經濟部中央標準局員工消費合作社印製 482725 A7 B7 五、發明説明（1 ) 發明領域 本發明大致闢於一由眾多浸漬纖維片所組成之裝飾層 合物，更特別的是，本發明有關一攙合有當曝露於紫外光 時發出可見光之材料的高壓裝飾片，與其製造方法。 發明背景 傳統上，高壓裝飾層合物係由兩實質層-一核層與一 表面層所組成，該核層構成在另一層所接合之一底部或一 撐層，在正常高壓層合製造時，核層由眾多纖維片所構成 ，該核片通常由浸漬有層合樹脂之牛皮紙所製成，常用於 核層之層合樹脂包括醜醛、三聚氰胺、氧、環氧、聚0旨、 矽酮與烯丙基苯二甲酸酯樹脂等等，裝飾用層合物之工業 較佳的層合樹脂為由酚與甲醛反應所製成之酚型樹脂。 核層上所置放之裝飾層通常由一個Μ上之含印花、圖 樣設計或浸漬Μ如三聚氰胺、胺、環氧、聚酯、聚矽酮與 二烯丙基苯二甲酸酯樹脂等透明樹脂之固色的纖維色紙， 較佳與典型用於裝飾層紙之樹脂為三聚氰胺-甲醛樹脂， 該硫化三聚氰胺甲醛樹脂為無色、耐光、熱，且抗多種溶 劑與污染。 當層合物之裝飾層包括一印花圖樣時，其常覆有通常 稱之為外層’其典型為浸漬以三聚氰胺-甲醛樹脂之高品 質高級纖維紙，此層保護裝飾層免於腐蝕磨損、撕裂、侵 触化學品、燃燒、灑水等外界不當使用，三聚氰胺-甲醛 樹脂主要負責保護層合物之性質，高級纖維紙作為水薄樹 脂所用之半透明載體、強化三聚氰胺·甲醛樹脂之強度、 $紙張尺度適用中國國家標準（CNS ) Α4規格（210>< 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 482725 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（2 ) 藉由作為充填片材Μ保持外層之均勻樹脂厚度、並控制樹 脂流。 在鋼壓平板間Κ階層關係層疊核層、裝飾層與外表面 層（如有需要），並施Μ壓力與加溫一段時間來硫化浸漬各 別層之層合樹脂，提升溫度與壓力實際上將造成片材中之 浸漬樹脂流動，其結合整體為熟知之整體質量，層合物可 作為地板表面、籌碼表面、桌面、家具、商店設施等，所 附之傳統高壓裝飾層合物見Grosheim等人之美國專利案第 3,418,189號、Casey等人之美國專利案第4,311,748號與 Diori等人之美國專利第4,751,968號等，其等應在此一併 作為參考。 發明摘要 根據本發明，所提供之裝飾層合物係由核層、一裝飾 層與一選擇性地表層或外層經由加溫與加壓下堆疊與層合 而組成，核層包括一個以上三聚氰胺或酚醛樹脂浸濱片或 牛皮紙等、裝飾層包括一個Μ上三聚氰胺浸漬印花片、而 選擇性之外層包括一個以上薄的保護三聚氰胺浸漬紙層， 於本發明之一實施例中，影像或印花係以含光致發光材料 印於一個以上之裝飾紙層上，進而當其曝露於紫外光源（ 即範圍在200至400nm間之電磁幅射源）可見之影像或印花 ’此處所用”光致發光”一詞係以標明其為可見磷光（即在 激化幅射終止後產生連續發光幅射或為可見螢光（即在 激化幄射去除後發光幅射立即停止裝飾紙層再各別飽 和Μ如三聚氰胺•酚醛之透明樹脂，再堆疊以核層，並選 本纸張尺度適用中國國家標準（CNS ) Α4規格（21 〇 X 297公董） (請先閱讀背面之注意事項再填寫本頁) -裝· 5 482725 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（3 ) 擇性地加Μ外層，而在熱與壓力下層合。 於另一實施例中，光致發光材料為曝露於激化幅射外 產生可見光範圍之可見磷光。 在另一實施例中，在與較佳為三聚氰胺之透明樹脂Μ 及光致發明材料的混合物層合前，先將一個Μ上之外層紙 及/或裝飾層紙加Μ浸漬，结果，於紫外光存在時，層合 物之全表面發出可見光。 於本發明之另一實施例中，將一個以上之裝飾層紙飽 和Μ樹脂與光致發光材料之混合物，或者以一含光致發光 材料之墨水印出圖樣與設計，並隨即加以低壓層合或熱熔 成如粒子板、纖維板等基板。 可見的是，本發明可用Μ提供當其作為如保齡球道、 賭桌、籌碼面、舞池與如”出口”之標幟等不同應用中之表 層時，造成獨特且具吸引力之外觀，本發明亦可用於提共 選擇性的可見印花資訊，諸如作業員身分證，另作為傳統 裝飾層合物應用。 較佳實施例之詳细說明 本發明係指摻有光致發光材料之裝飾層合物，在本發 明之第一實施例中，裝飾層合物包括一核層、一裝飾層、 與較佳之一外層，核層為已知之结構，具有一個Μ上之纖 維片，較佳為由牛皮紙所組成，而浸漬Μ層合樹脂，可使 用任何傳統上所習用作為核層之層合樹脂，諸如酚醛、三 聚氰胺、胺、環氧、聚酯、矽酮與烯丙基苯二甲酸酯樹脂 等等，較佳之層合樹脂為由酚與醛類反應所產生之酚醛樹 本紙浪尺度適用中國國家標準（CNS ) Α4規格（210Χ29?公釐） (請先閱讀背面之注意事項再填寫本頁) 、τ 482725 A7 B7 五、發明説明（4 ) 脂。 核層上所置放之裝飾層係由一個以上之纖維片所組成 ，較佳為高級纖維紙片，使用之包括有效量光致發光材料 之印花組合物時，將設計或圖樣施於形成裝飾層之一個Μ 上纖維片的裝飾層表面上，通常較佳將設計或圖樣施於片 材，其等在最終層合物中被定位離核層最遠以強化所層合 物表面所發出發光幅射之強度，圖樣或設計較佳地被施於 最外紙Η或片材，將印花組合物施於片材等的方法並不重 要，任何印花技術，諸如網印、照相印刷等。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 本發明所使用之印刷組成物包括一分散於可提供所 擇印刷方法所欲之流動特性的適當載體中，所提供之光致 發光材料之量係足Κ造成最終结構物內之印花設計或圖樣 發出可見光，可使用熟知的許多態樣的紫外光敏染料或顏 料，此外，易可應用可見光敏光致發光材料，特定顔料或 染料的選擇典型上係取決於當材料發光時所欲之顏色，或 特定應用中所需者為磷光或螢光，再者，所擇之光致發光 顏料或染料必須能夠承受當層狀物於連續層合過程中所受 之熱與壓力，較佳之光致發光材料可購自北卡羅來納Cla-riantCorp of Charlotte 之Leucophor BCRtra ， Leucophor BCRtmg液體之1，2二苯乙烯材料，其具有約49%之固體並 於發光時產生藍光，較佳為1,2二苯乙烯材料。 光致發光顏料或染料可和與所擇光致發光顏料或染料 相容之傳統印刷墨水相混合，且可均勻分散，舉例言之， 光致發光顏料或染料可與購自Massachusetts之Gotham 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 482725 經濟部中央標準局員工消費合作社印裝 Α7 Β7 五、發明説明（5 )Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 482725 A7 B7 V. Description of the Invention (1) Field of the Invention The present invention is broadly based on a decorative laminate composed of many impregnated fiber sheets. More specifically, the present invention relates to A high-voltage decorative sheet incorporating a material that emits visible light when exposed to ultraviolet light, and a method for manufacturing the same. BACKGROUND OF THE INVENTION Traditionally, a high-pressure decorative laminate is composed of two substantial layers-a core layer and a surface layer. The core layer constitutes a bottom or a support layer joined by another layer. During normal high-pressure lamination manufacturing, The core layer is composed of many fiber sheets. The core sheet is usually made of kraft paper impregnated with a laminated resin. The laminated resins commonly used in the core layer include ugaldehyde, melamine, oxygen, epoxy, polyoxymethylene, silicon Ketone and allyl phthalate resins, etc., the industrially preferred laminated resins for decorative laminates are phenolic resins made by the reaction of phenol and formaldehyde. The decorative layer placed on the core layer is usually made of a transparent material containing a print, pattern design or impregnation on the surface, such as melamine, amine, epoxy, polyester, silicone, and diallyl phthalate resin. The resin-fixed fiber-colored paper is preferably a melamine-formaldehyde resin that is typically used for decorative paper. The vulcanized melamine formaldehyde resin is colorless, light-resistant, heat-resistant, and resistant to a variety of solvents and pollution. When the decorative layer of the laminate includes a printed pattern, it is often covered with what is commonly referred to as an 'outer layer', which is typically a high-quality high-quality fiber paper impregnated with melamine-formaldehyde resin. This layer protects the decorative layer from corrosion, abrasion, and tearing. Cracking, interference with chemicals, burning, water spraying and other improper use. Melamine-formaldehyde resin is mainly responsible for protecting the properties of the laminate. High-grade fiber paper is used as a translucent carrier for water-thin resin. Paper size applies Chinese National Standard (CNS) Α4 specification (210 > < 297 mm) (Please read the notes on the back before filling out this page) Binding and binding 482725 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 5 2. Description of the invention (2) The uniform resin thickness of the outer layer is maintained as the filling sheet M, and the resin flow is controlled. The core layer, the decorative layer and the outer surface layer (if necessary) are laminated in the K-layer relationship between the steel plates, and the pressure and temperature are applied for a period of time to vulcanize and impregnate the laminated resins of the respective layers, and the temperature and pressure are actually increased. It will cause the impregnated resin in the sheet to flow, and its combination is generally known as the overall quality. The laminate can be used as floor surface, chip surface, table top, furniture, store facilities, etc. For the attached traditional high-pressure decorative laminates, see Grosheim et al. U.S. Pat. No. 3,418,189, Casey et al. U.S. Pat. No. 4,311,748, and Diori et al. U.S. Pat. No. 4,751,968, etc., which are hereby incorporated by reference. Summary of the Invention According to the present invention, the decorative laminate provided is composed of a core layer, a decorative layer, and a selective surface layer or an outer layer stacked and laminated under heating and pressure. The core layer includes more than one melamine or The decorative layer includes a melamine-impregnated sheet or a kraft paper, and the decorative layer includes one or more melamine-impregnated printed sheets, and the optional outer layer includes one or more thin protective melamine-impregnated paper layers. In one embodiment of the present invention, the image or printing is based on Images or prints containing photoluminescent material printed on more than one decorative paper layer and then visible when exposed to a UV light source (ie, an electromagnetic radiation source in the range of 200 to 400nm) 'Photoluminescence used here' The term is used to indicate that it is visible phosphorescence (that is, continuous luminous radiation or visible fluorescence is generated after the termination of the excitation radiation). • Phenolic transparent resin, stacked with a core layer, and selected paper size applicable to China National Standard (CNS) Α4 specification (21 〇 297 公 董) (please read first Note on the back, please fill out this page again)-Packing · 5 482725 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention (3) Optionally add the outer layer of M, and laminate under heat and pressure. In one embodiment, the photoluminescent material is visible phosphorescence in the visible light range which is generated by being exposed to the excited radiation. In another embodiment, prior to lamination with a mixture of a transparent resin M, preferably a melamine, and a photoinventive material, Firstly, impregnate one M upper outer paper and / or decorative paper with M, as a result, in the presence of ultraviolet light, the entire surface of the laminate emits visible light. In another embodiment of the present invention, more than one The decorative layer paper is a mixture of saturated M resin and photoluminescent material, or the pattern and design are printed with an ink containing photoluminescent material, and then laminated with low pressure or hot-melted into substrates such as particle boards and fiberboard. Visible Yes, the present invention can provide a unique and attractive surface when used as a surface layer in different applications such as bowling lanes, gaming tables, chip noodles, dance floors, and flags such as "exit" In terms of appearance, the present invention can also be used to provide selective visible print information, such as an operator's ID card, and it can also be used as a traditional decorative laminate. Detailed description of preferred embodiments The present invention refers to doped photoluminescent materials In the first embodiment of the present invention, the decorative laminate includes a core layer, a decorative layer, and a preferred outer layer. The core layer has a known structure and has a fiber sheet on M. It is preferably composed of kraft paper and the impregnated M laminated resin can be any conventionally used laminated resin such as phenol, melamine, amine, epoxy, polyester, silicone, and allylbenzene. Diformate resin, etc., the preferred laminated resin is the phenolic tree paper produced by the reaction of phenols and aldehydes. The size of the paper is suitable for the Chinese National Standard (CNS) A4 specification (210 × 29? Mm). Please fill in this page for matters), τ 482725 A7 B7 V. Description of the invention (4) Grease. The decorative layer placed on the core layer is composed of more than one fiber sheet, preferably a high-grade fiber paper sheet. When using a printing composition including an effective amount of a photoluminescent material, a design or pattern is applied to form the decorative layer. On the surface of the decorative layer of the fibrous sheet on one M, it is usually preferred to apply a design or pattern to the sheet, which is positioned farthest from the core layer in the final laminate to enhance the luminescence emitted from the surface of the laminate. The intensity of the shot, pattern or design is preferably applied to the outermost paper sheet or sheet, and the method of applying the printing composition to the sheet is not important. Any printing technique, such as screen printing, photo printing, etc. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling this page) The printing composition used in the present invention includes a suitable carrier dispersed in a suitable carrier that provides the desired flow characteristics of the selected printing method The amount of photoluminescence material provided is sufficient to cause visible light in the printed design or pattern in the final structure. Many well-known UV-sensitive dyes or pigments can be used. In addition, visible light-sensitive photoluminescence materials can be easily applied. The choice of a particular pigment or dye typically depends on the desired color when the material emits light, or the phosphorescent or fluorescent light required in a particular application. Furthermore, the chosen photoluminescent pigment or dye must be able to withstand The heat and pressure to which the layer is subjected during continuous lamination. Preferred photoluminescent materials can be purchased from Leucophor BCRtra, Leucophor BCRtmg liquid stilbene material of Cla-riant Corp of Charlotte, North Carolina. About 49% solids and produce blue light when emitting light, preferably stilbene materials. Photoluminescent pigments or dyes can be mixed with traditional printing inks compatible with the chosen photoluminescent pigments or dyes and can be dispersed uniformly. For example, photoluminescent pigments or dyes can be used with Gotham papers from Massachusetts Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) 482725 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5)
Ink of Marlboro之Clear Screen Print Extender^111 相混 合，易可選擇性地包括如棕色或白色之不透明有色顏料， 因此，取決於最終層合物之所欲外觀，印刷組成物可包括 不透明有色（非光致發光）顏料或染料，如此，當於正常光 照狀態下，可見影像與圖樣，然而，可加入非光致發光顏 料或染料特別係如棕色之深色有色顏料或染料Μ降低光致 發光效應，因此，在印刷組成物中加入非光致發光顏料或 染料通常不佳，使印刷組成物在正常光狀態下實質為透明 的。 一如熟於此技之人士所知者，印刷組程物易可包括不 背離本發明範圍之其它適量的添加物，諸如黏度改質劑、 熱穩定劑、濕潤劑、結合劑等。 此外，考慮可提供具有Μ傳統非光致發光墨水組成物 所印之圖樣或設計，Μ此方法，最終層合物可呈現之裝飾 表面具有多種圖樣或設計，一組係在正常光或日光下可見 的，另一組係在紫外光下為可見的。 一旦裝飾片具有所欲之圖樣與設計，隨即將每一片浸 漬如傳統之透明樹脂，透明樹脂之例如酚醛、三聚氰胺、 胺、環氧、聚酯、矽酮等，三聚氰胺為較佳者。 最後，通常提供Μ適當透明樹脂浸潰之纖維紙材的外 曆，較佳之外層為高品質之纖維紙，關於裝飾層，三聚氰 胺-酚醛為較佳之浸漬樹脂，當然，光致發光印刷組成物 之設計與圖樣可印於”外層”紙之一的片材上，在此一狀態 下，較佳地將印刷施於接近核層與裝飾層之外層上。 本紙張尺度適用中國國家標準（CNS ) Α4規格（21〇Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) Γ衣. 訂 經濟部中央標準局員工消費合作社印製 482725 A7 B7 五、發明説明（6 ) 在如鋼壓板間Μ預定之關係疊合核層、裝飾層與選擇 性的外表層，如熟於此技之人士所知者，可在核層之另一 面供設一額外之裝飾層與選擇性的外層，结果層合物之兩 主要表面係具裝飾性的，此技之人士所熟知者，疊層經過 足夠壓力與溫度，於一段時間後，硫化層合樹脂浸漬之各 別層，層合溫度至少為230°F，而通常在約250°F至300°F 之範圍中，所加之壓力通常在約305至1500psi，提增之溫 度與壓力造成片材中之浸漬樹脂流動，其固合整體成如層 合物之一整體。 當提供一紫外光時，其穿過外曆並到達裝飾層，结果 ，印於含裝飾層之片材的光致發光材料因此產生光幅射， 使所印之圖樣或設計變得可見，取決於所使用之光致發光 材料、所用此類材料之量、紫外光源之強度、與背景顏色 ，可能需要降低到達層合物之可見光程度，藉Μ強化發光 設計或圖樣之可見性。 在本發明之另一實施例中，含有效量光致發光材料之 印刷組成物被施於形成裝飾片之一個以上纖維板之上，可 使用任何傳統之印刷技術，以此方法，層合物之經處理的 全部表面在紫外光之存在下可發出可見光幅射。 在本發明之另一實施例中，可獲得相似之結果，其中 ，製備所擇較佳為三聚氰胺-酚醛之透明樹脂與一光致發 光材料的混合物，該光致發光材料可為上述之任何適用之 傳統習知者，Μ傳統之方式將一個以上之外紙及/或裝飾 紙浸漬Μ所得之樹脂與光致發光材料混合物，該核層、裝 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） (請先閱讀背面之注意事項再填寫本頁) .裝· 訂 482725 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（7 ) 飾層、與選擇性的外層Μ預定之關係被堆疊，並進行加溫 與加壓如已知之高壓裝飾層合物，再次，結果將此紫外光 下之層合物的全表面發光。 再者，當光致發光材料被施於一個外層之全表面上時 ，另外此類之紙可Μ不透明墨水提供所印出之圖樣、設計 與影像，較之施有光致發光材料之紙，施Μ不透明印刷之 紙係置放於較接近最終層合物之外表面處，結果，當存在 紫外光時，除了Μ不透明墨水所印之影像、圖樣與設計所 造成”負”像部份外，層合物之全部上表面將發光。 在本發明之另一實施例中，Μ前述者製造一個Μ上之 外層及/或裝飾層紙，經此處理之紙隨即併為一低壓層合 物，Μ光致發光材料所處理之紙係利用如顆粒板、纖維板 等剛性板Μ預定關係加Μ疊合，若在一片Μ上之紙施Μ印 刷，較好包括前述之外層，每一紙層係Μ前述討論之高壓 層合方法Μ樹脂加Μ浸漬，然而典型上，熟於此技之人士 皆知在低壓或熱熔層合下可利用一較高催化劑量，較佳為 三聚氰胺，所有層皆被置放於剛壓板之熱壓下，並進行相 對低溫與低壓一段時間使其足Κ硫化層合樹脂所浸漬之各 別層，一如傳統者。 再進一步說明，可Μ光致變色染料替代上述應用中之 任何光致發光材料，或一併使用，其在可見光之第一波長 之光存在下時其反射可見光譜中一種顏色，而存在不同之 光的紫外光之第二波長下時，其反射可見光譜中的第二不 同顏色之光致變色材料。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 經濟部中央標準局員工消費合作社印製 482725 A7 B7 五、發明説明（8 ) 下列之例係用K說明本發明，並不構成對本發明之標 的任何限制。 第1實施例 使用購自Massachusettes之含50%固體的Gotham Ink of Marlboro之Clear Screen Print Extendertm3000·。克 與購自 Clariant Corp之含49¾固體之的Leucophor BCRtItt， 161.1 克，所得溶液為Clear Screen Print Extendertn^D 佔固體約5%之Leucophor BCRtm，M圖樣將此一溶液網印 於供設有楓紋設計之多纖維紙片，在印刷前以三聚氰胺-甲醛浸漬此等紙片。 製備兩層合物，其各具有下列Μ預定關係所堆疊之層 :一少量三聚氰胺-甲醛浸漬外層片、兩耐耗損三聚氰胺-甲醛浸漬片、一個上述之網印三聚氰胺-甲醛浸漬裝飾片 、四十六酚浸漬牛皮紙核片（作為大體並強化）、一三聚氰 胺-甲醛浸潰（用以防止彎曲）、兩耐耗損外層三聚氰胺-甲 醛片、以及一少量三聚氰胺-甲醛浸潰外層片，其等片材 係置放於鋼壓板間並進行約120psi與最高溫約300°F下約 35分鐘。 KClear Screen Print £父七011(^1^111與1^11。〇?11(^ BCRtm 網印之圖樣不易在正常照明下看見，但當其曝露於紫外光 源時，其呈現優異螢光。 第2實施例 在5加侖容器中藉摻合K製備下列樹脂組成： 成分物 量（克） 重量百分比％ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -裝. 、11 482725 A7 B7 五、發明説明（9 )Ink of Marlboro's Clear Screen Print Extender ^ 111 is blended to easily and optionally include opaque colored pigments such as brown or white. Therefore, depending on the desired appearance of the final laminate, the printing composition may include opaque colored (non- Photoluminescence) pigments or dyes, so that under normal light conditions, images and patterns can be seen, however, non-photoluminescent pigments or dyes can be added, especially dark colored pigments or dyes such as brown to reduce the photoluminescence effect. Therefore, it is generally not good to add a non-photoluminescent pigment or dye to the printing composition, so that the printing composition is substantially transparent under normal light conditions. As known to those skilled in the art, the printing process can easily include other suitable amounts of additives such as viscosity modifiers, heat stabilizers, wetting agents, binding agents, and the like without departing from the scope of the present invention. In addition, it is considered that patterns or designs printed with traditional non-photoluminescent ink compositions can be provided. With this method, the decorative surface that the final laminate can present has a variety of patterns or designs, one set under normal or daylight. Visible, another group is visible under ultraviolet light. Once the decorative sheet has the desired pattern and design, then each sheet is impregnated with a conventional transparent resin, such as phenol, melamine, amine, epoxy, polyester, silicone, etc. Melamine is preferred. Finally, the external calendar of fiber paper impregnated with a suitable transparent resin is usually provided. The outer layer is preferably high-quality fiber paper. As for the decorative layer, melamine-phenolic resin is the preferred impregnating resin. Of course, the photoluminescent printing composition Designs and patterns can be printed on a sheet of one of the "outer layers" of paper. In this state, printing is preferably applied to the outer layers near the core and decorative layers. This paper size applies the Chinese National Standard (CNS) A4 specification (21〇 × 297 mm) (Please read the precautions on the back before filling this page) Γ. Ordered by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, printed 482725 A7 B7 5 (6) The core layer, decorative layer and optional outer surface layer are superimposed on the predetermined relationship such as between steel platens. As known to those skilled in the art, one can be provided on the other side of the core layer. Additional decorative layer and optional outer layer. As a result, the two main surfaces of the laminate are decorative. As is well known to those skilled in the art, the laminate is subjected to sufficient pressure and temperature. After a period of time, the vulcanized laminated resin is impregnated. For the individual layers, the lamination temperature is at least 230 ° F, and is usually in the range of about 250 ° F to 300 ° F. The applied pressure is usually about 305 to 1500psi. The increased temperature and pressure cause the The impregnated resin flows, and its solidification is integrated as one of the laminates. When an ultraviolet light is provided, it passes through the calendar and reaches the decorative layer. As a result, the photoluminescent material printed on the sheet containing the decorative layer thus generates light radiation, which makes the printed pattern or design visible, depending on Depending on the photoluminescent material used, the amount of such material used, the intensity of the UV light source, and the background color, it may be necessary to reduce the amount of visible light reaching the laminate, and enhance the visibility of the luminescent design or pattern by M. In another embodiment of the present invention, a printing composition containing an effective amount of a photoluminescent material is applied to one or more fiberboards forming a decorative sheet, and any conventional printing technique can be used. All treated surfaces emit visible light radiation in the presence of ultraviolet light. In another embodiment of the present invention, a similar result can be obtained, in which a mixture of a transparent resin selected as melamine-phenolic and a photoluminescent material is preferably prepared, and the photoluminescent material may be any of the above-mentioned applications. For those who are traditionally known, the traditional way of M is to impregnate more than one paper and / or decorative paper with a mixture of resin and photoluminescent material obtained by M. The core layer and paper size are in accordance with Chinese National Standard (CNS) A4 specifications. (210χ 297 mm) (Please read the notes on the back before filling out this page). Binding · Order 482725 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention (7) Finishing, and optional The predetermined relationship of the outer layers M is stacked, and heating and pressing are performed as known in the high-pressure decorative laminate, and again, as a result, the entire surface of the laminate under this ultraviolet light emits light. Furthermore, when photoluminescent material is applied to the entire surface of an outer layer, in addition, such paper can provide printed patterns, designs, and images with opaque ink, compared to paper with photoluminescent material. The opaque printed paper is placed closer to the outer surface of the final laminate. As a result, when UV light is present, in addition to the "negative" image portion caused by the image, pattern, and design printed by the opaque ink, the layer The entire upper surface of the composition will emit light. In another embodiment of the present invention, the aforementioned M manufactures an upper and outer paper of M and / or a decorative layer, and the paper thus treated is then a low-pressure laminate, and the paper system treated by the M photoluminescent material A rigid board such as particle board, fiberboard and other predetermined relationships are added and superimposed. If printing is performed on a sheet of paper, it preferably includes the aforementioned outer layer, and each paper layer is the high-pressure laminating method discussed above. Add M impregnation, but typically, those skilled in the art know that a higher amount of catalyst can be used under low pressure or hot melt lamination, preferably melamine, and all layers are placed under the hot pressing of a rigid plate And carry out the relatively low temperature and low pressure for a period of time to make the respective layers impregnated with K-cured laminated resin, just like the traditional ones. To further explain, M photochromic dyes can be used in place of any photoluminescent material in the above applications, or they can be used together. In the presence of light of the first wavelength of visible light, it reflects one color in the visible spectrum, but there are differences. At the second wavelength of the ultraviolet light, it reflects a photochromic material of a second different color in the visible spectrum. This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the precautions on the back before filling this page) Binding and printing printed by the Central Consumers Bureau of the Ministry of Economic Affairs Consumer Cooperatives 482725 A7 B7 V. Description of the invention (8) The following examples use K to illustrate the present invention and do not constitute any limitation on the subject matter of the present invention. First Example A 50% solids Gotham Ink of Marlboro from Massachusetts, Clear Screen Print Extendertm3000. G and Leucophor BCRtItt containing 49¾ solids from Clariant Corp., 161.1 g. The resulting solution was Clear Screen Print Extendertn ^ D. Leucophor BCRtm accounted for approximately 5% of solids. M solution was used to screen print this solution on a maple pattern. The designed multi-fiber paper sheets are impregnated with melamine-formaldehyde before printing. Prepare two laminates, each having the following stacked layers in a predetermined relationship: a small amount of melamine-formaldehyde impregnated outer sheet, two wear-resistant melamine-formaldehyde impregnated sheets, one of the aforementioned screen-printed melamine-formaldehyde impregnated decorative sheets, forty Hexaphenol-impregnated kraft core sheet (as a general and strengthened), a melamine-formaldehyde impregnation (to prevent bending), two wear-resistant outer melamine-formaldehyde sheets, and a small amount of melamine-formaldehyde impregnated outer sheet, and other sheets The system was placed between steel platens and subjected to a maximum temperature of about 120 psi and a maximum temperature of about 300 ° F for about 35 minutes. KClear Screen Print £ 7-1011 (^ 1 ^ 111 and 1 ^ 11.〇? 11 (^ BCRtm) The screen printing pattern is not easy to see under normal lighting, but when it is exposed to an ultraviolet light source, it exhibits excellent fluorescence. 2 Example The following resin composition was prepared by blending K in a 5-gallon container: Ingredients (g) Weight percent% This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the note on the back first Please fill in this page for matters)-Packing, 11 482725 A7 B7 V. Description of Invention (9)
Piomel 1101 18359.4 91.4 水 602-5 3.01 Hypersal2 26·6 0·13 氯化鎂 12.1 0·06 Leucophor BCR 1000.0 5.00 經濟部中央標準局員工消費合作社印製 1 ·購自 Main,Pioneer Plastic Corporation of Auburn 之三聚氰胺-甲醛樹脂。 2.購自Hoechst Celance之濕潤劑0 將外片（22tf基重之高級纖維紙）浸漬K上述組成內容 Κ混合物使具有69%重量之樹脂，製備3層合物之糸列，各 自具有一三聚氰胺-甲醛浸漬楓粒裝飾片、十個酚浸漬牛 皮紙核層、一個三聚氰胺-甲醛浸漬衡平片、二耐耗損外 層三聚氰胺-甲醛浸漬片、與一少量三聚氰胺-甲醛浸漬之 外層Η。每一3層合物供設有不同之頂表面構成，如下： (1) 一 22tf基重三聚氰胺-甲醛浸漬外層片； 一 K上述樹脂/螢光組成所浸漬之外層片； 一 22#基重三聚氰胺-甲醛浸漬之外層片； (2) 二22ίί基重三聚氰胺-甲醛浸漬外層片； 一個Μ上述樹脂/螢光組成浸漬之外層片； (3) — 22it基重三聚氰胺-甲醛浸漬外層片； 二個Μ上述樹脂/螢光組成所浸漬之外層片； 在每一狀況下，將其等片材係置放於鋼壓板間並進行 約120psi與最高溫約300°F下約35分鐘。 (請先閱讀背面之注意事項再填寫本頁) 裝· 訂 本纸張尺度適用中國國家標準（CNS ) A4規格（210Χ297公釐） 482725 Α7 Β7 五、發明説明（10 ) 所有的三層合物在曝露於紫外光源時呈現可見螢光， 在同樣紫外光源下，層合物（3)顯現高密度之螢光。 第3實施例 除Μ購自New Jersey United Mineral & Chemical Corporation of Lyndhurst之鱗光金屬氧化物顏料 Luminiva G300C代替Leucophor ，以第 1 實施例 中之方法製備三試樣，ΚΙ、2與5重量百分比之Luminiva G300C分別製備三試樣，並如第1實施例般地加以層合， 三試樣之每一在曝露於可見光後，於暗室中呈現可見螢光 之”光” 〇 第4實施例 製備如第2實施例之樹脂組成物，其M0.5重量百分 比之Day Glow D-282粉粒替代5重量百分比之Leucophor BCRh，該Day Glow D-282係由在固體溶液中含可呈螢光 之染料之有機樹脂粒子所構成，係購自Ohio Cleveland之 Day-Glo Color Corp，該試樣Μ第2實施例之法製備*所 得之層合物呈現高密度螢光。 (請先閱讀背面之注意事項再填寫本頁) -裝· 、11 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS )八4規格（21〇χ 297公釐）Piomel 1101 18359.4 91.4 Water 602-5 3.01 Hypersal2 26 · 6 0 · 13 Magnesium Chloride 12.1 0 · 06 Leucophor BCR 1000.0 5.00 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs1. Melamine-formaldehyde purchased from Main, Pioneer Plastic Corporation of Auburn Resin. 2. Wetting agent purchased from Hoechst Celance 0 The outer sheet (22tf basis weight high-grade fiber paper) was impregnated with the above composition K mixture to make a resin with 69% by weight to prepare a queue of 3 laminates, each with a melamine -Formaldehyde-impregnated maple grain decorative sheet, ten phenol-impregnated kraft paper core layers, one melamine-formaldehyde impregnated balance sheet, two wear-resistant outer layers of melamine-formaldehyde impregnated sheet, and a small amount of melamine-formaldehyde impregnated outer layer. Each 3 laminate is provided with a different top surface composition, as follows: (1) a 22tf basis weight melamine-formaldehyde impregnated outer layer sheet; a K above resin / fluorescent composition impregnated outer layer sheet; a 22 # basis weight Melamine-formaldehyde-impregnated outer sheet; (2) 22 22-based heavy melamine-formaldehyde-impregnated outer sheet; one M above resin / fluorescent composition-impregnated outer sheet; (3) — 22it-based heavy-melamine-formaldehyde-impregnated outer sheet; two The outer layers impregnated with the above resin / fluorescent composition; in each case, these sheets were placed between steel platens and subjected to about 120 psi and a maximum temperature of about 300 ° F for about 35 minutes. (Please read the precautions on the back before filling this page) The size of the bound and bound paper is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 482725 Α7 Β7 V. Description of the invention (10) All three-layer compounds Visible fluorescent light appears when exposed to an ultraviolet light source. Under the same ultraviolet light source, the laminate (3) shows high-density fluorescent light. In the third embodiment, except for the scale metal oxide pigment Luminiva G300C purchased from New Jersey United Mineral & Chemical Corporation of Lyndhurst, instead of Leucophor, three samples were prepared by the method in the first embodiment, KI, 2 and 5 weight percent. Three samples of Luminiva G300C were prepared and laminated as in the first embodiment. Each of the three samples exhibited the "light" of visible fluorescence in a dark room after being exposed to visible light. For example, in the resin composition of the second embodiment, M 0.5 weight percent of Day Glow D-282 powder replaces 5 weight percent of Leucophor BCRh. The Day Glow D-282 is composed of a fluorescent solution in a solid solution. The dye is composed of organic resin particles and was purchased from Ohio Cleveland's Day-Glo Color Corp. The sample M was prepared by the method of the second embodiment. The obtained laminate exhibited high-density fluorescence. (Please read the precautions on the back before filling this page)-Installed · 11 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs This paper size applies to China National Standards (CNS) 8-4 (21〇χ 297 mm)