TW457730B - Light-emitting device and method for fabricating the same - Google Patents

Light-emitting device and method for fabricating the same Download PDF

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Publication number
TW457730B
TW457730B TW88110078A TW88110078A TW457730B TW 457730 B TW457730 B TW 457730B TW 88110078 A TW88110078 A TW 88110078A TW 88110078 A TW88110078 A TW 88110078A TW 457730 B TW457730 B TW 457730B
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semiconductor layer
light
emitting device
patent application
conductive type
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TW88110078A
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Chinese (zh)
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Sung-Woo Kim
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Lg Electronics Inc
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Abstract

The present invention relates to a light-emitting device characterized by low operating voltage, high luminance, and long life and a method for fabricating the same. An n type semiconductor layer, an active layer, and a p type semiconductor layer are sequentially formed on a substrate and then a part of the n type semiconductor layer is exposed. Subsequently, a current spreading transparent electrode is formed on the p type semiconductor layer and then thermally processed. An n type electrode is then formed on the exposed n type semiconductor layer and a p type electrode is formed on the current spreading transparent electrode.

Description

4 i 7 7 3 Ο …y:充>_____ 五、發明說明(1) 發明背景 1. 發明領域 本發明之發明領域係有關於發光裝置,尤其是發光裝 置及其製造方法’其中該發光裝置的操作電壓相當低,且 照度相當高。 2. 相關技術說明 基本上使用二五族化合物半導體製造藍色發光裝置, 其表示成 I n xGa yA 1 ZN (χ + y + z = 1,0< x< 1,〇< y< 1,〇< 2 < 1 ) o 二五族化合物半導趙為直接透光型式的半導體,其具 有相當高的輻射效率,且相當廣的波長β從黃色區域到紫 色區域’甚至到紫外光區域,因此可使用在短波長的發光 裝置上。 由應用分子束磊晶(ΜΒΕ),金屬有機蒸汽相磊晶 (MOVPE)或含氫蒸汽相磊晶(HVPE)方法製造化合物半導 體。 在MOVPE中’在一基體上,於大氣壓力及低壓力下由 加熱基體’且加有機金屬化合物供應該基體而成長半導體 層’該金屬化合物包含第三族元素,包含第五族元素的粗 材料氣體。 MOVPE的優點為在非常寬的基體上成長均勻且高品質4 i 7 7 3 Ο… y: charge > _____ V. Description of the invention (1) Background of the invention 1. Field of the invention The field of invention of the present invention relates to light-emitting devices, especially light-emitting devices and manufacturing methods thereof, wherein the light-emitting device The operating voltage is quite low and the illumination is quite high. 2. Related technical description Basically, a two- or five-group compound semiconductor is used to manufacture a blue light-emitting device, which is expressed as I n xGa yA 1 ZN (χ + y + z = 1, 0 < x < 1, 0 < y < 1, 〇 < 2 < 1) o Group II and V semiconductors are semiconductors of direct light transmission type, which have relatively high radiation efficiency, and a relatively wide wavelength β from the yellow region to the purple region 'and even the ultraviolet region. Therefore, it can be used in short-wavelength light-emitting devices. Compound semiconductors are manufactured by applying molecular beam epitaxy (MBE), metal organic vapor phase epitaxy (MOVPE) or hydrogen-containing vapor phase epitaxy (HVPE). In MOVPE, a semiconductor layer is grown on a substrate by heating the substrate at atmospheric pressure and low pressure and adding an organometallic compound to the substrate to grow the semiconductor layer. The metal compound contains a Group III element and a coarse material containing a Group V element gas. The advantages of MOVPE are uniform growth and high quality on a very wide substrate

第4頁 ^57730 fS- u f ? ______ 五、發明說明(2) 的三五族化合物半導體。 下文中說明傳統上使用M0VPE成長方法製造藍色發光 裝置的製造。 首先,如圖1 A所示,在一藍寶石基體1 1上分別由磊晶 成長η型砷化氮三五族化合物半導體12’ 一 In xGa n-x)N ( 〇< X < 1 )活化層1 0,及一ρ型砷化氮三五族化合物半導體1 3。 蝕刻Ρ型半導體層1 3及下層活化層1 〇中的特定區域及η 型半導體層12中的一部份,以曝露出η塑半導體層12的一 部份。此後,在約7 0 (TC到1 0 0 CTC的溫度下,進行1 〇秒到 3 0分鐘的熱處理。 進行熱處理以從ρ型半導體層13上去除氫元素,且由 M0VPE成長並包含複雜的氫及摻雜劑Mg。但是無法用於載 送電流的電洞,因此活化摻雜劑Mg(電洞)而允許載送電 流。 但是,在熱處理期間,從ρ型半導體層1 3的上方釋放 氮元素,因此ρ型半導體層13的表面改變為高濃度的η型。 然後,依據下列步驟形成ρ型電極,使得蕭基接觸, 而非歐姆接觸,因此導致在透光電流時將產生錯誤。 此錯誤功能使得發光裝置的操作電壓喪失2 V到3 V,而 增加發光裝置的電阻,因此導致產生些許的熱產生。此將 使得發光裝置的特性變壞’而長期操作時該裴置的壽命將 變短。, 如圖1Β所示,在曝露的η型半導體層12上形成η楚電極 1 4 ’且在約7 0 0度C下進行處理,以在η型電極1 4及η型半導Page 4 ^ 57730 fS- u f? ______ 5. Description of the invention (2) The three or five compound semiconductors. Hereinafter, the manufacturing of a blue light emitting device using the MOVPE growth method is explained. First, as shown in FIG. 1A, n-type nitrogen arsenide three-five compound semiconductors 12'-In xGa nx) N (0 < X < 1) active layers are grown from epitaxial growth on a sapphire substrate 11 respectively. 10, and a p-type nitrogen arsenide three or five compound semiconductor 1 3. A specific region in the P-type semiconductor layer 13 and the lower active layer 10 and a part of the n-type semiconductor layer 12 are etched to expose a part of the n-type semiconductor layer 12. Thereafter, a heat treatment is performed at a temperature of about 70 (TC to 100 CTC) for 10 seconds to 30 minutes. A heat treatment is performed to remove hydrogen element from the p-type semiconductor layer 13, and grow from MOVPE and include complex Hydrogen and dopant Mg. However, it cannot be used for holes that carry current, so the dopant Mg (hole) is activated to allow current to be carried. However, during heat treatment, it is released from above the p-type semiconductor layer 13 Nitrogen, so the surface of the p-type semiconductor layer 13 is changed to a high-concentration n-type. Then, a p-type electrode is formed according to the following steps so that the Schottky contact is made instead of the ohmic contact, so that an error will occur in the transmission current. This error function causes the operating voltage of the light-emitting device to be lost by 2 V to 3 V, and increases the resistance of the light-emitting device, thereby causing a slight heat generation. This will cause the characteristics of the light-emitting device to deteriorate, and the life of the device during long-term operation It will be shorter. As shown in FIG. 1B, an n-type electrode 14 'is formed on the exposed n-type semiconductor layer 12 and processed at about 700 degrees C to make the n-type electrode 14 and the n-type half guide

第5頁 五、發明說明(3) --- 體層1 2之間達到歐姆接觸。 在形成P型電極之前先形成n型電極,此係因為基本 上,在低溫度處理之前需要進行高溫度處理。 隨ΐ =圖1C所示,在P型半導體層13上形成P型電極 15,且在約5〇〇c的溫度下執行熱處理。以在p型電i15及 p型半導體層13之間達到歐姆接觸。 Pi電極15及 最後,如圖1D所示,A 4 A , μ: ^ u 在包含P型電極1 5的p型半導體層 1 3的整個表面上沉積一屉宿 M . / A以奋^ 禮厚度相當薄,約2 0 0埃,而包含 造1程^。机分散透明電極1 6,®此完成了發光裝置的製 明電在極此16ΛΡ型半導體層13的整個表面上形成電流分散透 = 許光從ρ型半導體層13下方的活化層10的整 層1 3的榦〆 出來’其方式為允許電流作用到ρ型半導體 滑1 3的整個表面上。Page 5 V. Description of the invention (3) --- The ohmic contact between the body layers 12 is reached. An n-type electrode is formed before the P-type electrode is formed. Basically, high-temperature processing is required before low-temperature processing. As shown in FIG. 1C, a P-type electrode 15 is formed on the P-type semiconductor layer 13, and a heat treatment is performed at a temperature of about 500c. In order to achieve ohmic contact between the p-type electrical i15 and the p-type semiconductor layer 13. Pi electrode 15 and finally, as shown in FIG. 1D, A 4 A, μ: ^ u deposits a drawer M. / A on the entire surface of the p-type semiconductor layer 13 including the P-type electrode 15 to make a ceremony. The thickness is quite thin, about 200 angstroms, and it includes 1 pass ^. The transparent electrode 16 is dispersed mechanically. This completes the fabrication of the light-emitting device. The entire surface of the 16ΛP-type semiconductor layer 13 forms a current-dispersed transparent layer. = The entire layer of the activation layer 10 is allowed to pass from the p-type semiconductor layer 13 to the light. The drying out of 13 is done in a way that allows a current to be applied to the entire surface of the p-type semiconductor slide 1 3.

日 ί,Ι I 半®Γ ’因為電流分散透明電極16與ρ型半導體層13之 改變成A古再中該p型半導體層已在圖1八的熱處理期間’ 產生在傳南濃度的η型’蕭基接觸相當有效。所以問題係 型電極送電流時。由於不良的電流分佈,所以光只從ρ"I, I I semi-Γ" because the current-dispersing transparent electrode 16 and the p-type semiconductor layer 13 are changed to A. The p-type semiconductor layer has been produced during the heat treatment of Fig. 18, and the η-type is generated at the south concentration. 'The Shaw contact was quite effective. So the problem is when the electrode is supplying current. Due to the poor current distribution, light only flows from ρ

J 如上Γ的周邊中發射出來,所以得到照度變差。 袈置的媒’傳統上使用的發光裝置其缺點為增加發光 少裝署μ作電壓及電阻,減少照度’產生高溫及熱,且減 ν裝置的壽命。Since J is emitted from the periphery of Γ as described above, the illumination intensity is deteriorated. The conventional medium ′ traditionally used light-emitting device has the disadvantages of increasing light emission, reducing installation voltage and resistance, reducing illumination, and generating high temperature and heat, and reducing the life of the device.

第6頁 4i7?30 ;P / ^ if, _ 五、發明說明(4^^^ ~ -- 發明概述 本發明係有關於一發光裝 的方法’其可改進習知技術中 本發明的目的為提供一種 裝置的方法’其中該發光裝置 本發明的另一目的為提供 發光裝置的方法,其中該發光 本發明的另一目的為提供 光裝置的方法,其中經由減少 置的壽命。 由下文中的說明可了解本 中說明,申請專利範圍附圖之 其優點。 為了達成上述目的及優點 造發光裝置的方法,該方法包 別在一基體上形成第一導電型 及第二導電塑式的半導體層; 式半導體層,該下層活化層中 型式的半導體層中的一部份去 式之半導體層中的一部份;第 之半導體層上形成電流分散透 第四步驟:在該曝露的第一導 一導電型式之電極,且在該電 置’及用於製造該發光裝置 一或多個限制及其缺點。 發光裝置及用於製造該發光 的操作電壓相當低。 一種發光裝置及用於製造該 襞置的照度相當高。 一發光裝置及用於製造該發 裝置的熱阻及熱而延長該裝 發明的特徵及優點’而由文 更進一步了解本發明目的及 ,本發明中提供一種用於製 含下列步驟:第一少驟:分 式的半導體層,一活化層’ 第二步驟:將該第二導電型 特定的區域,及該第一導電 除,且曝露出該第〆導電型 三步驟:在該第二導電型式 明電極且進行熱處理;以及 電型式之半導體層上形成第 流分散透明電極上形成一第 卜Page 6 4i7? 30; P / ^ if, _ V. Description of the invention (4 ^^^ ~-Summary of the invention The invention relates to a method of a light-emitting device, which can improve the present invention in the conventional technology. The purpose is A method of providing a device 'wherein the light emitting device has another object of the present invention is a method of providing a light emitting device, wherein the light emitting device has another object of the present invention is a method of providing a light device, wherein the life of the device is reduced. The description can understand the advantages of the description in this specification and the patent application. In order to achieve the above purpose and advantages, a method for manufacturing a light emitting device includes forming a first conductive type semiconductor layer and a second conductive plastic type semiconductor layer on a substrate. ; A semiconductor layer, a part of the semiconductor layer of the type in the lower activation layer, and a part of the semiconductor layer of the type; forming a current dispersion on the semiconductor layer; a fourth step: the exposed first conductive layer; A conductive type of electrode, and one or more limitations and disadvantages of the light-emitting device and the light-emitting device used to make the light-emitting device are relatively low. A light-emitting device and the illuminance used to manufacture the device are relatively high. A light-emitting device and the thermal resistance and heat used to manufacture the device extend the features and advantages of the device invention, and the text further understands the purpose of the invention and The present invention provides a method for manufacturing the following steps: a first step: a fractional semiconductor layer, an activation layer; a second step: removing the specific region of the second conductivity type and the first conductivity, and Three steps of exposing the first conductive type: forming a second electrode of the second conductive type and performing heat treatment; and forming a first dispersed transparent electrode on the semiconductor layer of the electrical type to form a second electrode.

第7頁 4 6 7 7 3 (3 辦年“月4曰修正/更正/補充 五、發明說明(5) ---- 二導電型式電極》 該電流分散透明電極包含從Ni,pd,以,Ti,v, 及Nd中選擇之單一金屬,或其合金’或由該金屬堆疊之多 層金屬。 在非氧或惰性大氣下,於4 〇 〇到丨〇 〇 〇。〇的環境中,對電流 分散透明電極進行1 〇秒到3小時的熱處理。 " 另一方面,本發明提供一種發光裝置包含:一基體; 在該基體上形成一第一導電型式半導體層;在該第—導電 型式半導體層的特定區域上形成活化層;在該活化層上形 成第二導電型式半導體層;在該第二導電型式半導體層上 形成電流分散透明電極;以及在該第一導電塑式半導體層 及該電流分散透明電極上分別形成兩電極。由下文中的說明可更進一步了解本發明之特徵及優 點,閱讀時並請參考附圖。 明 發 本 解 了 步 1 進 更 可 者 術 技 本 習 熟 使 明於 說在 單係 簡圖 之附. 式 圖 構圖 且各 Ϊ1 原 之 明 發 本 明 說 於 用 以 份 部 1 的 書 明 說 成 中 視 ; 部 圖局 視的 部序 局程 的之 序置 程裝 之光 置發 裝造 光製 發明 統發 傳本 造據 製依 示示 D D 1 2 到到 A A 11 ολμ 圖圖 圖Page 7 4 6 7 7 3 (3th of the year of “Amendment / Correction / Supplement V. Explanation of the Invention (5) ---- Two-Conductivity Type Electrode” This current-dispersing transparent electrode consists of Ni, pd, and, A single metal selected from Ti, v, and Nd, or an alloy thereof, or a multilayer metal stacked from the metal. In a non-oxygen or inert atmosphere, the current is in an environment of 4,000 to 100,000. The dispersed transparent electrode is heat-treated for 10 seconds to 3 hours. &Quot; On the other hand, the present invention provides a light-emitting device including: a substrate; a first conductive type semiconductor layer is formed on the substrate; and the first conductive type semiconductor is provided on the substrate. Forming an active layer on a specific region of the layer; forming a second conductive type semiconductor layer on the active layer; forming a current-dispersing transparent electrode on the second conductive type semiconductor layer; and forming the first conductive plastic semiconductor layer and the current Two electrodes are respectively formed on the dispersed transparent electrodes. The features and advantages of the present invention can be further understood from the description below, and please refer to the drawings when reading. This study familiarizes Ming Yushu with a single series of diagrams. The composition of the pattern diagram and the original Mingfa of each Ϊ1 book is described in the book used for the Department 1 as the middle view; The installation of the light installation, the light installation, the light-making system, the invention of the system, the transmission of the production system, according to the instructions DD 1 2 to AA 11 ολμ

第8頁Page 8

,7月%修正/更正/補充 五、發明說明(6) 圖3示本發明及習知技術之電流電壓特性; 圖4示圖2 D之電流分散透明電極的品質下降的照片; 圖5示本發明及習知技術中C-V(電容電壓)量測之電洞 載體濃度。 圖號說明 1 0活化層 11藍寶石基體 1 2珅化氮三五族化合物半導體 13p型半導體層 1 4n型電極 2 0活化層 21藍寶石基體 2 2 η型砷化氮三五族化合物半導體層 23ρ塑砷化氮三五族化合物半導體層 2 4 η型電極 2 5下層活化層 2 7電流分散透明電極 較佳實施例之詳細說明: 下文將詳細說明較佳實施例,附圖中顯示該實施例。 請參考附圖,下文說明發光裝置及用於製造該裝置的Correction / correction / supply of July% V. Description of the invention (6) Figure 3 shows the current and voltage characteristics of the present invention and the conventional technology; Figure 4 shows the photo of the quality degradation of the current-dispersing transparent electrode in Figure 2 D; Hole carrier concentration for CV (capacitance voltage) measurement in the present invention and the conventional technology. Description of the drawing number: 1 0 activation layer 11 sapphire substrate 1 2 nitride tri-V5 compound semiconductor 13p type semiconductor layer 1 4n-type electrode 2 0 activation layer 21 sapphire substrate 2 2 n-type arsenide III-V compound semiconductor layer 23ρ Nitrogen arsenide group III-V compound semiconductor layer 2 4 η-type electrode 25 5 lower active layer 27 7 detailed description of the preferred embodiment of the current-dispersing transparent electrode: The preferred embodiment will be described in detail below, and shown in the accompanying drawings. Referring to the drawings, the following describes a light-emitting device and a device for manufacturing the same

感 57 7 3 L. ^ 濟年,,芹9¾修丑./更^ 五、發明說明(7) 方法。 在說明本發明之前,本發明中使用的項目定義如下。 首先:·,砷化氮三五族化合物半導體”指一含鎵(Ga)第 三族元素的半導體I化物’如GaN,GaAIN,InAlGaN。此 化合物半導體表禾成 ίηχΑ1 yGa(1-x-y)(OS 1,〇‘ yS 1,〇 S x+yS 1)ο 其次,當使用電極時’該項目透光指當從一砷化氮三 五族化合物半導體發出的光佔1 0%時的情況。此項並非指 電極必需無色或透明。 第三’包含至少兩種金屬的金屬材料為這些材料先前 必需是合金’或堆疊這些金屬以形成一多層結構。 當金屬材料包含至少兩種金屬時,此金屬的含量並不 加以限制,但是最好各金屬至少佔1%的原子百分比。 圖二3 2D為截面圖顯示本發明之發光裝置的製造程 序。如圖2儿所示,力目士 »八糾石曰士 e 在具有電絕緣性質的透明藍寶石基體21 上分別蟲晶成長η却;e* vL起 活化層20,及一】二^三五族化合物半導體層22, 一 在此,形成厚择氮三五族化合物半導體層23。 hp 雜如Si,Ge,Se,又約1到5 0 0仁m的n型半導體層22,且摻 易於取得,所以二^的n型雜質。S i為價格最低者,且 在此特予施# 形成此類型的 推薦。 且摻雜如Be,sr,导體層23,其厚度約〇. 2〜100以m, 到,且對應於深声 現 推薦。 …’其摻 已3’ Zn’或Mg之類的雜質。Mg易於得 雜的均勻度特優,在此特予Feeling 57 7 3 L. ^ Ji Nian ,, Qin 9 ¾ Xiu. / More ^ V. Description of the invention (7) Method. Before explaining the present invention, the items used in the present invention are defined as follows. First: ·, Group III-V compound semiconductors of nitrogen arsenide "means a semiconductor I-compound containing Group III elements such as GaN, GaAIN, InAlGaN. This compound semiconductor is composed of ηχΑ1 yGa (1-xy) ( OS 1, 0 'yS 1, 0S x + yS 1) ο Second, when an electrode is used,' this item is light-transmitting refers to a case when light emitted from a group III-5 semiconductor is 10%. This does not mean that the electrode must be colorless or transparent. The third 'metal material containing at least two metals is that these materials must have previously been alloys' or these metals are stacked to form a multilayer structure. When the metal material contains at least two metals, The content of this metal is not limited, but it is preferred that each metal account for at least 1% of the atomic percentage. Figure 2 3D is a cross-sectional view showing the manufacturing process of the light-emitting device of the present invention. Eight rectifier stones e on the transparent sapphire substrate 21 having electrical insulation properties, respectively, worm crystal growth η; e * vL from the activation layer 20, and one] two ^ three five compound semiconductor layer 22, one here, formed Thick nitrogen-selective III-V compound semiconductors Layer 23. hp n-type semiconductor layer 22, such as Si, Ge, Se, and about 1 to 500 n m, and doped easily available, so two n-type impurities. Si is the lowest price, and This special grant # # forms a recommendation of this type. And doping such as Be, sr, conductor layer 23, its thickness is about 0.2 to 100 to m, and corresponds to the current recommendation of deep sound.… '其 incorporating has 3 Impurities such as 'Zn' or Mg. Mg is easy to get impurities with excellent uniformity.

第10頁 S??3Page 10 S ?? 3

'發明說明1 使用 p'Invention note 1 using p

份,P型丰道中的活化離子蝕刻n型半導體層2 2中的一部 出_層?%體23及下層活化層2〇中特定的區域,可曝露 W的一部份。 上,i ϊ 1 i圖2Β所示,在Ρ型半導體層23的整個表面 熱處理LV Α有微透光的電流分散透明電極2 5,且然後執行 到歐姆接觸P型半導體層23及電流分散透明電極25之間得 钱觸’且活化P型半導體層2 3。 在此’電流分散透明電極25可由某一適當的金屬材料 形成。金,材料可為從,Pd,Cr,Ti , v, Zr,Ce及Nd 中選擇的單一金屬,此金屬可從p型半導體層23,該類金 屬之合金,或堆疊某些金屬之多層金屬中吸收氫。 如果電流分散透明電極2 5包含此金屬,且電流分散透 明電極25從p型半導體層23的上表面中吸收金屬。此允許 在p型半導體層2 3及電流分散透明電極2 5之間得到相當良 好的歐姆接觸。 結果’在p型半導體層2 3及電流分散透明電極25之間 的電壓降減少’因此整個發光裝置的操作電壓只滅少一 些0 在本發明的實施例中,在T i,pd及―的多層結構中形 成電流分散透明電極2 5 ** 即’在p型半導體層2 3上形成τ i,且然後分別在T i上 堆疊P dA N i。Part, the active ion in the P-type channel etches a part of the n-type semiconductor layer 22? Part of the body 23 and the lower activation layer 20 may expose a part of W. In the above, i ϊ 1 i as shown in FIG. 2B, the entire surface of the P-type semiconductor layer 23 is heat-treated. LV A has a light-transmitting current-dispersing transparent electrode 25, and then performs ohmic contact with the P-type semiconductor layer 23 and the current-dispersing transparent. The electrodes 25 touch each other, and the P-type semiconductor layer 23 is activated. Here, the 'current-dispersing transparent electrode 25 may be formed of a suitable metal material. Gold, the material can be a single metal selected from Pd, Cr, Ti, v, Zr, Ce, and Nd. This metal can be selected from the p-type semiconductor layer 23, an alloy of such metals, or a multilayer metal in which certain metals are stacked. Absorbs hydrogen. If the current-dispersing transparent electrode 25 contains this metal, and the current-dispersing transparent electrode 25 absorbs the metal from the upper surface of the p-type semiconductor layer 23. This allows a fairly good ohmic contact to be obtained between the p-type semiconductor layer 23 and the current-dispersing transparent electrode 25. As a result, the voltage drop between the p-type semiconductor layer 23 and the current-dispersing transparent electrode 25 is reduced. Therefore, the operating voltage of the entire light-emitting device is only reduced by a small amount. In the embodiment of the present invention, between T i, pd and- A current-dispersed transparent electrode 2 5 ** is formed in the multilayer structure, that is, τ i is formed on the p-type semiconductor layer 23, and then P dA N i is stacked on T i, respectively.

在熱處理期間’可形成具有多層結構的透明電極2 5之 合金。During the heat treatment, an alloy of the transparent electrode 25 having a multilayer structure can be formed.

第11頁 /? 正/更正/補充 五、發明說明(9) 此時’可在約50(TC的溫度或更高的溫度下進行熱處 理°如果電流分散透明電極2 5在低於5 0 0°C以下的溫度處 理熱處理,則不可能達成良好的歐姆接觸,且p型半導體 層2 3不活化’因此表示逹成發光電流的應用β 所以’熱處理的溫度需要低於坤化氮三五族化合物半 導體的分解溫度(低於約120(rc ),且低於用於電流分散透 明電極25之金屬材料的降級點(degradation point)。 在本發明的實施例中’在約400到1 〇〇〇。〇之間執行熱 處理,適當的溫度為5 0 0到7 0 (TC 〇Page 11 /? Correction / Correction / Supplementary V. Description of the invention (9) At this time, the heat treatment can be performed at a temperature of about 50 (TC or higher). If the current disperses the transparent electrode 2 5 at less than 5 0 0 If the heat treatment is performed at a temperature below ° C, it is impossible to achieve a good ohmic contact, and the p-type semiconductor layer 2 3 is not activated. The decomposition temperature of the compound semiconductor (below about 120 (rc), and lower than the degradation point of the metal material for the current-dispersing transparent electrode 25. In the embodiment of the present invention, it is' about 400 to 100. The heat treatment is performed at a temperature between 500 and 70 (TC 〇).

而且’熱處裡進行1 0秒鐘到3小時。尤其是,較適當 的時間為約2 0分鐘到一小時。最好,在惰性體,或者是在 如氮(Ν2)的非氧大氣中進行。 如果在上述情況下’進行熱處理,則可減少ρ型半導 體層23的特定電阻率。 此係因為在400°C的溫度或更高的溫度下,結合於口型 半導體層23内之受體雜質的氮元素將消失,因此活化受體 雜質。 在習知技術中為了減少ρ型半導體層23中特定的電阻 率’將如GoN’ AIN,I nN等的絕緣層加入ρ型坤化氮半導體 層中’所以可防止氮元素從ρ型氮化砷半導體層的表面上 消失。Moreover, it is performed in a hot place for 10 seconds to 3 hours. In particular, a more appropriate time is about 20 minutes to one hour. Preferably, this is done in an inert body or in a non-oxygen atmosphere such as nitrogen (N2). If the heat treatment is performed in the above case, the specific resistivity of the p-type semiconductor layer 23 can be reduced. This is because at a temperature of 400 ° C or higher, the nitrogen element of the acceptor impurity bound in the lip type semiconductor layer 23 will disappear, thereby activating the acceptor impurity. In order to reduce the specific resistivity in the p-type semiconductor layer 23 in the conventional technology, 'insulating layers such as GoN' AIN, I nN, etc. are added to the p-type kuni nitrogen semiconductor layer ', so that the nitrogen element can be prevented from being p-type nitrided. The arsenic semiconductor layer disappeared on the surface.

在本發明中,因為在電流分散透明電極25沉積後,進 行熱處理,所以在沉積透明電極25處產生局部的高熱導, 因此可得到良好的活化受體雜質。In the present invention, since the heat-dissipating transparent electrode 25 is subjected to heat treatment after deposition, a locally high thermal conductance is generated at the deposited transparent electrode 25, so that a good activated acceptor impurity can be obtained.

第12頁 457 73 / $年"月修正/星^稀龙 五、發明說明(ίο) " - 雷搞^且Pd,Ti’ V,Zr,Ce或⑽形成透明 =ί ^二特徵為可吸收在p型半導體層23中的氫元素’ 又體雜質的活化中作為一觸媒,且使得半導體層 具有較低的電阻β 另外,因為在ρ型半導體層23及透明電極“之間的介 面處形成優良的歐姆接觸,所以其優點為可使得透明電極 2 5及姓半導體層2 3之間介面處的電壓降達到最小。 作為透明電極2 5的金屬材料其厚度為丨〇到工〇 〇 〇 〇埃之 間。尤其是最好是厚度介於1〇〇到1〇〇〇埃之間。 9 w ί 透明電極25的某些金屬材料擴散過p型半導體層 23的内側,且某些透明電極則在熱處理期間向外擴散。 =果透明電極25比100埃薄,則金屬本身的電阻傾向 L 夕卜,如果透明電極25的厚度 '約1 0 0 0埃,則如圖 不,約5 0 0到700度c的熱處理期間,金屬表面將會變 質。 ,圖2 C所不’在完成熱處理後,在n塑半導體層2 2曝 露部位上形成η型電極24。廣泛使用乜τ· A1 τ ...Page 12 457 73 / $ year " month correction / star ^ thin dragon five, description of invention (ίο) "-Lei ^^ and Pd, Ti 'V, Zr, Ce or ⑽ form transparency = ^ The second feature is The hydrogen element 'that can be absorbed in the p-type semiconductor layer 23 acts as a catalyst in the activation of impurities, and makes the semiconductor layer have a lower resistance β. In addition, because between the p-type semiconductor layer 23 and the transparent electrode " An excellent ohmic contact is formed at the interface, so it has the advantage that the voltage drop at the interface between the transparent electrode 25 and the semiconductor layer 23 can be minimized. The thickness of the metal material as the transparent electrode 25 is from 0 to 0. Between 100 and 100 angstroms. Especially preferably, the thickness is between 100 and 1000 angstroms. 9 w Some metal materials of the transparent electrode 25 diffuse through the inside of the p-type semiconductor layer 23, and some These transparent electrodes diffuse outward during the heat treatment. = If the transparent electrode 25 is thinner than 100 Angstroms, the resistance of the metal itself tends to L. If the thickness of the transparent electrode 25 is about 100 Angstroms, as shown in the figure, During heat treatment at about 500 to 700 degrees c, the metal surface will deteriorate. FIG 2 C are not 'after completion of the heat treatment, η-type electrode on the exposed n exposed portion of the semiconductor layer 22 of plastic widely used NIE 24. τ · A1 τ ...

Ci之類的金屬作為η型電極24的材料。1 11 1及 母丨丰ίΪΪ明” ,形心型電極24, Μ式為在η 孓+導體層22上形成厚度約〗〇埃的^層,在c 度約2 0 〇埃的τ i層,且在τ i層上开;f忠ώ 厚 層。 啦增上形成厚度約200 0埃的Α1 如蒸發或電鍍形成η型電極 在此,現在使用的方法, 24。 457 7 3ι 五、發明說明(Π) ~~~~ 使用熱處理或不使用熱處理,均可形成η型電極的金 為η型半導體層在表面上缺乏氮元素,且因為在活 化電流分散透明電極2 5及ρ型半導體層2 3之熱處理期間, f濃度的η型半導體層之故,所以不見得一定需要進 處理。 恐 如果進行熱處理’則在約5 〇 〇到9 0 0°C的溫度進行1 〇和、 到3 0 0分鐘的熱處理。 ’ 隨後,如圖2D所示’在ρ型半導體層23上形成口型 2 6以在最後執行。 P型電極2 6進行一種墊電極,以在發光裝置的封裝期 =,進行打線之用,形成一金屬材料以防止長期操作裝置 時,在打線期間使用的Au球擴散,且滲透過口型半導體 2 3° 甚 。、用於ρ型電極2 6的金屬材料並沒有特別的限制,但是 可為下列具代表性且廣泛使用之金屬材料中的一項或數項 之結合,該金屬材料為Cr,Ni, Au,In,Pt,Mo,pd,A metal such as Ci is used as a material of the n-type electrode 24. 1 11 1 and its mother 丨 Feng Liming ", the centroid electrode 24, Μ formula is to form a ^ layer with a thickness of about 0 angstrom on the η 孓 + conductor layer 22, and a τ i layer of about 200 angstrom at c degrees And on top of the τ i layer; f is thick and thick. Lazeng forms A2 with a thickness of about 200 angstroms, such as evaporation or electroplating to form a η-type electrode. Here, the method currently used, 24. 457 7 3ι V. Invention Explanation (Π) ~~~~ Gold can form η-type electrodes with or without heat treatment. The η-type semiconductor layer lacks nitrogen on the surface, and the transparent electrode 25 and ρ-type semiconductor layer are dispersed by the activation current. During the heat treatment of 23, the η-type semiconductor layer with a concentration of f may not necessarily need to be processed. If the heat treatment is performed, the temperature of about 10 and 3 is performed at a temperature of about 5000 to 900 ° C. The heat treatment is performed for 0 minutes. 'Subsequently, as shown in FIG. 2D, a mouth shape 26 is formed on the p-type semiconductor layer 23 to be performed last. The P-type electrode 26 is subjected to a pad electrode during the packaging period of the light emitting device = , For wire bonding, forming a metal material to prevent long-term operation of the device, wire bonding The Au spheres used here diffuse and penetrate through the mouth semiconductor 2 3 °. The metal materials used for the p-type electrode 26 are not particularly limited, but can be among the following representative and widely used metal materials A combination of one or more items, the metal material is Cr, Ni, Au, In, Pt, Mo, pd,

Ge’ Si, Ti, W, Zr, Ta, Cu, Pb, Ag, Sn及 Zn。 、在本發明的實施例中,p型電極26包含三層金屬,分 別為先形成具有優良附著性的Cr,在CrV|上形成厚度約 3〇〇埃的Νι層’及在Ni層上形成厚度約2〇〇〇埃的^層。 在元成沉積三層金屬後,進行3 0秒到3 0分鐘的熱處 理,其處理厚度約為5 〇 〇到7 0 CTC,以增強在電流分散透明 電極2 5及ρ型電極2 6的内聚力。Ge 'Si, Ti, W, Zr, Ta, Cu, Pb, Ag, Sn and Zn. In the embodiment of the present invention, the p-type electrode 26 includes three layers of metal, respectively, firstly forming Cr with excellent adhesion, forming a Ni layer with a thickness of about 300 angstroms on CrV | and forming it on the Ni layer. A layer with a thickness of about 2000 Angstroms. After Yuancheng deposits three layers of metal, heat treatment is performed for 30 seconds to 30 minutes, and the treatment thickness is about 500 to 70 CTC to enhance the cohesion of the current-dispersing transparent electrode 25 and the p-type electrode 26. .

第14頁 457730 更正 Z 補充------—^ 五、發明說明(12) 依據本發明說明之處理製造之發光裝置的實施例其測 試方式說明如下: 第一實施例: 在本發明的第一實施例中,依據下列方式形成電流分 散透明電極:在p型半導體層下形成厚度約10埃的Ti’在 T i層上形成厚度約5 〇埃的pd,在Pd層上形成厚度约50埃的 N卜 然後在約7 0 (TC的溫度下,進行約3 0分鐘的熱處理, 以活化p型半導體層。 ^ μ A々眘她你丨的電流電壓特性將加以比Page 14 457730 Correction Z Supplement ---------- ^ V. Description of the Invention (12) An embodiment of the light-emitting device manufactured in accordance with the process described in the present invention is described in the following test mode: First embodiment: In the present invention, In the first embodiment, a current-dispersing transparent electrode is formed according to the following method: Ti ′ is formed under the p-type semiconductor layer to a thickness of about 10 angstroms; pd is formed on the Ti layer to a thickness of about 50 angstroms; 50 angstrom Nb is then subjected to a heat treatment at a temperature of about 70 ° C. for about 30 minutes to activate the p-type semiconductor layer. ^ ΜA々 her current and voltage characteristics will be compared

依據上述步驟製造之實施w J 較,且其結果顯示在圖3中。 曲線B指示依據習知技術製造之發光裝置的電流電壓 特徵,在此該裝置的電Is且為7,且產生更多的熱°而 且,照度為20mcd。 依據指示本發明之電流電壓特性之線A及習知技術之 線B的比較,可看出臨界電壓改進2-3V’且操作電壓改進 約3至4V。 而且,該裝置的電阻少於3 0Ω,且與習知技術比較, 產生的熱減少約50%,而照度改進約35mcd。 同時,如果由圖5所示之C-V(電容電壓)之量測的濃度 分佈看來,可知P型半導體層之雜質濃度從2x 1 0 l7cm -3(圖5 中的線B)(習知技術中的方法方法)增加到2x 1 〇 18cnr3(圖5 的線A ),其增加了 1 〇倍。An implementation w J comparison based on the above steps was performed, and the results are shown in FIG. 3. Curve B indicates the current-voltage characteristics of the light-emitting device manufactured according to the conventional technology, where the electrical Is of the device is 7 and more heat is generated, and the illuminance is 20 mcd. Based on a comparison of line A indicating the current-voltage characteristics of the present invention and line B of the conventional technology, it can be seen that the threshold voltage is improved by 2-3V 'and the operating voltage is improved by about 3 to 4V. Moreover, the resistance of the device is less than 30Ω, and compared with the conventional technology, the heat generated is reduced by about 50%, and the illuminance is improved by about 35mcd. At the same time, if the concentration distribution measured by the CV (capacitance voltage) shown in FIG. 5 appears, it can be seen that the impurity concentration of the P-type semiconductor layer is from 2 × 1 0 to 7 cm -3 (line B in FIG. 5) (the conventional technique The method in the method) is increased to 2 × 1018cnr3 (line A in FIG. 5), which is increased by 10 times.

第15頁 457730 五、發明說明(13) 看該項量測的結果,可看出很多的氫元素從P型半導 體層中逃逸出來,且為電流分散透明電極吸收,而從P型 半導體層中逃逸的氫元素有助於電洞載體的濃度。 第二實施例 在本發明的第二實施例中使用與第一實施例的相同的 狀態,唯p型半導體的熱處理係在約6 0 0度C的溫度下進行 3 0分鐘。 此實施例發光裝置的特徵為臨界電壓為2. 4伏,操作 電壓為3. 5 V,而電阻小於3 5Ω,且照度約3 5 m c d。 第三實施例 本發明的第三實施例中的狀態同於第一實施例,唯在 約5 0 0°C下對p型半導體進行3 0分鐘的熱處理》 在實施例的發光裝置其特性為臨界電壓為2. 7V,操作 電壓為3. 9 V,電阻少於4 0Ω。第三實施例之品質比第一及 第二實施例下降更多。此係因為P型半導體的活化小於第 二及第三實施例之故。此實施例的照度為30mcd。 第四實施例 在本發明的第四實施例中,電流分散透明電極之形成Page 15 457730 V. Description of the invention (13) Looking at the measurement results, it can be seen that many hydrogen elements escape from the P-type semiconductor layer and are absorbed by the current-dispersing transparent electrode, but from the P-type semiconductor layer. The escaping hydrogen element contributes to the concentration of the hole carrier. Second Embodiment In the second embodiment of the present invention, the same state as in the first embodiment is used, except that the heat treatment of the p-type semiconductor is performed at a temperature of about 600 ° C for 30 minutes. The light-emitting device of this embodiment is characterized in that the critical voltage is 2.4 volts, the operating voltage is 3.5 V, the resistance is less than 35 Ω, and the illumination is about 3 5 m c d. Third Embodiment The state of the third embodiment of the present invention is the same as that of the first embodiment, except that the p-type semiconductor is heat-treated at about 500 ° C for 30 minutes. In the light-emitting device of the embodiment, the characteristics are The critical voltage is 2. 7V, the operating voltage is 3. 9 V, and the resistance is less than 40 Ω. The quality of the third embodiment is much lower than that of the first and second embodiments. This is because the activation of the P-type semiconductor is smaller than that of the second and third embodiments. The illuminance of this embodiment is 30 mcd. Fourth Embodiment In a fourth embodiment of the present invention, the formation of a current-dispersing transparent electrode

第16頁 ^57730 巧年/丨TplB修i〖::· /更正/鍵充Page 16 ^ 57730 Qiaonian / 丨 TplB repair i :: · / correction / key charge

積厚度約1〇〇埃的Ni, 且在 五、發明說明(14) 方式為:在P型半導體層上沉 層上沉積厚度約1 00埃的Au。 然後在約7 0 0°C的溫度下, 鐘的熱處理。 結果,第四實施例之發光裝置的電流電壓 實施例相同。 第五實施例 對P塑半導體層進行約3〇分 徵與第 在本發明的第五實施例中’電流分散透明 方式為:在p型半導體層上形成厚度約2〇〇埃的^極,形成 上形成厚度約30 0埃的Ni,在Ni層上形成厚度約2〇 f Cr層 Al^與第一到第四實施例不同之處為不執行形成$的 2 6之最後處理》 收電極 第五實施例之發光裝置其特性為臨界電壓為3 作電壓為5.6V’電阻為58Ω,且照度為2〇mcde太厚接 明電極的表面質降導致圖4中所示的狀態。此係因=透 的 透明電極截斷該裝置發出的光,導致照度變差 本發明的發光裝置及依據本發明製造發光裝置 具有下列功效: 、万法 本發明使裝置的操作電壓下降,且擴大電流作用之 型半導體層面積,也擴大可使用的發光區域。結果,、p 裝置的照度增加。 光 另外,本發明減少裝置的電阻,因此減少熱產. ⑦王及功The thickness of Ni is about 100 angstroms, and in the fifth aspect of the invention (14), Au is deposited on the P-type semiconductor layer to a thickness of about 100 angstroms. The bell is then heat treated at a temperature of about 700 ° C. As a result, the current-voltage embodiment of the light-emitting device of the fourth embodiment is the same. In the fifth embodiment, the P-plastic semiconductor layer is divided into about 30 points. In the fifth embodiment of the present invention, the current distribution and transparency method is: forming a thickness of about 200 angstroms on the p-type semiconductor layer, Ni is formed at a thickness of about 300 Angstroms, and a layer of Cr is formed at a thickness of about 20 Å on the Ni layer. The difference from the first to fourth embodiments is that the final processing of forming 2 to 6 is not performed. The characteristics of the light-emitting device of the fifth embodiment are that the critical voltage is 3, the voltage is 5.6 V ', the resistance is 58 Ω, and the illuminance is 20 mcde. The surface quality of the exposed electrode is too thick, resulting in the state shown in FIG. This is because the transparent electrode intercepts the light emitted by the device, resulting in poor illumination. The light-emitting device of the present invention and the light-emitting device manufactured in accordance with the present invention have the following effects: 1. The present invention reduces the operating voltage of the device and increases the current. The area of the active semiconductor layer also expands the usable light emitting area. As a result, the illuminance of the p device increases. Light In addition, the present invention reduces the resistance of the device and therefore reduces the thermal output. ⑦ 王 及 功

第17頁 4易^日修j£ /更正/補充 五、發明說明(15) 率耗損。結果,裝置的品質慢慢下降,所以改進裝置的壽 命及可靠度。 此短波長的發光裝置可使用在自然色彩之LED顯示 器,LED導光,具有低功率耗損的導引資訊顯示及電信 號,因此本發明在工業上非常有效。 雖然文中已應較佳實施例說明本發明中的發光裝置及製造 發光裝置的方法,但嫺熟本技術者需了解可對上述實施例 加以更改及變更,而不偏離本發明的精神及觀點。P.17 4E ^^ Repair j £ / Correction / Supplement V. Description of the invention (15) Rate loss. As a result, the quality of the device gradually decreases, so the life and reliability of the device are improved. This short-wavelength light-emitting device can be used in natural-color LED displays, LED light guides, guidance information displays and telecommunications signals with low power consumption, so the present invention is very effective industrially. Although the light emitting device and the method of manufacturing the light emitting device in the present invention have been described in the preferred embodiments, those skilled in the art need to understand that the above embodiments can be modified and changed without departing from the spirit and perspective of the present invention.

第18頁 457730 Ά年”月4日修正/更正./補充 圖式簡單說明 圖式之簡單說明 附圊係在於使熟習本技術者可更進一步了解本發明, 且構成說明書的一部份,以用於說明本發明之原理。 各圖中: 圖1A到1D示製造傳統發光裝置之程序的局部視圖; 圖2A到2D示依據本發明製造發光裝置之程序的局部視 圖; 圖3示本發明及習知技術之電流電壓特性; 圖4示圖2D之電流分散透明電極的品質下降的照片; 圖5示本發明及習知技術中C-V(電容電壓)量測之電洞 載體濃度。Page 18 457730 "Year of the year" on the 4th of the month, amended / corrected. / Supplementary Schematic Description of the Schematic Description of the Schematic is attached to enable those skilled in the art to further understand the present invention, and forms a part of the specification to It is used to explain the principle of the present invention. In the drawings: FIGS. 1A to 1D are partial views of a process for manufacturing a conventional light-emitting device; FIGS. 2A to 2D are partial views of a process for manufacturing a light-emitting device according to the present invention; Current-voltage characteristics of the conventional technique; FIG. 4 shows a photo of the quality degradation of the current-dispersing transparent electrode of FIG. 2D; and FIG. 5 shows the hole carrier concentration measured by CV (capacitance voltage) measurement in the present invention and the conventional technique.

第19頁Page 19

Claims (1)

Ψ鳳…。,遍__ 六、申請專利範圍 1. 一種製造發光裝置的方法,該方法包含下列步驟: 第一步驟:分別在一基體上形成第一導電型式的半導 體層,一活化層,及第二導電型式的半導體層; 第二步驟:將該第二導電型式半導體層,該下層活化 層中特定的區域,及該第一導電型式的半導體層中的一部 -份去除,且曝露出該第一導電型式之半導體層中的一部 _ 份; 第三步驟:在該第二導電型式之半導體層上形成電流 分散透明電極且進行熱處理;以及 第四步驟:在該曝露的第一導電型式之半導體層上形 成第一導電型式之電極,且在該電流分散透明電極上形成 一第二導電型式電極。 2 .如申請專利範圍第1項之製造發光裝置的方法,其 中該基體包含藍寶石。 3. 如申請專利範圍第1項之製造發光裝置的方法,其 中該第一導電型式之半導體層包含η型砷化氮三五族化合 物半導體,且該第二導電型式之半導體層包含Ρ型砷化氮 . 三五族化合物半導體。 4. 如申請專利範圍第3項之製造發光裝置的方法,其 中該η型砷化氮三五族化合物半導體及該ρ型砷化氮三五族 ^ 化合物半導體包含GaN,GaAIN, InGaN及InAlGaN中的一 項。 5. 如申請專利範圍第3項之製造發光裝置的方法,其 - 中該η型砷化氮三五族化合物半導體摻雜S i,G e,S e,S及Wu Feng ... , __ VI. Patent Application Scope 1. A method for manufacturing a light-emitting device, the method includes the following steps: First step: forming a semiconductor layer of a first conductivity type, an activation layer, and a second conductivity on a substrate, respectively. Type semiconductor layer; second step: removing a part of the second conductive type semiconductor layer, a specific region in the lower active layer, and the first conductive type semiconductor layer, and exposing the first A part of the semiconductor layer of the conductive type; the third step: forming a current-dispersing transparent electrode on the semiconductor layer of the second conductive type and performing heat treatment; and the fourth step: the exposed semiconductor of the first conductive type An electrode of a first conductivity type is formed on the layer, and a second conductivity type electrode is formed on the current-dispersing transparent electrode. 2. A method of manufacturing a light emitting device according to item 1 of the patent application, wherein the substrate comprises sapphire. 3. The method for manufacturing a light-emitting device according to item 1 of the patent application, wherein the semiconductor layer of the first conductivity type includes an η-type arsenide group III-V compound semiconductor and the semiconductor layer of the second conductivity type includes P-type arsenic Nitrogen. Three or five compound semiconductors. 4. The method for manufacturing a light-emitting device according to item 3 of the application, wherein the n-type arsenide III-V compound semiconductor and the p-type arsenide III-V compound semiconductor include GaN, GaAIN, InGaN, and InAlGaN. Of one. 5. The method for manufacturing a light-emitting device according to item 3 of the patent application, wherein the n-type arsenide III-V compound semiconductor is doped with Si, Ge, Se, S and 第20頁 457 73 0 月/fe修.;;:._/更正/補充 -_ 六、申請專利範圍 Te中的一項,且該p型砷化氮三五族化合物半導體摻雜 Be,Sr, Ba, Zn及 Mg中的一項。 6 .如申請專利範圍第1項之製造發光裝置的方法,其 中形成厚度約1到50〇v m的第一導電型式之半導體層,且 形成厚度約0. 2到1 0 0/z m之第二導電型式的半導體層。 7. 如申請專利範圍第1項之製造發光裝置的方法,其 中該電流分散透明電極包含從Ni,Pd,Cr,Ti,V,Zr, Ce及Nd中選擇之單一金屬,或其合金,或由該金屬堆疊之 多層金屬。 8. 如申請專利範圍第7項之製造發光裝置的方法,其 中該多層金屬包含了丨^ P d及N i。 9. 如申請專利範圍第1項之製造發光裝置的方法,其 中該三步驟中的熱處理係在非氧或惰性氣體的大氣中,於 4 0 0到1 0 0°C的溫度下,進行1 0秒到3小時。 1 0 .如申請專利範圍第1項之製造發光裝置的方法,其 中形成厚度約1 0到1 0 0 0 0埃之電流分散透明電極。 11.如申請專利範圍第1項之製造發光裝置的方法,其 中該第一導電型式電極包含從Ti,Al,In,Ni,及Cr中選 擇出來之單一金屬,或這些金屬的合金,或這些金屬堆疊 的多層金屬。 1 2.如申請專利範圍第1項之製造發光裝置的方法,其 中該第二導電型式電極包含從Cr,Ni,Al,In,Pt,Mo, P d,G e,S i,T i,W,Z r,T a,C u,P b,A g,S n,及 Z n 中 選擇之單一金屬,其中一些金屬的合金,或這些金屬中一Page 20 457 73 0 month / fe repair. ;;: .// correction / supplement-_ VI. One of the patent application scope Te, and the p-type nitrogen arsenide III-V compound semiconductor is doped with Be, Sr , Ba, Zn and Mg. 6. The method for manufacturing a light emitting device according to item 1 of the scope of patent application, wherein a semiconductor layer of a first conductive type having a thickness of about 1 to 50 vm is formed, and a second layer having a thickness of about 0.2 to 100 / zm is formed. A conductive type semiconductor layer. 7. The method for manufacturing a light-emitting device according to item 1 of the patent application scope, wherein the current-dispersing transparent electrode comprises a single metal selected from Ni, Pd, Cr, Ti, V, Zr, Ce, and Nd, or an alloy thereof, or Multiple layers of metal stacked from this metal. 8. The method of manufacturing a light-emitting device according to item 7 of the patent application, wherein the multilayer metal includes Pd and Ni. 9. The method of manufacturing a light-emitting device according to item 1 of the scope of patent application, wherein the heat treatment in the three steps is performed in a non-oxygen or inert gas atmosphere at a temperature of 400 to 100 ° C. 0 seconds to 3 hours. 10. The method for manufacturing a light-emitting device according to item 1 of the scope of patent application, wherein a current-dispersing transparent electrode having a thickness of about 10 to 100 angstroms is formed. 11. The method for manufacturing a light-emitting device according to item 1 of the patent application, wherein the first conductive type electrode comprises a single metal selected from Ti, Al, In, Ni, and Cr, or an alloy of these metals, or these Metal stack of multiple layers of metal. 1 2. The method for manufacturing a light-emitting device according to item 1 of the scope of patent application, wherein the second conductive type electrode comprises Cr, Ni, Al, In, Pt, Mo, P d, G e, S i, T i, W, Z r, Ta, Cu, P b, Ag, Sn, and Z n selected from a single metal, an alloy of some of these metals, or one of these metals 第21頁 457730 的年丨(fid日甚庀/争正/铺赤._ 六、申請專利範圍 些金屬之堆疊的多層金屬。 1 3 .如申請專利範圍第1項之製造發光裝置的方法,其 中該第四步驟更進一步包含下列步驟: 在該曝露的第一導電型式之半導體層上形成第一導電 型式電極,且執行熱處理;以及 在該電流分散透明電極上形成第二導電型式電極,且 執行熱處理。 1 4.如申請專利範圍第3項之製造發光裝置的方法,其 中在形成第一導電型式電極後,在5 0 0到9 0 0°C的溫度下進 行1 0秒到3 0分鐘的熱處理。 1 5.如申請專利範圍第1 3項之製造發光裝置的方法, 其中該形成該第二導電型式電極後,在5 0 0到7 0 0°C的溫度 下,進行3 0秒到3 0分鐘的熱處理。 16.—種發光裝置包含: 一基體; 在該基體上形成一第一導電型式半導體層; 在該第一導電型式半導體層的特定區域上形成活化 層; 在該活化層上形成第二導電型式半導體層; 在該第二導電型式半導體層上形成電流分散透明電 極;以及 在該第一導電型式半導體層及該電流分散透明電極上 分別形成兩電極。 1 7.如申請專利範圍第1 6項之發光裝置,其中該基體Page 21, year 457730 (fid date is very low / continued / paved. _ 6. Multi-layer metal stacking of some metals for patent application. 1 3. If the method of manufacturing a light-emitting device in the first patent application scope, The fourth step further includes the following steps: forming a first conductive type electrode on the exposed semiconductor layer of the first conductive type and performing heat treatment; and forming a second conductive type electrode on the current-dispersing transparent electrode, and The heat treatment is performed. 4. The method of manufacturing a light emitting device according to item 3 of the patent application scope, wherein after forming the first conductive type electrode, the temperature is performed at a temperature of 500 to 900 ° C for 10 seconds to 30. Heat treatment in minutes. 1 5. The method for manufacturing a light-emitting device according to item 13 of the patent application scope, wherein after forming the second conductive type electrode, perform 30 at a temperature of 500 to 700 ° C. Heat treatment from seconds to 30 minutes. 16. A light-emitting device includes: a substrate; forming a first conductive type semiconductor layer on the substrate; forming activation on a specific region of the first conductive type semiconductor layer Forming a second conductive type semiconductor layer on the activation layer; forming a current dispersing transparent electrode on the second conductive type semiconductor layer; and forming two electrodes on the first conductive type semiconductor layer and the current dispersing transparent electrode, respectively 1 7. The light-emitting device according to item 16 of the patent application scope, wherein the substrate 第22頁 457730 丨,年"月β曰修正/更正/補充 六、申請專利範圍 為透明絕緣之藍寶石基體,且該第一及第二導電型式半導 體層包含一坤化氮三五族化合物半導體。 1 8.如申請專利範圍第1 6項之發光裝置,其中該電流 分散透明電極包含從Ni,Pd,Cr,Ti,V’ Zr,Ce及Nd中 選擇出來之單一項金屬,或這些金屬中數項的合金,或這 些金屬中數項堆疊而成的多層金屬。Page 22, 457730, year " month β said correction / correction / supplement VI. The scope of patent application is transparent sapphire substrate, and the first and second conductive type semiconductor layers include a group of compound semiconductors . 1 8. The light-emitting device according to item 16 of the patent application scope, wherein the current-dispersing transparent electrode comprises a single metal selected from Ni, Pd, Cr, Ti, V 'Zr, Ce, and Nd, or among these metals Several alloys, or multiple layers of these metals stacked. 第23頁Page 23
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