TW472064B - Olefin polymers and process for producing the same - Google Patents

Abstract

The invention provides a polymer of ethylene as a first component or monomer, with a branched olefin as a second component or monomer, and at least one different olefin as a third component or monomer. The olefins can be obtained from a Fischer-Tropsch process.

Description

A7 B7 V. Invention | Month (1 The present invention is about polymerization. It is particularly about polymers that use ethylene as the first and second monomer, and second and third monomers, and the party that manufactures the polymer in accordance with the present invention In a broad sense, a polymer is provided that uses ethylene as the first component or monomer, and a branched olefin as the second component or monomer, and at least one different alkane as the third component or monomer. The fluorene monomer in the polymer according to the present invention may be derived from the Fisher-Law method, that is, it may be obtained from the so-called Winter Fisher-Law method; however, any other polymeric grade olefin monomer obtained from other methods may be used instead One or more hydrocarbon-associated monomers derived from the Fisher-Law method. Therefore, a combination of monomers derived from the Fisher-Law method and those not derived from the Fisher-Law method may be used. Regarding the monomers or ingredients, derived from f Snow • 阙 Method " means that in the presence of a · Fisher • 阙 catalyst that is suitable for, it is usually an iron, or cobalt / iron Fisher / 雪 catalyst, at a high temperature in the reactor, which Usually a fixed or slurry bed reactor 'reaction contains a The synthesis gas of carbonized and hydrogen thus obtains a monomer or component obtained from a range of products, including monomers or components suitable for use in the polymer of the present invention. The product obtained from the Fisher • Ron reaction must then be processed to obtain Individual products, such as monomers or ingredients suitable for use in the polymers of the present invention ... Therefore, the polymers according to the present invention may have ethylene as the first monomer and at least one branched olefin as the second Monomers and tertiary olefins are polymers of the third monomer, and these fluorenes are obtained from the Frey 阙 process. They may be polymers substituted with any other polymerization-grade olefin monomers obtained from other processes' or their Can be derived from Fisher • Law or not derived from Fisher • Law 4-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm). Please read the > i notice on the back first Refill this page} Zero-packing ------- Order · --- s'. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs _ 137 _ _ 137 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 472064 Λ7 V. The olefins of January () The present inventors have surprisingly found that as a second monomer or component, for example, a first branched alpha olefin, and / or as a third monomer or component, for example, a linear α-associated smoke Or the second branched alpha olefin, and the olefin monomer used for the catalytic polymerization is obtained from the deduction method, the resulting polymer has a very large domain and / or application properties, and in some of these properties, all of them The monomer is excellent in obtaining a foot polymer by a conventional method. The inventors believe that this unexpected behavior was due to the very small amount of Rantallene solder present, and that—to date, it is considered to be Impurities. These other olefin components can be other hydrocarbons carrying one or more double bonds, whether linear, branched, or aromatic, except for those that destroy the catalyst to the point where monomers are no longer polymerized. The present inventors further believe that these ingredients can sometimes change the polydispersity of polymers obtained in accordance with the present invention, and therefore improve the processing power of these polymers. These components can selectively and / or partially and / or temporarily destroy some active sites of the catalyst, and thus hinder the rate of different reactions, such as monomer insertion and / or propagation and / or transfer and / or termination, and Change the distribution of comonomers in the polymer chain and / or the level of individual comonomers in the polymer and / or the branch length of the polymer backbone and / or? The molecular weight of the kappa compound and / or its molecular weight distribution, and / or its morphology, any one or more of which is reflected in the unexpected applicability of the resulting polymer. However, the inventors have also found that, for practical applications, The olefin monomers used in the polymerization medium as the first monomer component, for example, the first branched π olefin, and / or as the tertiary monomer component, for example, the linear alpha olefin or the second branch fluorene are obtained from Fisher • In the method, the proportion of the other olefin components mentioned above is smaller than -5-. This paper size applies the Chinese National Standard (CNS) A ·! Specifications (210 X 297_public love) ------- -f „----- --- Order --------- (Please read the urgent matters on the back before filling out this page) 472064 A7 ί! Τ.-Printed by the Ministry of Intellectual Property Bureau Staff Consumer Cooperatives It is preferably within specific limits. Therefore, when obtained from the Fisher-Law method, it exists in the second to, for example, the first branched alpha olefin, and / or the third monomeric dimer component, such as the te or the second branched alpha olefin. Of these other olefins ?, the total mass f 'of the linear α-body is shown on a mass or weight basis based on the single 2%, and more preferably 0.0%. 2% to 2%, and the best is 0/20 / 'Yes, 2% to the monomer case' in any of the second / ... in the second ㈣ or the second branch turtle, not composed :: 2: 3, line ^. Similarly, any second monomer present in it; m branch "Hydrocarbon, which does not form part of other hydrocarbon-associated components. ::: Any such one with a third monomer The component, the second party, the second party, the second party, the first party, and the second party will receive this part. ". Eighty percent of the participants will be served in accordance with the" reaction of each component or monomer in the total amount or proportion of one part: part. It should also pay attention to the In some cases, the total amount of other fluorene components in other comonomers can be increased above the above limit. @Need to ensure that the total amount of fluorene components in other comonomers is reduced. This increase / decrease mechanism Can be added in accordance with the rules, for example, the amount of other olefin components added to _ monomers can be the same as the reduction of other olefin components in other monomers used for polymerization, where 彳 l, r, and the total number remain the same However, in certain circumstances, it is not excluded that other olefin monomers exceed the limits shown above: the presence of ethyl acetate can also be used in Fisher • Process. However, due to the separation and purification of ethylene derived from Fisher • Process, in certain cases, polymers containing ethylene derived from Fisher • Process Ethylene does not show any difference. In addition, 'the third monomer or ingredient contains propylene or 丨 _ butene as described below and -6-this paper size applies to the national standard (CNSM ·! Specifications (2) 0 X 297 Gongai VIIW -------- Order --------- Line Φ (Please read the notes on the back before filling out this page) A7 B7 Five 'invention description (4 from Fisher-Law Law Industry The obtainable propylene is first processed so that it is substantially the same as other quotients W or butene. In this case, commercially available propylene or fluorene is produced in accordance with the present invention; the object f is in accordance with the present invention and is derived from other more In particular, according to 4: two things = show any difference. As the first component or monomer p, be "M, with ethylene monomer, and at least one species of V " associative hydrocarbon as the second component or compound, and wherein:" Hexane as the third component or monomer The comonomers are derived from Fisher's law. The second == :::, :: the second component or monomer of 'Provide-a kind of polymer', and 2: = the two and- branch: the reaction product of associating hydrocarbons or monomers:,: The third component, · method .: And at least one of the comonomers is derived. At their own expense. In addition, according to the present invention > the first ^ eighth ... m-a state, providing ethylene as

Injury or early body, disc_green eight + L body, and at least one different depleted hexane as the second component or monoTERfi. ^ Greek as a tertiary component or a terpolymer of monomer, and at least-the third component may contain-a kind of two r + .. a branch different from the two components of "the linear hydrocarbon of the tritium hydrocarbon intellectual property Bureau employee consumer cooperatives print agricultural alpha olefins or second branch alpha olefins. Molar ratio of ethylene ## Known ratio W Mole ratio of Greek hydrocarbons to different alpha olefins I = A9: 0 · 1 to 80: 2. . The best ratio of the proportion of Moles in the association to == the sum of Moto ratios of different metaphors is •… 90: 10. The molar ratio of the second group to the branch "Greek Smoke and Different Flats (The optimal ratio of the sum of the Wuer ratio is 99.9: G.u95: 5. This paper scale is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs of the People's Republic of China for printing 472064. Fifth, the invention said that in January (5) the ratio of the molar ratio of branched alpha olefins to the molar ratio of different 4 hydrocarbons may be 0.1: 99.9 to 99.9: 0. The preferred molar ratio is 莫: 99 to 99: i. The optimal ratio of the molar ratio of branched π associated hydrocarbons to the molar ratio of different 4 hydrocarbons is 2: 98 to 98: 2. 4: elsewhere 'Polymer can be by reacting ethylene in-or more reaction zones in the presence of a suitable catalyst or catalyst system, branching alpha olefins with different alpha olefins while maintaining atmospheric pressure to 5 in the anti-shame zone The pressure in the range of 0 kg / cm² and the temperature around 30 ° C. The inventors have discovered that the copolymerization of ethylene with different hydrocarbons, or the association of ethylene with at least two linear Λ-olefins The known techniques of polymerization cannot be applied or presumed to rely on the ethylene and Branched α 埽: Polymerization of a hydrocarbon as the second component and a specific linear third alpha olefin as the third component. In contrast, the inventors have surprisingly discovered that the terpolymer according to the present invention has an unexpected base The domain and / or application properties make the trimer usable in a wide range of applications. The inventors have also surprisingly discovered that according to the present invention, the trimerization of the ethyl acetate and the branched α-α ·· and third linear π dilute hydrocarbons Objects can have the same range of looseness and the same range of melt flow index, but 'may have different and surprising application properties.... More particularly, the inventors have surprisingly found that in accordance with the second aspect of the present invention, Among the broader groups of terpolymers with branched alpha olefins as the second component and linear alpha olefins as the third component, there are special populations with even more surprising application properties. For example, the inventors have found that It is obtained by the terpolymerization of linear alpha olefins and branched CV olefins with a total carbon number equal to 6 (please read the precautions on the back before filling this page). ------ Μ Τ -8-472064 A7 Warp Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the People's Republic of China. The ethylene terpolymer of the invention (6) is unexpectedly different from the linear "Hydrocarbons and Branches" of Hexacarbons by ethylene and total 6 The polymerization obtained = three: the thing: and the line through the ethylene and the total number of atoms less than 6: knife branch "three hydrocarbons obtained by the polymerization of ethylene terpolymers. The two and the inventors have been even more surprised It was found that among the three trimer groups in accordance with the present invention and branched alpha olefins as the second component and linear ρ, their tertiary polymerization is based on ethylene, total carbon atoms = 2%, and branched α 晞 hydrocarbons. The ethic group obtained by the action; the Bu ethnic group: the ethene terpolymer obtained by the polymerization of ethene, the total number of carbon atoms exceeding 6 = and the branch "Hydrocarbon tripolymerization" is the second group, and by The tertiary group of acetamidine terpolymers obtained from the tertiary polymerization of acetamidine, the total number of back atoms less than 6 ^ Xiyuan and the branched αammonium;;: A polymer group with the same characteristics is found, which has an The wide range of uncharacterized α 晞 hydrocarbons of the total carbon number is associated with unexpected properties. As expected, the nature of the individual members of San & is not proportional to the carbon number of the linear olefin. —, The properties of the terpolymers in each ethnic group and sub-ethnic group are mainly used for terpolymerization to form the dimer according to the present invention. ≫ Reward < ethylene > . The ratio of the sum of the proportions of the linear branches and 4 hydrocarbons, and the ratio of the "Hexane ratio to the linear" Hexane ratio. " The sum of the body content and the properties of the terpolymer can be changed by changing the ratio of the branched α-olefin to the ratio of the linear 4 smoke on a Mohr basis. In this way, a wide range of specific terpolymers with a wide range of application properties controlled within specific limits can be obtained. The resulting polymer is suitable for improved applications in major processing areas.聚物 of the trimer n H. _ I_I · nnnnn ^ ^ nn ^^ 1 __I 1 ^ 1 II l I ^ = 0 (Please read the notes on the back before filling this page) Line #. J .. -9- Five to seven cases

• 1 J Zhuang V order -------- 'ΜΦ, ----- y 丨 丨 (Read the precautions on the back before filling in this page) ^ ， Inventors say (; 1 includes extrusion, Blow molding and injection molding. Section d: The second state of the invention 'provides-species using ethylene as monomer, and ΐ :: species: at least-species branch: associating hydrocarbon as second component: substance., Polymerization of spring-shaped π-associated hydrocarbons as the two components or monomers of the horse ... According to the second state of the present invention, a polymer II is provided with B% as the first component or monomer branch 'as the second component or army It is called Λ, z, and y kinds of swords, and 八. Μ,-: 'to v A linear α-associated hydrocarbon is the reaction product of the second' sword milk early body. : The second state of the present invention provides-a kind of ethylene as: stray or early body, with at least _ branched α-associated hydrocarbons as the second component and at least-a linear "Hydrocarbon as the third component or monomer III. The ratio of the mole ratio of acetam to the sum of the mole ratios of branched α-olefins and other linear π-olefins can be 99 9: 0 "to 80:20. The molar ratio of ethylene is branched α-olefins and other linear α-olefins. Of The preferred ratio of the sum of the ear ratios is 99.9: 0. κ90: 10. The optimum ratio of the mole ratio of the ethylene to the sum of the mole ratios of the branched α-wall and other linear σ olefins is 99 9: 〇 ″ 95 : The molar ratio of the molar ratio of the branched alpha olefin to other linear π olefins may be .0. 丨: 99.9 to 99.9: 0.1. The molar ratio of the branched alpha olefins to other linear α olefins A preferred molar ratio is: 9 9 to 9 9: 1. The optimal molar ratio of the branched πene to the other linear pan-lean hydrocarbons is 2: 9 8 to 9 8: 2. The 10-k paper size uses the Chinese National Standard (CNS) A4 specification (2) 0 χ 297 mm Γ 472064 A7 B7 Five inventions I month (8 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs' The polymer according to the second state of the present invention can be a branched alpha olefin and a third linear alpha olefin by reacting ethylene in one or more reaction zones in the presence of a suitable t catalyst or catalyst system, at the same time in the The reaction zone is obtained by maintaining the pressure in the range of atmospheric pressure to 5000 kg / cm2 and the temperature in the surrounding area to 3. The polymer in the second state of the invention may have the following properties: a) Melt flow rate, which is measured in the range of 0 ° / 10 min according to ASTM 01238; and / or _brother b) Density, which is measured according to ASTM D1505 as C) about 0-835 to about 0950. When the hardness is plotted against its density, it conforms to the following formula: ~ c 545.4ρ -463.64 < Η < 545.4 / > -447 3 where P is The polymer density measured as above, and the hardness measured by H s imitated Ap p n n in accordance with ASTM D2240, make the formula valid in the range: 〇 < H < 60 and 0.82 < p < 0.96 is the second in the present invention. In a first specific embodiment of this state, the ash compound may be acetamidine, with 4-methyl-1_pentene as a branch, and olefins.,-Μ &物 0 Linear α. Hoofanes can be any quaternary hydrocarbon / hydrocarbons with a total number of 3 to 10 carbon atoms. This results in terpolymers with different third or linear α associations with: :: application properties Secondary group. Surprisingly, "Different people have discovered that the number of carbon atoms of a linear alpha olefin and the properties of the polymer produced are not equal to 11-This paper size applies to the Shenyang Standard (CNS) A · ! Specifications (210 X 297 mm) (Please read the notes on the back before filling this page) --------- Ί I *

1 I ---------------------- 'Grade Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 472064 A7-~ -__ B7_________ V. Description of Invention (9) Mathematical relationship. Terpolymers with 4-methyl-I-pentene as the second component and linear cubic olefins as the third component may have the following properties: a) Melt flow rate, which is measured in accordance with ASTM D1238 from 0.001 to about 1 g / 10 minute fan garden; and / or b) density, fan garden measured from about 0890 to about 0950 in accordance with ASTM 01505; and / or c) when drawing its tensile strength against its density , Which conforms to the following equation: < r > lll.lp -93.3 where P is the trimer density measured as above, and π is the yielding tensile strength measured in accordance with astm D638M. The valid range of the equation is: ; 0 and 0 · 84 < ρ <0.96; and / or d) When plotting its modulus against its density, it conforms to the following equation: E > 3636p -3090.9 where P is the density of the trimer as measured above, And E are the modulus measured according to astm D638M, and the valid range of the equation is: E > 0 and 0 · 85 < p < 0.96. In the first version of the first embodiment of the first form of the present invention, the 'dimer may be obtained by the reaction of ethylene with 4-fluorenyl-i-pentane and propylene. -12- This paper size applies to Chinese standard (CNS> A4 size (210 χ.297 mm) •, 0 4 k ---- (Please read the precautions on the back before filling in this page)

--Order ---------, M 472064 Λ7 B7 V. Description of the invention (10 Especially 'Ethylene, 4-methyl-1 -pentyl green and the following properties: Hardness impact strength (仟 Joules / square M) Drop strength (MPa) Drop elongation (%) Young's modulus (MPa) In another specific case, it may have the following: Hardness impact strength (shJ / m2) Drop strength (MPa) Drop extension ( %), Young's modulus (MPa) terpolymer of propylene may have properties of = 23 and / or = 17.6 and / or = 5.0 and / or = 7 6 and / or = 142: > 2 3 and / or > 17.6 and / or > 5.0 and / or > 76 and / or > 142 printed by " Ministry of Intellectual Property Bureau Staff Consumer Cooperatives? ^ In another specific case, it may have the following properties: Hard and good < 23 and / or impact strength (shijoules / square meter) < 17.6 and / or yield strength (MPa) < 5_0 and / or yield elongation (%) < 76 and / or Young's modulus (MPa) & lt 142 .. In the second version 4 of the first embodiment of the second state of the present invention, the trimerization product may be made of ethylene and 4-methyl-pentene and butene. Who deserves it. The terpolymer of ethylene, 4-methyl-1-pentene and butene can have the following properties: -13 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)- -II * 1 I ----- ------- Order '-------- (Please read the notes on the back before filling out this page) 472064 Λ7 B7 V. Invention: Ming ( 11 Hardness: 3 9 and / or impact strength (仟 Joules / square meter) = 3 4.1 and / or yield strength (MPa) = 8.4 and / or yield elongation (%) = 5 6 and / or Young's modulus (MPa ) = 269 In another specific case, it may have the following properties: hardness > 39 and / or impact strength (仟 Joules / square meter) > 34.1 and / or drop strength (MPa) > 8.4 and / or drop Elongation (%) > 56 and / or Young's Modulus (MPa) > 269 In another specific case, it may have the following properties hardness < 39 and / or impact strength (shJ / m2) ) ≪ 34.1 and / or reduced strength (MPa) < 8.4 and / or reduced elongation (%) < 56 and / or Young's modulus (MPa) < 269 first in the second state of the present invention Third specific embodiment Version (please read the precautions on the back before filling out this page) " Clothing -------- Order --------- Employee Cooperative of Intellectual Property Bureau of Ministry of Dust Economy The product may be obtained by the reaction of ethylene, 4-fluorenyl-1-pentene and 1-pentene. In particular, terpolymers of ethylene, 4-methyl-1 -pentene and 1-pentene can have the following properties: Hardness = 46 and / or impact strength (仟 Joules / square meter) = 4 2 and / Or -14-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 472064 A7 B7 12 V. Inventor (Drop strength (MPa) = 11_3 and / or Drop elongation (%) = 7 9 and / or Young's modulus (MPa) = 324 In another specific case, it can have the following properties: (Please read the precautions on the back before filling this page) | Installation -------- Order · --Hardness > 46 and / or impact strength (shJ / m2) > 4 2 and / or yield strength (MPa) > 11.3 and / or yield elongation (%) > 7 9 and / or Yang Modulus (MPa) > 324 In another specific case, it may have the following properties: hardness < 46 and / or impact strength (仟 Joules / square meter): < 4 2 and / or-yield strength (MPa ) < 11.3 and / or drop elongation (%) < 79 and / or 472064 A7 Β7 V. Inventory JI Month (13) Employees' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs printed Yang's mold (MPa) = 352 In another specific case, it may have the following properties: Hardness > 4 2 and / or impact strength (仟 Joules / square meter) > 3 1.8 and / or yield strength (MPa) > 8.8 And / or reduced elongation (%) > 47 and / or Young's modulus (MPa) > 352 In another specific case, it may have the following properties hardness < 4 2 and / or impact strength (仟 Joule / M 2) < 3 1 · 8 and / or yield strength (MPa) < 8.8 and / or yield elongation (%) '< 4 7 and / or .. Young's modulus (MPa) < 352 in this In the fifth version of the first embodiment of the second state of the invention, the 'dimer may be the one obtained by ethylene, 4-fluorenyl-1-pinene, and heptyl. Especially,' ethylene, 4 _Hexyl- 丨 _Pentene and 1-heptene have the following properties: The terpolymer of hardness can have .- = 58 and / or impact strength (仟 Joules / square meter) = 16.9 and / or drop strength (MPa) = 21.3 and / or reduced elongation (%) = 5 0 and / or Young's modulus (MPa) = 622 In another specific case, it may have the following properties: -16- This paper is applicable to the standard National Standards (CNS> A4 Specification (21〇χ297mm) (Please read the precautions on the back before filling out this page) * —I— ^ -o 1 Line Φ 472064 V. Inventive Use (14 Economy 郜 Wisdom Printed Hardness Impact Strength (仟 Joules / square meter) by the Consumer Property Cooperative of the Property Bureau Dropping Strength (MPa) Dropping Elongation (%) Young's Modulus (MPa) In another specific case, it can have the following hardness impact strength (仟 Joules) / M2) Drop strength (MPa) Drop elongation (%) Young's modulus (MPa) In the first embodiment of the second state of the present invention; the six-tilt version: the middle dimer can be made by ethylene , 4_ 曱 pentyl and i • Xin's reaction winner. In particular, terpolymers of ethylene, 4-methyl _ 丨 _pinene and bucinene may have the following properties: 'Hardness, phantom impact strength (仟 Joules / square meter) = 3 丨 .5 and / or Drop strength (MPa): = 7.8. And / or drop elongation (%) = 65 and / or Young's modulus (MPa) = 204. In another specific case, it may have properties below 0: hardness > 3 3 and / or impact strength (仟 Joules / square meter) > 3 丨 .5 and / or > 5 8 and / or > 16.9 and / or > 21.3 and / or > 50 and / or ' ^ Properties> 622 < 5 8 and / or < 16.9 and / or < 21.3 and / or < 50 and / or < 622 (please read the precautions on the back before filling this page) -pack ·- ------ Order --------- Line-17- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 472064 A7 B7 Employees ’Cooperatives, Bureau of Intellectual Property, Ministry of Economic Affairs印 * '1 衣 五 、 Invention £ | month (15 drop strength (MPa) drop elongation (%) Young's modulus (MPa) > 7.8 and / or > 6 5 and / or > 204 in another In specific cases, it may have the following properties: hardness < 33 and / or impact strength (charred Ears / square meter) < 3 1 _5 and / or yield strength (MPa) < 7.8 and / or yield elongation (%) < 6 5 and / or Young's modulus (MPa) < 204 In the seventh version of the first embodiment of the two states, the trimer may be obtained by the reaction of ethylene, 4-methyl-pentene, and 1-nonene. In particular, ethylene, 4- The terpolymers of fluorenyl-1 -pentene and 1-nonane may have the following properties: Hardness = 4 2 and / or impact strength (shijoules per square meter) = 38.5 and / or reduced strength (MPa) reduced elongation (%) Young's modulus (MPa) In another specific case, the hardness impact strength (shoules / square meter), drop strength (MPa), drop elongation (%) = 14.9 and / or = 90 and / or .- = 274. It can have the following properties: > 4 2 and / or > 3 8 5 and / or > 14.9 and / or > 90 and / or (please fill in the notes on the back of tf before filling out this page) ▼ and Clothing --------______ ι!, Φ -18- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 472064 A7 B7 16 V. Inventor (Yang's Modulus) (MPa) > 274 in another Under certain circumstances, it may have the following properties: Hardness < 42 and / or impact strength (仟 Joules / square meter) < 38.5 and / or drop strength (MPa) < 14_9 and / or drop elongation (%) < 90 and / or Young's Modulus (MPa) < 274 In the eighth version of the first embodiment of the second state of the present invention, the terpolymer may be 4-methyl- 1-pentene and 1-decane reaction obtained. In particular, terpolymers of ethylene, 4-fluorenyl-1 -pentene and 1-decene may have the following properties: '' Hardness = 5 and / or impact strength (仟 Joules per square meter) = 11.5 and / Or (Please read the precautions on the back before filling this page) Printed by the Ministry of Economic Affairs and Intellectual Property Bureau Consumer Co-operative Coefficient of Falling Strength (MPa) Falling Elongation (%) Young's Modulus (MPa) Hardness Impact Strength in Another Specific Situation (仟 Joules / square meter) Drop strength (MPa) Drop extension (%) Young's modulus (MPa) = 1.5 and / or = 3 4 and / or = 103 It can have the following properties:. · ≫ 5 and .7 or > 11.5 and / or > 1.5 and / or. ≫ 3 4 and / or > 103 In another specific case, it may have the following properties-19- This paper size applies Chinese national standards ( CNS) A4 specification (210x 297 mm) 472064 A7 B7 V. Inventory (17 < 5 and / or < 11.5 and / or < 1.5 and / or < 3 4 and / or < 103) Hardness impact Strength (仟 Joules / m 2) Reduced strength (MPa) Reduced elongation (%) Young's modulus (MPa) In the second specific embodiment of the second state of the present invention, The compound may be ethylene 'with 3-fluorenyl-1 · butene as the branched alpha olefin, and a linear "terpolymer of olefins. As shown above,' linear β fluorene may have a total number of 3 to 10 atoms. Any linear beta olefin, thus resulting in a tertiary sub-group of tertiary or linear π olefins with different contents and different application properties The terpolymer as the third component may have the following properties: a) the melting flow rate, which is in the range of 0 to 5 minutes in accordance with the amount of D123i0ll; and / or the soil b) density, It is measured in accordance with ASTM D1505 as a range of about 0 "; and / or Y5Z about 0.950 c) when formulating its buckled tensile strength relative to its density, the equation: & 'It meets the following consumption by the Intellectual Property Bureau staff Cooperative printed σ > 1 11.11 p -95.56 where P is the polymer density measured as above. The descent tensile strength measured by long σ D63 8M makes the formula valid according to ASTM (Τ > 0 and \ 知 固 为: (Τ > 0 and 0 · 86 < ρ < 〇.96: and / or -20-paper Scale applicable Chinese National Standards (Ci \ Ts) A4 size (210 X 297 mm) and ~ --- (please read the back issues of 1.Ϊ attention to fill out this page)

472064 A7 B7 Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4, | Agricultural Fifth, the invention said that in January (18 d), when the modulus was plotted against its density, it conformed to the following equation: E > 5555.56 p -4833.3 where P is the trimer density measured as above, and E is the modulus measured according to AST M D638M, and the range in which the equation is valid is: Ε > 0 and 0.87 < ρ < 0.96 0 in the second state of the present invention. In the first version of the two specific embodiments, the terpolymer can be obtained by reacting ethylene with 3-fluorenyl-1 -butene and propylene. In particular, terpolymers of ethylene, 3 -fluorenyl-1-butene and propylene can have the following properties: ... Hardness = 40 and / or impact strength (仟 Joules per square meter) = 3〇_ 1 and / Or yield strength (MPa) yield elongation (%) Young's modulus (MPa) hardness impact strength (仟 joules per square meter) in another specific case yield strength (MPa) yield elongation (%) Young's modulus (MPa) ) = 9.4 and / or = 37 and / or = 476 It may have the following properties: .- > 40 and / or > 30.1 and / or > 9.4 and / or > 3 7 and / or > 476 In another specific case, it may have the following properties: -21-This paper size applies Chinese National Standard (CNS) A4 (210 x 297 mm) n Ik I n «nn I t— I nnin- nn I .. nn-1 I— _ _ I (Please read the precautions on the back before filling this page) 4/2064 A7 B7 V. Invention I (19) Hardness Impact Strength (ShJ / m2) Drop Strength (MPa) F elongation (%) Young's modulus (MPa) < 40 and / or < 3 0 -1 and / or < 9.4 and / or < 37 and / or < 476 In the second state of the invention The second version of embodiment two particular embodiments, the terpolymers of ethylene may be by 3 - methyl-1-butene and trans alkenyl of Buding who should be. In particular, ethylene, 3-methyl-1-butene and 1-the following properties: hardness impact strength (仟 joules per square meter;) '. Drop strength (MPa) terpolymer of olefins can have (please read first Note on the back page, please fill in this page again) F Shengfu elongation (%) Young's modulus (MPa) In another specific case: 2 8 and / or: 22.4 and / or: 5.6 and / or: 144 and / or 199 Packing ------- Order --------- Consumer Cooperative Cooperatives 4 ,, Λ of the Intellectual Property Bureau of the Ministry of Economic Affairs may have the following properties: Hardness > 28 and / or impact strength (仟 Joules / square meter) > 22.4 and / or drop strength (MPa): > 5.6: and / or F-St elongation (%) > 144 and / or Young's modulus (MPa) > 199 in another In a specific case, it may have a hardness of below 0 _ < 2 8 and / or impact strength (仟 Joules / m 2) < 22.1 and / or 22- Chinese paper standard (CNS) A4 specification for this paper size (210 X 297 mm 472064 A7 B7 4'1 clothing printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

V. Description of the invention (2Q Drop-down strength (MPa) Drop-down elongation (%) Young's modulus (MPa) In the second embodiment of the second state of the present invention, the terpolymer may be made of ethylene and 3 -fluorene -Deserved. In particular, ethylene, 3 -fluorenyl-1-butene and the following properties: Hardness impact strength (仟 Joules / square meter) yield strength (MPa) yield elongation (%) Young's modulus ( MPa) In another specific case, it may have the following hardness Impact strength (仟 Joules / square meter) Drop strength (MPa) Drop elongation (%) Young's modulus (MPa) In another specific case, it may have the following hardness : Impact strength (仟 Joules / square meter) Drop strength (MPa) Drop elongation (%) -23- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) < 5.6 and / or < 144 and / or < 199 third version of embodiment 1-butane and 1-pentene anti-dilute terpolymer may have = 53 and / or = 47.7 and / or = 15.2. And / or = 8 3 and / or _ = 477 properties: > 5 3 and / or > 47.7 and / or > 15.2 and / or > 8 3 and / or: > 477 Properties: < 5 3 and / or < 4 7.7 and / or < 1 5.2 and / or < 8 3 and / or --- L --- i ------- clothing * --- ----- 1 ^ --------- M_ (Please read the notes on the back before filling in this page) 472064 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Young's modulus (MPa) < 477 In the fourth version of the second embodiment of the second state of the present invention, the terpolymer can be made by ethylene and 3-methyl-: 1-butene and The reaction of 1-hexene is 3. In particular, the terpolymer of ethylene, 3-methyl-1 -butene and 1-hexene may have the following properties: hardness = 1 4 and / or impact strength ( Shijoules / square meter) = 10 and / or yield strength (MPa) yield elongation (%) Young's modulus (MPa) hardness impact strength in another specific case (仟 joules per square meter) yield strength (MPa) yield elongation (%) Young's modulus (MPa) In another specific case, the hardness impact strength (平方米 Joules / square meter) F St. Volt strength (MPa) Drop elongation (%) Young's modulus (MPa) = 1.7 and / or = 7 4 and / or = 52 which may have the following properties _ > 1 4 and / or > 1 0 and / or > 1.7 and / or > 7 4 and / or > 5 2 It may have the following properties:: < 14 and / or < 1 0 And / or < 1.7 and / or < 74 and / or < 52 in the fifth version of the second specific embodiment of the second state of the present invention-24 This paper size applies Chinese National Standard (CNS ) A4 size (210 X 297 mm) (Please read the precautions on the back before filling out this page) _I _____ \ ~, ______ = 472 064 A7 5. The invention said that the dioxin in the month of (22) can be made from ethylene Obtained by reaction with 3-methyl- 丨 _ butene and 1-heptene. ~ In particular, the terpolymer of ethylene '3-methyl-1 -butene and 1-heptene can have the following properties: Hardness = 5 1 and / or impact strength (仟 Joules / square meter) = 28.3 and / Or yield strength (MPa) = 12.9 and / or yield elongation (%) 48 and / or Young's modulus (MPa) = 40. In another specific case, it can have the following properties: hardness impact strength (仟Joules / square meter) Drop strength (MPa) Drop extension (%) Young's modulus (MPa) > 5 1 and / or > 28.3 and / or > 12.9 and / or > 4 8 and / or > 406 ---, ί .------- ^ 衣 Γί # Read the notes on the back before filling in this page)

• li6JI — I Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs in another specific situation, which may have the following properties: Hardness < 5 1 and / or impact strength (仟 Joules / square meter) < 29.3 and / or Yield strength (MPa): < 12 · '· 9 and / or Yield elongation (%) < 4 8 and / or Young's modulus (MPa) < 406 Second specific implementation in the second state of the present invention In the sixth version of the example, the terpolymer can be obtained by the reaction of ethylene with 3-methyl-butene and I-octane. -25- The paper size of the table applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 472064 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The terpolymer of -methyl-1 -butene and 1-octene can have the following properties: Hardness = 49 and / or impact strength (仟 Joules / square meter) = 39.8 and / or drop strength (MPa) drop elongation (%) Young's modulus (MPa) Hardness impact strength in another specific case (仟 Joules / square meter) Drop strength (MPa) Drop yield elongation (%) Young's modulus (MPa) Hardness impact strength in another specific case (仟 Joules / square meter) Drop strength (MPa) Drop elongation (%) Young's modulus (MPa) = 9.9 and / or = 5 3 and / or = 380 It may have the following properties: > 4 9 and / Or > 3 9.8 and / or > 9.9 and / or > 5 3 and / or-> 380 which may have the following properties: < 4 9 and / or < 39.8 and / or < 9.9 and / Or < 5 3 and / or < 380 In the seventh version of the second embodiment of the second state of the present invention, the terpolymer may be made by ethylene and 3 -Methyl-l-butene and buprene reaction. In particular, terpolymers of acetamidine, 3- fluorenyl-bubutene and 1-nonene may have the following properties: -26- Paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297) (please read the precautions on the back before filling this page) 472064 A7 B7 V. Invention _ Ming (24 Hardness Impact Strength (仟 Joule / Square meter) yield strength (MPa) yield elongation (%) Young's modulus (MPa) hardness impact strength in another specific case (仟 joules per square meter) yield strength (MPa) yield elongation (%) Young's modulus ( MPa) Hardness impact strength (仟 Joules / square meter) in another specific case Drop strength (MPa) Drop elongation (%) Young's modulus (MPa) = 4 3 and / or = 24.2 and / or = 10.2 and / or = 4 1 and / or = 403 It may have the following properties: > 4 3 and / or > 24.2 and / or > 10.2 and / or > 4 1 and / or > 403 It may have the following Properties: < 4 3 and / or < 24.2 and / or & 10.2 and / or < 4 1 and / or &403; please read first. Note on the back

t Order 4 In the eighth version of the second specific embodiment of the second state of the present invention, the terpolymer may be a reaction of ethylene with 3 -fluorenyl-1 -butene and 1: -decene -Public recipients of the Ministry of Intellectual Property Bureau's Consumer Cooperatives. In particular, terpolymers of ethylene, 3-methyl-; 1-butene and decdecene may have the following properties:. Hardness = 46 and / or impact strength (仟 Joules / square meter) = 30_6 and / or 27- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 472064 Α7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs %) Young's modulus (MPa) Hardness impact strength in another specific case (仟 Joules / square meter) Falling strength (MPa) Falling elongation (%) Young's modulus (MPa) Hardness impact strength in another specific case (仟 Joules / square meter) Drop yield strength (MPa) Drop yield elongation (%) Young's modulus (MPa) = 13.3 and / or = 5 2 and / or = 347 It can have the following properties ... > 4 6 and / Or > 30.6 and / or > 13.3 and / or > 5 2 and / or > 347 which may have the following properties: < 4 6 and / or < 30.6 and / or < 13.3 and / or & lt 5 2 and / or < 347 In a third embodiment of the first state of the present invention, the polymer may be ethylene, with 4-methyl-1- Hexene is a branched π-olefin and a terpolymer of linear α-olefin. Also as shown above, linear π-associated hydrocarbons can be any linear α-olefin having a total number of 3 to 1 碟 disc atoms, thus resulting in a different third olefin. Or terpolymer subgroups with linear β-olefin content and different application properties. According to a third aspect of the present invention, an ethylene olefin is used as the first component or monomer, and at least one branched α-olefin is used as the second component or monomer, and at least one different α-olefin is used as the third component or monomer. Of polymers. -28- This paper size applies Chinese National Standard (CNS) A ·! Specifications (210 X 297 mm) (Please read the precautions on the back before filling this page) ▼ Packing ------- Order ' -------- 472064 Employee Consumption Cooperative Seal -29 Λ7 V. Description of the Invention (26 It is based on her third state, providing-a kind of polymer, B: as a component or monomer, and at least- Kind of branch ... adult 'and at least-different kinds of-associated smoke as the first: the reaction product of I /; or single hydration. This: According to the third state of the present invention, the L component or monomer is extracted, Xiao- A branched α-hydrocarbon is used as the second component, and a different type is removed. The brother cuts A Θ. The α-Hydrocarbon is the third component or monomer of the horse. According to the third state of the present invention, —A kind of polymer of two different branched α-olefins, acetamidine and magic. 3 By: Substituted with different branched alkane in accordance with the third state of the present invention: polymer hydrazone group B according to the second aspect of the present invention _ ingredients , We get-a new kind of three two: fluorene as the first =

'More surprisingly good' h ^, these trimers have even more order and therefore add to the solidity of their applications. T The inventors have surprisingly found that in this state according to the invention, Two different (specific branched polymers of the branched π 埽 hydrocarbon terpolymer family found even more surprising application properties .: olefin and the second component with a total number of carbon atoms equal to 6 ^ tri-polymerized olefin Yiyi ::: and the brother: the composition is different from ethylene and the total number of carbon atoms exceeds 6 ;: two unexpectedly and bamboo shoots = V 成 八 Φ yβ — the component branch β olefin association ... polymerization obtained by the B Like ... and straw field acetic acid and bamboo shoots with a total number of carbon atoms less than 6 _ a substance, the third component of the tri-polymerization of α 晞 hydrocarbons 彳 "blade π associated hydrocarbons and the properties of terpolymers in each group Mainly 2 ethyl cerium terpolymer. The proportion of% to the branch π 晞 I______-乙 y-The paper (CNS) A4 secret x 29 ~-

The total ratio, and the ratio of the two different fractions of olefins / 疋 α to τ, based on ethylene: the sum of the total comonomer content, Sanshui & 'sex'η by changing the two on a Mohr basis Branch ^ 晞 this way 'can be obtained with control in a specific: between the system including: (Dafanyuan specific trimer. Typical applications of trimer include 1 buckle' ρ man-made molding and injection molding.乂: The mole ratio to the first branch, and the ratio of the sum of the second branch "associated hydrocarbons 丨" may be 1 2 3: 0.1 to 80: 20. The molar ratio of ethylene to the first branch α olefin The preferred ratio of the molar ratio of the first branch to the first branch > one knife branch of α-associated hydrocarbons is 99.9: 〇 丨 to… ～, eight, .. ,, ^ ^ B Knife a _ fe and the second branch olefin m ... The optimal ratio of the knife from the ratio of the olefin to the total mol ratio is 99.9: 0.1 to 95: 5. The first ... Mole ratio of bisection "homogenous hydrocarbons. The ratio can be (M: 99.9 to 99.9: 〇 !. Chu jr ,,, ^ ν, 罘 —Mole ratio of branched π olefins to that of second branched α olefins. ... The ratio (the preferred ratio is 99 soil 99.1). The ratio of the ratio of the diole branch to the branch of the second branch α Peipei and the ear is 2: 9 8 to 9 8: 2 In particular, according to the third aspect of the present invention. &Amp; ^ ~ (Secondary compounds can be by the presence of a suitable catalyst or catalyst system, the household — 1 .. eight Shi ^ t ^-or more reaction zone reaction 2 ethyl grasshopper, spear branch π associated hydrocarbons and other chicory one-branch 々 olefins, while maintaining the reaction zone to atmospheric pressure to 5000 kg / umbrella, 3 to Then the temperature of r is obtained. The pressure and the week in the range of ^ cm are the first and third in the third state of the present invention. In the case of the polymer, the polymer may be ethylene, 4-methyl-1 -pentan Ethylene is different from the third one. It is a terpolymer of '0 green smoke. 472064 By-^ Intellectual Property Bureau Staff Consumer Cooperative Seal-Formula A7 B7 V. Invention Statement = Ming (28) So far it is generally believed that ethylene and 3 -A Polymers based on 1-pentene do not have the desired applications. However, the inventors have surprisingly found that in the polymerization of ethylene with 4-methyl-1 -pentene and 3- In the case of 1-pentene, the reaction is not only suitable, but also a polymer having excellent application properties. In the first version of the first embodiment of the third state of the present invention, the polymer may be B Trimer, terpolymer of 4-methyl-1 -pentene and 3-methyl_ 丨 _pentene. Ethylene and 4-methyl-1 -pentene as the second component and 3-methyl_ 1 _ The terpolymer of pentamidine as the third component may have the following properties: a) The dazzling flow rate, which is measured in accordance with a STMD 12 3 8 as a range of 0.001 to about 1,000 g / min for 0 minutes: and / Or b) density, which is measured in accordance with ASTM D1505 from about 0 to 890 to about 0950; _ Fanyuan; and / or c) when drawing its tensile strength against its density, it conforms to the following equation: σ > 240ρ -212.4 / 'The middle P is as above, then the density of I in the second, and π is the drop tensile strength measured according to Αττ D638M. The range that makes the equation valid is: σ > 0 and ...: 0.885 < ρ < 0.96: and / or d) When the modulus is plotted against the company and degree, it conforms to the following equation E > 700 / 0.〇6p-10500

Where p is the density of the trimer measured as above, and E is ordered according to MU I LU * ---------------- (Please read the back Note: Please fill in this page again.) 31 Form inversion 迖 闬 Chinese National Standard (CNS) A4 Specification (210 X 297 ^ 7 -----_ 472064 Λ7 07 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs " 5 、 Invention _ Ming (29 D63 8M measured modulus, the model to make the equation valid is: E > 0 and 0.9 < p <0.96; and / or e) when drawing its impact strength against its density, It conforms to the following equation: I > 150p-109 where P is the density of the trimer as measured above and I is the impact strength measured according to ASTM D25 6M. The valid range of the equation is: 1 > 20 and 0.86 < p & lt 0.943. In particular, terpolymers of ethylene, 3-methyl-1-pentene, and 4-methyl · 1-pentene can have the following properties:-Hardness impact strength (仟 Joules per square meter) Drop strength (MPa) Drop elongation (%) Young's modulus (MPa): 3 2 and / or: 2 7 and / or 4.8 and / or 5 5 and / or 272 In another specific case, it may have the following properties:Degree> 3 2 friends / or impact strength (仟 Joules / square meter) > 2 7 and / or reduced strength (MPa) > 4.8 and / or reduced elongation (%) > 5 5 and / or Young's modulus (MPa) > 272 In another specific case, it may have the following properties: -32- This paper size is based on Chinese National Standard (CNS) A4 (210 X 297 public love) (Please read the back Please fill in this page again) 472064 A7 B7 Fifth, the invention said I month (30 hardness impact strength (shJ / m2) drop strength (MPa) drop extension (. / 0) Young's modulus (Μ P a) & lt 3 2 and / or < 2 7 and / or < 4.8 and / or < 55 and / or < 272 In the second version of the third embodiment of the present invention, the polymer It may be a terpolymer by ethylene, 3-fluorenyl-butene and 4-methyl-pentene. In particular, ethylene, 3-methyl-1_pentene and 4_methyl_ 丨 _pentamidine The terpolymer can have the following properties: Hardness impact strength (仟 joules per square meter): _ Falling strength (MPa) Young's modulus (MPa) In another specific case, it can have the following properties: Degree impact strength (仟 joules per square meter) undulating strength (MPa) Young's modulus (MPa): 5 6 and / or 51.2 and / or 16.1 and / or 45 1 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs > 5 6 and / or > 51.2 and / or > 16.1 and / or.> 45Γ In another specific case, it may have the following properties: Hardness impact strength (仟 Joules / square meter) Drop strength (MPa) Young's Modulus (M P a) < 56 and / or < 51.2 and / or < 16.1 and / or < 451 I ----------- installation -------- Order ---------. (Please read the precautions on the back before filling out this page) -33 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) / 厶 WLTT 5 2. Description of the Invention (31) The Ministry of Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Affairs printed the third state of the present invention in the third state of the present invention. The polymer can be the same as the applicant. It has been found that in the ..., branch "the trimer of Greek hydrocarbons. In the polymerization of branched alpha olefins, =, ... spring-shaped alpha olefins and one other kind of cooperation, in different specific parties: the association of two kinds of branched alpha associations with specific polymers. It is even more so when used for polymerization. According to the fourth method of the present invention, this method includes the existence of a catalyst system for the production of polymers; As the first component or monomer with the co-catalyst, there are many insects; 0 The reaction zone reaction is at least B, the oxygen pressure to 5000 kg / single 4 ^ γ,. Kg / million range pressure and Ambient temperature to 300 ° C. The reaction is thus carried out in one or more reaction zones, which can be provided in a single stage reactor vessel or in a continuous two or more reactor vessel. The reaction can be carried out in a batch manner. The other branched π olefins and linear π are added simultaneously at the beginning of the reaction, while ethylene is continuously fed during the reaction and the product is not removed during the reaction. Alternatively, the reaction can be carried out in batches. Linear alpha olefins are the same as the other branched π hydrocarbons and ethylene. At the same time, continuously or discontinuously, the branched alpha olefins are added at the beginning of the reaction. Provide reaction, and do not remove the product early in the reaction and do not remove olefin or other in the reaction. In addition, the reaction can be carried out in a batch manner, linear pan _______ "3 π and ethylene in the reaction eye continuously at the beginning of the reaction Continuous addition of non-added monomers · Supplementation of non-continuous production and reverse production _ -34 ^ Paper size applies to China ^ standard (CNS > A4 specification (210 X 297 ^ ¾) 472064 A7 B7 V. Invention theory = Ming (32 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. However, the reaction can also be carried out continuously. During the reaction, ethylene is continuously added and linear alpha olefins are continuously or separately with other branched alpha olefins. Continuously added, and continuously pumped from the reaction zone ;: two products. Monohydrate 4 since this method and based on the specific feed composition and the specific reaction conditions of the polymer has mainly different The distribution determined by the reactivity of the monomers. It provides water to obtain a variety of ethylene, other branched alpha olefins and linear π hydrocarbon polymers ^ unique tools, whose properties are mainly controlled by its composition and non-uniformity. The molecular weight of the resulting polymer It can be adjusted by adding hydrogen to the reaction zone during the reaction. The greater the amount of hydrogen added, the smaller the molecular weight of the polymer. The upper t polymerization is preferably in a substantially oxygen-free and anhydrous state, and I am saturated with inert gas and It is carried out in the presence of hydrocarbons .. == In accordance with the present invention, the polymerization reaction in this state can be carried out in the charging phase and the solution phase in the vapor phase. The slurry phase polymerization is better in principle. Any suitable hydrocarbon or catalyst system D for hydrocarbons is known in the literature as heterogeneous and homogeneous, mixed with roads, complexes, units and other catalysts. However, each of the catalysts is supported or carried by The catalyst system on activated magnesium is better ° The best catalyst is specially prepared to carry the catalyst. Therefore, according to the state of the invention # .1 k for a manufacturing polymer, this method Contained in Specific Catalysts < q 4Y In the presence of a medium system, the reaction between the medium and the co-contact ~ or even in the reaction zone is at least as a component or monomer of the horse, and the alkene or olefin is used as the second component to form or or touch the gold catalyst. (Read the notes on the back and fill out this page)

v ^ i —in * ^ 1 n ^^ 1 ϋ ^^ 1 m ^^ 0 Ik. * ϋι 111 it ^^ 1 n 1 ^ 1 m UMI ^ · nm ^^ 1 1- — 1 ^ 1 I 「II : Sweat V = D s'. 35 Private paper size applicable (CNS) A4 specification

Nine 'invention said that in January (33) body, and linear β olefins as the third component or monomer, while maintaining atmospheric pressure to a pressure in the reaction zone to a pressure in the range of 5000 kg / cm2 and a temperature of ° C, the specific catalyst is obtained From: i 3 I) Suspend a part of anhydrous gasified magnesium in a highly purified hydrocarbon solvent to obtain a gasified magnesium slurry; &quot;, II) Add at least one alcohol and an ether to the slurry and stir the mixture for a period of time to obtain Part of activated magnesium carbide; ^ 0 added the alkyl aluminum compound in a dropwise manner, the resulting mixture was ground to a smooth consistency, and then cooled to room temperature to obtain activated magnesium carbide; 1 v) the activated gas was washed with a highly purified hydrocarbon solvent Magnesium to obtain cleaned activated gasified magnesium, which constitutes the catalyst support; v) Add the alcohol mixture to the cleaned support, and then stir to obtain the alcohol-supported support: vi) Four Gasification—adding an alcohol-supported support and stirring under reflux to form a mixture for a period of time to obtain a titanium-supported catalyst; and v 11) cooling and then washing the titanium-supported catalyst with a highly purified hydrocarbon solvent, followed by drying and crushing to obtain catalyst. The preferred hydrocarbon solvent is an inert saturated hydrocarbon liquid, such as an aliphatic or cycloaliphatic liquid. Most preferred are hexane and heptane. : The acid may be selected from linear ethers having a total number of carbon atoms of 8 to 16. The alcohol may be selected from the range of alcohols having 2 to 8 carbon atoms. The mixture is available at 40%. Stir at a temperature of 0 to 140 ° C for 1 to 12 hours. The calcined compound has the formula AIRm, where Rm is a group component having 1 to 10 carbon atoms. -36- This paper size applies to Zhongguanjia Standard (CNS) A4 specification ⑵〇χ 297 public hair (please read the precautions on the back before filling this page) | Printed by the Consumers 'Cooperatives of the Ministry of Economic Affairs and Intellectual Property Bureau 472064 A7 Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention _ Ming (34) According to this state of the invention— 〇 八 榀 ·, $ 个 具 姐Just examples, provide a manufacturing? fc compound 疋 法 卟 卟 卟 、 & & & & 也 ^ ^ ^ ㈣ ㈣, Γ contained in special μ media or contains specific catalysts and co-catalysts <catalyst in the presence of catalyst system ^, &amp; The main reaction zone in the Xixi area is: / Ethylene is used as the first component. From Π ::, and the line "Hydrocarbons are used as the third component or monomer, and at the same time, the atmospheric force to 5000 kg / Square meter to 30 (temperature of TC, the specific catalyst is obtained from: Force) i) Suspend part of anhydrous gasified magnesium in highly purified magnesium slurry; milk &quot;) Add at least one ether to the slurry and mix Stirring—for a period of time to obtain activated magnesium oxide: ui) filter and wash partially activated magnesium oxide with a highly purified hydrocarbon solvent until the frequency is checked in the washing solution to obtain a cleaned part of the activated gas Magnesium: 1 v) The alkyl aluminum compound is added in a dropwise manner, and then ground to a smooth degree JL and cooled to room temperature to obtain activated magnesium oxide; Aluminium alkyl was detected in the lotion to obtain the cleaned activated magnesium hydride, the composition of which was in contact with w;.. Vi) a mixture of alcohols The washed support is added and then stirred to obtain an alcohol-supported support: Vli) The alcohol-supported support is washed with a highly purified hydrocarbon solvent to obtain a clear alcohol-supported support: v Hi) Titanium tetrachloride Add the cleaned alcohol-bearing support and grind it to a thick slurry without washing to ---- pack -------- order ---------. (Please read the back first Please pay attention to this page before filling in this page) -37- This and Zhang scales are applicable to Chinese national standards (CNS> A4 specifications (210 X 297 Intellectual Property Bureau of the Ministry of Public Economics, Intellectual Property Bureau, Employee Consumption Cooperatives, India 472064 Λ7 B7) 35) smooth the consistency to obtain a titanium-containing catalyst: and i X) wash the titanium-containing catalyst with a highly purified hydrocarbon solvent until no war is detected in the washing solution to obtain the catalyst. The chemical can be partially water and can have a water content of 0.02 moles of water / one mole of magnesium fumes to 2 moles of water / one mole of magnesium fumes. A preferred smoke solvent is inert saturated Hydrocarbon liquids, such as aliphatic or cycloaliphatic liquid hydrocarbons. The most preferred are hexane and heptane. The ether may be selected from linear ethers having a total number of carbon atoms of 8 to 16. The mixture may be at 40 X : Stir to a temperature of 1 to 40 ° C for 1 to 12 hours. The slope-based chain compound may have the formula AlRm, where Rm is a group component having 1 to 10 carbon atoms. For this specific embodiment of the present invention, Aluminium alkyl compounds are chlorine-free. __ The catalyst can be pre-polymerized. For pre-polymerization, π-olefins of 2 to 8 carbon atoms are preferred. The amount of polymer produced by pre-polymerization is preferably from 1 to 500. Gram polymer / one gram catalyst range. Therefore, according to another specific embodiment of this state of the present invention, a method for manufacturing a polymer is provided. The method includes a specific catalyst or a specific catalyst and a co-catalyst. In the presence of a catalyst system, one or more reaction zones react with at least ethylene as the first component or monomer, branched π-olefins as the second component or monomer, and linear π-olefins as the third component or monomer. At the same time, the atmospheric pressure in the reaction zone is maintained to 500 Q kg / cm 2 Fan Yuan and the surrounding temperature to 300 ° C, wherein the catalyst has been π olefins with 2 to 8 carbon atoms or with 2 to 8 Prepolymerization of a mixture of carbon alpha olefins -38- The paper size is suitable for Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

472064 A7 B7 Printed by the Intellectual Property Bureau's Consumer Cooperative Cooperative, V. Invention Description_36 (36, and the amount of polymer produced by pre-polymerization is in the range of! To 5⑼g polymer / one gram of catalyst. Better For the pre-polymerization, the same monomers are used as in this method. Different pre-polymerization methods can be used. However, the best method and steps:-, 匁, 1) under inert conditions, in a closed In the container, an alkyl aluminum compound in an amount of 丨 to 〇wt% is added under stirring at about 8 (rc to add a highly purified hydrocarbon to obtain a liquid mixture: 'Corn flakes ii') in an amount of 0.1-1 wt% The catalyst is added to the liquid mixture: iii) less than 0-5 wt% of hydrogen is added to the closed container: iv) the monomers are co-reacted separately or as the mixture is successively obtained until the second polymer / catalyst is obtained. The required weight of the proportion is increased; and 'v) the prepolymerized catalyst formed is filtered and washed with a hydrocarbon solvent, followed by another filtration step and its subsequent drying. For gas phase processes, the catalyst is usually prepolymerized or supported. The best pre-polymerization cooperation is performed with the same monomers reacted in this way. Optimum support = terpolymer powder with the same composition as the terpolymer obtained in the dimerization, and this support is treated with the same fluorinated aluminum as the cosupport in the trimerization. ^ When the catalyst prepared according to the present invention is used for trimerization, a co-catalyst can be used. The preferred co-catalyst has the formula A1Rm, in which the claw is a component of a group having carbon atoms. ^ For solution polymerization, choose the method temperature and solution to make the trimer-39 This paper size is applicable to China National Standard (CNTS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page ) ▼ Packing -------- Order --------- A7 B7 V. Invention (37 'trimerized compound is completely soluble in the selected solvent. The above is used in accordance with this Inventors of this kind of terpolymerization can be obtained at their own expense. · Cloth "7" 3 "Method" However, as mentioned above, any other polymer-grade olefin monomer from "7" can be used instead One or more hydrocarbon-associating monomers derived from Fisher's law. Therefore, in a specific embodiment of this state of the present invention, ethylene can be obtained from Fisher's law. However, as shown previously, Fisher: A method of processing involved in manufacturing, isolation and purification, in some N-shaped, polymers containing ethene derived from Fisher's method are not shown for polymers containing ethylene obtained from conventional methods Any difference. In another embodiment of this state of the invention, Born from Fisher's method. Almost all known with practical applications, hydrocarbons can be obtained from Fisher's method. However, the preferred branch "olefins are: those with 4 to 10 carbon numbers. The best ones are The farthest end of the opposite double bond has eight branches #. These cottons may contain small amounts of other fluorenes. The best branched olefins are 3-methyl-1, butane, 4-methyl_ 丨 _pentenyl -1-hexene and 3-methyl-1-pentene. 4-methylhexene and 3 • fluorenyl '1- 戍 fefi; Kun compound is also better β 绖 &quot;-Intellectual Property Bureau employees Printed by a consumer cooperative in another specific embodiment of this state of the invention, &amp; .ρ ,,,,, ', or shape-associated hydrocarbons can be obtained from Fisher's method. A typical example of this linear π-olefin is propylene. Cockroach, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonyl and 1-decene: preferred examples of this olefin have 3 to 9 carbon numbers And the best one has 4 to 8 carbon numbers. As mentioned above, these olefins may contain a small amount and &lt; other hydrocarbon content = -40- this paper 掁 standard applies to China National Standard (CNS) A4 specifications ( 210 χ 297 public love) 4 / ZUD4 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. The invention said: Ming (38. In the different state of the present invention as the second, a typical example of the olefin derived from the first method is the Fisher Fisher of the ingredients. Generally, as described above, the state of the second and the second lies in it. Therefore, in the present invention, the content of the second and / or third components in the present invention is the second component and / or the third component. 0.002% to 2% of the other hydrocarbon-associated components of fragrant fragrant. In the present invention, the second component and / or the third component can be different-a specific implementation of your linene ene 栌 Shiba I contains 0. 〇2% to 2% mass ratio of φ, μ _ on: another implementation of this &amp; state furnace and / or second component may contain 0.2% to 2% mass ratio of its first part: in the present In another specific embodiment of this state of the invention, the trowel or small-component may contain 0.20 /. If it exceeds 2% by mass, its condition is' in the condition that, in the case where other rhenium is present in an amount exceeding 2% by mass = person. When it is seeded into bismuth, it exists proportionally in an amount below 2% by mass Among other ingredients. Naturally, if smaller amounts of other hydrocarbon-associated components are required, they can be present in other components. Typical examples of other olefin components include • Propylene, which has a total hydrocarbon content of Q5% and mainly contains: -2-fluorenyl] -butene-0.46% Non- ¥ Low proportion of branched olefins with 5 carbon atoms $ LOW RATIO is a cyclic olefin with an internal olefin ratio of 5 carbons and a cyclic olefin with 5 last numbers-a very low ratio of two 埽 1-hexane, the other olefin components mainly include: 刀 支 埽 工, which Mainly has 6 carbon numbers _ 〇. 5 1% ----- ----------- installed -------- order --------- (please first (Read the notes on the back and fill out this page)

472064 A7 V. Invention description = Ming (39 Printed by the Consumer Intellectual Property Agency of the Intellectual Property Bureau • Internal olefins, the king of which has a carbon number of -0.18% _Cyclic olefins, which mainly has a carbon number of -0.13%- Very low proportion of bis; ^ • heptene, other hydrocarbon-associated components mainly include:-branched fluorene, which mainly has 7 carbon numbers _〇48% _ internal olefins, which mainly has 7 carbon numbers-0.53% • 1-octene, other olefin components mainly include:-branched olefins M, which mainly have 8 carbon numbers _〇41%-internal olefins, whose kings have 8 carbon numbers _〇83% • 1-nonene, other The olefin component mainly includes ··· Blade, which mainly has 9 carbon numbers _〇.650 / 〇- internal olefin, which mainly has 9 carbon numbers _〇51% = · j-曱 基 _ 丨 _ 丁And other hydrocarbon-associated components mainly include a mixture of endo-fe-0.03%, and a very low amount of two mixtures of Shaw • 4-methylpropanthine and 3-methyl-propanthine, and All other olefin components (2〇 / 0) mainly contain 2,3_dimethyl_ 丨 _ butene: dimethyl_1-pentyl, of which all other fluorene components are 2%, and Wang wants to contain 3 -曱-丨 -Pentene 乂: While 'these typical examples do not exclude other hydrocarbon formation conditions, the monomer meets the restrictions on the total content of the ingredients as described above. When the third monomer or ingredient contains propylene or is derived from Fisher's law, it is first processed so that '&quot; and v * w,', N, and other commercially available I I know or 1-ding is substantially the same 'in In this case, I have ridiculed C ...., invented and derived 4 carbon atoms • ------------ installation ------- order * -------- (Please read the precautions on the back before filling out this page) —___________- 42-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 public reply 472064 A7) V. Inventor · Ming (40 II: Concluding or Polymers of 1-butene do not show any difference with respect to «available propionate or budding polymers in accordance with the present invention. Other examples are derived from other conditions that are busy in this state of the present invention. Copolymerized with 4 to -1 -pentene as a branched alpha olefin and linear "olefins". The fluorene / linear alpha olefin may be any olefin having a total carbon number of 3 to 10, thus making The specific method version of the subgroup is different from the third and second, that is, the linear sigma olefin used. The knife, the first version of this specific embodiment in this state of the present invention, the second monomer is the third woman. I am here, the second version of this specific embodiment of the present invention in the second version of the beta early body is 1-Ding. I am in the third version of this embodiment of the present invention in this third embodiment :, M _The second early body is 1-pentamidine '. In the fourth version of this specific embodiment of this state of the present invention, the second early body is 1-dihedral. ‘One in. In a fifth version of this specific embodiment of this state of the invention, the di-early body is 1-heptene. The sixth version of this specific embodiment in this state of the invention is two-early body. In a seventh version of this specific embodiment of this state of the present invention, the di-body is 1-nonyl. + In the eighth version of this specific practical example of this state of the invention, the second early body is 1-decanoate. In another specific embodiment of this state of the present invention, ethylene can be installed with 3 paper sizes _ tiT Home Standard (CNS) A4 specifications ⑵〇ί n, ί ------------ -------- Order ---------. (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs 43 Printed by the cooperative 472064 A7 B7 V. Invention (1) Methyl-I-butadiene as a branched alpha-hydrocarbon and linear (co-polymerization). Linear alpha olefins can have a total number of carbon atoms of 3 to 10 Any linear alpha olefin, which results in a specific method version of the subgroup, is different from the third component, that is, the linear associative hydrocarbon used. In the first version of this specific embodiment of this state of the invention, the The tri-monomer is propylene. In the second version of this embodiment of this state of the invention, the third monomer is 1-butene. The third of this embodiment of this state of the invention In the version, the third monomer is 1-pentamidine. In the fourth version of this embodiment of this state of the invention, the third monomer is 1-hexene. In a fifth version of this specific embodiment of this state of the invention, the third monomer is 1-heptene. In a sixth version of this specific embodiment of this state of the invention, the third monomer is Is 1-octene. In the seventh version of this embodiment of this state of the invention, the third monomer is 1-nonene. The eighth version of this embodiment of this state of the invention 'In this case, the third monomer is I-decane. According to a fifth state of the present invention, a method for manufacturing a trimer is provided. The method includes a specific catalyst or a catalyst containing a specific catalyst and a co-catalyst. In the presence of a media system, ethylene, the first branched α-olefin, and the second different branched π-olefin are reacted in one or more reaction zones, while maintaining in the reaction zone -44- This paper applies Chinese National Standards (CNS) A4 specifications (210x 297 mm) (Please read the precautions on the back before filling out this page) &quot; Clothing ----------- Order ------ 472064 A7 ________ B7 V. Invention _ Ming (42 ) Pressure in the range of atmospheric pressure to 5000 kg / cm² and temperature in the surroundings to 300. " It is carried out in one or more reaction zones, which can be provided in a single-stage reactor vessel or two or more reactor vessels in a row. Therefore, as shown in the fourth aspect of the present invention, the reaction can be carried out in batches. The first branch alpha olefin and the second branch alpha olefin are added simultaneously at the beginning of the reaction, and ethylene is continuously added with A during the reaction, and the product is not removed during the reaction. Alternatively, the reaction can be performed in a batch manner. One-shot alpha olefins are continuous and non-stop during the reaction at the same time as the second branch alpha olefins and ethylene ... and the product is not removed during the reaction. In addition, the reaction can be performed in a batch manner, the first branch ϋ! Or the second branch 4 hydrocarbons are added at the beginning of the reaction '@ethene is continuously added during the reaction, providing continuous or * unadded monomers at the beginning of the reaction It is continuously supplied without removing the product during the reaction. The reaction can also be carried out in a continuous manner. During the reaction, acetylene is added and the first branch α-olefin is added continuously or discontinuously together with the second branch "olefin, or separately, and continuously from the reaction zone. The terpolymer product is extracted.

I # The Ministry of Economic Affairs. ¾ Printed by the Consumers ’Cooperative of the Property Bureau 'in self-combat…, the method of this state of the invention and based on the specific feed composition, the terpolymer with special reaction conditions has mainly different orders. The bulk reactivity is decisive. The reaction rate of the distributed 'branched alpha olefins is usually lower than its corresponding linear shape. It provides a unique tool for obtaining a variety of ethylene, first branched "olefins and knife branch alpha olefin dimers. The properties are mainly controlled by its composition and non-uniformity. L --- -45- Ben · ⑵Q χ 297 Publication) 472064 A7 B7 43 5. The invention is congratulated (the molecular weight of the random dimer can be determined by the reaction Adjust the chlorine addition in the reaction zone. The larger the amount of hydrogen added, the smaller the molecular weight of the random trimer. The terpolymerization is preferably in a substantially oxygen-free and anhydrous state, and in the presence or absence of inert saturated hydrocarbons The terpolymerization reaction in this state according to the present invention can also be carried out in the slurry phase, the solution phase or the steam phase, and the slurry phase polymerization is preferred. In principle, at least any suitable copolymerized ethylene and olefin can be used. Touch Catalyst or catalyst system. It is known in the literature as heterogeneous _ nano, mainly chromium, metal complex 'units and other catalyst forms of catalysts. However, titanium catalysts are supported or supported on activated magnesium The catalyst system is better. The best catalysts are two kinds of titanium catalysts specially prepared according to the fourth state of the present invention, which are carried on special activated gaseous magnesium. A catalyst manufacturing method is also preferred. Therefore, according to a specific embodiment of this state of the present invention, a method for cracking a polymer is provided. This method includes a specific catalyst or a catalyst containing a specific catalyst and a co-catalyst. In the presence of the media system, one or more reaction zones should use ethylene as the first component or monomer, and branch 0 as the second component or monomer. The third component or monomer, while maintaining atmospheric pressure in the reaction zone to 5,000 kg: / square. The pressure of the centimeter and the surrounding temperature to 30 (rC, the specific catalyst is obtained from: knife 巳 s 将 suspend part of anhydrous magnesium chloride Advanced Purification of Hydrocarbon Solvents for Gasification Money: ii ) At least one ether is added to the slurry and the mixture is stirred for a period of time. Partially activated magnesium carbide; ′ -46 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297)

It .---------- # 装 -------- Order --------- (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Employees consume the printing room of the cooperative to get 472064 Λ7 B7 V. Inventive gas in May (44 iii) Wash a part of the activated magnesium slurry with a highly purified hydrocarbon solvent until no acid is detected in the washing liquid to obtain The partially cleaned activated magnesium iv) was added dropwise with stirring, and cooled to room temperature to obtain activated gasification money; v) the activated gasification ball was washed with a solvent by highly purified, Until no alkyl aluminum is detected in the washing solution to obtain the cleaned activated magnesium hydride, which constitutes the catalyst support: V i) Add the alcohol mixture to the cleaned target, slowly search and mix, To obtain an alcohol-supported support; vii) wash the alcohol-supported support at a degree of pH / cereal to obtain a cleaned alcohol-supported support: viii) add titanium tetragas to the cleaned alcohol-supported support Support, and grind it to a smooth consistency to obtain titanium-supported catalysts: and i X) purify the soot-solvent catalyst thoroughly with a degree of purified soda solvent until No titanium was detected in the lotion to obtain the catalyst. Magnesium fumes can be partially dehydrated and can have 0.02 Moore water / 丨 _Moore magnesium to 2 Moore water / 1-Moore magnesium water content 3 The preferred hydrocarbon solvent is inert Saturated hydrocarbon liquids, such as aliphatic or cycloaliphatic liquid base hydrocarbons. Best for kiln and Geng Yuan. 'The Ministry of Economic Affairs and Intellectual Property Bureau's Consumer Cooperatives Ethers can be selected from linear drums with a total of 8 to 16 carbon atoms. The mixture can be stirred at a temperature of 40 ° C to 140 ° C. The alkylaluminum compound may have the formula A1Rm, where Rm has a radical component of 至 to t0 carbon atoms. The reaction characteristic is no gas during the reaction. In addition, according to the method described in the fourth state of the present invention, the catalyst can be pre -__________- 47- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 Mm) 472064 A7 B7 45 V. Invention% (Polymerization. Fti first read the notes on the back before filling out this page) For gas phase trimerization, you can use support catalyst or prepolymerized ballast. Prepolymerized catalyst can be as above. As described. The most preferred support is a trimer powder having the same composition as the trimer obtained in trimer octal f, which is treated with the same alkylaluminum as a co-supporter in trimerization. When the catalyst prepared according to the present invention is used for terpolymerization, a co-catalyst may be used. The preferred co-catalyst has the formula A1 Rm, where R m is a base component with i to 10 carbon atoms. For solution polymerization, the temperature and solution of the method are selected so that the trimer is completely soluble during the trimerization The selected solvent. As described above in accordance with the fourth state of the present invention, the fluorene monomer used for the terpolymerization of the state according to the present invention can also be obtained from the Fisher method. However, as described above, any other Other polymer-grade olefin monomers of the process replace one or more of the hydrocarbon monomers obtained from the Fisher-Law process: Therefore, in a general example of this state of the invention, ethylene as the first monomer is available Since Fisher Fisherman. As mentioned above regarding the fourth state of the present invention 'In another embodiment of this state of the present invention, the first branch can be obtained from Fisher-manipulator. ::: Economic and Intellectual Property Bureau Employees Consumer Cooperatives ^ The preferred branch olefins are 3-methyl-1 -butene and 4-methyl-1 -pentene. However, the combination of 4-methyl-1 -hexanoyl and 3-fluorenyl-1 -pentanyl is optimal: In another specific embodiment of this state of the invention, both branched olefins are available Since Fisher Fisherman. The preferred embodiment of this olefin has 4 to 9 digits. -48- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 472064 Printed by A7 B7 of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Inventive note · 46 A typical example of the ethylene derived from the Fischer-Tropsch process is as described above with respect to the fourth aspect of the present invention. An additional example suitable for olefins is (based on the mass of 1%): '1-1 mixture of 4-methyl-1 -pentene and 3-methyl-1 -pinene, which has a mass ratio of 2% all Other dazzling ingredients. In another specific embodiment of this state of the present invention, ethylene may copolymerize 4-methyl-1 -pentene as the first branch "olefin or second comonomer component and a different second branch α-olefin as The third comonomer component. In the first version of this specific embodiment of this state of the invention, the third monomer may be 3 -fluorenyl-1 -butene. In the second version of this specific embodiment of this state of the invention, the third monomer may be 4 -fluorenyl-1 · hexene. ^ 一 _ In the third version of this specific embodiment of this state of the invention, the third monomer may be 3-methyl-pentazone. In another embodiment of this state of the present invention, ethylene may copolymerize 3-methyl-1 -butene as the first branched associative hydrocarbon or the second monomer component and the second different branched olefin or the third co-polymer. Single ingredient. Applicants have also surprisingly discovered that trimerization can be achieved by using one or two $ monomers as the reaction medium and introducing ethylene into the reaction medium containing the two co-monomers, or including a third monomer The reaction medium was carried out using ethylene and a second co-monomer. Therefore, according to the sixth state of the present invention, _ a kind of polymerization in the polymerization reaction &amp; ethylene as the first monomer and the second branch monomer and the third monomer is provided, wherein at least- Kinds of co-monomers are used as reaction mediators ____ -49- This paper size is applicable to China @ 家 standard (CNS) A4 specifications ⑵Q χ 297 public compound----- ------- installation -------- Order ---------. Γ Please read the precautions on the back before filling in this page} 472064 A7 B7 Printing of clothing by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs . Therefore, according to the sixth state of the present invention, at least one comonomer is used as a reaction medium or solvent. The heat of reaction can be removed by using conventional heat exchange equipment, such as cooling enclosures or cooling coils. However, the preferred method is to utilize the heat of evaporation of the monomeric reaction medium. Therefore, a controlled amount of the reaction medium monomer can be evaporated, cooled externally in the heat exchanger, and returned to the reaction vessel. According to a specific embodiment of this state of the present invention, a monomer is used as a reaction medium. According to a second specific lean embodiment of this state of the invention, a mixture of comonomers is used as a reaction medium. Λ According to the present invention, the comonomers used in this state may be selected from the ones described in the fourth and fifth states of the present invention. In a specific embodiment of this state & Ethylene is used as the first single fla reaction branched olefin as the second monomer and linear alpha olefin as the co-monomer.-In a version of this specific embodiment of this state of the invention, the branched monomer may be the reaction medium or solvent In another version of this embodiment of the present invention, the linear monomer may be a reaction medium or a solvent. In another version of this embodiment of the present invention, the linear monomer is Both the branched monomer and the branched monomer can be the reaction medium or solvent: &quot; In another embodiment of this state of the present invention, acetamidine is used as the Yin-one monomer to react the branched β-olefin as the second co-monomer and another branched hydrocarbon As a third co-monomer. ________________ 50-This paper is in accordance with the national standard (CNS) a4 specification "(210---(Please read the precautions on the back before filling this page) -------- Order · ----- Φ. 4/2064

In one version of this specific embodiment of this state of the present invention, the ~~ th branch monomer may be a reaction medium or a solvent. In another version of this embodiment of this state of the invention, the third branch monomer may be a reaction medium or a solvent. In another version of this specific embodiment of this state of the invention, both knife and knife monomers can be reaction media or dissolution profiles. The invention is now further described by the following non-limiting examples. It has been indicated in the examples that the monomers are derived from the Fisher-Kill method. All monomers not indicated to be derived from the Fisher-Henry method have a so-called polymerization grade, i.e., the highest peak 'is as defined by Fine Chemical's Aldrich Catelog Handbook. These polymer-grade monomers are commercially obtained or processed from Fisher-Thorium monomers. In the example, the percentage of other olefin components present in the second and / or third component is expressed on a mass basis. Example In a 250 ml flask equipped with a reflux condenser and a stirring device, 4 g of anhydrous gasified magnesium having a water content of 1.5% was suspended in 60 ml of highly purified heptane. However, 2 ml of ethanol and 1.4 ml of dibutyl ether were added, and the mixture was stirred for 3 hours. 90 ml of a 10% triethylaluminum and heptane solution was added dropwise to the flask to avoid excessive heat build-up. The resulting mixture was ground to a smooth network and cooled to room temperature with stirring. The resulting slurry was then subjected to twelve washes, each using 50 ml of heptane. To the activated support thus formed was added 2 ml of ethanol, an i: ii molar mixture of 3 _fluorenyl_ i • butanol and 2-methylpentanol, and a slurry -51 was produced-this paper is applicable to China Standard (CNS) A4 specification (210 X 297 mm) (碕 Please read the precautions on the back before filling this page) One binding --------- Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 4/2064

Printed by the Economic and Intellectual Property Bureau's Consumer Cooperatives V. Invention Statement = Ming (49) 3 hours. Then, 20 ml of TiCU was added to 100 ml of Gengxuan 'and the mixture was stirred under reflux for 60 minutes. After cooling, the slurry was washed ten times, using 50 ml of heptane each time. After final cleaning, the slurry is dried and crushed to produce a pale yellow powdery catalyst. Example 2 300 grams of highly purified n-heptane was introduced into a 1 liter stainless steel polymerization vessel equipped with a stirrer. After the container was completely flushed with nitrogen, 10 ml of triethylaluminum (a 10% solution in heptane), and 0.1 g of Catalyst A were introduced into the container. The temperature was set at 85 ° C and 200 mg of hydrogen was introduced into the container. After 5 minutes, simultaneous supply of acetam at a continuous flow rate of 10 g / min and 3-methyl-1-butene and 1-pentene at a 1: 1 mass mixture were started simultaneously. The monomer feed stopped after 10 minutes and the reaction continued for 1 hour. -. During this reaction, the polymerization vessel was depressurized and the catalyst was decomposed with isopropanol. The resulting copolymer was then filtered and repeatedly washed with propanol and acetone. The terpolymer was dried in an air oven at 70 ° C for 24 hours. The yield of terpolymer was 92 grams. The measured terpolymer properties are as follows: MFI is 1 dg / min, which is measured in accordance with ASTM D1238. The density was 0.932 g / cc 'which was measured in accordance with ASTMD 1505. The hardness is 5 3, which is measured in accordance with ASTM D2240. The yielding tensile strength is 15.2 MPa, which is measured in accordance with ASTM D638M. The yielding elongation is 83%, which is measured according to aSTM D638M. The modulus is 477 MPa, which is measured in accordance with ASTM P638M. The indentation Izod impact strength is 47 7 仟 Joules / square meter, which is based on 8 5 d 1 ^ 2 5 6; the amount. -52 · Loading -------- Order --------- (Please read the Jiang Yi matters on the back before filling this page) This paper size is applicable to China National Standard (cns) A4 specifications ( 2if 297 mm) 472064 A7 B7 50 V. Inventory (Composition: 2.5%. In other examples below, various properties were measured using the same ASTM method as used in Example 2. The composition was polymerized The sum of mole% of comonomers in the material is expressed as determined by C13 NMR. — 其他 In your other examples shown by F, the composition also uses mole% of comonomers 矣-, Η 夭 /. No, as determined by C1) NMR. Example 3 After the vessel was completely flushed with nitrogen, 300 g of a 99: 1 (based on mass) mixture of 3: methylbutane and 4 • methyl_1-pentene was introduced into a ^ liter stainless steel polymerization vessel equipped with a stirrer. in. 10 ml. Diethylaluminum urophyllum (a 10% solution in an alkane) 'and 0.1 g of the catalyst were introduced to Cryo +, w .. The mixture was set to a medium temperature of 85 °. (:, And 200 耄 of hydrogen was introduced into the container.…, Τ. 5 knives and 1 mile, began to supply acetam with a continuous flow rate of 10 g / min. The monomer is also _ k, η β β 4 into 10 It stopped after minutes and the reaction lasted for 1 hour. During this reaction, the polymerization was difficult, FI., U7 r 1 •, K. Valley pressure was depressurized and the catalyst was decomposed with isopropanol. The resulting copolymer was then filtered and treated with Propanol and acetone were repeatedly washed. Three were dried in an air oven at 70 ° C for 24 hours. The properties of the terpolymer were measured as follows: Yield (g) Density (g / cc) MFI (dg / min) Hardness Impact Strength (仟Joules / square meter) Drop strength (MPa) Drop extension (./) -53- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) IU, --- i ----- -# 装 -------- Order --------- (Please read the note on the back? Matters before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 80 0.9195 2.1 56 5 1.2 16.1 ~ 2U64 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 99 0.9158 0.2 4 8 47:25 10.7 88 297 2.76 V. The Invention J month (51 Yang's Number (MPa): 451 Composition: 2 f Example 4 After the container was completely rinsed with nitrogen, 300 g of 3-methyl-1 -butene and 4 -fluorenyl-1-pentamidine were 50:50 ( Based on mass) the mixture was introduced into a 1 liter stainless steel polymerization vessel equipped with a stirrer. 10 milliliters of triethylaluminum (10% falling in heptane) and 0.1 g of catalyst A were introduced into the vessel. The temperature was set It was 8 5 C and 200 mg of oxygen was introduced into the container. After 5 minutes, supply of ethylene at a continuous flow rate of 10 g / min was started. The monomer feed stopped after 10 minutes and the reaction continued for 1 hour. During this reaction Depressurize the polymerization vessel and decompose the catalyst with isopropanol. The resulting copolymer is then filtered and repeatedly washed with propanol and acetone. Terpolymer: Dry in an oven at 70 ° C for 24 hours. Measurement 3 The properties of the polymer are as follows: Yield (g) Density (g / cc) MFI (dg / min) Hardness Impact Strength (仟 Joules / m 2) Drop Strength (MPa) Drop Elongation (%) Young's Modulus (MPa) Composition (Mole%) Example 5 IU. Packing -------- Order --------- (Please read the precautions on the back before filling this page ) 54- 472064 A7 B7 52 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 72 0.923 1.3 46 4 2 .. 11.3 79 324 4.08 V. Invented (in a 1,000 ml stainless steel autoclave completely flushed with high purity nitrogen 300 grams of purified heptane was added and the temperature was set to 85 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of diethylaluminum in heptane is added and stirred for 5 minutes to reflect residual impurities in the system. To this solution was added 0 gram of catalyst eight and 40 milligrams of hydrogen. Then began the following supply to the autoclave: 丨 ethylene with a continuous flow rate of 1 g / min, and renyl-1 with a continuous flow rate of 0.3 g / min. Pentene (also containing 0 · 0 1% of 3-methyl-1 -Pentene) and a 50:50 (mass-based) mixture of 1-pentene (also containing 4-% 2-methyl-butene), both monomers were obtained from the Fisher-Ki method. These supplies continued until 100 grams of ethylene had been added. The flow of ethylene with other co-monomers was then stopped, and the reaction continued for another 20 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured = its chemical index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g) Density (g / cc) M FI (dg / min) Hardness Impact Strength (shJ / m2) Drop Strength (MPa) Drop Elongation (%) Young's Modulus (MPa) Combination (Moore%) Shidian 6 55- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) IV .--------- I ---- ---- Order * -------- &lt; Please read the notes on the back before filling out this page) Printed by the Consumers 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs *' ^ 472064 A7 B7 V. Inventory J month (53) 300 grams The highly purified n-heptane was introduced into a 1 liter stainless steel polymerization vessel equipped with a stirrer. After the container was completely flushed with nitrogen, 10 ml of triethylamine (a 10% solution in heptane), and 0.1 g of Catalyst A were introduced into the container. The temperature was set to 8 5 X: and 200 mg of hydrogen was introduced into the container. After 5 minutes, simultaneous supply of ethylene at a continuous flow rate of 10 g / min and 4-methyl-1 -pentene and 1-pentene at a continuous flow rate of 4 g / min]: 1 (based on mass) mixture was started. The monomer feed stopped after 10 minutes and the reaction lasted for 1 hour = During this reaction, the polymerization vessel was depressurized and the catalyst was decomposed with isopropanol. The resulting copolymer was then filtered and repeatedly washed with propanol and acetone. The terpolymer was dried in an oven at 70 ° C for 24 hours. The measured terpolymer properties are as follows: Yield (g): 82 Density (g / c C): 0.918 MFI (dg / min): 0.4 Young's Modulus (MPa): 320 Composition (Moore./): 4.99 Example 7 300 grams of highly purified n-heptane was introduced into a liter stainless steel polymerization vessel equipped with a stirrer. After the container was completely flushed with nitrogen, 10 ml of triethylaluminum (10% solution in heptane) and 0.1 g of Catalyst A were introduced into the container. The temperature was set at 85 ° C and 200 mg of hydrogen was introduced into the container. After 5 minutes, simultaneous supply of ethylene at a continuous flow rate of 10 g / min and 3-methyl-1 -pentene and 4-methyl-1 -pentene at a continuous flow rate of 1: 1 (based on 1 to 1 (based on Mass) mixture. The monomer feed stopped after 10 minutes and lasted for 1 hour. -56- This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) -Packing -------- Order --- A7

472064 Fifth, the invention = Ming (54) During this reaction, the polymerization vessel was depressurized and the catalyst was decomposed with isopropanol. The resulting co-hydrate was then filtered and washed repeatedly with propanol and acetone. The terpolymer was dried in an oven at 70C for 24 hours. The properties of the terpolymer measured are as follows: Yield (g): 92 Density (g / CC): 0.9185 MFI (dg / min) ·· 5 Hardness: 4 6 Impact strength (仟 Joules / m 2): 39.6 Dropping strength P a): 10.3 Elongation (%): 6 1 Young's Modulus (MPa): 336 Composition (mol%): 6.44 Example 8 A 1000 ml stainless steel autoclave completely flushed with high purity nitrogen 300 grams of purified heptane was added and the temperature was set to 85C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect residual impurities in the system. To this solution, 0.1 g of Catalyst A and 35 mg of hydrogen were added. Then the following supply to the autoclave was started: 1. · g / min continuous flow rate of ethylene and 0.4 g / min continuous flow rate of 4-methyl-1_pentene and 3-methyl-1_pentene 5 0: 5 0 (based on mass) mixture. These supplies continued until 1000 grams of acetam had been added. Then the flow of acetamidine with other comonomers was stopped and the reaction continued for another 20 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The material produced by the process is C-57- This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm). ---. (Please read the notes on the back before filling out this page) Economy ^-Printed by the Intellectual Property Bureau Staff Consumer Cooperative

Ketone M was washed and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The obtained results are as follows: Yield (g): 75 Density (g / cc): 0.925 MFI (dg / min): 1.8 Hardness: 50 Impact strength (仟 Joules / square meter): 41.9 Drop strength (MPa): 12.1 Drop extension (%): 84 Young's modulus (MPa): 338 Example 9 Preparation of catalyst B = 20 g of anhydrous gas with a water content of 1.5% in a 250 ml flask equipped with a reflux condenser and a stirring device Magnesium chloride was suspended in 50 ml of highly purified heptane. However, 40 ml of dipentyl ether was added, and the resulting slurry was refluxed for 3 hours. The slurry was then filtered and washed with heptane until no ether was detected in the washings. The solid substance thus obtained was stirred in 100 ml of triethylamine in the presence of a 10% solution of heptane for 24 hours, ground to a smooth degree and then washed with heptane until no detectable substance was detected in the washing solution Triethyl Add 200 ml of ethanol and 3- (1-Methyl) -1-butanol in a 1: 1 (based on mole) mixture, stir the mixture for 3 days and then wash it again 10 times, using 100 ml of heptane each time: This material was ground in the presence of 150 ml of TiCl4 and 100 ml of heptane at room temperature until a smooth consistency solid was obtained. Increase the temperature to 丨 〇〇 and incubate for 1 hour ', then it is cooled and washed with heptane until no detection in the lotion. (Please read the precautions on the back before filling out this page) -------- Order · -------- · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs * 1 472 064 A7 ---- ---_ B7____ V. Invention 1¾: Ming (56) to TiCl4. Example 10 Preparation of Catalyst C In a 250 ml flask equipped with a reflux condenser and a stirring device, 20 g of anhydrous vaporized magnesium having a water content of 1.5% was suspended in mo ml of highly purified heptane. Then, 40 ml of diethyl ether was added, and the resulting slurry was refluxed for 3 hours. The slurry was then filtered and washed with heptane until no acid was detected in the wash. The solid matter thus obtained was stirred in 100 ml of triethyl aluminum in the presence of a 10% solution of heptane for 24 hours, filtered, and then washed with heptane until no triethylaluminum was detected in the washing solution. Add 200 ml of a 1: 1 (based on mole) mixture of ethanol and 2-methyl-1 -pentanol. Stir the mixture for 3 times and wash again for 10 times. . This material was ground in the presence of 150 ml of TiCh and 100 ml of heptane at room temperature until a smooth consistency solid was obtained. The temperature was increased to 1000 and stirred for 1 hour, then it was cooled and washed with heptane until no Tic 14 was detected in the washing solution. A steel autoclave was charged with 350 grams of purified heptane and the temperature was set at 80 ° C. When the correct temperature has been reached, add 10 ml of triethylaluminum to a 10% solution of heptane and search for 5 minutes to reflect the residual impurities in the system. To this solution, 0.2 g of Bangle B and 50 mg of hydrogen were added, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then start the following supply to the autoclave: .4 g / min continuous flow rate Xi Yi 晞, and 1 g / min continuous flow rate of acrylic and 3-methyl _ 1-butyl association (also contains 0.005% of 2-曱Base-1-butene) 3 0/7 0 (based on mass) mixture, two-59- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back first (Fill in this page again) ▼ Packing -------- Order · -------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy / 2064 A7

Fifth, the invention is clear (57), the monomers are all obtained from Fisher-Eng method. Some supplies continued until 100 grams of &lt; ethylene had been added. Then the flow of ethylene with other co-monomers was stopped and the reaction was held for another 35 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropyl%. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 123 Density (g / c C): 0.915 M FI (dg / min): 2.4 Hardness: 47 Impact strength (shJ / m2): 37.1 Drop strength (iMPa):: 10.9 Elongation (%): 57 Young's Modulus (iM P a): 327 Composition: 4.0% Example 1 2 In a 100 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 35 g of purified heptane And the temperature is set to 80 ° C. When the correct temperature has been reached, 10 ml of a solution of triethylaluminum in heptane at 10% is added and stirred for 5 minutes in order to react to the remainder of the system. 0.2 g of catalyst b and 50 g of hydrogen 'were added to the liquid and the mixture was dropped for another 5 minutes to form an activated catalyst: Then the following supply to the autoclave was started: .4 g / min of ethylene at a continuous flow rate 'And 2 g / min continuous flow rate of propylene and 3-methyl _ 丨 _ butyl gui (also 厶 0.01% of 2-methyl-2-butene) mixture of 5 0/5 0 (based on mass), two • 60- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -Installation -------- Order .--- ----- Economic-Ministry Intellectual Property Bureau employee consumer cooperatives printed Ruyi 472064 A7 B7 V. Description of the invention (58 Intellectual Property Bureau employee consumer cooperatives printed * '^ The card body is paid by Fisher · _ law. These supplies Continue until 100 grams of ethylene have been injected. Then stop the flow of ⑽ with other comonomers' while the JL counter library continues for another 48 minutes, then depressurize the reactor and react with 100 ml of isopropanol &lt; addition And "Stop", the resulting slurry was filtered, washed with acetone and dried. The polymer was weighed, its melting index was measured, and then injection molding To measure some mechanical and physical properties. The results obtained are as follows: Yield (g)., • 6 6 Density (g / cc): 0.921 MFI (dg / min) · '· 5.6 Hardness: 40 Impact strength (仟 Joules / square) Meters): 30.1 Drop yield strength (MPa) .: • 9.4 Drop yield elongation (%). =: 3 7 Young's modulus (MPa): 300 Composition (mole%): 5.17 Example 1 3 In the 1000 ml non-steel autoclave completely flushed with high-purity nitrogen was charged with 350 grams of purified heptane and the temperature was set to 80. (:. When the correct temperature has been reached, add millilitre triethylamine to the 1 )% Solution and stir for 5 minutes to react the residual impurities in the system. To this solution was added G2 grams of contact and hydrogen, and the mixture was stirred for another 5 minutes to form an activated mesh. Afterwards, the following Supply of autoclave: 4 g / min ethylene with continuous flow rate, and 1 g / min continuous flow rate obtained from Fisher-Law's Method 丨 _nonene (also contains 0.01% of 2-A-1-1-Sin Olefin) 3-甲 其 1 but dagger _ i 甲 __1_butene 15/85 (based on -61-This paper size applies to China National Standard (CNS) A 4 specifications (210x 297 mm) (Please read the precautions on the back before filling out this page) -Installation ----------- Order --------- 472064 Α7 Β7 V. Inventive I month (59) quality) mixture. These supplies continue until 100 grams of ethylene have been added. Then the flow of ethylene with other co-monomers is stopped, and the reaction continues for another 3 5 minutes, then the reactor is depressurized and the reaction is borrowed by 100 ml of The addition of isopropanol ends. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed 'to determine its melt index and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 121 Density (g / c C): 0.92 M FI (dg / min): 9.5 Hardness •• 4 3 Impact strength (shJ / m2): 24.2 Drop yield strength (MPa) : 10.2 Elongation (%): 4 1 Young's Modulus (iM P a): 403 Composition • -4.2% Example 1 4 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 4, clothing (please read the note on the back first) Please fill in this page again.) In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 350 g of purified heptane and set the temperature to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect residual impurities in the system. To this solution was added 0.2 g of vehicle B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then the supply of the autoclave was started: .4 g / min of ethylene with a flow rate of 1 M and continuous flow rate of 1 g / min: 1-butane and 3-fluorenyl-1-butene obtained from Fisher. Also contains 〇1 〇 / 〇 2 -methyl-2-butene 7 7/3 0 (based on -62- This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm ) 厶 υΌ4 Α7 Β7 V. Invention description_ 明 （60〇 # 4） The present compound g keeps the supply performance until 100 grams of ethylene have been added. Then U h stops the flow of ethylene with other co-monomers, and the reaction continues for another 3 After 5 minutes, the reactor was depressurized and the reaction was filtered by the addition of 100 ml of isopropanol, and the slurry produced by the winter stop 3 was filtered, washed with acetone and dried. The polymer was weighed and its melting index was determined. Then injection molding to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 143 method, degree (g / CC): 0.903 MFI (dg / min): 7.8 Hardness: 28 Impact strength (仟 Joule / M 2): 22.4 Drop yield strength (MPa): 5.6 Drop yield elongation (%): 144 Young's modulus (MPa): 199 Composition: 7.5% Example 1 5 (Please read the notes on the back before filling this page) _κ Economy ^ Intellectual Property Bureau Staff Consumer Co-operative Society Printed in a 1000 ml stainless steel autoclave completely flushed with high purity nitrogen. Purify heptane and set the temperature to 8CTC. When the correct temperature has been reached, 10 ml of a solution of triethylaluminum in heptane 10% is added and mixed for 5 minutes to react the residual impurities in the system. In this solution Add 02 g of Catalyst 8 and 50 mg of hydrogen, and stir the mixture for another 5 minutes to form an activated bracelet. Then start supplying the following autoclave: 4 g / min continuous flow of ethylene, and 1 g / Min continuous flow rate of 1-hexene (also contains 5% 2-fluorenylpentene and 0.2% 2-methyl-2-pentene) and 3_fluorenyl_ 丨 _ butene (also contains- 63-t paper size applies to China National Standard (CN-S) A4 specifications (210 x 297 male cages, one pack .------- Order .--------. Γ. 472064 Intellectual Property of the Ministry of Economic Affairs A7 B7 printed by the Bureau's Consumer Cooperative Fifth, the invention was found to be (61) 0.5% 2-methyl-2-butene) 30/70 (based on mass) mixture, two The carcasses were obtained from the Fisher method. These supplies continued until 1000 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped, and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was borrowed by 1.0. The addition of 0 ml of isopropanol was terminated. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 1 17 Density (g / c C): 0.922 MFI (dg / min): 1.9 Hardness: 49 Impact strength (仟 Joules / square meter) ': 43.3 Drop-off strength (MPa): 12.5 Elongation (%): 50 Young's Modulus (MPa): 404 Composition: 3.7% Example 1 6 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 35 mm of siblings to Huagen Pit and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect residual impurities in the system. To this solution, 0.2 g of catalyst β and 50 milligrams of hydrogen 'were added; and the kun compound was mixed for another 5 minutes to form an activated catalyst. Then began to supply the autoclave: 4 g / min continuous flow of ethylene, and 2 g / min continuous 1-hexene and 3-methyl-1 _ butane-64-This paper is widely used China National Standard (CNS) A4 Specification (210 X 297 mm) Μ. Packing -------- Order · -------- (Please read the precautions on the back before filling this page) ^ / ^ U64 B7 Fifth, the Economic-Intellectual Property Bureau employee consumer cooperative printed the invention (62) 3 0/70 (based on quality) mixture. These supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other comonomers was stopped, and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 00 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 14 1 Density (g / cc): 0.840 MFI (clg / min): 22.6 Hardness: 1 0 Impact strength (仟 Joules / square meter) ·· 10 Dropping strength (MPa): 1.7 Elongation (%): 7 4 Young's modulus (MPa): 52 Composition (mol%): 10.58 Example 17 7 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, 350 g of Heptane was purified and the temperature was set to 80X :. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect the residual impurities in the system. To this solution were added 0.2 g of Bangle B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then start the following supply of 4 g / min ethylene with continuous flow rate to the autoclave, and 1-decene with 2 g / min continuous flow rate and 3-methyl-1 -butene (also containing 0.5% 2-Methyl-2 · Butene) 7 0/3 0 (Based on quality. 65-Sheet &amp; Degree Applicable to Chinese National Standard (CNS) A4 Specification (210 X 297 Meals) f Please read the back Note for filling in this page) | Binding -----

Mi 472064 Λ7 Fifth, the invention _ Ming (63 amount) mixture. These supplies continued until 100 grams of ethylene was stopped, and the flow of ethylene and other comonomers was stopped. And the reaction continued (Ethyl chloride a and then stopped after the reactor was depressurized and the reaction was borrowed 100 ml of isopropyl ^ for 3 5 minutes, then The resulting slurry was filtered, washed with acetone and dried. y t terminates with a markup. The melting index is then measured by injection molding-this 2D object is weighed to determine the economy $ Wisdom when the production bureau staff consumer cooperatives stamp * ''? &Lt;. Bu, price 'The results are as follows: Yield (grams) density (G / cc) MFI (dg / min) Hardness impact strength (仟 Joules / square meter) Drop strength (MPa) '' Drop yield elongation (%) Young's modulus (MPa) Composition f Example 1 8 in high purity 1000 ml of stainless steel purged completely flushed with nitrogen „Total force d into 350 grams of purified heptane and the temperature is set to 80 ° C. When the positive weight has been reached,-<temperature, 10 ml of triethyl is added A 10% solution of aluminum in heptane was stirred for 5 minutes to react the residual impurities in the system. To this solution was added 0.2 g of Catalyst B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then start supplying the following autoclaves: .4 g / min of ethylene at a continuous flow rate, and 1-heptene (also containing 1% of 2-methyl_? Hexene) at a continuous flow rate of 2 g / min and 3 -Methyl-1-butyl fluorene (also contains 0-〇1% of 2- fluorenyl-2-butyl fluorene) 14〇0.922 1.9 46 30.6 13.3 52 347 3-9% I n IL · 7—--Φ—-----Zhuang

II 57 · II, φ. 66-. Chinese National Standards of Yidu (CXSMJ Regulations) (210x 297 Meals) 472064 A7 _B7_ V. The Invention I Month (64) 3 0/7 0 (based on quality) Mixture, both monomers were obtained from the Fisher-East method. These supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped and the reaction was held for another 3 to 5 minutes, then the reactor was depressurized and reacted It was terminated by the addition of 100 ml of isopropanol. The resulting slurry was washed with acetone and dried. The polymer was weighed, its melt index was determined, and then injection molding was used to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 140 Density (g / cc): 0.925 (Please read the notes on the back before filling this page) 472064 Λ7 B7 Jingling ^ -Printed by the Intellectual Property Bureau Staff Consumer Cooperatives V. Invention Say J 30 (65-based-pentene (also containing 1% of 3-methyl- 丨 -pentene) 30/70 (based on mass) adduct. These supplies continue until 00 grams of ethylene have been added . Then stop the flow of ethylene with other comonomers, and the reaction continues For another 3 to 5 minutes, the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isobutanol. The resulting slurry was filtered, washed with acetone and weighed to dry polymer, the melt index was measured, and then injected. Molding to measure some mechanical and physical properties. The results obtained are as follows: Yield (g) Density (g / cc) M FI (dg / min) Hardness Impact Strength (仟 Joules / m2) _ Drop Strength (MPa) Drop Elongation (%) Young's modulus (MPa) Composition (Moore. / 〇) Example 2 0 144 0.895 7.7 3 1 22.3 6.6 6 1 305 8.15 Add in 1000 ml stainless barium autoclave completely flushed with high purity nitrogen 350 grams of purified heptane and the temperature was set to 80 ° C. When the correct temperature had been reached, 10 ml of a solution of triethylaluminum in heptane 10% was added and mixed back for 5 minutes to reflect the residual impurities in the system. To this solution was added 0.2 g of Vehicle B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated tin vehicle. Then the following supply to the autoclave was started: 3 g / min continuous flow of ethylene, and 2 G / min continuous flow rate of propane and 4- Base-1 -pentene-68- This paper size is based on Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) -i clothing · --- ---- Order ---------, ^ 必 472064 A7 B7: 1 19: 0-876: 11: 23: 17.6: 5.0: 76: 142: 8.7% V. Inventors (66) 5 Ο / 5 Ο (for quality-more) mixture. These supplies continued until more than 1,000 ethylene had been added. The flow of ethylene with other co-monomers was then stopped, and the reaction continued for another 3-5 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropyl ^. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: — @ Yield (grams) Density (grams / cc) MFI (dg / min) Hardness impact strength (耳 Joules / square meter) Yield strength (MPa) Yield elongation (%) Young's modulus (MPa) Composition Example 21 1 In a 1,000-ml non-steel steel autoclave that was completely flushed with 芫 purity nitrogen 加入 was added 3 克 of purified heptane and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5. minutes to react to the residual impurities in the system. Here; the container was charged with 0.2 g of catalyst b and $ 0 of black hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst s. Then the following supply to the autoclave was started: .4 g / min continuous flow rate 50/50 (based on mass) of ethylene, and propane and 4-methylpentamidine (also containing 2% of 3-methyl-1-pentene) at a continuous flow rate of 1 g / min, two ° single体 ° -69- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm), installed .------- Order ------- ((Please read the back first Please note this page, please fill out this page) Printed by the Intellectual Property Bureau Employee Consumer Cooperatives of the Ministry of Economic Affairs 472064 Economy-=-Printed by the Intellectual Property Bureau Employee Consumer Cooperatives 5 'Invention Note (67) A7 B7

Both are derived from 赀 雪 • 阙 法. These supplies continued until 00 grams of ethylene had been added. Then stop the flow of ethylene and other comonomers, and the reaction lasts another 3 to 5 minutes, and then depressurize your device and stop the reaction including 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The agglomerates are weighed, their melt index determined, and then injection molded to measure—the mechanical and physical properties. The results obtained are as follows: Yield (g): 125 Density (g / CC): 0-920 MFI (dg / min): 5.4 Hardness: 42 Impact strength (仟 Joules / square meter) •• 30.4 Drop-off strength (MPa): 9.6 Elongation under drop (%): 45.3 Young's modulus (MPa): 353 Composition: 7.6% Example 2 2 A 100-liter stainless steel autoclave was added in a nitrogen flushing unit at a degree of nitrogen of 3 degrees. 3 50 grams of purified heptam and the temperature was set to 80 ° C. When the correct temperature has been reached, add 10 ml of a 10% solution of triethylaluminum in heptane and stir $ cent = to reflect the residual impurities in the system. To this solution, 0.2 g of Catalyst B and 50 mg of hydrogen were added, and the mixture was stirred for another 5 minutes to form an activated catalyst. , Then began to supply the following autoclaves: .4 g / min continuous flow rate of ethylene, and 2 g / min continuous flow rate of 1 · octene and 4 _fluorenyl_ 1 _pentamidine 3 0/7 0 ( Based on mass) mixture. These supplies continue until 100 grams have been added. _____- 70- This paper is wattage which uses the Chinese National Standard (CNtS) a4 specification (210 * 297 mm) (Please read the precautions on the back before filling out this page. ) | Packing ------- Order --------- 472064 Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 B7 5. Invented the ethylene of January (68). The flow of ethylene with other co-monomers was then stopped, and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. Over; consider the resulting aggregates, clean and dry with acrylic. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 145 Density (g / cc): 0.915 MFI (dg / min): 2.0 Hardness: 4 2 Impact strength (仟 Joules / square meter): 39.5 Drop strength (MPa): 9.5 Drop Elongation (%): 5 7. Young's modulus (MPa): 293 Composition: 4.5% Example 2 3 100 milliliter non-narrated autoclave in the south of pure nitrogen was added to 350 milligrams of the autoclave. Heptane was purified and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect the residual impurities in the system. To this solution was added 0.2 g of Catalyst B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated tin vehicle. Then start the following supply to the autoclave: 4 g / min continuous flow of ethyl hoof, and 2 g / min continuous flow of 1-octene and 4 -fluorenyl-1 -fluorene hoof (also contains 2% of 3- Methyl-1 -pentamidine) 50/50 (mass based) mixture. These supplies continued until 100 grams of ethylene had been added. Then stop the ethylene and other total -71-This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) (please read the precautions on the back before filling this page) Ding _________ 472064 A7 Jing Ling- Printed by the Intellectual Property Bureau's Consumer Cooperative 145 0.918 2.1 44 40.8 10.8 5 0 334 3.22 V. Invented that J (69) was in a semi-physical condition and the reaction continued for another _ 3 or 5 minutes, and then the reactor went to the reaction phase · 100 litres of isopropanol pad and 蛘 <addition terminated. The resulting incineration was filtered, washed with acetone and dried. Grandfather ^ Measure compound weight% 'Determination of Lixuanhuahufeng and then injection molding to measure f-this Ηα t + ·· ^ number' mechanical and physical properties. The results obtained are as follows: Yield (g) Density (g / cc) MFI (dg / min) Hardness Impact Strength (仟 Joules / m2) Drop Strength (MPa) Drop Elongation (%) Young's Modulus (MPa) Composition (Molar%) Example 24 4 In a 1000-ml stainless steel autoclave completely flushed with high-purity nitrogen was added 350 grams of purified heptane and the temperature was set to 80. (: When the correct temperature has been reached, 10 ml of a solution of triethylaluminum in heptane is added and stirred for 5 minutes to react the residual impurities in the system. 0.2 g of catalyst B and 5 are added to this solution 〇mg of hydrogen 'and the mixture was stirred for another 5 minutes to form an activated monolith: Then the following supply to the autoclave was started: 4 g / min continuous flow of ethylene and 2 g / min continuous 1-octene ( It also contains 0.4% of 3-methyl-2-heptylfluorene and 4-fluorenyl-1-pentene (also contains 2% of 3-methyl-2-pentyl) 7 0/3 0 ( Based on mass) mixture, both monomers are obtained from Fisher • Question Method 72- This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) — ^ --- f ----- -Install -------- Order · &----; (Please read the notes on the back before filling this page) 472064 ： 145: 0.914 ： 4.5 •• 31.5 ： 7.8 ： 65: 204: 7% A7 B7 V. The invention said that in January (70) some supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped, and the reaction continued for another 35 minutes, then the reactor was depressurized and reaction Terminated by the addition of ml of isopropanol. The resulting material was filtered, washed with acrylic and dried. The polymer was weighed, its melt index was measured, and then shot to measure some mechanical and physical properties. The obtained The results are as follows: Yield (g) Density (g / cc) M FI (dg / min) Hardness Impact Strength (Shijoules / square meter) Drop Strength (MPa) _ Drop Elongation (%) Young's Modulus (MPa) Composition Example 25 5 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen was added 3 500 g of purified heptane and the temperature was set to 8 ° C. When the correct temperature had been reached, 10 liters of three 0% solution of ethylaluminum in heptane and stirred for 5. minutes to reverse the residual impurities in the system. To this solution was added 0.2 g of catalyst 8 and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form Activated catalyst ^ Then the following supply to the autoclave was started: 4 g / min continuous flow of ethylene and 2 g / min continuous flow of ^ butene and * from the Fisher-Law Process (Also contains 1% of 3_methyl_ 丨 _pentene) of 30/70 (based on quality -73 -The size of this paper meets the standard of China National Standard (CNS) A4 (210 X 297 public love) --C ---.------ install -------- order --- ------ (Please read the precautions on the back before filling this page) Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperatives of the Ministry of Economic Affairs ’Intellectual Property Bureau printed 472064 Α7 Β7 ) Amount) mixture. These supplies continued until 100 grams of acetam had been added. The flow of ethylene with other co-monomers was then stopped, and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 丨 48 Density (g / cc): 0.916 MFI (dg / min): 5.4 Hardness: 3 9 Impact strength (shJ / m2): 34.1 Drop yield strength (MPa): 8.4 Drop elongation (%): 5 6 Young's modulus (MPa): 269 Composition: 6.1% Example 2 6 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 350 g of purified heptane and set the temperature to 8 0 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 'minutes to react to residual impurities in the system. To this solution was added 0.2 g of hydrazone B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then began the supply of the autoclave: .4 g / min ethylene at a flow rate of DM, and 1-butene and 4-methyl-1 -copper at a continuous flow rate of 2 g / min (also containing 0.5% of 3 -Fluorenyl-1 -pentene) 50/50 (based on mass) mixture, two types -74-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (please read first) Note on the back, please fill out this page again) ▼ Installation ----------- Ordering --------. 472064 A7 137 --κ .¾¾¾¾1.¾The consumption cooperation of the staff of the property bureau. 138 0.890 6.0 2 8 22.8 6.4 100 195 8.29 Fifth, the invention said: the moon (72) monomers are all obtained from t snow · 阙 method. These supplies continued until 100 grams of acetylene had been added: Houyi'7. Stop acetylene flowing with other comonomers, and the reaction continued for another 3 5 minutes'. Then the reactor was depressurized and the reaction borrowed 100 ml of isopropyl Alcohol I addition terminated. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some of its geometric and physical properties. The results obtained are as follows: Yield (g) Density (g / cc) M FI (dg / min) Hardness Impact Strength (仟 Joules / m2) Drop Strength (MPa) s Drop Extension (%) Young's Modulus (MP) a) Composition (mol%) 2 7 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 350 grams of purified heptane and set the temperature to 8 (TC. When the correct temperature has been reached, Likou 10 ml of a 10% solution of triethylacetic acid in heptane was added and mixed for 5 minutes = the residual impurities in the reaction mixture. 纟 This solution was added with 0.2 g of the catalyst limb and hydrogen, and the mixture was stirred for another 5 minutes to form the activated catalyst 22. Start the following pressure on the uncle pressure. 1 S / &amp; ... The fast reaction of Zhai .: 4 g / min continuous flow rate of B •, and 1 g / min continuous Flow rate of 1 · nonene (also contains 0.01% 2-fluorenyl, 1-octene) and 4-fluorenyl-1 -pentamidine (also contains 05% 3-methyl-i-pentene '之 咖啡 家 鲜 (CNS) AI (210; 75- 29τΤ $ Τ --S Please read the phonetic on the back? Matters before filling out this page}

472064 Λ7 Description of the invention (73) ^ (based on mass) A mixture of both monomers obtained from the Fisher-Hermann method. "Continue until 100 grams of B # 3 has been added and then stop the flow of ethylene and co-M 'and the reaction continues for another 35 minutes, and the reaction is stopped by the addition of 100 ml of isopropanol. Over漶 Generate H α acetone for washing and drying. The polymer is weighed, its melting index is measured, and then injection molding is used to measure some mechanical and physical properties. The results obtained are as follows: ; ^,-Yield (g) Density (g / cc) MFI (dg / min) Hardness impact strength (仟 joule / m2) _ Drop strength (MPa) Drop extension (%) Young's modulus (MPa) Combination Example 2 8 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 3 50% of purified heparin: fe and the temperature is set to 80 C. When the correct temperature has been reached, add 10 ml 10% solution of triethylaluminum in heptane and stirred for 5 minutes to react the residual impurities in the system. To this solution was added 0.2 g of catalyst B and 50 mg of hydrogen, and the JL mixture was mixed; mixed for another 5 minutes to The activated catalyst 3 is formed and then the following supply to the autoclave is started: 4 g / Minute continuous flow of ethylene and 0.2-g / min of 1-heptene (also contains 1% 2-methyl-2 -hexane 122 0.914 0.75 42 38.5 14.9 90 274 5.1% (Please read the note on the back first Please fill in this page again for details) -Installation -------- Order · --------. -76- <t: ¾ 冃 中 Θ 舀 家 洁 准 (CN'S) A ·} Specification (210 X 297 public money) Employees of the Bureau of Economics and Intellectual Property, Consumer Cooperatives, printed 472064 Λ7 Π7 5. Invention = Ming (74) ene) and 4-methyl-1 -pentene (also 2 ° /. Of 3- A 70/30 (mass-based) mixture of methyl-1 -pentene), both monomers were obtained from the Fisher-East method. These supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped And the reaction was held for another 35 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 00 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer was weighed and measured for melting Index, then injection molding to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 105 Density (g / c C): 0.938 -MFI (dg / min): 0 .9 Hardness: 58 Impact strength (shJ / m2) •• 16.9 Drop yield strength (MPa): 21.3 Drop yield elongation (%): 50 0 Young's modulus (MPa): 622 Example 2 9 Completely with high purity nitrogen The flushed 1000 ml stainless steel autoclave was charged with 350 g of purified heptane and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and decanted for 5 minutes to remove residual impurities in the system = 0.2 g of vehicle B and 50 mg of Hydrogen, and the mixture was stirred for another 5 minutes to form an activated bracelet medium. Then began to supply the autoclave with: 4 g / min continuous flow of ethylene and 2 g / min continuous flow of 1-hexene and 4-methyl-1 -pentene-77- National Standard (CNS) .A4 specifications (210 X 297 cm)-Packing --------- Order · -------- (Please read the precautions on the back before filling this page) 472064 Λ7 B7 4--Second--Chi ^^ 4 Consumption Co-operation of Employees in the Bureau of Bureau of Civil Affairs & Quotation. 150 0.906 3.9 42 3 1.8 8.8 47 352 4.3% V. Inventive _ Ming (75 3 0/7 0 (based on quality) Mistakes ^ "Material. These supplies will continue until the ethylene has been added. However, it will stop, Bu t υυ brother, τ &amp; ~ flow with other comonomers, and react for another 3 5 minutes, after Qiao e. Waiting for% 'to depressurize the reactor and stop the reaction by the addition of 100 ml of Satoda. To taste the taste, this &lt; Wu Bingxuan. · * Generates a slurry, washed with acetone and dried. Like compound Weigh and determine its 指数 4 匕 &amp; ί (&amp; chemical index, and then injection molding to measure the mechanical and physical properties. The results obtained are as follows: ^ Yin Yield (g) Density (g / cc) ιΜ Π (dg / Min) Hardness impact strength (仟 Joules / square meter) Drop strength (MPa): Drop elongation (%) Young's modulus (MPa) Composition example 3 0 In a 0 000 milliliter rinsed with high purity SI The steel autoclave was added with 350 grams of purified Geng pit and the temperature was set to 80 C. When the correct temperature was reached, 10 ml of triethylaluminum was added to the 10% solution of Gengfen • Mix for 5 minutes to remove residual impurities in the reaction system. 3 Add 0.2 g of Catalyst B and 50 mg of hydrogen 'to this solution and stir the mixture for another 5 minutes to form an activated catalyst. Then start the following supply to the autoclave. : Ethylene at a continuous flow rate of 4 g / min, and 1-hexene at a continuous flow rate of 2 g / min and 4-methyl-1 -pinene (also containing a 3-methyl radical at 1/0) -1-pinene) of 5 0/5 〇 (based on the mass -78 large paper kill <Du this bow Zhongguan Guan Cheng Cheng (CXS) A · «present grid (210 x 297 public goods). Loaded --- ----- Order · -------- (Jing first read the precautions on the back and then fill out this page) 472064 B7 76 150 0.909 4.4 3 7 32.2 8.2 5 8 253 6.2% Five 'invention statement _ Ming ( Free) mixture These supplies were maintained until 00 grams of ethylene had been added. Then ethylene was stopped from flowing with other comonomers, and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was supplemented with 00 ml of isopropanol plus 1 = Terminate. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, its melt index is determined, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (grams) 荇 Degrees (g / cc) IVi FI (dg / min) Hardness Impact Strength (仟 Joules / square meter) Drop Strength (MPa) ^ Drop Extension (%) Young's Modulus (MPa) ) Composition Example 3 1 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, 350,000 Torr of purified heptane was added and the temperature was set to 80. 〇. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reverse the residual impurities in the system. To this 5 volume solution, 0.2 g of catalyst b and $ 00 mM hydrogen were added and the mixture was stirred for another 5 minutes to form an activated catalyst. Then, the following supply to the autoclave was started: 4 g / min of ethyl tellurium with a continuous flow rate, and 1 g / min of 1-hexene with a continuous flow rate (also containing 5% of 2_ 曱 基 _ 卜 戌 戌 and 0.2 % Of 2-methyl-2-pentene) and 4 _fluorenyl_ 1 _ pentene (also contains 0/50/0079 ZhongYin® family standard (C \ S) A4 specification (210x297 ^^- ------ Order --------- (Please read the notes on the back before filling out this page): 1: ~ ^ :, Smart ^ -Time and Industry Bureau staff eliminate cooperation ': 1 printed ^ Ministry of Intellectual Property, Industrial Property, Consumer Cooperatives' Seal; 472064 Λ7 B7 V. Invention Statement = Ming (77) 3-methyl- 丨 -pentene) 7 0/3 0 (based on quality ΐ) mixture, Both monomers were obtained from the snow method. These supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped, and the reaction continued for another 35 minutes, then the reactor was depressurized and reacted. Terminated by the addition of 100 ml of isopropanol. Excess; consider the resulting polymer, wash and dry with acrylic. The polymer is weighed, its melting index is measured, and then injection molding is used to measure some mechanical and physical Properties. The results obtained are as follows: Gram): 120 Density (g / c C): 0.918 MFI (dg / min): 1.2 Hardness: 48 Impact strength (shijoules / square meter): 44.8 Drop strength (MPa): 12.4 F volt elongation (%): 5 3 Young's modulus (MPa): 364 Composition: 4.6% Example 3 2 In a 1000 ml stainless copper autoclave completely flushed with high purity nitrogen, 350 g of purified heptane was added and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a solution of triethylaluminum in heptane and 0% is added for 5 minutes to react the residual impurities in the system. To this solution are added 0.2 g of Bangle B and 50 mg And the mixture was stirred for another 5 minutes to form an activated bracelet medium. Then the following supply to the autoclave was started: 4 g / min continuous flow of ethylene and 2 g / min continuous flow of:! -Decene and obtained Since Fisher · Law Method 4--80- This paper &degree; 0 Chinese standard (C \ S) .- U «I grid (210 X 297 male) 坌 · * ------ J11 · ----- 1 --- (please read first-notes on the back before filling this page) 472064 Λ7 B7 78 ： 143: 0.835 ： 27 ： 5: 11.5: 1.5: 34: 103 · '12.67 He said H-month (

A 70/30 (based on mass) mixture of methyl berberine (also containing 0.5% 3-methyl berberine hoof). These supplies continued until 100 grams of ethyl acetate had been added. Then the flow of ethylene and other co-monomers was stopped, and the reaction continued for another 3 to 5 minutes, then the reaction state was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed Y to determine its dazzling index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (g) Density (g / c C) MFI (dg / min) Hardness Impact Strength (仟 Joules / m 2):, Drop Strength (MPa) Drop Elongation (%) Young's Modulus (Μ) P a) Composition (mol%) Example 3 3 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, 350 g of purified heptane was added and the temperature was set to 80 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes = to reflect the residual impurities in the system. To this solution, 0.2 g of Catalyst 8 and 50 mg of hydrogen were added, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then began to supply the following autoclaves: _ 4 g / min continuous flow of ethylene, and 2 g / min continuous flow of didecylene and 4 _ methyl · 1 _ pent woman's -81-Ben Lu Yi Du Kind of 3 standard (CN.S) / U specifications ⑵〇χ 297 meals> ^ Outfit -------- Order --------- (Please read the precautions on the back first (Fill in this page) No-^ Intellectual Property Cooperative Employees ’Cooperatives Seal 472064 No Benefit ^ Intellectual Property Cooperative Employees' Cooperative Seals ^ A7 137 V. Invention Statement = Ming (79) 3 0/7 0 (based on quality )mixture. These supplies continued until 100 grams of ethyl acetate had been added. Then the flow of acetamidine with other co-monomers was stopped and the reaction continued for another 3 to 5 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer is weighed, measured for its melt index, and then injection molded to measure some edge and physical properties. The results obtained are as follows: Yield (g): 150 Density (g / c C): 0.869 'VIFI (dg / min): 14.9 Hardness: 20 Impact strength (仟 Joules / m 2): 16.3 Dropping strength (MPa). ^ I &gt; • J. J Elongation Elongation (%) •• 5 6 Young's Modulus (MPa): 174 Composition (mole%): 6.56 Example 3 4 Preparation of Catalyst D _ Prepolymerization in high purity nitrogen A fully rinsed 1,000 ml stainless steel autoclave equipped with an external filtering device was charged with 350 g of purified heptane and the temperature was set to 80 ° C ° When the correct temperature had been reached, 100 ml of triethylamine was added to the heptane A 10% solution of alkane was stirred for 5 minutes to react with residual impurities in the green system. 2 g of Catalyst B and 50 mg of hydrogen were added to this solution, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then began to supply the following autoclaves: -82 * support 3 in 2 Θ 0 samples (CN'S) A4 size (210 X 297) 坌-? · ---.------ installation · ------- Order · --------. (Please read the precautions on the back before filling this page) 472064 ί \ Ί vn V. Invention ^ month (80) 2 0 g / Acetone at a continuous flow rate of 10 minutes and a 50/50 (by mass) mixture of 3-methyl-1 -pinene and 4-methyl- 丨 -pentene at a continuous flow rate of 10 g / min, two dudan The bodies are all obtained from the snow method. These supplies continue until 50 grams of ethylene have been added. Then the flow of ethylene and other co-monomers is stopped, and a solid prepolymerization catalyst is separated from the liquid medium by an external filter. The prepolymerization catalyst The medium was washed twice with heptane, sealed in a filtering device, and then removed from the reactor and transferred to a glove box with a moody atmosphere, where the prepolymerized catalyst was transferred to a storage container after drying. Example 3 5- --Printed by the Intellectual Property Bureau employee consumer cooperative;-(Please read the precautions on the back before filling this page) Fully flushed in the south of the purity atmosphere 1 0 0 0 no-rise non-recording steel autoclave added 3 0 0 Kazunari Heptane and the temperature is set to 8 5 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to react to the residual impurities in the system. In this solution Add 0.5 g of prepolymerized catalyst D and 30 mg of hydrogen. Then start supplying the autoclave with: 2 g / min continuous flow of ethylene and 0.8 g / min continuous flow of 3-methyl-1-pentane A 2 5/7 5 (mass-based) mixture of alkenes and 4 -fluorenyl-1 -pinene (also containing 1% of 2.3-dimethyl-1 -butene), both monomers obtained from Fisher · Method. These supplies continue until 100 grams of ethylene have been added = then the flow of ethylene with other co-monomers is stopped, and the reaction continues for another 10 minutes, then the reactor is depressurized and the reaction is made by the addition of 100 ml of isopropanol Terminated. The resulting slurry was filtered, washed with acetone, and dried. The polymer was weighed, its melt index was measured, and then injection molding was performed to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 81 -83 -Original paper certificate (CXS) .- Vl size (210 X 297) 472064 A7 137. ^^^^^^ Industrial Bureau Employees' Consumer Cooperatives Co., Ltd. V. Invention Description = Density (81) Density (g / cc) M FI (dg / min) Hardness Impact Strength (仟 Joules / square meter) Drop Strength ( MPa) Drop elongation (%) Young's modulus (MPa) Composition example 36 6 Add 3,000 grams of purified heptane to a 100 ml non-steel hot-swipe device completely washed with 咼 purity SL 疋: and set the temperature For 8 5 C. When the correct temperature production has been reached, add 10 ml of a 10% solution of triethylaluminum in heptane and stir for 5 minutes in order to respond to the residual impurities in the system. To this solution was added 0.5 g of prepolymerized human catalyst 0 and 30 mg of hydrogen. Then start the following supply to the autoclave ... / Eight p-% with a flow rate of 3% and a continuous flow rate of 0.8 g / min. 3 trials | '-τ 丞 _ 1-pentene and 4-fluorenyl-1 -Pentamidine (also contains 1% of 2- 3-methyl 1 10/90 (based on mass) mixture, both monomers are obtained from ^ These supplies continue until 100 grams of acetamidine have been added. Then stop, '. Other The co-monomers flow, and the reaction continues for another 〇 (continued with ethylene and depressurized and the reaction is by the addition of 100 ml of isopropanol = then the reactor slurry is washed and dried with acetone. The polymer is weighed, Set and equal to the number of generations, and then injection molding to measure the physical properties of some mechanical toilets. The melting index is as follows: shells, yields (grams), -84 meanings, which are in the 0S standard (03) · Λ · 1 specification (210 X 297 male i: 0.935: 0.04: 56: 59.4: 22.2: 92: 566: 7.0% V '' · ^ ^ --------; ^ · ------ (Please read the precautions on the back before filling this page) ΛΎ 472064 Λ7 _I £ Five, the invention said that the month (82) density (g / c C): 0.939 MFI (dg / min): 0.9 hardness: 56 impact strength (仟 Joules / square meter): 60.6 P You Γ Μ P a, ο &lt; η (please read the back of the paper 472064 Λ7 Π7 V. Invention Note ^ 83 (83) Density (g / c C): 0.9414 M FI (dg / min) •• 0.6 Hardness: 58 Impact strength (仟 Joules / square meter): 33.8 Drop yield strength (MPa): 18.3 Drop yield elongation (%): 44 Young's modulus (MPa): 584 Composition: 1.7% Example 3 8 (Please read the precautions on the back first (Fill in this page again) In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add 300 g of purified heptane and set the temperature to 8 5 ° C. When the correct temperature has been reached, add 10 ml of triethyl A 10% solution of aluminum in heptane and stirred for 5 minutes to react to the residual impurities in the system. To this solution was added 0.5 g of prepolymerized media D and 100 mg of hydrogen. Then the following supply to the autoclave was started: 2 g / min continuous flow of ethylene and 1 g / min continuous flow rate of 3-methyl-1 -pentamidine and 4-methyl-1 -pentene (also containing 1.5% of 2,3-dimethylene Based on a 20/80 (based on mass) mixture of both monomers, both monomers were obtained from the Fisher-Time method. These supplies continued until Add 100 grams of ethylene. Then stop the flow of ethylene with other co-monomers, and the reaction lasts another 10 minutes, and then the reactor is depressurized and the reaction is terminated by the addition of 100 ml of isopropanol. The resulting slurry was washed with acetone and dried. The polymer was weighed, its melt index was measured, and then injection molding was performed to measure some mechanical and physical properties. The results obtained were as follows: Yield (g): 5 1 -86- This paper &lt; degree ii 冃 中 冃 国 丨 票Return (CXS) A4 specification (210 X 297 s) Gift-Printed by the Consumers 'Cooperative of the Ministry of Economic Affairs and Intellectual Property Bureau --- Printed by the Consumers' Cooperative of the Intellectual Property Bureau,-'' 472064 Λ7 B7 V. Invention 1 (84) Density (g / c C): 0.942 MFI (dg / min): 0.26 Hardness: 59 Impact strength (仟 Joules / square meter): 47.6 Drop strength (MPa): 20.8 Drop extension (%): 47 Young's Modulus (MPa): 618 Composition: 1.65% Example 3 9 A 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen was charged with 300 g of purified heptane and the temperature was set to 8 5 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect the residual impurities in the system. To this solution was added 0.5 g of prepolymerized catalyst D and 150 mg of hydrogen. Then began to supply the autoclave with 2 g / min continuous flow of ethylene and 1 g / min continuous 3-methyl-1 -pentene and 4-methyl-:!-Pentene (also containing 1 _ 5% of 2, 3 -difluorenyl-: 1-butene), 3 0/7 0 (mass-based) mixture, both monomers are obtained from Fisher • Method = these supplies continue until 100 has been added Grams of ethylene. The flow of ethylene with other comonomers was then stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. Over: consider the resulting slurry, wash and dry with acetone. The polymer is weighed, its melting index is determined, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (grams): 5 3 -87- Ben Niu &lt; degree is based on Zhongyin family standards (03), \ 4 specifications (210 x 297) -------- -\ 1τ · -------- (Please read the precautions on the back before filling this page) 472064 A7 137 Jing •• Λ Zhiye Industry Bureau 0.943 0.6 57 38.0 18.3 48 564 1.6% Consumers 、 Invention% Ming (85 Density (g / cc) MFI (dg / min) Hardness Impact Strength (仟 Joules / m 2) Drop Strength (MPa) Drop Elongation (%) Young's Modulus (MPa) Composition Example 4 0 In a 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen, add grams of purified heptane and set the temperature to 8 5 ° C. When the correct temperature has been reached, add 10 ml of triethylaluminum to heptane. 丨0% solution and stirred for 5 minutes to respond to the remaining residue in the system. To this solution was added 0.5 g of prepolymerized catalyst D and 120 mg of hydrogen. Then the following supply of autoclave was started: 2 g / Ethylene with a continuous flow rate of 1 minute, and 3 · methyl · 丨 · pentene and 4-methyl-1-pentene (also contains i.5% of 2,3_dimethyl_丨 _ Ding Association) of 4 0/6 0 (based on mass) mixture, both monomers are obtained from Fisher • The supply continues until 100 grams of ethylene have been added. Then the flow of ethylene with other co-monomers is stopped and the reaction continues for another 0 minutes, The reactor is then depressurized and the reaction is terminated by the addition of 100 liters of isopropanol. After the reaction, the resulting slurry is washed and dried with acetone. The polymer is weighed, its melting index is measured, and then injected Molding to measure some mechanical and physical properties. The results obtained are as follows: Yield (g) 5 5 -88- x297) Ministry of Intellectual Property Bureau Staff Consumer Cooperatives Seal: ^ 472064 Λ7 H7 5. Invention 1 Ming (86) Density (G / c C): 0.942 MFI (dg / min): 0.3 Hardness: 62 Impact strength (仟 joules / square meter): 42.7 Drop strength (MPa): 31.5 Drop extension (%) •• 6 2 Young's modulus (M P a) 727 Composition: 1.6% Example 4 1 In a 1,000 ml stainless steel autoclave completely flushed with high purity nitrogen, 300 g of purified heptane was added and the temperature was set to 85 ° C. When the correct temperature has been reached, add 10 ml of triethylaluminum in heptane] 0% solution and stir for 5 minutes to react to residual impurities in the system. To this solution was added 0.5 g of prepolymerized catalyst D and 150 mg of hydrogen. Then the following autoclave supply was started: ethylene at a continuous flow rate of 2 g / min, and 3-fluorenyl-1-pinene and 4-fluorenyl-1 -pentene (also containing 0.5 % 2, 3 -dimethyl-1-butene) 50/50 (based on mass) mixture, both monomers were obtained from the Fisher-Henry method. These supplies continued until 100 grams of ethylene had been added. The flow of ethylene with other comonomers was then stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting slurry was filtered, washed with acetone and dried. The polymer was weighed, its melting index was measured, and then injection molding was performed to measure some mechanical and physical properties. F: The results obtained are as follows: Yield (grams): 54 -89- This paper is a national standard (CNS) A4. (210 X 297 male) (Please read the precautions on the back before filling out this page) &quot; Clothing ------- Order ------- 472064 A7 V. Invention Description 1 ( 87) Density (g / c C) MF 丨 (dg / min): 0.920: 0.6 ^ yan 472064 Λ7 137-^-Chi '&quot; Printed by the Consumer Affairs Cooperative of the Property Bureau V. Invention 1¾: Ming (88) MF [(dg / minute) Hardness impact strength (仟 Joules / square meter) Drop strength (MPa) Drop extension (%) Young's modulus (MPa) Composition example 4 3 In 1000 ml 300 grams of purified heptane was added to the steel autoclave and the temperature was set to 8 5 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and stirred for 5 minutes to reflect the residual impurities in the system. To this solution was added 0.5 g of the prepolymerized catalyst d_ and 150 mg of hydrogen. Then start the following supply to the autoclave: 2 g / min continuous flow rate of ethylene, and 1 g / min continuous flow rate of 4-methyl-1_pentene and 1-hexene 70/30 (based on mass )mixture. These supplies continued until 100 grams of ethylene had been added. The flow of ethylene with other comonomers was then stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. The resulting polymer was filtered, washed with acetone and dried. The polymer was weighed 'to determine its melt index, and then injection molded to measure some mechanical and physical properties. Result 4 obtained ... 'Yield (g): 59 Density (g / cc): 0.941 MFI (dg / min): 0.8 Hardness • 0.6: 50: 27.1: 3.4% (Please read the precautions on the back before filling this page )

* II 11 · I-II-11 i i--i I-I -I n I -91-0.¾ Hi standard (CNS) / y regulations 丨 each (210 X 297 public) 7 ～ 2064 B7 V. Description of the invention (89) Impact strength (强度 joules / square meter) printed by the Ministry of Economic Affairs & Consumer Property Cooperative Cooperatives. Drop strength (MPa) Drop extension (%) Young's modulus (MPa) Combination Example 4 4 In 1000 ml of non-hot ^ human 3 () () purified heptane completely flushed with high purity nitrogen and set the temperature to 85X. When the correct temperature has been reached, add 10 ml of triethylaluminum to 10% solution of heptane and stirred off for 5 minutes = residual impurities in the reaction system. To this solution were added 0.01 g of catalyst 0 and 150 mg of hydrogen, and the mixture was stirred for 5 minutes to form an active catalyst. Then start The following are supplied to the autoclave: 2 g / min ethylene with a continuous flow rate, and 3 -fluorenyl-1 -pinene and 4 _methyl_ 丨 _pinene (also containing 0 · 5% (2,3-Difluorenyl-1-Butanidine) 1/10/9 0 (based on mass) mixture, both monomers are obtained from Fisher • Tritium. These supplies are maintained until Add 100 grams of ethylene. Then stop the flow of ethylene with other co-monomers, and the reaction continues for another 10 minutes, then depressurize the reactor and stop the reaction by the addition of 1000 ml of isopropanol. Filter the resulting slurry , Washed with acetone and dried. The polymer was weighed, its dazzling index was measured, and then injection molding was used to measure some mechanical and physical properties. The results obtained were as follows: 7.1% yield (g): 69 density (g / cc): 0.905 MFI (dg / min): 8.6 Hardness: 3 2 92- Large paper size Chinese National Standard (CNS) A4 specification (210 X 297 cm) (Please read the precautions on the back before filling this page) l · Installation -------- Order --------- Μ ^ _____ 07 ~ AJ64 Λ7 Five 'invention · 1¾ Ming (9〇) Impact strength (shijoules / square meter): 27.0 Dropping strength (MPa ): 4.8 Elongation (%): 55 Young's Modulus (MPa): 272 Composition (mole%): 7.94 Example 4 5 Economy ^ Intellectual Property Co., Ltd. Employee Consumer Cooperative Cooperative Seal * '1 · ^ in high purity 1000 ml of stainless steel autoclave with full nitrogen flushing was added with 300 g of purified heptogen and the temperature was set. 8 5 ° C. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane is added and left to stir for 5 minutes to react the residual impurities in the system. To this solution is added 0.1 g of contact Vehicle C and 150 mg of hydrogen, and the mixture was stirred for 5 minutes to form an active catalyst. Then start the following supply to the autoclave: 2 g / min continuous flow of ethylene and __ 6 g / min continuous flow of 3-fluorenyl-1-pentamidine and 4 _ methyl-1-pentene (also contains 10 / 〇 of 2,3-dimethyl-butadiene) 1/10/90 (based on mass) mixtures' Both monomers were obtained from the Fisher-Eng method. These supplies continued until 100 grams of ethylene had been added. The flow of ethylene with other co-monomers was then stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction was terminated by the addition of 100 ml of isopropanol. Filter the generated material, clean and dry it with C net. The polymer is weighed, measured for its melt index, and then injection molded to measure some mechanical and physical properties. The results obtained are as follows: Yield (grams): 10.09 Density (g / cc): 0.915 MFI (dg / min): 7.5 Hardness: 4 1 -93- This paper uses the China National Standard (CNS) .- Vl specifications (210 X 297 cm) (Please read the precautions on the back before filling out this page) Order --- ##-～ 2064 Λ7 〜 _______ H7 V. Inventive failure _ Ming (91) Impact strength (仟 Joule / Square meters): 34.4 Dropping strength (MPa): 8.2 Dropping elongation (%): 110 Young's modulus (MPa): 207 Composition (mole%): 6.02 Printed by the Ministry of Economic Affairs &quot; --- Consumer Cooperative of the Property Bureau &quot; (Please read the precautions on the back before filling this page) Add 1,000 grams of purified heptane to a 1,000 ml stainless steel autoclave completely flushed with high-purity nitrogen and set the temperature to 85. (:. When the correct temperature has been reached, 10 ml of a 10% solution of triethylaluminum in heptane was added and stirred for 5 minutes to react the residual impurities in the system. 0.1 g of catalyst C was added to this solution And 150 靟 of hydrogen 'and the mixture was stirred for 5 minutes to form an active catalyst. Then the following supply to the autoclave was started: acetam with a continuous flow rate of 2 g / min, and 3-methyl with a continuous flow rate of 6 g / min. A 30/70 (based on mass) mixture of -1 -pentamidine and 4-methyl-1 -pentamidine (also containing 2% of 2,3-difluorenyl-1-butene), both monomers Obtained from Fisher • The supply was continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction was borrowed by 100 ml The addition of isopropyl alcohol was terminated. The resulting material was filtered, washed with propylene copper and dried, and the polymer was weighed, and its melting index was measured. Then injection molding was used to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 9 6 go, degree (g / cc): 0.916 MFI (dg / min): 1.8 Hardness: 48 ____ ** 94-ds Caiyuan Gujia Standard (mu size ⑵0 x 297 cm) ⑺2064 Λ7 B7 V. Invention Statement = Ming (92) Impact strength (shJ / m2) Drop strength (MPa) Drop Elongation (%) Young's modulus (iMPa) Composition (mole%) Example 4 7 41.2 Π.1 89 343 3.03 Purified heptane at 1000 g was completely flushed with nitrogen of nitrogen purity and the temperature was set to 85. 〇々 is a steel autoclave to add 300… η …… When the correct temperature has been reached, add 10 ml of triethylaluminum to the i 0 '4 solution of heptane and stir for 5 minutes to counteract the loss of intellectual property. The employees of the Bureau ’s consumer cooperatives printed the residual impurities in the system. It ’s up to them. Lu ^ The machine looks at the edge of the knife to counter, _. ^ Π Here, I will put in 0.1 grams of catalyst 0 and 150 X lice, and Kun compound soaked ^ this ... mouthpieces are collected for 5 minutes to form an active catalyst. Then start the following counter pressure device; ^ ·,. ',', 仏 t 2 brother / minute continuous flow rate of Ethylene, and-. T group-Bu 戍 # and 4-methyl-1 -pentene (also contains 1.5% full 2 '3-difluorenyl_J_butene) 4 〇 / 〇 〇 (based on mass ) Mixed Both monomers were obtained from the Fisher • Process. These supplies continued until 100 grams of ethylene had been added. Then the flow of ethylene with other co-monomers was stopped, and the reaction continued for another 10 minutes, then the reactor was depressurized and the reaction borrowed The addition of 100 ml of isopropyl alcohol was terminated. The resulting polymer was washed with acetone and dried. The polymer was weighed, its melt index was measured, and then injection molding was used to measure some mechanical and physical properties. The results obtained are as follows: Yield (g): 1 07 Density (g / cc): 0.916 MFI (dg / min): 0.001 Hardness: 4 8 -95- iullr .------ · Packing ----- --- Order --------- S (Please read the precautions on the back before filling out this page) 472064 A7 B7 Jing-Yi-Property Bureau Employee Consumption Cooperatives Seal 4'1 ^ V. Invention = Ming (93) Impact strength (仟 Joules / square meter): 46.6 Drop yield strength (MPa): 11.3 Drop yield elongation (%): 101 Young's modulus (MPa): 321 Composition (mole%): 3.44 Example 4 8 A 1000 ml stainless steel autoclave completely flushed with high-purity nitrogen was charged with 3 50 g of purified heptane and the temperature was set to 80. (:. At the correct temperature, add 10 ml of a solution of triethylaluminum in heptane and stir it for 5 minutes to remove residual impurities in the reaction system. Add 0.2 g of catalyst to this solution. B and 50 mg of hydrogen, and the mixture was stirred for another 5 minutes to form an activated catalyst. Then the following supply to the autoclave was started: 4 g / min continuous flow of acetylene and 2 g / min continuous flow of A mixture of 1_octene (also containing 0.4% of 3-methyl-2-heptane) and 3-methyl-1 -butene in a 50/50 (based on mass) mixture of both monomers at their own expense Snow • The method. These supplies continue until 100 grams of ethylene have been added. Then the flow of ethylene with other comonomers is stopped, and the reaction continues for another 3 5 minutes, then the reactor is depressurized and the reaction is borrowed by 1000 ml. The addition of propanol was terminated. The resulting slurry was filtered, washed with acetone and dried. The polymer was weighed, its melting index was measured, and then injection molding was used to measure some mechanical and physical properties. The results obtained are as follows: Yield (G): 143 Density (g / cc): 0.920 MFI (dg / Minutes): 2.9 Hardness: 49 -96- This paper size is based on China National Standard (CNS) A ·! Specifications (210 X 297 cm) U # Binding --------- ^ 9— 472064 A7 _B7 V. Inventive failure_94 (94) Impact strength (仟 joules / square meter): 39.8 Drop yield strength (MPa): 9.9 Drop yield elongation (%): 53 Young's modulus (MPa): 3 80 Composition: 4.2%; j--W11 ------ install -------- order .-------- (Please read the precautions on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperatives. 97 National Standards (CNS) A4 Grid (210 X 297)

Claims (1)

472064 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs i. A polymer that uses ethylene as the first component or monomer, and a branch &quot; association as the second component or monomer, and is at least-different from α-k as the first component or monomer, and at least one of the co-monitoring systems is derived from Flscher-Tropsch to include other associated tobacco from 0.002% to 2% based on the total weight of the co-monomer Common ingredients. 2_ The polymer according to item 1 of the scope of the patent application, wherein the branched α-associated hydrocarbon system is derived from the Fisher's method. 3. The polymer according to item 2 of the Chinese patent application, wherein the branch ^ women's tobacco is 3-methyl-b-butyrene, and other olefin co-ingredients include internal olefins. 4. The polymer according to item 2 of the scope of the patent application, wherein the ... olefin is methyl 1-butene, and the other dilute hydrocarbon constituents include 3_methyl_ 1 _ pentamidine. 5. The polymer according to item i of the scope of the patent application, wherein the different "olefins are derived from the Fisher-Law method. 6. The polymer according to item 5 of the scope of the patent application, wherein the different" enefume systems are linear 0: Association of smoke. The polymer according to claim 6 of the patent application, wherein the linear alpha-hydrocarbon is 1-pentane, and the other olefin component contains 2-methyl-butene. 8. The polymer according to item 6 of the patent specification, in which the linear α 晞 smoke is 1-hexane, and the other olefin components include branched olefins having 6 carbon atoms, internal olefins having 6 carbon atoms, and carbon Number 6 cyclic olefin. 9. The polymer according to item 6 of the patent application, wherein the linear "women and tobacco is 1 heptene, and the other olefin components are branched olefins with carbon number 7, internal olefins with carbon number 7, and Cyclic olefins with carbon number 7. This paper is suitable for China National Standards (CNS) Α4 ^ _ (21 () &gt; &lt; 297 public directors) (Please read the notes on the back before filling this page) Order Φ. 472064 A8 B8 C8 D8 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 6. The scope of patent application K). According to the patent application for the polymer in Item 6, where the linear alpha tobacco is bucinene, and other olefins The composition system includes a branched olefin having 8 carbon atoms, an endogenous hydrocarbon having 8 carbon atoms, and a cyclic olefin having 8 carbon atoms. II. The polymer according to item 6 of the patent application park, wherein the linear "olefin system 1-nonene, and the other olefin components include branched fluorene having 9 carbon atoms, inner andrones having 9 carbon atoms, and cyclic associating hydrocarbons having 9 carbon atoms. 12. The polymer according to any one of claims 6 to 11 of the scope of application for a patent, wherein the branched α-olefin is 3-methyl-butadiene. 13_ The polymer according to item 12 of the scope of patent application, which has the following properties: a) a melting flow rate in the range of 0.001 to 100 g / m min measured according to ASTM D 1238; and, or b) a density in the range of 0 835 to 0950 as measured in accordance with ASTM D 1505; and / or c) when its density is plotted against its reduced tensile strength, it conforms to the following equation: σ &gt; 111 1 p-95.56 where P is the polymer density measured in accordance with ASTM D 1505 'and the drop is the tensile tensile strength measured in accordance with ASTM D 638 M, and the range in which the equation is valid is: &quot; &quot; 〇 · &gt; 0, and 0 · 86 &lt; ρ &lt;0.96; and / or d) When plotting its density with its modulus, it conforms to the following equation: Ε &gt; 3636 β -3090.9 ____: 2- This paper standard uses Chinese national standards (CNS) A4 specification (210X297 public holiday) (Please read the precautions on the back before filling out this page) Order 472064 Λ8 B8 C8 ____ D8 VI. Patent application scope where p is the density of the trimer measured according to ASTM D 1505, and E is the modulus measured according to ASTM D 638 Μ, so that the equation Valid range 14_ According to the scope of the application for patents No. 1 to 〖Le, where the ratio of ethylene mole 'ratio to branched α-olefins and different mole ratios of 99,9: 0.1 to 80:20. 15. According to the polymers in the first one of the range of application patents, the ratio of the molar ratio of the branched α-olefin to the molar ratio of the different α-olefins is from 0.1 to 9 9.9 to 99.9 : 〇. 1. 16. The polymer according to any one of claims 1 to 丨 丨, which is obtained by: in the presence of a catalyst or a catalyst system comprising a catalyst and a co-catalyst, In one or more reaction zones, the ethylene branch α-ene and linear Q: the olefin smoke is reacted with the different olefins, while maintaining the reaction zone at a pressure in the range of atmospheric pressure to 5000 kg / cm2 and a temperature of 300 to ambient Next, the catalyst is obtained as follows: i) Suspending partial water-emulsified magnesium in a highly purified smoke solvent to obtain a magnesium chloride slurry; ii) adding at least one alcohol and an ether to the slurry, and adding Stir the mixture for a period of time to obtain partially activated magnesium fumed magnesium; 1 11) Add the alkyl aluminum compound in a dropwise manner to produce a mixture that is ground to a smooth consistency, and then cooled to a bamboo shoot to obtain activated magnesium fumed magnesium; iv) Wash the activated magnesium with a highly purified hydrocarbon solvent to obtain the ------ __ this paper ^ button towel Guan Jia Pi (CNS) (210 × 297ϋ &quot; --- (Please read the back Note for this page, please fill in this page), 1Τ s'. Ministry of Economic Affairs Printed by the Consumer Standards Cooperative of the Central Bureau of Standards, Pei 472064 8 8 8 8 ABCD ϋ) iii) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 6. Activated magnesium carbonate, which is applied for cleaning in the scope of patents, is a support for the catalyst; ) Add the alcohol mixture to the washed support and then stir to obtain the alcohol-supported support; VI) Add titanium tetrachloride to the alcohol-supported support and stir to form a mixture under reflux for a period of time to obtain Titanium-supported catalyst; and vii) cooling and then washing the titanium-supported catalyst with a highly purified hydrocarbon solvent, followed by drying and pulverization to obtain the catalyst. 17. A polymer according to any one of claims i to i of the scope of patent application, which is carried out in the presence of a catalyst or a catalyst system comprising a catalyst and a co-catalyst in one or more In this reaction zone, ethylene, branched α-associated hydrocarbons, and the different α-olefins are reacted, while the reaction zone is maintained at a pressure in the range of atmospheric pressure to = kg / cm2 and a temperature in the surrounding range to 300 ° C. It is obtained in the following way: ~ 0 Suspend a portion of the typical water magnesium chloride in a highly purified hydrocarbon solvent to obtain a gasified magnesium slurry; add at least one ether to the slurry, and stir the mixture for a period of time to obtain a partially activated Gasification money; filtration and washing partially activated magnesium chloride slurry with a still-purified hydrocarbon solvent until no ether is detected in the washing solution to obtain a partially activated activated magnesium gasification after washing; iv) in a dropwise manner Add the aluminum alkyl compound, and then grind it to a smooth temperature and cool to room temperature to obtain the activated chlorinated town; 〇 Wash the activated gasification town with a purified hydrocarbon solvent at a degree until no alkane is detected in the washing solution Base aluminum to get cleaned Gasified magnesium, this paper is suitable for China National Standard (CNS) A Na_ (21Gx297 (Please read the precautions on the back before filling this page) Scope of patent application A8 B8 C8 D8 The Consumer Cooperative of the Central Standard Vehicle Bureau of the Ministry of Economic Affairs prints the supporting body that composes the catalyst; νι) Add the alcohol mixture to the supporting body that has been washed to the alcohol; VI 1) Alcohol-supported bodies are cleaned with a highly purified hydrocarbon solvent; contained <supported bodies to obtain cleaning VII i) osmium tetrachloride is added to Jingping, and __. Supported bodies, and It was ground to a consistency of 1000 g to obtain a hydrocarbon solvent that was purified with a high degree of purity. # ^ Fl |. The titanium catalyst was first loaded until titanium was not known in the washing solution to obtain the catalyst ^ 18_-A method for manufacturing polymers, this side touches; the pan ugly dagger I in a catalyst or a catalyst system containing a catalyst and a co-catalyst φ anti-flare I I below, one or more In the reaction zone, at least ethylene is used as the second component or monomer, and ΐ = early body, which is different from the branch α associating a ^ free. Ν „Different branch α olefins are used as the 阙 method (F: Γ early # 中 at least—a kind of co-monomer system is derived from Fisher. 002./M: "η.-) so as to include autogenous pressure based on the total weight of the co-monomers. A total of ingredients, while the reaction zone is maintained at a pressure of around big _ kg / sq cm Wan range to 300. . The catalyst is further down, the catalyst is by the following method i) floating part of the anhydrous gasified magnesium county in the combined production ~ contaminated in the degree of purification of pure hydrocarbon solvents to the gasified magnesium slurry; ⑴ at least- A kind of alcohol and a kind of mystery, or (b) at least a kind of ether are added, and the mixture is stirred for a period of time to obtain partially activated magnesium ratate; i) when step (ii) is added to the mass In the middle, the transition and the -5- this paper in Nurai County (^ 7 ^ 7 ^ 29; public fantasy (please read the precautions on the back before filling out this page) Order MW. 472064 8 S 8 $ ABCD VI 、 The scope of the patent application is highly purified hydrocarbon solvent cleaning: washing the partially activated magnesium carbonate slurry until no ether is detected in the washing solution to obtain the partially activated activated magnesium chloride; or iii) | in the step (Ii) When adding (b) to the slurry, wash the partially activated magnesium oxide slurry with a highly purified hydrocarbon solvent until no ether is detected in the washing solution to obtain a washed product. Partially activated magnesium oxide; iv). Add the Yujiming compound in a drop-wise manner, drop it as needed, and grind it to a smooth, thick consistency. 'Then it was cooled to room temperature to obtain activated magnesium carbonate; v) washing the activated magnesium chloride with a highly purified hydrocarbon solvent until no aluminum alkyl was detected in the washing solution to obtain washed activated magnesium carbonate' It constitutes the support of the catalyst; VI) Add the alcohol mixture to the cleaned support and then remove it to obtain the alcohol-supported support; Vii) In step (U), add (1)) When in the slurry, wash the alcohol-bearing support with a highly purified hydrocarbon solvent to obtain the cleaned alcohol-bearing support; printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives (ViH) as the system in step (U) When (a) is added to the slurry, tetra-gasified osmium is added to the washed alcohol-supported body 'and the resulting mixture is discharged under reflux for a period of time to obtain a titanium-supported catalyst; or 11) In the case of adding (b) to the slurry, titanium tetragas is added to the washed alcohol-supported body, and it is ground to the level of flat production to obtain a titanium-supported catalyst; or m 472064 A8 B8 C8 D8 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 6. Application for patents ix) When (a) is added to the slurry in step (ii), it will be cooled down first, then The purified hydrocarbon flux cleans the titanium-supported catalyst, and then dries and powders it to obtain the titanium-supported catalyst; or ix), when (b) is added to the slurry in step (Π), the Purified fe; Gu cut into the washing catalyst, until no titanium was detected in the washing solution to obtain the catalyst. 19. The method according to item 18 of the scope of patent application, wherein the reaction is performed in a batch mode, 'the branched alpha olefin and the different alpha olefin are added together at the beginning of the reaction, and the ethylene is continuously added during the reaction, And no product was removed during the reaction. 20. The method according to item 18 of the scope of patent application, wherein the reaction is performed in a batch manner, the branched a-olefin or a different α-olefin is added at the beginning of the reaction, and the ethylene is continuously added during the reaction, and Continuous or discontinuous supply provides monomer that was not added at the beginning of the reaction and no product was removed during the reaction. 21_ The method according to item 18 of the patent scope of Shenyin, wherein the reaction is performed in a continuous manner, during the reaction, the ethylene system is continuously added, and the branched α 晞 hydrocarbon and the different α olefin are continuously and separately Added, and during the reaction, the product was continuously taken out of the reaction zone. 22. The method according to item 18 of the scope of the patent application, wherein the reaction is performed in a continuous manner. 'During the reaction, the ethylene bromide is continuously added, and the branched alpha olefin is added together and continuously with the different olefins. During the reaction, the product is continuously taken out of the reaction zone. 23. According to the method of claim 1 & of the patent scope, where the response is continuous I paper from the application @ 国 橾 准 （CNS) A4 ^ (21Qx297 公 董) &quot; &quot; '(Please read the back first Please pay attention to this page and fill in this page again) Order s'. 472064 A8 B8 C8 —— ^ _ 08 _____ VI. Patent application method is carried out. During the reaction, ethylene is continuously added, and the branch α and Fe are different from the α-α-hydrocarbon. They are added together and discontinuously, and during the reaction, the product is continuously taken out of the reaction zone. 24_ The method according to item 18 of the scope of patent application 'wherein the reaction is performed in a continuous manner' During the reaction, the ethylene system is continuously added, and the branch β association is different and discontinuous from the different α associated hydrocarbon systems. It was added continuously and the product was continuously taken out of the reaction zone during the reaction. 25. A polymer comprising ethylene as the first component or monomer, at least one branched alkane as the second component or monomer, and at least one different branched alpha olefin as the third component or monomer . 26. The polymer according to item 25 of the scope of patent application, which is a polymer of ethylene and 4-methyl-1-pentene as the second component and 3-methyl- 丨 _pentamidine as the third component. 27. The polymer according to item 25 or 26 of the scope of patent application, which has the following properties: a) Melting in the range of 0.01 to 100 g / 1 () minutes measured according to ASTM D 1238 Flow rate; and / or b) Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumer Cooperatives (measured in accordance with ASTM D 1505) within the range of 0.890 to 0.950 (please read the notes on the back before filling this page). And / or c) When its reduced tensile strength is plotted against its density, it conforms to the following equation: σ> 240 ρ -212.4 where P is the density of the trimer measured according to ASTM D 1505, and σ is according to ASTM D 638 The measured tensile strength of Μ makes the equation -8-i paper size applicable to China's national standard ^ standard YcNS Α4 size (Tl0X297 mm) ^ --- 472064 printed by the Consumer Cooperatives of the Central Ladder Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 Six The valid range of the patent application formula is: σ &gt; 0, and 0.885 &lt; ρ &lt;0.96; and / or d) when the modulus is plotted against its density, it conforms to the following equation: E &gt; 700 / 0.06 ρ-10500 where P is the third measured in accordance with ASTM D 1505 Polymer density, and E is the modulus measured in accordance with ASTM D 638 M. The range in which the equation is valid is: Ε &gt; 0 and 0.9 &lt; ρ &lt;0.96; and / or e) when its impact strength is plotted against its density When it meets the equation: 1> 150 ρ-109 where P is the density of the trimer measured according to ASTM D 1505, and J is the impact strength measured according to ASTM D 256 M. The model that makes the equation valid is: 1 &gt; 20 and 0.86 &lt; ρ &lt; 0_943. 28. The polymer according to item 25 of the scope of the patent application, wherein the branched α-association is 4-methyl-1-pentamidine, and the other α-ene smoke is 3-methyl-fluorene-butane. 29. The polymer according to item 25 or 26 of the scope of patent application, which is in the presence of _ catalyst or a catalyst system comprising a catalyst and a co-catalyst in-or more reaction zones Make azimuth τ, branch α dilute hydrocarbons, and the different α 晞 _ _ -9- This paper size applies the Chinese National Standard (CNS) Α4 specification (210X297 mm) ~ '~~ (Please read the note on the back first Please fill in this page for further information), 1T ΜΨ. 472064 A8 B8 C8 D8 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 6. Application for patent scope response, while maintaining the reaction zone within the range of atmospheric pressure to kg / sq. Under pressure and ambient temperature up to 30 generations, the catalyst is obtained in the following manner: 1. Put some magnesium oxide in a highly purified tincture of magnesium chloride; j Η) Add at least one ether to the polymer In addition, the mixture is mixed to obtain partially activated chlorinated chloride; it is called to add the hydrazone compound in a dropwise manner, and then ground to a consistency, and then cooled to room temperature to obtain the activation gasification error; Hydrocarbon solvent to clean the activated gasification ballast to obtain / 3 washed activated gasified magnesium, which constitutes the support of the catalyst; v) the mixture of alcohol is added to the cleaned support, and then returns to obtain the alcohol-supported support; V1) four gasification Add the cleaned alcohol-supported body and teach the user under reflux: get the mixture-for a period of time to get the catalyst loaded with 及; and VII) clean the titanium-loaded catalyst with solvent purification and then dry And powdered to obtain catalyst. 30. A polymer according to item 25 or 26 of the scope of patent application, which is carried out in one or more reaction zones in the presence of a catalyst or a catalyst system comprising a catalyst and a co-catalyst. , Branch fluorene, and the different women's tobacco reactions, while maintaining the reaction zone at a pressure in the range of atmospheric pressure to 5000 kg / cm2 and the ambient temperature, the catalyst was obtained in the following manner: i) Suspend part of anhydrous gasified magnesium in highly purified hydrocarbon solvent to obtain (Please read the precautions on the back before filling this page) 472064 A8 B8 C8 Read the notes of the memorandum before writing 4 Order # Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 / ZUD4 A8 B8 C8 -------__ VI. Scope of patent application --- = = the first component or monomer, and the second difference: The olefin is used as the third component or monomer, and the reaction zone is maintained at a pressure ranging from atmospheric pressure to 5GG0 kg / million and a surrounding range to 300. (: At the temperature, the catalyst is obtained by the following method: 〇cognition of magnesium chloride is suspended in a highly purified hydrocarbon solvent to obtain a gasified magnesium slurry; U) will (a) at least- An alcohol and an ether, or 0) at least one ether is added to the slurry, and the mixture is stirred for a period of time to obtain a partially activated ratification ball; when (a) is added to the slurry in step (li) , Filtering and washing the partially activated magnesium chloride slurry with a highly purified hydrocarbon solvent until no ether is detected in the washing solution to obtain a partially activated magnesium chloride that has been cleaned; or when in step (ii) (B) When added to the slurry, the partially activated magnesium chloride slurry is washed with a highly purified hydrocarbon solvent, and no ether is detected in the washing solution to obtain a partially activated activated gasified magnesium that has been washed; iv) Add the aluminum alkyl compound in a drop-wise manner. Rinse as needed, grind it to a smooth consistency, and then cool to room temperature to obtain activated magnesium vaporized. v) Wash with highly purified hydrocarbon solvent. This activated gaseous magnesium remains undetected in the wash To the alkyl aluminum to obtain cleaned activated magnesium chloride, which is the support of the catalyst; vi) add the alcohol mixture to the cleaned support ', and then stir to get -12- This paper size applies to China Standard (CNS) A4 specification {210X297 mm) (Please read the precautions on the back before filling out this page), 1T ♦ Sixth, the scope of the patent application to the alcohol-supported support; VU) When the step (11) will be (B) When added to the slurry, the alcohol-supported support is washed with a highly pure solvent to obtain a cleaned alcohol-containing adaptor, and vin) is added in step (li) to the crowd. At the time, titanium tetraoxide is added to the washed alcohol-supported contact, the teeth are drunk, and the obtained substance is stirred under reflux for a period of time to obtain a titanium-containing catalyst; or the system in step (11) When (b) is added to the slurry, titanium tetrachloride is added, the alcohol-supported body is cleaned, and it is ground to a smooth sum to obtain a titanium-supported catalyst; or when it is used in step (11 ) The system is to add ⑷ to many liquids, and the first number =: then wash the catalyst with a highly purified hydrocarbon 嶋, Zhong While drying and powdering it to obtain the catalyst; or ix) Song in step (ii) to obtain Jiang α,) τ system (b) is added to the slurry, with a high slope &lt;k; The grains are cleaned and loaded with the catalyst. Ji S 丨 丨. +, 丄 I ,, ah, until S titanium is not detected in the lotion to obtain the catalyst. 32. According to the patent application No. 3 of the patent park, HB Shi Shiwan removes part of the magnesium chloride and has water between 0.02 and 7 lc / one foot of magnesium fluoride and 2 mol of foot /旲 Early battle • Water content of magnesium. 33. According to the scope of the applied patent No. 3105,... ^ /, The method, wherein the ether is selected from the alcohol range of linear atoms having a total of 8 to 16 carbon atoms. And% is selected from having 2 to 8 carbons. 34. According to the scope of application for the patent No. 31 or 32 # # γ. The method is sufficient, wherein the stirring of the mixture is performed at a temperature of 0C to 14 ° C for Ul 2 hours. Please read Note 1¾ below. I Consumer Consumption Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs. Printed by the Society 472064 Α8 Β8 C8 D8 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs. The method of item 31 or 32, wherein the aluminum alkyl compound has the formula AlRm 'where Rm is a group component having 1 to 10 carbon atoms' and no chlorine is present. 36. The method according to item 31 or 32 of the scope of the patent application, wherein the reaction is performed in a batch manner, the first and second branched alpha olefins are added at the beginning of the reaction, and the ethylene is continuously used during the reaction. Added and no product was removed during the reaction. 37. The method according to item 31 or 32 of the scope of the patent application, wherein the reaction is performed in a batch manner, the first branch is 0; diene or second branch α-olefin is added at the beginning of the reaction, and ethylene is Continuous addition during the reaction, and continuous or discontinuous supply provides monomers' that were not added at the beginning of the reaction and no product was removed during the reaction. 38. The method according to item 31 or 32 of the scope of the patent application, wherein the reaction is performed in a continuous manner. During the reaction, the women's department is continuously added, and the first branch α-carbon · hydrocarbon and the second branch The alpha-ene fume is added together and continuously, and the product is continuously taken out of the reaction zone during the reaction. 39. The method according to item 31 or 32 of the scope of patent application, wherein the reaction is performed in a continuous manner, during the reaction, ethylene is continuously added, and the first branch α-associated hydrocarbon and the second branch α-olefin are They were added successively and the product was continuously taken out of the reaction zone during the reaction. 40. The method according to item 3 丨 or 32 of the patent application park, wherein the reaction is performed in a continuous manner, and during the reaction, the ethylene system is continuously added, and the first branch α-olefin and the second branch α-olefin They are added together and discontinuously, and during the reaction, the product is continuously taken out of the reaction zone. (Please read the precautions on the back before filling in this page) Order Φ: 472064 A8 B8 C8 D8 VI. Application for patent scope 41. According to the method of the scope of patent application No. 31 or 32, the remote reaction is performed in a continuous manner During the reaction, ethylene is continuously added, and the first branched alkane and the second branch β-olefin are added separately and discontinuously, and during the reaction, the product is continuously taken out of the reaction zone. 42_ Method according to item 31 or 32 of the scope of the patent application 'wherein at least one wound or monomer is derived from Fisher's law and includes from 0 to 0 2% to 2% based on the total production of early body Other olefin ingredients. 43. The method according to item 42 of the scope of patent application, wherein the second component or single system is derived from the Fisher's law. 44. The method according to item π of the scope of patent application, wherein the second component or monomer is 4-methyl-1_pinene, and the other olefin component comprises 3_methyl. 1-butene. 45. The method according to item 43 of the scope of the patent application, wherein the second component or monofluorene is 3-methyl-1 -butene, and the other olefin component comprises an intrinsic hydrocarbon. (Please read the notes on the back before filling out this page), 1T s '. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs -15 The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (21〇 × 297 mm) )