A7 B7 經濟部中央標準局員工消費合作社印裝 五、發明説明 (1 1 1 本 發 明 係 SS 於 遮 光 塗 料 組 成 物 及 其 應 用 〇 更 特 別 地 • 1 1 1 本 發 明 係 闞 於 遮 光 塗 料 姐 成 物 t 其 可 用 >λ 形 成 用 於 液 晶 1 1 顯 示 器 成 像 裝 置 等 之 m 色 器 之 遮 光 薄 膜 » 及 m 於 此 塗 請 1 先- 1 料 組 成 物 之 應 用 〇 閱 讀 1 I 為 了 改 良 對 比 與 顔 色 純 度 或 防 止 光 線 g 用 於 液 晶 顧 示 背 1 I 之 1 器 (LCD)等之濾色器朝開關裝置漏出， 已知將所謂黑色 注 意 1 I 基 質 之 遮 光 薄 膜 交 錯 於 * 例 如 9 形 成 於 透 明 基 材 上 之 *1 事 項 * 1 1 Λ 綠 與 藍 之 各 透 明 有 色 精 细 圖 樣 間 1 或 將 其 提 供 於 安 置 -π 填 寫 本 裝 在 開 闞 裝 置 上 之 基 材 上 Μ 遮 蔽 不 必 要 之 光 〇 頁 1 I 隨 著 LCD之大小之快速增加 、正確性與精细度之改良 1 1 及 生 產 量 之 增 加 遮 光 薄 膜 之 各 種 性 質 之 需 求 及 其 生 產 1 1 力 近 來 變 為 嚴 格 〇 例 如 連 同 高 遮 光 安 定 性 r 亦 需 要 改 訂 良 平 坦 度 \ 平 滑 度 及 遮 光 薄 膜 之 基 材 與 面 漆 (保護膜） 上 1 之 黏 附 性 0 此 外 » 近 來 更 強 烈 地 需 要 遮 光 薄 膜 抗 热 水 1 1 水 份 、 驗 性 > 溶 劑 與 液 晶 之 可 靠 性 〇 1 I 主 要 用 K 形 成 此 遮 光 薄 瞑 之 物 質 為 金 觴 物 質 與 樹 脂 物 1 1 質 〇 使 用 之 金 雇 物 質 為 路 等 • 而 樹 脂 物 質 為 包 含 聚 合 物 線 | 質 (例如， 樹脂） 與 遮 光 物 質 (例如， 碳黑） 之 塗 料 組 成 物 1 1 0 然 而 9 如 铬 之 金 鼷 物 質 具 有 其 造 成 環 境 污 染 Λ 給 予 不 1 當 高 反 射 性 之 遮 光 薄 膜 及 生 成 高 生 產 成 本 之 問 題 Ο 在 此 1 | 情 形 » 樹 脂 物 質 巨 前 吸 引 注 意 〇 1 \ 樹 脂 物 質 Μ 感 光 塗 料 物 質 、 鹼 性 或 溶 劑 可 溶 性 塗 料 物 1 i 質 電 鍍 塗 料 物 質 印 刷 墨 水 等 之 形 式 使 用 〇 可 依 昭 八\\ 使 1 1 物 質 塗 覆 形 成 塗 膜 f m 而 經 具 3 - 有 預 定 圖 樣 之 光 罩 曝 光 然 1 1 1 1 1 1 本紙張尺度適用_國國家標準（CNS ) Α4规格（210Χ297公釐） 5 56 2 3 A7 B7 五、發明説明（> ) 後顯影之方法，予以使用感光物質《可依照使物質塗覆 形成塗膜，光阻靥形成於塗膜上及生成産生經光罩接受 曝光然後顯影之方法，予以使用鹾性或可溶性塗料物質 ,其可進行以分別或同時部份地排除光阻層與塗膜。電 鍍塗料物質可依如此之方法予以使用：表面上具有電導 性電路圆樣或未圖樣化之基材被置於含電導性塗料物質 浴中，繼而施處電流。印刷墨水可依已知之方法使用。 這些方法中所用之塗料物質之遮光物質主要為磺黑， 例如，JP-A-4-28201專利所述者c已知使用之其他物質 為金靥氣化物，如鈦黑舆黑氣化鐵，黑色顔料或染料， 及鉻染料或顔料之混合物。此外，JP-A-5-289336專利 掲示硫化铋，及JP-A-34938專利掲示酞青黑等作為遮光 物質。 然而，視形成遮光薄膜之方法而定，存在箸許多問題 ，如難以得到令人滿意之遮光性質，塗料物質之儲存安 定力與分散性安定力不令人滿意，及並非總是得到令人 滿意之膜，或並非總是得到所需遮光性質。 經濟部_央標率局員工消费合作社印製 (請先閱讀背面之注意事項声填寫本頁) 本發明人已進行廣泛之研究以解決上逑問題，且待別 地尋求一種可滿足濾色器與液晶顯示器所需之各種性質 的遮光膜之形成方法。結果，已發現上述目的可藉由在 用以形成薄膜之塗料物質使用指定顔料作為遮光物質而 得。 依照本發明，提供一種遮光塗料物質組成物，其包含 遮光物質與聚合物質，遮光物質為具有50平方公尺/克 本紙張尺度適用中國國家標率（CNS ) .M沈格（2IOX297公釐） 455623 A7 B7 五、發明説明（3 ) 或更小之比表面積之碳質黑色顔料；一種基材，其中遮 光薄賸交錯於其表面上之透明有色精细圖樣間，遮光薄 瞑包含Μ上之塗料物質；及製造基材之方法。 本發明詳细敘述於下。 用於本發明之碳質黑色顔料可為已知者。例如，其包 括碳黑，包括爐黑、槽黑、熱黑、乙炔黒、燈黑與骨黑 ,及所諝之黑鉛粉與石墨粉（Κ下稱為石墨）。其均為商 業可得。 在本發明中，比表面積由已知之氮氣吸附法测定。較 佳地使用之碳質黑色顔料具有在50平方公尺/克至10平 方公尺/克之範圍內，更佳為30平方公尺/克至15平方 公尺/克之範園内之表面積比。 碳質黑色顔料之含最較佳為5重量或更多，更佳為 15重量S；至60重量ίϊ ,基於存在於本發明遮光塗料姐成 物之固體想重量。 經濟部中央標隼局貝工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 本發明之遮光塗科姐成物含上述碳質黒色顔料作為重 要遮光物質，而且如果需要及希望，可進一步含對本發 明之優點無害之限制内之其他遮光物質，包括黑色顔料 (例如，鈦黑、黑氧化鏹、硫化鉍與二苯井蒽黑）、其他 顔料、補充顔料、直接染料、酸染料、反應性染料、分 敗染料、油溶性染料與堪原染料。 至於用於本發明之聚合物質，可使用已知之感光樹脂 、鹼性或溶劑可溶性樹脂、習知地用於已知感光塗料物 質之電泳型光或熱固化樹脂或熱固性樹脂鹼性或溶劑可 -5- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2! Ο X 297公釐） d5 56 2 3 A7 B7 經濟部中央樣準局員工消費合作社印製 五、發明説明 (4 ) 1 1 溶 性 樹 脂 、 電 锻 塗 料 物 質 與 印 刷 墨 水 9 並 無 特 別 之 限 制。 1 1 特 佳 為 9 本 發 明 之 遮 光 塗 料 姐 成 物 顧 示 感 光 性 〇 所 使 1 [ 用 之 感 光 性 樹 脂 物 質 包 括 • 例 如 r 丙 烯 基 樹 脂 型 聚 酷 請 1 先 1 樹 脂 型 聚 醢 亞 胺 樹 脂 型 與 環 氧 基 樹 脂 型 物 質 0 例 如 9 閲 讀 1 已 知 作 為 負 或 正 光 阻 劑 之 感 光 性 樹 脂 物 質 可 適 當 地 使 用 背 1 | 之 1 〇 例 如 1 負 光 阻 m 為 含 兩 烯 基 樹 脂 或 二 苯 基 酮 型 或 蒽醌 注 意 1 I 型 光 引 發 劑 者 〇 商 業 可 得 之 負 光 阻 m 包 括 V-259- P A ( 事 項 1 I I Sh in -H i t t e t S u化學公司製造） 與 Ka y a r a d INC- 116N (曰 寫 本 1 裝 本 化 學 有 限 公 司 製 造 ) 3 頁 V_〆 1 I 正 光 阻 劑 為 » 例 如 » 含 酚 醛 清 漆 型 酚 系 樹 脂 及 郯 錕 二 1 1 哄化 物 之 酯 化 產 物 〇 商 業 可 得 之 正 光 姐 劑 包 括 0FPR -800 1 i (東京Ohk a公司製造） > PF -7400 (住 友 化 學 有 限 公 司 製 造） 訂 與 FH -2030( 富 士 Hu n t 電 子 技 術 公 司 製 造 ) > 1 在 本 發 明 中 f 特 別 適 合 使 用 光 固 化 樹 脂 作 為 感 光 樹 脂 1 | * 其 為 至 少 一 種 在 分 子 中 具 有 聚 氧 化 烯 鐽 之 環 氧 基 樹 腊 1 I 與 至 少 一 種 a .β - 乙 烯 基 未 胞 和 酸 之 反 應 產 物 » >1 得 到 1 1 儲 存 安 定 性 與 分 散 安 定 性 特 別 優 異 之 所 需 遮 光 塗 料 組 成 線 I 物 〇 1 Ϊ 在 分 子 中 具 有 聚 氧 化 烯 鐽 之 環 氧 基 樹 脂 本 身 為 已 知 * [ 而 且 可 為 1 例 如 f 二 甘 油 基 -酯化產物， 如聚烷二酵二 1 1 甘 油 醚 及 藉 由 將 氧 化 烯 加 入 隻 酚 之 苯 基 而 得 之 二,甘 油 醚 1 1 ， 其 中 雙 酚 在 此 為 » 例 如 ί 雙 酚 A、 雙酚F與 雙 酚 S , 及 1 1 氧 化 烯 為 * 例 如 » 環 氧 乙 烷 環 氧 丙 烷 與 環 氧 丁 烷 〇 1 I a ,β - 乙 烯 基 未 飽 和 酸 之 典 型 但 非 限 制 性 洌 為 丙 烯 1 I 6 - 1 1 1 1 本紙張尺度適用中國國家標準（CNS > A4規格（210x2^«'、》> 經濟部中央標準局貝工消費合作社印製 455623 A7 B7 五、發明説明（（） 酸與甲基丙烯酸。 環氣基樹脂與α 乙烯基未飽和酸間之反_可在約 80-15(TC之溫度，較佳為在對反應為惰性有機溶劑之存 在下進行，如醚與酷β 基於形成遮光薄膜之光固化性質、所形成遮光薄膜之 性質、及待別是濾色器所需之性質，如此得到之光固化 樹脂中之雙鍵含量範圍較佳為1至5莫耳/公斤樹脂。 進一步考量工業光固化中紫外光之限制劑量，更佳為 ，雙鍵含量範圍為2至4莫耳/公斤樹脂。 雙鍵含量可藉由適當地選擇所使用α，办-乙烯基未飽 和酸之量而控制，此量通常選自每莫耳在分子中具有聚 氣化烯鐽之環氣基樹脂為0.5至2莫耳之大約範圍，以使 雙鍵含量在上述範圍内。 在本發明中使用感光樹脂作為聚合物質畤，常用之光 聚合引發劑可依照紫外光輻射之條件而使用。此引發劑 之指定實例包括安息（例如，安息香與安息香甲醚）、苯 乙® (例如，苯乙嗣與2,2-二甲氣基-2-苯基苯乙酮）、饈 醇（例如，2 -乙基憩展）、9 -氣二苯并硫哌喃（例如，2 , 4-二甲基-9-氣二苯并硫哌喃）、與縮_ (例如，苯乙_二甲 基縮酮）<•引發劑可基於關於作為聚合物質之感光樹脂與 遮光物質之固體總重量，以0.1至10重量X之量適當地使 用。 所使用這些聚合物質之量並未特別地限制，而且可依 照聚合物質之種類、遮光物質之種類、及硝質黑色顔料 之進一步表而積比之程度，適雷地決定。 本紙張尺度適用十國國家標準（CNS ) Α4規格（210X297公釐） I , I裝 訂 線 (請先閲讀背面之注意事項再填寫本頁) 4 5 56 2 3 A7 B7 經濟部中央標準局員工消費合作社印裝 五、發明説明 ( 5 1 1 考 盧 使 用 本 發 明 组 成 物 形 成 之 遮 光 薄 膜 之 m 光 性 質 1 1 平 坦 性 與 膜 強 度 t 及 滤 色 器 與 液 晶 顯 示 器 所 需 之 光 學 性 i 1 質 > 遮 光 物 質 對 聚 合 物 質 之 重 量 比 例 較 佳 為 在 1 C :90至 請 I 先 1 8C ：20 . 而 且 更 佳 為 20 : 80 至 70 : 30之 範 圍 内 〇 閱 1 除 了 指 定 之 遮 光 物 質 與 聚 合 物 質 本 發 明 之 遮 光 塗 料 背 ft 1 之 1 組 成 物 可 含 習 知 地 用 於 上 述 各 種 塗 料 物 質 與 墨 水 之 各 種 注 意 1 I 添 加 物 » 其 包 括 > 例 如 * 有 機 溶 劑 9 如 烴 链 酯 Λ 酮 事 項 1 1 > 醇 與 賽 珞 蘇 水 其 他 輔 肋 使 用 顔 料 感 光 m > 矽 院 寫 本 1 1 裝 偶 合 劑 > 钛 偁 合 劑 Λ 鋁 偁 合 劑 分 散 m % pH調 整 劑 防 頁 •>w« 1 1 沫 劑 及 塗 膜 調 平 劑 〇 1 1 本 發 明 之 遮 光 塗 料 組 成 物 可 藉 由 Μ 使 用 輥 磨 球 磨 Ή 1 I 沙 磨 粒 磨 等 之 習 知 方 法 1 均 句 地 分 散 及 混 合 上 述 各 物 1 訂 質 而 m 備 〇 如 此 得 到 之 本 發 明 之 遮 光 塗 料 姐 成 物 對 於 製 備 在 表 面 1 | 上 具 有 遮 光 薄 膜 之 基 材 特 別 有 用 9 其 作 為 LCD用之滤色 1 I 器 特 別 有 用 〇 遮 光 薄 膜 可 藉 習 知 方 法 在 基 材 上 形 成 » 其 1 1 可 載 有 紅 綠 Μ 等 顔 色 之 透 明 有 色 精 细 圖 樣 〇 更 特 地 線 1 V 遮 光 薄 膜 可 在 透 明 有 色 精 细 圖 樣 形 成 之 前 或 之 後 形 成 1 I Μ 填 充 透 明 有 色 精 囲 圖 揉 之 間 隙 9 或 者 ♦ 薄 瞑 可 形 成 1 1 於 與 載 有 透 明 有 色 精 细 圖 樣 之 基 材 m 立 之 另 一 個 基 材 上。 1 I 例 如 » 具 有 遮 光 薄 膜 Μ 填 充 透 明 有 色 精 细 圚 樣,之 間 隙 1 1 之 基 材 可 藉 由 Μ 習 知 方 法 » 如 印 刷 > 石 印 > 及 電 鍍 » 形 [ 1 成 透 明 有 色 精 细 圖 樣 I 然 後 賴 由 使 用 本 發 明 遮 光 塗 料 組 1 I 成 物 之 習 知 方 法 形 成 遮 光 薄 膜 8 - 而 製 備 0 在 此 情 況 r 當 本 1 1 1 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4说格（210X297公釐） 455623 A7 B7 經濟部中央樣準局員工消費合作社印製 藉之發色來面 之欲。之 ， 成基漏給 發y性 可箱本有於背 意不成材 膜。形在光可 1 曰B 本 S 定 材所覆明露之 滿之形基 薄材等，到物安 基成塗透暴諝 人生欲需 _ 光基上如察成漆與此膜散 需形上之膜所 令發不所¾.遮需材例觀組面^ 因 U分 所上面成塗為 不間之許 3 形所基。未料與溶。光與 ，材表形將知 如樣上允。 架到璃良時塗材 膜 U性 時基部上罩已 ，圖樣物一 框得玻優間之基 ® 薄 U 定 物明全 Μ 光法 題细圖成之 U 成而在質之明對殳光器安 成透之被為方 問精细組點2m形 ，Μ 性鏡發、U 遮«a存 組在材其作此 種色精料特73物漾用光光本良水之^儲 光先基 *樣。 各有色塗明3,成圖物遮偏，優 k 確之在 感首在膜圖影 成明有之發50姐细成在之法性水正Dffl物 為含後塗用顯 造透明明本5,料精姐膜叉方滑 '、與LC成 物包然成使而 常與透發為利塗色料薄交成平 0 细成組 成其，形後繼 經膜在本，專光有塗之人形膜Γ精形料 組，樣以然. 今薄膜用題國遮明光成插膜與、吠在塗 ) 料得匾物-光 迄光薄使問美之透遮生材闞性^形物之 ) 塗而细成蓋之 法遮光法述照明形之.基無坦優及成明 (7光法精姐覆面 光在遮光上依發窗明時該，平_、 姐發 明 遮方色料樣背。曝、及曝無-本成發膜或外膜_ 靠料本 ^ 之種有塗圖材法面成、面而者用形本薄獨此種黏可塗。 明 明一明之妞基光背形隙背造或使後當光單。一 ί! 度之用 發 發由透明精自曝 膜間在製 先然 遮材出予瞑高明有 、 五 ----------f.-----—ΐτ·------.^ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4規格（2i〇X297公釐） 465623 A7 B7 經濟部中央橾準局員工消費合作社印裝 五、發明説明 (8 ) 優 良 〇 本 發 明 參考實锊而詳 细 說明 ,但是本 發 明絕不 受 其限 制 〇 實 例 中出現之"份” 與 "S!"各為重量份及重量1 t 除非 另 有 指 示 0 啻 例 1 使 用 其 上已K20w m間隔之條形式提供80w n寬 度 ΙΤ0 膜 之 透 明 導電瞑之玻璃 基 材. 導電膜之 表 面電阻 率 為約 60 Ω /□, 紅色電鍍塗料 組 成物 [由25份Chr oaophtha ] Re d A2B(Ciba-Geigy公 司 製造 )與75份E s b i a«3000透明 漆 (電泳型熱固性樹脂， S h ϊ n t 〇塗科有限公司製） 製 備] 在 40 -80伏特進行電鍍1 0- 20秒 。電鍍產 物 K去離 子 水清 洗 及 在 2001C熱處理30分鐘。因此，在ΙΤ0膜上形 成 厚度 約 1 . 5 t 1 η 之透明有色精 细 圖樣 〇 在 75份 之丙烯基負光 阻 姐成 物（INC-1 1 6 N ,日本化學 有 限 公 司 製造）加入25份具有氮氣吸附法測定為約27平 方 公 尺 /克之比表面積之R a v e η 410 (爐黑 * C ο 1o nb i a η公 司 製 造 )及50份之丁卡必酵乙酸酯作為溶劑，全部混合 均 勻 並 且 Μ輥磨處理， 然 後3 份之光聚 合 引發劑 ( Ir g a C U re tt907,Ciba-Ge i ε y公司製造）加 入 混合物 1 而且 生 成 之 混 合物完全攪拌 ο 因此 ,得到本 發 明之遮 光 塗料 組 成 物 0 所 得 之 塗料驵成物藉 網 印塗 覆於上述 玻 璃基材 之 全部 表 面 上 * κ覆蓋有色精 细 圖樣 ,而且在 90亡預烤 10分鐘 得 到 厚 度約8 w η之塗 瞑 。賴 由使用高 壓 汞燈， 以 80瓦 "10 線 本紙張尺度適用中國國家標準{ CNS ) Α4規格（210X297公釐） 請 先 閲― 讀 背 面 之 注 意 事 項 . J Λ 頁 1 丁 455623 A7 B7 經濟部中央橾準局貝工消費合作社印製 五、發明説明（ 9 ) 1 1 /平方公分之照射密度， 膜暴露於來自基材之載膜表面 1 1 背 側 之 光 3- 20秒 〇 然 後 t 基 材 在 室 溫 浸 於 丁 基 饗 珞 蘇 2 1 1 分 鐘 以 去 除 塗 膜 之 未 暴 露 部 份 3 然 後 Μ 去 離 子 水 清 洗 及 請 1 先 1 在 200 C預热30分鐘 閱. 讀 1 Γ 如 此 得 到 — m 表 面 上 具 有 厚 度 約 1 . 5以Β 之 用 填 充 背 1 J 之 1 有 色 圖 樣 之 間 隙 之 圖 樣 化 遮 光 薄 膜 之 基 材 〇 1 事 1 如 此 得 到 之 基 材 顯 示 在 遮 光 薄 膜 與 有 色 ΕΞΙ 圖 樣 間 之 邊 界 項 再 1 無 光 漏 出 • 具 有 平 坦 與 高 均 勻 表 面 且 具 有 髙 遮 光 安 定 填 寫 本 1 力 * 在 基 材 單 獨 或 基 材 插 於 交 叉 之 起 偏 光 鏡 之 間 時 未 觀 i 1 I 察 到 不 必 要 光 之 漏 出 〇 因 此 1 此 基 材 顧 示 如 m 色 器 之 良 1 1 好 拋 光 〇 遮 光 塗 料 姐 成 物 亦 顧 示 良 好 之 安 定 力 • 塗 料 組 1 1 成 物 在 冷 及 暗 空 間 儲 存 —* 個 月 之 後 t 未 覼 察 在 退 化 〇 訂 實 例 2 重 複 如 實 例 1 之 相 同 步 驟 • 除 了 以 15份 之 S p e c i a 1 1 1 B 1 a c k250(表面積比約40平方公尺/ 克 之 爐 黑 ,D eg us s a 製 1 I 造 )及10份之钛黑13MH (钛 之 氧 化 物 或 氧 氮 化 物 三 菱 材 1 1 料 有 限 公 司 製 造 )取代2 5份之R a v e η 410 ( > 線 | 如 此 得 到 之 基 材 顯 示 在 遮 光 薄 膜 與 有 色 圖 樣 間 之 邊 界 I | 無 光 漏 出 » 具 有 平 坦 與 高 勻 勻 表 面 並 且 具 有 高 遮 光 安 定 I 1 力 t 在 基 材 單 獨 或 基 材 插 於 交 叉 之 偏 光 鏡 之 間 時 未 觀 察 1 I 到 不 必 要 光 之 漏 出 〇 因 此 ， 此 基 材 顧 示 如 m 色 器 之 良 好 1 I 拋 光 〇 1 1 遮 光 塗 料 組 成 物 亦 顯 示 良 好 之 安 定 性 9 塗 料 組 成 物 在 1 I 冷 及 暗 空 間 餡 存 一 個 月 之 後 9 未 親 察 到 退 化 〇 1 1 1 11 1 1 1 1 本紙沐尺度適川中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印裝 455623 A7 '_B7_ 五、發明説明（10) 參者例〗（光固化榭脂1之靱備） (1) 二乙二酵二甲醚 46.2份 (2) Epo1i ght 3002 326 . 0 份 (環氧丙烷之二甘油醚，Μ雙酚A改質，環氧基當 量：326克/當量，Kyoeisha Yushi化學Kogyo有限公苟 製造） (3) 丙烯酸 72. 0份 (4) 甲氧基氫醌 0.6份 (5) 三乙基节基銨氯化物 1.2份 成份（1)、（2)、（3)、（4)與（5)置於具有攢拌器、溫 度計與冷凝器之4 -頸燒瓶中，Μ攪拌提高混合物之溫 度，混合物保持在120±3=6小時，直到酸值變成5或 更小。A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (1 1 1 This invention is SS in light-shielding paint composition and its application. More specifically • 1 1 1 This invention is in light-shielding paint. t It can be used > λ to form a light-shielding film for m color devices for liquid crystal 1 1 display imaging devices and so on »and m apply here 1 first-1 application of the composition 〇Read 1 I In order to improve the contrast and color purity or Prevents light g. Color filters used for liquid crystal display 1 I-1 (LCD) etc. leaking toward the switching device. It is known that the so-called black black 1I substrate light-shielding film is staggered with *. For example, 9 is formed on a transparent substrate. * 1 Matters * 1 1 Λ Green and blue transparent colored fine pattern rooms 1 or provide them for placement -π Fill in the substrate mounted on the opening device. Shielding is unnecessary. 〇 Page 1 I With the rapid increase in the size of LCDs, the improvement of accuracy and fineness 1 1 and the increase in throughput, the demand for various properties of light-shielding films and their production 1 1 The force has recently become strict 〇 For example, together with high light-shielding stability Also need to modify the good flatness \ smoothness and the adhesion of 1 on the base material of the light-shielding film and the topcoat (protective film) 0 In addition »Recently, the light-shielding film is required to be more resistant to hot water 1 1 moisture, test & gt Reliability of solvents and liquid crystals 〇1 I The material used to form this light-shielding thin film is mainly K and the resin material 1 1 Quality 〇 The metal material used is road etc. • The resin material is composed of polymer wires | (For example, resin) and light-shielding substances (for example, carbon black) coating composition 1 1 0 However 9 gold 鼷 substances such as chromium have environmental pollution caused by them Λ give no 1 when highly reflective The problem of light-shielding film and high production cost 〇 Here 1 | Situation »Resin material attracts attention 〇1 \ Resin material M Photosensitive coating material, alkaline or solvent-soluble coating material 1 i quality plating coating material printing ink, etc. The use of the form can be made according to Zhao Ba \ 11 to make 1 1 substance coating to form a coating film fm and then expose it with a mask with a predetermined pattern 3-1 1 1 1 1 1 This paper is applicable to the national standard (CNS) Α4 Specifications (210 × 297 mm) 5 56 2 3 A7 B7 V. Description of the invention (>) The method of post-development is to use a photosensitive material "can be formed by coating the material with a coating film, photoresist is formed on the coating film and generated A method of generating exposure through a reticle and then developing it is used, using either a flexible or soluble coating material, which can be performed to partially or separately exclude the photoresist layer and the coating film. Electroplated coating materials can be used in such a way that a substrate with a circular or unpatterned pattern of conductive circuits on its surface is placed in a bath containing a conductive coating material and then subjected to an electrical current. Printing inks can be used according to known methods. The light-shielding substance of the coating substance used in these methods is mainly sulphur black. For example, JP-A-4-28201 patent c. Other substances known to be used are gold halide gas, such as titanium black and black gasified iron. Black pigments or dyes, and mixtures of chromium dyes or pigments. In addition, JP-A-5-289336 patent shows bismuth sulfide, and JP-A-34938 patent shows phthalocyanine and the like as a light-shielding substance. However, depending on the method of forming the light-shielding film, there are many problems, such as difficulty in obtaining satisfactory light-shielding properties, unsatisfactory storage stability and dispersion stability of coating materials, and not always satisfactory results. Film, or not always obtain the desired light-shielding properties. Ministry of Economic Affairs _ Printed by the Central Standards Bureau Staff Consumer Cooperative (please read the note on the back to fill out this page) The inventor has conducted extensive research to solve the problem of listing, and is looking elsewhere for a color filter Methods for forming light-shielding films with various properties required for liquid crystal displays. As a result, it has been found that the above object can be obtained by using a specified pigment as a light-shielding substance in a coating substance for forming a thin film. According to the present invention, a light-shielding coating material composition is provided, which comprises a light-shielding substance and a polymer substance, and the light-shielding substance is 50 square meters per gram of paper. Applicable to China National Standards (CNS). 455623 A7 B7 V. Description of the invention (3) Carbon black pigment with a specific surface area of 3 or less; a substrate in which light-shielding thin layers remain on the surface of the transparent colored fine pattern interlaced on the surface, and the light-shielding thin layer contains a coating on M Substances; and methods of making substrates. The present invention is described in detail below. The carbon black pigment used in the present invention may be known. For example, it includes carbon black, including furnace black, channel black, hot black, acetylene thorium, lamp black and bone black, and the black lead powder and graphite powder (hereinafter referred to as graphite). They are all commercially available. In the present invention, the specific surface area is measured by a known nitrogen adsorption method. The carbon black pigment that is preferably used has a surface area ratio in the range of 50 m 2 / g to 10 m 2 / g, and more preferably 30 m 2 / g to 15 m 2 / g. The content of the carbonaceous black pigment is most preferably 5 weights or more, more preferably 15 weights S; to 60 weights, based on the weight of the solids present in the light-shielding coating composition of the present invention. Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative (please read the precautions on the back, and then fill out this page) The light-shield coating product of the present invention contains the above carbonaceous ocher pigment as an important light-shielding substance, and if necessary and desired It may further contain other light-shielding substances within the limits that are not harmful to the advantages of the present invention, including black pigments (e.g., titanium black, black osmium oxide, bismuth sulfide, and diphenylene anthracene black), other pigments, supplementary pigments, direct dyes, acids Dyes, reactive dyes, split dyes, oil-soluble dyes, and kanhara dyes. As for the polymer substance used in the present invention, known photosensitive resins, alkaline or solvent-soluble resins, electrophoretic light or thermosetting resins or thermosetting resins conventionally used for known photosensitive coating materials may be used. 5- This paper size applies to China National Standard (CNS) A4 specification (2! 〇 X 297 mm) d5 56 2 3 A7 B7 Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs 5. Description of invention (4) 1 1 Solubility There are no particular restrictions on resins, electro-forged coating materials, and printing inks9. 1 1 Especially good is 9 The light-shielding coating material of the present invention is sensitive to photosensitivity. Use 1 [The photosensitive resin materials used include: • For example, acryl-based resins, such as polyimide, 1st, 1 resin-based polyimide resins. Type and epoxy resin type material 0 For example 9 Read 1 Photosensitive resin materials known as negative or positive photoresist can be used appropriately 1 | 1 of 1 〇 For example 1 negative photoresist m is two alkenyl resin or two Phenyl ketone type or anthraquinone Note 1 Type I photoinitiator. Commercially available negative photoresistance m includes V-259- PA (Item 1 II Sh in -Hittet Su Chemical Co., Ltd.) and Ka yarad INC- 116N (manufactured in 1 book, manufactured by Kirimoto Chemical Co., Ltd.) 3 pages V_〆1 I Positive photoresist is »For example» Novolac type phenolic resin and 郯 锟 2 1 1 esterification product of commercial compounds. 0 Commercially available Zhizheng Guangji Agent includes 0FPR-800 1 i (manufactured by Tokyo Ohka Corporation) > PF -7400 (manufactured by Sumitomo Chemical Co., Ltd.) and FH-2030 (manufactured by Fuji Hunt Electronics Technology Co., Ltd.) > 1 in the present invention f is particularly suitable for using a photocurable resin as the photosensitive resin 1 | * It is a reaction product of at least one epoxy-based wax 1 I having polyoxyalkylene fluorene in the molecule with at least one a. β-vinyl cyanide and acid »> 1 get 1 1 the required light-shielding coating composition line I which is particularly excellent in storage stability and dispersion stability 〇1 环 Epoxy resins with polyoxyalkylene 鐽 in the molecule are known per se * [and can be 1 for example f Diglyceryl-esterified products, such as polyalkylenediol di 1 1 glyceryl ether and bis, glyceryl ether 1 1 obtained by adding alkylene oxide to phenol-only phenyl group, where bisphenol is here » For example, bisphenol A, bisphenol F, and bisphenol S, and 1 1 alkylene oxide are * For example »ethylene oxide propylene oxide and butylene oxide 〇1 I a, β-vinyl unsaturated acid is typical but Non-limiting: acrylic 1 I 6-1 1 1 1 This paper size applies to Chinese national standards (CNS > A4 size (210x2 ^ «',>) > Printed by Shellfish Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs 455623 A7 B7 V. Description of the invention (() Acid and methacrylic acid. The reaction between the ring gas-based resin and the α vinyl unsaturated acid can be performed at a temperature of about 80-15 (TC, preferably in the presence of an inert organic solvent for the reaction, such as ether and cool β based on the formation of a light-shielding film The photo-curing properties of the light-curing resin, the properties of the light-shielding film to be formed, and the properties required for the color filter, the content of the double bonds in the photo-curing resin thus obtained is preferably in the range of 1 to 5 mol / kg of resin. The limiting dose of ultraviolet light in industrial light curing, more preferably, the double bond content ranges from 2 to 4 moles / kg of resin. The double bond content can be appropriately selected by the amount of α-vinyl unsaturated acid used While controlling, this amount is usually selected from the approximate range of 0.5 to 2 moles per mole of the ring gas-based resin having a polygasified alkylene in the molecule, so that the double bond content is within the above range. Used in the present invention Photosensitive resins are polymer polymers, and commonly used photopolymerization initiators can be used in accordance with the conditions of ultraviolet radiation. Specified examples of this initiator include benzoin (for example, benzoin and benzoin methyl ether), phenethyl® (for example, phenethylfluorene) With 2,2-dimethyl 2-phenylacetophenone), methyl alcohol (for example, 2-ethyl divergence), 9-gas dibenzothiopiperan (for example, 2, 4-dimethyl-9-gas dibenzo) Thiopran), and condensation (for example, phenethyl dimethyl ketal) < • The initiator may be in an amount of 0.1 to 10 weight X based on the total solid weight of the photosensitive resin and the light-shielding substance as a polymeric substance Appropriate use. The amount of these polymer materials used is not particularly limited, and can be determined appropriately according to the type of polymer material, the type of light-shielding substance, and the degree of the nitro black pigment. Paper size applies to the ten national standards (CNS) Α4 specifications (210X297 mm) I, I gutter (please read the precautions on the back before filling this page) 4 5 56 2 3 A7 B7 Employee Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Imprint 5. Description of the invention (5 1 1 The light properties of the light-shielding film formed by the use of the composition of the invention in Kaul 1 1 Flatness and film strength t 1 and the optical properties required for color filters and liquid crystal displays i 1 Quality >The weight ratio of the light-shielding substance to the polymer substance is preferably in the range of 1 C: 90 to 1 I 8C: 20. And more preferably in the range of 20:80 to 70:30. The light-shielding paint back ft 1 -1 composition of the present invention can be conventionally used for various kinds of coating materials and inks mentioned above. I Additives »It includes > For example, * Organic solvents 9 such as hydrocarbon chain esters ketene matters 1 1 > Alcohol and other ribs using pigment photosensitivity m > Silicone Manuscript 1 1 Coupling agent > Titanium coupler Λ Aluminum coupler dispersion m% pH adjuster Anti-leaf sheet &> w «1 1 Foam and film leveling agent 〇 1 1 The light-shielding coating composition of the present invention can be milled using a roller mill ball 1 I conventional methods such as sand mill grain milling 1 Disperse and mix each of the above-mentioned items 1 Customized and ready for preparation. The light-shielding coating product of the present invention thus obtained is particularly useful for preparing a substrate having a light-shielding film on the surface 1 | 9 It is particularly useful as a color filter for LCD 1 I. The light-shielding film can be borrowed Conventional methods to form on the substrate »Its 1 1 can carry transparent colored fine patterns of colors such as red and green M. More specifically, a 1 V light-shielding film can be formed before or after the formation of transparent colored fine patterns. 1 I Μ Filled with transparent colored The gap 9 of the refined pattern can be thinned to form 1 1 on another substrate which is standing on the substrate m with a transparent colored fine pattern. 1 I For example »With a light-shielding film M filled with transparent colored fine pattern, the substrate of the gap 1 1 can be used by M conventional methods» such as printing > lithography > and electroplating »shape [1 into transparent colored fine pattern I and then The light-shielding film 8 is formed by the conventional method of using the light-shielding coating group 1 I of the present invention to prepare 0. In this case, when the paper is 1 1 1 1 1 1 this paper size applies the Chinese National Standard (CNS) A4. ( (210X297 mm) 455623 A7 B7 The color of the hair is printed by the Consumer Cooperative of the Central Procurement Bureau of the Ministry of Economic Affairs. In other words, the formation of the base leaks to the hair, but the box has the intention of not forming a material film. Shaped in the light can 1 said B Ben S fixed material covered with the full shape of the thin base material, etc., until the material Anjicheng is painted and violently 谞 谞 desire for life The film makes the hair unbelievable ¾. The surface of the material needs to look at the surface ^ Because the U branch office is painted with a continuous 3 shape base. Unexpected and dissolved. The appearance of light and material will be known as such. The base material is covered when the coating material film is U-shaped when the glass is good. The pattern is framed to get the base of the thin glass. The thin U is fixed and the whole picture is completed. The light device An Chengtou is regarded as a square-shaped fine group point 2m, M-shaped mirror hair, U cover «a storage group in the material, it is used as this color concentrate, 73 objects, and the light is used to save the good water. *kind. Each color is painted 3, the picture is obscured, you are sure that you are in the first place in the film, the picture is bright, the hair is 50, the fine is the legal water, and the Dffl is a clear and transparent copy. 5, material fine sister film fork square slip ', with the LC products into the package, and often with the hair for the benefit of the coloring material thin and flat 0 fine composition to form, followed by the shape of the menstrual membrane in this, special light and painted Human-shaped film Γ fine-shaped material group, the same as it is today. The film uses the title of the country to cover the light into the film and the bark.) The material is a plaque-the light is so thin that it is beautiful and transparent. ()) The method of coating and thinning the cover is described in the light-shielding method. Ji Wutan You and Cheng Ming (7-light method fine sister cover light on the shade according to the window when the light should be, flat sister, invented a cover color Sample back. Exposure, and exposure without-this into a hair mask or outer film _ rely on the material ^ kind of painting materials, the surface of the surface, or the use of thin and thin, this type can only be coated. The back of the light is made by the gap or made light. One 单! The hair used by the degree is made by the transparent fine self-exposed film in the production of the prior masking material. .-----— ΐτ · ------. ^ (Please read the notes on the back before filling (This page) The paper size is in accordance with Chinese National Standard (CNS) Λ4 specification (2i × 297mm) 465623 A7 B7 Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (8) Excellent While the detailed description, but the present invention is by no means limited thereto, the "parts" and "S!" Appearing in the examples are parts by weight and weight 1 t unless otherwise indicated. 0 Example 1 K20w used on it The m-spaced strip form provides a transparent conductive glass substrate of 80w n width ITO film. The surface resistivity of the conductive film is about 60 Ω / □, red electroplating coating composition [by 25 parts Chro oaophtha] Re d A2B (Ciba -Made by Geigy) and 75 parts of Esbia «3000 clear lacquer (electrophoretic thermosetting resin, Sh h 〇 〇 Co., Ltd.) Preparation] Electroplating at 40-80 volts for 10-20 seconds. The electroplating product K goes to Ionized water cleaning and heat treatment at 2001C for 30 minutes. Therefore, a transparent colored fine pattern with a thickness of about 1.5 t 1 η was formed on the ITO film. To 75 parts of a propylene-based negative photoresist product (INC-1 1 6 N, manufactured by Nippon Chemical Co., Ltd.) was added 25 parts of R ave η 410 having a specific surface area measured by a nitrogen adsorption method of about 27 m 2 / g ( Furnace Black * C ο 1o nb ia η) and 50 parts of tetracarbine acetate as a solvent, all are mixed uniformly and processed by M roll milling, and then 3 parts of a photopolymerization initiator (Ir ga CU re tt907, (Manufactured by Ciba-Ge i ε y company) Add the mixture 1 and the resulting mixture is completely stirred. Therefore, the coating material obtained by obtaining the light-shielding coating composition 0 of the present invention is coated on the entire surface of the above glass substrate by screen printing. * κ covers colored fine patterns, and pre-bake at 90 ° C for 10 minutes to obtain a coating with a thickness of about 8 w η. Relying on the use of high-pressure mercury lamps, the paper size of 80 watts " 10-wire paper is applicable to the Chinese National Standard {CNS) A4 (210X297 mm) Please read ― Read the precautions on the back. J Λ Page 1 丁 455623 A7 B7 Economy Printed by the Central Bureau of Standards and Commerce, Shellfish Consumer Cooperative, V. Description of the invention (9) 1 1 / cm² irradiation density, the film is exposed to the surface of the carrier film from the substrate 1 1 light on the back side 3- 20 seconds, then t The substrate was immersed in butyl sulfoxide at room temperature for 2 1 minutes to remove the unexposed portion of the coating film 3 and then cleaned with deionized water. Please preheat 1 at 200 C for 30 minutes. Read 1 Γ So Obtained—m The substrate with a thickness of about 1.5 on the surface of the patterned light-shielding film filled with the gap between the colored pattern and the back of the substrate with a color pattern of J. 1 Matter 1 The substrate thus obtained is shown in the light-shielding film and the colored ΕΙΙ image.Boundary term between samples 1 No light leakage • Flat and highly uniform surface with 髙 light-shielding stability Fill in this note 1 Force * Not observed when the substrate is alone or the substrate is inserted between the crossed polarizers Unnecessary light leaks out. Therefore 1 This substrate is shown as good as m color device 1 1 Good polishing 0 The finished product of light-shielding paint also shows good stability • Coating group 1 1 The product is stored in cold and dark space — * Months later, no deterioration was observed. Order Example 2 Repeat the same steps as Example 1. • Except for 15 parts of Specia 1 1 1 B 1 ac k250 (the surface area ratio is about 40 square meters per gram of furnace black, D eg us sa (made by 1 I)) and 10 parts of titanium black 13MH (made by titanium oxide or oxynitride Mitsubishi Materials 1 1 Materials Co., Ltd.) instead of 2 5 parts of R ave η 410 (> line | thus obtained The substrate is shown in the light-shielding film and Boundary between colored patterns I | No light leakage »With flat and high uniform surface and high light-shielding stability I 1 Force t Not observed when the substrate is alone or the substrate is inserted between crossed polarizers 1 I to unnecessary light Leaked 〇 Therefore, this substrate is shown to be as good as m color device 1 I polished 〇1 1 The light-shielding coating composition also shows good stability 9 The coating composition is stored in 1 I cold and dark space for one month after filling 9 Degradation detected 〇1 1 1 11 1 1 1 1 This paper is suitable for Sichuan National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 455623 A7 '_B7_ V. Description of the invention (10 ) Participant examples (preparation of light-curing gelatin 1) (1) 46.2 parts of dioxane dimethyl ether (2) Epo1i ght 3002 326.0 0 parts (diglyceryl ether of propylene oxide, bisphenol A Modification, epoxy equivalent: 326 g / equivalent, Kyoeisha Yushi Chemical Kogyo Limited Manufacturing) (3) Acrylic 72.0 parts (4) Methoxyquinone 0.6 parts (5) Triethyl benzyl ammonium chloride 1.2 parts Ingredients (1), (2), (3), (4) and (5) Place in a 4-neck flask with a stirrer, thermometer and condenser, and stir to increase the temperature of the mixture. The mixture is maintained at 120 ± 3 = 6 hours until the acid value becomes 5 or less.
如此，得到黏性光固化樹脂1 (非揮發性樹脂含量：9 0 X ，雙鐽含量：2.5萁耳/公斤樹脂）。 兹者例來困化樹瞄2夕郸備） (1) 二乙二醇二甲醚 32. 6份 (2) Epolight 200P 220.0份 (三環氧丙烷二甘油醚，瑁氧基當量：220克/當最 ICyoeisha Yushi化學Kogyo有限公司製造） (3 >丙烯酸 7 2 . 0份‘ (4) 甲氧基氫醌 0 . 4份 (5) 三乙基节基銨氯化物 0.8份 本紙張尺度適用中國國家標準（CNS > A4規格（2I0X297公釐） I 裝 訂 線 - - (請先鬩讀背而之注意事項罗填寫本頁) 經濟部中央標準局員工消費合作社印裝 455623 A7 B7 五、發明説明（li ) 成份（1)、（2)、（3)、（4)與（5)置於具有授拌器、 溫度計與冷凝器之4 -頸燒瓶中，以攪拌提高混石物 之溫度，混合物保持在120 士 31C6小時，直到酸值 變成5或更小。 如此，得到黏性光固化樹脂2 (非揮發性樹脂含量：9 0 Si,雙合鐽含最：3.4莫耳/公斤樹脂）。 (1 )光固化樹脂 7 5份 (2) 丙二醇單甲醚 100份 (3) Raven 410 25份 (比表面積27平方公尺/克之®黑，CoUmbian 公司製造） (4) A-1120 2份 (矽烷偶合劑，日本Unikar有限公司製造） (5) Irgacure 907 1 份 (光引發劑，Ciba-Geigy公司製造） 成份（1)、（2)、（3)與（4)使用玻璃粒（EGB-503HM, 東芝- Barotini有限公司製造）分敗5小時，生成之 分散液以輥磨機進一步分散，然後成份（5>加入分 散液Μ得到可光固化遮光塗料組成物。 使用其上已以20/i πι間隔之條形式提供δθ/i η寬度ΙΤ0 _之透明等電膜之玻璃基材，等電膜之表面電阻率為約 60Ώ / □,紅色電鍍塗料組成物[由25份Chromophthal Red A2B(Ciba-Geigy公司製造）與 75 份 Esbia#3000 透明 -1 3 - 本紙依尺度適用中國S家標11. { CNS > Λ4说格（210X297公釐） ----------1-----—IT------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印装 455623 A7 ___B7_ 五、發明説明（i2 ) 漆（電泳型熱固性樹腊.Shinto塗料有限公司製造）製備 ]在40-80伏特進行電鍍10-20秒。電鍍產物Μ去皤子水清 洗及在200 t熱處理30分鐘。因此，在ΙΤ0膜上形成厚度 約1.5ϋ η之透明有色精细圖樣。 所得之可光固化塗料阻成物藉網印塗覆於上述玻璃基 材之全部表面上，Κ覆蓋有色精细圖樣，而且在90C預 烤10分鐘Μ得到厚度約之塗膜。藉由使用高壓汞燈 ，以80瓦/平方公分之照射密度，瞑暴露於來自基材背 面之光3-20秒。然後，基材在室溫浸於丁基賽珞蘇2分 鐘K去除塗膜之未暴露部份，然後Μ去離子水清洗及在 200 1預熱30分鐘。 如此，得到一個表面上具有厚度妁1.5wb之用以填充 有色匾樣之間隙之遮光薄膜之基材。 如此得到之基材顧示在遮光薄瞑與有色圖樣間之*界 無光漏出，具有平坦與高均勻表面並且具有高遮光安定 性，在基材單獨或基材插於交叉之偏光鏡之間時未親察 到不必要光之漏出。因此，此基材顯示如濾色器之良好 拋光。可光固化塗料姐成物亦顯示良好之安定性，塗料 姐成物在冷及暗空間儲存一個月之後，未觀察到退化。 奮例4 (1) 光固化樹脂2 60份 (2) 二異戊四醇六丙烯酸酯 20份 (3) 丙二醇單甲醚 100份 (4 )燈黑1 0 1 3 0份 -14- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨0Χ297公釐） I---------,Λ—-----ΪΤ------^ (請先閲讀背面之注意事項罗4寫本頁) 經濟部十央標準局員工消費合作社印製 4 5 5 6 2 3 A7 B7 五、發明説明（i3 ) (具有20平方公尺/克之比表面之碳黑，Degussa製造） (5) Pren Act ALH 2份 (鋁偶合劑，Ajinomoto有限公司製造） (6) Irgacure907 1 份 (光引發劑，Ciba-GeUy公司製造） 成份（1)、（2)、（3)與（4)使用玻璃粒（EGB-503MM,東 芝- Barotini有限公司製造）分散5小時，生成之分散液 Μ輥磨機進一步分敗，然後成份（5)與（6)加入分敗液Μ 得到遮光塗料組成物。 Μ上得到之塗料組成物藉網印Ml.1毫米厚度塗覆於 玻璃基材之全部表面上。在9010預乾10分鐘後，藉由使 用UVC-5039(Ushi〇公司製造）作為照射裝置，塗膜經具 有曝光部份寬度2〇 a m及遮光部份寬度80w a之條圖樣之 光罩，接受紫外線照射。曝光為240-1600焦耳/平方公 分0 暴露於光之後，基材在室溫浸於丁基賽珞蘇30分撞， 然後K去離子水清洗直到清洗水變透明。然後基材浸於 異丙醇及振盪，然後在2 0 0 t：烘烤及乾燥6 0分鐘。 如此，在玻璃基材上得到厚度lwi之遮光薄膜，此膜 具有預定之安定形狀，具有高遮光力及高硬度，而且在 餺色器所需之各種性質優良。此遮光姐成物亦顯示優良 之儲存安定性，遮光塗料姐成物在冷及暗空間儲存一個 月之後，未觀察到退化。 各在1996年5月23曰、6月17日已與6月21日已提出之 -15- 本紙張尺度適用中國國家標準（CNS ) 坊（公釐） ----------¾.-----—,π—------^ (請先閱讀背面之注意事項再镇寫本頁) 4 5 5 6 2 3 A7 B7 五、發明説明（W ) 日本專利申請案8-153110、 8-177056與8-181284之全部 併 部 全 此 在 要 逋 與 圍 範 利 專 請 Φ 、 書 明 說。 括考 包參 ，為 示作 揭人 一裝K----丨訂-------線 (請先M1讀背面之注意事項再，¥.寫本頁) 經濟部4-央標準局貝工消費合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）In this way, a viscous photocurable resin 1 (non-volatile resin content: 90 ×, double-fluorene content: 2.5 萁 ears / kg resin) was obtained. Here are some examples: (1) Diethylene glycol dimethyl ether 32.6 parts (2) Epolight 200P 220.0 parts (tripropylene oxide diglyceryl ether, methanol equivalent: 220 g / Made by ICyoeisha Yushi Chemical Kogyo Co., Ltd.) (3 > Acrylic 7 2.0 parts) (4) Methoxyhydroquinone 0.4 parts (5) Triethyl benzyl ammonium chloride 0.8 parts Paper size Applicable to Chinese national standards (CNS > A4 specification (2I0X297mm) I binding line--(please read the precautions and fill in this page first) Printed by the Central Consumers Bureau of the Ministry of Economic Affairs Consumer Cooperatives 455623 A7 B7 V. Description of the invention (li) Ingredients (1), (2), (3), (4) and (5) are placed in a 4-neck flask with a stirrer, a thermometer and a condenser to stir and improve the quality of the mixed stone. The temperature is maintained at 120 ± 31C for 6 hours until the acid value becomes 5 or less. In this way, a viscous photocurable resin 2 (non-volatile resin content: 90 Si, double bond content: 3.4 mol / kg Resin). (1) Light-curing resin 7 5 parts (2) Propylene glycol monomethyl ether 100 parts (3) Raven 410 25 parts (specific surface area of 27 square meters / gram Black, manufactured by CoUmbian Company) (4) A-1120 (silane coupling agent, manufactured by Unikar Co., Ltd.) (5) Irgacure 907 1 part (photoinitiator, manufactured by Ciba-Geigy) Ingredients (1), (2 ), (3) and (4) using glass pellets (EGB-503HM, manufactured by Toshiba-Barotini Co., Ltd.) for 5 hours, the resulting dispersion was further dispersed by a roller mill, and then the component (5> was added to the dispersion to obtain A photocurable light-shielding coating composition. Use a glass substrate on which a transparent isoelectric film with a δθ / i η width Ιτ0 _ has been provided in the form of a strip of 20 / i π interval, and the surface resistivity of the isoelectric film is about 60Ώ / □, red electroplating coating composition [made by 25 parts of Chromophthal Red A2B (made by Ciba-Geigy) and 75 parts of Esbia # 3000 transparent-1 3-This paper applies Chinese S house standard according to the standard 11. {CNS > Λ4 说 格 （ 210X297 mm) ---------- 1 ------- IT ------ ^ (Please read the notes on the back before filling out this page) Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumption Cooperative printed 455623 A7 ___B7_ 5. Description of the invention (i2) Lacquer (electrophoretic thermosetting wax). Made by Shinto Paint Co., Ltd. Preparation] electroplating 40-80 volts for 10-20 seconds. The electroplated product M was rinsed with deionized water and heat-treated at 200 t for 30 minutes. Therefore, a transparent colored fine pattern with a thickness of about 1.5 ϋ η was formed on the ITO film. The obtained photocurable coating resist was coated on the entire surface of the above glass substrate by screen printing, K was covered with a colored fine pattern, and pre-baked at 90C for 10 minutes to obtain a coating film having a thickness of about 30 Å. By using a high-pressure mercury lamp, the radon was exposed to light from the back surface of the substrate for 3-20 seconds at an irradiation density of 80 W / cm2. Then, the substrate was immersed in butylcellulose at room temperature for 2 minutes to remove the unexposed portion of the coating film, and then washed with deionized water and preheated at 200 for 30 minutes. In this way, a substrate having a thickness of 1.5 Wb on the surface of a light-shielding film for filling colored plaque-like gaps was obtained. The substrate obtained in this way has no leakage of light between the shading sheet and the colored pattern, has a flat and highly uniform surface, and has high light-shielding stability. The substrate is alone or the substrate is interposed between the crossed polarizers. No unnecessary light leakage was observed at the time. Therefore, this substrate shows good polishing like a color filter. The photocurable coatings also showed good stability. After storage of the coatings in cold and dark space for one month, no degradation was observed. Example 4 (1) Photocurable resin 2 60 parts (2) Diisopentaerythritol hexaacrylate 20 parts (3) Propylene glycol monomethyl ether 100 parts (4) Lamp black 1 0 1 3 0 parts -14- This paper Standards apply to Chinese National Standard (CNS) Α4 specifications (2 丨 0 × 297 mm) I ---------, Λ ------ ΪΤ ------ ^ (Please read the note on the back first Item 4 written on this page) Printed by the Consumers' Cooperative of Shiyang Standard Bureau of the Ministry of Economic Affairs 4 5 5 6 2 3 A7 B7 V. Invention Description (i3) (Carbon black with a surface area of 20 square meters per gram, manufactured by Degussa) (5) 2 parts of Pren Act ALH (aluminum coupling agent, manufactured by Ajinomoto Co., Ltd.) (6) 1 part of Irgacure907 (photoinitiator, manufactured by Ciba-GeUy) Ingredients (1), (2), (3), and (4 ) Use glass pellets (EGB-503MM, manufactured by Toshiba-Barotini Co., Ltd.) to disperse for 5 hours. The resulting dispersion M roller mill is further divided, and then components (5) and (6) are added to the divided solution M to obtain a shading coating composition. Thing. The coating composition obtained on M was applied on the entire surface of the glass substrate by screen printing M1.1 mm thick. After 10 minutes of pre-drying at 9010, by using UVC-5039 (manufactured by Ushio Co., Ltd.) as an irradiation device, the coating film was subjected to a mask having a stripe pattern with an exposure portion width of 20am and a light-shielding portion width of 80w a. Ultraviolet radiation. The exposure was 240-1600 Joules / cm 2 0 After exposure to light, the substrate was immersed in butyl cyperidine 30 minutes at room temperature, and then washed with K deionized water until the washing water became transparent. Then the substrate was immersed in isopropyl alcohol and shaken, and then baked and dried at 200 t: 60 minutes. In this way, a light-shielding film having a thickness of lwi is obtained on a glass substrate. The film has a predetermined stable shape, has a high light-shielding power and high hardness, and is excellent in various properties required for a toner. This shading product also showed excellent storage stability. No degradation was observed after storing the shading coating product in cold and dark space for one month. -15 on May 23, 1996, June 17 and June 21, respectively. -15- This paper size applies to China National Standards (CNS) Square (mm) ---------- ¾ .-----—, π —------ ^ (Please read the notes on the back before writing this page) 4 5 5 6 2 3 A7 B7 V. Description of Invention (W) Japanese Patent Application All of Cases 8-153110, 8-177056 and 8-181284 are all here and there. Fan Li specially invited Φ, Shu Ming to say. Including the test package, please install the K ---- 丨 order for the revealer. (Please read the precautions on the back of M1, and then write this page.) Ministry of Economic Affairs 4-Central Standard The paper size of the printed paper produced by the Bureau Cooperative Consumer Cooperative is applicable to the Chinese National Standard (CNS) A4 (210X297 mm)