 OH 2,4-Cl2-3-Me 3-36 5,5- (Me ) 2 OH 2,4-Cl2 3-37 5,5- (Me) 2 OH 2,4-Br2 3-38 5,5- (Me) 2 OH 2,4-Br2-3-〇CH2SMe 3-39 5,5- (Me) 2 OH 2-S〇2Me-4-Cl 3-40 5,5- (Me) 2 OH 2-S〇2Me-4-CF3 i III II I Order 11111!-* 5 ^ · (Please read the precautions on the back before IFk page) National Standard (CNS) A4 Specification (210 χ 297 mm) -51-508216 A7 B7 V. Description of Invention (49) Table 4: (V = V4): ο R7

ReRe

R9)q 實施例案號 R7 R8 (R9) ‘ 4-1 c-PrR9) q Example case number R7 R8 (R9) ‘4-1 c-Pr

CN :-Cl-3-OEt-4-S〇2Et 4-2 c-PrCN: -Cl-3-OEt-4-S〇2Et 4-2 c-Pr

CN 2-S〇2Me-4-CF：CN 2-S〇2Me-4-CF:

I I I I I 4-3 c-PrI I I I I 4-3 c-Pr

CN 2-S〇2Me-4-Cl 4-4 c-PrCN 2-S〇2Me-4-Cl 4-4 c-Pr

CN 2-S〇2Me-4-Br 4-5 c-PrCN 2-S〇2Me-4-Br 4-5 c-Pr

CN 2-CF3-4-S〇2Me 訂 4-6 c-PrCN 2-CF3-4-S〇2Me Order 4-6 c-Pr

CN 2-Cl-4-S〇2Me 4-7 c-PrCN 2-Cl-4-S〇2Me 4-7 c-Pr

CN 3,4-Cl2-2-S〇2Me 4-8 c-PrCN 3,4-Cl2-2-S〇2Me 4-8 c-Pr

CN 2,4-Cl2 4-9 c-PrCN 2,4-Cl2 4-9 c-Pr

CN 2,4-Br2 4-10 c-PrCN 2,4-Br2 4-10 c-Pr

CN 2-Cl-3-COOMe-4-S〇2Me 經濟部智慧財產局員工消費合作社印製 4-11 c-PrCN 2-Cl-3-COOMe-4-S〇2Me Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 4-11 c-Pr

CN 2,4-Cl2-3-Me -12 c-PrCN 2,4-Cl2-3-Me -12 c-Pr

CN 2,4-Br2-3-OCH2SMe 4-13 c-PrCN 2,4-Br2-3-OCH2SMe 4-13 c-Pr

CN 2-N〇2-4-S〇2Me 化學式（I I ) 一（ V I I )之安全劑（解毒劑）及基團（b )之化合物，例如上述所提及的基團a )至h ) 之安全劑，當於有用的莊稼植物上使用化學式（I )之具本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -52 508216 A7 __B7 經濟部智慧財產局員工消費合作社印製五、發明說明（5〇) 除草性活性物質時可減低或防止毒害植物的影響而實質上不會影響這些具除草性活性物質對有害植物功效。此允許傳統的莊稼保護產物之應用範圍相當廣泛地擴大及延伸，例如，至莊稼諸如小麥、大麥、玉蜀黍、米及其它迄今無法使用除草劑，或僅限制，的莊稼中也就是說以較低的比例及於限制的範圍。具除草性活性物質及上述提及的安全劑可一起施加（爲預拌好或利用槽混合方法）或連續的以任何所需的程序。安全劑的重量比率：具除草性活性物質可在廣泛的限制中不同及較佳地在1 : 100至100 ·· 1的範圍中，特別地從1 : 1 0至1 0 : 1。於每個實例中最理想的具除草性活性物質及安全劑的量視使用的具除草性活性物質或使用的安全劑及保持以處理的莊稼物種之型式而定，同時可於每個各別的實例中利用簡單、例行的預先實驗來測定〇根據本發明的組合物之主要應用範圍有，特別地，玉蜀黍及穀類莊稼（例如小麥、黑麥、大麥、燕麥）、米、高梁，但是亦可爲棉花及大豆，較佳地爲穀類、米及玉蜀黍。依其性質而定，根據本發明而使用的安全劑可用來預處理莊稼植物的種子（種子加工），或在播種之前倂入種子犁溝或與除草劑在植物顯現之前或之後一起施加。幼苗出土前的處理不僅包括在播種之前於耕作下的面積處理及種子已播種但是植物尙未暴露於耕作下的面積處理。較佳本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -53- (請先閱讀背面之注意事項再 » i I 本頁) 線· 508216 A7 _ B7 五、發明說明（51 ) 的連接地施加除草劑。最後，可使用槽混合或預混合。所需的安全劑之施加比例可於廣泛的限制中視指示及使用的具除草性活性物質而不同及通常的範圍每公頃從 0·001至5公斤，較佳地從0·005至0·5公斤，的活性物質。本發明因此亦關於一種從化學式（I )之除草劑的毒害植物側影響中保護莊稼植物之方法，其包括施加化學式 (II)、（III)、（IV)、（V)、（VI)、 (VI I)及/或（選擇自基團（b))的化合物之解毒有效量至植物、植物種子或在耕作下之面積，在與化學式 (I )的具除草性活性物質A之前、之後或同時。根據本發明之除草劑/安全劑組合亦可用來控制熟知或仍然在發展之遺傳工程植物莊稼中的有害植物。通常，遺傳學的植物具有特別的，優良的性質，例如抗某莊稼保護試劑、抗造成植物疾病諸如特別的昆蟲或微生物諸如真菌、細菌或病毒之植物疾病或病原體。其它特別的性質則關於例如，所獲得的物質就量、品質、儲存性質、組合物及特定的構成而論。因此，已知的遺傳學植物具有增加的澱粉成分或改良的澱粉品質，或獲得具有不同的脂肪酸組合物物質的那些。可將根據本發明之組合物經濟地使用在重要的有用植物及觀賞植物之遺傳學莊稼上，例如穀類諸如小麥、大麥、黑麥、燕麥、稗、米、樹薯及玉蜀黍或其它莊稼如糖甜菜、棉花、大豆、油菜、馬鈴薯、蕃茄、豌豆及其它型式本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -54 - (請先閱讀背面之注意事項 --__I 本頁)CN 2-N〇2-4-S〇2Me compounds of formula (II) one (VII) safener (antidote) and group (b), such as the groups a) to h) mentioned above Safener, when using chemical formula (I) on useful crop plants, the paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -52 508216 A7 __B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs System 5. Description of the invention (50) The herbicidal active substance can reduce or prevent the effects of toxic plants without substantially affecting the efficacy of these herbicidal active substances on harmful plants. This allows the application of traditional crop protection products to be expanded and extended quite extensively, for example, to crops such as wheat, barley, maize, rice, and other crops where hitherto no herbicides have been used, or only restricted, that is to say at a lower level The ratio is within the limits. The herbicidally active substance and the above-mentioned safener can be applied together (for pre-mixing or using a tank mixing method) or continuously in any desired procedure. The weight ratio of the safener: the herbicidally active substance may differ in a wide range of limits and preferably in the range of 1: 100 to 100 ·· 1, particularly from 1:10 to 10: 1. The optimal amount of herbicidal active substance and safener in each example depends on the type of herbicidal active substance or safener used and the type of crop species maintained for treatment, and can be individually In the examples, simple, routine preliminary experiments are used to determine the main applications of the composition according to the present invention. In particular, maize and cereal crops (such as wheat, rye, barley, oats), rice, sorghum, but It can also be cotton and soybeans, preferably cereals, rice and maize. Depending on its nature, the safener used according to the invention can be used to pre-treat the seeds of crop plants (seed processing), or to be planted in seed furrows before sowing or applied with or without herbicides before or after plant emergence. Pre-emergence treatments for seedlings include not only area treatment under cultivation prior to sowing and area treatment where seeds have been sown but plant pupae have not been exposed to cultivation. It is better that the paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) -53- (Please read the precautions on the back »i I on this page) Line · 508216 A7 _ B7 V. Description of the invention ( 51). Finally, tank mixing or premixing can be used. The required application rate of the safener can vary among a wide range of indications and the herbicidally active substance used and usually ranges from 0.001 to 5 kg per hectare, preferably from 0.005 to 0.5 Kg of active substance. The invention therefore also relates to a method for protecting crop plants from the side effects of poisoning plants of a herbicide of the chemical formula (I), which comprises applying chemical formulae (II), (III), (IV), (V), (VI), (VI I) and / or (selected from group (b)) a detoxifying effective amount of the plant, plant seed or area under cultivation, before and after contact with the herbicidally active substance A of chemical formula (I) Or both. The herbicide / safener combination according to the present invention can also be used to control harmful plants in crops of genetically engineered plants that are well known or still under development. Generally, genetic plants have special, excellent properties, such as resistance to crop protection agents, plant diseases or pathogens that cause plant diseases such as special insects or microorganisms such as fungi, bacteria, or viruses. Other special properties are concerned, for example, with respect to the substance obtained in terms of quantity, quality, storage properties, composition and specific composition. Thus, known genetic plants have increased starch content or improved starch quality, or obtain those with different fatty acid composition substances. The composition according to the invention can be used economically on genetic crops of important useful plants and ornamental plants, such as cereals such as wheat, barley, rye, oats, loquat, rice, cassava and maize or other crops such as sugar Beet, cotton, soybean, rapeseed, potato, tomato, pea and other types The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -54-(Please read the precautions on the back --__ I page)

------訂---------線L 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（52 ) 的蔬菜。當根據本發明其它莊稼上觀察到遺傳學莊稼上的特可控制的雜草系列傳學的莊稼可抵抗學的莊稼植物之生本發明因此亦傳學的莊稼植物中之組合物應用於遺傳學的對有害植物之影響經常會定影響之問題，例如改變，改變可使用的施加比例的除草劑具有好的相容性長及生產。關於使用根據本發明之組的有害植物。莊稼上時，於伴隨著應用於或明確擴大之，較佳地與遺，及改變遺傳合來控制於遺------ Order --------- Line L Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 B7 V. Vegetable Description of Invention (52). When genetics is observed on other crops according to the invention Genetically controlled weeds on crops. Crops resistant to crops. Plants resistant to crops. The present invention therefore applies the composition in crops to genetics. The impact on harmful plants often determines the impact issues, such as changing, changing the application rate of the herbicide that can be used, has good compatibility and long production. Concerning the use of harmful plants according to the group of the invention. When crops are planted, they are preferably used in conjunction with or explicitly expanded, preferably in combination with inheritance, and altered heredity to control inheritance.

化學式（I I I ) 經濟部智慧財產局員工消費合作社印製 (V I I )及基團（b )之安全 I)之具除草依特定之生物方之實施例有劑及其與一種或多種上述提及的化學式（I 物可以不同的方法配備，參數而定。可能的合適配性活性物質的組合學及/或化學物理可與水混合的粉末（W P )、可乳化的濃縮物（E C )、水可溶的粉末（SP)、水一可溶的濃縮物（SL) 、濃縮的乳化劑（B W )諸如油一於一水及水一於一油乳化劑、可噴灑的溶液或乳化劑、膠囊懸浮劑（C S )、油一或水一基礎的分散劑（S C )、懸浮乳化劑、懸浮劑濃縮物、粉末（D P )、油一可溶混的溶液（0 L )、種子處理產物、微粒形式之細粒（G R )、噴霧細粒、塗佈的細粒及吸附細粒、用於土壤施加或播種之細粒、水-可溶的細粒（S G )、水一可分散的細粒（W G ) 、U L V配方、微膠囊及蠟。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 55· 508216 A7 _ B7 五、發明說明（53) 這些各別的配方型式已熟知其原理同時描述，例如，於：Winnacker-Kuchler，"Chemische Technologie"〔化學工程學〕，第 7 冊，C. Hauser Verlag Munich，第 4 版， 1 9 8 6 ; Wade van Valkenburg，··殺蟲劑配方 ”，Marcel Dekker Ν·Υ.，1 9 7 3 ; K. Martens，”噴霧乾燥手冊"，第 3 版，1 9 7 9，G. Goodwin Ltd. London 〇或許需要的配方輔助劑，諸如惰性物質、表面活性劑、溶劑及其它添加劑亦熟知同時描述，例如，於：Watkins ，π殺蟲劑粉末稀釋劑及載體手冊π，第2版，Darland， Books，Caldwell N丄，H.v. Olphen，”黏土膠體化學槪論·· ，第 2 版，J. Wiley & Sons，N.Y. ; C. Marsden，··溶劑指南·’，第 2 版，Interscience，Ν·Υ. 1 9 6 3 ; McCutcheon 的"去垢劑及乳化劑年刊π，MC Publ. Corp.，Ridgewood N.J·; Sisley and Wood，"表面活性齊!1 百科全書”，Chem. Publ. Co. Inc.，Ν· Y. 1 9 6 4; Schonfeldt，·丨 Grenzflachenaktive Athylenoxidaddukte"〔表面-活性環氧乙院添加劑〕，Wiss. Verlagsgesell·，Stuttgart 1 9 7 6 ; Winnacker-Kuchler，’’Chemische Technologie” [化學工程學] ，第 7 冊，C. Hauser Verlag Munich，第 4 版，1 9 8 6 ο 根據這些配方，亦可製備含作爲莊稼保護劑的其它物質，諸如殺昆蟲劑、殺瞞劑、除草劑、殺真菌劑，及亦含安全劑、肥料及/或生長調節劑之組合物，例如以預拌形式或爲槽混合。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ~ (請先閲讀背面之注意事項再會· •線- 經濟部智慧財產局員工消費合作社印製 508216 A7 經濟部智慧財產局員工消費合作社印製 ______B7_____五、發明說明（54 ) 可與水混合的粉末均勻地可分散於水中而製備及其，除活性物質外，亦包含離子及/或非離子表面活性劑（濕潤劑、分散劑），例如聚氧乙基化的烷基酚、聚氧乙基化的脂肪醇類、聚氧乙基化的脂肪胺類、脂肪醇聚乙二醇醚硫酸鹽、烷烴磺酸鹽、烷基苯磺酸鹽、木質磺酸鈉、2 ’ 2’ 一二奈基甲烷一6， 6’一二磺酸鈉、二丁基萘磺酸鈉、或其它油醯基甲基牛磺酸鈉，除稀釋劑或惰性物質之外。製備可與水混合的粉末，具除草性活性物質細微地硏磨，例如於常用的設備中諸如鎚狀硏磨器、風箱硏磨器及空氣-噴射硏磨器，及它們同時或隨後地與配方輔助劑混合〇可乳化的濃縮物，例如，可利用於有機溶劑諸如丁醇、環己酮、二甲基甲醯胺、二甲苯、或其它較高沸點的飽合或未飽合脂肪族或芳香族、或含已加入一種或多種離子及/或非離子表面活性劑（乳化劑）之有機溶劑混合物中溶解活性物質來製備。已使用爲乳化劑之實施例物質有： (Ce—Ci 8) -烷基芳香基磺酸鈣諸如十二烷基苯磺酸鈣，或非離子乳化劑諸如脂肪酸聚乙二醇酯、（C 2 — C1S) -烷基芳香基聚乙二醇醚、脂肪醇聚乙二醇醚、環氧丙烷/環氧乙烷濃縮物、烷基聚醚、山梨聚糖酯，諸如山梨聚糖脂肪酸酯或聚氧乙烯山梨聚糖酯諸如聚氧乙烯山梨聚糖脂肪酸酯。通常地利用細微分開的固體物質，例如滑石、天然黏土諸如高嶺土、斑脫土及葉鱲石、或砂藻土碾磨活性物質 (請先閱讀背面之注意事項 I I—· I I 本頁) 訂----------岸本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 57 508216 A7 -__ B7 五、發明說明（55) 而獲得粉末。懸浮劑濃縮物可爲水-或油-基礎。它們可，例如，利用商業上可獲得之加入或沒加入表面活性劑，例如於上述已提及的其它配方型式之實例中的那些，的小珠硏磨器之溼式碾磨而製備。乳化劑，例如油一於一水乳化劑（E W )，可製備，例如，利用攪拌器、膠體硏磨器及/或使用於上述已提及，例如，於其它配方型式的實例中之表面活性劑的存在或缺乏下的水性有機溶劑之靜止混合器。可利用噴灑活性物質至吸附的、粒狀惰性物質或利用塗佈活性物質濃縮物至諸如沙、高嶺土或含輔助黏著劑，例如聚乙烯基醇、聚丙烯酸鈉或其它礦物油的粒狀惰性物質之載體表面而製備細粒。合適的活性物質亦可以常見肥料細粒，若必要時爲含肥料混合物，之製備方法製成粒狀。通常，水-可分散的細粒可利用常用的方法諸如噴霧-乾燥法、流動床成粒法、盤式成粒法、與高速混合器混合及沒有固·體惰性物質擠壓法製備。盤式、流動床、擠壓器及噴霧細粒之製備參見，例如，”噴霧-乾燥手冊'’第 3 版，1 9 7 9，G. Goodwin Ltd.， London ; J.E. Browning，”結塊”，化學及工程學，1 9 6 7 ，1 4 7頁及下列；’’Perry化學工程師手冊"，第5版， McGraw-Hill，紐約，1973，8 — 57 頁。更詳細的莊稼保護產物配方參見，例如，G. C. Klingman，"雜草控制科學’'，John Wiley 及 Sons，Inc.，本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -58 - (請先閱讀背面之注意事項再 I · I I 本頁)Chemical formula (III) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (VII) and the safety of the group (b) I) Examples of herbicides according to specific biological methods and their agents with one or more of the above-mentioned The chemical formula (I) can be equipped with different methods, depending on the parameters. The combinatorial and / or chemical and physical properties of possible suitable active substances can be mixed with water (WP), emulsifiable concentrate (EC), water Soluble powder (SP), water-soluble concentrate (SL), concentrated emulsifier (BW) such as oil-in-water and water-in-oil emulsifier, sprayable solution or emulsifier, capsule suspension Agent (CS), oil- or water-based dispersant (SC), suspension emulsifier, suspension concentrate, powder (DP), oil-miscible solution (0 L), seed treatment product, particulate form Fine particles (GR), spray fine particles, coated fine particles and adsorption fine particles, fine particles for soil application or seeding, water-soluble fine particles (SG), water-dispersible fine particles ( WG), ULV formula, microcapsule and wax. National Standard (CNS) A4 specification (210 X 297 mm) 55 · 508216 A7 _ B7 V. Description of the invention (53) These respective formulas are well known and their principles are described at the same time, for example, in: Winnacker-Kuchler, " Chemische Technologie " [Chemical Engineering], Volume 7, C. Hauser Verlag Munich, 4th Edition, 1 9 8 6; Wade van Valkenburg, ... · Insecticide Formulation ", Marcel Dekker Ν · Υ., 1 9 7 3; K. Martens, "Spray Drying Handbook", 3rd edition, 1979, G. Goodwin Ltd. London 〇 Formulation adjuvants that may be required, such as inerts, surfactants, solvents, and other additives are also well known Also described, for example, in: Watkins, π Insecticide Powder Diluent and Carrier Handbook π, 2nd Edition, Darland, Books, Caldwell N 丄, Hv Olphen, "Clay Colloid Chemistry ···, 2nd Edition, J Wiley & Sons, NY; C. Marsden, "Solvent Guide", 2nd Edition, Interscience, N.J. 1 9 6 3; McCutcheon's " Detergents and Emulsifiers, π, MC Publ. Corp., Ridgewood NJ ·; Sisley and Wood " Surface activeness! 1 Encyclopedia ", Chem. Publ. Co. Inc., N.Y. 1 9 6 4; Schonfeldt, · Grenzflachenaktive Athylenoxidaddukte " [Surface-Active Epoxy Resin Additive], Wiss. Verlagsgesell ·, Stuttgart 1 9 7 6; Winnacker-Kuchler, "Chemische Technologie" [Chemical Engineering], Book 7, C. Hauser Verlag Munich, 4th edition, 1 9 8 6 ο According to these formulas, Other substances used as crop protection agents, such as insecticides, insecticides, herbicides, fungicides, and compositions that also contain safeners, fertilizers and / or growth regulators, for example, in a ready-mixed form or as a tank mix . This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ~ (Please read the precautions on the back before meeting. • Line-Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives 508216 A7 Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives ______B7_____V. Description of the Invention (54) A powder that can be mixed with water can be evenly dispersed in water and prepared, and it contains ionic and / or non-ionic surfactants in addition to the active substance Wetting agents, dispersants), such as polyoxyethylated alkyl phenols, polyoxyethylated fatty alcohols, polyoxyethylated fatty amines, fatty alcohol polyethylene glycol ether sulfates, alkanes Acid salt, alkylbenzene sulfonate, sodium lignosulfonate, 2 '2'-diinalylmethane-6, 6'-di-disulfonate, sodium dibutylnaphthalenesulfonate, or other oleylmethyl Sodium taurate, in addition to diluents or inert substances. Preparation of water-miscible powders, fine honing with herbicidally active substances, such as in hammers, bellows hones in common equipment And air-jet honing machines, and they are It can be later mixed with formulation adjuvants. Emulsifiable concentrates, for example, can be used in organic solvents such as butanol, cyclohexanone, dimethylformamide, xylene, or other higher boiling saturated or unsaturated It is prepared by combining aliphatic or aromatic, or organic solvent mixtures containing one or more ionic and / or non-ionic surfactants (emulsifiers). Examples of substances that have been used as emulsifiers are: ( Ce—Ci 8) -Calcium alkylaryl sulfonate such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers such as fatty acid polyethylene glycol esters, (C 2 -C1S) -alkyl aromatic polyethylene Alcohol ethers, fatty alcohol polyethylene glycol ethers, propylene oxide / ethylene oxide concentrates, alkyl polyethers, sorbitan esters such as sorbitan fatty acid esters or polyoxyethylene sorbitan esters such as polyoxygen Ethylene sorbitan fatty acid esters. Active substances are usually milled using finely divided solid substances such as talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth (please read the precautions on the back first) — · II Page) Order ------- --- Kishimoto paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 57 508216 A7 -__ B7 V. Description of the invention (55) The powder can be obtained. The suspension concentrate can be water- or oil- They can, for example, be prepared by wet milling of commercially available bead hones with or without added surfactants, such as those in the examples of other formulations already mentioned above Emulsifiers, such as oil-to-water emulsifiers (EW), can be prepared, for example, using agitators, colloidal hones, and / or used on surfaces already mentioned above, for example, in the examples of other formulation types A static mixer of an aqueous organic solvent in the presence or absence of an active agent. The active substance can be sprayed onto the adsorbed, granular inert substance or the active substance concentrate can be applied to particulate inert substances such as sand, kaolin or auxiliary cohesive agents such as polyvinyl alcohol, sodium polyacrylate or other mineral oils. Fine particles are prepared on the surface of the carrier. Suitable active substances can also be fine granules of fertilizers, and if necessary a fertilizer-containing mixture, granulated by the preparation method. In general, the water-dispersible fine particles can be prepared by a common method such as a spray-drying method, a fluidized bed granulation method, a disc granulation method, mixing with a high-speed mixer, and an extrusion method without solid and inert substances. For disk, fluid bed, extruder, and spray granule preparation, see, for example, "Spray-Drying Handbook" 3rd Edition, 1979, G. Goodwin Ltd., London; JE Browning, "Agglomeration" , Chemistry and Engineering, 197, 147 and below; '' Perry Handbook of Chemical Engineers '', 5th edition, McGraw-Hill, New York, 1973, pp. 8-57. More detailed crop protection products For recipes, see, for example, GC Klingman, "Weed Control Science", John Wiley and Sons, Inc., This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) -58-(Please first (Read the precautions on the back, then I · II on this page)

— — — — — — — ^ ·1111111 IJ 經濟部智慧財產局員工消費合作社印製 508216 A7 __ B7___五、發明說明（56 ) 紐約，1 9 6 1，8 1 — 9 6 頁及 J. D. Freyer，S.A. Evans，π 雜草控制手冊”，第 5 版，Blackwell Scientific Publication ， Oxford ，1968 ，101 — 103 頁 ο 通常，農用化學配方包含以重量計0 · 1至9 9%，特別地以重量計0 · 1至9 5 %，的化學式（I I ) 一（ V I I )及/或（b )之活性物質或活性物質（I )及（ I I ) 一（V I I )及/或（b)的除草劑/解毒劑混合至 2 5 % 請先閱讀背面之注意項— — — — — — — ^ · 1111111 IJ printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Employee Cooperatives 508216 A7 __ B7___ V. Description of the Invention (56) New York, 1 9 6 1, 8 1-9 6 and JD Freyer, SA Evans, π Weed Control Handbook ", 5th edition, Blackwell Scientific Publication, Oxford, 1968, pp. 101-103 ο Generally, agrochemical formulations contain from 0.1 to 9 9% by weight, especially 0 by weight 1 to 95% of the active substance of the formula (II) one (VII) and / or (b) or the active substance (I) and (II) one (VII) and / or (b) herbicide / detoxification Mixing agent to 25% Please read the notes on the back first

頁 I I I I I 經濟部智慧財產局員工消費合作社印製物及以重量計1至9 9 . 9 %，特別地 99.8%，的固體或液體添加劑及以，特別地以重量計0 . 1至2 5 %，的於可與水混合的粉末中，活性物質重量計1 0至9 0%，以重量計至1 0 常用的配方成分組成。於可乳化的濃縮質濃度以重量計約1至8 0 %。粉末形計約1至2 0 %的活性物質，可噴灑的 0 . 2至2 0 %的活性物質。於諸如水細粒實例中，活性物質成分部分地視於的活性化合物而定。水-可分散的細粒通常，在以重量計1 0及9 0 %之間。此外，上述提及的活性物質配方可黏著劑、溼潤劑、分散劑、乳化劑、穿凍劑、溶劑、充塡劑、載體、.著色劑、制劑及Ρ Η及於每個實例中常用的黏度以重量計5 重量計0至表面活性劑濃度，例如 0 %的剩餘物實例中，式配方包括溶液以重量 -可分散的液體或固體之活性物質包括，若適透劑、防腐抗發泡劑、調節劑。，約以物則由活性物以重量計約細粒之形式中成分，當的，劑、防蒸發抑Page IIIII The employees of the Intellectual Property Bureau of the Ministry of Economic Affairs consume printed matter and 1 to 99.9%, especially 99.8% by weight of solid or liquid additives and, in particular, 0.1 to 25% by weight In powders that can be mixed with water, the active substance is composed of 10 to 90% by weight and from 10 to 10 by weight. The concentration of the emulsifiable concentrate is about 1 to 80% by weight. About 1 to 20% of active substance in powder form, 0.2 to 20% of active substance can be sprayed. In examples such as water fines, the active ingredient content depends in part on the active compound. Water-dispersible fines Generally, between 10 and 90% by weight. In addition, the above-mentioned active substance formulations can be adhesives, wetting agents, dispersants, emulsifiers, antifreezes, solvents, fillers, carriers, colorants, preparations, and solvents commonly used in each example. Viscosity from 0 to surfactant concentration by weight, such as 0%. In the example of the remainder, the formula includes a solution by weight-dispersible liquid or solid active material including, Agents, regulators. , About by the active by weight of the active ingredient in the form of fine particles, when the agent, anti-evaporation inhibitor

訂 I I I I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 59- 508216 A7 B7 五、發明說明（57) 可於混合的配方或於槽混合中使用根據本發明之混合物的組成爲，例如，熟知的活性物質如它們描述，例如，於雜草硏究26，441 一 445 (1986)，或”殺蟲劑手冊”，第10版，英國莊稼保護會議，1994，及在其中引用的文獻。從文獻中熟知及可與根據本發明之混合物結合的除草劑爲，例如，下列活性物質（注意：根據國際標準組織（I S 0 )的普通名稱或提供化合物的化學名稱，若適當的與常用的規則數目一起）：acetochlor ; acifluorfen; aclonifen; AKH 7 0 8 8，即〔〔〔1 — 〔5 —〔 2—氯4 一（二氟甲基）一苯氧基〕一 2 —硝基苯基〕一 2 —甲氧基亞乙基〕一胺基〕一氧〕一醋酸及其甲基酯；草不綠；alloxydim;莠滅淨；amidosulfuron;殺草強；AMS，即氨基磺酸銨；anilofos ;黃草靈；莠去津； azafenidine ( D P X — R 6 4 4 7 ) ，azimsulfurone ( DPX-A8947):疊氮津；燕麥靈；BAS 5 16H，即5 —氟—2 —苯基-4H— 3，1—苯並惡嗪—4 —酮；草除靈；benfluralin ; benfuresate ; bensulfuron-甲基；地散碟；苯達松；benzofluor;新燕靈；噻草隆；bialaphos ;治草醚；bispyribac-natrium ( K I Η - 2 0 2 3 )，除草定；bromobutide ;殺草全；溴苯腈； bromuron ； buminafos; busoxinone;去草胺；butamofos ； butenchlor ; buthidazole ; butralin ; butroxy dim ( I C ΙΟ 5 0 0 ) ，蘇達滅；cafenstrole (CH— 900);長殺草；cafentrazone; CDAA，即 2 —氯一 N，N -二一本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐) - 60- (請先閲讀背面之注意事項再 ·1 I 魏本頁) 經濟部智慧財產局員工消費合作社印製Order IIII This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 59-508216 A7 B7 V. Description of the invention (57) The compound according to the present invention can be used in mixing formula or in tank mixing. Compositions are, for example, well-known active substances as they are described, for example, in Weed Research 26,441-445 (1986), or "Pesticide Handbook", 10th Edition, British Crop Protection Conference, 1994, and in Literature cited therein. Herbicides that are well known from the literature and that can be combined with the mixtures according to the invention are, for example, the following active substances (note: according to the common name of the International Standards Organization (IS 0) or the chemical name of the compound, if appropriate and commonly used The number of rules together): acetochlor; acifluorfen; aclonifen; AKH 7 0 8 8 which is [[[1 — [5 — [2-chloro4-mono (difluoromethyl) -phenoxy]] 2-nitrophenyl ] 2-Methoxyethylene] monoamino] monooxy] monoacetic acid and its methyl esters; grass is not green; alloxydim; fendijing; amidosulfuron; herbicidal strong; AMS, ammonium sulfamate; anilofos; Huangcaoling; Atrazine; azafenidine (DPX — R 6 4 4 7), azimsulfurone (DPX-A8947): azidosulfurin; oatmeal; BAS 5 16H, that is, 5-fluoro-2 —phenyl-4H— 3 , 1-benzoxazin-4-one; herbicides; benfluralin; benfuresate; bensulfuron-methyl; ground powder discs; bentazon; benzofluor; new Yan Ling; thiasulfuron; bialaphos; herbicide ether; bispyribac -natrium (KI Η-2 0 2 3), weeding; bromobutide; Benzonitrile; bromuron; buminafos; busoxinone; desoxamine; butamofos; butenchlor; buthidazole; butralin; butroxy dim (IC ΙΟ 50 0 0); sudaben; cafenstrole (CH-900); long herbicide; cafentrazone; CDAA, That is 2-Chlorine N, N-21 paper size applicable to Chinese National Standard (CNS) A4 specifications (210 χ 297 mm)-60- (Please read the precautions on the back first, then 1 I Wei page) Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperative

-------訂--------- 線 I an·! > I Μ·· ΜΙΜ MB MB Μ·· I I ΜΒ·!· I ΜΜ I 508216 A7 經濟部智慧財產局員工消費合作社印製 __B7___五、發明說明（58 ) 2 —丙烯基乙醯胺；CDEC，即二乙基二硫氨基甲酸2 —氯烯丙酯；chlomethoxyfen;草滅平；chloransulam—甲基 (XDE — 565) ’chlorazifop — 丁基，氯溴隆；氯草靈 ;chlorfenac;氯甲丹；氛基氯噠嗪酮；chlorimuron —乙基 ;chlornitrofen;氯麥隆；枯草隆；氯苯胺靈； chlorsulfuron;敵草索；草克樂；cinidon—乙基， cinmethylin; cinosulfuron; clethodim; clodinafop及其酯衍生物（例如 clodinafop-propargyl) ; clomazone ; clomeprop ; cloproxydim; clopyralid; cumyluron ( J C 9 4 0 ):草淨津；草滅特；cyclosulfamuron (AC 014); cycloxydim; cycluron; cyhalofop及其酯衍生物（例如丁基酯，DEH— 112) ; cyperquat;環草津；cyprazole ; 2 ，4 — D B ;茅草枯；desmedipham ; desmetryn ;燕麥敵；麥草畏；敵草腈；2，4 一滴丙酸；二氯苯氧基丙酸及其酯類諸如二氯苯氧基丙酸甲酯；diclosulam ( X D E — 5 6 4 ) ，diethatyl ;枯莠隆；difenzoquat ; diflufenican ; diflufenzopyr-natrium (SAN— 835H) ，dimefuron ; dimethachlor ; dimethametryn ; dimethenamid ( S AN— 5 8 2H) ;dimethazone，5 —（4，6 —二甲基喃 U定一 2 一基一胺甲醯基氨磺醯基）一 1 一（2 —吡啶基）一吡唑 —4 —羧酸甲酯（NC — 330) ; tdaziflam ( I D Η — 110 5) ，clomazon ; dimethipin ; dimetrasulfuron， dinitramine; 2 —〔 1—甲基一正丙基〕一 4，6 — 二硝基苯酚；dinoterb ;草乃敵；殺草淨；敵草快；dithiopyr ;敵請先閱讀背 £ 之注項------- Order --------- Line I an ·! &Gt; I Μ ·· ΜΙΜ MB MB Μ ·· II ΜΒ ·! · I ΜΜ I 508216 A7 Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperative __B7___ V. Description of the invention (58) 2-propenylacetamide; CDEC, which is 2-chloroallyl diethyldithiocarbamate; chlomethoxyfen; chlorfenap; chloransulam-methyl ( XDE — 565) 'chlorazifop — butyl, chlorbromone; chlorfenac; chlorfenac; chlormethan; chlorochloropyrazinone; chlorimuron — ethyl; chlornitrofen; chloromelon; subtilon; chloraniline; chlorsulfuron Dipropoxol; Cacrole; cinodon-ethyl, cinmethylin; cinosulfuron; clethodim; clodinafop and its ester derivatives (such as clodinafop-propargyl); clomazone; clomeprop; cloproxydim; clopyralid; cumyluron (JC 9 4 0): grass Jingjin; Cufente; cyclosulfamuron (AC 014); cycloxydim; cycluron; cyhalofop and its ester derivatives (for example, butyl ester, DEH-112); cyperquat; cyperazine; cyprazole; 2, 4, 4-DB; desmedipham; desmetryn; oat foe; dicamba; dipropionitrile; 2, 4 One drop of propionic acid; dichlorophenoxypropionic acid and its esters such as methyl dichlorophenoxypropionate; diclosulam (XDE — 5 6 4), diethatyl; cumulone; difenzoquat; diflufenican; diflufenzopyr-natrium (SAN — 835H), dimefuron; dimethachlor; dimethametryn; dimethenamid (S AN—5 8 2H); dimethazone, 5 — (4,6 —dimethylamino U fixed 1 2 monomethylamine methylamidosulfamoyl) — 1 (2-pyridyl) -pyrazole-4-carboxylic acid methyl ester (NC — 330); tdaziflam (ID Η — 110 5), clomazon; dimethipin; dimetrasulfuron, dinitramine; 2 — [1-methyl-n-n Propyl] -4,6-dinitrophenol; dinoterb; grass is the enemy; dicamba; diquat; dithiopyr; enemies, please read the note of £

頁I I I I I I訂Page I I I I I I Order

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 61 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（59) 草隆；D N 〇 C ; eglinazine-乙基；EL 177，即 5 — 氰基一1— (1 ，1 一二甲基乙基）一N —甲基一 1H — 口比嗤一 4 —殘醯胺；草藻滅；epoprodan (MK — 2 4 3 )· ，E P T C ; esprocarb ; ethalfluralin ; ethametsulfuron —甲基；ethidimuron; ethiozin; ethofumesate; F 5 2 3 1 ，即 N -〔2 -氯—4 —氟—5 —〔4 — (3 —氟丙基）—4 ，5 -二氫一 5 —氧—1H —四疊氮一 1—基〕—苯基〕 —乙院磺胺；ethoxy fen及其酯（例如乙基酯，111^一 2 5 2) ;ethoxysulfuron (從 EP 3 4 2 5 6 9 )， etobenzanid (HW 52) ;3 — (4 -乙氧基一 6 —乙基一 1，3，5 —三吖嗪一 2—基）一1— (2，3 -二氫一1 ， 1一二氧一2-甲基苯肼〔b〕噻吩一7—磺醯基）尿素（EP — A 0 7 9 683) ; 3— (4 -乙基 —6 —甲氧基一 1，3，5-三吖嗪一2 —基）一 1—( 2，3 —二氫一1，1 一二氧—2_甲基苯肼〔b〕噻吩 —7 -磺醯基）尿素（EP — A079683); 2 ，4 ，5 一涕丙酸；fenoxan，fenoxaprop 及 fenoxaprop -P及其酯類，例如fenoxaprop - P ·乙基及fenoxaprop -乙基；fenoxydim;非草隆；flamprop -甲基； flazasulfuron I flufonacet (BAY— F〇E — 5043)This paper size applies to China National Standard (CNS) A4 (210 X 297 mm). 61 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 508216 A7 B7. 5. Description of the invention (59) Cao Long; DN 〇C; eglinazine-B EL 177, that is, 5- cyano-1— (1,1—dimethylethyl) —N—methyl—1H—lipofluorene—4—residue amine; chlorella; epoprodan (MK — 2 4 3) ·, EPTC; esprocarb; ethalfluralin; ethametsulfuron —methyl; ethidimuron; ethiozin; ethofumesate; F 5 2 3 1, that is, N-[2 -chloro-4 -fluoro-5 — [4 — (3-fluoro Propyl) -4,5 -dihydro-5 -oxo-1H -tetraazido-1 -yl] -phenyl]-ethoxylated sulfanilamide; ethoxy fen and its esters (such as ethyl esters, 111 ^-2 5 2); ethoxysulfuron (from EP 3 4 2 5 6 9), etobenzanid (HW 52); 3- (4-ethoxy-6-ethyl-1, 3, 5-triazine- 2-yl)- 1— (2,3-dihydro-1, 1-dioxo-2-methylphenylhydrazine [b] thiophene-7-sulfonyl) urea (EP — A 0 7 9 683); 3— (4- Ethyl-6-methoxy-1,3 5-triazine- 2-yl)-1- (2,3-dihydro-1,1-dioxo-2-methylphenylhydrazine [b] thiophen-7-sulfofluorenyl) urea (EP — A079683 ); 2,4,5 Monodipropionic acid; fenoxan, fenoxaprop, and fenoxaprop-P and esters thereof, such as fenoxaprop-P · ethyl and fenoxaprop-ethyl; fenoxydim; non-chloruron; flamprop-methyl; flazasulfuron I flufonacet (BAY— F〇E — 5043)

，fluazifop 及 fluazifop - P，florasulam ( D E — 5 7 0 )及其酯類，例如fluazifop - 丁基及fluazifop - P - 丁基 ;fluchloralin ; flumetsulam ; flumeturon ; flumiclorac及其酯類（例如戊基酯，S — 2 3 0 3 1 ) ;flumioxazin ( S 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -62 - -I — I I I I I 訂-! — — — — — —*5^ (請先閱讀背面之注意事項寫本頁) 再€, Fluazifop and fluazifop-P, floralasulam (DE-57.0) and their esters, such as fluazifop-butyl and fluazifop-P-butyl; fluchloralin; flumetsulam; flumeturon; flumiclorac and their esters (such as amyl esters, S — 2 3 0 3 1); flumioxazin (S This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) -62--I — IIIII order-! — — — — — — * 5 ^ (Please read the notes on the back to write this page)

508216 A7 _ B7___ 五、發明說明（6〇) — 482) ; flumipropyn ; flupoxam (KNW— 7 3 9 ) ;消草醚；fluoroglycofen—乙基；flupropacil ( U B I C —4 2 4 3 );鈉flupyrsulfuron —甲基（DPX — K E 4 5 9 ) ，fluridone ; flurochloridone ; fluroxypyr ; flurtamone ; fluthiacet —甲基（KIH — 9201)， fomesafen ; fosamine ; furyloxyfen ; glufosinate ;鎭草寧； halosafen; halosulfuron及其酯類（例如甲基酯，1^〇一 3 1 9 ) ; h a 1 o x y f ο p 及其酯類；h a 1 o x y f ο p · P ( = R - haloxyfop )及其酯類；環己基二甲胺基甲基三嗪二酮； imazamethabenz·甲基；imazamox (AC — 299263) ，imazapyr; imazaquin及鹽類諸如錢鹽；imazethamethapyr ;imazethapyr ; imazosulfuron ; iodosulfuron ( 4 一确一 2 閱讀背面之注項508216 A7 _ B7___ V. Description of the invention (60) — 482); flumipropyn; flupoxam (KNW — 7 3 9); herbicide; fluoroglycofen — ethyl; flupropacil (UBIC — 4 2 4 3); sodium flupyrsulfuron — a (DPX — KE 4 5 9), fluridone; flurochloridone; fluroxypyr; flurtamone; fluthiacet-methyl (KIH-9201), fomesafen; fosamine; furyloxyfen; glufosinate; humulin; halosafen; halosulfuron and its esters (for example, formazan) Esters, 1 ^ 〇-3 1 9); ha 1 oxyf ο p and its esters; ha 1 oxyf ο p · P (= R-haloxyfop) and its esters; cyclohexyldimethylaminomethyltriazine Diones; imazamethabenz · methyl; imazamox (AC — 299263), imazapyr; imazaquin and salts such as money salts; imazethamethapyr; imazethapyr; imazosulfuron; iodosulfuron (4 one sure one 2 Read the note on the back

η 頁I I I 層 I I 訂〔3 — (4 —甲氧基 —甲基一 1 5 —三吖嗪經濟部智慧財產局員工消費合作社印製一2-基）尿基磺醯基〕安息香酸甲酯，鈉鹽，WO 92 /13845);碘苯腈；isocarbamid ;異樂靈； isoproturon; isouron; isoxaben; isoxapyrifop;卡靈草； lactofen;環草定；linuron; MC P A ; MC P B ; 2 — 4 \ 甲氯丙酸；mefenacet ; mefluidid ; metamitron ; metazachlor ;噻卩坐隆；威百軟；滅草定；去草酮；methyldymrone; metabenzuron ， 2 [3-(4 二甲氧基嘧啶一 2 — 基）茚基磺醯基〕- 4 -甲烷嗍風醯胺基甲基安息香酸甲酯（W〇 95/10507) ; methonzuron ;莠谷隆； metolachlor; S-metolachlor，metosulam ( X R D 5 1 1 ) •，甲氧隆；賽克津；metsulfuron —甲基；ΜΗ ;草達滅；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -63·η Page III Tier II Order [3- — (4-methoxy-methyl-1 15-triazine printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs — 2-based) urethanesulfonyl] methyl benzoate , Sodium salt, WO 92/13845); iodobenzonitrile; isocarbamid; isorakrin; isoproturon; isouron; isoxaben; isoxapyrifop; carin grass; lactofen; cyclodoxin; linuron; MC PA; MC PB; 2 — 4 \ Mefenacetic acid; mefenacet; mefluidid; metamitron; metazachlor; thiazolone; carbendazol; chlorfendidin; humoxone; methyldymrone; metabenzuron, 2 [3- (4 dimethoxypyrimidine 2 -yl) Indenylsulfonyl]-4 -methane, sulfonylaminomethyl methyl benzoate (WO95 / 10507); methonzuron; melamine; metolachlor; S-metolachlor, metosulam (XRD 5 1 1) •, Metoxuron; secretion; metsulfuron —methyl; methoxide; grass-bent; this paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -63 ·

508216 經濟部智慧財產局員工消費合作社印製 A7 ___B7_ 五、發明說明（61 ) 殺草利；monocarbamide dihydrogensulfate;綠榖隆；滅草隆；MT 128,即6 -氯一 N —（3 -氯一 2 —丙烯基 )一 5 —甲基一N —苯基一3 —噠嗪胺；MT 5950，· 即N —〔3 —氯一4 一（1 一甲基乙基）一苯基〕一2_ 甲基戊烷醯胺；N，N —二甲基一2 —〔3 — (4，6 — 二甲氧基嘧啶一 2 —基）脲基磺醯基〕一 4 一甲醯基胺基一苯醯胺（W0 95/01344):萘氧基苯基丙醯胺 ;草萘胺；抑草生；NC 310，即4 一（2，4 一二氯苯甲醯）一 1 一甲基一5 —苄基氧吡唑；除莠劑； nicosulfuron ; nipyraclophen ; nitralin ;除草醚； nitrofluorfen ； norflurazon ; orbencarb ;黃草消；oxadiargy 1 (RP — 020630):惡草靈；oxaziclomefone ( MY—I〇〇)，〇xyfluorfen;oxasulfuron(CGA — 2 7 7 4 7 6 )，對草快；克草鑑；pendimethalin; pentoxazone (KPP — 314) ，perfluidone ; phenisopham ; phenmedipham ;毒莠定；piperophos ·， piributicarb ; pirifenop-丁基；pretilachlor ; primisulfuron-甲基；procyazine; prodiamine;卡樂施；proglinazine -乙基；撲滅通；撲草淨；毒草安；二氯丙醯苯胺；propaquizafop及其酯類；撲滅津；苯胺靈；propisochlor; propyzamide; prosulfalin ; prosulfocarb ; prosulfuron ( C G A — 1 5 2 0 0 5 );廣草胺；pyraflufen-乙基（E T - 7 5 I )，pyrazon ; pyrazosulfuron-乙基；pyrazoxyfen ; pyribenzoxim，pyridate ; pyriminobac —甲基（K I H — 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -64- -I I I I I I I 訂 I I I I I I *5^ (請先閱讀背面之注意事項再1^本頁) m.508216 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ___B7_ V. Description of the Invention (61) Herbicidal; monocarbamide dihydrogensulfate; Chrysanthemum; Herbazone; MT 128, which is 6-chloro-N — (3 -chloro- 2-propenyl)-5-methyl-N-phenyl-3-pyridazinamine; MT 5950, which is N- [3-chloro-4 ((1-methylethyl) -phenyl]-2_ Methylpentanefluorenamine; N, N -dimethyl-2-[3-(4,6-dimethoxypyrimidine-2 -yl) ureidosulfonyl]-4 -methylfluorenylamino- Benzamidine (W0 95/01344): naphthyloxyphenylpropanamine; chlorpyramidine; humicidin; NC 310, that is 4- (2,4-dichlorobenzidine)-1-methyl-5 —Benzyloxypyrazole; herbicides; nicosulfuron; nipyraclophen; nitralin; herbicides; nitrofluorfen; norflurazon; orbencarb; huangcaoxiao; oxadiargy 1 (RP — 020630): oxadiazine; oxaziclomefone (MY-I〇〇) 〇xyfluorfen; oxasulfuron (CGA — 2 7 7 4 7 6), fast to grass; Ke Cao Jian; pendimethalin; pentoxazone (KPP — 314), perfluidone; phenisopham; p henmedipham; piperidine; piperophos, piributicarb; pirifenop-butyl; pretilachlor; primisulfuron-methyl; procyazine; prodiamine; caroxif; proglinazine-ethyl; Propaquizafop and its esters; chlorphenazine; aniline; propisochlor; propyzamide; prosulfalin; prosulfocarb; prosulfuron (CGA — 15 2 0 0 5); palachlor; pyraflufen-ethyl (ET-7 5 I), pyrazon pyrazosulfuron-ethyl; pyrazoxyfen; pyribenzoxim, pyridate; pyriminobac — methyl (KIH — This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -64- -IIIIIII Order IIIIII * 5 ^ (Please (Please read the notes on the back before 1 ^ this page) m.

經濟部智慧財產局員工消費合作社印製 508216 A7 B7 五、發明說明（62) 6 1 2 7 ) ，pyrithiobac (KIH— 2031) ; pyroxop 及其酯類（例如炔丙基酯）；quinclorac; quinmerac; quinofop 及其酯衍生物，Quizalop及quizalop - P及酯衍生物，例如· quizalop -乙基；quizalop-P-tefuryl及-乙基；renriduron; rimsulfuron ( D P X — E 9 6 3 6 ) ;S 275，即 2 一〔4 一氯一 2 —氟一 5 -（2 —丙炔氧基）一苯基〕一 4，5，6，7 —四氫一 2H —卩弓丨哗；密草通；sethoxydim ;環草隆；西瑪三嗪；西草淨；S N 1 0 6 2 7 9，即2 一〔〔7_〔2 —氯_4 一（三氟甲基）一苯氧基〕一 2 一萘基〕-氧〕一丙酸及其甲基酯；sulfentrazone ( FMC — 9 7 2 8 5，F — 6 2 8 5) ; sulfazuron;Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 B7 V. Description of the Invention (62) 6 1 2 7), pyrithiobac (KIH-2031); pyroxop and its esters (such as propargyl esters); quinclorac; quinmerac; quinofop and its ester derivatives, Quizalop and quizalop-P and ester derivatives, such as quizalop-ethyl; quizalop-P-tefuryl and -ethyl; renriduron; rimsulfuron (DPX — E 9 6 3 6); S 275, That is 2-[4 -chloro- 2 -fluoro-5-(2-propynyloxy) -phenyl] -4,5,6,7 -tetrahydro- 2H-卩 bow 丨 rush; dense grass pass; sethoxydim Cycloprone; Cimatriazine; Xicaojing; SN 1 0 6 2 7 9 which is 2 [[7_ [2-Chloro_4 ((trifluoromethyl) -phenoxy]] 2 -naphthalene Group] -oxy] monopropionic acid and its methyl ester; sulfentrazone (FMC — 9 7 2 8 5, F — 6 2 8 5); sulfazuron;

sulfometuron -甲基；sulfosate ( I C I — A 〇 2 2 4 ); sulfosulfuron (M〇N — 3 7 5 0 0 ) ，TCA ; tebutam ( GCP — 5544) ; tebuthiuron ; tepraloxidim (BAS 一 620H)，特草定；芽根靈；terbuchlor ;甲氧去草淨 ;terbuthylazine;去草淨；T F Η 4 5 0，即 Ν，Ν - 二乙基一 3 —〔（2 —乙基—6 —甲基苯基）—磺醯基〕一 1Η— 1，2，4 —三哗—1—錢酿胺；thenylchlor ( NSK— 850) ； thiazafluron ； thiazopyr ( Μοη- 1 3 2 0 0 ) ;thidiazimin (SN - 124085); thifensulfuron-甲基；thiobencarb ; tiocarbazil ； tralkoxydim ;tri-allate ; triasulfuron ; triazofenamide ; tribenuron-甲基 ;triclopyr; tridiphane;草達津；贏樂靈；triflusulfuron 及酯類（例如甲基酯，DPX — 66037):三甲隆；本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -65· — — — — — — — ^ — — — — — — — — (請先閱讀背面之注意事項再«(寫本頁) ,¾ 508216 A7 -----B7 五、發明說明（63 ) tsitodef ;滅草錳；WL 1 10547，即 5 — 苯氧基一 1 一〔3—(三氟甲基）一苯基〕一1H —四唑；UBH 一 509;D-489;LS 82 - 556;KPP- 300 ;KPP 一 421，MT - 146，NC - 324 ;KH— 218 ; DPX — N8189 ; D〇WC〇一 535 ; DK — 8910 ; V— 53482 ; PP -600 ;MBH— 〇〇1。對於使用，商業上可獲得的形式配方，若必要時，以常用的方法稀釋，例如於可與水混合的粉末、可乳化的濃縮物、分散劑及水-可分散的細粒之實例中使用水。以粉末、土壤細粒、播種細粒及可噴灑的溶液形式製備者通常不於使用前進一步以任何其它惰性物質稀釋。需要的化學式（I )之除草劑施加比例隨著外部條件不同諸如，尤其是，溫度、濕度及使用的除草劑本質。可於廣泛的限制中而不同，例如在0 · 〇〇 1及1 〇 . 〇公斤/ h a之間或更多的除草劑，但是較佳地在0 . 0 0 5 及5公斤/ h a之間。接下來的實施例意欲闡明本發明： A.配方實施例 a )利用混合以重量計1 〇分的化學式（I I ) 一（ VI I)及/或從基團B (b)中的化合物或化學式 (I )的具除草性活性物質及化學式（I I ) 一（ V I I )的安全劑及/或從基團（b)中之活性物質混合物及以重量計9 0分滑石爲惰性物質及於鎚狀硏本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -66- (請先閱讀背面之注意事 h. II 訂·！ — I!-線 h 本頁) 經濟部智慧財產局員工消費合作社印製 508216 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（64) 磨器中硏磨此混合物而獲得的粉末。 b)可容易分散於水中之可與水混合的粉末可利用混合以重量計25分化學式（1丨）一（VI〗）及/或從· 基團B (b)中的化合物或化學式（I )及化學式（ I I) 一（VI I)安全劑及/或從基團B (b)中具除草性活性物質之活性物質混合物’以重量計6 4 分爲惰性物質之含高嶺土的石英’以重量計1〇分的鉀木質磺酸鹽及以重量計1分爲溼潤劑及分散劑的油基甲基牛磺酸鈉，同時於定盤硏磨器中碾磨混合物獲得。 c )可容易分散或懸浮於水中之濃縮物可利用混合以重量計20分的化學式（I I ) 一（VI I )及/或基團 B ( b )中的化合物或化學式（I )之具除草性活性物質及化學式（I I) 一（VI I)及/或基團B ( b )中之安全劑的活性物質混合物，以重量計6分的烷基酚聚乙二醇醚（©Triton X 2 0 7 )，以重量計 3分的異癸烷聚乙二醇醚（8 E0)及以重量計7 1分的烷烴石蠟礦物油（沸點範圍，例如，約2 5 5上至2 7 7 0 C )，同時於球硏磨器中碾磨混合物至5微米下之細粒而獲得。 d )可乳化的濃縮物可從以重量計1 5分的化學式（ 1 I) 一（VI I)及/或基團B (b)中的化合物或化學式（I )的具除草性活性物質及化學式（I I ) 一（ V I I )及/或基團B ( b )中的安全劑之活性物質混合請先閱讀背面之注意事項頁層sulfometuron-methyl; sulfosate (ICI — A 〇 2 2 4); sulfosulfuron (MON — 3 7 5 0 0), TCA; tebutam (GCP — 5544); tebuthiuron; tepraloxidim (BAS-620H), tamidine ; Bu Gen Ling; terbuchlor; trimethoxam; terbuthylazine; trimethazine; TF Η 4 50, which is Ν, Ν-diethyl- 3-[(2-ethyl-6-methylphenyl) —Sulfoamyl] —1Η—1,2,4—Tri-Bao—1—Centamidine; thenylchlor (NSK— 850); thiazafluron; thiazopyr (Μοη- 1 3 2 0 0); thidiazimin (SN-124085); thifensulfuron-methyl; thiobencarb; tiocarbazil; tralkoxydim; tri-allate; triasulfuron; triazofenamide; tribenuron-methyl; triclopyr; tridiphane; grassazine; trichlorsulfuron; triflusulfuron and esters (eg methyl esters, DPX — 66037) : Sanjialong; This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) -65 · — — — — — — ^ — — — — — — — — (Please read the notes on the back first Then «(write this page), ¾ 216 216 A7 ----- B7 V. Invention (63) tsitodef; manganese; WL 1 10547, which is 5-phenoxy-1 1- [3- (trifluoromethyl) -phenyl] -1H-tetrazole; UBH-509; D-489; LS 82-556; KPP-300; KPP-421, MT-146, NC-324; KH-218; DPX-N8189; D0WC〇-535; DK-8910; V-53482; PP-600; MBH-〇〇1. For use, commercially available form formulations are diluted, if necessary, by common methods, such as in water-miscible powders, emulsifiable concentrates, dispersants, and water-dispersible fine particles. Water is used in the examples. Producers in the form of powder, soil fines, seed fines and sprayable solutions are usually not further diluted with any other inert material before use. The required application rate of the herbicide of the formula (I) varies with external conditions such as, in particular, temperature, humidity, and the nature of the herbicide used. May vary in a wide range of limits, such as between 0.001 and 1 kg / ha or more herbicides, but preferably between 0.05 and 5 kg / ha . The following examples are intended to clarify the invention: A. Formulation Example a) A compound or formula of formula (II)-(VI I) and / or from group B (b) is used by mixing 10 minutes by weight (I) A herbicidally active substance and a safener of formula (II)-(VII) and / or an active substance mixture from the group (b) and 90% by weight talc is an inert substance and is in the shape of a hammer纸张 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) -66- (Please read the notice on the back h. II order! — I! -Line h page) Intellectual Property of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau of Labor Bureau 508216 A7 B7 Printed by the Consumer Cooperative of the Bureau of Intellectual Property of the Ministry of Economic Affairs 5. Description of Invention (64) The powder obtained by honing this mixture in a mill. b) Water-miscible powder that can be easily dispersed in water can be used by mixing 25 points by weight of the chemical formula (1 丨)-(VI) and / or the compound in the group B (b) or the chemical formula (I ) And chemical formula (II)-(VI I) safeners and / or active substance mixtures with herbicidally active substances from group B (b) 'by weight 6 4 kaolin-containing quartz divided into inert substances' to 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleyl methyl taurate as a wetting agent and dispersant were obtained by milling the mixture in a plate honing machine. c) Concentrates that can be easily dispersed or suspended in water can be used by mixing compounds of formula (II)-(VI I) and / or group B (b) or a herbicidal compound with formula (I) of 20 points by weight Active active substance and active substance mixture of formula (II) -1 (VI I) and / or safener in group B (b), 6 points by weight of alkylphenol polyethylene glycol ether (© Triton X 2 0 7), 3 points by weight of isodecane polyethylene glycol ether (8 E0) and 7 1 points by weight of alkane paraffin mineral oil (boiling point range, for example, about 2 5 5 up to 2 7 7 0 C), while milling the mixture to fine particles below 5 microns in a ball honer. d) Emulsifiable concentrates can be selected from compounds of formula (1 I)-(VI I) and / or group B (b) or herbicidally active substances of formula (I) by 15 points by weight and Mix the active substances of the safener in formula (II) one (VII) and / or group B (b), please read the precautions on the back page first

I 訂 • I I I ▲ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -67- 經濟部智慧財產局員工消費合作社印製 508216 A7 B7_ 五、發明說明（65 ) 物，以重量計7 5分爲溶劑的環己酮及以重量計1 0分爲乳化劑之乙氧基化的壬基酚中獲得。水-可分散的細粒可利用混合以重量計75分的化學式（I I) — (VI I)及 /或基團B (b)中的化合物或化學式（I )的具除草性活性物質及化學式（I I) — (VI I)及/或基團B ( b )中的安全劑之活性物質混合物而獲得以重量計10分的木質磺酸鹽鈣， .以重量計5分的月桂基硫酸鈉，以重量計3分的聚乙烯基醇及以重量計7分的高嶺土，於定盤硏磨器中碾磨混合物及於流動床中利用噴灑在水上爲粒狀液體而磨成粉末。水-可分散的細粒亦可利用於膠體硏磨器中均質化及預硏成粉末，以重量計2 5分的化學式（I I ) — ( V I I )及 /或基團B ( b )中的化合物或化學式（I )之具除草性活性物質及化學式（I I) 一（VI I)及/或基團B ( b )中之安全劑的活性物質混合物以重量計5分的2，2’ 一二萘基甲烷—6，6’一二磺酸鈉，以重量計2分的油基甲基牛磺酸鈉，以重量計1分的聚乙烯基醇，以重量計17分的碳酸鈣及本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱) -68-' -I ! I I I I 訂 i II ! I I - *5^ (請先閱讀背面之注意事項寫本頁) 太Order I • III ▲ This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -67- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 B7_ V. Description of Invention (65) It is obtained from cyclohexanone, which is divided into 75 parts by weight, and ethoxylated nonylphenol, which is divided into 10 parts by weight as an emulsifier. Water-dispersible fine particles can be used by mixing compounds of formulae (II)-(VI I) and / or group B (b) or herbicidally active substances and formulae of formula (I) with 75 minutes by weight. (II) — (VI I) and / or active substance mixture of safeners in group B (b) to obtain 10 points by weight of calcium lignosulfonate, 5 points by weight of sodium lauryl sulfate Polyvinyl alcohol at 3 points by weight and kaolin at 7 points by weight were milled in a fixed plate honer and ground in a fluidized bed by spraying on water as a granular liquid to obtain a powder. Water-dispersible fine particles can also be used in a colloidal honing machine to homogenize and pre-pulverize the powder. The formula (II)-(VII) and / or group B (b) Compound or active substance mixture with herbicidally active substance of formula (I) and safener in formula (II)-(VI I) and / or group B (b) 5 points by weight 2,2'- Dinaphthylmethane—6,6′-disulfonic acid, 2 points by weight of sodium oleyl methyl taurine, 1 point by weight of polyvinyl alcohol, 17 points by weight of calcium carbonate and This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 public love) -68- '-I! IIII Order i II! II-* 5 ^ (Please read the precautions on the back to write this page) too

經濟部智慧財產局員工消費合作社印製 508216 A7 _ B7 五、發明說明（66) 以重量計5 0分的水，隨後地於小珠硏磨器中碾磨混合物同時於噴霧塔中利用單一物質噴嘴原子化及乾燥產生的懸浮劑而獲得。生物學實施例 1 ·溫室實驗 1.1 幼苗出土前單子葉及雙子葉的有害植物及有用的植物之種子或地下莖放置於直徑9至13公分的含沙壤土鍋中同時覆蓋著土壤。再者，對於米測試，米植物及於此有用的莊稼植物中爲不想要的有害植物，於水浸的土壤中生長。配爲可乳化的濃縮物或粉末之除草劑及安全劑的不同劑量以水性分散劑或懸浮劑或乳化劑的形式以3 0 0至8 Ο Ο I的水/ h a (轉換）比例施加至土壤表面被覆物，或，於米測試的實例中，注入灌溉水。然後將鍋於最理想的條件下保持在溫室中以成長植物。於處理後3 - 4週，視覺地評鑑對有用植物及有害植物的損害。損害與未處理的控制比較而以百分比表示。測試結果編輯於表5及6中；（a · i ·=活性成份本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -69 - ϋ n ϋ 1 iBi ϋ 一聲OJβ ϋ ·1 1 n n ϋ I (請先閱讀背面之注意事項寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 508216 A7 _ B7 V. Description of the invention (66) 50 minutes by weight of water, followed by milling the mixture in a bead honing machine while using a single substance in a spray tower Obtained by atomizing and drying the nozzle. Biological Example 1 · Greenhouse Experiment 1.1 Before the emergence of seedlings, harmful or useful plants of monocotyledonous and dicotyledonous seeds and useful plant seeds or underground stems are placed in sandy clay pots with a diameter of 9 to 13 cm while covering the soil. Furthermore, for the rice test, rice plants and crop plants useful here are unwanted harmful plants that grow in flooded soil. Different doses of herbicides and safeners formulated as emulsifiable concentrates or powders are applied to the soil in the form of water dispersants or suspensions or emulsifiers at a water / ha (conversion) ratio of 300 to 8 〇 I Surface coatings, or, in the case of the meter test, irrigation water. The pot is then kept in a greenhouse under optimal conditions to grow plants. Visually assess damage to useful and harmful plants 3 to 4 weeks after treatment. Damage is compared to untreated controls as a percentage. The test results are compiled in Tables 5 and 6; (a · i · = active ingredients. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -69-ϋ n ϋ 1 iBi ϋ One OJβ ϋ · 1 1 nn ϋ I (Please read the notes on the back to write this page)

508216 公告本508216 Bulletin

Jilf澡88120184號專利申請案中文說明書修正頁民國90年7月修正五、發明説明（表5施加比例：2 0〇，4 0 〇克a 劑1 一 1 ;玉蜀黍公頃；除第 % 產物除草劑/安全劑施加比例 [克a.i·/公頃1 毒害植物於玉品種Felix :蜀黍[%] 品種除草劑1-1 400 85 80 除草劑1-1 300 85 85___- 除草劑1-1 200 78 78 除草激1-1/安全劑b-1 300+300 50 40 _一除草劑1-1/安全劑c-1 300+300 70 55__ 除草劑M/安全劑c-3 300+300 45 45 一除草劑1-1/安全劑c-7 300+300 35 25 除草劑1-1/安全劑c-10 300+300 40 38 -装-- C請先聞讀背面之注意事項存填寫本貢) 訂表6施加比例：1 0 0 — 3 0 0克a · 劑1 - 1 ;對牧草雜草/寬葉雜草作用公頃；除草經濟部智慧財產局員工消费合作社印製產物除草劑/安全劑施加比例 [克a.i·/公頃] 作用[%] ECHCG SETVI ABUTH PHBPU 除草劑Μ 300 99 100 98 90 除草劑1-1/安全劑b-1 300+300 99 100 99 90 除，草劑Μ/安全劑C-1 300+300 99 100 98 85 本紙張尺度適用中國國家標準（CNS ) A4規格（210X29*7公釐）經濟部智慧財產局員工消費合作社印製 508216 A7 _ B7 五、發明說明（68) 除草劑1一1:除草劑實施例案號1一1(表1) 安全劑b — 1 : 1 一〔4 一（2 —甲氧基苯甲醯氨磺醯基 )苯基〕一3—甲基尿素安全劑c 一 1 : 2 —甲氧基一 N —〔4一（2 —甲氧基苯甲醯氨磺醯基）苯基〕一乙醯胺安全劑c 一 3 : N —〔4 一（2 —甲氧基苯甲醯氨磺醯基 )苯基〕一環丁烷一羧醯胺安全劑c — 7 : N —〔4 一（2 -氯苯甲醯氨磺醯基）苯基〕-環丙烷羧醯胺安全劑c — 10 ·· N —〔4 一（2 —三氟甲氧基苯甲醯氨磺醯基）苯基〕-環一丙烷羧醯胺 E C H C G ： Echinocloa crus galli A B U Τ Η :向麻 PHBPU:圓葉牽牛 S E Τ V I :狗尾草 1.2 幼苗出土後單子葉及雙子葉的有害植物及有用植物的種子或地下莖放置於直徑9至13公分的含沙壤土鍋中及覆蓋著土壤。再者，對於米測試，米植物及於此有用的莊稼植物中爲不想要的有害植物於水浸的土壤中生長。於三-葉階段，即在實驗設定後大約三週，不同的除草劑及安全劑劑量，配爲可乳化的濃縮物或粉末，以水性分散劑或懸浮劑或乳化劑形式以3 0 0至8 0 0 I水/ h a (轉換）的施加比本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -71 - I I I 1 I I I « — — — — — — I— (請先閱讀背面之注意事項再本頁)Jilf bath 88120184 patent application Chinese specification amendment page July 90, Republic of China 5. Amendments to the invention (Table 5 Application ratio: 200,400 grams a agent 1 to 1; maize hectare; except for the first product herbicide / Safety agent application rate [gram ai // ha1 Toxic plant Yuyu variety Felix: Shujing [%] Variety herbicide 1-1 400 85 80 Herbicide 1-1 300 85 85 ___- Herbicide 1-1 200 78 78 Herbicide 1-1 / safety agent b-1 300 + 300 50 40 _ one herbicide 1-1 / safety agent c-1 300 + 300 70 55__ herbicide M / safety agent c-3 300 + 300 45 45 one herbicide 1-1 / safety agent c-7 300 + 300 35 25 Herbicide 1-1 / safety agent c-10 300 + 300 40 38 -pack-C Please read the notes on the back first and fill in this tribute) Order form 6 Application ratio: 1 0 0 — 3 0 g a · Agent 1-1; hectare effect on forage weeds / broad-leaved weeds; herbicide / safety agent application ratio of printed products produced by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Weeding and Economic Affairs [Gram ai // ha] Effect [%] ECHCG SETVI ABUTH PHBPU Herbicide M 300 99 100 98 90 Herbicide 1-1 / safener b-1 300 + 300 99 100 99 90 In addition, herbicide M / safener C -1 300+ 300 99 100 98 85 This paper size is in accordance with Chinese National Standard (CNS) A4 (210X29 * 7mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 508216 A7 _ B7 V. Description of the invention (68) Herbicide 1 1 1 : Herbicide Example No. 1-1 (Table 1) Safener b — 1: 1-[4-((2-methoxybenzylsulfamoyl) phenyl]] 3-methylurea safener c 1: 2 -methoxy-N-[4-((2-methoxybenzylsulfamoylsulfonyl) phenyl] -ethanamide safener c-3: N-[4-(2- Methoxy benzamidinesulfamoyl) phenyl] monocyclobutane-carboxamidine safener c — 7: N — [4 mono (2-chlorobenzylaminosulfamoyl) phenyl] -cyclopropane Carboxamide safety agent c — 10 ·· N — [4-mono (2-trifluoromethoxybenzylsulfamoyl) phenyl] -cyclomonopropanecarboxamide EHCCG: Echinocloa crus galli ABU Τ Η: Xiang Ma PHBPU: Morning Glory SE VT VI: Dogtail 1.2 Monocotyledonous and dicotyledonous harmful plants and seeds or useful plant seeds of underground plants after unearthed on sandy loam with a diameter of 9 to 13 cm In the pot and covered with soil. Furthermore, for the rice test, rice plants and crop plants useful herein are unwanted harmful plants growing in flooded soil. In the three-leaf stage, that is, about three weeks after the experimental setting, different herbicide and safener doses are formulated as emulsifiable concentrates or powders in the form of aqueous dispersants or suspensions or emulsifiers from 300 to 8 0 0 I water / ha (conversion) application ratio than the paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) -71-III 1 III «— — — — — — I— (please first (Read the notes on the back page)

508216 r~ ί * \ j Λ、 σ Α7 Β7 η ^iE| 五、發明説明（69) 例噴灑至植物的綠色部分或，於米測試中，亦注入灌溉水。爲了成長植物，於最理想的條件下將鍋保持於溫室中。在處理後2 - 3週視覺地評估對有用植物及有害植物的損害。測試結果編輯於表7至9。表7施加比例：1〇〇 — 3〇Q克劑3 - 1 ;小麥公頃；除草經濟部智慧財產局員工消费合作社印製產物？ ’除草劑/安全劑劑量 [公·斤a.i./公頃] ----1 損害[%] 小麥（品種Ralle) 除草劑3-1 300 40 除草劑3-1 200 ——^ 35 除草劑3-1 100 30 除草劑3-1/安全劑II-9 300+150 10 除草劑3-1/安全劑II-9 200+100 5 除草劑3-1/安全劑II-9 100+50 0 除草劑3-2 300 45 除草劑3-2 200 ~-----^ 30 除草劑3-2 100 30 除草劑3-2/安全劑II-9 300+300 10 除草劑3-2/安全劑II-9 200+200 0 除，草劑3-2/安全劑Π-9 100+100 0 裝！ f請先閱讀背面之注意事¾再填寫本頁) 訂 Φ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 508216508216 r ~ ί * \ j Λ, σ Α7 Β7 η ^ iE | 5. Description of the invention (69) Example: Spraying on the green part of the plant or, in the rice test, also injecting irrigation water. In order to grow plants, the pot is kept in a greenhouse under optimal conditions. Visually assess damage to useful and harmful plants 2-3 weeks after treatment. The test results are compiled in Tables 7 to 9. Table 7 Application ratios: 100-300 grams of agent 3-1; wheat hectares; weeding products printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs? 'Dosage of herbicides / safeners [kg · ai / ha] ---- 1 Damage [%] Wheat (variety Ralle) Herbicide 3-1 300 40 Herbicide 3-1 200 —— ^ 35 Herbicide 3- 1 100 30 Herbicide 3-1 / safener II-9 300 + 150 10 Herbicide 3-1 / safener II-9 200 + 100 5 Herbicide 3-1 / safener II-9 100 + 50 0 Herbicide 3-2 300 45 Herbicide 3-2 200 ~ ----- ^ 30 Herbicide 3-2 100 30 Herbicide 3-2 / safener II-9 300 + 300 10 Herbicide 3-2 / safener II -9 200 + 200 0 In addition, herbicide 3-2 / safener Π-9 100 + 100 0 Pack! f Please read the notes on the back ¾ before filling out this page) Order Φ This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) 508216

產物施加比例植物毒性至= Ξ蜀黍[%] 除草劑/安全劑 [克a.i./公頃1 品種Felix ^4Dea 除草劑1 -1 100 13 ^. 15 除草劑1 -1 300 45 30 除草劑1-1/安全劑b-1 300+300 13 3 除草，ϋ 1-1/安全劑c-1 300+300 5 18 除草劑1-1/安全劑II-9 300+300 10 20 -裝— f請先閲讀背面之注意事項再填寫本頁) 表9施加比例·· 5 0 0克a · i · /公頃；除草劑3〜1 ;玉蜀黍產物除草劑/安全劑施加比例 [克a.i./公頃1 植物毒性至品種Felix 玉蜀黍[%] 品種Dea 除草劑3-1 500 23 15 除草劑3-1/安全劑c-1 500+500 10 0 除草劑3-1/安全劑II-9 500+500 5 0 除草劑3-1/安全劑II-9 500+1000 0 0 除，草劑1 一 1 :除草劑實施例案號1 一 1 (表1 ) 除草劑3 — 1 :除草劑實施例案號3 — 1 (表3 ) 除草劑3 - 2 :除草劑實施例案號3 - 2 (表3 ) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -訂經濟部智慧財產局員工消費合作社印製 /% 1X 2 8 o 5 A7 ___B7___ 五、發明說明（71 ) 除草劑3 - 2 :除草劑實施例案號3 - 2 (表3) 安全劑I I 一 9 : 5，5 —二苯基一 2 -異惡唑啉一 3 — 羧酸乙酯安全劑b — 1 : 1 —〔4 一（2 —甲氧基苯甲醯氨磺醯基 )苯基〕一3—甲基尿素安全劑c 一 1 : 2_甲氧基一N —〔4 — (2 —甲氧基苯甲醯氨磺醯基）苯基〕一乙醯胺 2·田野實驗於8至1 0平方公尺的土地上進行田野實驗，及於2 至4個反疊中進行每個實驗。在已播種莊稼植物之後，測試製備施加於幼苗出土前，或於2 - 6葉階段，利用土地噴霧器。噴霧體積爲1〇〇 - 300 I水/ha;利用平坦-噴射噴嘴於壓力爲2 - 3巴下施加。利用視覺評分完成評估。對莊稼植物或於寬葉雜草/牧草雜草的影響則以與未處理的控制土地比較使用百分比程度（〇 — 1 〇〇 % )評估。在施加之後，評估植物3 - 4次其區間約在施加之後14、28、42天。結果顯示平均超過2 — 4個反疊。通常，於玉蜀黍的實例中莊稼損害可接受上至約1 5 %。抗雜草作用顯示> 6 0 %的效力。從播種直到實驗推斷，它們曝露至自然的天氣條件（沉澱、溫度、大氣濕度、日曬），如它們爲實驗場址的特徵。測試結果編輯在表1 0至1 3 ( d a t :在處理之後的天數）。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） - 74- (請先閱讀背面之注意事項 --- 寫本頁) n ·ϋ 1_1 1 · mMmt Biv ϋ eKmmm · 經濟部智慧財產局員工消費合作社印製 508216 J J7 / ........ ' — —f—*~·^—1 / *™T 、亡ar.Tv^· 五、發明説明（72) 表1 0田野試驗：於4 -葉階段施加，玉蜀黍（幼苗出土後）產物除草劑/安全劑施加比例 [克a.i·/公頃] 植物毒性3 14 dat [玉蜀黍[% ] 31 dat 除草劑1 -1 105 35 12 除草劑1-1/安全劑ΙΙ-9 105+100 7 0 安全劑ΙΙ-9 100 0 0 -裝-- (請先閲讀背面之注意事項再填寫本頁) 表1 1田野試驗：於4 -葉階段施加，玉蜀黍產物除草劑/安全劑施加比例 [克a.i·/公頃] 植物毒性至 14 dat 玉蜀黍[% ] 31· dat 除草劑1-1 50 42 18 除草劑1-1/安全劑II-9 50+120 8 2 安全劑II-9 120 0 0 、11 Φ 經濟部智惡財產局員工消费合作社印製表1 2作用於牧草雜草/寬廣-遺留雜草（幼苗出土後）產物除草劑/安全劑施加比例 [克a.i·/公頃] 植物毒性玉蜀黍 :至[% 小黍 ] 狗尾草向麻除草劑1-1 105 35 75 75 72 除草劑M/安全劑II-9 105+100 7 72 83 73 安全劑II-9 100 0 0 0 0 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 508216 丨㈣參”：五、發明説明（73 ) 表13含磺醯基尿素之混合物（幼苗出土後）產物除草劑/安全劑施加比例 [克a.i·/公頃] 植物毒性至 14 dat 玉蜀黍[% ] 42 dat 除草劑1 -1 50 42 18 除草劑2 120 13 7 除草劑1 -1 +除草劑2 + 安全劑II-9 50+120+120 10 5 安全，!ί ΓΙ-9 120 0 0 (請先閱讀背面之注意事項再填寫本頁) 除草劑1 一 1 :除草劑實施例案號1 一 1 (表1 ) 除草劑 2 : N，N —二甲基一2 —〔 3 — ( 4，6 —二甲氧基嘧啶一 2 -基）脲基磺醯基〕—4 —甲醯基胺基苯醯胺安全劑I I 一 9 : 5，5 -二苯基—2 -異惡唑啉—3 — 羧酸乙酯經濟部智慧財產局員工消黃合作社印¾ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Product application ratio phytotoxicity to = glutinous [%] herbicide / safener [gram ai / ha 1 variety Felix ^ 4Dea herbicide 1 -1 100 13 ^. 15 herbicide 1 -1 300 45 30 herbicide 1-1 / Safe agent b-1 300 + 300 13 3 herbicide, ϋ 1-1 / safe agent c-1 300 + 300 5 18 herbicide 1-1 / safe agent II-9 300 + 300 10 20 -pack — f first Read the notes on the reverse side and fill in this page) Table 9 Application Rates ·· 500 g a · i · / ha; Herbicides 3 ~ 1; Maize product herbicide / safener application rate [g ai / ha 1 Phytotoxicity To variety Felix Maize [%] Variety Dea Herbicide 3-1 500 23 15 Herbicide 3-1 / safener c-1 500 + 500 10 0 Herbicide 3-1 / safener II-9 500 + 500 5 0 Herbicide Agent 3-1 / Safety agent II-9 500 + 1000 0 0 In addition, herbicide 1-11: Herbicide example No. 1-11 (Table 1) Herbicide 3-1: Herbicide example No. 3— 1 (Table 3) Herbicide 3-2: Herbicide Example Case No. 3-2 (Table 3) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm)-Ordered by the Intellectual Property Bureau of the Ministry of Economic Affairs for employee consumption Printed by the cooperative /% 1X 2 8 o 5 A7 ___B7__ _ V. Description of the invention (71) Herbicide 3-2: Herbicide Example No. 3-2 (Table 3) Safener II-9: 5,5-diphenyl-2-isoxazoline-3-3 Ethyl carboxylate safener b — 1: 1 — [4-((2-methoxybenzylsulfamoyl) phenyl)] 3-methyl urea safener c—1: 2-methoxy— N — [4 — (2-Methoxybenzylsulfamoyl) phenyl] monoacetamide 2. Field experiments Field experiments were performed on 8 to 10 square meters of land, and 2 to 4 Each experiment was performed in eight inversions. After the crop plants have been sown, the test preparation is applied before the seedlings are unearthed, or in the 2-6 leaf stage, using a land sprayer. The spray volume was 100-300 I water / ha; it was applied with a flat-jet nozzle at a pressure of 2-3 bar. Evaluation is done using visual scoring. The effect on crop plants or broadleaf weeds / grass weeds was evaluated as a percentage of use (0-100%) compared to untreated control land. After application, the plants were evaluated 3-4 times with intervals approximately 14, 28, and 42 days after application. The results show an average of more than 2-4 overlaps. Generally, crop damage is acceptable up to about 15% in the case of maize. The anti-weed effect shows an effect of> 60%. From seeding to experimental inference, they are exposed to natural weather conditions (precipitation, temperature, atmospheric humidity, sunlight), as if they were characteristic of the experimental site. The test results are compiled in Tables 10 to 1 3 (d a t: days after processing). This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm)-74- (Please read the notes on the back --- write this page) n · ϋ 1_1 1 · mMmt Biv ϋ eKmmm · Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives 508216 J J7 / ........ '— —f— * ~ · ^ —1 / * ™ T ，亡 ar.Tv ^ · V. Description of Invention (72) Table 10 Field test: applied at the 4-leaf stage, maize (after seedlings are unearthed) Product herbicide / safener application ratio [gram ai // ha] Phytotoxicity 3 14 dat [Maize [%] 31 dat Herbicide 1 -1 105 35 12 Herbicide 1-1 / safener Ι-9-9 105 + 100 7 0 safener Ι-9-9 0 0 0 -pack-(Please read the precautions on the back before filling this page) Table 1 1 Field test: Applied at the 4-leaf stage, maize product herbicide / safener application ratio [g ai · / ha] Phytotoxicity to 14 dat Maize [%] 31 · dat herbicide 1-1 50 42 18 Herbicide 1-1 / safe Agent II-9 50 + 120 8 2 Safener II-9 120 0 0, 11 Φ Printed by the Consumer Cooperatives of the Intellectual Property Office of the Ministry of Economic Affairs 1 2 Action on forage weeds / broad-legacy weeds ( After the emergence of the seedlings) Product herbicide / safener application ratio [gram ai // ha] Phytotoxic maize: to [% barberry] Dogtail to hemp herbicide 1-1 105 35 75 75 72 Herbicide M / safener II- 9 105 + 100 7 72 83 73 Safener II-9 100 0 0 0 0 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 508216 丨㈣ginseng ”: 5. Description of the invention (73) Table 13 Mixture containing sulfonylurea (after seedling emergence) Product herbicide / safener application ratio [g ai · / ha] Phytotoxicity to 14 dat Maize [%] 42 dat Herbicide 1 -1 50 42 18 Herbicide 2 120 13 7 Herbicide 1 -1 + Herbicide 2 + Safener II-9 50 + 120 + 120 10 5 Safe!! ΓΙ-9 120 0 0 (Please read the precautions on the back before filling this page) Herbicide 1 1: 1: Herbicide Example No. 1-1 (Table 1) Herbicide 2: N, N-dimethyl-1 2- [3-(4,6-dimethoxypyrimidine-2 -yl) ureido Sulfonyl] -4-methylamidoaminobenzamide safener II-9: 5,5-diphenyl-2-isoxazoline-3—carboxylic acid ethyl ester Ministry of Economic Affairs Printed by the staff of the Hui Property Agency, Co-operative Yellow Cooperative ¾ This paper size applies to China National Standard (CNS) A4 (210X297 mm)

Claims

508216 A8 B8 C8 D8% Application ## Annex 2 (a): No. 8 8] _ 2 〇i 8 No. 4 Patent Application Chinese Application for Patent Scope Amendment July 1990 Revision 1 · A combination with herbicidal activity Compound, which includes a mixture of the following composition: One or more compounds of formula (I) with herbicidal activity: 〇 \ r Ο) (Please read the notes on the back before filling this page) where v is selected from (VI) and (V3) group R Ο (V1)

R · (R5),-(V3), 〇-nnnnnnn 口 V · ΜΗ MM mm amv ax — · Α Economy Zou intellectual property staff 01 consumption ^ 阼 ^ The symbols and superscripts have the following meanings: R Is argon or (C 1 -C 4) one courtyard; R 1 is hydrogen, (Cl-C4)-courtyard or (C3-C8)-ring courtyard R5 is (Cl-C4)-alkyl; R 6 Is a hydroxyl group; R 9 is the same or different, and is nitro, (c 1-c 4)-courtyard, this paper size is applicable to China National Standard (CNS) A4 (210 X 297 male 4) 508216 A8 B8 C8 D8t, patent application scope halogen, (Ci-CO-haloalkyl, (Ci-CO-haloalkoxy), (Ci-Cd) -alkanesulfonyl, or (Ci-Cd) -sulfuryl group; 1 is Integer from 0 to 2; Q is 2 or 3; and B ·-detoxifying effective amount of one or more of the following safe agents: a) Compounds of formula (II), (Please read the precautions on the back before filling this page )

The symbols and superscripts have the following meanings: η 'is a natural number from 0 to 2; W is a heterocyclic group of (W1) or (W4), and is printed by the Consumer Cooperative of Qi Zou Intellectual Property Bureau

(W1) (W4) 1Ή is 0 or 1, and R 1 7 is halogen; This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -2-nnn I »ϋ n 一, n ϋ n mmmme ϋ nn II n ϋ nnn an ϋ nn nn ϋ n «I n 508216 A8 B8 C8 D8 6. Application scope of patent R 1 8 is 0RRRR is hydrogen or (C 1 is hydrogen or (C 1 C 4)) C 4) a radical; R is the same or different and is a hydrogen C 1-C 4) alkyl or substituted or unsubstituted phenyl; b) N-fluorenylsulfonium of formula (V) Amine and its salts-, 31 R 3C

N

S00—N (V) (Please read the notes on the back before filling in this page) -0 〇 Where R is hydrogen, (Cl-C4)-academy-amine CC-a-oxygen-(CC 4)- College base; order --------- line of the RRR is hydrogen or (C i -C 4) -alkyl; is ammonia or (Cl-C4)-college base; the same or different, and is ( CC alkoxy

Member of the Economic Zou Intellectual Property Bureau 1-Consumer ^ 1? Printed t is an integer from 0 to 2; Includes stereoisomers and salts commonly used in agriculture, but excludes compounds of formula (I) (where V is V3) and A mixture of a safener of formula (II) (where W = W1 or W4, where m '= 1). 2. The composition with herbicidal activity as described in item 1 of the scope of patent application, wherein the weight ratio of herbicide: safety agent is 1: 1 to 0. This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297). (Centi) -3- 508 216 A8 B8 C8 D8 6. The scope of patent application is 10 0: 1. 3. The herbicidally active composition according to item 1 of the patent application scope, which additionally includes other herbicides. 4. The composition with herbicidal activity according to item 3 of the patent application scope, wherein the other herbicide is sulfonylurea. 5. A method for controlling harmful plants in useful crop plants, which comprises using an herbicidally effective amount of one or more of the herbicidally active compositions such as those in claims 1 to 4 to the harmful plants and crop plants , Plant seeds, or areas where plants grow. 6. The method of claim 5 in which the plant line is selected from the group consisting of maize, wheat, rye, barley, oats, rice, sorghum, cotton, and soybeans. 7. The method of claim 5 or 6, wherein the plant is a genetically modified plant. 8-The herbicidal composition according to item 1 of the patent application ', which is used to control harmful plants in useful crop plants. (Please read the precautions on the back before filling in this page.) 4-¾ member of the Ministry of Economic Affairs x. ^ F 合咋 if 设 -4- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) )