發』Οί AM__ 本發明傺關於鍰衝氣袋用氣驩發生劑組成物。詳言之 ，其像有鼸於提供一種在搭乘汽車等交通工具用於保護 人髏所需之氣袋套筒有鼸之形成操動氣體之低殘渣緩衝 氣袋用氣體發生劑組成物。 H抟術 現況，緩衝氣袋套筒一般所用發生氣體基劑，刖包括 有無機叠氮条化合物，待別是叠氮化納。此種含有無機 疊氮条化合物之組成物有鼸於其燃燒待性則無特別之問 題，現況已提供為廣泛實用。惟叠氮化納則在本質上具 有各種不適之特性。例如，偽一種毒性很高之物質，同 時疊氤化鈉容易和銅，鉛等重金鼷反應，而生成容易引 起突然發火式爆炸極具敏感之化合物，因此，製造，貯 轅及廢棄此種組成物時有必要做特別之處置。 經濟部中央榡準局負工消費合作社印製 玆為補拙此等缺點，而提案以非叠氮条氣膿發生_代 替#氮化鈉。例如，特開平3-208878號公報掲示以四唑 ，三唑或其金鼷鹽與鹸金鼷硝酸鹽等含氣之氣化劑為主 要成分之組成物。此種組成物比較叠氮条組成物，雖然 顯著減少毒性面，但在排氣生成物中尚形成有許多固膿 及液體粒子，故其氣髏産生效率並不很高。 又在tfO 95/ 047 1 0號之説明書中掲示含有相安定化硝 銨（PSAN)與之胺基胍硝酸鹽等含氮化合物之氣體發生劑 。又在USP 5,545,272號說明書與W0 96/ 27574號說明書 掲示以7〜20重量％鉀鹽形成相位安定化硝銨輿含有硝基 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 495496 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（> ) 胍混合物之氣醱發生劑。此種組成物，有可能以高水準 提升在燃燒時之氣醱發生率。但因發熱量相當大，其計 量理綸上之燃燒溫度超過2500K以上，因此發生高濃度 之C0輿ΗΟχ氣髏。 含氤化合物在通常之燃燒常中，由於僅使用化學當量 分，即化合物分子之磺、氫、其他元素在燃燒所必須發 生之氣氣量之氣化劑，故比較II氮条化合物有發熱董大 ，燃燒溫度高之缺點。如燃燒溫度過高時•刖有發生逮 超出對人體容許值之超量C0與ΝΟχ氣體之庚。又在氣體 發生劑組成物大量使用金《化合物（例如金屬氣化物等） 時，則所生成之固體及液體之粒子從氣龌發生器逸出， 直接碰觸袋體而有導致袋髏破裂之虞。如欲在氣髏發生 器中遮斷此種粒子卽有附設零件之必要，如此很難使氣 體發生器本身獲得小型化。即，氣體發生剛在燃燒時， 如具有燃燒溫度低，所發生之氣體量大，所生成固髏及 液體之粒子量小特性時則認為最具優越。因此，如上述 之習知氣體發生劑組成物尚不能滿足氣袋套筒之應用。 本發明者等旨在於解決上述問題經由反覆潛心研究結 果，遽而完成本發明。 亦即，本發明偽提供含有由相安定化硝銨（PSAN)混合 物所生成之氣化劑與含有硝基胍為必要成分，組成物中 之硝基胍含量在35重量％以下為特擻，藉由燃燒而發生 大量氣體，可做為汽車等交通工具之衝擊吸收安全袋使 — 4. — 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 495496 A7 B7 五、發明説明（；） 用適合於多項目的使氣袋膨脹所需之一種低殘渣緩衝氣 袋用氣體發生劑組成物者。 本發明之氣體發生劑組成物比較既有已掲示之氣體發 生酬組成物，非但減少殘渣之生成量，而且因使用本發 明之氣體發生劑組成物，可大幅減少去除殘渣所需附屬 零件之件數及數量，而得以開創出小型化氣體發生器之 途徑。 II 之一窟— 本發明之氣體發生劑組成物，在燃燒硝銨之際不會生 成固體殘渣，全部變成非腐蝕性氣體，利用所諝不發生 如氣，鹽酸一般之腐蝕性氣髏之特徽，極力抑止生成固 髏殘渣，比較既有之氣體發生器有可能大幅減少附颶零 件之件數與數量。 本發明即在於將組成物中之硝基胍含量設在35重量％ 以下，最好為5〜33重量％ ,比既有之組成可將燃燒溫度 降低約1 5 0〜3 0 0 Κ ,並可降低某程度之發熱量。降 低燃燒溫度則有利於減低有毒之C0與HO X氣體。又低燃 燒溫度及發熱量對於減少氣體發生器之附鼷零件亦有利。 關於混配35重量％以下硝基胍之本發明組成物與既有 之組成物，其燃燒溫度與發熱量的理論計算結果即如表 1所示。 又，在表1中，PSAHKP 10傺表示由90重量％硝銨與10 重量％過氣酸鉀所形成之相安定化硝銨，NQ則表示硝基 胍。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） (請先閲讀背面之注意事項再填寫本頁)发 』Οί AM__ The present invention relates to a gas generator generating composition for an airbag. In detail, it seems to provide a low-residue buffer gas-generating agent composition for an airbag, which has an airbag sleeve which is required for protecting a human skull when traveling by a vehicle or the like. H-Surgery At present, gas-based agents commonly used in cushioning airbag sleeves include inorganic azide strip compounds, to be other than sodium azide. Such a composition containing an inorganic azide compound has no particular problem in terms of its burnability, and the present condition has been provided for widespread practical use. However, sodium azide has various unpleasant properties in nature. For example, a highly toxic substance is pseudo, and at the same time, sodium sulfide is easily reacted with heavy metals such as copper and lead to form a highly sensitive compound that is likely to cause a sudden pyrophoric explosion. Therefore, such a composition is manufactured, stored, and discarded It is necessary to take special measures. Printed by the Central Labor Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives to compensate for these shortcomings, and the proposal is to use non-azide gas purulent _ instead of # sodium nitride. For example, Japanese Patent Application Laid-Open No. 3-208878 discloses a composition containing a gaseous gasifying agent such as tetrazolium, triazole or its gold osmium salt and osmium osmium nitrate as a main component. Compared with the azide strip composition, this composition significantly reduces the toxic side, but there are still many pus and liquid particles formed in the exhaust gas, so its gas skull production efficiency is not very high. In the specification of tfO 95/047 1 0, a gas generating agent containing phase-stabilizing ammonium nitrate (PSAN) and aminoguanidine nitrate and other nitrogen-containing compounds is shown. In USP No. 5,545,272 and WO 96/27574, it is stated that the phase is stabilized with 7-20% by weight potassium salt, and ammonium nitrate is contained. The paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). 495496 Economy Printed by A7 B7, Consumer Cooperatives of the Ministry of Standards, Ministry of Standards 5. Description of the Invention (>) An airborne generator of guanidine mixture. Such a composition may increase the incidence of gassing during combustion at a high level. However, because the calorific value is quite large, the measured combustion temperature on Polyester exceeds 2500K, so a high concentration of C0 gas is generated. Thorium-containing compounds are generally used in ordinary combustion, because only the chemical equivalents, that is, the sulfonate, hydrogen, and other elements of the gas molecules must be generated in the combustion of the gasification agent, so the comparison of II nitrogen compounds has a fever The disadvantage of high combustion temperature. If the combustion temperature is too high, there will be arrests. Excessive amounts of C0 and Νχχ gas that exceed the allowable value for the human body. When the gas generating agent composition uses a large amount of gold compounds (such as metal vapors, etc.), the solid and liquid particles generated escape from the gas generator and directly touch the bag body, which may cause the bag skull to rupture. Yu. If it is necessary to block such particles in the gas skull generator, it is necessary to attach parts, so it is difficult to miniaturize the gas generator itself. That is, it is considered to be the most superior when the gas generation is just after combustion, if the combustion temperature is low, the amount of gas generated is large, and the amount of particles generated by the solid skeleton and liquid is small. Therefore, the conventional gas generating agent composition as described above cannot satisfy the application of the airbag sleeve. The inventors of the present invention aim to solve the above-mentioned problems through repeated intensive research results to complete the present invention. That is, the present invention pseudo-provides that it contains a gasification agent generated from a phase-stabilized ammonium nitrate (PSAN) mixture and contains nitroguanidine as an essential component, and the content of nitroguanidine in the composition is 35% by weight or less. A large amount of gas is generated by combustion, which can be used as a shock absorbing safety bag for vehicles such as automobiles. — 4. — This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) (please read the note on the back first) Please fill in this page again.) Order printed by the Ministry of Economic Affairs, Central Standards Bureau, Consumer Cooperatives. 495496 A7 B7 V. Description of the invention (;) Use a low-residue buffer airbag gas generating agent suitable for multi-project expansion of airbags Composer. The gas generating agent composition of the present invention is compared with the existing gas generating composition, which not only reduces the amount of residue generated, but also uses the gas generating agent composition of the present invention, which can greatly reduce the number of auxiliary parts required to remove the residue. Number and quantity, which can create a way to miniaturize the gas generator. Cave No. II — The gas generating agent composition of the present invention does not generate solid residues during the combustion of ammonium nitrate, and all become non-corrosive gases. Emblem, trying to suppress the formation of solid skull residues. Compared with existing gas generators, it is possible to significantly reduce the number and number of parts with hurricanes. In the present invention, the content of nitroguanidine in the composition is set to less than 35% by weight, preferably 5 to 33% by weight. Compared with the existing composition, the combustion temperature can be reduced by about 150 to 300 κ, and Can reduce the amount of heat. Lowering the combustion temperature will help reduce the toxic C0 and HO X gases. The low combustion temperature and heat generation are also beneficial to reduce the attached parts of the gas generator. Table 1 shows the theoretical calculation results of the combustion temperature and calorific value of the composition of the present invention and the existing composition in which the nitroguanidine is blended in an amount of 35% by weight or less. In Table 1, PSAHKP 10 傺 indicates a phase formed by 90% by weight of ammonium nitrate and 10% by weight of potassium peroxyacid, and NQ indicates nitroguanidine. This paper size applies Chinese National Standard (CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page)
495496 A7495496 A7
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本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 495496 A7 B7 五、發明説明（Γ ) 純粹硝銨如通過32tJ時則有隨伴約3%體積變化之相 轉移發生。大成型體之體積變化，即有引起發生異常燃 燒之虞，不適於做為氣體發生劑。因此，本發明像使用 相安定化硝銨。 本發明所用之相安定化硝銨，最好為硝銨98〜70重量% 與相安定化劑2〜30重量％之混合物，例如，將鉀陽離子 導入於硝銨之結晶拉子，使硝銨的相予以安定乃為一般 所習知〇本發明即宜使用選自熱水溶性之有機或無機鉀 鹽群之至少1種做為相安定化劑。在相安定化硝銨中如 混配以2重量％以上相安定化劑時即可防止硝銨之相轉 移。但是如果相安定化劑之混配量過多時則對於以減低 固體殘渣為目的者不利，故最好相安定化硝銨中之相安 定化劑的混配量為2〜30重量％。 就本發明而言，做為相安定化劑使用之熱水溶性之有 機或無機鉀鹽，即包括選自硝酸鉀，過氣酸鉀，硫酸鉀 ,氣化鉀，氣酸鉀，鉻酸鉀，重鉻酸鉀，過錳酸鉀以及 草酸鈣群之至少1種。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 本發明之氣體發生劑組成物，雖包含由相安定化硝銨 混合物所形成之氣化劑，但本發明之氣化劑，除相安定 化硝銨以外，最好混配以含氣之氣化劑化合物，金鼷氣 化物或彼等之混合物。 本發明所使用含氣之氧化劑化合物，像包括由選自硝 酸、過氛酸或氣酸之鹸金羼鹽，鹸土類金羼鹽或銨鹽群之 至少1種，具體上則包括有過氛酸鉀，過氛酸銨，氣酸 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 495496 A7 B7 五、發明説明（合） 鉀，硝酸鉀，硝酸鈉，硝酸緦等。 本發明所用金颺氣化物僳包括由鋦，鈷，鐵，錳，鎳 ，鉻，鋅，鉬或鉍群所選取之金颶氣化物或複氯化物。 本發明組成物中之相安定化硝銨的混配量最好為60〜 85重量％。又，本發明組成物中之含氣化劑化合物，金 鼷氣化物或為彼等混合物之混配量最好為0〜25重量％。 本發明之紐成物，因霈促進燃燒速度最好混配有燃燒 速度促進觸媒。本發明所用之燃燒促進觸媒，包括由蘧 自鋦粉末，銅之化合物，鐵之化合物，鎳之化合物以及 鉻之化合物群所之至少1種。本發明所用之銅化合物， 有氣化銅，亞鉻酸銅等，鐵的化合物有，氧化鐵，雙（ 璟戊二嫌基）鐵（ferrocene)及其衍生物等，鎳之化合物 則有氣化鎳等，鉻之化合物則包括有，氣化鉻，重鉻酸 銨，重鉻酸鉀等。本發明組成物中之燃燒速度促進觸媒 之混合量最好在10重量％以下。 經濟部中央標隼局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 關於本發明，由於混配有如上述含氧之氧化劑化合物 或金鼷氣化物或燃燒速度促進觸媒，故可將組成物之燃 燒速度從廣闊之範圍作適當之選擇。並可適宜選擇此等 氯化劑或觸媒以形狀，粒度等。 本發明之氣體發生_組成物，欲保持成型鼷之形成而 含有20重量％以下之有機或無機結合劑。並由添加相關 之有機或無機結合劑而可從粉末狀混合物成形為成型體 。對於結合劑之種類，並無持別之限制在不損及氣髏發 生劑之性能範圍内，可使用一般之有機或無機之結合劑 -8 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 哪496 A7 -B7 —一 --------- 五、發明説明（？） 。有機或無機之結合劑，其具體例包括有羧甲基纖維素 之納鹽，醋酸纖維素，鎩粉，聚乙烯醇，聚丙烯酸鈉等 之有機結合劑，矽酸鈉，皂土，玻璃鐵維，矽酮橡膠等 無機結合劑。結合劑的使用量，過多時由於會損及氣體 發生劑的性能，故最好在20重量％以下，又，氣龌發生 劑因而燃燒時成型體的幾何構造本質上其燃燒舉動會受 到影嚮，蓋此乃為眾所習知，惟本發明之氣體發生劑組 成物由其所選擇之組成，將其成型為最適當之幾何構造 卽可，因此並無特別加以限制。This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 495496 A7 B7 V. Description of the invention (Γ) When pure ammonium nitrate passes 32tJ, phase transfer occurs with a volume change of about 3%. The volume change of a large molded body may cause abnormal combustion and is not suitable as a gas generating agent. Therefore, the present invention is like using phase stabilization ammonium nitrate. The phase-stabilizing ammonium nitrate used in the present invention is preferably a mixture of 98-70% by weight of ammonium nitrate and 2-30% by weight of the phase-stabilizing agent. The phase stabilization is generally known. In the present invention, it is appropriate to use at least one selected from the group of thermally water-soluble organic or inorganic potassium salts as a phase stabilizer. When phase stabilizers are blended with 2% by weight or more of a phase stabilizer, phase shift of ammonium nitrate can be prevented. However, if the compounding amount of the phase stabilizer is too large, it is disadvantageous for the purpose of reducing solid residues. Therefore, the compounding amount of the phase stabilizer in the phase stabilizer ammonium nitrate is preferably 2 to 30% by weight. For the purpose of the present invention, a thermally water-soluble organic or inorganic potassium salt used as a phase stabilizer, including a compound selected from potassium nitrate, potassium peroxyacid, potassium sulfate, potassium gasification, potassium gasate, potassium chromate , At least one of potassium dichromate, potassium permanganate, and calcium oxalate. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The gas generating agent composition of the present invention, although it contains the gasification agent formed by phase stabilization of ammonium nitrate mixture, but this The gasifier of the present invention is preferably compounded with a gasifier containing gas, a gold tincture or a mixture thereof in addition to the phase-stabilized ammonium nitrate. The gas-containing oxidant compounds used in the present invention include, for example, at least one selected from the group consisting of osmium salts, nitrates, ammonium salts, or ammonium salts of nitric acid, peroxy acids, or gas acids, and specifically includes Potassium sulphate, ammonium persulphate, sulphuric acid This paper is sized according to the Chinese National Standard (CNS) A4 (210X 297 mm) 495496 A7 B7 V. Description of the invention (combination) Potassium, potassium nitrate, sodium nitrate, thorium nitrate . Gold rhenium rhenium used in the present invention includes gold hurricane or double chloride selected from the group consisting of rhenium, cobalt, iron, manganese, nickel, chromium, zinc, molybdenum, or bismuth. The compounding amount of the phase-stabilized ammonium nitrate in the composition of the present invention is preferably 60 to 85% by weight. In addition, the compounding amount of the gasifying agent-containing compound, gold dysprosium gas or their mixture in the composition of the present invention is preferably 0 to 25% by weight. It is preferred that the button product of the present invention be mixed with a burning rate promoting catalyst because of its promotion of burning rate. The combustion-promoting catalyst used in the present invention includes at least one selected from the group consisting of rhenium powder, copper compounds, iron compounds, nickel compounds, and chromium compounds. The copper compounds used in the present invention include gasified copper, copper chromite and the like, iron compounds, iron oxide, bis (pentapentyl) iron (ferrocene) and derivatives thereof, etc., and nickel compounds have gas. Nickel and the like, chromium compounds include, gasified chromium, ammonium dichromate, potassium dichromate and the like. The blending amount of the burning rate promoting catalyst in the composition of the present invention is preferably 10% by weight or less. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page). Regarding the present invention, since it is mixed with the oxygen-containing oxidant compound or gold radon gaseous substance or the burning speed promotion catalyst Therefore, the burning speed of the composition can be appropriately selected from a wide range. These chlorinating agents or catalysts can be appropriately selected in terms of shape, particle size, and the like. The gas generating composition of the present invention contains an organic or inorganic binder in an amount of 20% by weight or less in order to maintain the formation of a molded plutonium. By adding related organic or inorganic binders, it can be formed into a compact from a powdery mixture. As for the type of the binding agent, there is no specific limitation on the range that does not impair the performance of the gas-skull generating agent. Ordinary organic or inorganic binding agents can be used. 8-This paper size applies to Chinese National Standard (CNS) A4 specifications. (210X 297mm) Which 496 A7 -B7 — a --------- 5. Description of the invention (?). Organic or inorganic binders, specific examples of which include sodium salts of carboxymethyl cellulose, cellulose acetate, powder, polyvinyl alcohol, sodium polyacrylate, and other organic binders, sodium silicate, bentonite, glass iron Vitamin, silicone rubber and other inorganic binders. When the amount of the binder is too much, the performance of the gas generating agent will be impaired, so it is preferably less than 20% by weight. In addition, the geometric structure of the molded body when the gas generating agent is burned will essentially affect the burning behavior of the molded body. It is well known that the gas generating agent composition of the present invention is composed of the composition of its choice, and it is acceptable to mold it into the most appropriate geometric structure, so it is not particularly limited.
竄复I 玆列舉實施例及比較例具髏說明本發明如下，惟本發 明並不受此等實施例之限制。 又，例如中之％如無特別表明均僳以重量為基準。 合成例1 (相安定化硝銨之製造） 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 將硝銨（AN)90%與過氛酸鉀（KCl〇4 )1〇%之混合物溶 解於相當份量之蒸餾水，經由攪拌所得之溶液放入於約 85它之熱乾燥器（以減壓者為佳），使水分蒸發。大部分 之水蒸發後，所生成之固形分薄面分佈在不綉鋼盤，以 約85¾充分使之乾燥。收集乾燥物，經由乳缽粉碎使之 能通過300 /im篩網。以TG-DTA檢测生成物之熱變化巔值 與硝銨含量，藉以確認是否生成為相安定化硝銨（PSAN) 或是否形成為均勻狀態。將依此所獲得之相安定化硝銨 (以下略稱為 PSAHKP 10, AN/KC104 (重量比）=90/10) 以TG-DTA分析結果，一般在硝銨含有物之DTA有待徽之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 495496 y A7 B7The present invention is described below with examples and comparative examples, but the present invention is not limited by these examples. In addition, for example, the percentages in% are based on weight unless otherwise specified. Synthesis Example 1 (Production of Phase Stabilization Ammonium Nitrate) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (Please read the precautions on the back before filling this page). Ammonium nitrate (AN) 90% and potassium peroxyacid (KCl 〇 4) 10% of the mixture is dissolved in a considerable amount of distilled water, and the solution obtained by stirring is placed in a thermal dryer (about 85 decompression is preferred) to evaporate the water. After most of the water evaporates, the resulting solid-shaped thin surface is distributed on the stainless steel plate, and it is fully dried with about 85¾. The dried material was collected and pulverized through a mortar to allow it to pass through a 300 / im sieve. TG-DTA was used to detect the peak thermal change of the product and the ammonium nitrate content, so as to confirm whether it was formed as phase-stabilized ammonium nitrate (PSAN) or whether it was formed into a uniform state. The phase stabilized ammonium nitrate obtained from this (hereinafter abbreviated as PSAHKP 10, AN / KC104 (weight ratio) = 90/10) is analyzed by TG-DTA. Generally, the DTA of ammonium nitrate-containing substances has to be identified. Paper size applies to China National Standard (CNS) A4 specification (210X297 mm) 495496 y A7 B7
L 修正捕乞 五、發明説明（/ ) 約5310之巔值變無，而在113υ之位置呈現新的顛值。 經TG分析結果，硝銨之含量為90%。 實施例1 將由合成例 1 所獲得 PSANKP 10(AN/KCl〇4 =90/10) 70%與硝基胍30%混配成之組成物粉末以乾式法充分 混合，以油壓筒將粉末在lOOkg/cn2之壓力下，壓縮成 型為高度約12.7mm,直徑約10mm之線股。此線股則以不 燃性璟氣条樹脂加以被覆。在70kg/cm 2之氮氣壓下進 行測定燃燒速度，此線股顯示有7.61BB1/S之燃燒速度。 I比組成物之理論燃燒溫度為2158K,而理論殘渣量（100 克組成物所生成之金屬化合物量）為3.8克。 實施例2 將由合成例1所得PSANKP 10 69.5%,硝基胍30%以 及氣化銅0.5%混配成之組成物以乾式法充分混合，仿 實施例1相同方法作成線股。此線股在70kg/cra2之氮 氣壓下所測定之燃燒速度為n.5niii/s。此組成物之理 論燃燒溫度為2151K,理論殘渣量為4.1克。 實施例3 將PSANKP 1 0 64%,硝基胍30%,羧甲基纖維素之鈉 鹽5.0 %以及氧化銅1.0%混合而成之組成物以乾式法充分 加以混合，仿實施例1相同方法作成線股。此線股在70 kg/c®2之氮氣壓下所測定之燃燒速度為11·3·πι/ε〇此 組成物之理論燃燒溫度為2435 K,理論殘渣量為4.8克。 - 10- 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨OX29?公釐） (請先閱讀背面之注意事項再填. 寫本頁) 經濟部中央標準局員工消費合作社印^L modified catching begging 5. Description of the invention (/) The peak value of about 5310 has disappeared, and the new value appears at 113υ. According to TG analysis, the content of ammonium nitrate was 90%. Example 1 A composition powder obtained by mixing 70% of PSANKP 10 (AN / KClO4 = 90/10) obtained in Synthesis Example 1 with 30% of nitroguanidine was thoroughly mixed by a dry method, and the powder was mixed with an oil pressure cylinder in Under a pressure of 100 kg / cn2, it is compression-molded into a strand having a height of about 12.7 mm and a diameter of about 10 mm. This strand is covered with non-combustible radon resin. The burning rate was measured under a nitrogen pressure of 70 kg / cm 2, and this strand showed a burning rate of 7.61 BB1 / S. The theoretical combustion temperature of the I ratio composition is 2158 K, and the theoretical residue amount (the amount of the metal compound produced by the 100 g composition) is 3.8 g. Example 2 A composition composed of 69.5% of PSANKP 10 obtained in Synthesis Example 1, 30% of nitroguanidine, and 0.5% of vaporized copper was thoroughly mixed by a dry method, and a strand was prepared in the same manner as in Example 1. The burning speed of this strand under nitrogen pressure of 70kg / cra2 is n.5niii / s. The theoretical burning temperature of this composition is 2151K, and the theoretical residue is 4.1 grams. Example 3 A composition obtained by mixing PSANKP 1 64%, nitroguanidine 30%, sodium salt of carboxymethyl cellulose 5.0%, and copper oxide 1.0% was thoroughly mixed by a dry method, the same method as in Example 1 Made into strands. The burning rate of this strand under a nitrogen pressure of 70 kg / c®2 was 11.3 · πm / ε. The theoretical burning temperature of this composition was 2435 K, and the theoretical amount of residue was 4.8 g. -10- This paper size is in accordance with Chinese National Standard (CNS) A4 (2 丨 OX29? Mm) (Please read the notes on the back before filling in. Write this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^