494088 A7 B7 五、發明說明（1) 發明之背景 1 .發明之領域 本發明提供一個相關於 法。此處理方法是利用天 ，特別是澱粉衍生物中的 分解廢污水中的有害化學 2,先前技術之描逑 經濟部智慧財產局員工消費合作社印製 許多 和廢污 因難。 燒或固 聚苯或 ，如多 處理。 利用 很多， 廢污水 有害性 事質上 中，將 水中的 另外 其他相 ，例如 產業製造或 泥混合物。 環保處理業 化的方式加 聚酚類的化 氯聯苯的燃 微生物如細 如水肥的分 中含苯類、 見諸於各種 是消毒劑或 會造成徼生 有害物質。 廢污水中可 似的重金屬 電路板的清 應用過 這些廢 者通常 以處理 學物質 燒即是 菌，輦 解處理 酚類、 文獻， 殺菌劑 物的喪 能含有 物質。 洗污水 廢污水和廢污泥混合物的處理方 然微合物的混合液和澱粉衍生物 聯櫬環（Cyclodextrins )來處理和 物質及重金屬。 程中，產生許多甚難處理的污水 水有重金屬離子，造成處理上的 必須用昂貴的處理方式如高溫燃 ，K符合當地的環保要求。一些 ，在燃燒過程中可能產生戴奥辛 一例，需要更進一步的空氣污染 藻來分解碳氫化合物的商業實例 和食品業的發酵處理等。但許多 酯類等化合物，對人體或動物的 而這些苯類或酚類的化學物質， 的基本原料，直接加徼生物於其 失功能及死亡，而無法分解廢污 重金屬離子如鋅、銅、錫、鉛等 這些金屬離子本身亦具殺菌作用 ，含苯酚類和重金屬結合的化合 ----：---------------"^訂 L-------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 4 經濟部智慧財產局員工消費合作社印製 494088 A7 B7_ 五、發明說明（2 ) 物，由於化學結構複雜，難Μ用燃燒方式處理。 澱粉衍生物的聯糊環，又可稱之為環糊精，在食品工業 用途可有果汁保鮮處理（美國專利第4, 975, 293號），香水 工業利用聯糊環來避免香料揮發，在食品工業利用聯画環 來從事薄荷糖的製造Κ減少薄荷的揮發，這些聯糊環的應 用方式皆強調利用聯糊環來含蓋或黏合所需要的化學物質 ，但没有利用聯糊環做為微生物吸收消化的應用，在廢污 水和廢污泥混合物的處理方式上，除了高溫燃燒和固化處 理外，仍需要有其他經濟、容易使用且有效的處理方法。 3 .發明之概述 本發明的突破是利用天然微生物混合液配合澱粉衍生物 中的聯糊環（Cyclodextrins )來合力處理廢污水中的有害化 學物質。本發明的處理方法是強調其經濟、容易使用、及 其有效性。 本發明的目的是提供一項作業方式，來分解含有清潔劑 或殺菌作用的化學廢水。同時，本發明的目的是在原先微 生物無法生存的廢污水中，分解廢水中的有害化學物質成 為有機肥料。 一些濃度較高的化學廢水，若只光使微生物來從事分解 作業前，必須把廢水稀釋百倍或千倍，所Μ其中所含的化 學成分才有可能自然分解。本發明的目的是減少此稀釋的 需要，Κ提高作業的經濟效益。 本發明的另一個目的是標示廢水中的特殊化學物質如多 氯聯苯，多鼢類的化學分子，使其容易被有效地分解，以 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ----:---------------P 訂」-------線^^ (請先閱讀背面之注意事項再填寫本頁) 494088 A7 B7_ 五、發明說明（3 ) 達到環保廢水排放的要求。 (請先閱讀背面之注意事項再填寫本頁) 另外，本發明的目的是氧化廢水中的重金屬離子，使重 金屬離子能達到類似高溫燃燒的氧化效果，且分解原先和 重金屬離子結合的苯酚化學物質。 4.圖式之簡單說明 圖1所示分別為α -，召-，7-聯糊環（Cyclodextrin )的 構造式。 5 .發明之詳细說明 本發明人經過深入的研究發琨，利用天然微生物混合疲 配合澱粉衍生物中的聯糊環可K有效地處理廢污水和/或 廢污泥中的有害化學物質。本發明的處理方法具有經濟、 容易使用、有效的特點。本發明正是基於上述發現而完成 的。 本發明提供一種處理廢污水或廢污泥混合物的方法，該 廢污水或廢污泥混合物中可含有苯酚類化學物質或金屬離 子，或苯酚金屬化合物；其包括下列步驟： 經濟部智慧財產局員工消費合作社印製 (a )加入適量的聯糊環，並經過適度的混合攪拌和需要 的混合時間； (b )再加入適當的微生物，經過需要的反應時間，Μ分 解該苯酚化學物質或氧化該金屬物質。 根據本發明，所用的聯糊環可Μ為α -，/3 -，7 -聯糊 環及其混合物，較佳使用点-聯糊環。但根據待處理的化 學物質本身尺寸的大小，可Μ使用較大或較小尺寸的聯櫬 環。這些聯_環例如可Μ從C e r e s t a r ϋ S A , I n c ,購得。 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） p 494088 A7 B7_ 五、發明說明（4 ) (請先閱讀背面之注意事項再填寫本頁) 聯糊環是澱粉鐽分子的結合體。常見的聯觀環是利用酵 素結合6個、7個或8個葡萄糖分子而成的環狀結構，一般 亦俗稱α -、点-、7 -聯糊環，分子結構圖列於圖1。聯觀 環本身結構穩定，並可抗酸鹼，其中空的環狀結構，使聯 糊環在應用上產生特殊的物理和化學性質。 聯糊環的加入量可Μ根據廢水中待處理的有害物質的量 而定。通常，聯糊環的量是有害物質量的1-1 5倍，較佳 2 - 1 0倍，更佳3 - 7倍，如5倍。例如，污水含有2 0 ρ ρ m的苯 類物質，則在污水中加入100 ΡΡΙΗ的聯糊環。較佳，聯糊環 的量比有害物質的量過量，Κ增加聯糊環和有害物質如苯 類的黏合機會。根據廢水處理的實際要求，例如根據一定 的廢水排放標準，也可使用比有害物質量少的聯觀環。 將聯糊環加入待處理的廢污水或油污泥水中，加Μ適度 不斷地攪拌。攪拌的方式可由機槭攪拌機來攪拌，或利用 循環幫浦保持廢污流體的來回循環。攪拌的速度並不需要 非常嚴格，只要能讓聯糊環有機會與有害物質如苯酚類物 質黏合。攪拌可Κ是連續性或間斷性的，但不需要特別的 經濟部智慧財產局員工消費合作社印製 快速攪拌。聯糊環有機會借由流體的流動和待處理液中的 苯酚化學分子，長鐽碳氫化合物，苯酚金屬化合物等接觸 。當聯糊環和這些化學分子相接觸時，經由分子間的相互 吸引力，將會產生黏合作用。由於聯糊環的中空結構尺寸 大小適合苯酚類分子的結構大小，有甚高的機率，這些化 學分子被套於聯糊環的中空結構中。當這些化學分子被外 圍的聯環分子包圍時，原先苯鼢類的化學性質亦無從顯 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） n 494088 A7 B7_ 五、發明說明（5 ) (請先閱讀背面之注咅心事項再填寫本頁) 現於廢水中，整個黏合的分子成為中性穩定物質。經過聯 糊環的作用標示廢水中的特殊化學物質如多氯聯苯，多酚 類的化學分子，從而使其容易被有效地分解。 對於一些聚苯類的長鐽分子，由於分子本身结構較大， 無法套在聯糊環中。但由於分子間的相互吸引力，可能有 兩個或更多的聯糊環附著於長鐽分子上。數個聯糊環附著 於長鐽聚苯分子可有許多不同幾何空間組合，依聯糊環所 著於長鏈聚苯分子組合空間的排列而定，長鏈聚苯分子可 能會或不會顯現其原來的化學性質。至於廢水中含的重金 屬，特別是苯鼢類金屬化合物*亦經由聯糊環的附著能力 ，附著於聯糊環的內部或外面側部，Μ整個巨觀統計的觀 點來看，整個液體中的有害化學性質經由聯糊環的作用而 減少甚多，而且聯糊環在流體中有標示作用，該微生物容 易找尋要分解處理的目標。也就是說，聯糊環可安定廢污 水中的有害化學物質，並具有標示作用，可改變原先徼生 物無法生存或繁殖的廢污水生態環境。 經濟部智慧財產局員工消費合作社印製 聯糊環與廢水的攪拌混合的時間也不是非常嚴格，這和 攪拌的速度、污水量、加入的聯_環的量等有關，只要聯 糊環與待處理的物質能基本上黏合即可。例如，對於500 或1 000毫升的實驗室量杯，攪拌2-1 5分鐘如5_ 10分鐘即可 ，而對於大型作業，攪拌時間會拉長，如15-30分鐘，或 更長如45-60分鐘。 上述步驟（a)的反應溫度可Κ是通常進行廢水處理的溫 度，如在廢水環境溫度下，例如0-85°C，較佳5-7(TC，更 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 。 494088 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（6 佳 10 - 6 0〇C 0 經過聯糊環適當混合攪拌的廢水，徐 锪於其中。這微生物濃縮液是Μ天然微 可包括喜氧菌、兼氧菌，厭氣菌和一些 的®種可有芽孢桿菌（B a c m u S )，假簞 ，固氮螺旋菌（Azospiriilus)，根瘤菌 他多種。各別單一的微生物菌種無法提 。選擇黴生物的首要絛件是微生物中不 ，且微生物濃縮液中混合的菌種，H能 的生態平衡。本發明所用的微生物混合 I n c , ϋ , S . A , Μ 商品名 V i t a B i 〇 購得。若 購得，可K將各種微生物先單獨在葡萄 殖，然後將數種微生物大致平均混合在 本發明中，微生物加入量可Κ根據需 於例如微生物的種類、廢水和聯糊環的 速度等。徼生物的量為每毫升廢水含有 物，例如1萬到50萬隻，較佳5-30萬隻< 是嚴格，例如加入營養物質後，可加快 此可Κ加入少量的微生物，或者若需要 需要加入較多的微生物優選加人微生物 拌讓微生物與廢水充分地混合。 同樣地，本發明的廢水與微生物混合 根據需要而改變，這取決於例如微生物 糊環的量、所希望的處理速度和所需要 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 徐加入適量的微生 生物為主。微生物 天然簟藻類。主要 胞菌(Pseudomonas) (Rhizodiuro)等其 供完整的廢水處理 含使人生病的病菌 保持微生物彼此間 物例如可從ACTS , 微生物混合物不易 糖營養液中培育繁 一起即可ΰ 要而改變，這取決 量、所希望的處禮 幾千或幾萬隻微生 徼生物的量並不 微生物的繁殖，因 快速處理廢水，則 後，經過適當的攪 物的反應時間可Μ 的種類、廢水和聯 達到的處理效果等 (請先閱讀背面之注意事項再填寫本頁) 9 494088 A7 B7_ 五、發明說明（7 ) 。反應時間可從幾小時到幾個月，例如從5小時至30天， 較佳10小時到兩周，如二天或三天。 當這些微生物加入廢水後，微生物脫離休眠狀態而開始 活動。此時微生物開始繁殖，吃食消化廢污水中的游離碳 •氫化合物。有時為加速微生物的繁殖量，可在廢汚水加適 量的肥料（氮磷鉀）或糖、澱粉等營養物質。這些營養物質 不但可加速微生物繁殖量，且容易和原先廢污水中的聯糊 環混合分子黏合，使微生物容易找尋聯觀環，增加對要分 解處理分子的標示作用並加速徼生物分解廢水中有害物質 的胯效。這些營養物質的加入時間可K在加入聯糊環或微 生物之前。過程中或之後加入。較佳在加入聯糊環後加入 微生物前加入。 微生物在繁殖過程中，逐漸適應廢污水中的生態環境， 並開始分解聯糊環和其所附著的化學物質。徼生物和廢水 中的有害化學物質反應是多方面且複雜的，並不是簡單的 單一步驟，對於被聯糊環套住或黏住的碳氫化合物，整體 分子結構的四周被微生物所包圍，各別微生物對此特定的 化學物質釋出特定的酵素互相爭食消化此特定的化學物質 。當數種或數十種酵素的結合力量來分解聯糊環及其附著 的化學物質，原先的化學物質被轉化成其它較適合微生物 分解的碳氫化合物中間副產品，原先釋出的酵素把處理有 害化學物質的能力傳給新生代的微生物，新生代的微生物 結合原先釋出的特定酵素在分解化學物質過程中，又把如 何更有效分解化學物質的能力更新在新的酵素裡。這樣一 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ，Λ (請先閱讀背面之注意事項再填寫本頁) 訂 l·-------線* 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 494088 ΚΙ _Β7 五、發明說明（8 )494088 A7 B7 V. Description of the invention (1) Background of the invention 1. Field of invention The present invention provides a method related to the method. This treatment method uses the harmful chemicals in the waste water, especially the decomposition of starch in starch derivatives. 2. Description of the previous technology, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the waste is difficult. Burn or solid polybenzene or, such as multi-processing. Utilize a lot, the harmfulness of waste water, in fact, the other phases in the water, such as industrial manufacturing or mud mixture. The environmental protection process is industrialized by adding polyphenols to chlorinated biphenyls. Microorganisms such as water and fertilizers contain benzene. They are used in various disinfectants or harmful substances. Similar to the cleaning of heavy metal circuit boards in waste water, these wastes are usually treated with chemical substances, which are bacteria that decompose and treat phenols, literature, and fungicides. Wastewater treatment Wastewater and waste sludge mixtures are treated as a mixture of micro compounds and starch derivatives. Cyclodextrins are used to treat substances and heavy metals. During the process, many sewage waters that are difficult to treat are produced with heavy metal ions. As a result, expensive treatment methods such as high temperature combustion must be used for treatment. K meets local environmental protection requirements. In some cases, dioxin may be generated during the combustion process, and further commercial examples of air pollution algae to decompose hydrocarbons and fermentation treatment in the food industry are needed. However, many esters and other compounds, the basic raw materials of these benzene or phenolic chemicals to humans or animals, directly add organisms to their failure and death, and cannot decompose waste heavy metal ions such as zinc, copper, These metal ions, such as tin and lead, also have a bactericidal effect, and the combination of phenols and heavy metals ----: ---- " ^ 定 L ---- --- line (please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 4 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 494088 A7 B7_ 5. Description of the invention (2) Because of its complicated chemical structure, it is difficult to handle it by combustion. Starch derivatives, also known as cyclodextrin, can be used in the food industry for fresh-keeping of fruit juices (US Patent No. 4,975,293). The perfume industry uses bicyclic rings to prevent the volatilization of perfumes. The food industry uses the joint ring to manufacture mint candy. K reduces the volatilization of mint. The application methods of these joint rings are to emphasize the use of the joint ring to cover or adhere the required chemicals, but the joint ring is not used. In the application of microbial absorption and digestion, in addition to high-temperature combustion and solidification treatment of waste sewage and waste sludge mixture treatment methods, other economical, easy-to-use and effective treatment methods are still needed. 3. Summary of the invention The breakthrough of the present invention is to use a natural microbial mixture solution combined with Cyclodextrins in starch derivatives to jointly treat harmful chemical substances in waste water. The treatment method of the present invention emphasizes its economy, ease of use, and its effectiveness. The object of the present invention is to provide a method of operation for decomposing chemical wastewater containing cleaning agents or bactericidal effects. At the same time, the object of the present invention is to decompose the harmful chemical substances in the waste water into organic fertilizer in the waste water in which the original microorganisms cannot survive. For some high-concentration chemical wastewater, if only the microorganisms are used to perform the decomposition operation, the wastewater must be diluted one hundred or one thousand times, so that the chemical components contained in it can be naturally decomposed. The object of the present invention is to reduce the need for this dilution and to increase the economic benefits of the operation. Another object of the present invention is to mark special chemical substances such as polychlorinated biphenyls and polyfluorinated chemical molecules in waste water, so that they can be easily decomposed effectively. The Chinese paper standard (CNS) A4 (210 X 297 mm) ----: --------------- P Order "------- line ^^ (Please read the precautions on the back before filling this page ) 494088 A7 B7_ 5. Description of the invention (3) Meet the requirements of environmental protection wastewater discharge. (Please read the precautions on the back before filling this page) In addition, the purpose of the present invention is to oxidize heavy metal ions in wastewater, so that heavy metal ions can achieve an oxidation effect similar to high temperature combustion, and decompose the phenol chemicals that were originally combined with heavy metal ions. . 4. Brief description of the diagram Figure 1 shows the structural formulas of α-, Zhao-, and 7-Cyclodextrin. 5. Detailed description of the invention After intensive research, the present inventors have discovered that the use of natural microorganisms in combination with bicyclic rings in starch derivatives can effectively treat harmful chemicals in waste water and / or waste sludge. The processing method of the present invention is economical, easy to use, and effective. The present invention has been completed based on the above findings. The invention provides a method for treating waste water or waste sludge mixture. The waste water or waste sludge mixture may contain phenol chemicals or metal ions, or phenol metal compounds. The method includes the following steps: Employees of the Bureau of Intellectual Property, Ministry of Economic Affairs Consumption cooperative prints (a) Adds the appropriate amount of bi-paste ring, and after moderate mixing and stirring and the required mixing time; (b) Adds appropriate microorganisms, and after the required reaction time, M decomposes the phenol chemical or oxidizes the Metal substances. According to the present invention, the bi-adhesive ring used may be α-, / 3-, 7-bi-adhesive ring and mixtures thereof, and a dot-bi-adhesive ring is preferably used. However, depending on the size of the chemical substance to be treated, it is possible to use a larger or smaller sized coupling ring. These bicyclic rings are commercially available, for example, from C e r s t ar ϋ S A, I n c. The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) p 494088 A7 B7_ V. Description of the invention (4) (Please read the notes on the back before filling this page.) Combination. A common synocyclic ring is a cyclic structure formed by combining enzymes with six, seven, or eight glucose molecules. It is also commonly known as α-, dot-, and 7-bicyclic rings. The molecular structure is shown in Figure 1. Lianguan ring itself is stable in structure and resistant to acids and bases. The hollow ring structure makes the bicyclic ring have special physical and chemical properties in application. The added amount of bi-paste ring can be determined according to the amount of harmful substances to be treated in the wastewater. Generally, the amount of the bi-paste ring is 1 to 15 times the mass of the harmful substance, preferably 2 to 10 times, and more preferably 3 to 7 times, such as 5 times. For example, if the sewage contains 20 ρ ρ m of benzene, then add 100 PPIL to the sewage. Preferably, the amount of the bicyclic ring is more than the amount of the harmful substance, and K increases the chance of adhesion of the bicyclic ring and the harmful substance such as benzene. According to the actual requirements of wastewater treatment, for example, according to certain wastewater discharge standards, it is also possible to use Lianguanhuan with less mass than harmful substances. Add the bi-paste ring to the waste water or oily sludge water to be treated, and add moderate and constant stirring. The stirring method can be stirred by a maple mixer, or the circulation pump can be used to keep the waste fluid circulating back and forth. The stirring speed does not need to be very strict, as long as the bicyclic ring has a chance to adhere to harmful substances such as phenols. Stirring can be continuous or intermittent, but does not require the special consumer office of the Intellectual Property Bureau of the Ministry of Economic Affairs to print fast stirring. The bi-paste ring has the opportunity to contact the phenol chemical molecules, long fluorene hydrocarbons, phenol metal compounds, etc. in the fluid to be treated by the flow of the fluid. When the bicyclic ring is in contact with these chemical molecules, cohesion will occur through the mutual attraction between the molecules. Because the size of the hollow structure of the bi-paste ring is suitable for the structure of phenol molecules, there is a high probability that these chemical molecules are trapped in the hollow structure of the bi-paste ring. When these chemical molecules are surrounded by peripheral bicyclic molecules, the chemical properties of the original phenylhydrazones are not apparent from the paper size. The Chinese national standard (CNS) A4 specification (210 X 297 mm) is applicable. 494088 A7 B7_ V. Description of the invention (5) (Please read the note on the back before filling out this page) Now in the wastewater, the entire bonded molecules become neutral stable substances. Through the action of bi-paste ring, special chemical substances such as PCBs and polyphenols are identified in the wastewater, so that they can be easily decomposed efficiently. For some polyphenylene long fluorene molecules, due to the large structure of the molecules, they cannot be nested in the bi-paste ring. However, due to the mutual attraction between molecules, there may be two or more bi-adhesive rings attached to the long molecule. Several bi-paste rings can be attached to long polyphenylene molecules with many different geometrical space combinations. Depending on the arrangement of the long-chain polyphenyl molecules in the bi-paste ring, long-chain polybenzene molecules may or may not appear Its original chemical nature. As for the heavy metals contained in the wastewater, especially the benzene fluorene metal compounds *, they are also attached to the inside or outside side of the bi-paste ring via the bi-paste ring's adhesion ability. From the viewpoint of the entire macro statistics, The harmful chemical properties are greatly reduced by the action of the bicyclic ring, and the bicyclic ring has a marking function in the fluid, and the microorganism is easy to find the target to be decomposed and treated. In other words, the bicyclic ring can stabilize the harmful chemicals in the waste water, and has a labeling effect, which can change the waste water ecological environment where the original living organisms could not survive or reproduce. The time for printing and mixing the mixed paste ring and waste water by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is not very strict. This is related to the speed of mixing, the amount of sewage, and the amount of added ring. The substances to be treated can be basically adhered. For example, for a 500 or 1 000 ml laboratory measuring cup, stirring for 2 to 15 minutes, such as 5 to 10 minutes, and for large operations, the stirring time will be extended, such as 15-30 minutes, or longer such as 45-60 minute. The reaction temperature of the above step (a) may be the temperature at which waste water is usually treated, such as at the temperature of the waste water environment, such as 0-85 ° C, preferably 5-7 (TC, and the paper size is applicable to Chinese national standards (CNS ) A4 specification (210 X 297 mm). 494088 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Among them, this microbial concentrate is M natural micro-can include aerobic bacteria, aerobic bacteria, anaerobic bacteria and some ® species can be Bacillus (B acmu S), Pseudomonas, Azospiriilus, nodules There are many kinds of bacteria. Individual single microbial strains cannot be mentioned. The first step in selecting a mold organism is the microorganisms that are mixed in the microbial concentrated solution, and the ecological balance of H energy. The microorganisms used in the present invention are mixed with I nc , ϋ, S. A, Μ are commercially available under the trade name Vita B i 〇. If purchased, K can be used to separate various microorganisms in grapes, and then several microorganisms can be mixed in the present invention on average. The amount of microorganisms can be added. KK as needed For example, the type of microorganisms, the speed of wastewater and bilayer ring, etc. The amount of tadpole organisms is contained per milliliter of wastewater, such as 10,000 to 500,000, preferably 50,000 to 300,000 < is strict, for example, after adding nutrients You can speed up this by adding a small amount of microorganisms, or if you need to add more microorganisms, it is better to add human microorganisms to mix the microorganisms with the wastewater. Similarly, the mixing of wastewater and microorganisms of the present invention may be changed as needed, depending on the needs. For example, the amount of microbial loops, the desired processing speed, and the required paper size are in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm). An appropriate amount of micro-organisms are added. The microorganisms are natural diatoms. Pseudomonas (Rhizodiuro), etc. are used for complete wastewater treatment. They contain disease-causing germs to keep microorganisms from each other. For example, they can be grown from ACTS, microbial mixtures are not easy to grow in sugar nutrient solution, which can be changed if necessary. Depending on the amount, the amount of thousands or tens of thousands of microbiological organisms you want to treat is not the proliferation of microorganisms, because of the rapid treatment of wastewater, Then, after appropriate reaction time of the agitation, the types of wastewater, wastewater, and the treatment effect achieved can be achieved (please read the precautions on the back before filling this page) 9 494088 A7 B7_ V. Description of the invention (7) The time can be from several hours to several months, such as from 5 hours to 30 days, preferably from 10 hours to two weeks, such as two or three days. When these microorganisms are added to the wastewater, the microorganisms leave the dormant state and begin to move. At this time, the microorganisms Began to breed and eat free carbon and hydrogen compounds in digested waste water. Sometimes in order to accelerate the multiplication of microorganisms, an appropriate amount of fertilizers (nitrogen, phosphorus, potassium) or sugar, starch and other nutrients can be added to the waste water. These nutrients can not only accelerate the growth of microorganisms, but also easily adhere to the bicyclic ring mixed molecules in the original waste water, making it easy for microbes to find the joint ring, increase the labeling effect on the molecules to be decomposed, and accelerate the harmfulness of the biodegradable wastewater. Material effects. These nutrients can be added at a time prior to the addition of the bicyclic ring or the microorganism. Added during or after. It is preferred to add it after adding the bicyclic ring before adding microorganisms. During the breeding process, the microorganisms gradually adapt to the ecological environment in the waste water, and begin to decompose the bicyclic ring and its attached chemical substances.反应 The reaction of harmful chemicals in biology and wastewater is multifaceted and complicated. It is not a simple single step. For the hydrocarbons that are trapped or stuck by the bicyclic ring, the entire molecular structure is surrounded by microorganisms. Other microorganisms release specific enzymes for this specific chemical substance to compete with each other to digest and digest this specific chemical substance. When the binding power of several or dozens of enzymes breaks down the bicyclic ring and its attached chemicals, the original chemicals are converted into other hydrocarbon by-products that are more suitable for microbial decomposition. The original released enzymes are harmful to the treatment The ability of chemical substances is passed to the new generation of microorganisms. The new generation of microorganisms combined with the specific enzymes originally released in the process of decomposing chemical substances, and renewed the ability to more effectively decompose chemical substances in the new enzyme. Such a paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm), Λ (Please read the precautions on the back before filling this page) Order l · ------- line * Ministry of Economy Printed by the Intellectual Property Bureau employee consumer cooperatives Printed by the Ministry of Economics Intellectual Property Bureau employee consumer cooperatives printed 494088 ΚΙ_Β7 V. Invention description
代傳一代，逐漸地使微生物適應如何分解待處理的化學鞍I 質。 至於在處理過程中的碳氫化合物中間副產品，則由其他 微生物加Κ進一步分解，分解成數小段的碳氫化合物，經 過多層次的消化分解，最後成為有機0Ε，蛋白質、水、和 二氧化碳、各種微生物在處理廢水的生態中，互相支援但 也互相平衡。使用聯糊環於有害化學物質的廢污水和廢污 泥中，基本上提供一個可讓微生物喘息生存的環境，使徼 生物在廢污水中，有機會逐步演變和適應，分解廢污水中 的有害物質。當微生物顯琨對某項特定化學物質有分解能 力時，微生物將對相類似的特定化學物質展現分解能力。 上逑步驟（b)的反應溫度可Κ是通常進行廢水處理的溫 度，如在環境溫度下進行，例如0-45 °C，較佳5-40 °C，更 佳 1 0 - 3 0 °C 〇 本發明所提供的處理方法，另一項重要特徵是可同時處 理廢水中的重金屬離子。重金屬離子本身並非微生物可直 接消化分解的食物，但由於聯觀環和金屬離子的黏合，或 是聯糊環和苯鼢類金屬化合物的黏合，徼生物在嘗試消化 此黏合分子時，釋放出特定的酵素。酵素幫助微生物把重 金屬離子和聯糊環中提供的氧粒子結合。特定的酵素成為 催化媒介，透過催化作用把較高位能的重金屬離子轉變成 較低位能的氧化金屬。經微生物氧化生成的金屬氧化物， 一般多成為固相，猶如燃燒生成的金屬氧化物，化學性質 安定，因比重較水高，較容易沉澱於水池底，可用重力沉 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂---------· 經濟部智慧財產局員工消費合作社印製 494088 A7 B7 五、發明說明（9 ) 澱分離，過濾或離心方式分離，分離的氧化金屬，可回收 再生利用。這獨特的生化反應中，實際含兩種主要的處理 效果，其一是微生物將苯酚等有害化學物質進行分解反應 ;其二是重金屬離子借由聯糊環的氧粒子和微生物酵素達 到氧化安定作用。這種在常溫下氧化重金屬離子及分解苯 鼢類化學物質的處理方式，可適用於一些電路板製程中的 廢水，廢棄潤滑油溶液，和油污泥的處理。 根據本發明，處蛵過的廢污水含有微生物及其產生的酵 素，在該處理過的廢污水中，再加入混名I聯糊環 的待處 理廢水，Μ加速待處理廢水中化學物質的分解時效。 適於本發明的廢水或廢污泥可Μ是多種多樣的，如電路 板製造過程中的廢水，廢棄潤滑油溶液，有機合成化工廠 排出的廢水，特別是含有苯鼢類化學質或金屬離子或苯酚 金屬化合物的那些廢水。 根據本發明的另一方面，提供一種清除吸附於物體表面 的油漬化學物質的方法，其包含： (a) 利用聯糊環和/或澱粉衍生物的混合粉料清除吸附物 體表面的油潰化學物質； (b) 將清除後收集的混合粉料加水混合攪拌； (c) 經過一段時間，加入適當的微生物Μ分解油漬化學 物質。 本發明所提供的處理方法，可蓮用的範圍廣泛。一些化 學油性的聚苯和聚鼢物質，容易黏附於其他接觸到的物體 表面，不容易用化學溶劑清洗，常造戚清除這些有害物質 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ----：---------------P 訂--------線 (請先閱讀背面之注意事項再填寫本頁) 494088 A7 _B7 五、發明說明（10 ) (請先閱讀背面之注音心事項再填寫本頁) 的困擾。如多氯聯苯容易黏附於塑膠桶或橡膠的表面，即 是一例。利用聯糊環和澱粉衍生物的混合物料，可用來清 除物體表面的油漬，將油性化學物質黏附於聯糊環和澱粉 衍生物的混合粉中，然後在將收集的混合粉料放在容器内 加水.，並經過適當的攪拌後，讓聯糊環有機會套合油性化 學物質。然後加入適當的微生物混合液，原先苯酚類化學 物質逐漸分解成為有機物質。這種清除油漬的應用，可使 用純的聯糊環，只是考慮到經濟成本時，聯糖環和澱粉衍 生物的混合物料在實際操作上較為經濟。此蓮用方式可用 於河岸海灘油污的清除作業。 當廢污水清除和處理作業完畢後，原先有害化學物質在 廢水中含量已降至徼量，而廢水中可供微生物利用的食料 已大量減少，造成縮減徼生物的繁殖量，恢復水中微生物 的生態平衡。依被處理的化學物質而定，剩餘的液體可排 放至當地的廢水處理廠，或經適當的處理，如雜質過濾後 ，成為農業可利用的有機物質。 實施例1 經濟部智慧財產局員工消費合作社印製 1 0 0毫升（m 1 )的水中，含0 . 3 重量的下列苯酚混合液， 苯酚的混合液含有苯甲酸（Benzoic A c i d )，1 -硝基-苯酚 (1 - Nirto-phenol)，胺苯酚（Amino — phenol)，2-ΐ 基 鼢（2-benzyl-phenol)和 2_胺基-5-氯-苯 ® (2-amino-5- chloro-phenol)。此混合液基本上有防腐殺菌的功效，使 用時用水稀釋500倍，可達到防腐效果。在此溶液中加約 1 0公克的聯糊環（購自C e r e s t a r U S A , I n c ♦)，混合攪拌約 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） 經濟部智慧財產局員工消費合作社印製 494088 A7 _B7_ 五、發明說明（11 ) 30分鐘，然後加徼生物濃縮液10毫升（Vi taBio,購自ACTS, Inc* , ϋ S A )，每一毫升的濃縮液中含超過1佰萬隻微生物 。微生物在7天左右即完全分解水中的苯酚化學物品。 實施例2 1 000毫升的污水其中含總共500ppir硝基酚和苯甲酸，加 入2000PPm的聯糊環，經過10分鐘的攪拌，再加人混合微 生物200毫升，然後加W曝氣，一星期後，再添加IOOOp pm 的聯糊環及200毫升的混合微生物（Vi taBi ο，購自ACTS, Inc. , USA)，然後曝露於空氣。微生物在總共2星期的時 間内，分解水中含化學物質至微量。 實施例3 將苯甲酸銅及水混合，然後加熱*使苯甲酸銅溶於水中 ，原來水的體積為1 000毫升，而溶解的苯甲酸銅濃度為20 ppsi。加lOOppm量之聯糊環及3公克的氮、磷、鉀化學肥料 。然後添加微生物混合液200inl(VitaBio，購自ACTS, I n c .，11S A )，給予密集連續曝氣，三天後，苯甲酸銅的含 量降至微量，而原先水中的銅離子，Μ氧化銅方式沉澱於 容器底部。 實施例4 原清潔劑廢水1 0 0 0 m 1內含約1 0 ρ ρ m的苯甲酸，C 0 D (化學 需氧量）值約1 8 50。首先，先在原廢水中加人20Ppin的聯糊 環，加以適度的攪拌Μ黏合廢水中的苯甲酸，然後加入 200ιπ1 的微生物混合物（VitaBio，購自 ACTS, Inc., USA) ，並加K曝氣，在經過2 1小時後，微生物在原清潔劑廢水 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 14 一 -------------------訂L-------線· (請先閱讀背面之注音心事項再填寫本頁) 1494088 Ό A7 B7 90. 12. 修正】 4 五、發明說明（1 2) 內大量繁殖，並將原廢水COD値降至48 濟請委員明示，本案修二疑是否變更原實質内容 經濟部智慧財產局員工消費合作社印製 實施例5 一工廠的 其中的苯甲 殺菌防腐作 理。原此工 量的聚凝劑 水沈澱池內 於池底。剩 解，曝氣後 自然沈澱， 排放。惟此 產生大量的 學污泥含苯 或鋁成分， 污水處理的 水收集池內 添加量約在 主。添加的 在污水中的 氣池內添加 (Vi t aBio， 曝氣，例如 氣池內的各 製程污水，其C0D(化學需氧量）値約2000，而 酸含量約在10至20ppm，由於苯甲酸本身具有 用，難直接用微生物處理方式來實行污水處 廠的污水處理方式是先在污水收集池內添加大 ，並用攪拌機加以攪拌，然後將污水流放入污 ，讓污水中的苯甲酸及其他有機化學物質沈澱 餘的污水再流入曝氣池內進行曝氣和微生物分 的污水，再進一步流入第二沈澱池內，讓污水 沈澱處理後的污水，其COD値低於100，然後 化學聚凝劑的污水處理方式，在第一沈澱池內 化學污泥，必須定期性的抽取淸除，因爲此化 甲酸及其他有機化學物質及聚凝劑內含的亞鐵 處理此化學污泥更成爲業者的負擔，增加整個 成本。本發明提供的污水處理方式，可先在污 添加聯糊環，並用攪拌機加以攪拌，聯糊環的 40至lOOppm，聯糊環的添加以yS -聯糊環爲 聯糊環包囊污水中的苯甲酸，降低整體苯甲酸 殺菌防腐作用。然後污水直接流入曝氣池。曝 喜氣菌，兼氣菌和厭氣菌混合的微生物 購自ACTS，INC .，USA)。曝氣池內進行間歇式 每小時曝氣4 0分鐘，停止曝氣2 0分鐘，使曝 種微生物能迅速繁殖，分解污水中的有機成份 (請先閱讀背面之注意事項再填寫本頁) 一*0, · --線- 本紙張尺度適用中國國家標準（CNS)A4規格（2]0 X 297公釐） 15 494088 【90.12· 1 4 δ〇. 12.4 4 修正頁 五、發明說明（1 3) (請先閱讀背面之注意事項再填寫本頁) 及被聯糊環包囊的苯甲酸。經過約1 6小時，曝氣池內的污 水溢流至第二沈澱池內滯留約8小時，使污水進行自然沈 澱及局部性厭氣分解。然後經由濾網過濾排放，排放污水 的COD値低於1 00。本發明提供添加聯糊環的處理方式， 是使聯糊環包囊（e n c a p s u 1 a t e )污水中的苯甲酸，所謂包囊 是苯甲酸分子被包在聯糊環分子的中空部分，使此苯甲酸 分子的化學性質無從顯現，使苯甲酸殺菌的化學性質無法 在污水中顯現。污水中的微生物逐漸分解污水中的有機物 質及聯糊環並逐漸降低污水的COD値。在此實施例中，可 避免污水因使用聚凝劑而產生的化學污泥，進而降低整個 污水處理的成本。 實施例6 β 經濟部智慧財產局員工消費合作社印製 一工廠在淸洗容器及使用器具時，因容器及使用器具表 面附著有油漬化學物質及苯酚類化學物質，不容易用水直 接淸洗。若使用溶劑如乙醚來淸洗，淸洗後的廢溶液，必 須先稀釋數千倍，才能排放到工廠內的污水處理設施內處 理，此將增加污水處理設施的處.理負擔，並有可能因苯酚 類的殺菌作用，而影響到原污水處理設施生物分解池內的 微生物。若容器及使用器具表面的苯酚化學物質平均含量 約在50ppm，可先將含量200至400ppm的聯糊環及澱粉加 水混合，然後用此混合液淸洗擦拭容器及使用器具表面。 將淸洗擦拭後的污水收集後，再添加些適量的水混合以便 於攪拌，攪拌時間約30至60分鐘，這樣讓聯糊環能包囊 淸洗下來的苯酚類化學物質，然後添加如實施例5的微生 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 16 494088 /ν' Γ:/^ η η ' 90.12. ί 4 Α7 Β7 9α 12.-14修正頁 五、發明說明（14 ) 初’並加以間歇曝氣以提局污水中的含氧量。微生物在此 污水中大量繁殖，並且分解此污水中所含的苯酣化學物. 質。而原淸洗容器及使用器具表面，若仍餘留有油漬，苯 酚化學物質，聯糊環及澱粉，可用淸水淸洗容器表面，淸 洗後的污水，可再添加少許的聯糊環，例如5至1 〇 P P m， 然後加以攪拌，攪拌時間約5至1 0分鐘，然後在排放至污 水處理設施內處理。 本發明提供的處理方法，在實際操作上可依廢污水中有 害的物質的含量，相對地彈性運用或重覆使用，而應用則 可非常廣泛在許多情況下，業者不但可以在自己工廠內用 此處理方法來達到環保要求，亦可節省許多此方面的開銷。 (請先閱讀背面之注音心事項再填寫本頁) > 丨訂i 線· 經濟部智慧財產局員工消費合作社印制狀 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 17From generation to generation, the microorganisms are gradually adapted to how to break down the chemical saddle substance I to be treated. As for the intermediate by-products of hydrocarbons in the treatment process, they are further decomposed by other microorganisms plus K, and decomposed into several small sections of hydrocarbons. After multi-level digestion and decomposition, they finally become organic OE, protein, water, carbon dioxide, and various microorganisms. In the ecology of wastewater treatment, we support each other but also balance each other. The use of bilayers in the waste water and waste sludge of harmful chemicals basically provides an environment in which microorganisms can breathe, so that the organisms in the waste water have the opportunity to gradually evolve and adapt to decompose the harmful substances in the waste water. substance. When microorganisms show significant ability to decompose a specific chemical substance, the microorganisms will exhibit decomposability to similar specific chemical substances. The reaction temperature in the step (b) may be the temperature at which wastewater is usually treated, such as at ambient temperature, such as 0-45 ° C, preferably 5-40 ° C, and more preferably 10-30 ° C. 〇 Another important feature of the treatment method provided by the present invention is that it can simultaneously treat heavy metal ions in wastewater. Heavy metal ions themselves are not foods that can be digested and decomposed directly by microorganisms. However, due to the adhesion of the synaptic ring and metal ions, or the adhesion of the bi-paste ring and phenylhydrazone metal compounds, the organisms release specific species when they try to digest this adhesion molecule. Enzymes. Enzymes help microorganisms combine heavy metal ions with oxygen particles provided in the bicyclic ring. Specific enzymes become catalytic mediators, which convert high-potential heavy metal ions into lower-potential oxidized metals through catalysis. Metal oxides generated by microbial oxidation generally become solid phases. They are chemically stable like metal oxides generated by combustion. Because they have a higher specific gravity than water, they are more likely to settle on the bottom of the pool. They can be gravity-sinked. The paper scale is applicable to Chinese national standards. (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling out this page) Order --------- · Printed by the Employee Consumption Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 494088 A7 B7 5 2. Description of the invention (9) Separation by precipitation, filtration or centrifugation. The separated metal oxide can be recycled. This unique biochemical reaction actually contains two main treatment effects. One is the decomposition reaction of harmful chemicals such as phenol by microorganisms; the other is the oxidation stability of heavy metal ions through the oxygen particles and microbial enzymes of the bicyclic ring. . This treatment method of oxidizing heavy metal ions and decomposing benzene hydrazone chemicals at room temperature can be applied to the treatment of wastewater, waste lubricating oil solutions, and oil sludge in some circuit board manufacturing processes. According to the present invention, the treated waste water contains microorganisms and their enzymes. To the treated waste water, the waste water to be treated mixed with I-linked ring is added to accelerate the decomposition of chemical substances in the waste water to be treated. aging. The waste water or waste sludge suitable for the present invention can be various, such as waste water in the manufacturing process of circuit boards, waste lubricating oil solutions, waste water discharged from organic synthetic chemical plants, especially containing benzene hydrazone chemicals or metal ions. Or those wastewater of phenol metal compounds. According to another aspect of the present invention, there is provided a method for removing oily chemical substances adsorbed on the surface of an object, comprising: (a) using a mixed powder of bicyclic ring and / or a starch derivative to remove oily chemicals on the surface of the adsorbed object; Substances; (b) Mix the mixed powder collected after removal with water and stir; (c) After a period of time, add appropriate microorganisms M to decompose the oily chemicals. The processing method provided by the present invention can be used in a wide range. Some chemically oily polybenzene and polyfluorene substances are easy to adhere to the surfaces of other objects that they come into contact with. They are not easy to clean with chemical solvents. They are often removed to remove these harmful substances. This paper applies Chinese National Standard (CNS) A4 (210 X 297) Mm) ----: --------------- P Order -------- Line (Please read the notes on the back before filling this page) 494088 A7 _B7 Fifth, the description of the invention (10) (please read the phonetic notes on the back before filling out this page). An example is PCBs that easily adhere to the surface of plastic buckets or rubber. The mixed material of bicyclic ring and starch derivative can be used to remove oil stains on the surface of the object, and oily chemicals are adhered to the mixed powder of bicyclic ring and starch derivative, and then the collected mixed powder is placed in a container Add water. After proper stirring, give the bicyclic ring a chance to fit oily chemicals. Then, an appropriate microbial mixture is added, and the original phenolic chemicals gradually decompose into organic substances. This application for removing oil stains can use a pure bicyclic ring. However, considering the economic cost, the mixture of bicyclic ring and starch derivative is more economical in actual operation. This lotus method can be used to remove oil pollution from river banks and beaches. After the waste water removal and treatment operations are completed, the content of the original harmful chemicals in the waste water has been reduced to tritium, and the food available for microorganisms in the waste water has been greatly reduced, resulting in a reduction in the breeding amount of tritium and restoration of the ecology of microorganisms in the water balance. Depending on the chemical being processed, the remaining liquid can be discharged to a local wastewater treatment plant, or after appropriate treatment, such as filtration of impurities, becomes an organic substance that can be used in agriculture. Example 1 The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed 100 ml (m 1) of water containing 0.3 weight of the following phenol mixture, and the phenol mixture contained benzoic acid (Benzoic A cid), 1- 1-Nirto-phenol, Amino-phenol, 2-benzyl-phenol and 2-amino-5-chloro-benzene® (2-amino-5 -chloro-phenol). This mixed solution basically has antiseptic and antiseptic effect. When used, it can be diluted 500 times with water to achieve antiseptic effect. Add about 10 grams of bi-paste ring (purchased from Cererestar USA, Inc ♦) to this solution, mix and stir about this paper. Applicable to China National Standard (CNS) A4 (210 x 297 mm). Printed by employee property cooperatives of the Property Bureau 494088 A7 _B7_ V. Description of the invention (11) 30 minutes, and then add 10 ml of biological concentrate (Vi taBio, purchased from ACTS, Inc *, ϋSA), each ml of the concentrate Contains over 1 million microorganisms. Microorganisms completely decompose phenol chemicals in water in about 7 days. Example 2 1 000 ml of sewage contains a total of 500 ppi of nitrophenol and benzoic acid, and a bi-paste ring of 2000 PPm is added. After stirring for 10 minutes, 200 ml of mixed microorganisms are added, and then aeration is performed. After one week, Then, 1000 p pm of bipyridine and 200 ml of mixed microorganisms (Vi ta Bi, purchased from ACTS, Inc., USA) were added, and then exposed to air. Microorganisms break down chemicals in water to trace amounts in a total of 2 weeks. Example 3 The copper benzoate was mixed with water, and then heated * to dissolve the copper benzoate in water. The original volume of water was 1,000 ml, and the dissolved copper benzoate concentration was 20 ppsi. Add 100 ppm of alicyclic and 3 grams of nitrogen, phosphorus, and potassium chemical fertilizers. Then 200inl of microbial mixture (VitaBio, purchased from ACTS, Inc., 11S A) was added, and dense continuous aeration was given. After three days, the content of copper benzoate was reduced to a trace amount, and the copper ion in the original water, M copper oxide The way settles to the bottom of the container. Example 4 The raw detergent wastewater 1 0 0 0 m 1 contains about 10 ρ ρ m of benzoic acid, and the C 0 D (chemical oxygen demand) value is about 1 8 50. First, add 20Ppin bi-paste ring to the raw wastewater, and moderately stir the benzoic acid in the M-bonded wastewater, then add 200 μπ1 of microbial mixture (VitaBio, purchased from ACTS, Inc., USA), and add K aeration. After 21 hours, the microbes in the original detergent wastewater were applied to the national standard (CNS) A4 specification (210 X 297 mm) on this paper scale. 14 A ---------------- --- Order L ------- line · (Please read the phonetic notes on the back before filling in this page) 1494088 Ό A7 B7 90. 12. Amendment] 4 V. Inventory description (1 2) Mass reproduction The COD of the original waste water was reduced to 48. Members are requested to make clear that they have doubts about whether the original substance of the case will be changed. The original flocculant water sedimentation tank is inside the bottom of the tank. Residual solution, spontaneous precipitation and discharge after aeration. However, a large amount of chemical sludge containing benzene or aluminum is produced, and the amount of the sewage treatment water collection tank is about the main amount. Added in the gas tank in the sewage (Vi t aBio, aeration, for example, the process wastewater in the gas tank, its COD (chemical oxygen demand) 値 about 2000, and the acid content of about 10 to 20ppm, because benzene Formic acid itself is useful, and it is difficult to directly implement the sewage treatment method of the sewage treatment plant by using a microbial treatment method. First, add a large amount in the sewage collection tank, stir it with a mixer, and then put the sewage stream into the sewage, so that the benzoic acid and The sewage remaining from the precipitation of other organic chemicals then flows into the aeration tank for aeration and microbial wastewater, and then flows into the second sedimentation tank, so that the sewage after the sewage sedimentation treatment has a COD 値 of less than 100, and then chemically aggregates. The sewage treatment method of the coagulant, the chemical sludge in the first sedimentation tank must be regularly extracted and removed, because this chemical formic acid and other organic chemicals and the ferrous contained in the coagulant are used to treat the chemical sludge. The burden on the operator increases the overall cost. The sewage treatment method provided by the present invention can first add a double paste ring to the sewage and stir it with a blender, and the 40 to 100 ppm of the double paste ring, The addition of the paste ring encapsulates benzoic acid in the sewage with yS-bicyclic ring as the double paste ring, reducing the overall bactericidal antiseptic effect. Then the sewage directly flows into the aeration tank. The aerobic bacteria, aerobic bacteria and anaerobes are mixed Microorganisms were purchased from ACTS, INC., USA). In the aeration tank, intermittent aeration is performed for 40 minutes per hour, and the aeration is stopped for 20 minutes, so that the exposed microorganisms can multiply rapidly and decompose the organic components in the sewage (please read the precautions on the back before filling this page). * 0, · --line-This paper size applies to China National Standard (CNS) A4 (2) 0 X 297 mm 15 494088 [90.12 · 1 4 δ〇. 12.4 4 Revised page V. Description of the invention (1 3 ) (Please read the notes on the back before filling out this page) After about 16 hours, the sewage in the aeration tank overflows and stays in the second sedimentation tank for about 8 hours, so that the sewage is naturally precipitated and the local anaerobic decomposition occurs. It is then discharged through a filter, and the COD 値 of the discharged sewage is lower than 100. The present invention provides a treatment method for adding bicyclic ring, which is to make benzoic acid in encapsu 1 ate sewage. The so-called encapsulation is that the benzoic acid molecule is encapsulated in the hollow part of the bicyclic ring molecule. The chemical properties of formic acid molecules cannot be revealed, making the chemical properties of benzoic acid sterilization impossible in sewage. The microorganisms in the sewage gradually decompose the organic matter and the bicyclic ring in the sewage and gradually reduce the COD 値 of the sewage. In this embodiment, chemical sludge generated by the use of a coagulant can be avoided, thereby reducing the cost of the entire sewage treatment. Example 6 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs When a factory washes containers and appliances, the surface of the containers and appliances was stained with oily chemicals and phenolic chemicals, so it was not easy to wash directly with water. If a solvent such as ether is used for rinsing, the rinsing waste solution must be diluted thousands of times before it can be discharged to the sewage treatment facility in the factory for treatment, which will increase the processing burden of the sewage treatment facility and may Due to the bactericidal effect of phenols, the microorganisms in the biological decomposition tank of the original sewage treatment facility are affected. If the average content of phenol chemicals on the surface of the container and the appliance is about 50 ppm, you can first mix the bisex ring and starch with water content of 200 to 400 ppm, and then use this mixture to rinse and wipe the surface of the container and the appliance. After collecting the effluent after washing and wiping, add some appropriate amount of water for mixing. The stirring time is about 30 to 60 minutes, so that the bi-paste ring can encapsulate the washed-out phenol chemicals. The paper size of Example 5 is based on the Chinese National Standard (CNS) A4 (210 X 297 mm) 16 494088 / ν 'Γ: / ^ η η' 90.12. Ί 4 Α7 Β7 9α 12.-14 2. Description of the invention (14) Initially, intermittent aeration is performed to improve the oxygen content in the sewage. Microorganisms multiply in this sewage, and decompose the phenylhydrazone chemicals in this sewage. For the original washing container and the surface of the appliance, if there are oil stains, phenol chemicals, paste ring and starch remaining, the surface of the container can be rinsed with water. After washing the sewage, a little paste ring can be added. For example, 5 to 10 PP m, and then agitate for about 5 to 10 minutes, and then treat it in a sewage treatment facility. The treatment method provided by the present invention can be used relatively flexibly or repeatedly according to the content of harmful substances in the waste water in practical operation, and the application can be very extensive. In many cases, the industry can not only use it in its own factories. This treatment method can meet environmental protection requirements and also save a lot of expenses in this regard. (Please read the phonetic notes on the back before filling out this page) > 丨 Order i-line · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) ) 17