455516 A7 B7 經濟部中央標準局貝工消費合作社印裝 五、發明説明 ( 1 ) 1 發 明 背 景 1 1 | 本 發 明 你 萠 於 種 方 法 和 —^ 種 裝 置 用 於 m m I 業 疫 棄 1 I 物 的 再 利 用 S 更 商 於 處 理 在 網 m 工 廠 中 所 形 成 之 標 的 物 請 1 先 1 或 m 棄 物 以 a 標 的 物 中 回 收 有 值 質 的 — 種 方 法 和 一 閱 1 背 I 種 裝 置 〇 面 之 1 一 般 « 在 銷 鐵 工 廠 中 必 然 産 生 大 量 的 各 種 廢 棄 物 〇 例 I 1 | 如 .* 這 廢 棄 物 包 括 鐵 礦 粉 塵 和 鐵 與 钢 的 粉 塵 〇 鐵 與 钢 Ϊ 再 1 的 粉 塵 是 出 現 於 m m 程 序 和 製 銷 程 序 之 中 0 這 些 廢 棄 物 填 寫 本 裝 統 稱 銷 鐵 工 業 廢 窠 物 或 簡 稱 廢 棄 物 0 頁 1 | 較 佳 者 钢 鐵 X 業 廢 棄 物 是 經 再 製 成 再 利 用 以 收 回 有 1 I 價 值 之 金 屬 > 例 如 留 存 在 鏑 鐵 工 業 廢 棄 物 中 的 鐵 0 將 此 1 1 併 列 入 考 慮 » 傳 統 的 方 法 已 被 用 以 再 處 理 及 再 利 用 上 1 訂 1 I 述 類 型 的 廢 棄 物 9 待 別 是 鐵 礦 粉 塵 和 m 鐵 粉 塵 〇 然 而 這 些 方 法 成 本 高 昂 9 因 而 難 於 工 業 中 實 際 利 用 〇 在 此 狀 況 1 1 下 廢 棄 物 最 常 用 和 處 理 方 式 為 陸 上 掩 埋 而 只 有 小 部 份 1 I 的 廢 棄 物 被 再 利 用 〇 1 近 年 來 * 由 於 陸 上 掩 埋 容 量 開 傜 • 使 廢 棄 物 逐 漸 成 為 1 蹉 重 問 題 Q 1 I 因 此 9 廢 棄 物 的 處 置 在 格 的 環 境 條 例 之 下 成 為 全 國 1 1 I 性 問 題 在 此 情 形 之 下 » 迫 切 需 要 提 高 資 源 的 再 利 用 〇 1 1 在 此 同 時 因 為 如 前 所 逑 * m 棄 物 包 含 t 所 以 須 考 1 1 盧 到 製 鐵 和 煉 铜 方 法 中 廢 棄 物 的 再 利 用 0 然 而 須 注 意 钢 1 戡 X 業 的 m 棄 物 常 含 有 m 和 鉛 等 重 金 m * 這 重 金 m 必 1 1 須 除 去 > 否 則 會 損 及 高 爐 it 3- 為 業 者 所 熟 知 〇 為了 除 去 1 1 1 I 1 本紙張尺度適用中國國家標隼（CNS > Λ4規格（210X297公釐） 455516 經濟部中央標準局員工消費合作社印製 A 7 __ B7_五、發明説明（> ) 捽和鉛，業者曾採取多種公知之方法。常用於網戡製造 程序的兩種第二方法。 特別是在第一方法中，含於睦棄物之氧化鋅是在一旋 轉窯中用焦炭作為堪原劑而揮發和逐漸滅少。於是氧化 鋅從廢棄物中被除去。進而氧化截被堪原成為低含梓量 之海綿狀戡而回瞭至髙爐或礦石燒结撻之中。 在第二方法中，鹺棄物中所含梓之成份用一濕式分塵 健依程度區分不同物質，使裔棄物被分成含高鋅濃度之 第一部份和含低梓濃度的第二部份。第一部份被用於非 餓金匾工業中作為原枓而第二部份被回饋至製鐵方法中 之高魃或燒结機中，其後，第二部份接受装網程序。 如前所述，萵爐和燒结機是製鐵程序中的裝置。換言 之.回收的材科是被用於製餌程序之前的製锁程序。 通常第一方法需要在饋入旋轉窯之前對預定程度之片 狀醆棄物預作處理。此外，回收之已去除鋅的材料不能 回饋至製爾程.序，但可用作製戡程序之原料。這是因為 在回收材料中所含的有價值之戡纯度低。因此，第一方 法是因回收材料的作業成本髙而不利。另一方面，由於 鋅之成份既不充分湄縮又不分離而為其缺點。 在此任一方法中，均不可能以低之作業成本回收有價 值之材料。 更特殊之處，第一方法使用旋轉窯有另一缺點.將予 說明。 第一方法應係Μ氣體與固體反®而使橄礦直接被堪原 -4 - (請先閱讀背面之注意事項再填寫本頁) 本畝張尺度通用中國國家標华（CNS ) Α4現格（2Ι0/ΝΊ 4 5 5 5 1 6 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（ ) 1 1 〇 因 而無可避免地在旋轉窯的原、理中與若干物質结合 * 1 1 I 结 果 由 於结合增大的問題而難Κ使旋轉窯不停櫬而作長時 1 1 間 運 轉 〇 由 於 顔 及 此 項 實 m 狀 況 « 旋 轉 Μ 因 而 須 在 戡 之 請 先 1 1 熔 酤 Μ 下 操 作 〇 閱 讀 1 背 1 實 際 上 ♦ 旋轉窯是在較低婼溫κ不高於約ΐ2〇ου 之 操 之 1 注 | 度 操 作 〇 意 擎 1 對 此 加 Μ 考 慮 9 所 用 旋 轉 窯 長 度 α)對直徑（d)之比 ( 項 再 1 填 L / D )不能小於2 0 0 此 外 I 燃 爐 安 置 於 旋 轉 窯 之 出 Ρ 側 0 寫 本 裝 在 任 何 速 率 * 旋 轉 窯 常 為 長 圓 筒 狀 Κ 保 持 足 夠 長 的 留 頁 Vw-· 1 1 滯 時 間 〇 Κ 上 述 之 结 構 • 旋 轉 窯 本 身 尺 碼 龐 大 而 昂 貴 0 1 1 如 上 所 述 » K 旋 轉 窯 用 於 網 m X 業 廢 棄 物 之 再 利 用 須 1 1 考 處 其 成 本 〇 因 此 • 旋 轉 窯 除 了 特 殊 例 子 外 9 並 未 應 用 1 訂 於 網 鐵 工 業 m 棄 物 的 再 利 用 〇 1 I 使 用 旋 轉 窯 於 網 戡 工 業 m 棄 物 再 利 用 有 另 — 問 題 » 説 1 1 明 如 下 〇 1 1 Η >-刖 述 之 安 排 t 一 燃 燒 氣 流 由 出 □ 側 相 對 於 廢 棄 物 在 I 旋 轉 Μ 内 逆 向 而 行 〇 如 此 之 燃 燒 氣 流 稱 為 逆 流 〇 燃 氣 之 1 逆 流 與 燃 熵 共 同 加 熱 於 輸 向 旋 轉 窯 出 Ρ 之 廢 棄 物 〇 所 以 1 1 旋 轉 窯 非 常 長 ， 如 刖 所 述 旋 轉 窯 内 之 溫 度 白 出 P 側 向 1 | 入 Ρ 側 逐 漸 降 低 0 雖 然 此 種 结 構 能 於 m 棄 物 輸 送 之 時 逐 1 1 漸 減 少 m 棄 物 而 於 出 口 側 完 成 減 降 作 用 * 在 旋 轉 窯 内 壁 1 | 上 结 附 的 m 棄 物 則 發 生 於 溫 度 變 化 大 的 區 域 〇 结 附 通 常 1 1 出 琨 環 形 形 狀 並 且 被 稱 為 堪 環 0 1 1 除 了 m 礦 粉 塵 和 網 Aff. 锇 粉 塵 之 外 t 網 i+fc m 工 業 廢 棄 物 包 含 1 | 5 - 1 1 ί 本紙伕尺度適用中國國家標準（CNS > Λ4現格（210X297公釐) 4 5 5 5 1 6 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 (4 ) 1 1 在 酸 浸 線 上 和 在 m 鋅 法 中 出 琨 的 淤 泥 〇 此 m 泥 含 有 m 1 1 I m 鉻 等 物 質 〇 此 淤 泥 因 為 實 際 上 不 能 脱 水 和 製 粒 > 所 1 I Μ 不 能 使 用 習 用 之 旋 轉 窯 處 理 〇 請 先 1 1 在 m 賴 工 廠 和 其 他 没 施 中 的 活 動 或 作 茱 1 另又 產 生 可 閲 讀 1 背 1 燃 性 材 科 如 m 紙 木 m * 和 m 油 >λ 及 各 種 含 碳 物 質 0 可 fir 之 1 注 I 燃 物 質 和 含 碳 物 質 统 稱 為 都 市 廢 棄 物 〇 可 燃 物 質 於 處 理 意 華 1 戡 礦 粉 塵 Λ 爾 m 粉 塵 和 淤 泥 而 產 生 海 綿 餓 時 可 作 為 燃 料 項 再 I 填 i 之 部 份 〇 另 —- 方 面 9 含 碳 物 質 可 於 產 生 海 綿 鐵 時 用 作 寫 本 堪 原 劑 〇 然 而 如 果 網 鐵 m 棄 物 (戡礦粉塵 >網撖粉塵、 頁 1 1 和 淤 泥 )之外堪有都市晓棄物在旋轉窯中被當作標的物 1 I 質 處 理 * 則 難 κ m 定 炫 溫 及 使 標 的 物 在 旋 轉 窯 内 順 利 移 1 1 動 〇 1 訂 如 上 所 述 售 使 用 旋 轉 窯 於 再 利 用 阚 Afh. 鐵 工 集 m 棄 物 時 % 1 I 有 各 種 極 待 消 除 之 問 題 〇 1 [ m 明 1 要 i 1 本 發 明 之 百 的 在 提 供 一 種 方 法 和 一 種 裝 置 作 為 自 一 標 1 咸 的 物 中 > 其 如 網 鐵 工 業 m 棄 物 参 回 收 有 價 值 之 物 質 t 其 1 如 鐵 合 金 而 可 直 接 用 為 製 鏑 程 序 之 材 料 Q 1 1 根 據 本 發 明 * 提 供 一 種 再 利 網 m 工 業 m 棄 物 之 方 法 f i I 其 為 以 m 棄 物 作 為 標 的 物 予 Μ 處 理 ， 利 用 — 旋 轉 窯 • 於 1 1 標 的 物 在 旋 轉 窯 由 上 游 側 輸 向 下 游 側 的 白 標 的 物 回 收 有 1 價 值 之 物 質 〇 此 方 法 所 含 之 步 驟 包 括 於 旋 轉 窯 内 之 墦 原 1 1 環 境 中 • 在 上 游 側 加 熱 於 標 的 物 » 以 獲 得 被 堪 原 之 產 物 1 1 $ 並 熔 融 該 產 物 使 成 包 含 金 蹰 6 - 熔 體 與 熔 渣 之 經 m 原 並 熔 1 1 1 ! i 本紙張尺度適用中國园家標準（CNS ) Λ4規格（2丨Ο X 297公《 ) 4 5 55 Γ6 A7 B7 經濟部中央標率局員工消費合作社印製 五、發明説明（- Γ ) 1 1 融 之 產 物 並 在 旋 轉 窯 下 游 側 由 已 堪 原 並 熔 融 產 物 中 回 1 1 I 收 有 會 值 之 物 質 〇 1 1 較 佳 者 在 上 述 方 法 之 中 » 於 旋 轉 窯 上 游 側 有 一 進 料 請 先 1 1 端 * 在 下 游 側 有 一 出 科 端 * 一 堰 位 於 m 近 旋 轉 黛 内 出 科 閲 讀 1 背 1 端 之 處 ， 在 出 料 端 指 囱 上 游 側 之 —— 預 定 距 離 内 形 成 一 盆 之 1 注 | 形 t 此 盆 形 成 —* 凹 部 而 内 徑 大 於 其 餘 部 份 0 意 事 i 根 據 本 發 明 » 也 提 供 一 種 装 置 Μ 再 利 用 網 Α*Λ 賴 X 業 m 棄 再 1 填 1 物 » 此 裝 置 包 含 —- 旋 轉 窯 t >X m 棄 物 為 標 的 物 而 予 處 理 本 裝 « 於 標 的 物 從 旋 轉 窯 内 上 游 側 輸 向 下 游 側 之 際 » 白 標 的 頁 1 1 物 中 抽 取 有 價 值 物 質 • 旋 轉 窯 有 一 加 熱 燃 値 設 於 上 游 側 1 I > Μ 使 標 的 物 在 預 定 之 溫 度 被 加 熱 而 熔 融 9 旋 轉 窯 有 一 J 1 氣 體 與 固 體 反 應 段 » 位 於 上 游 側 以 m 原 標 的 物 中 所 含 之 1 訂 ，金 属 氧 化 物 t 使 獲 得 低 拂 點 金 鼷 而 予 蒸 發 除 去 « 得 到 高 1 1 沸 點 金 届 而 為 熔 融 之 m 原 產 物 • 其 中 包 含 金 靥 熔 融 體 和 \ 1 熔 渣 » 旋 轉 窯 有 一 抽 取 段 位 於 下 游 側 Μ 抽 取 已 還 原 熔 融 1 丨 產 -物 中 之 有 價 值 物 質 〇 1 較 佳 者 在 上 述 裝 置 中 1 旋 轉 窯 在 上 游 側 有 —· 進 科 端 1 f 在 下 游 側 有 — 出 料 端 * 在 旋 轉 窯 内 出 料 端 鄰 近 處 有 一 1 i 堰 « 並 於 白 出 料 端 自 上 游 側 之 預 定 距 離 形 成 一 盆 i 此 盆 1 | 形 成 凹 部 而 有 大 於 其 餘 部 份 之 内 徑 〇 I 1 Μ 上 述 之 情 形 9 在 鋼 A*tt m 製 程 中 所 形 成 之 锁 碟 粉 塵 和 網 1 戡 粉 塵 被 再 m 而 成 可 再 利 用 之 資 源 〇 特 別 是 爾 m 粉 塵 被 1 | 堪 原 、 熔 融 並 分 離 成 金 臑 熔 體 和 熔 渣 二 層 而 分 別 被 數 集 1 1 或 收 回 〇 金 屬 熔 體 被 冷 卻 成 m 7 - 合 金 而 可 直 接 用 作 製 網 材 1 1 1 I 1 本紙张尺Λ 4 β中家样率< CMS > A4規格（2丨OX 297公釐） 455516 A7 B7 五、發明説明（知 作 ， 用 序 % 程 可 鋅 渣 鍍 熔 和 至 線 甚 浸 。 酸 序 於 0 現 戡 出 製 也 於 泥 用。淤 可料 ， 金材外 合基之 鐵路塵 ，或粉 者料鐵 或材網 。 泥除 料水 之可 用油 利廢 再和 可 、 收紙 回廢 而如 理諸 處料 時材 同燃 合 可 混， 塵 中 粉物 截棄 網廢 與市 泥都 淤在 使 〇 Μ 源 可資 煤 之0 所 原 堪 作 當 以 可 質 物 碳 含 而 料 燃 份 ： 部明 作說 用式 Μ 0 之 法 方 物 棄 廢 業 Η 娥 網 用 利 再 的 發 本 據 根 為圖 .， 1 圖 第明 說 第 剖 之 縱 窯 例 轉 施 旋 實 之 二 盆 第 有 之 附 窯 中 轉 法 旋 方 盆 際 附 茛 為 明 別· 發.，分 本圖圖 據面3Β 根剖第 為縱與 圖例圖 2 胞 3 第實第 剖 縱 例 施 實 三 第 之0 轉 於 盆 附 為 別 分 ;画 圖4Β 面第 剖與 横圖 β 4 圖第 0 ΓΧ3 剖 蹤 例 胞 實 ; 五 圖第 面之 剖窯 縱轉 例旋 施盆 實附 四為 第別 之分 ; 窯圄 圖轉6Β 面旋第 剖為與 橫匾圖 與 5 6 圖第第 面 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印裝 要 主 例 陁 實 六 第 之 窯 轉 旋 盆 附 為 別 分 ; 圈 圖7Β 面第 剖與 横圖 與7Α 圃第 面 之0 驗 試 之 用 法 方 明 發 本 ; 估 圖評 面為 ^u 苗 S 横分 與圖 圖8B 面第 剖與 縱圖 之8A 份第 部 之 察 覼 所 爐 驗 試 示 所 圖 β 8 第 與 圃 ‘， ΔΜ 3J 〇〇 圖 ; 第線 圖用曲 面.使率 剖示昇 横表上 一 圖度 及 g 溫 面第床 端 爐 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 455516 A7 B7 經濟部中央梯隼局員工消費合作社印製 五、發明説明（ 7 ) 1 1 第10圖表示在第8A圖與第8B圖所示試驗訄 中 於 形 成 熔 1 I 體 之 前 若 干 時 點 觀 察 所 得 堪 原 程 度 金 鼷 化 程 度 » 和 除 1 1 锌 程 度 曲 媒 圖 S 請 先 1 第11圖表示第8A圃與第8B圖所示試驗®所得银合金產 閱 讀 1 背 1 物 與 原 用 標 的 物 中 所 含 各 金 鼷 元 素 之 分 佈 比 率 分 析 圖 〇 之 1 注 | 較 佳 A 鵂 例 說 明 意 事 1 茲 先 說 明 本 發 明 之 原 理 〇 再 1 填 稂 據 本 說 明 之 方 法 i 標 的 物 質 被 迅 速 熱 至 高 溫 i 烴 遇 寫 本 裝 氣 體 固 體 反 應 • 得 一 熔 融 產 物 而 為 含 海 綿 m 之 已 堪 原 頁 1 1 產 物 〇 在 此 高 溫 中 > 瘩融庳物被分成金靥熔體和熔渣而 1 I 予 分 別 回 收 〇 熔 渣 可 被 熔 化 或 不 熔 化 〇 金 匾 熔 體 繼 而 被 1 1 冷 卻 變 成 A*ti m 合 金 因 此 1 可 Μ 消 除 傳 铳 方 法 中 由 於 结 附 1 訂 所 生 之 缺 點 而 有 效 回 收 有 價 值 之 材 料 0 1 I 在 本 發 明 方 法 中 所 用 旋 轉 窯 之 長 度 L 和 内 徑 D 所 成 之 1 f 比 率 (L/D)比習用方法所用者為小 >較佳者， 此比率不 1 1 大 於 5 ，如上所述， 此旋轉窯有- -加熱燃爐位於窯之上 1 1 游 側 0 以 此 结 構 « 旋 轉 窯 内 部 可 kK 完 全 充 份 加 熱 至 高 溫 1 〇 甚 至 發 生 上 述 之 结 附 時 1 結 附 物 也 被 加 熱 燃 爐 所 熔 化 1 1 而 被 除 去 〇 所 Μ 本 發 明 方 法 採 取 異 於 習 用 方 法 之 單 1 | 途 徑 〇 1 1 在 本 發 明 方 法 中 * 旋 轉 Μ 被 操 作 >λ 用 含 碳 瘩 原 劑 堪 原 1 I 標 的 物 使 成 已 堪 原 之 產 物 ， 並 熔 融 此 已 道 原 之 產 物 供 回 1 1 收 作 為 可 再 利 用 之 材 料 〇 標 的 物 包 含 製 m 程 序 和 製 網 程 1 1 序 中 之 餓 碾 粉 塵 和 網 蝕 粉 塵 t 以 及 出 現 於 酸 浸 線 和 鍍 鋅 1 | 9 - 1 1 1 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐） 4 5 551 © A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ) 1 1 1 程 序 中 之 淤 泥 # 而 且 含 有 戡 m 和 路 〇 特 別是標 的 物 1 1 I 中 所 含 金 靨 氧 化 物 被 用 堪 原 劑 堪 原 而 成 各 種 金鼷。 在 這 1 1 1 些 金 羼 中 1 低 沸 點 金 屬 之 如 鋅 者 被 蒸 發 除 去 。另方面 * 請 先 1 1 高 沸 點 金 屬 之 如 m 者 Κ 金 靥 熔 體 而 被 回 收 1 经冷卻 而 得 閱 1 I 撖 合 金 〇 殘 餘 物 被 Μ 熔 渣 回 收 〇 η έ 之 1 1 注 [ 於 是 所 回 收 鐵 合 金 有 低 含 梓 量 (Z n / F e 1 . 0/1000 重 量 意 事 1 比 >而可再用於製鋼程序 >亦或可以用於製鐵程序 > 項 再 1 填 在 饋 入 標 的 物 於 旋 轉 窯 之 前 1 含 碳 堪 原 劑 (粉煤 '焦 寫 本 裝 屑 > 或 類 U 者 )與標的物K習知之乾法或濕法予K混‘合 頁 1 1 Q 如 用 乾 法 • 混 合 物 直 接 加 入 旋 轉 窯 之 中 9 或與濕 法 中 1 I 所 得 之 脫 水 餅 混 合 〇 另 一 方 面 t 濕 法 製 得 之 混合物 被 脫 1 1 水 而 成 脫 水 餅 i 然 後 可 被 直 接 加 入 旋 轉 窯 中 ,或先 與 粉 1 訂 煤 混 合 0 1 | 本 發 明 之 旋 轉 窯 有 一 基 本 結 構 特 徵 t 其 為 1 (1)加熱燃爐位於旋轉窯上游樹£ ，此意為燃氣流平行 1 1 於 標 的 物 流 〇 ! (2)旋轉黛長度L 與直徑D 之選擇應使L/D比率不 大 於 Λ 1 5 (L/DS 5 ) 1 | (3)旋轉窯傾斜度相對於水平面在1 與 2。 之間以保持 1 1 反 應 (堪原） 或 熔 融 所 需 充 分 留 滯 時 間 〇 [ 1 (4)旋轉窝有- -排氣端接合於第二燃馍室 > 1 1 為 改 進 鐵 合 金 回 收 比 較 比 率 而 用 作 回 收 材 料，熔 渣 物 1 質 如 焚 灰 者 可 與 將 被 熔 融 之 標 的 物 m 合 在 一 起。在 其 中 ί 1 t 金 臑 熔 層 之 表 面 被 熔 渣 層 充 份 覆 蓋 而 免 於 使金靥 熔 層 1 1 1 0 1 1 ί i 本紙張尺度適用中國國家標窣{ CNS ) A4JlUi (. 公Λ > 455518 A7 _B7_ 五、發明説明（9 ) 被氧化。 接合於旋轉窯出枓端之第二燃燒室是由旋轉窯供給排 出氣SIK完全燃燒在排氣中未被燃燒之物質。此外，第 二燃燒室Μ高溫熱解將有害物質；如戴奧辛（Dioxitie) 者轉化作無害氣體而後排放於系铳之外。排出氣胼加热 至高溫之热能與第二燃燒室的燃燒熱被叵收至一鍋®中 作為次一階段蒸汽所需。因此，整個程序耗熱量被降低。 金靥熔體和熔渣被蝕入一水槽位於旋轉窯出料端之下 。在水槽中冷卻後，金屬熔體和熔渣被排出系統之外而 成回收物質。冷卻水槽10是連縝K循環水供應使金屬熔 體和熔渣被授拌而充份冷卻。如有需要，金屬溶體和熔 渣可在後續階段用磁力分離法予以分離。 隨後，根據本發明之再利用飼羧工業廢棄物之方法與 装置將參考附圖作詳细說明。 經濟部中央標準局員工消費合作社印裝 (請先聞讀背面之注意事項再填寫本頁) 參考第1圖說明本發明方法。在網鐵工廠中彩成之網 戡工業廢棄物包含網鐵工業粉塵1-1和鋼鐵工業淤泥卜2 被作為主要標的物處1里。網鐵工業粉歷1-1包含鐵碳粉 塵、收集自製鐵程序或製飼程序之岡戡粉蜃，和焚灰。 網戡工業淤泥1-2形成於酸浸嬝和鍍鋅程序。 於初步處理時，餌鐵工業粉塵1-1與含碳适原劑3如 煤和焦屑等混合於一濕式混合槽4之中而成一混合物。 此混合物於脫水機5中脫水而成脫水餅蝕入旋轉窯7。 在網鐵工業粉塵1-1中，熔渣物質之如焚灰者可以直接謂 人旋轉窯7之中。 -11- 本紙張尺度適用中國國家標準（CNS ) 格（2IOX 297公釐）455516 A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (1) 1 Background of the invention 1 1 | The present invention uses methods and devices for mm I industry to discard 1 I Reuse S to better deal with the target formed in the m factory of the network, please 1 first 1 or m to recover valuable materials with a target — a method and a review 1 back I kind of device 0 surface 1 Generally «a large amount of various wastes will inevitably be produced in iron sales factories. Example I 1 | such as. * This waste includes iron ore dust and iron and steel dust. Iron and steel dust. In the process of selling, 0 These wastes are filled in this package and collectively referred to as iron industry waste or waste for short 0 Page 1 | Better steel X industry waste is reprocessed Used to recover metals with a value of 1 I > For example, iron 0 remaining in the waste of the iron industry, take this 1 1 into consideration »Traditional methods have been used for reprocessing and reuse. Types of waste 9 are iron ore dust and m iron dust. However, these methods are expensive9 and difficult to use in industry. In this situation, the most commonly used and treated waste is landfill with only a small part. 1 I waste is reused 〇1 In recent years * As landfill capacity has been developed • The waste has gradually become a serious problem Q 1 I Therefore, 9 waste disposal has become a national 1 1 I under the environmental regulations Sexual problems in this situation »There is an urgent need to increase the reuse of resources 〇1 1 At the same time because of the * m t Therefore, it is necessary to test 1 1 recycling of waste to iron and copper smelting methods. 0 However, it must be noted that the m waste in the steel 1 and X industries often contains heavy metals such as m and lead. * This heavy metal m must be removed. > Otherwise it will damage the blast furnace it 3- It is well known to the industry 〇 In order to remove 1 1 1 I 1 This paper size applies Chinese national standard (CNS > Λ4 specification (210X297 mm) 455516 Employees' Cooperatives, Central Standards Bureau, Ministry of Economic Affairs Printing A 7 __ B7_ V. Description of Invention (>) Plutonium and lead, the industry has adopted a variety of well-known methods. Two second methods commonly used in web manufacturing processes. Especially in the first method, the zinc oxide contained in the waste material is volatilized and gradually destroyed by using coke as a priming agent in a rotary kiln. Zinc oxide is then removed from the waste. Furthermore, the oxidative interception of kanbara turned into sponge sponge with low content and returned to the oven or sintered tart. In the second method, the components of the catfish contained in the waste are distinguished from each other by a wet dust separation method, so that the waste is divided into a first part containing a high zinc concentration and a first part containing a low zinc concentration. Two parts. The first part was used in the non-starved gold plaque industry as the original sampan and the second part was fed back to the high slab or sintering machine in the iron making method. After that, the second part was subjected to the net loading procedure. As mentioned earlier, the lettuce oven and sintering machine are devices in the ironmaking process. In other words, the recovered material is used in the lock-making process before the bait-making process. Usually, the first method requires pre-treatment of a predetermined degree of sheet-like rejects before being fed into the rotary kiln. In addition, the recovered zinc-removed material cannot be returned to the manufacturing process, but it can be used as a raw material for the manufacturing process. This is due to the low purity of the valuable plutonium contained in the recycled material. Therefore, the first method is unfavorable because of the operating cost of recycling materials. On the other hand, zinc is disadvantageous because it does not shrink sufficiently and does not separate. In either of these methods, it is not possible to recover valuable materials at low operating costs. More specifically, the first method has another disadvantage. It will be explained. The first method should be M gas and solid reaction, so that the olive ore is directly Kangan-4-(Please read the precautions on the back before filling this page) This acre size is common to China National Standards (CNS) Α4. (2Ι0 / ΝΊ 4 5 5 5 1 6 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () 1 1 〇 Therefore, it is inevitable to combine with some substances in the principle and principle of the rotary kiln * 1 1 I It is difficult to make the rotary kiln run continuously for 1 1 due to the problem of increasing the size. Because of the condition of this item and the actual condition «Rotating M, you must wait for it. 1 1 〇Read 1 Back 1 Actually ♦ The rotary kiln is operated at a lower temperature κ not higher than about ΐ 2〇ου 1 Note | Degree operation 〇 Yiqing 1 plus M consider 9 length of the rotary kiln α) The ratio of diameter (d) (item 1 and L / D) cannot be less than 2 0 0 In addition I It is placed on the P side of the rotary kiln. 0 The writing book is installed at any rate. * Rotary kiln is often long cylindrical. Keep a long enough page Vw- · 1 1 lag time. 〇 The above structure • The rotary kiln itself is large and expensive. 0 1 1 As mentioned above »K rotary kiln for reuse of waste from the grid m X industry must 1 1 take into account its cost. Therefore • Rotary kiln 9 is not used except for special examples. Recycling 〇1 I uses a rotary kiln in the netting industry m. There is another problem in the reuse of waste. The problem is said that 1 1 is explained below. 〇 1 1 Η >-The arrangement described above a combustion air flow from the exit side to the waste Reverse in I rotation M. Such a combustion gas flow is called counter current. 1 The counter current of gas and the entropy of the fuel are heated together to waste P that is sent to the rotary kiln. So the 1 1 rotary kiln is very long, as described in 刖.The temperature in the rotary kiln is white P side 1 | the input P side gradually decreases 0 although this structure can be reduced 1 by 1 1 when m waste is transported and the reduction effect is completed on the outlet side * In the rotary kiln The m waste attached to the inner wall 1 | occurs in areas with large temperature changes. 0 Attachment is usually 1 1 out of the ring shape and is called kanhuan 0 1 1 In addition to m ore dust and net Aff. 锇 powder dust t Net i + fc m Industrial waste contains 1 | 5-1 1 ί The size of this paper is applicable to Chinese national standards (CNS > Λ4 is now (210X297 mm) 4 5 5 5 1 6 A7 B7 Employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative V. Description of the invention (4) 1 1 Sludge produced on the acid leaching line and in the m zinc method. This m mud contains m 1 1 I m chromium and other substances. This sludge cannot be dehydrated and granulated in practice. ; 1 Μ cannot be treated with conventional rotary kiln. Please first 1 1 in the Lai factory and other activities or other activities in the application 1 to produce a readable 1 back 1 flammable materials such as m paper wood m * and m oil > λ and various carbonaceous substances 0 may Fir 1 Note I Combustible substances and carbonaceous substances are collectively referred to as municipal waste. Combustible substances can be used as fuel when the sponges are hungry when processing Yihua 1 ore dust er m dust and sludge. 〇Other—- Aspect 9 Carbonaceous substances can be used as a scripting agent in the production of sponge iron. However, if the net iron m waste (yenite dust > net dust, page 1 1 and sludge) can be used outside the city The waste is treated as the target in the rotary kiln 1 I quality treatment *, it is difficult to set the temperature and make the target move smoothly in the rotary kiln 1 1 Movement 〇1 Order to use the rotary kiln for reuse as described above阚 Afh. % 1 I have various problems that need to be eliminated when working set m 1 [m 1 1 i 1 The invention of the present invention provides a method and a device as a standard from the standard 1> Such as The net iron industry m waste is involved in recovering valuable substances t 1 such as ferroalloys which can be directly used as the material for the process of making Q 1 1 According to the present invention * a method for reusing net m industry m waste fi i is Use m waste as the target for M treatment, use-rotary kiln • 1 1 target is transferred from the upstream side to the white label in the rotary kiln in the rotary kiln to recover 1 valuable material. The steps included in this method are included in墦 原 1 1 in a rotary kiln in an environment • heating the target on the upstream side »to obtain the kanbara product 1 1 $ and melting the product to contain gold 蹰 6-melt and The slag warp m original fusion 1 1 1! I This paper size applies the Chinese Gardener's Standard (CNS) Λ4 specification (2 丨 〇 X 297 male ") 4 5 55 Γ6 A7 B7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation 5. Description of the invention (-Γ) 1 1 The melted product is returned from the original and melted product on the downstream side of the rotary kiln. There is a feed at the upstream side of the rotary kiln, please first 1 end * there is a branch end at the downstream side * a weir is located near the end of the rotating dai inside the branch reading 1 at the back 1 end, at the discharge end refers to the upstream side of the mound— — 1 of a pot formed within a predetermined distance Note | Shape t This pot is formed— * a recessed portion with an inner diameter larger than the remaining portion 0 meaning i according to the invention »A device M recycling net A * Λ lai X industry m abandoned 1 more fill 1 »This pack Including —- rotary kiln t > X m waste as the target and pre-processed this package «On the occasion when the target is transported from the upstream side to the downstream side in the rotary kiln» White Label Page 1 1 Extract valuable substances • The rotary kiln has a heating burner located on the upstream side 1 I > Μ The target is heated and melted at a predetermined temperature 9 The rotary kiln has a J 1 gas and solid reaction section »located on the upstream side with the original target contained in m 1 order, the metal oxide t is obtained by evaporating and removing low-flutter gold tincture «to obtain high 1 1 boiling point gold and then melted m original product • which contains gold tin melt and \ 1 slag» a rotary kiln has a extraction The section is located on the downstream side. M Extracts the reduced and melted 1 丨 The valuable substances in the product-1 is better in the above device. 1 The rotary kiln is on the upstream side. The inlet end 1 f is on the downstream side. — Discharge end * There is a 1 i weir «near the discharge end in the rotary kiln, and a basin i is formed at a predetermined distance from the upstream side of the white discharge end. This basin 1 | forms a recess and has an inner diameter larger than the rest 〇I 1 Μ Case 9 above The disc dust and net 1 formed in the steel A * tt m process 1 The dust was re-used into reusable resources 〇 In particular, the dust was 1 | Kanahara, melting It is separated into two layers of gold smelt melt and slag, which are respectively collected by 1 1 or recovered. The metal melt is cooled to m 7-alloy and can be directly used as a mesh material. 1 1 1 I 1 This paper ruler Λ 4 β Home sample rate < CMS > A4 specification (2 丨 OX 297mm) 455516 A7 B7 V. Description of the invention (known as, the order of% can be zinc slag plating and melting and wire dipping. The acid sequence is produced at 0 and is also used in mud. Silt material, railroad dust, and powder metal or iron mesh. The sludge can be removed from oil and water, and can be recycled, and the paper can be collected and recycled, and the materials can be mixed with the fuel when the materials are disposed of. The No. 0 coal mine can be regarded as a kind of combustible carbon and the fuel is burned: Ministry Ming Zuo said that the method of formula M 0 is used to abandon the waste industry. The figure shows that the example of the vertical kiln in the second section is used to transfer the two solid bowls, and some of the kilns in the intermediate kiln are transferred to the square, and the pelvic edible buttercups are divided into different sections. Legends Figure 2 Cell 3 Section 3 Vertical Example Implementation 3rd Section 0 Turn to Basin Attachment as Separate; Draw Figure 4B Section Section and Cross Section β 4 Figure No. 0 Γ × 3 Trace Example Example Section 5 The example of the vertical turning of the split kiln is divided into four parts according to the actual application; the figure of the kiln is turned to 6B, and the cross section is the same as the horizontal plaque and the 5th figure. (Please read the precautions on the back before filling in this Page) The main examples of the printing of employee cooperatives by the Central Bureau of Standards of the Ministry of Economic Affairs The kiln rotary basin is attached separately; circle the figure 7B and the cross section and the 7A plot of the 0 test test method Fang Mingfa; the estimated map is ^ u Miao S cross section and the figure 8B section Figure 8A of the longitudinal section of the inspection report of the inspection of the furnace, β 8 The first and the ', ΔM 3J 〇〇; The line graph uses a curved surface. Warm surface bedside furnace This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X 297 mm) 455516 A7 B7 Printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) 1 1 Figure 10 Figure 8A and Figure 8B show the degree of virgin metallization degree and the division of the degree of galvanization »and the division of zinc degree S in the test sample shown in Figure 8A and Figure 8B. 8A and 8B The silver alloy obtained from the test® shown in Figure 1 Analyze the figure 〇1 Note | Better A Illustrate the meaning of the example 1 First, explain the principle of the present invention 〇 Then 1 fill in the method according to this description i The target substance is rapidly heated to high temperature i Hydrocarbon meets the written solid gas reaction • A molten product is obtained as the original product containing sponge m. 1 1 Product at this high temperature> The molten material is divided into gold alloy melt and slag and 1 I is recovered separately. The slag can be melted or The melting of the gold plaque is not melted, and then it is cooled by 1 1 to become A * ti m alloy. Therefore, 1 can eliminate the defects caused by the attachment in the transmission method and effectively recover valuable materials. 0 1 I In the method of the present invention The 1 f ratio (L / D) formed by the length L and the inner diameter D of the rotary kiln used in the method is smaller than that used in the conventional method. ≫ The better, the ratio is not 1 1 and greater than 5, as mentioned above, the rotary kiln Yes-heating The furnace is located above the kiln 1 1 swimming side 0 With this structure «The interior of the rotary kiln can be fully heated to high temperature 1K 〇 Even when the above-mentioned attachment occurs 1 the attachment is also melted by the heating furnace 1 1 and is Removal of 〇M The method of the present invention adopts a method 1 which is different from the conventional method | Path 〇1 1 In the method of the present invention * Rotation M is operated > The product of the original product is melted and returned to the original product for recycling. The 1st object is recyclable material. The subject matter includes the m-making process and the net-making process. Wire and galvanized 1 | 9-1 1 1 This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X297 mm) 4 5 551 © A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention) 1 1 1 Sludge in the procedure # and contains 戡 m and Lu 〇, especially the target 1 1 I The gold 靥 oxide contained in the 1 1 I is used as a kanji agent to make various kinds of gold 鼷. Among these 1 1 1 1 gold lumps, 1 low-boiling metals such as zinc were evaporated. On the other hand * Please recover 1 1 high boiling point metals such as m Κ gold 靥 melt and recover 1 1 after cooling 1 撖 alloy 〇 residues are recovered by Μ slag 〇 1 1 1 [ The recovered ferroalloy has a low content (Z n / F e 1. 0/1000 weight and meaning 1 ratio) and can be reused in the steelmaking process> or it can be used in the ironmaking process> item 1 is filled in the feed The target is placed before the rotary kiln. 1 The carbon-containing virgin agent (pulverized coal 'coke book loading chips> or U-like) and the target K are known to be mixed by dry or wet method to K'. 1 1 Q If used Dry method • The mixture is directly added to the rotary kiln9 or mixed with the dehydrated cake obtained from the wet process 1 I. On the other hand, the mixture prepared by the wet process is dehydrated 1 1 to form a dehydrated cake i and then can be directly added to the rotary kiln. Medium, or mixed with powder 1 before ordering coal 0 1 | The rotary kiln of the present invention has a basic structure Structural feature t It is 1 (1) The heating furnace is located in the upper tree of the rotary kiln. This means that the gas flow is parallel to the target stream 1! (2) The selection of the length L and the diameter D of the rotating dai should be an L / D ratio Not more than Λ 1 5 (L / DS 5) 1 | (3) The tilt of the rotary kiln with respect to the horizontal plane is between 1 and 2. In order to maintain the 1 1 reaction (Kanhara) or sufficient dwell time required for melting 〇 [1 (4) The rotating nest has--the exhaust end is connected to the second combustion chamber > 1 1 It is used as a recycling material in order to improve the ferroalloy recovery comparison ratio. The slag material 1 such as ashes can be compared with the target to be melted. The objects m are put together. On the surface of which 1 t gold smelt layer is fully covered by the slag layer to avoid the gold smelt layer 1 1 1 0 1 1 ί i This paper size applies to Chinese national standard {CNS ) A4JlUi (. Public Λ > 455518 A7 _B7_ 5. Explanation of the invention (9) is oxidized. The second combustion chamber connected to the outlet of the rotary kiln is the exhaust gas supplied by the rotary kiln. The SIK completely burns the unburned substances in the exhaust gas. In addition, the high temperature pyrolysis of the second combustion chamber M will convert harmful substances such as Dioxitie into harmless gases and then discharge them outside the system. The exhaust gas is heated to a high temperature and the heat of combustion in the second combustion chamber is collected in a pot ® as the next stage steam. Therefore, the entire program consumes less heat. The gold smelt melt and slag were eroded into a water tank located below the discharge end of the rotary kiln. After cooling in the water tank, the metal melt and slag are discharged out of the system to be recovered. The cooling water tank 10 is supplied with the flail K circulating water so that the metal melt and the slag are stirred and sufficiently cooled. If necessary, the metal solution and slag can be separated at a later stage by magnetic separation. Subsequently, the method and apparatus for reusing carboxylated industrial waste according to the present invention will be described in detail with reference to the accompanying drawings. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). The method of the present invention will be described with reference to Figure 1. In the net-iron plant, Saisei's net 戡 Industrial waste contains net-iron industry dust 1-1 and iron and steel industry sludge 2 and is used as the main object 1 mile. The net iron industry powder calendar 1-1 contains iron carbon dust, gangue powder dust that collects homemade iron processes or feeding processes, and incineration. Reticulated industrial sludge 1-2 is formed by acid leaching and galvanizing processes. At the time of preliminary treatment, bait-iron industrial dust 1-1 and carbon-containing activator 3 such as coal and coke dust are mixed in a wet mixing tank 4 to form a mixture. This mixture is dehydrated in a dehydrator 5 to form a dehydrated cake and rotted into a rotary kiln 7. In the net iron industry dust 1-1, the slag substance such as ashes can be directly referred to as the human rotary kiln 7. -11- The paper size is applicable to the Chinese National Standard (CNS) grid (2IOX 297 mm)
4 5 55 1 S A7 _B7 _ 五、發明説明（P ) 在大部份情況中，網耙工業游泥1-2是直接被饋入轉 窯7中.因脫水困難而不混合於濕式混合槽4之中如上述 。如果網戡工業淤泥1-2需要用碳堪原，一種外堪原劑（ 未示）於淤泥直接加入於旋轉窯7中時另外被加入其中。 此外，都市廢窠物2之如餒紙、木屑、塑膠廢棄物、 紙漿廢棄物、紙漿淤泥、和廢油等可以用作含碳适原劑 3之代替品或補充物質。其特別者，都市廢棄物2在濕 式混合槽4中與標的物質混合，其如含碳堪原劑3 。須 予瞭解者，即使其為用作堪原劑，都市廢棄物2本身主 要作為標的物處理。在都市廢棄物2之中含有比重小或 含，成份不適於濕式混合而被直接饋人轉窯7之中。 脫水餅作為標的物而被處理時，是於饋入段週邊溫度 為500與700t之間被饋人。此時，如霈外還原劑，即被 加入如上述。旋轉窯7為一平行流動式而且有一加熱燃 ^^1 I -- : HH I · —I- - ^^1 —- I {請先閱讀背面之注意事項再填寫本頁) 中 之 7 0 轉 旋 於 融 熔 並 、 原 0 ' 熱 加 。 被 段物 人的 饋標 於， 位後 6 隨 入下 饋過 自經 中。 7 熱 窯加 在 6 物爐 的燃 標之 之段 7 入 窯饋 轉於 旋位 入被 n LM 弓 0 被 ， ，段 者料 別出 特向 其輸 段 經濟部中央橾準局員工消費合作社印掣 金。 為卻 而冷 雔被 分步 並一 、 進 融而 熔出 kpr 、 5¾ 原 7 還窯 被轉 物旋 的自 標被 其 驟 ， 步渣 等熔 S4與 至體 S1熔 列屬 结可 。 物 份的 水標 含時 所此 物。 標送 目輸 發中 0 7 熱黨 加轉 7’旋 窯在。 轉而结 旋燥聚 人乾中 引被 7 被物窯 物的轉 的標旋 標，在 ml/ 4Π5 本紙張尺度適用中國國家標準（CNS ) Λ4現格（2IOX2?7公釐）4 5 55 1 S A7 _B7 _ 5. Description of the invention (P) In most cases, the net rake industrial sludge 1-2 is directly fed into the rotary kiln 7. Due to the difficulty of dehydration, it is not mixed with wet mixing The groove 4 is as described above. If the net sludge industrial sludge 1-2 requires carbon kangan, an exogenous agent (not shown) is added to the sludge when it is directly added to the rotary kiln 7. In addition, municipal wastes such as paper waste, wood chips, plastic waste, pulp waste, pulp sludge, and waste oil can be used as substitutes or supplements for the carbon-containing activator 3. Specifically, the municipal waste 2 is mixed with the target substance in a wet mixing tank 4 such as a carbon-containing kanogen agent 3. It must be understood that even if it is used as a virgin agent, the municipal waste 2 itself is mainly treated as a target. The municipal waste 2 has a small specific gravity or contains, and the ingredients are not suitable for wet mixing and are directly fed into the rotary kiln 7. When the dehydrated cake is treated as a target, it is fed to the surrounding temperature of the feeding section between 500 and 700t. At this time, as the external reducing agent, it is added as described above. The rotary kiln 7 is a parallel flow type and has a heating combustion ^^ 1 I-: HH I · —I--^^ 1 —- I (Please read the precautions on the back before filling this page) Rotate the fusion, the original 0 'heat plus. The person's feed was marked in, and the post 6 bits were fed through the Sutra. 7 The hot kiln is added to the section 6 of the burning stove of the 7-burner furnace. 7 The feed into the kiln is turned to the rotary position and the quilt n LM is bowed to 0 quilts. Indian gold. For this reason, the cold heading was step-by-step and merged to melt out the kpr, 5¾ and 7 kilns. The automatic standard of the rotating object was removed, and the step S4 and the melting of S4 were combined with the body S1. The water mark of the ingredients contains what it is sometimes. The bidding is in progress and the delivery is in progress. In turn, spin-drying gathers people's stems, and the standard of the 7 objects is converted to ml / 4Π5. This paper size applies the Chinese National Standard (CNS) Λ4 grid (2IOX2? 7 mm)
4 5 5 5 1 G A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（' ) 1 1 iL S?, -湛原程序 1 1 在 乾 燥 程 序 完 成 之 後 * 於 旋 轉 窯 7 内 有 效 進 行 各 種 氧 1 1 化 物 之 還 原 作 用 V 諸 如 標 的 物 中 之 氧 化 m > 氧 化 路 Λ 氧 請 先 1 化 鎳 氧 化 鋅 和 氧 化 鉛 〇 一 批 被 引 入 轉 窯 7 中 之 標 的 物 .閲 讀 合 1 1 被 稱 為 一 床 〇 當 床 被 加 熱 至 大 約 1000 υ 至 1200Ό 間 之 溫 之 [ 1 注 I 度 範 圍 1 遢 原 即 充 份 完 成 〇 低 沸 點 金 屬 之 如 鋅 者 被 堪 原 意 事 1 而 獲 得 1 卽 » 被蒸發並從堪原環境 中 之 床 轉 移 至 在 氧 化 項 再 ! 填 環 境 中 之 氣 體 空 間 0 在 氧 化 氣 氛 中 1 低 沸 點 金 靥 被 氧 化 寫 本 裝 並 排 出 旋 轉 窯 7 之 外 與 排 放 氣 體 共 同 於 後 鑛 階 段 中 被 頁 1 1 沈澱器14所收取 0 1 I 另 方 面 * 高 Α4» W 點 金 匾 之 所 在 還 原 作 用 所 得 之 海 绵 截 1 1 * 被 保 持 於 床 中 0 對 氧 化 金 屬 還 原 之 结 果 $ 生 成 一 氧 化 1 訂 碳 % 並 立 即 在 昧 上 被 來 白 燃 爐 6 之 過 星 空 氣 所 燃 燒 0 一 1 I 氧 化 碳 之 燃 燒 與 燃 訄 6 之 热 氣 合 併 供 對 床 之 加 熱 〇 一 氧 1 1 化 碳 m 燒 火 焰 也 有 肋 於 維 持 床 在 m 原環境 中 〇 1 1 驟 S3 -核鼬稃序 1 Λ 當 經 遇 氣 體 固 體 反 愿 之 堪 原 作 用 而 達 —*· 终 點 ， 且 溫 1 度 更 是 昇 至 1200 *C 或 更 高 之 時 * 每 綿 锇 被 還 原 劑 中 的 碳 1 1 所 飽 和 而 將 被 轉 m 為 金 鼷 熔 體 〇 此 金 屬 熔 體 再 與 如 鉻 與 1 I 線 等 金 臑 混 合 Μ 包 含 鐵 合 金 中 之 成 份 〇 除 戡 合 金 成 份 所 1 1 含 之 氧 化 物 如 S ί Ca 0 、和外之其餘氧化物可稱之 1 1 為 熔 渣 〇 金 龎 熔 體 和 熔 渣 被 轉 移 至 轉 窯 7 的 出 料 段 〇 在 1 出 料 段 保 持 溫 度 在 1 2 50 r 和 1 3 00 ¾ 之 間 » 金 靥 熔 體 和 溶 1 1 渣 被 利 用 溶 物 間 的 重 力 差 所 分 雔 〇 其 特 別 者 ， 金 靥 溶 體 1 | 13 1 1 1 本dAffl中gg家標準（CNS ) A4規格（210X297公釐） 4 5 55 1 l A7 __B7___ 五、發明説明（* ) 之比重大於溶渣。結果，金屬溶體沉於溶渣之下而完全 被溶渣所覆蓋。於是溶渣成為金匾溶膛與氧化環境間之 間隔。K比重分離之金靨溶體和溶渣於旋轉窯7之出料 端排放至一冷卻水樓10。 如果標的物中含有六價鉻，因係有害物質，六價鉻經 過堪原和熔融步驟如上述者，即被轉化成金蹰鉻或三價 鉻而為無害物質。 步既4 -排出餌泠節稈序 金靥熔體與熔渣被排出旋轉窯7之外，並供位至位於 旋轉窯7出料端下之冷$水槽10之中。在冷卻水槽10中 冷卻後，金靥熔體和熔渣被用輸送裝置12排出於冷卻水 槽10之外而為回收之材科。冷卻水槽10是連績K循環水 供應而攪拌金靨熔體與熔渣並予充份冷卻。如有需要. 金屬熔體與熔渣可K利用磁性分離法於後缜階段予以分 離。 經濟部中央橾準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 随後，排放氣體自旋轉窯7被排放出而將被處理於後 。從旋轉窯7排出之氣體被引人结合於旋轉窯7出料端 的第二燃燒室11。第二燃燒室中可使含於排放氣體中之 未燃物質完全燃燒。此外，含於排放氣體中之有害物質 被熱分解而轉變成無害物質。然後排放氣體被放經一熱 收回單元或熱交換器13,其如一涸鍋爐，而至沈澱器14 以待排放至大氣之中。 依據搮的物和性質，所希望回收物質的質與量，考處 堪原劑和燃料的成本，旋轉窯7內之氣氛可依兩項條件 本紙張尺度適用中國國家標準（CNS )別現格（210X297公釐> 經濟部中央標準局員工消費合作社印製 4 5 5 5 I A7 __B7五、發明説明（G ) 選擇，其為（A) —種堪原或極弱的氧化氣氛和（B)—種弱 的氧化瓌境。 (A)堪原或極弱之氧化環境。 假定在旋轉窯7之内部空間被保持於堪原環境或有低 氧含量之極弱氧化環境。在此環境中，金廳溶體很雔被 氧化。為提供如此之環境，在旋轉窯7之内須充份充K 适原劑。特別是加於標的物的垣原劑量可以為所需還原 劑計算當量之兩倍以上。或者，在旋轉窯7出口端之一 氧化碳濃度保持5X或更高，其發生於氣體空間且是堪原 之結果。在上述狀況中，旋轉窯較佳者設有一盆，其係 形成於留供金蹕熔體和焙渣用之出料段。在盆中，金屬 熔體和熔渣被引入充·份彼此接觸。在接觸間，熔渣中所 结合之各種元素因金匾素中熔渣轉移至金隰熔體和因為 金臈元素與溶渣間之分佈反應而分佈於熔渣和金屬熔體 之間。因此，在组成物中金屬熔體和熔渣樓定而被排出 旋轉窯之外成為回收材料。金屬熔體被製成一種鐵合金 。结果，可K精進戡合金的回收率而滅少留在熔渣中之 金臈含量。於是含少量金匾之熔渣可以應用於各種場合。 根據本發明，附盆之旋轉窯可Μ形成_多種结構。其間 若干種结構將參考附圖說明如後。 參考第2圖，一最簡單之旋轉窯21,其長度例如在10 與15公尺之間.自人口端（圖中之左手側）至出口端（圖 中之右手側）。旋轉窯21有一盆211和一出口堰212位於 其内表面上。盆211彤成於旋轉窯21出料端起算之預定 -15- (請先閲讀背面之注意事項再填寫本頁) 本紙伕尺度適用中國國家標牟（CNS . 2丨0X 297公聲） 45 55 1 6 A7 __B7_ 五、發明説明（K ) 範圍而延向人口端。例如，Μ上述長度之旋轉窯，其預 定距難為1公尺與2公尺之間。其特別者，盆2U是在 上述預定距離處加寬内徑而彤成。熔融之產物.包括金 屬熔體和熔渣，被保持於盆211中達預定之時間Μ容許 加速金鼷熔體自熔渣分出。為加寬旋轉窯21之内徑，一 内酎火層（未出 ')形成於旋轉窯21之内表面，於對應上 述盆211預定距雛中減小其厚度，使不改费旋轉窯21外 骰之外徑。或者，寬外殻之外徑而不改變内耐火層之厚 度。 參考第3Α圖與3Β圖，旋轉窯22有一盆221,至少在旋轉 窯22中形成一對出料道223,彼此Μ徑向相對，並有至少 一對出料塞22 4配置於出料道223。出料道223用於當旋 轉窯22停止時後旋轉窯22排出熔融產物。，出料塞224分 別藉塞之移離和置人出料道而用於啟開出料道223。 參考第4Α圖與第4Β圖，一旋轉窯23有一盆231和一形 成於盆231中之凸起塊233。 經濟部中央標準局員工消費合作社印策 ^^1- ^^^1 - · j - m ml I - (請先閱讀背面之注意事項再填寫本頁) 此凸起塊233用於授拌熔渣，使在盆231中熔渣與金匾 熔體之間有較佳之接觸而提昇結合於熔渣之金屬元素被 轉移至金鼷熔體之中，和金屬溶體與熔渣間之分佈反應。 參考第5圖，一旋轉窯24含有一圓筒形外殻和一形成 於外殺内表面之内耐火層，外骰與内耐火層在圓中未予 分別表示。内耐火層界定一盆241而有一内徑D1和長度L1 ,—中間段244有一内徑D2(D2<D1)和長度L2,和一氣體 一固體反應段243有一長度L3,和内徑D3,等於盆241之内 -1 6 - 本紙張尺度適用肀國囷家標準（CNS ) Μ規格（210X297公釐） 4 5 5 5 ] 經濟部中夹標準局員工消費合作社印裝 A7 _B7_五、發明説明（/ ) 徑D1。氣腊一固《I反應段243被中間段244與盆241隔開。 盆241、中間段244、和氣體一固體尽應段243可以依所 •需形狀改變內附火層之厚度而外骹直徑不變。此外，氣 體一固體反應段24 3可予加厚而K此结構使氧化環境對 床的影堪降低。於是床可保持曝露於堪原環境之中。再 者，中間段244之存在，熔融產物被保持於盆241中而得 防阻其擴張回至氣體固體反應段2 43,而且不致干預標的 物自上游側輸人下游側。此外，容易更換内附火層而不 須改變骰之外徑以改變氣體一固體反應段243和盆241之 面積。 參考第6A圖與第6B圖，一旋轉窯25有一盆251,—排放 堰252,和一内堰253, Μ此结構，金靥熔體層Μ在盆251 中被熔渣層S Μ某一厚度所覆蓋。如此以防金鼷熔體層 Μ之表面曝於氧化環境。 參考第7Α圖與第7Β圖，一旋轉窯26有一盆261和多數 個溝槽263形成於盆261中而以旋轉窯26之縱向延伸。金 鼷熔體層Μ澱積於溝槽263中，並經溝槽263排出。另一 方面，熔渣層S越過旋轉窯26整個遇邊而被排出。此種 结構之優點在於熔渣層S和金藺熔體層Μ可以分開由不 同位置排出，而且在盆261中之金屬體層可被防止一次 完全排出，甚至在產生大最熔融產物之時亦然。 (Β)弱氧化環境 旋轉窯内之空間可以保持氧化環境，使於金屬熔體長 時間被保持於旋轉窯内時促成發生氧化作用。為促成此 -17-4 5 5 5 1 G A7 B7 Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (') 1 1 iL S ?, -Zhanyuan Procedure 1 1 After the drying procedure is completed * Valid in the rotary kiln 7 Reduction of various oxygen 1 1 compounds V such as the oxidation of the target m > oxidation path Λ oxygen please first nickel oxide zinc oxide and lead oxide. A batch of the target is introduced into the rotary kiln 7. Reading 1 1 It is called a bed. When the bed is heated to a temperature of about 1000 υ to 1200Ό [1 Note 1 degree range 1 遢 原 is fully completed 〇 Low boiling point metals such as zinc are worth 1 to get 1 卽 » It is evaporated and transferred from the bed in the original environment to the oxidation item again! Fill the gas space in the environment 0 In the oxidizing atmosphere 1 The low boiling point gold tincture is packed and discharged out of the rotary kiln 7 together with the exhaust gas. 0 1 I collected by the depositor 14 during the mining phase. On the other hand * high A4 »W sponge sponge cut from the place where the gold plaque is located 1 1 * kept in the bed 0 result of reduction of oxidized metal $ generated The carbon monoxide is ordered by 1% and immediately burned by the star-crossing air from the white burner 6. 0 1 1 The combustion of carbon monoxide is combined with the heat of the burner 6 for the heating of the bed. The carbon m-burning flame is also ribbed to maintain the bed in the original environment. 0 1 1 S3-Weasel sequence 1 Λ When met by the gas-solid reaction, the end point is reached, and the temperature is more than 1 degree When it rises to 1200 * C or higher * Each cotton is saturated with carbon 1 1 in the reducing agent and will be converted into a gold alloy. This metal melt is then mixed with gold such as chromium and 1 I wire.臑 Mix Contains ingredients in iron alloys The oxides contained in the composition 1 1 such as S ί Ca 0 and the rest of the oxides can be referred to as 1 1 slag. The gold melt and slag are transferred to the discharge section of the rotary kiln 7. The temperature of the material section is between 1 2 50 r and 1 3 00 ¾ »Gold smelt melt and solvent 1 1 The slag is divided by the gravity difference between the melts. In particular, the gold smelt solution 1 | 13 1 1 1 In this dAffl, the gg home standard (CNS) A4 specification (210X297 mm) 4 5 55 1 l A7 __B7___ 5. The proportion of invention description (*) is greater than that of dissolved residue. As a result, the metal solution sinks under the slag and is completely covered by the slag. So the slag becomes the space between the dissolution chamber of the gold plaque and the oxidation environment. The solution and slag of gold ore separated by K specific gravity are discharged to a cooling water tower 10 at the discharge end of the rotary kiln 7. If the subject matter contains hexavalent chromium, it is a harmful substance. After passing through the primordial and melting steps as described above, hexavalent chromium is converted into gold tin chromium or trivalent chromium and is harmless. Step 4-Discharging the bait and stalk sequence The golden smelt melt and slag are discharged out of the rotary kiln 7 and placed in the cold $ water tank 10 located under the discharge end of the rotary kiln 7. After cooling in the cooling water tank 10, the gold smelt melt and slag are discharged out of the cooling water tank 10 by the conveying device 12 and are recovered materials. The cooling water tank 10 is a continuous K supply of circulating water, which stirs the gold tin melt and slag and cools it sufficiently. If necessary, the metal melt and slag can be separated at the subsequent stage by magnetic separation. Printed by the Consumers' Cooperative of the Central Government Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Subsequently, the exhaust gas is discharged from the rotary kiln 7 and will be processed later. The gas discharged from the rotary kiln 7 is introduced into the second combustion chamber 11 coupled to the discharge end of the rotary kiln 7. The second combustion chamber can completely burn unburned substances contained in the exhaust gas. In addition, harmful substances contained in the exhaust gas are thermally decomposed into non-hazardous substances. The exhaust gas is then passed through a heat recovery unit or heat exchanger 13, which is like a boiler, and then goes to the settler 14 to be discharged to the atmosphere. According to the nature and nature of the plutonium, the quality and quantity of the material to be recovered, and the cost of the original agent and fuel, the atmosphere in the rotary kiln 7 can be based on two conditions. This paper scale applies the Chinese National Standard (CNS). (210X297 mm > Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 5 5 5 I A7 __B7 V. Description of Invention (G) Choice, which is (A)-a kind of primordial or very weak oxidizing atmosphere and (B ) —A kind of weak oxidation environment. (A) Kanyuan or extremely weak oxidation environment. It is assumed that the internal space of the rotary kiln 7 is maintained in Kanyuan environment or a very weak oxidation environment with low oxygen content. In this environment The Jinting solution is very oxidized. In order to provide such an environment, the K activator must be fully charged in the rotary kiln 7. In particular, the original amount of the raw material added to the target can be calculated as two equivalents of the required reducing agent. Times. Or, the carbon oxide concentration at the exit end of the rotary kiln 7 is maintained at 5X or higher, which occurs in the gas space and is the result of the original. In the above situation, the rotary kiln is preferably provided with a pot, which is formed at It is reserved for the discharge section of gold tin melt and slag. In the process, the metal melt and slag are introduced into contact with each other. In the contact, the various elements combined in the slag are transferred to the gold smelt due to the slag in the gold plaque and because the metal slag and the molten slag The distribution reaction is distributed between the slag and the metal melt. Therefore, the metal melt and the slag in the composition are discharged out of the rotary kiln to become a recycled material. The metal melt is made into an iron alloy. As a result It can improve the recovery rate of the samarium alloy and eliminate the amount of gold samarium remaining in the slag. Therefore, the slag containing a small amount of gold plaque can be applied to various occasions. According to the present invention, a rotary kiln with a pot can be formed into a variety of types Structure. Several types of structures will be described later with reference to the drawings. Referring to Figure 2, a simplest rotary kiln 21 having a length of, for example, between 10 and 15 meters. From the population end (left-hand side in the figure) to The exit end (right hand side in the figure). The rotary kiln 21 has a basin 211 and an outlet weir 212 on its inner surface. The basin 211 is scheduled to be calculated from the discharge end of the rotary kiln -15- (Please read the back (Please fill in this page again for attention) National Standards (CNS. 2 丨 0X 297) 45 55 1 6 A7 __B7_ V. The scope of the invention description (K) extends to the population end. For example, for a rotary kiln of the above length, the predetermined distance is difficult to be 1 meter. Between 2 meters. In particular, the pot 2U is formed by widening the inner diameter at the above predetermined distance. The molten product, including metal melt and slag, is held in the pot 211 for a predetermined time Μ The accelerating gold smelt melt is allowed to separate from the slag. In order to widen the inner diameter of the rotary kiln 21, an inner flame layer (not shown) is formed on the inner surface of the rotary kiln 21, in a predetermined distance corresponding to the above-mentioned pot 211. Reduce its thickness so that the outer diameter of the outer die of the rotary kiln 21 is not changed. Or, the outer diameter of the outer shell is widened without changing the thickness of the inner refractory layer. Referring to FIGS. 3A and 3B, the rotary kiln 22 has a basin 221. At least a pair of discharge channels 223 are formed in the rotary kiln 22, which are radially opposed to each other, and at least a pair of discharge plugs 22 are arranged in the discharge channel. 223. The discharge channel 223 is used to discharge the molten product from the rotary kiln 22 when the rotary kiln 22 is stopped. The discharge plug 224 is used to open the discharge channel 223 by removing the plug and placing the discharge channel respectively. Referring to FIGS. 4A and 4B, a rotary kiln 23 has a pot 231 and a raised block 233 formed in the pot 231. Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^^ 1- ^^^ 1-· j-m ml I-(Please read the precautions on the back before filling this page) This raised block 233 is used for mixing slag Therefore, in the basin 231, there is a better contact between the slag and the gold plaque melt, and the metal elements that promote the binding of the slag are transferred into the gold tin melt, and the distribution reaction between the metal solution and the slag. Referring to Fig. 5, a rotary kiln 24 includes a cylindrical outer shell and an inner refractory layer formed on the inner surface of the outer slug. The outer dice and the inner refractory layer are not shown in circles. The inner refractory layer defines a basin 241 and has an inner diameter D1 and a length L1, the middle section 244 has an inner diameter D2 (D2 < D1) and a length L2, and a gas-solid reaction section 243 has a length L3, and an inner diameter D3, Equal to basin 241-1 6-This paper size applies the National Standard (CNS) M specification (210X297 mm) 4 5 5 5] Printed by the Consumer Cooperatives of the Zhongjia Standard Bureau of the Ministry of Economic Affairs A7 _B7_ V. Invention Explanation (/) Path D1. The gas wax-solid reaction section 243 is separated from the basin 241 by the middle section 244. The basin 241, the middle section 244, and the gas-solid response section 243 can be changed according to the required shape, and the thickness of the inner fire layer can be changed without changing the outer diameter. In addition, the gas-solid reaction section 243 can be thickened, and this structure reduces the influence of the oxidizing environment on the bed. The bed can then remain exposed to the original environment. In addition, the existence of the intermediate section 244, the molten product is kept in the basin 241 to prevent its expansion back to the gas-solid reaction section 2 43, and does not interfere with the object from the upstream side to the downstream side. In addition, it is easy to replace the internal fire layer without changing the outer diameter of the die to change the area of the gas-solid reaction section 243 and the basin 241. Referring to FIG. 6A and FIG. 6B, a rotary kiln 25 has a pot 251, a discharge weir 252, and an inner weir 253, Μ. With this structure, the gold smelt melt layer M is slag layer S M in the pot 251. Covered by thickness. This is to prevent the surface of the gold-alloy melt layer M from being exposed to an oxidizing environment. Referring to FIGS. 7A and 7B, a rotary kiln 26 has a basin 261 and a plurality of grooves 263 formed in the basin 261 so as to extend in the longitudinal direction of the rotary kiln 26. The gold rhenium melt layer M is deposited in the trenches 263 and discharged through the trenches 263. On the other hand, the slag layer S is discharged over the entire edge of the rotary kiln 26. The advantage of this structure is that the slag layer S and the gold melt layer M can be discharged from different locations separately, and the metal body layer in the basin 261 can be prevented from being completely discharged at one time, even when a large most molten product is produced. . (B) Weakly oxidizing environment The space in the rotary kiln can maintain the oxidizing environment, so that when the metal melt is held in the rotary kiln for a long time, oxidation occurs. To facilitate this -17-
—^ι· ί 1^11 ^^^1 n^— i n^— i ^^—^1 ^ V 0¾ 4a. (請先閲讀背面之注意事項再填寫本頁J 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 4 5 5 5 1 6 A7 _ B7__五、發明説明（4 ) 種環境，被加至標的物之堪原蜊量不大於堪原所需計算 當量約兩倍。產生於氧體空間中之一氧化碳•其濃度在 出料端大約低於5X。如此則在旋轉窯中無須形成盆區。 換言之.在於轉窓出料段不須設堰Μ成盆。此意指所設 計之旋轉窯使金匾熔體立即排出而不在旋轉窯内停留。 金屬熔體被製成鐵合金。此有盆之结構比較，鐵合金之 回收率較低而熔渣中金画含量較高。雖然如此，此種無 盆结構之優點為加至標的物之遢原劑可Μ減少，特別是 小至遢原所需計量之1.2至1.5倍。此外，燃科因還原所 生一氧化碳在旋轉窯内燃燒而得節省。 實施例 所說明者為關於網鐵工業廢棄物再利用方法之一特例 ，以及施行此方法所用之裝置。 在此實胞例中，Κ網鐵工廠所形成之一般粉塵供作試 驗。所用粉塵為製造不锈鏑之程序所形成。 作為標的物或材料之粉塵成份見於表1。 (請先閱讀背面之注意事項再填寫本頁} 經濟部中央標準局員工消費合作社印製 重量5! 表 1 T. Fe FeO Fe2°3 Cr Ni 2n Pb C P r S 39.6 9.8 45-8 8.1 2.5 0.50 0.10 0.83 0.06 0.14 CaO Si〇2 MnO 8*6 4.3 0*40 9.3 2.5 18™ 本紙依Λ1 4 阐家梂孪（CNS ) Λ4ϋ格（2lOX 297公釐） 經濟部中央標率局員工消費合作社印製 4 5 5.5 re A7 ___B7 _ 五、發明説明（) 材料之初步處理，上述粉塵以粉相與焦固堪原劑在濕 法中混合。脫水後，將温合物饋入試驗裝置。粉塵/焦 碳之粉塵為100/43重量比。焦屑之比率為相當於适原所 需計算當量之兩倍。 … 本試驗所用裝置為一如第8圖所示之批式旋轉窯爐之 試驗爐。所須注意者，雖然此試驗爐並非全與商業用裝 置之旋轉窯結構相同，標的物在旋轉窯內之縱向輸送位 置對應於試驗熵之操作時間。參考第8圖，旋轉®有一 訄室54, —燃爐55, —驅動齒鍵56, —輥輪57, —滑環 58, —排放塞59. —第一窺視口 60,逋之監視攝影機61 ，和一第二窺視口 62。訄室之内徑D為1300笔米而長度 L為500毫米。 在試驗中，140公斤之脫水餅含水量為22¾，被加人至 原為5001C之旋轉窯，以丙烷氣作燃料加熱。 旋轉窯K〇.4rp«i(每分鐘轉數）旋轉。床之溫度上昇率 見第9圖。在粉塵（脫水餅）加人後每90分鐘抽取金靨熔 體和熔渣之試樣，並進行至產生熔融產物為止。試樣之 分析，係除鋅程度、堪€程度、和金鼷化程度。特別是 鋅之除去程度Μ (原有鋅含里一琨有鋅含量）/(原有鋅含 量）表示。堪原程度Κ (原有氧含量一琨有氧含量）"原 有氧含量）表示。金屬化程度Μ (現有金靨鐵）/(現有總 鐵量）表示。 再後，在產生熔融產物之後，對金屬熔體和熔渣繼壤 取漾。從金麗熔體和熔渣的成份分析，得金圈熔體和熔 -19- 本紙悵尺度適用中國國家標準（CNS ) Λ4現格（210Χ297公釐） [ I I 訂 {請先閲讀背面之注意事項再填寫本頁) 455516 A7 B7 五、發明説明（，ί ) 渣之間每一金屬元素之分佈。本試驗在栢同條件下進行 五次試驗而得五姐試驗结果。 在五姐試驗结果中.少有起伏被費察。因此，Μ各試 驗结果中之一組單獨示於第10圈之中。 第10圖表示在形成熔體前不同時點之堪原程度、金展 化程度、和除鋅程度。 參考第10圖，可瞭解自粉塵饋人旋轉窯起約90分鐘之 後，疽些數值各已達90JK或Μ上。 在饋人粉塵約100分鐘之後，產生了金屬熔體。此時， 床之溫度約在12 50和1300 C之間，而且熔渣也被熔融。 表2表示鐵合金機熔渣在120分鐘之後取樣所分析之结 果0 表2中，T.Fe和Me.Fe分別代表「總戡量」和「金屬 鐵量J 。 鐵合金之姐成大約與高碳奥斯田基（Austenite)含Νί 與Cr不銹親相近且為非磁性。Ρ和S的含量分別在〇·〇9與 0.15¾之間和0.05與0.14¾之間。 羝合金（重量50 表 2 C—) ----------^------ΐτ------^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 蹁號 T*Fe Ζπ Pb Cr Ni S P C 1 82*4 0.016 0.02 6.7 4.2 0,14 0-15 3.3 2 72.0 0-015 0,02 8.0 3,9 0.09 0.14 4.2 3 69.7 0.033 0.03 11.0 4.0 0-05 0.12 5.4 4 71.0 0.005 0.01 ]4.2 3.7 0.09 0*03 4,7 5 63 · 4 0.006 0.01 16*9 4.0 0-06 0.09 5·2 -20 - 本紙張尺度適用中國國家標準（CNS ) ^ <2V7公« ) 45 5 5 T'0 " Α7 Β7 五、發明説明（，9 ) •表二（二） —-熔渣（屋量*：)-；- 試驗 垢號 T.Fe Me.Fe Zn Pb Cr Ni CaO Si02 Al2〇3 MgO 1 22.1 19.2 0.006 0.014 9,0 0.7 21,2 15.1 6.7 X3.4 2 13.1 11.1 · 0-006 0.011 8.5 0.6 24.3 17.2 6.3 17.3 3 18.6 14.6 0.024 0.013 6.6 0,7 18.8 13/8 4.4 13.0 4 17.7 11,0 0.014 0.008 10.2 0.6 20.6 14.2 10.3 14.9 5 22.0 18,3 0.006 0.007 9.6 1.1 23.4 14.5 4 Λ 16.7 獲 值 數 之 得 所 析 分率 從收 回 見 第 圖 收 回 Η 含 、 所 Fe物 含的 所搮 中示 金表 合00 趙1 M率 得 和— ^ Ι · ί 1 ^ 11 ^^^ 1 n ^ — in ^ — i ^^ — ^ 1 ^ V 0¾ 4a. (Please read the precautions on the back before filling in this page. J This paper size applies to Chinese national standards ( CNS) A4 specification (210 X 297 mm) 4 5 5 5 1 6 A7 _ B7__ V. Description of the invention (4) For the environment, the amount of kangaroo clams added to the subject is not greater than the calculated equivalent of kanyuan It is twice as much as that produced in the oxygen space. Its concentration is about 5X at the discharge end. In this way, there is no need to form a basin area in the rotary kiln. In other words, there is no need to set a weir to form a basin. This means that the designed rotary kiln allows the gold plaque melt to be immediately discharged without staying in the rotary kiln. The metal melt is made into an iron alloy. Compared with the structure of the pot, the recovery rate of the iron alloy is low and the gold content in the slag is low. Higher. However, the advantage of this non-pot structure is that the amount of rhenium agent added to the target can be reduced, especially as small as 1.2 to 1.5 times the required amount of rhenium. In addition, the carbon monoxide produced by the reduction of Ranke is reduced. It can be saved by burning in the rotary kiln. A special case, and the device used to implement this method. In this case, the general dust formed by the K-net iron factory is for testing. The dust used is formed by the process of manufacturing stainless steel. As the target or material The dust composition is shown in Table 1. (Please read the precautions on the back before filling out this page} Printed by the Consumers Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs, weight 5! Table 1 T. Fe FeO Fe2 ° 3 Cr Ni 2n Pb CP r S 39.6 9.8 45-8 8.1 2.5 0.50 0.10 0.83 0.06 0.14 CaO Si〇2 MnO 8 * 6 4.3 0 * 40 9.3 2.5 18 ™ This paper is based on Λ1 4 Interpreter (CNS) Λ4 grid (2lOX 297 mm) Central standard of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives 4 5 5.5 re A7 ___B7 _ 5. Description of the invention () Preliminary processing of the materials, the above dust is mixed with the powder phase and coking kanji agent in a wet process. After dehydration, the warm compound is fed into Test device. The dust / coke dust ratio is 100/43 by weight. The ratio of coke dust is twice the equivalent of the calculated equivalent of the original.… The device used in this test is a batch rotation as shown in Figure 8. Kiln test furnace. Attention must be paid Although this test furnace is not all the same as the rotary kiln structure of a commercial device, the longitudinal conveying position of the subject in the rotary kiln corresponds to the operating time of the test entropy. Referring to Figure 8, Rotary® has a chamber 54, a furnace 55, —drive tooth key 56, —roller wheel 57, —slip ring 58, —discharge plug 59. —first viewport 60, surveillance camera 61, and a second viewport 62. The inner diameter D of the chamber is 1300 strokes and the length L is 500 mm. In the test, the moisture content of 140 kg of dehydrated cake was 22¾, which was added to the original rotary kiln of 5001C and heated with propane gas as fuel. The rotary kiln K.4rp «i (revolutions per minute) rotates. See Figure 9 for the temperature rise rate of the bed. After the dust (dehydrated cake) has been added, samples of gold smelt melt and slag are taken every 90 minutes and proceeded until a molten product is produced. The analysis of the samples is based on the degree of zinc removal, the degree of resistance, and the degree of metallization. In particular, the degree of zinc removal (the original zinc content has a zinc content) / (the original zinc content) is expressed. The original degree K (original aerobic content) " original aerobic content " The degree of metallization M (existing gold iron) / (existing total iron content) is expressed. Then, after the molten product is generated, the metal melt and the slag are successively deposited. From the analysis of the composition of Jinli melt and slag, the gold ring melt and melt were obtained. -19- This paper's dimensions are applicable to Chinese National Standard (CNS) Λ4 grid (210 × 297 mm) [Order II {Please read the note on the back first Please fill in this page again for matters) 455516 A7 B7 V. Description of the invention (,) Distribution of each metal element between slags. This test was performed five times under the conditions of Baitong to get the test result of Wujie. In the five sister test results, few fluctuations were observed by Fei. Therefore, one set of each test result of M is shown separately on lap 10. Fig. 10 shows the degree of originality, the degree of golden spread, and the degree of zinc removal at different points in time before the melt is formed. Refer to Figure 10, it can be seen that after about 90 minutes since the dust was fed into the rotary kiln, the values of gangrene have reached 90 JK or M each. After about 100 minutes of feeding dust, a metal melt was produced. At this time, the temperature of the bed is between about 12 50 and 1300 C, and the slag is also melted. Table 2 shows the analysis results of the sampling of ferroalloy machine slag after 120 minutes. In Table 2, T.Fe and Me.Fe respectively represent the "total amount" and "metal iron amount J. The sister of ferroalloys is about the same as high carbon. Austenite contains Νί, which is close to Cr stainless steel and non-magnetic. The contents of P and S are between 0.09 and 0.15¾ and 0.05 and 0.14¾, respectively. 羝 Alloys (weight 50 table) 2 C—) ---------- ^ ------ ΐτ ------ ^ (Please read the notes on the back before filling out this page) Staff Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs Printed 蹁 T * Fe Znπ Pb Cr Ni SPC 1 82 * 4 0.016 0.02 6.7 4.2 0,14 0-15 3.3 2 72.0 0-015 0,02 8.0 3,9 0.09 0.14 4.2 3 69.7 0.033 0.03 11.0 4.0 0- 05 0.12 5.4 4 71.0 0.005 0.01] 4.2 3.7 0.09 0 * 03 4,7 5 63 · 4 0.006 0.01 16 * 9 4.0 0-06 0.09 5 · 2 -20-This paper size applies the Chinese National Standard (CNS) ^ < 2V7 Male «) 45 5 5 T'0 " Α7 Β7 V. Description of the invention (, 9) • Table 2 (II) —-Slag (house capacity *:) -—- Test scale number T.Fe Me.Fe Zn Pb Cr Ni CaO Si02 Al2〇3 MgO 1 22.1 19.2 0.006 0.014 9,0 0 .7 21,2 15.1 6.7 X3.4 2 13.1 11.1 · 0-006 0.011 8.5 0.6 24.3 17.2 6.3 17.3 3 18.6 14.6 0.024 0.013 6.6 0,7 18.8 13/8 4.4 13.0 4 17.7 11,0 0.014 0.008 10.2 0.6 20.6 14.2 10.3 14.9 5 22.0 18,3 0.006 0.007 9.6 1.1 23.4 14.5 4 Λ 16.7 The value obtained from the analysis is shown in the following figure. Η 见, Fe, Fe, Fe, 金, 金, gold, etc. 00 Zhao 1 M Rate sum
NN
之 中 金 合 鐵 於 佈 分 於 麽 對 率 收 回 ο 量 含 〇 原率 的比 Γ Γ c C 和和 *1 'N 置 有 含 的 素 元 素屬 17Π-金S”· 中下 物如 理表 處J 被另 f军 收 率)=回 收(¾屬 回率金 屬收示 金回上 於屬示 至金表 的 ' NiThe middle ferritic iron is distributed. The ratio is recovered. The ratio of the original ratio is Γ Γ c C and * 1 'N. The element element contained is 17Π-Gold S ”. Department J was harvested by another army) = recovery (¾ metal recovery rate metal display gold returned to the 'Ni
X 試料號碼 F e回収率[X] N i @収率[« C r回収率[X] 1 97 57 100 2 98 62 100 3 95 70 100 4 92 5 6 100 5 9 6 72 100 經濟部中央標率局負工消費合作社印裂 一收明棄程所體金髙。此 回30發廢製中固點-體因 、的2r本或種物一沸面熔〇 上和72根物中標氣1金而 如Ni與在的廠-之屬另成離 」)6票ΓΑ-則金容汙 及 式 者 解 暸 鐵 在 中 金 合 理鐵序游點被渣製 處網程上沸共溶於 窯在原窯高-他用 轉和還轉和物其接 旋、在旋颳産自直 用塵。在金原侧能 利粉用劑點還游而 以鐵利原沸已下質 可銷再還低為窯物 -、以用得。成轉值 能與中塵等被而去下旋價 所92置粉泥物原除留於有 中在裝礦淤化還而被屬收 圖為和鐵之氧所發靥金回 11別法如成靥段蒸金點以 第分方諸形金應被點沸可 率之物所含反屬沸高， 間 之 -約 大 在 和 賴回 製後 在鋅 , 除 中被 法塵 方粉 用锹 習餌 在和 , 塵 之粉 反礦 。 锘 料之 材成 種形 1 所 為中 作序 中程 序網 程製 網和 本紙乐尺度適用中國國家椋华（CNS ) Λ4現格（210X297公釐） 4 5 55 1 6 Α7 Β7 五、發明説明（w) 饋至高爐或燒結機中。與此類晋用方法比較，本方法為 具有工業上之用途β此外，根據本發明.不但可以利用 鐵合金•而且也可利用低金靨含量而難以氧化之熔渣。 在習用方法中，在酸浸線和鍍鋅程序中所形成之淤泥 .因為雔予脫水，因而甚難再予利用。 在另一方面，根據本發明，反種廢棄材料包括淤泥可 被處理而回收作為有用之材料。此外，也可同時處理曾 被認為難以再利用、曾被焚化和以陸埋處理等各種廢棄 材料。例如，廢棄物可Μ為紙漿廢棄物、家庭粉塵或類 似者。 --------I . ---- *--訂 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印策 -22- 本紙張尺度適用中國國家標準（CNS ) Λ4规格（210><297公釐）X Sample number F e Recovery rate [X] N i @Yield rate [«C r Recovery rate [X] 1 97 57 100 2 98 62 100 3 95 70 100 4 92 5 6 100 5 9 6 72 100 Central standard of the Ministry of Economic Affairs Lead the bureau's work co-operative consumer cooperative to crack down on the gold medals of the abandoned process. This time, 30 rounds of waste solid-point solids, 2r books, or seeds are melted on the boiling surface, and the standard gas in 72 roots is 1 gold, and if Ni and the plant in the factory are separate, they are separated.) 6 votes ΓΑ-The gold-contained dirt and iron solution solves the problem that iron is boiled and co-dissolved in the kiln at the reasonable iron sequence travel point of the slag system, and is soluble in the kiln at the original kiln. Scrape is produced from direct dust. On the side of Jinyuan, the powder can also be used as a powder, and the iron powder has been boiled down and can be sold as low as a kiln. The conversion value can be removed with Zhongchen, etc. The price of the mud and mud is 92. The original mud and mud are left in Youzhong, and the deposit is silted. If the steamed gold point in the Chenghuang section is divided into fractions, the various shapes of gold should be boiled at a high rate, and the interval is about-about Da after the Lai Hui system in the zinc, remove the dust powder Use a spade to bait in, and dust powder antimine. The material of the material is in a variety of shapes 1. The program is in the middle of the program, the program, the network, the paper, and the scale of the paper are applicable to the Chinese national Hua (CNS) Λ 4 grid (210X297 mm) 4 5 55 1 6 Α7 Β7 V. Description of the invention ( w) Feed into the blast furnace or sintering machine. Compared with this method, this method is industrially useful. In addition, according to the present invention, not only ferroalloys can be used, but also slags that are difficult to oxidize due to their low gold content. In the conventional method, the sludge formed in the acid leaching line and the galvanizing process is difficult to reuse because it is dehydrated. In another aspect, according to the present invention, reverse waste materials including sludge can be treated and recycled as useful materials. In addition, various waste materials that were once considered difficult to reuse, incinerated, and landfilled can be treated simultaneously. For example, the waste may be pulp waste, household dust, or the like. -------- I. ---- *-Order (please read the notes on the back before filling out this page) The Central Standards Bureau of the Ministry of Economic Affairs, Peigong Consumer Cooperatives, India 22-This paper size applies to China National Standard (CNS) Λ4 Specification (210 > < 297 mm)