TW505676B - Stabiliser combination for chlorine-containing polymers - Google Patents

Abstract

A stabiliser combination, mainly for PVC, is described, comprising (A) at least one compound of formula I wherein R*l and R*2 are each independently of the other Cl-C12alkyl, C3- C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 Cl-C4alkyl, Cl-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 Cl-C4alkyl, Cl-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*l and R*2 may additionally be hydrogen and Cl-C12alkyl, and Y is S or O, and (B) at least one compound from the following groups: (B1) perchlorate compounds, (B2) glycidyl compounds, (B3) beta-diketones and beta-keto esters, (B4) dihydropyridines and polydihydropyridines, (B5) polyols and disaccharide alcohols, (B6) sterically hindered amines (tetraalkylpiperidine compounds), (B7) alkali aluminosilicates (zeolites), (B8) hydrotalcites, (B9) alkali aluminocarbonates (dawsonites), (B10) alkali- (or alkaline earth-) carboxylates, -(bi)carbonates or -hydroxides, (B11) antioxidants and lubricants and (B12) organotin stabilisers.

Description

505676. A7 V. Description of the invention (/) The present invention relates to a stabilizer composition 'comprising a compound of formula I shown below 1 M and at least one substance selected from the group consisting of: perchlorate' epoxypropyl compound, / 3-dione, / 3-fluorenyl ester, dihydropyridine, polydihydropyridine, polyhydric alcohol, disaccharide alcohol, sterically hindered amine (tetraalkylpiperidine compound), alkali metal aluminosilicate, Hydrotalcite and alkali metal aluminate carbonate (sodium aluminate), alkali metal (or alkaline earth metal) carboxylate 'monocarbonate (hydrogen salt), hydroxide, antioxidant' lubricants or organotin compounds; It is suitable for stabilizing chlorinated polymers, especially P VC. P VC can be stabilized with many additives; lead 'barium and cadmium compounds are particularly suitable for this purpose', but its use is controversial today for ecological reasons or because of its heavy metal content (cf. “Kunstoffadditive” (Plastics additives), R. Gachter / H. Muller, Carl Hanser V er 1 ag, 3rd Edition, 1 9 8 9 pages 303-311 and `` Kunststoff Handb li ch PVCW (Plastics Handbook PVC), Volume 2/1, W , Becker / D. Braun, Carl Hanser Ver 1 ag, 2nd Edition, 1 9 8 5, pages 531-538; and printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page)

Kirk-Othmer: Encyclopedia of Chemical Technology ", 41, h Ed · 1 9 9 4, V o 1. 12, Heat Stabilizers p. 1 0 7 1-1 Q 9 1). So look for other lead, barium and An effective stabilizer and stabilizer composition for cadmium. Compounds of formula I have been described in DE — PS 1, 694,873, EP-65,934 and EP-41, 4 7 9 and can be M or more It is obtained through a variety of conventional procedures. A) The compound of formula I has been found: -5-This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (> 〇R * R * 〇 (I) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs, where R comes! C and C 2 alkyl, C 3 —CS alkenyl, and C 5 are unrelated to R 2 — CS cycloalkyl, which is unsubstituted or substituted with 1 to 3 Ci-C4 alkyl, Ci-C4 alkoxy, C5-C8 cycloalkyl or hydroxyl or chlorine atom, or C 7 —C 9 phenylalkyl, which is unsubstituted or consists of 1 to 3 C \ -C4 alkyl, C i -C 4 alkoxy, C 5-C 8 ring on the benzene ring Alkyl or substituted with a radical or chlorine atom And R 2 and R 2 may additionally be hydrogen, C i -C i 2 alkyl, and Y is S or 0, the compound of formula I may be combined with at least one group selected from the group consisting of perchloric acid Salt compounds and / or epoxypropyl compounds and / or, monodione and monoester and / or, dihydro Dtfc pyridine and polydihydropyridine and / or, polyhydric alcohols and disaccharide alcohols and / or, stereo positions Hindered amine (tetraalkylpiperidine compound) and / or, alkali metal aluminosilicate (zeolite) and / or, 6 —η — This paper size applies to China National Standard (CNS) A4 (210X297 mm) ( Please read the precautions on the back before filling in this page.) Clothing. Order d Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention ()) Hydrotalcite and / or, Alkali metal aluminum carbonate Bauxite) and / or, alkali metal (or alkaline earth metal-) carboxylate, -carbonate (hydrogen salt) or a hydroxide and / or, antioxidants and lubricants and / or organotin compounds ;. Its purpose is to stabilize chlorine-containing polymers, especially PVC. For compounds of formula I: Ci-C4 alkyl is, for example, methyl Ethyl, n-propyl, isopropyl, n-, iso-, sec-, or tert-butyl. C i -C i 2 alkyl is as defined above, for example, pentyl, hexyl, heptyl, octyl , 2-ethylhexyl, isooctyl, decyl, nonyl, undecyl or dodecyl. C i -C 4 alkoxy is, for example, methoxy, ethoxy, propoxy, isopropoxy, butoxy or isobutoxy. C 5 -C S cycloalkyl is, for example, cyclopentyl, cyclohexyl, cycloheptyl or cyclooctyl. C 7 —C 9 phenylalkyl is, for example, benzyl, 1- or 2-phenylethyl, 3-phenylpropyl, α, α-dimethylτyl, or 2-phenylisopropyl, Preferred is benzyl. When a phenylalkyl cycloalkyl moiety or a phenyl moiety is substituted, it is preferably substituted by two or one substituents, especially by C 1, hydroxyl, methyl or methyl Substituted with oxy. This paper size applies to Chinese National Standard (CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention (f) C 3-C 6 alkenyl is, for example, vinyl, allyl, allyl, 1-butenyl or 1-hexenyl, preferably allyl base. Preferred compounds of formula I are: wherein R to 1 and R m are unrelated to each other are C i -C 4 alkyl and hydrogen. It is particularly preferred that Rmi and Rmi are the same and are methyl, ethyl, propyl, butyl or allyl, or they are different and are ethyl and allyl. In order to stabilize the chlorinated polymer, the amount of the component A) compound is advantageously from 0 ♦ Ο 1 to 1 ◦% by weight, preferably from 0. 05 to 5% by weight, especially from 0. 1 to 3% by weight. The B) group-based compounds mentioned above are as listed below: Perchlorate compounds: Examples are compounds of formula M (C 1 0 4) η, where M is L I,

Na, K, Mg, Ca, Sr, Zn, Al, La or Ce. Depending on the value of M, n is 1, 2 or 3. Perchlorate can be combined with alcohols (polyols, cyclodextrin) or ether or ester alcohols. Ester alcohols also include polyol partial esters. Also suitable for polyhydric alcohols or polyhydric alcohols are their dimers, trimers, oligomers, and polymers, such as various one-two, three-one, four-one, and polyethylene glycol employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative (please read the notes on the back before filling out this page), and dione and tetra-pentaerythritol or polyvinyl alcohol. Perchlorate can be introduced in a variety of conventional ways, such as K-salts or aqueous solutions applied to substrates, such as PVC, calcium carbonate, zeolites, or hydrogenated talc, or a combination of chemical reactions and hydrogenated talc. Glycerol monoether and glycerol monothioether are the preferred polyol partial ethers. Other types are described in EPA — 3 9 4, 547, EPA — 457, 4'7 1 and W094 / 242 0 0 -8- This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) 505676

A

7 B Explanation

〇 〇 From the example of ο, it is especially used for its amount, so that 3 is enough, s 1 salt ο acid · chloride ο pass the benefit of--|| \ 5 amount to 1 part by weight ο 2 ο to. ) Group calculation basis: C, C, V, V: the total content of the ring P, the heavy group, the propyl group, the oxygen, and the ring. 1—I According to CHIR1

CH

-R 2 丨 R (Please read the notes on the back before filling this page) It is directly bonded to the carbon, oxygen or sulfur atom, where R i and R 3 are both hydrogen and Rz is hydrogen or methyl , And n = 0, or Ri and R3 — starting with a CHz — CH2 — or —CHz CHz CHz —, in this case R 2 is hydrogen and η = 0 or 1. I) Glycidyl and monomethylglycidyl esters, obtained from the reaction of a compound containing at least one carboxyl group in the molecule and epichlorohydrin, or glyceryl dichlorohydrin or -methyl epichlorohydrin. This reaction is preferably carried out in the presence of a base. The compound containing at least one carboxyl group in the molecule is suitably a fatty bar carboxylic acid. Examples of these carboxylic acids are glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid or dimerization Or tripolymerized linoleic acid, acrylic acid, methacrylic acid, hexanoic acid, caprylic acid, lauric acid, myristic acid, hexadecanoic acid, octadecanoic acid, and nonanoic acid, and the acids mentioned in the case of the aforementioned organic zinc compounds. However, it is also possible to use cycloaliphatic acid. For example, the size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm). Printed by the Ministry of Economic Affairs. A7 B7 printed by the Consumer Standards Cooperative of the Central Bureau of Standards 5. Description of Invention (i?), Tetrahydropeptide, 4-methyltetrahydrophthalic acid, hexahydropeptide or 4-methylhexahydrotitanate. It is also possible to use aromatic carboxylic acids, such as benzoic acid, titanic acid, isopeptide, trimellitic acid or pyromellitic acid. It is also possible to use carboxyl-terminated adducts, such as trimellitic acid and polyols, such as glycerol or 2,2-bis (4-hydroxycyclohexyl) propane. Other epoxides that can be used in the present invention are found in EP-Q, 5 Q 6, 6 1 7. II) Glycidyl or 3-methylglycidyl, obtained from a compound containing at least one free alcoholic hydroxyl group and / or phenolic hydroxyl group and an appropriately substituted epichlorohydrin under alkali metal conditions, or It is prepared by reacting in the presence of an acid catalyst followed by alkali treatment. This type of ether is derived, for example, from acyclic alcohols such as ethylene glycol, diethylene glycol and higher poly (oxyethylene) glycols, propane-1,2-diol or poly ( Oxypropylene) diol, propane-1,3-diol, butane-1,4-monodiol, poly (oxytetramethylene) diol, pentane-1,5-diol, hexane-1 , 6-diol, hexane-2,4,6-triol, glycerol, 1,1,1, trimethylene propane, bistrimethanol propane, pentaerythritol, sorbitol, and polyepichlorohydrin , Butanol, pentyl alcohol, pentanol, or derived from monofunctional alcohols such as isooctanol, 2-ethylhexanol, isodecanol and C 7-C 9 alcohols and C 9 -C ii alkanol mixtures And get. However, it can also be derived from, for example, cycloaliphatic alcohols like 1, 3 mono or 1, 4-dihydroxycyclohexane, bis (4-hydroxycyclohexyl) methane-1 0-(Please read the back (Please fill in this page again)

This paper size applies to China National Standard (CNS) A4 (210X 297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (1), 2, 2 — double (: 4 — hydroxyl ring) Hexyl) propane or 1,1-bis (hydroxymethyl) cyclohexyl-3-ene, or it may contain aromatic rings like N, N-bis (2-hydroxyethyl) aniline or p, p'-bis (2-Hydroxyethyl'amino) diphenylmethane. These epoxides can also be derived from mononuclear phenols, such as from phenol, resorcinol, or hydrofluorene; or they are based on M polycyclic phenols, such as bis (4-hydroxyphenyl) methane, 2, 2-bis (4-monohydroxyphenyl) propane, 2,2-bis (3,5-dibromo-4 4-hydroxyphenyl) propane, 4,4'-dihydroxydiphenyl block, or K-phenol and formaldehyde under acidic conditions Based on condensation products like phenolic resin. Examples of other possible terminal epoxides are: glycidyl 1-naphthyl ether, glycidyl 2-phenylphenyl ether, 2-bisphenyl glycidyl ether, N — (2, 3 — Epoxypropyl) titanium imine and 2,3-epoxypropyl-4-methoxyphenyl ether. III) (N-epoxypropyl) compound derived from the dehydrochlorination of the reaction product of epichlorohydrin and an amine, which contains at least one amine hydrogen atom. These amines, for example, aniline, N-methylaniline, toluidine, n-butylamine, bis (4-aminoaminophenyl) methane, m-phenylenedimethyldiamine or bis (4-methylamine) Phenyl) methane, but may also be N, N, 0-triglycidyl-m-aminophenol or N, N, 0-triglycidyl-p-aminophenol. However, (N- Epoxypropyl) compounds can also include N, N, 112, N, N,, N "-5-MN, N /, -11-Naphthalene Urea. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the notes on the back before filling out this page) • Clothing · Order 505676 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (t) N ", N / " —Tetraglycidyl derivative, such as ethylene urea or 1,3-propaneurethane, and N, N of ligustral urea > —Glycidyl derivative, like 5,5 —dimethyl Urea or diol biurea and triglycidyl isofluurate. IV) S-glycidyl compounds, such as di-s-glycidyl derivatives, derived from dithiols, such as ethane-1,2-dithiol or bis (4-mercaptomethylphenyl) )ether. ~ V) containing an epoxide of the group I of formula I, where R i and R 3 —are —C Η 2 —C Η 2 — and η is 0, an example is bis (2,3 —epoxycyclopentane Alkyl) ether, 2,3-epoxycyclopentylepoxypropyl ether or 1,2-bis (2,3-epoxycyclopentyloxy) ethane. A compound comprising a group of the formula I, in which R i and R 3 are taken together to form a C Η 2 —C Η 2 —, and η is 1. An example is (3,4-epoxy-6-methylcyclohexyl ) (3 '^ 4 / monoepoxy-6'-methylcyclohexyl) methyl methyl ester. Examples of suitable terminal epoxides are (TM stands for ㊣): a) Liquid bisphenol A diglycidyl ether, like A ra 1 dit ® GY 240, Araid it ® GY 250, Araldit ® GY 260, Araldit ® GY 2 6 6, A ra 1 dit ® GY 2 6 0 0, A ra 1 dit ® M Y 7 9 0; b) Solid bisphenol A diglycidyl ether, like A ra 1 dit ® GT 6 0 7 1, A ra 1 dit ® GT 7071, Araldit ® GT 7072, Araldit. ® GT 6 0 6 3, A ra 1 dit ® GT 7 2 0 3, A ra 1 di t.⑬ GT 6 0 6 4, A ra 1 dit ⑬ GT 7304, Araldit ® GT 7004, Araldit ⑬ GT 6084, -12- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page ) Order d Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Invention Description (7)

Araldit ® GT 1 9 9 9, A ra 1 dit ® GT 7 0 7 7, A1, a 1 dit ® GT 8 0 9 7, A ra 1 di t. ® GT 7 0 9 7, A ra 1 dit ® GT 7 0 0 8, A ra 1 dit ⑮ GT 6099, Araldit ⑯ GT 6608, Araldit ® GT 6609, Araldit ® GT 6610; c) Liquid bis F diepoxypropyl ether, like A ra 1 dit ㊣ GY 281, Araldit ⑯ PY 302, Araldit ® PY 306; d) solid polyepoxypropyl side of tetraphenylethane, like CG Epoxy Resin ㊣ 0 1 6 3; e) solid and fatigue polycyclic ring of phenol-formaldehyde phenolic resin Oxypropyl ethers, such as EPN 113 8, EPS 1139, GY 1 1 8 0, PY 3 0 7; f) ο —Solid and liquid polyepoxypropyl ethers of resorcinol-formaldehyde novolac, like ECN 1235, ECN 1273, ECN 1280, ECN 1299; g) liquid epoxypropyl ethers of alcohols, such as S he 11 ® epoxypropyl ether 1 6 2, Araldit⑩ DY 0390, Araldit㊣ DY 0391; h) Tired glycidyl ethers, like She 1 1 ⑮Cardura E para-peptide, trimellitate, Araldit ® PY 284; i) solid heterocyclic epoxy resin (triglycidyl isocyanurate), Like Araldit® PT 810; j) liquid Cycloaliphatic epoxy resins, such as Ar a 1 d i t ® C Υ 1 7 9; k) p-liquid amino N, N, 0 -triglycidyl ether of aminophenols, like Araldit® ΜY0510;

1) Tetraglycidyl-4,4'-methylene benzylamine, or N'-tetraglycidyl diaminophenylmethane, like Araldit ® MY -13- This paper size applies to Chinese national standards ( CNS) A4 specifications (2! 〇x29 < 7 mm) (Please read the precautions on the back before filling out this page) Order printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of Invention (/ D) 7 2 0, Ara 1 dit ® MY 7 21 〇 Preferred epoxides contain two functional groups, however, in principle compounds containing one, three or more functional groups can also be used. Epoxy compounds with aromatic: structure are mainly used, especially epoxy compounds. Mixtures of epoxides of different structures can also be used. Particularly preferred polyfunctional epoxides are K-bisphenol-based diglycidyl ethers, for example based on 2,2-bis (4-hydroxyphenyl) propane (bisphenol A), bis (4-hydroxybenzene Base) methane or a mixture of bis (o- / p-hydroxyphenyl) methane (bisphenol F). The amount of the epoxy compound that can be used is preferably at least 0.1, basically 0 ♦ 1 to 50, conveniently 1 to 30, especially 1 to 25 parts by weight (based on 100 parts by weight of PVC Calculations). Diamidine * / 3 — _ esters. 1,3-dicarbonyl compounds can be linear or cyclic dicarbonyl compounds. A preferred dicarbonyl compound of the following formula is: R 7 iCOCHR ^ -COR ^ where R / i is Ci-C22 alkyl, Cs — Ci0 hydroxyalkyl, (: 2 — C is alkenyl, phenyl, K 0 Η, C i — C 4 alkyl, Ci — C4 alkoxy or halogen-substituted phenyl * C7 — Ci 〇benzene-14- This paper size applies to China National Standard Plum (CNS) A4 (210X297 mm) ( (Please read the notes on the back before filling out this page)

、 1T 505676 A7 B7 V. Description of the invention (印) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and printed on the basis of C &C; C 4 fluorenyl or — — R / S — S — R / 6 or — R / 5 — 〇 — R / β group R / 2 is hydrogen 9 CI — C s Yuan CZ — C i 2 m Phenyl C 7 — C 1 2 heptyl%, C 7 — C 1 0 phenyl or — C 0 — R / 4 group R / 3 has the same definition as R / 1 or C 1 — C 1 8 methoxy 1 R / 4 is C i — C 4 or phenyl R / 5 is C 1 — C 1 S alkyl j and R / 6 is C i — C 1 Z alkyl 5 benzene 5 C 7 — CIS i penyl or C 7 —c 1 0 phenyl alkyl 0 These compounds include hydroxy-containing diones including EP 1 A 3 4 6 S 2 7 9 and Ep 1 A — 3 〇7% 3 5 8 oxadione—and thiadi and US — A — 4 5 3 3 9, 3 8 3 isocyanuric acid-based ketoesters 0 Rhenyl R / 1 and R / 3 can be especially C 1 — C 1 8 alkyl groups such as methyl Ethyl 5 n-propyl > Isopropyl f n-butylt-tert-butylpentylhexyl > heptyloctyl j decyldodecyl% or octadecyl 0 hydroxyalkyl R / 1 and R / 3 can be especially (C Η Zn) η — 〇Η > where η is 5 6 or 70 0 alkenyl R / 1 and R / 3 can be 9 such as vinyl allyl, methyl-15 -(Please read the notes on the back before filling out this page) The size of the paper used in this edition applies to the Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 V. Description of the invention (a single puppet) Dilute propyl, 1 piece Alkenyl, 1-hexenyl or oleyl, preferably allyl. OH—, alkyl-, alkoxy- or halogen-substituted phenyl R / i and R < 3 can be, for example, tolyl, xylyl, tert-butylphenyl, methoxyphenyl , Ethoxyphenyl, hydroxyphenyl, chlorinated phenyl or dichlorinated phenyl. Phenylalkyl R'i and R'3 can be especially benzyl; cycloalkyl or alkylcycloalkyl R'2 and R'3 can be especially cyclohexyl or methylcyclohexyl. Alkyl R'2 can be especially Ci-C4 alkyl, C2-Ci2 alkenyl, and R / 2 can be especially propyl. Alkylphenyl R < 2 can be especially tolyl; phenylalkyl R / z can be especially benzyl. R'2 is preferably hydrogen, and alkoxy R'3 can be, for example, methoxy, ethoxy, butoxy, hexyloxy, octyloxy, dodecyloxy, tridecyloxy , Tetradecyloxy, or octadecyloxy. C i -C i 0 alkylene R / 5 especially C 2 -C 4 alkylene, alkyl R '6 especially C 4 -C i 2 alkyl, for example, butyl, hexyl, octyl, decyl Or dodecyl. Alkylphenyl R / s is especially tolyl; phenylalkyl R'6 is especially benzyl. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page)醯 propyl noodles, Ding 醯 propyl _, heptyl propyl Ⅱ * stearyl donkey acetone, sixteen 焼 donkey propyl noodles, twelve pentyl propyl noodles, 7-tert-nonyl thioheptane-2, 4-dione , Benzamidine propane, benzophenazine methane, dodecane, benzamidine methane, cetane, benzamidine, methane, stearyl benzyl with methane, isooctyl benzamethane, 5-hydroxy Hexylbenzene-18- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (/ 4) Methane, triphenyl Formamidine methane, bis (4-methylbenzyl) methane, benzamidine-p-chlorobenzyl chloride, bis (2-hydroxybenzyl) methane, 4-monomethoxybenzylbenzene Methane, bis (4-methoxybenzidine) methane, 1-benzidine-1, 1-acetamnonane, benzamidine醯 phenylmethane, stearyl-1, 4-methoxybenzyl methane, bis (4-tert-butylbenzyl) methane, benzophenazine, methane (Cyclohexane) methane, bis (trimethylacetamidine) methane, 2-acetamylcyclopentanone, 2-benzylcyclopentanone, methyl diethylacetate, ethyl and allyl esters, benzene Methyl ethyl, methyl ethyl and methyl ethyl ethyl acetate, triethyl ethyl acetate, methyl ethyl acetate, ethyl ethyl, hexyl, octyl, dodecyl or octadecyl , Benzamidine methyl acetate, ethyl, butyl, 2-ethylhexyl, dodecyl or octadecyl ester, and propanyl mono- and butanyl mono-acetic acid C i -C i 8 alkyl esters. Stearyl acetate, ethyl, propyl, butyl, hexyl or octyl esters and polynuclear / 3-esters (described in EP-433, 230) and their dehydroacetic acid and zinc, magnesium or alkali metal salts. The preferred 3-dione compound of the above formula is wherein R > i is Ci-Ci 8 alkyl, phenyl, or phenyl substituted with OH, methyl or methoxy, and C7-Ci benzene Alkyl or cyclohexyl, R / 2 is hydrogen, and R / 3 has one as defined in R / i. The amount of the 1,3-difluorene compound used may be, for example, from 0. 0 1 to 10 parts by weight, conveniently 0 ♦ 0 1 to 3, preferably 0 ♦ 0 1 to 2 parts by weight (based on 1 0 0 parts by weight of PVC calculation) 0 -1 7- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) # 衣.

* 1T 505676

(Please read the notes on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs where T is C i —C 2 2 alkyl, which is unsubstituted, or consists of C i —Ci 8 alkoxy, Ci — Ci S alkyl sulfur, hydroxyl, Acrylic fluorenyloxy, methacryloxy, halogen, phenyl or substituted with naphthyl; C 5 —C i 〇aryl, which is unsubstituted, or by ci A paper size applies Chinese national standards ( CNS) A4 specification (210X297 mm) 505676 A 7 B7 V. Description of the invention (/ f) C i Q alkyl, C i -C 1 S alkoxy or halogen substituted 9 which may also be heterocyclic 9 c 3 — C 1 0 alkenyl i C Η 3 — C 〇—C Η 2-C 0 — 〇R — 5 C Η 3 — C 〇 -C Η 2 — C 〇0 — R /, C Η 3-C ( Ν R / // 2) = C Η One C 0 〇R — or C Η 3 — C (NR / // Z) C Η C 〇 — 〇R / 1 L has the definition 5 as T or One, two or more monovalent anti-m groups 5 selected g unsubstituted or C 1 —C 1 2 fluorenyloxy — 5 C 1 —C 1 2 thioxooxy — C β — C 1 0 aryl — 5 C 1 — C i 2 carboxyl — or hydroxyl — substituted straight or branched bond radicals J m and η are numbers from 0 to 2 0, and k is 0 or 1 9 j Is a number from 1 to 6 and the conditions of j '(k + m + η) > 1 and m + η > 0 must satisfy JR and R / mutually uncorrelated are methylene or phenylene, or one ( -C pH z P — X) tC pH 2 P — type of alkylene, which is unsubstituted or carries C i -C i 2 alkoxy, C i -C i 2 thioalkoxy, C 6 — Ci i aryl, Ci — Ci 2 substituents of carboxyl and hydroxy groups, p is a number from 2 to 18, t is a number from 0 to 10, X is oxygen or sulfur, or when k is When 0 and j &l; l, R and R /-form a direct bond with L-1 9- This paper size applies to China National Standard (CNS) A4 specification (2i0x297 mm) (Please read the note on the back first Please fill in this page again) Order-Printed by the Employees 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (/ ^ 7) R 〃 is hydrogen, or C i — C i 3 alkyl, C 2 — C i 8 alkoxycarbonyl, or C 6 — C i 0 aryl, each of which is Unsubstituted or substituted via one or more C i -C i 2 alkyl, C i -C, 3 alkoxy, halogen or N 0 2 substituents; and the two R 〃 reactive groups are the same or Different, and is hydrogen, Ci-Ci 3 alkyl, Ci — Ci 8 — hydroxyalkyl or Ci — Ci s alkoxyalkyl or together C3 — CS alkylene without interruption or 0 — interruption, Or a linear or branched C 2 -C 2 2 alkenyl group. These compounds are described in more detail in EP-0, 2 8 6, 8 8 7. Thiodiethylene-bis [5-methoxycarbonyl-1,2,6-dimethyl-1,4-dihydroxypyridine-3-carboxylate] is particularly preferred. The (poly) dihydropyridine compound is used in an amount of from 0 ♦ 0 0 1 to 5, preferably from 0 · 0 0 5 to 1 weight percent (based on the weight of the polymer). Polyols, disaccharide alcohols · 'Suitable examples of compounds of this type are: pentaerythritol, dipentaerythritol, tripentaerythritol, bistrimethylolpropane, bistrimethylolethane, ginsylmethylpropane, sorbitol , Sesitol, Isomalt, Lactitol, Licasin (1 ycasi η), mannitol, lactose, maltose, tris (hydroxyethyl) isoazaurate, butadiol (P a 1 atinit ο 1), Tetramethylolcyclohexanol, Tetra-20- This paper size applies to Chinese National Standard (cns) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Order 505676 A7 B7 5 Description of the invention (/ ^) methylolcyclopentanol, tetramethylolcyclopyranol, glycerol, diglycerol, polyglycerol and 1 — 0 — α — D —ethylene glycol —D —mannitol Dihydrate. Diol alcohol is preferred. The amount of the polyhydric alcohol used is, for example, 〇 · 〇 1 to 20 parts by weight, preferably 0 ♦ 1 to 20 parts by weight, especially 0 ♦ 1 to 10 parts by weight, and 10 ◦ parts by weight of P VC As a benchmark. Stereo hindered amines (tetraalkylpyrimidine compounds) can be used in the present invention for stereo hindered amines, and in particular pyridine compounds are well known, especially light stabilizers. These compounds contain one or more groups of the formula: (Please read the notes on the back before filling out this page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs These compounds can be of relatively low molecular weight (< 700) or relatively high molecular weight. The latter case is an oligomer or a polymerization product. Preferred tetramethylpyridine compounds have a molecular weight greater than 700 and are free of ester groups. The following tetramethylpyridine compounds are particularly important stabilizers. In the categories a) to f) under M, a substituent having a subscript in its chemical formula is equivalent to (for technical reasons) a substituent having a superscript in the specification or the description belonging to the definition of the chemical formula. Therefore, for example, in the formula The substituent 〃 R i in (ί I) is equivalent to 〃 R 1 〃 〇a in the description) The compound of formula II: -2 1- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 5 Description of the invention (($) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7

Wherein: η is a number from 1 to 4, preferably 1 or 2, R1 is hydrogen, oxygen, Ci—Ci2 alkyl, C3—Cs alkenyl,

Cs — Cs alkynyl, C7 — Ci2 aralkyl, Ci —Ca alkyl, C 3-C 5 alkenyl, epoxypropyl, or a group of formula C C 2 CH (OH) — Z, where Z is hydrogen, methyl, or phenyl, R 1 is preferably C i -C 4 alkyl, allyl, benzyl, ethenyl or propenyl, and wherein η is 1 and R 2 is hydrogen, Ci —Ci 8 alkyl, which is uninterrupted or interrupted by one or more oxygen atoms, cyanoethyl, benzyl, epoxypropyl, fatty strips, cycloaliphatic, araliphatic, unsubstituted Monovalent reactive group of saturated or aromatic carboxylic acid, carbamic acid or reactive group containing phosphoric acid or monovalent silicon group, preferably aliphatic carboxylic acid reactive group containing 2 to 18 carbon atoms, containing 7 to 15 A cycloaliphatic carboxylic acid having 1 to 3 carbon atoms, α, / 3 —unsaturated epidemic acid containing 3 to 5 carbon atoms, or an aromatic carboxylic acid containing 7 to 15 carbon atoms, and when η is 2, R ζ is C i a C i 2 hospital-22- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention) Supporting group, C 4 -C i 2 olefinic, xylene, aliphatic, cycloaliphatic, aralipid or aromatic dicarboxylic acid divalent reactive group, dicarbamic acid or Containing a discic acid or a divalent silicon-based reactive group, preferably a fatty dicarboxylic acid containing 2 to 36 carbon atoms, a cycloaliphatic or aromatic strip dicarboxylic acid containing 8 to 14 carbon atoms, or Aliphatic, cycloaliphatic: a reactive group of a dicarbamic acid or an aromatic dicarbamic acid containing 8 to 14 carbon atoms, and when η is 3, R 2 is a fatty, cycloaliphatic or aromatic tricarboxylic acid, aromatic Are trivalent carbamate or phosphoric acid-containing trivalent reactive group or tetravalent silicon reactive group, and when η is 4, R 2 is a tetravalent reactive group of aliphatic, cycloaliphatic, or aromatic tetracarboxylic acid. When any substituent is Ci-Ci2, it is, for example, methyl, ethyl, n-propyl, n-butyl, sec-butyl, tert-butyl, n-hexyl, n When octyl, 2-ethyl-hexyl, n-nonyl, n-decyl, n-undecyl or n-dodecyl 3 R 2 is C i -C is, it may be The group groups listed are also n-ten, trisynyl, n-tetradecyl, n-hexadecyl or n-octadecyl. When R 1 is C 3 -C 3 alkenyl, it can be printed by, for example, a consumer cooperative of the Central Standards Bureau of the Ministry of Economics of the Propylene (please read the precautions on the back before filling this page). Allyl, 2-butenyl, 2-pentenyl, 2-hexenyl, 2-octenyl or 4-tert-butyl- 2-butenyl. When R 1 is a C 3 -C 8 alkynyl group, a propynyl group is preferred. When R 1 is a C 7 -C i 2 aralkyl group, phenethyl is particularly preferred, and benzyl is more preferred. When R 1 is a C i -C 3 alkyl group, examples are methylamidino, propionyl-2 3-This paper size applies to China National Standard (CNS) A4 (210X297 mm) Employees of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative printed 505676 A7 B7 V. Description of the invention (/ °) group, butanyl group * octyl group, but preferably ethyl ethoxy group and C3-C5 alkenyl group, a particularly good example is propylene alcohol group. When R z is a monovalent reactive group of monophosphonic acid, examples are acetic acid, hexanoic acid, stearic acid, acrylic acid, methacrylic acid, benzoic acid or / 3-(3,5 -di-tert-butyl-4 -hydroxy Phenyl) monopropionic acid reactive group. When R 2 is a divalent reactive group of a dicarboxylic acid, examples are malonic acid, succinic acid, glutaric acid, adipic acid, suberic acid, sebacic acid, maleic acid, peptidic acid, di Butylmalonic acid, dibenzylmalonic acid, butyl mono (3,5-di-tert-butyl-4 4-hydroxybenzyl) malonate or dicycloheptene dicarboxylic acid reactive group. When R 2 is a trivalent reactive group of a tricarboxylic acid, an example thereof is a trimellitic acid or a nitrogen triacetic acid reactive group. When R 2 is a tetravalent reactive group of a tetracarboxylic acid, an example is a tetravalent reactive group of butane-1, 2, 3, 4 tetrakis (tetracarboxylic acid) or pyromellitic acid. When R 2 is a divalent reactive group of a dicarbamic acid, examples thereof are a hexamethylene dicarbamic acid or a 2,4-tolyl-dicarbamic acid reactive group. The compound under K is an example of such a polyalkylamidine compound: 1) 4-hydroxy-2,2,6,6-tetramethylpyrimidine; 2) 1-allyl-4 4-hydroxy-2,2 , 6,6-tetramethylpyridine; 3) 1-fluorenyl-4 amidyl-2,2,6,6-tetramethylpentamidine 4) 1- (4-tert-butylbutyl 2-butane Alkenyl) 4 —Hydroxy-2 2 -24- This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Order 505676 A7 B7

V. Description of the invention (V; 0 pyridine, I group # 6 6 I group, 4 methyl 2 6 I, 4, € 12 2 # 6 1, group, base 2 A; CD. Oxygen, five €, 醯 1 I Dayton 2 Yang-6 base, water base, methyl 2 I oxygen 6 tetra I 4 brewing, 1 醯 1 燏 2 6 aliphatic propyl,, hard ethyl 2 6 I i; 1 ί, 41σί41 2).) ·). ;), 5 6 group 7 pyridine 8 methyl tetrayl methyl penta-5 biscis,};) ';,}} ο ester 1 ester 3 9 group 1 acid 1 acid group 2 butyl |;, I-based ester 2 tert-benzoic acid , II di 2 di 1 ene-4 2 propionyl hydroxymethyl tetramethyl I 6 6 4 I; pyridyl oxanoate 1 4 I pyridyl methyl tetra-6 6 pentyl 1 4 1 pyridine Ethylmethyltetra-6- 6 6 2 2 r! \ Dihex.V! / I-4 I pyridylmethyltetra-6-6 2 2 di-2 ester 1 acid (Please read the notes on the back before filling this page) Economy Printed by the Consumers 'Cooperative of the Ministry of Standards, Ministry of Standards, Diacid I 2}' ,,} Acid} 4} 3 Ester 4 Di 5 _ 6 1 Acid 1 Dec 1 Pyridine 1 Dec \ 1 / I I 4 I I 6 6 2 2 / IV Diyl I 4 I Pyrimidine # ketopenta I 6 6 2 2 3 ester group, acid propyl 2 diene, decyl 1) 1 丨-6 2- keto tetra I 6 group Ethylpyridinylmethyltetra I 6 6 2 2 This paper size applies to Chinese National Standard (CNS) A4 (210X29? Mm) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (y2 /) 4-yl) peptidic acid ester; 17) 1-propynyl-4 cold-cyanoethoxy-2,2,6,6-tetramethylpyridine; 18) 1-ethynyl-2,2 , 6,6-tetramethylpyridine-4-yl acetate; 1 9) tris (2,2,6,6-tetramethylpyridine-4-yl) trimellitic acid; 20) 1 —Acryloyl-4—fluorenyloxy-2,2,6,6-tetramethylpiperidine; 21) Diethylmalonate di (2,2,6,6—tetramethylpiperidine 1-4 mono) esters; 22) bis (1,2,2,6,6-pentamethylpiperidine-4-yl) dibutyl malonate; 23) butyl mono (2,3-di) 1-tert-butyl-4 monohydroxybenzyl) -malonic acid di (1,2,2,6,6-pentamethylpyridinidine 4-diyl) ester; 24) dibenzyl monomalonate (1,2,2,6,6-Pentamethylepiridin-4-yl) ester; 25) Dibenzyl monomalonate di (1,2) , 3,6-tetramethyl-1,2,6-diethyl-mono-a-4-yl) ester; 2 6) hexane-1 / »6 /-bis (4-aminoformyloxy-1 1- N-Butyl-2,2,6,6-tetramethylpyridine); 27) Toluene-2 '^ 4 7-bis (4-aminocarbamyloxy-1 1-26) This paper size applies to China National Standard (CNS) A4 Specification (210X297 mm) (Please read the precautions on the back before filling this page)

505676

7 7 A B / V

Pyridin ## • 基基} methylpyridine tetramethyl # | tetrayl 6 monomethyl, 6 tetra 6,, I, 6 2 6 2,,,, 2.2 2 6 2, _, (2 radical 2 double (Propane,, _ tri-I ester 2 group, 1 mono-acid I methyl group; phospho-disilazane triphenylene ^.).)) ^).) I 8 group 9 oxy 2 group 3 I 6 6 4 oxygen I 4 pyridylmethyl tetra 4 3 3 4 I pyridyl methyl tetra-6 6 2 2 I propyl ____I I— __ __ Λ I (Please read the notes on the back before filling this page) Acid Radical JIII phosphorobenzene} 4 4 4}} radical} pyridine} radical 2 I 3 4 35 j 3 4 3 3 radical 3 I methylpyridine ·, tetrapyridine-keton 6 methyl-pentamethyl 6 I five, 6 1 2, 6 6, 2, 6 1 2, radical, 2 ethyl 2, radical, 2 hydroxy 1-i! J (; 1 N diester i I; amidine, acid ester I phosphine hydroxy hydroxyl

N order 6 dimethyl tetra-6 3 yl I; propylpyridyloxy hydroxycyclocyclyl propyl hydroxy-2 2 2 6 methyl tetra-6 6 2 2 I hydroxy hydroxy I 4 printed pyridine printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs锨 基 b type 合 合 ib This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 505676

η is a number of 1 or 2, printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, R 1 is as defined in a) above, R 3 is hydrogen C 1 -C 1 2 alkyl > C 2-C hydroxyalkyl i C-C 7 cyclohexyl f C 7 —C 8 aralkyl group> C 2 — C i 8 fluorenyl C 3 — C Benzene group or benzyl group 5 and when n is 1 > R 4 is hydrogen f C 1 -C 1 8 alkyl 5 C 3 -CS alkenyl i C 5 —C 7 cycloalkyl 5 C 1 — C 4 substituted with hydroxycyano, methoxycarbonyl or carbamate Alkyl group> Glycidyl group of formula — C Η 2 — C Η (0 Η) —Z or group of formula C 〇N Η — Zn> where Z is hydrogen, methyl or benzene And > and when η is 2, 5 R 4 is CZ — C 1 2 ll complete support group, C 6 — C 1 ζ arylene 5 xylene support ί — C Η 2 — C Η (0 Η) — C Η 2 — group basis, or a form — C Η 2 — C Η (0 Η) — C Η 2 — 0 — D — 0 — group basis Where D is C 2 — C 1 0 sintered, C 6 — C 1 s arylene or C 8 -C i 2 ring full-stranded, or (the limitation is that R 3 is not a fluorenyl, alkenyl or benzyl) ) R 4 can also be fatty 5 cycloaliphatic or aromatic Ά diacetic acid or diamino-28- ml ——— * 1 ——— m ^ l mu mu ml ml in (Please read the precautions on the back before filling (This page) The size of the paper used for this edition is in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 5. Description of the invention (Vf) The divalent reactive group of formic acid, or the group group of formula C 0 —, or When η is 1, R 3 and R 4 together may be a divalent reactive group of a fatty, cycloaliphatic, or aromatic 1, 2, or 1, 3-dicarboxylic acid. When any substituent is Ci-Ci2- or Ci-Ci8-radical, it may be as defined in a). When any substituent is a C 5 -C 7 cycloalkyl, it is particularly cyclohexyl. When Y 3 is a c7-C8 aralkyl group, phenylethyl is particularly preferred or benzyl is more preferred. When R 3 is C 2 -C E, or hydroxyalkyl, 2-'hydroxyethyl or 2-hydroxypropyl is particularly preferred. When R 3 is C 2 -C i, 3 alkylfluorenyl, examples thereof are propionyl, butylfluorenyl, octylfluorenyl, dodecylfluorenyl, cetylfluorenyl, octadecylfluorenyl, but ethyl is preferred. Fluorenyl; and when it is a C 3 -C 5 alkenyl, acryl fluorenyl is particularly preferred. When R 4 is C 2 -C 8 alkenyl, examples are allyl, allyl, 2-butenyl, 2-pentenyl, 2-hexenyl or 2-octenyl. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page). When R 4 is Ci-C4 alkyl, it is composed of hydroxyl, cyano, alkoxycarbonyl or carbon diamine groups. Examples are 2-hydroxyethyl, 2-monohydroxypropyl, 2-cyanoethyl, methoxycarbonylmethyl, 2-ethoxycarbonylethyl, 2-aminocarbonylpropyl or 2- (dimethylaminocarbonyl) -ethyl. When any substituent is C 2-C i 2 alkylene, the example is ethylene-2 9- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (7i ), Propane, 2,2-dimethyl propane, tetramethyl, hexamethyl, octamethyl, ten methyl, or twelve methyl. When any of the substituents is C 6 -C i 5 arylene, examples thereof are O-, m- or p-phenylene, 1, 4-naphthylene or 4, 4, diphenylene 0 D is C6 — In the case of Ci 2 cycloalkylene, cyclohexylene is particularly preferred. The following compounds are examples of such polyalkylpyridine compounds: 37) N, N7-bis (2,2,6,6-tetramethylmeridine-4-yl) hexamethylene-1,6-diamine; 38) a pair of (2,2,6,6-tetramethylpiperidine- 4-yl) hexamethylene-1,6-diethylpyramine and 1,6-dimethylformamide; 39) 1-ethyl alcohol 4-A (N-cyclohexylethylamino) -2,2,6,6-tetramethylpyridine; 40) 4-benzylamino-2,2,6,6-tetramethyl Piperidine; 41) N > N / bis (2,2,6,6-tetramethylpyridine-4-yl) -N, N fluorene-dibutyl-hexanediamine; 42) N, N / —Double (2,2,6,6 —Tetramethyl # pyridine 4 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) One base) One N, N "—Dicyclohexyl—2-hydroxypropylidene-1,3-diamine; 43) N, N, bis (2,2,6,6—tetramethylpyridine—4-yl) P—xylylene Mono-diamine; 44) N »N / bis (2,2,6,6 —tetramethylpyridine-4-yl) succinic acid diamine; -30- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (/ j) 4 5) N — (2, 2, 6, 6 — tetramethylpiperidine — 4 —Yl) mono / 3 —aminodipropionate di (2,2,6,6-tetramethylmethylpyridine—4-yl.) Vinegar, · 4 6) A compound of the formula: (Please read the Note for refilling this page) 01T Amine I Iethyl Ethyl Hydroxyl | ·, 2 Pyridine I 锨 Double Base {A I 5 41) 6 7 4 6 2 2 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 6 1 I , I group 6 methyl group, amine I 2 ene 3, propion 2 methyl III 4) 4} group 丨 8 amine 9 ·, 4 acid 4 € toluene i butyl I tertiary; a pyridine 5 «monomethyl methyl hydroxy tetra Paijia V 1 6 6 2 2

C type

Physicochemical V

This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (

〇〇 (IV), where η is 1 R 1 is when a is 1 as above when η is 2 or alkylene or C 4-(-C Η z) when R 5 is C 2 and the number is 1, R 5 is C Zn 2 z C (Definer, and Cz — Ca alkylene or Cz — Ca hydroxyalkoxyalkylene, and when η is 2, R is C Η ζ-) 2 C 3 Alkylene or C methyl-ethylene, 2-C 3 hydroxyalkylene, examples of which are propylene, 2-ethyl-propylene or 2 ----------- (Please read the Please fill in this page again) Printed by the Consumers Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Monoethyl 2-hydroxymethyl • R 5 is C 4 -C-based 2- 2-Acetyl 50) Dioxane 51) 9- Acryl-8,8,10 —1,5 -dioxaspiro [5 ♦ 5 52) 8 — Acetyl-2,7,7, propylpropyl. In the case of 2 2methoxyalkane, an example is 2-ethoxymethyl propane. The following compounds are examples of such polyalkylpyridine compounds: 9-a-yal-8,8,10,10-tetramethyl-1,5-spiro [5 ♦ 5] undecane; 10-tetramethyl Propyl 3-ethyl] undecane; 8,9,9 hexamethyl-1, 4-dioxaspiro [4 · 5] decane; 53) 9-acyl 3-hydroxymethyl-3 —Ethyl-8,8,9 10,10-pentamethyl-1,5—dioxaspiro [5 · 5] decacia; -32- This paper size applies to China National Standard (CNS) A4 specifications ( 210X297 mm) Order 505676 A7 B7 V. Description of the invention (/ |) 54) 9 —Acridine 3 —Ethyl 3 —Ethyloxymethyl — 9 —Acetyl — 8, 8, 10, 10 — Tetramethyl-l, 5-dioxaspiro [5 · 5] undecane; 55) 2,2,6,6-tetramethyl-pyridine-4,1,1,2,1 (1 /, 3 ' -Dioxane) a 5 '— 镙 一 5 " —dioxane) a 2 " -spiro-4, " one (2, ", 2 v, 6 / ", 6 / " — Tetramethyl # pyridine); (Please read the notes on the back before filling out this page) Co-op staff printed d) of formula V A, V B and V C compound is:

η (VA) (VB) (VC) Order-33- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 505676 Printed by A7 B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy η is a number of 1 or 2, Ri is as defined in a) above, R 6 is hydrogen, C i -C i 2 alkyl, allyl, benzyl, epoxypropyl or C 2 -C 6 alkyl Oxyalkyl, and when η is 1, R7 is hydrogen, Cjl-Cjl 2 hexyl, C3-Cs alkyl, C7-C9 aryl, Cs-C7 cyclofluorenyl, C2-C 4 hydroxyalkyl , C 2 -C 6 alkoxyalkyl, C 6 -C i. Aryl, glycidyl or group of formula (C Η 2) P-COO — Q, or the following formula — (C Η 2) P — 0 — CO — Q, where P is 1 or 2, and Q Is Ci-C4 alkyl or phenyl, and when η is 2, R7 is C2-Ci2 alkylene, C4-Ci2 alkylene, Ce-Ci 2 aromatic, the following formula is CH2-CH (0 Η)-CHz -0-D-〇-CH2 -CH (0 Η) — CHz — group group, where D is C2 — C i 0 alkylene, C. 6-C is arylene, C β — C i 2 cycloalkylene Or the following formula. -C Η 2 C Η (0 r r) CHz — (0 C Η 2-C Η (0 Ζ /) (: Η2) 2 —, where Z ′ is hydrogen and C i—C is 焼 group , Propyl, benzyl, C 2 —C i 2 alkylfluorenyl or benzamidine, τ i and T 2 are hydrogen independent of each other,-34-This paper size applies Chinese National Standard (CNS) A4 specifications ( 210X297 mm) (Please read the precautions on the back before filling in this tribute) ^^ Clothing · Order-505676 A7 B7 V. Description of the invention (i \) C i -C i 3 alkyl, or unsubstituted or halogen Mono- or C i -C 4 alkyl-substituted C 6 -C i aryl or C 7 -C 9aralkyl, or T and T 2 together Forms a C 5 —C i 2 cycloalkane ring with the carbon atom to which it is bonded. When any substituent is C i -C i 2 alkyl, examples are methyl, ethyl, n-propyl, n-propyl Monobutyl, sec-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethyl-hexyl, n-nonyl, n-decyl, n-undecyl or n-decyl Dialkyl. When any substituent has a C i -C i 3 alkyl definition, examples may be listed above, and in addition, for example, n-tridecyl, n-tetradecyl, n- Hexadecyl or n-octadecyl. When any substituent is C 2 -C s alkoxyalkyl, examples are methoxymethyl, ethoxymethyl, propoxymethyl , Tert-butoxymethyl, ethoxyethyl, ethoxypropyl, n-butoxyethyl, t-butoxyethyl, isopropoxyethyl or propoxypropyl When R 7 is C 3 -C 5 alkenyl, examples are 1-propenyl, allyl, allyl, 2-butenyl or 2-pent'enyl. Consumption by employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative (Please read the notes on the back first Complete this page) R 7, T 1 and T 2 are as C 7 - C 9 aralkyl group, especially phenethyl, or more particularly as a benzyl group. When T i and T 2 together form a cycloalkane ring with a carbon atom, the ring may be, for example, a cyclopentane, cyclohexane, cyclooctane or cyclododecane ring. When R 7 is C 2 -C 4 hydroxyalkyl, examples thereof are 2-hydroxyethyl, 2-hydroxypropyl, 2-hydroxybutyl or 4-monobutyl. -35- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (> > 〇1 1 R 7 Τ i and When T 2 is C 6 —C 1 0 aryl, 5 is especially benzene I 1 group a — β — M group which is unsubstituted or substituted with halogen or C 1 1 — C 4 fluorenyl group. Please read 1 1 1 When R 7 is C ZO-C Jade 2 Yuan support > An example of this is ethylene 1 propylene read back I ri surface 1 I, 2 2 dimethyl propylene tetramethyl methacrylate octamethyl methacrylate > 1 of the top ten Note 1 or twelve propane 0 Meaning 1 item 1 R 7 is C 4 — C 1 ζ When ethylenic > Especially preferred is 2 —butene and then filled% f 1 5 2 pentaene Ethylene or 3-hexene. When R 7 is C 6 —C 1 2 arylene, its Examples are 〇— jm — 1 1 or P—phenylene 1 4 —naphthylene or 4 4 / diphenylene 〇1 I when Zn / is C 2 -C 1 Zn alkyl group, its example is propionyl group> ; 1 1 order 1 butyl donkey > octyl 9 9 twelve courtyard 醯 9 but preferably ox donkey 〇D is C ZO-C 1 0 comprehensive support C Λ — C 1 arylene or C 6-1 IC 1 Z naphthenic time 9 which is as defined in b) above. Compounds under 0 1 1 M are examples of such polyethylenimine compounds: 1 5 6) 3 1 base 1 5 3, 8 3 acridine— 7 f 7 9 9 9 — 1 Tetramethylspiro C 4 ♦ 5 > J Decyl-1 2 4 1 2 11 f 1 I 5 7) 3 Mono-octyl — 1 9 3 9 8 — Diaz — 7 Ϊ 7 > 9 9 1 9 —tetramethylspiro '[4 • 5] decyl — 2, 4 monodione y I 1 I 5 8) 3 — allyl — 1 > 3, 8 — triazine — 1 7 3 7 9 r 5 9 — pentamethylspiro C 4 * 5] decyl — 2 4 one two 11 J 1 1 5 9) 3 one Oxypropyl-1 9 3 8 — Triazine — 7 $ 7 5 8 > 1 1 9, 9 — Pentamethylspiro [4 * 5] Decane — 2 5 4 — Di 11 1 1 I-36-1 1 1 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 () v 5. Description of the invention 6 0) 1,3,7,7,8,9,9 Heptamethyl -1,3, 8 -triacyl [4 ♦ 5] decane-2,4 -difluorene; 61) 2 -isopropyl-7,7,9,9 tetramethyl-1 -oxa- 3,8-diazine-4 monooxy-fluorene [4 ♦ 5] decane, 62) 2,2-dibutyl-7,7,9,9-tetramethyl-1 1-oxa-3, 8-diazine-4 monooxy-fluorene [4 · 5] decane; 63) 2,2,4,4-tetramethyl-7-oxa-3,20-diazine 2 1-oxo Bisspiro [5 · 1 ♦ 1 1 ♦ 2] pinane; 64) 2-butyl-butyl 7,7,9,9-tetramethyl-1 1-oxa-4,8-diazine 3-oxy- Spiro [4 · 5] decane; 65) 8-Ethylfluorenyl-3-dodecyl-1,3,8-triazine-7,7,9,9-tetramethylspirospira [4 · 5] Alkyl-2, 4 - two ϋ; or a compound of the formula: - * ------- (Read precautions and then fill the back side of this page)

, 1T CH3 CH,

CH3—N

NH — C = 〇 ch3… ch3 66)

C—N—CH2CH (OH) CH2- [OCH2-CH (OH) CH] —-N_c CH3X ch. Ο II

〇 = C

• N — CH. 〇 ch / ch3 印 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

, NH — C = 〇 〇 = C — NH

CH3, / CH3 C-N- (CH2) 6-N ——C

N-CK ch3 'CH3 37 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention qip 68) CH. CH.

CH, 2 CH. CH0

0 = C-NH

N — C II

NH 〇 CH ^ CH3

Xu / 9 6

o. c = 〇 -cl \

(CH

N ——CH2CH2C〇〇〇12H 25 e V formula compound:

R

N

(VI),

N

• R 10 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2 or i-I is n and R 8 is the group base of the following formula (A E-

-38- (Please read the notes on the back before filling this page)

This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention ^ Among them: R 1 is as defined in a) above, E is One or one NRii —, A is Cz — C6 alkylene or one (CHz) 3 — 0 —, and X is 0 or 1, R 9 is the same as R 8, or one of the following group groups: -NR 1 1 R 1 z, -0Ri3 ^ -NHC-HzOR13 or -NCCHzOR ") ^, when η is 1, R 1 〇 is the same as R 3 or r 9, and when η = 2 'R1 ° is the formula A group base of Ε — Β — Ε —, where B is a C 2 —C 6 alkylene group, which is uninterrupted or interrupted by an N (R 1 1) —

Ri 1 is Ci — Ci2 alkyl, cyclohexyl, benzyl or (^ — C4 hydroxyalkyl, or a group group of the formula:

R12 is Ci-Cl2 alkyl, cyclohexyl, benzyl, Ci-C4 hydroxyalkyl, and R1 3 is hydrogen, Ci-Ci 2 fluorenyl or phenyl, or R 1 1 and chi 1 2-C 5 Alkylene, or C4—C5 oxygen-39- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) ▼, ιτ

505676 A7 B7 V Description of the invention Heteroalkylene, such as Ο or

N —R -CH2CHr -CHXH, 〇 or

N —R-* -------- (Please read the notes on the back before filling this page) -CH2CH ^ -CHXH,

, 1T, or R 1 1 and R 1 z

NH-A-

Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. When any substituent is a C i -C i 2 alkyl group, it can be, for example, methyl'ethyl, n-one or two groups, n-butyl, sec-butyl, Tertiary butyl,-4 0-This paper size applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 505676 A7 B7 V. Description of the invention (U) n-hexyl, n-octyl, 2-ethylhexyl , N-nonyl, n-decyl, n-111 comprehensive base or n-12 burning base. When any substituent is Ci-C4-hydroxyalkyl, examples are 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 2-hydroxybutyl or 4-hydroxybutyl. When A is C 2 -C 6 alkylene, examples are ethylene, propylene, 2,2-dimethylpropylene, tetramethylene or hexamethylene. When Ri 1 and Ri 2 are taken together as c4-C5 alkylene or C4-C 5 oxaalkylene, the mule is tetramethylene, pentamethyl, or 3-oxapentamethyl. The following compounds are examples of such polyalkylpyridine compounds: (Please read the precautions on the back before filling this page) • ^^ 衣, 1Τ

Printed by the Consumers' Cooperatives of the Bureau of Missing Standards, Ministry of Economic Affairs

-41- The size of this paper applies to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 505676 A7 B7 V. Description of the invention () /)

R 72) N ^ N ^ human R where R = AH-CH2CH2CH2-〇

ch3, ch.

Λ CH2-CH2- (ΝΗ (Please read the precautions on the back before filling in this page) Clothing ch / ch3

ΝΗ

N CH2-CH2-NH- ^ ^-nh-ch2-ch2

N ch3 ,, η3

CH ^ CH3 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of invention 75)

ϊ R-NH- (CH2) 3-N -— (CH2)-N- (CH2) 3-NH-R

CH ch3

CH is 3 CH more. 76)

R

R R Lu (ch2VNs (CH2) 2-i (Ch2) R Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

(Please read the notes on the back before filling this page)

This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of invention (f spoon CHi

R

R CH, 3 77)

R-N — (CH2) 3—N — (CH2) 2—N —— (〇H2) 3 —N R

Where R

¾-- (Please read the notes on the back before filling this page) Order 78) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

1 4 4 # This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 505676 A7 B7 V. Description of the invention (A /) 79

Η Η Η C ό Η

NIC

CH Η 9 2 Η C 2 Η C

(Please read the notes on the back before filling this page)

, 1T \ 1/80 Η ό ό Η C 2 2

Η 4 NIC

c 3 Η

CH

C II Η -C 2 Η 9

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs This paper is in accordance with the Chinese National Standard (CNS) A4 (210 × 297 mm) 505676 A7 B7 5

2. Description of the invention (fW f) oligomeric or polymeric compounds whose structural repeating units contain one or more 2,2,6,6-tetraalkylpiperidine reactive groups of formula (I), especially polyesters, Polyamine, polyamine, polyamine, polyurethane, polyurea, polyaminotriazine, poly (meth) acrylic acid, polysiloxane, poly (meth) acrylamide, and containing these reactive groups Copolymer. Examples of this type of 2,2,6,6-polyalkylpyridine are photostable compounds as described below, where m is a number from 2 to about 200.

(Please read the precautions on the back before filling out this page) Clothing., 11 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention From CH, NH- • C—CH2—c — CH3 84) CH, ΓνΓ 丨 3 CH,

-CH2-CH (OH) -CH2 (Please read the precautions on the back before filling this page) = =-=-=-.......... .._...............- .................-- 1 —- = __ * — · 85) • N -

m order \ — / 6 8 reading Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

H c H c -C i c II H 9 2 H 9

o = -cό

OHMC This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of invention (f f) \\ f / 8 8 87)

ΝΠ

c

one 2) 4 Η (c TOH-C ό 9) 8

(Please read the notes on the back before filling this page)

Printed by 1T Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs 90) 〇 CH-c-c—〇

This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 V. Description of Invention 91)

N

Η n t— rm— mmmfl f In Is —ml —mmmmmmmmm n (Please read the notes on the back before filling out this page), printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 〇

49- m This paper size applies Chinese National Standard (CNS) A4 specification (210X2W mm) 505676 A7 B7 V. Description of the invention (Maishi 95) CH3I -Si-0- (CH2) 〇 3 m

Where R = H or CH3 H9C4 (R) N \ ^ n γ N (R) C4H9 NH (ch2) 3 (Please read the precautions on the back before filling this page) 96) h9c4 (r) n-

—N- (CH2) 2-N Νχ / N r N (R) C4H, (ch2) 3 MH person NH N, / NΛΛ H9C4 (R) Nx NN (R) C4H9 2-3 Staff consumption of the Central Standards Bureau of the Ministry of Economic Affairs Cooperative printed R in China

CH CH This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7

H9c4 (R) N 5. Description of the invention (Ref. 7) or Η NN (R) C4H9 (from the reaction trichlorotriazine and N Η 2 (C Η 2) 3 — NH — (C Η z) 3-Ν Η -(C Η ζ) ζ- (C Η 2) 3 -NΗζ reaction product and 4-N-butyl- 2, 2, 6, 6, 6-tetramethylpyridine derived from latent production). Of these classes, e) and f) are particularly suitable, especially those tetraalkylpiperidine compounds containing s-triazinyl. Particularly suitable are the compounds 74, 76, 84, 87, 92, 95 and 96. The preparation of N-pyridinyl-triazine is conventional (for example, ube ube η-Wey 1 "Methoden der organischen Chemie", Vo 1. VIII, P.233-237, 3 rd Ed., Thieme Ver 1 ag Stuttgart 1971) 〇 (Please read the notes on the back before filling out this page) Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, a pair of II, 2 5 2, basic chlorine I: 2,,, 2 Amine chloride is { 232, Diamine di-bis, I, 2, 1 ~ groups, 1-base 1-I alkyl alkyl esters 丨 Butyl diamine diacid bis I diethyl chloride dibasic bis, n-acid decyl decyl ester , Dihydroxyurethane or sulfonate} Propionate I I Cyanide I. Alkyl diacid I 1 amine via matrix alkidine butane diyl, · base amine I}} decyl benzyl ester 5--1 allyl radicals pentayl group} group} _ # or alkyl and methylpyridyl hydroxyl I hydrazine di | tetra «pyridine 1 pyridine N tris or tetrakis i piperidine 4 hydrazine I hydrazine trans 6 methyl 1 radical each 5 triazine essential, tetramethyl formaldehyde, I triple 6 1 3 5 I up-6 I 1 I use,, LO operation 2, 6, 6 un 6 can 1 3, 6, _, some | 1 3 2, 6 2 6 this chlorine 1, ′ · 2 '-, this paper Standards are applicable to Chinese National Standard (CNS) A4 specifications (210 × 29? Mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 505676 A7 V. Description of the invention Condensation product of the acid, Ν, Ν / -bis (2,2,6,6-tetramethyl-4-pyridinyl) hexamethylene diamine and 4-tert-octylamino-2,6- Condensation product of dichloro-1,3,5-s-triazine, tris (2,2,6,6-tetramethyl-4-pyridinyl) azatriacetate, tetras (2,2, 6, 6-tetramethyl-1 4-pyridyl) -1, 2, 3, 4-butane tetraester, 1, 1, 1, (1,2-ethanediyl), bis (3, 3, 5, 5-tetramethyltonazine), 4-benzylhydrazine 2, 2,6,6-tetramethylpyridine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis (1,2,2,6,6-pentamethylpyridine) )-2-n-butyl-2-(2-hydroxy-3,5-di-tert-butyl benzyl) malonate, 3-n-octyl-7, 7, 9, 9, 4 Methyl-1,3,8-triacylspiro [4,5] decane-2,4-di-2-, bis (1-octyloxy-2,2,6,6-tetramethylpyridinyl) Sebacate, bis (1-octyloxy-2,2,6,6-tetramethylpiperidinyl) succinate, N, N7-bis (2,2,6,6-tetramethyl) Condensation products of 4-piperidinyl) hexamethylenediamine and 4-morpholinyl-2,6-dichloro-1,3,5-triazine, 2-chloro-4,6-di (4-n Condensation of monobutylamino-1,2,6,6-tetramethylpiperidinyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethane Product, 2 — One 4,6—bis (4-n-butylamino-1,2,2,6,6-pentamethylpyridyl) —1,3,5-triazine and 1,2-bis ( 3 —Aminopropylamino) Condensation products of ethane, 8 —Acetidine-52- This paper size applies to China National Standards (CNS) A4 specification (210X297 mm) (Please read the notes on the back before filling (This page)

505676 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (^) 3-a-dodecyl-7, 7, 9, 9, 9-tetramethyl-1, 3, 8-triazine [4 ♦ 5] decane-2,4-dione, 3-dodecyl-1— (2,2,6,6—tetramethyl-1—4-pyridyl) pyridine-2,5 —Difluorene, 3-dodecyl-1— (1,2,2,6,6—pentamethyl-4 4-pentidyl) —pyrrolidine-2,5—difluorene 0 In addition to a single steric hindrance In addition to amines, mixtures using different sterically hindered amines are also included within the scope of the invention. The amount of sterically hindered amines is determined by the degree of stability desired. Generally speaking, from 0. 01 to 0. 5% by weight, especially from 0. 0 5 to 0. 5% by weight (based on polymerization Calculation). Hydrogen talc and alkali metal (alkaline earth metal) aluminosilicate (zeolite) The chemical composition of these compounds is well known to those skilled in the art, such as DE38, 43,581, US-4,00,100. , EP-062, 813, W093 / 20135. Compounds of hydrogenated talc can be represented by the general formula VII: M2 + 1-x M3 + x (OH) 2 (Ab ") x / b · d H2〇 (VII) where r M2 + M 3 + = A 1 or B, AA is an n-valent anion, -53- This paper size applies Chinese National Standard (CNS) A4 specification (210 × 29 < 7 mm) (Please read the precautions on the back before filling in this tribute.) ·· Order

505676 A7 B7 V. Description of the Invention (f) η is a number from 1 to 2 * & < X < 0 · 5, and m is a number from 0 to 2 0. Preferably:

An OH-, ClO4_, HC03-, CH3CO0-, C032-, (CH0HC00) z z ·, (CH2C00) 22_, CHs CHOHCO-one, HP03-or Η P 〇 4 2-. · Examples of hydrogenated talc: A 1 z 0 3 * 6MgO * C〇2 12HzO (i) M g 4 * 5 A 1 2 (OH) i 3 C 0 3 3 · 5 H 2 0-(i 1) 4MgO * Alz〇3C〇2 9H2〇 (iii) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) 4MgOAlz〇3COz6HzOJ Zn0 * 3Mg0 * Alz0s C 0 z 8 — 9Hz 0 and ZnOSMgOAlz 〇3 COz 5 — 6Hz 0. Particularly preferred are compounds of the i * i i and i i i types. Zeolites (alkaline and alkaline earth metal aluminosilicates) These can be represented by K type (VIII): -54- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 505676 Employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the consumer cooperative A7 B7 V. Description of the invention (jri) Μχ / η [(Αΐ〇2) χ (5 · ι〇2) γ] · -2〇 (VTII) where η is the charged number of the cation M; Μ is Group I or Group II elements, like Li, Na, K, Mg, Ca, Sr or Ba; y: x is a number from 0. 8 to 15, preferably from 0 '8 to 1 · 2; and w is a number from 0 to 3 0 0, preferably 0 ♦ 5 to 30. An example of a zeolite is sodium aluminum silicate of the formula:

Nai 2 A1 on 2 Si i 2 04 s · 27Η2 0 [Zeolite A],

Nae Ale Sie 〇 z 4 .2NaX.7.5H2 0; X = 〇H, tooth element, C1CU

[sodalite];

Nae Ale S i 3 〇 〇 7 z. 2 4 Η z 〇 i

Nas Als Si4 〇〇9 6.24Hz 〇; iNa i 6 A1 ie Si z 4 〇s 0 * 16H2 0; Na 1 6 A1 ie Si 3 2 〇 9 6 • 16Hz 0; Nas 6 A1 be Si i 3 β 〇3 S 4 • 250Ηζ 〇 [zeolite y] N a 3 6 A1 8 δ Si i 0 β 〇3 8 4 • 264Hz 〇 [zeolite X]; or m stone may be partially or completely replaced by N a ·· K, M g, ca 3 s Γ or Z η 9 image (N a, K) 1 0 A1 1 0 Si ζ 2 〇6 4 • 20Hz 0; C 3, 4 • 5 N a3 [(A 1 0 z) 1 2 ( SiOz) 1 ζ]. 30Hz 0; Kg Na3 [(A 10 z) i 2_ (Si〇z) 1 2]. 27Hz 0 〇 The preferred zeolite is a compound of the following formula: -55- This paper size is applicable China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention ¢ /) Nae Ale S i 3 〇〇7 z · 2 4 H 2 〇, N a 3 A 1 s S i 4 〇09 6 · 2 4 H 2 〇, Naie A 1 ie S i 2 4 0 a 〇. 16 H 2 0,

Nai 6 All g S13 z 〇9 β. 18 H 2 0,

Na5 s Al5 6 Si! 3 6 〇3 s 4 · 250Η2 0, [Zeolite Y],

Nas 6 AU 6 Si! 〇6 03 8 4 · 264Η2 0, [zeolite X], and the zeolites of the x and y type have an A 丨 / S i ratio of about 1: 1, or the zeolite may partially or completely replace N with the following elements a to form: Li, K, Mg, Ca, Sr, Ba, or Zn, like (Na, K) i 〇Ali〇Si2 2 〇 6 4. 20 Hz 〇;

Ca4 .5 Nas [(Al〇z) i 2 (S1O2) i 2] .30H2 0; K9 Nas [(Al〇z) 1 z (Si〇z) iz] .27Hz 〇; zeolite listed above can be low Water content, or may be non-aqueous: Other suitable zeolites are:

Naz 〇Al2 〇3 (2 to 5) Si0z (3.5 to 10) H2 0 [zeolite P],

Na2 0A12 (h 2Si02 (3.5-10) Ηζ 〇 [zeolite MAP], printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) or it may be part or all of the following elements Substitute Na to form: Li, K or Η, like: (Li, Na, K, H) i 〇Ali 〇Si2 2 06 s · 20Η2 0, κ9 Na3 [(Α1〇ζ) ι ζ (Si02) ι z]. 27Hz 〇, K4 AU Si4 0 i · 6HZ 〇 [Zeolite KF]

Nas Als Si4 〇〇ge .24Hz 〇 [Zeolite D] described in Barrer _56_ This paper size applies to China National Standard (CNS) A4 (21 OX 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy 505676 A7 B7 Description of the invention (fj) et al., J. Chem. Soc. 1 9 5 2, 1 5 6 1-7 1 and zeolites under US-2, 9 50, 9 5 2 K are also suitable: Potassium offretite, disclosed in EP-A-400,961; zeolite R, disclosed in GB-8 14.1, 8 1 2; zeolite LZ-2 17, disclosed in US-4, 5 () 3, 0 2 3; calcium-free zeolite LZ-2 1 8 is disclosed in ϋS-4, 3 3 3, 8 5 9; zeolite T, zeolite LZ-2 2 0 is disclosed in US-4, 5 0 3, Q 2 3;

Na3 KiS Al9 Si2 7 0 7 2 · 21Η2 0 [Zeolite L] Zeolite LZ — 2 1 1, disclosed in ϋ S-4, 5 0 3, 0 2 3; Zeolite LZ — 2 1 2, disclosed in US-4, 5 Q 3, Q 2 3; Zeolite 0, zeolite LZ — 2 1 7, disclosed in US-4, 50 3, 0 2 3; Zeolite LZ — 2 1 9, disclosed in US-4, 5 0 3, 0 2 3; Zeolite Rho, zeolite LZ — 214, disclosed in US- 4,503, 0 2 3; Zeolite ZK — 19, disclosed in Am · Mineral. 5 4 1 6 0 7 (1 9 6 9); Zeolite W (K-M), disclosed in Barrereta 1. J. Chem. Soc. 1956, 2882;

Na3 〇 Al3. Si6 s 0 i 9 2 · 98Hz 〇 [Zeolite Z K-5, Zeolite Q]. Particularly preferred is the use of P-type zeolite of formula I, where x is 2 to 5. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

505676 Printed by A7 B7, Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 5. Description of the invention (broken), and y is 3.5 to 10, and the best is the zeolite MAP of formula I, where x is 2 and y is 3 ♦ 5 to 10. It is preferred to use zeolites Na-P, i.e. M is sodium. This zeolite is usually found in various different variants Na — P — 1, Na — P — 2 and Na — P — 3, and the differences are cubic, tetragonal or orthorhombic (R · M B arrer, B. M. M unday, J · C he in · S oc · A 1 9 7 1, 2 9 0 9-1 4) ° This document also describes the zeolites P — 1 and P — 2 preparation. According to this document, zeolite P-3 is very scarce and therefore has no practical benefit. The structure of the zeolite P-1 is the same as the structure of the above-mentioned conventional azite (g i s m ο n d i t e) structure. Recent literature (EP-A-3 884,700) distinguishes cubic structure (zeolite B or P c) and tetragonal structure (zeolite P i) of P-type zeolite, and mentions that P-type zeolite has S i : The ratio of A 1 is lower than 1 · 07: 1. These zeolites are named MAP or MA-P, which stands for 〃maximum aluminum P〃. Based on the preparation of these zeolites, zeolite P can contain small amounts of other zeolites. Very pure zeolites are described at WO-9 4/2 6 6 6 2. Within the scope of the present invention, it is also possible to use finely granular water-insoluble sodium aluminum silicate, which is precipitated or crystallized in the presence of a water-soluble inorganic or organic dispersion. And it can be introduced into the reaction mixture in any manner before or at the same time as precipitation or crystallization. · Sodium zeolite A and sodium zeolite P are optimal. The amount of hydrogenated talc and / or zeolite used is basically from, for example: 〇 ♦ 1 to 2 ◦, advantageously from 0 ♦ 1 to 10, especially from 0.1 to 5 parts by weight (based on 1 0 0 Parts by weight of halogen-containing polymer meter -58- This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)

Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7__ V. Description of the Invention (β) Calculated Alkali Metal Aluminum Carbonate (dawsonites): These compounds are represented by the following formula: {(M2 〇) m. (Al203) nZ.pH2〇}, where M is H, Li, Na, K'Mgi / z, Cai / z, Sri / 2 or Zηι / ζ; 2 is 〇2'S 〇z '(C 1 ζ 〇 7)! / Z, B 4 〇ζ JS 2 O' 2 (thiosulfate) or C2〇2 (oxalate); when% is% §1 / 2 or C ai // 2, m is a number from 1 to 2, and in all other cases is a number from 1 to 3; η is a number from 1 to 4; 0 is a number from 2 to 4; and P is from The number c from 0 to 30 The aluminum salt compound of formula (I) which can be used in the present invention may be a naturally occurring mineral or a synthetically prepared compound. These metals may be partially replaced by each other. The aluminum salt compounds mentioned are crystalline, partially crystalline or amorphous, or can be present in the form of K-dryable gels. This aluminum salt compound can also exist in the form of a relatively rare crystalline modification; the method for preparing these compounds is described in EP 3-9 4, 6 7 0. Examples of naturally-occurring aluminum salt compounds are 1 $ indigirite, t. Unisite, IS aluminohydrocalcite, para-aluniinohydrocalcite, and refining stone (s, r ο nit, i 〇dresserite), and hydrostr ni 炼. iodresserite. Other examples of aluminum salt compounds are carbon-59- This paper size applies Chinese National Standard (CNS) A4 specification (21 OX297 mm) ▼ Packing-(Please read the precautions on the back before filling this page) Order # 505676 A7 B7 V. Description of the invention (jri) Potassium aluminum [(K2 0) Ul2 〇3) · (C02) 2 · 2H2 0], sodium aluminum thiosulfate [(Na2 0) (Al 2 03) · (S2 〇2 ) 2 · 2H2 0], aluminum potassium sulfite [(Κ2 0) · (Α12 03) (S02) 2 · 2Η2 0], calcium aluminum oxalate [(CaO). (Al2 03). (C2 02) 2 · 5Η2 0], aluminum magnesium tartrate [

(MgO). (Α12 〇3). (Β4 〇8) ζ. ΔΗζ 〇J J

[([Mg 〇.z Na 〇 · 〇] z 0). (Alz 〇3) '(C〇2) z 4 .1H 2 〇], [([[Mg 〇. 2 Na 〇.8] z 〇 〇 ). (Alz 03) (C〇z) z 4 · 3 H 2 0], and [([Mg 0.3 Na Na. 4} z 〇). (Α1ζ O3) (C〇)) z. 2 4 . 9H 2 0j. A mixed aluminum salt compound can also be obtained by a conventional cation exchange method, and is preferably prepared from an alkali metal aluminum salt compound or from a combined precipitate (see, for example, U S-5, 05, 5, 8 4). The preferred aluminum salt of the above formula is: Μ is Na or K; Z is COz, S〇2 or (C 1 z 0 7) \ / z is 1-3; n is 1 to 4; 〇 is the Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (please read the notes on the back before filling out this page) 2-4, and p is 0-2 0. Z is especially C 0 2. The preferred compound is a compound represented by the following chemical formula: M2.Al2O3. (C2) 2.ρ2 (1α) (M2O) 2. (Al2O3) 2. (C02) 2 · pH2〇 (lb) M2〇. (Al2〇3) 2. (C〇2) 2. PH2〇 (Ic) -60- This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of invention d where M is a metal, such as Na, K, Mgi / 2 JC ai / z, Sri / 2 or Zn 1/2, and p Is a number from 0 to 12. Particularly preferred are sodium aluminum hydroxycarbonate (DASC) and an equivalent potassium compound (DAPC). Dawsonite can also be substituted by lithium aluminum hydroxycarbonate or lithium aluminum hydroxycarbonate-magnesium, as described in EP-5 49,34 and DE-4,425,266. The amount of sodium bauxite used is, for example, from 0 to 0, 1 to 5, and advantageously from 0 to 1 to 3, especially from 0 to 1 to 2 parts by weight per 100 parts by weight of the halogen-containing polymer. The stabilizer composition preferably includes component A), and at least one selected as component B) selected from the group consisting of a perchlorate compound, an epoxypropyl compound, or dihydropyridine and polydihydropyridine. The stabilizer composition of the present invention can be used with other additives conventionally used for processing and stabilizing chlorine-containing polymers, such as: Zinc compounds: Organic zinc compounds have a Z η — 0 鐽, are pinenolates and / or Zinc gallate. The latter are, for example, fatty saturated C 2 -C 2 2 carboxylates * fatty unsaturated C 3 -C 2 2 carboxylates, fatty C 2 -C 2 2 carboxylates, which are substituted via at least one oxo group, Or its chain is interrupted by at least one 0 atom (oxic acid), cyclic and bicyclic carboxylic acid-6 1- This paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) (Please read the back first Please pay attention to this page, please fill in this page) Order printed by the Ministry of Economic Affairs, Central Standards Bureau, Consumer Cooperatives 505676 A7 B7 V. Description of the invention (if) Salt contains 5-2 2 carbon atoms, phenyl carboxylate, which is unsubstituted , Or substituted via at least one OH group and / or via Ci-Ci 6 alkyl, phenyl-C i -C i 6 alkyl-phosphonate, or benzoate, which is unsubstituted, or Substituted by C i -C i 2 alkyl, or abietic acid. Names that can be specifically mentioned are, for example, zinc salts of monovalent carboxylic acids, such as acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid, and heptanoic acid. , Caprylic acid, neodecanoic acid * 2-ethylhexanoic acid, nonanoic acid, capric acid, undecanoic acid, dodecanoic acid, tridecanoic acid, myristic acid , Hexadecanoic acid, lauric acid, isostearic acid, stearic acid, 12-hydroxystearic acid, 9,10-dihydroxystearic acid, oleic acid, 3,6-dioxaheptanoic acid, 3, 6,9 trioxadecanoic acid, arsenic dicarboxylic acid, benzoic acid, p-tert-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-di-tert-butyl-4-monohydroxybenzoic acid , Toluic acid, dimethyl benzoic acid, ethyl benzoic acid, n-propyl benzoic acid, salicylic acid, p-tert-octyl xylic acid, and zinc salts of sorbic acid; zinc salts of divalent carboxylic acids Or its monoesters, such as oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, butanedioic acid, pentane-1,5-dicarboxylic acid, hexane-1,6-di Carboxylic acid, heptane-1,7-dicarboxylic acid, octane-1,8-dicarboxylic acid, 3,6,9-trioxadecane-1,10-dicarboxylic acid, lactic acid, malonic acid Acid, maleic acid, tartaric acid, oxalic acid, salicylic acid, polyethylene glycol dicarboxylic acid (η = 10-12), titanic acid, isotitanic acid, terephthalic acid and hydroxyphthalic acid; and three A di- or tri-ester of a mono- or tetra-valent carboxylic acid, like trimellitic acid, trimellitic acid Acids, pyromellitic acid, citric acid and so-called overbased zinc carboxylates. -62- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) (please read the notes on the back before filling this page), 1T 505676 Printed by A7 B7, Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Description of the invention (Di) The zinc enolate is preferably the enolate of acetopropylammonium benzoate or dibenzomethane, and the ethyl acetate and benzothionate, and dehydrogenation. Enolate of acetic acid. In addition to 'inorganic zinc compounds like zinc oxide' zinc hydroxide, zinc sulfide or zinc carbonate can also be used. The preferred carboxylic acid zinc carboxylate contains 7 to 25 carbon atoms (zinc bismuth), like Benzoates or alkanoates, preferably cs alkanoates 'stearates, oleates, laurates, hexadecanoates' arsenates, wilenoates, hydroxy hard Fatty acid salt, dihydroxystearate 'p-tert-butyl benzoate, or (iso) octanoate. Stearates, oleates' wilenoates, benzoates, p-tert-butylbenzoate and 2-ethylhexanoate are particularly preferred. In addition to stilbene zinc compounds, other organoaluminum, praseodymium, or lanthanum compounds with a metal of 100% are also suitable. Useful and preferred aluminum compounds include osmates and enolates. The amount of the above-mentioned metal soap or its mixture is basically 0. 0 0 1 to 1 0, advantageously 0 0 to 5 and preferably 0 0 1 to 3 parts by weight (based on 100). Parts by weight of chlorine-containing polymer). This stabilizer composition can be used in conjunction with other stabilizers, rib stabilizers and processing agents, such as alkali metal and alkaline earth metal compounds, lubricants, plasticizers, pigments, fillers, phosphites, thiophosphites And thiophosphates, mercaptocarboxylic acid esters, epoxidized fatty acid esters, antioxidants, UV absorbers and light stabilizers, optical brighteners, impact strength modifiers and processing ribs -63- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the Invention (Stone 6), gelling agent, antistatic agent, biocide, metal deactivator, flame retarder and drainage agent, and antifog agent (Cf. ^ Handbook of PVC Formulating5 'by E · J · Wickson, John Wiley & Sons, New York 1993). K is a non-limiting way. Some conventional additives and processing ribs are as follows: Alkali and alkaline earth metal compounds: It is necessary to understand that carboxylates including epithionate are included, but relatively equivalent Oxides or hydroxides or bicarbonates. Mixtures with organic acids are also suitable. Examples are Na 〇Η, sodium stearate, Na HC 0 3, KO Η, potassium stearate, KHCOs, LiOH, Li 2 C 0 3, Li stearate, CaO, Ca (0 H 2) 'M g 0, M g (0 H) 2, magnesium stearate, C a C 0 3,

Mg C0. »And dolomite, huntit, chalk, alkaline magnesium carbonate, and other fatty acid sodium and potassium salts.

Na0H, K0H, Ca0, Ca (0Hz), Ms0 ' Mg (OH) 2, CaC03 and MgC03 are also suitable fatty acid sodium and potassium salts. In the case of alkaline earth metals and zinc carboxylates, it may also be an adduct with M0 or M (OH) z (M = C a, Mg, Sr or Zn), the so-called 〃perkaline 〃 compound . In addition to the stabilizer composition of the present invention, alkali metals, alkaline earth metals and / or aluminum carboxylates are preferred. -64- $ Paper size is applicable to Chinese countries; ^ ~ ((: 阳) 八 4standard (210/297 mm) " " (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention (4ί) Other metal stabilizers: Special mention should be made of organic tin stabilizers, carboxylates, sulfides and sulfides. Examples of suitable compounds can be found in U S — 4, 7 4 3, 6 4 0. Lubricants: Suitable lubricants are, for example: fucoxane, fatty acid esters, PE wax, amine waxes, chlorinated paraffins, glycerides or alkaline earth metal soaps. Suitable lubricants are also described in "kunststoffadditive" (Plastics additives), R. Gachter / H. Muller, Carl Hanser Ver 1 ag, 3rd Ed., 1 9 8 9, pages 4 7 8-4 8 8. Also Includes fatty acids (described in DE-4 2, 0 4, 8 8 7) and silicon-based lubricants (described in EP-2 2 5, 2, 6 1) or combinations thereof (described in EP-2 5 9, 7 8 3). Plasticizers: Suitable organic plasticizers are, for example, the groups listed below: A) Phthalic acid g Purpose) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs _ Packing- (Please read the notes on the back before filling this page) # Basic examples of these plasticizers are dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dihexyl titanate, di One 2-ethylhexyl phthalate, two η-octyl titanate, two isooctyl titanate, two isononyl phthalate, two is isodecyl phthalate, two isomer Tridecyl phthalate, dicyclohexyl titanate, dimethyl cyclohexyl titanate, dimethyl glycol titanate, dibutyl glycol peptidate, benzyl butyl titanate, and Diphenyl Peptide »65» Ben Zhang scale is applicable to China National Standard (CNS) A4 specification (210 × 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention Esters and mixtures of titanates, like C 7-C 9 Peptides and C 9 -C 1 i alkyl titanates, which are mainly composed of linear alcohols, C 6-C i 0 -η-alkyl titanates and C. s-C i 0-η-alkyl It is prepared from titanate. Preferred are dibutyl titanate, dihexyl titanate, di-2-ethylhexyl phthalate, di-n-octyl titanate, di-isooctyl Phthalate, diisononyl titanate, diisodecyl titanate, diisotridecyl peptidate and benzyl butyl peptidate, and mixtures of alkyl titanates. Particularly preferred are di-2-ethylhexyl, diisononyl and diisodecylphthalate. The traditional abbreviations are: D Ο (dioctylphthalate, di-2-ethylhexylphthalate Esters), DINP (diisononyl peptidate), DI DP (diisodecyl titanate). B) fatty dicarboxylic esters, especially adipic acid, azelaic acid and sebacic acid Esters · These plasticizers Basic examples are di-2-ethylhexyl adipate, diisooctyl adipate (mixture), diisononyl adipate (mixed Ju), diisodecyl adipate Acid esters (mixtures), benzylbutyl adipate, benzyloctyl adipate, di-2-ethylhexyl azelate, di-2-ethylhexyl sebacate and dione Isodecylsebacate (mixture); di-2-ethylhexyl adipate and diisooctyl adipate are preferred. C) Esters of trimellitic acid: For example: tris-2-ethylhexyl trimellitate, tris-isodecyl trimellitate (mixture), tri-isotridecyl trimellitate ， 三 -66- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the Invention ((^) Monoisooctyl trimellitate (mixture) and Trinyl C β — CS alkyl, Trin C 6 — C i 〇 Alkyl trimellitate, Tri-C 7-C 9 Alkyl trimellitate and Tri-C 9 -C ii Alkyl trimellitate The alkanol mixture is obtained by esterifying trimellitic acid, and the preferred trimellitic acid ester is tris-2-ethylhexylbenzene hexametriate and the trimellitic acid ester formed from the alkanol mixture, especially Benzotribenzoate obtained from a mixture of C 6 —C i 2 alkanols. The traditional abbreviation is: Τ Ο Μ (Trioctylphenyl trimellitate, Tri-2-hexylphenyl trimellitate) , T I DTM (triisoisodecyl trimellitate) and T ITD TM (triisotridecyl trimellitate). D) Epoxide plasticizers are mainly epoxidized unsaturated fatty acids , Like epoxy soybean oil. Ε) Polymer plasticizers

Plastics Additives' edited by R. Gachter and Η Muller, Hanser Verlag, 1990, p. 393, paragraph 5.9.6 and "PVC Technology", edited by W. V. T itow, 4 th E d · , Elserier Pub 1 ·, 1 9 8 4, pp. 165-170. The most useful starting materials for the preparation of these polyester plasticizers are: dicarboxylic acids, essentially adipic acid, titanic acid, azelaic acid, and sebacic acid; glycols, like 1,2-propanediol, 1, 3 -Butanediol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, and diethylene glycol. F) Phosphate ester-67- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) _ installed-(Please read the precautions on the back before filling this page) Order # Staff Central Bureau of Standards Staff Consumption Printed by the cooperative 505676 A7 __ B7 V. Description of the invention The definition of these esters can be found in the above 〃 T as c heIIbuc h der

"Kunstoffadditive" (Plastics Additives), pages 4 Q 8 -4 1 2 and chapters 5 · 9 · 5. The basic examples of these phosphates are tributyl phosphate, trione 2 -ethylbutyl phosphate, trione 2 monoethylhexylphosphonic acid, trichloroethyl phosphate, 2 monoethylhexyl diphenyl phosphate, tolyl diphenyl phosphate, triphenyl phosphate, tricresyl phosphate 'And tris (xylyl) delta dance esters. Tris 2-ethylhexyl phosphate and fluorene re 0f 0 s 50 and 9 5 (C iba-G eigy) are preferred. G) chlorination Hydrocarbons or chlorinated (paraffin) 烃) hydrocarbons I) monocool, basically butyl oleate, phenoxyethyl oleate, tetrahydrofuran oleate, and alkyl sulfonate. J) a §? S The purpose is basically the purpose of di (diol) benzoic acid. Examples of plasticizers from G) to J) are found in the operation manual described below:

Kunststoffadditive (Plastics Additives) ", edited by R. Gachter and Muller, Hans er Verlag, 3rd Ed., 19 8 9, pages 4 2 2-4 2 5 and chapters 5 · 9 · 14 · 2 (G ) And Chapter 9 · 1 · 4 · 1, page 4 2 2 (Η). ΗPVC Technology ", edited by WV · T itow, 4th Ed *

Elsevier Publishers, 1984, pages 1 7 1-1 7 3, chapter 6.10.2 (G), page 174, page 6.115 (H), page 173, 6.10 · 3 (Ι) and 173 -174 pages, Chapter 6.10.4 (J). -68- This paper size applies to Chinese National Standard (CNS) A4 (210x297 mm) (Please read the precautions on the back before filling this page)

505676 Printed by A7 B7, Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention. It is also possible to use a mixture of different plasticizers. , Especially from 20 to 70 parts by weight (calculated based on 100 parts by weight of PVC) ° Pigments: Suitable substances are familiar to those skilled in the art. Examples of inorganic pigments are τ 丨 〇2, carbon Black, F e 2 0 3, S b 2 0 3 (TI, Ba'Sb) 0 2 * Crz 0 b, spinel, like cobalt blue and cobalt green, C d (S, S e), Buddha Cyan. Organic pigments are, for example, azo pigments, titanium cyan pigments, quinacridone pigments, perylene pigments, dipyridyl pyrrolyl pigments, and quinone ketone pigments. Preferably, the emblem is a fine powder in the form of T i. 2 . Its definition and further explanation can be found in “H an db ο 〇k of PVC Formulating”, EJ Wickson, John Wiley & Sons, New York 1 9 9 3 〇 Filler: Filler (HANDB 0 0 K OF PVC FORMULATING, EJ Wickson John Wiley & Sons, Inc., 1993pp. 393-449) and auxiliary agents (TASC Η ENB ϋ CH der KA, e (HANDBOOK of Plastics Additives), R. Gachter & H. Muller, Carl Hanser, 1 9 9 0, pp 5 4 9-6 1 5) (Like calcium carbonate, dolomite, silica ash -69- This paper size applies to China National Standard (CNS) A4 size (210X297 mm) (Please read the back (Please fill in this page again)

505676 A7 B7 V. Description of the invention ("stone, magnesium oxide, magnesium hydroxide, silicate, glass fiber, talc, kaolin, chalk, mica :, metal oxides and hydroxides, carbon black or graphite) 〇 White was Phosphites: Examples of phosphites are triphenylphosphite, diphenylalkylphosphite, phenyldialkylphosphite, and tri (nonylphenyl) phosphite Phosphate, Trilauryl Phosphite, Tris-octadecyl phosphite, Distearylpentaerythritol diphosphite, Trinity (2,4 bis-tert-butylphenyl) Phosphite, diisodecyl pentaerythritol diphosphite, bis (2, printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 4 Monobutylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite, diiso Decyloxypentaerythritol diphosphite, bis, 4, t-butyl-t-butyl-6-methylphenyl) pentaerythritol Phosphite, bis (2,4,6-tri- (tert-butylphenyl) pentaerythritol diphosphite, tristearyl with sorbitol triphosphite, bis (2,4-di Mono-tert- 6-methylphenyl) methyl phosphite, bis (2,4-tert-butyl-6-methylphenyl) ethyl phosphite. Particularly suitable phosphites are tris Octyl phosphite, tridecyl phosphite, tris (dodecyl) phosphite, tris (tetradecyl) phosphite, tristearyl phosphite, trioleyl phosphite, tris Phenylphosphite, tricresylphosphite, ginsyl-p-nonylphenylphosphite or tricyclohexyl-70- This paper size applies to China National Standard Plum (CNS) A4 specification (210X297 mm) 505676 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of invention U "Phosphorous acid phosphite i", particularly preferred are aryldialkyl phosphinate M and alkyl diaryl phosphite, such as benzene Didecyl phosphite, (2,4-di-tert-butylphenyl) di (dodecyl) phosphite and (2,6-di-tert-butylphenyl) di Dodecyl) phosphites and dialkyl mono and diaryl-pentaerythritol diphosphites, such as distearyl pentaerythritol diphosphite and non-stoichiometric triaryl phosphites, such as (C 3 Η 1 9 -Cs Η 4 —〇) 1 · 5 — ρ ((0 — C 1 ζ i 3 Η 2 5-2 7) i · 5. The preferred organic acid is the distearyl group. Pentaerythritol diphosphite, trinonylphenylphosphite and phenyldidecylphosphite. The amount of organic phosphite used is basically, for example, 0 ♦ 〇1 to 1 〇, conveniently 0 ♦ 0 to 5 and preferably 0 to 1 to 3 parts by weight (based on 100 parts by weight of PVC). Thiophosphites and phosphorothioates: It must be understood that the thiophosphites and phosphorothioate compounds are as follows: (RS) 3P, (RS) 3P or (rs) 3p = s, which Described in DE-28, 09, 492, EP-090, 770 and EP-573,394. Examples of these compounds are: trithiohexyl phosphite, trithiooctyl phosphite, trithiolauryl phosphite, trithiobenzyl phosphite, trithiophosphate tri (carbon isooctyl) (Oxy) methyl ester, trithiophosphoric acid-71- This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Clothing · Order ♦ Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 505676 A7 B7 V. Description of the invention (good) Tris (carbotrimethylcyclohexyloxy) methyl ester, trithiophosphoric acid, S, S, S-tris (carbon isooctyloxy) Methyl) esters, trithiophosphoric acid S, S, S-tris (carbon-2-ethylhexyloxy) methyl esters, trithiophosphoric acid S, S, S-trione 1- (carbon hexyloxy) Ethyl), ethyl ester, trithiophosphoric acid S, S, S — trione 1 — (carbon — 2 —ethylhexyloxy) monoethyl ester, trithiophosphoric acid S, S, S — trione 2 — (Carbon-2-ethylhexyloxy) monoethyl esters 0 carboxylic acid esters: Examples of such compounds are thioglycolic acid, thiohydroxysuccinic acid, fluorenylpropionic acid Thio or mercapto acid ester of lactic acid, which is described in F R - 2,459,8 1 6, EP -. 90,748, FR - 2, 55 2,440 and EP - 365, 483. The sulfhydryl carboxylate also includes polyol esters and partial esters thereof. Epoxy fatty acid ester: The stabilizer composition of the present invention further comprises: preferably at least one epoxy fatty acid ester. Particularly suitable are fatty acid esters (fatty acid glycerides) of natural origin, such as soybean oil or vegetable oil. However, it is also possible to use synthetic products like epoxybutyl oleate. Antioxidants: Examples of suitable antioxidants are: -72- This paper size is applicable to China National Standards (CNS) A4 specifications (2i × 297mm) (Please read the precautions on the back before filling this page) Order # 经济 部Printed by the Central Bureau of Standards Consumer Cooperatives 505676 • A7 B7 V. Description of the Invention (θ) 1. Alkylated monophenols, such as 2,6-di-tri-mono-butyl-4 mono-methylphenol, 2-tertiary Monobutyl-4,6-dimethylphenol, 2,6-tertiary monobutyl-4-ethylphenol, 2,6-ditertiary monobutyl-4-n-butylphenol, 2 , 6-Di-tertiary mono-butyl-4 4-isobutylphenol, 2,6-di-cyclopentyl-4-methyl age, 2- (α-methylcyclohexyl) -4 '6-di Methylphenol, 2,6-dioctadecyl- 4-methylamidine '2, 4,6-tri-cyclohexylphenol, 2,6-di-tertiary monobutyl-4-methoxy Methyl phenol, 2,6-di-nonyl-4-methyl, 2,4-dimethyl-6- (1,1-methyl-undecane-1'-yl) phenol, 2, 4-dimethyl-1-6- (1, monomethyl ——Ht alkane-1′-yl) phenol, 2,4 bis-methyl-6— (1, -methyltridecane-1, yl), octyl ester, nonylphenol, ten Dialkylphenols and mixtures thereof. 2 ♦ Fluorenylthiomethylphenol, such as 2,4-dioctylthiomethyl-6-tertiary monobutylphenol, 2,4-dioctylthiomethyl-6-methyl Phenol, 2,4-octylthiomethyl-6-ethylphenol, 2,6-dodecanylthiomethyl 4-nonylphenol. 3 ♦ Alkylated hydroquinones, for example, 2,6-di-tertiary monobutyl-4 monomethoxyphenol, 2,5-di-tertiary monobutylhydroquinone, 2,5-di- Tertiary-pentyl-hydroquinone, 6-diphenyl-4-octadecyloxyphenol, 2,6-di-tertiary-monobutylhydrofluorene, 2,5-di-tertiary Monobutyl-4, triphenylbenzene, 3,5-di-tertiary monobutyl-4 monohydroxyanisole, 3,5-tri-tributyl monobutyl-4 monohydroxyphenyl hard-73 -'This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the notes on the back before filling this page) Order 505676 A7 B7 V. Description of the invention (y 〇) fatty acid, and double ( 3,5-di-tertiary monobutyl-4 monohydroxyphenyl) adipate. 4 ♦ Hydroxylated diphenyl sulfide, for example, 2, 2, monothiobis (6-tertiary monobutyl-4 methylol), 2, 2-thiomonobis (4-octylphenol) ) '4' 4 'Monothio-bis (6-secondary monobutyl-3-methylphenol), 4, 4, 4-thio-bis (6-tertiary butyl-2-methylphenol) ), 4,4, monothio-bis (3,6-diamino-pentylphenol) and 4,4, bis (2,6-dimethyl-4-hydroxyphenyl) disulfide . 5 ♦ Alkylene-bisphenols, eg, 2, 2, mono-methylene-bis (6-tri-mono-butyl-4-methylphenol), 2, 2, mono-methylene-bis (6- tertiary 1-butyl-1, 4-ethylphenol), 2, 2 '1-methyl-6- [4-methyl-6- (α-methylcyclohexyl) phenol], 2, 2' 1-methylene-bis (4 —Methyl-6-cyclohexylphenol), 2,2,1-methylene-bis (6-nonyl-4—methylphenol), 2,2,1-methylene-bis (4,6—two-three Grade-butylphenol), 2,2,1-ethylidene-bis (4,6—two-three-grade monobutyl_), 2,2'-ethylidene-one-bis (6-three-grade monobutyl) Printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China (please read the precautions on the back before filling this page). Yl) -1, 4-nonylphenol], 2,2 ', 1-methylidene-bis [6 -— (α, α-dimethyl-benzyl) -4—nonylphenol], 4, 4, 1-methylidene-bis (22,6-tertiary monobutylphosphonium), 4,4'-methylene-bis (6-tertiary monobutyl 2-methylphenol) 1,1 bis (5 — secondary monobutyl — 4 —hydroxy — 2 —methylphenyl) butadiene, 2, 6 — -74- This paper size applies to China National Standard (CNS) A4 specification (210 × 297) 5%) 505676 A7 B7 V. Description of the invention (/) Bis (3-tertiary monobutyl-5-methyl-2 2-hydroxybenzyl) -4 monomethylphenol, 1, 1, 3, 1 ginseng ( 5-tertiary monobutyl-4 monohydroxy-2 methyl) butane, 1, 1-bis (5-tertiary monobutyl-4 4-hydroxy-1 2-methylphenyl) 3-n-one Dodecylhydrothiobutane, ethylene glycol bis [3,3-bis (3'-tertiary-butyl-4'-hydroxyphenyl) but'enoic acid S]], bis (3-bis Mono-butyl-4, trimethyl-5methylphenyl) dicyclopentadiene, bis [2-((3'-tertiary-butyl-2, _hydroxy-5, monomethylbenzyl) 6 —Tertiary monobutyl-4 methylphenyl] terephthalate, 1,1 bis (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis ( 3,5-two three three one Γ group 4 one hydroxyphenyl) C, 2, 2 Bis (5-tertiary monobutyl-1, 4-trimethyl-2-methylphenyl), 4-n-dodecyl hydrothiobutane and 1 '1, 5, 5, 4- (5-secondary Monobutyl 4-hydroxy-2-methylphenyl) pentane. 6. Benzyl compounds, examples 3, 5, 3, 5, 5, 1413, 3D, printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). 4'-dihydroxydibenzyl ether, octadecyl-4, 4-hydroxy-3, 5-dimethylbenzyl hydrothioacetate, (3,5-di-tertiary monobutyl-4 4-hydroxy Benzyl) amine, bis (4-tertiary monobutyl-3, hydroxy-1,6-dimethylbenzyl) dithioterephthalate, bis (3,5-tri-tertiary monobutyl Phenyl-4,4-benzyl) sulfide, and isooctyl-3,5-tertiary monobutyl-4,4-hydroxybenzyl hydrothioacetate. 7 ♦ Hydroxybenzyl malonate, such as dioctadecyl, 2,2-bis (3,5-di-tertiary-butyl-2-hydroxybenzyl) malonate-75- This paper size applies to China National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of Invention (Production :), 218 焼 2-(3- Secondary monobutyl-4 methyl a-5,5-methylbenzyl) malonate, dodecanehydrothioethyl, 2,2-bis (3,5-di-tertiary-butyl Mono-4-hydroxybenzyl) malonate, di [4- (1,1,3,3-tetramethylbutyl) phenyl] 2,2 bis (3,5-di-tertiary monobutyl) A 4-hydroxybenzyl) malonate 0 8 · Hydroxybenzyl-aromatic compounds, for example: 1,3,5-ginseng (3,5-two-three-three mono-butyl-4-hydroxybenzyl) -2,4,6 monotrimethylbenzene, 1,4-bis (3,5-di-tri-n-butyl-4 hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4,6 a ginseng (3,5-two three three monobutyl one 4 monohydroxybenzyl) phenol. 9 ♦ Triazine compounds, for example, 2,4-bis-octylhydrosulfide-6- (3,5-di-tertiary-monobutyl-4-hydroxyaniline) -1,3,5-triazine, 2-octylhydrosulfanyl-4,6-bis (3,5-dione-secondary-4 4-hydroxyaniline)-1 ν 3,5-triazine, 2-octylhydrosulfanyl-4,6 -Bis (3,5-di-tertiary monobutyl-4 monohydroxyphenoxy) -1,3,5-triazine, 2,4,6-ginseng 4- (4-hydroxyphenoxy) -1,2,3-triazine, 1,3,5--ginseno (3,5—di-tertiary monobutyl-4 4-hydroxybenzyl) isocyanurate , 2,4,6--ginseng (4-tertiary monobutyl-3-hydroxy-2,6-di-methylbenzyl) isocyanurate, 2,4,6 —ginseno (3,5- Two-three-grade—butyl-1, 4-hydroxyphenylethyl) -1, 3, 5-triazine, 1, 3, 5- — ginseng (3,5 —-76-) This paper size applies to the Chinese National Standard (CNS ) Α4 size (210 × 297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention (7) Two-three-level monobutyl-4 monohydroxyphenylpropanyl) hexahydro-1,3,5-triazine and 1,3,5-tris (3,5 —Dicyclohexyl—4-hydroxybenzyl) isocyanurate. 1 0 · phosphonates and phosphinates, for example, dimethyl-2,5-di-tert-butyl-4 ~ tert-butyl- 5 ----- 3, octa-1 phosphonate, 3 4} of monoethyl esters / 1, 8, 10-4 1, 3, 2-2)-5 2 4, 8-hydroxybenzyl phosphonate, diethyl 3, 5- Di-4 monohydroxybenzyl phosphonate, bis (octadecyl) -tert-butylbutyl-4 monohydroxybenzyl phosphonate, di (undec-tert-butyl-1, 4-hydroxy-1, 3-methyl) Benzylmethyl 5-di-tert-butyl-4 4-hydroxybenzyl-phosphonic acid calcium salt, tetra (2,4-di-tert-butylphenyl) -phenylene diphosphinate, 6-Isooctyloxy-2,4, 1-tert-butyl-12H-dibenzo. [D, g] -dioxaphosphocine, 6-fluoro, 10-tetra-tert-butyl 12-Methyldibenzo (Please read the notes on the back before filling this page) [d Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1,3,1 1 ♦ Aminoaminophenol, eg -Hydroxystearate Acid acetanilide phenyl) carbamate butyl 12 acid and 1,2-alcohol, g 2 -dioxaphosphine. For example, 4-hydroxy-l-lauryl taniline, 4 octyl-N — (3,5-di-tert-4-4-hydroxy • β — (3,5-di-tert-butyl-4-hydroxyphenyl) Propane mono- or poly-hydroalcohol 6-hexanediol, 1, neopentyl alcohol, pentaerythrylene glycol triethylene diester, such as and methanol, ethanol, stearyl alcohol, 9-nonanediol , Ethylene glycol, 1, diol, thiodiethylene glycol, diethylene ditetraol, tris (hydroxyethyl) isocyanurate-77- This paper is applicable to Chinese National Standard (CNS) A4 specifications ( 210X297 mm) 505676 A7 B7 V. Description of the invention (7 ^) Ester, N, N, bis (hydroxyethyl) ethylenediamine diamine, 3-thiaundecanol, 3-thiopentadecanyl alcohol, Trimethylhexanediol, trimethylolpropionamidine, 4-hydroxymethyl-1-6-methyl-2,6,7-trioxabicyclo [2 ♦ 2, 2] octane. 13 · /? — (5-tert-butyl-1, 4-hydroxy-1, 3-methylphenyl) esters of propionic acid and mono- or polyhydric alcohols, such as, and methanol, ethanol, stearyl alcohol, 1,6-hexane Diol, 1,9-nonane-diol, Ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanate Uric acid esters, Ν, Ν'-bis (hydroxyethyl) ethylenediaminediamine, 3-monothiaundecanol, 3-thiapentadecanyl alcohol, trimethylhexanediol, trimethyl酉? Propionate '4 once methyl methyl-1-5-2-6, 6, 7-trioxabicyclo [2 * 2, 2] octane. 1 1 4 · call one (3, 5-dicyclohexyl one 4 Monohydroxyphenyl) propionic acid and mono- or polyhydric alcohol esters, such as with methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1,9 monononanediol, ethylene glycol , 1,2 — Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, Triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethylenediamine diamine, 3-_undecanol, 3 —Thiapentadecanol, three Hexanediol, trimethylolpropane, 4-monomethylol- 1-phospho-2,6,7-trioxabicyclo [2 · 2 • 2] octane. 15.3, 5 -di One tertiary, one butyl-1, 4-phenylphenylacetic acid and mono-78- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 Five 1. Description of the invention: Monoesters or polyhydric alcohols, such as with methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1,9 monononanediol, ethylene glycol, 1,2-propanediol Alcohol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N ^ N? One pair (Hydroxymonoethyl) ethylenediamine, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethyl alcohol propane, 4-hydroxymethyl-1 1 Phosphorus-2,6,7-trioxabicyclo [2 ♦ 2 ♦ 2] octane. 16 · / 3 — (3,5-di-tert-butyl- 4 -hydroxyphenyl) propanamide, such as N, N, bis (3,5-di-tert-butyl- 1- 4-Hydroxyphenylpropylammonium) hexamethylene diamine, Ν, Ν'-bis (3,5,1,2-tert-butyl-4-hydroxyphenylpropyl ugly) trimethylenediamine, Ν, Ν, one pair (3,5-di-tert-butyl-4 4-hydroxy-phenylpropionamidine) hydrazine. Antioxidants of groups 1 to 5, 10 and 12 are preferred, especially 2,2-bis (4-monohydroxyphenyl) propane, 3,5-di-tert-butyl- 4 monohydroxybenzene Esters of propionic acid and octanol, stearyl alcohol or pentaerythritol, or tris (2,4-di-tert-butylphenyl) phosphite. Mixtures of antioxidants with different structures may also be used where appropriate. The amount of antioxidant used is, for example, from 0 · 0 1 to 10, conveniently 0 · 1 to 10, and preferably 0 · 1 to 5 parts by weight (calculated based on 100 parts by weight VC). -7 9- This paper size applies to Chinese National Standard (CNS) Α4 size (210X297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (7 ^) UV absorption and light stabilizer: Examples are: 1 ♦ 2 — (2, —hydroxyphenyl) benzotrivalyl, for example , 2-(2, -hydroxy-5'-methylphenyl) -benzotriazolyl, 2- (3 ', 5'-di-tert-butyl-2' '-hydroxyphenyl) benzo Triazolyl, 2- (5, mono-tert-butyl-2 'monohydroxyphenyl) benzotriazolyl, 2- (2, monohydroxy-5' mono (1, 1, 3, 3-tetramethyl) Butyl) phenyl) benzotriazolyl, 2 — (3,5′-tert-butyl- 2′-hydroxybenzyl) -5 —chloro-benzotriazolyl, 2 — (3'-tert-butyl-2, 1-hydroxy-5, -methylphenyl) -5-chloro-benzotriazolyl, 2- (3, -sec-butyl-5,1-tert- Butyl- 2'-hydroxyphenyl) benzotriazolyl, 2- (2'-hydroxy-4'-octyloxyphenyl) benzotriazolyl, 2- (3,, 5, —di-tert-yl Monopentyl-2, monohydroxyphenyl) benzotriazolyl, 2-(3 /, 5, 1, bis (^, ^-dimethylbenzyl) -2, 1-hydroxyphenyl) benzotriazolyl, 2-(3'-tert-butyl-1 2'-hydroxyl-5 'Mono (2-octyloxycarbonylethyl) phenyl) -5-chloromonobenzotriazolyl, 2- (3, -tert-butyl-5'-[2- (2-ethylhexyl (Oxygen) -ethyl] -2'-hydroxyphenyl) -5-chloro-benzotriazolyl, 2-(3'-tert-butyl-2'-meridyl-5, a (2-methyl Oxycarbonylethyl) phenyl) 5-chloro-benzotriazolyl, 2- (3, t-tert-butyl-2, hydroxy-5,1- (2-methoxycarbonylethyl) Phenyl) benzotriazolyl, 2 — (3 'mono-tert-80-) This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Order

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the invention (7) Butyl-2'-hydroxy-5 / — (2-octyl-oxycarbonylethyl) phenyl) benzotriazole , 2 — (3, —tert-butyl-5, — [2-(2-ethylhexyloxy) carbonylethyl]-2 'monohydroxyphenyl) benzotriazolyl, 2 — (3, 1 Dodecyl-2'-hydroxy-5'-methylphenyl.) Benzo-dioxalyl, and 2- (3-tert-butyl-2'-hydroxy-1 5 '-(2-isooctyl Oxycarbonylethyl) phenylbenzotriazolyl 2,2'-methyl-a-bis [4-mono (1,1,3,3-tetramethylbutyl) -6-benzotriazolyl-2 -Ylphenol] mixture; 2-[3 ^ mono-t-butyl-5, mono- (2-methoxycarbonylethyl)-2'-hydroxy-phenyl]-2H-benzotriazolyl and poly Esterification product of ethylene glycol 30 0; where R = 3'-tert-butyl- 4'-hydroxy-5'-2H-benzotriazolyl-2-ylphenyl. 2 · 2-hydroxydiphenyl Ketones, for example, 4-hydroxy, 4-methoxy 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2,4,4-trihydroxy and 2, hydroxy-1,4,4-dimethyl Oxygen derivatives. 3 ♦ Ester of substituted or unsubstituted benzoic acid, such as 4-t-butyl-phenylsalicylate, phenylsalicylate, octylphenylsalicylate, di Benzamidine resorcinol, bis (4-tert-butylbenzylhydrazone) resorcinol, resorcinol, 2,4-tert-butylphenyl 3,5-dione Tert-Butyl-4 monohydroxybenzoate, cetyl 3,5-di-tert-butyl-4 monohydroxybenzoate, octadecyl 3,5-di-tert-butyl —4 Monohydroxybenzoate, 2 —Methyl-4,6 —Di-tert-Butyl-8 1-This paper size applies to China National Standard (CNS) A4 (210X297 mm) (please read the back first) (Notes for filling in this page)

505676 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention 9)) Phenylphenyl 3,5-di-tert-butyl-1, 4-hydroxymonobenzoate. 4 · Aromatic esters, such as ethyl α-fluoro-1 / ?, / 3-diphenyl acrylate, isooctyl α-cyano-3, / 3-di-phenyl acrylate, methyl α- Carbomethoxycinnamate, methyl ex-cyano-Θ, / 3-methyl-P-methoxy-cinnamate, butyl ex-cyano / 3, / 3-methyl-ρ- Methoxy-cinnamate, methyl α-carbomethoxy-ρ-methoxy sarcoate and N- (/ 3-carbomethoxy- / 3-cyanovinyl)-2 -methyl Gindin asked. 5 ♦ Nickel compounds ♦ For example, 2, 2 'monothio-bis- [4 — (1, 1, 3,' 3-tetra-methylbutyl)] nickel complex, such as 1 * 1 or 1: 2 complexes, with or without additional reactive groups, like n-butylamine, triethanolamine or eta-cyclohexyldiethanolamine, nickel dibutyldithiothiocarbamate, 4-hydroxy-3, Nickel salts of monoalkyl esters of 5-di-tert-butylphosphoniumphosphonic acid, such as methyl or ethyl esters, nickel complexes of oxime, such as 2-hydroxy-4methylmethylundecane Ketone oxime, a 1-phenyl-4 lauryl-5,5-hydroxy carbazolyl nickel complex, with or without additional reactive groups. 6, sterically hindered amines (Sterica 11 yhindei, edamines), such as bis (2,2,6,6-tetramethyl-eridinyl) sebacate, bis (2, 2,6 * 6-tetramethyl) Mono-piperidinyl) succinate, bis (1,2,2,6,6-pentamethylmethylpyridinyl) sebacate g, bis (1,2,2,6,6-pentamethyl) Keatonyl) η-Butyl-3,5-di-tert-butyl-4-hydroxybenzylmethylmalonate, 1- (2-hydroxyethyl) This paper is applicable to the Chinese national standard ( CNS) A4 specification (210 × 297 mm) (please read the precautions on the back before filling this page). ♦ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. , 6-tetramethyl-1,4-hydroxysuccinic acid succinic acid concentrate, N, N, bis (2,2,6,6-tetramethyl-1,4-piperidinyl) hexamethylenediamine and 4 mono-tert-octylamino-2,6-dichloro-1,3,5-triazine'trione (2,2,6,6-tetramethyl-1 4-piperidinyl), four ( 2, 2, 6, 6 — four Methyl-4-oxo-pyridinyl) -1,2,3,4,1-butane-tetracarboxylic acid ester, 1,1,-(1,2-ethanediyl) bis (3,3,5, · 5-tetramethylpyrazine hydrazone), 4-benzylhydrazone-2,2,6,6-tetramethylmethyl, 4-stearylmethyloxy-2,2,6,6-tetramethyl Pyridine, bis (1,2,2,6,6-pentamethylpyridinyl)-2-η-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzoyl Propyl) malonate, 3 -η-octyl-7,7,9,9-tetramethyl-1,3,8-triazafluorene [4 · 5] decane-2,4-dihedral , Bis (1-octyloxy-2,2,6,6-tetra-methylmethylpyridinyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethyl) Concentrate of stilbene) succinate, N, N ^ -bis (2,2,6,6-tetramethyl-1, 4-group, 0-base) hexamethylenediamine and 4-monomorpholino-2 , 6-dichloro-1,3,5-diazine condensate, 2-chloro-1,4,6-bis (4-a-n-butyl-amino-2,2,6,6-tetramethyl base Pyridyl) -Concentrate of 1,3,5-triazine and 1,2-bis (3-aminopropylamino) -ethane, 2-chloro-4,6-dione (4-n-butane Aminoamino-1,2,2,6,6-pentamethylpiperidinyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethyl-83-benzyl Paper size applies Chinese National Standard (CNS) Α4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 505676 A7 B7 V. Description of the Invention (and) Alkanes, 8-Ethyl-3, Dodecyl-7, 7, 9, 9, 9-Tetramethyl-1, 3 , 8-triazaphosphonium [4 ♦ 5] decane-2,4-diamine, 3-dodecyl-1 1- (2,2,6,6-tetramethyl-1 4 steep group) K Interview with 1, 2, 2-, 2-, 3-dodecyl-1, 1- (1,2, 2, 6, 6, 6-pentamethyl-1, 4-pyridyl) pyrrolidine-2, 5-divalent and Chimassorb 966. 7 ♦ Diethylene glycol diamines, such as 4,4'-dioctyloxymonooxoaniline, 2,2,12-dioctyloxy-5,5,1,2-tert-butoxy-monobutyrate Aniline, 2,2, 222 alkoxyl-5,5, -di-tert-butoxyfluortanilide, 2-ethoxy-2'-ethoxyfluortanilide, N, N, 1 Bis (3-dimethylaminopropyl) ethylenedifluorenediamine, 2-ethoxy-1,5-tert-butyl-1,2'-ethoxythioaniline and its 2-ethoxy-1,2'-1 A mixture of ethyl-5,4'-di-tert-butoxyanilide and a mixture of ortho- and meta-methoxydisubstituted oxotetanil, and 0- and P-ethoxy- Disubstituted oxamidine. 8 ♦ 2 — (2-hydroxyphenyl) -1,3,5-triazine, for example: 2,4,6-dione (2-hydroxy-4 4-octyloxy-phenyl) -1,3 , 5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2 — (2,4 dihydroxyphenyl) — 4,6 —bis (2, 4 dimethylphenyl) — 1, 3, 5-triazine, 2, 4 — bis (2 — hydroxy — 4 — Propyloxyphenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-octyloxy-8-4-paper size Applicable Chinese National Standard (CNS) A4 specification (21〇 × 29 * 7mm) —ί # 1— (Please read the precautions on the back before filling this page)

TT

505676 A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention) Phenyl) -1,4,6-bis (4-methylphenyl) -1,3,5-triazine, 2-(2 —Hydroxy-4 dodecyl monooxyphenyl) —4,6—bis (2,4-dimethylphenyl) —1,3,5-triazine, 2-[2-hydroxyl, 4-((2-hydroxy-3-butyloxy-propoxy) phenyl] -4,6--bis (2,4-dimethyl) -1,3,5-triazine, 2 -— [2- — Hydroxy-4 4- (2-hydroxy-3-octyloxy-propyloxy) phenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine . Drainage agents (Pr ο p e 11 a n t s) Drainage agents are organic azo and hydrazine compounds, tetrazole, oxazine, N-carboxyaminobenzoic anhydride, and sodium carbonate and sodium bicarbonate. Preferred are azodicarbamide and sodium bicarbonate and mixtures thereof. Definitions and examples of impact strength modifiers and processing co-ribs, gelling agents, antistatic agents, biocides, metal deactivators, optical brighteners, flame retarders and anti-fog agents are described in 〃 Kunst st of f additive "(Plastics Additives), R. Gachter / H. Muller, Carl Hanser V er 1 ag, 3rd Ed., 1989, and" Handbook of Polyvinyl Chloride Formulating ', "E. J. Wilson, J. Wiley & Sons, 1S33. Impact modifiers are also widely described in " Impact Modifiers for PVC :, J. T. Lutz / D. L. Dunkelberger, John Wiley & Sons, 1992. This stabilizer composition cannot be limited to It is prepared in the device and the paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7 5. The invention description (JV) can be obtained, and some other added additives and / or molten metal soap can be made before adding ingredient A). This method is particularly suitable for the preparation of calcium acetoacetate (c f * E P — 3 3 6, 2 8 9). Examples of stabilized chlorinated polymers, or their reproductions: vinyl chloride polymers and vinyl chloride polymers containing ethylene resin units in the structure, such as copolymers of vinyl chloride and fatty acid vinyl esters, especially ethyl acetate ; Copolymers of vinyl chloride and acrylic acid and methacrylic acid and acrylonitrile; copolymers of vinyl chloride and difluorene compounds and unsaturated dicarboxylic acids or anhydrides thereof, such as vinyl chloride and diethyl maleate, diethyl Copolymers of methyl fumarate or maleic anhydride; monochlorinated polymers (ρ ost-ch 1 〇rinated) and copolymers after vinyl chloride; vinyl chloride and vinylidene chloride and unsaturated aldehydes, Ketones and other substances, such as propane 11, butenal, ethylene methylhexene, ethylene methyl ether, ethylene isobutyl ether, and the like; polymers of vinylidene chloride, and its compounds with ethylene chloride and others Copolymers of polymeric compounds; polymers of ethylene chloroacetate and divinyl dichloride; chlorinated polymers of ethylene acetate, chlorinated polymeric esters of acrylic acid and alpha-substituted acrylic acid; chlorinated styrene , Such as dichlorostyrene Polymers; chlorinated rubber; chlorinated polymers of ethylene; polymers of chlorinated butadiene and post-chlorinated polymers and their copolymers with vinyl chloride; rubber hydrochlorides and chlorinated rubber hydrochlorides Copolymers; and mixtures of the polymer and another or other polymerizable compound. Chlorinated polymers also include graft polymers of PVC and EVA, ABS and MBS. The preferred substrate is a mixture of the above homopolymers and copolymers, especially vinyl chloride homopolymers, and other thermoplastics and / or elastomers. -86- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) ) (Please read the notes on the back before filling this page)

505676 A7 B7 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention ((f)) 1 1 «Polymer polymer mixtures, especially with ABS? Μ Β S, Ν Β R 9 1 1 SANEVA c PE Μ Mixtures of BAS, Μ A 5 Ρ Μ Μ AI, EPD Μ and polylactones 0 Please 1 [read suspension polymers and block and milky polymers are preferred. 的 Read Back | Polyvinyl Chloride I Ethylene is a particularly good chlorinated polymer 9 Especially in suspension and block Note 1 | Shaped polymer 0 Meaning 1 Item 1 It is within the scope of the present invention-jy solution is P VC also includes refilling t 1 Copolymer or graft polymer of PVC and polymerizable compound 5 Like acrylonitrile ethylene acetate or ABS and it may be suspended. Block or milky 1 1 Polymer 0 Preferred is Homopolymer of PVC and polyacrylate 0 1 I ^ rft of chlorinated polymer The product of the present invention is also particularly stable. This 1 1 compound has been ordered as described above and is used or stored for processing. Cause 1 Damage 0 洹 Sit rework can also include small amounts of other substances 9 like paper pigments 1 1 and additives (usually difficult to remove) 0 These other substances may also be caused by contact with various substances during use or processing 1 1 Produces 5 residues like drainage agent 5 1 small amount of paint and small amount of metal and initiator residues. The present invention also relates to a method for stabilizing a chlorinated polymer 9 including the addition of 1 1 polymer as described in the patent application No. 1 Item stabilizer composition% and 1 1 9 homogeneously mix these ingredients in a suitable device 0 I 1 Advantageously this m tincture can be used under Method of adding: It is added in the form of emulsion or dispersion (one may be, for example, like a paste 1 mixture) 0 The composition M of the present invention has the advantages of 1 1 the stability of the paste f 1 1 1- 87-1 1 1 This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 505676 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention (outside) ^ Additive ingredients or polymers When the mixture is added, the type of the dry mixture is added; the rice is directly added in the processing device (for example, the calender 'mixer', kneader, extruder or the like); or ^ added as a solution or a melt. The present invention also relates to a stabilized P VC, which can be prepared by a conventional method of kappa, wherein the stabilizer composition (and other suitable additives) of the present invention is mixed using a conventional device, such as a processing device on top . In this procedure, the stabilizer can be added alone, or in the form of a K mixture 'or on the other hand as a K precursor. The present invention also relates to a method for preparing stabilized P VC, comprising using a suitable apparatus such as a calender, a mixer, a kneader, an extruder and the like to mix P VC with the above-mentioned ingredients (b), (c) And (d), and other appropriate additives. K The stable PVC of the present invention can be formed into various shapes by conventional methods, such as grinding, calendering, extrusion, injection molding, sintering or spinning, and also includes blow extrusion molding, or K dissolving Molding method. This stabilized P V C can also be processed into a foam shape. When using azocarbon amine as a drainage agent, it is advantageous not to use an additional 1,3-difluorene. Μ The stable P V C of the present invention is suitable, for example, as a semi-rigid or soft formulation, and is particularly suitable for wire coverings and glass-breaking mats (automobiles) and as wire insulators. In the semi-rigid formulation, the p VC of the present invention is particularly suitable for decorative films, foams, agricultural layers, tubes, dense-88-This paper size applies to China National Standard (CNS) A4 specifications (210 × 297 (Mm) (Please read the notes on the back before filling out this page), 1T # Printed by 505676 A7 B7_, the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (p <) Sealing contours, and office films. In the rigid formula, the stabilized PVC of the present invention is particularly suitable for hollow articles (bottles), packaging coverings (thermoformed coverings) 'blown layers, pipes, foams, heavy duty contours (window frames) 'Transparent wall contours, building contours, exterior wall objects, fixtures, office coverings and canisters (computers and home appliances) ° The plasticizer (p 1 as t. Is ◦) of the polymer PVC of the present invention 1 s) Application examples are artificial leather, floor coverings, textile coatings, 'wall covering paper, coil coatings, and automotive bottom seals.' Application examples of the sintered PVC of the present invention are 'slimes, slime models, and coils. Coating. Preferred are PVC rigid foam models and PVC pipes, such as PVC pipes for pressure water or wastewater, pressure pipes, gas pipes, conduits for wire and protection pipes, coated pipes for industrial pipelines, and drainage Pipe, waste pipe, sewage pipe. More detailed information can be found in 〃 Kunststoffhandbuch PVC ”(PVC Plastics Handbook), Volume 2/2, W. Becker / H.Braun, 2nd Ed., 1985, Carl Hanser V er 1 ag, pages 1236-1277 〇K The following example will further illustrate the present invention, but it is not limiting. Parts and percentages in other parts of the present invention are calculated by K weight unless otherwise specified. Example 1: Static heat test. -89 -This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Order

505676 A7 B7 V. Description of the invention (yesterday) Plasticize each mixture according to the following table for 5 minutes (190 ° C, and on a roller, 170 ° C). A test strip (0.3 mm thick) was cut out from the resulting layer, and a M t h i s T h e r m 〇-T ak e r test (1 90 ° C) was performed for the time indicated in the table below. The yellowing index (Y I) was then tested according to A S T M — 1 2925 — 70. The lower the yellowing index, the better the effect of the stabilizer system to prevent yellowing (that is, damage to the substance). The long-term thermal stability of stabilized polymers can also be measured by the appearance of sudden discoloration of the entire polymer. Yanyuan, the time of discoloration when heated, or the lower the value of the discoloration and the better the color retention (low discoloration), the better the effect of the stabilizer. Table I: Equilibrium thermal test (190 ° C, rolling at 190 ° C for 5 minutes (please read the precautions on the back before filling this page) Order the printed mixture I of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 1 12 13 Sol vie 268 DC (S-PVC K value 68) 100 100 100 0 μ ya 1 ite 3 0 T 1) 3. 0 / / calcium stearate 0.6. 6 0. 6 0. 6 Hostalub H42 1. 0 1. 0 1. 0 Η osta 1 ub H 1 2 za 0. 2 0. 2 0. 2 CH 3003 0. 4 0. 4 0. 4 Mark 6045 ACM4 0. 3 0. 3 0. 3 Stabilizer 5 0. 2 0. 2 0. 2 -90-

This paper size applies to China National Standard (CNS) A4 (210X297 mm). 5. Description of the invention (Η) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 505676 A7 B7

NaC 14 // 0.05 YI YI YI minutes 10 2 0.7 2 9.9 2 2.2 15 28.4 66.6 29.1 20 40.2 108.4 39.2 1 chalk 2 guide agent, 2 a guide agent (polar vinyl wax) provided by Hoechst (石 躐), 3-based isodecylphosphite 49% NaCl4, 45% CaCO3, 40UaSi (h, 6% H2 0 mixture) 6-amino-1,3-dimethyl-uracil provided by Hoechst It was found that the use of a small amount of perchlorate compound as the component B in the mixtures I 1 and I 3 of the present invention has better stabilization effect than the mixture without the component B. Table II: Equilibrium heat test (190 ° C, Rolled for 5 minutes at 170 ° C) Mixture III II 2 II 3

Evipol SH 6030 -9 1- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention (PVCK value 60) 100 100 100 CH- 3 0 0 3 0. 8 0. 8 Was Εβ 0. 4 0. 4 0. 4 Epoxy soybean oil 5. 0 5 0 5. 0 Araldite GY 2507 / / / Ara 1 dite PT 8 10s / / / Stabilizer 1 5 1. 0 / / Stabilizer 2 9/1. 0 / Stabilizer 3 1 〇 / / 1.0 minutes YI YI YI 20 17.4 17.3 15.6 2 5 23.2 33.7 29.5 30 33.6 54.9 46.3 (Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Mixture Evipol SH 6030 (PVC K value 60) CH-3003 Was Εβ epoxy soybean oil Aral elite GY 2 5 0 7 A ra 1 dite FT 81〇Q 14 100 92- This paper size applies to China National Standard (CNS) A4 specifications (210X29? Mm) 5 100 I 16 100 505676 A7 B7 V. Description of the invention) Stabilizer printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 15 1 · 0 / / Stabilizer 2 9 / 1. 0 / Stabilizer 3 1 ° / / 1. 0 YI YI YI minutes 2 0 13.4 11.8 12.5 25 17.8 18.5 17.7 30 23.5 29.9 27.8 Mixture II 7 I 18 II Evipol SH 6030 (PVC K value 60) 10 0 100 100 CH-3003 0. 8 0. 8 0. 8 Was E8 0. 4 0. 4 0. 4 Epoxidized soybean oil // / / Araldite GY 2 5 0 7 / / / Araldite PT 8 1〇s 5. 0 5. 0 5. 0 Stabilizer 1 5 1.0 // stabilizer 2 9/1. 0 / stabilizer 3 1 ° / / 1.0 0 YI YI YI minutes 20 14.8 16.2 17.1 -93- 『Packing-(Please read the precautions on the back before filling this page) Order # This paper size applies Chinese National Standard (CNS) A4 specification (21〇29 < 7 mm) 505676 5. Description of the invention) Economy Central Bureau of Standards staff printed consumer cooperatives

A7 B7 25 2 1.2 24.4 24.0 30 27.2 33.6 30.8 3 Phenylisodecylphosphite 6-ester wax (K-nonadecanoic acid based) 7 Diglycidyl of bisphenol A (liquid epoxide) 3 Solid heterocyclic epoxy resin (triglycidyl isocyanurate) 9 6-Amino-1,3-di-n-butyluracil Results The amine uracil compound and epoxypropyl compound of the present invention The stabilizer composition (II 4 to II 9) is effective. Table I I I: Equilibrium heat test (19 0 ° C, rolling at 17 0 ° C for 5 minutes) Mixture I I I 1 I I I 2

Evipol SH 6030 (PVC K value 60) 100 100 CH-3003 〇 · 8 0.8

Was E 6 0.4 0.4 Epoxy soybean oil 5.Q 5.0

Rhodiastab 501 1 0.2 0. 2 Calcium stearate 0. 3 0.3 -94- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

505676 A7 B7 V. Description of the invention (f /) Zinc stearate printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0.5 0.5 0.5 0.5 DASC 1 2 / / / Alkamizer I 1 3 / / / stabilizer 1 5 1. 0 / / stabilizer 2 9/1. 0 / stabilizer 3 1 ^ / / 1. 0 YI YI YI minutes 20 15.2 2 2.7 37.4 25 3 1.4 66.9 30 57.2 Mixture III 4 III 5 III 6 Evipol SH 6030 (PVC K value 60) 100 100 100 CH-3003 0.8 0. 8 0. 8 Was E6 0.4 0. 4 0.4 Epoxy soybean oil 5. 0 5. 0 5. 0 Rhodiastab 5 0 1 1 0. 2 0. 2 0 .2 Calcium stearate 0. 3 0. 3 0. 3 Zinc stearate 0. 5 0.5 0. 5 DASC 1 z 1. 0 1. 0 1,0 A 1 kamizer I 1 3 / / / »95 -_ Equipment-(Please read the precautions on the back before filling this page)

、 1T This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm) 505676 A7 B7 V. Description of invention qX) Stabilizer printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 15 1. 0 / / Stabilizer 2 9 / 1. 0 / stabilizer 3 1 〇 / / 1.0 minutes YI YI YI 20 12.9 10.6 16.1 2 5 20.6 22.5 26.5 30 34.0 49.1 4 1.8 Mixture E vi ρ 〇1 SH 6 0 3 0 III 7 III 8 III 9 (PVC K value 60) 100 100 100 CH-3003 0. 8 0. 8 0. 8 Was E6 0. 4 0.4 0. 4 Epoxy soybean oil 5. 0 5. 0 5 · 0 Rhodiastab 5 0 1 1 0. 2 0. 2 0. 2 Calcium stearate 0. 3 0.3 0. 3 Zinc stearate 0. 5 0. 5 0. SDASC 1 z / / / Alkamizer I 1 3 1. 0 1. 0 1. 0 Stable Agent 15 1.0 / / Stabilizer 2 9/1. 0 / Stabilizer 3 1 ° / / 1. 1.0 -96- (Please read the precautions on the reverse side before filling out this page) The paper size of the paper is subject to Chinese national standards ( CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of invention (/ M YI YI YI minutes 20 10.0 10.2 12.4 2 5 16.3 17.0 18.8 3 0 24.1 2 9.7 26.5 1 1 Benzene stearate Trimethane (provided by R Η 0 NE-P 0 ULENC) 1 2 Sodium dihydroxyaluminum carbonate (DASC) 1 3 Hydrotalcite (supplied by KY0WA Japan) Adding sodium aluminum hydride and hydrogenated talc can increase stability. Table I v: Equilibrium thermal test (1 9 ο υ, rolling at 1 70 ° C for 5 minutes) | Equipment-(Please read the precautions on the back before filling this page) Order by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation mixture IV 1 IV 2 IV 5 W Evipol SH 6030 (PVC K value 60) 100 100 100 CH-3003 0. 8 0. 8 0. 8 Was E8 0. 4 0. 4 0.4 Epoxy soybean oil 2. 0 2 0 2. 0 Rhodiastab 5 0 1) 0. 2 0. 2 0. 2 Chimassorb 9441 " μ / / / -97- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 V. Description of Invention (/ f) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Malbit CR (maltite) / / / dipentaerythritol / / stabilizer 1 5 1. 0 / / stabilizer 2 9/1. 0 / stabilizer 3 1 9 '/ / 1.0 YI YI YI minutes 1 0 6.0 6.6 10.3 15 10.1 12.7 18.7 2 0 24.2 29.5 4 7.9 25 59.9 > 70 > 60 Mixture IV 4 IV 6 IV 6 Evipol SH 6030 (PVC K value 60) 100 100 100 CH-3003 0. 8 0. 8 0.8 Was E6 0. 4 0. 4 0. 4 Epoxidized soybean oil 2. 0 2. 0 2. 0 Rhodiastab 501] [0.2 0. 2 0. 2 Chiniassorb 9 4 4 1 4 0.15 0.15 0.15 Malbit CR (maltite) / / / dipentaerythritol // / / Stabilizer 1 5 1. 0 / / -98- (Please read the precautions on the back before filling this page)

This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (if) Stabilizer 2 9 Stabilizer 3 1 9 / / 1.0 minutes YI YI YI 10 8. 6 5 8 9. 0 15 7.8 7. 7 11.1 20 13.8 10.6 15.4 25 29.1 32.1 24.8 Mixture Evipol SH 6030 IV 7 IV 8 IV 9 (PVC K value 60) 100 100 10 0 _pack-(Please read the notes on the back first (Please fill in this page for matters) Order printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

CH-3003 〇.8 Was E6 0.4 epoxy soybean oil 2.0 Rhodiastab 501 1 0.2 Chimassorb 9441 4 / Malb it CR (maltite) 0 dipentaerythritol / stabilizer 1 5 1.0 stabilizer 29 / stabilizer 3 1 9 / YI

YI # / / / / /

YI -99- This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 505676 A7 B7 V. Description of invention 10 15 20 2 5 11.1 19 10. 1 1. 16. 16. Mixture IV 1 0 Evipol SH 6030 (PVC K value 60) 100 CH- 3 0 0 3 〇 8 Was E6 0.4 epoxy soybean oil 2.0 Rhodiastab 501 1 0. 2 Chimassorb 9441 4 / Malbit CR (raaltite) / dipentaerythritol 0.5 IV 1 1 V 1 2 10 0 100 — 装 — (Please read the precautions on the back before filling out this page) Order // / / / «Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5 9 i 12 3 / /

I— * Y

I1 Y This paper size is applicable to China National Standard (CNS) A4 specification (210 × 297 mm) 505676 A7 B7 V. Description of the invention (17) 20 11.7 · 20.1 15.7 25 21.9 48.0 25.2 1 4 Stereo hindered amine, by C iba- The stabilizer composition (IV 4 to IV 1 2) supplied by Geigy AG (HALS) of the present invention has an improved / stabilized activity. Table V: Equilibrium thermal test (1 90 ° C, rolling for 5 minutes at 170 TJ _ equipment-(Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Mixture Evipol SH 6030 V 1 V 2 V (PVC K value 60) 100 10 0 100 CH-3003 0. 8 0. 8 0. 8 Was E6 0. 4 0. 4 0. 4 Epoxy soybean oil 2.0 2. 0 2. 0 Rhodiastab 5 0 1 1 0. 2 0.2. 0. 2 Calcium stearate 0.3. 3 0.3 0. 3 Zinc stearate 0.5. 0. 5 0. 5 Wessalite P 1 5 / / / Zeolite P 1 β / / / stabilizer · 15 1. 0 -101- / / order · # This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) 505676 Α7 Β7 5. Description of the invention (M stable Agent 2 9/1. 0 / Stabilizer 3 1 ° / / 1. 0 YI YI YI minutes 2 0 10.3 12.3 15.4 25 19.6 34.7 28.6 30 4 1.1 29.5 58.8 Mixture V 4 V 5 V 6 Evipol SH 6030 (PVC L value 60) 10 0 100 100 CH-3003 Was Εβ Epoxidized soybean oil Rhodiastab 501 Calcium stearate Zinc stearate printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Wessalite P 1 5 Zeolite P 1 6 Stabilizer 15 Given agent Stabilizer 29 ^ 31

./ / YI

YI / / / / /

YI -102- (Please read the notes on the back before filling this page)

This paper size applies to China National Standard (CNS) A4 (210X29? Mm) 505676 A7 B7 V. Description of invention (printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2 0 8. 8 10.6 14.2 2 δ 12.4 16.8 19.5 30 2 1.0 32.5 30.5 Mixture V 7 V 8 V f Evipol SH 6030 (PVC K value 60) 100 100 100 CH-3003 0.8 0. 8 0. 8 Was E6 0. 4 0. 4 0. 4 Epoxy soybean oil 2.0 2. 0 2. 0 Rhodiastab 5 0 1 1 0. 2 0. 2 0. 2 calcium stearate 0. 3 0. 3 0. 3 zinc stearate 0.5 0.5 0. 5 Wessalite P 1 5 / / / zeolite P 1 6 1. 0 1. 0 1. 0 Stabilizer 15 1. 0 / / Stabilizer 2 9 / 1.0 / Stabilizer 3 1 〇 / / 1. 0 YI YI YI Minute 20 9. 3 9. 4 15.7 25 13.3 15.3 2 2.6 -103- 4 (Please read the notes on the back before filling this page)

、 1T # This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 505676 A7 B7 V. Description of the invention ^ b) 30 25.0 29.2 34.8 1 5 Na Zeolite A is provided by DEGUSSA 1 6 Na Zeolite P is The stabilizer composition containing hydrogenated talc and zeolite provided by DEGUSSA has better results I 丨 (Please read the precautions on the back before filling in this tile) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs VI: Equilibrium thermal test (190 °, rolling for 5 minutes at 17 ° C) Mixture V 1 V 2 V 3 V 4 Evipol SH 6030 (PVC K value 60) 100 10 0 10 0 10 0 Was Εβ 0.40 4 0. 4 0. 4 CH3003 0. 8 0. 8 0. 8 0. 8 Epoxy Soybean Oil 5. 0 5. 0 5. 0 5. 0 Calcium Stearate 0.5. 55 0. 55 0. 55 0 .55 Zinc stearate 0. 25 0. 25 0. 25 0. 25 Rhodiastab 501 1 / / 0. 3 0. 3 D- 2 6-1 5 5 1 7 / / / 0.3 stabilizer 15 / 1. 0 / / stabilizer 2 9 1. 0/1. 0 1. 0 " 10 4- order

This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention ((. () (YI YI YI YI minutes 20 18.5 9. 7 11.4 15.6 2 5 36.5 18.8 2 1.9 28.3 30 103 33.3 46.0 59.2 The following formula is / Ϊ 1 7 ketone cool Y y = (CHz) z -O-CO-CHz -CO-CH3 .4 (Please read the precautions on the back before filling this page) --- install -The result is that the composition containing / 3-difluorene or monoketone ester has better results. Table VII: Equilibrium heat test (190 ° C, rolling for 5 minutes at 170 ° C) Order Ministry of Economic Affairs Printed Mixture VIII VII 2 V by the Consumer Standards Cooperative of the Central Bureau of Standards: [13 E vip ο 1 SH 6 0 3 0 (PVC K value 60) 100 100 100 CH-3003 0. 8 0. 8 0.8 Was E6 0. 4 0 4 0. 4 Epoxidized soybean oil 5. 0 5. 0 5. 0 Calcium stearate 0.55 0.55 0.55 鉾 Stearate 0.25 0.25 0.25 -105- # This paper size applies to China National Standard (CNS) A4 specification (210X297 (Mm) 505676 A7 B7 ¾ 5. Description of the invention (Bull ·) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs S ynesa 1 Μ 1 8 / / / Stavinor D 5 0 7 1 9 / / Stabilizer 1 5 1. 0 / / Stabilizer 29 1 1. 0 / Stabilizer 3 1 〇 1 / 1. 0 minutes 0 YI 5 4 YI 4. 8 YI 6. 3 5 6. 4 4. 7 β 7 10 6. 7 5. 5 7. 0 15 7. 3 7. 8 8. 3 20 10.8 12.3 12.5 25 19.9 28.5 22.9 30 33.7 65.8 4 5.1 Mixture VII 4 VII 5 VII 6 E vi ρ 〇1 S Η 6 0 3 0 (PVC KK value 60) 100 100 100 CH-3003 0. 8 0. 8 0. 8 Was E6 0. 4 0. 4 0 4 Epoxidized soybean oil 5. 0 5.0 5. 0 Calcium stearate 0.55 0.55 0.55 Zinc stearate 0.25 0.25 0.25 -106- -4T (Please read the precautions on the back before filling this page) Order # This paper Standards are applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) 505676 A7 B7 4, V. Description of invention (p Printed by Synesa 1 M 1 8 S tavi η ο γ d 5 0 7 1 9 /! 0 (Stabilizer 15 1. 0/1. Stabilizer 2 9 / 1.0 Stabilizer 3 1 D / / min YI YI YI 0 2. 9 3. 9 1 · 3 5 3. 5 4. 1 1. 3 10 4. 4 5. 3 3. 5 15 5. 4 7. 5 5. 4 20 8 9 13.9 9. 3 25 18.0 27.2 17.5 30 3 1.8 64.2 32.3 Mixture Evipol SH 6030 VII 7 VII 8 (PVC L value 60) 100 100 CH-30Q3 0. 8 0. 8 Was E6 0. 4 0. 4 Epoxy Soybean oil 5. 0 5. 0 Calcium stearate 0.55 0.55 Zinc stearate 0.25 0.25 -107 (Please read the precautions on the back before filling this page) One pack ·

、 1T # This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 505676 A7 B7 V. Description of the invention (丨 ^) S ynesa 1 Μ 1 8 S tavi η or D 5 0 stabilizer 1 5 stabilizer 29 Stabilizer 3 1 2 3 ° minutes 0

/ YI ///

YI (Please read the notes on the back before filling out this page) One pack · 10 15 20 2 5 30 11.3 2 3.8 6 2.6 11.9 2 1.3 38.4 Ordered by the Central Consumers Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives 1 8 Thiodiethylene A bis (5-methoxy-carbonyl-2,6-di: methyl-1,4-dihydropyridine) -a 3-capric acid ester, provided by LAG 0 R 2 1 9 3 -bis Dodecyloxycarbonyl-2,6-dimethyl-1,4-dihydropyridine, provided by AT 0 C Η EM 3 Test results show that stabilizers containing dihydropyridine (VII 4 to VII 8) The composition has improved initial color and color durability (average color). -1 0 8-

Claims (1)

505676 6. Scope of Patent Application 1 * A stabilizer composition including: A) at least one compound of formula I: 〇 Among them, R to i and R to 2 are unrelated to each other Ci—Ci 2 complex, —Cs alkenyl, C5 — Cs ring gauge, which are unsubstituted, or from 1 to 3 涸 Ci—C4 alkyl , Ci—CU alkoxy, Cs-C3 cycloalkyl, or substituted by a hydroxyl group or by a chlorine atom, or C7-C9 phenylalkyl, which is unsubstituted, or from 1 to C 一 C4 alkyl, C C 4 alkoxy, C s-C 8 cycloalkyl or substituted with hydroxyl or chlorine atom, and R to i and 3 R to 2 may additionally be hydrogen, and Y is S or 0, and B) a compound of at least one of the following groups: B 1) an alkali metal perchlorate compound fluorene, B 2) a diepoxypropyl group of bisphenol A Ether and / or triglycidyl isocyanurate_, B3) acetamidine propionate calcium, or / 3-keto_ with the following formula, Π Y = (CH, V〇-CO-CHrCO-CH3, Y .Y one (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 505676 A8 B8 C8 D8 VI. Patent Application Scope (Please read the precautions on the back first Fill out this page again) B4) Thiodiethylene-bis (5-methoxy-carbonyl-2,6-dimethyl-1,4-dihydro-pyridine) -3-carboxylic acid ester and / or 3-didodecyloxycarbonyl-2,6-dimethyl-1,4-dihydropyridine, B 5) polyol, B 6) tetramiryl compound; B 7) Shishi A and / Or zeolite P, B 8) hydrotalcite, B 9) sodium carbonate. The 2 + 5B string stabilizer composition of item 1 in which R to i and R to each other are 来 and C Η a C 4 alkyl or C 一 a C 4 alkyl, respectively. 3 * As in the stabilizer composition of Examination Patent Fanyuan Item 1, wherein the compound A) is 6-amino-1,3-dimethyl-uracil, 6-junyl-1,3- Di-n-propyl-urine_shoes, 6-junyl-1, 3-di-n-butyl-uracil, 6-amino-1, 3-diethyl-a-uracil® or 6 —Junji-1,3-di-n-butyl-one hinders the generation of uracil. 4 * If the stability of the item 1, 2 or 3 of the series of patents is referred to as the composition, the paper size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 505676 A8 B8 C8 D8 It additionally contains at least one epoxy fatty acid. (Please read the notes on the back before filling out this page) 5 'If the stability of item 1, 2, or 3 of the patent range is combined, it also includes zinc and / or alkali metals and / or alkaline earth metals. Carboxylic salt or Aluminium alloy & 6 * If Φ please apply the stabilizer composition in the scope of the patent, it also contains zinc and / or alkali metal and / or alkaline earth metal carboxylate or aluminum gallate 7 ♦ If you read the stabilizer composition of item 1, 2 or 3 of the patent model, it also contains at least one other compound selected from sulfite, anti-oxidation, /? Dicarbonyl compound, plastic filler, Guidance and quality of pigments. 8 * As described in item 5 of the patent scope, it is a combination of 锪, which additionally-contains at least one other selected from the group consisting of phosphorous acid, antioxidants, 3-dicarbonyl compounds, plasticizers, guides and pigment substance. 9. The stabilizer composition according to item 6 of the patent, which further comprises at least one other selected from the group consisting of phosphites, antioxidants, / 3-dicarbonyl compounds, plasticizer fillers, fillers and pigments. substance. 1 0 ♦ As the surface stabilizer composition of the 7th in the scope of the patent, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 505676 098892 ABCD 6. The scope of the patent application The filler is chalk . 1 1 * If you apply for the patented noodle combination No. 7 of the patent fan garden, the guide is called calcium stearate. 2 1 2 * For example, the stable tobacco composition of item 7 of the patent, wherein the titanium dioxide is used as a Yankee. 1 3 ♦ Please ask for the stable smoke of item 1 of the patent scope! Combination 锪, including ingredients A and B 1. 1 4 * Please refer to the stabilizer composition of Patent Fanyuan Item 1, including ingredients A and B 2. 1 5 ♦ Stable composition as described in item 1 of the patent scope, including makeup A and B 3. 1 6 * Such as the composition of item 1 in the patent patent garden, including ingredients A and B 4 ϋ i 7, such as the composition of the stabilizer item 1 in the patent scope, including components A and B 5. This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before filling out this page) 0 、 \ έ 505676 A8 B8 C8 D8 VI. Patent application scope 1 8 ♦ If The stabilizer composition of item 1 of the patent scope includes (Please read the notes on the back before writing this page) Ingredients A and B 7. 1 9 * As described in item 1 of the patent scope, the stable surface composition includes ingredients A and B 8. 20. A composition comprising a chlorine-containing polymer and a stabilizer composition as claimed in any one of the patent claims 1 to 19. 2 i + is the composition of item 20 of the patent patent, where the chlorine-containing polymerization polymer is P V C. 2 2 ♦ A method for stabilizing a chlorinated polymer, comprising incorporating into the chlorinated polymer a stabilizer composition as described in any one of the items 1 to 19 of the patent specification. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)